TWI691518B - A boat with an enhanced buoyant body and foam filling method for the buoyant body - Google Patents

A boat with an enhanced buoyant body and foam filling method for the buoyant body Download PDF

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TWI691518B
TWI691518B TW107131367A TW107131367A TWI691518B TW I691518 B TWI691518 B TW I691518B TW 107131367 A TW107131367 A TW 107131367A TW 107131367 A TW107131367 A TW 107131367A TW I691518 B TWI691518 B TW I691518B
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polyether polyol
foam material
buoyancy body
buoyant body
foaming
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TW107131367A
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TW202010765A (en
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張定瑋
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馬來西亞商源耀造船有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
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    • Y02T70/10Measures concerning design or construction of watercraft hulls

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Abstract

ABSTRACT
The present invention relates to a boat with an enhanced buoyant body and a foam filling method for the buoyant body, wherein a first material of polyether polyol as well as a second material mixed by polymethylene polyphenyl polyisocyanate and methylene bisphenyl isocyanate build up the foam material of the buoyant body, whereby it is achieved, that safety is improved while filling the foam material.

Description

改良浮力體內部填充之發泡材料的船艇及該浮力體的發泡填充方法 Ship with improved foam material filled inside buoyancy body and foaming filling method of buoyancy body

本發明係有關於一種改良浮力體內部填充之發泡材料的船艇及該浮力體的發泡填充方法;特別是有關於一種具有由一第一包覆層及填充於第一包覆層內部的發泡材料所構成的浮力體,並改良該浮力體內的發泡材料的船艇及該浮力體的發泡填充方法。 The invention relates to a boat and a foaming method for improving the foaming material filled inside the buoyancy body; in particular, it relates to a first cladding layer and filled in the first cladding layer A buoyant body composed of a foamed material, and a boat and a foamed filling method of the buoyant body improved in the buoyant body.

專利文獻1:臺灣專利公告第M381588號專利。 Patent Literature 1: Taiwan Patent Notice No. M381588.

在專利文獻1中,發明人提出一種「防翻覆陸上型救生艇」,其主要特徵之一在於浮力體是由一包覆層及填充於包覆層內部的發泡材料所構成,具有就算是包覆層意外破損也不易發生包覆層內部進水或發泡材料洩漏等影響浮力的問題的優點,經多年的發展,這種以發泡材料填充浮力體之包覆層的船艇可稱為一種發泡填充之船艇。 In Patent Document 1, the inventor proposes a "anti-overturning land-based lifeboat", one of its main features is that the buoyancy body is composed of a cladding layer and a foam material filled inside the cladding layer. Accidental damage to the coating is also not prone to problems such as water inflow inside the coating or leakage of foamed materials that affect buoyancy. After years of development, this kind of boat filled with foamed material to cover the buoyancy body can be called A foam-filled boat.

習用的發泡填充之船艇是以橡皮艇為基礎並進一步改良而成,藉以節省許多結構設計的成本。此外,由於浮力體的包覆層內部填充了發泡材料,增加了浮力體的強度,因此被更進一步的廣泛應用於例如救生艇、運輸船、釣魚船等領域中。 The conventional foam-filled boats are based on rubber boats and further improved to save the cost of many structural designs. In addition, since the buoyant body is filled with foam material inside the buoyant body, which increases the strength of the buoyant body, it is further widely used in fields such as lifeboats, transport ships, and fishing boats.

在參考文獻1中僅揭示發泡材料可使用聚酯胺 泡沫塑料,或者是EVA等其他類似性質的發泡性人造樹脂材料,然而不同的發泡性人造樹脂材料之間具有許多差異,例如基材與所需的發泡劑不同、基材與發泡劑混合後的反應時間不同、熔融溫度不同、發泡時的溫度不同等等,上述各項條件都會影響工作人員、環境,例如基材與發泡劑混合後的反應時間若太短,會有難以均勻混合就進入發泡狀態的問題。此外,有些習用的發泡材料的發泡溫度達到攝氏120度左右,包覆層只能採用能承受該發泡溫度的材料,造成包覆層可採用的材料種類受到限制,例如不能採用聚氯乙烯(PVC)等材料製成。 In Reference 1, it is only disclosed that the foaming material can use polyesteramine Foamed plastic, or other similar properties of foamable artificial resin materials such as EVA, but there are many differences between different foamable artificial resin materials, such as different substrates and foaming agents required, substrates and foaming The reaction time after the agent is mixed is different, the melting temperature is different, and the temperature during foaming is different. The above conditions will affect the staff and the environment. For example, if the reaction time of the substrate and the foaming agent is too short, there will be It is difficult to evenly mix and enter the foaming state. In addition, some conventional foaming materials have a foaming temperature of about 120 degrees Celsius. Only materials that can withstand the foaming temperature can be used for the coating layer, which limits the types of materials that can be used for the coating layer. For example, PVC cannot be used. Made of vinyl (PVC) and other materials.

發明人有鑑於此,乃苦思細索,積極研究,加以多年從事相關產品研究之經驗,並經不斷試驗及改良,終於發展出本發明。 In view of this, the inventor thought hard, actively researched, combined with years of experience in researching related products, and after continuous experimentation and improvement, finally developed the present invention.

本發明的目的在於提供一種可提高填充發泡材料時之安全性的改良浮力體內部填充之發泡材料的船艇。 An object of the present invention is to provide a boat with an improved foam material filled inside a buoyancy body that can increase the safety when foam material is filled.

本發明達成上述目的之結構包括:一浮力體,概呈管狀並概呈U形,由一第一包覆層及填充於該第一包覆層內部的發泡材料所構成;及一底板,設於該浮力體的底部;以及一尾板,設於該浮力體與底板後端;其特徵在於:該浮力體的發泡材料由聚醚多元醇及二異氰酸二苯甲烷混合而成。 The structure for achieving the above object of the present invention includes: a buoyant body, generally tubular and generally U-shaped, composed of a first cladding layer and a foam material filled inside the first cladding layer; and a bottom plate, It is arranged at the bottom of the buoyancy body; and a tail plate is arranged at the rear end of the buoyancy body and the bottom plate; it is characterized in that the foaming material of the buoyancy body is formed by mixing polyether polyol and diisocyanated diphenylmethane .

較佳者,該浮力體的發泡材料包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷,可使混合液的預定反應時間、發泡狀態時的溫度等數值被控制 在最適合填充於浮力體的第一包覆層中的狀態。 Preferably, the foaming material of the buoyant body includes 100 parts by weight of polyether polyol and 80 to 120 parts by weight of diphenylmethane diisocyanate, which enables the predetermined reaction time of the mixed liquid and the temperature in the foamed state Equal value is controlled In the state most suitable for filling in the first cladding layer of the buoyant body.

較佳者,該浮力體外側環繞設置一概呈圓桿狀的防撞筒,可形成浮力體的防撞保護結構。 Preferably, an anti-collision cylinder with a generally round rod shape is arranged around the outer side of the buoyancy body, which can form an anti-collision protection structure of the buoyancy body.

較佳者,該防撞筒由一第二包覆層及填充於該第二包覆層內部的發泡材料所構成;該防撞筒的發泡材料由聚醚多元醇及二異氰酸二苯甲烷混合而成,藉以提高在防撞筒中填充發泡材料時的安全性。 Preferably, the anti-collision cylinder is composed of a second cladding layer and a foam material filled inside the second cladding layer; the foam material of the anti-collision cylinder is composed of polyether polyol and diisocyanic acid Diphenylmethane is mixed to improve the safety when filling foam into the crash tube.

較佳者,該防撞筒的發泡材料包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷。 Preferably, the foaming material of the anti-collision cylinder includes 100 parts by weight of polyether polyol and 80 to 120 parts by weight of diisocyanic diphenylmethane.

本發明的另一目的在於提供一種可提高填充發泡材料時之安全性的浮力體的發泡填充方法。 Another object of the present invention is to provide a foam filling method for a buoyant body that can improve the safety when filling a foam material.

本發明達成上述目的之步驟包括:S11控制步驟,將聚醚多元醇的溫度控制在預定溫度範圍;S12混合步驟,將聚醚多元醇與二異氰酸二苯甲烷混合成混合液;S13灌注步驟,將混合液灌注於一浮力體的第一包覆層中以發泡填充該浮力體。 The steps of the present invention to achieve the above objectives include: S11 control step to control the temperature of the polyether polyol in a predetermined temperature range; S12 mixing step to mix the polyether polyol and diisocyanate diphenylmethane to form a mixed solution; S13 perfusion In the step, the mixed liquid is poured into the first coating layer of a buoyant body to foam and fill the buoyant body.

較佳者,該預定溫度範圍為聚醚多元醇的凝固點以上、沸點以下的任意溫度,藉以方便聚醚多元醇與二異氰酸二苯甲烷均勻混合。 Preferably, the predetermined temperature range is any temperature above the freezing point and below the boiling point of the polyether polyol, so as to facilitate the uniform mixing of the polyether polyol and the diisocyanic diphenylmethane.

較佳者,該聚醚多元醇與二異氰酸二苯甲烷混合成之混合液包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷,可使混合液的預定反應時間、發泡狀態時的溫度等數值被控制在最適合填充於浮力體的第一包覆層中的狀態。 Preferably, the mixed solution of the polyether polyol and diisocyanated diphenylmethane includes 100 parts by weight of polyether polyol and 80 to 120 parts by weight of diisocyanated diphenylmethane. Values such as the predetermined reaction time and the temperature in the foamed state are controlled to the state most suitable for filling in the first coating layer of the buoyant body.

本發明為達到上述及其他目的,其所採取之技術手段、元件及其功效,茲採一較佳實施例配合圖示說明 如下。 In order to achieve the above and other objects, the technical means, components and their functions adopted by the present invention, a preferred embodiment is used in conjunction with the illustration as follows.

100:改良浮力體內部填充之發泡材料的船艇 100: A boat with improved foam material filled inside the buoyancy body

1:浮力體 1: Buoyancy body

11:第一包覆層 11: The first coating

12:發泡材料 12: foam material

2:底板 2: bottom plate

3:尾板 3: tailgate

4:防撞筒 4: Anti-collision tube

41:第二包覆層 41: Second coating

42:發泡材料 42: foam material

S11:控制步驟 S11: Control steps

S12:混合步驟 S12: mixing steps

S13:灌注步驟 S13: Infusion step

圖1為本發明的改良浮力體內部填充之發泡材料的船艇的立體圖。 FIG. 1 is a perspective view of a boat with foam material filled inside the improved buoyancy body of the present invention.

圖2為本發明的浮力體的結構示意圖。 FIG. 2 is a schematic structural view of the buoyancy body of the present invention.

圖3為本發明的浮力體的發泡填充方法的流程圖。 FIG. 3 is a flow chart of the foam filling method of the buoyancy body of the present invention.

如圖1~2所示,本發明改良浮力體內部填充之發泡材料的船艇100包括:一浮力體1,概呈管狀並概呈U形,由一第一包覆層11及填充於第一包覆層11內部的發泡材料12所構成;及一底板2,設於浮力體1的底部;以及一尾板3,設於浮力體1與底板2後端;其特徵在於:浮力體1的發泡材料12由聚醚多元醇及二異氰酸二苯甲烷混合發泡而成;藉此結構,可達到提高填充發泡材料時之安全性的目的。下文將詳予說明。 As shown in FIGS. 1-2, the boat 100 of the present invention with an improved buoyant body filled with foam material includes: a buoyant body 1, generally tubular and generally U-shaped, composed of a first cladding layer 11 and filled in A foam material 12 inside the first cladding layer 11 is formed; and a bottom plate 2 is provided at the bottom of the buoyancy body 1; and a tail plate 3 is provided at the rear end of the buoyancy body 1 and the bottom plate 2; its characteristics are: buoyancy The foaming material 12 of the body 1 is formed by mixing and foaming polyether polyol and diisocyanatodiphenylmethane; with this structure, the purpose of improving the safety when filling the foaming material can be achieved. This will be explained in detail below.

如圖3所示,本發明進一步揭示一種浮力體的發泡填充方法,其包括下列步驟:S11控制步驟,將聚醚多元醇的溫度控制在預定溫度範圍;S12混合步驟,將聚醚多元醇與二異氰酸二苯甲烷混合成混合液;S13灌注步驟,將混合液灌注於一浮力體的第一包覆層中以發泡填充浮力體。 As shown in FIG. 3, the present invention further discloses a method for foaming and filling a buoyant body, which includes the following steps: S11 control step to control the temperature of the polyether polyol to a predetermined temperature range; S12 mixing step to change the polyether polyol Mix with diisocyanatodiphenylmethane to form a mixed liquid; S13 pouring step, the mixed liquid is poured into the first coating layer of a buoyant body to foam-fill the buoyant body.

浮力體1、底板2及尾板3可組成一個堅固的浮力體,可用於例如承載人或物品。 The buoyancy body 1, the bottom plate 2 and the tail plate 3 can form a solid buoyancy body, which can be used to carry people or objects, for example.

浮力體1的發泡材料12由聚醚多元醇及二異氰酸二苯甲烷混合發泡而成。發泡材料12的聚醚多元醇及二 異氰酸二苯甲烷可分別採用力波科技有限公司所販售的PU-G8912聚醚多元醇及MILLIONATE MR-100二異氰酸二苯甲烷,兩者在常溫下均為液態。 The foam material 12 of the buoyancy body 1 is formed by mixing and foaming polyether polyol and diisocyanatodiphenylmethane. Foam material 12 polyether polyol and two Isocyanic diphenylmethane can use PU-G8912 polyether polyol sold by Libo Technology Co., Ltd. and MILLIONATE MR-100 diisocyanic diphenylmethane, both of which are liquid at normal temperature.

聚醚多元醇及二異氰酸二苯甲烷混合後呈液態(以下稱為混合液)。混合液在經過一預定反應時間後會進入發泡狀態。在進行發泡填充工程時,例如混合液的預定反應時間、發泡狀態時的溫度等數值均有關工作人員的安全性。本發明藉由在每100重量份的聚醚多元醇中添加80~120重量份的二異氰酸二苯甲烷,輔以前述的發泡填充方法,可使混合液的預定反應時間、發泡狀態時的溫度等數值被控制在最適合填充於浮力體的第一包覆層中的狀態。 The polyether polyol and diisocyanatodiphenylmethane are mixed into a liquid state (hereinafter referred to as a mixed liquid). The mixed liquid will enter a foaming state after a predetermined reaction time. In the foaming and filling process, for example, the predetermined reaction time of the mixed liquid and the temperature in the foamed state are all related to the safety of the staff. In the present invention, by adding 80 to 120 parts by weight of diisocyanatodiphenylmethane per 100 parts by weight of polyether polyol, supplemented by the aforementioned foaming and filling method, the predetermined reaction time and foaming of the mixed liquid can be achieved Numerical values such as temperature in the state are controlled to the state most suitable for filling in the first cladding layer of the buoyant body.

S11控制步驟為將聚醚多元醇的溫度控制在預定溫度範圍。預定溫度範圍為聚醚多元醇的凝固點以上、沸點以下的任意溫度,藉以方便聚醚多元醇與二異氰酸二苯甲烷均勻混合。 The S11 control step is to control the temperature of the polyether polyol to a predetermined temperature range. The predetermined temperature range is any temperature above the freezing point and below the boiling point of the polyether polyol, so as to facilitate the uniform mixing of the polyether polyol and the diisocyanic diphenylmethane.

S12混合步驟為將聚醚多元醇與二異氰酸二苯甲烷混合成混合液。 S12 mixing step is to mix polyether polyol and diisocyanatodiphenylmethane to form a mixed solution.

如前所述,混合液的預定反應時間與工作人員的安全性有關,因為預定反應時間的長短會影響工作人員工作時間,倘若預定反應時間太短,會造成工作人員的壓力,容易產生失誤。本發明藉由聚醚多元醇的材料特性,當聚醚多元醇的溫度越接近凝固點時,聚醚多元醇與二異氰酸二苯甲烷混合後至進入發泡狀態的預定反應時間越長,因此可藉由控制聚醚多元醇的溫度達到控制預定反應時間的效果,可方便工作人員均勻調和聚醚多元醇及二異 氰酸二苯甲烷,減少例如混合不均勻而產生發泡不完全之缺失。此外,由於可控制混合液的預定反應時間,所以工作人員不需要急著將混合液注入第一包覆層中,可增加整個發泡填充工程的安全性。 As mentioned above, the predetermined reaction time of the mixed liquid is related to the safety of the staff, because the length of the predetermined reaction time will affect the working time of the staff. If the predetermined reaction time is too short, it will cause pressure on the staff and it is easy to make mistakes. According to the material characteristics of the polyether polyol of the present invention, when the temperature of the polyether polyol is closer to the freezing point, the longer the predetermined reaction time after the polyether polyol and diphenylmethane diisocyanate are mixed into the foamed state, Therefore, the effect of controlling the predetermined reaction time can be achieved by controlling the temperature of the polyether polyol, which can facilitate the staff to uniformly reconcile the polyether polyol and diiso Diphenylmethane cyanate, for example, reduces the lack of uneven foaming due to uneven mixing. In addition, since the predetermined reaction time of the mixed liquid can be controlled, the worker does not need to rush to inject the mixed liquid into the first coating layer, which can increase the safety of the entire foaming and filling process.

S13灌注步驟為將混合液灌注於一浮力體的第一包覆層中以發泡填充浮力體。在將混合液灌注於浮力體的第一包覆層中時,可透過高壓灌注的方式將混合液灌入浮力體的第一包覆層中以便在混合液進入發泡狀態後可填充浮力體的第一包覆層內部。 In the step S13 of pouring, the mixed liquid is poured into the first coating layer of a buoyant body to fill the buoyant body with foam. When pouring the mixed liquid into the first coating layer of the buoyant body, the mixed liquid can be poured into the first coating layer of the buoyant body by high-pressure infusion so that the buoyant body can be filled after the mixed liquid enters the foaming state Inside the first cladding layer.

在前述的浮力體1外側可環繞設置一概呈圓桿狀的防撞筒4,不但可形成浮力體的防撞保護結構,還可增加浮力體的穩定性,並且可供作為水中的人員爬上浮力體時的踩踏階梯。 An anti-collision cylinder 4 of substantially round rod shape can be placed around the outer side of the buoyancy body 1 not only to form a crash protection structure for the buoyancy body, but also to increase the stability of the buoyancy body and to be used as a person in the water to climb up Stepping on stairs when buoyant body.

防撞筒4可由一第二包覆層41及填充於第二包覆層41內部的發泡材料42所構成。防撞筒4的發泡材料42可與浮力體1的發泡材料12一樣可由聚醚多元醇及二異氰酸二苯甲烷混合而成,且防撞筒的發泡材料可包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷,藉以提高在防撞筒4中填充發泡材料時的安全性。 The crash tube 4 can be composed of a second cladding layer 41 and a foam material 42 filled in the second cladding layer 41. The foaming material 42 of the crash cylinder 4 can be the same as the foaming material 12 of the buoyancy body 1 can be made of a mixture of polyether polyol and diisocyanatodiphenylmethane, and the foaming material of the crash cylinder can include 100 parts by weight Of polyether polyol and 80-120 parts by weight of diisocyanatodiphenylmethane, in order to improve the safety of the crash tube 4 when filled with foam material.

以上為本案所舉之實施例,僅為便於說明而設,當不能以此限制本案之意義,即大凡依所列申請專利範圍所為之各種變換設計,均應包含在本案之專利範圍中。 The above is the embodiment cited in this case, which is only for the convenience of explanation, but the meaning of this case cannot be limited in this way, that is, all kinds of altered designs according to the scope of the patent application listed should be included in the patent scope of this case.

1:浮力體 1: Buoyancy body

11:第一包覆層 11: The first coating

12:發泡材料 12: foam material

4:防撞筒 4: Anti-collision tube

41:第二包覆層 41: Second coating

42:發泡材料 42: foam material

Claims (8)

一種改良浮力體內部填充之發泡材料的船艇,其中包括:一浮力體,呈管狀並呈U形,由一第一包覆層及填充於該第一包覆層內部的發泡材料所構成;及一底板,設於該浮力體的底部;以及一尾板,設於該浮力體與底板後端;其特徵在於:該浮力體的發泡材料由聚醚多元醇及二異氰酸二苯甲烷混合而成。 An improved buoyant body filled with foam material boat, which includes: a buoyancy body, which is tubular and U-shaped, and is composed of a first cladding layer and a foam material filled inside the first cladding layer Composition; and a bottom plate, which is arranged at the bottom of the buoyancy body; and a tail plate, which is arranged at the rear end of the buoyancy body and the bottom plate; characterized in that: the foaming material of the buoyancy body is made of polyether polyol and diisocyanic acid Mixed with diphenylmethane. 如請求項1所述之改良浮力體內部填充之發泡材料的船艇,其中該浮力體的發泡材料包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷。 The ship with the improved buoyancy body filled with foam material as described in claim 1, wherein the foam material of the buoyancy body includes 100 parts by weight of polyether polyol and 80 to 120 parts by weight of diisocyanic diphenyl Methane. 如請求項1所述之改良浮力體內部填充之發泡材料的船艇,其中該浮力體外側環繞設置一呈圓桿狀的防撞筒。 The ship with the improved buoyancy body filled with foam material as described in claim 1, wherein a round rod-shaped anti-collision cylinder is arranged around the outside of the buoyancy body. 如請求項3所述之改良浮力體內部填充之發泡材料的船艇,其中該防撞筒由一第二包覆層及填充於該第二包覆層內部的發泡材料所構成;該防撞筒的發泡材料由聚醚多元醇及二異氰酸二苯甲烷混合而成。 The boat with the foam material filled inside the improved buoyancy body according to claim 3, wherein the crash tube is composed of a second cladding layer and the foam material filled inside the second cladding layer; The foaming material of the anti-collision tube is made of polyether polyol and diisocyanatodiphenylmethane. 如請求項4所述之改良浮力體內部填充之發泡材料的船艇,其中該防撞筒的發泡材料包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷。 The boat with improved foam material filled inside the buoyancy body as described in claim 4, wherein the foam material of the crash tube includes 100 parts by weight of polyether polyol and 80 to 120 parts by weight of diisocyanic diisocyanate Benzenemethane. 一種浮力體的發泡填充方法,其中包括下列步驟:S11控制步驟,將聚醚多元醇的溫度控制在預定溫度範圍; S12混合步驟,將聚醚多元醇與二異氰酸二苯甲烷混合成混合液;S13灌注步驟,將混合液灌注於一浮力體的第一包覆層中以發泡填充該浮力體。 A method for foaming and filling a buoyant body, which includes the following steps: S11 control step, controlling the temperature of the polyether polyol to a predetermined temperature range; S12 mixing step, mixing polyether polyol and diisocyanatodiphenylmethane to form a mixed liquid; S13 infusion step, pouring the mixed liquid into the first coating layer of a buoyant body to foam-fill the buoyant body. 如請求項6所述之浮力體的發泡填充方法,其中該預定溫度範圍為聚醚多元醇的凝固點以上、沸點以下的任意溫度。 The method for foaming and filling a buoyant body according to claim 6, wherein the predetermined temperature range is any temperature above the freezing point and below the boiling point of the polyether polyol. 如請求項6所述之浮力體的發泡填充方法,其中該聚醚多元醇與二異氰酸二苯甲烷混合成之混合液包括100重量份的聚醚多元醇及80~120重量份的二異氰酸二苯甲烷。 The method for foaming and filling a buoyant body according to claim 6, wherein the mixture of the polyether polyol and diisocyanatomethane comprises 100 parts by weight of polyether polyol and 80 to 120 parts by weight of Diisocyanic diphenylmethane.
TW107131367A 2018-09-06 2018-09-06 A boat with an enhanced buoyant body and foam filling method for the buoyant body TWI691518B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWM417327U (en) * 2011-07-11 2011-12-01 Shun-Fa Jian Multifunctional safety inflation-free rubber boat
CN106866933A (en) * 2017-02-20 2017-06-20 上海材料研究所 A kind of solid buoyancy material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWM417327U (en) * 2011-07-11 2011-12-01 Shun-Fa Jian Multifunctional safety inflation-free rubber boat
CN106866933A (en) * 2017-02-20 2017-06-20 上海材料研究所 A kind of solid buoyancy material and preparation method thereof

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