TWI556020B - Composite polarizing plate - Google Patents

Composite polarizing plate Download PDF

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TWI556020B
TWI556020B TW102135765A TW102135765A TWI556020B TW I556020 B TWI556020 B TW I556020B TW 102135765 A TW102135765 A TW 102135765A TW 102135765 A TW102135765 A TW 102135765A TW I556020 B TWI556020 B TW I556020B
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polarizing plate
refractive index
patterned
layer
retardation film
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TW102135765A
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TW201403146A (en
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崔鳳珍
金炳仁
趙午炯
權純凡
河京秀
金龍煥
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東友精細化工有限公司
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3083Birefringent or phase retarding elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B30/00Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images
    • G02B30/20Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images by providing first and second parallax images to an observer's left and right eyes
    • G02B30/34Stereoscopes providing a stereoscopic pair of separated images corresponding to parallactically displaced views of the same object, e.g. 3D slide viewers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/42Polarizing, birefringent, filtering
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polarising Elements (AREA)
  • Liquid Crystal (AREA)

Description

複合偏光板 Composite polarizer

本發明關於圖案化阻滯劑積層複合偏光板以及使用該複合偏光板的顯示裝置。 The present invention relates to a patterned retarder laminated composite polarizing plate and a display device using the composite polarizing plate.

當看著顯示器時,觀看者生理上以及經驗上察覺至三維深度。通常,三維影像基於雙眼視差實施,其為用以解釋為什麼該觀看者在近距離感覺到三維深度的基本原理。 When looking at the display, the viewer is physiologically and empirically aware of the three-dimensional depth. Typically, a three-dimensional image is implemented based on binocular parallax, which is the basic principle to explain why the viewer perceives a three-dimensional depth at close range.

使用該雙眼視差,使用用於左眼以及右眼的至少兩個相機而分開擷取兩個不同的影像,且所擷取的影像被分開地顯示至該左眼以及右眼。然後該影像在腦中被結合,以給出三維深度的感知。 Using the binocular parallax, two different images are separately captured using at least two cameras for the left eye and the right eye, and the captured images are separately displayed to the left eye and the right eye. The image is then combined in the brain to give a three-dimensional depth of perception.

三維影像技術可劃分成兩個種類:使用偏光眼鏡的方法以及不使用偏光眼鏡的方法。使用眼鏡之技術的範例包括(1)互補色法,其使用其中該兩個鏡片為不同顏色的眼鏡,(2)偏極法,其使用其中該兩個鏡片具有不同偏極方向的眼鏡,以及(3)分時法,其使用與該螢幕更新率同步的快門眼鏡。 3D imaging technology can be divided into two categories: methods using polarized glasses and methods without using polarized glasses. Examples of techniques for using glasses include (1) a complementary color method using glasses in which the two lenses are different colors, and (2) a polarization method using glasses in which the two lenses have different polarization directions, and (3) Time-sharing method using shutter glasses synchronized with the screen update rate.

使用偏光眼鏡的技術需要用於顯示三維影像的顯示裝置以及用於觀察所顯示之三維影像的偏光眼鏡。 The technique of using polarized glasses requires a display device for displaying a three-dimensional image and polarized glasses for observing the displayed three-dimensional image.

同時,許多使用偏光眼鏡的三維顯示器包括圖案化的阻滯劑(在基底薄膜上的阻滯劑圖案)。該圖案化阻滯劑藉由永久的或壓敏的黏著劑而積層在偏光板的一側。 Meanwhile, many three-dimensional displays using polarized glasses include a patterned retarder (a retarder pattern on a base film). The patterned retarder is laminated on one side of the polarizing plate by a permanent or pressure sensitive adhesive.

然而,該圖案化阻滯劑可導致顯示品質的惡化,因為該圖案化阻滯劑的每個圖案化區域的光軸方向(異常軸的方向)彼此不同。 However, the patterned retarder may cause deterioration in display quality because the optical axis direction (direction of the abnormal axis) of each of the patterned regions of the patterned retarder is different from each other.

在包括重複配置阻滯劑圖案的圖案化阻滯劑中,由於該圖案 In a patterned retarder comprising a repeating arrangement of a retarder pattern, due to the pattern

然而,該圖案化阻滯劑可導致顯示品質的惡化,因為該圖案化阻滯劑的每個圖案化區域的光軸方向(異常軸的方向)彼此不同。 However, the patterned retarder may cause deterioration in display quality because the optical axis direction (direction of the abnormal axis) of each of the patterned regions of the patterned retarder is different from each other.

在包括重複配置阻滯劑圖案的圖案化阻滯劑中,由於該圖案化阻滯劑之折射率以及穿透比的差異,光與影的圖案可被偵測,且當該光與影圖案與背光的漫射圖案或稜鏡片的光與影圖案等等相干涉時,雲紋圖案(moire pattern)也可被偵測。 In a patterned retarder comprising a repeating arrangement of a retarder pattern, due to the difference in refractive index and transmittance ratio of the patterned retarder, a pattern of light and shadow can be detected, and when the light and shadow pattern and the backlight are diffused When a light of a pattern or a cymbal interferes with a shadow pattern or the like, a moire pattern can also be detected.

本發明用以提供一種包括圖案化阻滯劑的複合偏光板,以至於光的偏極化、該偏極光的相差補償以及三維影像的影像分離可同時完成。 The invention provides a composite polarizing plate comprising a patterned retarder, so that the polarization of the light, the phase difference compensation of the polarized light and the image separation of the three-dimensional image can be simultaneously performed.

本發明也用以提供一種複合偏光板,以改善由於圖案化阻滯劑中圖案化區域之間的亮度差以及該圖案化阻滯劑與黏著層之間折射率差異所造成的雲紋效應。 The present invention is also directed to providing a composite polarizing plate to improve the moiré effect due to the difference in brightness between the patterned regions in the patterned retarder and the difference in refractive index between the patterned retarder and the adhesive layer.

本發明也用以提供一種包括該複合偏光板的顯示裝置。 The invention also serves to provide a display device comprising the composite polarizing plate.

本發明提供了一種包括圖案化阻滯劑的複合偏光板,該圖案化阻滯劑藉由黏著層而積層在偏光板上,其中該黏著層的折射率(N)滿足下述等式(1):min(n0,ne)≦N≦max(n0,ne) (1)其中n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者。 The present invention provides a composite polarizing plate comprising a patterned retarder laminated on a polarizing plate by an adhesive layer, wherein the refractive index (N) of the adhesive layer satisfies the following equation (1) ):min(n 0 ,n e )≦N≦max(n 0 ,n e ) (1) where n 0 represents the ordinary refractive index of the patterned retarder, and n e represents the abnormality of the patterned retarder The refractive index, min(n 0 , n e ) represents the smaller of n 0 and n e , and max(n 0 , n e ) represents the larger of n 0 and n e .

本發明提供了一種包括圖案化阻滯劑的複合偏光板,該圖案化阻滯劑藉由黏著層積層在偏光板上,其中該折射率(N)滿足下述等式(2):min(n0,ne)+| n0-ne|/3≦N≦max(n0,ne)-| n0-ne|/3 (2) 其中n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者。 The present invention provides a composite polarizing plate comprising a patterned retarder laminated on a polarizing plate by an adhesive layer, wherein the refractive index (N) satisfies the following equation (2): min ( n 0 ,n e )+| n 0 -n e |/3≦N≦max(n 0 ,n e )-| n 0 -n e |/3 (2) where n 0 represents the patterned retarder The usual refractive index, n e represents the abnormal refractive index of the patterned retarder, min(n 0 , n e ) represents the smaller of n 0 and n e , and max(n 0 , n e ) represents The larger between n 0 and n e .

本發明提供了一種複合偏光板包括圖案化阻滯劑的複合偏光板,該圖案化阻滯劑藉由黏著層積層在偏光板上,其中該折射率(N)滿足下述等式(3):0.99Ne≦N≦1.01Ne (3)其中Ne=(n0+ne)/2,n0代表該圖案化阻滯劑的平常折射率,以及ne代表該圖案化阻滯劑的異常折射率。 The present invention provides a composite polarizing plate comprising a patterned retarder, the patterned retarder is laminated on a polarizing plate by an adhesive layer, wherein the refractive index (N) satisfies the following equation (3) : 0.99 Ne ≦ N ≦ 1.01 Ne (3) wherein Ne = (n 0 + n e ) /2, n 0 represents the ordinary refractive index of the patterned retarder, and n e represents the abnormality of the patterned retarder Refractive index.

本發明提供了一種複合偏光板包括圖案化阻滯劑的複合偏光板,該圖案化阻滯劑藉由黏著層積層在偏光板上,其中該折射率(N)滿足下述等式(4):0.994Ne≦N≦1.006Ne (4)其中Ne=(n0+ne)/2,n0代表該圖案化阻滯劑的平常折射率,以及ne代表該圖案化阻滯劑的異常折射率。 The present invention provides a composite polarizing plate comprising a patterned retarder, the patterned retarder is laminated on a polarizing plate by an adhesive layer, wherein the refractive index (N) satisfies the following equation (4) :0.994Ne≦N≦1.006Ne (4) wherein Ne=(n 0 +n e )/2, n 0 represents the ordinary refractive index of the patterned retarder, and n e represents the abnormality of the patterned retarder Refractive index.

.據本發明的複合偏光板,因為由於圖案化阻滯劑以及黏著層之間折射率的差異所造成的雲紋效應可被改善,其可能提供均勻的三維影像。 According to the composite polarizing plate of the present invention, since the moiré effect due to the difference in refractive index between the patterned retardant and the adhesive layer can be improved, it is possible to provide a uniform three-dimensional image.

根據本發明的複合偏光板,因為該圖案化阻滯劑可直接積層在偏光板上,且不需要分開的基底薄膜,其可能提供薄的顯示裝置。 According to the composite polarizing plate of the present invention, since the patterned retarder can be directly laminated on the polarizing plate and a separate base film is not required, it is possible to provide a thin display device.

根據本發明的複合偏光板,因為圖案化區域之間的亮度差非常小,其可能減少由於影像中亮度差所造成的眼睛疲勞以及暈眩,該影像由左眼以及右眼察覺。 According to the composite polarizing plate of the present invention, since the difference in luminance between the patterned regions is very small, it is possible to reduce eye fatigue and dizziness caused by a difference in luminance in the image, which is perceived by the left eye and the right eye.

當本發明的複合偏光板應用至顯示器製程時,當積層圖案化阻滯劑於偏光板上時,其可能降低外來物質被包括在層之間的可能性。 When the composite polarizing plate of the present invention is applied to a display process, when a patterned retarder is laminated on a polarizing plate, it may reduce the possibility that foreign matter is included between the layers.

根據本發明的複合偏光板可廣泛地應用至許多類型的顯示裝置,例如反射式或穿透反射式液晶顯示器(LCD)、電漿顯示面板(PDP)以及有機EL顯示器(OLED)等等。 The composite polarizing plate according to the present invention can be widely applied to many types of display devices such as a reflective or transflective liquid crystal display (LCD), a plasma display panel (PDP), an organic EL display (OLED), and the like.

10、11、40、41、60、110、310‧‧‧偏光板 10, 11, 40, 41, 60, 110, 310‧‧‧ polarizing plates

20、21‧‧‧圖案化阻滯層 20, 21‧‧‧ patterned barrier layer

30、31、320‧‧‧阻滯層 30, 31, 320‧‧‧ Blocking layer

61‧‧‧第一影像顯示區域 61‧‧‧First image display area

62‧‧‧第二影像顯示區域 62‧‧‧Second image display area

63、120‧‧‧圖案化阻滯劑 63, 120‧‧‧ patterned blockers

64‧‧‧第一圖案化區域 64‧‧‧First patterned area

65‧‧‧第二圖案化區域 65‧‧‧Second patterned area

70‧‧‧偏光眼鏡 70‧‧‧ Polarized glasses

71‧‧‧第一偏極化區域 71‧‧‧First polarization zone

72‧‧‧第二偏極化區域 72‧‧‧Second polarization zone

74‧‧‧左鏡片 74‧‧‧ left lens

75‧‧‧右鏡片 75‧‧‧right lens

130‧‧‧黏著層 130‧‧‧Adhesive layer

140‧‧‧透明基底層 140‧‧‧Transparent basal layer

200‧‧‧液晶顯示面板 200‧‧‧LCD panel

240‧‧‧反射層 240‧‧‧reflective layer

410‧‧‧背光單元 410‧‧‧Backlight unit

在圖式中:第1圖以及第2圖顯示了根據本發明之複合偏光板的範例;第3圖以及第4圖顯示了包括根據本發明之複合偏光板的反射式液晶顯示器範例;第5圖以及第6圖顯示了包括根據本發明之複合偏光板的穿透反射式液晶顯示器範例;第7圖以及第8圖顯示了包括根據本發明之複合偏光板的電漿顯示面板或有機EL顯示器範例;第9圖顯示了包括根據本發明之複合偏光板的眼鏡型三維影像顯示系統;以及第10圖是用以簡短解釋第9圖中該三維影像顯示系統之原理的圖示。 In the drawings: FIGS. 1 and 2 show an example of a composite polarizing plate according to the present invention; FIGS. 3 and 4 show an example of a reflective liquid crystal display including a composite polarizing plate according to the present invention; Figure 6 and Figure 6 show an example of a transflective liquid crystal display comprising a composite polarizing plate according to the present invention; Figures 7 and 8 show a plasma display panel or an organic EL display including a composite polarizing plate according to the present invention. Example; FIG. 9 shows a glasses-type three-dimensional image display system including a composite polarizing plate according to the present invention; and FIG. 10 is a diagram for explaining briefly the principle of the three-dimensional image display system in FIG.

本發明關於一種包括圖案化阻滯劑的複合偏光板,該圖案化阻滯劑藉由黏著層而積層在偏光板上,其中該黏著層的折射率(N)滿足上述等式(1)-(4)的其中一個。包含該複合偏光板的三維顯示裝置可顯示均勻的三維影像,因為由於圖案化阻滯劑以及黏著層之間折射率的差異所造成的雲紋可被改善。因為該圖案化阻滯劑可直接積層在該偏光板上,且不需要分開的基底薄膜,該複合偏光板可能提供較薄的顯示裝置。當製備包括圖案化阻滯劑以及偏光板的顯示裝置時,該複合偏光板也可能大大地降低外 來物質被包括在層之間的可能性。 The present invention relates to a composite polarizing plate comprising a patterned retarder laminated on a polarizing plate by an adhesive layer, wherein the refractive index (N) of the adhesive layer satisfies the above equation (1)- One of (4). The three-dimensional display device including the composite polarizing plate can display a uniform three-dimensional image because the moiré can be improved due to the difference in refractive index between the patterned retardant and the adhesive layer. Since the patterned retarder can be directly laminated on the polarizing plate and a separate base film is not required, the composite polarizing plate may provide a thin display device. When a display device including a patterned retarder and a polarizing plate is prepared, the composite polarizing plate may also be greatly reduced The possibility that a substance is included between layers.

此後,本發明被細節地描述。 Hereinafter, the present invention is described in detail.

如第1圖中所示,複合偏光板可包括偏光板110、積層在該偏光板110上的黏著層130以及積層在該黏著層130上的圖案化阻滯劑120。該圖案化阻滯劑120可被直接地塗層在該偏光板上。例如,該圖案化阻滯劑120可被塗層於放置在該偏光板表面上的偏光鏡保護薄膜或阻滯薄膜上。 As shown in FIG. 1, the composite polarizing plate may include a polarizing plate 110, an adhesive layer 130 laminated on the polarizing plate 110, and a patterned retarder 120 laminated on the adhesive layer 130. The patterned retarder 120 can be directly coated on the polarizing plate. For example, the patterned retarder 120 may be coated on a polarizer protective film or a retardation film placed on the surface of the polarizing plate.

此外,當物理特性,例如該圖案化阻滯劑120的強度足夠時,或在製程中先製備該圖案化阻滯劑120,之後再將它積層至該偏光板是有利時,該圖案化阻滯劑120可被形成在透明基底層140上,然後該圖案化阻滯劑120形成於其上的該基底層140可被積層在該偏光板上。 In addition, when physical properties, such as the strength of the patterned retarder 120, are sufficient, or the patterned retarder 120 is prepared in the process, and then it is advantageous to laminate it to the polarizing plate, the patterning resistance is The stagnation agent 120 may be formed on the transparent substrate layer 140, and then the base layer 140 on which the patterned retarder 120 is formed may be laminated on the polarizing plate.

常使用於顯示器中的任何偏光板可用以作為本發明中的偏光板。例如,包括偏光鏡的積層結構,以及至少一個功能薄膜可用以作為本發明的偏光板,該至少一個功能薄膜選自積層在該偏光鏡的一側或兩側上的偏光鏡保護薄膜以及阻滯薄膜所組成的群組。同樣地,可使用藉由在透明基底層上形成微圖案化傳導網柵以及在該傳導網柵的凹部與脊部上塗層絕緣層而製造的薄偏光板。 Any polarizing plate commonly used in displays can be used as the polarizing plate in the present invention. For example, a laminate structure including a polarizer, and at least one functional film may be used as the polarizing plate of the present invention, the at least one functional film being selected from a polarizer protective film laminated on one or both sides of the polarizer and blocking A group of films. Likewise, a thin polarizing plate fabricated by forming a micropatterned conductive mesh on a transparent substrate layer and coating an insulating layer on the recesses and ridges of the conductive mesh can be used.

在本發明中偏光鏡的類型不受限制,且可使用在顯示器中可一般使用的任何類型偏光鏡。例如,可使用藉由以碘或二色性染料染色聚乙烯醇薄膜並延伸它而製造的偏光鏡。 The type of polarizer is not limited in the present invention, and any type of polarizer that can be generally used in a display can be used. For example, a polarizer manufactured by dyeing a polyvinyl alcohol film with iodine or a dichroic dye and extending it can be used.

本發明的黏著層用以將圖案化阻滯劑附著在偏光板的一側上。 The adhesive layer of the present invention is used to attach a patterned retarder to one side of the polarizing plate.

在本發明中,該黏著層可由永久的黏著劑或壓敏的黏著劑構成。 In the present invention, the adhesive layer may be composed of a permanent adhesive or a pressure sensitive adhesive.

在本發明中,在單軸的阻滯層中,異常折射率(ne)代表在x、y以及z軸的折射率之間具有不同折射率值之方向的折射率,以及平常折射率(n0)代表其他兩個方向的折射率(垂直於該異常折射率之方向的該 其他方向的折射率)。 In the present invention, in the uniaxial retardation layer, the abnormal refractive index (n e ) represents a refractive index having a direction of a different refractive index value between the refractive indices of the x, y, and z axes, and a normal refractive index ( n 0 ) represents the refractive index of the other two directions (the refractive index of the other direction perpendicular to the direction of the abnormal refractive index).

在雙軸的阻滯層中,異常折射率(ne)代表x、y以及z軸之 折射率之間的最大折射率或最小折射率,其中一個比另外一個與既非最大折射率也非最小折射率的折射率具有較大的差異,以及平常折射率(n0)代表其他兩個方向的折射率。 In the biaxial retardation layer, the anomalous refractive index (n e ) represents the maximum or minimum refractive index between the refractive indices of the x, y, and z axes, one of which is different from the other and neither the maximum refractive index nor The refractive index of the minimum refractive index has a large difference, and the ordinary refractive index (n 0 ) represents the refractive indices of the other two directions.

如該下述等式(1)所示,本發明黏著層的折射率(N)想要在 圖案化阻滯劑的平常折射率(n0)以及異常折射率(ne)之間。其用以減少阻滯劑圖案之間的亮度差,並消除雲紋效應。 As shown in the following equation (1), the refractive index (N) of the adhesive layer of the present invention is intended to be between the ordinary refractive index (n 0 ) and the abnormal refractive index (n e ) of the patterned retarder. It is used to reduce the difference in brightness between the retarder patterns and to eliminate the moiré effect.

min(n0,ne)=N=max(n0,ne) (1) (在上述等式中,n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者)。 Min(n 0 , n e )=N=max(n 0 , n e ) (1) (In the above equation, n 0 represents the normal refractive index of the patterned retarder, and n e represents the patterned resistance The anomalous refractive index of the retarder, min(n 0 , n e ) represents the smaller of n 0 and n e , and max(n 0 , n e ) represents the larger of n 0 and n e ) .

此外,在本發明中,為了減少阻滯劑圖案之間的亮度差並消除雲紋效應,較想要黏著層的折射率(N)在下述等式(2)中所描述的範圍內。該等式(2)顯示了,當平常折射率以及異常折射率之間的差距以三等分劃分時,如果該折射率(N)是在包含該平常折射率以及該異常折射率之算術平均數的部分內,減少阻滯劑圖案之間的亮度差並消除雲紋圖案會更有效。 Further, in the present invention, in order to reduce the difference in luminance between the retarder patterns and to eliminate the moiré effect, it is desirable that the refractive index (N) of the adhesive layer is within the range described in the following equation (2). The equation (2) shows that when the difference between the ordinary refractive index and the abnormal refractive index is divided into three equal parts, if the refractive index (N) is in the arithmetic mean of including the ordinary refractive index and the abnormal refractive index Within the portion of the number, it is more effective to reduce the difference in brightness between the retarder patterns and eliminate the moiré pattern.

(在上述等式中,n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者。) (In the above equation, n 0 represents the ordinary refractive index of the patterned retarder, n e represents the abnormal refractive index of the patterned retarder, and min(n 0 , n e ) represents n 0 and n e The smaller one, and max(n 0 , n e ) represent the larger of n 0 and n e .)

此外,在本發明中,為了減少阻滯劑圖案之間的亮度差,並消除雲紋圖案,更想要黏著層的折射率(N)在下述等式(3)中所描述的範圍內。該等式(3)顯示了當該黏著層之折射率(N)以及該平常折射率與該異常折射率之算術平均數之間的差異小於1%時,減少阻滯劑圖案之間的的亮度差並消除雲紋圖案會更有效。 Further, in the present invention, in order to reduce the difference in luminance between the retarder patterns and to eliminate the moiré pattern, it is more desirable that the refractive index (N) of the adhesive layer is within the range described in the following equation (3). The equation (3) shows that when the refractive index (N) of the adhesive layer and the difference between the ordinary refractive index and the arithmetic mean of the abnormal refractive index are less than 1%, the pattern between the retarder patterns is reduced. It is more effective to have a difference in brightness and eliminate the moiré pattern.

0.99Ne=N=1.01Ne (3)(在上述等式中,Ne=(n0+ne)/2,n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率。) 0.99Ne=N=1.01Ne (3) (In the above equation, Ne=(n 0 +n e )/2, n 0 represents the normal refractive index of the patterned retarder, and n e represents the patterned resistance The abnormal refractive index of the retarder.)

此外,在本發明中,為了減少阻滯劑圖案之間的亮度差,並消除雲紋圖案,更想要黏著層的折射率(N)在下述等式(4)中所描述的範圍內。該等式(4)顯示了當該黏著層之折射率(N)以及該平常折射率與該異常折射率之算術平均數之間的差異小於0.6%時,減少阻滯劑圖案之間的的亮度差並消除雲紋圖案會更有效。 Further, in the present invention, in order to reduce the difference in luminance between the retarder patterns and to eliminate the moiré pattern, it is more desirable that the refractive index (N) of the adhesive layer is within the range described in the following equation (4). The equation (4) shows that when the refractive index (N) of the adhesive layer and the difference between the ordinary refractive index and the arithmetic mean of the abnormal refractive index are less than 0.6%, the pattern between the retarder patterns is reduced. It is more effective to have a difference in brightness and eliminate the moiré pattern.

0.994Ne=N=1.006Ne (4)(在上述等式中,Ne=(n0+ne)/2,n0代表該圖案化阻滯劑的平常折射率,ne代表該圖案化阻滯劑的異常折射率。) 0.994Ne=N=1.006Ne (4) (In the above equation, Ne=(n 0 +n e )/2, n 0 represents the ordinary refractive index of the patterned retarder, and n e represents the patterned resistance The abnormal refractive index of the retarder.)

假設兩層具有不同的折射率(第一媒介以及第二媒介)。當光穿過該兩層的邊緣時,從該第一媒介垂直入射至該第二媒介的光的折射率是R=((n2-n1)/(n2+n1))2(在等式中,n1是該第一媒介的折射率,以及n2是該第二媒介的折射率)。 It is assumed that the two layers have different refractive indices (first medium and second medium). When light passes through the edges of the two layers, the refractive index of light incident perpendicularly from the first medium to the second medium is R = ((n 2 - n 1 ) / (n 2 + n 1 )) 2 ( In the equation, n 1 is the refractive index of the first medium, and n 2 is the refractive index of the second medium.

假設黏著層是該第一媒介,以及圖案化阻滯劑是該第二媒介,當入射光的偏極方向在該異常折射率的方向時,n2=ne以及Re=((ne-n1)/(ne+n1))2,以及當入射光的偏極方向在該平常折射率的方向時,n2=n0以及R0=((n0-n1)/(n0+n1))2Assuming that the adhesive layer is the first medium, and the patterned retarder is the second medium, when the polarization direction of the incident light is in the direction of the abnormal refractive index, n 2 =n e and R e =((n e -n 1 ) / (n e + n 1 )) 2 , and when the direction of the polarization of the incident light is in the direction of the normal refractive index, n 2 = n 0 and R 0 = ((n 0 - n 1 ) / (n 0 +n 1 )) 2 .

同時,圖案化阻滯劑之兩個圖案化區域(第一圖案化區域以及第二圖案化區域)的異常軸被配置成彼此垂直,所以當入射光平行於該第一圖案化區域的異常軸時,該入射光垂直於該第二圖案化區域的異常軸。因此,該第一圖案化區域以及該第二圖案化區域的反射值分別為Re=((ne-n1)/(ne+n1))2以及R0=((n0-n1)/(n0+n1))2At the same time, the abnormal axes of the two patterned regions (the first patterned region and the second patterned region) of the patterned retarder are arranged to be perpendicular to each other, so when the incident light is parallel to the anomalous axis of the first patterned region The incident light is perpendicular to the anomalous axis of the second patterned region. Therefore, the reflection values of the first patterned region and the second patterned region are respectively R e =((n e -n 1 )/(n e +n 1 )) 2 and R 0 =((n 0 - n 1 ) / (n 0 + n 1 )) 2 .

如果n1不是介於ne以及n0之間,Re以及R0之間的差異變大, 並由於該圖案化阻滯劑的穿透率衰減而發生嚴重的亮度衰減。然而,如果n1在ne以及n0之間,Re以及R0之間的差異變小,且整體的穿透率不快速地改變,所以由於該圖案化阻滯劑穿透率衰減造成的亮度衰減不嚴重。 If n 1 is not between n e and n 0 , the difference between R e and R 0 becomes large, and severe luminance decay occurs due to the attenuation of the transmittance of the patterned retarder. However, if n 1 is between n e and n 0 , the difference between R e and R 0 becomes small, and the overall transmittance does not change rapidly, due to the attenuation of the patterned retarder transmittance The brightness decay is not serious.

如上所述,當本發明黏著層的折射率滿足該等式(1)時,阻滯劑圖案之間的亮度差可被減少,且雲紋效應可被消除。此外,本發明的折射率滿足該等式(2)、(3)以及(4),且變得更接近Ne的值,其為該平常折射率以及該異常折射率的算術平均數,上述效果變得更有效。 As described above, when the refractive index of the adhesive layer of the present invention satisfies the equation (1), the difference in luminance between the retarder patterns can be reduced, and the moiré effect can be eliminated. Further, the refractive index of the present invention satisfies the equations (2), (3), and (4), and becomes closer to the value of Ne, which is the ordinary refractive index and the arithmetic mean of the abnormal refractive index, and the above effects Become more effective.

較佳維持入射光至該圖案化阻滯劑的偏極方向在該圖案化阻滯劑的兩個圖案化區域(該第一圖案化區域以及該第二圖案化區域)的異常軸之間,以及該黏著層的折射率在上述範圍中。此外,較佳該偏極方向較靠近該兩個異常軸的中間(平分在該兩個異常軸之間角度的方向)。 Preferably, the direction of polarization of the incident light to the patterned retarder is maintained between the anomalous axes of the two patterned regions of the patterned retarder (the first patterned region and the second patterned region), And the refractive index of the adhesive layer is in the above range. Further, it is preferable that the biasing direction is closer to the middle of the two abnormal axes (the direction of the angle between the two abnormal axes).

例如,當該第一圖案化區域的光軸(異常軸)是x(0°),以及第二圖案化區域的光軸(異常軸)是y(90°)時,從該黏著層垂直入射至該圖案化阻滯劑的光的偏極方向想要在0°以及90°之間,以及更想要較接近45°,例如,在22.5°以及67.5°之間。 For example, when the optical axis (abnormal axis) of the first patterned region is x (0°) and the optical axis (abnormal axis) of the second patterned region is y (90°), the light is incident perpendicularly from the adhesive layer. The direction of polarization of the light to the patterned retarder is desirably between 0 and 90, and more desirably closer to 45, for example between 22.5 and 67.5.

如上述所配置的該偏極方向能夠抑制該圖案化阻滯劑中圖案化區域之間的反射以及該圖案化阻滯劑以及該黏著層之間的反射。理由如下。 The polarization direction as configured above can suppress reflection between the patterned regions in the patterned retarder and reflection between the patterned retarder and the adhesive layer. The reasons are as follows.

當具有任意偏極方向的光進入該圖案化阻滯劑時,藉由將該光分成兩個電場成分,Ee1以及E01,以及加總兩個分別從Ee1以及E01計算的反射率而計算入射至該第一圖案化區域的光的反射率。藉由將該光分成兩個電場成分,Ee2以及E02,以及加總兩個分別從Ee2以及E02計算的反射率而計算入射至該第二圖案化區域的光的反射率。 When light having an arbitrary polarization direction enters the patterned retarder, by dividing the light into two electric field components, E e1 and E 01 , and summing two reflectances calculated from E e1 and E 01 respectively The reflectance of the light incident on the first patterned region is calculated. The reflectance of light incident on the second patterned region is calculated by splitting the light into two electric field components, E e2 and E 02 , and summing the two reflectances calculated from E e2 and E 02 , respectively.

例如,當該第一圖案化區域的ne以及n0大約相同於該第二圖案化區域的ne以及n0(ne1=ne2,n01=n02),以及只有異常軸彼此不同時,ne-n1並不同於n0-n1,除非n1=(ne+n0)/2。該反射光的強度可被表示為Ei 2×Ri= Eei 2×Re+E0i 2×R0(這裡,Eei以及E0i代表該第一以及第二圖案化區域中異常軸以及平常軸之方向的電場強度)。在此情況中,當光進入該第一或第二圖案化區域時,具有較接近該電場向量方向之光軸的光的電場成分具有較高的強度。 For example, when n e and n 0 of the first patterned region are approximately the same as n e and n 0 (n e1 =n e2 , n 01 =n 02 ) of the second patterned region, and only the abnormal axes are different from each other When n e -n 1 is different from n 0 -n 1 unless n 1 =(n e +n 0 )/2. The intensity of the reflected light can be expressed as E i 2 × R i = E ei 2 × R e + E 0i 2 × R 0 (here, E ei and E 0i represent anomalous axes in the first and second patterned regions) And the electric field strength in the direction of the normal axis). In this case, when light enters the first or second patterned region, the electric field component of light having an optical axis closer to the direction of the electric field vector has a higher intensity.

在此情況中,因為在該第一以及第二圖案化區域之間的Re 變得不同,每個圖案化區域的整體反射率之間發生差異。因此,對於每個圖案化區域的亮度不同。此外,由於每個該圖案化區域之間的反射率差異,光之偏極化中的錯誤可發生。因此,在本發明中,已入射至該圖案化阻滯劑的該偏極方向被配置成不在每個圖案化區域異常軸的方向,但在該圖案化阻滯劑之兩個圖案化區域的異常軸之間,且更想要地在較靠近該兩個異常軸中間的方向,用以減少每個該圖案化區域中的反射。 In this case, since the R e between the first and second patterned regions becomes different, a difference occurs between the overall reflectances of each of the patterned regions. Therefore, the brightness is different for each patterned area. Furthermore, errors in the polarization of light can occur due to the difference in reflectivity between each of the patterned regions. Therefore, in the present invention, the polarization direction that has been incident on the patterned retarder is configured not in the direction of the anomalous axis of each patterned region, but in the two patterned regions of the patterned retarder Between the anomalous axes, and more desirably in the direction closer to the middle of the two anomalous axes, to reduce reflections in each of the patterned regions.

如上所述,如果該折射率滿足該等式(1)至(4)中的任何一 個,且入射至該圖案化阻滯劑的該偏極方向在該圖案化阻滯劑之兩個圖案化區域的異常軸之間,減少阻滯劑圖案之間的亮度差並消除雲紋效應是最有效的。 As described above, if the refractive index satisfies any one of the equations (1) to (4) And the polarization direction incident on the patterned retarder is between the abnormal axes of the two patterned regions of the patterned retarder, reducing the brightness difference between the retarder patterns and eliminating the moiré effect It is the most effective.

本發明的圖案化阻滯劑包括單軸的圖案化阻滯劑以及雙軸 的圖案化阻滯劑。該單軸圖案化阻滯劑中該異常折射率以及該平常折射率之間的上述關係可同樣地應用至該雙軸圖案化阻滯劑中最大折射率以及最小折射率之間的關係。 The patterned retarder of the present invention comprises a uniaxial patterned retarder and a biaxial Patterned retarder. The above relationship between the abnormal refractive index and the ordinary refractive index in the uniaxially patterned retarder can be similarly applied to the relationship between the maximum refractive index and the minimum refractive index in the biaxially patterned retarder.

在本發明中,前阻滯(Re)想要在0以及10nm之間。當該前 阻滯多於10nm時,因為已穿過該第一以及該第二圖案化區域的光之間的相差不必要地大於想要的程度,可在顯示器中發生漏光或圖片品質的惡化。 In the present invention, the front retardation (R e ) is intended to be between 0 and 10 nm. When the front retardation is more than 10 nm, light leakage or deterioration of picture quality may occur in the display because the phase difference between the light that has passed through the first and the second patterned regions is unnecessarily larger than desired. .

例如,在三維顯示器的例子中,穿過該圖案化阻滯劑之直線 偏極光的相位分別位移成±λ/4,以被該第一或第二圖案化區域轉變成右旋圓偏極化或左旋圓偏極化。然而,當多於10nm的前阻滯被加至每個被轉變的光時,因為該偏極化被轉變成橢圓偏極化而非圓偏極化,而發生了漏光 或圖片品質惡化。 For example, in the example of a three-dimensional display, a straight line passing through the patterned retarder The phases of the polarized light are respectively shifted by ±λ/4 to be converted into right-handed circular polarization or left-handed circular polarization by the first or second patterned region. However, when a front block of more than 10 nm is applied to each of the converted lights, light leakage occurs because the polarization is converted into elliptical polarization instead of circular polarization. Or the picture quality is deteriorating.

在本發明中,在維持上述折射率範圍的同時,想要使用不具 有前阻滯的黏著層。然而,考慮常使用永久或非永久的黏著劑以及製程,想要使用可造成對該前阻滯以及該圖案化阻滯劑與該偏光鏡之折射率最小影響的永久或非永久的黏著劑。 In the present invention, while maintaining the above refractive index range, it is desirable to use Adhesive layer with a front block. However, considering the use of permanent or non-permanent adhesives and processes, it is desirable to use permanent or non-permanent adhesives that can cause a minimal impact on the front retardation and the retardation of the patterned retarder and the polarizer.

在本發明中,UV硬化的永久黏著劑或UV硬化的非永久黏著 劑可用以作為黏著層。該UV硬化的永久黏著劑或UV硬化的非永久黏著劑常使用於本發明的領域,且不限於任何特定類型。 In the present invention, UV hardened permanent adhesive or UV hardened non-permanent adhesion The agent can be used as an adhesive layer. The UV hardened permanent adhesive or UV hardened non-permanent adhesive is often used in the field of the invention and is not limited to any particular type.

例如,該黏著層可包括選自丙烯酸共聚物、天然橡膠、苯乙 烯-異戊二烯-苯乙烯嵌段共聚物、苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯丁烯-苯乙烯嵌段共聚物、苯乙烯-丁二烯橡膠、聚丁二烯、聚異戊二烯、聚異丁烯、丁基橡膠、氯平橡膠以及矽氧橡膠所組成之群組的其中之一。 For example, the adhesive layer may comprise an acrylic acid copolymer, natural rubber, styrene Alkene-isoprene-styrene block copolymer, styrene-butadiene-styrene block copolymer, styrene-ethylene butylene-styrene block copolymer, styrene-butadiene rubber, One of a group consisting of polybutadiene, polyisoprene, polyisobutylene, butyl rubber, chloroprene rubber, and silicone rubber.

用以形成圖案化阻滯劑的方法在本發明中不受限制,且可使 用任何常使用的方法。該方法的範例是在聚合物薄膜上校直液晶以及使用光阻形成圖案。 The method for forming a patterned retarder is not limited in the present invention and can be Use any method that is commonly used. An example of this method is to align liquid crystals on a polymer film and form a pattern using photoresist.

該方法常如下述進行:藉由在透明基底層上塗層校直溶液而形成校直層、磨光、光阻處理、磨光光阻帶、液晶塗層以及硬化。 The method is often carried out by forming a alignment layer, a buffing, a photoresist treatment, a buffing photoresist strip, a liquid crystal coating, and hardening by coating a solution on a transparent substrate layer.

可使用非雙折射材料或低雙折射材料作為該透明基底層。例如,可使用玻璃、壓克力、或非可延伸的聚碳酸酯,等等。 A non-birefringent material or a low birefringent material may be used as the transparent base layer. For example, glass, acrylic, or non-extensible polycarbonate can be used, and the like.

該校直層用於校直液晶,且常使用的磨光聚合物可用於該校直層。 The straight layer of the school is used to straighten the liquid crystal, and the commonly used polishing polymer can be used for the straight layer.

塗層方法不限於任何特定的方法,且可使用可形成均勻塗層的任何常使用方法。具體而言,可使用旋轉塗佈、線棒塗佈、微凹版塗佈、浸泡塗佈或噴灑塗佈方法。 The coating method is not limited to any particular method, and any commonly used method that can form a uniform coating can be used. Specifically, spin coating, wire bar coating, micro gravure coating, dip coating, or spray coating method can be used.

在乾燥之後,該校直層的厚度想要在800以及200Å之間。當 該厚度少於800Å時,其不能具有足夠的校直調整力量,且當該厚度大於2000Å時,當該校直時,其難以具有塗層的均勻性。 After drying, the thickness of the straight layer is intended to be between 800 and 200 Å. when When the thickness is less than 800 Å, it cannot have sufficient alignment adjustment force, and when the thickness is more than 2000 Å, it is difficult to have uniformity of coating when the alignment is straight.

接下來,藉由磨光在該校直層上形成校直方向。 Next, a straightening direction is formed on the straight layer by polishing.

接下來,在光阻上放上主要薄膜,並以該主要薄膜的黑色部 分作為遮罩而曝露並形成該光阻。然後,剩下相應於該黑色部分之該光阻的一部分。這裡,剩下光阻之間的寬度以及距離根據應用該圖案化層之面板(例如LCD以及PDP)的像素間距而不同。 Next, place the main film on the photoresist and use the black part of the main film. The portion is exposed as a mask and the photoresist is formed. Then, a portion of the photoresist corresponding to the black portion remains. Here, the width and distance between the remaining photoresists differ depending on the pixel pitch of the panel (for example, LCD and PDP) to which the patterned layer is applied.

接下來,使用該剩下光阻作為遮罩而進行磨光。被該光阻保 護之該校直層的一部分維持原來的校直方向,而不被該光阻保護之其他部分的方向被改變成另一個校直方向。在完成該第二次磨光之後,用以作為遮罩的該光阻藉由浸泡在蝕刻溶液中而移除。 Next, the remaining photoresist is used as a mask for polishing. Protected by the light A part of the straight layer of the school maintains the original alignment direction, and is not changed to another alignment direction by the direction of the other part of the photoresist protection. After the second buffing is completed, the photoresist used as a mask is removed by immersion in an etching solution.

接下來,藉由塗層以及硬化液晶而完成該圖案化阻滯劑。 Next, the patterned retarder is completed by coating and hardening the liquid crystal.

積層在該透明基底層上的該圖案化阻滯劑包括具有第一校 直方向的第一硬化液晶層以及具有第二校直方向的第二硬化液晶層。該第一以及第二校直方向是異常軸的方向,所以穿過該第一以及第二圖案化區域的光具有相差。 The patterned retarder laminated on the transparent substrate layer includes having a first school a first hardened liquid crystal layer in a straight direction and a second hardened liquid crystal layer in a second straight direction. The first and second alignment directions are the directions of the anomalous axes, so the light passing through the first and second patterned regions has a phase difference.

根據本發明的該複合偏光板可包括積層在該圖案化阻滯劑 上的透明基底層。該透明基底層保護該圖案化阻滯劑的表面。 The composite polarizing plate according to the present invention may include a layered layer in the patterned retarder Transparent base layer on top. The transparent substrate layer protects the surface of the patterned retarder.

如上所述,當製造該圖案化阻滯劑時,當使用該透明基底層 時,該透明基底層可為用於形成該圖案化阻滯劑的基底薄膜或板,且也可為在該圖案化阻滯劑頂部用於保護該圖案化阻滯劑的保護薄膜。此外,考慮必要的條件,可移除該透明基底層,例如該圖案化阻滯劑的強度,等等。 As described above, when the patterned retarder is fabricated, when the transparent substrate layer is used The transparent substrate layer may be a base film or plate for forming the patterned retarder, and may also be a protective film for protecting the patterned retardant on top of the patterned retarder. Furthermore, the transparent substrate layer, such as the strength of the patterned retarder, can be removed, taking into account the necessary conditions, and the like.

該複合偏光板可額外地包括一或更多個積層在該圖案化阻 滯劑上的功能層,該功能層選自永久黏著層或非永久黏著層、保護層、阻滯層、抗目眩層、抗反射層、防靜電層、以及硬塗層層所組成的群組。 The composite polarizing plate may additionally include one or more laminates in the patterned resistor a functional layer on a retardant selected from the group consisting of a permanent adhesive layer or a non-permanent adhesive layer, a protective layer, a retardation layer, an antiglare layer, an antireflection layer, an antistatic layer, and a hard coat layer .

該永久或非永久黏著層是用於黏著其他的功能層。該保護層 是用於預防該偏光板或該圖案化阻滯劑破裂或損傷的層。該阻滯層是用於額外地控制阻滯。該抗目眩層是具有微粗糙性的層,該微粗糙性藉由噴沙、浮雕過程或噴灑包含顆粒的溶液而形成。該抗反射層是用於預防由於外部光反射所造成之能見度的衰減,且該抗反射層包括藉由沉積或噴濺而形成的金屬氧化物。該防靜電層是用於預防由於靜電所造成的灰塵,且由包括防靜電材料的UV硬化聚合物形成。該硬塗層層是用於預防該偏光板表面的破裂或損傷,且由壓克力或矽氧UV硬化聚合物形成。 The permanent or non-permanent adhesive layer is used to adhere to other functional layers. Protective layer It is a layer for preventing cracking or damage of the polarizing plate or the patterned retarder. This retardation layer is used to additionally control the block. The anti-glare layer is a layer having micro-roughness formed by sandblasting, embossing, or spraying a solution containing particles. The anti-reflection layer is for preventing the attenuation of visibility due to reflection of external light, and the anti-reflection layer includes a metal oxide formed by deposition or sputtering. The antistatic layer is for preventing dust due to static electricity, and is formed of a UV hardening polymer including an antistatic material. The hard coat layer is for preventing cracking or damage of the surface of the polarizing plate, and is formed of an acryl or a UV-curable polymer.

根據本發明包括偏光板以及圖案化阻滯劑的該複合偏光板 可被包括在顯示裝置中。 The composite polarizing plate comprising a polarizing plate and a patterned retarder according to the present invention It can be included in the display device.

能夠顯示三維影像的任何顯示裝置可為上述顯示裝置。例 如,該顯示裝置可包括反射式或穿透反射式液晶顯示器(LCD)、電漿顯示面板(PDP)、有機EL顯示器(OLED),等等。 Any display device capable of displaying a three-dimensional image may be the above display device. example For example, the display device may include a reflective or transflective liquid crystal display (LCD), a plasma display panel (PDP), an organic EL display (OLED), and the like.

根據本發明的該複合偏光板可使用作為先前技術之偏光板以及圖案化阻滯劑的替代物。 The composite polarizing plate according to the present invention can use a polarizing plate as a prior art and a substitute for a patterned retarder.

例如,如第3圖中所示的反射式液晶顯示器可包括背光單元410;將從該背光單元發射出的光轉變成偏極光的低偏光板310;該偏極光所進入的液晶面板200;偵測已穿過該液晶面板之光的資訊的上偏光板110;根據圖案而將已穿過該上偏光板110的光轉變成兩個不同偏極光的圖案化阻滯劑120。 For example, the reflective liquid crystal display as shown in FIG. 3 may include a backlight unit 410; a low polarizing plate 310 that converts light emitted from the backlight unit into polarized light; a liquid crystal panel 200 into which the polarized light enters; The upper polarizing plate 110 that has passed the information of the light of the liquid crystal panel; converts the light that has passed through the upper polarizing plate 110 into two patterned retarders 120 of different polarized lights according to the pattern.

第4圖描繪了第3圖中所示之顯示裝置在最外層進一步包括透明基底層140的範例。 Figure 4 depicts an example in which the display device shown in Figure 3 further includes a transparent substrate layer 140 at the outermost layer.

此外,例如,如第5圖中所示的反射式液晶顯示器可包括背光單元410;將從該背光單元發射出的光轉變成偏極光的下偏光板310;位移該偏極光的相位的阻滯層320;液晶顯示面板200接收訊號,根據所接收的訊號提供資訊至該相移的偏極光;反射已穿過該液晶顯示面板的光的反射層240;偵測已穿過該液晶面板之光的資訊的上偏光板110;根據圖案而將已穿 過該上偏光板110的光轉變成兩個不同偏極光的圖案化阻滯劑120。在此情況中,當維持相同相差的同時,所反射的偏極光穿過該液晶顯示面板。 Further, for example, the reflective liquid crystal display as shown in FIG. 5 may include a backlight unit 410; a lower polarizing plate 310 that converts light emitted from the backlight unit into polarized light; and a retardation of shifting the phase of the polarized light The layer 320 receives the signal, provides information according to the received signal to the phase-shifted polarized light, reflects the reflective layer 240 of the light that has passed through the liquid crystal display panel, and detects the light that has passed through the liquid crystal panel. Information on the upper polarizer 110; will be worn according to the pattern The light passing through the upper polarizing plate 110 is converted into two different patterned polarizing agents 120. In this case, the reflected polarized light passes through the liquid crystal display panel while maintaining the same phase difference.

第6圖描繪第5圖中所示之顯示裝置在最外層進一步包括透明基底層140的範例。 Fig. 6 depicts an example in which the display device shown in Fig. 5 further includes a transparent substrate layer 140 at the outermost layer.

此外,根據本發明的該複合偏光板可應用至第7圖中所示的電漿顯示面板(PDP)或有機EL顯示器(OLED),以及該複合偏光板可在最外層額外地包括透明基底層140。 Further, the composite polarizing plate according to the present invention can be applied to a plasma display panel (PDP) or an organic EL display (OLED) shown in FIG. 7, and the composite polarizing plate can additionally include a transparent base layer on the outermost layer. 140.

在包括根據本發明之該複合偏光板的顯示裝置中實施三維影像的原理與使用傳統偏光板以及圖案化阻滯劑的先前技術相同。 The principle of implementing a three-dimensional image in a display device including the composite polarizing plate according to the present invention is the same as the prior art using a conventional polarizing plate and a patterned retarder.

根據本發明該複合偏光板可應用至三維影像顯示系統。如第9圖中所示,該系統可包括液晶顯示器以及一副偏光眼鏡70。該液晶顯示器包括具有第一影像顯示區域61與第二影像顯示區域62的偏光板60,以及具有第一圖案化區域64與第二圖案化區域65的圖案化阻滯劑63,該第一圖案化區域64轉變已穿過該第一影像顯示區域61之光的偏極化,該第二圖案化區域65轉變已穿過該第二影像顯示區域62之光的偏極化。該副偏光眼鏡包括將已穿過該圖案化阻滯劑之光的偏極化轉變成線性偏極化的第一偏極化區域71以及第二偏極化區域72,以及左鏡片與右鏡片74與75。 The composite polarizing plate can be applied to a three-dimensional image display system according to the present invention. As shown in FIG. 9, the system can include a liquid crystal display and a pair of polarized glasses 70. The liquid crystal display includes a polarizing plate 60 having a first image display area 61 and a second image display area 62, and a patterned retarder 63 having a first patterned area 64 and a second patterned area 65, the first pattern The region 64 transforms the polarization of light that has passed through the first image display region 61, and the second patterned region 65 transforms the polarization of light that has passed through the second image display region 62. The secondary polarized glasses include a first polarized region 71 and a second polarized region 72 that convert polarization of light that has passed through the patterned retarder into linear polarization, and left and right lenses. 74 and 75.

第10圖描繪了使用第9圖中所示之系統而實施三維影像的原理。當穿過偏光板10以及11時,從光源發射出的白光被轉變成線性偏極的光,以及當穿過該液晶顯示器的圖案化阻滯層20以及21時,該線性偏極的光被轉變成圓形偏極的光。該圓形偏極的光允許穿過或被阻滯層30與31以及該副偏光眼鏡的偏光板40與41阻擋。 Figure 10 depicts the principle of implementing a three-dimensional image using the system shown in Figure 9. When passing through the polarizing plates 10 and 11, the white light emitted from the light source is converted into linearly polarized light, and when passing through the patterned retardation layers 20 and 21 of the liquid crystal display, the linearly polarized light is Turned into a circular polarized light. The circularly polarized light is allowed to pass through or be blocked by the retardation layers 30 and 31 and the polarizing plates 40 and 41 of the sub-polarized glasses.

根據下述範例,可了解本發明,該範例僅為示範性且不限制本發明的範圍,本發明範圍是由所附帶的申請專利範圍所定義。 The invention may be understood by the following examples, which are merely exemplary and not limiting the scope of the invention, which is defined by the scope of the appended claims.

範例以及比較性範例 Examples and comparative examples

如第1圖中所示,製造出了包括偏光板110、具有丙烯酸共聚 物的黏著層130以及圖案化阻滯劑120(Zeon,COP)並以此順序堆疊的複合偏光板。該複合偏光板的大小是10cm*10cm,以及該圖案化阻滯劑的異常折射率(ne)以及平常折射率(n0)示於表1至3中。 As shown in Fig. 1, a composite polarizing plate comprising a polarizing plate 110, an adhesive layer 130 having an acrylic copolymer, and a patterned retarder 120 (Zeon, COP) was stacked and stacked in this order. The size of the composite polarizing plate was 10 cm * 10 cm, and the abnormal refractive index (n e ) and the ordinary refractive index (n 0 ) of the patterned retarder are shown in Tables 1 to 3.

表1至3是考慮該圖案化阻滯劑之該異常折射率(ne)以及該平常折射率(n0)而關於該黏著層折射率的反射率。供您參考,在表1中,反射率之間的差異|R0-Re|可視為穿透(亮度)比之間的差異|T0-Te|,因為Re=1-Te,以及R0=1-T0Tables 1 to 3 are reflectances regarding the refractive index of the adhesive layer in consideration of the abnormal refractive index (n e ) of the patterned retarder and the ordinary refractive index (n 0 ). For your reference, in Table 1, the difference between the reflectances |R 0 -R e | can be regarded as the difference between the penetration (brightness) ratios |T 0 -T e |, since R e =1-T e , and R 0 =1-T 0 .

表4至6是包括複合偏光板之液晶顯示器能見度的測試結果,該複合偏光板具有表1至3中所示的性質。該測試由測試LCD能見度中的 專家執行。範例或比較性範例的能見度與在相同的表中的其他的範例或比較性範例相比較。 Tables 4 to 6 are test results of the visibility of the liquid crystal display including the composite polarizing plate having the properties shown in Tables 1 to 3. This test is tested in LCD visibility Expert implementation. The visibility of an example or comparative example is compared to other examples or comparative examples in the same table.

◎:非常好 ○:好 △:改善 X:差 ◎: Very good ○: Good △: Improvement X: Poor

如表4至6中所示,其確認了當本發明黏著層的折射率(N)是在圖案化阻滯劑的平常折射率(n0)以及異常折射率(ne)之間時,雲紋圖案被消除,且能見度測試結果極佳。 As shown in Tables 4 to 6, it was confirmed that when the refractive index (N) of the adhesive layer of the present invention is between the ordinary refractive index (n 0 ) of the patterned retarder and the abnormal refractive index (n e ), The moiré pattern is eliminated and the visibility test results are excellent.

此外,該結果顯示當該黏著層的折射率越接近Ne的值(該平常折射率以及該異常折射率的算術平均數)時,該能見度測試結果變好。尤其是,當該黏著層折射率以及該平常折射率與該異常折射率之算術平均數(Ne)之間的差異小於1%時,可獲得最好的結果。 Furthermore, the results show that when the refractive index of the adhesive layer is closer to N e value (which is usually a refractive index and an arithmetic average of the extraordinary refractive index), the visibility of test results is improved. In particular, the best results are obtained when the refractive index of the adhesive layer and the difference between the ordinary refractive index and the arithmetic mean (Ne) of the abnormal refractive index are less than 1%.

60‧‧‧偏光板 60‧‧‧Polar plate

61‧‧‧第一影像顯示區域 61‧‧‧First image display area

62‧‧‧第二影像顯示區域 62‧‧‧Second image display area

63‧‧‧圖案化阻滯劑 63‧‧‧Phase blockers

64‧‧‧第一圖案化區域 64‧‧‧First patterned area

65‧‧‧第二圖案化區域 65‧‧‧Second patterned area

70‧‧‧偏光眼鏡 70‧‧‧ Polarized glasses

71‧‧‧第一偏極化區域 71‧‧‧First polarization zone

72‧‧‧第二偏極化區域 72‧‧‧Second polarization zone

74‧‧‧左鏡片 74‧‧‧ left lens

75‧‧‧右鏡片 75‧‧‧right lens

Claims (13)

一種複合偏光板,包括一圖案化阻滯膜,該圖案化阻滯膜是藉由一黏著層而積層在一偏光板上,其中該黏著層的一折射率(N)滿足下述等式(1):min(n0,ne)≦N≦max(n0,ne) (1)其中n0代表該圖案化阻滯膜的一平常折射率,ne代表該圖案化阻滯膜的一異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者。 A composite polarizing plate comprising a patterned retardation film laminated on a polarizing plate by an adhesive layer, wherein a refractive index (N) of the adhesive layer satisfies the following equation ( 1): min(n 0 , n e )≦N≦max(n 0 , n e ) (1) wherein n 0 represents a normal refractive index of the patterned retardation film, and n e represents the patterned retardation film An anomalous refractive index, min(n 0 , n e ) represents the smaller of n 0 and n e , and max(n 0 , n e ) represents the larger of n 0 and n e . 如申請專利範圍第1項所述的複合偏光板,其中該折射率(N)滿足下述等式(2):min(n0,ne)+|n0-ne|/3≦N≦max(n0,ne)-|n0-ne|/3 (2)其中n0代表該圖案化阻滯膜的一平常折射率,ne代表該圖案化阻滯膜的一異常折射率,min(n0,ne)代表n0以及ne之間的較小者,以及max(n0,ne)代表n0以及ne之間的較大者。 The composite polarizing plate of claim 1, wherein the refractive index (N) satisfies the following equation (2): min(n 0 , n e )+|n 0 -n e |/3≦N ≦max(n 0 , n e )-|n 0 -n e |/3 (2) wherein n 0 represents a normal refractive index of the patterned retardation film, and n e represents an abnormality of the patterned retardation film The refractive index, min(n 0 , n e ) represents the smaller of n 0 and n e , and max(n 0 , n e ) represents the larger of n 0 and n e . 如申請專利範圍第1項所述的複合偏光板,其中該折射率(N)滿足下述等式(3):0.99Ne≦N≦1.01Ne (3)其中Ne=(n0+ne)/2,n0代表該圖案化阻滯膜的一平常折射率,ne代表該圖案化阻滯膜的一異常折射率。 The composite polarizing plate of claim 1, wherein the refractive index (N) satisfies the following equation (3): 0.99Ne≦N≦1.01Ne (3) wherein Ne=(n 0 +n e ) /2, n 0 represents a normal refractive index of the patterned retardation film, and n e represents an abnormal refractive index of the patterned retardation film. 如申請專利範圍第1項所述的複合偏光板,其中該折射率(N)滿足下述等式(4):0.994Ne≦N≦1.006Ne (4) 其中Ne=(n0+ne)/2,n0代表該圖案化阻滯膜的一平常折射率,ne代表該圖案化阻滯膜的一異常折射率。 The composite polarizing plate according to claim 1, wherein the refractive index (N) satisfies the following equation (4): 0.994 Ne ≦ N ≦ 1.006Ne (4) wherein Ne = (n 0 + n e ) /2, n 0 represents a normal refractive index of the patterned retardation film, and n e represents an abnormal refractive index of the patterned retardation film. 如申請專利範圍第1-4項中任一項所述的複合偏光板,更包括被積層在該圖案化阻滯膜上的一透明基底層。 The composite polarizing plate of any one of claims 1-4, further comprising a transparent substrate layer laminated on the patterned retardation film. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該黏著層是一永久黏著層或一壓敏黏著層。 The composite polarizing plate of any one of claims 1-4, wherein the adhesive layer is a permanent adhesive layer or a pressure sensitive adhesive layer. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該黏著層的一前阻滯(Re)是在0以及10nm之間。 The composite polarizing plate of any one of claims 1-4, wherein a pre-blocking (R e ) of the adhesive layer is between 0 and 10 nm. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該黏著層包括一UV硬化的永久黏著膜或一UV硬化的壓敏黏著膜。 The composite polarizing plate of any one of claims 1-4, wherein the adhesive layer comprises a UV-cured permanent adhesive film or a UV-cured pressure-sensitive adhesive film. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該黏著層包括選自丙烯酸共聚物、天然橡膠、苯乙烯-異戊二烯-苯乙烯嵌段共聚物、苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯丁烯-苯乙烯嵌段共聚物、苯乙烯-丁二烯橡膠、聚丁二烯、聚異戊二烯、聚異丁烯、丁基橡膠、氯平橡膠,以及矽氧橡膠所組成的群組的至少其中之一。 The composite polarizing plate according to any one of claims 1 to 4, wherein the adhesive layer comprises an acrylic copolymer, a natural rubber, a styrene-isoprene-styrene block copolymer, and a benzene. Ethylene-butadiene-styrene block copolymer, styrene-ethylene butylene-styrene block copolymer, styrene-butadiene rubber, polybutadiene, polyisoprene, polyisobutylene, butyl At least one of a group consisting of a base rubber, a chlorine rubber, and a silicone rubber. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該圖案化阻滯膜的一個圖案化區域的一異常軸的一方向不同於該圖案化阻滯膜的另一個圖案化區域的一異常軸的一方向。 The composite polarizing plate according to any one of claims 1 to 4, wherein a direction of an abnormal axis of one patterned region of the patterned retardation film is different from another of the patterned retardation film A direction of an anomalous axis of the patterned region. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中已進入該圖案化阻滯膜的一光的一偏極方向是在該圖案化阻滯膜兩個圖案化區域的異常軸的方向之間。 The composite polarizing plate according to any one of claims 1 to 4, wherein a polarization direction of a light that has entered the patterned retardation film is in two patterned regions of the patterned retardation film. The direction of the anomalous axis. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中一或更多的功 能層被積層在該圖案化阻滯膜上,該功能層選自永久黏著層或壓敏黏著層、保護層、阻滯層、抗目眩層、抗反射層、防靜電層以及硬塗層所組成的群組。 The composite polarizing plate according to any one of claims 1-4, wherein one or more of the work The energy layer is laminated on the patterned retardation film, and the functional layer is selected from the group consisting of a permanent adhesive layer or a pressure sensitive adhesive layer, a protective layer, a retardation layer, an antiglare layer, an antireflection layer, an antistatic layer, and a hard coat layer. The group consisting of. 如申請專利範圍第1-4項中任一項所述的複合偏光板,其中該偏光板是包括一偏光鏡的一積層結構,以及該功能薄膜中的至少其中之一選自被積層在該偏光鏡一側或兩側的一偏光鏡保護薄膜以及一阻滯薄膜所組成的群組。 The composite polarizing plate according to any one of claims 1 to 4, wherein the polarizing plate is a laminated structure including a polarizing mirror, and at least one of the functional films is selected from the layered layer. A group of polarizer protective films and a retardation film on one or both sides of the polarizer.
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