TWI669150B - Gas dissolving system with double mixers - Google Patents

Gas dissolving system with double mixers Download PDF

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TWI669150B
TWI669150B TW107137862A TW107137862A TWI669150B TW I669150 B TWI669150 B TW I669150B TW 107137862 A TW107137862 A TW 107137862A TW 107137862 A TW107137862 A TW 107137862A TW I669150 B TWI669150 B TW I669150B
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liquid
gas
mixer
inlet
pressure
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TW202015789A (en
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劉輝堂
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劉輝堂
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Abstract

本發明揭示一種使用雙混合器之氣體溶解系統以產生高氣體濃度之液體。本發明之氣體溶解系統主要包括兩個氣體混合器、一除氣裝置、一壓力閥、一逆止閥、一壓力感測器、及一幫浦。液體流經混合器以引入氣體,因此液體含有溶解之氣體與未溶解之氣體。該液體隨後流入該除氣裝置使未溶解之氣體得以被釋放至外界環境而溶解之氣體仍留在液體中。含有溶解氣體之液體與未經處理液體混合而被稀釋成為所要氣體濃度之液體並作為液體輸出。在不與未經處理液體混合之情況下,液體流經混合器且經多次循環後可獲得含有高濃度氣體之液體。The present invention discloses a gas dissolution system using a dual mixer to produce a liquid having a high gas concentration. The gas dissolution system of the present invention mainly comprises two gas mixers, a degassing device, a pressure valve, a check valve, a pressure sensor, and a pump. The liquid flows through the mixer to introduce a gas, so the liquid contains dissolved gas and undissolved gas. The liquid then flows into the degassing device so that the undissolved gas is released to the outside environment and the dissolved gas remains in the liquid. The liquid containing the dissolved gas is mixed with the untreated liquid to be diluted into a liquid of a desired gas concentration and output as a liquid. The liquid flows through the mixer without being mixed with the untreated liquid and a liquid containing a high concentration of gas can be obtained after a plurality of cycles.

Description

具有雙混合器之氣體溶解系統Gas dissolution system with dual mixer

本發明關於使用雙混合器之氣體溶解系統以達到液體之高氣體溶解度。 The present invention relates to a gas dissolution system using a dual mixer to achieve high gas solubility of the liquid.

氣體可溶於水,但溶解度在不同之氣體之間差異甚大。在一大氣壓及標準室溫(攝氏25度)下,NH3、CO2、O3、O2在水中之溶解度分別為每公升的水可溶解700、1、0.4及0.03公升。在工業應用中,通常使用文氏管(Venturi)作為氣體與液體之混合器,液體通過文氏管時氣體可被液體引入而與液體混合。利用此方法,被引入的氣體只能部分溶解於液體;相當大的另外一部分氣體並不溶於液體。經由文氏管處理之液體之氣體濃度通常遠低於飽和濃度而可能不符某些使用的要求。因此,需要一種能產生含有高濃度氣體之液體之系統。 The gas is soluble in water, but the solubility varies widely between gases. At atmospheric pressure and standard room temperature (25 degrees Celsius), the solubility of NH 3 , CO 2 , O 3 , O 2 in water is 700, 1, 0.4 and 0.03 liters per liter of water, respectively. In industrial applications, Venturi is commonly used as a gas and liquid mixer. When the liquid passes through the venturi, the gas can be introduced into the liquid to mix with the liquid. With this method, the introduced gas can only be partially dissolved in the liquid; a considerable portion of the gas is not soluble in the liquid. The gas concentration of the liquid treated via the venturi is typically much lower than the saturation concentration and may not meet certain application requirements. Therefore, there is a need for a system that produces a liquid containing a high concentration of gas.

在上述常使用之氣體中之臭氧在多項工業使用中愈趨重要,例如,廢水處理及飲用水消毒,因為臭氧可殺死致病的細菌、原生物及病毒。 Ozone in the above-mentioned commonly used gases is becoming more and more important in many industrial applications, such as wastewater treatment and disinfection of drinking water, because ozone can kill pathogenic bacteria, protozoa and viruses.

相對於有毒、侵蝕性的化學製程,臭氧主要的優點在於能提供安全、有效、對環境有善的方式。 The main advantage of ozone over toxic and aggressive chemical processes is the ability to provide a safe, effective, and environmentally sound way.

水消毒所需臭氧之濃度遠低於清洗晶圓所需者,研究證明 在現有之清洗方式中,臭氧可提供更為環境友善之選擇且在很多情況下,其效果更佳。 The concentration of ozone required for water disinfection is much lower than that required to clean the wafer. Among the existing cleaning methods, ozone provides a more environmentally friendly choice and in many cases, the effect is better.

臭氧分子相當不穩定,其具有很短之半衰期。因此,其在一段時間後將衰變成氧氣(O2),依下列反應式進行:2O3 3O2 Ozone molecules are quite unstable and have a very short half-life. Therefore, it will decay into oxygen (O 2 ) after a period of time, according to the following reaction formula: 2O 3 3O 2

因為半衰期很短,臭氧在產生之後隨即衰變,在水中之半衰期約為30分鐘,表示臭氧在水中之濃度每半小時即減少一半。 Because the half-life is very short, the ozone decays immediately after it is produced. The half-life in water is about 30 minutes, indicating that the concentration of ozone in water is reduced by half every half hour.

因含有高溶解度臭氧之液體並不容易獲得,因此,需要一種為產生含有高濃度臭氧之液體之系統。 Since a liquid containing high solubility ozone is not easily available, a system for producing a liquid containing a high concentration of ozone is required.

根據本發明之系統係使用兩組負壓汲引混合器並配有除氣裝置及壓力閥以達到高氣體溶解度之液體之目的。其中一組混合器係用以汲取氣體以與液體混合;另一組混合器係用以混合來自液體源之液體與含氣液體。藉由控制壓力閥,本發明之系統可提供兩種液體輸出,一種是高氣體濃度之氣溶液體、另一種是普通氣體濃度之氣溶液體,係為被稀釋成所要氣體濃度之氣溶液體。 The system according to the invention uses two sets of vacuum simmer mixers and is equipped with a degassing device and a pressure valve for the purpose of achieving a high gas solubility liquid. One set of mixers is used to draw gas to mix with the liquid; another set of mixers is used to mix liquid and gas-containing liquids from the liquid source. By controlling the pressure valve, the system of the present invention can provide two liquid outputs, one is a gas solution with a high gas concentration, and the other is a gas solution of a common gas concentration, which is a gas solution diluted to a desired gas concentration. .

本發明之系統藉由增加氣體破除器可處理有害而不能直接排放到外界環境之氣體。含有氣體之液體被導入附有該氣體破除器之除氣裝置。該氣體破除器包含氣體破除媒介劑,液體中之未溶解氣體與氣體破除媒介劑反應成為無害氣體而被釋放到外界環境中。 The system of the present invention can treat gases that are harmful and cannot be directly discharged to the external environment by adding a gas breaker. The liquid containing the gas is introduced into a deaerator equipped with the gas breaker. The gas breaker comprises a gas-breaking medium, and the undissolved gas in the liquid reacts with the gas-breaking medium to become a harmless gas and is released into the external environment.

1‧‧‧氣體溶解系統 1‧‧‧ gas dissolution system

2‧‧‧未經處理液體之液體源 2‧‧‧ Liquid source of untreated liquid

4‧‧‧壓力閥 4‧‧‧pressure valve

6‧‧‧壓力感測器 6‧‧‧ Pressure sensor

8‧‧‧逆止閥 8‧‧‧ check valve

10‧‧‧第一混合器之液體入口 10‧‧‧Liquid inlet for the first mixer

11‧‧‧第一混合器之液體入口 11‧‧‧Liquid inlet for the first mixer

12‧‧‧第一混合器之液體出口 12‧‧‧Liquid outlet for the first mixer

13‧‧‧第一混合器之喉部入口 13‧‧‧ throat inlet of the first mixer

20‧‧‧第二混合器 20‧‧‧Second mixer

21‧‧‧第二混合器之液體入口 21‧‧‧Liquid inlet for the second mixer

22‧‧‧第二混合器之液體出口 22‧‧‧Liquid outlet for the second mixer

23‧‧‧第二混合器之喉部入口 23‧‧‧ throat inlet of the second mixer

32‧‧‧幫浦 32‧‧‧

33‧‧‧氣體源 33‧‧‧ gas source

34‧‧‧氣溶液體出口 34‧‧‧ gas solution outlet

35‧‧‧閥 35‧‧‧ valve

40‧‧‧除氣裝置 40‧‧‧Degassing device

41‧‧‧除氣裝置之入口 41‧‧‧ Entrance to the degassing device

42‧‧‧除氣裝置之出口 42‧‧‧Export of degassing device

43‧‧‧除氣裝置之氣體排放口 43‧‧‧Gas vents for degassing devices

45‧‧‧管路 45‧‧‧pipe

50‧‧‧閥 50‧‧‧ valve

101‧‧‧管路 101‧‧‧ pipeline

102‧‧‧管路 102‧‧‧pipe

103‧‧‧管路 103‧‧‧pipe

圖1顯示本發明之具有雙混合器之氣體溶解系統之配置。 Figure 1 shows the configuration of a gas dissolution system with a dual mixer of the present invention.

以下將以圖式配合詳細說明本發明之一實施例。 Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings.

本發明係關於一種具有雙混合器之氣體溶解系統1,其配置顯示於圖1。該系統包括兩個混合器10,20、一除氣裝置40、一壓力感測器6、壓力閥4、逆止閥8、閥35,50及一幫浦32。 The present invention relates to a gas dissolution system 1 having a dual mixer, the configuration of which is shown in FIG. The system includes two mixers 10, 20, a degassing device 40, a pressure sensor 6, a pressure valve 4, a check valve 8, valves 35, 50 and a pump 32.

如圖1示,一第一混合器10具有一液體入口11、一液體出口12、及一喉部入口13,其中該液體入口11透過一壓力閥4與一未經處理液體之液體源2連接,而該液體出口12經由一管路101連接至一氣溶液體出口34。該管路101安裝有一壓力感測器6,其電連接(在圖1中以虛線表示)至該壓力閥4。 As shown in FIG. 1, a first mixer 10 has a liquid inlet 11, a liquid outlet 12, and a throat inlet 13, wherein the liquid inlet 11 is connected to a liquid source 2 of untreated liquid through a pressure valve 4. And the liquid outlet 12 is connected to a gas solution body outlet 34 via a line 101. The line 101 is fitted with a pressure sensor 6 which is electrically connected (shown in phantom in Figure 1) to the pressure valve 4.

系統1包括一第二混合器20,其具有一液體入口21、一液體出口22、及一喉部入口23。該液體入口21連接至在第一混合器10之液體出口12與該壓力感測器6之間之該管路101,且該喉部入口23透過一逆止閥8連接一氣體源33。 The system 1 includes a second mixer 20 having a liquid inlet 21, a liquid outlet 22, and a throat inlet 23. The liquid inlet 21 is connected to the line 101 between the liquid outlet 12 of the first mixer 10 and the pressure sensor 6, and the throat inlet 23 is connected to a gas source 33 through a check valve 8.

本發明之系統1包括一除氣裝置40,其具有一入口41、一出口42、及一氣體排放口43。該除氣裝置40之入口41經由管路103連接至第二混合器20之液體出口22,且該出口42經由一安裝有幫浦32之管路45連接至第一混合器10之喉部入口13。 The system 1 of the present invention includes a degassing device 40 having an inlet 41, an outlet 42, and a gas vent 43. The inlet 41 of the deaerator 40 is connected to the liquid outlet 22 of the second mixer 20 via a line 103, and the outlet 42 is connected to the throat inlet of the first mixer 10 via a line 45 to which the pump 32 is mounted. 13.

本發明之系統進一步包括一閥50,其在幫浦32與第一混合器10之喉部入口13之間之位置連接至該管路45。 The system of the present invention further includes a valve 50 coupled to the line 45 at a location between the pump 32 and the throat inlet 13 of the first mixer 10.

混合器10,20可為文氏管,文氏管在其中段位置具有一狹窄喉部。當主要流體(第一流體)通過文氏管,其在管內之喉部會加速且壓力會下降。在文氏管之壓力下降可被利用以汲引第二流體(在本發明中為氣體)而與主要流體(在本發明中為液體)混合。氣體被汲引入液體時僅有 部分溶於液體中,很大部分的氣體並未溶於液體中。 The mixers 10, 20 can be venturis having a narrow throat at a mid-section. When the primary fluid (first fluid) passes through the venturi, it will accelerate in the throat of the tube and the pressure will drop. The pressure drop in the venturi can be utilized to dip the second fluid (in the present invention a gas) to be mixed with the primary fluid (in the present invention, a liquid). When the gas is introduced into the liquid by the helium Partially dissolved in the liquid, a large part of the gas is not dissolved in the liquid.

除氣裝置40包含一氣-液分離器,當液體流經該氣-液分離器,未溶於液體中之氣體將與液體分離並被釋放至環境中。當欲處理之氣體為臭氧時,除氣裝置40將進一步包含一氣體破除器。 The degassing device 40 includes a gas-liquid separator through which the gas that is not dissolved in the liquid will separate from the liquid and be released into the environment as the liquid flows through the gas-liquid separator. When the gas to be treated is ozone, the degassing device 40 will further comprise a gas breaker.

臭氧對於環境係有害的,當臭氧存在環境中時,其本身即為一種污染物,且可破壞森林、農作物、及人體健康。氣體破除器包含臭氧破除媒介劑可將臭氧分解為氧氣,藉此可避免臭氧直接排放所造成之環境污染。 Ozone is harmful to the environment. When ozone is present in the environment, it is a pollutant itself and can damage forests, crops, and human health. The gas decomposer contains ozone decomposing media to decompose ozone into oxygen, thereby avoiding environmental pollution caused by direct ozone emission.

如圖1示,液體由未經處理液體之液體源2經由壓力閥4導入本發明之氣體溶解系統1。該壓力閥4在接收由壓力感測器6之信號指示壓力小於一預設壓力時會開啟,下面將更詳細敘述。 As shown in Fig. 1, liquid is introduced into the gas dissolution system 1 of the present invention from a liquid source 2 of untreated liquid via a pressure valve 4. The pressure valve 4 opens upon receipt of a signal indicative of a pressure by the pressure sensor 6 that is less than a predetermined pressure, as will be described in more detail below.

在未經處理之液體導入系統1之後,該液體流經第一混合器10,接著其一部分沿著管路102而非沿著管路101流動,因為安裝在接近管路101末端之閥35係關閉。沿著管路102流動之液體接著流經第二混合器20。因為文氏管效應形成壓力降低或負壓(即壓力小於大氣壓力)之緣故,來自氣體源33之氣體經由喉部入口23被導入第二混合器20而與流經第二混合器20之液體混合。 After the untreated liquid is introduced into the system 1, the liquid flows through the first mixer 10, and then a portion thereof flows along the line 102 rather than along the line 101 because the valve 35 is installed near the end of the line 101. shut down. The liquid flowing along line 102 then flows through second mixer 20. Since the venturi effect forms a pressure drop or a negative pressure (i.e., the pressure is less than atmospheric pressure), the gas from the gas source 33 is introduced into the second mixer 20 via the throat inlet 23 and the liquid flowing through the second mixer 20. mixing.

流出第二混合器20之液體含有溶解之氣體及未溶解之氣體,接著該液體經由管路103被導入一除氣裝置40。該除氣裝置40包含一氣-液分離器,該氣-液分離器可將未溶解於液體中之氣體由液體分離出並將其釋放於外界環境中。若氣體為臭氧,因為臭氧對環境有害,所以未溶解之臭氧需經處理後才能釋放至外界環境中,此處理係將臭氧通過除氣裝置40中之破除器,使臭氧與破除器中之破除媒介劑反應而分解成氧氣並排 放到外界環境中。 The liquid flowing out of the second mixer 20 contains dissolved gas and undissolved gas, which is then introduced into a deaerator 40 via line 103. The degassing device 40 includes a gas-liquid separator that separates the gas that is not dissolved in the liquid from the liquid and releases it into the external environment. If the gas is ozone, because the ozone is harmful to the environment, the undissolved ozone needs to be treated before being released to the external environment. This treatment passes the ozone through the breaker in the deaerator 40 to break the ozone and the breaker. The medium reacts and decomposes into oxygen side by side Put it in the outside world.

除氣裝置40之出口42經由安裝有幫浦32之管路45連接至第一混合器10之喉部入口13。流出該除氣裝置40之液體含有溶解之氣體且被幫浦32壓送並被汲入第一混合器10中。汲入第一混合器10之液體與來自未經處理液體之液體源2之液體混合而被稀釋至所要之濃度,成為氣溶液體而由氣溶液體出口34輸出。 The outlet 42 of the deaerator 40 is connected to the throat inlet 13 of the first mixer 10 via a line 45 to which the pump 32 is mounted. The liquid flowing out of the deaerator 40 contains dissolved gas and is pumped by the pump 32 and is drawn into the first mixer 10. The liquid that has entered the first mixer 10 is mixed with the liquid from the liquid source 2 of the untreated liquid, and is diluted to a desired concentration to become a gas solution and output from the gas solution body outlet 34.

當閥35關閉,管路101,102,103,及45將形成一封閉迴路。因為未有氣溶液體輸出,迴路壓力不變,壓力感測器6所示之壓力值保持不變。因為幫浦32之作用,在此迴路中之液體持續流動而來自氣體源33之氣體亦持續被汲入第二混合器20,液體中之氣體濃度在每一循環之後增高,直到接近飽和濃度。閥50在幫浦32與第一混合器10之間的位置連接至管路45,當開啟閥50時可獲得具有高氣體濃度之液體,而閥50成為具有高氣體濃度之液體之輸出口。 When valve 35 is closed, lines 101, 102, 103, and 45 will form a closed loop. Since there is no gas solution output, the circuit pressure is constant, and the pressure value shown by the pressure sensor 6 remains unchanged. Because of the action of the pump 32, the liquid in this circuit continues to flow and the gas from the gas source 33 continues to be drawn into the second mixer 20, and the gas concentration in the liquid increases after each cycle until it approaches the saturation concentration. The valve 50 is connected to the line 45 at a position between the pump 32 and the first mixer 10, and when the valve 50 is opened, a liquid having a high gas concentration can be obtained, and the valve 50 becomes an output port of a liquid having a high gas concentration.

壓力感測器6電連接至壓力閥4。壓力閥4開啟程度係由壓力感測器6感測輸出管路101中液體壓力降所控制。壓力感測器6被配置以依該壓力降之大小送出訊號至壓力閥4。當閥50開啟後,管路101中之壓力下降。管路101壓力下降被壓力感測器6感知,壓力感測器6於是送出一訊號至壓力閥4使壓力閥4開啟。當閥50關閉,管路101內之壓力升高至其正常位準且該壓力閥4被壓力感測器6通知以關閉。 The pressure sensor 6 is electrically connected to the pressure valve 4. The degree of opening of the pressure valve 4 is controlled by the pressure sensor 6 sensing the pressure drop in the output line 101. The pressure sensor 6 is configured to send a signal to the pressure valve 4 in accordance with the magnitude of the pressure drop. When the valve 50 is opened, the pressure in the line 101 drops. The pressure drop in the line 101 is sensed by the pressure sensor 6, and the pressure sensor 6 then sends a signal to the pressure valve 4 to open the pressure valve 4. When the valve 50 is closed, the pressure in the line 101 rises to its normal level and the pressure valve 4 is notified by the pressure sensor 6 to close.

熟悉本發明技術領域可了解上述實施例係作為說明而非限制本發明,再者,針對該實施例可進行各種改變或修改而仍為不脫離本發明之原則及精神,本發明之範圍係界定於申請專利範圍。 The above-described embodiments are to be understood as illustrative and not restrictive, and the invention may be modified or modified without departing from the spirit and scope of the invention. Apply for a patent.

Claims (5)

一種具有雙混合器之氣體溶解系統,包括: 一第一混合器(10),具有一液體入口(11)、一液體出口(12)、及一喉部入口(13),其中該液體入口(11)經由一壓力閥(4)連接至一未經處理液體之液體源(2),且該液體出口(12)經由安裝有一壓力感測器(6)之一管路(101)電連接至一氣溶液體出口(34); 一第二混合器(20),具有一液體入口(21)、一液體出口(22)、及一喉部入口(23),其中該液體入口(21)在第一混合器(10)之液體出口(12)與該壓力感測器(6)之間連接至該管路(101),且該喉部入口(23)經由一逆止閥(8)連接至一氣體源(33); 一除氣裝置(40)具有一入口(41)、一出口(42)、及一氣體排放口(43),其中該入口(41)經由一管路(103)連接至第二混合器(20)之液體出口(22),且該出口(42)經由安裝有一幫浦(32)之一管路(45)連接至該第一混合器(10)之喉部入口(13); 一閥(50),在該幫浦(32)與第一混合器(10)之喉部入口(13)之間連接至該管路(45)。A gas dissolving system having a dual mixer, comprising: a first mixer (10) having a liquid inlet (11), a liquid outlet (12), and a throat inlet (13), wherein the liquid inlet ( 11) connected to a liquid source (2) of an untreated liquid via a pressure valve (4), and the liquid outlet (12) is electrically connected via a line (101) to which a pressure sensor (6) is mounted a gas solution outlet (34); a second mixer (20) having a liquid inlet (21), a liquid outlet (22), and a throat inlet (23), wherein the liquid inlet (21) is at A liquid outlet (12) of a mixer (10) is connected to the pressure sensor (6) to the line (101), and the throat inlet (23) is connected to the check valve (8) via a check valve (8) a gas source (33); a degassing device (40) having an inlet (41), an outlet (42), and a gas discharge port (43), wherein the inlet (41) is connected via a line (103) a liquid outlet (22) to the second mixer (20), and the outlet (42) is connected to the throat inlet of the first mixer (10) via a conduit (45) mounted with a pump (32) (13); a valve (50) in the pump (32) with the first The throat inlet (13) of the mixer (10) is connected to the line (45). 如請求項1之氣體溶解系統,其中該壓力閥(4)開啟之程度由壓力感測器(6)感知之管路(101)壓力降來控制,該壓力感測器(6)依該壓力降之大小送出訊號至該壓力閥(4)。The gas dissolution system of claim 1, wherein the degree of opening of the pressure valve (4) is controlled by a pressure drop of the pipeline (101) sensed by the pressure sensor (6), the pressure sensor (6) according to the pressure The magnitude of the drop is sent to the pressure valve (4). 如請求項1之氣體溶解系統,其中該第一混合器(10)及該第二混合器(20)各為一文氏管。The gas dissolution system of claim 1, wherein the first mixer (10) and the second mixer (20) are each a venturi. 如請求項2之氣體溶解系統,其中該第一混合器(10)及該第二混合器(20)各為一文氏管。The gas dissolution system of claim 2, wherein the first mixer (10) and the second mixer (20) are each a venturi. 如請求項4之氣體溶解系統,其中該除氣裝置(40)包括一氣-液分離器及一氣體破除器,且該氣體源(33)係一臭氧源。The gas dissolving system of claim 4, wherein the deaerator (40) comprises a gas-liquid separator and a gas breaker, and the gas source (33) is an ozone source.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030012925A (en) * 2003-01-20 2003-02-12 이병주 The reciprocal arrangement of multi step micro bubble diffusion system for higher efficiency
WO2004004876A1 (en) * 2002-07-08 2004-01-15 Mitsubishi Rayon Co.,Ltd. Apparatus for producing carbonated water and method for producing carbonated water using the same
US20080017558A1 (en) * 2005-03-31 2008-01-24 Pollock David C Methods and Devices for Improved Aeration From Vertically-Orientated Submerged Membranes
TW201332641A (en) * 2011-10-17 2013-08-16 Asahi Organic Chem Ind Ozonated water manufacturing method and manufacturing apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004004876A1 (en) * 2002-07-08 2004-01-15 Mitsubishi Rayon Co.,Ltd. Apparatus for producing carbonated water and method for producing carbonated water using the same
KR20030012925A (en) * 2003-01-20 2003-02-12 이병주 The reciprocal arrangement of multi step micro bubble diffusion system for higher efficiency
US20080017558A1 (en) * 2005-03-31 2008-01-24 Pollock David C Methods and Devices for Improved Aeration From Vertically-Orientated Submerged Membranes
TW201332641A (en) * 2011-10-17 2013-08-16 Asahi Organic Chem Ind Ozonated water manufacturing method and manufacturing apparatus

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