TW201716566A - A beverage containing wood components - Google Patents

A beverage containing wood components Download PDF

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TW201716566A
TW201716566A TW105122917A TW105122917A TW201716566A TW 201716566 A TW201716566 A TW 201716566A TW 105122917 A TW105122917 A TW 105122917A TW 105122917 A TW105122917 A TW 105122917A TW 201716566 A TW201716566 A TW 201716566A
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beverage
content
limonene
gallic acid
ppm
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TW105122917A
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TWI696694B (en
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Sadahiro Ito
Akira Yoshihiro
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Suntory Holdings Ltd
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Abstract

The present invention provides a beverage in which the characteristic flavor and profoundness of wood components derived from wooden containers such as barrels or from wooden pieces are maintained and yet the bitter and astringent taste of the wood components is suppressed to thereby ensure that the beverage can be drunk until it produces a refreshing aftertaste. Incorporated in a beverage are (A) 0.4 to 10.0 ppm of galic acid and/or 0.4 to 10.0 ppm of sinapaldehyde, plus (B) 0.2 to 5.0 ppm of limonene and/or 0.1 to 5.0 ppm of 1-terpinen-4-ol.

Description

含木質成分之飲料 Woody beverage

本發明係有關於一種容器填裝飲料,其係使用如白蘭地般以酒桶等的木製容器經過熟成的酒類、或使用含有木質成分的溶液所製成的容器填裝飲料,其可充分活用該等溶液中的木質成分之特徵,同時可抑制木質成分特有的苦澀味而能夠餘味感到舒暢地飲用。 The present invention relates to a container-filled beverage which is filled with a beverage made of a cooked wooden wine in a wooden container such as a wine barrel, or a container made of a solution containing a wood component, which can fully utilize the beverage. The characteristics of the wood component in the solution, while suppressing the bitter taste characteristic of the wood component, and allowing the aftertaste to be enjoyed comfortably.

眾所皆知,如白蘭地般使用酒桶等的木製容器經過熟成的酒類,透過熟成而讓味道變得更圓潤,硫化合物等呈現不佳之香氣(未熟成香)的成分消失,另一方面則生成起因於酯類或雜醇類、糠醛等之如果實般的華麗香氣(熟成香),而發揮各酒類特有的香味。另外,已知來自木製容器之成分(木質成分)會藉由醇類分解、溶出,而對酒類賦予甜味或澀味等味道的深醇感。如此所得之含有木質成分的酒類有時會直接飲用,有時也會與冰塊一起飲用、或用水稀釋等而飲用。又,例如,已知有一種藉由對裝有冰塊的平底玻璃杯(tumbler)倒入使用木製容器經過熟成的酒類,再倒滿冰涼蘇打水並輕輕攪動所作成之稱為 「高杯酒(highball,高球)」的雞尾酒調酒法(非專利文獻1)。高杯酒由於可藉由用蘇打水稀釋之簡便的手段作成具有清爽風味的雞尾酒而極受歡迎,隨時可於居酒屋等餐飲處品嚐之。 It is well known that, in the case of brandy, wooden containers such as wine barrels are used to make the taste more rounded by ripening, and the ingredients such as sulfur compounds that exhibit poor aroma (unripe into aroma) disappear. On the other hand, The scent which is characteristic of each wine is exhibited by the scent of the scent of the scent of the scent of the scent of the scent. Further, it is known that a component (wood component) derived from a wooden container is decomposed and eluted by an alcohol to impart a deep alcoholy feeling such as a sweet taste or an astringent taste to the wine. The wood-containing wine thus obtained may be directly consumed, and may be drunk with ice or diluted with water. Further, for example, a method is known in which a tumbler containing ice cubes is poured into a wooden container and the cooked wine is poured, and then the cold soda is poured and gently stirred. Cocktail bartending method of "highball (highball)" (Non-Patent Document 1). The high glass wine is extremely popular because it can be made into a refreshing cocktail by the simple means of dilution with soda water. It can be tasted at any catering room such as the Izakaya.

另一方面,由於柑橘類具有爽口的芳香或酸甜味,其果汁、果實或香料經常作為飲食品的原料極受歡迎。又,由於容器填裝飲料有別於在家庭或居酒屋等在臨飲用前摻混各種飲料或果汁等而成的飲料,要在填充步驟中對容器填充飲料後經過殺菌步驟、或經過長時間的流通或保存步驟,熱歷程極為嚴峻,也有時會損及新鮮的風味而產生劣化香味。 On the other hand, since citrus has a refreshing aroma or sweet and sour taste, its juice, fruit or spice is often very popular as a raw material for foods and drinks. Moreover, since the container-filled beverage is different from a beverage obtained by blending various beverages or fruit juices before drinking, such as a family or an izakaya, it is necessary to sterilize the container after filling the beverage in the filling step, or after a long period of time. In the circulation or storage steps, the heat history is extremely severe, and sometimes the flavor is deteriorated and the flavor is deteriorated.

[先前技術文獻] [Previous Technical Literature] [非專利文獻] [Non-patent literature]

[非專利文獻1] NBA Official Cocktailbook,社團法人日本調酒師協會編著,柴田書店股份有限公司,1990年9月1日發行 [Non-Patent Document 1] NBA Official Cocktailbook, edited by Japan Association of Bartenders, Japan, Shibata Bookstore Co., Ltd., issued on September 1, 1990

如此,使用以酒桶等的木製容器經過熟成的酒類所製作的飲料、或使用含有木質成分的溶液所製作的飲料有各式各樣。其中,將如高杯酒般以酒桶等的木製容 器經過熟成的酒類以碳酸鈉稀釋時,儘管該酒類的含量會減少,但木質成分的味道有時仍會以不佳之形態影響餘味。 As described above, beverages prepared by using cooked wines in wooden containers such as wine barrels or beverages prepared using solutions containing wood components are various. Among them, the wooden capacity of a wine barrel, like a tall glass of wine When the cooked wine is diluted with sodium carbonate, although the content of the wine is reduced, the taste of the wood component sometimes affects the aftertaste in a poor form.

本案發明人等就來自酒桶等的木製容器或木材之木質成分的苦澀味,著眼於沒食子酸與芥子醛。沒食子酸及芥子醛為木製容器或木材所含之單寧或木質素經水解而向飲料中溶出的物質,係對飲料的味道賦予苦澀感或深醇感、濃厚感的成分。本案發明人等致力進行研究的結果發現,針對特定量的沒食子酸及/或芥子醛,使其含有特定量的檸檬烯及/或1-萜品烯-4-醇時,可維持來自木製容器或木材之木質成分的獨特的風味或濃厚感,同時可減少來自沒食子酸及/或芥子醛的苦澀味,而能夠製造至餘味仍舒暢順口的飲料。亦即,本發明雖不限定於此等,惟包含以下之態樣。 The inventors of the present invention focused on the bitter taste of the woody component of the wooden container or the wood from the casks, and focused on gallic acid and sinaldehyde. Gallic acid and mustard aldehyde are components in which a tannin or lignin contained in a wooden container or wood is hydrolyzed and eluted into a beverage, and is a component which imparts a bitter feeling or a deep sensation and a strong feeling to the taste of the beverage. As a result of intensive studies conducted by the inventors of the present invention, it has been found that when a specific amount of gallic acid and/or guar aldehyde is contained in a specific amount of limonene and/or 1-terpinene-4-ol, it can be maintained from wood. The unique flavor or richness of the woody ingredients of the container or wood, while reducing the bitter taste from gallic acid and/or squalic aldehyde, can produce a beverage that has a smooth aftertaste. That is, the present invention is not limited to this and the like, but includes the following aspects.

(1)一種容器填裝飲料,其係包含(A)0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛、以及(B)0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。 (1) A container-filled beverage comprising (A) 0.4 to 10.0 ppm of gallic acid and/or 0.4 to 10.0 ppm of sinaldehyde, and (B) 0.2 to 5.0 ppm of limonene and/or 0.1~ 5.0 ppm of 1-terpinene-4-ol.

(2)如(1)之容器填裝飲料,其係滿足以下之i)~iv)的任一項以上:i)包含沒食子酸與檸檬烯時,沒食子酸含量相對於檸 檬烯含量的比率為10:1~1:10;ii)包含沒食子酸與1-萜品烯-4-醇時,沒食子酸含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10;iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 (2) The container of (1) is filled with a beverage which satisfies any one of the following i) to iv): i) when gallic acid and limonene are contained, the gallic acid content is relative to the lemon The ratio of limen content is 10:1~1:10; ii) when gallic acid and 1-terpinene-4-ol are included, the content of gallic acid is relative to the content of 1-pinene-4-ol The ratio is 10:1~1:10; iii) when the content of squalene and limonene is included, the ratio of the content of sinapine to the content of limonene is 10:1~1:10; iv) contains squalane and 1-terpinene- In the case of 4-alcohol, the ratio of the content of sinapic aldehyde to the content of 1-nonpinen-4-ol is 10:1 to 1:10.

(3)如(1)或(2)之容器填裝飲料,其酒精含量為0~25v/v%。 (3) If the container of (1) or (2) is filled with a beverage, the alcohol content is 0 to 25 v/v%.

(4)如(1)~(3)中任一項之容器填裝飲料,其係含有二氧化碳。 (4) The container-filled beverage according to any one of (1) to (3), which contains carbon dioxide.

(5)如(4)之容器填裝飲料,其中二氧化碳的壓力為1.5kgf/cm2以上。 (5) The container according to (4), wherein the pressure of carbon dioxide is 1.5 kgf/cm 2 or more.

(6)如(1)~(5)中任一項之容器填裝飲料,其係含有威士忌及/或白蘭地。 (6) The container-filled beverage according to any one of (1) to (5) which contains whiskey and/or brandy.

(7)如(1)~(6)中任一項之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 (7) The container-filled beverage according to any one of (1) to (6), wherein a total value of each of sucrose, glucose, and fructose is 8.0 g/100 ml or less.

(8)如(7)之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為1.7g/100ml以下。 (8) The container according to (7), wherein the total content of each of sucrose, glucose, and fructose is 1.7 g/100 ml or less.

根據本發明,可提供一種可在含有來自木製容器或木材之木質成分的飲料中維持木質成分之獨特的風味或濃厚感,同時可抑制木質成分之苦澀味,至餘味仍可 舒暢地飲用的飲料。 According to the present invention, it is possible to provide a unique flavor or a rich feeling of a wood component in a beverage containing a wood component from a wooden container or wood, and at the same time, suppress the bitterness of the wood component until the aftertaste remains A drink that is comfortable to drink.

[實施發明之形態] [Formation of the Invention]

本發明係提供一種在含有特定量的沒食子酸及/或芥子醛作為呈現來自酒桶等的木製容器或木材之木質成分特有的苦澀味之成分的飲料中,透過使其含有特定量的檸檬烯及/或1-萜品烯-4-醇,可維持木質成分所具之獨特的風味與濃厚感,同時可抑制苦澀味,至餘味仍可舒暢地飲用的飲料。 The present invention provides a beverage containing a specific amount of gallic acid and/or serranoaldehyde as a component of a bitter taste characteristic of a wood container or wood component derived from a wine barrel or the like, and is contained in a specific amount. Limonene and/or 1-terpinene-4-ol, a beverage that maintains the unique flavor and richness of woody ingredients, while suppressing bitterness and taste, and allowing for a relaxing aftertaste.

(沒食子酸、芥子醛) (gallic acid, mustard aldehyde)

沒食子酸(gallic acid,C7H6O5)及芥子醛(sinapaldehyde,C11H12O4)為酒桶等的木製容器或使用之木材中的單寧或木質素經水解而向飲料中溶出的物質,係對飲料的味道賦予苦澀感或深醇感的成分之一。本發明之飲料係包含0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛作為木質成分。沒食子酸的含量較佳為0.4~5.0ppm,更佳為0.5~2.0ppm。芥子醛的含量較佳為0.4~5.0ppm,更佳為0.5~2.0ppm。沒食子酸或芥子醛的含量若未達0.4ppm,無法感受到木質成分所產生之味道的深醇感;超過10.0ppm則苦澀味顯著,縱使進行後述之檸檬烯及/或1-萜品烯-4-醇的添加亦不易抑制苦澀味。此外,本說明書中單位ppm係與單位mg/l同義。 Gallic acid (C 7 H 6 O 5 ) and sinapaldehyde (C 11 H 12 O 4 ) are wooden containers such as wine barrels or tannin or lignin in wood used for hydrolysis The substance eluted in the beverage is one of the ingredients which impart a bitter feeling or a deep sensation to the taste of the beverage. The beverage of the present invention contains 0.4 to 10.0 ppm of gallic acid and/or 0.4 to 10.0 ppm of sinapic aldehyde as a wood component. The content of gallic acid is preferably from 0.4 to 5.0 ppm, more preferably from 0.5 to 2.0 ppm. The content of the mustard aldehyde is preferably from 0.4 to 5.0 ppm, more preferably from 0.5 to 2.0 ppm. If the content of gallic acid or mustard aldehyde is less than 0.4 ppm, the deep alcoholy sensation of the taste of the wood component cannot be felt; if it exceeds 10.0 ppm, the bitter taste is remarkable, even if the limonene and/or 1-terpinene described later is carried out. The addition of -4-ol is also not easy to suppress bitterness. In addition, the unit ppm system in this specification is synonymous with the unit mg/l.

飲料中的沒食子酸及芥子醛的量可使用高效液相層析儀(HPLC)或超高效液相層析儀(UHPLC)等來測定。能以例如以下之分析機種、條件來測定。 The amount of gallic acid and mustard aldehyde in the beverage can be measured using a high performance liquid chromatography (HPLC) or an ultra high performance liquid chromatography (UHPLC) or the like. It can be measured, for example, by the following analysis models and conditions.

測定機種:LC HP 1100 series(Agilent Technologies) Measuring machine: LC HP 1100 series (Agilent Technologies)

管柱:phenomenex Luna 5μ C18(2)100A 150 * 4.60mm(00F-4252-E0) Column: phenomenex Luna 5μ C18(2)100A 150 * 4.60mm(00F-4252-E0)

管柱溫度:40℃ Column temperature: 40 ° C

檢測器:UV-VIS Detector: UV-VIS

注入量:5.0μl。 Injection amount: 5.0 μl.

飲料中的沒食子酸及/或芥子醛,若考量飲料之風味的平衡,則較佳為來自酒桶等的木製容器或木材者;亦可含有其他物質,例如萃取自其他植物者,例如萃取自茶葉、藥草、或香料者,又,亦可含有香料、色素等。 The gallic acid and/or serranic aldehyde in the beverage is preferably a wooden container or wood from a wine barrel or the like if the balance of the flavor of the beverage is considered; and may also contain other substances, such as those extracted from other plants, for example Extracted from tea, herbs, or spices, it may also contain spices, pigments, and the like.

(檸檬烯、1-萜品烯-4-醇) (limonene, 1-terpinene-4-ol)

檸檬烯(d-limonene,C10H16)為柑橘果實的果皮等所含之單環式單萜烯的一種,係呈現所謂柑橘般的香氣的成分。1-萜品烯-4-醇(1-Terpinene-4-ol,C10H18O)為柑橘果實的果皮等所含之單萜烯醇的一種,係呈現所謂柑橘般的香氣的成分。本發明之飲料係包含0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。檸檬烯的含量較佳為0.3~2.5ppm。1-萜品烯-4-醇的含量較佳為0.15~2.5ppm。藉由對含有前述之特定量的沒食子酸及/或芥子 醛的飲料,使其以上述量含有檸檬烯及/或1-萜品烯-4-醇,可適度地遮蔽沒食子酸及/或芥子醛之木質成分的苦澀味,同時可提高飲料的舒暢感。檸檬烯的含量少於0.2ppm或1-萜品烯-4-醇的含量少於0.1ppm時,無法獲得苦澀味的抑制效果;另一方面,檸檬烯及/或1-萜品烯-4-醇的含量多於5.0ppm時則檸檬烯或1-萜品烯-4-醇特有之柑橘般的香氣(尤為檸檬般的香氣)會過強,且來自沒食子酸或芥子醛的味道濃厚感也會降低,而喪失飲料的風味平衡或味道濃厚感的平衡。 Limonene (d-limonene, C 10 H 16 ) is a kind of monocyclic monoterpene contained in the peel of citrus fruits, etc., and is a component which exhibits a so-called citrus-like aroma. 1-terpinene-4-ol (1-Terpinene-4-ol, C 10 H 18 O) is one of the monoterpene alcohols contained in the peel of a citrus fruit, etc., and is a component which exhibits a so-called citrus-like aroma. The beverage of the present invention comprises from 0.2 to 5.0 ppm of limonene and/or from 0.1 to 5.0 ppm of 1-terpinene-4-ol. The content of limonene is preferably from 0.3 to 2.5 ppm. The content of 1-nonpinene-4-ol is preferably from 0.15 to 2.5 ppm. By including a specific amount of gallic acid and/or serranoaldehyde in the above-mentioned beverage, limonene and/or 1-terpinene-4-ol are contained in the above amount, and the gallic acid can be appropriately masked. / or the bitter taste of the woody component of the mustard aldehyde, while improving the comfort of the beverage. When the content of limonene is less than 0.2 ppm or the content of 1-terpinene-4-ol is less than 0.1 ppm, the inhibitory effect of bitter and astringent taste cannot be obtained; on the other hand, limonene and/or 1-terpinene-4-ol When the content is more than 5.0 ppm, the citrus-like aroma (especially lemon-like aroma) unique to limonene or 1-terpinene-4-ol is too strong, and the taste from gallic acid or mustard aldehyde is also strong. It will decrease, and lose the balance of flavor balance or rich taste of the beverage.

飲料中的檸檬烯及1-萜品烯-4-醇的含量,例如可藉由對飲料提供含有檸檬烯及/或1-萜品烯-4-醇的精油或香料等來調整,亦可藉由對飲料提供含有檸檬烯及/或1-萜品烯-4-醇的柑橘蒸餾酒或柑橘浸漬酒來調整,也可藉由對飲料添加包含檸檬烯及/或1-萜品烯-4-醇之柑橘果實的果汁來調整。檸檬烯及/或1-萜品烯-4-醇為在柑橘果實中富含於果皮的成分,因此,若使用柑橘果實的果汁時,較佳使用含有果皮或果皮油的果汁,例如帶肉果汁。使用柑橘果實的果汁時,果實的種類不特別限定,例如包含於柑橘屬(Citrus)、金橘屬(Fortunella)、枳屬(Poncirus)之葡萄柚、檸檬、萊姆、柳橙、柚子、酢橘、臭橙、八朔、金橘、臺灣香檬等略帶酸味的柑橘果實由於可提高飲料的舒暢感,因而較佳。飲料中之果汁的含量係取決於果汁中的檸檬烯及/或1-萜品烯-4-醇的含量,而相對於飲料全體,以果汁率換算較佳為30.0w/w%以下左右,更佳為 0.5~10.0w/w%,但不限定於此。此外,「果汁率」係指將榨取果汁所得之純果汁設為100%時的相對濃度。例如,可基於JAS規格(果實飲料之日本農林規格)所示之各種果實之純果汁的糖用折射計讀值之基準或酸度之基準,藉由計算而求得。 The content of limonene and 1-terpinene-4-ol in the beverage can be adjusted, for example, by providing an essential oil or a fragrance containing limonene and/or 1-terpinene-4-ol to the beverage, or by Adjusting the beverage with citrus distilled liquor or citrus impregnated liquor containing limonene and/or 1-terpinene-4-ol, or by adding lemonene and/or 1-terpinene-4-ol to the beverage The juice of the citrus fruit is adjusted. Limonene and/or 1-terpinene-4-ol is a component rich in peel in citrus fruits. Therefore, when fruit juice of citrus fruit is used, it is preferred to use a juice containing peel or peel oil, for example, with meat juice. . When the juice of the citrus fruit is used, the type of the fruit is not particularly limited, and is, for example, included in the genus Citrus, Fortunella, grapefruit of the genus Poncirus, lemon, lime, orange, grapefruit, and medlar. Slightly sour citrus fruits such as tangerine, orange, gossip, kumquat, and Taiwanese lemon are preferred because they improve the comfort of the beverage. The content of the juice in the beverage depends on the content of limonene and/or 1-terpinene-4-ol in the juice, and is preferably about 30.0 w/w% or less in terms of the juice ratio with respect to the entire beverage. Good for 0.5 to 10.0 w/w%, but is not limited thereto. In addition, the "fruit juice rate" refers to the relative concentration when the pure juice obtained by extracting the juice is set to 100%. For example, it can be calculated by calculation based on the basis of the refractometer reading value or the acidity of the pure fruit juice of various fruits shown by the JAS specification (Japanese agricultural and forestry specifications of fruit drinks).

飲料中的檸檬烯及1-萜品烯-4-醇的含量可依以下方法測定。 The content of limonene and 1-terpinene-4-ol in the beverage can be determined by the following method.

[檸檬烯及1-萜品烯-4-醇的測定] [Determination of limonene and 1-terpinene-4-ol]

將作為試料的液體組成物依以下條件供予至氣相層析分析(GC-FID)。分析條件如下:分析前處理:將試樣填充於Extrelut NT-1管柱,以醚進行萃取。 The liquid composition as a sample was supplied to gas chromatography analysis (GC-FID) under the following conditions. The analytical conditions were as follows: pre-analytical treatment: The sample was filled in an Extrelut NT-1 column and extracted with ether.

分析裝置:GC6890N(Agilent Technologies) Analytical device: GC6890N (Agilent Technologies)

管柱:HP-ULTRA2內徑0.32mm、長度50m、膜厚0.52μm Column: HP-ULTRA2 inner diameter 0.32mm, length 50m, film thickness 0.52μm

載送氣體:Helium Carrier gas: Helium

流量:2.2ml/min Flow rate: 2.2ml/min

注入口:Splitless Note entry: Splitless

注入口溫度:250℃ Injection temperature: 250 ° C

烘箱溫度:45℃(1.5min)→5℃/min→230℃(11.5min) Oven temperature: 45 ° C (1.5 min) → 5 ° C / min → 230 ° C (11.5 min)

檢測器:FID Detector: FID

檢測器溫度:260℃ Detector temperature: 260 ° C

注入量:1.0μl Injection amount: 1.0μl

標準物質:檸檬烯或1-萜品烯-4-醇 Reference material: limonene or 1-terpinene-4-ol

本發明之飲料不限定於此,惟較佳滿足以下之i)~iv)的任一項以上之條件。 The beverage of the present invention is not limited thereto, and it is preferable to satisfy the conditions of any one of the following i) to iv).

i)包含沒食子酸與檸檬烯時,沒食子酸含量相對於檸檬烯含量的比率為10:1~1:10;ii)包含沒食子酸與1-萜品烯-4-醇時,沒食子酸含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10;iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 i) When gallic acid and limonene are included, the ratio of gallic acid content to limonene content is 10:1 to 1:10; ii) when gallic acid and 1-terpinene-4-ol are included, The ratio of gallic acid content to 1-nonpinene-4-ol content is 10:1 to 1:10; iii) when mustard aldehyde and limonene are included, the ratio of mustard aldehyde content to limonene content is 10:1 ~1:10; iv) When the content of sinapicaldehyde and 1-terpinene-4-ol is included, the ratio of the content of sinapicaldehyde to the content of 1-terpinene-4-ol is 10:1 to 1:10.

再者,i)沒食子酸含量相對於檸檬烯含量的比率為3:1~1:3則更佳,ii)沒食子酸含量相對於1-萜品烯-4-醇含量的比率為3:1~1:3則更佳,iii)芥子醛含量相對於檸檬烯含量的比率為3:1~1:3則更佳,iv)芥子醛含量相對於1-萜品烯-4-醇含量的比率為3:1~1:3則更佳。若滿足上述之條件,則可進一步提高檸檬烯及/或1-萜品烯-4-醇所產生之苦澀味的遮蔽效果、與飲料之舒暢感的提升效果。 Furthermore, i) the ratio of gallic acid content to limonene content is preferably 3:1 to 1:3, and ii) the ratio of gallic acid content to 1-terpinene-4-ol content is 3:1~1:3 is better, iii) the ratio of mustard aldehyde content to limonene content is 3:1~1:3, and iv) mustard aldehyde content relative to 1-terpinene-4-ol A ratio of content of 3:1 to 1:3 is more preferable. When the above conditions are satisfied, the shading effect of the bitter taste produced by limonene and/or 1-terpinene-4-ol can be further improved, and the effect of improving the comfort of the beverage can be improved.

(飲料) (Drink)

本發明之飲料的酒精含量較佳為0~25v/v%,更佳為3~25v/v%,再更佳為3~9v/v%。此外,於本發明中,若非特別合先敘明,則「酒精」係指乙醇。又,酒精含量係 指乙醇的含量(v/v%)。飲料的酒精含量可利用周知之手法來測定。例如,可藉由國稅廳規定分析法(平19國稅廳訓令第6號,2007年6月22日改定)所記載的方法來測定。 The alcohol content of the beverage of the present invention is preferably from 0 to 25 v/v%, more preferably from 3 to 25 v/v%, still more preferably from 3 to 9 v/v%. Further, in the present invention, "alcohol" means ethanol unless otherwise specified. Also, the alcohol content Refers to the content of ethanol (v / v%). The alcohol content of the beverage can be determined by well-known techniques. For example, it can be measured by the method described in the National Tax Agency's Regulations (April 19 National Tax Agency Order No. 6, revised on June 22, 2007).

本發明之飲料係如上述含有沒食子酸及/或芥子醛。沒食子酸與芥子醛為使用酒桶等的木製容器經過熟成所得之酒類中來自木製容器之苦澀味成分的指標之一,本發明之飲料較佳含有使用酒桶等的木製容器經過熟成所得之酒類。作為此種酒類,不特別限定,可舉出例如威士忌、白蘭地、康雅白蘭地、卡瓦多斯、蘭姆酒、龍舌蘭酒、酒桶熟成燒酒、酒桶熟成梅酒、葡萄酒、苦艾酒、蘋果酒等。威士忌或白蘭地,來自酒桶等的木材之成分係大量含於酒中,可謂較適宜者。 The beverage of the present invention contains gallic acid and/or sinaldehyde as described above. Gallic acid and mustard aldehyde are one of the indicators of the bitter and astringent component from the wooden container in the wine obtained by using a wooden container such as a wine barrel, and the beverage of the present invention preferably contains a wooden container using a wine barrel or the like. Alcohol. The wine is not particularly limited, and examples thereof include whiskey, brandy, Kangya brandy, calvados, rum, tequila, casks, casks, casks, wine, and absinthe. Cider and so on. Whiskey or brandy, the ingredients of wood from barrels, etc. are abundant in the wine, which is more suitable.

使本發明之飲料含有使用木製容器製得之熟成酒時,其含量係取決於熟成酒中的沒食子酸及芥子醛的含量,例如,相對於飲料全體,較佳為1~50v/v%左右,更佳為3~25v/v%,再更佳為5~20v/v%。 When the beverage of the present invention contains cooked wine obtained by using a wooden container, the content thereof depends on the content of gallic acid and sinapic aldehyde in the cooked wine, for example, preferably 1 to 50 v/v with respect to the whole beverage. % or so, more preferably 3~25v/v%, and even more preferably 5~20v/v%.

本發明之飲料,除上述之使用木製容器製得之熟成酒外,亦可含有其他的酒類。作為此種酒類,不特別限定,可舉出烈酒類(例如琴酒、伏特加、白蘭姆酒、橙皮甜酒(triple sec)等的烈酒、及原料用酒等)、利口酒類、燒酒等,甚而清酒、甘味果實酒、啤酒等的釀造酒。 The beverage of the present invention may contain other alcoholic beverages in addition to the cooked wine obtained by using the wooden container described above. The wine is not particularly limited, and examples thereof include spirits (such as gin, vodka, white rum, triple sec, and other raw materials), liqueurs, shochu, and the like. Even brewed wines such as sake, sweet fruit wine, and beer.

本發明之飲料亦可含有二氧化碳。一般含有二氧化碳的飲料,由於二氧化碳在口中迸開的觸感,而易使飲料獨特之風味增強,例如,有飲料的苦澀味過度增強 的傾向。因此,易因二氧化碳使苦澀味增強的飲料,可謂適宜根據本發明抑制苦澀味而飲用。又,二氧化碳亦可發揮提高飲料之舒暢的餘味的效果。 The beverage of the present invention may also contain carbon dioxide. Beverages that generally contain carbon dioxide, because of the touch of carbon dioxide in the mouth, can easily enhance the unique flavor of the beverage, for example, the bitter taste of the beverage is excessively enhanced. Propensity. Therefore, a beverage which is easily enhanced by bitterness by carbon dioxide is suitable for drinking in accordance with the present invention to suppress bitterness. Moreover, carbon dioxide can also exert the effect of improving the comfortable aftertaste of the beverage.

對飲料賦予二氧化碳的方法不特別限定,例如,可使二氧化碳在加壓下溶解於飲料中,也可使用Zuhen Hagen公司之碳酸化器等的混合器在配管中將二氧化碳與飲料混合;又,亦可藉由對充滿二氧化碳的儲槽中噴灑飲料使飲料吸收二氧化碳,也可將飲料與碳酸水混合。 The method of imparting carbon dioxide to the beverage is not particularly limited. For example, carbon dioxide may be dissolved in the beverage under pressure, or a mixer such as a carbonator of Zuhen Hagen Co., Ltd. may be used to mix the carbon dioxide with the beverage in the piping; The beverage can be made to absorb carbon dioxide by spraying a beverage into a tank filled with carbon dioxide, and the beverage can also be mixed with carbonated water.

使飲料含有二氧化碳時,若為稍高的壓力則可提升飲料的爽快感,因而較佳,例如,較佳以1.5kgf/cm2以上的二氧化碳壓力使飲料含有二氧化碳,更佳為1.8~3.5kgf/cm2,再更佳為1.9~3.0kgf/cm2。此外,於本說明書中,就氣體壓力,除非特別記載,否則意指試料溫度為20℃時的氣體壓力。飲料中的二氧化碳壓力可使用京都電子工業製氣體體積測量裝置GVA-500A來測定。使試料溫度達20℃,在前述氣體體積測量裝置中抽除容器內空氣中的氣體(洩氣)並振動後,測定二氧化碳壓力。 When the beverage contains carbon dioxide, if the pressure is slightly higher, the refreshing feeling of the beverage can be improved. Therefore, for example, it is preferred to use a carbon dioxide pressure of 1.5 kgf/cm 2 or more to make the beverage contain carbon dioxide, more preferably 1.8 to 3.5 kgf. /cm 2 , more preferably 1.9~3.0kgf/cm 2 . Further, in the present specification, the gas pressure means a gas pressure at a sample temperature of 20 ° C unless otherwise specified. The carbon dioxide pressure in the beverage can be measured using a gas volume measuring device GVA-500A manufactured by Kyoto Electronics Industry. The sample temperature was brought to 20 ° C, and the gas in the air in the container was evacuated (vibrated) in the gas volume measuring device and vibrated, and then the carbon dioxide pressure was measured.

另外,本發明之飲料中,在不妨礙本發明之效果的範圍內,亦可與一般的飲料同樣地摻混各種添加劑等。作為各種添加劑,可舉出例如糖類等的甜味料、酸味料、香料、維生素、色素類、抗氧化劑、乳化劑、保存料、萃取物類、食物纖維、pH調整劑、品質安定劑等。 Further, in the beverage of the present invention, various additives and the like may be blended in the same manner as a general beverage, insofar as the effects of the present invention are not impaired. Examples of the various additives include sweeteners such as saccharides, sour materials, flavors, vitamins, coloring matters, antioxidants, emulsifiers, preservatives, extracts, dietary fibers, pH adjusters, and quality stabilizers.

本發明之飲料中的蔗糖、葡萄糖、及果糖之各含量的合計值較佳為8.0g/100ml以下。糖含量若超過8.0g/100ml則甜味過於顯著,無法以舒暢的餘味入喉。此等糖類的各含量可藉由使用流動注入裝置的生物感測器法(BF-7,王子計測機器製)來測定。蔗糖、葡萄糖、及果糖之各含量的合計值更佳為1.7g/100ml以下。於此種範圍內,不僅苦澀味的遮蔽效果優良,而且甜味不會過強而能以舒暢的餘味飲用飲料。該合計值更佳為0.1~1.7g/100ml,再更佳為0.2~1.5g/100ml。此等糖類的含量的合計值,僅有此等當中的一種存在於飲料中時係指其含量;僅有二種存在時係指彼等之含量的合計值;三種均存在時則指彼等之含量的合計值。 The total value of each of the contents of sucrose, glucose, and fructose in the beverage of the present invention is preferably 8.0 g/100 ml or less. If the sugar content exceeds 8.0 g/100 ml, the sweetness is too significant, and it is impossible to enter the throat with a pleasant aftertaste. The content of these saccharides can be measured by a biosensor method (BF-7, manufactured by Oji Scientific Instruments Co., Ltd.) using a flow injection device. The total value of each of the contents of sucrose, glucose, and fructose is preferably 1.7 g/100 ml or less. Within this range, not only is the shading effect excellent, but the sweetness is not too strong and the beverage can be enjoyed with a pleasant aftertaste. The total value is preferably 0.1 to 1.7 g/100 ml, more preferably 0.2 to 1.5 g/100 ml. The total value of the contents of such sugars refers to the content of only one of them when present in the beverage; only two of them exist as the total of their contents; when all three are present, they refer to them. The total value of the content.

本發明之飲料係視需求經過殺菌等步驟,而製成容器填裝飲料。例如,藉由將飲料填充於容器後進行熱水噴淋殺菌等的加熱殺菌之方法、或對飲料進行殺菌後填充於容器的方法,可製造經過殺菌的容器填裝飲料。 The beverage of the present invention is subjected to a sterilization step or the like to form a container for filling a beverage. For example, a method in which a beverage is filled in a container, followed by heat sterilization such as hot water spray sterilization, or a method in which the beverage is sterilized and then filled in a container can be used to manufacture a sterilized container to fill the beverage.

根據本發明,可提供一種可活用含木質成分之飲料所具之獨特的風味或濃厚感,同時可抑制來自木質成分之苦澀味的飲料。再者,可提供一種不死甜,至餘味仍可舒暢地飲用,且兼具柑橘類果實之新鮮的風味的容器填裝飲料。根據本發明,例如,可實現如單僅去除來自木材之苦澀味成分等、或單僅添加柑橘類的果汁、果實或者香料來賦予香味、或使用砂糖或膠質糖漿(gum syrup)來賦予甜味之因應方式無法實現之新的風味。 According to the present invention, it is possible to provide a beverage having a unique flavor or a rich feeling which can utilize a wood-containing beverage while suppressing the bitterness of the wood component. Further, it is possible to provide a container-filled beverage which is not dead sweet, is still drinkable after the aftertaste, and has a fresh flavor of citrus fruits. According to the present invention, for example, it is possible to impart a sweetness by simply removing only a bitter taste component derived from wood, or simply adding a citrus juice, fruit or spice to impart a flavor, or using a sugar or gum syrup. A new flavor that cannot be achieved in response to the method.

[實施例] [Examples]

以下基於實施例進行本發明之說明,惟本發明不限定於此等實施例。 The invention is described below based on the examples, but the invention is not limited to the examples.

(實施例1)含有沒食子酸與檸檬烯的飲料 (Example 1) Beverage containing gallic acid and limonene

對使用水與原料用酒將酒精含量調整成0~25v/v%的溶液,添加以下表1所記載的量的沒食子酸與檸檬烯,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表1。 For the solution in which the alcohol content and the raw material wine were adjusted to 0 to 25 v/v%, gallic acid and limonene in the amounts shown in the following Table 1 were added to prepare each sample. For each sample, the shading effect of bitterness, the intensity of lemon scent, and the comprehensive evaluation were evaluated by three trained professional inspectors following the following criteria. The results are shown in Table 1.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸而不含檸檬烯時的苦澀味作為控制組,針對使其含有檸檬烯時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Shading effect of bitterness: For each sample, the bitterness and taste of gallic acid alone and no limonene are used as a control group, and the degree of bitterness can be masked when the limonene is contained, and the degree of bitterness is masked to 5 levels. Evaluation. Those who can strongly feel the masking effect are rated as 4; those who can feel slightly stronger are rated as 3; those who feel strongly are rated as 2; those who are almost unfeasible are rated as 1; those who are less likely to be rated are rated as 0;

檸檬香的強度:針對各試料,就檸檬般的香氣的強度,以5等級進行評估。將完全未感到檸檬香者評為4;將幾乎未感到者評為3;將可感到但還不到喪失飲料的風味平衡之程度者評為2;將可稍強感到且對飲料的風味平衡已產生影響者評為1;將可強烈感到且已喪失飲料的風味平衡者評為0。 Strength of lemon scent: For each sample, the intensity of the lemon-like aroma was evaluated in 5 grades. Those who did not feel lemon scent at all were rated as 4; those who felt almost no feeling were rated as 3; those who felt but did not lose the flavor balance of the beverage were rated as 2; they would feel slightly stronger and balanced the flavor of the beverage The influencer has been rated as 1; the flavor balance who can feel strongly and has lost the beverage is rated as 0.

綜合評估:針對各試料,綜合性地評估遮蔽效果與檸檬香的強度所產生的飲料的風味平衡,以5等級 表示之。將極良好者評為4;將良好者評為3;將可容許者評為2;將無法容許者評為1;將不良者評為0。 Comprehensive evaluation: For each sample, comprehensively evaluate the flavor balance of the beverage produced by the shading effect and the intensity of lemon scent, to 5 grades Express it. Ranked very good as 4; good as 3; admissible as 2; unacceptable as 1; bad as 0.

此外,表中「Alc.」係表示酒精含量,「GAL」表示沒食子酸,「LIM」則表示檸檬烯。 In addition, "Alc." in the table indicates the alcohol content, "GAL" indicates gallic acid, and "LIM" indicates limonene.

由實施例1可知,在沒食子酸的含量為0.4~10.0ppm的情況下,將檸檬烯的含量取0.2~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知沒食子酸含量:檸檬烯含量的比率為3:1~1:3時有綜合評估提高的傾向。 As is clear from Example 1, when the content of gallic acid is 0.4 to 10.0 ppm, when the content of limonene is 0.2 to 5.0 ppm, the unique flavor or richness of the wood component can be maintained for the first time, and at the same time, A beverage that inhibits the bitterness of woody ingredients and allows for a relaxing aftertaste. In particular, it is known that there is a tendency for a comprehensive evaluation to increase in the ratio of gallic acid content to limonene content of from 3:1 to 1:3.

(實施例2)含有沒食子酸與1-萜品烯-4-醇的飲料 (Example 2) Beverage containing gallic acid and 1-terpinene-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表2所記載的量的沒食子酸與1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表2。 For the solution in which the raw material was added to water and the alcohol content was adjusted to 3 v/v%, gallic acid and 1-terpinene-4-ol described in the following Table 2 were added to prepare each sample. For each sample, the shading effect of bitterness, the intensity of lemon scent, and the comprehensive evaluation were evaluated by three trained professional inspectors following the following criteria. The results are shown in Table 2.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸而不含1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Shading effect of bitterness: For each sample, the bitter taste of gallic acid alone and without 1-terpinene-4-ol was used as a control group, and it was made to contain 1-nonpinene-4-ol. The degree to which the aftertaste can mask the bitter taste is evaluated on a scale of 5. Those who can strongly feel the masking effect are rated as 4; those who can feel slightly stronger are rated as 3; those who feel strongly are rated as 2; those who are almost unfeasible are rated as 1; those who are less likely to be rated are rated as 0;

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Intensity and comprehensive evaluation of lemon aroma: evaluated in the same manner as in Example 1.

此外,表中「TEP」係表示1-萜品烯-4-醇。 Further, "TEP" in the table means 1-terpinene-4-ol.

由實施例2可知,在沒食子酸的含量為0.4~10.0ppm的情況下,將1-萜品烯-4-醇的含量取0.1~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知沒食子酸含量:1-萜品烯-4-醇含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 2 that when the content of gallic acid is 0.4 to 10.0 ppm, when the content of 1-nonpinene-4-ol is 0.1 to 5.0 ppm, the wood component can be produced for the first time. A unique flavor or richness, while suppressing the bitterness of woody ingredients, to a drink that can be enjoyed comfortably aftertaste. In particular, it can be seen that there is a tendency for the comprehensive evaluation to be improved when the ratio of gallic acid content: 1-terpinene-4-ol content is from 3:1 to 1:3.

(實施例3)含有芥子醛與檸檬烯的飲料 (Example 3) Beverage containing guaraldehyde and limonene

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表3所記載的量的芥子醛與檸檬烯,作 成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表3。 For the solution in which the raw material was added to water and the alcohol content was adjusted to 3 v/v%, the amount of sinaldehyde and limonene described in Table 3 below was added. Into each sample. For each sample, the shading effect of bitterness, the intensity of lemon scent, and the comprehensive evaluation were evaluated by three trained professional inspectors following the following criteria. The results are shown in Table 3.

苦澀味的遮蔽效果:針對各試料,將僅含有芥子醛而不含檸檬烯時的苦澀味作為控制組,針對使其含有檸檬烯時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 The shading effect of bitterness and taste: For each sample, the bitterness and taste of the case of containing only sinaldehyde and not containing limonene was used as a control group, and the degree of the bitterness was blocked when the limonene was contained, and it was evaluated in five grades. Those who can strongly feel the masking effect are rated as 4; those who can feel slightly stronger are rated as 3; those who feel strongly are rated as 2; those who are almost unfeasible are rated as 1; those who are less likely to be rated are rated as 0;

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Intensity and comprehensive evaluation of lemon aroma: evaluated in the same manner as in Example 1.

此外,表中「SINAP」係表示芥子醛。 In addition, "SINAP" in the table indicates mustard aldehyde.

由實施例3可知,在芥子醛的含量為0.4~10.0ppm的情況下,將檸檬烯的含量取0.2~5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知芥子醛含量:檸檬烯含量的比率為3:1~1:3時有綜合評估提高的傾向。 As is clear from Example 3, when the content of squalene is 0.4 to 10.0 ppm, when the content of limonene is 0.2 to 5.0 ppm, the unique flavor or richness of the wood component can be maintained for the first time, and at the same time, it can be suppressed. A bitter taste of woody ingredients, a drink that can be enjoyed comfortably aftertaste. In particular, it can be seen that there is a tendency for a comprehensive evaluation to be improved when the ratio of the guaraldehyde content: limonene content is from 3:1 to 1:3.

(實施例4)含有芥子醛與1-萜品烯-4-醇的飲料 (Example 4) Beverage containing guaraldehyde and 1-terpinene-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表4所記載的量的芥子醛與1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、 檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表4。 To the solution in which the raw material was added to water and the alcohol content was adjusted to 3 v/v%, the amount of sinaldehyde and 1-terpinene-4-ol described in the following Table 4 was added to prepare each sample. For each sample, the shading effect of bitterness, The strength and comprehensive assessment of lemon aroma are evaluated by three trained professional inspectors following the following criteria. The results are shown in Table 4.

苦澀味的遮蔽效果:針對各試料,將僅含有芥子醛而不含1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Shading effect of bitterness: For each sample, the bitterness and taste of only the guaraldehyde-containing but not 1-terpinene-4-ol is used as a control group, and when it is made to contain 1-terpinol-4-ol, The aftertaste can mask the degree of bitterness and is evaluated in 5 grades. Those who can strongly feel the masking effect are rated as 4; those who can feel slightly stronger are rated as 3; those who feel strongly are rated as 2; those who are almost unfeasible are rated as 1; those who are less likely to be rated are rated as 0;

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Intensity and comprehensive evaluation of lemon aroma: evaluated in the same manner as in Example 1.

由實施例4可知,在芥子醛的含量為0.4~10.0ppm的情況下,將1-萜品烯-4-醇的含量取0.1~ 5.0ppm時可初次製造可維持木質成分所具之獨特的風味或濃厚感,同時可抑制木質成分的苦澀味,至餘味仍可舒暢地飲用的飲料。特別是,可知芥子醛含量:1-萜品烯-4-醇含量的比率為3:1~1:3時有綜合評估提高的傾向。 It can be seen from Example 4 that, when the content of squalene is 0.4 to 10.0 ppm, the content of 1-nonpinene-4-ol is 0.1 to 0.1%. At 5.0 ppm, it can be used for the first time to produce a beverage that can maintain the unique flavor or richness of the woody ingredients, while suppressing the bitterness of the woody ingredients to a comfortable aftertaste. In particular, it can be seen that there is a tendency for a comprehensive evaluation to be improved when the ratio of the content of the mustard aldehyde: 1-terpinol-4-ol is from 3:1 to 1:3.

發明品8及發明品28雖為酒精含量為0v/v%的飲料,亦即為無酒精飲料,但可獲得同樣的效果。 Inventive product 8 and invention product 28 are beverages having an alcohol content of 0 v/v%, that is, non-alcoholic beverages, but the same effects can be obtained.

(實施例5)二氧化碳的效果 (Example 5) Effect of carbon dioxide

對混合水、原料用酒、碳酸水並調整成以下表5所記載之酒精含量及二氧化碳壓力的溶液,添加以下表5所記載的量的沒食子酸與檸檬烯,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,以與實施例1同樣的方式進行評估。將結果示於表5。 For the solution of the mixed water, the raw material wine, and the carbonated water adjusted to the alcohol content and the carbon dioxide pressure shown in the following Table 5, gallic acid and limonene in the amounts shown in the following Table 5 were added to prepare each sample. For each sample, evaluation was performed in the same manner as in Example 1 in terms of the shading effect of bitterness, the intensity of lemon scent, and the comprehensive evaluation. The results are shown in Table 5.

由實施例5可知,當二氧化碳壓力為1.5~2.5kgf/cm2時,可進一步獲得本發明之遮蔽效果及舒暢的口感。 As is apparent from Example 5, when the carbon dioxide pressure is 1.5 to 2.5 kgf/cm 2 , the masking effect and the pleasant mouthfeel of the present invention can be further obtained.

(實施例6)含有沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇的飲料 (Example 6) A beverage containing gallic acid, sinapic aldehyde, limonene, and 1-terpinene-4-ol

對將原料用酒添加於水中而將酒精含量調整成3v/v%的溶液,添加以下表6所記載的量的沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇,作成各試料。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度、及綜合評估,依循以下基準請3位受過訓練的專業官能檢查員進行評估。將結果示於表6。 The solution in which the raw material was added to water and the alcohol content was adjusted to 3 v/v% was added to the amount of gallic acid, sinaldehyde, limonene, and 1-terpinene-4-ol described in Table 6 below. , made each sample. For each sample, the shading effect of bitterness, the intensity of lemon scent, and the comprehensive evaluation were evaluated by three trained professional inspectors following the following criteria. The results are shown in Table 6.

苦澀味的遮蔽效果:針對各試料,將僅含有沒食子酸及芥子醛而不含檸檬烯及1-萜品烯-4-醇時的苦澀味作為控制組,針對使其含有檸檬烯及1-萜品烯-4-醇時至餘味可遮蔽苦澀味至何種程度,以5等級進行評估。將可強烈感到遮蔽效果者評為4;將可稍強感到者評為3;將可感到者評為2;將幾乎感受不到者評為1;將完全感受不到者評為0。 Shading effect of bitterness: For each sample, the bitterness and astringency of gallic acid and serranoaldehyde alone and without limonene and 1-terpinene-4-ol are used as a control group to contain limonene and 1- The extent to which terpinen-4-ol can be used to mask the bitter taste to the aftertaste is evaluated on a 5 scale. Those who can strongly feel the masking effect are rated as 4; those who can feel slightly stronger are rated as 3; those who feel strongly are rated as 2; those who are almost unfeasible are rated as 1; those who are less likely to be rated are rated as 0;

檸檬香的強度及綜合評估:以與實施例1同樣的方式評估。 Intensity and comprehensive evaluation of lemon aroma: evaluated in the same manner as in Example 1.

由實施例6可知,縱為同時含有沒食子酸與 芥子醛的飲料,沒食子酸、芥子醛、檸檬烯、及1-萜品烯-4-醇的含量若為本發明之範圍內,則仍可獲得本發明之遮蔽效果及舒暢的口感。 It can be seen from Example 6 that the vertical contains both gallic acid and In the case of the sinapyl aldehyde beverage, if the content of gallic acid, sinapic aldehyde, limonene, and 1-terpinene-4-ol is within the range of the present invention, the masking effect and the pleasant mouthfeel of the present invention can be obtained.

(實施例7)糖之含量的影響 (Example 7) Effect of sugar content

對使用水與原料用酒將酒精含量調整成3v/v%的溶液,添加表7所記載的量的沒食子酸、檸檬烯,作成各試料。又,添加果糖葡萄糖液糖。以下表中所記載之「糖合計」,係指蔗糖、葡萄糖及果糖的合計量。針對各試料,就苦澀味的遮蔽效果、檸檬香的強度請3位受過訓練的專業官能檢查員進行評估,並實施綜合評估。苦澀味的遮蔽效果與檸檬香的強度之評估基準係與實施例1相同。以下示出甜味的評估基準與綜合評估的評估基準。將結果示於表7。 For the solution in which the alcohol content and the raw material wine were adjusted to 3 v/v%, the amount of gallic acid and limonene described in Table 7 was added to prepare each sample. Further, fructose glucose liquid sugar was added. The "sugar total" described in the following table refers to the total amount of sucrose, glucose, and fructose. For each sample, the shading effect of bitterness and the intensity of lemon aroma were evaluated by three trained professional inspectors and a comprehensive evaluation was carried out. The evaluation criteria of the shading effect of bitterness and the intensity of lemon aroma were the same as in Example 1. The evaluation criteria for sweetness and the evaluation criteria for comprehensive evaluation are shown below. The results are shown in Table 7.

<甜味> <sweet taste>

4分:不甜,可強烈感到舒暢的美味感。 4 points: It is not sweet, and it feels refreshingly delicious.

3分:不甜,至餘味仍可舒暢地飲用。 3 points: Not sweet, until the aftertaste is still comfortable to drink.

2分:感到稍甜,但至餘味仍可舒暢地飲用。 2 points: I feel a little sweet, but I can still drink it afterwards.

1分:感到稍微死甜,不舒暢。 1 point: I feel a little bit sweet and not comfortable.

0分:極為死甜,餘味差。 0 points: Extremely sweet and sweet, with poor aftertaste.

<綜合評估> <Comprehensive evaluation>

5分:極良好者 5 points: very good

4分:較良好者 4 points: better

3分:良好者 3 points: good

2分:可容許 2 points: allowable

1分:無法容許 1 point: Unacceptable

0分:不良 0 points: bad

存在有特定量之作為追加成分的糖時,在苦澀味的遮蔽、檸檬香、甜度方面可獲得特別優良的效果。 When there is a specific amount of sugar as an additional component, a particularly excellent effect can be obtained in the masking of bitterness, lemon flavor, and sweetness.

Claims (8)

一種容器填裝飲料,其係包含(A)0.4~10.0ppm的沒食子酸及/或0.4~10.0ppm的芥子醛、以及(B)0.2~5.0ppm的檸檬烯及/或0.1~5.0ppm的1-萜品烯-4-醇。 A container-filled beverage comprising (A) 0.4 to 10.0 ppm of gallic acid and/or 0.4 to 10.0 ppm of sinaldehyde, and (B) 0.2 to 5.0 ppm of limonene and/or 0.1 to 5.0 ppm 1-terpinene-4-ol. 如請求項1之容器填裝飲料,其係滿足以下之i)~iv)的任一項以上:i)包含沒食子酸與檸檬烯時,沒食子酸含量相對於檸檬烯含量的比率為10:1~1:10;ii)包含沒食子酸與1-萜品烯-4-醇時,沒食子酸含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10;iii)包含芥子醛與檸檬烯時,芥子醛含量相對於檸檬烯含量的比率為10:1~1:10;iv)包含芥子醛與1-萜品烯-4-醇時,芥子醛含量相對於1-萜品烯-4-醇含量的比率為10:1~1:10。 The container of claim 1 is filled with a beverage which satisfies any one of the following i) to iv): i) when gallic acid and limonene are contained, the ratio of gallic acid content to limonene content is 10 :1~1:10; ii) When gallic acid and 1-terpinene-4-ol are included, the ratio of gallic acid content to 1-pinene-4-ol content is 10:1~ 1:10; iii) When mulberry aldehyde and limonene are included, the ratio of sinapic aldehyde content to limonene content is 10:1 to 1:10; iv) when mustard aldehyde and 1-terpinene-4-ol are used, mustard aldehyde The ratio of the content to the 1-nonpinene-4-ol content is from 10:1 to 1:10. 如請求項1或2之容器填裝飲料,其酒精含量為0~25v/v%。 If the container of claim 1 or 2 is filled with a beverage, the alcohol content is 0 to 25 v/v%. 如請求項1~3中任一項之容器填裝飲料,其係含有二氧化碳。 The container according to any one of claims 1 to 3, which contains a carbon dioxide. 如請求項4之容器填裝飲料,其中二氧化碳的壓力為1.5kgf/cm2以上。 The container of claim 4 is filled with a beverage in which the pressure of carbon dioxide is 1.5 kgf/cm 2 or more. 如請求項1~5中任一項之容器填裝飲料,其係含有威士忌及/或白蘭地。 The container of any one of claims 1 to 5, which contains a whiskey and/or brandy. 如請求項1~6中任一項之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為8.0g/100ml以下。 The container according to any one of claims 1 to 6, wherein the total content of each of sucrose, glucose, and fructose is 8.0 g/100 ml or less. 如請求項7之容器填裝飲料,其中蔗糖、葡萄糖、及果糖之各含量的合計值為1.7g/100ml以下。 The container of claim 7 is filled with a beverage, wherein the total content of each of sucrose, glucose, and fructose is 1.7 g/100 ml or less.
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JP7053351B2 (en) * 2018-04-06 2022-04-12 アサヒビール株式会社 Containerized carbonated alcoholic beverages and their manufacturing methods
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