TWI696694B - Drinks with woody ingredients - Google Patents

Drinks with woody ingredients Download PDF

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TWI696694B
TWI696694B TW105122917A TW105122917A TWI696694B TW I696694 B TWI696694 B TW I696694B TW 105122917 A TW105122917 A TW 105122917A TW 105122917 A TW105122917 A TW 105122917A TW I696694 B TWI696694 B TW I696694B
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beverage
content
limonene
container
erucaldehyde
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TW105122917A
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TW201716566A (en
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伊藤定弘
吉弘晃
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日商三得利控股股份有限公司
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Abstract

本發明課題在於提供一種可維持來自酒桶等的木製容器或木材之木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分之苦澀味,至餘味仍可舒暢地飲用的飲料。 The object of the present invention is to provide a beverage that can maintain the unique flavor or thickness of a wooden component from a wine barrel or the like and the wood component of the wood, while suppressing the bitter and astringent taste of the wood component and allowing the aftertaste to be consumed comfortably.

解決手段為使飲料含有(A)0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛、以及(B)0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。 The solution is to make the beverage contain (A) 0.4-10.0 ppm gallic acid and/or 0.4-10.0 ppm erucaldehyde, and (B) 0.2-5.0 ppm limonene and/or 0.1-5.0 ppm 1-terpene Pinen-4-ol.

Description

含木質成分之飲料 Drinks with woody ingredients

本發明係有關於一種容器填裝飲料,其係使用如白蘭地般以酒桶等的木製容器經過熟成的酒類、或使用含有木質成分的溶液所製成的容器填裝飲料,其可充分活用該等溶液中的木質成分之特徵,同時可抑制木質成分特有的苦澀味而能夠餘味感到舒暢地飲用。 The present invention relates to a container-filled beverage, which is a bottle-filled beverage that is prepared by using a wooden container such as a brandy that has been cooked in a wooden container such as a wine barrel, or a solution containing a wooden component, which can make full use of the beverage The characteristics of the woody ingredients in the solution, while suppressing the unique bitterness of the woody ingredients and being able to drink with a pleasant aftertaste.

眾所皆知,如白蘭地般使用酒桶等的木製容器經過熟成的酒類,透過熟成而讓味道變得更圓潤,硫化合物等呈現不佳之香氣(未熟成香)的成分消失,另一方面則生成起因於酯類或雜醇類、糠醛等之如果實般的華麗香氣(熟成香),而發揮各酒類特有的香味。另外,已知來自木製容器之成分(木質成分)會藉由醇類分解、溶出,而對酒類賦予甜味或澀味等味道的深醇感。如此所得之含有木質成分的酒類有時會直接飲用,有時也會與冰塊一起飲用、或用水稀釋等而飲用。又,例如,已知有一種藉由對裝有冰塊的平底玻璃杯(tumbler)倒入使用木製容器經過熟成的酒類,再倒滿冰涼蘇打水並輕輕攪動所作成之稱為 「高杯酒(highball,高球)」的雞尾酒調酒法(非專利文獻1)。高杯酒由於可藉由用蘇打水稀釋之簡便的手段作成具有清爽風味的雞尾酒而極受歡迎,隨時可於居酒屋等餐飲處品嚐之。 It is well known that after aging in a wooden container such as a brandy using a wine barrel, the taste becomes more rounded through aging, and sulfur compounds and other components that exhibit a poor aroma (unripe fragrance) disappear, on the other hand It produces a truly gorgeous aroma (cooked aroma) due to esters, fusel alcohols, furfural, etc., and develops the unique aroma of each wine. In addition, it is known that a component derived from a wooden container (wood component) decomposes and dissolves out by alcohol, thereby imparting a deep alcoholic taste to the alcohol, such as sweetness or astringency. The alcohol containing wood ingredients obtained in this way may be drunk directly, and sometimes it may be drunk with ice or diluted with water. Also, for example, there is known a method of pouring a flat-bottomed glass (tumbler) filled with ice cubes into a cooked liquor using a wooden container, and then pour cold soda water and gently stir it. "Highball (highball)" cocktail mixing method (Non-Patent Document 1). Tall glass of wine is extremely popular because it can be made into a refreshing cocktail by the simple method of diluting it with soda water, and it can be tasted at any izakaya and other food and beverage outlets.

另一方面,由於柑橘類具有爽口的芳香或酸甜味,其果汁、果實或香料經常作為飲食品的原料極受歡迎。又,由於容器填裝飲料有別於在家庭或居酒屋等在臨飲用前摻混各種飲料或果汁等而成的飲料,要在填充步驟中對容器填充飲料後經過殺菌步驟、或經過長時間的流通或保存步驟,熱歷程極為嚴峻,也有時會損及新鮮的風味而產生劣化香味。 On the other hand, because citrus has a refreshing aroma or sweet and sour taste, its juices, fruits, or spices are often extremely popular as raw materials for food and drink. In addition, since the beverage filled in the container is different from a beverage prepared by blending various beverages or fruit juices before drinking in a home or an izakaya, etc., the container needs to be filled with the beverage through the sterilization step or after a long time The heat history is extremely severe in the circulation or storage step, and sometimes the fresh flavor is impaired and the degraded flavor is produced.

[先前技術文獻] [Prior Technical Literature] [非專利文獻] [Non-patent literature]

[非專利文獻1] NBA Official Cocktailbook,社團法人日本調酒師協會編著,柴田書店股份有限公司,1990年9月1日發行 [Non-Patent Document 1] NBA Official Cocktailbook, edited by the Japan Bartenders Association, Shibata Bookstore Co., Ltd., issued on September 1, 1990

如此,使用以酒桶等的木製容器經過熟成的酒類所製作的飲料、或使用含有木質成分的溶液所製作的飲料有各式各樣。其中,將如高杯酒般以酒桶等的木製容 器經過熟成的酒類以碳酸鈉稀釋時,儘管該酒類的含量會減少,但木質成分的味道有時仍會以不佳之形態影響餘味。 In this way, there are various types of beverages prepared using matured liquor in wooden containers such as wine barrels, or beverages prepared using solutions containing wood components. Among them, the wooden container like a wine When the cooked wine is diluted with sodium carbonate, although the content of the wine will be reduced, the taste of the woody ingredients may still affect the aftertaste in a poor form.

本案發明人等就來自酒桶等的木製容器或木材之木質成分的苦澀味,著眼於沒食子酸與芥子醛。沒食子酸及芥子醛為木製容器或木材所含之單寧或木質素經水解而向飲料中溶出的物質,係對飲料的味道賦予苦澀感或深醇感、濃厚感的成分。本案發明人等致力進行研究的結果發現,針對特定量的沒食子酸及/或芥子醛,使其含有特定量的檸檬烯及/或1-萜品烯-4-醇時,可維持來自木製容器或木材之木質成分的獨特的風味或濃厚感,同時可減少來自沒食子酸及/或芥子醛的苦澀味,而能夠製造至餘味仍舒暢順口的飲料。亦即,本發明雖不限定於此等,惟包含以下之態樣。 The inventors of the present invention focused on gallic acid and erucaldehyde with respect to the bitter taste of wooden components such as wine barrels or wood components of wood. Gallic acid and erucaldehyde are substances that dissolve into tannins or lignin contained in wooden containers or wood and dissolve into beverages through hydrolysis, and are ingredients that impart a bitter, deep, and rich taste to the taste of beverages. The inventors of the present case have made intensive studies and found that when a specific amount of gallic acid and/or erucaldehyde is contained in a specific amount of limonene and/or 1-terpinen-4-ol, the The unique flavor or thickness of the wood component of the container or wood, while reducing the bitter taste from gallic acid and/or erucaldehyde, can produce beverages with a pleasant aftertaste. That is, the present invention is not limited to these, but includes the following aspects.

(1)一種容器填裝飲料,其係包含(A)0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛、以及(B)0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。 (1) A container filled beverage comprising (A) 0.4 to 10.0 ppm gallic acid and/or 0.4 to 10.0 ppm erucaldehyde, and (B) 0.2 to 5.0 ppm limonene and/or 0.1 to 5.0 ppm of 1-terpinen-4-ol.

(2)如(1)之容器填裝飲料,其係滿足以下之i)~iv)的任一項以上:i)包含沒食子酸與檸檬烯時,沒食子酸含量相對於檸 檬烯含量的比率為10:1~1:10;ii)包含沒食子酸與1-萜品烯-4-醇時,沒食子酸含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10;iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 (2) The container filled with beverage as in (1), which satisfies any one of the following i) to iv): i) When containing gallic acid and limonene, the content of gallic acid relative to lemon The ratio of limonene content is 10:1~1:10; ii) When gallic acid and 1-terpinene-4-ol are included, the content of gallic acid relative to the content of 1-terpinene-4-ol The ratio is 10:1~1:10; iii) when erucaldehyde and limonene are included, the ratio of erucaldehyde content to limonene content is 10:1~1:10; iv) contains erucaldehyde and 1-terpinene- For 4-alcohol, the ratio of erucaldehyde content to 1-terpinen-4-ol content is 10:1~1:10.

(3)如(1)或(2)之容器填裝飲料,其酒精含量為0~25v/v%。 (3) The container filled with beverages as in (1) or (2) has an alcohol content of 0~25v/v%.

(4)如(1)~(3)中任一項之容器填裝飲料,其係含有二氧化碳。 (4) The container filled with beverage as in any one of (1) to (3) contains carbon dioxide.

(5)如(4)之容器填裝飲料,其中二氧化碳的壓力為1.5kgf/cm2以上。 (5) The container as described in (4) is filled with beverages, wherein the pressure of carbon dioxide is 1.5 kgf/cm 2 or more.

(6)如(1)~(5)中任一項之容器填裝飲料,其係含有威士忌及/或白蘭地。 (6) The container-filled beverage according to any one of (1) to (5) contains whiskey and/or brandy.

(7)如(1)~(6)中任一項之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 (7) The container-filled beverage according to any one of (1) to (6), wherein the total value of the contents of sucrose, glucose, and fructose is 8.0 g/100 ml or less.

(8)如(7)之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為1.7g/100ml以下。 (8) The beverage filled with the container according to (7), wherein the total value of the contents of sucrose, glucose, and fructose is 1.7 g/100 ml or less.

根據本發明,可提供一種可在含有來自木製容器或木材之木質成分的飲料中維持木質成分之獨特的風味或濃厚感,同時可抑制木質成分之苦澀味,至餘味仍可 舒暢地飲用的飲料。 According to the present invention, it is possible to provide a beverage containing wood components derived from a wooden container or wood to maintain the unique flavor or thickness of the wood component, while suppressing the bitter and astringent taste of the wood component until the aftertaste remains Drinks that drink comfortably.

[實施發明之形態] [Forms for carrying out the invention]

本發明係提供一種在含有特定量的沒食子酸及/或芥子醛作為呈現來自酒桶等的木製容器或木材之木質成分特有的苦澀味之成分的飲料中,透過使其含有特定量的檸檬烯及/或1-萜品烯-4-醇,可維持木質成分所具之獨特的風味與濃厚感,同時可抑制苦澀味,至餘味仍可舒暢地飲用的飲料。 The present invention provides a beverage containing a specific amount of gallic acid and/or erucaldehyde as a component exhibiting a bitter taste characteristic of a wooden component from a wooden container such as a wine barrel or wood, by containing a specific amount of Limonene and/or 1-terpinen-4-ol can maintain the unique flavor and thickness of the woody ingredients, while suppressing the bitter taste, and the drink can be comfortably consumed aftertaste.

(沒食子酸、芥子醛) (Gallic acid, erucaldehyde)

沒食子酸(gallic acid,C7H6O5)及芥子醛(sinapaldehyde,C11H12O4)為酒桶等的木製容器或使用之木材中的單寧或木質素經水解而向飲料中溶出的物質,係對飲料的味道賦予苦澀感或深醇感的成分之一。本發明之飲料係包含0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛作為木質成分。沒食子酸的含量較佳為0.4~5.0ppm,更佳為0.5~2.0ppm。芥子醛的含量較佳為0.4~5.0ppm,更佳為0.5~2.0ppm。沒食子酸或芥子醛的含量若未達0.4ppm,無法感受到木質成分所產生之味道的深醇感;超過10.0ppm則苦澀味顯著,縱使進行後述之檸檬烯及/或1-萜品烯-4-醇的添加亦不易抑制苦澀味。此外,本說明書中單位ppm係與單位mg/l同義。 Gallic acid (C 7 H 6 O 5 ) and sinapaldehyde (C 11 H 12 O 4 ) are tannins or lignins in wooden containers such as wine barrels or used wood, which are hydrolyzed to The substance dissolved in the beverage is one of the ingredients that imparts a bitter or deep alcohol to the taste of the beverage. The beverage of the present invention contains 0.4 to 10.0 ppm of gallic acid and/or 0.4 to 10.0 ppm of erucaldehyde as a wood component. The content of gallic acid is preferably 0.4 to 5.0 ppm, more preferably 0.5 to 2.0 ppm. The content of erucaldehyde is preferably 0.4 to 5.0 ppm, more preferably 0.5 to 2.0 ppm. If the content of gallic acid or erucaldehyde does not reach 0.4 ppm, the deep mellow taste of the woody component cannot be felt; if it exceeds 10.0 ppm, the bitter taste is remarkable, even if the later-mentioned limonene and/or 1-terpinene is carried out The addition of -4-ol is also not easy to suppress the bitter taste. In addition, the unit ppm in this specification is synonymous with the unit mg/l.

飲料中的沒食子酸及芥子醛的量可使用高效液相層析儀(HPLC)或超高效液相層析儀(UHPLC)等來測定。能以例如以下之分析機種、條件來測定。 The amounts of gallic acid and erucaldehyde in the beverage can be measured using high performance liquid chromatography (HPLC) or ultra high performance liquid chromatography (UHPLC). It can be measured by, for example, the following analysis models and conditions.

測定機種:LC HP 1100 series(Agilent Technologies) Measurement model: LC HP 1100 series (Agilent Technologies)

管柱:phenomenex Luna 5μ C18(2)100A 150 * 4.60mm(00F-4252-E0) Column: phenomenex Luna 5μ C18(2)100A 150 * 4.60mm(00F-4252-E0)

管柱溫度:40℃ Column temperature: 40℃

檢測器:UV-VIS Detector: UV-VIS

注入量:5.0μl。 Injection volume: 5.0μl.

飲料中的沒食子酸及/或芥子醛,若考量飲料之風味的平衡,則較佳為來自酒桶等的木製容器或木材者;亦可含有其他物質,例如萃取自其他植物者,例如萃取自茶葉、藥草、或香料者,又,亦可含有香料、色素等。 The gallic acid and/or erucaldehyde in the beverage, if considering the balance of the flavor of the beverage, it is preferably from wooden containers or wood such as wine barrels; it may also contain other substances, such as those extracted from other plants, such as Extracted from tea, herbs, or spices, and may also contain spices, pigments, etc.

(檸檬烯、1-萜品烯-4-醇) (Limonene, 1-terpinen-4-ol)

檸檬烯(d-limonene,C10H16)為柑橘果實的果皮等所含之單環式單萜烯的一種,係呈現所謂柑橘般的香氣的成分。1-萜品烯-4-醇(1-Terpinene-4-ol,C10H18O)為柑橘果實的果皮等所含之單萜烯醇的一種,係呈現所謂柑橘般的香氣的成分。本發明之飲料係包含0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。檸檬烯的含量較佳為0.3~2.5ppm。1-萜品烯-4-醇的含量較佳為0.15~2.5ppm。藉由對含有前述之特定量的沒食子酸及/或芥子 醛的飲料,使其以上述量含有檸檬烯及/或1-萜品烯-4-醇,可適度地遮蔽沒食子酸及/或芥子醛之木質成分的苦澀味,同時可提高飲料的舒暢感。檸檬烯的含量少於0.2ppm或1-萜品烯-4-醇的含量少於0.1ppm時,無法獲得苦澀味的抑制效果;另一方面,檸檬烯及/或1-萜品烯-4-醇的含量多於5.0ppm時則檸檬烯或1-萜品烯-4-醇特有之柑橘般的香氣(尤為檸檬般的香氣)會過強,且來自沒食子酸或芥子醛的味道濃厚感也會降低,而喪失飲料的風味平衡或味道濃厚感的平衡。 Limonene (d-limonene, C 10 H 16 ) is a type of monocyclic monoterpene contained in the peel of citrus fruit and the like, and is a component exhibiting a so-called citrus-like aroma. 1-Terpinene-4-ol (1-Terpinene-4-ol, C 10 H 18 O) is one of the monoterpene alcohols contained in the peel of citrus fruit and the like, and is a component exhibiting a so-called citrus-like aroma. The beverage of the present invention contains 0.2 to 5.0 ppm of limonene and/or 0.1 to 5.0 ppm of 1-terpinen-4-ol. The content of limonene is preferably 0.3 to 2.5 ppm. The content of 1-terpinen-4-ol is preferably 0.15 to 2.5 ppm. By containing the above-mentioned specific amount of gallic acid and/or erucaldehyde in a beverage containing limonene and/or 1-terpinen-4-ol in the above amount, the gallic acid and /Or the bitter taste of the wood component of erucaldehyde, and at the same time can improve the comfort of the beverage. When the content of limonene is less than 0.2 ppm or the content of 1-terpinen-4-ol is less than 0.1 ppm, the bitter taste suppression effect cannot be obtained; on the other hand, limonene and/or 1-terpinen-4-ol When the content is more than 5.0ppm, the citrus-like aroma (especially lemon-like aroma) peculiar to limonene or 1-terpinene-4-ol will be too strong, and the strong taste from gallic acid or erucaldehyde will also be Will be reduced, and lose the flavor balance or the balance of the rich taste of the beverage.

飲料中的檸檬烯及1-萜品烯-4-醇的含量,例如可藉由對飲料提供含有檸檬烯及/或1-萜品烯-4-醇的精油或香料等來調整,亦可藉由對飲料提供含有檸檬烯及/或1-萜品烯-4-醇的柑橘蒸餾酒或柑橘浸漬酒來調整,也可藉由對飲料添加包含檸檬烯及/或1-萜品烯-4-醇之柑橘果實的果汁來調整。檸檬烯及/或1-萜品烯-4-醇為在柑橘果實中富含於果皮的成分,因此,若使用柑橘果實的果汁時,較佳使用含有果皮或果皮油的果汁,例如帶肉果汁。使用柑橘果實的果汁時,果實的種類不特別限定,例如包含於柑橘屬(Citrus)、金橘屬(Fortunella)、枳屬(Poncirus)之葡萄柚、檸檬、萊姆、柳橙、柚子、酢橘、臭橙、八朔、金橘、臺灣香檬等略帶酸味的柑橘果實由於可提高飲料的舒暢感,因而較佳。飲料中之果汁的含量係取決於果汁中的檸檬烯及/或1-萜品烯-4-醇的含量,而相對於飲料全體,以果汁率換算較佳為30.0w/w%以下左右,更佳為 0.5~10.0w/w%,但不限定於此。此外,「果汁率」係指將榨取果汁所得之純果汁設為100%時的相對濃度。例如,可基於JAS規格(果實飲料之日本農林規格)所示之各種果實之純果汁的糖用折射計讀值之基準或酸度之基準,藉由計算而求得。 The content of limonene and 1-terpinene-4-ol in the beverage can be adjusted, for example, by providing essential oils or spices containing limonene and/or 1-terpinene-4-ol to the beverage, or by The beverage can be adjusted by providing citrus distilled wine or citrus dip wine containing limonene and/or 1-terpinene-4-ol, or by adding alcohol containing limonene and/or 1-terpinene-4-ol to the beverage Adjust the juice of citrus fruit. Limonene and/or 1-terpinen-4-ol is a component that is rich in the peel of citrus fruit. Therefore, when using juice from citrus fruit, it is preferable to use juice containing peel or peel oil, such as fruit juice . When using the juice of citrus fruit, the type of fruit is not particularly limited. For example, grapefruit, lemon, lime, orange, orange, grapefruit, and citron are included in Citrus, Fortunella, and Poncirus. Citrus fruits such as tangerines, stinky oranges, bashuo, kumquat, and Taiwanese lemon are slightly sour because they can improve the comfort of beverages, so they are better. The content of fruit juice in the beverage depends on the content of limonene and/or 1-terpinene-4-ol in the fruit juice, and it is preferably about 30.0 w/w% or less in terms of juice ratio relative to the entire beverage. Jiawei 0.5~10.0w/w%, but not limited to this. In addition, "juice rate" refers to the relative concentration when the pure juice obtained from squeezed juice is set to 100%. For example, it can be obtained by calculation based on the reference value of the refractometer reading or the acidity reference for the sugar of pure fruit juices of various fruits as shown in the JAS standard (Japanese Agricultural and Forestry Standards for Fruit Drinks).

飲料中的檸檬烯及1-萜品烯-4-醇的含量可依以下方法測定。 The content of limonene and 1-terpinen-4-ol in the beverage can be determined according to the following method.

[檸檬烯及1-萜品烯-4-醇的測定] [Determination of Limonene and 1-terpinen-4-ol]

將作為試料的液體組成物依以下條件供予至氣相層析分析(GC-FID)。分析條件如下:分析前處理:將試樣填充於Extrelut NT-1管柱,以醚進行萃取。 The liquid composition as a sample was subjected to gas chromatography analysis (GC-FID) under the following conditions. The analysis conditions are as follows: pre-analysis treatment: the sample is packed in an Extrelut NT-1 column and extracted with ether.

分析裝置:GC6890N(Agilent Technologies) Analysis device: GC6890N (Agilent Technologies)

管柱:HP-ULTRA2內徑0.32mm、長度50m、膜厚0.52μm Column: HP-ULTRA2 inner diameter 0.32mm, length 50m, film thickness 0.52μm

載送氣體:Helium Carrier gas: Helium

流量:2.2ml/min Flow rate: 2.2ml/min

注入口:Splitless Note entrance: Splitless

注入口溫度:250℃ Note inlet temperature: 250℃

烘箱溫度:45℃(1.5min)→5℃/min→230℃(11.5min) Oven temperature: 45℃(1.5min)→5℃/min→230℃(11.5min)

檢測器:FID Detector: FID

檢測器溫度:260℃ Detector temperature: 260℃

注入量:1.0μl Injection volume: 1.0μl

標準物質:檸檬烯或1-萜品烯-4-醇 Reference material: limonene or 1-terpinen-4-ol

本發明之飲料不限定於此,惟較佳滿足以下之i)~iv)的任一項以上之條件。 The beverage of the present invention is not limited thereto, but preferably satisfies any one of the following conditions i) to iv).

i)包含沒食子酸與檸檬烯時,沒食子酸含量相對於檸檬烯含量的比率為10:1~1:10;ii)包含沒食子酸與1-萜品烯-4-醇時,沒食子酸含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10;iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 i) When gallic acid and limonene are included, the ratio of gallic acid content to limonene content is 10:1 to 1:10; ii) when gallic acid and 1-terpinen-4-ol are included, The ratio of gallic acid content to 1-terpinene-4-ol content is 10:1 to 1:10; iii) when erucaldehyde and limonene are included, the ratio of erucaldehyde content to limonene content is 10:1 ~1:10; iv) When erucaldehyde and 1-terpinen-4-ol are included, the ratio of erucaldehyde content to 1-terpinen-4-ol content is 10:1 to 1:10.

再者,i)沒食子酸含量相對於檸檬烯含量的比率為3:1~1:3則更佳,ii)沒食子酸含量相對於1-萜品烯-4-醇含量的比率為3:1~1:3則更佳,iii)芥子醛含量相對於檸檬烯含量的比率為3:1~1:3則更佳,iv)芥子醛含量相對於1-萜品烯-4-醇含量的比率為3:1~1:3則更佳。若滿足上述之條件,則可進一步提高檸檬烯及/或1-萜品烯-4-醇所產生之苦澀味的遮蔽效果、與飲料之舒暢感的提升效果。 Furthermore, i) the ratio of gallic acid content to limonene content is 3:1~1:3 is better, ii) the ratio of gallic acid content to 1-terpinen-4-ol content is 3:1~1:3 is better, iii) the ratio of erucaldehyde content to limonene content is 3:1~1:3 is better, iv) erucaldehyde content relative to 1-terpinen-4-ol The content ratio of 3:1~1:3 is better. If the above conditions are satisfied, the masking effect of the bitter taste produced by limonene and/or 1-terpinen-4-ol can be further improved, and the improvement effect of the comfort of the beverage can be improved.

(飲料) (Drink)

本發明之飲料的酒精含量較佳為0~25v/v%,更佳為3~25v/v%,再更佳為3~9v/v%。此外,於本發明中,若非特別合先敘明,則「酒精」係指乙醇。又,酒精含量係 指乙醇的含量(v/v%)。飲料的酒精含量可利用周知之手法來測定。例如,可藉由國稅廳規定分析法(平19國稅廳訓令第6號,2007年6月22日改定)所記載的方法來測定。 The alcohol content of the beverage of the present invention is preferably from 0 to 25v/v%, more preferably from 3 to 25v/v%, and even more preferably from 3 to 9v/v%. In addition, in the present invention, unless otherwise specified, "alcohol" refers to ethanol. Also, alcohol content Refers to the content of ethanol (v/v%). The alcohol content of beverages can be determined using well-known techniques. For example, it can be measured by the method described in the analysis method prescribed by the National Tax Administration (Ping 19 National Tax Administration Training Order No. 6, revised on June 22, 2007).

本發明之飲料係如上述含有沒食子酸及/或芥子醛。沒食子酸與芥子醛為使用酒桶等的木製容器經過熟成所得之酒類中來自木製容器之苦澀味成分的指標之一,本發明之飲料較佳含有使用酒桶等的木製容器經過熟成所得之酒類。作為此種酒類,不特別限定,可舉出例如威士忌、白蘭地、康雅白蘭地、卡瓦多斯、蘭姆酒、龍舌蘭酒、酒桶熟成燒酒、酒桶熟成梅酒、葡萄酒、苦艾酒、蘋果酒等。威士忌或白蘭地,來自酒桶等的木材之成分係大量含於酒中,可謂較適宜者。 The beverage of the present invention contains gallic acid and/or erucaldehyde as described above. Gallic acid and erucaldehyde are one of the indicators of the bitterness component derived from the wooden container in the wine obtained by aging using a wooden container such as a wine barrel. The beverage of the present invention preferably contains the aging obtained by using a wooden container such as a wine barrel Wine. Such alcohols are not particularly limited, and examples thereof include whiskey, brandy, kangya brand, cavados, rum, tequila, casks shochu, casks ume plum, wine, vermouth, Cider etc. Whiskey or brandy, wood from barrels and other ingredients are contained in a large amount of wine, which is more suitable.

使本發明之飲料含有使用木製容器製得之熟成酒時,其含量係取決於熟成酒中的沒食子酸及芥子醛的含量,例如,相對於飲料全體,較佳為1~50v/v%左右,更佳為3~25v/v%,再更佳為5~20v/v%。 When the beverage of the present invention contains cooked wine prepared in a wooden container, the content depends on the content of gallic acid and sucralaldehyde in the cooked wine, for example, it is preferably 1 to 50 v/v relative to the entire beverage %, more preferably 3~25v/v%, even more preferably 5~20v/v%.

本發明之飲料,除上述之使用木製容器製得之熟成酒外,亦可含有其他的酒類。作為此種酒類,不特別限定,可舉出烈酒類(例如琴酒、伏特加、白蘭姆酒、橙皮甜酒(triple sec)等的烈酒、及原料用酒等)、利口酒類、燒酒等,甚而清酒、甘味果實酒、啤酒等的釀造酒。 The beverage of the present invention may contain other alcohols in addition to the matured wine made using the wooden container described above. Such alcohols are not particularly limited, and include spirits (for example, spirits such as gin, vodka, white rum, triple sec, and raw material liquor), liqueurs, shochu, etc. , Even sake, sweet fruit wine, beer and other brewed wine.

本發明之飲料亦可含有二氧化碳。一般含有二氧化碳的飲料,由於二氧化碳在口中迸開的觸感,而易使飲料獨特之風味增強,例如,有飲料的苦澀味過度增強 的傾向。因此,易因二氧化碳使苦澀味增強的飲料,可謂適宜根據本發明抑制苦澀味而飲用。又,二氧化碳亦可發揮提高飲料之舒暢的餘味的效果。 The beverage of the present invention may also contain carbon dioxide. Generally, beverages containing carbon dioxide tend to enhance the unique flavor of the beverage due to the feeling of carbon dioxide bursting in the mouth. For example, the bitterness of the beverage is excessively enhanced Propensity. Therefore, beverages that are prone to enhance the bitter taste due to carbon dioxide can be said to be suitable for drinking according to the present invention while suppressing the bitter taste. In addition, carbon dioxide can also exert the effect of enhancing the pleasant aftertaste of beverages.

對飲料賦予二氧化碳的方法不特別限定,例如,可使二氧化碳在加壓下溶解於飲料中,也可使用Zuhen Hagen公司之碳酸化器等的混合器在配管中將二氧化碳與飲料混合;又,亦可藉由對充滿二氧化碳的儲槽中噴灑飲料使飲料吸收二氧化碳,也可將飲料與碳酸水混合。 The method for imparting carbon dioxide to the beverage is not particularly limited. For example, carbon dioxide can be dissolved in the beverage under pressure, or carbon dioxide can be mixed with the beverage in the piping using a mixer such as a carbonator of Zuhen Hagen; The beverage can be absorbed by carbon dioxide by spraying the beverage into a storage tank full of carbon dioxide, or the beverage can be mixed with carbonated water.

使飲料含有二氧化碳時,若為稍高的壓力則可提升飲料的爽快感,因而較佳,例如,較佳以1.5kgf/cm2以上的二氧化碳壓力使飲料含有二氧化碳,更佳為1.8~3.5kgf/cm2,再更佳為1.9~3.0kgf/cm2。此外,於本說明書中,就氣體壓力,除非特別記載,否則意指試料溫度為20℃時的氣體壓力。飲料中的二氧化碳壓力可使用京都電子工業製氣體體積測量裝置GVA-500A來測定。使試料溫度達20℃,在前述氣體體積測量裝置中抽除容器內空氣中的氣體(洩氣)並振動後,測定二氧化碳壓力。 When the beverage contains carbon dioxide, if the pressure is slightly higher, the refreshment of the beverage can be improved, so it is preferable, for example, it is preferable to make the beverage contain carbon dioxide with a carbon dioxide pressure of 1.5 kgf/cm 2 or more, more preferably 1.8 to 3.5 kgf /cm 2 , even better is 1.9~3.0kgf/cm 2 . In addition, in this specification, the gas pressure means the gas pressure at a sample temperature of 20°C unless otherwise specified. The carbon dioxide pressure in the beverage can be measured using a gas volume measuring device GVA-500A manufactured by Kyoto Electronics Industry. After the temperature of the sample was brought to 20°C, the gas in the air in the container was evacuated (vented) and vibrated in the gas volume measuring device, and then the carbon dioxide pressure was measured.

另外,本發明之飲料中,在不妨礙本發明之效果的範圍內,亦可與一般的飲料同樣地摻混各種添加劑等。作為各種添加劑,可舉出例如糖類等的甜味料、酸味料、香料、維生素、色素類、抗氧化劑、乳化劑、保存料、萃取物類、食物纖維、pH調整劑、品質安定劑等。 In addition, in the beverage of the present invention, various additives and the like may be blended in the same manner as general beverages as long as the effect of the present invention is not hindered. Examples of various additives include sweeteners such as sugars, sours, spices, vitamins, pigments, antioxidants, emulsifiers, preservatives, extracts, dietary fiber, pH adjusters, and quality stabilizers.

本發明之飲料中的蔗糖、葡萄糖、及果糖之各含量的合計值較佳為8.0g/100ml以下。糖含量若超過8.0g/100ml則甜味過於顯著,無法以舒暢的餘味入喉。此等糖類的各含量可藉由使用流動注入裝置的生物感測器法(BF-7,王子計測機器製)來測定。蔗糖、葡萄糖、及果糖之各含量的合計值更佳為1.7g/100ml以下。於此種範圍內,不僅苦澀味的遮蔽效果優良,而且甜味不會過強而能以舒暢的餘味飲用飲料。該合計值更佳為0.1~1.7g/100ml,再更佳為0.2~1.5g/100ml。此等糖類的含量的合計值,僅有此等當中的一種存在於飲料中時係指其含量;僅有二種存在時係指彼等之含量的合計值;三種均存在時則指彼等之含量的合計值。 The total value of the contents of sucrose, glucose, and fructose in the beverage of the present invention is preferably 8.0 g/100 ml or less. If the sugar content exceeds 8.0g/100ml, the sweetness is too significant, and it cannot enter the throat with a pleasant aftertaste. Each content of these sugars can be measured by the biosensor method (BF-7, manufactured by Oji Scientific Instruments) using a flow injection device. The total value of the contents of sucrose, glucose, and fructose is more preferably 1.7 g/100 ml or less. Within this range, not only the masking effect of the bitter taste is excellent, but also the sweetness is not too strong, and the beverage can be consumed with a pleasant aftertaste. The total value is more preferably 0.1 to 1.7g/100ml, and even more preferably 0.2 to 1.5g/100ml. The total value of the contents of these sugars refers to the content when only one of them exists in the beverage; the total value of the contents when only two of them exist; the total value of them when all three are present The total value of the content.

本發明之飲料係視需求經過殺菌等步驟,而製成容器填裝飲料。例如,藉由將飲料填充於容器後進行熱水噴淋殺菌等的加熱殺菌之方法、或對飲料進行殺菌後填充於容器的方法,可製造經過殺菌的容器填裝飲料。 The beverage of the present invention is made into a container and filled with beverages through sterilization and other steps as required. For example, a sterilized container-filled beverage can be manufactured by a method of heat sterilization such as hot water spray sterilization after filling a container with a beverage, or a method of sterilizing a beverage after filling a container.

根據本發明,可提供一種可活用含木質成分之飲料所具之獨特的風味或濃厚感,同時可抑制來自木質成分之苦澀味的飲料。再者,可提供一種不死甜,至餘味仍可舒暢地飲用,且兼具柑橘類果實之新鮮的風味的容器填裝飲料。根據本發明,例如,可實現如單僅去除來自木材之苦澀味成分等、或單僅添加柑橘類的果汁、果實或者香料來賦予香味、或使用砂糖或膠質糖漿(gum syrup)來賦予甜味之因應方式無法實現之新的風味。 According to the present invention, it is possible to provide a beverage which can utilize the unique flavor or thickness of a beverage containing woody ingredients while suppressing the bitter taste from woody ingredients. Furthermore, it can provide a container-filled beverage that is immortal sweet, can be drunk comfortably aftertaste, and has a fresh flavor of citrus fruits. According to the present invention, for example, it is possible to remove only bitter and astringent ingredients from wood, or to add only citrus juices, fruits, or spices to impart flavor, or to use sugar or gum syrup to impart sweetness. New flavors that cannot be realized by the way of coping.

[實施例] [Example]

以下基於實施例進行本發明之說明,惟本發明不限定於此等實施例。 The following describes the present invention based on examples, but the present invention is not limited to these examples.

(實施例1)含有沒食子酸與檸檬烯的飲料 (Example 1) Drink containing gallic acid and limonene

對使用水與原料用酒將酒精含量調整成0~25v/v%的溶液,添加以下表1所記載的量的沒食子酸與檸檬烯,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表1。 For a solution in which the alcohol content of water and raw material wine was adjusted to 0 to 25 v/v%, the amounts of gallic acid and limonene described in Table 1 below were added to prepare each sample. For each sample, three masked professional functional inspectors were asked to evaluate the masking effect of bitterness, the intensity of lemon scent, and comprehensive evaluation according to the following criteria. The results are shown in Table 1.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸而不含檸檬烯時的苦澀味作為控制組,針對使其含有檸檬烯時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Masking effect of bitterness: For each sample, the bitterness when only gallic acid is contained but no limonene is used as a control group, and the degree of bitterness can be masked to the extent that the aftertaste can be masked when it contains limonene in 5 levels Evaluation. The person who can feel the masking effect strongly is rated as 4; the person who can feel slightly stronger is rated as 3; the person who can feel it is rated as 2; the person who can hardly feel it is rated as 1; the person who can hardly feel it is rated as 0.

檸檬香的強度:針對各試料,就檸檬般的香氣的強度,以5等級進行評估。將完全未感到檸檬香者評為4;將幾乎未感到者評為3;將可感到但還不到喪失飲料的風味平衡之程度者評為2;將可稍強感到且對飲料的風味平衡已產生影響者評為1;將可強烈感到且已喪失飲料的風味平衡者評為0。 Intensity of lemon fragrance: For each sample, the intensity of lemon-like aroma was evaluated on a 5-level scale. Rated 4 for those who did not feel the lemon scent at all; 3 for those who hardly felt it; 2 for those who could feel but did not lose the flavor balance of the beverage; 2 who felt slightly stronger and balanced the flavor of the beverage Those who have had an influence are rated 1; those who can feel strongly and have lost the flavor balance of the beverage are rated 0.

綜合評估:針對各試料,綜合性地評估遮蔽效果與檸檬香的強度所產生的飲料的風味平衡,以5等級 表示之。將極良好者評為4;將良好者評為3;將可容許者評為2;將無法容許者評為1;將不良者評為0。 Comprehensive evaluation: For each sample, comprehensively evaluate the flavor balance of the beverage produced by the masking effect and the intensity of lemon flavor, with a rating of 5 Express it. The excellent ones are rated 4; the good ones are rated 3; the allowable ones are rated 2; the unacceptable ones are rated 1; the bad ones are rated 0.

此外,表中「Alc.」係表示酒精含量,「GAL」表示沒食子酸,「LIM」則表示檸檬烯。 In addition, "Alc." in the table means alcohol content, "GAL" means gallic acid, and "LIM" means limonene.

Figure 105122917-A0202-12-0014-1
Figure 105122917-A0202-12-0014-1

由實施例1可知,在沒食子酸的含量為0.4~10.0ppm的情況下,將檸檬烯的含量取0.2~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知沒食子酸含量:檸檬烯含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 1 that when the content of gallic acid is 0.4-10.0 ppm, when the content of limonene is 0.2-5.0 ppm, it can be manufactured for the first time, and can maintain the unique flavor or thickness of the wood component, while Beverage that suppresses the bitterness of woody ingredients and can be consumed comfortably aftertaste. In particular, it can be seen that when the ratio of gallic acid content: limonene content is 3:1 to 1:3, there is a tendency for comprehensive evaluation to increase.

(實施例2)含有沒食子酸與1-萜品烯-4-醇的飲料 (Example 2) Beverage containing gallic acid and 1-terpinen-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表2所記載的量的沒食子酸與1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表2。 To a solution in which raw material wine was added to water to adjust the alcohol content to 3 v/v%, gallic acid and 1-terpinen-4-ol in the amounts described in Table 2 below were added to prepare each sample. For each sample, three masked professional functional inspectors were asked to evaluate the masking effect of bitterness, the intensity of lemon scent, and comprehensive evaluation according to the following criteria. The results are shown in Table 2.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸而不含1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Masking effect of bitterness: For each sample, the bitterness when only gallic acid was contained but no 1-terpinen-4-ol was used as a control group, and it was made to contain 1-terpinen-4-ol To the extent that the aftertaste can mask the bitter taste, it is evaluated on a 5-level scale. The person who can feel the masking effect strongly is rated as 4; the person who can feel slightly stronger is rated as 3; the person who can feel it is rated as 2; the person who can hardly feel it is rated as 1; the person who can hardly feel it is rated as 0.

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Lemon flavor intensity and comprehensive evaluation: evaluated in the same manner as in Example 1.

此外,表中「TEP」係表示1-萜品烯-4-醇。 In addition, "TEP" in the table means 1-terpinen-4-ol.

Figure 105122917-A0202-12-0016-2
Figure 105122917-A0202-12-0016-2

由實施例2可知,在沒食子酸的含量為0.4~10.0ppm的情況下,將1-萜品烯-4-醇的含量取0.1~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知沒食子酸含量:1-萜品烯-4-醇含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 2 that when the content of gallic acid is 0.4-10.0 ppm, when the content of 1-terpinen-4-ol is 0.1-5.0 ppm, it can be manufactured for the first time to maintain the wood component. The unique flavor or richness, while suppressing the bitter and astringent taste of the woody ingredients, the drink can be comfortably consumed to the aftertaste. In particular, it can be seen that when the ratio of gallic acid content: 1-terpinen-4-ol content is 3:1 to 1:3, there is a tendency to improve comprehensively.

(實施例3)含有芥子醛與檸檬烯的飲料 (Example 3) Beverage containing mustard aldehyde and limonene

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表3所記載的量的芥子醛與檸檬烯,作 成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表3。 To a solution in which wine for raw materials is added to water to adjust the alcohol content to 3 v/v%, the amounts of mustardaldehyde and limonene described in Table 3 below are added to make Into samples. For each sample, three masked professional functional inspectors were asked to evaluate the masking effect of bitterness, the intensity of lemon scent, and comprehensive evaluation according to the following criteria. The results are shown in Table 3.

苦澀味的遮蔽效果:針對各試料,將僅含有芥子醛而不含檸檬烯時的苦澀味作為控制組,針對使其含有檸檬烯時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Masking effect of bitter taste: For each sample, the bitter taste when only erucaldehyde was contained and no limonene was used as a control group, and the degree to which the bitter taste could be masked by the aftertaste when it contained limonene was evaluated in 5 levels. The person who can feel the masking effect strongly is rated as 4; the person who can feel slightly stronger is rated as 3; the person who can feel it is rated as 2; the person who can hardly feel it is rated as 1; the person who can hardly feel it is rated as 0.

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Lemon flavor intensity and comprehensive evaluation: evaluated in the same manner as in Example 1.

此外,表中「SINAP」係表示芥子醛。 In addition, "SINAP" in the table means erucaldehyde.

Figure 105122917-A0202-12-0018-3
Figure 105122917-A0202-12-0018-3

由實施例3可知,在芥子醛的含量為0.4~10.0ppm的情況下,將檸檬烯的含量取0.2~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知芥子醛含量:檸檬烯含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 3 that when the content of erucaldehyde is 0.4 to 10.0 ppm, when the content of limonene is 0.2 to 5.0 ppm, it can be manufactured for the first time, which can maintain the unique flavor or thickness of the wood component and can be suppressed The bitter and astringent taste of woody ingredients, to the aftertaste can still drink comfortably. In particular, it can be seen that when the ratio of erucaldehyde content: limonene content is 3:1 to 1:3, there is a tendency for comprehensive evaluation to increase.

(實施例4)含有芥子醛與1-萜品烯-4-醇的飲料 (Example 4) Beverage containing erucaldehyde and 1-terpinen-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表4所記載的量的芥子醛與1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、 檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表4。 To a solution in which raw material wine was added to water to adjust the alcohol content to 3 v/v%, erucaldehyde and 1-terpinen-4-ol in the amounts described in Table 4 below were added to prepare each sample. For each sample, the masking effect of bitterness, For the intensity and comprehensive evaluation of lemon scent, three trained professional functional inspectors will be evaluated according to the following criteria. The results are shown in Table 4.

苦澀味的遮蔽效果:針對各試料,將僅含有芥子醛而不含1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Masking effect of bitterness: For each sample, the bitterness when only erucaldehyde is contained and no 1-terpinen-4-ol is included as a control group, and when it contains 1-terpinen-4-ol to The degree of bitterness can be masked by the aftertaste, and it is evaluated on a 5-level scale. The person who can feel the masking effect strongly is rated as 4; the person who can feel slightly stronger is rated as 3; the person who can feel it is rated as 2; the person who can hardly feel it is rated as 1; the person who can hardly feel it is rated as 0.

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Lemon flavor intensity and comprehensive evaluation: evaluated in the same manner as in Example 1.

Figure 105122917-A0202-12-0019-4
Figure 105122917-A0202-12-0019-4

由實施例4可知,在芥子醛的含量為0.4~10.0ppm的情況下,將1-萜品烯-4-醇的含量取0.1~ 5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知芥子醛含量:1-萜品烯-4-醇含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 4 that when the content of erucaldehyde is 0.4 to 10.0 ppm, the content of 1-terpinen-4-ol is taken to be 0.1 to At 5.0 ppm, it can be manufactured for the first time to maintain the unique flavor or thickness of the wood component, while suppressing the bitter taste of the wood component, and the beverage can be comfortably consumed after the taste. In particular, it can be seen that when the ratio of erucaldehyde content: 1-terpinen-4-ol content is 3:1 to 1:3, there is a tendency to improve comprehensively.

發明品8及發明品28雖為酒精含量為0v/v%的飲料,亦即為無酒精飲料,但可獲得同樣的效果。 Invention 8 and invention 28 are beverages with an alcohol content of 0 v/v%, that is, non-alcoholic beverages, but the same effect can be obtained.

(實施例5)二氧化碳的效果 (Example 5) Effect of carbon dioxide

對混合水、原料用酒、碳酸水並調整成以下表5所記載之酒精含量及二氧化碳壓力的溶液,添加以下表5所記載的量的沒食子酸與檸檬烯,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,以與實施例1同樣的方式進行評估。將結果示於表5。 To a solution in which water, raw material wine, and carbonated water were mixed and adjusted to the alcohol content and carbon dioxide pressure described in Table 5 below, gallic acid and limonene were added in the amounts described in Table 5 below to prepare each sample. For each sample, the masking effect of bitterness, the strength of lemon scent, and the comprehensive evaluation were evaluated in the same manner as in Example 1. The results are shown in Table 5.

Figure 105122917-A0202-12-0020-5
Figure 105122917-A0202-12-0020-5

由實施例5可知,當二氧化碳壓力為1.5~2.5kgf/cm2時,可進一步獲得本發明之遮蔽效果及舒暢的口感。 It can be seen from Example 5 that when the carbon dioxide pressure is 1.5 to 2.5 kgf/cm 2 , the shielding effect and the smooth mouthfeel of the present invention can be further obtained.

(實施例6)含有沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇的飲料 (Example 6) Beverage containing gallic acid, erucaldehyde, limonene, and 1-terpinen-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表6所記載的量的沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表6。 To a solution in which wine for raw materials is added to water to adjust the alcohol content to 3 v/v%, gallic acid, erucaldehyde, limonene, and 1-terpinen-4-ol in the amounts described in Table 6 below are added , To make each sample. For each sample, three masked professional functional inspectors were asked to evaluate the masking effect of bitterness, the intensity of lemon scent, and comprehensive evaluation according to the following criteria. Table 6 shows the results.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸及芥子醛而不含檸檬烯及1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有檸檬烯及1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Masking effect of bitter taste: For each sample, the bitter taste when only containing gallic acid and erucaldehyde but not limonene and 1-terpinene-4-ol was used as a control group, and it was designed to contain limonene and 1- Terpinen-4-ol is evaluated to a degree of 5 to the extent that the aftertaste can mask the bitter taste. The person who can feel the masking effect strongly is rated as 4; the person who can feel slightly stronger is rated as 3; the person who can feel it is rated as 2; the person who can hardly feel it is rated as 1; the person who can hardly feel it is rated as 0.

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Lemon flavor intensity and comprehensive evaluation: evaluated in the same manner as in Example 1.

Figure 105122917-A0202-12-0021-6
Figure 105122917-A0202-12-0021-6

由實施例6可知,縱為同時含有沒食子酸與 芥子醛的飲料,沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇的含量若為本發明之範圍內,則仍可獲得本發明之遮蔽效果及舒暢的口感。 It can be seen from Example 6 that even if it contains gallic acid and If the content of gallic acid, erucaldehyde, limonene, and 1-terpinen-4-ol is within the scope of the present invention, the shielding effect and the smooth mouthfeel of the present invention can still be obtained.

(實施例7)糖之含量的影響 (Example 7) Influence of sugar content

對使用水與原料用酒將酒精含量調整成3v/v%的溶液,添加表7所記載的量的沒食子酸、檸檬烯,作成各試料。又,添加果糖葡萄糖液糖。以下表中所記載之「糖合計」,係指蔗糖、葡萄糖及果糖的合計量。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度請3位受過訓練的專業官能檢查員進行評估,並實施綜合評估。苦澀味的遮蔽效果與檸檬香的強度之評估基準係與實施例1相同。以下示出甜味的評估基準與綜合評估的評估基準。將結果示於表7。 To a solution in which the alcohol content was adjusted to 3 v/v% using water and raw material wine, the amounts of gallic acid and limonene described in Table 7 were added to prepare each sample. In addition, fructose glucose liquid sugar is added. "Total sugar" described in the following table refers to the total amount of sucrose, glucose and fructose. For each sample, three masked trained functional inspectors are required to evaluate the masking effect of bitterness and the intensity of lemon flavor, and conduct a comprehensive evaluation. The evaluation criteria for the masking effect of bitterness and the intensity of lemon scent are the same as in Example 1. The evaluation criteria for sweetness and evaluation criteria for comprehensive evaluation are shown below. The results are shown in Table 7.

<甜味> <sweetness>

4分:不甜,可強烈感到舒暢的美味感。 4 points: It is not sweet, but it can strongly feel a comfortable and delicious taste.

3分:不甜,至餘味仍可舒暢地飲用。 3 points: It is not sweet, and it can be consumed smoothly until the aftertaste.

2分:感到稍甜,但至餘味仍可舒暢地飲用。 2 points: It feels a little sweet, but you can still drink it even aftertaste.

1分:感到稍微死甜,不舒暢。 1 point: I feel slightly sweet and uncomfortable.

0分:極為死甜,餘味差。 0 points: Extremely sweet and poor aftertaste.

<綜合評估> <Comprehensive Evaluation>

5分:極良好者 5 points: very good

4分:較良好者 4 points: the better

3分:良好者 3 points: Good

2分:可容許 2 points: Allowable

1分:無法容許 1 point: Unacceptable

0分:不良 0 points: bad

Figure 105122917-A0202-12-0023-7
Figure 105122917-A0202-12-0023-7

存在有特定量之作為追加成分的糖時,在苦澀味的遮蔽、檸檬香、甜度方面可獲得特別優良的效果。 When there is a specific amount of sugar as an additional component, a particularly excellent effect can be obtained in terms of masking of bitterness, lemon flavor, and sweetness.

Claims (12)

一種容器填裝飲料,其係包含(A)0.4~10.0ppm的芥子醛、以及(B)0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。 A container filled beverage comprising (A) 0.4-10.0 ppm erucaldehyde, (B) 0.2-5.0 ppm limonene and/or 0.1-5.0 ppm 1-terpinen-4-ol. 如請求項1之容器填裝飲料,其係滿足以下之iii)~iv)的任一項以上:iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 If the container of claim 1 is filled with a beverage, it satisfies any one of the following iii) to iv): iii) When erucaldehyde and limonene are included, the ratio of erucaldehyde content to limonene content is 10:1~1 : 10; iv) When erucaldehyde and 1-terpinen-4-ol are included, the ratio of the erucaldehyde content to the 1-terpinen-4-ol content is 10:1 to 1:10. 如請求項1或2之容器填裝飲料,其酒精含量為0~25v/v%。 If the container of claim 1 or 2 is filled with beverage, its alcohol content is 0~25v/v%. 如請求項1或2之容器填裝飲料,其係含有二氧化碳。 If the container of claim 1 or 2 is filled with beverage, it contains carbon dioxide. 如請求項4之容器填裝飲料,其中二氧化碳的壓力為1.5kgf/cm2以上。 If the container of claim 4 is filled with a beverage, the pressure of carbon dioxide is 1.5 kgf/cm 2 or more. 如請求項1或2之容器填裝飲料,其係含有威士忌及/或白蘭地。 If the container of claim 1 or 2 is filled with beverage, it contains whiskey and/or brandy. 如請求項1或2之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 The beverage filled in the container according to claim 1 or 2, wherein the total value of the contents of sucrose, glucose, and fructose is 8.0g/100ml or less. 如請求項7之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為1.7g/100ml以下。 The beverage filled in the container according to claim 7, wherein the total value of the contents of sucrose, glucose, and fructose is 1.7 g/100 ml or less. 如請求項1之容器填裝飲料,其酒精含量為0~ 25v/v%,且含有二氧化碳。 If the container of claim 1 is filled with beverage, its alcohol content is 0~ 25v/v%, and contains carbon dioxide. 如請求項9之容器填裝飲料,其中二氧化碳的壓力為1.5kgf/cm2以上。 If the container of claim 9 is filled with a beverage, the pressure of carbon dioxide is 1.5 kgf/cm 2 or more. 如請求項9之容器填裝飲料,其係含有威士忌及/或白蘭地,且蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 The container filled with beverage according to claim 9 contains whiskey and/or brandy, and the total value of the contents of sucrose, glucose, and fructose is 8.0 g/100 ml or less. 如請求項10之容器填裝飲料,其係含有威士忌及/或白蘭地,且蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 The beverage filled in the container of claim 10 contains whiskey and/or brandy, and the total value of the contents of sucrose, glucose, and fructose is 8.0 g/100 ml or less.
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