TWI655264B - Rework device, rework method, and rework solution for electronic device - Google Patents

Rework device, rework method, and rework solution for electronic device Download PDF

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TWI655264B
TWI655264B TW103127136A TW103127136A TWI655264B TW I655264 B TWI655264 B TW I655264B TW 103127136 A TW103127136 A TW 103127136A TW 103127136 A TW103127136 A TW 103127136A TW I655264 B TWI655264 B TW I655264B
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rework
solution
electronic device
limonene
group
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TW103127136A
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TW201606035A (en
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黃家偉
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美商3M新設資產公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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Abstract

本案關於一種電子裝置之重工裝置、重工方法以及重工溶液,其中重工裝置包含釋放元件,其包括相互連通之釋放部及容置空間,重工溶液容置於容置空間中並透過釋放部釋放至電子裝置以黏著層黏合之第一表面及第二表面之間,使第一表面和第二表面可分離而進行重工,而重工溶液包含萜類成分及溶劑,其中萜類成分係選自檸檬烯,溶劑係選自乙醇,而兩者比例為1:9至7:3。 The present invention relates to a rework device, a rework method, and a rework solution for an electronic device, wherein the rework device includes a release member including a release portion and an accommodation space that communicate with each other, and the rework solution is accommodated in the accommodating space and released to the electron through the release portion. The device is bonded between the first surface and the second surface by the adhesive layer, so that the first surface and the second surface are separable for rework, and the heavy work solution comprises a terpenoid component and a solvent, wherein the terpene component is selected from the group consisting of limonene, a solvent It is selected from ethanol and the ratio of the two is 1:9 to 7:3.

Description

電子裝置之重工裝置、重工方法以及重工溶液 Heavy equipment of electronic device, heavy work method and heavy work solution

本發明係關於一種電子裝置之重工裝置、重工方法以及應用於該重工裝置及重工方法之重工溶液,尤指一種可使電子裝置已藉一黏著層黏合之第一、第二表面分離的電子裝置重工裝置、重工方法以及重工溶液。 The present invention relates to an electronic device rework device, a heavy work method, and a heavy work solution applied to the heavy work device and the heavy work method, and more particularly to an electronic device capable of separating the first and second surfaces of the electronic device that have been bonded by an adhesive layer. Heavy equipment, heavy work methods, and heavy work solutions.

隨著科技的進步,電子裝置亦日新月異。舉例而言,電子裝置的操作介面自傳統的機械式按鍵操控,突破性地發展至現今常見的觸控式螢幕。 With the advancement of technology, electronic devices are changing with each passing day. For example, the operation interface of the electronic device has been developed from the traditional mechanical button control to the common touch screen.

為了實現觸碰式螢幕的可能,觸控式螢幕的玻璃上多佈有感應線路,且此種觸控式螢幕的玻璃價格昂貴,因此,於組裝觸控式電子裝置若有失誤時,例如:觸控式螢幕的玻璃未妥善安裝於框架或顯示面板上時,必須進行重工。 In order to realize the possibility of a touch screen, the touch screen has a plurality of sensing lines on the glass, and the glass of the touch screen is expensive. Therefore, if there is a mistake in assembling the touch type electronic device, for example: When the glass of the touch screen is not properly mounted on the frame or display panel, it must be reworked.

中華民國專利公開號200926470之文獻提及一種觸控式顯示裝置之重工方法。其係使用以接合顯示面板及觸控面板之積層膠帶一端凸出顯示面板,並預留於一切線,如有重工需要,則沿著積層膠帶實質上垂直於長邊且遠離主動區域之方向拉動其凸出於顯示面板之部分,以將積層膠帶自顯示面板及觸控面板之間移出而分離觸控面板及顯示面板。然而,此種重工方式無法避免積層膠帶斷裂而無法進行重工之問題。 The document of the Republic of China Patent Publication No. 200926470 refers to a method of reworking a touch display device. The utility model uses a laminated tape which is used to join the display panel and the touch panel to protrude the display panel at one end, and is reserved for all lines. If necessary for rework, the laminated tape is pulled substantially perpendicular to the long side and away from the active area. It protrudes from the display panel to separate the touch panel and the display panel by removing the laminated tape from the display panel and the touch panel. However, this type of heavy work cannot avoid the problem that the laminated tape is broken and cannot be reworked.

韓國專利編號KR20100115529之文獻述及利用低溫氣體進行重工之方 式,其係於兩被分離之表面間提供一間隙,並於間隙中導人低溫氣體以降低黏著劑的黏性,從而進行重工。然而,當溫度降低時,觸控式玻璃、框架或顯示面板可能因無法承受低溫而最脆化甚或損壞,反有造成成本增加及良率下降之虞。此外,由於兩被分離表面之間必須提供一間隙供低溫氣體導入,此亦增加了重工的難度。 Korean Patent No. KR20100115529 refers to the use of cryogenic gas for heavy work. The method provides a gap between the two separated surfaces, and introduces a low temperature gas in the gap to reduce the viscosity of the adhesive, thereby performing heavy work. However, when the temperature is lowered, the touch glass, the frame or the display panel may be most embrittled or even damaged due to the inability to withstand the low temperature, which may cause an increase in cost and a drop in yield. In addition, since a gap must be provided between the two separated surfaces for the introduction of low temperature gas, this also increases the difficulty of rework.

除前述以低溫方式降低黏著劑之黏性而進行重工之方式外,現行另有加溫至80℃以上以降低黏著劑黏性而進行重工之手段。然而,不論降溫或升溫,其或許可適用於金屬基材,但對塑膠基材或是佈有導電線路或印刷完成之觸控式螢幕的玻璃,溫度的變化極易破壞該等材質,此皆導致重工之人力、時間和資源的浪費。 In addition to the above-mentioned method of reducing the viscosity of the adhesive at a low temperature to carry out heavy work, there is currently a means of heating to 80 ° C or more to reduce the viscosity of the adhesive and to carry out heavy work. However, whether it is cooling or warming, it may be suitable for metal substrates, but for plastic substrates or glass with conductive lines or printed touch screens, temperature changes can easily damage these materials. The waste of manpower, time and resources that lead to heavy work.

本發明係關於一種電子裝置之重工裝置、重工方法以及重工溶液,其中重工溶液可滲入電子裝置以黏著劑黏合之第一表面及第二表面,藉此減低黏著劑之黏性,使電子裝置黏合之第一表面及第二表面得以分離。 The invention relates to a rework device, a heavy work method and a heavy work solution for an electronic device, wherein the heavy work solution can penetrate into the electronic device to adhere the first surface and the second surface of the adhesive, thereby reducing the adhesiveness of the adhesive and bonding the electronic device. The first surface and the second surface are separated.

本案之一實施例提供一種電子裝置之重工裝置,其包含釋放元件及重工溶液,其中釋放元件包括釋放部及容置空間,其係相互連通,而重工溶液係容置於釋放元件之容置空間中,並透過釋放部釋放至電子裝置以一黏著層黏合之第一表面及第二表面之間,以作用於該黏著層而進行重工。 An embodiment of the present invention provides a reworking device for an electronic device, comprising a release component and a rework solution, wherein the release component includes a release portion and an accommodation space, which are in communication with each other, and the rework solution is placed in a receiving space of the release component. And releasing through the release portion to the electronic device between the first surface and the second surface adhered by an adhesive layer to act on the adhesive layer for rework.

於一實施例中,重工溶液包含一萜類成分及一溶劑,萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合。 In one embodiment, the heavy work solution comprises a terpenoid component and a solvent selected from the group consisting of monoterpene compounds and monoterpene derivatives.

於一實施例中,重工溶液之萜類成分選自檸檬烯而溶劑選自乙醇,其比例為1:9至7:3。 In one embodiment, the terpene component of the rework solution is selected from the group consisting of limonene and the solvent is selected from the group consisting of ethanol in a ratio of 1:9 to 7:3.

於一實施例中,重工溶液之檸檬烯及乙醇之比例為2:8至6:4。 In one embodiment, the ratio of limonene to ethanol in the rework solution is from 2:8 to 6:4.

於一實施例中,重工溶液之檸檬烯及乙醇之比例為5:5。 In one embodiment, the ratio of limonene to ethanol in the rework solution is 5:5.

於一實施例中,重工溶液之檸檬烯為右旋檸檬烯。 In one embodiment, the limonene of the rework solution is d-limonene.

於一實施例中,重工溶液更包含一界面活性劑,其可選自陰離子界面活性劑,例如:十二烷基硫酸鈉。 In one embodiment, the rework solution further comprises a surfactant, which may be selected from an anionic surfactant such as sodium lauryl sulfate.

於一實施例中,重工裝置之釋放元件為注射針筒,其中釋放部為一針頭而容置空間為針筒;於另一實施例中,重工裝置之釋放元件為滴管,其中釋放部為滴管出口而容置空間為滴管管身。 In one embodiment, the release component of the rework device is an injection syringe, wherein the release portion is a needle and the accommodation space is a syringe; in another embodiment, the release component of the rework device is a dropper, wherein the release portion is The dropper outlet and the accommodation space are the dropper body.

本案之另一實施例為提供一種電子裝置之重工方法,其包括:(a)提供一電子裝置,其包括由黏著層黏合之第一、第二表面;(b)提供一重工裝置,其包括釋放元件與重工溶液,其中釋放元件包括釋放部及容置空間,釋放部係與容置空間連通,而重工溶液係容置於釋放元件之容置空間中;及(c)將重工裝置之重工溶液透過釋放部由容置空間釋放至電子裝置之黏著層,俾使重工溶液作用於黏著層而使電子裝置之第一、第二表面分離。 Another embodiment of the present invention provides a method of reworking an electronic device, comprising: (a) providing an electronic device including first and second surfaces bonded by an adhesive layer; (b) providing a rework device including a release member and a rework solution, wherein the release member includes a release portion and an accommodation space, the release portion is in communication with the accommodation space, and the rework solution is placed in the accommodation space of the release member; and (c) the rework of the rework device is performed The solution is released from the accommodating space to the adhesive layer of the electronic device through the release portion, and the rework solution acts on the adhesive layer to separate the first and second surfaces of the electronic device.

本案之又一實施例提供一種電子裝置之重工溶液,其係用以將電子裝置以一黏著層黏合之第一表面與第二表面分離,重工溶液包含萜類成分及溶劑,該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合,例如:檸檬烯,而溶劑可選自乙醇,其比例為1:9至7:3。 A further embodiment of the present invention provides a rework solution for an electronic device for separating an electronic device by a first surface bonded to an adhesive layer, the rework solution comprising a terpenoid component and a solvent, the anthraquinone component It is selected from a combination of monoterpene compounds and monoterpene derivatives, for example, limonene, and the solvent may be selected from ethanol in a ratio of 1:9 to 7:3.

本案之再一實施例提供一種萜類成分及溶劑組合物之用途,其係用以製備電子裝置重工溶液,俾使重工溶液將電子裝置由黏著層黏合之第一、第二表面分離,其中萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合,例如選自檸檬烯,而溶劑可選自乙醇,其比例範圍可為1:9至7:3。 Still another embodiment of the present invention provides a use of an anthraquinone component and a solvent composition for preparing an electronic device rework solution, wherein the rework solution separates the electronic device from the first and second surfaces to which the adhesive layer is bonded, wherein The class of ingredients is selected from the group consisting of monoterpene compounds and monoterpene derivatives, for example selected from limonene, and the solvent may be selected from ethanol in a ratio ranging from 1:9 to 7:3.

1、3‧‧‧重工裝置 1, 3‧‧‧ Heavy equipment

11、31‧‧‧釋放元件 11, 31‧‧‧ release components

111、311‧‧‧釋放部 111, 311‧‧ ‧ release department

112、312‧‧‧容置空間 112, 312‧‧‧ accommodating space

12、32‧‧‧重工溶液 12, 32‧‧‧ Heavy work solution

2‧‧‧電子裝置 2‧‧‧Electronic devices

21‧‧‧第一結構 21‧‧‧First structure

211‧‧‧表面 211‧‧‧ surface

22‧‧‧第二結構 22‧‧‧Second structure

221‧‧‧表面 221‧‧‧ surface

23‧‧‧黏著層 23‧‧‧Adhesive layer

S1-S3‧‧‧電子裝置之重工方法 S1-S3‧‧‧Rework method for electronic devices

圖1係為本案電子裝置之重工裝置應用於電子裝置的一較佳實施例。 1 is a preferred embodiment of a rework device of an electronic device of the present invention applied to an electronic device.

圖2係為本案電子裝置之重工裝置應用於電子裝置的另一較佳實施例。 FIG. 2 is another preferred embodiment of the electronic device of the electronic device of the present invention applied to the electronic device.

圖3係為本案電子裝置之重工方法流程圖。 FIG. 3 is a flow chart of the method for reworking the electronic device of the present invention.

請參閱圖1,其係為本案電子裝置之重工裝置應用於電子裝置的一較佳實施例。如圖1所示,電子裝置2包括第一結構21和第二結構22,其中第一結構21具有一表面211,而第二結構22亦具有一表面221相對於第一結構21之表面211,且兩表面211/221之間透過黏著層23黏合。於一些實施例中,電子裝置2可為觸控式電子裝置之顯示面板,而第一結構21可為觸控玻璃,並於其表面上部有感應線路,而第二結構22可為框架或顯示面板,使觸控玻璃可透過黏著層23與框架或顯示面板結合。 Please refer to FIG. 1 , which is a preferred embodiment of the electronic device of the electronic device of the present invention applied to an electronic device. As shown in FIG. 1, the electronic device 2 includes a first structure 21 and a second structure 22, wherein the first structure 21 has a surface 211, and the second structure 22 also has a surface 221 opposite to the surface 211 of the first structure 21. And the two surfaces 211 / 221 are bonded through the adhesive layer 23 . In some embodiments, the electronic device 2 can be a display panel of the touch-sensitive electronic device, and the first structure 21 can be a touch glass and has an inductive line on the upper surface thereof, and the second structure 22 can be a frame or a display. The panel allows the touch glass to be bonded to the frame or display panel through the adhesive layer 23.

請再參閱圖1,本發明係利用重工裝置1使相互黏合之第一結構21的表面211與第二結構22的表面221可分離以進行重工,其中,重工裝置1包括釋放元件11及重工溶液12,釋放元件11具有釋放部111及容置空間112,釋放部111係與容置空間112連通,重工溶液12則容置於容置空間112中並透過釋放部111釋放至電子裝置2之第一結構21的表面211與第二結構22的表面221間的黏著層23。於本實施例中,釋放元件11可選用注射針筒,而釋放部111可為針頭,容置空間112則為針筒。 Referring to FIG. 1 again, the present invention utilizes the rework device 1 to separate the surface 211 of the first structure 21 bonded to each other from the surface 221 of the second structure 22 for rework, wherein the rework device 1 includes the release member 11 and the rework solution. The release member 11 has a release portion 111 and an accommodating space 112. The release portion 111 is in communication with the accommodating space 112. The rework solution 12 is received in the accommodating space 112 and released to the electronic device 2 through the release portion 111. An adhesive layer 23 between the surface 211 of the structure 21 and the surface 221 of the second structure 22. In this embodiment, the release member 11 can be an injection syringe, and the release portion 111 can be a needle, and the accommodation space 112 can be a syringe.

至於重工溶液12包含該萜類成分及溶劑,其中萜類成分可選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合,又以檸檬烯((R)-4-Isopropenyl-1-methyl-1-cyclohexene,Limonene)為佳, 更以右旋檸檬烯(D-limonene)為佳;至於溶劑可選自乙醇,但不以此為限。檸檬烯與乙醇之比例可為1:9至7:3,舉例而言,可為1:9、1.5:8.5、2:8、2.5:7.5、3:7、3.5:6.5、4:6、4.5:5.5、5:5、5.5:4.5、6:4、6.5:3.5或7:3,較佳為2:8至6:4,其中又以5:5為最佳。此外,重工溶液12亦可包含界面活性劑,而介面活性劑之選用係以陰離子界面活性劑為佳,以避免傷及電子裝置,例如:十二烷基硫酸鈉(Sodium dodecyl sulfate,SDS),但不以此為限。 The heavy work solution 12 comprises the terpenoid component and a solvent, wherein the terpenoid component may be selected from the group consisting of monoterpene compounds and monoterpene derivatives, and limonene ((R)-4-Isopropenyl -1-methyl-1-cyclohexene, Limonene) is preferred, More preferably, D-limonene is preferred; and the solvent may be selected from ethanol, but not limited thereto. The ratio of limonene to ethanol may range from 1:9 to 7:3, for example, 1:9, 1.5:8.5, 2:8, 2.5:7.5, 3:7, 3.5:6.5, 4:6, 4.5. : 5.5, 5:5, 5.5:4.5, 6:4, 6.5:3.5 or 7:3, preferably 2:8 to 6:4, of which 5:5 is the best. In addition, the heavy work solution 12 may also contain a surfactant, and the surfactant is preferably selected as an anionic surfactant to avoid injuring electronic devices such as sodium dodecyl sulfate (SDS). But not limited to this.

請參閱圖2,其係為本案電子裝置之重工裝置應用於電子裝置的另一較佳實施例。如圖2所示,電子裝置2之結構係與本案第一圖所示者相似,故不贅述,而重工裝置3亦包括釋放元件31和重工溶液32,釋放元件31包括相互聯通之釋放部311和容置空間312。於本實施例中,重工裝置之釋放元件31為一滴管,而釋放部311為該滴管出口,容置空間312則為滴管管身,以容置重工溶液32。是以重工溶液32可透過滴管之出口由滴管管身釋出至電子裝置2之表面211、221之間的黏著層23,使重工溶液32可與黏著層23作用而降低黏著層23的黏著力,從而使表面211、221分離而可進行電子裝置2之重工。 Please refer to FIG. 2 , which is another preferred embodiment of the electronic device of the electronic device of the present invention applied to the electronic device. As shown in FIG. 2, the structure of the electronic device 2 is similar to that shown in the first figure of the present invention, and therefore, the rework device 3 also includes a release member 31 and a rework solution 32. The release member 31 includes a release portion 311 that communicates with each other. And accommodation space 312. In the present embodiment, the release member 31 of the rework device is a dropper, and the release portion 311 is the dropper outlet, and the accommodation space 312 is the dropper body to accommodate the heavy duty solution 32. The adhesive layer 32 is released from the dropper body through the outlet of the dropper to the adhesive layer 23 between the surfaces 211 and 221 of the electronic device 2, so that the heavy work solution 32 can act on the adhesive layer 23 to lower the adhesive layer 23. The adhesion of the electronic device 2 can be performed by the adhesion so that the surfaces 211, 221 are separated.

請參閱圖3,其係為電子裝置之重工方法。如圖3所示,其中前兩步驟(S1)、(S2)為提供一電子裝置及提供一重工裝置,電子裝置包括由黏合層黏合之第一表面及第二表面,而重工裝置包括包含釋放部及容置空間之釋放元件以及容置於容置空間中的重工溶液,然而應可理解,步驟(S1)及步驟(S2)並無先後順序之分別。請再參閱圖3,於步驟S3係將重工裝置之重工溶液透過釋放部由容置空間釋放至電子裝置之第一、第二表面間的黏著層,俾使重工溶液作用於黏著層而將電子裝置黏合的第一表面與第二表面分 離。 Please refer to FIG. 3, which is a rework method of an electronic device. As shown in FIG. 3, wherein the first two steps (S1), (S2) provide an electronic device and provide a rework device, the electronic device includes a first surface and a second surface bonded by an adhesive layer, and the rework device includes a release The release component of the portion and the accommodating space and the rework solution accommodated in the accommodating space, however, it should be understood that there is no difference between the steps (S1) and (S2). Referring to FIG. 3, in step S3, the rework solution of the rework device is released from the accommodating space to the adhesive layer between the first and second surfaces of the electronic device through the release portion, so that the rework solution acts on the adhesive layer to carry the electrons. The first surface and the second surface of the device are bonded from.

本發明亦提供一種萜類成分及溶劑組合物之用途,其中該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合,以檸檬烯為佳,又以右旋檸檬烯為最佳,而溶劑則以選自乙醇為佳。該組合物之用途係用以製備電子裝置之重工溶液,以利用該重工溶液將電子裝置由黏著劑黏合之第一表面及第二表面分離,以進行重工。重工溶液之檸檬烯與乙醇之比例範圍可為1:9至7:3,舉例而言,可為1:9、1.5:8.5、2:8、2.5:7.5、3:7、3.5:6.5、4:6、4.5:5.5、5:5、5.5:4.5、6:4、6.5:3.5或7:3,較佳為2:8至6:4,其中又以5:5為最佳。此外,重工溶液更可包含其於成分,例如:介面活性劑,而介面活性劑的選用以陰離子藉活性劑為佳,例如:烷基硫酸鹽中之十二烷基硫酸鈉,但不以此為限。 The present invention also provides the use of an anthraquinone component and a solvent composition, wherein the anthraquinone component is selected from the group consisting of monoterpene compounds and monoterpene derivatives, preferably limonene, and D-limonene is preferred, and the solvent is preferably selected from the group consisting of ethanol. The use of the composition is to prepare a heavy work solution for an electronic device to separate the electronic device from the first surface and the second surface to which the adhesive is bonded by using the heavy work solution for rework. The ratio of limonene to ethanol in the rework solution may range from 1:9 to 7:3, for example, 1:9, 1.5:8.5, 2:8, 2.5:7.5, 3:7, 3.5:6.5, 4 : 6, 4.5: 5.5, 5: 5, 5.5: 4.5, 6: 4, 6.5: 3.5 or 7: 3, preferably 2: 8 to 6: 4, of which 5:5 is the best. In addition, the heavy work solution may further comprise a component thereof, for example, an surfactant, and the surfactant is preferably selected from an anion-based active agent, for example, sodium lauryl sulfate in an alkyl sulfate, but not Limited.

以下為本發明之實驗例。 The following is an experimental example of the present invention.

將不銹鋼測試板(型號304不鏽鋼板,粗糙度0.050±0.025μm,尺寸:50mm×125mm×1.1mm)上黏著3MTM VHBTM膠帶(型號4914-025,厚度0.25mm)於23℃下以2Kg之滾輪來回滾壓1次,並於1小時後以不同實驗例組別之重工溶液2ml進行測試。測試方法係使用拉伸測試儀(型號5965,購自INSTRON)以50mm/min(2英寸/min)的速度測量180°剝離黏著力。重工溶液為不同右旋檸檬烯(購自FLORACHEM Corporation,型號:CFLOOT-0177)及乙醇(購自台灣菸酒股份有限公司,型號:九十五度優質酒精)之比例進行混合,比較例為不添加重工溶液。黏著力降低之百分比則以比較例之180°剝離黏著力減各實驗例之180°剝離黏著力/比較例之180°剝離黏著力。測試結果(三重複平均值)如下表所示: A stainless steel test board (model 304 stainless steel plate, roughness 0.050±0.025 μm, size: 50 mm×125 mm×1.1 mm) was adhered to 3M TM VHB TM tape (model 4094-025, thickness 0.25 mm) at 23 ° C at 2 kg. The roller was rolled back and forth once, and after 1 hour, it was tested with 2 ml of the rework solution of different experimental groups. The test method was to measure the 180° peel adhesion at a speed of 50 mm/min (2 inches/min) using a tensile tester (Model 5965, available from INSTRON). The rework solution was mixed with different ratios of d-limonene (purchased from FLORACHEM Corporation, model: CFLOOT-0177) and ethanol (purchased from Taiwan Tobacco and Liquor Co., Ltd., model: 95-degree high-quality alcohol), and the comparative example was not added. Heavy work solution. The percentage of adhesion reduction was reduced by the 180° peel adhesion of the comparative example and the 180° peel adhesion of each of the experimental examples/180° peel adhesion of the comparative example. The test results (three replicate averages) are shown in the following table:

由表一可知,實驗例2至實驗例8皆可降低30%以上之膠帶黏著力,其中實驗例3至實驗例7可降低35%以上之膠帶黏著力,而實驗例6更可降低膠帶之黏著力至45%以上。 It can be seen from Table 1 that the experimental examples 2 to 8 can reduce the adhesiveness of the adhesive tape by more than 30%, wherein the experimental examples 3 to 7 can reduce the adhesiveness of the adhesive tape by more than 35%, and the experimental example 6 can reduce the adhesive tape. Adhesive strength to more than 45%.

實驗例12係為右旋檸檬烯:乙醇:陰離子界面活性劑十二烷基硫酸鈉((Sodium dodecyl sulfate,SDS,型號:62862,購自Sigma-Aldrich)為1:1:0.1(wt%)之比例混合而成的重工溶液,並將實驗例12之重工溶液1.5ml注入以寬度3mm之3MTM VHBTM膠帶(4914-025)貼合72小時之市售油墨印 刷玻璃(TMBK945)與聚碳酸酯基材(MAKROLON®)結合件,壓合條件為15PSI,15秒鐘,並於室溫23℃下以4Kg之荷重測試其靜態抗拉強度測試值(ASTM D 3654)。而結果顯示實驗例12可於21分鐘內將油墨印刷玻璃與聚碳酸酯基材分離,但未經任何處理之油墨印刷玻璃與聚碳酸酯基材結合件於超過10000分鐘後兩者仍緊密的黏合。是以可知,本發明之重工溶液,不管是否額外添加介面活性劑,皆可有效的減低黏著劑之強度,俾利作為電子裝置之重工溶液以方便電子裝置重工作業。 Experimental Example 12 is D-limonene: Ethanol: Anionic surfactant sodium dodecyl sulfate (SDS, model: 62862, purchased from Sigma-Aldrich) is 1:1:0.1 (wt%) A ratio of the reconstituted solution was reconstituted, and 1.5 ml of the rework solution of Experimental Example 12 was injected into a 3M TM VHB TM tape (4914-025) having a width of 3 mm for 72 hours of commercial ink printing glass (TMBK945) and polycarbonate. The substrate (MAKROLON®) joint was pressed at 15 PSI for 15 seconds, and its static tensile strength test value (ASTM D 3654) was tested at a load of 4 kg under a room temperature of 23 ° C. The results show that Example 12 The ink printing glass can be separated from the polycarbonate substrate in 21 minutes, but the ink printing glass and the polycarbonate substrate bonding member without any treatment are still tightly bonded after more than 10,000 minutes. The heavy work solution of the present invention can effectively reduce the strength of the adhesive regardless of whether or not the additional surfactant is added, and the utility model can be used as a heavy work solution of the electronic device to facilitate the heavy work of the electronic device.

以上敘述係用以說明而非用以限定本發明之申請專利範圍,本發明之範疇係由以下之申請專利範圍所界定。凡依本發明申請專利範圍所作之均等變化與修飾,皆應屬本發明之涵蓋範圍。 The above description is intended to be illustrative, and not to limit the scope of the invention, which is defined by the following claims. Equivalent changes and modifications made within the scope of the invention as claimed should be within the scope of the invention.

Claims (22)

一種重工裝置,其係將一電子裝置以一黏著層黏合之一第一表面及一第二表面分離,該重工裝置包含:一釋放元件,其包括一釋放部及一容置空間,該釋放部係與該容置空間連通;一重工溶液,其係容置於該釋放元件之該容置空間中,並透過該釋放部釋放至該第一表面及該第二表面之間之該黏著層,該重工溶液係包含一萜類成分及一溶劑,該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合。 A rework device for separating an electronic device by bonding an adhesive surface to a first surface and a second surface, the rework device comprising: a release component comprising a release portion and an accommodation space, the release portion Connected to the accommodating space; a rework solution that is placed in the accommodating space of the release member and released through the release portion to the adhesive layer between the first surface and the second surface, The heavy work solution comprises a terpenoid component and a solvent selected from the group consisting of monoterpene compounds and monoterpene derivatives. 如申請專利範圍第1項之重工裝置,其中該重工溶液之該萜類成分係選自檸檬烯,該溶劑係選自乙醇。 The heavy equipment of claim 1, wherein the hydrazine component of the heavy duty solution is selected from the group consisting of limonene, the solvent being selected from the group consisting of ethanol. 如申請專利範圍第2項之重工裝置,其中檸檬烯與乙醇之比例為1:9至7:3。 For example, the heavy equipment of claim 2, wherein the ratio of limonene to ethanol is 1:9 to 7:3. 如申請專利範圍第2項之重工裝置,其中檸檬烯與乙醇之比例為2:8至6:4。 For example, the heavy equipment of claim 2, wherein the ratio of limonene to ethanol is from 2:8 to 6:4. 如申請專利範圍第2項之重工裝置,其中檸檬烯與乙醇之比例為5:5。 For example, the heavy equipment of claim 2, wherein the ratio of limonene to ethanol is 5:5. 如申請專利範圍第2項之重工裝置,其中該重工溶液之檸檬烯為右旋檸檬烯。 The heavy equipment of claim 2, wherein the limonene of the heavy work solution is d-limonene. 如申請專利範圍第1項之重工裝置,其中該重工溶液更包含一界面活性劑,其可選自陰離子界面活性劑。 The rework device of claim 1, wherein the rework solution further comprises a surfactant, which may be selected from the group consisting of an anionic surfactant. 如申請專利範圍第7項之重工裝置,其中該重工溶液之該界面活性劑為十二烷基硫酸鈉。 The heavy equipment of claim 7, wherein the surfactant of the heavy work solution is sodium lauryl sulfate. 如申請專利範圍第1項之重工裝置,其中該釋放元件係為一注射針筒,該釋放部係為一針頭,而該容置空間為一針筒。 The rework device of claim 1, wherein the release member is an injection syringe, the release portion is a needle, and the accommodation space is a syringe. 如申請專利範圍第1項之重工裝置,其中該釋放元件係為一滴管,該釋放部為滴管出口,而該容置空間為滴管管身。 The rework device of claim 1, wherein the release member is a dropper, the release portion is a dropper outlet, and the receiving space is a dropper body. 一種電子裝置重工方法,其包括:(a)提供一電子裝置,該電子裝置包括由一黏著層黏合之一第一表面及一第二表面;(b)提供一重工裝置,其包括:一釋放元件,其包括一釋放部及一容置空間,該釋放部係與該容置空間連通;一重工溶液,其係容置於該釋放元件之該容置空間,該重工溶液包含一萜類成分及一溶劑,該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合;以及(c)將該重工裝置之該重工溶液透過該釋放部由該容置空間釋放至該電子裝置之該黏著層,俾使該重工溶液作用於該黏著層而使該電子裝置之該第一表面與該第二表面分離。 An electronic device rework method comprising: (a) providing an electronic device comprising: bonding a first surface and a second surface by an adhesive layer; (b) providing a rework device comprising: a release The component includes a release portion and an accommodating space, wherein the release portion is in communication with the accommodating space; a rework solution is disposed in the accommodating space of the release member, and the rework solution contains a quinone component And a solvent, the quinone component is selected from the group consisting of monoterpene compounds and monoterpene derivatives; and (c) the rework solution of the rework device is passed through the release portion. The space is released to the adhesive layer of the electronic device, and the rework solution is applied to the adhesive layer to separate the first surface of the electronic device from the second surface. 如申請專利範圍第11項之重工方法,其中該重工溶液之該萜類成分係選自檸檬烯,該溶劑係選自乙醇。 The method of reworking according to claim 11, wherein the hydrazine component of the heavy work solution is selected from the group consisting of limonene, and the solvent is selected from the group consisting of ethanol. 如申請專利範圍第12項之重工方法,其中該重工溶液之檸檬烯及乙醇比例為1:9至7:3。 For example, the heavy work method of claim 12, wherein the ratio of limonene to ethanol in the heavy work solution is 1:9 to 7:3. 如申請專利範圍第12項之重工方法,其中該重工溶液之檸檬烯與乙醇比例為2:8至6:4。 The method of reworking according to claim 12, wherein the ratio of limonene to ethanol in the heavy work solution is from 2:8 to 6:4. 如申請專利範圍第12項之重工方法,其中該重工溶液之檸檬烯與乙醇之比例為5:5。 The method of reworking according to claim 12, wherein the ratio of limonene to ethanol in the heavy work solution is 5:5. 如申請專利範圍第12項之重工方法,其中該重工溶液之檸檬烯為右旋 檸檬烯。 For example, the heavy work method of claim 12, wherein the limonene of the heavy work solution is a right-handed Limonene. 如申請專利範圍第11項之重工方法,其中該重工溶液更包含一界面活性劑,其可選自陰離子界面活性劑。 The method of rework according to claim 11, wherein the heavy work solution further comprises a surfactant, which may be selected from the group consisting of an anionic surfactant. 如申請專利範圍第17項之重工方法,其中該重工溶液之該界面活性劑為十二烷基硫酸鈉。 The method of rework according to claim 17, wherein the surfactant of the heavy work solution is sodium lauryl sulfate. 一種電子裝置重工溶液,其係用以將該電子裝置以一黏著層黏合之一第一表面與一第二表面分離,該電子裝置重工溶液包含一萜類成分及一溶劑,該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合。 An electronic device rework solution for separating a first surface of an electronic device by an adhesive layer and a second surface, the electronic device rework solution comprising a quinone component and a solvent, the hydrazine component It is selected from the group consisting of monoterpene compounds and monoterpene derivatives. 如申請專利範圍第19項所述之重工溶液,其中該萜類成分係選自檸檬烯而該溶劑係選自乙醇,其比例為1:9至7:3。 The heavy work solution of claim 19, wherein the terpenoid component is selected from the group consisting of limonene and the solvent is selected from the group consisting of ethanol in a ratio of 1:9 to 7:3. 一種萜類成分及溶劑組合物之用途,其係用以製備電子裝置重工溶液,俾使該重工溶液將一電子裝置由一黏著層黏合之第一表面及第二表面分離,其中該萜類成分係選自單萜烯類化合物(monoterpene compounds)及其衍生物(monoterpene derivative)之組合。 The use of an anthraquinone component and a solvent composition for preparing an electronic device rework solution, wherein the rework solution separates an electronic device from a first surface and a second surface bonded by an adhesive layer, wherein the anthraquinone component It is selected from the group consisting of monoterpene compounds and monoterpene derivatives. 如申請專利範圍第21項所述之萜類成分及溶劑組合物之用途,其中該萜類成分係選自檸檬烯而該溶劑係選自乙醇,其比例為1:9至7:3。 The use of an anthraquinone component and a solvent composition as described in claim 21, wherein the anthraquinone component is selected from the group consisting of limonene and the solvent is selected from the group consisting of ethanol in a ratio of 1:9 to 7:3.
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