TWI655908B - Milk-based acidified beverage and method of production thereof - Google Patents

Milk-based acidified beverage and method of production thereof Download PDF

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TWI655908B
TWI655908B TW103145812A TW103145812A TWI655908B TW I655908 B TWI655908 B TW I655908B TW 103145812 A TW103145812 A TW 103145812A TW 103145812 A TW103145812 A TW 103145812A TW I655908 B TWI655908 B TW I655908B
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beverage
milk
water
acidic
acidic milk
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TW201538082A (en
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小泉哲郎
吉川徹
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日商朝日飲料股份有限公司
日商朝日集團控股股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/12Fermented milk preparations; Treatment using microorganisms or enzymes
    • A23C9/13Fermented milk preparations; Treatment using microorganisms or enzymes using additives
    • A23C9/137Thickening substances
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/154Milk preparations; Milk powder or milk powder preparations containing additives containing thickening substances, eggs or cereal preparations; Milk gels
    • A23C9/1542Acidified milk products containing thickening agents or acidified milk gels, e.g. acidified by fruit juices
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/04Production of frozen sweets, e.g. ice-cream
    • A23G9/045Production of frozen sweets, e.g. ice-cream of slush-ice, e.g. semi-frozen beverage
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/60Drinks from legumes, e.g. lupine drinks
    • A23L11/65Soy drinks
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/66Proteins

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Botany (AREA)
  • Dispersion Chemistry (AREA)
  • Microbiology (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Dairy Products (AREA)

Abstract

本發明係提供一種可有效抑制特定低糖度的酸性乳性飲料於冷凍、融解後所產生之離水現象,且具有飲食時優良外觀之酸性乳性飲料及其製造方法。本發明之酸性乳性飲料係含有乳、大豆多糖類以及水,無脂乳固體份量係0.1~1.0質量%,糖度係0.5~1.7(°Bx),且pH為3.6~4.2,特徵係將飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲食,特別係適用於填充於具高透明度容器之冷凍飲料製品。 The present invention provides an acidic milk beverage which can effectively suppress the water-out phenomenon which is generated after freezing and melting of an acidic milk beverage having a specific low sugar content, and which has an excellent appearance at the time of eating and a method for producing the same. The acidic milk beverage of the present invention contains milk, soybean polysaccharides and water, and the fat-free milk solid content is 0.1 to 1.0% by mass, the sugar content is 0.5 to 1.7 (°Bx), and the pH is 3.6 to 4.2. After at least a part of the frozen portion is frozen, a part or all of the frozen portion is melted and then eaten, in particular, it is suitable for filling in a frozen beverage product having a highly transparent container.

Description

酸性乳性飲料及其製造方法 Acidic milk beverage and method of producing the same

本發明係有關將飲料的至少一部分進行冷凍後,再於融解了冷凍部分的一部分或全部之後進行飲食之酸性乳性飲料及其製造方法,更詳細係有關可有效抑制於前述融解後所產生之酸性乳性飲料之離水現象,且於飲用時具優良外觀,並可防止製品價值降低之酸性乳性飲料,及其製造方法以及抑制該酸性乳性飲料之離水現象之方法。 The present invention relates to an acidic milk beverage which is prepared by freezing at least a part of a beverage and then melting a part or all of the frozen portion, and a method for producing the same, and more specifically relates to an effect which can be effectively suppressed after the melting An acidic milk beverage which has a water-repellent phenomenon of an acidic milk beverage and which has an excellent appearance when consumed, and can prevent a decrease in the value of the product, a method for producing the same, and a method for suppressing the water-off phenomenon of the acidic milk-based beverage.

為抵禦猛暑,常會將飲料冷凍後再飲用。為了滿足這樣的需求,目前已販售有多種連同容器一起冷凍後,於緩緩融解的同時可供飲用之製品。另外,即使於未預期進行冷凍之情況下,也可能因冷藏庫內溫度不均一而使飲料的一部分或全部被冷凍。因此,在飲料的至少一部分遭冷凍後,融解了冷凍部分的一部分或全部後再飲食之容器包裝飲料,於融解後亦可保持製品價值係一重要的課題。 In order to resist the heat, the drink is often frozen and then consumed. In order to meet such demands, a variety of products that are ready to be consumed while being slowly melted together with the container have been sold. Further, even in the case where freezing is not expected, a part or all of the beverage may be frozen due to temperature unevenness in the refrigerator. Therefore, after at least a part of the beverage is frozen, it is an important subject to preserve the value of the product after melting, after melting part or all of the frozen portion and then packaging the beverage.

目前已知特別是低卡路里、低糖度的飲料,於夏季補 給水份時,可無需在意攝取到多餘的卡路里而大口飲用,且由於具有低滲透壓,於融解時較少發生經時性的風味變化。 At present, especially low-calorie, low-sugar drinks are known to be supplemented in summer. When water is supplied, it is possible to drink large amounts without having to take extra calories, and because of the low osmotic pressure, a temporal change in flavor is less likely to occur during melting.

預計進行冷凍之先前已提案的飲食品,可舉出例如專利文獻1中已提案之藉由進行冷凍使飲料均勻地含有細微的冰結晶,同時具有柔軟且滑順的口感,於室溫或冷藏狀態下可以液體狀態直接飲用的冰沙狀飲料。該冰沙狀飲料,自冷凍庫取出後即使經過長時間,亦可由PET容器的飲用口直接飲用。為了製成如該等飲料之PET瓶裝飲料,於該文件1中記載包含含有選自葡萄糖、麥芽糖、糊精以及糖醇之一種以上的糖類、果膠以及大豆多糖類此二者之多糖類系安定劑,且該等之摻混量係滿足特定條件之組成。 The foods and beverages which have been previously proposed to be frozen are, for example, disclosed in Patent Document 1, which allows the beverage to uniformly contain fine ice crystals while being frozen, and has a soft and smooth texture at room temperature or refrigerated. A smooth drink that can be directly consumed in a liquid state. The smoothie-like beverage can be directly consumed from the drinking port of the PET container even after a long period of time after being taken out of the freezer. In order to produce a PET bottled beverage of such a beverage, the document 1 contains a polysaccharide system containing one or more sugars, pectins, and soybean polysaccharides selected from the group consisting of glucose, maltose, dextrin, and sugar alcohol. Stabilizer, and the blending amount is a composition that satisfies specific conditions.

專利文獻2則提案含有含澱粉糖之糖類,且糖類的Dextrose Equivalent(DE)值(葡萄糖當量值)、飲料的可溶性固體份%、飲料的黏度均滿足特定條件之冰沙狀飲料用組成物。 Patent Document 2 proposes a composition for a smoothie-like beverage containing a sugar containing a starch sugar, and a Dextrose Equivalent (DE) value (glucose equivalent value) of the saccharide, a soluble solid fraction of the beverage, and a viscosity of the beverage satisfying specific conditions. .

專利文獻3則提案含有為了防止因冷凍造成比重差沈澱的黏性食材以及黏性材料,與為了獲得藉由小核形成冰結晶的食材,且可於常溫下進行流通,較先前的常溫流通形式的冷飲具有更佳品質之冷飲。 Patent Document 3 proposes a cohesive food material and a viscous material which are precipitated in order to prevent a difference in specific gravity due to freezing, and a food material which is formed by ice crystallization in a small nucleus and which can be circulated at a normal temperature, which is a conventional room temperature circulation form. The cold drink has a better quality cold drink.

市售品之冷凍用的酸性乳性飲料,已知有例如含有大豆多糖類與果膠之商品名為「冰晶冰沙葡萄」(SANGARIA公司製),及含有大豆多糖類之商品名為 「冷凍後好喝的可爾必思」(可爾必思公司製)。 For example, the so-called soy polysaccharides and pectin are commercially available under the trade name "Ice Crystal Smoothie Grape" (manufactured by SANGARIA Co., Ltd.) and the trade name containing soybean polysaccharides. "Calbes that is good after freezing" (made by Calpis).

然而,非專利文獻1中記載,長時間冷凍保存牛乳時,乳蛋白質會不安定並生成沈澱。一般而言,乳性飲料等所含之乳蛋白質,會因為pH的影響與長期保存而產生沈澱、凝集等,出現安定性的問題。該等乳蛋白質之安定性,與抑制乳蛋白質與其他成分的凝集之技術,有例如非專利文獻2中,已提案使用具有增黏性與高水合性之HM果膠、CMC、大豆多糖類等高分子化合物。另外,該文件中亦記載最適合HM果膠的pH為3.7~4.2、最適合大豆多糖類的pH為3.3~3.7,及大豆多糖類係以較果膠為低的pH下作用。 However, Non-Patent Document 1 discloses that when milk is stored frozen for a long period of time, the milk protein is unstable and precipitates. In general, milk proteins contained in milk beverages and the like may cause precipitation and aggregation due to the influence of pH and long-term storage, and there is a problem of stability. For example, in Non-Patent Document 2, HM pectin having a viscosity-increasing property and high hydration property, CMC, soybean polysaccharide, etc. have been proposed for the stability of the milk protein and the technique for inhibiting the aggregation of the milk protein and other components. Polymer compound. In addition, the document also states that the pH optimum for HM pectin is 3.7 to 4.2, the pH optimum for soybean polysaccharides is 3.3 to 3.7, and the soybean polysaccharide is used at a lower pH than pectin.

專利文獻4中,提案有於長時間保存時,實質上不會產生凝集、沈澱,具優異風味之保存安定性良好的含有乳的酸性乳飲料之製造方法,係使用大豆多糖類以及果膠。 Patent Document 4 proposes a method for producing a milk-containing acidic milk beverage which does not substantially cause aggregation or precipitation during long-term storage, and which has excellent flavor and good storage stability, and uses soybean polysaccharides and pectin.

先前技術文件 Prior technical document 專利文獻 Patent literature

專利文獻1:特開2007-330216號公報 Patent Document 1: JP-A-2007-330216

專利文獻2:特開2008-11835號公報 Patent Document 2: JP-A-2008-11835

專利文獻3:特開平11-155490號公報 Patent Document 3: Japanese Laid-Open Patent Publication No. Hei 11-155490

專利文獻4:特開2001-190254號公報 Patent Document 4: JP-A-2001-190254

非專利文獻 Non-patent literature

非專利文獻1:系列<食品科學>乳科學,(股份有 限)朝倉書店,1996年3月10日發行,p.52 Non-Patent Document 1: Series <Food Science> Milk Science, (There are shares Limited) Asakura Bookstore, issued on March 10, 1996, p.52

非專利文獻2:最新.軟性飲料,(股份有限)光琳,平成15年9月30日發行,p.367-368 Non-Patent Document 2: Latest. Soft drink, (limited stock) Guanglin, issued on September 30, 2005, p.367-368

根據本發明團隊之研究,已得知即使於冷凍、融解後飲用之飲料中,於低糖度的酸性乳性飲料,由於融解後產生離水現象,外觀有顯著變化,而喪失作為成果之製品價值。另外已知該現象係酸性乳性飲料的卡路里愈低時愈容易發生。進而,已知一旦發生過離水現象之該酸性乳性飲料,即使之後搖盪容器使乳蛋白質分散,亦會經時性地再度發生離水現象。 According to the research of the team of the present invention, it has been found that even in the beverages which are consumed after freezing and melting, the acidic milk beverage having a low sugar content has a significant change in appearance due to the phenomenon of water separation after melting, and the value of the product as a result is lost. It is also known that this phenomenon is more likely to occur when the calorie of the acidic milk beverage is lower. Further, it is known that once the acidic milk beverage has undergone the phenomenon of water detachment, even if the container is shaken afterwards to disperse the milk protein, the water detachment phenomenon reoccurs over time.

本發明之課題係提供一種可有效抑制特定低糖度的酸性乳性飲料於冷凍、融解後所產生之離水現象,且具有飲用時優良外觀之酸性乳性飲料及其製造方法。 An object of the present invention is to provide an acidic milk beverage which can effectively suppress the water detachment phenomenon of an acidic milk beverage having a specific low sugar content after freezing and melting, and which has an excellent appearance at the time of drinking and a method for producing the same.

本發明之另一課題,係提供一種可有效抑制特定低糖度的酸性乳性飲料於冷凍、融解後所產生之離水現象,飲用時具有優良外觀,且低卡路里之酸性乳性飲料。 Another object of the present invention is to provide an acidic milk beverage which has an excellent appearance and a low calorie when it is effective in suppressing the phenomenon of water separation caused by freezing and melting of an acidic milk beverage having a specific low sugar content.

本發明之其他課題,係提供一種可有效抑制特定低糖度的酸性乳性飲料,於冷凍、融解後產生離水現象之酸性乳性飲料的抑制離水之方法。 Another object of the present invention is to provide a method for suppressing water detachment of an acidic milk beverage which can effectively suppress a specific low sugar content and which causes a water-repellent phenomenon after freezing and melting.

根據本發明,係提供一種酸性乳性飲料,其係為了冷凍、融解後飲食之酸性乳性飲料, 該飲料係含有乳、大豆多糖類以及水,無脂乳固體份量係0.1~1.0質量%,糖度係0.5~1.7(°Bx),且pH為3.6~4.2,係將該飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲食之酸性乳性飲料(以下,有時略稱作本發明之飲料)。 According to the present invention, there is provided an acidic milk beverage which is an acidic milk beverage for a diet after freezing and melting. The beverage contains milk, soybean polysaccharides and water, the non-fat milk solids amount is 0.1 to 1.0% by mass, the sugar content is 0.5 to 1.7 (°Bx), and the pH is 3.6 to 4.2, and at least a part of the beverage is frozen. After that, a part or all of the frozen portion is melted and the acidic milk beverage (hereinafter, abbreviated as the beverage of the present invention).

另外根據本發明,提供一種本發明飲料的製造方法,其係為了冷凍、融解後飲食之酸性乳性飲料之製造方法, 該方法係包含準備含有乳、大豆多糖類以及水之原材料之步驟、混合該原材料之步驟以及將所得飲料之pH調整為3.6~4.2之步驟,其特徵係於準備該原材料之步驟中,使所得飲料之無脂乳固體份量成為0.1~1.0質量%之範圍,且使糖度成為0.5~1.7(°Bx)之範圍而調製原材料之組成。 Further, according to the present invention, there is provided a method for producing a beverage of the present invention, which is a method for producing an acidic milk beverage for a diet after freezing and melting, The method comprises the steps of preparing a raw material containing milk, soybean polysaccharides and water, the step of mixing the raw materials, and the step of adjusting the pH of the obtained beverage to 3.6 to 4.2, which is characterized in that the step of preparing the raw material is obtained. The fat-free milk solid content of the beverage is in the range of 0.1 to 1.0% by mass, and the composition of the raw material is prepared by setting the sugar content to a range of 0.5 to 1.7 (°Bx).

進而根據本發明,提供一種酸性乳性飲料之抑制離水方法,其係抑制將含有乳以及水,糖度為0.5~1.7(°Bx)之酸性乳性飲料的至少一部分冷凍後,因融解了冷凍部分的一部分或全部而產生之離水現象之方法, 製造該酸性乳性飲料時,其特徵係準備含有乳、大豆多糖類以及水之原材料、混合準備之原材料,以及將所得混合物之pH調整為3.6~4.2,且使無脂乳固體份量成為0.1~1.0質量%而調製該原材料之組成。 Further, according to the present invention, there is provided a method for inhibiting water detachment of an acidic milk beverage, which comprises inhibiting at least a part of an acidic milk beverage containing milk and water and having a sugar content of 0.5 to 1.7 (° Bx), thereby melting the frozen portion Part or all of the method of water separation, When the acidic milk beverage is produced, it is characterized in that a raw material containing milk, soybean polysaccharides, and water, and a raw material prepared by mixing are prepared, and the pH of the obtained mixture is adjusted to 3.6 to 4.2, and the solid content of the non-fat milk is 0.1 to 0.1. The composition of the raw material was prepared by 1.0% by mass.

進而再根據本發明,提供一種酸性乳性飲料之使用, 其係為了將飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲食之酸性乳性飲料,一種酸性乳性飲料之使用, 該酸性乳性飲料係含有乳、大豆多糖類以及水,無脂乳固體份量係0.1~1.0質量%,糖度係0.5~1.7(°Bx),且pH為3.6~4.2。 Further in accordance with the present invention, there is provided an use of an acidic milk beverage, An acidic milk-based beverage, an acidic milk-based beverage, for use in a diet in which at least a portion of the beverage is frozen, and then a part or all of the frozen portion is melted. The acidic milk beverage contains milk, soybean polysaccharides and water, and the fat-free milk solid content is 0.1 to 1.0% by mass, the sugar content is 0.5 to 1.7 (°Bx), and the pH is 3.6 to 4.2.

另外根據本發明,提供一種酸性乳性飲料之飲食方法,其係將含有乳、大豆多糖類以及水,無脂乳固體份量係0.1~1.0質量%,糖度係0.5~1.7(°Bx),且pH為3.6~4.2之酸性乳性飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲食。 Further, according to the present invention, there is provided a method for eating an acidic milk beverage comprising milk, soybean polysaccharides and water, the fat-free milk solid portion is 0.1 to 1.0% by mass, and the sugar content is 0.5 to 1.7 (°Bx), and At least a part of the acidic milk beverage having a pH of 3.6 to 4.2 is frozen, and then a part or all of the frozen portion is melted and then eaten.

由於本發明之飲料採用上述構成,無關乎其係含有乳以及水之特定低糖度的酸性乳性飲料,將飲料的至少一部分進行冷凍後,可有效抑制將冷凍部分的一部分或全部融解後產生的離水現象,且於具有飲用時之優良外觀。因此,可適用於冷凍、融解後飲食之容器包裝,特別係填充於具高透明度容器之酸性乳性飲料製品。 Since the beverage of the present invention adopts the above-described constitution, irrespective of the acid milk beverage having a specific low sugar content containing milk and water, after at least a part of the beverage is frozen, it is possible to effectively suppress the melting of a part or all of the frozen portion. It is a phenomenon of water separation and has an excellent appearance when drinking. Therefore, it can be applied to container packaging for frozen and melted diets, in particular, acidic dairy beverage products filled with containers having high transparency.

由於本發明之製造方法係採用上述構成,而可簡便地獲得本發明之飲料。 Since the manufacturing method of the present invention employs the above configuration, the beverage of the present invention can be easily obtained.

由於本發明之抑制離水方法採用上述構成,於含有乳以及水之特定低糖度的酸性乳性飲料,可有效抑制冷凍後因融解所產生的離水現象。 Since the method for inhibiting water separation according to the present invention employs the above-described constitution, it is possible to effectively suppress the phenomenon of water detachment due to melting after freezing in an acidic milk beverage having a specific low sugar content containing milk and water.

[圖1]係實施例1~3以及比較例1~3中調製之PET寶特瓶包裝酸性乳性飲料之外觀照片。 Fig. 1 is a photograph showing the appearance of a PET bottle packaged acidic milk beverage prepared in Examples 1 to 3 and Comparative Examples 1 to 3.

以下,進而詳細說明本發明。 Hereinafter, the present invention will be described in detail.

本發明之飲料係使用於將飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲用此一飲食方式之酸性乳性飲料,係含有乳、大豆多糖類以及水。 The beverage of the present invention is used to freeze at least a part of the beverage, and then melt a part or all of the frozen portion to drink the acidic milk beverage of the diet, which contains milk, soybean polysaccharides and water.

此處,將飲料的至少一部分冷凍,係指使本發明之飲料,飲料整體呈現為完全冷凍的狀態,或半冷凍的狀態。為了達成該狀態,可使本發明的飲料處於凝固點以下的溫度,若於平常的大氣壓,一般為0℃以下,較佳為藉由保持於0~-20℃的溫度範圍進行,且藉由調整該溫度與維持時間,可達成前述的狀態。另外,融解冷凍部分的一部分,亦即,融解完全冷凍狀態或半冷凍狀態的冷凍物的一部分,係指具有融解部分與未完全融解部分,例如製成為冰沙狀。 Here, freezing at least a part of the beverage means that the beverage of the present invention, the whole beverage, is in a state of being completely frozen, or a state of being semi-frozen. In order to achieve this state, the beverage of the present invention can be brought to a temperature below the freezing point, and is usually 0 ° C or less at a normal atmospheric pressure, preferably maintained at a temperature range of 0 to -20 ° C, and is adjusted by This temperature and the maintenance time can achieve the aforementioned state. Further, melting a part of the frozen portion, that is, melting a part of the frozen product in a completely frozen state or a semi-frozen state, means having a melted portion and an incompletely melted portion, for example, made into a smoothie.

本發明中使用之乳類,可為來自動物或植物的任一種乳類。例如可使用牛乳、山羊乳、羊乳、馬乳等獸乳、豆漿等植物乳,一般係使用牛乳。該等乳類可單獨或以2種以上的混合物形式使用。另外,亦可使用利用乳酸菌與比菲德士菌等微生物發酵後的發酵乳。 The milk used in the present invention may be any type of milk derived from an animal or a plant. For example, vegetable milk such as cow's milk, goat's milk, goat's milk, horse's milk, and the like may be used, and cow's milk is generally used. These milks may be used singly or in the form of a mixture of two or more. Further, fermented milk obtained by fermenting a lactic acid bacterium and a microorganism such as F. faecalis may also be used.

並未特別限制乳類的形態,可舉出例如全脂乳、脫脂乳、乳清、乳蛋白濃縮物,另外,亦可使用還原自粉乳與濃縮乳的乳類。 The form of the milk is not particularly limited, and examples thereof include whole milk, skim milk, whey, and milk protein concentrate, and milks reduced from powdered milk and concentrated milk may be used.

本發明飲料中乳類的含有比例,無脂乳固體份量為0.1~1.0質量%。其下限較佳為0.2質量%,更佳為0.25質量%。另其上限較佳為0.6質量%,更佳為0.4質量%。乳類的含有比例當無脂乳固體份量未達0.1質量%時,可能會降低做為乳性飲料的風味,超過1.0質量%時則有可能產生乳蛋白質沈澱與凝集。 The content of the milk in the beverage of the present invention is 0.1 to 1.0% by mass in the solid content of the non-fat milk. The lower limit thereof is preferably 0.2% by mass, more preferably 0.25% by mass. Further, the upper limit is preferably 0.6% by mass, more preferably 0.4% by mass. When the content of the milk-free milk is less than 0.1% by mass, the flavor of the milky beverage may be lowered, and when it exceeds 1.0% by mass, milk protein precipitation and aggregation may occur.

使用於本發明之大豆多糖類,係可使用已知為乳蛋白質的安定化劑者,一般係可使用自大豆製品製造過程中副產物之豆腐渣(纖維狀的榨漿後的豆渣)所萃取之多糖類,係來自所含之半乳糖醛酸的羧基於酸性環境下帶有負電荷者。市售品可舉出例如商品名為「SM-1200」(三榮源F.F.I(股份有限)製)。 As the soybean polysaccharide used in the present invention, a stabilizer known as milk protein can be used, and it can be generally extracted from bean curd (fibrous soy pulp) which is a by-product of the soybean product manufacturing process. The polysaccharide is derived from a carboxyl group containing galacturonic acid which is negatively charged in an acidic environment. The commercial item is, for example, a product name "SM-1200" (San Fon-yeon F.F.I (share limited) system).

本發明飲料中,大豆多糖類的含有比例可為了獲得本發明效果,因應乳的含量比例等而適當地選擇,一般以使用飲料全量中的0.01~0.5質量%的範圍為佳。 In the beverage of the present invention, the content ratio of the soybean polysaccharides can be appropriately selected in order to obtain the effect of the present invention, and is preferably in the range of 0.01 to 0.5% by mass based on the total amount of the beverage.

並未特別限制使用於本發明中的水,例如可使用離子交換水。 Water used in the present invention is not particularly limited, and for example, ion-exchanged water can be used.

本發明飲料中水的含有比例,可使其他成分的含有比例,及後述之糖度以及pH值為期望範圍而適宜地選擇。 The content ratio of water in the beverage of the present invention can be appropriately selected by setting the ratio of the other components, the sugar content and the pH value described later to a desired range.

本發明飲料中除上述之必須成分以外,可於不損及本發明效果、所規定的物性之範圍內,因應需要而使其適當 地含有其他成分。其他成分可舉出例如為了調整pH的酸味料、果汁、糖度調整劑、大豆多糖類以外的乳蛋白質安定化劑、高甜度甜味料、香料、色素。 In addition to the above-mentioned essential components, the beverage of the present invention can be appropriately adapted to the extent that the effects of the present invention and the specified physical properties are not impaired. The ground contains other ingredients. Examples of the other components include a sour material for adjusting pH, a fruit juice, a sugar content adjuster, a milk protein stabilizer other than soybean polysaccharides, a high-intensity sweetener, a flavor, and a coloring matter.

酸味料可舉出例如乳酸、檸檬酸、蘋果酸、酒石酸、乙酸、植物酸、葡萄糖酸、琥珀酸、反丁烯二酸等有機酸或其鹽、磷酸等無機酸或其鹽。 The sour material may, for example, be an organic acid such as lactic acid, citric acid, malic acid, tartaric acid, acetic acid, vegetable acid, gluconic acid, succinic acid or fumaric acid or a salt thereof, or an inorganic acid such as phosphoric acid or a salt thereof.

果汁可舉出例如柳橙、檸檬、葡萄柚等柑橘系果汁、葡萄、桃子、蘋果、香蕉等之果汁。 Examples of the fruit juice include citrus juices such as orange, lemon, and grapefruit, and juices such as grapes, peaches, apples, and bananas.

糖度調整劑可舉出例如蔗糖、麥芽糖、果糖、葡萄糖、果糖葡萄糖液糖、寡糖等糖類,及赤藻糖醇、麥芽糖醇、木糖醇等糖醇,及難消化性的糊精、洋菜等食物纖維。 Examples of the sugar content adjusting agent include sugars such as sucrose, maltose, fructose, glucose, fructose glucose liquid sugar, and oligosaccharides, and sugar alcohols such as erythritol, maltitol, and xylitol, and indigestible dextrin and foreign countries. Food fiber such as vegetables.

大豆多糖類以外的乳蛋白質安定化劑可舉出例如HM果膠、羧甲基纖維素(CMC)、結蘭膠、關華豆膠、三仙膠、阿拉伯膠。由於該等安定化劑,有時會對本發明飲料中期望的效果造成不良影響,使其含於飲料中時,其量以較少為佳,或者以不含有更佳。 The milk protein stabilizer other than the soybean polysaccharide may, for example, be HM pectin, carboxymethyl cellulose (CMC), yam, gum, gum, gum arabic or gum arabic. Such stabilizers may adversely affect the desired effect in the beverage of the present invention, and when it is contained in a beverage, the amount thereof is preferably less or less.

高甜度甜味料可舉出例如蔗糖素、甜菊、醋磺內酯鉀、糖精鈉、阿斯巴甜、甘草素、甘草酸二鉀、索馬甜。 The high-intensity sweetener may, for example, be sucralose, stevia, acesulfame lactone, sodium saccharin, aspartame, glycyrrhizin, dipotassium glycyrrhizinate or thaumatin.

本發明飲料之糖度係0.5~1.7(°Bx),其上限以1.5(°Bx)為佳,更佳係1.2(°Bx)。糖度超過1.7(°Bx)時,與飲料的pH值無關,難以發生冷凍、融解後的離水現象。 The sugar content of the beverage of the present invention is 0.5 to 1.7 (°Bx), and the upper limit is preferably 1.5 (°Bx), more preferably 1.2 (°Bx). When the sugar content exceeds 1.7 (°Bx), regardless of the pH of the beverage, it is difficult to cause water detachment after freezing and melting.

本發明中糖度係於20℃時糖用屈折計的表示度數, 例如意指使用數位式屈折計Rx-5000(Atago公司製)於20℃所測定之本發明飲料中可溶性固體份量。 In the present invention, the degree of sugar is expressed at 20 ° C, and the degree of expression of the sugar is used. For example, it means the amount of soluble solids in the beverage of the present invention measured at 20 ° C using a digital refractive instrument Rx-5000 (manufactured by Atago).

本發明飲料的pH值為3.6~4.2,其上限以4.0為佳。pH值超過4.2時,可抑制飲料的冷凍、融解後的離水現象,但有可能會損及經時性的乳蛋白質的安定性與增加沈澱,不適用為酸性乳性飲料。 The pH of the beverage of the present invention is 3.6 to 4.2, and the upper limit is preferably 4.0. When the pH exceeds 4.2, the phenomenon of water detachment after freezing and melting of the beverage can be suppressed, but the stability and precipitation of the milk protein over time may be impaired, and it is not suitable for an acidic milk beverage.

本發明中pH值之調整,可藉由例如使用酸味料的方法、使用發酵乳的方法、使用果汁的方法、或併用該等方法之方法而進行,若為可達成期望的pH值則無特別限制。酸味料、發酵乳及果汁係可使用於上所述者。 The adjustment of the pH value in the present invention can be carried out, for example, by a method using a sour material, a method using fermented milk, a method using fruit juice, or a method using the same, and if the desired pH is attained, there is no particular limit. Sour materials, fermented milk and fruit juices can be used in the above.

由於本發明飲料係製為低卡路里飲料,以調整各原材料種類以及含有量而控制其熱量為佳。特別係將本發明飲料的熱量控制於6kcal/100ml以下,5kcal/100ml以下特佳。並未特別限制其下限值,一般為1kcal/100ml。 Since the beverage system of the present invention is a low calorie beverage, it is preferred to control the amount of each raw material and the amount thereof to control the amount of heat. In particular, the calorie of the beverage of the present invention is controlled to be 6 kcal/100 ml or less, and particularly preferably 5 kcal/100 ml or less. The lower limit is not particularly limited, and is generally 1 kcal/100 ml.

本發明之飲料以製成填充於容器之酸性乳性飲料為佳。容器可舉出例如玻璃製、聚對酞酸乙二酯(PET)、聚乙烯、聚丙烯等塑膠製、紙製、鋁製、鋼製的密封容器,特別為了容易確認本發明期望的效果,以使用可目視確認本發明飲料之具高透明性的容器為佳。 The beverage of the present invention is preferably made into an acidic milk beverage filled in a container. The container may, for example, be a glass, polyethylene terephthalate (PET), polyethylene, polypropylene or the like, a sealed container made of paper, aluminum or steel, and in particular, in order to easily confirm the desired effect of the present invention, It is preferred to use a container which can visually confirm the high transparency of the beverage of the present invention.

本發明之為了於冷凍、融解後飲食之酸性乳性飲料之製造方法,係包含含有準備乳類、大豆多糖類及水之上述各原材料之步驟。該步驟中,可依據常用方法調製為了使所得飲料的無脂乳固體份量成為0.1~1.0質量%,且獲得之飲料的糖度為0.5~1.7(°Bx)的範圍的原材料之組成。 The method for producing an acidic milk beverage for a diet after freezing and thawing according to the present invention includes a step of preparing each of the above-mentioned raw materials for preparing milk, soybean polysaccharide, and water. In this step, a composition of a raw material in which the amount of the non-fat milk solid content of the obtained beverage is 0.1 to 1.0% by mass and the sugar content of the obtained beverage is in the range of 0.5 to 1.7 (°Bx) can be prepared according to a usual method.

本發明之為了於冷凍、融解後飲食之酸性乳性飲料之製造方法,係包含上述之準備原材料的步驟、混合已準備之原材料之步驟,以及將所的飲料之pH值調整為3.6~4.2之步驟。該等混合、pH值之調整係可依據周知的方法進行。 The method for producing an acidic milk beverage for a diet after freezing and thawing according to the present invention includes the steps of preparing the raw material described above, mixing the prepared raw materials, and adjusting the pH of the beverage to 3.6 to 4.2. step. These mixing and pH adjustments can be carried out according to well-known methods.

本發明製造方法中對於所得之飲料,可進行一般的均質化處理及殺菌處理。 In the production method of the present invention, the obtained beverage can be subjected to general homogenization treatment and sterilization treatment.

均質化處理一般可使用均質機進行。並未特別限制均質化條件,可舉出較佳以溫度為5~25℃,壓力為10~50Mpa之條件。均質化處理可於殺菌處理之前或之後進行,亦可於殺菌前後均進行。 Homogenization can generally be carried out using a homogenizer. The homogenization conditions are not particularly limited, and those having a temperature of 5 to 25 ° C and a pressure of 10 to 50 MPa are preferred. The homogenization treatment can be carried out before or after the sterilization treatment, or both before and after sterilization.

殺菌處理可以例如65℃,10分鐘及具有同等以上的殺菌效果之加熱處理。並未特別限制殺菌處理的方法,一般可採用平板式殺菌、管式殺菌、軟罐頭殺菌、批次殺菌、自動高溫高壓殺菌等方法。另外,殺菌處理可於均質化處理之前或之後進行,亦可於該步驟之前後均進行,或可於填充於容器之前或之後進行,亦可於該步驟之前後均進行。 The sterilization treatment can be, for example, 65 ° C, 10 minutes, and heat treatment having an sterilizing effect equal to or higher. The method of sterilizing treatment is not particularly limited, and generally, flat plate sterilization, tube sterilization, soft can sterilization, batch sterilization, automatic high temperature and high pressure sterilization, and the like can be employed. In addition, the sterilization treatment may be carried out before or after the homogenization treatment, or may be carried out before or after the step, or may be carried out before or after filling in the container, or may be performed before and after the step.

將殺菌處理後之本發明飲料製成容器包裝的酸性乳性飲料之方法,可藉由例如將飲料填充入作為容器的加熱袋,再冷卻填充容器之方法,或將飲料冷卻至適合填充於容器的溫度,無菌填充於經預先洗淨殺菌的容器等方法。 The method for preparing the sterilized beverage of the present invention into a container-packed acidic milk beverage can be carried out by, for example, filling the beverage into a heating bag as a container, cooling the filling container, or cooling the beverage to be suitable for filling the container. The temperature is aseptically filled in a pre-washed sterilized container or the like.

本發明之抑制離水現象之方法,係抑制將含有乳類以及水,糖度為0.5~1.7(°Bx)之酸性乳性飲料的至少一部分 冷凍後,因融解了冷凍部分的一部分或全部而產生之離水現象之方法, 於製造該酸性乳性飲料時,係準備含有乳類、大豆多糖類以及水之原材料、混合準備之原材料,以及調整pH值為3.6~4.2,且使無脂乳固體份量成為0.1~1.0質量%而調製該原材料之組成。 The method for inhibiting water detachment of the present invention inhibits at least a part of an acidic milk beverage containing milk and water and having a sugar content of 0.5 to 1.7 (° Bx). a method of separating water caused by melting a part or all of the frozen portion after freezing, In the production of the acidic milk beverage, the raw materials containing the milk, the soybean polysaccharide, and the water are prepared, and the raw materials prepared by mixing are adjusted, and the pH is adjusted to 3.6 to 4.2, and the solid content of the non-fat milk is 0.1 to 1.0% by mass. The composition of the raw material is modulated.

前述之酸性乳性飲料之各原料,可使用上述本發明飲料中所說明者。特別以低卡路里飲料為佳,例如以選擇使用可使酸性乳性飲料之熱量控制於5kcal/100ml以下的原材料為佳。並未特別限制其下限值,一般為1kcal/100ml。 The raw materials of the above-described acidic milk beverage can be used as described in the above-described beverage of the present invention. In particular, it is preferable to use a low calorie beverage, for example, a raw material which can control the calorie of the acidic milk beverage to 5 kcal/100 ml or less. The lower limit is not particularly limited, and is generally 1 kcal/100 ml.

[實施例] [Examples]

以下藉由實施例、比較例以及參考例更詳細說明本發明,但本發明未因此有任何限制。 Hereinafter, the present invention will be described in more detail by way of Examples, Comparative Examples, and Reference Examples. However, the present invention is not limited thereto.

例中,大豆多糖類可使用商品名「SM-1200」(三榮源F.F.I(股份有限)製),果膠使用了商品名「YM-115-LJ」(三晶(股份有限)製)。另外,均質化處理使用實驗室用均質機(型號15MR,APV殼林公司製),於處理溫度20℃,處理壓力15MPa進行。加熱殺菌採用達到95℃之達溫殺菌。 In the example, the soybean polysaccharide can be used under the trade name "SM-1200" (San F. F. F.I (share limited)), and the pectin uses the trade name "YM-115-LJ" (Sanjing (limited stock) )system). Further, the homogenization treatment was carried out using a laboratory homogenizer (Model 15MR, manufactured by APV Shell Co., Ltd.) at a treatment temperature of 20 ° C and a treatment pressure of 15 MPa. Heat sterilization is achieved by reaching a temperature of 95 ° C.

實施例1 Example 1

於104g的25質量%的還原脫脂乳粉(以下略稱為脫脂乳)中,加入300g之3質量%之大豆多糖類水溶液 (以下略稱為大豆多糖類水溶液),並攪拌至均勻。其次,添加195g的10質量%之檸檬酸水溶液(以下略稱為檸檬酸水溶液)並充分攪拌。接著再使用離子交換水使全量成為9.5kg後,以144g之10質量%之檸檬酸三鈉水溶液(以下略稱為檸檬酸三Na水溶液)調整pH值為4.0。再使用離子交換水使全量成為10kg後進行均質化處理,調製為調合液。加熱殺菌獲得之調合液,得到酸性乳性飲料。將所得之酸性乳性飲料以熱袋包裝法填充於350ml的PET寶特瓶中,再以水冷冷卻至室溫。 300 g of a 3% by mass aqueous solution of soybean polysaccharide is added to 104 g of 25% by mass of reduced skim milk powder (hereinafter abbreviated as skim milk) (hereinafter referred to as a soy polysaccharide aqueous solution), and stirred until uniform. Next, 195 g of a 10% by mass aqueous citric acid solution (hereinafter abbreviated as an aqueous citric acid solution) was added and stirred well. Then, the total amount was 9.5 kg, and the pH was 4.0 with 144 g of a 10% by mass aqueous solution of trisodium citrate (hereinafter abbreviated as a three-Na citric acid solution). Further, ion-exchanged water was used to make the whole amount 10 kg, and then homogenization treatment was carried out to prepare a preparation liquid. The prepared liquid obtained by heat sterilization is obtained to obtain an acidic milk beverage. The obtained acidic milk beverage was filled in a 350 ml PET PET bottle in a hot bag packaging method, and then cooled to room temperature with water cooling.

所得之PET寶特瓶包裝酸性乳性飲料(以下稱為檢體),於-20℃冷凍室冷凍一晚後,於37℃融解,並進行以下之評價。結果示於表1。另外,獲得之酸性乳性飲料的物性值之pH值、糖度、無脂乳固體份量以及熱量(卡路里)亦示於表1中。 The obtained PET PET bottle-packed acidic milk beverage (hereinafter referred to as a sample) was frozen in a freezer at -20 ° C for one night, and then melted at 37 ° C, and the following evaluation was performed. The results are shown in Table 1. Further, the pH value, the sugar content, the fat-free milk solid content, and the calorie (calorie) of the physical properties of the obtained acidic milk beverage are also shown in Table 1.

<評價方法> <Evaluation method> (1)外觀評價 (1) Appearance evaluation

以目視觀察冷凍融解後的檢體。將結果以檢體外觀照片示於圖1。 The specimen after freezing and melting was visually observed. The results are shown in Fig. 1 as a photograph of the appearance of the specimen.

(2)離水度評價 (2) Evaluation of water separation

於獲得檢體之底部至高度1/2的位置,採樣內溶液之酸性乳性飲料,並測定所得內溶液之吸光度A(650nm)。另外,使檢體內溶液充分地分散均勻後,測 定全體內溶液之吸光度B(650nm)。然後利用下述式計算離水度C(%)。 The acidic milk beverage of the solution was sampled at the bottom of the sample to a height of 1/2, and the absorbance A (650 nm) of the obtained internal solution was measured. In addition, after the solution in the sample is sufficiently dispersed, the measurement is performed. The absorbance B (650 nm) of the solution was determined. Then, the water separation degree C (%) was calculated by the following formula.

離水度C(%)=吸光度A/吸光度B×100 Separation degree C (%) = absorbance A / absorbance B × 100

(3)綜合評價 (3) Comprehensive evaluation

依據離水度評價結果,將離水度C為60以上者記作+++,35以上,未達60者記作++,15以上,未達35者記作+,未達15者記作-。且+++~+為合格,-則評價為不合格。 According to the evaluation result of water separation degree, those who have a water C of 60 or more are recorded as +++, 35 or more, those who are less than 60 are recorded as ++, 15 or more, those who are less than 35 are recorded as +, and those who are less than 15 are recorded as - . And +++~+ is qualified, - then the evaluation is unqualified.

實施例2~9 Example 2~9

除了將檸檬酸三Na水溶液的摻混量及脫脂乳的摻混量變更如表1所示,另外,將實施例8及9中調製的檢體的融解溫度變更為5℃,進而,針對實施例4、5、8以及9,使糖度調整為如表1所示量的果糖葡萄糖液糖,在投入脫脂乳之後、大豆多糖類水溶液添加前,進行投入之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地對測定獲得之酸性乳性飲料的物性值以及進行對檢體的評價。結果示於表1及圖1。且,針對外觀評價,雖僅將實施例2及3示於圖1,但實施例4~9的外觀評價結果亦與實施例2及3之任一個相同。 In addition, as shown in Table 1, the blending amount of the citric acid tri-Na aqueous solution and the blending amount of skim milk were changed, and the melting temperature of the sample prepared in Examples 8 and 9 was changed to 5 ° C, and further, In Examples 4, 5, 8 and 9, the fructose glucose liquid sugar was adjusted to the amount shown in Table 1, and was prepared in the same manner as in Example 1 except that the non-fat milk was introduced and the soybean polysaccharide aqueous solution was added before the addition. Acidic milk drinks and samples. The physical property value of the obtained acidic milk beverage and the evaluation of the sample were carried out in the same manner as in Example 1. The results are shown in Table 1 and Figure 1. Further, although the examples 2 and 3 are shown in Fig. 1 for the appearance evaluation, the results of the appearance evaluation of the examples 4 to 9 are the same as those of the examples 2 and 3.

自表1可明確得知,相同糖度且相同無脂乳固體份量時,產生了依賴pH值之冷凍融解後的離水現象發生程度之變化。pH3.6~4.0之實施例1~9中係可有效抑制離水現象,呈現安定狀態。 It can be clearly seen from Table 1 that when the same sugar content and the same fat-free milk solid content are obtained, the degree of occurrence of the water-off phenomenon after the freeze-thaw depending on the pH value is generated. In Examples 1 to 9 of pH 3.6 to 4.0, the phenomenon of water detachment was effectively suppressed and a stable state was exhibited.

比較例1~7 Comparative Example 1~7

除了將檸檬酸三Na水溶液的摻混量及脫脂乳的摻混量變更如表2所示,另外,將比較例7調製的檢體之融解溫度變更為5℃,進而,針對比較例4以及7,使糖度調整為如表2所示量的果糖葡萄糖液糖,在投入脫脂乳之後、大豆多糖類水溶液添加前,進行投入之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地對測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表2及圖1。且,針對外觀評價,雖僅將比較例1~3示於圖1,但比較例4~7的外觀評價結果亦與 比較例1~3之任一個相同。 The mixing amount of the citric acid tri-Na aqueous solution and the blending amount of the skim milk were changed as shown in Table 2, and the melting temperature of the sample prepared in Comparative Example 7 was changed to 5 ° C, and further, Comparative Example 4 and 7. The fructose glucose liquid sugar was adjusted to the amount shown in Table 2, and the acidic milk beverage and the sample were prepared in the same manner as in Example 1 except that the non-fat milk was put in and the soybean polysaccharide liquid solution was added before the addition. . The physical property value of the obtained acidic milk beverage and the sample were evaluated in the same manner as in Example 1. The results are shown in Table 2 and Figure 1. Further, for the appearance evaluation, only Comparative Examples 1 to 3 are shown in Fig. 1, but the evaluation results of Comparative Examples 4 to 7 are also Comparative Examples 1 to 3 were the same.

自表2可明確得知,pH3.2~3.5之比較例1~7,無關乎pH之外的要素係與實施例1~9相同,無法有效抑制離水現象。 As is clear from Table 2, in Comparative Examples 1 to 7 of pH 3.2 to 3.5, the elements other than the pH were the same as those of Examples 1 to 9, and the water detachment phenomenon could not be effectively suppressed.

實施例10 Example 10

除了將檸檬酸三Na水溶液及大豆多糖類水溶液的摻混量變更如表3所示之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表3。且,由於物性值中糖度與無脂乳固體份量與實施例1為相同的結果,而未示於表3。另外,針對外觀評價,與實施例3之外觀評價相同。進而,表3中合併揭示實施例2以及3 之結果。 The acidic milk beverage and the sample were prepared in the same manner as in Example 1 except that the blending amount of the aqueous solution of the citric acid tri Na and the aqueous solution of the soybean polysaccharide was changed as shown in Table 3. The physical property value of the obtained acidic milk beverage was measured in the same manner as in Example 1, and the sample was evaluated. The results are shown in Table 3. Further, since the sugar content and the non-fat milk solid content in the physical property values were the same as those in Example 1, they were not shown in Table 3. In addition, the appearance evaluation was the same as the appearance evaluation of Example 3. Further, the combination of Tables 3 reveals Embodiments 2 and 3. The result.

比較例8 Comparative Example 8

除了將檸檬酸三Na水溶液的摻混量變更如表3所示,及使用3質量%的果膠水溶液(以下略稱為果膠水溶液)來取代大豆多糖類水溶液之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表3。且,由於物性值中糖度與無脂乳固體份量與實施例1為相同的結果而未示於表3。另外,針對外觀評價,與比較例3之外觀評價結果相同。 The same as in Example 1, except that the blending amount of the aqueous solution of citric acid tri-Na was changed as shown in Table 3, and the aqueous solution of pectin (hereinafter abbreviated as a solution of pectin) was used in place of the soybean polysaccharide aqueous solution. The acidic milk beverage and the sample are prepared. The physical property value of the obtained acidic milk beverage was measured in the same manner as in Example 1, and the sample was evaluated. The results are shown in Table 3. Further, since the sugar content and the non-fat milk solid content in the physical property values were the same as those in Example 1, they are not shown in Table 3. Further, the appearance evaluation was the same as the appearance evaluation result of Comparative Example 3.

自表3可明確得知,大豆多糖類水溶液摻混量相異之實施例3與實施例10中,未發現離水現象程度為有意義的差異。另外,使用果膠取代作為安定化劑之大豆多糖類 的比較例8中,發生了液體上半部變為幾乎完全透明的激烈的離水現象。 As is clear from Table 3, in Example 3 and Example 10 in which the blending amounts of the soybean polysaccharide aqueous solution were different, no significant difference in the degree of water separation was found. In addition, the use of pectin to replace soybean polysaccharides as stabilizers In Comparative Example 8, a severe water detachment phenomenon in which the upper half of the liquid became almost completely transparent occurred.

實施例11~15 Example 11~15

除了將檸檬酸三Na水溶液及脫脂乳的摻混量變更如表4所示,另外,針對實施例11及12,使糖度調整為如表4所示量的果糖葡萄糖液糖,在投入脫脂乳之後、大豆多糖類水溶液添加前,進行投入之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表4。且,針對外觀評價,與實施例2及3之任一結果相同。另外,表4中亦合併揭示實施例4及6之結果。 In addition to the change in the blending amount of the aqueous solution of citric acid tri-Na and the skim milk, as shown in Table 4, the sugar content was adjusted to the amount of fructose glucose liquid sugar as shown in Table 4 in Examples 11 and 12, and the skim milk was put in. Then, the acidic milk beverage and the sample were prepared in the same manner as in Example 1 except that the soybean polysaccharide aqueous solution was added before the addition. The physical property value of the obtained acidic milk beverage was measured in the same manner as in Example 1, and the sample was evaluated. The results are shown in Table 4. Further, the appearance evaluation was the same as any of the results of Examples 2 and 3. In addition, the results of Examples 4 and 6 are also disclosed in Table 4.

自表4可明確得知無脂乳固體份量為0.1~0.5之實施例11、12、4及6之間,離水現象程度並無大的差異。而有關無脂乳固體份量為0.6~1.0之實施例13~15,由於伴隨無脂乳固體份量增加亦同時引起糖度增加,雖此一結果具參考價值,但結果可得知發生離水現象之程度並未依賴無脂乳固體份量。 It can be clearly seen from Table 4 that there is no significant difference in the degree of water separation between Examples 11, 12, 4 and 6 in which the solid content of the non-fat milk is from 0.1 to 0.5. In the case of Examples 13 to 15 in which the solid content of the non-fat milk was 0.6 to 1.0, the increase in the sugar content was accompanied by an increase in the solid content of the non-fat milk. Although the result has a reference value, the result can be known to the extent of the phenomenon of water separation. Does not rely on the fat free milk solids.

實施例16,比較例9~11 Example 16, Comparative Example 9-11

除了將檸檬酸三Na水溶液、檸檬酸水溶液及大豆多糖類水溶液的摻混量變更如表5所示,且比較例11係使用依表5所示量之果膠水溶液取代大豆多糖類水溶液之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表5。且,針對外觀評價,與實施例2之外觀評價結果相同。 The blending amount of the aqueous solution of citric acid tri-Na, the aqueous solution of citric acid, and the aqueous solution of soybean polysaccharide was changed as shown in Table 5, and Comparative Example 11 was replaced with an aqueous solution of pectin according to the amount shown in Table 5 in place of the aqueous solution of soybean polysaccharide. The acidic milk beverage and the sample were prepared in the same manner as in Example 1. The physical property value of the obtained acidic milk beverage was measured in the same manner as in Example 1, and the sample was evaluated. The results are shown in Table 5. Further, the appearance evaluation was the same as the appearance evaluation result of Example 2.

自表5可明確得知,糖度0.5(°Bx)之實施例16並未發生離水現象。另外,糖度1.8(°Bx)之比較例10無關乎pH值為相當低的3.2並未發生離水現象。另外,比較例11無關乎使用了果膠,未發生離水現象。 It can be clearly seen from Table 5 that the water-repellent phenomenon did not occur in Example 16 having a sugar content of 0.5 (°Bx). In addition, Comparative Example 10 having a sugar content of 1.8 (°Bx) did not cause a water separation phenomenon irrespective of a pH value of 3.2. In addition, Comparative Example 11 did not use pectin, and no water leaving phenomenon occurred.

實施例17 Example 17

除了將檸檬酸三Na水溶液及檸檬酸水溶液的摻混量變更如表6所示之外,與實施例1相同地調製酸性乳性飲料以及檢體。與實施例1相同地測定獲得之酸性乳性飲料的物性值以及對檢體進行評價。結果示於表6。且,針對外觀評價,與實施例2之外觀評價結果相同。另外,表6中亦合併揭示實施例2及16之結果。 An acidic milk beverage and a sample were prepared in the same manner as in Example 1 except that the blending amount of the aqueous solution of citric acid tri-Na and the aqueous solution of citric acid was changed as shown in Table 6. The physical property value of the obtained acidic milk beverage was measured in the same manner as in Example 1, and the sample was evaluated. The results are shown in Table 6. Further, the appearance evaluation was the same as the appearance evaluation result of Example 2. In addition, the results of Examples 2 and 16 are also disclosed in Table 6.

自表6可明確得知,糖度及檸檬酸酸度相異之實施例2、16及17之間並未發現離水現象程度具有大的差異。 It can be clearly seen from Table 6 that there is no significant difference in the degree of water separation between Examples 2, 16, and 17 in which the sugar content and the citric acidity are different.

Claims (7)

一種酸性乳性飲料,其係為了冷凍、融解後飲食之酸性乳性飲料,該飲料係含有乳、大豆多糖類以及水,無脂乳固體份量係0.1~1.0質量%,糖度係0.5~1.7(°Bx),且pH為3.6~4.2,係將該飲料的至少一部分進行冷凍後,再將冷凍部分的一部分或全部融解後飲食。 An acidic milk beverage, which is an acidic milk beverage for freezing and melting, the beverage contains milk, soybean polysaccharides and water, and the fat-free milk solid content is 0.1 to 1.0% by mass, and the sugar content is 0.5 to 1.7 ( °Bx), and the pH is 3.6 to 4.2, after at least a part of the beverage is frozen, and then part or all of the frozen portion is melted and then eaten. 如請求項1之飲料,其中大豆多糖類之含有比例,係飲料全量中之0.01~0.5質量%。 The beverage according to claim 1, wherein the content of the soybean polysaccharide is 0.01 to 0.5% by mass based on the total amount of the beverage. 如請求項1或2之飲料,其熱量係5kcal/100ml以下。 The beverage of claim 1 or 2 has a calorie of 5 kcal/100 ml or less. 如請求項1或2之飲料,其係實際上未含有HM果膠。 A beverage according to claim 1 or 2 which does not actually contain HM pectin. 一種如請求項1之酸性乳性飲料之製造方法,其係為了冷凍、融解後飲食之酸性乳性飲料之製造方法,該方法係包含準備含有乳、大豆多糖類以及水之原材料之步驟、混合該原材料之步驟以及將所得飲料之pH調整為3.6~4.2之步驟,其特徵係於準備該原材料之步驟中,使所得飲料之無脂乳固體份量成為0.1~1.0質量%之範圍,且使糖度成為0.5~1.7(°Bx)之範圍而調製原材料之組成。 A method for producing an acidic milk beverage according to claim 1, which is a method for producing an acidic milk beverage for a diet after freezing and thawing, the method comprising the steps of: preparing a raw material containing milk, soybean polysaccharides and water; The step of the raw material and the step of adjusting the pH of the obtained beverage to 3.6 to 4.2 are characterized in that in the step of preparing the raw material, the fat-free milk solid content of the obtained beverage is in the range of 0.1 to 1.0% by mass, and the sugar content is obtained. The composition of the raw material is prepared by the range of 0.5 to 1.7 (°Bx). 一種抑制酸性乳性飲料之離水現象之方法,其係抑制將含有乳以及水,糖度為0.5~1.7(°Bx)之酸性乳性飲料的至少一部分冷凍後,因融解了冷凍部分的一 部分或全部而產生之離水現象之方法,製造該酸性乳性飲料時,其特徵係準備含有乳、大豆多糖類以及水之原材料,混合準備之原材料,以及將所得混合物之pH調整為3.6~4.2,且使無脂乳固體份量成為0.1~1.0質量%而調製該原材料之組成。 The invention relates to a method for inhibiting the water-discharging phenomenon of an acidic milk beverage, which comprises inhibiting at least a part of an acidic milk beverage containing milk and water and having a sugar content of 0.5 to 1.7 (°Bx), and melting the frozen portion Part or all of the method of separating water, when the acidic milk beverage is produced, it is characterized by preparing raw materials containing milk, soybean polysaccharides and water, mixing the prepared raw materials, and adjusting the pH of the obtained mixture to 3.6 to 4.2. And the composition of the raw material is prepared by setting the solid content of the non-fat milk to 0.1 to 1.0% by mass. 如請求項6之抑制離水現象之方法,其係使該酸性乳性飲料的熱量成為5kcal/100ml以下而調製原材料之組成。 The method of suppressing the phenomenon of water detachment according to claim 6, wherein the heat of the acidic milk beverage is 5 kcal/100 ml or less to prepare a composition of the raw material.
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JP2005323530A (en) * 2004-05-13 2005-11-24 Sanei Gen Ffi Inc Acidic milk beverage

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