TWI642722B - 對聚胺基甲酸酯層具改善之黏著性的聚碳酸酯組成物 - Google Patents
對聚胺基甲酸酯層具改善之黏著性的聚碳酸酯組成物 Download PDFInfo
- Publication number
- TWI642722B TWI642722B TW103135770A TW103135770A TWI642722B TW I642722 B TWI642722 B TW I642722B TW 103135770 A TW103135770 A TW 103135770A TW 103135770 A TW103135770 A TW 103135770A TW I642722 B TWI642722 B TW I642722B
- Authority
- TW
- Taiwan
- Prior art keywords
- weight
- component
- parts
- polymer
- sum
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 111
- 239000004814 polyurethane Substances 0.000 title claims abstract description 72
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 66
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 52
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 49
- 239000002131 composite material Substances 0.000 claims abstract description 49
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 34
- 125000003118 aryl group Chemical group 0.000 claims abstract description 33
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 32
- 229920000642 polymer Polymers 0.000 claims abstract description 28
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 27
- 239000000654 additive Substances 0.000 claims abstract description 25
- 229920000728 polyester Polymers 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 229920006163 vinyl copolymer Polymers 0.000 claims abstract description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 238000004945 emulsification Methods 0.000 claims abstract description 8
- 239000000725 suspension Substances 0.000 claims abstract description 8
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims abstract description 7
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 60
- -1 vinyl aromatic compound Chemical class 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 33
- 229920001169 thermoplastic Polymers 0.000 claims description 31
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
- 239000005056 polyisocyanate Substances 0.000 claims description 21
- 229920001228 polyisocyanate Polymers 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 claims description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims 1
- 239000012760 heat stabilizer Substances 0.000 claims 1
- 229920013730 reactive polymer Polymers 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 19
- 229920005862 polyol Polymers 0.000 description 18
- 150000003077 polyols Chemical class 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 16
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 15
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 15
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 15
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000011159 matrix material Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000012948 isocyanate Substances 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- 239000004416 thermosoftening plastic Substances 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000011527 polyurethane coating Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 6
- 239000012876 carrier material Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 238000005199 ultracentrifugation Methods 0.000 description 6
- 229920005830 Polyurethane Foam Polymers 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- 239000011257 shell material Substances 0.000 description 5
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 239000006085 branching agent Substances 0.000 description 4
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 150000003512 tertiary amines Chemical class 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 239000004609 Impact Modifier Substances 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 150000008360 acrylonitriles Chemical class 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 125000005587 carbonate group Chemical group 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000004872 foam stabilizing agent Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
- 229960003742 phenol Drugs 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920005906 polyester polyol Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical class C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001409 amidines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000000022 bacteriostatic agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229920000891 common polymer Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000004989 dicarbonyl group Chemical group 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000010559 graft polymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MGAXYKDBRBNWKT-UHFFFAOYSA-N (5-oxooxolan-2-yl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1OC(=O)CC1 MGAXYKDBRBNWKT-UHFFFAOYSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- RTWWCANQVXFKPJ-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;trihydrochloride Chemical compound Cl.Cl.Cl.NC1=NC(N)=NC(N)=N1 RTWWCANQVXFKPJ-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- ZMESHQOXZMOOQQ-UHFFFAOYSA-N 1-(naphthalen-1-ylmethyl)naphthalene Chemical compound C1=CC=C2C(CC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ZMESHQOXZMOOQQ-UHFFFAOYSA-N 0.000 description 1
- AXFVIWBTKYFOCY-UHFFFAOYSA-N 1-n,1-n,3-n,3-n-tetramethylbutane-1,3-diamine Chemical compound CN(C)C(C)CCN(C)C AXFVIWBTKYFOCY-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical class OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- GUJZISPOCRVAMW-UHFFFAOYSA-N 2-[1-(2-hydroxyphenyl)-9h-fluoren-2-yl]phenol Chemical class OC1=CC=CC=C1C1=CC=C(C=2C(=CC=CC=2)C2)C2=C1C1=CC=CC=C1O GUJZISPOCRVAMW-UHFFFAOYSA-N 0.000 description 1
- KYGLCUAXJICESS-UHFFFAOYSA-N 2-[2,3-di(propan-2-yl)phenyl]phenol Chemical class CC(C)C1=CC=CC(C=2C(=CC=CC=2)O)=C1C(C)C KYGLCUAXJICESS-UHFFFAOYSA-N 0.000 description 1
- CQOZJDNCADWEKH-UHFFFAOYSA-N 2-[3,3-bis(2-hydroxyphenyl)propyl]phenol Chemical compound OC1=CC=CC=C1CCC(C=1C(=CC=CC=1)O)C1=CC=CC=C1O CQOZJDNCADWEKH-UHFFFAOYSA-N 0.000 description 1
- OGFZJRIBYKSVTN-UHFFFAOYSA-N 2-amino-2-methylpentane-1,3-diol Chemical compound CCC(O)C(C)(N)CO OGFZJRIBYKSVTN-UHFFFAOYSA-N 0.000 description 1
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 description 1
- XBQRPFBBTWXIFI-UHFFFAOYSA-N 2-chloro-4-[2-(3-chloro-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(Cl)=CC=1C(C)(C)C1=CC=C(O)C(Cl)=C1 XBQRPFBBTWXIFI-UHFFFAOYSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 1
- MVRPPTGLVPEMPI-UHFFFAOYSA-N 2-cyclohexylphenol Chemical compound OC1=CC=CC=C1C1CCCCC1 MVRPPTGLVPEMPI-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- ZDKYYMRLZONTFK-UHFFFAOYSA-N 3,4-bis(isocyanatomethyl)bicyclo[2.2.1]heptane Chemical compound C1CC2(CN=C=O)C(CN=C=O)CC1C2 ZDKYYMRLZONTFK-UHFFFAOYSA-N 0.000 description 1
- ZDWSNKPLZUXBPE-UHFFFAOYSA-N 3,5-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1 ZDWSNKPLZUXBPE-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- KQIGMPWTAHJUMN-UHFFFAOYSA-N 3-aminopropane-1,2-diol Chemical compound NCC(O)CO KQIGMPWTAHJUMN-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
- HVXRCAWUNAOCTA-UHFFFAOYSA-N 4-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=C(O)C=C1 HVXRCAWUNAOCTA-UHFFFAOYSA-N 0.000 description 1
- KJWMCPYEODZESQ-UHFFFAOYSA-N 4-Dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=C(O)C=C1 KJWMCPYEODZESQ-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- NIRYBKWMEWFDPM-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-3-methylbutyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CCC1=CC=C(O)C=C1 NIRYBKWMEWFDPM-UHFFFAOYSA-N 0.000 description 1
- MIJYTDQAOVQRRT-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylhept-2-en-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)=CC(C)(C=1C=CC(O)=CC=1)CC(C)(C)C1=CC=C(O)C=C1 MIJYTDQAOVQRRT-UHFFFAOYSA-N 0.000 description 1
- IQNDEQHJTOJHAK-UHFFFAOYSA-N 4-[4-[2-[4,4-bis(4-hydroxyphenyl)cyclohexyl]propan-2-yl]-1-(4-hydroxyphenyl)cyclohexyl]phenol Chemical compound C1CC(C=2C=CC(O)=CC=2)(C=2C=CC(O)=CC=2)CCC1C(C)(C)C(CC1)CCC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 IQNDEQHJTOJHAK-UHFFFAOYSA-N 0.000 description 1
- LIDWAYDGZUAJEG-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=CC=C1 LIDWAYDGZUAJEG-UHFFFAOYSA-N 0.000 description 1
- BOCLKUCIZOXUEY-UHFFFAOYSA-N 4-[tris(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 BOCLKUCIZOXUEY-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- KNDDEFBFJLKPFE-UHFFFAOYSA-N 4-n-Heptylphenol Chemical compound CCCCCCCC1=CC=C(O)C=C1 KNDDEFBFJLKPFE-UHFFFAOYSA-N 0.000 description 1
- ISAVYTVYFVQUDY-UHFFFAOYSA-N 4-tert-Octylphenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 ISAVYTVYFVQUDY-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- MGYGFNQQGAQEON-UHFFFAOYSA-N 4-tolyl isocyanate Chemical compound CC1=CC=C(N=C=O)C=C1 MGYGFNQQGAQEON-UHFFFAOYSA-N 0.000 description 1
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004358 Butane-1, 3-diol Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- TXOFSCODFRHERQ-UHFFFAOYSA-N N,N-Dimethylphenethylamine Chemical compound CN(C)CCC1=CC=CC=C1 TXOFSCODFRHERQ-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 1
- ZMUITFUVZGNSKM-UHFFFAOYSA-N NC(=O)Nc1cccc-2c1Cc1ccccc-21 Chemical compound NC(=O)Nc1cccc-2c1Cc1ccccc-21 ZMUITFUVZGNSKM-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- BQMQLJQPTQPEOV-UHFFFAOYSA-N OP(=O)OC=C Chemical class OP(=O)OC=C BQMQLJQPTQPEOV-UHFFFAOYSA-N 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004146 Propane-1,2-diol Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229920006164 aromatic vinyl copolymer Polymers 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- RGAMPJYGTCSRAG-UHFFFAOYSA-N bis[2-(diethylamino)ethyl] hexanedioate Chemical compound CCN(CC)CCOC(=O)CCCCC(=O)OCCN(CC)CC RGAMPJYGTCSRAG-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000001622 bismuth compounds Chemical class 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000001718 carbodiimides Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical class OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- XXKOQQBKBHUATC-UHFFFAOYSA-N cyclohexylmethylcyclohexane Chemical compound C1CCCCC1CC1CCCCC1 XXKOQQBKBHUATC-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- RRBRFYNWESTLOL-UHFFFAOYSA-L hexanoate;tin(2+) Chemical compound [Sn+2].CCCCCC([O-])=O.CCCCCC([O-])=O RRBRFYNWESTLOL-UHFFFAOYSA-L 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002466 imines Chemical group 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- BWTBHGDNJBIYAQ-UHFFFAOYSA-N n,n'-diethyl-n,n'-dimethylethane-1,2-diamine Chemical compound CCN(C)CCN(C)CC BWTBHGDNJBIYAQ-UHFFFAOYSA-N 0.000 description 1
- XFLSMWXCZBIXLV-UHFFFAOYSA-N n,n-dimethyl-2-(4-methylpiperazin-1-yl)ethanamine Chemical compound CN(C)CCN1CCN(C)CC1 XFLSMWXCZBIXLV-UHFFFAOYSA-N 0.000 description 1
- ZWRDBWDXRLPESY-UHFFFAOYSA-N n-benzyl-n-ethylethanamine Chemical compound CCN(CC)CC1=CC=CC=C1 ZWRDBWDXRLPESY-UHFFFAOYSA-N 0.000 description 1
- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- HXSACZWWBYWLIS-UHFFFAOYSA-N oxadiazine-4,5,6-trione Chemical compound O=C1ON=NC(=O)C1=O HXSACZWWBYWLIS-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003226 polyurethane urea Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- NWELCUKYUCBVKK-UHFFFAOYSA-N pyridin-2-ylhydrazine Chemical class NNC1=CC=CC=N1 NWELCUKYUCBVKK-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical class [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0003—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor of successively moulded portions rigidly joined to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1676—Making multilayered or multicoloured articles using a soft material and a rigid material, e.g. making articles with a sealing part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
- B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0278—Polyurethane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/308—Heat stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/10—Trains
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/18—Aircraft
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
本發明有關於一種組成物,包含A)55至75重量份的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)25至45重量份的至少一種混合物,包含至少一種藉乳化、懸浮或溶液聚合反應製備的丁二烯系接枝聚合物與至少一種不含聚丁二烯的乙烯基(共)聚合物,C)0.1至20.0重量份(以各情況下成分A與B之總和為基準)的至少一種聚合物添加劑,於此該聚丁二烯含量以成分A與B之重量份總和為基準為10%至20%(以重量計),及於此該來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為12%至23%(以重量計),及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100;及關於形成自這些組成物與一聚胺基甲酸酯層之複合組件,其在二個層體間的改善黏著性係顯著的;及關於一種製造該複合組件之方法。
Description
本發明提供對聚胺基甲酸酯系統具有改善之黏著性之聚碳酸酯組成物,包含這些聚碳酸酯組成物及聚胺基甲酸酯系統之複合體系統(composite system),還有形成自這些複合體系統之成形體及用於製造該複合體系統之方法。該聚碳酸酯組成物不僅僅對該聚胺基甲酸酯系統的改善黏著性是顯著的,而且對持續高的韌性、高的耐熱變形性與良好的熔體穩定性(melt stability)及高的斷裂時伸長率(elongation at break)為顯著的。
WO 2006/072366 A1敘述一種在具有至少兩個空穴之模塑體(mould)中形成及塗布一基材之方法。該方法包含下述步驟:a)在該模塑體之第一空穴中形成一基材,b)將前述步驟中製得的基材引入該模塑體之第二空穴內及c)以一塗層材料塗布在該第二空穴中的基材,該塗布係在升高壓力下實行。
藉由實施例及優選之方式,述及的有聚胺基甲酸酯塗層材料及PC+ABS基材(聚碳酸酯+丙烯腈-丁二烯-苯乙烯基材)。於這申請案中沒有任何指示(pointers)予以關於該載體材料組成物在該材料複合物(material composite)之黏著性質上的影響。
EP 2089207 A1揭示一種製造一複合組件(composite component)(尤其是包含一注射模塑體(injection moulding)及一聚胺基甲酸酯元件)之方法,包含下述步驟
a)製造一載體組件(carrier component),b)將該載體組件移動或轉移至一模塑體之開啟的空穴,c)閉合該模塑體至一預定位置,生成一具有第一尺寸之擴大的空穴,d)於該第一尺寸之擴大的空穴中產生一下降的壓力,e)將一灌注材料(flooding material)引入該擴大的空穴內及f)與該灌注材料之引入同時及/或在引入之後進行一壓紋(embossing)步驟,同時至少稍微地減小該空穴的大小。
為改善該複合體黏著性,在此敘述藉火焰、電漿處理或氣體活化該熱塑性塑膠表面。於這申請案中沒有任何指示予以關於該載體材料組成物在該材料複合物之黏著性質上的影響。
DE 10 2006 033 059 A1揭示一種製造塑膠內部組件之方法。於這方法,於第一步驟中,該載體被形成於第一模塑體中,然後該第一模塑體至少部分被第二模塑體替代及之後於第二步驟中的載體上形成頂層。所用的載體材料為一硬質成分,e.g.PA+ABS摻合物(聚醯胺+丙烯腈-丁二烯-苯乙烯)或PC+ABS摻合物(聚碳酸酯+丙烯腈-丁二烯-苯乙烯),及所用的頂層為軟質成分,較佳為聚胺基甲酸酯發泡體。於這申請案中沒有任何指示予以關於該載體材料之組成物在該如此製得的組件之複合性質上的影響。替代的是,DE 10 206 033 059 A1同時提出藉底料(primer)或藉雷射、電暈或電漿處理製備該表面而改善黏著性。
WO 99/20464 A1揭示彼此直接接合的至少兩種不同聚合物材料之複合體:a)一熱塑性聚合物或一聚合物之熱塑性塑膠混合物,其含有週期表主族1至5或週期表過渡金屬族1至8之至少一種金屬的至少一種極性化合物作為超細分布的無機粉末,與b)以一發泡體、塗層材料或壓實材料之形式存在的聚胺基甲酸酯。對該複合體不需要任何黏著性促進層。就ABS含量與橡膠含量而論於這公開案中沒有任何指示予以關於該載體材料組成物在該材料複合物之黏著性質上的影響。
DE 101 09 226 A1揭示一種聚碳酸酯組成物,包含a)芳香族聚碳酸酯及
/或聚酯碳酸酯,b)接枝聚合物及c)苯乙烯與一含有羧基之單體之共聚物,於此所述共聚物具有一平均分子量(mean molecular weight)Mw為>=10 500g/mol,及於此所述共聚物可含有一或多種乙烯基單體。成分C較佳為苯乙烯與順丁烯二酸酐之共聚物。DE 101 09226 A1另揭示複合組件包含至少一第一層(I)及一第二層(2),其中層(1)包括至少一種聚碳酸酯組成物(如於a、b及c中所特定的)及層(2)含有至少一種聚胺基甲酸酯。該複合體特性為,在一雙重交替環境試驗(double alternating climate test)之後介於層(1)與層(2)間的發泡體黏著性下降為最多35%。就ABS含量與橡膠含量而論於這公開案中沒有任何指示予以關於該載體材料組成物在該材料複合物之黏著性質上的影響。
US 2008/0194756 A1揭示一種熱塑性塑膠組成物,包含聚碳酸酯、一包含ABS之衝擊性改質劑、一除了ABS之另外衝擊性改質劑、一芳香族乙烯基共聚物及一凝膠形式之添加劑。該組成物對良好機械、熱的及流變性質、及低的表面光澤度是顯著的。然而,未揭示具有聚胺基甲酸酯塗層之複合體系統及改善之黏著性質。
本發明之目的係為了提供對聚胺基甲酸酯系統具有改善之黏著性之改善的聚碳酸酯組成物,包含這些聚碳酸酯組成物及聚胺基甲酸酯層之複合體系統,及形成自這些複合體系統之成形體。聚碳酸酯組成物對該聚胺基甲酸酯系統之改善之黏著性、及對持續高的韌性、高的耐熱變形性、良好的熔體穩定性及高的斷裂時伸長率應是顯著的。
此外,係為了提供一種用於製造這些複合組件之方法。
該聚胺基甲酸酯層可用來例如改善該複合組件之表面性質,例如耐刮擦性、自行復原性(self-healing)、風化穩定性、觸覺(tactile)性質、光學性質、隔音及隔熱。
達成本發明之目的係藉聚碳酸酯組成物,其包含
A)55至75重量份,較佳地57至74重量份,更佳地64至73重量份,的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)25至45重量份,較佳地26至43重量份,更佳地27至36重量份,的至少一種混合物,其包含至少一種藉乳化、懸浮或溶液聚合反應製備的聚丁二烯系接枝聚合物與至少一種不含丁二烯的乙烯基(共)聚合物,C)0.1至20.0重量份,較佳地0.2至15.0重量份,更佳地0.3至10.0重量份(以各情況下成分A與B之總和為基準),的至少一種聚合物添加劑,於此該聚丁二烯含量以成分A與B之重量份總和為基準為10%至20%(以重量計),較佳地11%至18%(以重量計),更佳地12%至17%(以重量計),及於此該來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為12%至23%(以重量計),較佳地12%至20%(以重量計),更佳地13%至19%(以重量計),及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
圖1顯示根據本發明方法製造複合組件之實施例說明。
當所提及的適宜範圍可與彼此隨意組合時,適宜予以與各個第一、中間及最後範圍彼此組合。
本發明還提供一種組成物,包含A)55至75重量份的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)25至45重量份的至少一種混合物,其包含至少一種聚丁二烯系接枝聚合物與至少一種不含聚丁二烯的乙烯基(共)聚合物,C)0.1至20.0重量份(以各情況下成分A與B之總和為基準)的至少一種聚合物添加劑,
於此該聚丁二烯含量以成分A與B之重量份總和為基準為10%至20%(以重量計),及於此該來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為12%至23%(以重量計),及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100,及i)該接枝聚合物係藉乳化、懸浮或溶液聚合反應製備或ii)該組成物係不含具有一甲基丙烯酸甲基酯之接枝殼體(graft shell)之接枝聚合物或iii)該接枝聚合物係已藉乳化、懸浮或溶液聚合反應製備及該組成物係不含具有一甲基丙烯酸甲基酯之接枝殼體之接枝聚合物。
於一另外較佳具體實施,該組成物包含A)55至75重量份的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)25至45重量份的至少一種混合物,其包含至少一種藉乳化聚合反應製備的聚丁二烯系接枝聚合物與至少一種不含丁二烯的乙烯基(共)聚合物,C)0.1至20.0重量份(以各情況下成分A與B之總和為基準)的至少一種聚合物添加劑,於此該聚丁二烯含量以成分A與B之重量份總和為基準為10%至20%(以重量計),及於此該來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為12%至23%(以重量計),及於此該聚丁二烯系接枝聚合物之接枝基質具有一中值粒子大小(median particle size)(d50)為0.2至1.0μm,其藉超離心方法測得,及於此成分B之接枝聚合物,以該接枝聚合物為基準,包含25%至60%(以重量計)的至少一種乙烯基單體與75%至40%(以重量計)的一或多種聚丁二烯系接枝基質,
及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
於一另外較佳具體實施,該組成物包含A)64至73重量份的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)27至36重量份的至少一種混合物,其包含至少一種藉乳化聚合反應製備的聚丁二烯系接枝聚合物與至少一種苯乙烯與丙烯腈之不含丁二烯的共聚物,C)0.3至10.0重量份(以各情況下成分A與B之總和為基準)的至少一種聚合物添加劑,於此該聚丁二烯含量以成分A與B之重量份總和為基準為12%至17%(以重量計),及於此該來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為13%至19%(以重量計),及於此該聚丁二烯系接枝聚合物之接枝基質具有一中值粒子大小(d50)為0.2至0.5μm,其藉超離心方法測得,及於此成分B之接枝聚合物,以該接枝聚合物為基準,包含25%至60%(以重量計)的至少一種乙烯基單體與75%至40%(以重量計)的一或多種聚丁二烯系接枝基質,及於此成分B之接枝聚合物不含有任何甲基丙烯酸甲基酯,及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
於一另外較佳具體實施,該聚碳酸酯組成物只有成分A、B及C構成。
於一另外較佳具體實施,該聚碳酸酯組成物係不含填充劑與強化劑,例如滑石、玻璃纖維或碳纖維(選擇地包括研磨的纖維)、(中空)玻璃或陶瓷珠、雲母、高嶺土、CaCO3及玻璃碎片。
於一另外較佳具體實施,該聚碳酸酯組成物係不含滯焰劑與不含滯焰
劑協同劑,諸如抗滴劑。
此外且適宜者,本發明之目的係藉包含下述之複合組件達成的,
a)一載體,由一如上述特定的聚碳酸酯組成物所構成
b)至少一種聚胺基甲酸酯層。
所述聚胺基甲酸酯層可,例如,為一PU塗層材料、一PU發泡體或者是一具有聚胺基甲酸酯層厚度為(例如)1μm至多20cm之壓實PU皮。
於一較佳具體實施,該聚胺基甲酸酯層為一具有層厚度為1至1000μm之塗層材料,另較佳地10至500μm及更佳地50至300μm。
於一另外較佳具體實施,該聚胺基甲酸酯層為一具有層厚度為1mm至20cm之發泡體,另較佳地1mm至10cm及更佳地1mm至1cm。
於一另外較佳具體實施,該聚胺基甲酸酯層為一具有層厚度為0.5mm至10.0mm之壓實皮(compact skin),較佳地0.5mm至5.0mm及更佳地1.0mm至4.0mm。
該複合組件原則上可以任何已知方式被製造。
較佳地,該聚胺基甲酸酯層係藉包含下述之反應性聚胺基甲酸酯原料混合物之完全聚合反應製造的- 至少一種聚異氰酸酯成分,- 至少一種多官能性H-活性化合物,及- 選擇地至少一種聚胺基甲酸酯添加劑及/或加工助劑,係與事先已成形自該熱塑性塑膠組成物與已被固化的載體直接接觸。
該載體組件可預製(例如)自該熱塑性PC+ABS組成物及該反應性聚胺基甲酸酯原料混合物可被施用至其且完全反應。根據該聚胺基甲酸酯反應成分之反應性,它們可先已被預混合或可在施用期間以已知方式被混合。該施用可藉包括噴塗(spraying)、刀-塗布或軋光(calendaring)之方法實行。
若欲製得發泡的複合體時,可以本身已知方式將該反應混合物引入一含有預先形成的與固化的支撐組件(support component)之模塑體內。選擇地,該模塑體還可含有一另外的裝飾層(decorative layer)(通常稱為"皮"),其由(例如)聚氯乙烯(PVC)、熱塑性聚烯烴類(TPO)、熱塑性聚胺基甲酸酯(TPU)或可噴塗的聚胺基甲酸酯皮所構成。於該模塑體中,該可發泡的反應混合物發泡體係與該載體組件與任意的裝飾層接觸,及形成該複合組件。該模塑體內(in-mould)發泡可依諸如該複合組件在它的表面具有一胞孔結構(cell structure)之方式實施。或者是,可依諸如該複合組件具有一壓實皮及一蜂窩芯(cellular core)(積合發泡體(integral foams))之方式進行。利用高壓或低壓機器可將該聚胺基甲酸酯成分引入該模塑體內。
聚胺基甲酸酯發泡體還可被製成塊狀發泡體(slabstock foam)。
聚胺基甲酸酯複合體還可以夾層(sandwich)模式被製造。該方法可被組態成或為庫式方法(depot method)或為殼建式方法(shell-building method)。該庫式方法及該殼建式方法本身均是已知的。於該庫式方法(填充模式)中,兩個半殼(例如製自聚合物之外層)被預製及被插入一模塑體內,及介於殼體之間的空穴藉以PUR發泡體發泡填充。於殼建式模式中,PUR發泡體核芯被置於一模塑體中及之後包裹有適合的殼材料,例如提及的熱塑性塑膠之一者。於夾層複合體之製造中,適宜為予以殼建式模式。
於本發明之一較佳具體實施,該複合組件係藉一方法製得,其中(i)於第一方法步驟中,將該熱塑性塑膠組成物之熔體注入一第一模塑體空穴內及之後冷卻,(ii)於第二方法步驟中,將該熱塑性塑膠成分轉移至一較大空穴內及藉此製得一界定的間隙(defined gap),
(iii)於第三方法步驟中,於該熱塑性塑膠成分與該擴大的空穴之模塑體表面之間所產生的間隙注入有一包含下述之反應性聚胺基甲酸酯原料混合物- 至少一種聚異氰酸酯成分,- 至少一種多官能性H-活性化合物,及- 選擇地至少一種聚胺基甲酸酯添加劑及/或加工助劑,該聚胺基甲酸酯原料混合物係以與該熱塑性塑膠載體的表面直接接觸之方式完全聚合,以得到一壓實聚胺基甲酸酯層或得到一聚胺基甲酸酯發泡體層,及(iv)於第四方法步驟中,該複合組件自該模塑體空穴中被脫模。
於本發明之一另外較佳具體實施,方法步驟(i)至(iv)在該複合組件製造中彼此緊接著依序跟隨。
若需要的話,該較大的空穴在方法步驟(iii)之前利用一分離劑處理。
該方法步驟之緊接著次序係避免在該方法期間該工件(workpiece)冷卻降到室溫。這達到製造次數上的減少及該整體方法之較高能量效益。
隨著該聚胺基甲酸酯系統之變化,方法步驟(ii)及(iii)可被重複至少一次,於其情況下一或多種聚胺基甲酸酯層被施用至該載體之一或兩面上,以使產生一由熱塑性塑膠載體與至少兩種相同或不同的PU組件所構成的複合組件,該PU組件可選擇地還具有多於二-層結構。
在步驟(ii)及(iv)中的工件脫模之前,該工件被降溫直到它為尺寸上穩定。
為於方法步驟(ii)中製造該間隙,可以開啟該注射模塑體及隨後將一半的注射模塑體空穴換成具較大空穴尺寸之新的一半注射模塑體空穴,或將該組件自該第一模塑體空穴移動至一第二空穴(就它的空穴尺寸而論係較大
的)或至一第二模塑體,或開啟該欲產生一間隙之第一空穴。
於方法步驟(ii)中該基材之移動作用可藉已知方法實行,如以(例如)多色(multicolour)注射模塑施用。典型方法為首先利用一轉盤(turntable)、一轉板(turning plate)、一滑動空穴或一指標板(index plate)移動,或其中該基材保留在一核芯上之可相比擬的方法。若該用於移動之基材保留在該核芯上時,這具有即使在移動之後準確界定該位置之優點。其次,先前技術揭示用於移動一基材之方法,其中該基材係例如借助一操控系統自一空穴去除,及被置入另一空穴內。隨著該基材去除之移動在該塗布操作中提供更高的組態自由度,例如產生一摺邊(edge fold)或遮蔽區域。
於一較佳具體實施,於該第一方法步驟中,使用一熱塑性聚合物組成物,在依ISO 180-1 A之缺口衝擊性試驗(notched impact test)中,其在室溫下及更佳地還在-20℃下,具有高韌性,特徵在於耐缺口衝擊性值為高於30kJ/m2
用於本發明複合組件之製造的反應性聚胺基甲酸酯原料混合物較佳地具有一指數為>80至<125,另較佳地>90至<120,及更佳地100至110。
該指數被定義為,實際上使用的異氰酸酯之用量對在與該H-活性多官能性成分之完全反應情況下計算的化學計量之百分比例,i.e.指數=(使用的異氰酸酯之用量/異氰酸酯之計算的化學計量) * 100。
於一另選具體實施,它還可以使用一熱塑性聚胺基甲酸酯,而不是該反應性聚胺基甲酸酯原料混合物。
於一另外較佳具體實施,與該熱塑性聚合物組成物接觸的注射模塑體之表面於方法步驟(iii)中被加熱至50至100℃範圍之溫度,較佳地55至95℃,及更佳地60至90℃。
於一另外較佳具體實施,與該反應性聚胺基甲酸酯混合物接觸的注射模塑體之表面於方法步驟(iii)中被加熱至50至160℃範圍之溫度,較佳地50至120℃,另較佳地60至110℃,及更佳地60至90℃。
於一另外較佳具體實施,與該熱塑性聚合物組成物接觸的注射模塑體之表面於方法步驟(iii)中被加熱至50至100℃範圍之溫度,較佳地55至95℃,及更佳地60至90℃,及與該反應性聚胺基甲酸酯混合物接觸的注射模塑體之表面被加熱至50至160℃範圍之溫度,較佳地50至120℃,另較佳地60至110℃,及更佳地60至90℃。
若涵蓋一具裝飾層之發泡的聚胺基甲酸酯系統時,於一另選具體實施,與該熱塑性聚合物組成物接觸或與該裝飾皮接觸的發泡模塑體之表面可被加熱至20至80℃範圍之溫度,較佳地30至60℃。
本發明複合組件特別適合作為鐵路車輛、飛機或汽車之內部或外部組件,及適用於電氣/電子組件與IT組件。
於本發明複合組件中介於該由聚碳酸酯組成物所構成的載體與該聚胺基甲酸酯塗層之間的複合體黏著性,於一較佳具體實施,係為至少1N/mm,依DIN EN 1464以一100mm/min運行速度(traversing speed),於一浮動輥(floating roller)試驗中,在取自該組件之具有20mm寬度的條狀樣品上測得。
用於根據本發明方法中的聚合物組成物包含:
成分A
依照本發明適合的成分A之芳香族聚碳酸酯類及/或芳香族聚酯碳酸酯類為文獻上已知的或可藉文獻上已知的方法製備(用於芳香族聚碳酸酯類之製備見,例如,Schnell,"Chemistry and Physics of Polycarbonates",Interscience Publishers,1964,還有DE-B 1 495 626,DE-A 2 232 877,DE-A 2
703376,DE-A 2 714 544,DE-A 3 000 610,DE-A 3 832 396;用於芳香族聚酯碳酸酯類之製備,例如DE-A 3 077 934)。
製備芳香族聚碳酸酯類及聚酯碳酸酯類係,例如,藉使二酚類與碳酸系鹵化物(carbonic halide)(較佳地光氣)、及/或與芳香族二羰基二鹵化物(較佳地苯二羰基二鹵化物)之反應,藉界面方法,選擇地使用鏈終止劑,例如單酚類,及選擇地使用三官能性或多於三官能性支化劑,例如三酚類或四酚類。經由熔體聚合反應方法透過二酚類與(例如)碳酸二苯酯之反應,其製備同樣可行。
用於該芳香族聚碳酸酯類及/或芳香族聚酯碳酸酯類製備之二酚類較佳為彼等式(I)
式中A 為一單鍵、C1至C5-伸烷基、C2至C5-亞烷基、C5至C6-環亞烷基、-O-、-SO-、-CO-、-S-、-SO2-、C6至C12-伸芳基,可稠合另外的選擇性含有雜原子之芳香族環至其上,或一式(II)或(III)之自由基
B 於各情況下為C1至C12-烷基(較佳地甲基)、鹵素(較佳地氯及/或
溴),x 於各情況下獨立地為0、1或2,p 為1或0,及R5及R6可獨立地被選用於各X1,及各獨立地為氫或C1至C6-烷基,較佳地氫、甲基或乙基,X1 為碳及m 為4至7之整數,較佳地4或5,其條件為在至少一個X1原子上的R5及R6同時為烷基。
較佳的二酚類為氫醌(hydroquinone)、間苯二酚(resorcinol)、二羥基二酚類、雙(羥基苯基)-C1-C5-烷類、雙(羥基苯基)-C5-C6-環烷類、雙(羥基苯基)醚類、雙(羥基苯基)亞碸類(sulphoxides)、雙(羥基苯基)酮類、雙(羥基苯基)碸類(sulphones)及α,α-雙(羥基苯基)二異丙基苯類,及其環-溴化的及/或環-氯化的衍生物。
特佳的二酚類為4,4’-二羥基二苯基、雙酚A、2,4-雙(4-羥基苯基)-2-甲基丁烷、1,1-雙(4-羥基苯基)環己烷、1,1-雙(4-羥基苯基)-3,3,5-三甲基環己烷、4,4’-二羥基二苯基硫化物、4,4’-二羥基二苯基碸及其二-與四溴化的或-氯化的衍生物,例如2,2-雙(3-氯-4-羥基苯基)丙烷、2,2-雙(3,5-二氯-4-羥基苯基)丙烷或2,2-雙(3,5-二溴-4-羥基苯基)丙烷。尤佳的是2,2-雙(4-羥基苯基)丙烷(雙酚A)。
可以單獨地或以任何所希望的混合物之形式使用二酚類。該二酚類為文獻上已知的或可藉文獻上已知方法獲得。
適用於該熱塑性芳香族聚碳酸酯類製備之鏈終止劑實例包括酚、p-氯酚、p-tert-丁基酚或2,4,6-三溴酚,而還有長鏈烷基酚類諸如4-[2-(2,4,4-三甲基戊基)]酚、4-(1,3-四甲基丁基)酚(根據DE-A 2 842 005),或於該烷基取代基中具有總數8至20個碳原子之單烷基酚類或二烷基酚類,諸如3,5-二-tert-丁基酚、p-異辛基酚、p-tert-辛基酚、p-十二烷基酚及2-(3,5-二甲基庚基)酚
及4-(3,5-二甲基庚基)酚。欲被使用的鏈終止劑之用量一般介於0.5mol%至10mol%,於各情況下以所用的二酚類之莫耳和為基準。
該熱塑性芳香族聚碳酸酯類可為以已知方式分支的,較佳地透過合併0.05至2.0mol%的三官能性或多於三官能性化合物,例如彼等具有三個或以上酚系基團,以所用的二酚類之總和為基準。
均聚碳酸酯類及共聚碳酸酯類均適合。對本發明成分A之共聚碳酸酯類之製備,還可以使用1%至25%(以重量計),較佳地2.5%至25%(以重量計)的具有羥基芳氧基端基之聚二有機矽氧烷類,以所用的二酚類之總用量為基準。這些係已知的(US 3 419 634)及可藉由文獻上已知的方法製備。含有聚二有機矽氧烷之共聚碳酸酯類的製備敘述於DE-A 3 334 782。
較佳的聚碳酸酯類(以及該雙酚A均聚碳酸酯類)為雙酚A與至多15mol%(以二酚類之莫耳和為基準)的其它二酚類(具體為較佳的或特佳的、尤其是2,2-雙(3,5-二溴-4-羥基苯基)丙烷)之共聚碳酸酯類。
用於芳香族聚酯碳酸酯類製備之芳香族二羰基二鹵化物較佳為間苯二甲酸、對苯二甲酸、二苯基醚4,4’-二羧酸及萘-2,6-二羧酸之二酸二氯化物。
特別適宜為予以該以介於1:20至20:1比例的間苯二甲酸與對苯二甲酸之二酸二氯化物之混合物。
於聚酯碳酸酯類之製備中,碳酸系鹵化物(較佳地光氣)還用作為雙官能性酸衍生物。
可用於該芳香族聚酯碳酸酯類製備的鏈終止劑包括,除了已述及的單酚類外,其氯碳酸系酯類及該芳香族單羧酸之酸氯化物,其可選擇性被C1至C22-烷基或被鹵素原子所取代,及脂族C2至C22-單羰基氯化物。
該鏈終止劑之用量於各情況下為0.1至10mol%,以於該酚系鏈終止劑情況下的二酚莫耳數及以於單羰基氯化物鏈終止劑情況下的二羰基二氯化物之莫耳數為基準。
該芳香族聚酯碳酸酯類還可含有合併的芳香族羥基羧酸類。
該芳香族聚酯碳酸酯類可以已知方式或為線性或為分支的(見DE-A 2 940 024及DE-A 3 007 934)。
所用的支化劑可,例如,為三-或多官能性羰基氯化物,諸如三甲磺醯基三氯化物(trimesyl trichloride)、三聚氰胺三氯化物、3,3’,4,4’-二苯甲酮四羰基四氯化物、1,4,5,8-萘四羰基四氯化物或苯均四甲酸四氯化物,以0.01至1.0mol%之用量(以所用的二羰基二氯化物為基準),或三-或多官能性酚類,諸如間苯三酚(phloroglucinol)、4,6-二甲基-2,4,6-三(4-羥基苯基)庚-2-烯、4,6-二甲基-2,4-6-三(4-羥基苯基)庚烷、1,3,5-三(4-羥基苯基)苯、1,1,1-三(4-羥基苯基)乙烷、三(4-羥基苯基)苯基甲烷、2,2-雙[4,4-雙(4-羥基苯基)環己基]丙烷、2,4-雙(4-羥基苯基異丙基)酚、四(4-羥基苯基)甲烷、2,6-雙(2-羥基-5-甲基苄基)-4-甲基酚、2-(4-羥基苯基)-2-(2,4-二羥基苯基)丙烷、四(4-[4-羥基苯基異丙基]苯氧基)甲烷、1,4-雙[4,4’-二羥基三苯基)甲基]苯,以0.01至1.0mol%之用量,以所用的二酚類為基準。酚系支化劑最初可與該二酚類一起進料;酸氯化物支化劑可與該酸二氯化物一起被引入。
於該熱塑性芳香族聚酯碳酸酯類中的碳酸酯構造單元之比例可如所希望的變化。較佳地,碳酸酯基團之比例為至多100mol%,尤其是至多80mol%,更佳地至多50mol%,以酯基團與碳酸酯基團之總和為基準。該芳香族聚酯碳酸酯類之酯部分及碳酸酯部分在該聚縮合物中均可以嵌段或以無規分布之形式存在。
芳香族聚碳酸酯類及聚酯碳酸酯類之相對溶液黏度(ηrel)較佳於1.18至1.4之範圍,更佳於1.20至1.32之範圍(在25℃下,於0.5g的聚碳酸酯或聚酯
碳酸酯於100ml的二氯甲烷之溶液中測量)。芳香族聚碳酸酯類及聚酯碳酸酯類之重量平均分子量Mw較佳於15 000至35 000之範圍,另較佳於20 000至33 000之範圍,更佳地23 000至30 000,係藉GPC(凝膠滲透層析法,於二氯甲烷中,以聚碳酸酯作為標準品)測定。
成分B
成分B包含聚丁二烯系接枝聚合物或聚丁二烯系接枝聚合物與不含丁二烯的乙烯基(共)聚合物之混合物,成分B之聚丁二烯含量為至少25.0重量%。
用於成分B之聚丁二烯系接枝聚合物包含B.1 5%至95%,較佳地15%至92%及尤其是25%至60%(以重量計)的至少一種乙烯基單體,以該接枝聚合物為基準,在B.2 95%至5%,較佳地85%至8%及尤其是75%至40%(以重量計)的一或多種聚丁二烯系接枝基質上,以該接枝聚合物為基準。
該接枝基質B.2一般具有一中值粒子大小(d50)為0.05至10.00μm,較佳地0.1至5.0μm,更佳地0.2至1.0μm,及最佳地0.2至0.5μm。
該平均粒子大小(mean particle size)d50為50重量%的粒子落在超過或低於其之直徑。它可藉由超離心測量之方式測得(W.Scholtan,H.Lange,Kolloid,Z.and Z.Polymere 250(1972),782-1796)。
單體B.1較佳為下述之混合物
B.1.1 50%至99%,較佳地65%至85%及尤其是75%至80%(以重量計)的乙烯基芳香族化合物及/或環-取代的乙烯基芳香族化合物(諸如苯乙烯、α-甲基苯乙烯、p-甲基苯乙烯、p-氯苯乙烯)及/或甲基丙烯酸(C1-C8)-烷基酯類(諸如甲基丙烯酸甲基酯、甲基丙烯酸乙基酯),以B.1為基準,及B.1.2 1%至50%,較佳地15%至35%及尤其是20%至25%(以重量計)的乙烯基氰化物(不飽和腈類諸如丙烯腈及甲基丙烯腈)及/或(甲基)丙烯酸
(C1-C8)-烷基酯類諸如甲基丙烯酸甲基酯、丙烯酸n-丁基酯、丙烯酸t-丁基酯,及/或不飽和羧酸之衍生物(諸如酸酐類及醯亞胺類),例如順丁烯二酸酐及N-苯基馬來醯亞胺,以B.1為基準。
單體B.1另較佳為下述之混合物
B.1.1 50%至99%,較佳地65%至85%及尤其是75%至80%(以重量計)的乙烯基芳香族化合物及/或環-取代的乙烯基芳香族化合物(諸如苯乙烯、α-甲基苯乙烯、p-甲基苯乙烯、p-氯苯乙烯),以B.1為基準,及B.1.2 1%至50%,較佳地15%至35%及尤其是20%至25%(以重量計)的乙烯基氰化物(不飽和腈類諸如丙烯腈及甲基丙烯腈)及/或不飽和羧酸之衍生物(諸如酸酐及醯亞胺類),例如順丁烯二酸酐及N-苯基馬來醯亞胺,以B.1為基準。
特佳的單體B.1.1為選自該單體苯乙烯、α-甲基苯乙烯及甲基丙烯酸甲基酯之至少一者;較佳的單體B.1.2為選自該單體丙烯腈及順丁烯二酸酐之至少一者。最佳的單體為B.1.1苯乙烯及B.1.2丙烯腈。
適用於成分B中的接枝聚合物之接枝基質B.2為純的聚丁二烯橡膠或聚丁二烯橡膠之混合物或聚丁二烯橡膠之共聚物或其與另外可共聚的單體(例如根據B.1.1及B.1.2)之混合物,其條件是成分B.2之玻璃轉移溫度為<10℃以下,較佳地<0℃以下,更佳地<-20℃以下。
該玻璃轉移溫度為,根據標準DIN EN 61006,藉由差分熱分析(DSC)之方式,在加熱速率10K/min下測定,以Tg定義為中點溫度(切線方法)。
特佳的接枝基質B.2為純的聚丁二烯橡膠。
於成分B中的特佳接枝聚合物為,例如,ABS聚合物如敘述(例如)於DE-A 2 035 390(=US-A 3 644 574)或於DE-A 2 248 242(=GB-A 1 409 275)或於Ullmanns,Enzyklopadie der Technischen Chemie[Encyclopaedia of
Industrial Chemistry],vol.19(1980),p.280 ff。
於成分B中的接枝聚合物為藉自由基聚合反應製備,例如藉乳化、懸浮或溶液聚合反應,尤其是藉乳化聚合反應。
於一特佳具體實施,不存在任何已由總體聚合反應製備的接枝聚合物。
在於成分B中的接枝聚合物係已以乳化聚合方法製備之情況下,接枝基質B.2之含量較佳為20%至95%(以重量計),更佳地40%至85%(以重量計),尤其是50%至75%(以重量計),以於各情況下該接枝聚合物為基準。
該接枝基質B.2之凝膠含量為至少30重量%,較佳地至少40重量%,尤其是至少60重量%,以於各情況下B.2為基準及測量為於甲苯中之不可溶成分。
因為該接枝反應(如熟知的)不需要將該接枝單體完全地接枝至該接枝基質上,根據本發明,於成分B中的接枝聚合物還了解的是意指彼等在接枝基質B.2存在下藉該接枝單體B.1之(共)聚合反應得到的且還有在處理中得到的產物。這些產物還因而還可含有不會化學上鍵結至該聚丁二烯之接枝單體B.1.的自由基(共)聚合物。
該接枝基質B.2或於成分B中的接枝聚合物之凝膠含量係在25℃下於適合溶劑中測定為不可溶於這些溶劑的成分(M.Hoffmann,H.Kromer,R.Kuhn,Polymeranalytik I und II[Polymer Analysis I and II],Georg Thieme-Verlag,Stuttgart 1977)。
於成分B中不含丁二烯的乙烯基(共)聚合物較佳為至少一種單體之不含丁二烯的均-及/或共聚物B.1,該單體係選自乙烯基芳香族化合物、乙烯基氰化物(不飽和腈類)、(甲基)丙烯酸(C1至C8)-烷基酯類、不飽和羧酸及不飽和羧酸之衍生物(諸如酸酐類及醯亞胺類)之群組。
這些(共)聚合物B.1為樹脂狀、熱塑性且不含丁二烯。更佳地,該共聚物係形成自B.1.1苯乙烯及B.1.2丙烯腈。
這類型的(共)聚合物B.1為已知的及可藉自由基聚合反應製備,尤其是藉乳化、懸浮、溶液或總體聚合反應。該(共)聚合物較佳具有平均分子量Mw(重量-平均,藉GPC測定)介於15 000g/mol至250 000g/mol,較佳於80 000至150 000g/mol之範圍。
成分C
該組成物可包含常用的聚合物添加劑作為成分C。對成分C之可行的常用聚合物添加劑包括添加劑諸如(例如)內部與外部潤滑劑及脫模劑(例如四硬脂酸季戊四醇酯、硬脂酸硬脂醯基酯、褐煤蠟(montan wax)或聚乙烯蠟)、流動性助劑、抗靜電劑(例如環氧乙烷與環氧丙烷之嵌段共聚物,其它聚醚類或聚羥基醚類,聚醚醯胺類,聚酯醯胺類或磺酸鹽類)、導電性添加劑(例如導電性黑料或碳奈米管)、穩定劑(例如UV/光穩定劑,熱穩定劑,抗氧化劑,水解穩定劑)、抗菌添加劑(例如銀或銀鹽)、耐刮擦性-改善添加劑(例如矽酮油或硬質填充劑諸如(中空)陶瓷珠)、IR吸收劑、光學增亮劑、螢光添加劑,還有染料及顏料(例如碳黑,二氧化鈦或氧化鐵)、不涵蓋於B定義的衝擊性改質劑,及作為鹼清除劑(base scavenger)之Brønsted酸系化合物,或者是複數種所述及的添加劑之混合物。
更佳地,本發明組成物包含至少一種脫模劑,較佳地0.1至1.0重量份的四硬脂酸季戊四醇酯,以成分A與B之總和為基準,及至少一種穩定劑,較佳為一酚系抗氧化劑,更佳地0.01至1.0重量份的2,6-二-tert-丁基-4-(十八烷氧基羰基乙基)酚,以成分A與B之總和為基準。
另外適宜為予以至少兩種穩定劑之穩定劑組合,該第二穩定劑包含0.01至1.0重量份的Brønsted酸系化合物,以成分A與B之總和為基準。較佳地,該第二穩定劑為磷酸、含水磷酸溶液或磷酸的自由流動摻合物或具0.01至1.0重量份濃度的細微分散的親水性矽石凝膠之含水磷酸溶液,以成分A與
B之總和為基準。
另一更佳的添加劑為0.05至1.0重量份濃度的檸檬酸,以成分A與B之總和為基準。
於一較佳具體實施,該組成物不包含任何填充劑與強化劑作為成分C,例如滑石、玻璃纖維或碳纖維(選擇地包括磨碎的纖維)、(中空)玻璃或陶瓷珠、雲母、高嶺土、CaCO3及玻璃碎片。
於一另外較佳具體實施,該組成物不包含任何滯焰劑或任何滯焰劑協同劑(諸如抗滴劑)作為成分C。
聚胺基甲酸酯層
所用的聚胺基甲酸酯層較佳為一聚胺基甲酸酯發泡體或一壓實聚胺基甲酸酯層。
依照本發明所用的聚胺基甲酸酯類係藉使聚異氰酸酯類與H-活性多官能性化合物(較佳地多醇類)之反應而獲得的。
於本發明內文中,該術語"聚胺基甲酸酯"還了解的是意指聚胺基甲酸酯脲類,其中所用的H-活性多官能性化合物為彼等具有N-H官能度之化合物,選擇地為與多醇類之摻合物。
適合的聚異氰酸酯類為本身是此項技術領域熟悉者已知的芳香族、芳脂族、脂族或環脂族聚異氰酸酯類及具有較佳地≧2之NCO官能度,其還可具有亞胺氧雜二嗪二酮、異氰脲酸酯、脲二酮、胺基甲酸酯、脲甲酸酯、縮二脲、脲、氧雜二嗪三酮,氧雜唑烷酮(oxazolidinone)、醯基脲及/或碳二醯亞胺結構。這些可單獨或以與彼此之任何所希望的混合物之形式使用。
前述聚異氰酸酯類係以本身是此項技術領域熟悉者已知的二-或三異氰酸酯類為基底及具有脂族性、環脂族性、芳脂族性及/或芳香族性鍵結的異氰酸酯基團,這些是否係已使用光氣或係藉不含光氣之方法製備並不重要。此類二-或三異氰酸酯類之實例為1,4-二異氰酸酯基丁烷、1,5-二異氰酸酯基戊烷、1,6-二異氰酸酯基己烷(HDI)、2-甲基-1,5-二異氰酸酯基戊烷、1,5-二異氰酸酯基-2,2-二甲基戊烷、2,2,4-或2,4,4-三甲基-1,6-二異氰酸酯基己烷、1,10-二異氰酸酯基癸烷、1,3-與1,4-二異氰酸酯基環己烷、1,3-與1,4-雙(異氰酸酯基甲基)環己烷、1-異氰酸酯基-3,3,5-三甲基-5-異氰酸酯基甲基環己烷(異佛爾酮二異氰酸酯,IPDI)、4,4’-二異氰酸酯基二環己基甲烷(Desmodur® W,Bayer AG,Leverkusen,DE)、4-異氰酸酯基甲基-1,8-辛烷二異氰酸酯(三異氰酸酯基壬烷,TIN)、ω,ω’-二異氰酸酯基-1,3-二甲基環己烷(H6XDI)、1-異氰酸酯基-1-甲基-3-異氰酸酯基甲基-環己烷、1-異氰酸酯基-1-甲基-4-異氰酸酯基甲基環己烷、雙(異氰酸酯基甲基)-降冰片烯(norbornane)、萘1,5-二異氰酸酯、1,3-與1,4-雙(2-異氰酸酯基丙-2-基)苯(TMXDI)、2,4-與2,6-二異氰酸酯基甲苯(TDI),尤其是該2,4與該2,6異構物,及該二種異構物之技術級混合物,2,4’-與4,4’-二異氰酸酯基二苯基甲烷(MDI),聚合性MDI(pMDI),1,5-二異氰酸酯基萘,1,3-雙(異氰酸酯基甲基)苯(XDI)及所述及的化合物之任何所希望的混合物。
該聚異氰酸酯類較佳具有一平均NCO官能度為2.0至5.0,較佳為2.2至4.5,更佳為2.2至2.7,及一異氰酸酯基的含量為5.0%至37.0%(以重量計),較佳為14.0%至34.0%(以重量計)。
於一較佳具體實施,使用上述特定類型的聚異氰酸酯類或聚異氰酸酯混合物,其具有專有脂族性及/或環脂族性鍵結的異氰酸酯基團。
最佳地,上述特定類型的聚異氰酸酯類為以六亞甲基二異氰酸酯、異佛爾酮二異氰酸酯、該異構性雙(4,4’-異氰酸酯基環己基)甲烷類及其混合物為基底。
在相當高分子量的改質的聚異氰酸酯類之中,由聚胺基甲酸酯化學已知的具有終端的異氰酸酯基團及分子量範圍為400至15 000(較佳地600至12 000)之預聚物特別受到關注。這些化合物以本身已知的方式藉使過量的上述藉由實例方式特定的類型之單純聚異氰酸酯類與具有對異氰酸酯基團有反應性之至少兩個基團之有機化合物(尤其是有機多羥基化合物)之反應而製備。這類型適合的多羥基化合物為分子量範圍為62至599(較佳地62至200)之單純多元醇類,例如乙二醇、三羥甲基丙烷、丙烷-1,2-二醇或丁烷-1,4-二醇或丁烷-2,3-二醇,而尤其是得自聚胺基甲酸酯化學本身已知的這類型高分子量聚醚多醇類及/或聚酯多醇類,其具有分子量為600至12 000,較佳地800至4000,且具有至少兩個(一般2至8,而較佳地2至6)一級及/或二級羥基基團。當然還可以使用彼等NCO預聚物,其(例如)係已獲自藉由實例方式特定的類型之較低分子量聚異氰酸酯類與具有對異氰酸酯基團有反應性之次佳的化合物,例如聚硫醚多醇類、具有羥基之聚縮醛類、多羥基聚碳酸酯類、具有羥基之聚酯醯胺類或含有羥基之烯烴性不飽和化合物之共聚物。
具有對異氰酸酯基團有反應性之基團(尤其是羥基)且適用於NCO預聚物製備之化合物為,例如,揭示於US-A 4 218 543之化合物。於該NCO預聚物製備中,這些具有對異氰酸酯基團有反應性之基團之化合物係與藉由實例方式特定的類型之上述單純聚異氰酸酯類反應,同時維持NCO過量。該NCO預聚物一般具有NCO含量為10%至26%及較佳為15%至26%(以重量計)。由此已清楚的是,於本發明內文中,"NCO預聚物"及"具有終端異氰酸酯基之預聚物"據了解意指該反應產物及該含過量的未轉換的起始聚異氰酸酯類之混合物二者,其還經常係指為"半預聚物(semiprepolymer)"。
具有OH數為>500mg KOH/g之可用的脂族二醇包括常用於聚胺基甲酸酯化學之鏈延長劑(chain extender),諸如乙二醇、二乙二醇、丙二醇、二丙二醇、丁烷-1,4-二醇、丙烷-1,3-二醇。適宜為予以二醇類諸如2-丁烷-1,4-二醇、丁烷-1,3-二醇、丁烷-2,3-二醇及/或2-甲基丙烷-1,3-二醇。將理解的是以彼此的混合物形式使用脂族二醇類亦是可行的。
適合的H-活性成分為具有平均OH數為5至600mg KOH/g及平均官能度為2至6之多醇類。依照本發明適合的多醇類為,例如,多羥基聚醚類,其可獲自諸如乙二醇、二乙二醇、1,4-二羥基丁烷、1,6-二羥基己烷、二羥甲基丙烷、丙三醇、季戊四醇、山梨糖醇或蔗糖之適合起始劑分子之烷氧化反應。所用的起始劑同樣可為氨或胺類諸如乙二胺、己二胺、2,4-二胺基甲苯、苯胺或胺醇類或酚類(諸如雙酚A)。該烷氧化反應係使用環氧丙烷及/或環氧乙烷以任何所希望的順序或為一混合物之方式實行的。
以及多醇類,其對欲存在的至少一種交聯劑及/或鏈延長劑是另外可行的,係選自包含下述胺類及胺醇類之組群,例如乙醇胺、二乙醇胺、二異丙醇胺、乙二胺、三乙醇胺、異佛爾酮二胺、N,N’-二甲基(二乙基)乙二胺、2-胺基-2-甲基(或乙基)-1-丙醇、2-胺基-1-丁醇、3-胺基-1,2-丙烷二醇、2-胺基-2-甲基(乙基)-1,3-丙烷二醇,及醇類,例如乙二醇、二乙二醇、1,4-二羥基丁烷、1,6-二羥基己烷、二羥甲基丙烷、丙三醇及季戊四醇,還有山梨糖醇及蔗糖,或這些化合物之混合物。
還適合的是聚酯多醇類,其為可以本身已知方式藉低分子量醇類與多元羧酸類(諸如己二酸、鄰苯二甲酸、六氫鄰苯二甲酸、四氫鄰苯二甲酸或這些酸的酸酐類)之反應而獲得,其條件為該H-活性成分之黏度不會變得過高。較佳的具有酯基團之多醇為蓖麻油(castor oil)。還另外適合的是包含蓖麻油之調配物,其如可藉樹脂(例如醛-酮樹脂)之溶解作用,及蓖麻油與以其它天然油為基底的多醇類之改質作用而獲得。
同樣適合的是彼等相當高分子量的多羥基聚醚類,其中高分子量聚加成物或聚縮合物或聚合物係以細微分散的、溶解的或接枝的形式存在。這類型改質的多羥基化合物可以本身已知的方式獲得,例如,當聚加成反應(e.g.於聚異氰酸酯類與胺基-官能性化合物之間的反應)或聚縮合反應(例如於甲醛與酚類及/或胺類之間的反應)時,可使得在具有羥基之化合物中原位進行。替代地,混合一利用多羥基化合物之加工的水性聚合物分散液及之後將水自該混合物中移除亦是可行的。
藉乙烯基聚合物改質的多羥基化合物,如(例如)藉在聚醚類或聚碳酸酯多醇類存在下使苯乙烯與丙烯腈之聚合反應獲得,亦適用於聚胺基甲酸酯類之製備。當使用根據DE-A 2 442 101、DE-A 2 844 922及DE-A 2 646 141藉與乙烯基膦酸酯類及選擇性(甲基)丙烯腈、(甲基)丙烯醯胺或OH-官能性(甲基)丙烯系酯類之接枝聚合反應改質的聚醚多醇類時,可獲得卓越滯焰性之聚合物。
所述及的欲用作為H-活性化合物之代表性化合物敘述(例如)於High Polymers,Vol.XVI,“Polyurethanes Chemistry and Technology”,Saunders-Frisch(ed.)Interscience Publishers,New York,London,vol.1,p.32-42,44,54及vol.II,1984,p.5-6及p.198-199。
使用所列舉化合物之混合物亦是可行的。
該H-活性成分之平均OH數及平均官能度之限制特別是源起於所產生的聚胺基甲酸酯之增加的脆性(embrittlement)。然而,原則上,此項技術領域熟悉者知悉影響該聚胺基甲酸酯之物理聚合物性質之方式,以使NCO成分、脂族二醇及多醇可以有利方式彼此互相配合。
該聚胺基甲酸酯層(b)可為發泡的或固體形式,例如為清漆或塗層形式。
可使用任何本身已知的輔助劑及添加劑製造,例如分離劑、發泡劑(blowing agent)、填充劑、催化劑及滯焰劑。
可選用的輔助劑及添加劑為:
a)水及/或揮發性無機或有機物質作為發泡劑
可用的有機發泡劑包括,例如,丙酮、乙酸乙酯、鹵素-取代的烷類,諸如二氯甲烷、氯仿、亞乙基氯化物、偏氯乙烯、單氟三氯甲烷、氯二氟甲烷、二氯二氟甲烷,還有丁烷、己烷、庚烷或二乙基醚,及可用的無機
發泡劑包括空氣、CO2、或N2O。發泡效果還可透過添加在超過室溫之溫度下隨著氣體除去作用(例如氮氣除去作用)而分解的化合物而達成,實例為偶氮化合物諸如偶氮二甲醯胺(azodicarbonamide)及偶氮異丁腈(azoisobutyronitrile)。
b)催化劑
該催化劑為,例如,三級胺類(諸如三乙基胺、三丁基胺、N-甲基嗎啉、N-乙基嗎啉、N,N,N’,N’-四甲基乙二胺、五甲基二伸乙基三胺及更高級的同系物、1,4-二氮雜雙環[2.2.2]辛烷、N-甲基-N’-二甲基胺基乙基哌嗪、雙(二甲基胺基烷基)哌嗪類、N,N-二甲基苄基胺、N,N-二甲基環己基胺、N,N-二乙基苄基胺、雙(N,N-二乙基胺基乙基)己二酸酯、N,N,N’,N’-四甲基-1,3-丁烷二胺、N,N-二甲基-β-苯基乙基胺、1,2-二甲基-咪唑、2-甲基咪唑)、單環系與雙環系醯胺類、雙(二烷基胺基)烷基醚類、具有醯胺基(較佳地甲醯胺基)之三級胺類、形成自二級胺類(諸如二甲基胺)與醛類(較佳地甲醛)或酮(諸如丙酮、甲基乙基酮或環己酮)及酚類(諸如酚、壬基酚或雙酚)之Mannich鹼、具有對異氰酸酯基團有活性之氫原子之三級胺(e.g.三乙醇胺、三異丙醇胺、N-甲基二乙醇胺、N-乙基二乙醇胺、N,N-二甲基乙醇胺),及其與環氧烷類(諸如環氧丙烷及/或環氧乙烷)之反應產物,二級/三級胺類,具有碳-矽鍵之矽胺類(silaamines)(2,2,4-三甲基-2-矽嗎啉及1,3-二乙基胺基甲基四甲基二矽氧烷),含有氮之鹼(諸如四烷基銨氫氧化物),鹼金屬氫氧化物(諸如氫氧化鈉),鹼金屬苯氧化物(諸如苯氧化鈉),鹼金屬烷氧化物(諸如甲氧化鈉),及/或六氫三嗪類(hexahydrotriazines)。
利用於該內醯胺與該具有酸性氫之化合物之間的結合之初始形成作用,於NCO基團與Zerewitinoff-活性氫原子之間的反應,係以本身已知的方式,還藉內醯胺類(lactams)與氮雜內醯胺類(azalactams)大幅度地加速。
使用有機金屬化合物作為催化劑亦是可行的,尤其是有機錫及/或鉍化合物。可用的有機錫化合物包括,以及硫化合物諸如二-n-辛基錫硫醇鹽(octyltin mercaptide),較佳地羧酸之錫(Il)鹽諸如乙酸錫(II)、辛酸錫(II)、乙
基己酸錫(II)及月桂酸錫(II),及錫(IV)化合物,例如氧化二丁基錫、二氯化二丁基錫、二乙酸二丁基錫、二月桂酸二丁基錫、馬來酸二丁基錫或二乙酸二辛基錫。有機鉍催化劑敘述(例如)於專利申請案WO 2004/000905。
當然可以使用上述提及的任何催化劑作為混合物。於本內文中特別受關注的是有機金屬化合物與脒類(amidines)、胺基吡啶類或肼基吡啶類(hydrazinopyridines)之組合。
該催化劑一般以約0.001%至10%(以重量計)之用量使用,以具有對異氰酸酯有反應性之至少兩個氫原子之化合物之總用量為基準。
c)表面-活性添加劑諸如乳化劑及發泡體穩定劑
可用的乳化劑包括,例如,蓖麻油磺酸鹽之鈉鹽或脂肪酸與胺類之鹽類,諸如油酸二乙基銨鹽或硬脂酸二乙醇銨鹽。使用磺酸之鹼金屬或銨鹽作為表面-活性添加劑亦是可行的,例如十二烷基苯磺酸或二萘基甲烷二磺酸,或脂肪酸諸如蓖麻油酸(ricinoleic acid)或聚合性脂肪酸之鹼金屬或銨鹽。
可用的發泡體穩定劑包括特別是聚醚矽氧烷類,尤其是水溶性代表物。這些化合物之結構一般使得一環氧乙烷與環氧丙烷之共聚物鍵結至聚二甲基矽氧烷自由基。特別關注的是具經由脲甲酸酯基之多重支化(multiple branching)之聚矽氧烷-聚氧伸烷基共聚物。
d)反應延遲劑
可用的反應延遲劑包括,例如,酸性物質(諸如氫氯酸或有機酸鹵化物)。
e)添加劑
可用的PU添加劑包括,例如,本身已知類型之單元調節劑(cell regulator)(諸如石蠟類或脂肪醇類)或二甲基聚矽氧烷類,還有顏料或染料及本身已知類型的滯焰劑(例如參(氯乙基)磷酸酯、三甲酚基磷酸酯或磷酸銨及聚磷酸酯),還有抗老化及風化影響之穩定劑、塑化劑及抑菌性(fungistatic)
與制菌性(bacteriostatic)物質,還有填充劑(諸如硫酸鋇、矽藻土(kieselguhr)、碳黑或沉澱的白堊(precipitated chalk))。
依照本發明任選的另外用途,表面-活性添加劑及發泡體穩定劑,還有單元調節劑、反應延遲劑、穩定劑、滯焰性物質、塑化劑、染料及填充劑,還有抑菌性與制菌性物質之其它實例為此項技術領域熟悉者已知的及敘述於文獻中。
實施例
成分A
以雙酚A為基底之線性聚碳酸酯,具有重量平均分子量Mw為26 000g/mol。
成分B-1
ABS乳化聚合物,具有丙烯腈:丁二烯:苯乙烯比例為20:26:54重量份及該接枝基質之中值粒子大小d50為230nm,藉超離心測量方法測定。
成分B-2
ABS乳化聚合物,具有丙烯腈:丁二烯:苯乙烯重量比例為12:57:31重量份及該接枝基質之中值粒子大小d50為340nm,藉超離心測量方法測定。
成分B-3
ABS總體聚合物,具有丙烯腈:丁二烯:苯乙烯比例為24:10:66重量份及該接枝基質之中值粒子大小d50為700nm,藉超離心測量方法測定。
成分B-4
不含橡膠之共聚物,以總體聚合反應方法,製備自76重量%的苯乙烯與24重量%的丙烯腈,具有重量平均分子量Mw為130 000g/mol(藉GPC以聚苯乙烯作為標準品測定)。
成分C-1
四硬脂酸季戊四醇酯,可商業上獲自如Emery Oleochemicals之Loxiol VPG 861。
成分C-2
Irganox® B900
80重量份的Irgafos® 168(參(2,4-二-tert-丁基)苯基亞磷酸酯)與20重量份的Irganox® 1076(十八烷基3-(3,5-二-tert-丁基-4-羥苯基)丙酸酯)之混合物(BASF,Germany)。
成分C-3
Irganox® 1076(十八烷基3-(3,5-二-tert-丁基-4-羥苯基)-丙酸酯)(BASF,Germany)。
成分C-4
檸檬酸,可商業上獲自Hamann und Reimer。
成分C-5
黑色顏料Black Pearls 800(碳黑),可商業上獲自Cabot Corporation。
成分C-6
雙(2-羥基-3-環己基-5-甲基苯基)甲烷之亞磷酸酯,可商業上獲自如Rhein Chemie Rheinau GmbH之Addovate ThermoStab。
反應性聚胺基甲酸酯塗層系統
所用的聚胺基甲酸酯塗層系統,為一Desmophen® XP 2488(多醇成分)與Desmodur® N3600(聚異氰酸酯成分)之混合物,兩者均得自Bayer MaterialScience AG,Leverkusen,Germany,以1:1.7重量份之混合比例。
Desmophen® XP 2488為分支的聚酯多醇,具有依DIN 53019在20℃下13 250mPa.s之黏度,依DIN 51757在20℃下1.12g/cm3之密度,及16.0%之OH含量。
Desmodur® N3600為以六亞甲基二異氰酸酯為基底的脂族異氰酸酯,具有依DIN EN ISO 11909之NCO含量為23.5重量%,依DIN EN ISO 3219/A.3在23℃下黏度為1200mPa.s,及依DIN EN ISO 2811在20℃下密度為1.16g/cm3。
該聚胺基甲酸酯塗層系統之交聯,係以商業上得自OMG Borchers GmbH,Langenfeld之二月桂酸二丁基錫(DBTL)催化。所添加的量為0.5重量份,以多醇成分與聚異氰酸酯成分之總和為基準。
該聚碳酸酯模塑組成物之製造及特性化
於一雙螺桿擠壓機(twin-screw extruder)(ZSK-25)(得自Werner and Pfleiderer)中,列示於表1之原料在220rpm速度下與在260至280℃範圍之熔融溫度下以20kg/h通量(throughput)被摻合及在該化合物的熔體冷卻與固化之後被粒化。
產生自該特定摻合操作之顆粒係以注射模塑機(得自Arburg)在260℃熔融溫度下與80℃模塑溫度下製得,以得到尺寸80mm x 10mm x 4mm之試驗樣品。
除非另有說明,特定於本申請案中的參數藉下述方法測定:該模塑組成物之延展性(ductility),使用依ISO 180-1A在23℃及-20℃下在這些試驗樣品上測得的耐缺口衝擊性值ak評估。
該模塑組成物之延展性,使用依ISO 180-1U在-30℃下在這些試驗樣品上測得的耐衝擊性值an評估。
耐熱變形性,使用依ISO 306在這些試驗樣品上測得的Vicat B120值評估。
熔體穩定性,使用依ISO 11443在260℃及剪切速率1000s-1下測得的熔體黏度評估。
在斷裂時伸長率,依ISO 527-1,-2之拉伸試驗以50mm/min之延伸速率測量。
於該由聚碳酸酯組成物所構成的基材與該聚胺基甲酸酯皮之間的複合體黏著性,係在具有20mm寬度之條狀樣品(其由此製得的部分PU-塗布的2-成分複合片部分鋸出)上,依DIN EN 1464藉浮動輥(floating roller)試驗以100mm/min之試驗速度測定。
複合組件之製造
具有412cm2之突出區域(projected area)之部分表面-塗布的模塑體以注射模塑機於具有二個空穴(一基材-面空穴與一被連接至RIM系統之聚胺基甲酸酯-面塗層空穴)之注射模塑體中製造。該複合組件係由一熱塑性聚合物(載體)所構成之片狀組件,其表面係已被部分塗布有聚胺基甲酸酯層。該載體模塑體(carrier moulding)之璧厚度為約4mm。該聚胺基甲酸酯層厚度為
200μm。
為更佳描述,敘述於實施例之根據本發明用於製造本發明複合組件之方法示於圖1。
於第一方法步驟中,製造該載體模塑體。為這目的,如表1所述的組成物之熱塑性聚合物顆粒係於一射出-模塑筒(injection-moulding barrel)中熔融及在270℃溫度下注入該閉合的模塑體之第一模塑體空穴內(於圖1之步驟1及2)。將這模塑體空穴加熱至80℃之溫度。在保持-壓力時間及冷卻時間之後,其導致該載體之固化作用,隨時間過去,於第二方法步驟中開啟該模塑體(於圖1之步驟3)。完成此,係藉保持該注射模塑體之推出器面(ejector side)上製造的載體組件及從該載體位置(於圖1之步驟3)連同該模塑體核芯使用一滑桿(slider)將它一起移動至該塗布位置內(於圖1之步驟4)。其後,再度閉合該注射模塑體(於圖1之步驟5),施予一最大壓力200巴之夾持力(clamping force)及,於第三方法步驟中,在約30巴壓力下將該不含溶劑的反應性聚胺基甲酸酯系統(見上述)注入該塗布空穴內(於圖1之步驟6)。完成此,係藉將該聚胺基甲酸酯塗層系統之二個反應性成分從該RIM系統輸送至一高壓逆流混合頭(high-pressure countercurrent mixing head)內及在注入之前於其中混合它們。將該PU-面空穴加熱至80℃溫度。在注入結束後,為了避免該塗層材料之回流(backflow),該聚胺基甲酸酯混合頭之注射噴嘴(injection nozzle)藉由液壓筒(hydraulic cylinder)之方式在50巴壓力下先予密封。在反應及冷卻時間過後,於第四方法步驟中,再次開啟該模塑體(於圖1之步驟7)及將該塗布的模塑體脫模(於圖1之步驟8)。
由表1顯而易見,本發明實施例1至7展現不僅對該聚胺基甲酸酯系統的黏著性上明顯改善作用且有持續高的或改善的韌性及持續高的耐熱變形性與優異的熔體穩定性及高的斷裂時伸長率之組合。最適之性質組合只當該聚丁二烯含量以成分A+B為基準落在本發明範圍內時達成且,同時,不含丁二烯的乙烯基(共)聚合物之含量同樣落在本發明範圍內。如比較例1,若該聚丁二烯含量過低及使用不是藉乳化、懸浮或溶液聚合反應製備的聚丁二烯系接枝聚合物時,該黏著性不會達到產業上所要求的程度。再者,不會達到所要求的耐衝擊性及所要求的穩定性。如於比較例2及3,若不含丁二烯的乙烯基(共)聚合物含量過高時,該黏著性同樣不會到達產業上所要求的程度。更且,不會達到所要求的耐熱變形性及所要求的熔體穩定性。
Claims (15)
- 一種組成物,包含A)55至75重量份的至少一種聚合物,選自包括芳香族聚碳酸酯與芳香族聚酯碳酸酯之構成組群,B)25至45重量份的至少一種混合物,其包含至少一種藉乳化、懸浮或溶液聚合反應製備的聚丁二烯系接枝聚合物與至少一種不含聚丁二烯的乙烯基(共)聚合物,C)0.1至20.0重量份的至少一種聚合物添加劑,以各情況下成分A與B之總和為基準,於此該聚丁二烯含量以成分A與B之重量份總和為基準為10%至20%(以重量計),及於此來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量以成分A與B之重量份總和為基準為12重量%至23重量%,及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
- 根據申請專利範圍第1項之組成物,其特徵在於成分B之丁二烯系接枝聚合物係藉乳化聚合反應製備的。
- 根據申請專利範圍第1或2項之組成物,其中該聚丁二烯系接枝聚合物包含B.1 5重量%至95重量%的至少一種乙烯基單體,以該接枝聚合物為基準,在B.2 95重量%至5重量%的一或多種聚丁二烯接枝基質上,以該接枝聚合物為基準。
- 根據申請專利範圍第3項之組成物,其中成分B.1包含下述之混合物B.1.1 50重量%至99重量%的乙烯基芳香族化合物及/或環-取代的乙烯基芳香族化合物(諸如苯乙烯、α-甲基苯乙烯、p-甲基苯乙烯、p-氯苯乙烯),以B.1為基準,及B.1.2 1重量%至50重量%的乙烯基氰化物及/或不飽和羧酸之衍生物,以B.1為基準。
- 根據申請專利範圍第1或2項之組成物,包含57至74重量份的成分A);26至43重量份的成分B);0.2至15.0重量份的成分C);於此該聚丁二烯含量以成分A與B之重量份總和為基準為11重量%至18重量%及於此來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量,以成分A與B之重量份總和為基準,為12重量%至20重量%,及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
- 根據申請專利範圍第1或2項中一或多項之組成物,包含64至73重量份的成分A);27至36重量份的成分B);0.3至10.0重量份的成分C);於此該聚丁二烯含量以成分A與B之重量份總和為基準為12重量%至17重量%及於此來自成分B之不含丁二烯的乙烯基(共)聚合物之總含量,以成分A與B之重量份總和為基準,為13重量%至19重量%,及於此在該聚碳酸酯組成物中的成分A與B之重量份總和被標定至100。
- 根據申請專利範圍第1或2項中一或多項之組成物,其中成分C包含至少一種聚合物添加劑,選自包括熱穩定劑、脫模劑、色料及UV吸收劑之構成組群。
- 一種複合組件,包含a)一載體,由根據申請專利範圍第1至7項中任一項之熱塑性塑膠組成物所構成b)至少一種聚胺基甲酸酯層,得自包括塗層材料、發泡體及壓實皮之構成組群,包含-至少一種聚異氰酸酯成分,-至少一種多官能性H-活性化合物,及及特徵為NCO-對H-活性基團之莫耳比為1:1至1.1:1。
- 根據申請專利範圍第8項之複合組件,其中該聚胺基甲酸酯層為一具有層厚度為50至300μm之塗層材料。
- 根據申請專利範圍第8項之複合組件,其中該聚胺基甲酸酯層為一具有層厚度為1mm至1cm之發泡體。
- 根據申請專利範圍第8項之複合組件,其中該聚胺基甲酸酯層為一具有層厚度為1mm至4mm之壓實皮。
- 一種製造根據前述申請專利範圍第8至11項中任一項之複合組件之方法,其特徵在於該聚胺基甲酸酯層係已藉反應性聚胺基甲酸酯原料混合物之完全聚合反應製得的,該混合物包含-至少一種聚異氰酸酯成分,-至少一種多官能性H-活性化合物,及其係與該事先已成形自該熱塑性塑膠組成物及固化的載體直接接觸。
- 一種製造根據前述申請專利範圍第8至12項中任一項之複合組件之方法,其特徵在於(i)於第一方法步驟,將該熱塑性塑膠組成物之熔體注入一第一模塑體空穴內及之後冷卻,(ii)於第二方法步驟,將該冷卻的熱塑性塑膠組件移入一較大的空穴內及藉此製得一界定的間隙,(iii)於第三方法步驟,於該熱塑性塑膠組件與該擴大的空穴之模塑體表面之間所形成的間隙內注入有一反應性聚胺基甲酸酯原料混合物,其包含-至少一種聚異氰酸酯成分,-至少一種多官能性H-活性化合物,及與該熱塑性塑膠載體表面直接接觸使該聚胺基甲酸酯原料混合物完全聚合,以得到一壓實聚胺基甲酸酯層或得到一聚胺基甲酸酯發泡體層,(iv)於第四方法步驟,將該複合組件從該模塑體空穴中脫模,方法步驟(i)至(iv)係彼此接著立即連續進行。
- 根據申請專利範圍第13項之方法,特徵在於方法步驟(iii)中,該與熱塑性塑膠組成物接觸之注射模塑體之表面被加熱至60至90℃範圍之溫度,及該與反應性聚胺基甲酸酯混合物接觸之注射模塑體之表面被加熱至60至90℃範圍之溫度。
- 一種根據申請專利範圍第8至11項中任一項之複合組件之用途,係用作為鐵路車輛、飛機或汽車之內部或外部組件及用於電氣/電子組件與IT組件。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
??13189298.6 | 2013-10-18 | ||
EP13189298 | 2013-10-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201529714A TW201529714A (zh) | 2015-08-01 |
TWI642722B true TWI642722B (zh) | 2018-12-01 |
Family
ID=49382342
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW103135770A TWI642722B (zh) | 2013-10-18 | 2014-10-16 | 對聚胺基甲酸酯層具改善之黏著性的聚碳酸酯組成物 |
TW103135768A TWI644974B (zh) | 2013-10-18 | 2014-10-16 | 具有對聚胺基甲酸酯層改良黏著性之聚碳酸酯組成物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW103135768A TWI644974B (zh) | 2013-10-18 | 2014-10-16 | 具有對聚胺基甲酸酯層改良黏著性之聚碳酸酯組成物 |
Country Status (7)
Country | Link |
---|---|
US (2) | US20160251513A1 (zh) |
EP (1) | EP3057755B1 (zh) |
KR (1) | KR20160073390A (zh) |
CN (1) | CN105658397B (zh) |
MX (1) | MX2016004995A (zh) |
TW (2) | TWI642722B (zh) |
WO (1) | WO2015055577A1 (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3293222A1 (en) * | 2016-09-09 | 2018-03-14 | Trinseo Europe GmbH | Multi-layer composite article including polyurethane layer and pc/abs layer |
CN110088178B (zh) | 2016-12-28 | 2022-09-06 | 科思创德国股份有限公司 | 复合部件 |
TWI660964B (zh) * | 2018-02-14 | 2019-06-01 | 遠東新世紀股份有限公司 | 磷酸酯穩定劑的製備方法 |
EP4309864A1 (de) * | 2022-07-18 | 2024-01-24 | Covestro Deutschland AG | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend polycarbonat mit spezifischem oh-gehalt |
WO2024017706A1 (de) * | 2022-07-18 | 2024-01-25 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend polycarbonat mit spezifischem oh-gehalt |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080194756A1 (en) * | 2007-02-12 | 2008-08-14 | General Electric Company | Low gloss polycarbonate compositions |
CN102762372A (zh) * | 2009-12-08 | 2012-10-31 | 拜耳知识产权有限责任公司 | 具有改进的粘附力的得自聚碳酸酯-/聚酯组合物和聚氨酯的复合构件 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4677162A (en) * | 1983-04-15 | 1987-06-30 | Mobay Corporation | Polycarbonate blends having low gloss |
DE3738143A1 (de) * | 1987-11-10 | 1989-05-18 | Bayer Ag | Verwendung von redoxpfropfpolymerisaten zur verbesserung der benzinbestaendigkeit von thermoplastischen, aromatischen polycarbonat- und/oder polyestercarbonat-formmassen |
US5270387A (en) | 1990-01-02 | 1993-12-14 | The Dow Chemical Company | High heat styrenic copolymer blends having improved tensile properties |
US5223573A (en) * | 1992-02-28 | 1993-06-29 | General Electric Company | PC/ABS blends exhibiting reduced gloss |
US5717021A (en) * | 1996-11-18 | 1998-02-10 | General Electric Company | Polycarbonate/ABS blends |
DE19962929A1 (de) * | 1999-12-24 | 2001-06-28 | Bayer Ag | Polycarbonat-Formmassen mit speziellem Talk |
DE10109226A1 (de) * | 2001-02-26 | 2002-09-05 | Bayer Ag | Polycarbonat-Zusammensetzungen mit verbesserter Schaumhaftung |
KR100462531B1 (ko) * | 2002-07-08 | 2004-12-17 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
US20060079615A1 (en) * | 2004-10-12 | 2006-04-13 | Derudder James L | Stabilized blends of polycarbonate with emulsion derived polymers |
DE102004062510A1 (de) * | 2004-12-24 | 2006-07-06 | Bayer Materialscience Ag | Verfahren zum Formen und Beschichten eines Substrats |
DE102005058836A1 (de) * | 2005-12-09 | 2007-06-14 | Bayer Materialscience Ag | Polycarbonat-Formmassen |
DE102005058847A1 (de) * | 2005-12-09 | 2007-06-14 | Bayer Materialscience Ag | Polycarbonat-Formmassen |
DE102009035807A1 (de) * | 2009-08-01 | 2011-02-03 | Bayer Materialscience Ag | Verbesserte Haftung zwischen Thermoplasten und Polyurethan |
US20110135934A1 (en) * | 2009-12-08 | 2011-06-09 | Bayer Materialscience Ag | Process For The Production Of Polyurethane Composite Components |
DE102009058180A1 (de) * | 2009-12-15 | 2011-06-16 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyurethan-Verbundbauteilen |
JP6138822B2 (ja) * | 2011-12-29 | 2017-05-31 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 改良された接着性を有するポリマー組成物 |
-
2014
- 2014-10-13 CN CN201480056819.8A patent/CN105658397B/zh not_active Expired - Fee Related
- 2014-10-13 EP EP14789206.1A patent/EP3057755B1/de not_active Revoked
- 2014-10-13 KR KR1020167012635A patent/KR20160073390A/ko not_active Application Discontinuation
- 2014-10-13 WO PCT/EP2014/071880 patent/WO2015055577A1/de active Application Filing
- 2014-10-13 US US15/027,019 patent/US20160251513A1/en not_active Abandoned
- 2014-10-13 MX MX2016004995A patent/MX2016004995A/es active IP Right Grant
- 2014-10-16 TW TW103135770A patent/TWI642722B/zh not_active IP Right Cessation
- 2014-10-16 TW TW103135768A patent/TWI644974B/zh not_active IP Right Cessation
-
2019
- 2019-01-28 US US16/259,638 patent/US10934429B2/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080194756A1 (en) * | 2007-02-12 | 2008-08-14 | General Electric Company | Low gloss polycarbonate compositions |
CN102762372A (zh) * | 2009-12-08 | 2012-10-31 | 拜耳知识产权有限责任公司 | 具有改进的粘附力的得自聚碳酸酯-/聚酯组合物和聚氨酯的复合构件 |
Also Published As
Publication number | Publication date |
---|---|
US20160251513A1 (en) | 2016-09-01 |
US10934429B2 (en) | 2021-03-02 |
EP3057755B1 (de) | 2020-01-01 |
TW201529713A (zh) | 2015-08-01 |
MX2016004995A (es) | 2017-02-28 |
EP3057755A1 (de) | 2016-08-24 |
US20190153218A1 (en) | 2019-05-23 |
TWI644974B (zh) | 2018-12-21 |
CN105658397A (zh) | 2016-06-08 |
WO2015055577A1 (de) | 2015-04-23 |
CN105658397B (zh) | 2019-05-14 |
TW201529714A (zh) | 2015-08-01 |
KR20160073390A (ko) | 2016-06-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI642721B (zh) | 對於聚胺甲酸酯層具有改良黏著性之聚碳酸酯組成物 | |
TWI588207B (zh) | 製造聚胺基甲酸酯複合組件之方法 | |
JP5931739B2 (ja) | ポリカーボネート/ポリエステル組成物とポリウレタンの改良された接着性を有する複合材料部材 | |
TWI480149B (zh) | 改良熱塑性塑膠與聚胺基甲酸酯之間的黏附 | |
TWI572669B (zh) | 具改良之黏著性之聚合物組成物 | |
US10934429B2 (en) | Polycarbonate compositions having improved adhesion to polyurethane layers | |
US10138370B2 (en) | Polycarbonate compositions having improved adhesion to polyurethane layers | |
CN110088178B (zh) | 复合部件 | |
CN114599736A (zh) | 阻燃聚碳酸酯组合物和由其制成的模塑部件以及制品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |