TWI568350B - Fluorescent means for working rope in the dark area - Google Patents
Fluorescent means for working rope in the dark area Download PDFInfo
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- TWI568350B TWI568350B TW103115853A TW103115853A TWI568350B TW I568350 B TWI568350 B TW I568350B TW 103115853 A TW103115853 A TW 103115853A TW 103115853 A TW103115853 A TW 103115853A TW I568350 B TWI568350 B TW I568350B
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- body portion
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B21/00—Tying-up; Shifting, towing, or pushing equipment; Anchoring
- B63B21/04—Fastening or guiding equipment for chains, ropes, hawsers, or the like
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/005—Composite ropes, i.e. ropes built-up from fibrous or filamentary material and metal wires
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2083—Jackets or coverings
- D07B2201/2087—Jackets or coverings being of the coated type
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2083—Jackets or coverings
- D07B2201/2092—Jackets or coverings characterised by the materials used
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
本發明涉及一種繩索用熒光識別標識器具。特別地,本發明涉及在海上或水上進行作業的過程中直接暴露在海水的狀態下,可依然徹底防止其表面的水解作用,被波濤和周邊船隻和海上漂浮的各種浮游物體撞擊,或者因這些外力,其表面損傷,也依然有效防止微細氣泡的破損,以持續發揮作為熒光體的功能的繩索用熒光識別標識器具。本發明是對傳統的夜間識別標識器具進行改進的結果。 The present invention relates to a fluorescent identification marker for a rope. In particular, the present invention relates to direct exposure to seawater during operations at sea or on water, and still completely prevents the hydrolysis of its surface, being struck by waves and surrounding vessels and various floating objects floating on the sea, or The external force, the surface damage, is also effective in preventing the breakage of fine bubbles, and the fluorescent identification device for ropes that functions as a fluorescent material is continuously exhibited. The present invention is a result of improvements in conventional nighttime identification marking appliances.
一般在海上為了采獲水產品或捕獲魚類,有很多種類的船隻。鄰接海岸的沿岸碼頭使用纖維繩索拴著這些船隻。 There are many types of vessels generally found at sea for the capture of aquatic products or for catching fish. Coastal piers adjacent to the coast use fiber ropes to carry these vessels.
在海上作業的船隻使用網捕獲各種魚類,相反,為了作業中或作業以後易於識別此網的存在,使用各種能夠浮在水面的各種形狀的浮標。 Ships operating at sea use nets to capture a variety of fish. Conversely, in order to easily identify the presence of the net during or after work, various buoys of various shapes that float on the surface of the water are used.
這種浮標需要浮在水面,因此,比重彼此低於水,不能夠溶解於水或受到水的腐蝕,能夠由某種有形物固定住,不易受到波濤等外力的破損。 Such buoys need to float on the surface of the water. Therefore, the specific gravity is lower than water, and it cannot be dissolved in water or corroded by water. It can be fixed by some kind of tangible material and is not easily damaged by external forces such as waves.
至今,這種浮標主要使用於纖維繩索。纖維繩索為將細絲狀纖維搓成繩股,再將幾個繩股搓在一起而形成。纖維繩索材料使用尼龍等韌性較強的材料,相比較於鋼絲繩更柔軟,不會被海水腐蝕或侵蝕,故用於海岸碼頭或船隻等。 To date, such buoys have been mainly used for fiber ropes. The fiber rope is formed by twisting the filamentous fibers into strands and twisting together several strands. The fiber rope material uses a tougher material such as nylon, which is softer than steel wire rope and will not be corroded or corroded by seawater, so it is used in coastal docks or ships.
傳統的浮標使用於這種纖維繩索,白天一般不會出現問題,但夜間或周圍突然變暗時卻無法準確識別。因此,為補償這些缺陷,開發出一種夜間識別用浮標。夜間識別用標識和夜間識別用浮標使用於海岸或海上,而且,為了在夜 間或暗處把自己的位置告知他人,或者相互容易識別自己和他人的位置,將少量熒光物質與基本材料混在一起製造。 Conventional buoys are used in such fiber ropes, which are generally not problematic during the day, but cannot be accurately identified when the night or surroundings suddenly become dark. Therefore, in order to compensate for these defects, a buoy for night recognition has been developed. The nighttime identification logo and the nighttime identification buoy are used on the coast or at sea, and, in order to be at night Indirectly or in the dark, telling others about their position, or easily recognizing each other and the position of others, and mixing a small amount of fluorescent substances with the basic materials.
傳統的夜間識別用標識和浮標有韓國註冊專利第10-985573號「用廢橡膠和廢合成樹脂的混合材料製成的夜光浮標」以及韓國註冊專利第10-1256083號「繩索的夜間識別標識器具」。韓國註冊專利第10-985573號「用廢橡膠和廢合成樹脂的混合材料製成的夜光浮標」以廢橡膠和廢合成樹脂為主要原料,再加上少量EVA有機添加劑和少量無機添加劑以及少量熒光顏料一起使用。 The conventional nighttime identification mark and buoy are Korean registered patent No. 10-985573 "Night buoy made of a mixture of waste rubber and waste synthetic resin" and Korean registered patent No. 10-1256083 "Night identification mark of rope" "." Korean registered patent No. 10-985573 "Night buoys made of a mixture of waste rubber and waste synthetic resin" with waste rubber and waste synthetic resin as the main raw materials, plus a small amount of EVA organic additive and a small amount of inorganic additives and a small amount of fluorescence Use together with pigments.
但,韓國註冊專利第10-985573號使用的廢橡膠是用液氮在零下170℃至200℃的條件下對廢橡膠塊進行瞬間粉碎而成,技術難度大,所需設備也比較複雜。 However, the waste rubber used in Korean registered patent No. 10-985573 is formed by instantaneously pulverizing the waste rubber block under the condition of liquid nitrogen at 170 ° C to 200 ° C. The technical difficulty is large and the required equipment is complicated.
其缺點是,為粉碎廢橡膠塊,必須採用高技術和投入高額經費。而且,韓國註冊專利第10-1256083號「繩索的夜間識別標識器具」所採用的技術是,形成聚氨酯發泡體,在發泡體的形成過程中依然添加熒物質,利用熒光聚氨酯發泡體製造夜間識別標識器具。 The disadvantage is that in order to smash the waste rubber block, high technology and high investment must be used. Further, the technique used in the Korean Patent No. 10-1256083 "Night Identification Marking Device for Ropes" is to form a polyurethane foam, which is still added with a fluorescent substance during the formation of the foam, and is manufactured by using a fluorescent polyurethane foam. Identification of the identification device at night.
此技術由本發明人開發,為保護夜間或在暗處進行繩索作業的人員及其周邊行人的安全,做出了很多改進。但是,韓國專利註冊第10-1256083號為,將多羥基化合物和異氰酸酯以適當比例混合,添加熒光物質後實施氨基甲酸酯鍵和發泡作業,製造過程複雜,難度也大。 This technique was developed by the inventors to make many improvements to protect the safety of people working on the ropes at night or in the dark and the pedestrians around them. However, Korean Patent Registration No. 10-1256083 discloses that a polyhydroxy compound and an isocyanate are mixed in an appropriate ratio, and a urethane bond and a foaming operation are carried out after adding a fluorescent substance, and the manufacturing process is complicated and difficult.
由此表明,由於氨基甲酸酯的特性,如果不能夠精密地實施控制,則難以保證產品質量,發泡產品也會出現不均勻的狀態。即使根據韓國註冊專利第10-1256083號製造出發泡熒光製品,但是在海上使用時,因聚氨酯發泡製品不耐於水分,製品壽命不會長久。 This indicates that, due to the characteristics of the urethane, if the control cannot be precisely performed, it is difficult to ensure the quality of the product, and the foamed product may also be in an uneven state. Even if a foamed fluorescent article is manufactured according to Korean Patent No. 10-1256083, when it is used at sea, since the polyurethane foamed article is not resistant to moisture, the life of the product does not last long.
推究其起因,可能是聚氨酯發泡製品的氨基甲酸酯鍵透過水分分解,導致形成網結構的封閉室結構被破壞而造成。韓國專利註冊第10-1256083號的聚氨酯製品用於海水 面或水中,但海水含有鹽等離子性物質,會進一步促進發泡製品的氣孔結構破壞。對於發泡製品而言,必須保證微細氣孔結構的穩定性,但是因暴露在海水,其表面被波濤和周圍船隻以及海上漂浮的各種浮游物體撞擊或者被這些外力受到損傷,導致微細氣孔結構進一步受到破壞。 The reason for this may be that the urethane bond of the polyurethane foamed product is decomposed by moisture, resulting in the destruction of the closed cell structure forming the mesh structure. Polyurethane product of Korean Patent Registration No. 10-1256083 for seawater In the surface or in water, the seawater contains salt and plasma substances, which further promotes the destruction of the pore structure of the foamed product. For foamed products, the stability of the fine pore structure must be ensured. However, due to exposure to seawater, the surface of the foamed product is struck by or damaged by surrounding ships and various floating objects floating on the sea, resulting in further damage to the fine pore structure. damage.
總而言之,聚氨酯發泡製品即使添加夜間識別用熒光物質而具備夜間熒光功能,但事實上不能夠否認的是,因聚氨酯發泡製品不耐於水,無法完整地發揮作為夜間識別標識器具應有的性能和功能。 All in all, the polyurethane foamed product has a nighttime fluorescent function even if it is added with a fluorescent material for nighttime recognition. However, it cannot be denied that the polyurethane foamed product is not resistant to water and cannot be fully utilized as a nighttime identification device. Performance and features.
因此,本發明人對這種傳統的作為識別標志的浮標和作為夜間識別標志的器具仔細進行調查的結果如下。 Therefore, the inventors carefully investigated the conventional buoy as an identification mark and an instrument as a nighttime identification mark as follows.
【專利文獻】 [Patent Literature]
韓國公開專利第1998-8498號「以EVA為主要原料的多色網用浮標的製造方法」(1998.4.30.);韓國公開實用新型第2000-14560號「網的浮標裝置」(2000.7.25.);韓國公開專利第2003-22237號「浮標製造方法及其利用該方法製造的浮標」(2003.3.15.);韓國註冊專利第10-461697號「具備光反射型或發光型浮標的防污染裝置」(2004.12.03.);韓國註冊專利第10-720162號「利用樹脂合成物浮標製造方法」(2007.5.14.);韓國公開專利第2012-57591號「浮標製造方法」(2012.6.5.);韓國公開專利第2006-53790號「浮標用發泡體合成物及其製造方法」(2006.5.22.);韓國註冊專利第10-985573號「廢橡膠和廢合成樹脂的混合材料夜光浮標」(2010.9.29.);韓國註冊專利第10-1256083號「繩索的夜間識別標識器具」(2013.4.12.)。 Korean Laid-Open Patent Publication No. 1998-8498 "Manufacturing Method of Buoys for Multicolor Nets Using EVA as Main Material" (1998.4.30.); Korean Public Utility Model No. 2000-14560 "Buoy Device for Nets" (2000.7.25) .); Korean Patent No. 2003-22237 "Buoy manufacturing method and buoy manufactured by the method" (2003.3.15.); Korean registered patent No. 10-461697 "with light reflection type or luminous buoy prevention" "Pollution device" (2004.12.03.); Korean registered patent No. 10-720162 "Method for manufacturing resin composite buoy" (2007.5.14.); Korean Patent Publication No. 2012-57591 "Buoy manufacturing method" (2012.6. 5.); Korean Patent Publication No. 2006-53790 "Foam composition for buoys and its manufacturing method" (2006.5.22.); Korean registered patent No. 10-985573 "mixture of waste rubber and waste synthetic resin" Luminous Buoy" (2010.9.29.); Korean registered patent No. 10-1256083 "Night identification device for ropes" (2013.4.12.).
為克服傳統技術上存在的諸多問題,本發明提供了一種作為海上或水上作業期間使用的晝夜間識別標志,即暴露於海水的狀態下,依然防止其表面水解作用,其表面被波濤和周邊船隻及海面上漂浮的各種浮游物或這些外力受損時,會依然有效防止氣泡破損,以持續發揮熒光體功能的繩索熒光標識器具及其製造方法。 In order to overcome many problems existing in the conventional art, the present invention provides a nighttime identification mark used during sea or water work, that is, in the state of being exposed to seawater, the surface hydrolysis is still prevented, and the surface thereof is surrounded by waves and surrounding vessels. And a variety of floating objects floating on the sea surface or when these external forces are damaged, the rope fluorescent marking device which can effectively prevent the bubble from being damaged and which can continuously exhibit the function of the fluorescent body and the manufacturing method thereof.
本發明是對上述韓國註冊專利第10-1256083號「繩索的識別標識器具」進一步進行改進的結果。 The present invention is a result of further improvement of the above-mentioned Korean Patent No. 10-1256083 "Identification Identification Device for Ropes".
為實現上述目的,本發明對包括內部具有多個微細氣泡且具有橢圓形外部形態的本體部,以及在本體部的中央形成並可插入繩索的本體孔的繩索用識別標識器具進行了改進。 In order to achieve the above object, the present invention is improved for a rope identifying body having a body portion having a plurality of fine cells therein and having an elliptical outer shape, and a body hole formed in the center of the body portion and insertable into the body of the rope.
根據本發明,本體部的組成包括:由EVA共聚物100重量份;相對於EVA共聚物100重量份,包括熒光物質3重量份至15重量份、發泡劑2重量份至5重量份、交聯劑0.5重量份至5重量份以及其他添加劑0.01至2重量份發泡而成的EVA發泡部;與EVA發泡部使用同一個成分構成,但沒有EVA發泡部的微細氣泡,且形成強韌的外表面,在EVA發泡部外側形成的EVA表面層;較佳地,相對於EVA共聚物100重量份,還包括使用環氧樹脂0.1重量份至5重量份。 According to the present invention, the composition of the body portion comprises: 100 parts by weight of the EVA copolymer; 3 parts by weight to 15 parts by weight, and 2 parts by weight to 5 parts by weight of the blowing agent, based on 100 parts by weight of the EVA copolymer, 0.5 parts by weight to 5 parts by weight of the crosslinking agent and 0.01 to 2 parts by weight of the other additive foamed EVA foaming portion; the same component is used for the EVA foaming portion, but the fine bubbles of the EVA foaming portion are not formed and formed The tough outer surface is an EVA surface layer formed on the outer side of the EVA foam portion; preferably, 0.1 to 5 parts by weight of the epoxy resin is used with respect to 100 parts by weight of the EVA copolymer.
本體孔是,由與EVA發泡部使用同一個成分構成,但沒有如EVA發泡部的微細氣泡的狀態下形成強韌的內部表面,且在EVA發泡部的內側形成的EVA圓筒層形成。 The main body hole is formed of the same component as the EVA foaming portion, but does not have a strong inner surface in the state of fine bubbles of the EVA foaming portion, and the EVA cylinder layer is formed inside the EVA foaming portion. form.
本體部為由半圓筒形的第一本體部和可與第一本體部結合或分離的半圓筒形第二本體部形成,第一本體部 和第二本體部是相互結合的狀態下使用。 The body portion is formed by a semi-cylindrical first body portion and a semi-cylindrical second body portion that can be coupled or separated from the first body portion, the first body portion And the second body portion is used in a state of being combined with each other.
本發明的繩索用熒光識別標識器具的有益效果是,基材成分由EVA構成,接觸到水以後不會發生水解作用,即使接觸到海水,其微氣泡也不會受到破壞。 The fluorescent recognition marker device for ropes of the present invention has an advantageous effect that the base material component is composed of EVA, and does not undergo hydrolysis after contact with water, and the microbubbles are not damaged even when exposed to sea water.
本發明的繩索用熒光識別標識器具是其EVA表面層的外表面堅固,受到外部的衝擊,也不容易受到損傷。 The fluorescent identification marking device for ropes of the present invention is such that the outer surface of the surface layer of the EVA is strong and is subjected to external impact and is not easily damaged.
本發明的繩索用熒光識別標識器具包含EVA共聚物和環氧樹脂成分,則透過環氧樹脂的硬化作用,表面形成得很堅固,對於外部衝擊比較強韌,而且在外部的衝擊下,其表面即使受到損傷,也可以防止微細氣泡被破壞的現象。因此,便於夜間作業人員或行人識別本發明的熒光識別標器具,從而有效預防安全事故。 The fluorescent identification marking device for ropes of the present invention comprises an EVA copolymer and an epoxy resin component, and the surface is formed to be strong by the hardening action of the epoxy resin, and is strong against external impact, and the surface is externally impacted. Even if it is damaged, it can prevent the phenomenon that fine bubbles are destroyed. Therefore, it is convenient for the nighttime worker or the pedestrian to recognize the fluorescent identification device of the present invention, thereby effectively preventing a safety accident.
本發明的繩索用熒光識別標識器具不使用液態的多羥基化合物和異氰酸酯等原料物質,不使用有害於人體的成分,故製造工藝簡單方便、安全。 The fluorescent identification marker for a rope according to the present invention does not use a raw material such as a liquid polyhydroxy compound or an isocyanate, and does not use a component harmful to the human body, so that the manufacturing process is simple, convenient, and safe.
10‧‧‧本體部 10‧‧‧ Body Department
12‧‧‧氨基甲酸酯發泡部 12‧‧‧Carbamate Foaming Department
16‧‧‧氨基甲酸酯表面層 16‧‧‧Carbamate surface layer
20‧‧‧氨基甲酸酯圓筒層 20‧‧‧Carbamate cylinder
22‧‧‧凸塊部 22‧‧‧Bumps
51‧‧‧上部模具 51‧‧‧Upper mold
52‧‧‧下部模具 52‧‧‧Lower mold
53‧‧‧加注管 53‧‧‧Adding tube
61‧‧‧右側中心銷 61‧‧‧right center pin
62‧‧‧左側中心銷 62‧‧‧left center pin
100、200‧‧‧繩索用熒光識別標識器具 100,200‧‧‧Fluorescent identification marking instruments for ropes
110‧‧‧本體部 110‧‧‧ Body Department
112‧‧‧EVA發泡部 112‧‧‧EVA foaming department
116‧‧‧EVA表面層 116‧‧‧EVA surface layer
120‧‧‧EVA圓筒層 120‧‧‧EVA cylinder layer
122‧‧‧凸塊部 122‧‧‧Bumps
125‧‧‧邊緣加強部 125‧‧‧Edge Strengthening Department
210‧‧‧第一本體部 210‧‧‧First Body Department
220‧‧‧第二本體部 220‧‧‧Second body
230‧‧‧結合裝置 230‧‧‧ Combined device
232‧‧‧滑動凸部 232‧‧‧Sliding convex
233‧‧‧滑動槽部 233‧‧‧Sliding groove
234‧‧‧夾入凸部 234‧‧‧ Sandwiched into the convex part
235‧‧‧夾入槽部 235‧‧‧Into the groove
236‧‧‧紮帶 236‧‧‧ Cable Ties
237‧‧‧夾入孔 237‧‧‧Clip into the hole
238‧‧‧螺紋螺栓 238‧‧‧Threaded bolts
239‧‧‧螺母 239‧‧‧ nuts
270‧‧‧船隻 270‧‧‧ vessel
280‧‧‧系船浮標 280‧‧‧Boat buoy
290‧‧‧錨 290‧‧‧ anchor
第1圖,係為傳統的繩索用夜間識別標識器具的概略透視圖及剖視圖;第2a圖,係為本發明的繩索用熒光識別標識器具100的概略透視圖;第2b圖,係為繩索用熒光識別標識器具100的A-A線切斷面剖視圖;第3a圖至第3f圖,係為第2圖的繩索用熒光識別標識器具100的製造方法的概念圖;第4圖,係為本發明另一較佳實施例,第4a圖,係為分 離型繩索用熒光識別標識器具200大致分解狀態透視圖,第4b圖,係為分離型繩索用熒光識別標識器具200裝配狀態的概念圖;第5圖,係為本發明的再一較佳實施例,第5a圖,係為將分離型繩索用熒光識別標識器具200使用滑動方式裝配的例示圖,第5b圖,係為滑動結合的狀態剖面圖;第6圖,係為本發明的又一較佳實施例,第6a圖,係為將分離型繩索用熒光識別標識器具200使用夾入結合方式裝配的例示圖,第6b圖,係為使用夾入結合方式結合的狀態部面圖;第7圖,係為本發明的又一較佳實施例,第7a圖,係為將分離型繩索用熒光識別標識器具200以標記結合方式裝配的例示圖,第7b圖,係為以標記結合方式結合狀態的部視圖,第7c圖,係為裝配狀態下的概略透視圖;第8圖,係為本發明的又一較佳實施例,將分離型繩索用熒光識別標識器具200使用擰螺絲方式結合的狀態剖視圖;第9圖,係為本發明的又一較佳實施例,將分離型繩索用熒光識別標識器具200結合後插入繩索的狀態下的剖面概略圖;以及第10圖,係為在深海使用本發明時的較佳例示圖。 Fig. 1 is a schematic perspective view and a cross-sectional view of a conventional nighttime identification marking device for ropes; Fig. 2a is a schematic perspective view of a fluorescent identification marking device 100 for a rope according to the present invention; and Fig. 2b is for a rope FIG. 3A to FIG. 3f are conceptual views of a method of manufacturing the fluorescent marker device 100 for a rope according to FIG. 2; and FIG. 4 is another embodiment of the present invention. A preferred embodiment, Figure 4a, is a sub- FIG. 4b is a conceptual view showing an assembled state of the fluorescent identification marker device 200 for a separate type rope, and FIG. 5 is a further preferred embodiment of the present invention. For example, Fig. 5a is an illustration of a slide-type assembly in which the fluorescent-type identification device 200 for a separate type of rope is used, and Fig. 5b is a cross-sectional view showing a state in which the separation is slidable; and Fig. 6 is another view of the present invention. In a preferred embodiment, FIG. 6a is an illustration of assembling the separation type cord fluorescent identification marker device 200 by using a sandwiching and bonding method, and FIG. 6b is a state diagram of a state in which a sandwiching and bonding method is used; Figure 7 is a further preferred embodiment of the present invention, and Figure 7a is an illustration of the assembly of the fluorescent-type identification device 200 for the separate type of rope in a mark-bonding manner, and Figure 7b is a combination of marks. The sectional view of the combined state, the 7th view is a schematic perspective view in the assembled state; and the eighth figure is a further preferred embodiment of the present invention, and the fluorescent identification marking device 200 for the separate type rope is screwed. Knot FIG. 9 is a cross-sectional schematic view showing a state in which a separate type of rope is combined with a fluorescent identification marker 200 and inserted into a rope, and FIG. 10 is a schematic view of the present invention. A preferred illustration of the use of the present invention in the deep sea.
下面將結合附圖,對本發明的較佳實施例詳細進行描述。顯然,所描述的實施例是本發明一部分實施例,而不是全部的實施例。基於本發明中的實施例,本領域普通技術人員在沒有做出創造性勞動前提下所獲得的所有其他實施例,都屬於本發明保護的範圍。 DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. It is apparent that the described embodiments are a part of the embodiments of the invention, and not all of the embodiments. All other embodiments obtained by those skilled in the art based on the embodiments of the present invention without creative efforts are within the scope of the present invention.
第1圖係為傳統的繩索用夜間識別標識器具的概略透視圖及剖視圖,第1a圖係為夜間識別標識器具的概略透視圖,第1b圖是第1a圖的切斷面剖視圖。 Fig. 1 is a schematic perspective view and a cross-sectional view of a conventional nighttime identification marker for a rope. Fig. 1a is a schematic perspective view of a nighttime identification marker, and Fig. 1b is a cross-sectional view of a cutaway surface of Fig. 1a.
本發明是將「繩索的夜間識別標識器具」進一步實施改進的結果,其組成包括:由透過多個氨基甲酸酯鍵的微細氣泡形成且使用氨基甲酸酯材料構成的橢圓形本體部10、在本體部10的內部內側中央形成的氨基甲酸酯圓筒層20。橢圓形本體部10的內部包括:由氨基甲酸酯發泡體形成的氨基甲酸酯發泡部12以及在氨基甲酸酯發泡部12的外側形成的氨基甲酸酯表面層16。氨基甲酸酯圓筒層20可包括多個凸塊部22形成。「繩索的夜間識別標識器具」的缺陷是,通過氨基甲酸酯鍵的微細氣泡容易被水或海水出現水解現象。 The present invention is a result of further improving the "nocturnal identification device for a rope", and the composition thereof comprises: an elliptical body portion 10 formed of fine bubbles that are transmitted through a plurality of urethane bonds and using a urethane material, A urethane cylinder layer 20 is formed at the inner inner side of the main body portion 10. The inside of the elliptical body portion 10 includes a urethane foam portion 12 formed of a urethane foam and a urethane surface layer 16 formed outside the urethane foam portion 12. The urethane cylinder layer 20 may include a plurality of bump portions 22 formed. A drawback of the "nocturnal identification device for ropes" is that the fine bubbles passing through the urethane bond are easily hydrolyzed by water or seawater.
本發明是對「繩索的識別標識器具」進行改進的結果。 The present invention is a result of improvement of the "cord identification device".
第2圖係為本發明的繩索用熒光識別標識器具100,第2a圖係為本發明的繩索用熒光識別標識器具100的概略透視圖,第2b圖係為繩索用熒光識別標識器具100的A-A線切斷面剖視圖。 Fig. 2 is a perspective view of a fluorescent identification marking device 100 for a rope according to the present invention. Fig. 2a is a schematic perspective view of a fluorescent identification marking device 100 for a rope according to the present invention, and Fig. 2b is an AA for a fluorescent identification marking device 100 for a rope. Cutaway view of the line cut surface.
本發明是其內部包括由多個微細氣泡形成且使用EVA材料構成的橢圓形本體部110、在本體部110的內部內側中央形成的EVA圓筒層120。EVA材料包括EVA共聚物。較佳地,EVA圓筒層120的兩側末端還包括邊緣加強部125。較佳地,邊緣加強部125係由耐磨損性和耐衝擊性較強的工程塑料形成。邊緣加強部125不需對EVA實施發泡也可形成。 The present invention includes an elliptical body portion 110 formed of a plurality of fine bubbles and formed of an EVA material, and an EVA cylinder layer 120 formed at the inner inner center of the body portion 110. EVA materials include EVA copolymers. Preferably, both end ends of the EVA cylinder layer 120 further include an edge reinforcement portion 125. Preferably, the edge reinforcing portion 125 is formed of an engineering plastic having high abrasion resistance and impact resistance. The edge reinforcing portion 125 can be formed without foaming the EVA.
本發明由EVA材料構成,此EVA材料包括由多個微細氣泡形成的橢圓形本體部110。橢圓形本體部110包括將EVA共聚物與熒光物質一起發泡形成的熒光EVA發泡體。熒光EVA發泡體是將EVA共聚物和環氧樹脂混合重整的狀態下混合熒光物質,重新使用發泡劑發泡為宜。橢圓形本體部110的組成包括:由熒光EVA發泡體構成的EVA發泡部112以及在EVA發泡部112的外側形成的EVA表面層116。 The present invention is composed of an EVA material including an elliptical body portion 110 formed of a plurality of fine bubbles. The elliptical body portion 110 includes a fluorescent EVA foam formed by foaming an EVA copolymer together with a fluorescent substance. In the fluorescent EVA foam, the fluorescent material is mixed in a state where the EVA copolymer and the epoxy resin are mixed and reformed, and it is preferable to foam the foaming agent again. The elliptical body portion 110 includes an EVA foaming portion 112 composed of a fluorescent EVA foam and an EVA surface layer 116 formed on the outer side of the EVA foaming portion 112.
根據本發明,橢圓形本體部110較佳地由EVA共聚物100重量份;相對於EVA共聚物100重量份,配合熒光物質3重量份至15重量份、發泡劑2重量份至10重量份、交聯劑0.5重量份至5重量份及其它添加劑0.01至2重量份發泡形成。 According to the present invention, the elliptical body portion 110 is preferably 100 parts by weight of the EVA copolymer; 3 parts by weight to 15 parts by weight, and 2 parts by weight to 10 parts by weight of the blowing agent, based on 100 parts by weight of the EVA copolymer. 0.5 parts by weight to 5 parts by weight of the crosslinking agent and 0.01 to 2 parts by weight of other additives are foamed.
根據本發明,EVA共聚物使用包括聚乙烯樹脂和乙酸乙烯酯樹脂的共聚物。聚乙烯樹脂是從由低密度聚乙烯、線型低密度聚乙烯、超低密度聚乙烯以及高密度聚乙烯形成組中選擇的一個或兩個以上的混合物為宜。乙酸乙烯酯是乙酸乙烯酯含量在20重量分至40重量份之間為宜。乙酸乙烯酯含量低於20重量份,則成型過程中出現不太光滑的問題,相反,乙酸乙烯酯含量大於40重量份,則黏合力強而容易發生問題,且最終生產產品強度太弱而不宜選擇。 According to the present invention, the EVA copolymer uses a copolymer comprising a polyethylene resin and a vinyl acetate resin. The polyethylene resin is preferably one or a mixture of two or more selected from the group consisting of low density polyethylene, linear low density polyethylene, ultra low density polyethylene, and high density polyethylene. Vinyl acetate is preferably a vinyl acetate content of from 20 parts by weight to 40 parts by weight. When the vinyl acetate content is less than 20 parts by weight, the problem of less smoothness occurs during the molding process. On the contrary, if the vinyl acetate content is more than 40 parts by weight, the adhesion is strong and the problem is liable to occur, and the final product is too weak to be produced. select.
根據本發明,EVA共聚物即使發泡也沒有實施聚氨酯的氨基甲酸酯鍵,在水中不會發生水解反應,使用時間更長,長時間使用也不會出現變色的問題。 According to the present invention, even if the EVA copolymer is foamed, the urethane bond of the polyurethane is not carried out, the hydrolysis reaction does not occur in water, and the use time is longer, and the problem of discoloration does not occur for a long period of use.
本發明是將EVA共聚物與環氧樹脂均勻地混合改成重整EVA共聚物使用為宜。使用EVA共聚物時,相對於EVA共聚物100重量份,均勻地混合環氧樹脂0.1重量份至5重量份。相對於EVA共聚物100重量份使用的環氧樹脂重量份低於0.1,則環氧成分變弱,無法完整地發揮黏合劑和表面層形成功能,相反,環氧樹脂重量份大於5,則作為硬化劑的功能變強,從經濟角度考慮也不太適合考慮。 In the present invention, it is preferred to uniformly mix the EVA copolymer and the epoxy resin into a reformed EVA copolymer. When the EVA copolymer is used, 0.1 to 5 parts by weight of the epoxy resin is uniformly mixed with respect to 100 parts by weight of the EVA copolymer. When the weight fraction of the epoxy resin used is less than 0.1 with respect to 100 parts by weight of the EVA copolymer, the epoxy component becomes weak, and the function of forming the binder and the surface layer cannot be fully realized. On the contrary, when the weight fraction of the epoxy resin is more than 5, The function of the hardener becomes stronger, and it is not suitable for consideration from an economic point of view.
根據本發明,環氧成分是最少為實施兩種功能而使用。 According to the invention, the epoxy component is used at least for carrying out both functions.
其中第一個功能是黏合劑的功能。此功能可以加強EVA共聚物成分和熒光物質之間的化學結合,最終提升本發明的作為熒光體的功能。因為,透過作為黏合劑的化學結合,EVA共聚物的官能團和環氧樹脂的官能團以及熒光物質的官能團相互形成化學氫鍵。具體地,環氧樹脂的環氧基()的氧原子(-O-)和EVA共聚物以及熒光物質的氫原子(-H)相互透過靜電引力形成氫鍵,形成非常強大的結合關係,而透過氫鍵(-O-H)的結合力與將EVA共聚物和熒光物質簡單混合獲得的結合力相比更強。 The first of these functions is the function of the adhesive. This function enhances the chemical bonding between the EVA copolymer component and the fluorescent substance, and ultimately enhances the function as a phosphor of the present invention. Because, by chemical bonding as a binder, the functional group of the EVA copolymer and the functional group of the epoxy resin and the functional group of the fluorescent substance form a chemical hydrogen bond with each other. Specifically, the epoxy group of the epoxy resin ( The oxygen atom (-O-) and the EVA copolymer and the hydrogen atom (-H) of the fluorescent substance form a hydrogen bond through electrostatic attraction, forming a very strong bonding relationship, and the binding force through the hydrogen bond (-OH) The adhesion obtained by simply mixing the EVA copolymer and the fluorescent substance is stronger.
第二功能是堅固的表面層形成功能。具體地,在本發明製造工藝的實施過程中,環氧成分與注塑成型機的模具表面的接觸面在高熱作用下產生硬化反應,在其接觸面形成堅固的環氧硬化層。環氧樹脂在熱量作用下產產生的硬化反應是本技術領域的公知技術,不再詳述。 The second function is a solid surface layer forming function. Specifically, in the implementation of the manufacturing process of the present invention, the contact surface of the epoxy component with the mold surface of the injection molding machine generates a hardening reaction under high heat, and a strong epoxy hardened layer is formed on the contact surface thereof. The hardening reaction produced by the epoxy resin under the action of heat is well known in the art and will not be described in detail.
環氧樹脂的第三個功能是,與邊緣加強部125的強力黏合功能。而且,EVA圓筒層120的兩側末端形成邊緣加強部125才能夠發揮此功能,但是,可將構成邊緣加強部125的工程塑料和構成本體部110的EVA共聚物成分透過化學結合堅固地結合在一起。 The third function of the epoxy resin is a strong bonding function with the edge reinforcing portion 125. Further, the edge reinforcing portions 125 are formed at both ends of the EVA cylinder layer 120 to perform this function, but the engineering plastic constituting the edge reinforcing portion 125 and the EVA copolymer component constituting the body portion 110 can be strongly combined by chemical bonding. Together.
另一方面,根據本發明,利用環氧樹脂成分的三種功能在本發明構成要素中的應用相互不同。就是說,第一個功能應用於EVA發泡部112本身的構成成分,第二個功能應用於EVA表面層116和EVA圓筒層120本身,相反,第三個功能涉及於本體部110和EVA圓筒層120之間的關係。也 就是說,環氧樹脂成分在本發明的基材成分EVA共聚物中使用的結果,其第一個功能和第二個功能以及第三個功能應用的領域相互不同,但是,這些從整體上又形成絕妙地協調在一起。如上所述,環氧村脂成分的多重功能及由此產生的加強效果是傳統的任何先有技術都無法具備的本發明的獨創技術。 On the other hand, according to the present invention, the application of the three functions of the epoxy resin component to the constituent elements of the present invention is different from each other. That is, the first function is applied to the constituent components of the EVA foaming portion 112 itself, and the second function is applied to the EVA surface layer 116 and the EVA cylinder layer 120 itself, and conversely, the third function relates to the body portion 110 and the EVA. The relationship between the cylinder layers 120. and also That is, as a result of the use of the epoxy resin component in the substrate component EVA copolymer of the present invention, the first function and the second function and the third function application field are different from each other, but these are collectively Formed a wonderfully coordinated relationship. As described above, the multiple functions of the epoxy resin component and the resulting reinforcing effect are the original techniques of the present invention which are not available in any conventional prior art.
根據本發明,相對於EVA共聚物100重量份,使用熒光物質3重量份至15重量份。此熒光物質為,夜間受到光,吸收光的能量,光消失以後,借助通過光受到的能量向外部顯示明亮顏色的物質。熒光物質一般又稱為熒光顏料、發光顏料、夜光顏料或蓄光顏料。熒光物質不含有放射性物質或重金屬,對人體無害,將光吸收儲存並放射時發光性較高,可以半永久性地使用。熒光物質應是在高溫下從化學上極其穩定的結晶體,且耐熱性和耐寒性超強,耐藥品性突出為宜。 According to the invention, from 3 parts by weight to 15 parts by weight of the fluorescent substance is used with respect to 100 parts by weight of the EVA copolymer. This fluorescent substance is a substance that receives light at night and absorbs light, and after the light disappears, the bright color is displayed to the outside by the energy received by the light. Fluorescent materials are also commonly referred to as fluorescent pigments, luminescent pigments, luminous pigments or light-storing pigments. The fluorescent substance does not contain radioactive substances or heavy metals, and is harmless to the human body. When the light is absorbed and stored and emitted, the luminosity is high, and it can be used semi-permanently. The fluorescent substance should be a chemically extremely stable crystal at a high temperature, and is excellent in heat resistance and cold resistance, and is excellent in chemical resistance.
根據本發明,熒光物質相對於EVA共聚物100重量份包含3重量份以下,則夜間無法發揮熒光性能,大於15重量份,則有利於熒光性能,但不是投入的量大,熒光特性也相應地加強,因此不宜選擇。熒光物質是與重整的EVA共聚物混合使用為宜。 According to the present invention, when the fluorescent substance is contained in an amount of 3 parts by weight or less based on 100 parts by weight of the EVA copolymer, the fluorescent property is not exhibited at night, and if it is more than 15 parts by weight, the fluorescent property is favored, but the amount of the fluorescent material is not large, and the fluorescent property is correspondingly Strengthened, so it is not appropriate to choose. The fluorescent substance is preferably used in combination with the reformed EVA copolymer.
根據本發明,相對於EVA共聚物100重量份,可以包括2重量份至10重量份的發泡劑製造。 According to the present invention, it may be produced by including 2 parts by weight to 10 parts by weight of a foaming agent with respect to 100 parts by weight of the EVA copolymer.
根據本發明,發泡劑為使用熱量使得包括EVA共聚物的混合物發泡,在此過程中形成微細氣泡,形成氣泡孔。發泡劑為只要用於EVA共聚物的發泡,則從產品選擇上沒有特別限制。一般使用在130℃以分解的發泡劑,如偶氮雙甲醯胺(ADCA)、N,N'-四硫化雙五亞甲基秋蘭姆(DPT)、p,p'-氧代雙苯磺醯肼(OBSH)、二苯碸-3,3'-二磷基醯肼(DS-33)等。發泡劑低於2重量份,則發泡體的性能下降,相反,大於10重量份,則微細氣泡過多而不適合。 According to the present invention, the foaming agent foams a mixture including the EVA copolymer by using heat, and fine bubbles are formed in the process to form pores. The foaming agent is not particularly limited in terms of product selection as long as it is used for foaming of the EVA copolymer. Generally used at 130 ° C to decompose foaming agents, such as azobisformamide (ADCA), N, N'-tetrasulfide dipentamethylene thiuram (DPT), p, p'-oxo double Benzene sulfonium (OBSH), diphenyl hydrazine-3, 3'-diphosphoryl hydrazine (DS-33), and the like. When the amount of the foaming agent is less than 2 parts by weight, the performance of the foam is lowered. On the other hand, when it is more than 10 parts by weight, the fine bubbles are too large to be suitable.
本發明是相對於EVA共聚物100重量份,包括交聯劑0.5重量份至5重量份。交聯劑為,發泡劑分解形成微細氣泡時,使得EVA共聚物成分具有高溫粘彈性,以耐受因發泡劑的氣體壓力。交聯劑為,可以適用於EVA共聚物發泡即可,沒有特別的限制。一般可以使用過氧化氫系的交聯劑,比較典型的是過氧化苯甲醯、過氧化二異丙苯,或者這些物質的混合物。交聯劑低於0.5重量份,則交聯不足而無法產生粘彈性,大於5重量份,則交聯過度,容易阻礙微細氣泡的形成而不適合。 The present invention is included in an amount of from 0.5 part by weight to 5 parts by weight based on 100 parts by weight of the EVA copolymer. The crosslinking agent is such that when the blowing agent decomposes to form fine bubbles, the EVA copolymer component has high-temperature viscoelasticity to withstand the gas pressure due to the blowing agent. The crosslinking agent is applicable to foaming of the EVA copolymer, and is not particularly limited. It is generally possible to use a hydrogen peroxide-based crosslinking agent, typically benzammonium peroxide, dicumyl peroxide, or a mixture of these substances. When the amount of the crosslinking agent is less than 0.5 part by weight, the crosslinking is insufficient to produce viscoelasticity, and if it is more than 5 parts by weight, the crosslinking is excessive and the formation of fine bubbles is easily inhibited.
本發明是,相對於EVA共聚物100重量份,包括其他添加劑重量份0.01至2重量份製造。此其他添加劑係指對EVA共聚物充分的發泡作用發揮補助作用,改善交聯反應,或進一步加強最終產品的性能而補充添加的成分。此其他添加劑並不是必須添加的成分,而是根據製造工藝或最終產品選擇使用的任意輔助成分,只要是在本技術領域普遍使用的則沒有特別限制。例如,發泡促進劑、交聯輔助劑、軟化劑、流動改善劑、填充劑、著色劑等可作為此其他添加劑。此其他添加劑可以使用單一成分,也可以將多個成分混合使用。 The present invention is produced in an amount of 0.01 to 2 parts by weight based on 100 parts by weight of the EVA copolymer, including other additives. This other additive refers to a component which supplements the addition of a sufficient foaming action of the EVA copolymer, improves the crosslinking reaction, or further enhances the properties of the final product. This other additive is not an ingredient that must be added, but is any optional ingredient selected for use according to the manufacturing process or the final product, and is not particularly limited as long as it is generally used in the art. For example, a foaming accelerator, a crosslinking assistant, a softener, a flow improver, a filler, a colorant, or the like can be used as the other additive. This other additive may be used as a single component or a mixture of a plurality of components.
本發明是可以將EVA共聚物和環氧樹脂混合均勻地混煉並製成重整形態的EVA共聚物混合物,然後重新對EVA共聚物混合物加入熒光物質和發泡劑、交聯劑以及其他添加劑,均勻地混煉以後放入注塑成型機的模具內部,在注塑成型機的模具內部用130℃以上的高溫加熱,形成熒光EVA發泡體而製成。 The invention is capable of mixing and mixing the EVA copolymer and the epoxy resin uniformly and preparing the EVA copolymer mixture in a reformed form, and then re-adding the fluorescent substance and the foaming agent, the crosslinking agent and other additives to the EVA copolymer mixture. After uniformly kneading, it is placed in the mold of the injection molding machine, and is heated inside the mold of the injection molding machine at a high temperature of 130 ° C or higher to form a fluorescent EVA foam.
本發明是在注塑成型機的模具內部放入包括熒光物質的EVA共聚物混合物,製造EVA發泡體,但在其過程中可以同時形成橢圓形本體部110以及EVA圓筒層120。 In the present invention, an EVA copolymer mixture including a fluorescent substance is placed inside a mold of an injection molding machine to produce an EVA foam, but an elliptical body portion 110 and an EVA cylinder layer 120 can be simultaneously formed in the process.
本發明是對傳統的氯基甲酸酯鍵的發泡體中存在的缺陷進行改進的結果,選擇EVA共聚物及其重整的EVA 共聚物作為基質的基本物質,對其基質的基本物質添加夜間熒光物質,使其具有特定功能而成。 The present invention is the result of an improvement in the defects existing in the conventional chloroformate-bonded foam, and the selection of the EVA copolymer and its reformed EVA The copolymer serves as a basic substance of the matrix, and a nighttime fluorescent substance is added to the basic substance of the matrix to have a specific function.
根據本發明,橢圓形本體部110的組成可包括:使用EVA發泡體構成的EVA發泡部112,以EVA發泡部112的外側形成的EVA表面層116。EVA表面層116使用熒光EVA發泡體成分構成,其外表面沒有形成EVA發泡部112微細氣泡而形成堅固、強韌的表面層。EVA表面層116不是與EVA發泡部112分別形成或者單獨形成後粘貼或結合,而是與EVA發泡部112使用同樣材料和同樣的製造工藝同時製成。本發明包括本體部110的內部內側中央形成的EVA圓筒層120。 According to the present invention, the composition of the elliptical body portion 110 may include an EVA foaming portion 112 formed of an EVA foam, and an EVA surface layer 116 formed at the outer side of the EVA foaming portion 112. The EVA surface layer 116 is composed of a fluorescent EVA foam component, and the outer surface thereof is not formed with fine bubbles of the EVA foaming portion 112 to form a strong and strong surface layer. The EVA surface layer 116 is not formed separately or separately formed from the EVA foaming portion 112, but is bonded or bonded to the EVA foaming portion 112 at the same time using the same material and the same manufacturing process. The present invention includes an EVA cylinder layer 120 formed at the inner inner center of the body portion 110.
根據本發明,EVA圓筒層120使用熒光EVA發泡體成本構成,EVA圓筒層120的外表面沒有EVA發泡部112的微細氣泡,也可以形成堅硬、強韌的表面層,並形成圓筒形的孔。EVA圓筒層120和本體部110不是分別形成或單獨形成粘貼或結合,而是使用與本體部110同樣的材料和同樣製造工藝製造之後,同時或快速實施後續工藝而成。透過EVA圓筒層120插入纖維繩或鋼絲繩,使得本發明的繩索用熒光識別標識器具100在船隻或碼頭上得以使用。 According to the present invention, the EVA cylinder layer 120 is constructed using a fluorescent EVA foam, and the outer surface of the EVA cylinder layer 120 is free of fine bubbles of the EVA foaming portion 112, and a hard, strong surface layer can be formed and formed into a circle. Cylindrical hole. The EVA cylinder layer 120 and the body portion 110 are not formed separately or separately formed by bonding or bonding, but are formed by using the same material and the same manufacturing process as the body portion 110, and simultaneously or rapidly performing the subsequent process. The fiber rope or wire rope is inserted through the EVA cylinder layer 120, so that the rope fluorescent identification device 100 of the present invention can be used on a ship or a dock.
一般,插入繩索使用時,EVA圓筒層120與繩索產生摩擦而磨損,或者受到外部衝擊而容易出現損傷的現象,因此,在EVA圓筒層120的兩側末端還會形成邊緣加強部125。邊緣加強部125是使用其他工藝製作之後,透過本體部110的製造工藝形成一體為宜。 In general, when the inserting rope is used, the EVA cylinder layer 120 is rubbed against the rope to be worn, or is subjected to external impact and is liable to be damaged. Therefore, the edge reinforcing portion 125 is formed at both ends of the EVA cylinder layer 120. The edge reinforcing portion 125 is preferably formed integrally with the manufacturing process of the body portion 110 after being fabricated by another process.
根據本發明,EVA圓筒層120較佳地在其兩側末端分別形成凸塊部122。凸塊部122是在纖維繩或鋼絲繩上插入本發明產品後,壓迫纖維繩或鋼絲繩,防止從纖維繩或鋼絲繩脫離或而擠到其他地方。 In accordance with the present invention, the EVA cylinder layer 120 preferably forms bump portions 122 at the ends of its sides, respectively. The bump portion 122 compresses the fiber rope or the wire rope after inserting the product of the present invention on the fiber rope or the wire rope to prevent detachment from the fiber rope or the wire rope or to be squeezed to other places.
根據本發明,邊緣加強部125是圓筒內面部位稍微凸出地形成,而且凸出部位最終作為產品的凸塊部122發揮功能。本發明的附圖中顯示的是使得邊緣加強部125的圓 筒內面部位稍微凸出而形成凸塊部122的實施例。根據本發明,凸塊部122可以形成為多個。而且凸塊部122夾入透過纖維繩的繩股形成的凹陷部分,防止從纖維繩脫離。本發明提供繩索用熒光識別標識器具100的製造方法。第3圖是將繩索用熒光識別標識器具100的製造方法使用注塑成型機的模具裝置概略顯示的圖示。本發明係為,利用對上部模具51和下部模具52插入右側及左側中心銷61、62,通過加注管53加注EVA共聚物混合物或重整的EVA共聚物混合物的注塑成型方式製造為宜。首先,上部模具51和下部模具52相離的狀態下,在上部模具51和下部模具52之間插入左側中心銷62以及右側中心銷61,或者將單獨製作的邊緣加強部125插入右側中心銷61內部的內側深處,並插入其末端之後將左側中心銷62和所述右側中心銷61插進去。(參見第3a圖)。將左側中心銷62和右側中心銷61插進去的狀態下,移動上部模具51和下部模具52的動模,相互牢固地形成一對。(參見第3b圖)。上部模具51和下部模具52相互嚙合的狀態下,在成型機的螺杆(圖未示)上,通過加注管53,將EVA共聚物混合的熔融物或重整的EVA共聚物混合物的熔融物加注到上部模具51和下部模具52的內部。上部模具51和下部模具52是在加熱的狀態下保持130℃以上。(參見第3c圖)。加注上部模具51和下部模具52內部的EVA共聚物混合的熔融物或重整的EVA共聚物混合物的熔融物為,因其內部發泡劑而發泡,因其內部的交聯劑而形成交聯鍵,因此,上部模具51和下部模具52內部形成既定的熒光EVA發泡體。熒光EVA發泡體在上部模具51和下部模具52的內部大致形成本體部110的形狀和EVA圓筒層120的形狀。稍後,在上部模具51和下部模具52的內部,使得右側中心銷61脫離模具。(參見第3d圖)。在上部模具51和下部模具52內部,使得左側中心銷62脫離模具。在此狀態下,EVA圓筒層120的內部兩側末端顯示出分別結合邊緣加強部125的狀態。(參見第3e圖)。在上 部模具51和下部模具52,使得右側中心銷61和左側中心銷62脫離之後,移動相當於動模的上部模具51,取出其內部的EVA發泡成型物。(參見第3f圖)。本發明是通過此製造過程得以完成。此外,作為本發明的較佳實施例提供一種由分離型產品形成的繩索用熒光識別標識器具200。作為本發明的較佳實施例,橢圓形本體部110可由半圓筒形的第一本體部210以及可與第一本體部結合或分離的半圓筒形第二本體部220組成,並包括使得第一本體部210和第二本體部220結合的結合裝置230。結合裝置230包括將第一本體部210和第二本體部220結合後在繩索上結合本體部的各種裝置。第一本體部210和第二本體部220是在相互結合的狀態下使用,第一本體部210和第二本體部220相互結合的狀態下自然而然地形成EVA圓筒層120。第4圖係為本發明的較佳實施例圖示,第4a圖係為根據其實施例的繩索用熒光識別標識器具200大致分解狀態的透視圖,第4b圖係為繩索用熒光識別標識器具200組裝狀態的概念圖。 According to the present invention, the edge reinforcing portion 125 is formed such that the inner surface portion of the cylinder is slightly convex, and the protruding portion finally functions as the bump portion 122 of the product. Shown in the drawings of the present invention is a circle that causes the edge reinforcement 125 An embodiment in which the inner surface portion of the cylinder is slightly convex to form the bump portion 122. According to the present invention, the bump portions 122 may be formed in plurality. Further, the bump portion 122 sandwiches the recessed portion formed by the strands of the fiber rope to prevent detachment from the fiber rope. The present invention provides a method of manufacturing a fluorescent identification marking device 100 for a rope. Fig. 3 is a view schematically showing a mold apparatus for manufacturing a method for using a fluorescent identification marker 100 for a rope using an injection molding machine. The present invention is preferably manufactured by inserting the upper and left center pins 61, 62 into the upper mold 51 and the lower mold 52, and filling the EVA copolymer mixture or the reformed EVA copolymer mixture through the filler tube 53. . First, in a state where the upper mold 51 and the lower mold 52 are separated, the left center pin 62 and the right center pin 61 are inserted between the upper mold 51 and the lower mold 52, or the separately formed edge reinforcing portion 125 is inserted into the right center pin 61. The inner side of the inner side is deep and the left center pin 62 and the right center pin 61 are inserted after being inserted into the end thereof. (See Figure 3a). In a state where the left center pin 62 and the right center pin 61 are inserted, the movable molds of the upper mold 51 and the lower mold 52 are moved to form a pair firmly with each other. (See Figure 3b). In a state in which the upper mold 51 and the lower mold 52 are engaged with each other, a melt of the EVA copolymer mixed melt or the reformed EVA copolymer mixture is melted by a filling pipe 53 on a screw (not shown) of the molding machine. The inside of the upper mold 51 and the lower mold 52 is filled. The upper mold 51 and the lower mold 52 are maintained at 130 ° C or higher in a heated state. (See Figure 3c). The melt of the EVA copolymer-mixed melt or the reformed EVA copolymer mixture in which the upper mold 51 and the lower mold 52 are filled is foamed by the internal foaming agent, and formed by the internal crosslinking agent. The cross-linking bonds, therefore, form a predetermined fluorescent EVA foam inside the upper mold 51 and the lower mold 52. The fluorescent EVA foam substantially forms the shape of the body portion 110 and the shape of the EVA cylinder layer 120 inside the upper mold 51 and the lower mold 52. Later, inside the upper mold 51 and the lower mold 52, the right center pin 61 is released from the mold. (See Figure 3d). Inside the upper mold 51 and the lower mold 52, the left center pin 62 is disengaged from the mold. In this state, the inner side ends of the EVA cylinder layer 120 are in a state in which the edge reinforcing portions 125 are respectively joined. (See Figure 3e). above After the right side center pin 61 and the left side center pin 62 are disengaged, the partial mold 51 and the lower mold 52 move the upper mold 51 corresponding to the movable mold, and take out the EVA foam molded product inside. (See Figure 3f). The present invention has been completed by this manufacturing process. Further, as a preferred embodiment of the present invention, a fluorescent identification marking instrument 200 for a rope formed of a separate product is provided. As a preferred embodiment of the present invention, the elliptical body portion 110 may be composed of a semi-cylindrical first body portion 210 and a semi-cylindrical second body portion 220 that may be coupled or separated from the first body portion, and includes first The binding device 230 is combined with the body portion 210 and the second body portion 220. The bonding device 230 includes various devices that combine the first body portion 210 and the second body portion 220 to join the body portion on the cord. The first body portion 210 and the second body portion 220 are used in a state of being coupled to each other, and the first body portion 210 and the second body portion 220 are naturally combined to form the EVA cylinder layer 120. 4 is a view showing a preferred embodiment of the present invention, and FIG. 4a is a perspective view showing a substantially exploded state of the fluorescent identification marking device 200 for a rope according to an embodiment thereof, and FIG. 4b is a fluorescent identification marking device for a rope. Conceptual diagram of the 200 assembly state.
本發明包括:由多個微細氣泡形成且用EVA材料構成的本體部110,以及在本體部110的內部內側中央形成的EVA圓筒層120。在此狀態下,本體部110包括:形成一側一面的第一本體部210;以及與第一本體部210對應,並與第一本體部結合形成完整本體的第二本體部220。 The present invention includes a body portion 110 formed of a plurality of fine bubbles and made of an EVA material, and an EVA cylinder layer 120 formed at the inner inner side of the body portion 110. In this state, the body portion 110 includes: a first body portion 210 that forms one side; and a second body portion 220 that corresponds to the first body portion 210 and that is combined with the first body portion to form a complete body.
根據本發明,第一本體部210和第二本體部220也是由使用EVA共聚物為主要原料製造的熒光EVA發泡體成分構成。熒光EVA發泡體的構成成分及其製造方法與說明內容相同,故不再說明。 According to the present invention, the first body portion 210 and the second body portion 220 are also composed of a fluorescent EVA foam component which is produced using an EVA copolymer as a main raw material. The constituent components of the fluorescent EVA foam and the method for producing the same are the same as those described, and therefore will not be described.
根據本發明的繩索用夜間識別標識器具200還包括使得第一本體部210和第二本體部220相互結合的結合裝置230。第5圖係為本發明的再一較佳實施例,將繩索用熒光識別標識器具200以滑動方式製造的例示圖。 The nighttime identification marking appliance 200 for a rope according to the present invention further includes a coupling device 230 that causes the first body portion 210 and the second body portion 220 to be coupled to each other. Fig. 5 is a view showing an example of manufacturing a rope fluorescent identification marker device 200 in a sliding manner according to still another preferred embodiment of the present invention.
第5圖係為第一本體部210和第二本體部220分 解的狀態例示圖,第5b圖係為將第一本體部210和第二本體部220以相互滑動方式結合的狀態下其剖面圖示。 Figure 5 is a first body portion 210 and a second body portion 220 FIG. 5b is a cross-sectional view showing a state in which the first body portion 210 and the second body portion 220 are slidably coupled to each other.
根據本發明,使得第一本體部210和第二本體部220成為一體的結合裝置230可以在第一本體部210和第二本體部220分別改成滑動方式形成。在此狀態下,第一本體部210上形成滑動凸部232,相反,第二本體部220上形成滑動槽部233。 According to the present invention, the bonding device 230 that integrates the first body portion 210 and the second body portion 220 can be formed in a sliding manner in the first body portion 210 and the second body portion 220, respectively. In this state, the sliding convex portion 232 is formed on the first body portion 210, and the sliding groove portion 233 is formed on the second body portion 220.
第6圖係為本發明的又一較佳實施例,顯示將繩索用熒光識別標識器具200以夾入結合方式製造的例示圖。 Fig. 6 is a view showing an alternative embodiment of the present invention, in which a fluorescent identification marker 200 for a rope is manufactured by being sandwiched and joined.
第6a圖係為第一本體部210和第二本體部220分解狀態的例示圖,第6b圖為將第一本體部210和第二本體部220以相互夾入結合方式結合狀態下的剖面圖示。 6a is an illustration of an exploded state of the first body portion 210 and the second body portion 220, and FIG. 6b is a cross-sectional view of the first body portion 210 and the second body portion 220 in a state of being joined to each other in a combined manner. Show.
根據本發明,使得第一本體部210和第二本體部220相互成為一體的結合裝置230在第一本體部210上形成夾入凸部234,在第二本體部220上形成夾入槽部235而製成。在此狀態下,第一本體部210上形成的夾入凸部234被插入第二本體部220上形成的夾入槽部235而結合。 According to the present invention, the bonding device 230 that integrates the first body portion 210 and the second body portion 220 with each other forms a sandwiching convex portion 234 on the first body portion 210 and a sandwiching groove portion 235 on the second body portion 220. And made. In this state, the sandwiching convex portion 234 formed on the first body portion 210 is inserted into the sandwiching groove portion 235 formed in the second body portion 220 to be coupled.
第7圖係為本發明的又一較佳實施例,為將繩索用熒光識別標識器具200以標記結合方式製造的例示圖。 Fig. 7 is a view showing an alternative embodiment of the present invention for manufacturing a cord fluorescent identification marker 200 in a label-bonding manner.
在此狀態下,第7a圖係為第一本體部210和第二本體部220分解的狀態例示圖,第7b圖為將第一本體部210和第二本體部220以相互夾入結合方式結合狀態下的剖面圖示,第7c圖為將第一本體部210和第二本體部220相互結合狀態下的概略透視圖。 In this state, FIG. 7a is a state diagram in which the first body portion 210 and the second body portion 220 are exploded, and FIG. 7b is a combination of the first body portion 210 and the second body portion 220 in a sandwiching manner. FIG. 7c is a schematic perspective view showing a state in which the first body portion 210 and the second body portion 220 are coupled to each other.
根據本發明,第一本體部210和第二本體部220相互成為一體的結合裝置230是,在第一本體部210和第二本體部220上形成夾入孔237,夾入孔237上插入其他紮帶236,利用紮帶236將第一本體部210和第二本體部220相互結合起來的狀態。 According to the present invention, the first body portion 210 and the second body portion 220 are integrated with each other. The first body portion 210 and the second body portion 220 are formed with a pinching hole 237, and the pinching hole 237 is inserted into the other. The cable tie 236 is in a state in which the first body portion 210 and the second body portion 220 are coupled to each other by the cable tie 236.
第8圖係為本發明的又一較佳實施例,是以擰螺 絲方式製造繩索用熒光識別標識器具200的例示圖。 Figure 8 is a further preferred embodiment of the present invention, which is a screw An illustration of a fluorescent identification marking device 200 for a rope is manufactured by a wire method.
根據本發明,繩索用熒光識別標識器具200可使用螺紋螺栓238和螺母239將第一本體部210和第二本體部220結合起來。在此狀態下,結合裝置230具體是螺紋螺栓238和螺母239。螺紋螺栓238和螺母239是使用塑膠材料構成比金屬材料更適合。因為,海水含鹽分,金屬在海水中容易腐蝕,因此,較佳地使用塑膠材料,從各方面都更適宜。 According to the present invention, the fluorescent identification marker device 200 for a cord can use the threaded bolt 238 and the nut 239 to join the first body portion 210 and the second body portion 220. In this state, the bonding device 230 is specifically a threaded bolt 238 and a nut 239. The threaded bolt 238 and the nut 239 are more suitable to be constructed using a plastic material than a metal material. Since seawater contains salt and metals are easily corroded in seawater, it is preferable to use a plastic material in various aspects.
第9圖係為本發明的又一較佳實施例,是將第一本體部210和第二本體部220結合插入繩索的狀態下的其剖面概略圖。 Fig. 9 is a schematic cross-sectional view showing a state in which the first body portion 210 and the second body portion 220 are inserted into a rope in a still further preferred embodiment of the present invention.
根據本發明,EVA圓筒層120在其兩側末端分別形成凸塊部122為宜。凸塊部122為,繩索上插入本發明的產品以後,會壓迫繩索,防止從繩索脫離或者被擠到其他地方。 According to the present invention, it is preferable that the EVA cylinder layer 120 is formed with a bump portion 122 at both ends thereof. The bump portion 122 compresses the rope after the product of the present invention is inserted into the rope to prevent it from being detached from the rope or being pushed to other places.
根據本發明,凸塊部122可以形成多個。在此狀態下,凸塊部122是夾進被繩索的繩股形成的凹陷部分而防止脫離繩索。 According to the present invention, the bump portions 122 may be formed in plurality. In this state, the bump portion 122 is a recessed portion formed by the strands of the rope to prevent the rope from coming off.
根據本發明的繩索用熒光識別標識器具200主要用於海上或陸地,但也可以與在深海使用的深海繩索結合使用。特別地,將在深海開採石油或燃氣的石油鑽井船或燃氣鑽井船用鋼絲繩停泊時,可以將錨拋入深海,將石油鑽井船和燃氣鑽井船等與鋼絲繩連接使用,但可在鋼絲繩上結合根據本發明的繩索用熒光識別標識器具200使用。在此狀態下,潛水員為確認鋼絲繩是否腐蝕等狀態,進入黑暗的深海處進行作業時,便於潛水員在黑暗的深海中識別鋼絲繩加以靠近,並採取必要措施。 The fluorescent identification marking device 200 for ropes according to the present invention is mainly used at sea or on land, but can also be used in combination with deep sea ropes used in the deep sea. In particular, when mooring oil or gas drilling oil or gas drilling ship ropes for deep sea mining, the anchors can be thrown into the deep sea, and the oil drilling ship and the gas drilling ship can be connected with the steel wire rope, but the wire rope can be used. The fluorescent identification marker device 200 for use with a cord according to the present invention is used in combination. In this state, the diver enters the dark deep sea to confirm whether the wire rope is corroded or the like, and it is convenient for the diver to recognize the wire rope in the dark deep sea and take necessary measures.
第10圖係為本發明的又一較佳實施例,是在深海使用狀態下的例示。在此狀態下,海上漂浮著進行作業的船隻270,船隻270的周圍有系船浮標280,從系船浮標280到深海底面,全部連接鋼絲繩,使用錨290固定住船隻。鋼絲繩上每隔一段結合本發明的繩索用熒光識別標識器具200。 Figure 10 is a further preferred embodiment of the present invention and is an illustration in the deep sea use state. In this state, a vessel 270 is operated floating on the sea. The vessel 270 is surrounded by a mooring buoy 280, from the mooring buoy 280 to the bottom of the deep sea, all connected to the wire rope, and the anchor 290 is used to fix the vessel. The fluorescent identification marking device 200 is incorporated into the rope of the present invention at every other stage on the wire rope.
以上實施例僅用以說明本發明的繩索用熒光識別標識器具100、200,而非對其限制;儘管參照前述實施例對本發明進行了詳細的說明,本領域的普通技術人員應當理解:其依然可以對前述各實施例所述的技術方案進行修改,或者對其中部分技術特徵進行等同替換;而這些修改或者替換,並不使相應技術方案的本質脫離本發明各實施例所述技術方案的範圍。本發明的保護範圍應根據下述的專利申請範圍進行解釋,而且在其同等範圍內的所有技術方案應都屬於本發明的專利申請範圍。 The above embodiments are merely illustrative of the fluorescent identification marking devices 100, 200 of the present invention, and are not limited thereto; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those skilled in the art that The technical solutions described in the foregoing embodiments may be modified, or some of the technical features may be equivalently replaced; and the modifications or substitutions do not deviate from the technical solutions of the embodiments of the present invention. . The scope of the present invention should be construed in accordance with the scope of the following patent application, and all technical solutions within the scope of the invention should fall within the scope of the invention.
110‧‧‧本體部 110‧‧‧ Body Department
200‧‧‧繩索用熒光識別標識器具 200‧‧‧Fluorescent identification device for ropes
210‧‧‧第一本體部 210‧‧‧First Body Department
220‧‧‧第二本體部 220‧‧‧Second body
230‧‧‧結合裝置 230‧‧‧ Combined device
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Applications Claiming Priority (1)
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KR1020130098612A KR101346043B1 (en) | 2013-08-20 | 2013-08-20 | Fluorolecent means for working rope in the dark area |
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TW201517789A TW201517789A (en) | 2015-05-16 |
TWI568350B true TWI568350B (en) | 2017-02-01 |
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TW103115853A TWI568350B (en) | 2013-08-20 | 2014-05-02 | Fluorescent means for working rope in the dark area |
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KR (1) | KR101346043B1 (en) |
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KR101436883B1 (en) * | 2014-03-25 | 2014-11-04 | 신한테크(주) | Equipment manufacturing and rope fisheries |
CN109649585B (en) * | 2019-01-08 | 2020-01-14 | 秦永乐 | Luminous cable skimming head and application thereof |
KR102613875B1 (en) * | 2023-06-01 | 2023-12-14 | 주식회사 오션테크 | Air pocket type buoy using eco-friendly materials |
KR102647828B1 (en) | 2023-11-06 | 2024-03-14 | (주)케이씨산업 | Eva float |
Citations (3)
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CN1325916A (en) * | 2000-05-29 | 2001-12-12 | 张锡永 | Process for preparing foamed float ball |
CN2567987Y (en) * | 2002-09-19 | 2003-08-27 | 威海富海渔具有限公司 | Float |
TWM456699U (en) * | 2012-12-13 | 2013-07-11 | wen-hua Xie | Buoy structure of fishing net |
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KR100720162B1 (en) * | 2005-01-07 | 2007-05-18 | 최능호 | Manufacturing method of fishing float using resin compound |
KR100985573B1 (en) * | 2008-09-05 | 2010-10-05 | 장상무 | A noctilucent buoy of mixing materials of waste rubber and plastic |
KR101196480B1 (en) * | 2011-01-11 | 2012-11-01 | 정영석 | Buoy product method |
KR101249520B1 (en) * | 2011-01-12 | 2013-04-01 | (주)로프캠프 | A luminescence rope |
KR101241604B1 (en) * | 2011-07-15 | 2013-03-11 | 이태선 | Coating buoy |
KR101248432B1 (en) | 2012-08-20 | 2013-04-02 | 대광기업 주식회사 | Fluorescent wire rope with fluorescent tube(s) and method of producing the same |
KR101256083B1 (en) | 2012-08-20 | 2013-04-29 | 아시아쉬핑(주) | Fluorolecent means for fabric rope |
CN103072675B (en) * | 2012-12-21 | 2015-06-17 | 海洋化工研究院有限公司 | Umbilical cable floating body |
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2013
- 2013-08-20 KR KR1020130098612A patent/KR101346043B1/en active IP Right Grant
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- 2014-04-30 CN CN201410183253.7A patent/CN104417715B/en not_active Expired - Fee Related
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1325916A (en) * | 2000-05-29 | 2001-12-12 | 张锡永 | Process for preparing foamed float ball |
CN2567987Y (en) * | 2002-09-19 | 2003-08-27 | 威海富海渔具有限公司 | Float |
TWM456699U (en) * | 2012-12-13 | 2013-07-11 | wen-hua Xie | Buoy structure of fishing net |
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KR101346043B1 (en) | 2013-12-31 |
CN104417715A (en) | 2015-03-18 |
TW201517789A (en) | 2015-05-16 |
CN104417715B (en) | 2018-01-19 |
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