TWI703077B - Film roll body and method for manufacturing film roll body - Google Patents

Film roll body and method for manufacturing film roll body Download PDF

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TWI703077B
TWI703077B TW105137741A TW105137741A TWI703077B TW I703077 B TWI703077 B TW I703077B TW 105137741 A TW105137741 A TW 105137741A TW 105137741 A TW105137741 A TW 105137741A TW I703077 B TWI703077 B TW I703077B
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film
peeling
adhesive film
release
roll body
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TW105137741A
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Chinese (zh)
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TW201731746A (en
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荒木雄太
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日商迪睿合股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/40Adhesives in the form of films or foils characterised by release liners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H75/00Storing webs, tapes, or filamentary material, e.g. on reels
    • B65H75/02Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
    • B65H75/04Kinds or types
    • B65H75/08Kinds or types of circular or polygonal cross-section
    • B65H75/14Kinds or types of circular or polygonal cross-section with two end flanges
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02Electrically-conducting adhesives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/10Adhesives in the form of films or foils without carriers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B5/00Non-insulated conductors or conductive bodies characterised by their form
    • H01B5/14Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature

Abstract

本發明提供一種可獲得優異之暫貼性之膜捲裝體、及該膜捲裝體之製造方法。膜捲裝體具備:接著膜(2),其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面(凹面)、及形成於第1面之相反側之平坦之第2面(平坦面);剝離膜(3),其具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面;及卷盤(4),其將接著膜及剝離膜捲裝於卷芯;膜捲裝體係以接著膜2之第1面與剝離膜(3)之重剝離面接觸、並且接著膜(2)之第2面與剝離膜(3)之輕剝離面接觸之方式捲裝而成。 The present invention provides a film roll body that can obtain excellent temporary stickiness, and a method for manufacturing the film roll body. The film roll body is provided with: an adhesive film (2) having a first surface (concave surface) formed at both ends of the width direction along the length direction and having a thickness greater than the thickness of the central portion, and formed on the opposite side of the first surface A flat second surface (flat surface); a peeling film (3), which has a heavy peeling surface with a relatively high peeling force and a light peeling surface with a relatively low peeling force; and a reel (4), which will adhere to the film And the release film roll on the core; the film roll system uses the first side of the adhesive film 2 to contact the heavy release surface of the release film (3), and the second side of the adhesive film (2) and the release film (3) Rolled by lightly peeling surface contact.

Description

膜捲裝體、及膜捲裝體之製造方法 Film roll body and method for manufacturing film roll body

本發明係關於一種捲繞有ACF(Anisotropic Conductive Film,異向性導電膜)、NCF(Non Conductive Film,非導電性膜)等接著膜之膜捲裝體、及膜捲裝體之製造方法。本申請案係以2015年11月20日於日本提出申請之日本專利申請案號特願2015-228229為基礎而主張優先權,該申請案以參照之方式引用於本申請案。 The present invention relates to a film roll body wound with adhesive films such as ACF (Anisotropic Conductive Film) and NCF (Non Conductive Film), and a method for manufacturing the film roll body. This application claims priority based on Japanese Patent Application No. Japanese Patent Application No. 2015-228229 filed in Japan on November 20, 2015, and this application is incorporated into this application by reference.

習知,ACF、NCF等接著膜係經過將寬幅之接著膜裁斷(切條)成例如寬度為1~3mm之窄幅之切條步驟而獲得。切條步驟後之接著膜之一面沿長條方向隆起,另一面平坦(例如參照專利文獻1)。 Conventionally, adhesive films such as ACF, NCF, etc. are obtained by cutting (cutting) a wide adhesive film into narrow strips with a width of 1 to 3 mm, for example. After the slitting step, one surface of the adhesive film is raised in the longitudinal direction, and the other surface is flat (for example, refer to Patent Document 1).

即,切條步驟後之接著膜具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之一面(凹面)、及平坦之另一面(平坦面)。 That is, the adhesive film after the slitting step has one surface (concave surface) formed in the longitudinal direction such that the thickness of both ends in the width direction is greater than the thickness of the central portion, and the other flat surface (flat surface).

於使用捲繞有此種接著膜之膜捲裝體之情形時,通常,於接著膜之平坦面與剝離膜接著之狀態下被拉出。因此,於基板等被黏著材貼附接著膜之凹面,難以獲得優異之暫貼性。 In the case of using a film roll body wound with such an adhesive film, it is usually pulled out in a state where the flat surface of the adhesive film is bonded to the release film. Therefore, it is difficult to obtain excellent temporary adhesion properties on the concave surface of the adhesive film attached to the substrate or the like.

[專利文獻1]日本特開2012-102278號公報 [Patent Document 1] JP 2012-102278 A

本發明係解決上述習知技術中之課題者,其提供一種可獲得優異之暫貼性之膜捲裝體、及該膜捲裝體之製造方法。 The present invention solves the above-mentioned problems in the prior art, and provides a film roll body that can obtain excellent temporary stickiness, and a manufacturing method of the film roll body.

為解決上述課題,本發明之膜捲裝體之製造方法之特徵在於,具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面、與形成於該第1面之相反側的平坦之第2面;剝離膜,其具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面;及卷芯,其捲裝上述接著膜及上述剝離膜;以上述接著膜之第1面與上述剝離膜之重剝離面接觸、並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸之方式捲裝於上述卷芯而成。 In order to solve the above-mentioned problems, the method for manufacturing a film roll body of the present invention is characterized by comprising: an adhesive film having a first surface formed at both ends of the width direction along the longitudinal direction and having a thickness greater than the thickness of the central portion, and A flat second surface formed on the opposite side of the first surface; a peeling film having a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force; and a roll core, which is packaged as described above Adhesive film and said release film; wound on said core such that the first surface of said adhesive film is in contact with the heavy release surface of said release film, and the second surface of said adhesive film is in contact with the light release surface of said release film Become.

又,本發明之膜捲裝體之製造方法之特徵在於,其係將具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面、與形成於該第1面之相反側之平坦之第2面的接著膜、及具有剝離力相對較高之重剝離面與剝離力相對較低之輕剝離面的剝離膜,以上述接著膜之第1面與上述剝離膜之重剝離面接觸、並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸之方式捲裝於卷芯。 In addition, the method of manufacturing a film roll body of the present invention is characterized in that it has a first surface formed on both ends of the longitudinal direction in the width direction and whose thickness is greater than the thickness of the central portion, and formed on the first surface The adhesive film with the flat second side on the opposite side, and the release film with the heavy peeling surface with relatively high peeling force and the light peeling surface with relatively low peeling force, the first surface of the adhesive film and the peeling film The heavy peeling surface is in contact with the adhesive film and the second surface of the adhesive film is in contact with the light peeling surface of the peeling film.

又,本發明之連接構造體之製造方法之特徵在於:自如下述之膜捲裝體拉出下述接著膜之第1面與下述剝離膜之重剝離面接觸之積層 膜,將下述接著膜之第2面暫貼於第1電路構件,將剝離膜剝離,將第2電路構件載置於下述接著膜上並正式壓接;其中,該膜捲裝體具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度的第1面、與形成於該第1面之相反側的平坦之第2面;剝離膜,其具有剝離力相對較高之重剝離面與剝離力相對較低之輕剝離面;以及卷芯,其捲裝上述接著膜及上述剝離膜;上述接著膜之第1面與上述剝離膜之重剝離面接觸並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸。 In addition, the method of manufacturing the connection structure of the present invention is characterized in that the following film roll body is drawn from the following laminated film in which the first surface of the following adhesive film is in contact with the heavy peeling surface of the following release film Film, temporarily stick the second side of the following adhesive film to the first circuit member, peel off the release film, place the second circuit member on the following adhesive film and formally press-bond; wherein the film roll body has : Adhesive film, which has a first surface formed in the longitudinal direction such that the thickness of both ends in the width direction is greater than the thickness of the central portion, and a flat second surface formed on the opposite side of the first surface; release film, which A heavy peeling surface with a relatively high peeling force and a light peeling surface with a relatively low peeling force; and a core that wraps the adhesive film and the peeling film; the heavy peeling of the first surface of the adhesive film and the peeling film Face contact and the second surface of the adhesive film is in contact with the light peeling surface of the release film.

根據本發明,於接著膜之凹面與剝離膜接著之狀態下被拉出,並且於基板等被黏著材上貼附接著膜之平坦面,故可獲得優異之暫貼性。 According to the present invention, the concave surface of the adhesive film is pulled out in a state where the release film is bonded, and the flat surface of the adhesive film is attached to the substrate or other adhered material, so that excellent temporary adhesion can be obtained.

1‧‧‧膜捲裝體 1‧‧‧Film roll body

2‧‧‧接著膜 2‧‧‧Adhesive film

3‧‧‧剝離膜 3‧‧‧Peeling film

4‧‧‧卷盤 4‧‧‧Reel

5‧‧‧卷芯 5‧‧‧Core

6‧‧‧凸緣 6‧‧‧Flange

7‧‧‧覆蓋膜 7‧‧‧Cover film

圖1係示意性地表示膜捲裝體之一例之立體圖。 Fig. 1 is a perspective view schematically showing an example of a film roll.

圖2係示意性地表示接著膜之剖面圖。 Fig. 2 schematically shows a cross-sectional view of the adhesive film.

圖3係示意性地表示自膜捲裝體拉出之接著膜之剖面圖。 Fig. 3 schematically shows a cross-sectional view of the adhesive film drawn from the film roll body.

圖4係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第1構成例之膜捲裝體之最外周側的剖面圖。 4 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the first configuration example on the A-A section of the film package shown in Fig. 2.

圖5係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第1構成例之膜捲裝體之於拉出時之最外周側的剖面圖。 Fig. 5 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the first configuration example on the A-A section of the film package shown in Fig. 2 at the time of drawing out.

圖6係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第2構成例之膜捲裝體之於拉出時之最外周側的剖面圖。 Fig. 6 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the second configuration example on the A-A cross section of the film package shown in Fig. 2 at the time of drawing out.

圖7係示意性地表示於圖2所示之膜捲裝體之A-A剖面上接著膜溢出且附著於凸緣之狀態之剖面圖。 Fig. 7 is a cross-sectional view schematically showing a state where the film overflows and adheres to the flange on the A-A section of the film roll body shown in Fig. 2.

圖8係示意性地表示寬幅之接著膜(原料片)之局部剖面圖。 Fig. 8 schematically shows a partial cross-sectional view of a wide adhesive film (raw sheet).

圖9係示意性地表示切條步驟之接著膜之剖面圖。 Fig. 9 is a cross-sectional view schematically showing the adhesive film in the slitting step.

以下,按照下述順序對本發明之實施形態詳細地進行說明。 Hereinafter, embodiments of the present invention will be described in detail in the following order.

1.膜捲裝體 1. Film roll body

2.膜捲裝體之製造方法 2. Manufacturing method of film roll body

3.連接構造體之製造方法 3. Manufacturing method of connecting structure

4.實施例 4. Example

<1.膜捲裝體> <1. Film roll body>

本實施形態之膜捲裝體具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面(凹面)、及形成於第1面之相反側之平坦之第2面(平坦面);剝離膜,其具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面;及卷盤構件,其將接著膜及剝離膜捲裝於卷芯;該膜捲裝體係以接著膜之第1面與剝離膜之重剝離面接觸、並且接著膜之第2面與剝離膜之輕剝離面接觸之方式捲裝而成。藉此,於接著膜之凹面與支持膜接著之狀態下被拉出,並且於基板等被黏著材貼附接著膜之平坦面,故可獲得優異之暫貼性。 The film roll body of this embodiment includes: an adhesive film having a first surface (concave surface) formed at both ends in the width direction along the length direction and having a thickness greater than the thickness of the center portion, and formed on the opposite side of the first surface The flat second surface (flat surface); the peeling film, which has a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force; and a reel member, which rolls the adhesive film and the peeling film It is installed in the core; the film roll system is rolled up in such a way that the first side of the adhesive film is in contact with the heavy peeling surface of the release film, and then the second side of the film is in contact with the light release surface of the release film. Thereby, the concave surface of the adhesive film is pulled out in a state where the support film is bonded, and an adhesive material such as a substrate is attached to the flat surface of the adhesive film, so that excellent temporary adhesion can be obtained.

圖1係示意性地表示本實施形態之膜捲裝體之一例之立體圖。如圖1所示,膜捲裝體1係藉由將接著膜2及剝離膜3捲繞於卷盤4 而形成。 Fig. 1 is a perspective view schematically showing an example of the film package of this embodiment. As shown in Figure 1, the film roll body 1 is formed by winding the adhesive film 2 and the release film 3 on the reel 4 And formed.

圖2係示意性地表示接著膜之剖面圖,圖3係示意性地表示自膜捲裝體拉出時之接著膜之剖面圖。 FIG. 2 is a schematic cross-sectional view of the adhesive film, and FIG. 3 is a schematic cross-sectional view of the adhesive film when it is pulled out from the film roll.

接著膜2具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面(凹面)、與形成於第1面之相反側之平坦之第2面(平坦面)。如圖2所示,接著膜2之寬度方向之剖面為凹形狀,於凹面之寬度方向之兩端形成有沿長度方向連續之凸部2a,且於凹面之寬度方向之中央部形成有沿長度方向連續之凹部2b。凹面之寬度方向之兩端之凸部2a之合計之接觸寬度Sa(Sa1+Sa2)例如為平坦面之寬度方向之接觸寬度Sb的10~60%。又,平坦面之寬度方向之接觸寬度Sb例如為0.6mm~5.0mm。又,凸部2a與凹部2b之高度h例如為5μm以上,其上限值為膜厚度之70%以下。又,接著膜之長度例如為50m~5000m。 Next, the film 2 has a first surface (concave surface) formed along the length direction such that the thickness of both ends in the width direction is greater than the thickness of the central portion, and a flat second surface (flat surface) formed on the opposite side of the first surface. As shown in Fig. 2, the cross-section of the adhesive film 2 in the width direction is a concave shape. The two ends of the concave surface in the width direction are formed with convex portions 2a that are continuous in the length direction, and the central portion in the width direction of the concave surface is formed along the length. Concavity 2b with continuous direction. The total contact width Sa (Sa1+Sa2) of the convex portions 2a at both ends in the width direction of the concave surface is, for example, 10 to 60% of the contact width Sb in the width direction of the flat surface. In addition, the contact width Sb in the width direction of the flat surface is, for example, 0.6 mm to 5.0 mm. Moreover, the height h of the convex part 2a and the recessed part 2b is 5 micrometers or more, for example, and the upper limit value is 70% or less of a film thickness. In addition, the length of the adhesive film is, for example, 50 m to 5000 m.

作為接著膜2,可舉出例如異向性導電膜(ACF:Anisotropic Conductive Film)、接著劑膜(NCF:Non Conductive Film)、及連接太陽電池之電極與接合線之導電性接著膜等。 Examples of the adhesive film 2 include an anisotropic conductive film (ACF: Anisotropic Conductive Film), an adhesive film (NCF: Non Conductive Film), and a conductive adhesive film for connecting the electrode of the solar cell and the bonding wire.

剝離膜3係成型為帶狀且支持接著膜之支持膜。作為用於剝離膜3之基材,可舉出例如PET(Poly Ethylene Terephthalate,聚對苯二甲酸乙二酯)、OPP(Oriented Polypropylene,定向聚丙烯)、PMP(Poly-4-methlpentene-1,聚4-甲基戊烯-1)、PTFE(Polytetrafluoroethylene,聚四氟乙烯)等。 The release film 3 is a support film formed into a belt shape and supporting the adhesive film. As the base material used for the release film 3, for example, PET (Poly Ethylene Terephthalate, polyethylene terephthalate), OPP (Oriented Polypropylene, oriented polypropylene), PMP (Poly-4-methlpentene-1, Poly 4-methylpentene-1), PTFE (Polytetrafluoroethylene, polytetrafluoroethylene), etc.

剝離膜3具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面。此處,所謂剝離力相對較高之重剝離面係指於相同條件測 定剝離膜3之兩面之剝離力時剝離力較高之面,所謂剝離力相對較低之輕剝離面係指於相同條件測定剝離膜3之兩面之剝離力時剝離力較低之面。重剝離面及輕剝離面之剝離力例如能夠根據聚矽氧等剝離劑之種類、基材之表面粗糙度(Rz)等而調整。又,作為剝離力之測定方法,可舉出180°剝離強度試驗(JIS K 6854-2)、90°剝離強度試驗(JIS K 6854-1)等。 The peeling film 3 has a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force. Here, the so-called heavy peeling surface with relatively high peeling force refers to the measurement under the same conditions When the peeling force of both sides of the peeling film 3 is determined, the peeling force is higher. The so-called light peeling surface with relatively low peeling force refers to the surface with the lower peeling force when the peeling force of the peeling film 3 is measured under the same conditions. The peeling force of the heavy peeling surface and the light peeling surface can be adjusted according to, for example, the type of release agent such as silicone, the surface roughness (Rz) of the substrate, and the like. In addition, as a method for measuring the peeling force, a 180° peel strength test (JIS K 6854-2), a 90° peel strength test (JIS K 6854-1), etc. can be mentioned.

於本實施形態中,將凹面與重剝離面之間之寬度方向之接觸寬度乘以重剝離面之剝離力所得的值大於將平坦面與輕剝離面之間之寬度方向之接觸寬度乘以輕剝離面之剝離力所得的值。具體而言,自「將凹面與重剝離面之間之寬度方向之接觸寬度Sa乘以重剝離面之180°剝離力Ta所得之值」減去「將平坦面與輕剝離面之間之寬度方向之接觸寬度Sb乘以輕剝離面之180°剝離力Tb所得之值」的差量值[(Ta×Sa)-(Tb×Sb)]較佳為0.3mN以上且4.5mN以下,更佳為0.5mN以上且3.0mN以下,進而佳為1.0mN以上且2.5mN以下。藉此,於接著膜之凹面與支持膜接著之狀態下被拉出,並且於基板等被黏著材上貼附接著膜之平坦面,故可獲得優異之暫貼性。 In this embodiment, the value obtained by multiplying the contact width in the width direction between the concave surface and the heavy peeling surface by the peeling force of the heavy peeling surface is greater than multiplying the light contact width between the flat surface and the light peeling surface in the width direction. The value obtained from the peeling force of the peeling surface. Specifically, "the value obtained by multiplying the width of the contact width Sa between the concave surface and the heavy peeling surface by the 180° peeling force Ta of the heavy peeling surface" subtracts "the width between the flat surface and the light peeling surface" The difference of the value obtained by multiplying the contact width Sb in the direction by the 180° peeling force Tb of the light peeling surface [(Ta×Sa)-(Tb×Sb)] is preferably 0.3mN or more and 4.5mN or less, more preferably It is 0.5 mN or more and 3.0 mN or less, more preferably 1.0 mN or more and 2.5 mN or less. Thereby, the concave surface of the adhesive film and the support film are pulled out, and the flat surface of the adhesive film is stuck on the substrate or other adhered material, so that excellent temporary adhesion can be obtained.

卷盤4具有捲取接著膜2及剝離膜3之筒狀之卷芯5、及分別設置於卷芯5之兩端之板狀之凸緣6。卷芯5具有用以使卷盤4旋轉之旋轉軸插入之軸孔。於卷芯5,連接有接著膜2或剝離膜3之長度方向之一端部,且捲繞接著膜2及剝離膜3。 The reel 4 has a cylindrical core 5 for winding the adhesive film 2 and the release film 3, and plate-shaped flanges 6 respectively provided at both ends of the core 5. The core 5 has a shaft hole for inserting a rotating shaft for rotating the reel 4. One end in the longitudinal direction of the adhesive film 2 or the release film 3 is connected to the winding core 5, and the adhesive film 2 and the release film 3 are wound.

卷芯5及凸緣6例如可使用各種塑膠材料而形成。凸緣6亦可在其與接著膜2接觸之面實施靜電處理。作為實施靜電處理之方法,可舉出例如將聚噻吩等化合物塗佈於凸緣6之方法等。再者,圖1所示之 膜捲裝體設為將接著膜捲裝於兩端具有凸緣6之卷芯5之構成,但亦可為將接著膜捲裝於無凸緣之卷芯之構成。 The core 5 and the flange 6 can be formed using various plastic materials, for example. The flange 6 may also be subjected to electrostatic treatment on its contact surface with the adhesive film 2. As a method of carrying out the electrostatic treatment, for example, a method of applying a compound such as polythiophene to the flange 6 and the like. Furthermore, as shown in Figure 1 The film roll body has a structure in which an adhesive film is wound on a core 5 having flanges 6 at both ends, but it may be a structure in which an adhesive film is wound on a core without flanges.

[第1構成例] [First configuration example]

圖4係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第1構成例之膜捲裝體之最外周側的剖面圖。如圖4所示,剝離膜3係於寬度方向上接著膜2之凹面與重剝離面以規定之接觸寬度Sa接觸,並且接著膜2之平坦面與輕剝離面以規定之接觸寬度Sb接觸。 4 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the first configuration example on the A-A section of the film package shown in Fig. 2. As shown in FIG. 4, the release film 3 is in contact with the concave surface of the film 2 and the heavy peeling surface in the width direction with a predetermined contact width Sa, and the flat surface of the film 2 and the light peeling surface are in contact with the predetermined contact width Sb.

該第1構成例之膜捲裝體係藉由將接著膜2之平坦面與剝離膜3之輕剝離面接觸之積層膜以接著膜2側成為內周側之方式捲裝而構成。 The film roll system of the first configuration example is configured by winding the laminated film in which the flat surface of the adhesive film 2 and the lightly peelable surface of the release film 3 are in contact with the adhesive film 2 side as the inner peripheral side.

圖5係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第1構成例之膜捲裝體於拉出時之最外周側之剖面圖。圖5所示,最外周之剝離膜3被剝下1周量,且於拉出時接著膜2在與內周側之剝離膜3接觸之狀態下被拉出。 Fig. 5 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the first configuration example on the A-A section of the film package shown in Fig. 2 when it is drawn out. As shown in FIG. 5, the peeling film 3 on the outermost periphery is peeled off for one week, and the adhesive film 2 is pulled out while being in contact with the peeling film 3 on the inner periphery when being pulled out.

[第2構成例] [Second configuration example]

圖6係示意性地表示於圖2所示之膜捲裝體之A-A剖面上第2構成例之膜捲裝體於拉出時之最外周側的剖面圖。該第2構成例之膜捲裝體係藉由將接著膜2之平坦面與剝離膜3之輕剝離面接觸之積層膜以接著膜2側成為外周側之方式捲裝而構成。圖6所示,最外周之接著膜2被剝下1周量,且於拉出時接著膜2在與外周側之剝離膜3接觸之狀態下被拉出。 Fig. 6 is a cross-sectional view schematically showing the outermost peripheral side of the film package of the second configuration example on the A-A section of the film package shown in Fig. 2 when it is drawn out. The film roll system of the second configuration example is configured by wrapping the laminated film in which the flat surface of the adhesive film 2 and the lightly peelable surface of the release film 3 are in contact with each other so that the adhesive film 2 side becomes the outer peripheral side. As shown in FIG. 6, the adhesive film 2 on the outermost periphery is peeled off for one week, and the adhesive film 2 is pulled out while being in contact with the peeling film 3 on the outer periphery side when pulling out.

[關於耐黏連性] [About blocking resistance]

圖7係示意性地表示於圖2所示之膜捲裝體之A-A剖面上接著膜溢出且附著於凸緣之狀態的剖面圖。膜捲裝體有時藉由因溫度而導致之伸縮、 拉出操作等而產生接著膜2之捲壓。其結果為,有時接著膜2之樹脂(接著劑成分)向「沿樹脂之長度方向的寬度方向之一端」更靠外側流動,且自剝離膜3之側面溢出。圖7所示,若接著膜2之樹脂自剝離膜3之側面溢出,則有時接著膜之樹脂會附著於卷盤之凸緣6之側面,產生使接著膜無法正常地拉出之黏連。 Fig. 7 is a cross-sectional view schematically showing a state where the film overflows and adheres to the flange on the A-A section of the film roll body shown in Fig. 2. The film roll body sometimes expands and contracts due to temperature, The drawing operation and the like cause the rolling pressure of the adhesive film 2. As a result, the resin (adhesive component) of the adhesive film 2 may flow to the "one end in the width direction along the length of the resin" to the outside, and may overflow from the side surface of the release film 3. As shown in Fig. 7, if the resin of the adhesive film 2 overflows from the side of the peeling film 3, the resin of the adhesive film will sometimes adhere to the side of the flange 6 of the reel, resulting in adhesion that prevents the adhesive film from being pulled out normally. .

本實施形態之膜捲裝體將具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面(凹面)、與形成於第1面之相反側的平坦之第2面(平坦面)的接著膜捲裝。因此,如圖2、3所示,於接著膜2之凹面與剝離膜3之間,沿長度方向連續地形成有凹部2b。如此,於接著膜2之凹面與剝離膜3之間形成有由凹部2b所產生之空隙,藉此於產生捲壓時,可緩和捲壓之力,並且可使接著膜2之樹脂流動至由凹部2b所產生之空隙。因此,可抑制樹脂之溢出,從而可獲得優異之耐黏連性。 The film roll body of this embodiment has a first surface (concave surface) formed at both ends in the width direction along the length direction and having a thickness greater than the thickness of the central portion, and a flat second surface formed on the opposite side of the first surface. Adhesive film roll on the surface (flat surface). Therefore, as shown in FIGS. 2 and 3, between the concave surface of the adhesive film 2 and the release film 3, the concave part 2b is formed continuously along the longitudinal direction. In this way, a gap created by the recessed portion 2b is formed between the concave surface of the adhesive film 2 and the release film 3, whereby when the rolling pressure is generated, the force of the rolling pressure can be relieved, and the resin of the adhesive film 2 can flow to The void created by the recess 2b. Therefore, the overflow of the resin can be suppressed, and excellent blocking resistance can be obtained.

又,根據第1構成例之膜捲裝體,於拉出膜之方向側存在有接著膜,故能夠以剝離膜3將接著膜2上拉之方式拉出。因此,即便於凸緣6附著有樹脂,亦能夠以可消除黏連之此種較強之力將其剝下,從而可獲得優異之耐黏連性。 In addition, according to the film roll body of the first configuration example, since the adhesive film is present on the side in the direction in which the film is drawn out, the adhesive film 2 can be pulled up by the peeling film 3. Therefore, even if resin is attached to the flange 6, it can be peeled off with such a strong force that can eliminate the adhesion, so that excellent adhesion resistance can be obtained.

<2.膜捲裝體之製造方法> <2. Manufacturing method of film roll package>

其次,對膜捲裝體之製造方法進行說明。本實施形態之膜捲裝體之製造方法係將具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面(凹面)與形成於第1面之相反側之平坦之第2面(平坦面)的接著膜、及具有剝離力相對較高之重剝離面與剝離力相對較低之輕剝離面的剝離膜以接著膜之第1面與剝離膜之重剝離面接觸、並且接著膜之第2 面與剝離膜之輕剝離面接觸的方式捲裝於卷盤構件之卷芯。 Next, the manufacturing method of the film roll body is demonstrated. The method of manufacturing the film roll body of this embodiment is to have a first surface (concave surface) formed on the opposite side of the first surface and the first surface (concave surface) formed on the opposite side of the first surface with the thickness of both ends formed in the width direction along the length direction being greater than the thickness of the central part. Adhesive film on the second side (flat surface), and release film with a relatively high peeling force and a light peeling surface with relatively low peeling force. The first side of the adhesive film and the heavy peeling surface of the release film Contact and adhere to the second film It is wound on the core of the reel member in such a way that the surface is in contact with the light peeling surface of the release film.

首先,準備具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面之剝離膜,且於輕剝離面上以成為規定之厚度之方式塗佈接著膜之組成物。藉此,於捲裝後拉出時,能夠使接著膜轉接著於重剝離面。作為接著膜之組成物,可使用ACF(Anisotropic Conductive Film)、NCF(Non Conductive Film)等公知者。 First, prepare a release film having a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force, and apply the composition of the adhesive film on the light peeling surface to have a predetermined thickness. Thereby, when pulling out after the package, the adhesive film can be transferred to the heavy peeling surface. As the composition of the adhesive film, known ones such as ACF (Anisotropic Conductive Film) and NCF (Non Conductive Film) can be used.

圖8係示意性地表示寬幅之接著膜(原料片)之局部剖面圖。如圖8所示,於形成寬幅之接著膜(原料片)之後,由於裁斷時異物混入,故較佳為於接著膜上貼附覆蓋膜7。 Fig. 8 schematically shows a partial cross-sectional view of a wide adhesive film (raw sheet). As shown in FIG. 8, after forming a wide adhesive film (raw material sheet), since foreign matter is mixed in during cutting, it is preferable to attach the cover film 7 on the adhesive film.

圖9係示意性地表示切條步驟之接著膜之剖面圖。於切條步驟中,將寬幅之接著膜裁斷成規定之寬度。於該裁斷時,因剝離膜3與覆蓋膜7之強度差、切入刃等之影響而於接著膜形成凹面。由此,於自膜上方觀察凹面之情形時,有時可觀察到與長度方向處於大致平行之表示凹部之階差之線。再者,表示凹部之階差之線亦有為直線之情形,但亦有一部分彎曲、或一部分中斷,存在有非直線之部分之情形。於裁斷後,剝下覆蓋膜7,將接著膜2及剝離膜3捲裝於卷盤4,藉此可獲得膜捲裝體1。 Fig. 9 is a cross-sectional view schematically showing the adhesive film in the slitting step. In the cutting step, the wide adhesive film is cut into a prescribed width. At the time of this cutting, a concave surface is formed in the adhesive film due to the influence of the strength difference between the release film 3 and the cover film 7 and the cutting blade. Therefore, when the concave surface is observed from above the film, a line representing the step difference of the concave portion that is substantially parallel to the longitudinal direction may be observed. Furthermore, the line representing the step difference of the recess may also be straight, but some may be bent or some may be interrupted, and there may be non-straight parts. After cutting, the cover film 7 is peeled off, and the adhesive film 2 and the release film 3 are wound on the reel 4, whereby the film roll body 1 can be obtained.

此處,圖4所示之第1構成例之膜捲裝體可藉由將接著膜2之平坦面與剝離膜3之輕剝離面接觸之積層膜以接著膜2側成為內周側之方式捲裝於卷盤而獲得。 Here, the film roll body of the first configuration example shown in FIG. 4 can be a laminated film in which the flat surface of the adhesive film 2 is in contact with the light release surface of the release film 3 so that the adhesive film 2 side becomes the inner peripheral side. It is obtained by mounting on a reel.

又,圖6所示之第2構成例之膜捲裝體可藉由將接著膜2之平坦面與剝離膜3之輕剝離面接觸之積層膜以接著膜2側成為外周側之方式捲裝於卷盤而獲得。 In addition, the film roll body of the second configuration example shown in FIG. 6 can be wound with a laminate film in which the flat surface of the adhesive film 2 is in contact with the light release surface of the release film 3 so that the adhesive film 2 side becomes the outer peripheral side Obtained on reel.

又,亦可藉由將自第1構成例或第2構成例之膜捲裝體拉出之接著膜2之凹面與剝離膜3之重剝離面接觸之積層膜,以接著膜2側成為外周側或內周側之方式捲裝於其他卷盤而獲得。 In addition, a laminated film in which the concave surface of the adhesive film 2 drawn from the film roll body of the first configuration example or the second configuration example is in contact with the heavy peeling surface of the release film 3 may be used to make the adhesive film 2 side the outer periphery It is obtained by winding it on other reels by means of side or inner circumference side.

<3.連接構造體之製造方法> <3. Manufacturing method of connecting structure>

本實施形態之連接構造體之製造方法係自如下述之膜捲裝體,拉出下述接著膜之第1面與剝離膜之重剝離面接觸之積層膜,將下述接著膜之第2面暫貼於第1被黏著體,將剝離膜剝離,將第2電路構件載置於接著膜上並正式壓接;其中,膜捲裝體具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度的第1面(凹面)與形成於第1面之相反側之平坦的第2面(平坦面);剝離膜,其具有剝離力相對較高之重剝離面與剝離力相對較低之輕剝離面;以及,卷盤構件,其將接著膜及剝離膜捲裝於卷芯;該膜捲裝體係以接著膜之第1面與剝離膜之重剝離面接觸並且接著膜之第2面與剝離膜之輕剝離面接觸之方式捲裝而成。 The manufacturing method of the connection structure of this embodiment is to pull out the laminated film in which the first side of the following adhesive film is in contact with the heavy peeling surface of the release film, and the second of the following adhesive film The surface is temporarily attached to the first adherend, the release film is peeled off, and the second circuit member is placed on the adhesive film and formally crimped; wherein the film roll body includes: an adhesive film having a width formed along the length direction The first surface (concave surface) whose thickness at both ends of the direction is greater than that of the central portion and the flat second surface (flat surface) formed on the opposite side of the first surface; release film, which has relatively high peeling force The heavy peeling surface and the light peeling surface with relatively low peeling force; and, the reel member, which rolls the adhesive film and the release film on the core; the film roll system uses the first side of the adhesive film and the weight of the release film It is rolled up in such a way that the peeling surface is in contact with the second surface of the film and the light peeling surface of the peeling film.

第1電路構件及第2電路構件並無特別限制,可根據目的而適當選擇。作為第1電路構件,可舉出例如電漿顯示面板(PDP)用途、LCD(Liquid Crystal Display)面板用途等之玻璃基板、印刷配線板(PWB)等。又,作為第2電路構件,可舉出例如COF(Chip On Film)等撓性基板(FPC:Flexible Printed Circuits)、帶式載體封裝(TCP)基板、IC(Integrated Circuit)等。 The first circuit member and the second circuit member are not particularly limited, and can be appropriately selected according to the purpose. Examples of the first circuit member include glass substrates and printed wiring boards (PWB) for plasma display panel (PDP) applications, LCD (Liquid Crystal Display) panel applications, and the like. Moreover, as the second circuit member, for example, flexible printed circuits (FPC: Flexible Printed Circuits) such as COF (Chip On Film), tape carrier package (TCP) substrates, IC (Integrated Circuit), and the like can be mentioned.

根據本實施形態之連接構造體之製造方法,將接著膜之平坦面貼附於第1電路構件,故可獲得優異之暫貼性。又,於正式壓接時藉由第2電路構件之壓接而使接著膜之凹面消失,故可獲得優異之接著強度。 According to the manufacturing method of the connection structure of the present embodiment, the flat surface of the adhesive film is attached to the first circuit member, so that excellent temporary attachability can be obtained. In addition, the concave surface of the adhesive film is eliminated by the crimping of the second circuit member during the actual crimping, so that excellent adhesive strength can be obtained.

<4.實施例> <4. Example>

[實施例] [Example]

<4.1 第1實施例> <4.1 First Embodiment>

以下,對本發明之第1實施例進行說明。於第1實施例中,使用剝離力不同之剝離膜,將自由基系ACF以所謂向內捲之構成進行捲繞,製作膜捲裝體。然後,對拉出ACF時之ACF之轉接著性、及暫貼性進行評價。再者,本發明並不限定於該等實施例。 Hereinafter, the first embodiment of the present invention will be described. In the first example, release films with different peeling forces were used, and the radical-based ACF was wound in a so-called inward winding configuration to produce a film package. Then, the ACF's transferability and temporary adhesion when the ACF is pulled out are evaluated. Furthermore, the present invention is not limited to these embodiments.

[剝離膜之剝離力之測定] [Measurement of peeling force of peeling film]

使用與實施例相同之自由基系ACF組成物而測定剝離膜之剝離力。自由基系ACF組成物係藉由將苯氧樹脂(商品名:YP-50,新日鐵化學(股)製造)50質量份、2官能基丙烯酸單體(商品名:A-200,新中村化學(股)製造)20質量份、丙烯酸胺酯(商品名:U-2PPA,新中村化學(股)製造)20質量份、過氧化二月桂醯(商品名:Nyper-BW,日本油脂(股)製造)5質量份、及導電性粒子(品名;AUL704,積水化學工業公司製造)5質量份以通常方法均勻地混合而獲得。將該自由基系ACF組成物以乾燥後之厚度成為25μm之方式塗佈於約38μm厚度之未剝離處理之PET膜上,使其乾燥,製作出寬度5cm之附PET之自由基系ACF。 Using the same radical-based ACF composition as in the examples, the peeling force of the peeling film was measured. The radical-based ACF composition is made of 50 parts by mass of phenoxy resin (trade name: YP-50, manufactured by Nippon Steel Chemical Co., Ltd.) and a bifunctional acrylic monomer (trade name: A-200, Shinnakamura Chemical Co., Ltd. 20 parts by mass, urethane acrylate (trade name: U-2PPA, manufactured by Shinnakamura Chemical Co., Ltd.) 20 parts by mass, dilaurel peroxide (trade name: Nyper-BW, Nippon Oil & Fats Co., Ltd.) ) Manufacturing) 5 parts by mass and 5 parts by mass of conductive particles (product name: AUL704, manufactured by Sekisui Chemical Industry Co., Ltd.) are uniformly mixed and obtained by a normal method. The radical-based ACF composition was coated on an unpeeled PET film with a thickness of approximately 38 μm so that the thickness after drying became 25 μm, and dried to produce a radical-based ACF with PET with a width of 5 cm.

使用2kg輥將附PET之自由基系ACF貼附於寬度5cm之剝離膜之測定面,依據180°剝離強度試驗(JIS K 6854-2)而測定30分鐘後之剝離力(帶剝離,剝離角度180°,剝離速度300mm/min)。 Use a 2kg roller to attach the free radical ACF with PET to the measuring surface of a peeling film with a width of 5 cm. According to the 180° peel strength test (JIS K 6854-2), measure the peeling force after 30 minutes (tape peeling, peeling angle) 180°, peeling speed 300mm/min).

[轉接著性之評價] [Evaluation of transferability]

自卷盤將ACF拉出長度200m,測定於ACF之凹面接著有剝離膜之轉 接著狀態之長度,算出轉接著比率。然後,根據下述指標進行轉接著性之評價。 Pull out the ACF from the reel to a length of 200m, and measure it on the concave surface of the ACF followed by the rotation of the release film After the length of the state, calculate the transfer rate. Then, the transferability was evaluated based on the following indicators.

A:轉接著比率為90%以上且100%以下 A: The transfer ratio is above 90% and below 100%

B:轉接著比率為50%以上且未達90% B: The transfer rate is above 50% and less than 90%

C:轉接著比率未達50% C: The transfer rate is less than 50%

[暫貼性之評價] [Evaluation of Temporary Posting]

將自卷盤拉出之10片ACF以下述之條件暫貼於厚度0.7mm之原玻璃,將剝離膜剝離。於剝離膜剝離後,對在原玻璃暫貼有ACF之狀態之成功片數進行計數。然後,根據下述指標進行暫貼性之評價。 Ten sheets of ACF drawn from the reel were temporarily pasted on the original glass of thickness 0.7mm under the following conditions, and the release film was peeled off. After the peeling film is peeled off, count the number of successful sheets with ACF temporarily attached to the original glass. Then, evaluate the temporary stickiness based on the following indicators.

接合條件:溫度60℃-圧力1MPa-時間1sec Joining conditions: temperature 60℃-pressure 1MPa-time 1sec

緩衝材:矽橡膠(厚度200μm) Buffer material: silicone rubber (thickness 200μm)

A:成功片數為8~10片 A: The number of successful pieces is 8~10 pieces

B:成功片數為3~7片 B: The number of successful films is 3~7

C:成功片數為0~2片 C: The number of successful pieces is 0~2 pieces

[實施例1] [Example 1]

準備具有剝離力Ta為0.05N/cm之A面、與剝離力Tb為0.01N/cm之B面之剝離膜。 Prepare a release film with a peeling force Ta of 0.05 N/cm on side A and a peeling force Tb of 0.01 N/cm on side B.

藉由將苯氧樹脂(商品名:YP-50,新日鐵化學(股)製造)50質量份、2官能基丙烯酸單體(商品名:A-200,新中村化學(股)製造)20質量份、丙烯酸胺酯(商品名:U-2PPA,新中村化學(股)製造)20質量份、過氧化二月桂醯(商品名:Nyper-BW,日本油脂(股)製造)5質量份、及導電性粒子(品名:AUL704,積水化學工業公司製造) 5質量份以通常方法均勻地混合而製備自由基系ACF之組成物。 By adding 50 parts by mass of phenoxy resin (trade name: YP-50, manufactured by Nippon Steel Chemical Co., Ltd.), a bifunctional acrylic monomer (trade name: A-200, manufactured by Shinnakamura Chemical Co., Ltd.) 20 Parts by mass, urethane acrylate (trade name: U-2PPA, manufactured by Shinnakamura Chemical Co., Ltd.) 20 parts by mass, dilaurel peroxide (trade name: Nyper-BW, manufactured by Nippon Oil & Fats Co., Ltd.) 5 parts by mass, And conductive particles (product name: AUL704, manufactured by Sekisui Chemical Industry Co., Ltd.) 5 parts by mass are uniformly mixed by a usual method to prepare a radical-based ACF composition.

將上述組成物以成為25μm厚度之方式塗佈於剝離膜之B面之後,貼附覆蓋膜,裁斷成寬度0.15cm而獲得長度200m之ACF。該裁斷步驟後之ACF於圖2示意性所示之剖面中,凹面之凸部2a之接觸寬度Sa為約0.06cm,平坦面之接觸寬度Sb為0.15cm。 After applying the above composition to the B side of the release film so as to have a thickness of 25 μm, a cover film was attached and cut into a width of 0.15 cm to obtain an ACF with a length of 200 m. In the cross section schematically shown in FIG. 2 for the ACF after the cutting step, the contact width Sa of the convex portion 2a of the concave surface is about 0.06 cm, and the contact width Sb of the flat surface is 0.15 cm.

其次,剝下覆蓋膜,且以於內周側配置ACF之方式將ACF與剝離膜捲取至卷盤,獲得所謂向內捲之膜捲裝體。表1中顯示實施例1之膜捲裝體之評價結果。 Next, the cover film is peeled off, and the ACF and the release film are wound on the reel so that the ACF is arranged on the inner peripheral side to obtain a so-called inwardly rolled film package. Table 1 shows the evaluation results of the film package of Example 1.

[實施例2] [Example 2]

除準備具有剝離力Ta為0.03N/cm之A面、與剝離力Tb為0.01N/cm之B面之剝離膜之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示實施例2之膜捲裝體之評價結果。 A film roll body was obtained in the same manner as in Example 1, except that a release film having a side A with a peeling force Ta of 0.03 N/cm and a side B with a peeling force Tb of 0.01 N/cm was prepared. Table 1 shows the evaluation results of the film package of Example 2.

[實施例3] [Example 3]

除準備具有剝離力Ta為0.08N/cm之A面、與剝離力Tb為0.01N/cm之B面之剝離膜之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示實施例3之膜捲裝體之評價結果。 A film package was obtained in the same manner as in Example 1, except that a release film having a side A with a peeling force Ta of 0.08 N/cm and a side B with a peeling force Tb of 0.01 N/cm was prepared. Table 1 shows the evaluation results of the film package of Example 3.

[實施例4] [Example 4]

除準備具有剝離力Ta為0.1N/cm之A面、與剝離力Tb為0.01N/cm之B面之剝離膜之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示實施例4之膜捲裝體之評價結果。 A film roll was obtained in the same manner as in Example 1, except that a release film having a side A with a peeling force Ta of 0.1 N/cm and a side B with a peeling force Tb of 0.01 N/cm was prepared. Table 1 shows the evaluation results of the film package of Example 4.

[實施例5] [Example 5]

除準備具有剝離力Ta為0.05N/cm之A面、與剝離力Tb為0.01N/ cm之B面之剝離膜且裁斷成寬度0.20cm之外,以與實施例1相同之方式獲得膜捲裝體。該裁斷步驟後之ACF於圖2示意性所示之剖面中,凹面之凸部2a之接觸寬度Sa為約0.08cm,平坦面之接觸寬度Sb為0.20cm。表1中顯示實施例5之膜捲裝體之評價結果。 In addition to preparing the A side with a peeling force Ta of 0.05N/cm, and a peeling force Tb of 0.01N/ The release film on the B side of cm was cut to a width other than 0.20 cm, and the film roll was obtained in the same manner as in Example 1. In the cross section schematically shown in FIG. 2 for the ACF after the cutting step, the contact width Sa of the convex portion 2a of the concave surface is about 0.08 cm, and the contact width Sb of the flat surface is 0.20 cm. Table 1 shows the evaluation results of the film package of Example 5.

[實施例6] [Example 6]

除準備具有剝離力Ta為0.05N/cm之A面、與剝離力Tb為0.01N/cm之B面之剝離膜且裁斷成寬度0.10cm之外,以與實施例1相同之方式獲得膜捲裝體。該裁斷步驟後之ACF於圖2示意性所示之剖面中,凹面之凸部2a之接觸寬度Sa為約0.03cm,平坦面之接觸寬度Sb為0.10cm。表1中顯示實施例6之膜捲裝體之評價結果。 A film roll was obtained in the same manner as in Example 1, except that a peeling film having a peeling force Ta of 0.05N/cm on side A and a peeling film on B side with a peeling strength of 0.01N/cm and cut into a width of 0.10cm was prepared. Body. In the cross section schematically shown in FIG. 2 for the ACF after the cutting step, the contact width Sa of the convex portion 2a of the concave surface is about 0.03 cm, and the contact width Sb of the flat surface is 0.10 cm. Table 1 shows the evaluation results of the film package of Example 6.

[比較例1] [Comparative Example 1]

除準備具有剝離力Ta為0.01N/cm之A面、與剝離力Tb為0.05N/cm之B面之剝離膜之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示比較例1之膜捲裝體之評價結果。 A film roll body was obtained in the same manner as in Example 1, except that a release film having a side A with a peeling force Ta of 0.01 N/cm and a side B with a peeling force Tb of 0.05 N/cm was prepared. Table 1 shows the evaluation results of the film package of Comparative Example 1.

[比較例2] [Comparative Example 2]

除準備具有剝離力Ta為0.02N/cm之A面、與剝離力Tb為0.02N/cm之B面之剝離膜之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示比較例2之膜捲裝體之評價結果。 A film roll body was obtained in the same manner as in Example 1, except that a release film having a side A with a peeling force Ta of 0.02 N/cm and a side B with a peeling force Tb of 0.02 N/cm was prepared. Table 1 shows the evaluation results of the film package of Comparative Example 2.

Figure 105137741-A0202-12-0015-1
Figure 105137741-A0202-12-0015-1

如比較例1般,在將接著膜及剝離膜以凹面與輕剝離面接觸、並且平坦面與重剝離面接觸之方式捲裝之情形時,難以於接著膜之凹面接著有剝離膜之轉接著狀態下拉出,暫貼較困難。又,如比較例2般,即便於剝離膜不具有重剝離面與輕剝離面之情形時,亦難以於轉接著狀態下拉出,暫貼較困難。 As in Comparative Example 1, when the adhesive film and the release film are wound in such a way that the concave surface is in contact with the light release surface and the flat surface is in contact with the heavy release surface, it is difficult to transfer the release film to the concave surface of the adhesive film. Pulling out with the status, it is difficult to post temporarily. Also, as in Comparative Example 2, even when the release film does not have a heavy peeling surface and a light peeling surface, it is difficult to pull out in the transferred state, and it is difficult to temporarily stick.

另一方面,如實施例1~6般,在將接著膜及剝離膜以凹面與重剝離面接觸、並且平坦面與輕剝離面接觸之方式捲裝之情形時,可於接著膜之凹面接著有剝離膜之轉接著狀態下拉出,而可進行暫貼。 On the other hand, as in Examples 1 to 6, when the adhesive film and the release film are wound in such a way that the concave surface is in contact with the heavy release surface, and the flat surface is in contact with the light release surface, the concave surface of the adhesive film can be bonded When the peeling film is attached, it can be pulled out and temporarily pasted.

又,自「將凹面與重剝離面之間之寬度方向之接觸寬度Sa乘以重剝離面之180°剝離力Ta所得之值」減去「將平坦面與輕剝離面之間之寬度方向之接觸寬度Sb乘以輕剝離面之180°剝離力Tb所得之值」的差量值[(Ta×Sa)-(Tb×Sb)]為0.3mN以上且4.5mN以下,藉此可獲得優異之轉接著性及暫貼性。 Also, subtract "the value obtained by multiplying the width of the contact width Sa between the concave surface and the heavy peeling surface by the 180° peeling force Ta of the heavy peeling surface" from "the width between the flat surface and the light peeling surface" The difference between the contact width Sb multiplied by the 180° peeling force Tb of the light peeling surface [(Ta×Sa)-(Tb×Sb)] is 0.3mN or more and 4.5mN or less, so that excellent Adhesion and temporary attachment.

<4.2 第2實施例> <4.2 Second embodiment>

以下,對本發明之第2實施例進行說明。於第2實施例中,對所謂向 內捲之膜捲裝體、及向外捲之膜捲裝體、以及於單面具有凹面之膜捲裝體、及僅具有平坦面之膜捲裝體,評價其轉接著性、暫貼性、及耐黏連性。再者,本發明並不限定於該等實施例。 Hereinafter, the second embodiment of the present invention will be described. In the second embodiment, the so-called Inner-rolled film rolls, outward-rolled film rolls, film rolls with a concave surface on one side, and film rolls with only flat surfaces, evaluate their transferability and temporary attachment Performance, and resistance to adhesion. Furthermore, the present invention is not limited to these embodiments.

剝離膜之剝離力之測定、轉接著性之評價、及暫貼性之評價與第1實施例同樣地進行。 The measurement of the peeling force of the peeling film, the evaluation of the transferability, and the evaluation of the temporary adhesion were performed in the same manner as in the first example.

[耐黏連性之評價] [Evaluation of blocking resistance]

使用具有直徑85mm之卷芯軸部、與由平均厚度1.5mm之聚苯乙烯所構成之凸緣之兩面凸緣型之卷盤構件,將ACF與剝離膜於捲取張力20g之條件下捲取至卷盤構件之卷芯軸部。然後,將捲取至卷盤構件之ACF於拉出張力70g、拉伸速度500mm/sec下,以數cm為單位拉出5小時,對無法自卷盤正常地拉出接著膜之狀態之黏連之產生次數進行計數。 Using a double-sided flange-type reel member with a reel core with a diameter of 85mm and a flange made of polystyrene with an average thickness of 1.5mm, the ACF and release film are wound under the condition of a winding tension of 20g To the core part of the reel component. Then, the ACF wound to the reel member is pulled out for 5 hours at a drawing tension of 70g and a drawing speed of 500mm/sec in units of several centimeters. The number of consecutive generations is counted.

A:產生次數為0~3 A: The number of generations is 0~3

B:產生次數為4~10 B: The number of generations is 4~10

C:產生次數為11以上 C: The number of occurrences is 11 or more

[實施例1] [Example 1]

對實施例1之膜捲裝體之耐黏連性進行評價。表2中顯示實施例1之膜捲裝體之評價結果。 The blocking resistance of the film roll body of Example 1 was evaluated. Table 2 shows the evaluation results of the film package of Example 1.

[實施例7] [Example 7]

以於外周側配置ACF之方式將ACF與剝離膜捲取至卷盤而獲得所謂向外捲之膜捲裝體,除此之外,以與實施例1相同之方式獲得膜捲裝體。表2中顯示實施例7之膜捲裝體之評價結果。 The ACF and the release film were wound on the reel so that the ACF was arranged on the outer peripheral side to obtain a so-called out-wound film package, except that the film package was obtained in the same manner as in Example 1. Table 2 shows the evaluation results of the film package of Example 7.

[參考例] [Reference example]

除準備具有剝離力Ta為0.02N/cm之A面、與剝離力Tb為0.02N/cm之B面之剝離膜且以兩面成為平坦之方式裁斷之外,以與實施例1相同之方式獲得膜捲裝體。表1中顯示比較例3之膜捲裝體之評價結果。 It was obtained in the same manner as in Example 1, except that a release film having a peeling force Ta of 0.02N/cm on side A and a peeling film on B side with a peeling strength of 0.02N/cm was prepared and cut so that both sides became flat. Film roll body. Table 1 shows the evaluation results of the film package of Comparative Example 3.

Figure 105137741-A0202-12-0017-2
Figure 105137741-A0202-12-0017-2

如參考例般,在將兩面平坦之接著膜與兩面之剝離力相同之剝離膜以所謂向內捲構成而捲繞之情形時,接著膜之接著劑成分大量溢出,且附著於卷盤之凸緣,故黏連之產生次數較多。 As in the reference example, when the adhesive film on both sides is flat and the release film with the same peeling force on both sides is wound in a so-called inward-rolling configuration, the adhesive component of the adhesive film overflows in large quantities and adheres to the convexity of the reel. Because of this, there are more occurrences of adhesion.

另一方面,如實施例7般,在將具有凹面之接著膜與剝離力不同之剝離膜以所謂向外捲構成而捲繞之情形時,黏連之產生次數較少。認為其原因在於,藉由形成於凹面之寬度方向之中央部之空隙而可使接著膜之接著劑成分之溢出量減少。 On the other hand, as in Example 7, when an adhesive film having a concave surface and a release film having a different peeling force are wound in a so-called roll-out configuration, the number of occurrences of blocking is small. The reason for this is considered to be that the amount of overflow of the adhesive component of the adhesive film can be reduced by the void formed in the center portion of the width direction of the concave surface.

進而,如實施例1般,在以所謂向內捲構成而捲繞之情形時,黏連之產生次數更少。認為其原因在於,藉由轉接著而使於拉出之方向側存在有接著膜,故能夠以將剝離膜上拉之方式拉出接著膜,因此即便於凸緣上附著有樹脂,亦能夠以較強之力將其剝下。 Furthermore, as in Example 1, in the case of winding in a so-called inward winding configuration, the number of occurrences of blocking is smaller. It is considered that the reason is that the adhesive film is present on the side of the pull-out direction due to the transfer, so that the adhesive film can be pulled out by pulling up the release film. Therefore, even if the resin adheres to the flange, the adhesive film can be pulled out. Peel it off with strong force.

1‧‧‧膜捲裝體 1‧‧‧Film roll body

2‧‧‧接著膜 2‧‧‧Adhesive film

3‧‧‧剝離膜 3‧‧‧Peeling film

4‧‧‧卷盤 4‧‧‧Reel

5‧‧‧卷芯 5‧‧‧Core

6‧‧‧凸緣 6‧‧‧Flange

Claims (11)

一種膜捲裝體,具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面、及形成於該第1面之相反側的平坦之第2面;剝離膜,其具有剝離力相對較高之重剝離面、與剝離力相對較低之輕剝離面;及卷芯,其捲裝上述接著膜及上述剝離膜;該膜捲裝體係以上述接著膜之第1面與上述剝離膜之重剝離面接觸、並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸之方式捲裝於上述卷芯而成。 A film roll body, comprising: an adhesive film having a first surface formed at both ends of the width direction along the length direction with a thickness greater than the thickness of the central portion, and a flat first surface formed on the opposite side of the first surface 2 sides; peeling film, which has a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force; and a roll core, which rolls the adhesive film and the peeling film; the film roll system The first surface of the adhesive film is in contact with the heavy release surface of the release film, and the second surface of the adhesive film is in contact with the light release surface of the release film. 如申請專利範圍第1項之膜捲裝體,其中,將上述第1面與上述重剝離面之間之寬度方向之接觸寬度乘以上述重剝離面之剝離力所得的值,大於將上述第2面與上述輕剝離面之間之寬度方向之接觸寬度乘以上述輕剝離面之剝離力所得的值。 For example, the film roll body of the first item of the scope of patent application, wherein the value obtained by multiplying the contact width in the width direction between the first surface and the heavy peeling surface by the peeling force of the heavy peeling surface is greater than The value obtained by multiplying the contact width in the width direction between the two sides and the light peeling surface by the peeling force of the light peeling surface. 如申請專利範圍第1項之膜捲裝體,其中,由將上述第1面與上述重剝離面之間之寬度方向之接觸寬度乘以上述重剝離面之180°剝離力所得之值減去將上述第2面與上述輕剝離面之間之寬度方向之接觸寬度乘以上述輕剝離面之180°剝離力所得之值的差量值為0.3mN以上且4.5mN以下。 For example, the film roll body of item 1 of the scope of patent application, in which the value obtained by multiplying the contact width in the width direction between the first surface and the heavy peeling surface by the 180° peeling force of the heavy peeling surface is subtracted The difference in the value obtained by multiplying the contact width in the width direction between the second surface and the light peeling surface by the 180° peeling force of the light peeling surface is 0.3 mN or more and 4.5 mN or less. 如申請專利範圍第1項之膜捲裝體,其係將上述接著膜之第2面與上述剝離膜之輕剝離面接觸之積層膜以上述接著膜側成為內周側之方式捲裝而成。 For example, the film roll body of the first item of the scope of patent application, which is a laminated film in which the second surface of the adhesive film is in contact with the light release surface of the release film, and the adhesive film side becomes the inner peripheral side. . 如申請專利範圍第1項之膜捲裝體,其係將上述接著膜之第1面與上述剝離膜之重剝離面接觸之積層膜以上述接著膜側成外周側之方式捲裝而成。 For example, the film roll body of the first item in the scope of patent application is formed by winding a laminated film in which the first surface of the adhesive film and the heavy peeling surface of the release film are in contact with the adhesive film side as the outer peripheral side. 如申請專利範圍第1項之膜捲裝體,其係於上述卷芯之兩端設置凸緣而成。 For example, the film roll body of item 1 of the scope of patent application is formed by arranging flanges on both ends of the above-mentioned roll core. 如申請專利範圍第1項之膜捲裝體,其中,上述接著膜之寬度為0.6mm~5.0mm。 For example, the film roll body of item 1 in the scope of patent application, wherein the width of the adhesive film is 0.6mm~5.0mm. 如申請專利範圍第1至7中任一項之膜捲裝體,其中,上述接著膜係異向性導電膜。 Such as the film roll body of any one of the 1st to 7th patents, wherein the adhesive film is an anisotropic conductive film. 一種膜捲裝體之製造方法,其係將具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度之第1面與形成於該第1面之相反側之平坦之第2面的接著膜、及具有剝離力相對較高之重剝離面與剝離力相對較低之輕剝離面的剝離膜,以上述接著膜之第1面與上述剝離膜之重剝離面接觸、並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸之方式捲裝於卷芯。 A method for manufacturing a film roll body, which includes a first surface having both ends formed in the width direction along the length direction and having a thickness greater than the thickness of the central portion, and a flat second surface formed on the opposite side of the first surface The first surface of the adhesive film is in contact with the heavy peeling surface of the peeling film, and the peeling film has a heavy peeling surface with relatively high peeling force and a light peeling surface with relatively low peeling force. Then, the second surface of the film is in contact with the lightly peeled surface of the above-mentioned release film and is wound on the core. 一種連接構造體之製造方法,其係自如下述之膜捲裝體,拉出下述接著膜之第1面與下述剝離膜之重剝離面接觸之積層膜,將下述接著膜之第2面暫貼於第1電路構件,且將剝離膜剝離,將第2電路構件載置於下述接著膜上並正式壓接;該膜捲裝體具備:接著膜,其具有沿長度方向形成為寬度方向之兩端部之厚度大於中央部之厚度的第1面與形成於該第1面之相反側的平坦之第2面;剝離膜,其具有剝離力相對較高之重剝離面與剝離力相對 較低之輕剝離面;以及,卷芯,其捲裝上述接著膜及上述剝離膜;上述接著膜之第1面與上述剝離膜之重剝離面接觸並且上述接著膜之第2面與上述剝離膜之輕剝離面接觸。 A method of manufacturing a connecting structure, which is free from the following film roll body, pulling out the laminated film with the first side of the following adhesive film in contact with the heavy peeling surface of the following release film, and placing the first side of the following adhesive film Two sides are temporarily pasted on the first circuit member, and the release film is peeled off, the second circuit member is placed on the following adhesive film and formally crimped; the film roll body is equipped with: an adhesive film, which has a lengthwise formation It is a first surface where the thickness of both ends in the width direction is greater than the thickness of the central part and a flat second surface formed on the opposite side of the first surface; a release film which has a heavy release surface with relatively high release force and Relative peel force The lower light peeling surface; and, the core, which wraps the adhesive film and the peeling film; the first surface of the adhesive film is in contact with the heavy peeling surface of the peeling film and the second surface of the adhesive film is with the peeling The light peeling surface of the film touches. 如申請專利範圍第10項之連接構造體之製造方法,其中,上述接著膜係異向性導電膜。 Such as the manufacturing method of the connection structure of the 10th patent application, wherein the adhesive film is an anisotropic conductive film.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11241049A (en) * 1998-02-26 1999-09-07 Sumitomo Bakelite Co Ltd Anisotropic conductive adhesive film wind-up roll
JPH11293206A (en) * 1998-04-15 1999-10-26 Hitachi Chem Co Ltd Winding having adhesive layer
JP2000144064A (en) * 1998-11-12 2000-05-26 Hitachi Chem Co Ltd Crosslinkable adhesive tape structure
JP2012102278A (en) * 2010-11-12 2012-05-31 Sony Chemical & Information Device Corp Reel object and manufacturing method therefor, method for planarizing adhesive film
CN103270124A (en) * 2010-12-24 2013-08-28 迪睿合电子材料有限公司 Reel body and process for production of reel body

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101625250B1 (en) * 2008-09-30 2016-05-27 린텍 가부시키가이샤 Film-peeling method, process for production of optical film, film-peeling mechanism, and apparatus for production of optical film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11241049A (en) * 1998-02-26 1999-09-07 Sumitomo Bakelite Co Ltd Anisotropic conductive adhesive film wind-up roll
JPH11293206A (en) * 1998-04-15 1999-10-26 Hitachi Chem Co Ltd Winding having adhesive layer
JP2000144064A (en) * 1998-11-12 2000-05-26 Hitachi Chem Co Ltd Crosslinkable adhesive tape structure
JP2012102278A (en) * 2010-11-12 2012-05-31 Sony Chemical & Information Device Corp Reel object and manufacturing method therefor, method for planarizing adhesive film
CN103270124A (en) * 2010-12-24 2013-08-28 迪睿合电子材料有限公司 Reel body and process for production of reel body

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