TWI588575B - Liquid crystal structure and its making method - Google Patents
Liquid crystal structure and its making method Download PDFInfo
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- TWI588575B TWI588575B TW098104637A TW98104637A TWI588575B TW I588575 B TWI588575 B TW I588575B TW 098104637 A TW098104637 A TW 098104637A TW 98104637 A TW98104637 A TW 98104637A TW I588575 B TWI588575 B TW I588575B
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- 239000004973 liquid crystal related substance Substances 0.000 title claims description 219
- 238000000034 method Methods 0.000 title claims description 27
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 claims description 197
- 239000000758 substrate Substances 0.000 claims description 100
- 230000005684 electric field Effects 0.000 claims description 88
- 229920000642 polymer Polymers 0.000 claims description 58
- 239000000178 monomer Substances 0.000 claims description 27
- 230000009977 dual effect Effects 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 230000008014 freezing Effects 0.000 claims description 4
- 238000007710 freezing Methods 0.000 claims description 4
- 239000000975 dye Substances 0.000 description 45
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 36
- 239000007788 liquid Substances 0.000 description 19
- 235000012000 cholesterol Nutrition 0.000 description 18
- 230000008859 change Effects 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 7
- 239000003094 microcapsule Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004990 Smectic liquid crystal Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000004988 Nematic liquid crystal Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
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- Liquid Crystal (AREA)
Description
本發明有關於一種液晶結構及其製作方法,主要可以對可見光波長範圍內的光源進行反射,同時亦可應用在反射式、穿透式或半反射半穿透式的面板上。 The invention relates to a liquid crystal structure and a manufacturing method thereof, which can mainly reflect a light source in a visible wavelength range, and can also be applied to a reflective, transmissive or semi-reflective semi-transmissive panel.
一般存在於自然界的物質主要可以區分氣態、液態以及固態。這些狀態在某些特定的條件下可以互相的轉變,例如溫度或壓力的改變,這就是我們一般所說的相變化。對大部分的物質來說在發生相變化時,僅僅是由某一相變化到另外一相,例如由固態變化成為液態,且在相變化的過程中並沒有中間過渡帶的發生。 Substances that are generally found in nature can mainly distinguish between gaseous, liquid, and solid. These states can be transformed into each other under certain conditions, such as changes in temperature or pressure, which is what we generally call phase changes. For most substances, when a phase change occurs, only one phase changes to another phase, for example, from solid state to liquid state, and there is no intermediate transition zone in the process of phase change.
然而有些物質在加熱熔融後,其相變化並不直接由固體變為液體。這些物質在失去某些固體性質後仍然具有某些的規則性,一般稱之為液晶(liquid crystal,LC)。這種狀態的物質同時具有固體晶體的某種程度的規則性排列狀態以及液體的某種程度流動性。就因為有這種特殊的性質,因此液晶物質的應用非常重要而廣泛。 However, some substances change their phase and do not change directly from solid to liquid after heating and melting. These materials still have some regularity after losing some solid properties, commonly referred to as liquid crystal (LC). The substance in this state has both a certain regular arrangement state of the solid crystal and a certain degree of fluidity of the liquid. Because of this special nature, the application of liquid crystal materials is very important and extensive.
目前業界經常使用的液晶主要包括有以下幾種: At present, the liquid crystals frequently used in the industry mainly include the following:
層列型液晶(smectic LC):這類型的液晶為棒狀的分子以層狀構造排列,各個分子與層面垂直或具有一傾斜角度,而且所構呈的分子均為互相平行排列。 Smectic LC: This type of liquid crystal is a rod-like molecule arranged in a layered structure, each molecule being perpendicular to the layer or having an oblique angle, and the molecules formed are arranged in parallel with each other.
向列型液晶(nematic LC):向列型液晶亦為棒狀分子作平行排列,其分子軸方向保持平行,但不具有層列型液晶般的層狀構造,只有一維的規則度。具有光學上的正折射性,與層列型液晶比較,該液晶分子於長軸方向容易自由運動,因此其分子間的作用力小,黏度也較小,且易於滑動,為所有的種類液晶中,流動性最大者,是液晶成員中最重要的,也是最廣泛被使用者。 Nematic LC: Nematic liquid crystals are also arranged in parallel with rod-shaped molecules, and their molecular axis directions remain parallel, but they do not have a layered structure like a smectic liquid crystal, and have only one-dimensional regularity. It has optical positive refraction. Compared with smectic liquid crystals, the liquid crystal molecules are easy to move freely in the long axis direction, so their intermolecular forces are small, the viscosity is small, and they are easy to slide, which is used in all kinds of liquid crystals. The most liquid, the most important and most widely used LCD members.
膽固醇液晶(cholesteric LC):膽固醇型液晶基本上都具有不對稱碳原子。由這類分子所構成的液晶,其分子平行堆積層狀排列,層和層間互相平行,在每一層中分子有一向列型一般彼此同向排列著,其長軸和層 面平行。在相鄰的兩層之間,分子的長軸方向規則性地依次旋轉一定角度,層層旋轉下來形成一個螺旋狀結構。 Cholesterol LC: Cholesterol-type liquid crystals basically have asymmetric carbon atoms. In the liquid crystal composed of such molecules, the molecules are arranged in parallel in a layered manner, and the layers and the layers are parallel to each other. In each layer, the molecules have a nematic type and are generally aligned with each other, and the long axis and the layer thereof. The faces are parallel. Between adjacent layers, the long axis direction of the molecules is regularly rotated by a certain angle, and the layers are rotated to form a spiral structure.
由於膽固醇型液晶具有雙穩態的特性,因此被廣泛的使用在不需要電源供應便可維持狀態的顯示器上,例如電子紙。請參閱第1圖,膽固醇液晶面板10主要包括有一前基板11及後基板15,其中後基板15上可塗佈黑漆,並於兩者之間設置有一膽固醇液晶13,膽固醇液晶13則包括有複數個膽固醇液晶分子131。當施加在膽固醇液晶13上的電壓改變時,膽固醇液晶13的排列方式將會隨之改變,例如膽固醇液晶13可為平面型排列(Planar Texture)103、焦點圓錐型排列(Focal Conic Texture)101或垂直型排列(Homeotropic Texture)102。 Since cholesteric liquid crystals have bistable characteristics, they are widely used in displays that maintain state without requiring a power supply, such as electronic paper. Referring to FIG. 1 , the cholesteric liquid crystal panel 10 mainly includes a front substrate 11 and a rear substrate 15 , wherein the rear substrate 15 can be coated with black lacquer, and a cholesteric liquid crystal 13 is disposed between the two, and the cholesteric liquid crystal 13 includes A plurality of cholesteric liquid crystal molecules 131. When the voltage applied to the cholesteric liquid crystal 13 changes, the arrangement of the cholesteric liquid crystal 13 will change accordingly. For example, the cholesteric liquid crystal 13 may be a Planar Texture 103, a Focal Conic Texture 101 or Homeotropic Texture 102.
其中平面型排列103及焦點圓錐型排列101皆為穩態,換言之,當膽固醇液晶13為平面型排列103或焦點圓錐型排列101時,都不需要外加電壓便可以維持原本的排列狀態。 The planar arrangement 103 and the focal conic arrangement 101 are all in a steady state. In other words, when the cholesteric liquid crystal 13 is in the planar arrangement 103 or the focal conic arrangement 101, the original alignment state can be maintained without applying a voltage.
外界光源L在進入平面型排列103的液晶後,將會因為膽固醇液晶分子131螺旋節距(pitch)的不同,而使得部分波長範圍的光源L產生布拉格反射(Bragg reflection),並成為亮態。反之,當外界光源L進入焦點圓錐型排列101的液晶後將會穿透,並被後基板15上所設置的黑漆吸收而成為暗態。 After entering the liquid crystal of the planar arrangement 103, the external light source L will cause the Bragg reflection of the light source L in a partial wavelength range to become a bright state due to the difference in the pitch of the cholesteric liquid crystal molecules 131. On the contrary, when the external light source L enters the liquid crystal of the focal conical arrangement 101, it will penetrate and be absorbed by the black paint provided on the rear substrate 15 to become a dark state.
本發明之主要目的,在於提供一種液晶結構,主要於膽固醇液晶內摻雜染料,並使得膽固醇液晶為指紋型排列,且其螺旋軸方向具有一定秩序,藉由此一結構將可以對可見光波長範圍內的光源進行反射。 The main object of the present invention is to provide a liquid crystal structure, which is mainly doped with a dye in a cholesteric liquid crystal, and causes the cholesteric liquid crystal to be in a fingerprint type arrangement, and the direction of the spiral axis has a certain order, whereby the structure can be used for the visible light wavelength range. The light source inside is reflected.
本發明之次要目的,在於提供一種液晶結構,其中膽固醇液晶以指紋型排列時為亮態,以平面型排列時則為暗態,藉此液晶結構將可以應用在反射式、穿透式或半反射半穿透式的面板上。 A secondary object of the present invention is to provide a liquid crystal structure in which a cholesteric liquid crystal is in a bright state when arranged in a fingerprint type, and a dark state in a planar arrangement, whereby the liquid crystal structure can be applied to a reflective, transmissive or Semi-reflective semi-transparent panel.
本發明之又一目的,在於提供一種液晶結構,主要是使得膽固醇液晶為指紋型排列,且其螺旋軸方向具有一定秩序,再利用聚合物凍結該指紋型排列結構,而指紋型排列及平面型排列皆為穩態,且兩者之間的切換速度較習用構造快,藉此將有利於提高面板的顯示品質。 Another object of the present invention is to provide a liquid crystal structure, which mainly makes a cholesteric liquid crystal of a fingerprint type arrangement, and has a certain order of a spiral axis direction, and then freezes the fingerprint type arrangement structure by using a polymer, and the fingerprint type arrangement and the planar type The arrangement is steady state, and the switching speed between the two is faster than the conventional structure, thereby facilitating the display quality of the panel.
本發明之又一目的,在於提供一種液晶結構的製作方法,可以將高分子單體、膽固醇液晶(正型或雙頻液晶)及染料進行混合,並對膽固醇液晶平面型排列在d/p>3/2之情況下施加縱向小電場(約0.3V/um),以形成螺旋軸方向垂直配向方向之指紋型排列,再以聚合物凍結該指紋型排列 結構。 Another object of the present invention is to provide a method for fabricating a liquid crystal structure, which can mix a polymer monomer, a cholesteric liquid crystal (positive or dual-frequency liquid crystal) and a dye, and arrange the cholesteric liquid crystal in a planar form at d/p> In the case of 3/2, a longitudinal small electric field (about 0.3 V/um) is applied to form a fingerprint-type arrangement in the direction perpendicular to the direction of the helical axis, and then the fingerprint is frozen by the polymer. structure.
本發明之又一目的,在於提供一種液晶結構的製作方法,可以將高分子單體、膽固醇液晶(雙頻液晶)及染料進行混合,並對膽固醇液晶施加一高頻水平電場,使得膽固醇液晶表現出負型液晶特色且形成螺旋軸方向具有一定秩序性的指紋型排列,而後再進行一如光照或加熱等固化程序,促使高分子單體聚合為一聚合物以凍結該指紋型排列結構。若施加縱方向之低頻高電壓脈衝則可讓膽固醇液晶表現出正型液晶特色並切換為平面型排列,施加縱方向低頻低電壓脈衝則切換為指紋型排列。 Another object of the present invention is to provide a method for fabricating a liquid crystal structure, which can mix a polymer monomer, a cholesteric liquid crystal (dual-frequency liquid crystal) and a dye, and apply a high-frequency horizontal electric field to the cholesteric liquid crystal to make the cholesterol liquid crystal display. The negative-type liquid crystal features and forms a fingerprint-like arrangement with a certain order in the direction of the spiral axis, and then a curing process such as illumination or heating is performed to promote polymerization of the polymer monomer into a polymer to freeze the fingerprint-type alignment structure. If a low-frequency high-voltage pulse in the longitudinal direction is applied, the cholesteric liquid crystal exhibits a positive liquid crystal characteristic and is switched to a planar arrangement, and a vertical low-frequency low-voltage pulse is applied to switch to a fingerprint type arrangement.
本發明之又一目的,在於提供一種液晶結構的製作方法,可以將膽固醇液晶(負型或雙頻液晶)及染料進行混合,並對膽固醇液晶施加一水平電場,使得膽固醇液晶為指紋型排列。若施加縱方向電場或移除水平電場,藉由基板的水平配向而成為膽固醇液晶平面型排列結構。 Another object of the present invention is to provide a method for fabricating a liquid crystal structure in which a cholesteric liquid crystal (negative or dual-frequency liquid crystal) and a dye are mixed, and a horizontal electric field is applied to the cholesteric liquid crystal so that the cholesteric liquid crystal is in a fingerprint type arrangement. When a vertical electric field is applied or a horizontal electric field is removed, a cholesteric liquid crystal planar arrangement structure is formed by horizontal alignment of the substrate.
為達成上述目的,本發明提供一種液晶結構,主要包括有:一膽固醇液晶,為指紋型排列,且膽固醇液晶之螺旋軸方向具有一定的秩序;及一染料,摻雜於膽固醇液晶內。 In order to achieve the above object, the present invention provides a liquid crystal structure, which mainly comprises: a cholesteric liquid crystal, which is arranged in a fingerprint type, and has a certain order in the direction of the spiral axis of the cholesteric liquid crystal; and a dye which is doped into the cholesteric liquid crystal.
此外,本發明尚提供一種液晶結構的製作方法,主要包括有以下步驟:於一膽固醇液晶內摻雜至少一染料;將該膽固醇液晶與一高分子單體進行混合;將該膽固醇液晶切換成為螺旋軸方向具有一定的秩序或朝單一方向的指紋型排列;及對該高分子單體進行一固化程序,以形成為一聚合物,並藉此聚合物以凍結該膽固醇液晶之指紋型排列。 In addition, the present invention further provides a method for fabricating a liquid crystal structure, which mainly includes the steps of: doping at least one dye into a cholesteric liquid crystal; mixing the cholesteric liquid crystal with a polymer monomer; and switching the cholesteric liquid crystal into a spiral The axial direction has a certain order or a fingerprint type arrangement in a single direction; and the polymer monomer is subjected to a curing process to form a polymer, and the polymer is arranged to freeze the fingerprint of the cholesteric liquid crystal.
又,本發明尚提供一種液晶結構的製作方法,主要包括有以下步驟:於一膽固醇液晶內摻雜至少一染料;將膽固醇液晶及染料放置於一第一基板及一第二基板之間;將該膽固醇液晶切換成為螺旋軸方向具有一定秩序或朝單一方向的指紋型排列;及將該膽固醇液晶切換成為平面型排列。 Moreover, the present invention further provides a method for fabricating a liquid crystal structure, comprising the steps of: doping at least one dye into a cholesteric liquid crystal; and placing the cholesteric liquid crystal and the dye between a first substrate and a second substrate; The cholesteric liquid crystal is switched to have a certain order in the direction of the spiral axis or a fingerprint type arrangement in a single direction; and the cholesteric liquid crystal is switched to a planar arrangement.
10‧‧‧膽固醇液晶面板 10‧‧‧Cholesterol LCD panel
101‧‧‧焦點圓錐型排列 101‧‧‧Focus Conical Arrangement
102‧‧‧垂直型排列 102‧‧‧Vertical arrangement
103‧‧‧平面型排列 103‧‧‧flat arrangement
11‧‧‧前基板 11‧‧‧ front substrate
13‧‧‧膽固醇液晶 13‧‧‧Cholesterol LCD
131‧‧‧膽固醇液晶分子 131‧‧‧Cholesterol liquid crystal molecules
15‧‧‧後基板 15‧‧‧Back substrate
20‧‧‧液晶結構 20‧‧‧Liquid structure
21‧‧‧膽固醇液晶 21‧‧‧Cholesterol LCD
211‧‧‧膽固醇液晶分子 211‧‧‧Cholesterol liquid crystal molecules
213‧‧‧膽固醇液晶分子 213‧‧‧Cholesterol liquid crystal molecules
215‧‧‧膽固醇液晶分子 215‧‧‧Cholesterol liquid crystal molecules
217‧‧‧膽固醇液晶分子 217‧‧‧Cholesterol liquid crystal molecules
23‧‧‧染料 23‧‧‧D dyes
25‧‧‧高分子單體 25‧‧‧ polymer monomer
30‧‧‧液晶結構 30‧‧‧Liquid structure
301‧‧‧指紋型排列 301‧‧‧Fingerprint arrangement
302‧‧‧垂直型排列 302‧‧‧Vertical arrangement
303‧‧‧平面型排列 303‧‧‧ flat arrangement
304‧‧‧球石狀排列 304‧‧‧ ball-like arrangement
305‧‧‧焦點圓錐型排列 305‧‧‧Focus Conical Arrangement
306‧‧‧第二指紋型排列 306‧‧‧Second fingerprint type arrangement
307‧‧‧第三指紋型排列 307‧‧‧ Third fingerprint type arrangement
308‧‧‧第四指紋型排列 308‧‧‧ Fourth fingerprint type arrangement
309‧‧‧第五指紋型排列 309‧‧‧ Fifth fingerprint type arrangement
311‧‧‧第一基板 311‧‧‧First substrate
313‧‧‧第二基板 313‧‧‧second substrate
32‧‧‧反射層 32‧‧‧reflective layer
33‧‧‧第一電極 33‧‧‧First electrode
35‧‧‧第二電極 35‧‧‧second electrode
40‧‧‧液晶結構 40‧‧‧Liquid structure
45‧‧‧聚合物 45‧‧‧ polymer
46‧‧‧絕緣層 46‧‧‧Insulation
47‧‧‧第三電極 47‧‧‧ third electrode
475‧‧‧第四電極 475‧‧‧fourth electrode
50‧‧‧液晶結構 50‧‧‧Liquid structure
60‧‧‧液晶結構 60‧‧‧Liquid structure
70‧‧‧液晶結構 70‧‧‧Liquid structure
71‧‧‧液晶滴 71‧‧‧Liquid Crystal Drops
72‧‧‧微膠囊液晶滴 72‧‧‧Microcapsule liquid crystal droplets
77‧‧‧微膠囊外殼層 77‧‧‧Microcapsule shell
80‧‧‧液晶結構 80‧‧‧Liquid structure
90‧‧‧液晶結構 90‧‧‧Liquid crystal structure
91‧‧‧偏光板 91‧‧‧Polar plate
93‧‧‧突出物 93‧‧‧ Outstandings
935‧‧‧突出物 935‧‧ ‧ protrusions
95‧‧‧隙縫 95‧‧‧ slit
955‧‧‧隙縫 955‧‧‧ slit
100‧‧‧液晶結構 100‧‧‧Liquid structure
110‧‧‧液晶結構 110‧‧‧Liquid crystal structure
120‧‧‧液晶結構 120‧‧‧Liquid structure
130‧‧‧液晶結構 130‧‧‧Liquid structure
140‧‧‧液晶結構 140‧‧‧Liquid structure
150‧‧‧液晶結構 150‧‧‧Liquid structure
第1圖:為習用習用膽固醇液晶面板的構造示意圖。 Fig. 1 is a schematic view showing the construction of a conventional cholesteric liquid crystal panel.
第2圖:為本發明液晶結構一較佳實施例之構造示意圖。 Fig. 2 is a schematic view showing the construction of a liquid crystal structure according to a preferred embodiment of the present invention.
第3圖:為本發明液晶結構在切換時的構造示意圖。 Fig. 3 is a schematic view showing the structure of the liquid crystal structure of the present invention at the time of switching.
第4圖:為本發明液晶結構又一實施例之構造示意圖。 Fig. 4 is a structural schematic view showing still another embodiment of the liquid crystal structure of the present invention.
第5圖:為本發明液晶結構又一實施例之構造示意圖。 Fig. 5 is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第6圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 6 is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第7圖:為本發明液晶結構一實施例的部分構造俯視圖。 Figure 7 is a partial plan view showing an embodiment of a liquid crystal structure of the present invention.
第8圖:為本發明液晶結構一實施例的部分構造俯視圖。 Fig. 8 is a partial plan view showing an embodiment of a liquid crystal structure according to the present invention.
第9圖:為本發明液晶結構一實施例的部分構造俯視圖。 Fig. 9 is a partial plan view showing an embodiment of a liquid crystal structure according to the present invention.
第10圖:為本發明液晶結構一實施例的部分構造俯視圖。 Fig. 10 is a partial plan view showing an embodiment of a liquid crystal structure according to the present invention.
第11圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 11 is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第12A圖:為本發明液晶結構又一實施例之構造示意圖。 Fig. 12A is a schematic view showing the configuration of still another embodiment of the liquid crystal structure of the present invention.
第12B圖:為本發明液晶結構又一實施例之構造示意圖。 12B is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第13A圖:為本發明液晶結構又一實施例之構造示意圖。 Fig. 13A is a schematic view showing the configuration of still another embodiment of the liquid crystal structure of the present invention.
第13B圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 13B is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第14圖:為本發明液晶結構又一實施例在切換時之構造示意圖。 Figure 14 is a schematic view showing the construction of a liquid crystal structure according to another embodiment of the present invention at the time of switching.
第15圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 15 is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第16圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 16 is a schematic view showing the structure of still another embodiment of the liquid crystal structure of the present invention.
第17A圖:為本發明液晶結構又一實施例之構造示意圖。 17A is a schematic view showing the configuration of still another embodiment of the liquid crystal structure of the present invention.
第17B圖:為本發明如第17A圖所示實施例之部分構件俯視圖。 Figure 17B is a plan view of a portion of the components of the embodiment of the present invention as shown in Figure 17A.
第18圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 18 is a schematic view showing the configuration of still another embodiment of the liquid crystal structure of the present invention.
第19圖:為本發明液晶結構又一實施例在切換時之構造示意圖。 Figure 19 is a schematic view showing the construction of another embodiment of the liquid crystal structure of the present invention at the time of switching.
第20圖:為本發明液晶結構又一實施例之構造示意圖。 Figure 20 is a schematic view showing the configuration of still another embodiment of the liquid crystal structure of the present invention.
請參閱第2圖,為本發明液晶結構一較佳實施例之構造示意圖。如圖所示,本發明所述之液晶結構20包括有一膽固醇液晶21,並於膽固醇液晶21內摻雜有一染料(Dyes)23,如第2圖所示之斜線部分,膽固醇液晶21包括有複數個膽固醇液晶分子211,並致使膽固醇液晶21之螺旋軸方向或排列將具有一定的秩序的指紋型排列(Fingerprint Texture),例如將膽固醇液晶分子211的螺旋軸朝單一方向X1。接續再將該指紋型排列的膽固醇液晶21藉由一聚合物予以凍結固定。 Please refer to FIG. 2 , which is a schematic structural view of a liquid crystal structure according to a preferred embodiment of the present invention. As shown in the figure, the liquid crystal structure 20 of the present invention comprises a cholesteric liquid crystal 21, and is doped with a dye (Dyes) 23 in the cholesteric liquid crystal 21, as shown by the oblique line portion shown in FIG. 2, and the cholesteric liquid crystal 21 includes a plurality of The cholesteric liquid crystal molecules 211, and cause the spiral axis direction or arrangement of the cholesteric liquid crystal 21 to have a certain order of Fingerprint Texture, for example, the spiral axis of the cholesteric liquid crystal molecules 211 is directed to a single direction X1. The fingerprint-type cholesteric liquid crystal 21 is then freeze-fixed by a polymer.
本發明於膽固醇液晶21內所摻雜的染料23可以是二色性染料(Dichroic Dyes),一般而言二色性染料可為在分子長軸方向具有光吸收特性的P型二色性染料,及在分子短軸方向具有光吸收特性的N型二色性染料。染料23摻雜在膽固醇液晶21內,且染料23和膽固醇液晶分子211以相互平行的方式排列,藉此染料23的排列將會隨著膽固醇液晶分子211的運動而改變。 The dye 23 doped in the cholesteric liquid crystal 21 of the present invention may be a dichroic dye (Dichroic Dyes). Generally, the dichroic dye may be a P-type dichroic dye having a light absorbing property in the long axis direction of the molecule. And an N-type dichroic dye having light absorption characteristics in the short axis direction of the molecule. The dye 23 is doped in the cholesteric liquid crystal 21, and the dye 23 and the cholesteric liquid crystal molecules 211 are arranged in parallel with each other, whereby the arrangement of the dye 23 will change with the movement of the cholesteric liquid crystal molecules 211.
請參閱第3圖,為本發明液晶結構在切換時的構造示意圖。如圖所示,本發明所述之液晶結構30包括有一第一基板(或稱前基板)311及一第二基板(或稱後基板)313,並將膽固醇液晶21及染料23設置在第一基板311及第二基板313之間,而膽固醇液晶21將成為指紋型排列,其螺旋軸方向具有一定的秩序,例如膽固醇液晶21包括有複數個膽固醇液晶分子211,且膽固醇液晶分子211的螺旋軸朝單一方向X1。該指紋型排列的膽固醇液晶21將藉由一聚合物45予以凍結固定。 Please refer to FIG. 3, which is a schematic structural view of the liquid crystal structure of the present invention at the time of switching. As shown in the figure, the liquid crystal structure 30 of the present invention includes a first substrate (or front substrate) 311 and a second substrate (or rear substrate) 313, and the cholesteric liquid crystal 21 and the dye 23 are disposed first. Between the substrate 311 and the second substrate 313, the cholesteric liquid crystal 21 will be a fingerprint type arrangement having a certain order in the direction of the spiral axis. For example, the cholesteric liquid crystal 21 includes a plurality of cholesteric liquid crystal molecules 211, and the spiral axis of the cholesteric liquid crystal molecules 211 X1 in a single direction. The fingerprint-type cholesteric liquid crystal 21 will be freeze-fixed by a polymer 45.
第一基板311上可設置有一第一電極33,而第二基板313上則設置有一第二電極35,在使用時可藉由第一電極33及第二電極35供給電壓,並於第一基板311及第二基板313之間形成電場,藉此電場將可以對膽固醇液晶21的排列或螺旋軸方向進行改變。 A first electrode 33 may be disposed on the first substrate 311, and a second electrode 35 is disposed on the second substrate 313. The first electrode 33 and the second electrode 35 may be used to supply a voltage to the first substrate. An electric field is formed between the 311 and the second substrate 313, whereby the electric field can change the alignment of the cholesteric liquid crystal 21 or the direction of the helical axis.
當液晶結構30為平面型排列(Planar Texture)303時,由外界進入的外界光源L1及/或背光光源L3將會被液晶結構30內的染料23所吸收並成為暗態。在應用時,可以對平面型排列303的液晶施加一低電壓脈衝(VL),並使其切換為指紋型排列301。 When the liquid crystal structure 30 is a Planar Texture 303, the external light source L1 and/or the backlight source L3 entering from the outside will be absorbed by the dye 23 in the liquid crystal structure 30 and become a dark state. In application, a low voltage pulse (V L ) can be applied to the liquid crystal of the planar arrangement 303 and switched to the fingerprint arrangement 301.
請同時參閱第4圖,當膽固醇液晶21為指紋型排列301時,由外界進入的光源L1將有部分會被染料23所吸收,而有部分的光源L1則會穿透指紋型排列301的液晶並被反射層反射成為亮態。例如偏振方向垂直膽固醇液晶21螺旋軸方向X1的垂直光X5會被染料23吸收,而偏振方向平行膽固醇液晶21螺旋軸方向X1的平行光X4則會穿透液晶,未被染料23所吸收,並被設於第二基板313內部或底層之反射層32所反射。 Please also refer to FIG. 4, when the cholesteric liquid crystal 21 is in the fingerprint type arrangement 301, a part of the light source L1 entering from the outside will be absorbed by the dye 23, and a part of the light source L1 will penetrate the liquid crystal of the fingerprint type arrangement 301. And reflected by the reflective layer into a bright state. For example, the vertical light X5 of the polarization direction vertical cholesteric liquid crystal 21 in the helical axis direction X1 is absorbed by the dye 23, and the parallel light X4 whose polarization direction is parallel to the helical axis direction X1 of the cholesteric liquid crystal 21 penetrates the liquid crystal and is not absorbed by the dye 23, and It is reflected by the reflective layer 32 provided inside or under the second substrate 313.
使用時若對指紋型排列301的膽固醇液晶21施加一高電壓脈衝VH,例如一可將膽固醇液晶21從指紋型排列301切換成為垂直型排列(Homeotropic Texture)302的臨界電壓(Euw)脈衝,藉此液晶結構30將會經由垂直型排列302後而被切換成平面型排列303,如箭頭S1/S2。 When using, a high voltage pulse V H is applied to the cholesteric liquid crystal 21 of the fingerprint type array 301, for example, a threshold voltage (Euw) pulse for switching the cholesteric liquid crystal 21 from the fingerprint type array 301 to the homeotropic texture 302. Thereby, the liquid crystal structure 30 will be switched to the planar arrangement 303 via the vertical alignment 302, as indicated by the arrows S1/S2.
在實際操作下,如果對指紋型排列301的液晶21施加高電壓脈衝VH後,高電壓脈衝VH持續期間將會形成垂直型排列(Homeotropic Texture)302的液晶,如程序箭頭S1。而當高電壓脈衝VH被移除或消失之後,液晶結構30將會由垂直型排列302切換為平面型排列303,如程序箭頭S2。由於垂直型排列302一般係非穩態,因此,垂直型排列302也可被稱為一過渡程序。 Under actual operation, if a high voltage pulse V H is applied to the liquid crystal 21 of the fingerprint type array 301, the high voltage pulse V H will form a liquid crystal of the homeotropic texture 302 during the duration, such as the program arrow S1. When the high voltage pulse V H is removed or disappears, the liquid crystal structure 30 will be switched from the vertical alignment 302 to the planar alignment 303, as in the program arrow S2. Since the vertical alignment 302 is generally non-steady, the vertical alignment 302 can also be referred to as a transition procedure.
又,如果對膽固醇液晶21施加一低電壓脈衝VL,如程序箭頭S3,則液晶結構30又可從平面型排列303切換為指紋型排列301。 Further, if a low voltage pulse is applied to the cholesteric liquid crystal 21 V L, such as program arrow S3, the switching of the liquid crystal structure 30 in turn from the planar arrangement 303 arranged 301 fingerprint type.
平面型排列303及指紋型排列301皆為穩態,因此當液晶結構30切換為平面型排列303或指紋型排列301後便不需要繼續供給電壓,並可長時間維持在平面型排列303或指紋型排列301。 Both the planar arrangement 303 and the fingerprint arrangement 301 are in a steady state. Therefore, when the liquid crystal structure 30 is switched to the planar arrangement 303 or the fingerprint arrangement 301, the voltage supply does not need to be continued, and the planar arrangement 303 or the fingerprint can be maintained for a long time. Type arrangement 301.
由於平面型排列303為暗態,指紋型排列301為亮態,因此本發明所述之液晶結構30可使用在反射式、穿透式或半反射半穿透式的面板上,並可以對可見光波長範圍內的光源進行反射。例如在第4圖中,指紋型排列301,其第二基板313底層設有一部分畫素區域之反射層32,而另一部分畫素區域為背光光源L3可以穿透的透明層,因此此指紋型排列30即為一半反射半穿透式之液晶結構。 Since the planar arrangement 303 is in a dark state and the fingerprint-type arrangement 301 is in a bright state, the liquid crystal structure 30 of the present invention can be used on a reflective, transmissive or semi-reflective semi-transmissive panel and can be used for visible light. Light sources in the wavelength range are reflected. For example, in FIG. 4, the fingerprint type arrangement 301 has a reflective layer 32 of a part of the pixel area on the bottom layer of the second substrate 313, and a transparent layer that the backlight source L3 can penetrate through the other part of the pixel area, so the fingerprint type The array 30 is a half-reflective, semi-transmissive liquid crystal structure.
如果第二基板313底層只有背光光源L3而無反射層32,則此結構即為一穿透式液晶結構。又,如果第二基板313底層只有反射層32而無背光光源L3,則此結構即為一反射式液晶結構 If the bottom layer of the second substrate 313 has only the backlight source L3 and no reflective layer 32, the structure is a transmissive liquid crystal structure. Moreover, if the bottom layer of the second substrate 313 has only the reflective layer 32 and no backlight source L3, the structure is a reflective liquid crystal structure.
背光光源L3至少包括有平行X1之平行光X4及垂直X1之垂直光X5。當背光光源L3從第二基板313射入液晶21時,則有平行光X4可穿透,而垂直光X5則會被吸收,因此穿透光L4就只有平行光X4。 The backlight source L3 includes at least parallel light X4 parallel to X1 and vertical light X5 perpendicular to X1. When the backlight source L3 is incident on the liquid crystal 21 from the second substrate 313, the parallel light X4 is permeable, and the vertical light X5 is absorbed, so that the transmitted light L4 has only the parallel light X4.
外界光源L1也同樣具有平行X1之平行光X4及垂直X1之垂直光X5,當外界光源L1從第一基板311入射時,垂直光X5將會被吸收,而平行光X4將可到達第二基板313,如入射光L12,再藉由設於第二基板313上內部、表面或底層之反射層32反射,以成為一反射光L2。反射光L2存在有平行光X4,而反射光L2將可穿透液晶21以反射出去。 The external light source L1 also has parallel light X4 parallel to X1 and vertical light X5 perpendicular to X1. When the external light source L1 is incident from the first substrate 311, the vertical light X5 will be absorbed, and the parallel light X4 will reach the second substrate. 313, such as incident light L12, is reflected by the reflective layer 32 disposed on the inner, surface or bottom layer of the second substrate 313 to become a reflected light L2. The reflected light L2 is present with parallel light X4, and the reflected light L2 will penetrate the liquid crystal 21 to be reflected.
外界光源L1在穿透指紋型排列301的膽固醇液晶21後,將會被反射層32所反射,並使得液晶結構為亮態。此外相較於習用膽固醇液晶面板(10)以平面型排列及焦點圓錐型排列為雙穩態之構造而言,本發明之穩態主要是藉由平面型排列303及指紋型排列301之間的切換動作而成,因此可提高切換的速度以提高顯示的品質。 The external light source L1 will be reflected by the reflective layer 32 after penetrating the cholesteric liquid crystal 21 of the fingerprint type arrangement 301, and the liquid crystal structure is in a bright state. In addition, the steady state of the present invention is mainly between the planar arrangement 303 and the fingerprint type arrangement 301, compared to the conventional cholesteric liquid crystal panel (10) having a planar arrangement and a focal conic arrangement as a bistable structure. The switching action is made, so the switching speed can be increased to improve the quality of the display.
請參閱第5圖,為本發明液晶結構又一實施例之構造示意圖。如圖所示,本發明所述之液晶結構40包括有一第一基板311及第二基板313,並於第一基板311上設置有至少一第一電極33,第二基板313上則依序設置有至少一第二電極35及至少一第三電極47。其中第二電極35及第三電極47之間還設置有一絕緣層46,且第三電極47為一共平面電極,而膽固醇液晶21及染料23則設置在第一基板311及第二基板313之間。 Please refer to FIG. 5, which is a schematic structural view of still another embodiment of the liquid crystal structure of the present invention. As shown in the figure, the liquid crystal structure 40 of the present invention includes a first substrate 311 and a second substrate 313, and at least one first electrode 33 is disposed on the first substrate 311, and the second substrate 313 is sequentially disposed. There are at least one second electrode 35 and at least one third electrode 47. An insulating layer 46 is disposed between the second electrode 35 and the third electrode 47, and the third electrode 47 is a coplanar electrode, and the cholesteric liquid crystal 21 and the dye 23 are disposed between the first substrate 311 and the second substrate 313. .
在此本發明實施例中,膽固醇液晶21可為一雙頻液晶(Dual Frequency LC),雙頻液晶在低頻電壓下會表現出正型液晶特性,而在高頻 電壓下則會表現出螺旋軸跟水平電場平行之負型液晶特性。因此在應用時可將膽固醇液晶21(雙頻液晶)及染料23設置於第一基板311及第二基板313之間,並透過第三電極47所形成的高頻水平電場E使得膽固醇液晶21成為指紋型排列,且膽固醇液晶21的螺旋軸朝單一方向或螺旋軸方向具有一定的秩序。 In the embodiment of the present invention, the cholesteric liquid crystal 21 can be a dual frequency liquid crystal (Dual Frequency LC), and the dual frequency liquid crystal exhibits positive liquid crystal characteristics at a low frequency voltage, and at a high frequency. Under voltage, the negative liquid crystal characteristics of the spiral axis parallel to the horizontal electric field are exhibited. Therefore, when applied, the cholesteric liquid crystal 21 (dual-frequency liquid crystal) and the dye 23 can be disposed between the first substrate 311 and the second substrate 313, and the high-frequency horizontal electric field E formed by the third electrode 47 can make the cholesteric liquid crystal 21 become The fingerprint type is arranged, and the spiral axis of the cholesteric liquid crystal 21 has a certain order in a single direction or a spiral axis direction.
在實際製作時可將膽固醇液晶21與一高分子單體(monomer,例如BAB6)25混合,並進行聚合以凍結指紋型排列,之後再透過第一電極33及第二電極35之間的低頻電場來改變膽固醇液晶21的排列方式。對第一電極33及第二電極35輸入一縱向高電壓脈衝,例如一縱向低頻高電壓脈衝,便可以將膽固醇液晶21切換為平面型排列;若對第一電極33及第二電極35再輸入一縱向低電壓脈衝,例如一縱向低頻低電壓脈衝,則會將膽固醇液晶21切換為指紋型排列。 In actual production, the cholesteric liquid crystal 21 may be mixed with a polymer monomer (for example, BAB6) 25, and polymerized to freeze the fingerprint type arrangement, and then pass through the low frequency electric field between the first electrode 33 and the second electrode 35. To change the arrangement of the cholesteric liquid crystals 21. By inputting a longitudinal high voltage pulse, for example, a longitudinal low frequency high voltage pulse, to the first electrode 33 and the second electrode 35, the cholesteric liquid crystal 21 can be switched to a planar arrangement; if the first electrode 33 and the second electrode 35 are re-entered A longitudinal low voltage pulse, such as a longitudinal low frequency low voltage pulse, switches the cholesteric liquid crystal 21 to a fingerprint type arrangement.
在製作時主要於一膽固醇液晶21內摻雜至少一染料23;再將膽固醇液晶21與一高分子單體25進行混合;並使得膽固醇液晶21為螺旋軸具有一定秩序或朝單一方向的指紋型排列;最後再對高分子單體25進行一光照或加熱等固化程序,以凍結膽固醇液晶21,例如使其維持在指紋型排列結構。 At the time of production, at least one dye 23 is doped into the cholesteric liquid crystal 21; the cholesteric liquid crystal 21 is mixed with a polymer monomer 25; and the cholesteric liquid crystal 21 has a certain order or a fingerprint direction in a single direction. Arrangement; finally, the polymer monomer 25 is subjected to a curing process such as light irradiation or heating to freeze the cholesterol liquid crystal 21, for example, to maintain the fingerprint type alignment structure.
在本發明一實施例中,高分子單體25被進行一光照或加熱等固化程序後,將致使高分子單體成為一聚合物45,並以該聚合物以凍結膽固醇液晶21的結構。 In an embodiment of the present invention, after the polymer monomer 25 is subjected to a curing process such as light irradiation or heating, the polymer monomer becomes a polymer 45, and the polymer freezes the structure of the cholesteric liquid crystal 21.
由於本發明之膽固醇液晶21將成為指紋型排列,其螺旋軸方向具有一定的秩序性或單一方向,且將藉由高分子單體25所形成之聚合物45以凍結指紋型排列,因此即便之後不再以第三電極47來形成水平電場E,膽固醇液晶21依然會維持其指紋型排列。 Since the cholesteric liquid crystal 21 of the present invention will be a fingerprint type arrangement, the direction of the spiral axis has a certain order or a single direction, and the polymer 45 formed by the polymer monomer 25 is arranged in a frozen fingerprint type, so even after The horizontal electric field E is no longer formed by the third electrode 47, and the cholesteric liquid crystal 21 still maintains its fingerprint type arrangement.
前述各實施例之高電壓脈衝或低電壓脈衝皆為在膽固醇液晶領域專業人士所能極易思及之用詞,例如公開刊載於(http://osdlab.eic.nctu.edu.tw/LC/data/issues/2004_1/05.pdf):中國液態晶體學會簡訊-2004年第一期(2004年06月)-膽固醇型液晶電子書(E-Book),因此在本發明中不對高電壓脈衝及低電壓脈衝進行詳盡之定義或說明。 The high voltage pulses or low voltage pulses of the foregoing embodiments are all words that can be easily considered by professionals in the field of cholesterol liquid crystals, for example, published in (http://osdlab.eic.nctu.edu.tw/LC /data/issues/2004_1/05.pdf): China Liquid Crystal Society Newsletter - 2004, Issue 1 (June 2004) - Cholesterol-type LCD e-book (E-Book), so in the present invention, no high voltage pulse And a low voltage pulse for a detailed definition or description.
請參閱第6圖,為本發明液晶結構又一實施例之構造示意圖。如圖所示,本發明所述之液晶結構50包括有一第一基板311及第二基板313,第二基板313上設置有至少一第三電極47,並於第一基板311及第二基板313之間設置膽固醇液晶21及染料23。 Please refer to FIG. 6 , which is a schematic structural view of still another embodiment of the liquid crystal structure of the present invention. As shown in the figure, the liquid crystal structure 50 of the present invention includes a first substrate 311 and a second substrate 313. The second substrate 313 is provided with at least one third electrode 47, and is disposed on the first substrate 311 and the second substrate 313. Cholesteric liquid crystal 21 and dye 23 are disposed between each other.
在此本發明實施例中,膽固醇液晶21為一負型液晶,而藉由第三電極47來產生一與第一基板311及/或第二基板313呈現水平的水平電場E時,將使得膽固醇液晶21成為一螺旋軸具有一定秩序或朝單一方向的指紋型排列。而當第三電極47所形成水平電場E被移除後,膽固醇液晶21便會因為第一基板311及第二基板313的水平配向而成為平面型排列結構。 In the embodiment of the present invention, the cholesteric liquid crystal 21 is a negative liquid crystal, and when the third electrode 47 generates a horizontal electric field E that is horizontal to the first substrate 311 and/or the second substrate 313, the cholesterol is caused. The liquid crystal 21 is a fingerprint type arrangement in which a spiral axis has a certain order or a single direction. When the horizontal electric field E formed by the third electrode 47 is removed, the cholesteric liquid crystal 21 becomes a planar arrangement due to the horizontal alignment of the first substrate 311 and the second substrate 313.
當然在實際應用時亦可以選擇在第一基板311上設置有至少一第一電極33,而在第二基板313上則設置有至少一第二電極35,並有一絕緣層46介於第二電極35與第三電極47之間。當第一電極33及第二電極35之間形成或施加一縱向電場E1時,也可以使得膽固醇液晶21成為平面型排列,藉此將有利於膽固醇液晶21之結構排列形態轉換速度的提高。 Of course, in the actual application, at least one first electrode 33 may be disposed on the first substrate 311, and at least one second electrode 35 is disposed on the second substrate 313, and an insulating layer 46 is interposed between the second electrodes. 35 is between the third electrode 47. When a longitudinal electric field E1 is formed or applied between the first electrode 33 and the second electrode 35, the cholesteric liquid crystal 21 can be arranged in a planar arrangement, whereby the structural morphological conversion speed of the cholesteric liquid crystal 21 is favored.
為此,第一電極33、第二電極35及/或第三電極47的設置與否將可依據膽固醇液晶21的特性來進行調整或改變。 For this reason, the setting of the first electrode 33, the second electrode 35, and/or the third electrode 47 may be adjusted or changed depending on the characteristics of the cholesteric liquid crystal 21.
請參閱第7圖,為本發明液晶結構一實施例的部分構造俯視圖。本發明前述第5圖及第6圖所示之第三電極47係可以一長條狀的方式設置,相鄰兩兩第三電極47將相互平行,藉此膽固醇液晶21的螺旋軸將會朝單一方向,如第7圖所示之第一方向X1。 Please refer to FIG. 7 , which is a partial structural plan view of an embodiment of a liquid crystal structure according to the present invention. The third electrode 47 shown in the fifth and sixth figures of the present invention may be disposed in a strip shape, and the adjacent two third electrodes 47 will be parallel to each other, whereby the spiral axis of the cholesteric liquid crystal 21 will be directed toward Single direction, such as the first direction X1 shown in Figure 7.
在本發明又一實施例中,第三電極47也可以如第8圖所示之「ㄑ」狀、或如第9圖所示之波浪狀、或第10圖所示之螺旋狀或多角形的方式設置,膽固醇液晶21之螺旋軸方向將會具有一定的秩序,但並不會全部朝同一個單一方向,有部分膽固醇液晶21的螺旋軸朝向第二方向X2,而有部分膽固醇液晶21的螺旋軸則會朝第三方向X3。 In still another embodiment of the present invention, the third electrode 47 may have a "ㄑ" shape as shown in FIG. 8, or a wave shape as shown in FIG. 9, or a spiral shape or a polygonal shape as shown in FIG. In the way of setting, the direction of the spiral axis of the cholesteric liquid crystal 21 will have a certain order, but not all of them are in the same single direction, and the spiral axis of the partial cholesteric liquid crystal 21 faces the second direction X2, and there is a part of the cholesteric liquid crystal 21 The screw shaft will be X3 in the third direction.
本實施例中,膽固醇液晶21之螺旋軸方向具有一定的秩序,但並不是只有單一方向X2或單一方向X3,與第7圖所示實施例中只有單一方向X1之態樣並不相同。以單一畫素來看,雖然螺旋軸方向並非朝向單一方向,但以畫素之部分區域來看,螺旋軸方向仍然是具有單一方向,因此,膽固醇液晶21之螺旋軸方向具有一定的秩序。 In the present embodiment, the direction of the spiral axis of the cholesteric liquid crystal 21 has a certain order, but it is not only the single direction X2 or the single direction X3, which is different from the single direction X1 in the embodiment shown in Fig. 7. In terms of a single pixel, although the direction of the spiral axis is not directed to a single direction, in the case of a part of the pixel, the direction of the spiral axis still has a single direction. Therefore, the direction of the spiral axis of the cholesteric liquid crystal 21 has a certain order.
請參閱第11圖,為本發明液晶結構又一實施例之構造示意圖。如圖所示,本發明所述之液晶結構60包括有一第一基板311及第二基板313,並於第一基板311上設置有至少一第一電極33,第二基板313上則設置有至少一第二電極35,而具有正型液晶特色之膽固醇液晶21及染料23則設置在第一基板311及第二基板313之間。 Please refer to FIG. 11 , which is a schematic structural view of still another embodiment of the liquid crystal structure of the present invention. As shown in the figure, the liquid crystal structure 60 of the present invention includes a first substrate 311 and a second substrate 313, and at least one first electrode 33 is disposed on the first substrate 311, and at least a second substrate 313 is disposed on the second substrate 313. A second electrode 35, and a cholesteric liquid crystal 21 having a positive liquid crystal characteristic and a dye 23 are disposed between the first substrate 311 and the second substrate 313.
在應用時,於形成第一電極33及第二電極35後,將在第一電 極33/第二電極35及/或第一基板311/第二基板313表面進行互為平行或反平行之水平配向處理,如圖式X6。再藉由第一電極33及第二電極35對膽固醇液晶21之平面型排列結構施加一縱向小電場E2,例如在d/p>3/2(d為面板間距,p為膽固醇液晶螺距)且平面型排列303之狀況條件下,對膽固醇液晶21施加約為0.3V/um的縱向小電場E2,藉此可使得膽固醇液晶21成為螺旋軸垂直於水平配向方向X6的指紋型排列301,再藉由高分子單體所形成的聚合物45將膽固醇液晶21凍結於指紋型排列結構301。 In application, after forming the first electrode 33 and the second electrode 35, the first electricity will be The surface of the pole 33 / the second electrode 35 and / or the first substrate 311 / the second substrate 313 are horizontally aligned or anti-parallel to each other, as shown in the formula X6. Applying a longitudinal small electric field E2 to the planar arrangement of the cholesteric liquid crystal 21 by the first electrode 33 and the second electrode 35, for example, at d/p>3/2 (d is the panel pitch, p is the cholesteric liquid crystal pitch) Under the condition of the planar arrangement 303, a longitudinal small electric field E2 of about 0.3 V/um is applied to the cholesteric liquid crystal 21, whereby the cholesteric liquid crystal 21 can be made into a fingerprint-type arrangement 301 in which the helical axis is perpendicular to the horizontal alignment direction X6. The polymer 45 formed of a polymer monomer freezes the cholesteric liquid crystal 21 in the fingerprint-type array structure 301.
在應用時,可以對第一電極33及第二電極35輸入一高電壓脈衝,將使得膽固醇液晶21從指紋型排列301切換為平面型排列303。若對第一電極33及第二電極35再輸入一低電壓脈衝時,又可使得膽固醇液晶21從平面型排列303切換為指紋型排列301,如第3圖所示之程序S1/S2/S3。 In application, a high voltage pulse can be input to the first electrode 33 and the second electrode 35 to switch the cholesteric liquid crystal 21 from the fingerprint type arrangement 301 to the planar type arrangement 303. When a low voltage pulse is input to the first electrode 33 and the second electrode 35, the cholesteric liquid crystal 21 can be switched from the planar arrangement 303 to the fingerprint arrangement 301, as shown in FIG. 3, the program S1/S2/S3. .
在本發明又一實施例中,正型液晶亦可使用一雙頻液晶配合一低頻電壓,使其表現正型液晶特色。同理,負型液晶亦可使用雙頻液晶配合一高頻電壓,使其表現負型液晶特色。 In still another embodiment of the present invention, the positive liquid crystal may also use a dual frequency liquid crystal in combination with a low frequency voltage to make it exhibit a positive liquid crystal characteristic. Similarly, the negative-type liquid crystal can also use a dual-frequency liquid crystal with a high-frequency voltage to make it exhibit negative-type liquid crystal characteristics.
接續,請參閱第12A圖,係為本發明又一實施例在切換時之構造示意圖。本發明液晶結構70亦可適用於掺雜有大量高分子單體之高分子分布型膽固醇液晶結構(Polymer Dispersed Cholesteric Liquid Crystal;PDCLC),主要係將膽固醇液晶21內掺雜有至少一染料23,並與一高分子單體(25)混合,且需調控液晶/高分子單體(CLC/monomer)重量比。 Next, please refer to FIG. 12A, which is a schematic diagram of the configuration at the time of switching according to still another embodiment of the present invention. The liquid crystal structure 70 of the present invention can also be applied to a Polymer Dispersed Cholesteric Liquid Crystal (PDCLC) doped with a large amount of polymer monomers, mainly by doping the cholesteric liquid crystal 21 with at least one dye 23, And mixed with a high molecular monomer (25), and need to regulate the liquid crystal / polymer monomer (CLC / monomer) weight ratio.
將調配好之膽固醇液晶21、染料23及高分子單體(25)放置於第一基板311及第二基板313之間。對高分子單體(25)及膽固醇液晶21進行一光照或加熱等固化程序,以形成一聚合物45及複數個液晶滴(droplet)71,聚合物45將包覆液晶滴71,而液晶滴71內則存在有膽固醇液晶21及染料23。 The prepared cholesterol liquid crystal 21, the dye 23, and the polymer monomer (25) are placed between the first substrate 311 and the second substrate 313. The polymer monomer (25) and the cholesteric liquid crystal 21 are subjected to a curing process such as light irradiation or heating to form a polymer 45 and a plurality of liquid crystal droplets 71, and the polymer 45 will coat the liquid crystal droplets 71, and the liquid crystal droplets There are cholesterol liquid crystal 21 and dye 23 in 71.
如果在形成條件搭配適宜下,例如搭配配向、液晶/高分子重量比、光照/加熱等固化程序及/或液晶滴尺寸遠大於液晶螺距等形成條件,膽固醇液晶21及染料23將在液晶滴21內形成一球石狀(spherulite)排列304。 If the formation conditions are properly matched, for example, the alignment process, the liquid crystal/polymer weight ratio, the light/heating curing process, and/or the liquid crystal droplet size is much larger than the liquid crystal pitch, the cholesteric liquid crystal 21 and the dye 23 will be in the liquid crystal droplet 21 A spherulite arrangement 304 is formed therein.
在本發明一實施例中,其膽固醇液晶21係可為一負型液晶或一可表現負型特色之雙頻液晶,例如一E7(向列型)液晶。高分子單體(25)可選用一NOA65材料(照光或加熱會鏈結為聚合物的單體),而液晶/高分子單體重量比則調控為1:1,藉此以形成球石狀之液晶排列304。 In an embodiment of the invention, the cholesteric liquid crystal 21 can be a negative liquid crystal or a dual frequency liquid crystal which can exhibit a negative characteristic, such as an E7 (nematic) liquid crystal. The polymer monomer (25) can be selected from a NOA65 material (lighting or heating will be a polymer monomer), and the liquid crystal/polymer monomer weight ratio is regulated to 1:1, thereby forming a ball-like shape. The liquid crystal array 304.
在第一基板311及第二基板313之間輸入一水平電場E,例如藉由第三電極47所形成之水平電場E,可將球石狀之膽固醇液晶21及染料23從球石狀排列304切換為指紋型排列301,而指紋型排列301之膽固醇液晶21將具有一定的秩序或朝單一方向之螺旋軸。 A horizontal electric field E is input between the first substrate 311 and the second substrate 313. For example, the horizontal electric field E formed by the third electrode 47 can align the spherical cholesteric liquid crystal 21 and the dye 23 from the ball-like shape 304. Switching to the fingerprint type arrangement 301, and the cholesteric liquid crystal 21 of the fingerprint type arrangement 301 will have a certain order or a spiral axis in a single direction.
如果再移除水平電場E,則位於液晶滴71內之膽固醇液晶21又可從指紋型排列301切換為球石狀排列304。因此可藉由水平電場E之存在與否以決定液晶結構70之暗亮態樣。例如球石狀排列304係為暗態,而指紋型排列301係為亮態。 If the horizontal electric field E is removed again, the cholesteric liquid crystal 21 located in the liquid crystal droplet 71 can be switched from the fingerprint type arrangement 301 to the ball-like arrangement 304. Therefore, the dark state of the liquid crystal structure 70 can be determined by the presence or absence of the horizontal electric field E. For example, the ball-like arrangement 304 is in a dark state, and the fingerprint-type arrangement 301 is in a bright state.
在本發明又一實施例中,如第12B圖所示,如果膽固醇液晶21係為一正型液晶或一可表現正型特色之雙頻液晶,第一基板311及第二基板313之間輸入一縱向電場E1,例如由第一電極33及第二電極35所形成之縱向電場E1,則球石狀排列304之膽固醇液晶21及染料23將被切換為指紋型排列301。因此可藉由縱向電場E1之存在與否以決定液晶結構70之暗亮態樣。例如指紋型排列301係為亮態,而球石狀排列304係為暗態。 In another embodiment of the present invention, as shown in FIG. 12B, if the cholesteric liquid crystal 21 is a positive liquid crystal or a dual frequency liquid crystal which can exhibit a positive characteristic, the input between the first substrate 311 and the second substrate 313 A longitudinal electric field E1, for example, a longitudinal electric field E1 formed by the first electrode 33 and the second electrode 35, the cholesteric liquid crystal 21 and the dye 23 in the spheroidal arrangement 304 are switched to the fingerprint type arrangement 301. Therefore, the dark state of the liquid crystal structure 70 can be determined by the presence or absence of the longitudinal electric field E1. For example, the fingerprint type arrangement 301 is in a bright state, and the ball-shaped arrangement 304 is in a dark state.
請參閱第13A圖,係為本發明又一實施例在切換時之構造示意圖,本發明液晶結構80可適用於微膠囊膽固醇液晶結構。利用一已被熟知之微膠囊製程技術,例如類似電泳顯示器製作微膠囊的技術,可形成複數個微膠囊液晶滴72,而微膠囊液晶滴72主要係利用一微膠囊外殼層77以包覆膽固醇液晶21及染料23,並形成球石狀排列304。而膽固醇液晶21係可選用負型液晶或可表現負型液晶特色之雙頻液晶。 Please refer to FIG. 13A, which is a schematic diagram of a configuration of a further embodiment of the present invention at the time of switching. The liquid crystal structure 80 of the present invention can be applied to a microcapsule cholesteric liquid crystal structure. Using a well-known microcapsule process technology, such as a microcapsule-like technique for forming an electrophoretic display, a plurality of microcapsule liquid crystal droplets 72 can be formed, while the microcapsule liquid crystal droplets 72 utilize a microcapsule shell layer 77 to coat the cholesterol. The liquid crystal 21 and the dye 23 form a ball-like arrangement 304. The cholesteric liquid crystal 21 system can be selected with a negative liquid crystal or a dual-frequency liquid crystal which can exhibit a negative liquid crystal characteristic.
同理,可藉由水平電場E之存在與否以決定液晶結構80之暗亮態樣。例如沒有水平電場E存在時之球石狀排列304係為暗態,而有水平電場E存在時之指紋型排列301係為亮態。 Similarly, the dark state of the liquid crystal structure 80 can be determined by the presence or absence of the horizontal electric field E. For example, the spherical arrangement 304 in the absence of the horizontal electric field E is in a dark state, and the fingerprint arrangement 301 in the presence of the horizontal electric field E is in a bright state.
當然,如第13B圖所示,如果膽固醇液晶21係為一正型液晶或一可表現正型特色之雙頻液晶,也可藉由縱向電場E1之存在與否以決定液晶結構80之暗亮態樣。例如有縱向電場E1存在時之指紋型排列301係為亮態,而沒有縱向電場E1存在時之球石狀排列304係為暗態。 Of course, as shown in FIG. 13B, if the cholesteric liquid crystal 21 is a positive liquid crystal or a dual frequency liquid crystal which can exhibit a positive characteristic, the presence or absence of the vertical electric field E1 can also determine the darkness of the liquid crystal structure 80. Aspect. For example, the fingerprint type arrangement 301 in the presence of the longitudinal electric field E1 is in a bright state, and the spherical arrangement 304 in the absence of the longitudinal electric field E1 is in a dark state.
另外,請參閱第14圖,係本發明又一實施例在切換時之構造示意圖,本實施例液晶結構90類似前述第3圖所示實施例,將雙頻液晶21、染料23混合後放置於第一基板311及第二基板313之間。 In addition, referring to FIG. 14, a schematic diagram of a configuration of another embodiment of the present invention at the time of switching, the liquid crystal structure 90 of the present embodiment is similar to the embodiment shown in FIG. 3, and the dual-frequency liquid crystal 21 and the dye 23 are mixed and placed. Between the first substrate 311 and the second substrate 313.
當第一電極33及第二電極35之間產生一縱向電場E2時,液晶結構90將成為焦點圓錐型排列305,表現出正型液晶特色。經由輸入之 一高電壓(VH)而將膽固醇液晶21切換為垂直型排列302(VH持續供給期間),如箭頭S1,或輸入一高電壓脈衝(VH)而切換成平面型排列303,如箭頭S1/S2。又,輸入一縱向低電壓脈衝(VL)時,平面型排列303之液晶結構90又可切換回焦點圓錐型排列305,如箭頭S3。 When a longitudinal electric field E2 is generated between the first electrode 33 and the second electrode 35, the liquid crystal structure 90 will become the focal conic arrangement 305, exhibiting a positive liquid crystal characteristic. And the cholesteric liquid crystal 21 is switched to the vertical arrangement of 302 (V H during the continuous supply) via one of the input high voltage (V H), as indicated by arrows S1, input or a high voltage pulse (V H) is switched to the planar arrangement 303 , such as the arrow S1/S2. Also, when a longitudinal low voltage pulse (V L ) is input, the liquid crystal structure 90 of the planar array 303 can be switched back to the focal conic arrangement 305, as indicated by arrow S3.
而在平面型排列303、垂直型排列302或焦點圓錐型排列305時,若輸入第三電場47所形成之水平電場E,雙頻液晶21將表現出負型液晶特色,以致使膽固醇液晶21成為螺旋軸具有一定秩序或朝單一方向的指紋型排列301,指紋型排列301係為一亮態,如箭頭S4或S5。 In the case of the planar arrangement 303, the vertical alignment 302 or the focal conic arrangement 305, if the horizontal electric field E formed by the third electric field 47 is input, the dual-frequency liquid crystal 21 will exhibit a negative liquid crystal characteristic, so that the cholesteric liquid crystal 21 becomes The spiral axis has a certain order or a fingerprint type arrangement 301 in a single direction, and the fingerprint type arrangement 301 is in a bright state, such as an arrow S4 or S5.
藉由染料23及/或膽固醇液晶21種類之選擇,指紋型排列301、平面型排列303或焦點圓錐型排列305之亮暗態可搭配設計。 By the selection of the type of dye 23 and/or cholesteric liquid crystal 21, the bright and dark states of the fingerprint type arrangement 301, the planar type arrangement 303 or the focal conic type arrangement 305 can be matched with the design.
請參閱第15圖,係本發明又一實施例之構造示意圖,本發明液晶結構100主要係在第一基板311上分別設有一偏光板91及一第四電極475,第二基板313上則設有第三電極47,第四電極475將與第三電極47形成隔空相互交錯垂直態樣,且第四電極475及第三電極47都個別為一共平面電極。 FIG. 15 is a schematic view showing a configuration of another embodiment of the present invention. The liquid crystal structure 100 of the present invention is mainly provided with a polarizing plate 91 and a fourth electrode 475 on the first substrate 311, and a second substrate 313. There is a third electrode 47, and the fourth electrode 475 is formed in a vertical manner with the third electrode 47, and the fourth electrode 475 and the third electrode 47 are each a coplanar electrode.
於此實施例中,偏光板91之通過軸方向X6為入射紙面,而外界光源L1具有平行X軸之水平光X4及垂直光X5,垂直光X5與通過軸方向X6同方向。 In this embodiment, the passing axis direction X6 of the polarizing plate 91 is the incident paper surface, and the external light source L1 has the horizontal X4 and the vertical light X5 parallel to the X axis, and the vertical light X5 is in the same direction as the passing axis direction X6.
當第三電極47形成水平電場E時,液晶結構100之膽固醇液晶21即可從平面型排列(303)切換成(第一)指紋型排列301,膽固醇液晶21之螺旋軸具有一定秩序或朝單一方向X1。外界光源L1在通過偏光板91時,外界光源之水平光X4將被濾除,僅允許指向紙面之垂直光X5通過,以形成入射光L12。入射光L12將被染料23所吸收或散射,不會形成反射光(L2),因此,在(第一)指紋型排列301係為暗態。 When the third electrode 47 forms the horizontal electric field E, the cholesteric liquid crystal 21 of the liquid crystal structure 100 can be switched from the planar arrangement (303) to the (first) fingerprint type arrangement 301, and the spiral axis of the cholesteric liquid crystal 21 has a certain order or a single Direction X1. When the external light source L1 passes through the polarizing plate 91, the horizontal light X4 of the external light source will be filtered out, and only the vertical light X5 directed to the paper surface is allowed to pass to form the incident light L12. The incident light L12 is absorbed or scattered by the dye 23, and does not form reflected light (L2). Therefore, the (first) fingerprint type array 301 is in a dark state.
當第三電極47之水平電場E消失時,液晶結構100之膽固醇液晶21又可從第一指紋型排列301切換成平面型排列(303)。 When the horizontal electric field E of the third electrode 47 disappears, the cholesteric liquid crystal 21 of the liquid crystal structure 100 can be switched from the first fingerprint type arrangement 301 to the planar type arrangement (303).
當第四電極475形成第二水平電場E3時,液晶結構100之膽固醇液晶21可從平面型排列(303)切換成第二指紋型排列306,膽固醇液晶21之螺旋軸具有一定秩序或朝單一方向X6(指向紙面)。外界光源L1在通過偏光板91時,同樣僅允許指向紙面之垂直光X5通過,以形成入射光L12。而具有X5方向之入射光L12將可通過膽固醇液晶21及染料23,並被反射鏡32反射以形成一反射光L2,因此,在第二指紋型排列306係為亮態。 When the fourth electrode 475 forms the second horizontal electric field E3, the cholesteric liquid crystal 21 of the liquid crystal structure 100 can be switched from the planar arrangement (303) to the second fingerprint type arrangement 306, and the spiral axis of the cholesteric liquid crystal 21 has a certain order or a single direction. X6 (pointing to the paper). When the external light source L1 passes through the polarizing plate 91, only the vertical light X5 directed to the paper surface is allowed to pass to form the incident light L12. The incident light L12 having the X5 direction passes through the cholesteric liquid crystal 21 and the dye 23, and is reflected by the mirror 32 to form a reflected light L2. Therefore, the second fingerprint type arrangement 306 is in a bright state.
同理,當第四電極475之第二水平電場E3消失時,液晶結構100之膽固醇液晶21又可從第二指紋型排列306切換成平面型排列(303)。 Similarly, when the second horizontal electric field E3 of the fourth electrode 475 disappears, the cholesteric liquid crystal 21 of the liquid crystal structure 100 can be switched from the second fingerprint type arrangement 306 to the planar type arrangement (303).
藉由第三電極47所形成之(第一)水平電場E或第四電極475所形成之第二水平電場E3,即可決定膽固醇液晶21之螺旋軸方向,係成為一與偏光板91之通過軸方向相互垂直之暗態,或一與偏光板91之通過軸方向相互水平之亮態。 The spiral electric axis direction of the cholesteric liquid crystal 21 can be determined by the (first) horizontal electric field E formed by the third electrode 47 or the second horizontal electric field E3 formed by the fourth electrode 475, and is passed through the polarizing plate 91. A dark state in which the axial directions are perpendicular to each other, or a horizontal state in which the direction of the passing direction of the polarizing plate 91 is horizontal.
於本發明又一實施例中,亦可藉由聚合物45之形成以凍結固定住第一指紋型排列301或第二型指紋型排列306,再選擇係由第三電極47或第四電極475來產生橫向之水平電場E或E3(如第17B圖所示),以改變膽固醇液晶21之螺旋軸方向,如此也可以產生液晶結構100之暗亮態。 In still another embodiment of the present invention, the first fingerprint type arrangement 301 or the second type fingerprint type arrangement 306 may be fixed by freezing by the formation of the polymer 45, and then selected by the third electrode 47 or the fourth electrode 475. The lateral horizontal electric field E or E3 (as shown in Fig. 17B) is generated to change the direction of the helical axis of the cholesteric liquid crystal 21, so that the dark state of the liquid crystal structure 100 can also be produced.
例如以聚合物45凍結固定第一指紋型排列301,並致使第一指紋型排列301之螺旋軸方向與偏光板91之通過軸方向垂直,以成為暗態。藉由第四電極475所形成之第二水平電場E3,則可讓膽固醇液晶21之螺旋軸選轉90度,以與偏光板91之通過軸方向同方向,以成為第二指紋型排列306之亮態。而第二水平電場E3移除消失時,又可將膽固醇液晶21從第二指紋型排列306切換回暗態之第一型指紋型排列301。 For example, the first fingerprint type arrangement 301 is freeze-fixed by the polymer 45, and the spiral axis direction of the first fingerprint type array 301 is made perpendicular to the direction of the passing axis of the polarizing plate 91 to be in a dark state. By the second horizontal electric field E3 formed by the fourth electrode 475, the spiral axis of the cholesteric liquid crystal 21 can be rotated by 90 degrees so as to be in the same direction as the direction of the passing axis of the polarizing plate 91, so as to become the second fingerprint type arrangement 306. Bright state. When the second horizontal electric field E3 is removed, the cholesteric liquid crystal 21 can be switched from the second fingerprint type array 306 to the dark type first fingerprint type array 301.
於本發明又一實施例中,第一指紋型排列301(或第二型指紋型排列306)亦可適用於如第11圖所示之方法,即是以雙頻液晶21先經由縱向小電場E2及配向處理以形成指紋型排列301後,再經過一固化程序以聚合物45凍結固定第一指紋型排列301。接續,再利用第四電極475來改變雙頻液晶21切換為第二型指紋型排列306,藉此同樣可達到配合偏光板91以切換液晶結構100暗亮態之目的。 In still another embodiment of the present invention, the first fingerprint type arrangement 301 (or the second type fingerprint type arrangement 306) may also be applied to the method as shown in FIG. 11, that is, the dual-frequency liquid crystal 21 first passes through a longitudinal small electric field. After the E2 and the alignment process are performed to form the fingerprint type arrangement 301, the first fingerprint type arrangement 301 is freeze-fixed by the polymer 45 through a curing process. Then, the fourth electrode 475 is used to change the dual-frequency liquid crystal 21 to the second-type fingerprint type array 306, thereby achieving the purpose of matching the polarizing plate 91 to switch the dark state of the liquid crystal structure 100.
在此實施例中,第一電極(33)及第二電極(35)必須存在,但第三電極47及第四電極475則只需選擇其一存在即可。當然,若第一基板311上若設有第一電極(33),則第一電極(33)與第四電極475之間也會存在有一絕緣層。 In this embodiment, the first electrode (33) and the second electrode (35) must be present, but the third electrode 47 and the fourth electrode 475 need only be selected. Of course, if the first electrode (33) is disposed on the first substrate 311, an insulating layer may also exist between the first electrode (33) and the fourth electrode 475.
請參閱第16圖,係為本發明又一實施例之構造示意圖,於第一基板311及第二基板313之間相距有一間隔厚度d。如果液晶結構110在第二型指紋型排列306時,其外界光源L1或背光光源L3之通過軸與膽固醇液晶21之螺旋軸方向平行(或稱同方向),則外界光源L1或背光光源L3將可反射或穿透,以致使液晶結構110在第二型指紋型排列306係為亮態。 Please refer to FIG. 16 , which is a schematic structural view of another embodiment of the present invention, with a gap thickness d between the first substrate 311 and the second substrate 313 . If the liquid crystal structure 110 is in the second type fingerprint type arrangement 306, the passing axis of the external light source L1 or the backlight source L3 is parallel to the spiral axis direction of the cholesteric liquid crystal 21 (or the same direction), then the external light source L1 or the backlight source L3 will It can be reflected or penetrated such that the liquid crystal structure 110 is in a bright state in the second type fingerprint pattern arrangement 306.
當第三電極47產生橫向水平電場E時,接近第三電極47之膽固醇液晶分子213將形成螺旋軸朝向X1,且與水平電場E平行之第一指紋型排列(301),而遠離第三電場47之膽固醇液晶分子215由於厚度d之加寬,因此將不受水平電場E影響,還是維持第二型指紋型排列306,以成為一第三型指紋型排列307。第三型指紋型排列307中的膽固醇液晶分子213及膽固醇液晶分子215之螺旋軸將相互垂直,不管係外界光源L1或背光光源L3將被膽固醇液晶21及/或染料23所吸收,因此第三型指紋型排列307將成為一暗態。 When the third electrode 47 generates the lateral horizontal electric field E, the cholesteric liquid crystal molecules 213 close to the third electrode 47 will form a first fingerprint type arrangement (301) whose spiral axis is oriented toward X1 and parallel to the horizontal electric field E, away from the third electric field. Since the condensed liquid crystal molecules 215 of 47 are widened by the thickness d, they are not affected by the horizontal electric field E, or the second type fingerprint type arrangement 306 is maintained to become a third type fingerprint type arrangement 307. The spiral axes of the cholesteric liquid crystal molecules 213 and the cholesteric liquid crystal molecules 215 in the third type fingerprint type arrangement 307 will be perpendicular to each other, regardless of whether the external light source L1 or the backlight source L3 will be absorbed by the cholesteric liquid crystal 21 and/or the dye 23, and thus the third The fingerprint type arrangement 307 will become a dark state.
如果移除水平電場E,由於第二型指紋型排列306已被一聚合物45予以凍結固定,因此液晶結構110又可從第三型指紋型排列307切換回亮態之第二型指紋型排列306。膽固醇液晶21係可選用負型液晶或具有液晶特色之雙頻液晶。 If the horizontal electric field E is removed, since the second type fingerprint type arrangement 306 has been frozen and fixed by a polymer 45, the liquid crystal structure 110 can be switched from the third type fingerprint type arrangement 307 back to the bright type second type fingerprint type arrangement. 306. The cholesteric liquid crystal 21 system can be selected from a negative liquid crystal or a dual frequency liquid crystal having a liquid crystal characteristic.
圖式中,介於膽固醇液晶213與膽固醇液晶215之間的膽固醇液晶217由於將受到水平電場E之部分影響,因此其螺旋軸X7將轉一角度,例如45度。 In the drawing, the cholesteric liquid crystal 217 interposed between the cholesteric liquid crystal 213 and the cholesteric liquid crystal 215 is affected by a portion of the horizontal electric field E, so that the helical axis X7 thereof is rotated by an angle, for example, 45 degrees.
又,請參閱第17A圖及第17B圖,係分別為本發明又一實施例之構造示意圖及第三電極47/第四電極475之俯視圖,液晶結構120可藉由前述實施例所陳述之製作方法以形成一指紋型排列,例如第二指紋型排列306,係為一亮態。而當設於第一基板311之第四電極475產生橫向第二水平電場E3,且設於第二基板313之第三電極47也同時產生(第一)水平電場E時,鄰近之膽固醇液晶分子215/213將受到影響,而形成膽固醇液晶分子215/213之螺旋軸相互垂直之第三指紋型排列307,則為一暗態。 17A and 17B are top views of a further embodiment of the present invention and a top view of a third electrode 47/fourth electrode 475, which can be fabricated by the foregoing embodiments. The method is to form a fingerprint type arrangement, such as the second fingerprint type arrangement 306, which is a bright state. When the fourth electrode 475 disposed on the first substrate 311 generates a lateral second horizontal electric field E3, and the third electrode 47 disposed on the second substrate 313 simultaneously generates a (first) horizontal electric field E, the adjacent cholesteric liquid crystal molecules 215/213 will be affected, and the third fingerprint type arrangement 307, which forms a spiral axis of the cholesteric liquid crystal molecules 215/213, is a dark state.
第四電極475與第三電極47一樣係為一共平面電極,且第四電極475也可為為一長條狀、一「ㄑ」狀、一波浪狀、一多角形或一螺旋狀。 The fourth electrode 475 is a coplanar electrode like the third electrode 47, and the fourth electrode 475 can also be a strip shape, a "ㄑ" shape, a wave shape, a polygon shape or a spiral shape.
在此實施例中,可藉由第四電極475產生橫向第二水平電場E3以維持第二指紋型排列306之亮態,再藉由第三電極47之(第一)水平電場E之存在與否以決定是否形成第三指紋型排列307之暗態。 In this embodiment, the lateral second horizontal electric field E3 can be generated by the fourth electrode 475 to maintain the bright state of the second fingerprint type arrangement 306, and the presence of the (first) horizontal electric field E by the third electrode 47 is No to determine whether to form the dark state of the third fingerprint type arrangement 307.
在另一實施例中,亦可利用聚合物45先凍結固定第二指紋型排列306之亮態,再藉由第三電極47之(第一)水平電場E之存在與否以決定是否形成第三指紋型排列307之暗態。 In another embodiment, the polymer 45 can be used to freeze and fix the bright state of the second fingerprint type arrangement 306, and then the presence or absence of the (first) horizontal electric field E of the third electrode 47 is used to determine whether or not to form the first The dark state of the three fingerprint type arrangement 307.
本實施例亦可與前述之偏光板(91)搭配使用,利用第二指紋型排列306及第三指紋型排列307間之切換以決定光線是否可通過偏光板(91) 之通過軸,相對也可改變液晶結構120之暗亮態樣。 This embodiment can also be used in combination with the polarizing plate (91) described above, and the switching between the second fingerprint type arrangement 306 and the third fingerprint type arrangement 307 can be used to determine whether the light can pass through the polarizing plate (91). Through the axis, the dark state of the liquid crystal structure 120 can also be changed relatively.
另外,請參閱第18圖,係為本發明又一實施例之構造示意圖。本發明液晶結構130主要係在第一基板311上設有一第一電極33,第一電極33上設有至少一突出物(bump)93及/或至少一隙縫(slit)95,而第二基板313上則設有一第二電極35。 In addition, please refer to FIG. 18, which is a schematic structural view of still another embodiment of the present invention. The liquid crystal structure 130 of the present invention is mainly provided with a first electrode 33 on the first substrate 311, and at least one bump 93 and/or at least one slit 95 is disposed on the first electrode 33, and the second substrate A second electrode 35 is provided on the 313.
當第一電極33及第二電極35間產生一縱向電場(E4)時,由於突出物93及/或隙縫95之作用,將影響縱向電場形成為一斜向電場E4,斜向電場E4將有近似水平電場(E)之性質,而膽固醇液晶21及染料23也相對受到影響而改變其螺旋軸,以致使液晶結構130將從平面型排列303切換成第四指紋形排列308。也因此可改變液晶結構130之暗亮態樣。 When a longitudinal electric field (E4) is generated between the first electrode 33 and the second electrode 35, the longitudinal electric field will be formed into an oblique electric field E4 due to the action of the protrusion 93 and/or the slit 95, and the oblique electric field E4 will have The nature of the horizontal electric field (E) is approximated, and the cholesteric liquid crystal 21 and the dye 23 are also relatively affected to change their helical axes, so that the liquid crystal structure 130 will be switched from the planar arrangement 303 to the fourth fingerprint arrangement 308. It is thus also possible to change the darkness of the liquid crystal structure 130.
當然,如果移除斜向電場E4後,液晶結構130又可從第四指紋形排列308之亮態切換為平面型排列303之暗態。 Of course, if the oblique electric field E4 is removed, the liquid crystal structure 130 can be switched from the bright state of the fourth fingerprint arrangement 308 to the dark state of the planar arrangement 303.
本實施例亦可與前述之偏光板(91)搭配使用,利用平面型排列303及第四指紋形排列308間之切換以決定光線是否可通過偏光板(91)之通過軸,相對也可改變液晶結構130之暗亮態樣。 The embodiment can also be used in combination with the polarizing plate (91), and the switching between the planar arrangement 303 and the fourth fingerprint arrangement 308 can be used to determine whether the light can pass through the axis of the polarizing plate (91), and can also be changed. The dark state of the liquid crystal structure 130.
請參閱第19圖,係為本發明又一實施例在切換時之構造示意圖,本發明液晶結構140在藉由斜向電場E4以形成第四指紋型排列308時,可利用高分子單體所形成之聚合物45以凍結固定該第四指紋型排列308結構,為一亮態。之後再利用第一電極33及第二電極(35)間之高電壓脈衝及/或低電壓脈衝,以作為第四指紋型排列308、平面型排列303或垂直型排列302之切換,藉此以獲得液晶結構140之暗/亮態或雙穩態之間的切換。 Referring to FIG. 19, it is a schematic diagram of a configuration of a further embodiment of the present invention. When the liquid crystal structure 140 of the present invention forms a fourth fingerprint type array 308 by oblique electric field E4, a polymer monomer can be used. The formed polymer 45 freezes and fixes the structure of the fourth fingerprint type arrangement 308, and is in a bright state. Then, a high voltage pulse and/or a low voltage pulse between the first electrode 33 and the second electrode (35) is used as a switch of the fourth fingerprint type arrangement 308, the planar type arrangement 303 or the vertical type arrangement 302, thereby Switching between dark/bright states or bistable states of the liquid crystal structure 140 is obtained.
於本發明又一實施例中,其第二電極(35)也可由第三電極或畫素電極47所取代,而第三電極47或第二電極(35)上也可形成有一隙縫955或一突出物935,同樣可達到產生斜向電場E4之目的。 In still another embodiment of the present invention, the second electrode (35) may also be replaced by a third electrode or a pixel electrode 47, and the third electrode 47 or the second electrode (35) may also be formed with a slit 955 or a The protrusion 935 can also achieve the purpose of generating an oblique electric field E4.
又,突出物93/935及/或隙縫95/955係可為一圓環、一同心圓或一多角形者。 Also, the protrusions 93/935 and/or the slits 95/955 can be a ring, a concentric circle or a polygon.
最後,請參閱第20圖,係為本發明又一實施例之構造示意圖,本發明液晶結構150亦可將膽固醇液晶21先行加熱處理至等向性(isotropic)液態後再降溫,以致使每一個膽固醇液晶21之螺旋軸雖然還是平行第一基板311或第二基板313,但螺旋軸方向並不相同或有一定秩序,例如X1、X5及X7,以形成一第五指紋型排列309,係為暗態。 Finally, please refer to FIG. 20 , which is a schematic structural view of another embodiment of the present invention. The liquid crystal structure 150 of the present invention can also heat the cholesteric liquid crystal 21 to an isotropic liquid state and then cool down, so that each Although the spiral axis of the cholesteric liquid crystal 21 is parallel to the first substrate 311 or the second substrate 313, the directions of the spiral axes are not the same or have a certain order, for example, X1, X5 and X7, to form a fifth fingerprint type arrangement 309. Dark state.
再利用聚合物45以凍結固定第五指紋型排列309後,利用第 三電極47所產生之水平電場E即可將液晶結構150切換成第一指紋型排列301之亮態。如果再移除水平電場E,又可切換回暗態之第五指紋型排列309。如此同樣可達到切換本發明液晶結構150亮暗態之目的。 Reusing the polymer 45 to freeze and fix the fifth fingerprint type arrangement 309, and then using the The horizontal electric field E generated by the three electrodes 47 can switch the liquid crystal structure 150 to the bright state of the first fingerprint type arrangement 301. If the horizontal electric field E is removed again, the fifth fingerprint type arrangement 309 of the dark state can be switched back. Thus, the purpose of switching the bright state of the liquid crystal structure 150 of the present invention can be achieved.
當然,在本發明又一實施例中,膽固醇液晶係為正型液晶或具有正型液晶特色之雙頻液晶時,當聚合物45以凍結固定第五指紋型排列309後,可利用一縱向小電場,同樣可將液晶結構150切換成第一指紋型排列301之亮態。 Of course, in another embodiment of the present invention, when the cholesteric liquid crystal is a positive liquid crystal or a dual frequency liquid crystal having a positive liquid crystal characteristic, when the polymer 45 is frozen and fixed to the fifth fingerprint type array 309, a vertical small length can be utilized. The electric field can also switch the liquid crystal structure 150 to the bright state of the first fingerprint type arrangement 301.
以上所述者,僅為本發明之較佳實施例而已,並非用來限定本發明實施之範圍,例如正型液晶、雙頻液晶、負型液晶或染料材料之搭配選擇來改變暗亮態等變化,即凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 The above is only the preferred embodiment of the present invention, and is not intended to limit the scope of the practice of the present invention, such as positive liquid crystal, dual frequency liquid crystal, negative liquid crystal or dye material combination to change the dark state, etc. Variations, modifications, and modifications of the shapes, structures, features, and spirits of the present invention should be included in the scope of the present invention.
21‧‧‧膽固醇液晶 21‧‧‧Cholesterol LCD
211‧‧‧膽固醇液晶分子 211‧‧‧Cholesterol liquid crystal molecules
23‧‧‧染料 23‧‧‧D dyes
30‧‧‧液晶結構 30‧‧‧Liquid structure
301‧‧‧指紋型排列 301‧‧‧Fingerprint arrangement
302‧‧‧垂直型排列 302‧‧‧Vertical arrangement
303‧‧‧平面型排列 303‧‧‧ flat arrangement
311‧‧‧第一基板 311‧‧‧First substrate
313‧‧‧第二基板 313‧‧‧second substrate
32‧‧‧反射層 32‧‧‧reflective layer
33‧‧‧第一電極 33‧‧‧First electrode
35‧‧‧第二電極 35‧‧‧second electrode
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