TWI595615B - Touch panel - Google Patents

Touch panel Download PDF

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Publication number
TWI595615B
TWI595615B TW103111162A TW103111162A TWI595615B TW I595615 B TWI595615 B TW I595615B TW 103111162 A TW103111162 A TW 103111162A TW 103111162 A TW103111162 A TW 103111162A TW I595615 B TWI595615 B TW I595615B
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Taiwan
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conductive film
transparent conductive
pattern
touch panel
transparent
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TW103111162A
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Chinese (zh)
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TW201448148A (en
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Yutaka Ito
Takanori Ohara
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Toppan Printing Co Ltd
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    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • G06F3/0445Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using two or more layers of sensing electrodes, e.g. using two layers of electrodes separated by a dielectric layer

Description

觸控面板 Touch panel

本發明涉及利用已被圖案化的透明導電膜所構成的透明的觸控面板。 The present invention relates to a transparent touch panel constructed using a patterned transparent conductive film.

近年來,使用透明的觸控面板作為在各種電子機器的顯示器上的輸入裝置。就觸控面板的方式而言,可舉出:電阻膜式、靜電容式等。在電阻膜式方面,係藉由上下的電極接觸來檢測出觸摸位置。又,在靜電容式方面,係藉由指尖等碰觸時的表面的靜電容的變化來檢測出觸摸位置。 In recent years, transparent touch panels have been used as input devices on displays of various electronic devices. Examples of the method of the touch panel include a resistive film type and a static capacitance type. In the resistive film type, the touch position is detected by the upper and lower electrode contacts. Further, in the static capacitance type, the touch position is detected by a change in the electrostatic capacitance of the surface when the fingertip or the like touches.

靜電容式的觸控面板大致分為表面電容型和投射型。在投射型方面,作為檢測靜電容的變化的電極,係使用藉由蝕刻處理等而在透明導電膜形成(圖案化)有導電膜的部分和沒有導電膜的部分。此時有導電膜的部分和沒有導電膜的部分的光學特性不一樣,因而導電層的圖案變得醒目,視認性變差。 The capacitive touch panel is roughly classified into a surface capacitive type and a projected type. In the projection type, as the electrode for detecting the change in the electrostatic capacitance, a portion where the conductive film is formed (patterned) in the transparent conductive film and a portion having no conductive film by etching treatment or the like is used. At this time, the optical characteristics of the portion having the conductive film and the portion having no conductive film are different, and thus the pattern of the conductive layer becomes conspicuous and the visibility is deteriorated.

為了使此導電膜的圖案變得不醒目,提出了一種方法,藉由形成以如下方式圖案化的虛擬圖案,來使圖案難以被看到:與供檢測導電膜的觸摸位置使用的有導電膜的部分隔絕地,留下不連續的小面積形狀的導電膜(參照專利文獻1)。 In order to make the pattern of the conductive film unobtrusive, a method has been proposed to make the pattern difficult to see by forming a dummy pattern patterned in such a manner as to be used with a conductive film for detecting a touch position of the conductive film. In part, the conductive film having a discontinuous small-area shape is left in isolation (see Patent Document 1).

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]國際公開第2011/033907號 [Patent Document 1] International Publication No. 2011/033907

然而,若在導電膜使用虛擬圖案則會在幾乎整面上留下導電膜,因導電膜存在所造成的偏黃增加或霧度上升會成為問題。即,若在非導電部形成虛擬圖案,則在電極的導電膜層的圖案、和非導電層部分的虛擬圖案彼此形狀不同,因而導電層的圖案變得醒目、視認性變差。 However, if a dummy pattern is used in the conductive film, a conductive film is left on almost the entire surface, and an increase in yellowing or an increase in haze due to the presence of the conductive film may become a problem. In other words, when the dummy pattern is formed in the non-conductive portion, the pattern of the conductive film layer of the electrode and the dummy pattern of the non-conductive layer portion are different from each other, and thus the pattern of the conductive layer becomes conspicuous and the visibility is deteriorated.

本發明係為了解決如上述的現有技術的課題,提供一種觸控面板,其可以將虛擬圖案的利用抑制在最小限度,謀求偏黃或霧度的降低,且難以看到圖案,從而能提高視認性。 In order to solve the problems of the prior art as described above, the present invention provides a touch panel capable of suppressing the use of a virtual pattern to a minimum, thereby reducing yellowing or haze, and making it difficult to see a pattern, thereby improving visibility. Sex.

用於解決上述課題的本發明的一局面,係一種觸控面板,至少具備:第一透明基板;第一透明導電膜,係圖案化形成在第一透明基板的一方的面;第一金屬配線,係連接於第一透明導電膜;第二透明基板;第二透明導電膜,係圖案化形成在第二透明基板的一方的面;第二金屬配線,係連接於第二透明導電膜;及透明黏著層,第一透明導電膜係實質上已在矩形內部開孔的矩形圖案,第二透明導電膜係實質上已在矩形內部置入 狹縫(slit)的矩形圖案,第一透明導電膜的孔係配置在與第二透明導電膜重疊的位置。 A first aspect of the present invention for solving the above problems is a touch panel comprising at least a first transparent substrate, and a first transparent conductive film patterned on one surface of the first transparent substrate; the first metal wiring And being connected to the first transparent conductive film; the second transparent substrate; the second transparent conductive film is patterned on one surface of the second transparent substrate; and the second metal wiring is connected to the second transparent conductive film; a transparent adhesive layer, the first transparent conductive film is a rectangular pattern having a substantially inner opening in a rectangular shape, and the second transparent conductive film is substantially placed inside the rectangular shape A rectangular pattern of slits, the pores of the first transparent conductive film being disposed at a position overlapping the second transparent conductive film.

又,本發明的其他局面,係一種觸控面板,至少具備:透明基板;第一透明導電膜,係圖案化形成在透明基板的一方的面;第一金屬配線,係連接於第一透明導電膜;第二透明導電膜,係圖案化形成在透明基板的他方的面;第二金屬配線,係連接於第二透明導電膜,第一透明導電膜係實質上已在矩形內部開孔的矩形圖案,第二透明導電膜係實質上已在矩形內部置入狹縫的矩形圖案,第一透明導電膜的孔係配置在與第二透明導電膜重疊的位置。 According to still another aspect of the present invention, a touch panel includes at least: a transparent substrate; the first transparent conductive film is patterned on one surface of the transparent substrate; and the first metal wiring is connected to the first transparent conductive a second transparent conductive film is formed on the other side of the transparent substrate; the second metal wiring is connected to the second transparent conductive film, and the first transparent conductive film is a rectangle having a substantially inner opening in the rectangular shape The pattern, the second transparent conductive film is a rectangular pattern in which a slit is substantially placed inside the rectangle, and the hole of the first transparent conductive film is disposed at a position overlapping the second transparent conductive film.

又,第一透明導電膜的孔,係在已形成在第一透明導電膜的狹縫配置虛擬圖案而形成,在對面板面的俯視下虛擬圖案可以不具有與對向的第二透明導電膜的重疊部。 Further, the hole of the first transparent conductive film is formed by disposing a dummy pattern in the slit formed in the first transparent conductive film, and the dummy pattern may not have the second transparent conductive film opposite to the facing in the plan view of the panel surface. The overlap.

又,在對觸控面板面的俯視下第一透明導電膜的圖案與第二透明導電膜的重疊部的面積可以是平均每個地方在0.0025mm2以上0.10mm2以下的範圍內。 Further, in the plan view of the touch panel area of the face pattern of the first transparent conductive film and the second transparent conductive film overlapping portion may be in the range where the average of 2 or less than 0.0025mm 2 0.10mm.

又,第一透明導電膜的孔,沿著橫貫第二透明導電膜的圖案之邊的寬度,可以比該邊疊置的第二透明導電膜的圖案的寬度寬0.020mm以上0.15mm以下。 Further, the width of the hole of the first transparent conductive film may be 0.020 mm or more and 0.15 mm or less wider than the width of the pattern of the second transparent conductive film stacked on the side along the width of the side of the second transparent conductive film.

又,至少第二透明導電膜的圖案的非狹縫部的最窄部寬度可以在0.050mm以上0.35mm以下的範圍內。 Further, at least the narrowest portion width of the non-slit portion of the pattern of the second transparent conductive film may be in the range of 0.050 mm or more and 0.35 mm or less.

又,至少第二透明導電膜的圖案的狹縫部的 最窄部寬度可以與非狹縫部的最窄部寬度相同或比非狹縫部的最窄部寬度寬。 Further, at least the slit portion of the pattern of the second transparent conductive film The narrowest portion width may be the same as the width of the narrowest portion of the non-slit portion or wider than the width of the narrowest portion of the non-slit portion.

又,透明導電膜可以至少包含奈米金屬線。 Further, the transparent conductive film may contain at least a nanowire.

又,奈米金屬線可以被樹脂層覆蓋。 Also, the nanowire can be covered by the resin layer.

又,第一透明導電膜與第二透明導電膜之間的最短距離可以在20μm以上150μm以下的範圍內。 Further, the shortest distance between the first transparent conductive film and the second transparent conductive film may be in the range of 20 μm or more and 150 μm or less.

又,透明基板的厚度可以在20μm以上150μm以下的範圍內。 Further, the thickness of the transparent substrate may be in the range of 20 μm or more and 150 μm or less.

又,表示觸控面板的透過光的散射的霧度率可以是1.5%以下。 Moreover, the haze ratio indicating the scattering of the transmitted light of the touch panel may be 1.5% or less.

一般而言,為了避免看到已被圖案化形成的透明導電膜的圖案,而採取以下的手法:以不會與電極短路的方式用虛擬的透明導電膜覆蓋透明導電膜的電極部以外的部分。在此狀態下將上下兩層的電極重疊的情況,實質上兩層份的透明導電膜會對偏黃或霧度率造成影響。在本發明中,將透明導電膜的電極圖案作成置入狹縫及開孔的矩形,將一方的透明導電膜的孔配置在與他方的透明導電膜重疊的位置,從而能在抑制偏黃或霧度率下有效地抑制圖案的可見度。尤其是,在將奈米銀線等奈米金屬線用於透明導電膜的情況,是非常有效的。 In general, in order to avoid seeing the pattern of the transparent conductive film which has been patterned, the following method is employed: a portion other than the electrode portion of the transparent conductive film is covered with a dummy transparent conductive film so as not to be short-circuited with the electrode. . In the case where the electrodes of the upper and lower layers are overlapped in this state, substantially the two-layer transparent conductive film affects the yellowing or haze ratio. In the present invention, the electrode pattern of the transparent conductive film is formed into a rectangular shape in which the slit and the opening are formed, and the hole of one of the transparent conductive films is disposed at a position overlapping with the other transparent conductive film, thereby suppressing yellowing or The visibility of the pattern is effectively suppressed at the haze rate. In particular, it is very effective in the case where a nanowire such as a nano silver wire is used for a transparent conductive film.

如上所述,根據本發明,能提供一種觸控面板,其將虛擬圖案的利用抑制在最小限度,謀求偏黃或霧度的降低,且難以看到圖案而提升視認性。 As described above, according to the present invention, it is possible to provide a touch panel which minimizes the use of a virtual pattern, reduces yellowing or haze, and makes it difficult to see a pattern to improve visibility.

1‧‧‧透明基板 1‧‧‧Transparent substrate

2‧‧‧樹脂層 2‧‧‧ resin layer

3‧‧‧硬化膜 3‧‧‧hard film

4‧‧‧光學調節層 4‧‧‧Optical adjustment layer

5‧‧‧透明導電膜 5‧‧‧Transparent conductive film

6‧‧‧透明黏著層 6‧‧‧Transparent adhesive layer

7‧‧‧保護玻璃 7‧‧‧protective glass

10、20、30‧‧‧觸控面板 10, 20, 30‧‧‧ touch panel

40、41、80、81‧‧‧觸控面板的透明導電膜圖案 40, 41, 80, 81‧‧‧ transparent conductive film pattern of touch panel

51、91‧‧‧第一透明導電膜 51, 91‧‧‧ first transparent conductive film

52‧‧‧第二透明導電膜 52‧‧‧Second transparent conductive film

511、911‧‧‧第一透明導電膜導電部 511, 911‧‧‧ first transparent conductive film conductive part

512、914‧‧‧第一透明導電膜孔部 512, 914‧‧‧ first transparent conductive film hole

912‧‧‧第一透明導電膜狹縫部 912‧‧‧The first transparent conductive film slit

913‧‧‧第一透明導電膜虛擬部 913‧‧‧The first transparent conductive film virtual department

521‧‧‧第二透明導電膜導電部 521‧‧‧Second transparent conductive film conductive part

522‧‧‧第二透明導電膜狹縫部 522‧‧‧Second transparent conductive film slit

60、70‧‧‧比較例的觸控面板的透明導電膜圖案 60, 70‧‧‧ Transparent conductive film pattern of the touch panel of the comparative example

第1圖係顯示本發明的實施形態的第一觸控面板的構成的剖面圖。 Fig. 1 is a cross-sectional view showing the configuration of a first touch panel according to an embodiment of the present invention.

第2圖係顯示本發明的實施形態的第二觸控面板的構成的剖面圖。 Fig. 2 is a cross-sectional view showing the configuration of a second touch panel according to an embodiment of the present invention.

第3圖係顯示本發明的實施形態的第三觸控面板的構成的剖面圖。 Fig. 3 is a cross-sectional view showing the configuration of a third touch panel according to an embodiment of the present invention.

第4圖係顯示本發明的第一實施形態的透明導電膜圖案的構成的平面圖。 Fig. 4 is a plan view showing the configuration of a transparent conductive film pattern according to the first embodiment of the present invention.

第5圖係顯示構成本發明的第一實施形態的透明導電膜圖案的重複單位圖案的平面圖。 Fig. 5 is a plan view showing a repeating unit pattern constituting the transparent conductive film pattern of the first embodiment of the present invention.

第6圖係顯示本發明的第一實施形態的第一透明導電膜的圖案的平面圖。 Fig. 6 is a plan view showing the pattern of the first transparent conductive film of the first embodiment of the present invention.

第7圖係顯示本發明的實施形態的第二透明導電膜的圖案的平面圖。 Fig. 7 is a plan view showing a pattern of a second transparent conductive film according to an embodiment of the present invention.

第8圖係顯示本發明的第二實施形態的透明導電膜圖案的構成的平面圖。 Fig. 8 is a plan view showing the configuration of a transparent conductive film pattern according to a second embodiment of the present invention.

第9圖係顯示構成本發明的第二實施形態的透明導電膜圖案的重複單位圖案的平面圖。 Fig. 9 is a plan view showing a repeating unit pattern constituting the transparent conductive film pattern of the second embodiment of the present invention.

第10圖係顯示本發明的第二實施形態的第一透明導電膜的圖案的平面圖。 Fig. 10 is a plan view showing the pattern of the first transparent conductive film of the second embodiment of the present invention.

第11圖係顯示第一比較例的透明導電膜圖案的構成的平面圖。 Fig. 11 is a plan view showing the configuration of a transparent conductive film pattern of the first comparative example.

第12圖係顯示第二比較例的透明導電膜圖案的構成的平面圖。 Fig. 12 is a plan view showing the configuration of the transparent conductive film pattern of the second comparative example.

[實施發明之形態] [Formation of the Invention]

以下,一邊使用圖式一邊說明用於實施本發明的形態。又,本發明不受以下記載的實施形態限定,可以基於同業者的知識添加設計的變更等,添加了這種變更的實施形態也包含在本發明的範圍內。 Hereinafter, embodiments for carrying out the invention will be described using the drawings. Further, the present invention is not limited to the embodiments described below, and may be changed based on the knowledge addition design of the same person, and the embodiment in which such a change is added is also included in the scope of the present invention.

第1圖~第3圖係本發明的觸控面板的剖面構成的一例。 1 to 3 are examples of the cross-sectional structure of the touch panel of the present invention.

第1圖所示的觸控面板10的構成如下:在透明基板1的任一方的面上依序具備透明導電膜5和硬化膜3的兩片基板,彼此用透明黏著層6貼合一方基材的透明基板1的他方的面側與另一方基材的硬化膜3側,再進一步將保護玻璃(cover glass)7透過透明黏著層6貼合在一方基材的硬化膜3側。 The touch panel 10 shown in FIG. 1 has a configuration in which two substrates of the transparent conductive film 5 and the cured film 3 are sequentially provided on one surface of the transparent substrate 1 and are bonded to each other by a transparent adhesive layer 6. On the other side of the transparent substrate 1 and the cured film 3 side of the other substrate, the cover glass 7 is further adhered to the cured film 3 side of the one substrate through the transparent adhesive layer 6.

第2圖所示的觸控面板20的構成如下:在透明基板1的任一方的面上和他方的面上各自依序具備透明導電膜5和硬化膜3,再進一步將保護玻璃7透過透明黏著層6貼合在一方的硬化膜3側。 The touch panel 20 shown in FIG. 2 has a configuration in which the transparent conductive film 5 and the cured film 3 are sequentially provided on one surface and the other surface of the transparent substrate 1, and the protective glass 7 is further transparent. The adhesive layer 6 is bonded to one side of the cured film 3 side.

第3圖所示的觸控面板30的構成如下:在透明基板1的任一方的面上和他方的面上各自依序具備光學調節層4和透明導電膜5,進一步將保護玻璃7透過透明黏著層6貼合在一方的透明導電膜5側,同時在他方的透明導電膜5上具備硬化膜3。 The touch panel 30 shown in FIG. 3 is configured such that the optical adjustment layer 4 and the transparent conductive film 5 are sequentially provided on one surface of the transparent substrate 1 and the other surface thereof, and the protective glass 7 is further transparent. The adhesive layer 6 is bonded to one side of the transparent conductive film 5, and the cured film 3 is provided on the other transparent conductive film 5.

本發明使用的透明基板1,除了玻璃以外,還可使用由樹脂所構成的塑膠薄膜。作為塑膠薄膜,若在 成膜製程及後製程中有充分的強度、表面的平滑性良好的話,便沒有特別限定,例如,可舉出:聚對苯二甲酸乙二酯薄膜、聚對苯二甲酸丁二酯薄膜、聚萘二甲酸乙二酯薄膜、聚碳酸酯薄膜、聚醚碸薄膜、聚碸薄膜、聚芳香酯(polyarylate)薄膜、環狀聚烯烴薄膜、聚醯亞胺薄膜等。其厚度,考量構件的薄型化和積層體的可撓性,使用10μm以上20μm以下左右者,尤其是使用厚度在20μm以上150μm以下範圍內者。又,在將本發明的觸控面板配置在顯示器前面使用的情況下,透明基板必須具有高透明性,適合使用全光透過率為85%以上者。 As the transparent substrate 1 used in the present invention, in addition to glass, a plastic film composed of a resin can be used. As a plastic film, if The film forming process and the post-process are not particularly limited as long as they have sufficient strength and surface smoothness, and examples thereof include a polyethylene terephthalate film and a polybutylene terephthalate film. Polyethylene naphthalate film, polycarbonate film, polyether ruthenium film, polyfluorene film, polyarylate film, cyclic polyolefin film, polyimine film, and the like. The thickness thereof is preferably 10 μm or more and 20 μm or less, in particular, a thickness of 20 μm or more and 150 μm or less is used in consideration of the thickness reduction of the member and the flexibility of the laminate. Moreover, when the touch panel of the present invention is disposed in front of the display, the transparent substrate must have high transparency, and it is suitable to use a total light transmittance of 85% or more.

作為透明基板1所含有的材料,也可以使用周知的各種添加劑或穩定劑,例如抗靜電劑、可塑劑、滑劑、易接著劑等。也可以為了改善與各層的密著性而施加電暈(corona)處理、低溫電漿處理、離子轟擊(ion bombard)處理、藥品處理等作為前處理。 As the material contained in the transparent substrate 1, various known additives or stabilizers such as an antistatic agent, a plasticizer, a slip agent, an easy-adhesive agent and the like can be used. Corona treatment, low temperature plasma treatment, ion bombard treatment, pharmaceutical treatment, or the like may be applied as a pretreatment in order to improve the adhesion to each layer.

在本發明的透明基板1也可以形成樹脂層2。在本發明使用的樹脂層2係為了使透明導電膜6具有機械強度而設置。作為所使用的樹脂,沒有特別限定,較佳為具有透明性、適度的硬度和機械強度的樹脂。具體而言,較佳為如以能期待三維交聯的3官能以上的丙烯酸酯作為主成分的單體或交聯性寡聚物的光硬化性樹脂。樹脂層2,在第1圖的觸控面板10方面係在透明基板1的他方的面上,在第2圖的觸控面板20及第3圖的觸控面板30方面係分別設置在透明基板1的一方的面上和他方的面上。 The resin layer 2 can also be formed on the transparent substrate 1 of the present invention. The resin layer 2 used in the present invention is provided in order to impart mechanical strength to the transparent conductive film 6. The resin to be used is not particularly limited, and is preferably a resin having transparency, moderate hardness, and mechanical strength. Specifically, it is preferably a photocurable resin such as a monomer or a crosslinkable oligomer having a trifunctional or higher acrylate which is three-dimensionally crosslinked as a main component. The resin layer 2 is disposed on the other surface of the transparent substrate 1 in the touch panel 10 of FIG. 1 , and is disposed on the transparent substrate in the touch panel 20 of FIG. 2 and the touch panel 30 of FIG. 3 , respectively. The face of one side of one and the other side of the face.

作為3官能以上的丙烯酸酯單體,較佳為三羥 甲基丙烷三丙烯酸酯、異三聚氰酸EO改性三丙烯酸酯、新戊四醇三丙烯酸酯、二新戊四醇三丙烯酸酯、二新戊四醇四丙烯酸酯、二新戊四醇五丙烯酸酯、二新戊四醇六丙烯酸酯、二三羥甲基丙烷四丙烯酸酯、新戊四醇四丙烯酸酯、聚酯丙烯酸酯等。特佳為異三聚氰酸EO改性三丙烯酸酯及聚酯丙烯酸酯。它們可以單獨使用也可以併用兩種以上。又,除了這些3官能以上的丙烯酸酯以外還可以併用環氧丙烯酸酯、胺基甲酸酯丙烯酸酯、多元醇丙烯酸酯等所謂的丙烯酸系樹脂。 As the trifunctional or higher acrylate monomer, trihydroxyl is preferred Methylpropane triacrylate, isomeric cyanide EO modified triacrylate, neopentyl alcohol triacrylate, dipentaerythritol triacrylate, dipentaerythritol tetraacrylate, dipentaerythritol Pentaacrylate, dipentaerythritol hexaacrylate, ditrimethylolpropane tetraacrylate, neopentyltetraol tetraacrylate, polyester acrylate, and the like. Particularly preferred are isomeric cyanuric acid EO modified triacrylates and polyester acrylates. They may be used singly or in combination of two or more. Further, in addition to these trifunctional or higher acrylates, so-called acrylic resins such as epoxy acrylate, urethane acrylate, and polyol acrylate may be used in combination.

作為交聯性寡聚物,較佳為聚酯(甲基)丙烯酸酯、聚醚(甲基)丙烯酸酯、聚胺基甲酸酯(甲基)丙烯酸酯、環氧(甲基)丙烯酸酯、矽酮(甲基)丙烯酸酯等丙烯酸寡聚物。具體而言有聚乙二醇二(甲基)丙烯酸酯、聚丙二醇二(甲基)丙烯酸酯、雙酚A型環氧丙烯酸酯、聚胺基甲酸酯的二丙烯酸酯、甲酚酚醛型環氧(甲基)丙烯酸酯等。 As the crosslinkable oligomer, polyester (meth) acrylate, polyether (meth) acrylate, polyurethane (meth) acrylate, epoxy (meth) acrylate is preferred. An acrylic oligomer such as an anthrone (meth) acrylate. Specifically, there are polyethylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, bisphenol A epoxy acrylate, polyurethane diacrylate, cresol novolac type Epoxy (meth) acrylate and the like.

樹脂層2亦可於其他含有粒子、光聚合開始劑等的添加劑。 The resin layer 2 may be an additive containing other particles, a photopolymerization initiator, or the like.

作為添加的粒子,可舉出有機或無機的粒子,若考慮透明性的話,則較佳為使用有機粒子。作為有機粒子,可舉出由丙烯酸樹脂、聚苯乙烯樹脂、聚酯樹脂、聚烯烴樹脂、聚醯胺樹脂、聚碳酸酯樹脂、聚胺基甲酸酯樹脂、矽酮樹脂及氟樹脂等所構成的粒子。 The particles to be added include organic or inorganic particles, and when transparency is considered, organic particles are preferably used. Examples of the organic particles include an acrylic resin, a polystyrene resin, a polyester resin, a polyolefin resin, a polyamide resin, a polycarbonate resin, a polyurethane resin, an anthrone resin, and a fluororesin. The particles that make up.

粒子的平均粒子徑,係依樹脂層2的厚度而不同,但從霧度等外觀上的理由考慮,使用下限為2μm以 上,更佳為5μm以上,上限為30μm以下,更佳為15μm以下者。又,基於同樣的理由,粒子的含有量,相對於樹脂,較佳為0.5重量%以上5重量%以下。 The average particle diameter of the particles differs depending on the thickness of the resin layer 2, but from the viewpoint of appearance such as haze, the lower limit of use is 2 μm. More preferably, it is 5 μm or more, and the upper limit is 30 μm or less, and more preferably 15 μm or less. Moreover, for the same reason, the content of the particles is preferably 0.5% by weight or more and 5% by weight or less based on the resin.

在添加光聚合開始劑的情況,作為自由基產生型的光聚合開始劑有苯偶姻、苯偶姻甲基醚、苯偶姻乙基醚、苯偶姻異丙基醚、苄基甲基縮酮(benzil methylketal)等苯偶姻和其烷基醚類;苯乙酮、2,2-二甲氧基-2-苯基苯乙酮、1-羥基環己基苯基酮等苯乙酮類;甲基蒽醌、2-乙基蒽醌、2-戊基蒽醌等蒽醌類;氧硫(thioxanthone)、2,4-二乙基氧硫、2,4-二異丙基氧硫等氧硫類;苯乙酮二甲基二醯、苄基二甲基二醯等二醯類;二苯基酮、4,4-雙甲基胺基二苯基酮等二苯基酮類及偶氮化合物等。它們能單獨使用或以兩種以上的混合物使用,還能與三乙醇胺、甲基二乙醇胺等3級胺;2-二甲基胺基乙基安息香酸、4-二甲基胺基安息香酸乙酯等安息香酸衍生物等的光開始輔助劑組合使用。 In the case of adding a photopolymerization initiator, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzyl methyl group as a radical polymerization type photopolymerization initiator Benzoin (benzil methylketal) and other alkyl ethers; acetophenone, 2,2-dimethoxy-2-phenylacetophenone, 1-hydroxycyclohexyl phenyl ketone and other acetophenone Class; hydrazines such as methyl hydrazine, 2-ethyl hydrazine, 2-pentyl hydrazine; (thioxanthone), 2,4-diethyloxysulfide 2,4-diisopropyloxysulfide Oxygen sulfur a diterpenoid such as acetophenone dimethyl dihydrazine or benzyl dimethyl dihydrazine; diphenyl ketones such as diphenyl ketone and 4,4-dimethylaminodiphenyl ketone; Compounds, etc. They can be used singly or in combination of two or more, and can also be a tertiary amine such as triethanolamine or methyldiethanolamine; 2-dimethylaminoethylbenzoic acid, 4-dimethylaminobenzoic acid B A light-starting adjuvant such as a benzoic acid derivative such as an ester is used in combination.

上述光聚合開始劑的添加量,相對於主成分的樹脂,為0.1重量%以上5重量%以下,較佳為0.5重量%以上3重量%以下。低於下限值則硬塗層(hard coat layer)的硬化變得不充分而不佳。又,在超過上限值的情況,會發生硬塗層變黃、耐候性降低,故而不佳。用來使光硬化型樹脂硬化的光為紫外線、電子線、或是伽瑪線等,在電子線(electron beam)或伽瑪線的情況,不一定要含有光聚合開始劑或光開始助劑。作為這些線源,能使用 高壓水銀燈、氙燈、金屬鹵化物燈或加速電子等。 The amount of the photopolymerization initiator to be added is 0.1% by weight or more and 5% by weight or less, preferably 0.5% by weight or more and 3% by weight or less based on the resin of the main component. Below the lower limit, the hardening of the hard coat layer becomes insufficient. Moreover, when it exceeds the upper limit, the hard coat layer turns yellow and the weather resistance falls, which is not preferable. The light used to harden the photocurable resin is ultraviolet light, electron beam, or gamma line. In the case of an electron beam or a gamma line, it is not necessary to contain a photopolymerization initiator or a photoinitiator. . As these line sources, can be used High-pressure mercury lamps, xenon lamps, metal halide lamps or accelerating electronics.

又,樹脂層2的厚度,沒有特別限定,較佳為在0.5μm以上15μm以下的範圍。又,更佳為折射率與透明基板1相同或是近似,較佳為1.45以上1.75以下左右。 Further, the thickness of the resin layer 2 is not particularly limited, but is preferably in the range of 0.5 μm or more and 15 μm or less. Further, it is more preferable that the refractive index is the same as or similar to that of the transparent substrate 1, and is preferably about 1.45 or more and 1.75 or less.

樹脂層2的形成方法,係使主成分的樹脂等溶解在溶劑,用模具塗布機(die coater)、簾幕流動式塗布機(curtain flow coater)、輥塗布機、逆輥塗布機(reverse roll coater)、凹版塗布機(gravure coater)、刮刀塗布機(knife coater)、棒塗布機、旋轉塗布機、微凹版塗布機(micro-gravure coater)等周知的塗布方法形成。 In the method of forming the resin layer 2, a resin of a main component or the like is dissolved in a solvent, and a die coater, a curtain flow coater, a roll coater, and a reverse roll coater are used. A coating method such as a coater, a gravure coater, a knife coater, a bar coater, a spin coater, or a micro-gravure coater is formed.

對於溶劑,只要是溶解上述主成分的樹脂等者,便沒有特別限定。具體而言,作為溶劑,可舉出:乙醇、異丙醇、異丁醇、苯、甲苯、二甲苯、丙酮、甲基乙基酮、甲基異丁基酮、醋酸乙酯、醋酸n-丁酯、醋酸異戊酯、乳酸乙酯、甲基賽路蘇(methyl cellosolve)、乙基賽路蘇、丁基賽路蘇、甲基賽路蘇乙酸酯、丙二醇單甲基醚乙酸酯等。這些溶劑可以單獨使用一種,也可以併用兩種以上。 The solvent is not particularly limited as long as it is a resin that dissolves the above main component. Specific examples of the solvent include ethanol, isopropanol, isobutanol, benzene, toluene, xylene, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, and acetic acid n- Butyl ester, isoamyl acetate, ethyl lactate, methyl cellosolve, ethyl celecoxib, butyl sirlo, methyl sarbuta acetate, propylene glycol monomethyl ether acetate Ester and the like. These solvents may be used alone or in combination of two or more.

光學調節層4,具有調節透明導電膜的透過率或色相的功能,供使視認性提升用的層。在使用無機化合物作為光學調節層4的情況,可以使用氧化物、硫化物、氟化物、氮化物等材料。由上述無機化合物所構成的薄膜,折射率會因其材料而不同,可以藉由以特定的膜厚形成其折射率不同的薄膜來調節光學特性。在使用有機化合物作為光學調節層4的情況,係藉由將根據目標折 射率的無機化合物添加在與樹脂層2相同的交聯性樹脂,以特定的膜厚形成來使用。又,作為光學調節層的層數,可以根據作為目標光學特性而為複數層。 The optical adjustment layer 4 has a function of adjusting the transmittance or hue of the transparent conductive film, and is used for improving the visibility. In the case where an inorganic compound is used as the optical adjustment layer 4, a material such as an oxide, a sulfide, a fluoride, or a nitride can be used. The film composed of the above inorganic compound differs in refractive index depending on the material thereof, and optical characteristics can be adjusted by forming a film having a different refractive index with a specific film thickness. In the case where an organic compound is used as the optical adjustment layer 4, it is to be folded according to the target The inorganic compound of the incident rate is added to the same crosslinkable resin as the resin layer 2, and is used in a specific film thickness. Further, the number of layers as the optical adjustment layer may be a plurality of layers depending on the target optical characteristics.

作為折射率低的材料,可舉出:氧化鎂(1.6)、二氧化矽(1.5)、氟化鎂(1.4)、氟化鈣(1.3~1.4)、氟化鈰(1.6)、氟化鋁(1.3)等。又,作為折射率高的材料,可舉出:氧化鈦(2.4)、氧化鋯(2.4)、硫化鋅(2.3)、氧化鉭(2.1)、氧化鋅(2.1)、氧化銦(2.0)、氧化鈮(2.3)、氧化鉭(2.2)等。其中,上述括號內的數值表示折射率。 Examples of the material having a low refractive index include magnesium oxide (1.6), cerium oxide (1.5), magnesium fluoride (1.4), calcium fluoride (1.3 to 1.4), cerium fluoride (1.6), and aluminum fluoride. (1.3) and so on. Further, examples of the material having a high refractive index include titanium oxide (2.4), zirconium oxide (2.4), zinc sulfide (2.3), cerium oxide (2.1), zinc oxide (2.1), indium oxide (2.0), and oxidation.铌 (2.3), bismuth oxide (2.2), etc. Here, the numerical value in the above parentheses indicates the refractive index.

透明導電膜5,作為無機化合物,可舉出:氧化銦、氧化鋅、氧化錫的任一者,或是,它們的兩種或三種混合的氧化物,進一步添加其他添加物者,能依照目的、用途使用各種材料,沒有特別限定。目前,可靠性最高、有許多實績的材料為氧化銦錫(ITO)。 The transparent conductive film 5, as the inorganic compound, may be any of indium oxide, zinc oxide, and tin oxide, or an oxide of two or three kinds thereof, and further additives may be added according to the purpose. The use of various materials is not particularly limited. At present, the most reliable material with many achievements is indium tin oxide (ITO).

在使用最常見的透明導電膜的氧化銦錫(ITO)作為透明導電膜5的情況,被摻雜在氧化銦的氧化錫的含有比係根據裝置所要求的規格來選擇任意的比例。例如,在透明基板為塑膠薄膜的情況,在提高機械強度的目的下為了使薄膜結晶化使用的濺鍍靶材料,較佳為氧化錫的含有比低於10重量%,為了將薄膜非晶質化而使其具有可撓性,較佳為氧化錫的含有比係10重量%以上。又,在薄膜要求低電阻的情況,較佳為氧化錫的含有比在2重量%至20重量%的範圍。 In the case where indium tin oxide (ITO) of the most common transparent conductive film is used as the transparent conductive film 5, the content ratio of tin oxide doped with indium oxide is selected in an arbitrary ratio depending on the specifications required for the device. For example, when the transparent substrate is a plastic film, the sputtering target material used for crystallizing the film for the purpose of improving the mechanical strength is preferably such that the content of tin oxide is less than 10% by weight, in order to make the film amorphous. It is made flexible, and it is preferable that the content ratio of tin oxide is 10 weight% or more. Further, in the case where the film requires low resistance, the content ratio of tin oxide is preferably in the range of 2% by weight to 20% by weight.

在光學調節層4及透明導電膜5為無機化合物的情況,作為其製造方法,若可以控制膜厚的話則任何 成膜方法皆可,其中薄膜的形成乾式法是較優的。這能夠使用真空蒸鍍法、濺鍍等物理性氣相析出法或如CVD法的化學性氣相析出法。尤其是,為了在大面積上形成膜質均勻的薄膜,製程穩定、薄膜緻密化的濺鍍法是較佳的。又,在光學調節層4為由有機化合物或塗液或溶液等所形成的情況下,能使用與樹脂層2的形成方法相同的手法。 When the optical adjustment layer 4 and the transparent conductive film 5 are inorganic compounds, any method can be used as the manufacturing method. The film forming method is acceptable, and the dry method of forming the film is superior. This can be carried out by a physical vapor deposition method such as a vacuum deposition method or sputtering or a chemical vapor deposition method such as a CVD method. In particular, in order to form a film having a uniform film quality over a large area, a sputtering method in which the process is stable and the film is densified is preferable. Further, when the optical adjustment layer 4 is formed of an organic compound, a coating liquid, a solution, or the like, the same method as the method of forming the resin layer 2 can be used.

又,透明導電膜5能使用奈米金屬粒子或奈米金屬線、奈米碳管、石墨烯(graphene)、導電性高分子等材料,能藉由使其溶解或分散在有機溶劑或醇、水等,利用塗敷、乾燥來形成。再者,考量作為透明導電膜的片電阻或透明性,更適合使用奈米金屬線。 Further, the transparent conductive film 5 can be made of a material such as a nano metal particle, a nanowire, a carbon nanotube, a graphene or a conductive polymer, and can be dissolved or dispersed in an organic solvent or an alcohol. Water or the like is formed by coating and drying. Further, considering the sheet resistance or transparency of the transparent conductive film, it is more suitable to use a nano metal wire.

奈米金屬線係與樹脂等混合,藉由分散在水或醇、有機溶劑等來調液,藉由在塗敷後進行乾燥,奈米金屬線彼此交纏而成為網眼狀,從而即使是少量的導電性物質仍能形成良好的電性傳導路徑,能使導電性層的電阻值進一步降低。進一步地,在形成這種網眼狀的情況,因為網眼的間隙部分的開口大,因此即使纖維狀的導電性物質本身不是透明的,仍然可以達成作為塗膜的良好的透明性。 The nanowire is mixed with a resin or the like, and is mixed with water, an alcohol, an organic solvent, or the like to adjust the liquid, and after drying after coating, the nanowires are intertwined to form a mesh shape, thereby even A small amount of conductive material can still form a good electrical conduction path, which can further reduce the resistance value of the conductive layer. Further, in the case of forming such a mesh shape, since the opening of the gap portion of the mesh is large, even if the fibrous conductive material itself is not transparent, good transparency as a coating film can be achieved.

作為奈米金屬線的金屬,具體而言,可舉出:鐵、鈷、鎳、銅、鋅、釕、銠、鈀、銀、鎘、鋨、銥、鉑、金,從導電性的觀點考慮,較佳為金、銀、銅、鉑、金。 Specific examples of the metal of the nanowire include iron, cobalt, nickel, copper, zinc, ruthenium, rhodium, palladium, silver, cadmium, osmium, iridium, platinum, and gold, from the viewpoint of electrical conductivity. Preferably, it is gold, silver, copper, platinum or gold.

作為使用奈米金屬線等在透明基板上形成透 明導電膜的方法,能使用噴灑塗布、棒塗布、輥塗布、模具塗布、噴墨塗布、網版塗布、浸漬塗布等周知的塗布方法。 Formed on a transparent substrate by using a nanowire or the like As a method of the conductive film, a well-known coating method such as spray coating, bar coating, roll coating, die coating, inkjet coating, screen coating, or dip coating can be used.

若透明導電層的膜厚太薄,則有不能達成作為導體的充分導電性的傾向,若太厚,則有因霧度值上升、全光線透過率降低等而透明性受損的傾向。通常在10nm以上10μm以下之間進行適宜的調節,但是在如奈米金屬線般導電性物質本身不透明的情況下,會容易因膜厚的增加而喪失透明性,大多形成膜厚更薄的導電層。在此情況是開口部極多的導電層,當用接觸式膜厚計測定時,就平均膜厚而言,膜厚範圍較佳為10nm以上500nm以下,更佳為30nm以上300nm以下,最佳為50nm以上150nm以下。 When the film thickness of the transparent conductive layer is too small, sufficient conductivity as a conductor tends to be insufficient, and if it is too thick, the transparency tends to be impaired due to an increase in the haze value and a decrease in the total light transmittance. Usually, it is suitably adjusted between 10 nm or more and 10 μm or less. However, when the conductive material itself is opaque, such as a nanowire, it is easy to lose transparency due to an increase in film thickness, and most of the conductive thin film is formed. Floor. In this case, the conductive layer has a large number of openings. When the film thickness is measured by a contact film thickness meter, the film thickness is preferably from 10 nm to 500 nm, more preferably from 30 nm to 300 nm. 50 nm or more and 150 nm or less.

硬化膜3,能為了保護透明導電膜5,或使透明導電性薄膜具有機械強度而設置。作為所使用的樹脂,沒有特別限定,較佳為具有透明性和適度的硬度和機械強度的樹脂。具體而言,較佳為如以能期待三維交聯的3官能以上的丙烯酸酯作為主成分的單體或交聯性寡聚物的光硬化性樹脂,能使用與樹脂層2相同的材料形成。形成法也能與樹脂層2相同。 The cured film 3 can be provided to protect the transparent conductive film 5 or to provide mechanical strength to the transparent conductive film. The resin to be used is not particularly limited, and is preferably a resin having transparency and moderate hardness and mechanical strength. Specifically, a photocurable resin such as a monomer or a crosslinkable oligomer having a trifunctional or higher acrylate which is expected to be three-dimensionally crosslinked as a main component can be formed using the same material as the resin layer 2 . . The formation method can also be the same as the resin layer 2.

本發明的光學調節層4或是透明導電膜5,也可以在形成它們之前形成密著層。作為用作密著層的材料,例如,可舉出:矽、鎳、鉻、錫、金、銀、鉑、鋅、鈦、鎢、鋯、鈀等金屬,或是,由兩種以上的這些元素所構成的化合物,或是,這些元素的氧化物、氟化物 、硫化物、氮化物,或是,這些氧化物、氟化物、硫化物、氮化物的混合物等。上述材料當中,氧化物、氟化物、硫化物、氮化物的化學組成,若可讓密著性提升的話,則可以不與化學計量的組成一致。又,也能使用與樹脂層2同樣的丙烯酸樹脂等交聯性樹脂。 The optical adjustment layer 4 of the present invention or the transparent conductive film 5 may form an adhesion layer before forming them. Examples of the material used as the adhesion layer include metals such as ruthenium, nickel, chromium, tin, gold, silver, platinum, zinc, titanium, tungsten, zirconium, and palladium, or two or more of these. a compound composed of elements, or an oxide or fluoride of these elements , sulfides, nitrides, or mixtures of such oxides, fluorides, sulfides, nitrides, and the like. Among the above materials, the chemical composition of oxides, fluorides, sulfides, and nitrides may not conform to the stoichiometric composition if the adhesion can be improved. Further, a crosslinkable resin such as an acrylic resin similar to the resin layer 2 can also be used.

(第一實施形態) (First embodiment)

第一實施形態的透明導電膜5,係施行如第4圖或第5圖的圖案。如第6圖及第7圖般,所形成的圖案係導電性圖案區域(在第6圖的第一透明導電膜51係由導電部511所構成,在第7圖的第二透明導電膜52係由導電部521所構成)、和非導電性圖案區域(在第6圖的第一透明導電膜51係由孔部512所構成,在第7圖的第二透明導電膜52係由狹縫部522所構成)。導電性圖案區域係與金屬配線(未圖示)接觸,連接於能偵測電壓變化的電路。人的手指等,若接近檢測電極的導電性圖案區域,則由於整體的靜電容變化而電路的電壓變動,能判定接觸位置。貼合第6圖及第7圖的圖案,與電壓變化偵測電路連接,從而得到二維的位置資訊。 The transparent conductive film 5 of the first embodiment is a pattern as shown in Fig. 4 or Fig. 5. As shown in FIGS. 6 and 7, the pattern formed is a conductive pattern region (the first transparent conductive film 51 in FIG. 6 is composed of the conductive portion 511, and the second transparent conductive film 52 in FIG. 7 is formed. The conductive portion 521 and the non-conductive pattern region (the first transparent conductive film 51 in FIG. 6 is composed of the hole portion 512, and the second transparent conductive film 52 in FIG. 7 is formed by the slit portion). 522 constitutes). The conductive pattern region is in contact with a metal wiring (not shown) and is connected to a circuit capable of detecting a voltage change. When a human finger or the like approaches the conductive pattern region of the detecting electrode, the voltage of the circuit fluctuates due to the change in the overall electrostatic capacitance, and the contact position can be determined. The pattern of Fig. 6 and Fig. 7 is attached to the voltage change detecting circuit to obtain two-dimensional position information.

作為透明導電膜5的圖案形成方法,可舉出:由在透明導電膜5上塗布或貼合阻劑,利用曝光、顯影形成圖案後使透明導電膜5化學性溶解的光微影術(photolithography)所構成的方法;在真空中利用化學反應使其氣化的方法;利用雷射使透明導電膜昇華的方法等。圖案形成方法,能依照圖案的形狀、精度等適宜選擇,但考慮圖案精度、細線化,較佳為由光微影術所構 成的方法。 As a pattern forming method of the transparent conductive film 5, photolithography (photolithography) in which the transparent conductive film 5 is chemically dissolved by patterning by exposure or development is applied by coating or bonding a resist on the transparent conductive film 5. a method of forming a method of vaporizing a chemical reaction using a chemical reaction in a vacuum, and a method of sublimating a transparent conductive film by using a laser. The pattern forming method can be appropriately selected according to the shape and precision of the pattern, but considering the pattern precision and thinning, it is preferably constructed by photolithography. The method of formation.

在本實施形態的透明導電膜5所形成的圖案,如第4圖~第7圖所示,係第一透明導電膜51和第二透明導電膜52兩種,該第一透明導電膜51具有實質上已在矩形內部開孔的矩形圖案(在第6圖顯示由導電部511和孔部512所構成的第一透明導電膜51),該第二透明導電膜52具有實質上已在矩形內部置入狹縫的矩形圖案(在第7圖顯示由導電部521和狹縫522所構成的第二透明導電膜52),藉由將它們配置在第一透明導電膜51的孔部512與第二透明導電膜52的導電部521重疊的位置,上下地組合,來用作靜電容式觸控面板的電容偵測感測器。透明導電膜5可以在一片透明基材的兩面進行圖案化,也可以在個別的透明基材設置已分別進行圖案化的透明導電膜,透過透明黏著層6加以貼合而上下地配置。利用透明導電膜5所構成的各電極,係分別與金屬配線(未圖示)連接,連接於檢測由第一透明導電膜51所構成的電極與由第二透明導電膜52所構成的電極之間的電容變化的電路,從而作為靜電容式的觸摸感測器(touch sensor)而動作。觸摸感測器最後透過透明黏著層6而與保護玻璃7貼合,從而能製作觸控面板。 The pattern formed by the transparent conductive film 5 of the present embodiment is two types of the first transparent conductive film 51 and the second transparent conductive film 52 as shown in FIGS. 4 to 7 . The first transparent conductive film 51 has a pattern. A rectangular pattern having substantially a hole inside the rectangle (the first transparent conductive film 51 composed of the conductive portion 511 and the hole portion 512 is shown in FIG. 6), and the second transparent conductive film 52 has substantially inside the rectangle A rectangular pattern in which the slit is placed (the second transparent conductive film 52 composed of the conductive portion 521 and the slit 522 is shown in FIG. 7), and they are disposed in the hole portion 512 of the first transparent conductive film 51 and the first portion. The positions where the conductive portions 521 of the two transparent conductive films 52 overlap are combined up and down to be used as a capacitance detecting sensor of the capacitive touch panel. The transparent conductive film 5 may be patterned on both surfaces of a single transparent substrate, or a transparent conductive film which has been separately patterned may be provided on an individual transparent substrate, and may be bonded to the transparent adhesive layer 6 to be placed upside down. Each of the electrodes formed of the transparent conductive film 5 is connected to a metal wiring (not shown), and is connected to an electrode formed of the first transparent conductive film 51 and an electrode composed of the second transparent conductive film 52. A circuit in which a capacitance changes between, and thus acts as a capacitive touch sensor. The touch sensor is finally bonded to the cover glass 7 through the transparent adhesive layer 6, so that the touch panel can be fabricated.

第一透明導電膜51的圖案和第二透明導電膜52的圖案的重疊部的面積,例如能訂定為平均每個地方在0.0025mm2以上0.10mm2以下的範圍內。又,例如第一透明導電膜51的孔512,係將沿著橫貫第二透明導電膜52的圖案之邊的寬度訂定為比該邊疊置的第二透明導電膜 52的寬度寬0.020mm以上0.15mm以下。又,例如第二透明導電膜52的圖案的非狹縫部(導電部521)的最窄部寬度能訂定在0.050mm以上0.35mm以下的範圍內。又,例如第二透明導電膜52的圖案的狹縫部(狹縫522)的最窄部寬度能訂定為與非狹縫部(導電部521)的最窄部寬度相同或比非狹縫部的最窄部寬度寬。透明導電膜例如可以至少包含奈米金屬線,該奈米金屬線例如可以被樹脂層2覆蓋。第一透明導電膜51與第二透明導電膜52之間的最短距離例如能訂定在20μm以上150μm以下的範圍內。 A pattern area of the overlapping portion of the pattern of the first transparent conductive film 51 and the second transparent conductive film 52 of, for example, can be set as the average or more places 0.0025mm 2 to 0.10mm 2 or less range. Further, for example, the hole 512 of the first transparent conductive film 51 defines the width along the side of the pattern traversing the second transparent conductive film 52 to be 0.020 mm wider than the width of the second transparent conductive film 52 overlying the side. Above 0.15mm. Further, for example, the narrowest portion width of the non-slit portion (conductive portion 521) of the pattern of the second transparent conductive film 52 can be set in a range of 0.050 mm or more and 0.35 mm or less. Further, for example, the narrowest portion width of the slit portion (slit 522) of the pattern of the second transparent conductive film 52 can be set to be the same as the narrowest portion width of the non-slit portion (the conductive portion 521) or the most non-slit portion. The width of the narrow portion is wide. The transparent conductive film may, for example, contain at least a nanowire, and the nanowire may be covered, for example, by the resin layer 2. The shortest distance between the first transparent conductive film 51 and the second transparent conductive film 52 can be set, for example, in the range of 20 μm or more and 150 μm or less.

根據上述各構成的觸控面板,便能將表示觸控面板的透過光的散射的霧度率訂定在1.5%以下。 According to the touch panel of each of the above configurations, the haze ratio indicating the scattering of the transmitted light of the touch panel can be set to 1.5% or less.

(第二實施形態) (Second embodiment)

第二實施形態的透明導電膜5,係施行如在第8圖或第9圖以平面圖所示的圖案。第9圖的透明導電膜圖案81係顯示抽出構成第8圖的透明導電膜圖案80的重複的單位圖案者。作為已施加圖案的透明導電膜5,係形成具有實質上已在矩形內部置入狹縫的矩形圖案的第一透明導電膜91和第二透明導電膜52。如第10圖及第7圖般,所形成的圖案係由導電性圖案區域(在第10圖的第一透明導電膜91方面係由導電部911及虛擬圖案的虛擬部913所構成,在第7圖的第二透明導電膜52方面係由導電部521所構成)、和非導電性圖案區域(在第10圖的第一透明導電膜91方面係由在內部包含虛擬部913的狹縫部912所構成,在第7圖的第二透明導電膜52方面係由狹縫部522所構成)所構成。導電性圖案區域係與金屬配線(未圖示)連接 ,連接於能偵測電壓變化的電路。人的手指等,若接近檢測電極的導電性圖案區域,則由於整體的靜電容變化而電路的電壓變動,能判定接觸位置。藉由貼合第10圖及第7圖的圖案,與電壓變化偵測電路連接,來得到二維的位置資訊。 The transparent conductive film 5 of the second embodiment is patterned as shown in plan view in Fig. 8 or Fig. 9. The transparent conductive film pattern 81 of Fig. 9 shows a person who extracts the repeated unit pattern constituting the transparent conductive film pattern 80 of Fig. 8. As the transparent conductive film 5 to which the pattern has been applied, the first transparent conductive film 91 and the second transparent conductive film 52 having a rectangular pattern in which a slit is substantially placed inside the rectangle are formed. As shown in FIGS. 10 and 7, the formed pattern is composed of a conductive pattern region (the first transparent conductive film 91 in FIG. 10 is composed of the conductive portion 911 and the dummy portion 913 of the dummy pattern, in the first The second transparent conductive film 52 in Fig. 7 is composed of the conductive portion 521 and the non-conductive pattern region (the slit portion 912 including the dummy portion 913 in the first transparent conductive film 91 in Fig. 10) The configuration is constituted by the slit portion 522 in the second transparent conductive film 52 of Fig. 7 . The conductive pattern region is connected to a metal wiring (not shown) Connected to a circuit that detects voltage changes. When a human finger or the like approaches the conductive pattern region of the detecting electrode, the voltage of the circuit fluctuates due to the change in the overall electrostatic capacitance, and the contact position can be determined. The two-dimensional position information is obtained by attaching the patterns of FIGS. 10 and 7 to the voltage change detecting circuit.

作為透明導電膜5的圖案形成方法,可舉出:由在透明導電膜5上塗布或貼合阻劑,利用曝光、顯影形成圖案後使透明導電膜5化學性溶解的光微影術所構成的方法;在真空中利用化學反應使其氣化的方法;利用雷射使透明導電膜昇華的方法等。圖案形成方法,能依照圖案的形狀、精度等適宜選擇,但考慮圖案精度、細線化,較佳為利用光微影術的方法。 The pattern forming method of the transparent conductive film 5 is composed of photolithography which is formed by coating or bonding a resist on the transparent conductive film 5, forming a pattern by exposure and development, and chemically dissolving the transparent conductive film 5. A method of vaporizing a chemical reaction in a vacuum; a method of sublimating a transparent conductive film by using a laser. The pattern forming method can be appropriately selected in accordance with the shape, accuracy, and the like of the pattern. However, in consideration of pattern accuracy and thinning, a method using photolithography is preferred.

如第10圖所示,第一透明導電膜91係在狹縫部912的內部圖案化形成虛擬圖案的虛擬部913。藉此,形成在已配置在第一透明導電膜91的各狹縫部912內部的、鄰接的虛擬部913之間的孔914。第一透明導電膜91和第二透明導電膜52,係配置在孔914與第二透明導電膜52的導電部521重疊的位置,上下地予以組合。此時,在對觸控面板面的俯視下,第一透明導電膜虛擬部913不具有與對向的第二透明導電膜52的重疊部。已被圖案化形成的透明導電膜5能用作靜電容式觸控面板的電容偵測感測器。透明導電膜5可以配置在一片透明基材的兩面,也可以在個別的透明基材設置已分別進行圖案化的透明導電膜5,透過透明黏著層6加以貼合而上下地配置。利用透明導電膜5所構成的各電極,係分別與金屬配線(未 圖示)連接,連接於檢測由第一透明導電膜91所構成的電極與由第二透明導電膜52所構成的電極之間的電容變化的電路,從而作為靜電容式的觸摸感測器而動作。觸摸感測器最後透過透明黏著層6而與保護玻璃7貼合,從而能製作觸控面板。 As shown in FIG. 10, the first transparent conductive film 91 is patterned into a dummy portion 913 in which a dummy pattern is formed inside the slit portion 912. Thereby, the hole 914 between the adjacent dummy portions 913 which are disposed inside the respective slit portions 912 of the first transparent conductive film 91 is formed. The first transparent conductive film 91 and the second transparent conductive film 52 are disposed at positions where the holes 914 overlap the conductive portion 521 of the second transparent conductive film 52, and are vertically combined. At this time, the first transparent conductive film dummy portion 913 does not have an overlapping portion with the opposing second transparent conductive film 52 in a plan view of the touch panel surface. The transparent conductive film 5 that has been patterned can be used as a capacitance detecting sensor of a capacitive touch panel. The transparent conductive film 5 may be disposed on both surfaces of a single transparent substrate, or the transparent conductive film 5 which has been separately patterned may be provided on an individual transparent substrate, and may be bonded to the transparent adhesive layer 6 to be placed upside down. Each of the electrodes formed by the transparent conductive film 5 is separately connected to the metal wiring (not The connection is connected to a circuit for detecting a change in capacitance between an electrode composed of the first transparent conductive film 91 and an electrode composed of the second transparent conductive film 52, thereby serving as a capacitive touch sensor. action. The touch sensor is finally bonded to the cover glass 7 through the transparent adhesive layer 6, so that the touch panel can be fabricated.

第一透明導電膜91的圖案和第二透明導電膜52的圖案的重疊部的面積,例如能訂定為平均每個地方在0.0025mm2以上0.10mm2以下的範圍內。又,例如第一透明導電膜91的孔914,係將沿著橫貫第二透明導電膜52的圖案之邊的寬度訂定為比該邊疊置的第二透明導電膜52的寬度寬0.020mm以上0.15mm以下。又,例如第一透明導電膜91的圖案及第二透明導電膜52的圖案的各非狹縫部(第一透明導電膜導電部911、第二透明導電膜導電部521)的最窄部寬度能訂定在0.050mm以上0.35mm以下的範圍內。又,例如第一透明導電膜91的圖案及第二透明導電膜52的圖案的狹縫部(第一透明導電膜狹縫部912、第二透明導電膜狹縫部522)的各最窄部寬度,能訂定為與各自的上述非狹縫部的最窄部寬度相同或比上述非狹縫部的最窄部寬度寬。透明導電膜例如可以至少包含奈米金屬線,該奈米金屬線例如可以被樹脂層2覆蓋。第一透明導電膜51與第二透明導電膜之間的最短距離例如能訂定在20μm以上150μm以下的範圍內。 A pattern area of the overlapping portion of the pattern of the first transparent conductive film 91 and the second transparent conductive film 52 of, for example, can be laid in the range of 2 to less than 0.0025mm 2 0.10mm average place. Further, for example, the hole 914 of the first transparent conductive film 91 defines the width along the side of the pattern traversing the second transparent conductive film 52 to be 0.020 mm wider than the width of the second transparent conductive film 52 overlying the side. Above 0.15mm. Further, for example, the narrowest portion width of each of the non-slit portions (the first transparent conductive film conductive portion 911 and the second transparent conductive film conductive portion 521) of the pattern of the first transparent conductive film 91 and the second transparent conductive film 52 can be It is set in the range of 0.050 mm or more and 0.35 mm or less. In addition, for example, the narrowest portion width of the slit portion (the first transparent conductive film slit portion 912 and the second transparent conductive film slit portion 522) of the pattern of the first transparent conductive film 91 and the pattern of the second transparent conductive film 52 can It is set to be the same as the width of the narrowest portion of each of the non-slit portions or wider than the width of the narrowest portion of the non-slit portion. The transparent conductive film may, for example, contain at least a nanowire, and the nanowire may be covered, for example, by the resin layer 2. The shortest distance between the first transparent conductive film 51 and the second transparent conductive film can be set, for example, in the range of 20 μm or more and 150 μm or less.

根據上述各構成的觸控面板,便能將表示觸控面板的透過光的散射的霧度率訂定在1.5%以下。 According to the touch panel of each of the above configurations, the haze ratio indicating the scattering of the transmitted light of the touch panel can be set to 1.5% or less.

[實施例] [Examples]

以下,利用具體的實施例詳細地說明本發明,但這些實施例係以說明為目的,本發明不受其限定。 Hereinafter, the present invention will be described in detail by way of specific examples, but these examples are intended to be illustrative, and the invention is not limited thereto.

<實施例1> <Example 1>

製作具有與第1圖相同的層構成的觸控面板10。使用PET(50μm)作為透明基板1,將UV硬化性透明丙烯酸樹脂以微凹版塗布在單面作為樹脂層2後,進行乾燥、UV硬化,從而形成3μm的厚度。以成為片電阻100Ω/□的方式將奈米銀線以狹縫式塗布(slot die coat)塗敷在透明基板1的與樹脂層2相反的面作為透明導電膜5,同樣地以130nm的厚度塗敷UV硬化性透明丙烯酸樹脂作為硬化膜3。 A touch panel 10 having the same layer configuration as that of Fig. 1 was produced. PET (50 μm) was used as the transparent substrate 1, and a UV-curable transparent acrylic resin was applied to the resin layer 2 as a single layer on a single surface, followed by drying and UV curing to form a thickness of 3 μm. The nano silver wire was applied to the surface of the transparent substrate 1 opposite to the resin layer 2 as a transparent conductive film 5 by a slot die coat so as to have a sheet resistance of 100 Ω/□, similarly to a thickness of 130 nm. A UV curable transparent acrylic resin is applied as the cured film 3.

藉由將所得到的附透明導電膜的基材分割成兩半,利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方形成為第4圖的以51表示的圖案作為第一透明導電膜,將另一方形成為第4圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜51係在導電部511具有複數個孔部512,孔部的面積為B×C,設為B=500μm、C=300μm,在一方向上相鄰的孔部512彼此係隔著A=280μm配置。第二透明導電膜52係在導電部521具有複數個狹縫部522,導電部的寬度D設為200μm,狹縫部的寬度E設為500μm。當進行光微影時,光阻的顯影係用碳酸鈉水溶液進行,用氯化亞鐵溶液蝕刻奈米銀線,用氫氧化鈉水溶液剝離阻劑。第一及第二透明導電膜係已被隔絕的一個一個透明導電膜電極分別被連接於銀配線。銀配線係藉由用網版印刷來印刷銀膏而形成。 配線寬度為100μm。 By dividing the obtained substrate with the transparent conductive film into two halves, the photoresist is exposed and developed by photolithography, and then etching and peeling resist are performed to form one of the substrates as the fourth image. The pattern indicated by 51 is referred to as a first transparent conductive film, and the other square is a pattern indicated by 52 in FIG. 4 as a second transparent conductive film. The first transparent conductive film 51 has a plurality of holes 512 in the conductive portion 511, and the area of the hole portion is B × C, and B = 500 μm and C = 300 μm, and the hole portions 512 adjacent in one direction are spaced apart from each other. A = 280 μm configuration. The second transparent conductive film 52 has a plurality of slit portions 522 in the conductive portion 521, the width D of the conductive portion is set to 200 μm, and the width E of the slit portion is set to 500 μm. When photolithography is performed, the development of the photoresist is carried out with an aqueous solution of sodium carbonate, the nano silver wire is etched with a ferrous chloride solution, and the resist is peeled off with an aqueous sodium hydroxide solution. The first and second transparent conductive films are respectively connected to the silver wiring by the one transparent conductive film electrodes. The silver wiring is formed by printing silver paste by screen printing. The wiring width is 100 μm.

使用厚度75μm的透明黏著層6貼合由以上所得到的附第一透明導電膜51的基材、和已圖案化形成第二透明導電膜52的基材的兩片基材,同樣地在最表面貼合厚度0.55mm的保護玻璃7,從而得到觸控面板10。第一透明導電膜51及第二透明導電膜52係如第4圖和第5圖所示,以將第二透明導電膜52的導電部521配置在第一透明導電膜51的複數個孔部512上的方式位置精度佳地予以貼合。觸控面板10的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。透過保護玻璃7測定的全光線透過率及霧度率分別為89.8%及1.0%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 The base material with the first transparent conductive film 51 obtained above and the two base materials of the substrate on which the second transparent conductive film 52 has been patterned are bonded together using a transparent adhesive layer 6 having a thickness of 75 μm. The cover glass 10 having a thickness of 0.55 mm is attached to the surface to obtain the touch panel 10. The first transparent conductive film 51 and the second transparent conductive film 52 are arranged as shown in FIGS. 4 and 5 to dispose the conductive portion 521 of the second transparent conductive film 52 in a plurality of holes of the first transparent conductive film 51. The position on the 512 is precisely positioned to fit. In the operation of the touch panel 10, the silver wiring is connected to the drive LSI via the flexible printed circuit board to confirm the operation, and the contact of the finger and the position of the detected coordinate can be satisfactorily detected. The total light transmittance and the haze ratio measured by the cover glass 7 were 89.8% and 1.0%, respectively, and the shape of the pattern was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<實施例2> <Example 2>

製作具有與第2圖相同的層構成的觸控面板20。使用PET(50μm)作為透明基板1,將已添加20wt%的UV吸收劑的UV硬化性透明丙烯酸樹脂以微凹版塗布在兩面作為樹脂層2後,進行乾燥、UV硬化,從而形成5μm的厚度。進一步地,以成為片電阻100Ω/□的方式將奈米銀線以狹縫式塗布塗敷在兩面作為透明導電膜5,同樣地以130nm的厚度塗敷UV硬化性透明丙烯酸樹脂作為硬化膜3。 A touch panel 20 having the same layer configuration as that of FIG. 2 is produced. PET (50 μm) was used as the transparent substrate 1, and a UV curable transparent acrylic resin to which 20 wt% of a UV absorber was added was applied to both sides as a resin layer 2 by microgravure, dried, and UV-cured to form a thickness of 5 μm. Further, the nano silver wire was applied as a transparent conductive film 5 by slit coating so as to have a sheet resistance of 100 Ω/□, and a UV curable transparent acrylic resin was applied as a cured film 3 in a thickness of 130 nm. .

藉由將所得到的附兩面透明導電膜的基材,與實施例1同樣地利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方的面形成為第4圖的以51表示的圖案作為第一透明導電膜,將另一方的面形 成為第4圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜51及第二透明導電膜52的圖案形狀係與實施例1同樣地作成。第一透明導電膜51及第二透明導電膜52,係如第4圖和第5圖所示,以將第二透明導電膜52的導電部521配置在第一透明導電膜51的複數個孔部512上的方式形成。又,銀配線也是與實施例1同樣地形成。 The substrate having the double-sided transparent conductive film obtained was subjected to photolithography in the same manner as in Example 1 to expose and develop the photoresist, and then etching and peeling off the resist to form one surface. The pattern indicated by 51 in Fig. 4 serves as the first transparent conductive film, and the other surface shape The pattern indicated by 52 in Fig. 4 is referred to as a second transparent conductive film. The pattern shapes of the first transparent conductive film 51 and the second transparent conductive film 52 were created in the same manner as in the first embodiment. The first transparent conductive film 51 and the second transparent conductive film 52 are arranged in the plurality of holes of the first transparent conductive film 51 by the conductive portion 521 of the second transparent conductive film 52 as shown in FIGS. 4 and 5 . The form on the portion 512 is formed. Moreover, the silver wiring was also formed in the same manner as in the first embodiment.

在由以上所得到的基材的第二透明導電膜52側,使用厚度75μm的透明黏著層6貼合厚度0.55mm的保護玻璃7,從而得到觸控面板20。觸控面板20的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。透過保護玻璃7測定的全光線透過率及霧度率分別為91.0%及0.9%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 On the second transparent conductive film 52 side of the substrate obtained above, a cover glass 20 having a thickness of 0.55 mm was bonded to the transparent adhesive layer 6 having a thickness of 75 μm to obtain a touch panel 20. In the operation of the touch panel 20, the silver wiring is connected to the drive LSI via the flexible printed circuit board, and the operation is confirmed, whereby the contact of the finger and the position of the detected coordinate can be satisfactorily detected. The total light transmittance and the haze ratio measured by the cover glass 7 were 91.0% and 0.9%, respectively, and the pattern shape was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<實施例3> <Example 3>

製作具有與第3圖相同的層構成的觸控面板30。使用PET(50μm)作為透明基板1,將已添加20wt%的UV吸收劑的UV硬化性透明丙烯酸樹脂以微凹版塗布在兩面作為樹脂層2後,進行乾燥、UV硬化,從而形成5μm的厚度。進一步地,在兩面形成厚度90nm的加入氧化鋯粒子的UV硬化性丙烯酸樹脂作為光學調節層4。此時,光學調節層4的折射率為1.70。所得到的基材係進一步在真空下利用DC磁控濺鍍在兩面形成厚度22nm的ITO(錫含有率5wt%)作為透明導電膜5,在150℃、60分鐘下將其退火,從而得到單面的片電阻150Ω/□。 A touch panel 30 having the same layer configuration as that of Fig. 3 was produced. PET (50 μm) was used as the transparent substrate 1, and a UV curable transparent acrylic resin to which 20 wt% of a UV absorber was added was applied to both sides as a resin layer 2 by microgravure, dried, and UV-cured to form a thickness of 5 μm. Further, a UV curable acrylic resin to which zirconium oxide particles were added having a thickness of 90 nm was formed as an optical adjustment layer 4 on both sides. At this time, the refractive index of the optical adjustment layer 4 was 1.70. The obtained substrate was further subjected to DC magnetron sputtering to form ITO (tin content: 5 wt%) having a thickness of 22 nm on both sides as a transparent conductive film 5, and annealed at 150 ° C for 60 minutes to obtain a single sheet. The sheet resistance of the surface is 150Ω/□.

藉由將所得到的附兩面透明導電膜的基材,與實施例1同樣地利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方的面形成為第4圖的以51表示的圖案作為第一透明導電膜,將另一方的面形成為第4圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜51及第二透明導電膜52的圖案形狀係與實施例1同樣地作成。第一透明導電膜51及第二透明導電膜52,係如第4圖和第5圖所示,以將第二透明導電膜52的導電部521配置在第一透明導電膜51的複數個孔部512上的方式形成。又,銀配線也是與實施例1同樣地形成。進一步在所得到的基材的第一透明導電膜51側用網版印刷塗敷透明樹脂作為硬化膜3後,進行UV硬化從而形成10μm的厚度。 The substrate having the double-sided transparent conductive film obtained was subjected to photolithography in the same manner as in Example 1 to expose and develop the photoresist, and then etching and peeling off the resist to form one surface. The pattern indicated by 51 in Fig. 4 is referred to as a first transparent conductive film, and the other surface is formed as a pattern indicated by 52 in Fig. 4 as a second transparent conductive film. The pattern shapes of the first transparent conductive film 51 and the second transparent conductive film 52 were created in the same manner as in the first embodiment. The first transparent conductive film 51 and the second transparent conductive film 52 are arranged in the plurality of holes of the first transparent conductive film 51 by the conductive portion 521 of the second transparent conductive film 52 as shown in FIGS. 4 and 5 . The form on the portion 512 is formed. Moreover, the silver wiring was also formed in the same manner as in the first embodiment. Further, a transparent resin was applied as a cured film 3 by screen printing on the side of the first transparent conductive film 51 of the obtained substrate, and then UV-cured to form a thickness of 10 μm.

在由以上所得到的基材的第二透明導電膜52側,使用厚度75μm的透明黏著層6貼合厚度0.55mm的保護玻璃7,從而得到觸控面板30。觸控面板30的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。透過保護玻璃7測定的全光線透過率及霧度率分別為90.5%及0.7%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 On the second transparent conductive film 52 side of the substrate obtained above, a cover glass 30 having a thickness of 0.55 mm was bonded to the transparent adhesive layer 6 having a thickness of 75 μm to obtain a touch panel 30. In the operation of the touch panel 30, the silver wiring is connected to the drive LSI via the flexible printed circuit board to confirm the operation, and the contact of the finger and the position of the detected coordinate can be satisfactorily detected. The total light transmittance and the haze ratio measured by the cover glass 7 were 90.5% and 0.7%, respectively, and the shape of the pattern was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<實施例4> <Example 4>

製作具有與第1圖相同的層構成的觸控面板10。使用PET(50μm)作為透明基板,將UV硬化性透明丙烯酸樹脂以微凹版塗布在單面作為樹脂層2後,進行乾燥、UV硬 化,從而形成3μm的厚度。以成為片電阻100Ω/□的方式將奈米銀線以狹縫式塗布塗敷在基板的與樹脂層2相反的面作為透明導電膜5,同樣地以130nm的厚度塗敷UV硬化性透明丙烯酸樹脂作為硬化膜3。 A touch panel 10 having the same layer configuration as that of Fig. 1 was produced. PET (50 μm) was used as a transparent substrate, and a UV curable transparent acrylic resin was applied to a single surface as a resin layer 2 by microgravure, followed by drying and UV hardening. The thickness was formed to a thickness of 3 μm. The nano silver wire was applied to the surface of the substrate opposite to the resin layer 2 as a transparent conductive film 5 by slit coating so as to have a sheet resistance of 100 Ω/□, and UV curable transparent acrylic was applied in the same manner at a thickness of 130 nm. The resin serves as the cured film 3.

藉由將所得到的附透明導電膜的基材分割成兩半,利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方形成為第8圖的以91表示的圖案作為第一透明導電膜,將另一方形成為第8圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜91係在導電部911具有複數個狹縫部912,在狹縫內部有虛擬部913,該虛擬部913係在對面板面的俯視下、以不具有與第二透明導電膜52的重疊部的方式所配置的虛擬圖案。第一透明導電膜91的導電部的寬度A設為200μm,狹縫部912的寬度B設為300μm。第二透明導電膜52係在導電部521具有複數個狹縫部522,導電部的寬度D設為200μm,狹縫部的寬度E設為500μm。當進行光微影時,光阻的顯影係用碳酸鈉水溶液進行,用氯化亞鐵溶液蝕刻奈米銀線,用氫氧化鈉水溶液剝離阻劑。 By dividing the obtained base material with a transparent conductive film into two halves, the photoresist is exposed and developed by photolithography, and then etching and peeling resist are performed to form one of the substrates as the eighth figure. The pattern indicated by 91 is referred to as a first transparent conductive film, and the other square is a pattern indicated by 52 in FIG. 8 as a second transparent conductive film. The first transparent conductive film 91 has a plurality of slit portions 912 in the conductive portion 911, and has a dummy portion 913 inside the slit, and the dummy portion 913 does not have the second transparent conductive film 52 in a plan view of the panel surface. The virtual pattern of the overlapping portion of the way. The width A of the conductive portion of the first transparent conductive film 91 is set to 200 μm, and the width B of the slit portion 912 is set to 300 μm. The second transparent conductive film 52 has a plurality of slit portions 522 in the conductive portion 521, the width D of the conductive portion is set to 200 μm, and the width E of the slit portion is set to 500 μm. When photolithography is performed, the development of the photoresist is carried out with an aqueous solution of sodium carbonate, the nano silver wire is etched with a ferrous chloride solution, and the resist is peeled off with an aqueous sodium hydroxide solution.

第一及第二透明導電膜91、52係已被隔絕的一個一個透明導電膜電極分別被連接於銀配線。銀配線係藉由用網版印刷來印刷銀膏而形成。配線寬度為100μm。 The ones of the first and second transparent conductive films 91, 52, which have been isolated, are respectively connected to the silver wiring. The silver wiring is formed by printing silver paste by screen printing. The wiring width is 100 μm.

使用厚度75μm的透明黏著層6貼合由以上所得到的附第一及第二透明導電膜91、52的兩片基材,同樣地在最表面貼合厚度0.55mm的保護玻璃7,從而得到 觸控面板。第一及第二透明導電膜91、52係如第8圖和第9圖所示,以第一透明導電膜91的狹縫部912的虛擬部913與第二透明導電膜52的導電部521不重疊的方式位置精度佳地予以貼合。此時,第一透明導電膜91和第二透明導電膜52的圖案的重疊部的面積為平均每個地方0.04mm2。觸控面板的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。 The two base materials with the first and second transparent conductive films 91 and 52 obtained above were bonded to each other using a transparent adhesive layer 6 having a thickness of 75 μm, and the protective glass 7 having a thickness of 0.55 mm was bonded to the outermost surface in the same manner. Touch panel. The first and second transparent conductive films 91 and 52 are as shown in FIGS. 8 and 9 , and the dummy portion 913 of the slit portion 912 of the first transparent conductive film 91 and the conductive portion 521 of the second transparent conductive film 52 are not The overlapping position is precisely matched to the positional accuracy. At this time, the area of the overlapping portion of the pattern of the first transparent conductive film 91 and the second transparent conductive film 52 is 0.04 mm 2 on average per place. In the operation of the touch panel, the silver wiring is connected to the drive LSI via the flexible printed circuit board, and the operation is confirmed, so that the contact of the finger and the position of the detected coordinate can be satisfactorily detected.

透過保護玻璃7測定的全光線透過率及霧度率分別為89.9%及1.0%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 The total light transmittance and the haze ratio measured by the cover glass 7 were 89.9% and 1.0%, respectively, and the pattern shape was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<實施例5> <Example 5>

製作具有與第2圖相同的層構成的觸控面板20。使用PET(50μm)作為透明基板,將已添加20wt%的UV吸收劑的UV硬化性透明丙烯酸樹脂以微凹版塗布在兩面作為樹脂層2後,進行乾燥、UV硬化,從而形成5μm的厚度。進一步地,以成為片電阻100Ω/□的方式將奈米銀線以狹縫式塗布塗敷在兩面作為透明導電膜5,同樣地以130nm的厚度塗敷UV硬化性透明丙烯酸樹脂作為硬化膜3。 A touch panel 20 having the same layer configuration as that of FIG. 2 is produced. PET (50 μm) was used as a transparent substrate, and a UV curable transparent acrylic resin to which 20 wt% of a UV absorber was added was applied to both sides as a resin layer 2 by microgravure, dried, and UV-cured to form a thickness of 5 μm. Further, the nano silver wire was applied as a transparent conductive film 5 by slit coating so as to have a sheet resistance of 100 Ω/□, and a UV curable transparent acrylic resin was applied as a cured film 3 in a thickness of 130 nm. .

藉由將所得到的附兩面透明導電膜的基材,與實施例4同樣地利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方的面形成為第8圖的以91表示的圖案作為第一透明導電膜,將另一方的面形成為第8圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜91及第二透明導電膜52的圖案形狀係與實施 例4同樣地作成。第一及第二透明導電膜91、52,係如第8圖和第9圖所示,在對面板面的俯視下、以第一透明導電膜91的狹縫部912的虛擬部913與第二透明導電膜52的導電部521不具有重疊部的方式位置精度佳地予以貼合。此時,第一透明導電膜91和第二透明導電膜51的圖案的重疊部面積為平均每個地方0.04mm2。又,銀配線亦與實施例4同樣地形成。 The base material with the double-sided transparent conductive film obtained was subjected to photolithography in the same manner as in Example 4, and after exposure and development of the photoresist, etching and peeling of the resist were performed to form one surface. The pattern indicated by 91 in Fig. 8 is referred to as a first transparent conductive film, and the other surface is formed as a pattern indicated by 52 in Fig. 8 as a second transparent conductive film. The pattern shapes of the first transparent conductive film 91 and the second transparent conductive film 52 were created in the same manner as in the fourth embodiment. The first and second transparent conductive films 91 and 52 are as shown in Figs. 8 and 9 and have a dummy portion 913 and a second portion of the slit portion 912 of the first transparent conductive film 91 in a plan view of the panel surface. The conductive portion 521 of the transparent conductive film 52 is bonded to each other without having an overlapping portion. At this time, the overlapping portion area of the pattern of the first transparent conductive film 91 and the second transparent conductive film 51 is 0.04 mm 2 on average per place. Further, the silver wiring was also formed in the same manner as in the fourth embodiment.

在由以上所得到的基材的第二透明導電膜52側,使用厚度75μm的透明黏著層6貼合厚度0.55mm的保護玻璃7,從而得到觸控面板。觸控面板的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。 On the second transparent conductive film 52 side of the substrate obtained above, a cover glass having a thickness of 0.55 mm was bonded to the transparent adhesive layer 6 having a thickness of 75 μm to obtain a touch panel. In the operation of the touch panel, the silver wiring is connected to the drive LSI via the flexible printed circuit board, and the operation is confirmed, so that the contact of the finger and the position of the detected coordinate can be satisfactorily detected.

透過保護玻璃7測定的全光線透過率及霧度率分別為91.1%及0.9%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 The total light transmittance and the haze ratio measured by the cover glass 7 were 91.1% and 0.9%, respectively, and the shape of the pattern was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<實施例6> <Example 6>

製作具有與第3圖相同的層構成的觸控面板30。使用PET(50μm)作為透明基板,將已添加20wt%的UV吸收劑的UV硬化性透明丙烯酸樹脂以微凹版塗布在兩面作為樹脂層2後,進行乾燥、UV硬化,從而形成5μm的厚度。進一步地,在兩面形成厚度90nm的加入氧化鋯粒子的UV硬化性丙烯酸樹脂作為光學調節層4。此時,光學調節層4的折射率為1.70。所得到的基材係進一步在真空下利用DC磁控濺鍍在兩面形成厚度22nm的ITO(錫含有率5wt%)作為透明導電膜5,在150℃、60分鐘下將其退火,從而 得到單面的片電阻150Ω/□。 A touch panel 30 having the same layer configuration as that of Fig. 3 was produced. PET (50 μm) was used as a transparent substrate, and a UV curable transparent acrylic resin to which 20 wt% of a UV absorber was added was applied to both sides as a resin layer 2 by microgravure, dried, and UV-cured to form a thickness of 5 μm. Further, a UV curable acrylic resin to which zirconium oxide particles were added having a thickness of 90 nm was formed as an optical adjustment layer 4 on both sides. At this time, the refractive index of the optical adjustment layer 4 was 1.70. The obtained substrate was further subjected to DC magnetron sputtering to form ITO (tin content: 5 wt%) having a thickness of 22 nm on both sides as a transparent conductive film 5, and annealed at 150 ° C for 60 minutes. A one-sided sheet resistance of 150 Ω/□ was obtained.

藉由將所得到的附兩面透明導電膜的基材,與實施例4同樣地利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,來將一方的面形成為第8圖的以91表示的圖案作為第一透明導電膜,將另一方的面形成為第8圖的以52表示的圖案作為第二透明導電膜。第一透明導電膜91及第二透明導電膜52的圖案形狀係與實施例4同樣地作成。第一及第二透明導電膜91、52,係如第8圖和第9圖所示,在對面板面的俯視下、以第一透明導電膜91的狹縫部812的虛擬部813與第二透明導電膜52的導電部521不具有重疊部的方式位置精度佳地予以貼合。此時,第一透明導電膜91和第二透明導電膜52的圖案的重疊部面積為平均每個地方0.04mm2。又,銀配線亦與實施例4同樣地形成。進一步在所得到的基材的第一透明導電膜91側用網版印刷塗敷透明樹脂作為硬化膜3後,進行UV硬化從而形成10μm的厚度。 The base material with the double-sided transparent conductive film obtained was subjected to photolithography in the same manner as in Example 4, and after exposure and development of the photoresist, etching and peeling of the resist were performed to form one surface. The pattern indicated by 91 in Fig. 8 is referred to as a first transparent conductive film, and the other surface is formed as a pattern indicated by 52 in Fig. 8 as a second transparent conductive film. The pattern shapes of the first transparent conductive film 91 and the second transparent conductive film 52 were created in the same manner as in the fourth embodiment. The first and second transparent conductive films 91 and 52 are as shown in Figs. 8 and 9 and have a dummy portion 813 and a second portion of the slit portion 812 of the first transparent conductive film 91 in plan view of the panel surface. The conductive portion 521 of the transparent conductive film 52 is bonded to each other without having an overlapping portion. At this time, the overlapping portion area of the pattern of the first transparent conductive film 91 and the second transparent conductive film 52 is 0.04 mm 2 on average per place. Further, the silver wiring was also formed in the same manner as in the fourth embodiment. Further, a transparent resin was applied as a cured film 3 by screen printing on the side of the first transparent conductive film 91 of the obtained substrate, and then UV-cured to form a thickness of 10 μm.

在由以上所得到的基材的第二透明導電膜52側,使用厚度75μm的透明黏著層6貼合厚度0.55mm的保護玻璃7,從而得到觸控面板。觸控面板的動作係將銀配線經由可撓性印刷基板連接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。 On the second transparent conductive film 52 side of the substrate obtained above, a cover glass having a thickness of 0.55 mm was bonded to the transparent adhesive layer 6 having a thickness of 75 μm to obtain a touch panel. In the operation of the touch panel, the silver wiring is connected to the drive LSI via the flexible printed circuit board, and the operation is confirmed, so that the contact of the finger and the position of the detected coordinate can be satisfactorily detected.

透過保護玻璃7測定的全光線透過率及霧度率分別為90.5%及0.7%,在螢光燈下觀察時圖案形狀不醒目而幾乎看不到。 The total light transmittance and the haze ratio measured by the cover glass 7 were 90.5% and 0.7%, respectively, and the shape of the pattern was not noticeable when viewed under a fluorescent lamp, and was hardly seen.

<比較例1> <Comparative Example 1>

製作具有與第1圖相同的層構成的觸控面板10。使用PET(50μm)作為透明基板,將UV硬化性透明丙烯酸樹脂以微凹版塗布在單面作為樹脂層2後,進行乾燥、UV硬化,從而形成3μm的厚度。以成為片電阻100Ω/□的方式將奈米銀線以狹縫式塗布塗敷在基板的與樹脂層2相反的面作為透明導電膜5,同樣地以130nm的厚度塗敷UV硬化性透明丙烯酸樹脂作為硬化膜3。 A touch panel 10 having the same layer configuration as that of Fig. 1 was produced. PET (50 μm) was used as a transparent substrate, and a UV curable transparent acrylic resin was applied to the resin layer 2 as a single layer on a single surface, followed by drying and UV curing to form a thickness of 3 μm. The nano silver wire was applied to the surface of the substrate opposite to the resin layer 2 as a transparent conductive film 5 by slit coating so as to have a sheet resistance of 100 Ω/□, and UV curable transparent acrylic was applied in the same manner at a thickness of 130 nm. The resin serves as the cured film 3.

藉由將所得到的附透明導電膜的基板分割成兩半,利用光微影術,在光阻進行曝光、顯影後,進行蝕刻及剝離阻劑,如第11圖的平面圖所示的透明導電膜圖案60般,將一方形成為以61表示的圖案作為第一透明導電膜,將另一方形成為以62表示的圖案作為第二透明導電膜。當進行光微影時,光阻的顯影係用碳酸鈉水溶液進行,用氯化亞鐵溶液蝕刻奈米銀線,用氫氧化鈉水溶液剝離阻劑。 By dividing the obtained substrate with the transparent conductive film into two halves, the photoresist is exposed and developed by photolithography, and then the etching and peeling resist are performed, as shown in the plan view of FIG. Similarly to the film pattern 60, one of the squares is formed as a first transparent conductive film, and the other square is a pattern of 62 as a second transparent conductive film. When photolithography is performed, the development of the photoresist is carried out with an aqueous solution of sodium carbonate, the nano silver wire is etched with a ferrous chloride solution, and the resist is peeled off with an aqueous sodium hydroxide solution.

第一及第二透明導電膜61、62係已被隔絕的一個一個透明導電膜電極分別被連接於銀配線。銀配線係藉由用網版印刷來印刷銀膏而形成。配線寬度為100μm。 The ones of the first and second transparent conductive films 61, 62, which have been isolated, are respectively connected to the silver wiring. The silver wiring is formed by printing silver paste by screen printing. The wiring width is 100 μm.

使用厚度75μm的透明黏著層6貼合由以上所得到的附第一及第二透明導電膜61、62的兩片基材,同樣地在最表面貼合厚度0.55mm的保護玻璃7,從而得到觸控面板。第一及第二透明導電膜61、62係如第11圖所示,以透明導電膜圖案的長邊相互交叉90°的方式予以貼合。觸控面板的動作係將銀配線經由可撓性印刷基板連 接驅動LSI進行動作確認,從而能良好地偵測手指的接觸和檢測座標位置。 The two base materials with the first and second transparent conductive films 61 and 62 obtained above were bonded to each other using a transparent adhesive layer 6 having a thickness of 75 μm, and the cover glass 7 having a thickness of 0.55 mm was bonded to the outermost surface in the same manner. Touch panel. The first and second transparent conductive films 61 and 62 are bonded to each other such that the long sides of the transparent conductive film pattern intersect each other by 90° as shown in Fig. 11 . The operation of the touch panel connects the silver wiring through the flexible printed substrate The drive LSI is checked for operation, so that the contact of the finger and the position of the detected coordinate can be well detected.

透過保護玻璃7測定的全光線透過率及霧度率分別為89.5%及1.0%。第二透明導電膜52的圖案在螢光燈下被清楚地觀察到,成為外觀品質差的觸控面板。 The total light transmittance and the haze ratio measured by the cover glass 7 were 89.5% and 1.0%, respectively. The pattern of the second transparent conductive film 52 is clearly observed under the fluorescent lamp, and becomes a touch panel having poor appearance quality.

<比較例2> <Comparative Example 2>

除了比較例1的第二透明導電膜62的圖案為第12圖以平面圖所示的透明導電膜圖案72以外,全部和比較例1同樣地製作第1圖所示的構造的觸控面板。第二透明導電膜72的電極間的小正方形為已被電性絕緣的虛擬圖案。 The touch panel having the structure shown in Fig. 1 was produced in the same manner as in Comparative Example 1, except that the pattern of the second transparent conductive film 62 of Comparative Example 1 was the transparent conductive film pattern 72 shown in plan view in Fig. 12 . The small square between the electrodes of the second transparent conductive film 72 is a dummy pattern that has been electrically insulated.

進行觸控面板的動作確認後,能良好地偵測手指的接觸和檢測座標位置,在螢光燈下觀察到的透明導電膜的圖案不醒目,全光線透過率及霧度率為88.7%及1.9%,以外觀品質而言成為透明感差的觸控面板。 After the operation of the touch panel is confirmed, the contact of the finger and the position of the coordinate are well detected, and the pattern of the transparent conductive film observed under the fluorescent lamp is not conspicuous, and the total light transmittance and the haze ratio are 88.7%. 1.9%, which is a touch panel with poor transparency in terms of appearance quality.

[產業上之可利用性] [Industrial availability]

本發明的觸控面板,尤其可用作靜電容式觸控面板,可以作為配置在智慧型手機和平板電腦、筆記型PC等的前面的使用者界面利用。 The touch panel of the present invention can be used, in particular, as a capacitive touch panel, and can be utilized as a user interface disposed in front of a smart phone, a tablet computer, a notebook PC, or the like.

Claims (11)

一種觸控面板,至少具備:第一透明基板;第一透明導電膜,係圖案化形成在前述第一透明基板的一面;第一金屬配線,係連接於前述第一透明導電膜;第二透明基板;第二透明導電膜,係圖案化形成在前述第二透明基板的一面;第二金屬配線,係連接於前述第二透明導電膜;及透明黏著層,前述第一透明導電膜係實質上已在矩形內部開孔的矩形圖案,前述第二透明導電膜係實質上已在矩形內部置入狹縫(slit)的矩形圖案,前述第一透明導電膜的孔係配置在與前述第二透明導電膜重疊的位置,前述第一透明導電膜的孔,係在已形成在前述第一透明導電膜的狹縫配置虛擬圖案而形成,在對觸控面板面的俯視下,前述虛擬圖案不具有與對向的前述第二透明導電膜的重疊部。 A touch panel includes at least: a first transparent substrate; a first transparent conductive film patterned on one side of the first transparent substrate; a first metal wiring connected to the first transparent conductive film; and a second transparent a second transparent conductive film patterned on one surface of the second transparent substrate; a second metal wiring connected to the second transparent conductive film; and a transparent adhesive layer, wherein the first transparent conductive film is substantially a rectangular pattern having a hole inside the rectangle, wherein the second transparent conductive film has a rectangular pattern in which a slit is substantially placed inside the rectangle, and the hole of the first transparent conductive film is disposed in the second transparent a position at which the conductive film overlaps, wherein the hole of the first transparent conductive film is formed by a dummy pattern formed on a slit formed in the first transparent conductive film, and the dummy pattern does not have a plan view of the touch panel surface An overlapping portion with the opposite second transparent conductive film. 一種觸控面板,至少具備:透明基板;第一透明導電膜,係圖案化形成在前述透明基板的一面;第一金屬配線,係連接於前述第一透明導電膜;第二透明導電膜,係圖案化形成在前述透明基板的另一面;第二金屬配線,係連接於前述第二透明導電膜,前述第一透明導電膜係實質上已在矩形內部開孔的矩形圖案,前述第二透明導電膜係實質上已在矩形內部置入 狹縫的矩形圖案,前述第一透明導電膜的孔係配置在與前述第二透明導電膜重疊的位置,前述第一透明導電膜的孔,係在已形成在前述第一透明導電膜的狹縫配置虛擬圖案而形成,在對觸控面板面的俯視下,前述虛擬圖案不具有與對向的前述第二透明導電膜的重疊部。 A touch panel comprising at least: a transparent substrate; a first transparent conductive film patterned on one side of the transparent substrate; a first metal wiring connected to the first transparent conductive film; and a second transparent conductive film Patterning is formed on the other surface of the transparent substrate; the second metal wiring is connected to the second transparent conductive film, and the first transparent conductive film is a rectangular pattern having substantially a hole inside the rectangular shape, and the second transparent conductive layer The membrane system has been placed substantially inside the rectangle a rectangular pattern of the slit, wherein a hole of the first transparent conductive film is disposed at a position overlapping the second transparent conductive film, and a hole of the first transparent conductive film is formed in a narrow portion of the first transparent conductive film The virtual pattern is formed by sewing, and the dummy pattern does not have an overlapping portion with the opposing second transparent conductive film in a plan view of the touch panel surface. 如請求項1或2之觸控面板,其中,在對觸控面板面的俯視下,前述第一透明導電膜的圖案與前述第二透明導電膜的圖案的重疊部的面積,係平均每個地方在0.0025mm2以上0.10mm2以下的範圍內。 The touch panel of claim 1 or 2, wherein an area of the overlapping portion of the pattern of the first transparent conductive film and the pattern of the second transparent conductive film is averaged in a plan view of the touch panel surface 0.0025mm 2 or more places in the range of 2 or less 0.10mm. 如請求項1或2之觸控面板,其中,前述第一透明導電膜的孔,沿著橫貫前述第二透明導電膜的圖案之邊的寬度,係比該邊疊置的前述第二透明導電膜的圖案的寬度寬0.020mm以上0.15mm以下。 The touch panel of claim 1 or 2, wherein the hole of the first transparent conductive film is wider than the side of the pattern of the second transparent conductive film, and the second transparent conductive layer is stacked on the side The width of the pattern of the film is 0.020 mm or more and 0.15 mm or less. 如請求項1或2之觸控面板,其中,至少前述第二透明導電膜的圖案的非狹縫部的最窄部寬度係在0.050mm以上0.35mm以下的範圍內。 The touch panel of claim 1 or 2, wherein at least the narrowest portion width of the non-slit portion of the pattern of the second transparent conductive film is in a range of 0.050 mm or more and 0.35 mm or less. 如請求項1或2之觸控面板,其中,至少前述第二透明導電膜的圖案的狹縫部的最窄部寬度,係與非狹縫部的最窄部寬度相同或比前述非狹縫部的最窄部寬度寬。 The touch panel of claim 1 or 2, wherein at least the narrowest portion width of the slit portion of the pattern of the second transparent conductive film is the same as or smaller than the width of the narrowest portion of the non-slit portion The width of the narrow portion is wide. 如請求項1或2之觸控面板,其中,前述透明導電膜至少包含奈米金屬線。 The touch panel of claim 1 or 2, wherein the transparent conductive film comprises at least a nanowire. 如請求項7之觸控面板,其中,前述奈米金屬線被樹 脂層覆蓋。 The touch panel of claim 7, wherein the aforementioned nano metal wire is a tree Cover the lipid layer. 如請求項1或2之觸控面板,其中,前述第一透明導電膜與前述第二透明導電膜之間的最短距離係在20μm以上150μm以下的範圍內。 The touch panel of claim 1 or 2, wherein the shortest distance between the first transparent conductive film and the second transparent conductive film is in a range of 20 μm or more and 150 μm or less. 如請求項1或2之觸控面板,其中,前述透明基板的厚度係在20μm以上150μm以下的範圍內。 The touch panel of claim 1 or 2, wherein the thickness of the transparent substrate is in a range of 20 μm or more and 150 μm or less. 如請求項1或2之觸控面板,其中,表示前述觸控面板的透過光的散射的霧度率係1.5%以下。 The touch panel of claim 1 or 2, wherein the haze ratio indicating the scattering of the transmitted light of the touch panel is 1.5% or less.
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