TWI695895B - Method of fabricating aluminum-magnesium-silicon alloy sheet with high bendability - Google Patents

Method of fabricating aluminum-magnesium-silicon alloy sheet with high bendability Download PDF

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TWI695895B
TWI695895B TW108136899A TW108136899A TWI695895B TW I695895 B TWI695895 B TW I695895B TW 108136899 A TW108136899 A TW 108136899A TW 108136899 A TW108136899 A TW 108136899A TW I695895 B TWI695895 B TW I695895B
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aluminum
magnesium
silicon alloy
alloy sheet
hot
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TW202115265A (en
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石漢正
庾忠義
洪啟洋
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中國鋼鐵股份有限公司
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Abstract

This invention is focused on a method of fabricating an aluminum-magnesium-silicon alloy sheet with high bendability. In this method, the aluminum slabs with a specific composition range were hot-rolled and cold-rolled into aluminum sheets by specific steps, followed by a necessary heat treatment. During the fabrication, an innovative two-step homogenization process was introduced on aluminum slabs to remove the harmful low-melting-point Mg 2Si phase and further to spheroidize the irregular, hard Al 15(Fe,Mn) 3Si 2phase. Moreover, a unique intermediate annealing process at high temperatures is also applied between a hot rolling step and a cold rolling step, so that the obtained aluminum-magnesium-silicon alloy sheets with randomized distribution of grain orientation show very excellent bendability, which do not cause microcracks during a bending process and still have a commercially acceptable post-baking yield strength (PBYS).

Description

高彎折性鋁鎂矽合金片材的製造方法Method for manufacturing high-bending aluminum magnesium silicon alloy sheet

本發明係關於一種合金片材的製造方法,特別是關於一種高彎折性鋁鎂矽合金片材的製造方法。The invention relates to a method for manufacturing an alloy sheet, in particular to a method for manufacturing an aluminum magnesium silicon alloy sheet with high bendability.

鋁鎂矽合金因具有質量輕、成形性佳以及塗漆烘烤後強度高的優點,此種材料已經成為世界汽車輕量化的主流。然而,此種材料於沖壓成型為引擎蓋之外鈑件和內鈑件之後,外鈑件尚需經過彎折來包覆內鈑件。雖然,在彎折處具有粗糙表面是可被接受的,但不可具有微裂縫。因為這會影響上述組合件的安全性。然而,現有的鋁鎂矽合金在彎折處往往會產生微裂縫。Al-Mg-Si alloy has the advantages of light weight, good formability and high strength after painting and baking. This kind of material has become the mainstream of lightweight vehicles in the world. However, after this material is stamped and formed into the outer and inner sheet parts of the hood, the outer sheet parts still need to be bent to cover the inner sheet parts. Although it is acceptable to have a rough surface at the bend, it should not have micro cracks. Because this will affect the safety of the above assembly. However, existing aluminum-magnesium-silicon alloys often produce micro-cracks at the bends.

故,有必要提供一種高彎折性鋁鎂矽合金片材,以解決習用技術所存在的問題。Therefore, it is necessary to provide a high-bendability aluminum-magnesium-silicon alloy sheet to solve the problems in the conventional technology.

本發明之一目的在於提供一種高彎折性鋁鎂矽合金片材的製造方法,其係通過特定的熱軋與冷軋步驟將特定組成的鋁胚製成鋁片,然後施予必要的熱處理;其間,藉由創新的兩段式均質化步驟來去除鋁胚中有害的低熔點相(Mg 2Si),並且將不規則的硬脆相(Al 15(Fe,Mn) 3Si 2)予以球化,此外,也在熱軋步驟與冷軋步驟之間施予獨特的高溫中間退火步驟,使得所製高彎折性鋁鎂矽合金片材的晶粒方位能散亂分佈,因而在彎折過程中不致產生微裂縫,同時仍具有商業上可接受的烘烤後降伏強度(PBYS)。 One object of the present invention is to provide a method for manufacturing a high-bendability aluminum magnesium silicon alloy sheet, which is to form aluminum sheets of a specific composition into aluminum sheets through specific hot rolling and cold rolling steps, and then apply necessary heat treatment ; In the meantime, through the innovative two-stage homogenization step to remove the harmful low-melting phase (Mg 2 Si) in the aluminum embryo, and the irregular hard and brittle phase (Al 15 (Fe,Mn) 3 Si 2 ) Spheroidization, in addition, a unique high-temperature intermediate annealing step is also applied between the hot rolling step and the cold rolling step, so that the grain orientation of the produced highly bendable aluminum magnesium silicon alloy sheet can be scattered and distributed No micro-cracks are generated during the folding process, while still having commercially acceptable yield strength after baking (PBYS).

為達上述之目的,本發明提供一種高彎折性鋁鎂矽合金片材的製造方法,包含步驟:提供一鋁胚,包含:0.8至1.5重量百分比的矽;0.2至0.7重量百分比的鎂;0.1至0.5重量百分比的鐵;0.01至0.2重量百分比的錳;總量小於0.15重量百分比的一或多個雜質;及其餘為鋁;對該鋁胚進行一均質化處理,包含:以530至540℃對該鋁胚進行一第一段均質化步驟達3至8小時;及以560至570℃對該鋁胚進行一第二段均質化步驟達9至12小時;對進行該均質化處理後的該鋁胚進行一熱軋步驟,以形成一熱軋板材,其中該熱軋步驟的一完軋溫度介於250至300℃之間;以380至560℃對該熱軋板材進行一中間退火步驟達30秒至3小時;對進行該中間退火步驟後的該熱軋板材進行一冷軋步驟,以形成一冷軋片材;以及對該冷軋片材進行一熱處理步驟,以製得該高彎折性鋁鎂矽合金片材。In order to achieve the above object, the present invention provides a method for manufacturing a highly bendable aluminum magnesium silicon alloy sheet, comprising the steps of: providing an aluminum blank, comprising: 0.8 to 1.5 weight percent silicon; 0.2 to 0.7 weight percent magnesium; 0.1 to 0.5 weight percent iron; 0.01 to 0.2 weight percent manganese; the total amount of one or more impurities is less than 0.15 weight percent; and the rest is aluminum; a homogenization treatment of the aluminum embryo, including: 530 to 540 Perform a first homogenization step on the aluminum embryo at ℃ for 3 to 8 hours; and Perform a second homogenization step on the aluminum embryo at 560 to 570 °C for 9 to 12 hours; after performing the homogenization treatment The aluminum blank is subjected to a hot-rolling step to form a hot-rolled sheet, wherein a finishing temperature of the hot-rolling step is between 250 and 300°C; an intermediate annealing is performed on the hot-rolled sheet at 380 to 560°C Steps from 30 seconds to 3 hours; performing a cold rolling step on the hot rolled sheet after the intermediate annealing step to form a cold rolled sheet; and performing a heat treatment step on the cold rolled sheet to obtain the High bending aluminum magnesium silicon alloy sheet.

在本發明一實施例中,矽與鎂的一重量比介於1.4至2.0之間。In an embodiment of the invention, a weight ratio of silicon to magnesium is between 1.4 and 2.0.

在本發明一實施例中,以540至560℃對該熱軋板材進行該中間退火步驟達30秒至60秒。In an embodiment of the invention, the hot-rolled sheet is subjected to the intermediate annealing step at 540 to 560°C for 30 to 60 seconds.

在本發明一實施例中,該熱軋步驟更包含以450至550℃預熱該鋁胚至少2小時。In an embodiment of the invention, the hot rolling step further includes preheating the aluminum blank at 450 to 550°C for at least 2 hours.

在本發明一實施例中,從該鋁胚形成該熱軋板材的裁減率係介於99%至99.6%之間。In an embodiment of the invention, the reduction rate of forming the hot-rolled sheet from the aluminum blank is between 99% and 99.6%.

在本發明一實施例中,從該熱軋板材形成該冷軋片材的裁減率係介於50%至75%之間。In an embodiment of the invention, the reduction rate of forming the cold-rolled sheet from the hot-rolled sheet is between 50% and 75%.

在本發明一實施例中,從該熱處理步驟包含:以560至580℃對該冷軋片材進行一固溶處理達40至60秒。In an embodiment of the invention, the heat treatment step includes: performing a solution treatment on the cold-rolled sheet at 560 to 580°C for 40 to 60 seconds.

在本發明一實施例中,該熱處理步驟包含:在進行該固溶處理後,進行一時效處理,以使該高彎折性鋁鎂矽合金片材具備一預定強度。In an embodiment of the invention, the heat treatment step includes: performing an aging treatment after the solution treatment to make the highly bendable aluminum magnesium silicon alloy sheet have a predetermined strength.

在本發明一實施例中,該鋁胚在進行該第一段均質化步驟後,該鋁胚不含Mg 2Si相。 In an embodiment of the invention, after the aluminum embryo is subjected to the first homogenization step, the aluminum embryo does not contain the Mg 2 Si phase.

在本發明一實施例中,該鋁胚在進行該第二段均質化步驟後,該鋁胚包含球化Al 15(Fe,Mn) 3Si 2相。 In an embodiment of the invention, after the second stage homogenization step is performed on the aluminum embryo, the aluminum embryo includes a spheroidized Al 15 (Fe,Mn) 3 Si 2 phase.

為了讓本發明之上述及其他目的、特徵、優點能更明顯易懂,下文將特舉本發明較佳實施例,並配合所附圖式,作詳細說明如下。再者,本發明所提到的方向用語,例如上、下、頂、底、前、後、左、右、內、外、側面、周圍、中央、水平、橫向、垂直、縱向、軸向、徑向、最上層或最下層等,僅是參考附加圖式的方向。因此,使用的方向用語是用以說明及理解本發明,而非用以限制本發明。In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the preferred embodiments of the present invention will be specifically described below in conjunction with the accompanying drawings, which will be described in detail below. Furthermore, the terms of direction mentioned in the present invention, such as up, down, top, bottom, front, back, left, right, inner, outer, side, surrounding, center, horizontal, horizontal, vertical, longitudinal, axial, The radial direction, the uppermost layer or the lowermost layer, etc., are only the directions referring to the attached drawings. Therefore, the directional terminology is used to illustrate and understand the present invention, not to limit the present invention.

請參照第1圖,本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10主要包含下列步驟11至16:提供一鋁胚,包含:0.8至1.5重量百分比的矽;0.2至0.7重量百分比的鎂;0.1至0.5重量百分比的鐵;0.01至0.2重量百分比的錳;總量小於0.15重量百分比的一或多個雜質;及其餘為鋁(步驟11);對該鋁胚進行一均質化處理,包含:以530至540℃對該鋁胚進行一第一段均質化步驟達3至8小時;及以560至570℃對該鋁胚進行一第二段均質化步驟達9至12小時(步驟12);對進行該均質化處理後的該鋁胚進行一熱軋步驟,以形成一熱軋板材,其中該熱軋步驟的一完軋溫度介於250至300℃之間(步驟13);以380至560℃對該熱軋板材進行一中間退火步驟達30秒至3小時(步驟14);對進行該中間退火步驟後的該熱軋板材進行一冷軋步驟,以形成一冷軋片材(步驟15);以及對該冷軋片材進行一熱處理步驟,以製得該高彎折性鋁鎂矽合金片材(步驟16)。本發明將於下文詳細說明實施例之上述各步驟的實施細節及其原理。Please refer to FIG. 1, a manufacturing method 10 of an aluminum-magnesium-silicon alloy sheet according to an embodiment of the present invention mainly includes the following steps 11 to 16: providing an aluminum blank, including: 0.8 to 1.5 weight percent silicon; 0.2 To 0.7 weight percent magnesium; 0.1 to 0.5 weight percent iron; 0.01 to 0.2 weight percent manganese; the total amount of one or more impurities is less than 0.15 weight percent; and the rest is aluminum (step 11); A homogenization treatment includes: performing a first homogenization step on the aluminum embryo at 530 to 540°C for 3 to 8 hours; and performing a second homogenization step on the aluminum embryo at 560 to 570°C for 9 To 12 hours (step 12); performing a hot rolling step on the aluminum blank after the homogenization treatment to form a hot rolled sheet, wherein the finishing temperature of the hot rolling step is between 250 and 300°C (Step 13); performing an intermediate annealing step on the hot-rolled sheet at 380 to 560°C for 30 seconds to 3 hours (Step 14); performing a cold rolling step on the hot-rolled sheet after the intermediate annealing step, to Forming a cold-rolled sheet (step 15); and performing a heat treatment step on the cold-rolled sheet to produce the highly bendable aluminum magnesium silicon alloy sheet (step 16). The present invention will describe in detail the implementation details and principles of the above steps in the embodiments below.

請參照第1圖所示,本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10首先係步驟11:提供一鋁胚,包含:0.8至1.5重量百分比的矽;0.2至0.7重量百分比的鎂;0.1至0.5重量百分比的鐵;0.01至0.2重量百分比的錳;總量小於0.15重量百分比的一或多個雜質;及其餘為鋁。Please refer to FIG. 1, a method 10 for manufacturing a highly bendable aluminum-magnesium-silicon alloy sheet according to an embodiment of the present invention is first step 11: providing an aluminum blank including: 0.8 to 1.5 weight percent silicon; 0.2 to 0.7 weight percent magnesium; 0.1 to 0.5 weight percent iron; 0.01 to 0.2 weight percent manganese; the total amount of one or more impurities is less than 0.15 weight percent; and the rest is aluminum.

在一實施例中,添加矽的目的在於增加片材塗漆烘烤後鎂矽(Mg-Si)強化相(β”)的析出,以提高片材的烘烤後降伏強度(Post-bake yield strength;PBYS)。當上述片材應用於生產汽車的外鈑件和內鈑件時,可具有足夠的耐凹性。上述效果在矽含量大於0.8wt.%時特別顯著。然而,隨矽含量的增加,會產生粗大的鎂矽鑄造相和析出相,從而降低片材的彎曲性,尤其是當矽含量大於1.5wt.%時更為顯著。In one embodiment, the purpose of adding silicon is to increase the precipitation of magnesium silicon (Mg-Si) strengthening phase (β”) after the sheet is painted and baked to improve the post-bake yield of the sheet. strength; PBYS). When the above sheet is used in the production of outer and inner sheet parts of automobiles, it can have sufficient dent resistance. The above effect is particularly significant when the silicon content is greater than 0.8wt.%. However, with the silicon content The increase will produce coarse magnesium silicon casting phase and precipitation phase, thereby reducing the flexibility of the sheet, especially when the silicon content is greater than 1.5wt.%.

在一實施例中,添加鎂的目的在於和矽一起形成前述之鎂矽強化相(β”),其效果在鎂含量為0.25wt.%以上時較佳。然而,當鎂含量大於0.7wt.%時,片材的成形性和彎曲性劣化。在一實施例中,鐵為原材料(例如初生鋁錠)無法避免的雜質成分(>0.1wt.%)外,微量的鐵可改善所製得之鋁鎂矽合金片材的繩狀條紋之問題。然而,當鐵含量高於0.5wt.%時,在片材鑄造的過程中將形成粗大脆硬的鋁鐵錳矽(Al-(Fe,Mn)-Si)化合物,不僅使片材的延韌性變差,且由於強化元素矽也被消耗,同時片材的強度也會降低。In one embodiment, the purpose of adding magnesium is to form the aforementioned magnesium-silicon strengthening phase (β”) together with silicon, and its effect is better when the magnesium content is 0.25 wt.% or more. However, when the magnesium content is greater than 0.7 wt. %, the formability and bendability of the sheet deteriorates. In one embodiment, iron is an inevitable impurity component (>0.1wt.%) of raw materials (such as primary aluminum ingots), a small amount of iron can improve the The problem of rope streaks of aluminum-magnesium-silicon alloy sheets. However, when the iron content is higher than 0.5wt.%, coarse and brittle aluminum-iron-manganese-silicon (Al-(Fe, The Mn)-Si) compound not only deteriorates the ductility and toughness of the sheet, but also consumes the strengthening element silicon, and the strength of the sheet also decreases.

在一實施例中,添加微量錳元素的目的係於均質化階段能形成細小的鋁鐵錳((Mn,Fe)Al 6)分散相(Dispersoids)時,因此可用以抑制高溫固溶時的晶粒成長,以避免片材在沖壓成形時,其表面因粗晶引發粗糙的橘皮現象。然而,若錳含量高於0.2wt.%時,類似於添加過多的鐵元素之效果,也有產生粗大的晶出物之虞。在一實施例中,可例如將前述成分範圍的原料(初生鋁錠以及母合金錠)加以熔煉,並進行直接急冷澆鑄法(Direct Chill Casting;DC),以獲得本發明此處所稱之鋁胚。 In one embodiment, the purpose of adding a trace amount of manganese element is to form fine aluminum-iron-manganese ((Mn,Fe)Al 6 ) dispersed phases (Dispersoids) during the homogenization stage, so it can be used to suppress crystals during high-temperature solid solution The grain grows to avoid the rough orange peel phenomenon caused by coarse crystals on the surface of the sheet during stamping. However, if the manganese content is higher than 0.2 wt.%, similar to the effect of adding too much iron, there is also a risk of coarse crystals. In one embodiment, for example, the raw materials (primary aluminum ingot and master alloy ingot) in the aforementioned composition range may be smelted and subjected to direct quenching casting (Direct Chill Casting; DC) to obtain the aluminum embryo referred to herein as the present invention. .

在一實施例中,矽與鎂的一重量比小於或等於2.0。在一範例中,矽與鎂的一重量比介於1.4至2.0之間,例如1.5、1.6、1.7、1.8或1.9。In one embodiment, the weight ratio of silicon to magnesium is less than or equal to 2.0. In one example, a weight ratio of silicon to magnesium is between 1.4 and 2.0, such as 1.5, 1.6, 1.7, 1.8, or 1.9.

本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10接著係步驟12:對該鋁胚進行一均質化處理,包含:以530至540℃對該鋁胚進行一第一段均質化步驟達3至8小時;及以560至570℃對該鋁胚進行一第二段均質化步驟達9至12小時。在本步驟12中,該第一段均質化步驟主要是透過特定溫度加熱該鋁胚達特定時間,以完全消除或幾乎完全消除該鋁胚中Mg 2Si相。要提到的是,前述的完全消除或幾乎完全消除的判斷方式例如可以是,通過顯微鏡觀測鋁胚中的晶出相並且無法發現該Mg 2Si相,或者即使有發現微量的該Mg 2Si相,但其含量實質上已不影響高彎折性鋁鎂矽合金片材的特性(例如彎折特性,機械性質)。此外,特別提到的是,Mg 2Si相屬於低溶點相,並且具有粗大且硬脆的性質。因此,通過該第一段均質化步驟可有效的減少Mg 2Si相所帶來的不利影響。另外,該第二段均質化步驟主要是透過特定溫度加熱該鋁胚達特定時間,以使原本是細長且形狀不規則的Al 15(Fe,Mn) 3Si 2相產生球化效果。由於晶出相是細長且形狀不規則的Al 15(Fe,Mn) 3Si 2相時容易在鋁片彎折過程中引發微裂縫,因此通過該第二段均質化步驟可有效的減少非球化Al 15(Fe,Mn) 3Si 2相所帶來的不利影響。 A method 10 for manufacturing a highly bendable aluminum magnesium silicon alloy sheet according to an embodiment of the present invention is followed by step 12: performing a homogenization treatment on the aluminum embryo, including: performing a first on the aluminum embryo at 530 to 540°C The stage homogenization step takes 3 to 8 hours; and the aluminum embryo is subjected to a second stage homogenization step at 560 to 570°C for 9 to 12 hours. In this step 12, the first homogenization step is mainly to heat the aluminum embryo through a specific temperature for a specific time to completely eliminate or almost completely eliminate the Mg 2 Si phase in the aluminum embryo. It should be mentioned that the foregoing method of judging complete or almost complete elimination may be, for example, observing the crystalline phase in the aluminum embryo through a microscope and failing to find the Mg 2 Si phase, or even trace amounts of the Mg 2 Si Phase, but its content has not substantially affected the characteristics (such as bending characteristics, mechanical properties) of the highly bendable aluminum magnesium silicon alloy sheet. In addition, it is specifically mentioned that the Mg 2 Si phase belongs to a low-melting point phase, and has a coarse, hard and brittle nature. Therefore, the first-stage homogenization step can effectively reduce the adverse effects caused by the Mg 2 Si phase. In addition, the second homogenization step is mainly to heat the aluminum embryo through a specific temperature for a specific time, so that the originally elongated and irregularly shaped Al 15 (Fe,Mn) 3 Si 2 phase produces a spheroidizing effect. Since the crystalline phase is the elongated and irregularly shaped Al 15 (Fe,Mn) 3 Si 2 phase, it is easy to cause micro-cracks during the bending of the aluminum sheet, so this second stage of homogenization step can effectively reduce the non-spherical The adverse effects of Al 15 (Fe,Mn) 3 Si 2 phase.

在一實施例中,先進行該第一段均質化步驟後再進行該第二段均質化步驟,以避免Mg 2Si相無法藉由固溶於鋁基地中來達成消除效果。具體而言,第二段均質化步驟的處理溫度高於第一段均質化步驟的處理溫度,因此低溫相的Mg 2Si相在高溫中會直接成為液化相,而無法以固溶形式存在於鋁基地中。當該液化相在冷卻後就會回復為Mg 2Si相,無法達成消除效果。 In one embodiment, the first homogenization step is performed before the second homogenization step to prevent the Mg 2 Si phase from being dissolved in the aluminum base to achieve the elimination effect. Specifically, the processing temperature of the second homogenization step is higher than the processing temperature of the first homogenization step, so the Mg 2 Si phase of the low-temperature phase will directly become the liquefied phase at high temperatures, and cannot exist in the form of solid solution In the aluminum base. After cooling, the liquefied phase will return to the Mg 2 Si phase, and the elimination effect cannot be achieved.

本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10接著係步驟13:對進行該均質化處理後的該鋁胚進行一熱軋步驟,以形成一熱軋板材,其中該熱軋步驟的一完軋溫度介於250至300℃之間。在本步驟13中,例如可以450至550℃預熱該鋁胚至少2小時(例如2至24小時之間),之後進行軋延處理。在一實施例中,從該鋁胚形成該熱軋板材的裁減率係介於99%至99.6%之間。在一範例中,例如該鋁胚具有介於400至600mm的厚度,並且熱軋至2至3mm的厚度。A method 10 for manufacturing a highly bendable aluminum magnesium silicon alloy sheet according to an embodiment of the present invention is followed by step 13: performing a hot rolling step on the aluminum blank after the homogenization treatment to form a hot rolled sheet, wherein The finishing temperature of this hot rolling step is between 250 and 300°C. In this step 13, the aluminum blank may be preheated at 450 to 550°C for at least 2 hours (for example, between 2 and 24 hours), and then subjected to rolling treatment. In one embodiment, the reduction rate of forming the hot-rolled sheet from the aluminum blank is between 99% and 99.6%. In one example, for example, the aluminum blank has a thickness between 400 and 600 mm, and is hot rolled to a thickness of 2 to 3 mm.

本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10接著係步驟14:以380至560℃對該熱軋板材進行一中間退火步驟達30秒至3小時。在本步驟14中,主要是透過中間退火步驟來使熱軋板材內的沿軋延方向優選排列的長條狀分佈的晶粒得以重新再結晶,並使其晶粒方位轉為散亂分佈的狀態。上述的晶粒方位在經過後續冷軋步驟及熱處理後仍可維持為散亂分佈的狀態。換言之,通過該中間退火步驟,本發明所製得的高彎折性鋁鎂矽合金片材在彎曲時不會使得方位相同排列的眾多晶粒同時往同方向發生變形,從而避免應變集中和微裂縫串聯的不良效應。因此,本發明所製得的高彎折性鋁鎂矽合金片材可提升耐彎折性。在一實施例中,例如可以是以540至560℃對該熱軋板材進行該中間退火步驟達30秒至60秒。在另一實施例中,亦可以是380至400℃對該熱軋板材進行該中間退火步驟達1.5至3小時。The manufacturing method 10 of the high-bending aluminum magnesium silicon alloy sheet according to an embodiment of the present invention is followed by step 14: performing an intermediate annealing step on the hot-rolled sheet at 380 to 560°C for 30 seconds to 3 hours. In this step 14, it is mainly through the intermediate annealing step to recrystallize the elongated grains that are preferably arranged along the rolling direction in the hot-rolled sheet, and turn the grain orientation into a scattered distribution status. After the subsequent cold rolling step and heat treatment, the above-mentioned grain orientations can still be maintained in a scattered distribution state. In other words, through this intermediate annealing step, the highly bendable aluminum-magnesium-silicon alloy sheet produced by the present invention will not cause many grains arranged in the same orientation to be deformed in the same direction at the same time during bending, thereby avoiding strain concentration and micro The adverse effect of cracks in series. Therefore, the highly bendable aluminum-magnesium-silicon alloy sheet produced by the present invention can improve the bend resistance. In one embodiment, for example, the hot-rolled sheet may be subjected to the intermediate annealing step for 30 seconds to 60 seconds at 540 to 560°C. In another embodiment, the intermediate annealing step may be performed on the hot rolled sheet at 380 to 400°C for 1.5 to 3 hours.

本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10接著係步驟15:對進行該中間退火步驟後的該熱軋板材進行一冷軋步驟,以形成一冷軋片材。在本步驟15中,從該熱軋板材形成該冷軋片材的裁減率例如係介於50%至75%之間。在一具體範例中,該熱軋板材具有2至3mm的厚度,通過該冷軋步驟例如是將該熱軋板材軋延到0.8至1.2mm的冷軋片材。The method 10 for manufacturing a highly bendable aluminum magnesium silicon alloy sheet according to an embodiment of the present invention is followed by step 15: performing a cold rolling step on the hot-rolled sheet after the intermediate annealing step to form a cold-rolled sheet . In this step 15, the reduction rate of forming the cold-rolled sheet from the hot-rolled sheet is, for example, between 50% and 75%. In a specific example, the hot rolled sheet has a thickness of 2 to 3 mm, and the cold rolling step is, for example, rolling the hot rolled sheet to a cold rolled sheet of 0.8 to 1.2 mm.

本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法10接著係步驟16:對該冷軋片材進行一熱處理步驟,以製得該高彎折性鋁鎂矽合金片材。在本步驟16中,該熱處理步驟可例如以560至580℃對該冷軋片材進行一固溶處理達40至60秒。另外,還可根據欲使該高彎折性鋁鎂矽合金片材達到一預定強度來進行時效處理。要提到的是,該熱處理步驟主要可使該高彎折性鋁鎂矽合金片材整體具有較均勻的表現性質,並且時效處理可提高烘烤後硬化性。值得一提是的是,時效處理可根據實際應用來設計其所使用的溫度與時間,以使該高彎折性鋁鎂矽合金片材具備需要的烘烤後硬化性。A method 10 for manufacturing a high-bendability aluminum-magnesium-silicon alloy sheet according to an embodiment of the present invention is followed by step 16: performing a heat treatment step on the cold-rolled sheet to obtain the high-bendability aluminum-magnesium-silicon alloy sheet . In this step 16, the heat treatment step may perform a solution treatment on the cold-rolled sheet at 560 to 580°C for 40 to 60 seconds, for example. In addition, aging treatment can also be performed according to the high bending aluminum-magnesium-silicon alloy sheet to achieve a predetermined strength. It should be mentioned that the heat treatment step mainly makes the high-bendability aluminum-magnesium-silicon alloy sheet as a whole have more uniform performance properties, and the aging treatment can improve the hardenability after baking. It is worth mentioning that the aging treatment can design the temperature and time used according to the actual application, so that the highly bendable aluminum magnesium silicon alloy sheet has the required post-baking hardenability.

在一實施例中,在該均質化處理和該熱軋步驟之間,本發明之高彎折性鋁鎂矽合金片材的製造方法可進一步包含對鋁胚進行刨皮步驟。此處所稱之刨皮步驟係為將均質化處理後的鋁胚表面的脆性層刨除,以進一步提升所製得之高彎折性鋁鎂矽合金片材的表面品質。In one embodiment, between the homogenization process and the hot rolling step, the method for manufacturing a highly bendable aluminum magnesium silicon alloy sheet of the present invention may further include a planing step for the aluminum embryo. The skinning step referred to here is to remove the brittle layer on the surface of the aluminum blank after the homogenization treatment, so as to further improve the surface quality of the produced highly bendable aluminum magnesium silicon alloy sheet.

在一實施例中,本發明的高彎折性鋁鎂矽合金片材的製造方法僅適用於6000系列的鋁合金(即主要包含0.8至1.5重量百分比的矽、0.2至0.7重量百分比的鎂、0.1至0.5重量百分比的鐵與0.01至0.2重量百分比的錳、總量小於0.15重量百分比的一或多個雜質、其餘為鋁),其他系列的金屬合金或鋁合金無法適用於本發明的高彎折性鋁鎂矽合金片材的製造方法。In one embodiment, the manufacturing method of the highly bendable aluminum-magnesium-silicon alloy sheet of the present invention is only applicable to 6000 series aluminum alloys (that is, mainly contains 0.8 to 1.5 weight percent silicon, 0.2 to 0.7 weight percent magnesium, 0.1 to 0.5% by weight of iron and 0.01 to 0.2% by weight of manganese, the total amount of one or more impurities is less than 0.15% by weight, the rest is aluminum), other series of metal alloys or aluminum alloys can not be applied to the high bending of the present invention Folding aluminum magnesium silicon alloy sheet manufacturing method.

以下將舉出數個實施例及數個比較例,以說明本發明製造方法所製得的高彎折性鋁鎂矽合金片材確實具有優良的彎折性。Several examples and several comparative examples are given below to illustrate that the highly bendable aluminum-magnesium-silicon alloy sheet produced by the manufacturing method of the present invention does have excellent bendability.

實施例1Example 1

首先,提供一鋁胚,該鋁胚符合6000系列的鋁合金規範,其中該鋁胚的矽與鎂的一重量比約為2.0。接著,對該鋁胚進行一均質化處理,其中包含以約530℃對該鋁胚進行一第一段均質化步驟達約8小時,以及以約570℃對該鋁胚進行一第二段均質化步驟達9小時。接著,對進行該均質化處理後的該鋁胚進行一熱軋步驟,以形成一熱軋板材,其中該熱軋步驟的一完軋溫度介於250至300℃之間,從該鋁胚形成該熱軋板材的裁減率約為99.6%。之後,以約550℃對該熱軋板材進行一中間退火步驟達約50秒。對進行該中間退火步驟後的該熱軋板材進行一冷軋步驟,以形成一冷軋片材,其中從該熱軋板材形成該冷軋片材的裁減率係約為50%。接著,對該冷軋片材進行一熱處理步驟,以製得實施例1的高彎折性鋁鎂矽合金片材。First, an aluminum blank is provided, which meets the 6000 series aluminum alloy specifications, wherein the weight ratio of silicon to magnesium of the aluminum blank is about 2.0. Next, a homogenization treatment is performed on the aluminum embryo, which includes performing a first homogenization step on the aluminum embryo at about 530°C for about 8 hours, and performing a second homogenization on the aluminum embryo at about 570°C 9 hours. Next, a hot rolling step is performed on the aluminum blank after the homogenization treatment to form a hot rolled sheet, wherein a finishing temperature of the hot rolling step is between 250 and 300°C, formed from the aluminum blank The reduction rate of this hot-rolled sheet is about 99.6%. Thereafter, the hot rolled sheet is subjected to an intermediate annealing step at about 550°C for about 50 seconds. A cold-rolling step is performed on the hot-rolled sheet after the intermediate annealing step to form a cold-rolled sheet, wherein the reduction rate of forming the cold-rolled sheet from the hot-rolled sheet is about 50%. Next, a heat treatment step is performed on the cold-rolled sheet to obtain the highly bendable aluminum magnesium silicon alloy sheet of Example 1.

實施例2至3及比較例1至5Examples 2 to 3 and Comparative Examples 1 to 5

實施例2至3及比較例1至5的製造方式類似於實施例1,惟其不同之處在於部分參數不同,或者部分步驟不進行,詳細的不同處請參考下表一。The manufacturing methods of Examples 2 to 3 and Comparative Examples 1 to 5 are similar to Example 1, except that some of the parameters are different or some steps are not performed. For the detailed differences, please refer to Table 1 below.

表一   Si/Mg重量比 均質化處理 中間退火步驟 彎折性 (等級) 烘烤後降伏強度判斷 比較例1 2.0 5 商用可接受 比較例2 2.0 一段 (550至570℃持溫9至12小時) 4 商用可接受 比較例3 2.0 兩段 (530至540℃持溫3至8小時,及 560至570℃持溫9至12小時) 3 商用可接受 比較例4 1.4 3 商用可接受 比較例5 1.4 兩段 (530至540℃持溫3至8小時;及560至570℃持溫9至12小時) 3 商用可接受 實施例1 2.0 兩段 (約530℃持溫8小時;及約570℃持溫9小時) 約550℃,約50秒 2 商用可接受 實施例2 1.4 兩段 (約540℃持溫3小時;及約560℃持溫12小時) 約390℃,約2小時 2 商用可接受 實施例3 1.4 兩段 (約535℃持溫5小時;及約565℃持溫10小時) 550℃,約50秒 1 商用可接受 Table I Si/Mg weight ratio Homogenization Intermediate annealing step Bending (level) Judgment of yield strength after baking Comparative example 1 2.0 no no 5 Commercially acceptable Comparative example 2 2.0 One period (550 to 570°C for 9 to 12 hours) no 4 Commercially acceptable Comparative Example 3 2.0 Two stages (530 to 540°C for 3 to 8 hours, and 560 to 570°C for 9 to 12 hours) no 3 Commercially acceptable Comparative Example 4 1.4 no no 3 Commercially acceptable Comparative example 5 1.4 Two stages (530 to 540°C for 3 to 8 hours; and 560 to 570°C for 9 to 12 hours) no 3 Commercially acceptable Example 1 2.0 Two stages (about 530℃ for 8 hours; and about 570℃ for 9 hours) About 550℃, about 50 seconds 2 Commercially acceptable Example 2 1.4 Two stages (about 540℃ for 3 hours; and about 560℃ for 12 hours) About 390℃, about 2 hours 2 Commercially acceptable Example 3 1.4 Two stages (about 535°C for 5 hours; and about 565°C for 10 hours) 550℃, about 50 seconds 1 Commercially acceptable

對實施例1至3及比較例1至5進行彎折性與烘烤後降伏強度判斷。針對於彎折性判斷,主要是根據飛雅特-克萊斯勒車廠(FCA)標準進行判斷。具體而言,將各實施例及各比較例進行彎折後與標準內的照片比對,其中:等級1表示無微裂縫,表面光滑;等級2表示無微裂縫,表面較粗糙;等級3表示外表面有微裂縫;等級4表示外表面有中等裂縫;等級5表示外表面有嚴重裂縫。等級1及2表示商用可接受,等級3至5表示商用不可接受。另外,針對於烘烤後降伏強度判斷,主要是透過判斷烘烤後降伏強度是否大於等於200MPa來判斷。若是大於等於200MPa,則判斷商用可接受;若是小於200 MPa,則判斷商用不可接受。Examples 1 to 3 and Comparative Examples 1 to 5 were judged for bendability and yield strength after baking. Regarding the judgment of bendability, the judgment is mainly based on the Fiat Chrysler (FCA) standard. Specifically, each example and each comparative example are bent and compared with the photos in the standard, where: level 1 means no micro-cracks and the surface is smooth; level 2 means no micro-cracks and the surface is rough; level 3 means There are micro cracks on the outer surface; grade 4 indicates that the outer surface has medium cracks; grade 5 indicates that the outer surface has severe cracks. Levels 1 and 2 indicate commercial acceptance, and levels 3 to 5 indicate commercial acceptance. In addition, for the determination of the yield strength after baking, it is mainly determined by determining whether the yield strength after baking is greater than or equal to 200 MPa. If it is greater than or equal to 200 MPa, it is judged that the commercial use is acceptable; if it is less than 200 MPa, it is judged that the commercial use is not acceptable.

對於比較例1及2,其主要是針對Si/Mg比為2.0的Al-Mg-Si鋁合金。比較例1和2分別為不進行均質化及僅進行一段均質化處理,而且皆沒有施以任何中間退火處理,致其細長的低熔點相(Mg 2Si)和/或晶出相(Al 15(Fe,Mn) 3Si 2)未能以固溶的方式回溶至鋁基地,再加上晶粒排列較具方向性,故其彎折性最差(分別為等級5和4)。 For Comparative Examples 1 and 2, it is mainly for Al-Mg-Si aluminum alloys with a Si/Mg ratio of 2.0. Comparative Examples 1 and 2 are respectively without homogenization and only one period of homogenization treatment, and are not subjected to any intermediate annealing treatment, resulting in their elongated low melting point phase (Mg 2 Si) and/or crystalline phase (Al 15 (Fe,Mn) 3 Si 2 ) failed to be dissolved back to the aluminum base by solid solution, and the grain arrangement is more directional, so its bendability is the worst (grade 5 and 4 respectively).

對於比較例3,其主要是針對Si/Mg比為2.0的Al-Mg-Si鋁合金,並且進行兩段均質化處理。然而,由於其未進行中間退火步驟,所以彎折性仍不可接受(等級3)。For Comparative Example 3, it is mainly for an Al-Mg-Si aluminum alloy with a Si/Mg ratio of 2.0, and is subjected to two-stage homogenization treatment. However, since it does not undergo an intermediate annealing step, the bendability is still unacceptable (grade 3).

對於比較例4及5,其主要是針對Si/Mg比為1.4的Al-Mg-Si鋁合金。比較例4未進行均質化及中間退火,所以彎折性仍不可接受(等級3)。另外,比較例5雖進行兩段均質化處理,但未進行中間退火步驟,所以彎折性仍不可接受(等級3)。Comparative Examples 4 and 5 are mainly for Al-Mg-Si aluminum alloys with a Si/Mg ratio of 1.4. Comparative Example 4 did not undergo homogenization and intermediate annealing, so the bendability was still unacceptable (grade 3). In addition, in Comparative Example 5, although the two-step homogenization treatment was performed, the intermediate annealing step was not performed, so the bendability was still unacceptable (level 3).

對於實施例1及2,其分別採用Si/Mg比為2及1.4的Al-Mg-Si鋁合金,並且經過兩段均質化處理及不同參數的中間退火步驟,皆可達到商用可接受的彎折性(等級2)。For Examples 1 and 2, Al-Mg-Si aluminum alloys with Si/Mg ratios of 2 and 1.4 were used, and after two stages of homogenization treatment and intermediate annealing steps with different parameters, commercially acceptable bending can be achieved Folding (level 2).

對於實施例3,其是採用低Si/Mg比(1.4),並且經過兩段均質化處理及高溫短時的中間退火步驟。這種作法的優點在於,兩段均質化過程可分別消除細長的低溶點相(Mg 2Si相)以及使不規則且硬脆的晶出相(Al 15(Fe,Mn) 3Si 2)產生球化效果。然後,高溫短時的中間退火步驟可使晶粒排列由沿軋延方向的優選方位轉呈為散亂化分佈。因此,在進行彎折性測試時,不會導致應變過度集中,從而避免微裂縫的產生。此外,實施例3具有最佳的彎折性測試結果(等級1)。 For Example 3, it adopts a low Si/Mg ratio (1.4), and undergoes two stages of homogenization treatment and a short-term intermediate annealing step at high temperature. The advantage of this method is that the two-stage homogenization process can eliminate the elongated low-melting point phase (Mg 2 Si phase) and the irregular and hard and brittle crystalline phase (Al 15 (Fe,Mn) 3 Si 2 ) Produce a spheroidizing effect. Then, the short-term intermediate annealing step at high temperature can change the grain arrangement from a preferred orientation along the rolling direction to a randomized distribution. Therefore, when the bending test is performed, the strain will not be excessively concentrated, thereby avoiding the generation of micro cracks. In addition, Example 3 has the best bendability test results (level 1).

另外,雖然實施例1至3及比較例1至5皆具有可接受的烘烤後降伏強度(大於等於200MPa),但由於比較例1至5無法通過彎折性測試。由此可見,本發明實施例的製造方法所製得的高彎折性鋁鎂矽合金片材確實具有上述效果。In addition, although Examples 1 to 3 and Comparative Examples 1 to 5 have acceptable yield strength after baking (200 MPa or more), Comparative Examples 1 to 5 fail to pass the bendability test. Thus, it can be seen that the highly bendable aluminum magnesium silicon alloy sheet produced by the manufacturing method of the embodiment of the present invention does have the above effect.

要提到的是,在比較例1至5中所使用的各種參數不代表本案發明人承認其為先前技術。特別說明的是,本案的製造方法主要是使用特定的步驟及參數來達成上述的效果,至少需包含:特定的鋁成份(需為6000系列鋁材);特定參數範圍的兩段均質化處理步驟(用於去除或球化特定晶相);及特定參數範圍的中間退火步驟(可使晶粒排列轉為散亂化分佈)。換言之,至少需透過上述三個特定步驟及參數,以及相關的熱軋、冷軋及熱處理等步驟,才可製得本發明的高彎折性鋁鎂矽合金片材。It should be mentioned that the various parameters used in Comparative Examples 1 to 5 do not represent that the inventor of the present case recognized it as prior art. In particular, the manufacturing method in this case mainly uses specific steps and parameters to achieve the above effects, at least including: a specific aluminum composition (need to be 6000 series aluminum material); two stages of homogenization treatment steps of a specific parameter range (Used to remove or spheroidize a specific crystal phase); and an intermediate annealing step within a specific parameter range (which can turn the grain arrangement into a randomized distribution). In other words, at least the above three specific steps and parameters, as well as the related hot rolling, cold rolling and heat treatment steps, can be used to produce the highly bendable aluminum magnesium silicon alloy sheet of the present invention.

雖然本發明已以較佳實施例揭露,然其並非用以限制本發明,任何熟習此項技藝之人士,在不脫離本發明之精神和範圍內,當可作各種更動與修飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with this skill can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the present invention The scope of protection shall be as defined in the scope of the attached patent application.

10:方法 11~16:步驟10: Method 11~16: Step

第1圖是本發明一實施例之高彎折性鋁鎂矽合金片材的製造方法的流程示意圖。FIG. 1 is a schematic flow chart of a method for manufacturing a highly bendable aluminum magnesium silicon alloy sheet according to an embodiment of the invention.

10:方法 10: Method

11~16:步驟 11~16: Step

Claims (10)

一種高彎折性鋁鎂矽合金片材的製造方法,包含步驟: 提供一鋁胚,包含: 0.8至1.5重量百分比的矽; 0.2至0.7重量百分比的鎂; 0.1至0.5重量百分比的鐵; 0.01至0.2重量百分比的錳; 總量小於0.15重量百分比的一或多個雜質;及 其餘為鋁; 對該鋁胚進行一均質化處理,包含: 以530至540℃對該鋁胚進行一第一段均質化步驟達3至8小時;及 以560至570℃對該鋁胚進行一第二段均質化步驟達9至12小時; 對進行該均質化處理後的該鋁胚進行一熱軋步驟,以形成一熱軋板材,其中該熱軋步驟的一完軋溫度介於250至300℃之間; 以380至560℃對該熱軋板材進行一中間退火步驟達30秒至3小時; 對進行該中間退火步驟後的該熱軋板材進行一冷軋步驟,以形成一冷軋片材;以及 對該冷軋片材進行一熱處理步驟,以製得該高彎折性鋁鎂矽合金片材。 A method for manufacturing a highly bendable aluminum magnesium silicon alloy sheet, comprising the steps of: Provide an aluminum embryo, including: 0.8 to 1.5 weight percent silicon; 0.2 to 0.7 weight percent magnesium; 0.1 to 0.5 weight percent iron; 0.01 to 0.2 weight percent manganese; One or more impurities with a total amount of less than 0.15 weight percent; and The rest is aluminum; Perform a homogenization treatment on the aluminum embryo, including: Performing a first homogenization step on the aluminum embryo at 530 to 540°C for 3 to 8 hours; and Perform a second homogenization step on the aluminum embryo at 560 to 570°C for 9 to 12 hours; Performing a hot rolling step on the aluminum blank after the homogenization treatment to form a hot rolled sheet, wherein a finishing temperature of the hot rolling step is between 250 and 300°C; Performing an intermediate annealing step on the hot-rolled sheet at 380 to 560°C for 30 seconds to 3 hours; Performing a cold rolling step on the hot rolled sheet after the intermediate annealing step to form a cold rolled sheet; and A heat treatment step is performed on the cold-rolled sheet to obtain the highly bendable aluminum magnesium silicon alloy sheet. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中矽與鎂的一重量比介於1.4至2.0之間。The method for manufacturing a high-bending aluminum-magnesium-silicon alloy sheet according to claim 1, wherein a weight ratio of silicon to magnesium is between 1.4 and 2.0. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中以540至560℃對該熱軋板材進行該中間退火步驟達30秒至60秒。The method for manufacturing a high-bendability aluminum magnesium silicon alloy sheet according to claim 1, wherein the hot-rolled sheet is subjected to the intermediate annealing step at 540 to 560°C for 30 seconds to 60 seconds. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中該熱軋步驟更包含以450至550℃預熱該鋁胚至少2小時。The method for manufacturing a high-bendability aluminum magnesium silicon alloy sheet according to claim 1, wherein the hot rolling step further includes preheating the aluminum blank at 450 to 550°C for at least 2 hours. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中從該鋁胚形成該熱軋板材的裁減率係介於99%至99.6%之間。The method for manufacturing a high-bendability aluminum-magnesium-silicon alloy sheet according to claim 1, wherein the reduction rate of forming the hot-rolled sheet from the aluminum blank is between 99% and 99.6%. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中從該熱軋板材形成該冷軋片材的裁減率係介於50%至75%之間。The method for manufacturing a high-bendability aluminum-magnesium-silicon alloy sheet according to claim 1, wherein the reduction rate of forming the cold-rolled sheet from the hot-rolled sheet is between 50% and 75%. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中該熱處理步驟包含:以560至580℃對該冷軋片材進行一固溶處理達40至60秒。The method for manufacturing a high-bendability aluminum magnesium silicon alloy sheet according to claim 1, wherein the heat treatment step includes: performing a solution treatment on the cold-rolled sheet at 560 to 580°C for 40 to 60 seconds. 如請求項7所述的高彎折性鋁鎂矽合金片材的製造方法,其中該熱處理步驟包含:在進行該固溶處理後,進行一時效處理,以使該高彎折性鋁鎂矽合金片材具備一預定強度。The method for manufacturing a high-bendability aluminum-magnesium-silicon alloy sheet according to claim 7, wherein the heat treatment step includes: performing an aging treatment after the solution treatment to make the high-bendability aluminum-magnesium-silicon sheet The alloy sheet has a predetermined strength. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中該鋁胚在進行該第一段均質化步驟後,該鋁胚不含Mg 2Si相。 The method for manufacturing a high-bending aluminum-magnesium-silicon alloy sheet according to claim 1, wherein the aluminum embryo does not contain an Mg 2 Si phase after performing the first homogenization step. 如請求項1所述的高彎折性鋁鎂矽合金片材的製造方法,其中該鋁胚在進行該第二段均質化步驟後,該鋁胚包含球化Al 15(Fe,Mn) 3Si 2相。 The method for manufacturing a high-bendability aluminum magnesium silicon alloy sheet according to claim 1, wherein after performing the second homogenization step, the aluminum embryo comprises spheroidized Al 15 (Fe, Mn) 3 Si 2 phase.
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