TWI675009B - Sludge degradation method by using homogenizer and ozone - Google Patents

Sludge degradation method by using homogenizer and ozone Download PDF

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TWI675009B
TWI675009B TW107119714A TW107119714A TWI675009B TW I675009 B TWI675009 B TW I675009B TW 107119714 A TW107119714 A TW 107119714A TW 107119714 A TW107119714 A TW 107119714A TW I675009 B TWI675009 B TW I675009B
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sludge
ozone
homogenizer
sludge reduction
rpm
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TW202000603A (en
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蕭明謙
蕭妙璇
江智偉
洪莉雯
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崑山科技大學
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Abstract

一種利用均質機搭配臭氧之汙泥減量方法,至少包含下列步驟:提供一均質機;提供一臭氧反應器,用以產生一臭氧;以及以均質機及臭氧同時對一汙泥進行一汙泥減量處理步驟。此汙泥減量方法可以提高汙泥處理效率。 A sludge reduction method using a homogenizer and ozone, including at least the following steps: providing a homogenizer; providing an ozone reactor for generating an ozone; and performing a sludge reduction on a sludge by using the homogenizer and ozone simultaneously. Processing steps. This sludge reduction method can improve sludge treatment efficiency.

Description

利用均質機搭配臭氧之汙泥減量方法 Sludge reduction method using homogenizer and ozone

本發明是有關於一種汙泥減量方法,特別是有關於一種利用均質機搭配臭氧之汙泥減量方法。 The invention relates to a method for reducing sludge, in particular to a method for reducing sludge by using a homogenizer and ozone.

台灣每年所產生的汙泥量遠大於可掩埋的供應量,導致每年的汙泥囤積量大增。隨著水污染的日益嚴重,對各種污水進行經濟有效的處理勢在必行。 The amount of sludge produced in Taiwan each year is far greater than the supply that can be buried, resulting in a large increase in the amount of sludge accumulated each year. With the increasingly serious water pollution, it is imperative to carry out economic and effective treatment of various sewage.

中國專利申請公開CN101481191A公開了一種汙泥回流消化減量的汙水處理方法,其中將剩餘汙泥返回厭氧沉澱池中在厭氧沉澱池下部的沉澱汙泥區長期積累以便將汙泥消化減量,污水進料通過厭氧沉澱池後進行汙水處理得到淨化水和剩餘汙泥,未消化的汙泥需要定期清掏。 Chinese patent application publication CN101481191A discloses a sewage treatment method for sludge reflux digestion and reduction, in which the remaining sludge is returned to the anaerobic sedimentation tank for a long-term accumulation in the sedimentation sludge area at the lower part of the anaerobic sedimentation tank to reduce sludge digestion, After the sewage feed is passed through the anaerobic sedimentation tank, the sewage is treated to obtain purified water and excess sludge. Undigested sludge needs to be removed regularly.

美國專利申請公開US2002/0030003A1公開了一種活性汙泥汙水處理系統和方法,其中在接觸罐中用汙泥處理污水,然後在固液分離器中分離汙泥和水,分離的汙泥與部分污水在消化罐中混合並曝氣以使汙泥消化減量,經曝氣的泥水混合液部分返回接觸罐,部分排出。 United States Patent Application Publication US2002 / 0030003A1 discloses an activated sludge sewage treatment system and method, in which sewage is treated with sludge in a contact tank, and then sludge and water are separated in a solid-liquid separator, and the separated sludge and parts The sewage is mixed in the digestion tank and aerated to reduce the sludge digestion. The aerated mud-water mixture is partially returned to the contact tank and partially discharged.

而傳統活性汙泥法也具有以下缺陷:(1)曝氣池中生物濃度低;(2)耐水質、水量衝擊負荷能力差,運行不夠穩定;(3)易產生汙泥膨脹;(4)汙泥產量大;(5)基建和運行費用高,占地面積大等。 The traditional activated sludge method also has the following disadvantages: (1) low biological concentration in the aeration tank; (2) poor water resistance and water shock load capacity, and unstable operation; (3) easy to produce sludge swelling; (4) Large sludge production; (5) High capital construction and operating costs, large area, etc.

特別地,現有污水生物處理工藝最引人注目的問題就是大量剩餘汙泥的產生。汙泥處理的費用異常之高,大約占汙水處理廠建設和運行總費用的50%~60%左右。剩餘汙泥需要進行必要的處置因而增加了汙水處理的運行費用,同時也限制了汙泥處理方法的選擇。常見的汙泥減量方法有消化法(包括厭氧消化和好氧消化)、汙泥合並曝氣以使汙泥消化減量,經曝氣的泥水混合液部分返回接觸罐,部分排出。 In particular, the most striking problem of the existing sewage biological treatment process is the generation of large amounts of residual sludge. The cost of sludge treatment is unusually high, accounting for about 50% to 60% of the total cost of construction and operation of the sewage treatment plant. The remaining sludge requires necessary disposal, which increases the operating cost of sewage treatment, and also limits the choice of sludge treatment methods. Common methods of sludge reduction include digestion (including anaerobic digestion and aerobic digestion), sludge combined with aeration to reduce sludge digestion, and the aerated mud-water mixture is partially returned to the contact tank and partially discharged.

綜上所述,目前台灣汙泥以掩埋為主,但目前台灣掩埋場已飽和,焚化法則費用太高,故仍然需要發展新的汙泥處理方法以解決上述問題。 In summary, the sludge in Taiwan is currently the main landfill, but currently the landfill in Taiwan is saturated, and the cost of incineration is too high. Therefore, new sludge treatment methods still need to be developed to solve the above problems.

有鑑於上述習知技藝之問題,本發明之一目的就是在提供一種利用均質機搭配臭氧之汙泥減量方法,以解決現有汙泥處理方法的缺失。 In view of the problems of the above-mentioned conventional techniques, an object of the present invention is to provide a sludge reduction method using a homogenizer and ozone to solve the lack of existing sludge treatment methods.

為達前述目的,本發明提出一種利用均質機搭配臭氧之汙泥減量方法,至少包含下列步驟:提供一均質機;提供一臭氧反應器,用以產生一臭氧;以及以均質機及臭氧同時對一汙泥進行一汙泥減量處理步驟。 In order to achieve the foregoing object, the present invention proposes a method for reducing sludge by using a homogenizer and ozone, including at least the following steps: providing a homogenizer; providing an ozone reactor for generating an ozone; A sludge reduction step is performed.

其中,在汙泥減量處理步驟中,均質機之轉速介於5,000轉/分至9,000轉/分。 Among them, in the sludge reduction step, the speed of the homogenizer is between 5,000 rpm and 9,000 rpm.

其中,在汙泥減量處理步驟中,臭氧之數量實質為0.05g/gMLSS。 Among them, in the sludge reduction treatment step, the amount of ozone is substantially 0.05 g / g MLSS.

其中,汙泥減量處理步驟之處理時間介於15分鐘至75分鐘。 The treatment time of the sludge reduction treatment step ranges from 15 minutes to 75 minutes.

其中,汙泥減量處理步驟之汙泥減量率介於31%至59%。 Among them, the sludge reduction rate of the sludge reduction treatment step is between 31% and 59%.

其中,汙泥減量處理步驟中,均質機之轉速實質為8,000轉/分,臭氧之數量實質為0.05g/gMLSS,處理時間實質為60分鐘,且汙泥減量率為57%。 Among them, in the sludge reduction treatment step, the rotation speed of the homogenizer is substantially 8,000 rpm, the amount of ozone is substantially 0.05g / gMLSS, the treatment time is substantially 60 minutes, and the sludge reduction rate is 57%.

其中,汙泥之有機質含量實質高於87%。 Among them, the organic content of sludge is substantially higher than 87%.

其中,汙泥之有機質含量實質為87.2%,且pH值為7.13。 Among them, the organic content of the sludge was substantially 87.2%, and the pH value was 7.13.

承上所述,依本發明之利用均質機搭配臭氧之汙泥減量方法,其可具有一或多個下述優點: As mentioned above, the sludge reduction method using a homogenizer and ozone according to the present invention may have one or more of the following advantages:

(1)本發明之利用均質機搭配臭氧之汙泥減量方法,藉由均質機搭配臭氧來進行汙泥減量處理步驟,可以有效提高汙泥處理效率。 (1) The sludge reduction method using a homogenizer and ozone according to the present invention, by performing a sludge reduction treatment step with a homogenizer and ozone, the sludge treatment efficiency can be effectively improved.

(2)本發明之利用均質機搭配臭氧之汙泥減量方法,藉由將均質機設定為適當的轉速,搭配適當量的臭氧以及適當的反應處理時間,可以最佳化地提高汙泥處理效率。 (2) The sludge reduction method using the homogenizer and ozone of the present invention, by setting the homogenizer to an appropriate rotation speed, combined with an appropriate amount of ozone and an appropriate reaction treatment time, the sludge treatment efficiency can be optimally improved .

茲為使鈞審對本發明的技術特徵及所能達到的技術功效有更進一步的瞭解與認識,謹佐以較佳的實施例及配合詳細的說明如後。 In order to enable Junshen to have a further understanding and understanding of the technical features and technical effects of the present invention, I would like to refer to the preferred embodiments and the detailed description below.

S10、S20、S30‧‧‧步驟 S10, S20, S30‧‧‧ steps

40‧‧‧均質機 40‧‧‧ Homogenizer

42‧‧‧安全夾鉗 42‧‧‧Safety Clamp

44‧‧‧反應器皿 44‧‧‧Reactor

46‧‧‧轉動件 46‧‧‧Rotating parts

50‧‧‧臭氧反應器 50‧‧‧ozone reactor

52‧‧‧氣體管路 52‧‧‧Gas pipeline

60‧‧‧速度控制器 60‧‧‧speed controller

圖1為本發明之利用均質機搭配臭氧之汙泥減量方法之流程示意圖。 FIG. 1 is a schematic flowchart of a sludge reduction method using a homogenizer and ozone according to the present invention.

圖2為本發明利用均質機搭配臭氧之汙泥減量方法所採用之設備示意圖。 FIG. 2 is a schematic diagram of equipment used in the sludge reduction method using a homogenizer and ozone according to the present invention.

為利瞭解本創作之技術特徵、內容與優點及其所能達成之功效,茲將本創作配合圖式,並以實施例之表達形式詳細說明如下,而其中所使用之圖式,其主旨僅為示意及輔助說明書之用,未必為本創作實施後之真實比例與精準配置,故不應就所附之圖式的比例與配置關係解讀、侷限本創作於實際實施上的權利範圍。此外,為使便於理解,下述實施例中的相同元件係以相同的符號標示來說明。 In order to better understand the technical characteristics, content and advantages of this creation and the effect that it can achieve, we will combine this creation with diagrams and use the expressions of the embodiments to explain in detail below. The main purpose of the diagrams used is only For the purpose of indicating and assisting the manual, the actual scale and precise configuration after the implementation of the creation may not be interpreted and the scope of the rights of the actual implementation of the creation should not be interpreted or restricted in relation to the proportion and configuration of the attached drawings. In addition, in order to facilitate understanding, the same elements in the following embodiments are described with the same symbols.

請一併參閱圖1及圖2,圖1為本發明之利用均質機搭配臭氧之汙泥減量方法之流程示意圖,圖2為本發明利用均質機搭配臭氧之汙泥減量方法所採用之設備示意圖。如圖1及圖2所示,本發明之利用均質機搭配臭氧之汙泥減量方法至少包含下列步驟S10至S30。其中,在步驟S10中,提供一台均質機40。在步驟S20中,提供臭氧反應器50,用以產生一臭氧。在步驟S30中,以均質機40及臭氧同時對汙泥進行汙泥減量處理步驟。 Please refer to FIG. 1 and FIG. 2 together. FIG. 1 is a schematic flow chart of a method for reducing sludge by using a homogenizer and ozone according to the present invention, and FIG. 2 is a schematic view of a device using the method of reducing sludge by using a homogenizer and ozone according to the present invention . As shown in FIG. 1 and FIG. 2, the sludge reduction method using a homogenizer and ozone according to the present invention includes at least the following steps S10 to S30. In step S10, a homogenizer 40 is provided. In step S20, an ozone reactor 50 is provided to generate an ozone. In step S30, a sludge reduction treatment step is performed on the sludge simultaneously with the homogenizer 40 and ozone.

本發明係利用均質機40與臭氧反應器50來進行汙泥減量處理,均質機40舉例為購自新光精機,且型號例如為HM-0025均質機。均質機40的運作速度可例如受速度控制器60控制,其可無段式調整轉速,均質機40之轉速(RPM)範圍可介於500轉/分至11,000轉/分,且轉速較佳為介於5,000轉/分至9,000轉/分。由於均質機40在每分鐘8,000轉以上易造成機器過熱,故在不增加成本(例如增設冷卻設備)又要獲得良好汙泥減量率的前提下,因此轉速更佳為8,000轉/分。 The present invention uses a homogenizer 40 and an ozone reactor 50 to carry out sludge reduction treatment. The homogenizer 40 is an example of a homogeneous machine purchased from Shinko Seiki and the model is HM-0025. The operating speed of the homogenizer 40 can be controlled, for example, by the speed controller 60, which can adjust the rotation speed steplessly. The speed (RPM) of the homogenizer 40 can range from 500 rpm to 11,000 rpm, and the rotation speed is preferably Between 5,000 rpm to 9,000 rpm. Since the homogenizer 40 can cause the machine to overheat at more than 8,000 revolutions per minute, it does not increase costs (such as adding cooling equipment) and obtain a good sludge reduction rate, so the rotation speed is more preferably 8,000 revolutions per minute.

均質機40上可例如設有安全夾鉗42,安全夾鉗42係用以夾持反應器皿44,反應器皿44係用以置入待反應之汙泥,且均質機40之轉動件46則是伸入反應器皿44用以均質化汙泥。 The homogenizer 40 may be provided with, for example, safety clamps 42 for holding the reaction vessel 44, the reaction vessel 44 for placing sludge to be reacted, and the rotating part 46 of the homogenizer 40 is The reaction vessel 44 is extended to homogenize the sludge.

臭氧反應器50舉例為購自登氏企業有限公司,且型號例如為OWA-1000臭氧機,其可無段式調整臭氧發生量,且臭氧發生量之範圍介於0g/hr至1g/hr,臭氧發生量較佳為0.1g/hr至1g/hr,較佳之臭氧數量為0.05g/gMLSS。其中,臭氧反應器50可例如與均質機40連通。舉例而言,臭氧反應器50所產生之臭氧可藉由氣體管路52通入反應器皿44中,藉以使得在汙泥減量處理過程中臭氧可均勻接觸汙泥。又,在本發明中,汙泥之性質如下:混合液懸浮固體(Mixed Liquid Suspended Solids,MLSS)為18,850mg/L、混合液揮發性懸浮固體(Mixed Liquid Volatile Suspended Solids,MLVSS)為16,433mg/L、MLVSS/MLSS(%)為87.2、pH值為7.13。汙泥有機質含量在87%以上者,適合進行汙泥減量處理。 The ozone reactor 50 is an example purchased from Deng's Enterprise Co., Ltd. and the model is, for example, OWA-1000 ozone machine, which can adjust the ozone generation amount in a stepless manner, and the ozone generation amount ranges from 0 g / hr to 1 g / hr. The amount of ozone generation is preferably from 0.1 g / hr to 1 g / hr, and the preferred amount of ozone is 0.05 g / g MLSS. The ozone reactor 50 may be in communication with the homogenizer 40, for example. For example, the ozone generated by the ozone reactor 50 can be passed into the reaction vessel 44 through the gas pipeline 52, so that the ozone can uniformly contact the sludge during the sludge reduction process. In the present invention, the properties of the sludge are as follows: Mixed Liquid Suspended Solids (MLSS) is 18,850 mg / L, and Mixed Liquid Volatile Suspended Solids (MLVSS) is 16,433 mg / L, MLVSS / MLSS (%) was 87.2, and the pH was 7.13. Those with an organic matter content of 87% or more are suitable for sludge reduction.

表一係列出均質機不同轉速配合臭氧進行汙泥減量之結果圖表。其中,汙泥量為200mL,汙泥之MLVSS/MLSS(%)為87.2、pH值為7.13;臭氧之臭氧量為0.05g/gMLSS。經均質機分別以不同轉速(5,000轉/分、6,000轉/分、7,000轉/分、8,000轉/分、9,000轉/分)以及通入臭氧進行30分鐘之汙泥減量處理,檢測得汙泥減量率分別為24%、34%、38%、43%、46%。由於均質機轉速過高時,機器容易過熱,故均質機轉速為8,000轉/分較佳。 The table shows a series of results of sludge reduction with different speeds of the homogenizer and ozone. Among them, the amount of sludge was 200 mL, the MLVSS / MLSS (%) of the sludge was 87.2, the pH value was 7.13, and the ozone amount of ozone was 0.05 g / g MLSS. The homogenizer was used to reduce the sludge for 30 minutes at different speeds (5,000 rpm, 6,000 rpm, 7,000 rpm, 8,000 rpm, 9,000 rpm) and ozone. The reduction rates were 24%, 34%, 38%, 43%, and 46%, respectively. As the speed of the homogenizer is too high, the machine is likely to overheat, so the speed of the homogenizer is preferably 8,000 rpm.

表二係列出均質機配合臭氧不同反應時間進行汙泥減量之結果圖表。其中,汙泥量為200mL,汙泥之MLVSS/MLSS(%)為87.2、pH值為7.13;臭氧之臭氧量為0.05g/gMLSS;均質機轉速為8,000轉/分,分別進行15分鐘、30分鐘、45分鐘、60分鐘、75分鐘之汙泥減量處理,檢測得汙泥減量率分別為31%、 43%、52%、57%、59%。由此圖表可得知,反應時間為60分鐘時可得汙泥減量57%,反應時間為75分鐘時,汙泥減量率僅由57%上升為59%,顯示反應時間為60分鐘較佳。 Table 2 shows the results of sludge reduction by using a homogenizer with different ozone reaction times. Among them, the amount of sludge is 200mL, the MLVSS / MLSS (%) of the sludge is 87.2, the pH value is 7.13; the ozone amount of ozone is 0.05g / gMLSS; the rotation speed of the homogenizer is 8,000 rpm, which is performed for 15 minutes, 30 Minute, 45 minutes, 60 minutes, and 75 minutes of sludge reduction treatment, the sludge reduction rate was 31%, 43%, 52%, 57%, 59%. From the chart, it can be known that the sludge reduction of 57% can be obtained when the reaction time is 60 minutes, and the sludge reduction rate is only increased from 57% to 59% when the reaction time is 75 minutes, which indicates that the reaction time is preferably 60 minutes.

另外,本發明更針對各種汙泥減量方法進行汙泥減量率比對。其中,汙泥量為200mL,汙泥之MLVSS/MLSS(%)為87.2、pH值為7.13;臭氧之臭氧量為0.05g/gMLSS;均質機轉速為8,000轉/分;反應時間為30分鐘。詳言之,單獨使用臭氧處理汙泥時,汙泥減量率為29%。單獨使用均質機處理汙泥時,汙泥減量率為18%。然而,本發明經使用臭氧均質機聯合處理汙泥,其汙泥減量率為43%。相較之下,本發明之利用均質機搭配臭氧之汙泥減量方法所得之汙泥減量率相較於單獨使用臭氧及均質機之汙泥減量率可分別增加1.48倍及2.39倍,本發明無疑能提高汙泥處理效率。 In addition, the present invention further compares sludge reduction rates for various sludge reduction methods. Among them, the amount of sludge is 200mL, the MLVSS / MLSS (%) of the sludge is 87.2, the pH value is 7.13; the ozone amount of ozone is 0.05g / gMLSS; the speed of the homogenizer is 8,000 rpm; the reaction time is 30 minutes. In detail, when the sludge was treated with ozone alone, the sludge reduction rate was 29%. When using a homogenizer alone to treat sludge, the sludge reduction rate is 18%. However, in the present invention, the sludge reduction rate is 43% by using an ozone homogenizer to jointly treat the sludge. In comparison, the sludge reduction rate obtained by using the homogenizer and ozone sludge reduction method of the present invention can be increased by 1.48 times and 2.39 times compared to the sludge reduction rate of ozone and homogenizer alone. The present invention is undoubtedly Can improve sludge treatment efficiency.

綜上所述,本發明之利用均質機搭配臭氧之汙泥減量方法,藉由均質機搭配臭氧來進行汙泥減量處理步驟,可以有效提高汙泥處理效率。本發明之利用均質機搭配臭氧之汙泥減量方法,藉由將均質機設定為適當的轉速,搭配適當量的臭氧以及適當的反應處理時間,可以最佳化地提高汙泥處理效率。 In summary, the sludge reduction method using a homogenizer and ozone according to the present invention, by performing a sludge reduction treatment step with a homogenizer and ozone, can effectively improve the sludge treatment efficiency. According to the sludge reduction method using the homogenizer and ozone of the present invention, by setting the homogenizer to an appropriate rotation speed, combined with an appropriate amount of ozone and an appropriate reaction treatment time, the sludge treatment efficiency can be optimally improved.

以上所述僅為舉例性,而非為限制性者。任何未脫離本發明之精神與範疇,而對其進行之等效修改或變更,均應包含於後附之申請專利範圍中。 The above description is exemplary only, and not restrictive. Any equivalent modification or change made without departing from the spirit and scope of the present invention shall be included in the scope of the attached patent application.

Claims (7)

一種利用均質機搭配臭氧之汙泥減量方法,至少包含下列步驟:提供一均質機;提供一臭氧反應器,用以產生一臭氧;以及以該均質機及該臭氧同時對一汙泥進行一汙泥減量處理步驟,其中在該汙泥減量處理步驟中,該均質機之轉速介於5,000轉/分至9,000轉/分,該均質機為新光精機HM-0025均質機。 A method for reducing sludge by using a homogenizer and ozone, including at least the following steps: providing a homogenizer; providing an ozone reactor for generating an ozone; and using the homogenizer and the ozone to simultaneously pollute a sludge The sludge reduction processing step, wherein in the sludge reduction processing step, the rotation speed of the homogenizer is between 5,000 rpm and 9,000 rpm, and the homogenizer is a Shinko Seiki HM-0025 homogenizer. 如申請專利範圍第1項所述之利用均質機搭配臭氧之汙泥減量方法,其中在該汙泥減量處理步驟中,該臭氧之數量實質為0.05g/gMLSS。 The sludge reduction method using a homogenizer and ozone as described in item 1 of the scope of the patent application, wherein in the sludge reduction treatment step, the amount of ozone is substantially 0.05 g / gMLSS. 如申請專利範圍第1項所述之利用均質機搭配臭氧之汙泥減量方法,其中該汙泥減量處理步驟之處理時間介於15分鐘至75分鐘。 The sludge reduction method using a homogenizer and ozone as described in item 1 of the scope of the patent application, wherein the treatment time of the sludge reduction treatment step ranges from 15 minutes to 75 minutes. 如申請專利範圍第1項所述之利用均質機搭配臭氧之汙泥減量方法,其中該汙泥減量處理步驟之汙泥減量率介於31%至59%。 The sludge reduction method using a homogenizer and ozone as described in item 1 of the scope of the patent application, wherein the sludge reduction rate in the sludge reduction treatment step is between 31% and 59%. 如申請專利範圍第1項所述之利用均質機搭配臭氧之汙泥減量方法,其中在該汙泥減量處理步驟中,該均質機之轉速實質為8,000轉/分,該臭氧之數量實質為0.05g/gMLSS,處理時間實質為60分鐘,且汙泥減量率為57%。 The sludge reduction method using a homogenizer and ozone as described in item 1 of the scope of patent application, wherein in the sludge reduction treatment step, the speed of the homogenizer is substantially 8,000 rpm, and the amount of ozone is substantially 0.05. g / gMLSS, the treatment time is substantially 60 minutes, and the sludge reduction rate is 57%. 如申請專利範圍第1項所述之利用均質機搭配臭氧之汙泥減量方法,其中該汙泥之有機質含量實質高於87%。 The sludge reduction method using a homogenizer and ozone as described in item 1 of the scope of the patent application, wherein the organic content of the sludge is substantially higher than 87%. 如申請專利範圍第6項所述之利用均質機搭配臭氧之汙泥減量方法,其中該汙泥之有機質含量實質為87.2%,且pH值為7.13。 The sludge reduction method using a homogenizer and ozone as described in item 6 of the scope of patent application, wherein the organic matter content of the sludge is substantially 87.2%, and the pH value is 7.13.
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