TWI592531B - Air-permeable fabric being woven by composite fibers - Google Patents

Air-permeable fabric being woven by composite fibers Download PDF

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TWI592531B
TWI592531B TW104117858A TW104117858A TWI592531B TW I592531 B TWI592531 B TW I592531B TW 104117858 A TW104117858 A TW 104117858A TW 104117858 A TW104117858 A TW 104117858A TW I592531 B TWI592531 B TW I592531B
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fiber
layer
composite
composite fiber
fabric
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TW104117858A
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TW201643284A (en
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黃賜源
林彥文
王珮如
劉虣虣
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財團法人鞋類暨運動休閒科技研發中心
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透氣複合纖維織物Breathable composite fiber fabric

一種纖維織物,特別是一種具有透氣性的複合纖維織物。A fiber fabric, in particular a composite fiber fabric having gas permeability.

預浸布或是含浸纖維織物是目前最常使用的高性能複合材料,廣泛使用於運動器材、鞋材等物品。一般製作纖維預浸布或是含浸纖維織物時,會先將纖維編織或排列成纖維布後,再將纖維布覆蓋或浸入加熱的樹脂中,使樹脂複合於纖維布上形成纖維預浸布或是含浸纖維織物。Prepreg or impregnated fiber fabric is the most commonly used high-performance composite material, and is widely used in sports equipment, shoe materials and the like. Generally, when fabricating a fiber prepreg or impregnating a fiber fabric, the fibers are first woven or arranged into a fiber cloth, and then the fiber cloth is covered or immersed in a heated resin, and the resin is composited on the fiber cloth to form a fiber prepreg or It is impregnated with fiber fabric.

利用上述作法所製成的預浸布或是含浸纖維織物,因樹脂完全覆蓋或浸入纖維布的細縫或孔洞中,使得此種預浸布或是含浸纖維織物相對缺乏可透氣性,對於運動器材或是鞋材等需要強調透氣舒適性質之物品,雖可透過額外增加穿孔或結構上的調整來達到透氣性的需求,但往往影響到其原有的材料強度,使用上依然有其限制。The prepreg or the impregnated fiber fabric produced by the above method is completely covered or immersed in the slits or holes of the fiber cloth, so that the prepreg or the impregnated fiber fabric is relatively lack of gas permeability, and is suitable for sports. Items such as equipment or shoe materials that need to emphasize breathable comfort properties, although the need for additional perforation or structural adjustment to achieve breathability, but often affect the original material strength, there are still restrictions on its use.

為了解決既有預浸布或是含浸纖維織物透氣性不足之缺點,本發明提供一種透氣複合纖維織物,其係利用具有內外層結構之複合纖維所編織而成,兩兩交錯之該複合纖維交接處熔融結合,兩兩相鄰未結合之複合纖維未交接處形成複數個透氣間隙,該複合纖維包含有一內纖維層以及一包覆外層,該包覆外層至少部分包覆該內纖維層之外部表面,該內纖維層之材質機械特性與熔點高於該包覆外層,該包覆外層於熔融後使接觸之該複合纖維織物緊密結合。In order to solve the disadvantages of insufficient permeability of the prepreg or the impregnated fiber fabric, the present invention provides a breathable composite fiber fabric which is woven by a composite fiber having an inner and outer structure, and the composite fibers are intertwined. Where the fusion bonding is performed, a plurality of gas permeable gaps are formed at the unbonded adjacent unbonded composite fibers, and the composite fiber comprises an inner fiber layer and a coating outer layer, the coating outer layer at least partially covering the outer portion of the inner fiber layer The surface of the inner fiber layer has a mechanical property and a melting point higher than the outer layer of the coating, and the outer layer of the coating is tightly bonded to the composite fiber fabric that is in contact after being melted.

其中,該內纖維層是天然纖維或人造纖維。Wherein the inner fiber layer is a natural fiber or a rayon.

其中,該包覆外層是熱塑性彈性體、熱塑性橡膠或天然橡膠。Wherein the covering outer layer is a thermoplastic elastomer, a thermoplastic rubber or a natural rubber.

其中,該天然纖維包含有棉纖維、麻纖維或是絲纖維,該人造纖維是聚乙烯、聚丙烯、聚對苯二甲酸乙二酯、聚酯、尼龍、熱塑性聚氨酯、聚氯乙烯、碳纖維或是玻璃纖維,該熱塑性彈性體是熱塑性聚氨酯、尼龍彈性體或是苯乙烯系熱塑性彈性體。Wherein the natural fiber comprises cotton fiber, hemp fiber or silk fiber, the rayon fiber is polyethylene, polypropylene, polyethylene terephthalate, polyester, nylon, thermoplastic polyurethane, polyvinyl chloride, carbon fiber or It is a glass fiber, and the thermoplastic elastomer is a thermoplastic polyurethane, a nylon elastomer or a styrene-based thermoplastic elastomer.

其中,該內外層結構形成的方法包含有環錠紡絲、轉杯紡絲、噴氣紡絲、靜電紡絲、含浸成型或是將該包覆外層與該內纖維層利用共擠壓製程形成。Wherein, the method for forming the inner and outer layers comprises ring spinning, rotor spinning, air-jet spinning, electrospinning, impregnation or forming the outer layer of the coating and the inner fiber layer by a co-extrusion process.

其中,該透氣纖維織物進一步加熱固化形成具有透氣間隙之鞋子鞋面、鞋墊、中底板、袋體、包體或是副木。Wherein, the ventilated fiber fabric is further heat-cured to form a shoe upper, an insole, a bottom plate, a bag body, a bag body or a secondary wood having a gas permeable gap.

根據上述說明,本發明具有以下優點:According to the above description, the present invention has the following advantages:

1. 本發明的透氣複合纖維織物於熱壓成型後,成品自然形成複數個透氣間隙或縫隙,使成品可具有高度透氣性,無需額外二次加工形成透氣孔,製程簡單。1. After the hot-press forming of the breathable composite fiber fabric of the present invention, the finished product naturally forms a plurality of gas permeable gaps or slits, so that the finished product can have high gas permeability, and no additional secondary processing is needed to form the venting holes, and the process is simple.

2. 本發明的製程簡單且透氣複合纖維織物的透氣間隙為熱壓製程時自然形成,故相對於既有二次加工穿孔的技術,本發明不會影響原本纖維織物的結構支撐性。2. The process of the present invention is simple and the gas permeable gap of the gas permeable composite fiber fabric is naturally formed during the hot pressing process, so the present invention does not affect the structural support of the original fiber fabric relative to the technique of the secondary processing perforation.

3. 本發明因具有許多間隙穿孔,所形成的透氣複合纖維織物具有質輕、薄且透氣之特性,可廣泛應用於鞋體、袋體、包體等生活用品,亦可應用於副木之醫療用品。3. The present invention has a plurality of gap perforations, and the formed breathable composite fiber fabric has the characteristics of light weight, thinness and air permeability, and can be widely applied to daily articles such as shoes, bags, and bags, and can also be applied to the side wood. medical supplies.

請參考圖1~圖3,本發明之透氣複合纖維織物的複合纖維一較佳實施例係包含一內纖維層10以及一包覆外層20,該包覆外層20至少部分包覆該內纖維層10之外部表面形成類殼球(Core Shell)之內外雙層結構狀態。Referring to FIGS. 1 to 3, a preferred embodiment of the composite fiber of the breathable composite fiber fabric of the present invention comprises an inner fiber layer 10 and a coating outer layer 20, the outer covering layer 20 at least partially covering the inner fiber layer. The outer surface of 10 forms the inner and outer double-layer structure state of the Core Shell.

其中,該內纖維層10之材質係提供該透氣複合纖維織物整體結構強度,提供該透氣複合纖維織物機械支撐性。該內纖維層10可以是天然纖維或人造纖維,該天然纖維包含有棉纖維、麻纖維或是絲纖維;該人造纖維包含有聚乙烯(Polyethylene, PE)、聚丙烯(Polypropylene, PP)、聚對苯二甲酸乙二酯(Polyethylene Terephthalate, PET)、聚酯(Polyester)、尼龍(Nylon)、熱塑性聚氨酯(Thermal Polyurethane, TPU)、聚氯乙烯(Polyvinyl Chloride, PVC)、碳纖維(Carbon Fiber)或是玻璃纖維(Glass Fiber)。該包覆外層20為具有加熱後產生黏性或沾附性之材料,所謂的黏合或是沾附性係指當該包覆外層20加熱後包覆於該內纖維層10局部或全部表面時,可產生黏合或沾附特性,使得該包覆外層20可與該內纖維層10產生緊密的連結,不易剝離或脫落,該包覆外層20可以是熱塑性彈性體(TPE)、熱塑性橡膠(TPR)或天然橡膠(Nature Rubber);該熱塑性彈性體(TPE)可以是熱塑性聚氨酯(Thermal Polyurethane, TPU)、尼龍彈性體(PAE)、苯乙烯系列熱塑性彈性體(SBCs);該苯乙烯系列熱塑性彈性體包含苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物(SEBS)或苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)。Wherein, the material of the inner fiber layer 10 provides the overall structural strength of the gas permeable composite fiber fabric, and provides mechanical support for the gas permeable composite fiber fabric. The inner fiber layer 10 may be a natural fiber or a rayon fiber, and the natural fiber comprises cotton fiber, hemp fiber or silk fiber; the rayon fiber comprises polyethylene (Polyethylene, PE), polypropylene (polypropylene, PP), poly Polyethylene Terephthalate (PET), Polyester, Nylon, Thermal Polyurethane (TPU), Polyvinyl Chloride (PVC), Carbon Fiber or It is a glass fiber (Glass Fiber). The covering outer layer 20 is a material which has viscosity or adhesion after heating, and the so-called adhesive or adhesive means that when the coating outer layer 20 is heated and coated on a part or the whole surface of the inner fiber layer 10 The adhesive outer layer 20 can be tightly bonded to the inner fiber layer 10, and is not easily peeled off or peeled off. The outer cover 20 can be a thermoplastic elastomer (TPE) or a thermoplastic rubber (TPR). Or Natural Rubber; the thermoplastic elastomer (TPE) may be Thermoplastic Polyurethane (TPU), Nylon Elastomer (PAE), Styrene Series Thermoplastic Elastomer (SBCs); The body comprises styrene-ethylene-butylene-styrene block copolymer (SEBS) or styrene-butadiene-styrene block copolymer (SBS).

形成上述該透氣複合纖維織物的複合纖維製造方法包括環錠紡絲(Ring Spinning)、轉杯紡絲(Roter Spinning)、噴氣紡絲(Jet Spinning)、靜電紡絲(Electrostatic Spinning)、含浸成型或是將該包覆外層20與該內纖維層10利用共擠壓製程形成該類殼球(Core Shell)構造。The composite fiber manufacturing method for forming the above-mentioned gas permeable composite fiber fabric includes Ring Spinning, Roter Spinning, Jet Spinning, Electrostatic Spinning, impregnation or The cladding outer layer 20 and the inner fiber layer 10 are formed into a core shell structure by a co-extrusion process.

該透氣複合纖維織物的複合纖維除了可以是單一內纖維層10外包覆該包覆外層20,亦可以複數種內纖維層10外包覆該包覆外層20,可進一步增強本發明複合纖維的強度。The composite fiber of the gas permeable composite fiber fabric may be coated with the outer layer 20 except for the single inner fiber layer 10. The outer layer 20 may be coated with a plurality of inner fiber layers 10 to further enhance the composite fiber of the present invention. strength.

本發明將上述類殼球構造的複合纖維編織成透氣複合纖維織物後,再進一步將該透氣複合纖維織物加熱固化成型為所需要的形狀,如熱壓成型為鞋材之鞋面、鞋墊、中底板或包包、袋子等生活用品,亦可應用於副木之醫療用品。加熱時該透氣複合纖維織物外部之該包覆外層20會再次產生黏性或沾附性,使得織物的複合纖維交接處產生黏合或結合,而複合纖維未交接處則自然形成複數個細微的透氣間隙30或孔隙。本發明透過熱壓製程後,成品可自然形成複數個透氣間隙30,使本發明之成品具有高度透氣性且具備相對較佳的支撐強度,成品無需額外加工形成透氣孔,更可降低生產製造的成本。In the present invention, after the composite fiber of the above-mentioned shell-ball structure is woven into a gas permeable composite fiber fabric, the gas permeable composite fiber fabric is further heat-cured into a desired shape, such as hot pressing into a shoe upper, an insole, a middle The bottom plate or the daily necessities such as bags and bags can also be applied to the medical supplies of the secondary wood. When the heating, the outer layer 20 of the outer surface of the gas permeable composite fiber fabric will reproduce adhesiveness or adhesion, so that the composite fiber of the fabric is bonded or bonded at the intersection of the composite fibers, and the composite fibers are not overlapped to form a plurality of fine ventilation. Clearance 30 or pores. After the hot pressing process of the invention, the finished product can naturally form a plurality of gas permeable gaps 30, so that the finished product of the invention has high gas permeability and relatively good supporting strength, and the finished product does not need additional processing to form venting holes, and the manufacturing process can be reduced. cost.

依據上述說明可知,本發明具有以下優點:According to the above description, the present invention has the following advantages:

1. 本發明的複合纖維織物於熱壓成型後,成品自然形成複數個透氣間隙或孔隙,使成品具有高度透氣性,無需額外加工形成透氣孔,製程相對單純簡單。1. After the thermocompression molding of the composite fiber fabric of the present invention, the finished product naturally forms a plurality of gas permeable gaps or pores, so that the finished product has high gas permeability, and no additional processing is required to form the venting holes, and the process is relatively simple and simple.

2. 本發明的製程簡單,透氣複合纖維織物的透氣間隙為熱壓製程時自然形成,故相對於額外加工穿孔的技術,本發明不會影響原本纖維織物的結構支撐性。2. The process of the present invention is simple, and the gas permeable gap of the gas permeable composite fiber fabric is naturally formed during the hot pressing process, so the present invention does not affect the structural support of the original fiber fabric relative to the technique of additionally processing the perforation.

3. 本發明因具有許多間隙穿孔,所形成的透氣複合纖維織物具有質輕、薄且透氣之特性,可廣泛應用於鞋體、袋體、包體等生活用品,亦可應用於副木之醫療用品。3. The present invention has a plurality of gap perforations, and the formed breathable composite fiber fabric has the characteristics of light weight, thinness and air permeability, and can be widely applied to daily articles such as shoes, bags, and bags, and can also be applied to the side wood. medical supplies.

10‧‧‧內纖維層
20‧‧‧包覆外層
30‧‧‧透氣間隙
10‧‧‧ inner fiber layer
20‧‧‧ coated outer layer
30‧‧‧ Ventilation gap

圖1為本發明透氣複合纖維織物一較佳實施例示意圖。 圖2為本發明透氣複合纖維織物一較佳實施例之上視圖。 圖3為圖2之A-A剖面圖。BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic view of a preferred embodiment of a breathable composite fiber fabric of the present invention. Figure 2 is a top plan view of a preferred embodiment of a breathable composite fiber fabric of the present invention. Figure 3 is a cross-sectional view taken along line A-A of Figure 2;

10‧‧‧內纖維層 10‧‧‧ inner fiber layer

20‧‧‧包覆外層 20‧‧‧ coated outer layer

30‧‧‧透氣間隙 30‧‧‧ Ventilation gap

Claims (6)

一種透氣複合纖維織物,其係利用具有內外層結構之複合纖維所編織而成,兩兩交錯之該複合纖維交接處熔融結合,兩兩相鄰未結合之複合纖維未交接處形成複數個透氣間隙,該複合纖維包含有一內纖維層以及一包覆外層,該包覆外層至少部分包覆該內纖維層之外部表面,該內纖維層之材質機械特性與熔點高於該包覆外層,該包覆外層於熔融後使接觸之該複合纖維緊密結合。A gas permeable composite fiber fabric woven by a composite fiber having an inner and outer structure, wherein the composite fibers at the intersection of two and two are fused, and a plurality of adjacent unbonded composite fibers form a plurality of venting gaps The composite fiber comprises an inner fiber layer and a coating outer layer, the outer layer at least partially covering an outer surface of the inner fiber layer, wherein the inner fiber layer has a material mechanical property and a melting point higher than the outer layer of the coating, the package The outer layer is melted to tightly bond the composite fibers that are in contact. 如申請專利範圍第1項之透氣複合纖維織物,該內纖維層是天然纖維或人造纖維。The breathable composite fiber fabric of claim 1, wherein the inner fiber layer is a natural fiber or a rayon fiber. 如申請專利範圍第1項之透氣複合纖維織物,該包覆外層是熱塑性彈性體、熱塑性橡膠或天然橡膠。The breathable composite fiber fabric of claim 1 is a thermoplastic elastomer, a thermoplastic rubber or a natural rubber. 如申請專利範圍第2項之透氣複合纖維織物,該天然纖維包含有棉纖維、麻纖維或是絲纖維,該人造纖維是聚乙烯、聚丙烯、聚對苯二甲酸乙二酯、聚酯、尼龍、熱塑性聚氨酯、聚氯乙烯、碳纖維或是玻璃纖維,該熱塑性彈性體是熱塑性聚氨酯、尼龍彈性體或是苯乙烯系熱塑性彈性體。The breathable composite fiber fabric of claim 2, wherein the natural fiber comprises cotton fiber, hemp fiber or silk fiber, and the rayon fiber is polyethylene, polypropylene, polyethylene terephthalate, polyester, Nylon, thermoplastic polyurethane, polyvinyl chloride, carbon fiber or glass fiber, the thermoplastic elastomer is a thermoplastic polyurethane, a nylon elastomer or a styrene thermoplastic elastomer. 如申請專利範圍第1或2或3項之透氣複合纖維織物,該內外層結構形成的方法包含有環錠紡絲、轉杯紡絲、噴氣紡絲、靜電紡絲、含浸成型或是將該包覆外層與該內纖維層利用共擠壓製程形成。The gas-permeable composite fiber fabric of claim 1 or 2 or 3, wherein the method for forming the inner and outer layers comprises ring spinning, rotor spinning, air-jet spinning, electrospinning, impregnation or The coated outer layer and the inner fibrous layer are formed by a co-extrusion process. 如申請專利範圍第5項之透氣複合纖維織物,該透氣複合纖維織物進一步加熱固化形成具有透氣間隙之鞋子鞋面、鞋墊、中大底、袋體、包體或是副木。The breathable composite fiber fabric of claim 5 is further heat-cured to form a shoe upper, an insole, a midsole, a bag, an inclusion or a secondary wood having a gas permeable gap.
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