TWI659485B - Substrate processing apparatus and substrate processing method - Google Patents

Abstract

A substrate processing apparatus efficiently discharges a flue gas generated from a processing liquid.

The substrate processing apparatus includes: a substrate holding member; a rotation mechanism for rotating the holding member around a rotation axis; a processing liquid supply mechanism; an inner protective cover; an outer protective cover provided outside the inner protective cover; and a row The air duct includes an exhaust port communicating with the flow path, and guides the gas in the flow path to the outside; the inner shield and the outer shield are exhausted with respect to the rotation resistance of the flow path with respect to the rotation axis. The port side is smaller than the opposite side of the exhaust port, and the gas in the part above the substrate is higher than the upper end of the inner shield and lower than the upper end of the outer shield. Set by the way of side flow.

Description

   Substrate processing device and substrate processing method   

The present invention relates to a semiconductor wafer, a glass substrate for a liquid crystal display device, a glass substrate for a plasma display, a substrate for an optical disk, a substrate for a magnetic disk, a substrate for a magneto-optical disk, and a photomask. A substrate processing technique for supplying a processing liquid using a glass substrate, a substrate for a solar cell, or the like (hereinafter, simply referred to as a "substrate").

In a manufacturing process of a semiconductor device or the like, a resist pattern is formed on a surface of a substrate for selective etching or selective ion implantation. Thereafter, a resist peeling process is performed to peel the resist from the substrate. In the resist peeling liquid used when the resist is peeled off by a liquid treatment, for example, a mixed solution of sulfuric acid and aqueous hydrogen peroxide (a mixed solution of sulfuric acid and hydrogen peroxide. SPM: sulfuric acid / hydrogen peroxide mixture) can be used. Since SPM contains peroxymonosulfate with strong oxidizing power, and it can raise the liquid temperature by the reaction heat generated when sulfuric acid and hydrogen peroxide water are mixed, it can exert a higher resistance Removal ability. Since the SPM is higher in temperature within the allowable range of the device and the treating process, the resistance removal ability is also improved, so it may be further heated by a heater or the like.

When a high-temperature SPM is supplied to the surface of a substrate on which a resist pattern is formed, the high-temperature SPM and the resist react, and a large amount of a substance after the oxidation of the resist, a component derived from sulfuric acid, and a component containing the resist The gas-like SPM fume (hereinafter, also simply referred to as "flue gas") such as water vapor that is decomposed and evaporated, diffuses from the surface of the substrate. When the smoke floating in the chamber, or the smoke, which has been attached to the baffle plate above the substrate, is attached to the substrate, a problem that particles become particles occurs. Therefore, there is a need for a technology that can efficiently discharge the generated flue gas.

As a technique for exhausting a gas generated from a processing liquid in a step other than the resist peeling step, Patent Document 1 discloses a gas composed of a developing liquid that has been volatilized from a substrate in a developing step. A substrate processing apparatus that performs a development process while discharging from a space above a substrate surrounded by a guard. The device includes: a substrate rotation mechanism that rotates the substrate while holding it; a processing liquid supply mechanism that supplies the processing liquid to the surface of the substrate; a protective cover (also known as a "splash guard", a "cup body" (cup) "), which surrounds the substrate held by the substrate rotation mechanism; an exhaust mechanism for exhausting the gas in the protective cover; an exhaust port, which is provided on the back side of the substrate in the protective cover; and a flow path, It is formed in the protective cover along the periphery of the substrate and guides the gas from the front side to the back side. This flow path is configured such that the ventilation resistance becomes smaller as it goes away from the exhaust port.

When the ventilation resistance of the flow path is uniform in the circumferential direction of the substrate, the gas system easily passes through the part of the flow path that is closer to the exhaust port. In contrast, in the device of Patent Document 1, the flow path is based on The ventilation resistance is configured to decrease as the distance from the exhaust port decreases. Therefore, even the gas in the flow path that is far away from the exhaust port can easily enter. That is, the device sets a flow path in which the airflow resistance becomes smaller as it moves away from the exhaust port, so that the gas composed of the volatilized developing solution flows from the central portion of the substrate at a uniform flow rate. Each part of the peripheral portion flows, and the exhaust efficiency of the gas is improved.

[Prior technical literature]

[Patent Literature]

Patent Document 1: Japanese Patent Application Laid-Open No. 2015-56626.

In order to exhaust the SPM fumes, it is conceivable to apply the configuration of the protective cover of Patent Document 1 applied in the developing step to the method in the resist peeling step. However, compared with the gas volatilized from the developing solution in the developing step, an extremely large amount of smoke is generated in the resist peeling step. Therefore, in the case of using the device configuration of Patent Document 1, the exhaust capacity of the device is insufficient with respect to a large amount of smoke, and the smoke is retained in the space surrounded by the protective cover.

In addition, the exhaust mechanism of the device of Patent Document 1 is connected to an exhaust facility of a factory or the like. In this exhaust equipment, a plurality of devices including the substrate processing device are usually connected. This exhaust system distributes a predetermined exhaust capacity to each device connected to it and exhausts each device. Therefore, it has not been possible to adopt a technique for increasing the exhaust efficiency of the flue gas by increasing the exhaust capacity of the device allocated to Patent Document 1.

An object of the present invention is to provide a technology capable of efficiently exhausting the flue gas generated in a substrate processing process, and a particular object is to provide an efficient exhaust gas generated from a flue gas as exemplified in the resist peeling process. Heavy smoke technology.

In order to solve the above-mentioned problems, the substrate processing apparatus of the first aspect includes a holding member capable of rotating while holding the substrate in a substantially horizontal posture; a rotating mechanism that rotates the holding member with a rotation axis as a center; and processing The liquid supply mechanism supplies the processing liquid to the surface of the substrate; the inner protective cover in the shape of a cylinder surrounds the surrounding of the holding member and the upper end is in an open state; And arranged on the outer side of the inner protective cover so as to form a flow path between the inner protective cover and the inner protective cover to guide the gas above the substrate, and the upper end is in an open state; Including an exhaust port communicating with the flow path formed between the inner shield and the outer shield, and guiding the gas in the flow path to the outside; the upper end of the outer shield is positioned at a position higher than the inner side The upper end of the protective cover is higher; the opening formed by the upper end of the outer protective cover and the upper end of the inner protective cover is facing forward The inside shield and the outside shield use the ventilation resistance of the flow path to make the exhaust port side smaller than the opposite side of the exhaust port with respect to the rotation axis, and The gas in a part above the upper end of the inner shield and lower than the upper end of the outer shield is mainly provided so as to flow from above the substrate toward the exhaust port side.

The substrate processing apparatus of the second aspect is the substrate processing apparatus of the first aspect, wherein the inner shield and the outer shield each include a cylindrical side wall that surrounds the periphery of the holding member and extends along the rotation axis. The distance between the side wall of the inner shield and the side wall of the outer shield is wider with respect to the rotation axis than the side opposite to the exhaust port.

The substrate processing apparatus of the third aspect is the substrate processing apparatus of the second aspect, in which the exhaust port side is made to be larger than the foregoing with respect to the rotation axis at a distance between the side wall of the inner shield and the side wall of the outer shield. In a manner that the opposite side of the exhaust port is wider, the outer shield is relatively eccentric to the inner shield.

The substrate processing apparatus of the fourth aspect is the substrate processing apparatus of the third aspect, wherein the central axis of the side wall of the inner shield is consistent with the rotation axis; the side wall of the outer shield is eccentric to the rotation axis to The exhaust port side.

The substrate processing apparatus of the fifth aspect is the substrate processing apparatus of the third aspect, wherein the central axis of the side wall of the outer shield is consistent with the rotation axis; the side wall of the inner shield is eccentric to the rotation axis to The opposite side of the aforementioned exhaust port.

The substrate processing apparatus of the sixth aspect is the substrate processing apparatus of the third aspect, wherein the side wall of the outer protective cover is eccentric to the exhaust port side with respect to the rotation axis, and the side wall of the inner protective cover is relative to the aforementioned The rotation shaft is eccentric to the opposite side of the exhaust port.

The substrate processing apparatus of a seventh aspect is the substrate processing apparatus of the first aspect, wherein the inner shield and the outer shield each include a cylindrical side wall that surrounds the periphery of the holding member and extends along the rotation axis. ; The first semi-straight line is defined by an imaginary semi-straight line extending from the rotation axis to the center of the exhaust port in a plan view; and the first semi-straight line is directed toward the substrate by using the rotation axis as a center An imaginary half straight line obtained by turning an acute angle downstream of the rotation direction to define a second half straight line; the distance between the side wall of the inner shield and the side wall of the outer shield is a side view of the side wall of the inner shield and the outside The side wall of the protective cover intersects the second half straight line at the widest part.

An eighth aspect of the substrate processing apparatus is the substrate processing apparatus of any one of the first aspect to the seventh aspect, wherein the processing liquid supply mechanism is provided with a nozzle that faces the substrate from above the substrate. The treatment liquid is discharged from a liquid injection position on the surface of the substrate with respect to the center of the substrate, and the liquid injection position is a position where a liquid film covers the center of the substrate, and the liquid film has been discharged to the foregoing. The processing liquid at the landing position is formed on the surface of the substrate.

A ninth aspect of the substrate processing method is a method by a substrate processing apparatus that rotates a substrate while holding the substrate in a substantially horizontal posture by using a holding member. The substrate processing apparatus includes: a tube-shaped inner side; A protective cover surrounds the surrounding holding member and the upper end is in an open state; a cylindrical outer protective cover surrounds the surrounding holding member and is formed between the inner protective cover and the inner protective cover to guide the substrate. The way of the upper gas flow path is provided on the outer side of the inner shield, and the upper end is open; and the exhaust duct includes a communication path to the flow path formed between the inner shield and the outer shield. Exhaust port, and guide the gas in the flow path to the outside; the upper end of the outer shield is above the upper end of the inner shield; the upper end of the outer shield and the upper end of the inner shield The opening formed is opposite to the axis of rotation of the substrate; the inner shield and the outer shield are formed by the flow path. The ventilation resistance makes the exhaust port side smaller than the opposite side of the exhaust port with respect to the rotation axis, and the upper part of the substrate is higher than the upper end of the inner shield and higher than the outer shield. The gas at the lower part of the upper end is mainly provided so that the gas flows from above the substrate toward the exhaust port side. The substrate processing method includes a rotation step in which the rotation axis is centered while the substrate is maintained in a substantially horizontal posture. And a processing liquid supply step, which supplies a processing liquid to the surface of the substrate.

The substrate processing method of the tenth aspect is the substrate processing method of the ninth aspect, wherein the inner shield and the outer shield each include a cylindrical side wall that surrounds the periphery of the holding member and extends along the rotation axis. The distance between the side wall of the inner shield and the side wall of the outer shield is wider with respect to the rotation axis than the side opposite to the exhaust port.

The substrate processing method according to the eleventh aspect is the substrate processing method according to the tenth aspect, wherein the exhaust port side is made larger than the foregoing with respect to the rotation axis at a distance between the side wall of the inner shield and the side wall of the outer shield. In a manner that the opposite side of the exhaust port is wider, the outer shield is relatively eccentric to the inner shield.

The substrate processing method of the twelfth aspect is the substrate processing method of the eleventh aspect, wherein the center axis of the side wall of the inner shield is consistent with the rotation axis; the side wall of the outer shield is eccentric to the rotation axis to The exhaust port side.

The substrate processing method of the thirteenth aspect is the substrate processing method of the eleventh aspect, wherein the central axis of the side wall of the outer shield is consistent with the rotation axis; the side wall of the inner shield is eccentric to the rotation axis to The opposite side of the aforementioned exhaust port.

The substrate processing method of a fourteenth aspect is the substrate processing method of the eleventh aspect, wherein the side wall of the outer protective cover is eccentric to the exhaust port side with respect to the rotation axis, and the side wall of the inner protective cover is relative to the aforementioned The rotation shaft is eccentric to the opposite side of the exhaust port.

The substrate processing method of a fifteenth aspect is the substrate processing method of the ninth aspect, wherein the inner shield and the outer shield each include a cylindrical side wall that surrounds the periphery of the holding member and extends along the rotation axis. ; The first semi-straight line is defined by an imaginary semi-straight line extending from the rotation axis to the center of the exhaust port in a plan view; and the first semi-straight line is directed toward the substrate by using the rotation axis as a center An imaginary half straight line obtained by turning an acute angle downstream of the rotation direction to define a second half straight line; the distance between the side wall of the inner shield and the side wall of the outer shield is a side view of the side wall of the inner shield and the outer side in a plan view The side wall of the protective cover intersects the second half straight line at the widest part.

The substrate processing method of the sixteenth aspect is the substrate processing method of any one of the ninth aspect to the fifteenth aspect, wherein the step of supplying the processing liquid is performed on the surface of the substrate relative to the surface of the substrate from above the substrate. The step of discharging the processing liquid with the center of the substrate at the liquid injection position on the exhaust port side; the liquid injection position is a position where a liquid film covers the center of the substrate, and the liquid film has been discharged to the liquid injection position. The processing liquid is formed on the surface of the substrate.

According to the invention of the first aspect, in order to make the gas in the portion above the substrate higher than the upper end of the inner shield and lower than the upper end of the outer shield mainly flow from the upper portion of the substrate toward the exhaust port side, The ventilation resistance of the flow path between the inner shield and the outer shield is such that the exhaust port side is smaller than the opposite side of the exhaust port with respect to the rotation axis. Therefore, the flue gas generated from the processing liquid that has been supplied to the substrate can be efficiently introduced into the flow path from the part on the exhaust port side of the flow path by turning the air flow above the substrate on the exhaust port side, It is efficiently discharged to the outside through the exhaust duct.

According to the invention of the second aspect, since the distance between the side wall of the inner shield and the side wall of the outer shield is wider with respect to the rotation axis than the exhaust port side, the ventilation resistance of the flow path is relatively Make the exhaust port side smaller on the rotation axis than the opposite side of the exhaust port.

According to the invention of the third aspect, the side of the inner side cover and the side of the outer side cover are made wider with respect to the rotation axis so that the exhaust port side is wider than the opposite side of the exhaust port. Eccentric to the inner shield. Therefore, the space between the side wall of the inner shield and the side wall of the outer shield can be easily realized, and the exhaust port side is wider than the opposite side of the exhaust port with respect to the rotation axis.

According to a seventh aspect of the invention, the inner shield and the outer shield each include a cylindrical side wall that surrounds the holding member and extends along the rotation axis; and extends from the rotation axis in a plan view. The first half straight line is defined by an imaginary half straight line to the center of the exhaust port; and the imaginary half obtained by rotating the first half straight line at an acute angle downstream of the rotation direction of the substrate by using the rotation axis as a center. When the second semi-straight line is defined by a straight line; the distance between the side wall of the inner shield and the side wall of the outer shield is that the side wall of the inner shield and the side wall of the outer shield cross the second semi-straight line respectively in a plan view. The widest part. Since this part is easy to concentrate the smoke by the viscosity of the flue gas and the influence of the rotation of the substrate, and the flue gas can be efficiently introduced into the flow path from this part, it is possible to suppress the position due to the rotation of the substrate. The effect of the resulting centrifugal force reduces the exhaust efficiency of the flue gas.

According to the eighth aspect of the invention, the nozzle of the processing liquid supply mechanism discharges the processing liquid to the liquid injection position on the exhaust port side with respect to the center of the substrate in the surface of the substrate. The liquid injection position is a position where the liquid film covers the center of the substrate, and the liquid film is formed by forming the processing liquid that has been discharged to the liquid injection position on the surface of the substrate. Since the flue gas is mostly generated near the liquid injection position of the processing liquid, it is more likely to be generated on the exhaust port side than the center of the substrate. Therefore, the generated flue gas can be efficiently discharged from the exhaust port side portion of the flow path.

According to the ninth aspect of the invention, in order to make the gas in the portion above the substrate higher than the upper end of the inner shield and lower than the upper end of the outer shield mainly flow from the upper portion of the substrate toward the exhaust port side, The ventilation resistance of the flow path between the inner shield and the outer shield is such that the exhaust port side is smaller than the opposite side of the exhaust port with respect to the rotation axis. Therefore, the flue gas generated from the processing liquid that has been supplied to the substrate can be efficiently introduced into the flow path from the part on the exhaust port side of the flow path by turning the air flow above the substrate on the exhaust port side, It is efficiently discharged to the outside through the exhaust duct.

1, 100‧‧‧ substrate processing equipment

2‧‧‧Rotary chuck (rotary holding mechanism)

3.300‧‧‧Scatter Prevention Department

5‧‧‧Processing Department (Processing Liquid Supply Mechanism)

6‧‧‧ Nozzle moving mechanism

7, 71, 72‧‧‧ exhaust pipe

9‧‧‧ substrate

11‧‧‧ chamber

12‧‧‧FFU

21‧‧‧Swivel base (holding member)

22‧‧‧Rotating shaft

23‧‧‧Rotary drive unit

24‧‧‧shell

25‧‧‧ chuck pin

31‧‧‧Splash cover

32‧‧‧Splash shield drive mechanism

41‧‧‧First Half Straight

42‧‧‧Second Half Straight

50‧‧‧ Nozzle holding member

51, 51A‧‧‧ nozzle

52‧‧‧ front side

52b‧‧‧ bottom

52c‧‧‧Spit Out

63‧‧‧arm

66‧‧‧Nozzle Abutment

68‧‧‧Elevation drive unit

69‧‧‧Rotary drive unit

71a, 72a‧‧‧ exhaust port

83‧‧‧ Treatment liquid supply department

90‧‧‧ bezel

91‧‧‧ lower surface

92‧‧‧ side

93‧‧‧Rotating part

94‧‧‧ Shaft member

95‧‧‧through hole

97‧‧‧ baffle rotation mechanism

98‧‧‧Baffle lifting mechanism

99‧‧‧ exhaust equipment

109‧‧‧ facing department

130‧‧‧Control Department

201‧‧‧ Liquid film

231‧‧‧rotating mechanism

241‧‧‧ flange-shaped member

310‧‧‧ Internal components

311‧‧‧Middle member (inside protective cover)

311A, 312A‧‧‧ sidewall

311B, 312B‧‧‧Upper wall

312‧‧‧External components (outer protective cover)

315‧‧‧ raised

316‧‧‧Block

511‧‧‧ mixing room

513, 514‧‧‧ entrance

831‧‧‧ Hydrogen peroxide supply source

832、842‧‧‧Piping

841‧‧‧ Sulfuric acid supply source

833, 843‧‧‧ On-off valve

834, 844‧‧‧flow regulating valve

845‧‧‧heater

3101‧‧‧ bottom

3102‧‧‧Inner wall

3103, 3114‧‧‧ guide wall

3111, 3121‧‧‧‧Inner peripheral wall

3112, 3122‧‧‧‧ peripheral wall

a1‧‧‧rotation axis

b1‧‧‧ the center of the building blocks

b2‧‧‧ Center of external components

c1‧‧‧ the center of the substrate

A1‧‧‧Airflow

Part C1, C2‧‧‧‧

CA, CB‧‧‧flow

D1 to D4‧‧‧Width

F1, F100‧‧‧ Smoke

H1, H100‧‧‧ Mobile

L1‧‧‧ liquid flow

P1‧‧‧ landing position

T1, T2‧‧‧path

X1, X2, Y1, Y2 ‧‧‧ parts

θ‧‧‧ angle

FIG. 1 is a schematic side view illustrating a configuration example of a substrate processing apparatus according to the embodiment.

FIG. 2 is a schematic top view illustrating a configuration example of the substrate processing apparatus of FIG. 1.

FIG. 3 is a schematic side view for explaining the flow of the flue gas generated in the substrate processing apparatus of the comparative technology.

FIG. 4 is a schematic side view for explaining the flow of the flue gas generated in the substrate processing apparatus of FIG. 1.

FIG. 5 is a schematic top view showing an example of an arrangement relationship between the rotation shaft, the inner shield and the outer shield of FIG. 1.

FIG. 6 is a schematic top view showing an example of an arrangement relationship between the rotation shaft and the inner shield and the outer shield of FIG. 1.

FIG. 7 is a schematic top view showing an example of an arrangement relationship between the rotation shaft and the inner shield and the outer shield of FIG. 1.

FIG. 8 is a schematic cross-sectional view for explaining the ejection of the processing liquid by the nozzle of the substrate processing apparatus of FIG. 1.

FIG. 9 is a schematic plan view for explaining the discharge of the processing liquid by the nozzle of the substrate processing apparatus of FIG. 1.

FIG. 10 is a schematic cross-sectional view for explaining another example of the nozzle of the substrate processing apparatus of FIG. 1 and the discharge of the processing liquid by the nozzle.

11 is a flowchart showing an example of the operation of the substrate processing apparatus according to the embodiment.

FIG. 12 is a schematic side view showing an example of the configuration of the inner shield and the outer shield of FIG. 1.

FIG. 13 is a schematic side view showing an example of the configuration of the inner shield and the outer shield of FIG. 1.

Hereinafter, embodiments will be described with reference to the drawings. The following embodiment is an example in which the present invention has been embodied, and is not intended to limit the technical scope of the present invention. In addition, in each of the drawings referred to below, for ease of understanding, the size of each part may be exaggerated or simplified for illustration. The vertical direction is a vertical direction, and the substrate side is upward with respect to the spin chuck.

<Related embodiment>

<1. Overall configuration of substrate processing apparatus>

The configuration of the substrate processing apparatus 1 will be described with reference to FIGS. 1 to 2. 1 to 2 are schematic diagrams for explaining the structure of the substrate processing apparatus 1 according to the embodiment. 1 and 2 are a schematic side view and an upper view of the substrate processing apparatus 1.

In FIG. 1 and FIG. 2, when the nozzle 51 is disposed above the center c1 of the substrate 9, the substrate 9 is rotated around a rotation axis a1 by a spin base 21 toward a predetermined rotation direction (arrow AR1). Direction). More specifically, FIG. 1 and FIG. 2 show a state where the nozzle 51 is scanned along the path T1 between above the peripheral edge portion of the substrate 9 and above the center c1. Moreover, FIG. 2 shows the nozzle 51 etc. which were arrange | positioned at the retreat position with the imaginary line. In FIG. 2, the description of some of the constituent elements of the processing liquid supply unit 83 and the like of the processing unit 5 among the constituent elements of the substrate processing apparatus 1 is omitted. In FIG. 2, the outer peripheral wall portion 3112 in the side wall 311A of the middle member 311 is shown, and the inner peripheral wall portion 3121 in the side wall 312A of the outer member 312 is shown, and the description of the upper wall 311B and the upper wall 312B is omitted. When the nozzle 51 supplies a high-temperature SPM as a processing liquid to the substrate 9 and performs a resist peeling treatment to peel off a pattern of the resist formed on the upper surface of the substrate 9, the high-temperature SPM and the resist on the substrate Will react to produce smoke F1.

The surface shape of the substrate 9 is substantially circular. The loading and unloading of the substrate 9 to and from the substrate processing apparatus 1 is performed by a robot or the like in a state where the nozzle 51, the splash guard 31, and the like have been arranged at the retracted position. The substrate 9 which has been carried into the substrate processing apparatus 1 is detachably held by the rotation base 21.

The substrate processing apparatus 1 includes a box-shaped chamber 11, a spin chuck 2, a scattering prevention section 3, a processing section 5, a nozzle moving mechanism 6, an exhaust duct 7, an opposing section 109, and a control section 130. Each of the rotating chuck 2, the scattering prevention unit 3, the processing unit 5, the nozzle moving mechanism 6, and the facing unit 109 is electrically connected to the control unit 130 and operates in accordance with an instruction from the control unit 130. As the control unit 130, for example, the same as a general computer can be adopted. That is, the control unit 130 is, for example, a CPU (Central Processing Unit) that performs various arithmetic processing, and a ROM (Read Only Memory) that is a read-only memory for storing a basic program. Memory), RAM (Random Access Memory), which is a readable and writable memory for storing various kinds of information, magnetic disks such as software or data for memory control in advance. In the control unit 130, the CPU as the main control unit performs arithmetic processing in the order described in the program to control each unit of the substrate processing apparatus 1.

<2. Substrate 9>

The surface shape of the substrate 9 to be processed in the substrate processing apparatus 1 is substantially circular. The radius of the substrate 9 is, for example, 150 mm. The substrate 9 is previously coated with a resist on the upper surface, which is a device surface, and then subjected to processes such as exposure, development, and etching to carry out impurity implantation and activation. A resist pattern remains on the upper surface of the substrate 9 above the fine pattern of the etched conductor, and the substrate 9 is at a stage where a resist peeling process (resistor removing process) is subsequently performed. The substrate processing apparatus 1 supplies SPM as a processing liquid from the nozzle 51 to the substrate 9 and performs a resist peeling process to peel off the resist of the substrate 9.

<3. Configuration of Parts of Substrate Processing Apparatus 1>

<Chamber 11>

The chamber 11 contains the spin chuck 2 or the nozzle 51 and the like. An upper part of the chamber 11 is provided with a FFU (Fan Filter Unit) 12 as a blower unit that sends clean air (air filtered by a filter) to the chamber 11. The FFU 12 generates a downward flow of clean air ("downward flow") in the chamber 11 during the processing of the substrate 9.

An exhaust duct 7 is connected to the lower portion of the chamber 11 and communicates with an exhaust device 99 to the outside of the substrate processing apparatus 1. The exhaust duct 7 guides the gas in the flow path CA formed between the member 311 and the outer member 312 in the splash guard 31 described later to the exhaust device 99.

<Rotary Chuck 2>

The rotary chuck ("rotary holding mechanism") 2 refers to a mechanism capable of rotating the substrate 9 while the main surface of one of the substrates 9 is turned upward while being held in a substantially horizontal posture. The spin chuck 2 rotates the substrate 9 around a vertical rotation axis a1 passing through the center c1 of the main surface. When the substrate processing apparatus 1 uses SPM as a processing liquid, the substrate processing apparatus 1 rotates the substrate 9 at, for example, a rotation speed of 100 rpm.

The spin chuck 2 is provided with a rotary base ("holding member", "substrate holding portion") 21 which is a disk-shaped member slightly larger than the substrate 9. The rotation base 21 is provided so that the upper surface may become substantially horizontal, and its center axis may coincide with the rotation axis a1. A cylindrical rotating shaft portion 22 is connected to the lower surface of the rotating base 21. The rotation shaft part 22 is arrange | positioned so that the axis | shaft may follow a vertical direction. The axis of the rotating shaft portion 22 coincides with the rotating shaft a1. A rotary drive unit (for example, a servo motor) 23 is connected to the rotary shaft portion 22. The rotation driving portion 23 rotates and drives the rotation shaft portion 22 about the axis of the rotation shaft portion 22. Accordingly, the rotation base 21 can rotate with the rotation shaft portion 22 about the rotation shaft a1 as a center. The rotation driving section 23 and the rotation shaft section 22 refer to a rotation mechanism 231 that rotates the rotation base 21 with the rotation shaft a1 as a center. The rotation shaft portion 22 and the rotation driving portion 23 are housed in a cylindrical casing 24.

A plurality of (for example, six) chuck pins 25 are provided near the peripheral edge portion of the upper surface of the rotary base 21 at appropriate intervals. The chuck pin 25 is in contact with the end surface of the substrate 9 to perform horizontal positioning of the substrate 9 and is slightly higher than the upper surface of the rotary base 21 (that is, spaced from the upper surface of the rotary base 21). The determined interval is maintained), and the substrate 9 is detachably held in a substantially horizontal posture. That is, the chuck pin 25 holds the peripheral edge portion of the substrate 9 with a gap separated from the upper surface of the spin base 21. Accordingly, the rotation base 21 holds the substrate 9 at a substantially horizontal level from below through the chuck pins 25. The upper surface of the rotary base 21 is substantially parallel to the lower surface of the substrate 9 with a gap therebetween, for example.

In this configuration, in a state where the rotation base 21 has sucked and held the substrate 9, when the rotation driving portion 23 rotates the rotation shaft portion 22, the rotation base 21 rotates about an axis along the vertical direction. Thereby, the substrate 9 held on the rotation base 21 is rotated toward the arrow AR1 with the vertical rotation axis a1 passing through the center c1 in the plane as a center.

In addition, the rotary chuck 2 is not limited to a clamping type, and a vacuum suction type (vacuum chuck) that holds the substrate 9 in a horizontal posture by vacuum suctioning the back surface of the substrate 9 may be used, for example.

<Scattering Prevention Unit 3>

The scattering prevention unit 3 receives the processing liquid and the like scattered from the substrate 9 that is held and rotated by the rotation base 21.

The scattering prevention unit 3 is provided with a splash guard 31. The splash guard 31 refers to a cylindrical member having an opened upper end, and is provided so as to surround the rotation base 21. In this embodiment, the splash guard 31 is, for example, three members including an inner member 310, a middle member (also referred to as "inside protective cover") 311, and an outer member (also referred to as "outer protective cover") 312. Make up. Furthermore, a protective cover may be further provided on the outer side of the splash guard 31 so as to surround the rotary chuck 2.

The inner member 310 refers to a cylindrical member having an opened upper end, and includes: a circular bottom portion 3101; a cylindrical inner wall portion 3102 extending upward from an inner edge portion of the bottom portion 3101; and a cylindrical shape The guide wall 3103 extends upward from the outer edge of the bottom portion 3101. At least the vicinity of the front end of the inner wall portion 3102 is accommodated in an inner space of the flange-shaped member 241 that has been provided in the housing 24 of the rotary base 21.

A drain groove (not shown) communicating with the space between the inner wall portion 3102 and the guide portion 3103 is formed at the lower end portion of the bottom portion 3101. The drainage tank is connected to the drainage line of the factory. The space between the inner wall portion 3102 and the guide wall 3103 refers to a space for collectively draining the processing liquid used in the substrate 9 after processing, and the processing liquid concentrated in this space is discharged from the drain tank.

The middle member 311 refers to a tubular member having an opened upper end, and is provided outside the inner member 310. The middle member 311 surrounds the periphery of the rotation base 21 in a circumferential direction with the rotation axis a1 as a center. That is, the middle member 311 surrounds the substrate 9 along the edge of the substrate 9 that has been held on the rotation base 21. The middle member 311 includes: a ring-shaped upper wall 311B, which constitutes the upper portion ("upper side portion", "upper portion") of the middle member 311 and surrounds the rotation axis a1; and a cylindrical side wall 311A from above The outer peripheral portion of the wall 311B extends along the side surface (end edge) of the rotary base 21 to surround the rotary base 21 and extends downward. The upper wall 311B extends upward and inward. That is, the upper wall 311B extends diagonally upward toward the rotation axis a1.

The side wall 311A, which is the lower part of the middle member 311, includes a cylindrical inner peripheral wall portion 3111 that extends downward toward the rotation base 21; and a cylindrical outer peripheral wall portion 3112 that is provided on the inner peripheral wall portion 3111. The outer side extends downward along the inner peripheral wall portion 3111. The guide wall 3103 of the inner member 310 is housed between the inner peripheral wall portion 3111 and the outer peripheral wall portion 3112 of the middle member 311. The lower end of the outer peripheral wall portion 3112 is close to the inner edge portion of the annular bottom portion 3113. A cylindrical guide wall 3114 extending upward is provided from the outer edge portion of the bottom portion 3113. As the middle member 311, for example, a member including only the side wall 311A of the side wall 311A and the upper wall 311B may be used.

The outer member 312 is a cylindrical member whose upper end is in an open state, and is provided outside the middle member 311 so as to form a flow path CA between the outer member and the middle member 311. The flow path CA introduces a gas existing inside the outer member 312 and guides the gas to the exhaust duct 71. In other words, the flow path CA refers to the gas above the substrate 9. The outer member 312 surrounds the periphery of the middle member 311 along a circumferential direction with the rotation axis a1 as a center, that is, surrounds the periphery of the rotation base 21 along the side surface (end edge) of the rotation base 21. That is, the outer member 312 surrounds the substrate 9 along the edge of the substrate 9 that has been held on the rotation base 21. The outer member 312 includes an annular upper wall 312B, which constitutes the upper portion ("upper end side portion", "upper end portion") of the outer member 312 and surrounds the rotation axis a1; and a cylindrical side wall 312A, which is from above An outer peripheral portion of the wall 312B surrounds the periphery of the rotary base 21 and extends downward. The upper wall 312B extends upward and inward. That is, the upper wall 312B extends diagonally upward toward the rotation axis a1.

The side wall 312A includes a cylindrical inner peripheral wall portion 3121 and a cylindrical outer peripheral wall portion 3122 at a lower portion thereof. The inner peripheral wall portion 3121 faces the outer peripheral wall portion 3112 and the guide wall 3114 of the middle member 311 and extends downward along the outer peripheral wall portion 3112. The outer peripheral wall portion 3122 is provided outside the inner peripheral wall portion 3121 and extends downward along the inner peripheral wall portion 3121. The guide wall 3114 of the middle member 311 is housed between the inner peripheral wall portion 3121 and the outer peripheral wall portion 3122 of the outer member 312.

The splash shield 31 is provided with a splash shield drive mechanism 32 for moving the splash shield up and down. The splash guard driving mechanism 32 is configured by, for example, a stepping motor. In this embodiment, the splash guard driving mechanism 32 independently raises and lowers the three inner members 310, the middle members 311, and the outer members 312 including the splash guard 31.

When the substrate 9 is exchanged, the three inner members 310, the middle member 311, and the outer member 312 are positioned at the lower end of the retreat position lower than the upper surface of the rotary base 21.

When the substrate processing apparatus 1 supplies SC1 to the substrate 9 already held on the spin base 21 and processes the substrate 9 from, for example, an SC1 supply mechanism (not shown), the SC1 system does not generate flue gas F1. The splash hood 31 is positioned at the first processing position. In a state where the splash guard 31 has been arranged at the first processing position, the middle member 311 and the outer member 312 are arranged with the respective inner peripheral edges of the upper walls 311B and 312B in a state where the respective upper walls 311B and 312B are overlapped. It is slightly above the side of the substrate 9.

When the substrate 9 is processed using SPM, since the flue gas F1 is generated, the splash guard 31 is positioned at the second processing position. In a state where the splash guard 31 has been positioned at the second processing position, the middle member 311 is disposed at the same position as the first processing position, and the outer member 312 is disposed above the middle member 311. Specifically, the outer member 312 is disposed above the middle member 311, for example, about 25 mm. The generated flue gas F1 is introduced into the flow path CA from the inner peripheral edge of the upper wall 311B of the middle member 311 and the inner peripheral edge of the upper wall 312B of the outer member 312.

The guide wall 3114 of the middle member 311 is housed in the inner peripheral wall portion 3121 of the outer member 312 even in a state where the splash guard 31 has been positioned in the retracted position, the first processing position, and the second processing position. And the outer peripheral wall portion 3122. The inner member 310 is disposed relative to the middle member 311 so that its guide wall 3103 is accommodated between the inner peripheral wall portion 3111 and the outer peripheral wall portion 3112 of the middle member 311.

The splash shield driving mechanism 32 is electrically connected to the control unit 130 and operates under the control of the control unit 130. In other words, the position of the splash guard 31 (specifically, the respective positions of the inner member 310, the middle member 311, and the outer member 312) is controlled by the control unit 130. Furthermore, the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 may overlap with respect to the rotation axis a1 on the side opposite to the exhaust port 71a.

The distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is set such that the exhaust port 71a side is wider than the opposite side of the exhaust port 71a with respect to the rotation axis a1.

The side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 make the exhaust port 71a side wider with respect to the rotation axis a1 than the opposite side of the exhaust port 71a, so that the outer member 312 is relatively eccentric. Component 311. In the examples shown in FIGS. 1 and 2, the respective central axis systems of the rotation base 21, the inner member 310, and the middle member 311 correspond to each other. The center axis of the outer member 312 is eccentric to the center axis of the middle member 311 to the exhaust port 71a side. By this eccentricity, the guide portion 3114 of the middle member 311 accommodated in the inner peripheral wall portion 3121 of the outer member 312 and the outer peripheral wall portion 3122 is moved relative to the inner peripheral wall portion 3121 and the outer peripheral wall portion 3122. Therefore, the interval between the inner peripheral wall portion 3121 and the outer peripheral wall portion 3122 is set to an interval at which the guide wall 3114 can perform the relative movement.

5 to 7 are top schematic diagrams showing an example of the arrangement relationship between the center c1 (rotation axis a1) of the substrate 9 (rotation base 21) and the middle member 311 and the outer member 312, respectively. 5 to 7 show the substrate 9, the side wall 311A of the middle member 311, the side wall 312A of the outer member 312, and the exhaust port 71a in the substrate processing apparatus 1, and descriptions of other elements are omitted. The side walls 311A and 312A are formed in a circular shape in plan view of the substrate 9. Even in any of FIGS. 5 to 7, the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is opposite to the exhaust port 71a side with respect to the rotation axis a1. Set wider side. In FIGS. 5 to 7, the center b1 of the middle member 311 and the center b2 of the outer member 312 are located on a straight line connecting the center of the rotation axis a1 and the exhaust port 71 a in a plan view. Even in FIG. 5 to FIG. 7, the distance between the side wall 311A and the side wall 312A on the straight line becomes the maximum value D1 equal to each other on the side of the exhaust port 71a, and is at the exhaust port 71a relative to the rotation axis a1. The opposite sides become the minimum values D2 which are equal to each other.

In the example of FIG. 5, as in FIGS. 1 and 2, the center c1 (rotation axis a1) of the substrate 9 (rotation base 21) coincides with the center b1 of the middle member 311. The center b2 of the outer member 312 is offset from the center b1 (the rotation axis a1 of the rotation base 21) of the middle member 311 to the exhaust port 71a side. That is, the middle member 311 is not eccentric to the rotation axis a1 of the rotation base 21, and the outer member 312 is disposed in a state eccentric to the rotation axis a1 of the rotation base 21 to the exhaust port 71 a side.

In addition, the rotation base 21 is consistent with the central axis of the inner member 310 and the outer member 312, and the central axis of the middle member 311 may be eccentric from the central axis of the outer member 312 along the diameter direction of the substrate 9 to the opposite of the exhaust duct 71 side.

In the example of FIG. 6, the rotation axis a1 (center c1) coincides with the center b2 of the outer member 312. The center b1 of the middle member 311 is offset from the rotation axis a1 to the opposite side of the exhaust port 71a. That is, the outer member 312 is not eccentric to the rotation axis a1, and the middle member 311 is disposed in a state of being eccentric to the rotation axis a1 to the opposite side to the exhaust port 71a.

In the example of FIG. 7, the rotation axis a1 (the center c1) is different from the center b1 of the middle member 311 and the center b2 of the outer member 312. The center b1 is offset from the rotation axis a1 to the opposite side to the exhaust port 71a. The center b2 is offset from the rotation axis a1 to the exhaust port 71a side. That is, the middle member 311 is disposed in a state of being eccentric to the rotation axis a1 to the opposite side to the exhaust port 71a. The outer member 312 is disposed in a state of being eccentric to the exhaust port 71a with respect to the rotation axis a1.

The eccentricity of the center b2 of the outer member 312 in FIG. 5 with respect to the rotation axis a1 is equal to the eccentricity of the middle member 311 in FIG. 6 with respect to the rotation axis a1. In FIG. 7, the eccentricities of the centers b1 and b2 with respect to the rotation axis a1 are equal to each other, and become the center b2 (center b1) of the outer member 312 (middle member 311) in FIG. 5 (FIG. 6) relative to the rotation. Half of the eccentricity of the axis a1. That is, as shown in FIG. 7, as long as both the middle member 311 and the outer member 312 are eccentric with respect to the rotation axis a1, only one of them is eccentric. In contrast, even if the amount of eccentricity is reduced, the eccentricity can be reduced. The interval between the side wall 311A and the side wall 312A is formed to be the same interval as when only one of them is eccentric.

Furthermore, the middle member 311 and the outer member 312 are substantially concentric cylindrical bodies. For example, the vicinity of the exhaust port 71 a in the side wall 312A of the outer member 312 may expand toward the outside in the diameter direction of the substrate 9. Even with this configuration, the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 can be made wider with respect to the rotation axis a1 than the exhaust port 71a side. In addition, the shapes of the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 are not limited to a circular shape in a plan view, and may be, for example, an ellipse or a polygon.

The distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is preferably a portion of the portion near the exhaust port 71a on the downstream side of the rotation base 21 with respect to the exhaust port 71a. Set in the widest way. In FIG. 2, the first semi straight line 41 is an imaginary semi straight line extending from the rotation axis a1 to the center of the exhaust port 71 a in a plan view of the substrate 9. The second half straight line 42 is a virtual half straight line obtained by rotating the first half straight line 41 toward the downstream side of the rotation direction of the substrate 9 with the rotation axis a1 as the center. The angle θ is an acute angle. The angle θ is set to, for example, 10 degrees to 20 degrees.

Here, the flow path CB refers to a portion between the side wall 311A (outer peripheral wall portion 3112) and the side wall 312A (inner peripheral wall portion 3121) in the flow path CA. The distance between the side wall 311A (outer peripheral wall portion 3112) and the side wall 312A (inner peripheral wall portion 3121), that is, the width of the flow path CB is the side wall 311A (outer peripheral wall portion 3112) and the side wall 312A (inner peripheral wall portion 3121) and The widest portions (the portion C1 in the flow path CB) of the second semi-straight lines 42 intersect each other. The portion C1 refers to a portion having the widest width in the diameter direction of the substrate 9 in the flow path CB.

The above-mentioned angle θ refers to an angle formed by the direction from the rotation axis a1 of the substrate 9 to the portion C1 and the direction from the rotation axis a1 to the exhaust duct 71. The angle θ may be set to a smaller angle than the range or a larger angle than the range in accordance with the rotation speed of the substrate 9. The portion C1 is positioned on the exhaust duct 71 side with respect to the rotation axis a1. The width D1 of the portion C1 is larger than the width D2 of the portion C of the flow path CB located on the opposite side of the portion C1 with respect to the rotation axis a1, and is the widest among the widths of the portions of the flow path CB.

The gas system formed in the flow path CA between the middle member 311 and the outer member 312 is discharged to an exhaust device 99 outside the substrate processing apparatus 1 through an exhaust duct 71 described later. In addition, the gas system existing between the case 24 and the middle member 311 is sequentially discharged to the exhaust equipment through exhaust pipes 72 and 71 described later.

The middle member 311 and the outer member 312 are raised and lowered by the splash cover driving mechanism 32. It is preferable that the middle member 311 and the outer member 312 are configured to be movable in a horizontal direction (for example, the diameter direction of the substrate 9). For example, the scattering prevention unit 3 may be provided with a ball screw mechanism that moves the middle member 311 and the outer member 312 toward the diameter direction of the substrate 9 and the operator uses the balls before the operation of the substrate processing apparatus 1 is started. The screw mechanism sets the distance between the middle member 311 and the outer member 312. The scattering prevention section 3 may be provided with a moving mechanism that relatively moves the outer member 312 to the middle member 311 along the diameter direction of the substrate 9, and the movement mechanism changes the interval between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312.

<Processing Section 5>

The processing unit ("processing liquid supply mechanism") 5 performs processing on the substrate 9 already held on the rotary base 21. Specifically, the processing unit 5 in FIG. 1 selectively supplies SPM and hydrogen peroxide water as a processing liquid to the upper surface of the substrate 9 that has been held on the spin base 21. The processing unit 5 includes a nozzle holding member 50, a nozzle 51, and a processing liquid supply unit 83.

The nozzle holding member 50 refers to a member that holds the nozzle 51. The nozzle holding member 50 is attached to the front end of a long arm 63 provided in a nozzle moving mechanism 6 described later. The arm portion 63 extends along a horizontal plane.

The nozzle holding member 50 is formed by a plate-like member extending along a vertical surface, for example. The upper end of the nozzle holding portion 50 is attached to the front end of the arm portion 63. The nozzle 51 is attached to the lower end portion of the nozzle holding member 50 so as to protrude toward the opposite side of the arm portion 63 along the extending direction of the arm portion 63.

In the example of FIG. 1, the processing unit 5 can selectively discharge the SPM and the hydrogen peroxide, which are a mixed solution of sulfuric acid and hydrogen peroxide water, supplied from the processing liquid supply unit 83 according to the control of the control unit 130. Water was used as the treatment liquid. FIG. 8 is a schematic cross-sectional view for explaining the structure of the nozzle 51 and the discharge of the processing liquid by the nozzle 51. FIG. 9 is a schematic plan view for explaining the discharge of the processing liquid by the nozzle.

The nozzle 51 has, for example, a substantially cylindrical case. A mixing chamber 511 is formed inside the casing forming the upper portion of the nozzle 51. The nozzle 51 includes a front end side portion 52 extending toward the upper surface of the substrate 9 below the mixing chamber 511. The front-end side portion 52 includes a bottom portion 52b that locks and faces the lower end portion of the substrate 9, a cylindrical side wall portion that extends upward from the peripheral edge of the bottom portion 52b, and a discharge port 52c that is provided in the side wall portion. The part on the side of the exhaust port 71a. The nozzle 51 discharges the SPM which belongs to the mixed liquid which mixed the sulfuric acid and hydrogen peroxide water in the mixing chamber 511 from the discharge opening 52c to the upper surface of the board | substrate 9.

The treatment liquid supply unit 83 includes a pipe 842 connected to the nozzle 51 and supplied with sulfuric acid from a sulfuric acid supply source 841 and a pipe 832 provided with hydrogen peroxide water from a hydrogen peroxide water supply source 831.

In the middle of the pipe 842, an on-off valve 843, a flow rate adjustment valve 844, and a heater 845 are provided in order from the nozzle 51 side to open and close the pipe 842. The heater 845 maintains sulfuric acid at a temperature higher than room temperature (a fixed temperature in a range of 70 ° C to 120 ° C. For example, 100 ° C). The heater 845 for heating sulfuric acid may be either a one-pass heater as shown in FIG. 1 or a cycle for heating sulfuric acid by circulating sulfuric acid inside a circulation path including the heater. Way of heater. Although not shown, the flow regulating valve 844 includes, for example, a valve body, which is provided with a valve seat inside; a valve element for opening and closing the valve seat; and an actuator. , The valve element is moved between the open position and the closed position. The same applies to other flow regulating valves.

In the middle portion of the pipe 832, an on-off valve 833 and a flow rate adjustment valve 834 for opening and closing the pipe 832 are sequentially provided from the nozzle 51 side. The nozzle 51 is supplied with hydrogen peroxide water at a normal temperature (approximately 23 ° C.) without temperature adjustment through a pipe 832. The on-off valve 833 is opened and closed by the control by the control valve 130.

The piping 842 is connected to an introduction port 514 for sulfuric acid disposed on a side wall of the mixing chamber 511 surrounding the nozzle 51. The pipe 832 is an inlet 513 for the hydrogen peroxide water, which is connected to the side wall of the casing of the nozzle 51 and is arranged above the inlet 514.

When the on-off valve 843 and the on-off valve 833 are opened, sulfuric acid from the pipe 842 is supplied from the inlet 514 to the mixing chamber 511 in the nozzle 51, and hydrogen peroxide water from the pipe 832 is supplied from the inlet 513 to the nozzle 51 It is supplied to the mixing chamber 511. The sulfuric acid and the hydrogen peroxide water that have flowed into the mixing chamber 511 are sufficiently mixed (stirred) inside the mixing chamber 511. By this mixing, sulfuric acid and hydrogen peroxide water can be uniformly mixed together, and a mixed solution (SPM) of sulfuric acid and hydrogen peroxide water is generated by the reaction of sulfuric acid and hydrogen peroxide water. SPM contains peroxymonosulfuric acid (H ₂ SO ₅ ), which has strong oxidizing power, and is heated to a temperature (100 ° C or higher, such as 160 ° C) higher than the temperature of sulfuric acid and hydrogen peroxide water before mixing. . The high-temperature SPM generated in the mixing chamber 511 of the nozzle 51 is discharged from a discharge port 52c provided at the front end portion 52 of the nozzle 51.

In addition, as the processing unit 5, a configuration in which sulfuric acid and hydrogen peroxide water are mixed in advance outside the nozzle 51 to generate SPM and necessary heating may be employed, and a high-temperature SPM is supplied to the nozzle 51.

As shown in FIGS. 8 and 9, the nozzle 51 discharges a processing liquid (SPM) to a portion below the nozzle 51 on the surface of the substrate 9 so as to touch the liquid injection position P1 on the exhaust port 71 a side. The nozzle 51 discharges the processing liquid to a portion (path T1) below the front end side portion 52 in the surface of the substrate 9 so as to touch the portion on the exhaust port 71 a side. The front end portion 52 of the nozzle 51 may be formed of, for example, an L-shaped pipe that is bent in a substantially horizontal direction after extending downward.

The liquid flow L1 of the processing liquid that has been discharged to the landing position P1 forms a liquid film 201 that spreads from the landing position P1 to the surroundings in a plan view on the upper surface of the substrate 9. The liquid injection position P1 may also be a position where the liquid film 201 covers the center c1 of the substrate, and the liquid film 201 is formed on the surface (upper surface) of the substrate 9 with the processing liquid discharged to the liquid injection position P1. The processing liquid flows further from the liquid film 201 toward its surroundings (the portion on the outer side in the diameter direction of the substrate 9 and on the downstream side in the rotation direction). The film thickness of the liquid film 201 is thicker than the film thickness of the surrounding processing liquid. When the nozzle moving mechanism 6 described later moves the nozzle 51 along the path T1, the impact position P1 moves along a path T2 parallel to the path T1.

The high-temperature SPM that has been discharged to the substrate 9 is relatively high in the vicinity of the landing position P1 and has high reactivity. Since the flue gas is mostly generated near the liquid injection position P1 of the processing liquid, it is more generated on the exhaust port 71a side than the center c1 of the substrate 9. Therefore, the generated flue gas can be efficiently discharged from the portion C1 on the exhaust port 71a side of the flow path CA.

FIG. 10 is a schematic cross-sectional view for explaining the nozzle 51A as another example of the nozzle of the substrate processing apparatus 1 and the discharge of the processing liquid by the nozzle 51A. As shown in FIG. 10, the front end portion 52 is a cylindrical body extending toward the upper surface of the substrate 9, and the front end portion may be provided with a liquid injection position on the upper surface of the substrate 9 along the extending direction of the cylindrical body. P1 discharges the discharge opening of a processing liquid.

As mentioned above, although SPM is heated to high temperature by the reaction heat of sulfuric acid and hydrogen peroxide water, when the proportion of hydrogen peroxide water mixed with sulfuric acid is increased, the reaction heat generated when sulfuric acid and hydrogen peroxide water are mixed is increased. It will increase, the liquid temperature of SPM will rise more and make the reactivity higher, and the amount of flue gas F1 generated by the reaction between SPM and the resist will also increase. The processing unit 5 supplies a large amount of hydrogen peroxide water from the nozzle 51 to the substrate 9 when the discharge of the SPM is completed. In this case, an extremely large amount of smoke F1 is generated. Therefore, when the flue gas F1 is not sufficiently discharged from the flow path CA through the exhaust duct 71 to the exhaust device 99, a large amount of the flue gas F1 will stay above the substrate 9 and increase the generation of fine particles.

The on-off valves 833 and 843 and the flow rate adjustment valves 834 and 844 included in the processing liquid supply unit 83 are opened and closed under the control of the control unit 130 through valve opening and closing mechanisms (not shown) electrically connected to the control unit 130. In other words, the discharge state of the processing liquid from the nozzle 51 (specifically, the discharge start timing, the discharge end timing, the discharge flow rate, and the like of the discharged processing liquid) are controlled by the control unit 130. That is, the nozzle 51 of the processing unit 5 discharges the liquid flow L1 of the processing liquid under the control of the control unit 130 so as to touch the liquid injection position P1 on the upper surface of the substrate 9 which is rotated with the rotation axis a1 as the center.

<Nozzle moving mechanism 6>

The nozzle moving mechanism 6 refers to a mechanism that moves the nozzle 51 between its processing position and a retracted position. The nozzle moving mechanism 6 includes a horizontally extending arm portion 63, a nozzle base 66, an elevating driving portion 68, and a rotating driving portion 69. The nozzle holding member 50 is attached to the front end portion of the arm portion 63.

The base end portion of the arm portion 63 is connected to the upper end portion of the nozzle base 66. The nozzle base 66 is arrange | positioned on the outer side of the housing 24 so that the axis | shaft may follow a vertical direction. The nozzle base 66 includes a rotation shaft that extends in the vertical direction along its axis and is rotatable about the axis. The axis of the nozzle base 66 coincides with the axis of the rotation shaft. An upper end portion of the nozzle base 66 is attached to the upper end of the rotation shaft. By the rotation of the rotation axis, the upper end portion of the nozzle base 66 rotates around the axis of the rotation axis, that is, the axis of the nozzle base 66 as a center. The nozzle base 66 is provided with a rotation drive unit 69 that rotates its axis of rotation about the axis. The rotation driving unit 69 is configured by, for example, a servo motor.

In addition, the nozzle base 66 is provided with a lift driving unit 68. The elevating driving unit 68 is configured by, for example, a servo motor. The elevating driving unit 68 raises and lowers the rotation axis of the nozzle base 66 along its axis through a ball screw mechanism having a ball screw and the like connected to its output shaft.

The rotation driving unit 69 rotates the upper end portion of the nozzle base 66 through a rotation axis of the nozzle base 66. Along with the rotation of the upper end portion, the nozzle holding member 50 also rotates about the axis of the nozzle base 66. Accordingly, when the nozzle 51 discharges the processing liquid to the substrate 9, the rotation driving unit 69 controls the nozzle 51 along the periphery of the substrate 9 and above the center c1 according to the control by the nozzle 51. The path T1 moves horizontally. The path T1 is set when viewed from above the substrate 9, for example, to pass through the center c1 of the substrate 9. The rotation driving unit 69 may stop the nozzle 51 above the substrate 9 when the nozzle 51 discharges the processing liquid to the substrate 9. When the nozzle 51 moves along the path T1, the liquid injection position P1 of the processing liquid discharged from the nozzle 51 moves along the path T2 parallel to the path T1.

The raising and lowering driving unit 68 raises and lowers the rotation axis of the nozzle base 66 along its axis to raise and lower the nozzle holding member 50 even when the nozzle 51 is raised and lowered. The elevating driving unit 68 and the rotary driving unit 69 are interlocked with each other at a processing position near the substrate 9 that has been held on the rotation base 21, and a retreat position that is located outside and above the processing base along the diameter direction of the substrate 9, for example. At this time, the nozzle 51 is moved.

The respective retreat positions of the nozzle holding member 50 and the nozzle 51 refer to various positions where the nozzle holding member 50 and the nozzle 51 do not interfere with the conveying path of the substrate 9, and the nozzle holding member 50 and the nozzle 51 do not interfere with each other. . Each retreat position is, for example, a position outside and above the splash guard 31.

The lift driving unit 68 and the rotation driving unit 69 are electrically connected to the control unit 130 and operate under the control of the control unit 130. In other words, the position of the nozzle 51 is controlled by the control unit 130.

<Exhaust Duct 7>

The exhaust duct 7 includes an exhaust duct 71 and an exhaust duct 72. The exhaust duct 71 includes an exhaust port 71 a that communicates with a flow path CA formed between the middle member 311 and the outer member 312, and is used to introduce the gas in the flow path CA from the exhaust port 71 a to the exhaust duct 71. And is guided to an exhaust device 99 outside the substrate processing apparatus 1.

The exhaust duct 72 communicates with the exhaust duct 71 at one end. An exhaust port 72 a is formed at the other end of the exhaust duct 72 and communicates with a flow path between the inner peripheral wall portion 3111 of the middle member 311 and the guide wall 3103 of the inner member 310. The exhaust duct 72 mainly introduces the gas between the casing 24 and the inner peripheral wall portion 3111 of the middle member 311 through the exhaust port 72 a to the exhaust duct 72, and exhausts the exhaust duct 72 to the exhaust equipment 99. The exhaust device 99 is a decompression exhaust duct 7 and sucks the gas in the flow path CA.

In order to make the gas in the portion above the substrate 9 higher than the inner peripheral edge of the upper wall 311B of the middle member 311 and lower than the inner peripheral edge of the upper wall 312B of the outer member 312, the gas is mainly exhausted from above the substrate 9 toward the exhaust. The flow is on the side of the port 71a, and the ventilation resistance of the flow path CA is smaller than the side of the exhaust port 71a with respect to the rotation axis a1. The upper end of the outer member 311 is positioned higher than the upper end of the middle member 311. The opening formed by the upper end of the outer member 312 and the upper end of the middle member 311 is opposite to the rotation axis a1, and along the center of the rotation axis a1. The circumferential direction surrounds the rotation axis a1. The middle member 311 and the outer member 312 are designed to make the gas in the portion above the substrate 9 higher than the upper end of the middle member 311 and lower than the upper end of the outer member 312 mainly from the upper portion of the substrate 9 to the exhaust port 71a. The side flow and the ventilation resistance of the flow path CA are set in a geometric relationship that the exhaust port 71a side is smaller than the opposite side of the exhaust port 71a with respect to the rotation axis a1. Thereby, in the portion above the substrate 9, the portion above the inner peripheral edge of the upper wall 311B of the middle member 311 and below the inner peripheral edge of the upper wall 312B of the outer member 312 is mainly generated mainly from the base 9 The air flow A1 flowing upward toward the exhaust port 71a side. 12 and 13 are schematic side views each showing an example of a configuration of an inner shield and an outer shield. In order to make the ventilation resistance of the flow path CA smaller than the side of the exhaust port 71a with respect to the rotation axis a1, a disturbance structure such as a protrusion 315 that disturbs the air flow in the flow path CA may be provided in the middle. The member 311 and the outer member 312 (refer to FIG. 12). The protrusion 315 may be provided on only one of the middle member 311 and the outer member 312. In addition, the area of the portion of the opening of the flow path CA located on the side opposite to the exhaust port 71a with respect to the rotation axis a1 is formed to be smaller than the area of the portion of the opening located on the side of the exhaust port 71a. A shutter 316 may be provided on at least one of the upper end (inner periphery) of the middle member 311 and the upper end (inner periphery) of the outer member 312 (see FIG. 13). In this way, by providing the shutter 316, the ventilation resistance of the flow path CA can be made smaller on the side of the exhaust port 71a with respect to the rotation axis a1 than on the side opposite to the exhaust port 71a.

Even if the nozzle 51 ejects the SPM to the upper surface of the substrate 9 and uses the reaction between the SPM and the resist to generate the flue gas F1, the generated flue gas F1 will still be efficiently carried to the stream by the air flow A1. The part on the exhaust port 72a side of the path CA is introduced into the flow path CA, and is discharged to the exhaust device 99 through the exhaust duct 71. The exhaust device 99 is, for example, a factory device, and has a pump or the like to generate exhaust capacity. Exhaust ducts 99 are generally connected to exhaust ducts of devices other than the substrate processing apparatus 1, and the exhaust capacity of the exhaust apparatuses 99 is equally distributed to exhausts of other apparatuses other than the substrate processing apparatus 1. Therefore, since it is not possible to allocate a large capacity only to the substrate processing apparatus 1 that performs exhaust of the flue gas F1, it is not possible to increase the exhaust of the flue gas F1 by increasing the exhaust capacity supplied from the exhaust device 99. Gas efficiency. In the substrate processing apparatus 1, the ventilation resistance of the flow path CA is smaller on the side of the exhaust port 71 a than on the side opposite to the exhaust port 71 a with respect to the rotation axis a1. Therefore, by the suction force of the exhaust duct 71, gas in the portion above the base plate 9 above the middle member 311 upper portion and lower than the upper end of the outer member 312 is generated mainly from the base plate 9 The air flow A1 flowing upward toward the exhaust port 71a side. Even in a case where the ability to be distributed to the substrate processing apparatus 1 cannot be increased, the substrate processing apparatus 1 can efficiently recover the flue gas F1 generated from the SPM through the flow path CA and the exhaust duct 71 to Exhaust equipment 99.

<Opposite section 109>

The opposing portion 109 protects the upper surface of the substrate 9 by opposing the upper surface of the substrate 9 that has been held on the rotation base 21 with a gap. The facing portion 109 can change the width of the gap.

The opposing portion 109 includes a cylindrical shaft member 94. The central axis system of the shaft member 94 coincides with the rotation axis a1. The facing portion 109 further includes a cylindrical rotating portion 93 and a disc-shaped baffle 90. The rotating portion 93 is attached to the lower end portion through a bearing in a state where the lower end portion of the shaft member 94 is inserted. The central axis system of the rotation portion 93 coincides with the rotation axis a1. Thereby, the rotation part 93 is able to rotate around the shaft member 94 with the rotation shaft a1 as a center toward the circumferential direction.

A disc-shaped baffle (“opposing member”) 90 is attached to the lower portion of the rotating portion 93 so as to be able to rotate integrally with the rotating portion 93. The baffle 90 has a disk-like shape that is the same as or slightly larger than the substrate 9, and the rotation axis a1 passes through its center. Thereby, the baffle plate 90 can be rotated toward the circumferential direction with the rotation axis a1 as a center. The baffle 90 includes a lower surface (“main surface”) 91 which is opposed to the entire area of the upper surface of the substrate 9 and a side surface 92 which is erected upward from the peripheral edge of the lower surface 91. The lower surface 91 is circular. A through hole 95 communicating with the shaft member 94 is provided in the center of the baffle 90. The lower surface 91 faces the upper surface of the substrate 9 held by the chuck pin 25 with a gap therebetween. The width of the gap varies depending on the height of the facing portion 109.

A baffle rotating mechanism 97 is coupled to the rotating portion 93. The baffle rotation mechanism 97 includes an electric motor, a gear, and the like controlled by the control unit 130 and rotates the rotation unit 93 with the rotation axis a1 as the center in the circumferential direction. Thereby, the baffle 90 rotates integrally with the rotating portion 93. More specifically, the shutter rotation mechanism 97 rotates the shutter 90 and the rotation portion 93 in the same direction at the same rotation speed as the substrate 9 in accordance with the control of the control unit 130.

An upper end portion of the shaft member 94 is provided with a holding member (not shown) that holds the shaft member 94, and a shutter lift mechanism 98 including an electric motor, a ball screw, and the like controlled by the control unit 130 is incorporated. The shutter elevating mechanism 98 raises and lowers the shaft member 94 in the vertical direction together with the shutter 90 and the rotating portion 93. The baffle lifting mechanism 98 is arranged between the lower surface 91 of the baffle 90 adjacent to the upper position of the substrate 9 held by the rotating base 21 and the retracted position provided above the adjacent position, so that the baffle 90 The rotating portion 93 and the shaft member 94 are raised and lowered. The shutter lifting mechanism 98 is capable of holding the shutter 90 at various positions between the adjacent position and the retracted position. The retreat position of the baffle 90 is specifically a height from the upper surface of the substrate 9 to the lower surface 91 of the baffle 90, and it is, for example, a height position of 150 mm. The adjacent position refers to a position where the height is, for example, 3 mm. The substrate processing apparatus 1 further includes, for example, a rinsing liquid supply mechanism that supplies a rinsing liquid to the upper surface of the substrate 9 from a nozzle that has been inserted into the hollow portion of the shaft member 94. 90 is disposed in a state of being adjacent to the substrate 9 and is supplied with a rinse liquid and the like.

<4. Ventilation resistance of the flow path and exhaust efficiency of the flue gas>

FIG. 3 is a schematic side view illustrating the flow H100 of the flue gas F100 generated in the substrate processing apparatus 100 of the comparative technology. Fig. 4 is a schematic side view illustrating the flow H1 of the flue gas F1 generated in the substrate processing apparatus 1 according to the embodiment.

The substrate processing apparatus 100 is the same as the substrate processing apparatus 1 except that it includes a scattering prevention unit 300 instead of the scattering prevention unit 3 of the substrate processing apparatus 1. Although the scattering prevention portion 3 and the scattering prevention portion 300 each include the middle member 311 and the outer member 312, in the scattering prevention portion 3 and the scattering prevention portion 300, the outer member 312 is opposed to the diametric direction of the substrate 9 of the middle member 311 The configuration relationship is different.

The substrate processing apparatus 1 is located between the side wall 311A (outer peripheral wall portion 3112) of the middle member 311 and the side wall 312A (inner peripheral wall portion 3121) of the outer member 312. The flow path CB is located at the exhaust side with respect to the rotation axis a1. The width D1 of the portion X1 on the duct 71 (exhaust port 71a) side is the widest among the widths of the portions of the flow path CB. The width D2 of the portion X2 of the flow path CB which is located on the opposite side of the portion X1 with respect to the rotation axis a1 is the narrowest among the widths of the portions of the flow path CB. The width D1 is larger than the width D2. The ventilation resistance of the part X1 on the exhaust port 71a side of the flow path CB is smaller than the ventilation resistance of the part X2.

Therefore, the portion above the base plate 9 is higher than the upper end of the middle member 311 and lower than the upper end of the outer member 312, that is, the upper end of the outer member 312 and the middle member 311 in the portion above the base plate 9 The height position of the opening formed by the upper end mainly generates an air flow A1 that flows mainly from above the substrate 9 toward the exhaust port 71a side. Although the high-temperature SPM discharged from the nozzle 51 to the substrate 9 and the fume F1 generated by the reaction of the resist with the substrate 9 rise from the substrate 9 toward the baffle 90 side, they hardly adhere to the lower surface of the baffle 90. Instead, it is efficiently guided from the exhaust port 71 a side to the flow path CA including the flow path CB, and is discharged to the exhaust device 99 through the exhaust duct 71. Therefore, the generated flue gas F1 is not easily a cause of contamination of the substrate 9 or fine particles.

In the substrate processing apparatus 100, between the side wall 311A (outer peripheral wall portion 3112) of the middle member 311 and the side wall 312A (inner peripheral wall portion 3121) of the outer member 312, the flow path CB is located at the exhaust side with respect to the rotation axis a1 The width D3 of the portion Y1 on the duct 71 (exhaust port 71a) side is the narrowest among the widths of the portions of the flow path CB. The width D4 of the portion Y2 of the flow path CB which is located on the opposite side of the portion Y1 with respect to the rotation axis a1 is the widest among the widths of the portions of the flow path CB. The width D3 is smaller than the width D4. The ventilation resistance of the portion Y1 on the exhaust port 71a side of the flow path CB is greater than the ventilation resistance of the portion Y2 on the opposite side to the exhaust port 71a with respect to the rotation axis a1. Therefore, unevenness in the flow rate of the flow path CA when the gas above the substrate 9 enters the flow path CA from various positions of the opening of the flow path CA surrounding the rotation axis a1 can be suppressed in the circumferential direction of the flow path CA. Therefore, the air flow B1 which is turned at a radial and substantially equal flow rate from above the center of the substrate 9 (below the baffle 90) toward each position of the opening of the flow path CA is generated, and the generated flue gas F100 is generated from the substrate 9 After the upper surface rises toward the baffle 90 side in a substantially vertical direction, it is shielded by the baffle 90 and flows in a radial pattern from above the center of the substrate 9 to the opening of the flow path CA. Therefore, the flue gas F1 adheres to the lower surface of the baffle 90 before entering the flow path CA, and becomes a major cause of fine particles.

<5. Operation of substrate processing apparatus 1>

FIG. 11 is a flowchart showing an example of the operation of the substrate processing apparatus 1. The substrate processing apparatus 1 processes a substrate 9 with a processing liquid along this flowchart. Before the operation of this flowchart is started, the substrate 9 is held in advance by the rotation base 21. In addition, the upper surface of the substrate 9 is a pattern in which a resist remains on the fine pattern of the etched conductor, and the substrate 9 is assumed to be in a stage where a resist peeling treatment (resistor removing treatment) is subsequently performed.

First, the rotation mechanism 231 starts the rotation of the rotation base 21 according to the control of the control unit 130, thereby starting the rotation of the substrate 9 held on the rotation base 21 (step S10 in FIG. 1).

Next, the valve opening and closing mechanism of the processing unit 5 opens the on-off valves 833 and 843 at a predetermined opening degree under the control of the control unit 130, and the nozzle 51 starts to discharge the processing liquid so as to contact the liquid on the upper surface of the substrate 9. Position P1 (step S20).

The control unit 130 waits for the time required for processing by the processing liquid ("processing time") to elapse (step S30), and causes the valve opening and closing mechanism of the processing unit 5 to close the on-off valves 833 and 843 to stop passing through the nozzle 51. The discharged processing liquid is discharged (step S40), and thereafter, the rotation mechanism 231 stops the rotation of the rotation base 21 to stop the rotation of the substrate 9 (step S50). The processing operation of the substrate processing apparatus 1 shown in FIG. 11 ends.

According to the substrate processing apparatus of the present embodiment configured as described above, the flow path CA is formed between the middle member 311 and the outer member 312. Then, in order to make the gas in the portion above the substrate 9 higher than the inner peripheral edge of the upper wall 311B of the middle member 311 and lower than the inner peripheral edge of the upper wall 312B of the outer member 312, the gas mainly faces from above the substrate 9 The side of the exhaust port 71a flows, and the ventilation resistance of the flow path CA makes the side of the exhaust port 71a smaller than the side opposite to the exhaust port 71a with respect to the rotation axis a1. Therefore, the flue gas F1 generated from the processing liquid supplied to the substrate 9 can be partially redirected from the exhaust port 71a side of the flow path CA by the airflow A1 above the substrate 9 on the exhaust port 71a side. It is preferably introduced into the flow path CA and is efficiently discharged to the outside through the exhaust duct 71.

According to the substrate processing apparatus of the present embodiment, the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is wider with respect to the rotation axis a1 than the exhaust port side 71a opposite to the exhaust port 71a. Therefore, the ventilation resistance of the flow path CA is smaller with respect to the rotation axis a1 than the exhaust port side 71a on the opposite side to the exhaust port 71a.

Further, according to the substrate processing apparatus of this embodiment, the space between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is wider with respect to the rotation axis a1 than the exhaust port side 71a opposite to the exhaust port 71a. Way, the outer member 312A is eccentric to the middle member 311. Therefore, the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 can be easily realized, and the exhaust port 71a side is wider with respect to the rotation axis a1 than the opposite side of the exhaust port 71a.

Furthermore, according to the substrate processing apparatus of this embodiment, the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is located near the exhaust port 71a in the rotary base 21 with respect to the exhaust port 71a. Since the portion on the downstream side in the direction of rotation is the widest, it is possible to suppress the exhaust efficiency of the flue gas F1 from being reduced due to the viscosity of the flue gas F1 and the influence of the rotation of the substrate 9.

The flue gas F1 is directed to the exhaust port 71a by the airflow A1 above the substrate 9 on the side of the exhaust port 71a. Furthermore, due to the viscosity of the flue gas F1 and the rotation of the substrate 9, the force on the downstream side of the rotation direction of the substrate 9 also acts on the flue gas F1. Therefore, since the flue gas F1 is turned to the downstream side of the rotation direction of the substrate 9 while turning to the exhaust port 71a side in a plan view, the portion near the exhaust port 71a faces the rotating base with respect to the exhaust port 71a. The part on the downstream side of the rotation direction of 21 flows most. Here, since the distance between the side wall 311A of the middle member 311 and the side wall 312A of the outer member 312 is the widest in the portion on the downstream side, it is possible to efficiently capture and guide the smoke F1 flowing toward the portion on the downstream side. Into the flow path CA. Thereby, the exhaust efficiency of the flue gas F1 can be suppressed from being reduced due to the influence of the viscosity of the flue gas F1 and the rotation of the substrate 9.

Further, according to the substrate processing apparatus of this embodiment, the nozzle 51 of the processing liquid supply mechanism discharges the processing liquid to a portion below the nozzle 51 on the surface of the substrate 9 so as to touch a portion on the exhaust port 71a side. The flue gas F1 is generated in the vicinity of the portion where the processing liquid has touched the substrate 9. Therefore, the generated flue gas F1 can be efficiently discharged from the part on the exhaust port 71a side of the flow path CA.

In addition, according to the substrate processing apparatus of this embodiment, it is possible to realize the nozzle 51 that discharges the processing liquid to the portion below the nozzle 51 on the surface of the substrate 9 so as to touch the portion on the exhaust port 71a side with a simple configuration.

Although the present invention has been shown and described in detail, the above description is exemplified and not limited in all aspects. Therefore, the present invention can appropriately change and omit embodiments within the scope of the invention.

Claims (14)

A substrate processing apparatus includes a holding member that holds a substrate in a substantially horizontal posture and can be rotated using a rotation axis in a vertical direction as a center; a rotation mechanism that rotates the holding member with the rotation axis as a center; and a processing liquid supply A mechanism for supplying a processing liquid to the surface of the substrate; an inner protective cover having a cylindrical side wall surrounding the holding member and extending along the rotation axis, and the upper end of the inner protective cover is open; the outer protective cover Is provided on the outer side of the inner shield so as to form a flow path between the inner shield and the inner shield to guide the gas above the substrate, and the outer shield has a periphery surrounding the holding member and extending along the outer shield. A cylindrical side wall extending along the rotation axis, and an upper end of the outer protective cover is opened; and an exhaust duct including an exhaust gas communicating with the flow path formed between the inner protective cover and the outer protective cover Mouth, and guide the gas in the flow path to the outside; the upper end of the outer protective cover is positioned It is higher than the upper end of the inner protective cover; the opening formed by the upper end of the outer protective cover and the upper end of the inner protective cover is opposite to the rotation axis; the side wall of the inner protective cover and the side wall of the outer protective cover are opposite to each other. The outer shield is relatively eccentric to the inner shield in such a manner that the interval is wider with respect to the rotation axis than the opposite side of the exhaust opening, whereby the inner shield and the outer shield are arranged relatively eccentrically. The cover is provided in such a manner that the ventilation resistance of the flow path relative to the rotation axis makes the exhaust port side smaller than the opposite side of the exhaust port, and the portion above the substrate is larger than that of the inner protective cover. The gas above the upper end and lower than the upper end of the outer shield is mainly oriented from above the substrate, and is more oriented toward the rotation axis than the opening on the opposite side of the exhaust port to the rotation axis. The aforementioned opening on the exhaust port side flows. The substrate processing apparatus according to claim 1, further comprising: a sulfuric acid supply mechanism for supplying sulfuric acid to the substrate; and a hydrogen peroxide water supply mechanism for supplying hydrogen peroxide water to the substrate; a side wall of the inner protective cover and the aforementioned The interval between the side walls of the outer shield is adjusted in such a way that the flue gas generated when mixing sulfuric acid and hydrogen peroxide water crosses the above substrate and mainly faces the opening on the exhaust port side with respect to the rotation axis. flow. The substrate processing apparatus according to claim 1 or 2, wherein the central axis of the side wall of the inner shield is consistent with the rotation axis; the side wall of the outer shield is eccentric to the exhaust port side with respect to the rotation axis. The substrate processing apparatus according to claim 1 or 2, wherein the central axis of the side wall of the outer protective cover is consistent with the rotation axis; the side wall of the inner protective cover is eccentric to the exhaust shaft relative to the exhaust shaft side. The substrate processing apparatus according to claim 1 or 2, wherein the side wall of the outer shield is eccentric to the exhaust port side with respect to the rotation axis, and the side wall of the inner shield is eccentric to the row with respect to the rotation axis. The opposite side of the port. The substrate processing apparatus according to claim 1 or 2, wherein the first half straight line is defined by an imaginary half straight line extending from the rotation axis to the center of the exhaust port in a plan view, and by rotating the rotation When the second half straight line is defined by an imaginary half straight line obtained by rotating the first half straight line at an acute angle to the downstream side of the rotation direction of the substrate with the axis as the center, the distance between the sidewall of the inner shield and the side wall of the outer shield The portion which becomes the side wall of the inner shield and the side wall of the outer shield in a plan view is the widest at each portion that intersects the second semi-straight line. The substrate processing apparatus according to claim 1 or 2, wherein the processing liquid supply mechanism is provided with a nozzle, and the nozzle is positioned at the center of the surface of the substrate from above the substrate with respect to the center of the substrate at the exhaust port. The processing liquid is discharged from the liquid injection position on the side; the liquid injection position is a position where the liquid film covers the center of the substrate, and the liquid film is formed on the surface of the substrate from the processing liquid that has been discharged to the liquid injection position. A substrate processing method is a method performed by a substrate processing apparatus. The substrate processing apparatus rotates a substrate around a vertical axis of rotation while holding the substrate in a substantially horizontal posture by using a holding member. The substrate processing apparatus includes: : The inner protective cover having a cylindrical side wall surrounding the holding member and extending along the rotation axis, and the upper end of the inner protective cover is open; the outer protective cover is provided between the inner protective cover and the inner protective cover; It is provided on the outside of the inner shield so as to form a flow path for guiding the gas above the substrate, and the outer shield has a cylindrical side wall that surrounds the holding member and extends along the rotation axis. The upper end of the outer protective cover is open; and an exhaust duct includes an exhaust port communicating with the flow path formed between the inner protective cover and the outer protective cover, and guides the gas in the flow path. Lead to the outside; the upper end of the outer protective cover is positioned above the upper end of the inner protective cover; The opening formed by the upper end of the outer protective cover and the upper end of the inner protective cover is opposed to the rotation axis of the substrate; the distance between the side wall of the inner protective cover and the side wall of the outer protective cover is relative to the rotation axis. The exhaust port side is wider than the opposite side of the exhaust port, so that the outer protective cover is relatively eccentrically disposed with respect to the inner protective cover, whereby the inner protective cover and the outer protective cover are provided in the following manner: The ventilation resistance of the flow path relative to the rotation axis makes the exhaust port side smaller than the opposite side of the exhaust port, and the upper part of the substrate is higher than the upper end of the inner shield and protected from the outer side. The gas at the lower part of the cover mainly flows from above the substrate toward the opening on the side opposite to the exhaust port compared to the rotation axis with respect to the opening on the exhaust port side. The substrate processing method includes a rotation step of moving the substrate forward while maintaining the substrate in a substantially horizontal posture. Rotating the rotary shaft as a center; and a treatment liquid supplying step, the surface treating solution for the supply of the substrate. The substrate processing method according to claim 8, further comprising a sulfuric acid supply step of supplying sulfuric acid to the substrate and a hydrogen peroxide water supply step of supplying hydrogen peroxide water to the substrate; a side wall of the inner protective cover and the aforementioned The distance between the side walls between the outer shields is adjusted in such a manner that the flue gas generated when the sulfuric acid and the hydrogen peroxide water are mixed crosses the above the substrate and mainly faces the aforementioned portion located on the exhaust port side with respect to the rotation axis. Openings flow. The substrate processing method according to claim 8 or 9, wherein the central axis of the side wall of the inner shield is consistent with the rotation axis; the side wall of the outer shield is eccentric to the exhaust port side with respect to the rotation axis. The substrate processing method according to claim 8 or 9, wherein the central axis of the side wall of the outer protective cover is the same as the rotation axis; the side wall of the inner protective cover is eccentric to the exhaust shaft and opposite to the exhaust port. side. The substrate processing method according to claim 8 or 9, wherein the side wall of the outer shield is eccentric to the exhaust port side with respect to the rotation axis, and the side wall of the inner shield is eccentric to the row with respect to the rotation axis. The opposite side of the port. The substrate processing method according to claim 8 or 9, wherein the first half straight line is defined by an imaginary half straight line extending from the rotation axis to the center of the exhaust port in a plan view, and by rotating the rotation When the second half straight line is defined by an imaginary half straight line obtained by rotating the first half straight line at an acute angle to the downstream side of the rotation direction of the substrate with the axis as the center, the distance between the side wall of the inner shield and the side wall of the outer shield is The portion which becomes the side wall of the inner shield and the side wall of the outer shield in a plan view is the widest at each portion that intersects the second semi-straight line. The method for processing a substrate according to claim 8 or 9, wherein the step of supplying the processing liquid is to discharge the liquid injection position on the surface of the substrate from the upper side of the substrate relative to the center of the substrate with respect to the center of the substrate. The step of the processing liquid; the liquid-receiving position is a position where the liquid film covers the center of the substrate, and the liquid film is formed on the surface of the substrate from the processing liquid that has been discharged to the liquid-receiving position.