TWI541385B - Manufacturing method of anode for oxygen generation - Google Patents

Description

Method for producing oxygen generating anode

The present invention relates to an oxygen generating anode used in various industrial electrolysis and a method for producing the same, and more particularly to an industrial production of electrolytic copper foil such as electrolytic copper foil, power supply in aluminum liquid, continuous electrogalvanizing steel sheet manufacturing, metal taking, and the like. An anode for oxygen generation for high load resistance having excellent durability under high-load electrolysis conditions, and a method for producing the same, used in electrolysis.

In industrial electrolysis such as electrolytic copper foil, aluminum liquid supply, continuous electrogalvanized steel sheet, metal take-up, etc., since the anode is accompanied by oxygen generation, the anode is mostly coated on the metal titanium substrate and used as an electrode catalyst. Produces resistant cerium oxide to oxygen. Generally, such industrial electrolysis, which is accompanied by oxygen generation at the anode, is carried out in accordance with a constant current in terms of production efficiency, energy saving, and the like. It is set based on the current density taken from the metal industry and the like is mainly used in a number A / dm ^2, the electrolytic copper foil to a maximum of 100A / in the range of dm ^2.

However, in recent years, in order to improve the quality of products and to impart special properties, it is also common to perform electrolysis at a current density of 300 A/dm ² to 700 A/dm ² or higher. Such a high current is considered not to flow through all the anodes installed in the industrial electrolysis apparatus, but to the special properties of the products obtained by electrolysis, and is set as an auxiliary anode in a specific place under high-load electrolysis conditions.

Under such high current density electrolysis, since the load on the electrode catalyst layer is increased and current concentration is likely to occur, the consumption of the electrode catalyst layer is accelerated. also, In order to stabilize the product, organic substances and impurity elements are added, which causes various electrochemical reactions and chemical reactions, resulting in an increase in the concentration of hydrogen ions (pH lowering) derived from the oxygen generation reaction, resulting in faster consumption of the electrode catalyst. .

To solve this situation, increasing the surface area of the electrode catalyst layer and reducing the actual current load is considered to be one of the solution strategies. For example, by replacing a conventional plate substrate, a substrate such as a mesh or a punched metal plate is used instead, and physical increase in surface area is also a solution strategy. However, if such substrates are used, there is a loss of a derivative cost due to excessive processing costs. Moreover, by actually increasing the surface area of the substrate, the actual current density is lowered, but the current is not concentrated on the electrode catalyst layer, and the effect on the catalyst consumption is only slightly reduced.

Furthermore, the electrode catalyst layer is repeatedly coated and calcined to form a thermal decomposition method. If simple thinking is made, it is assumed that the amount of ruthenium coating can be increased every time to form a soft catalyst layer, and only by this method is used. The effective surface area of the catalyst layer of the electrode is only slightly increased, and it has not been clearly found that the catalyst layer consumption and the durability improvement effect under high load conditions are suppressed.

Such an electrode for electrolysis requires an electrode having a low oxygen generating potential and a long life. Conventionally, such an electrode is used as an insoluble electrode coated on a conductive metal substrate such as titanium and coated with a catalyst layer containing a noble metal or a noble metal oxide. For example, Patent Document 1 discloses that a catalyst layer containing cerium oxide and a valve metal oxide is heated and calcined in an oxidizing atmosphere of 650 ° C to 850 ° C on a conductive metal substrate such as titanium to form a valve metal oxide. A portion of the insoluble electrode of the crystallized catalyst layer. However, because the electrode is above 650 ° C When calcination is performed at a high temperature, interfacial corrosion of a metal substrate such as titanium occurs, and a metal substrate such as titanium becomes a poor electric conductor, causing an increase in oxygen overvoltage, making it impossible to use it as an electrode. Further, the particle size of the cerium oxide in the catalyst layer is increased, and as a result, the effective surface area of the catalyst layer is small and the catalyst activity is poor.

Further, Patent Document 2 discloses that a catalyst layer in which an amorphous yttrium oxide and an amorphous yttrium oxide are mixed is provided on a conductive metal substrate such as titanium, and an anode for copper plating and copper foil production is used. However, since the electrode is characterized by amorphous cerium oxide, the electrode durability is insufficient. When amorphous yttrium oxide is formed, the reason why the corrosion resistance is lowered is that the amorphous cerium oxide is in an amorphous state, and the bond between cerium and oxygen is unstable compared to the crystalline cerium oxide.

Further, Patent Document 3 discloses that a double-layered catalytic layer composed of a crystalline lower layer of cerium oxide and an upper layer composed of amorphous cerium oxide is coated in order to suppress the consumption of the catalyst layer and improve the durability of the electrode. The electrode. However, in the electrode disclosed in Patent Document 3, since the upper layer of the catalyst layer is composed of amorphous ruthenium oxide, the electrode durability is insufficient. Further, the crystalline cerium oxide is only present in the lower layer, and the entire catalyst layer is not uniformly distributed, resulting in insufficient electrode durability.

Further, Patent Document 4 discloses that zinc oxide is provided by a catalyst layer in which a mixed layer of crystalline cerium oxide and amorphous cerium oxide is contained, in which an amorphous cerium oxide is contained on a conductive metal substrate such as titanium. In the case of an anode, it is disclosed in Patent Document 5 that it is necessary to contain an amorphous yttrium oxide on a conductive metal substrate such as titanium, and a cobalt electrolysis layer in which a cerium oxide crystal and a cerium oxide amorphous mixed catalyst layer are provided is used. anode. However, because any of the electrodes are large The amount of amorphous cerium oxide is an essential component, and thus it is considered that the electrode durability is insufficient.

In order to solve these problems, the inventors of the present invention have mainly aimed at reducing the overvoltage of oxygen generation, and developed that (1) formation of low temperature calcination (370 ° C~) when the amount of ruthenium coating per one time is 2 g/m ² or less 400 ° C) + high temperature post-baking (520 ° C ~ 600 ° C) formed by the formation of crystalline cerium oxide and amorphous cerium oxide mixed catalyst layer calcination method, and (2) only contains high temperature calcination (410 ° C ~ 450 °C) + high temperature post-baking (520 ° C ~ 560 ° C) formed a slightly complete crystalline cerium oxide catalyst layer calcination method, together with this application filed two patent applications in the same day.

According to the two inventions, in the electrolysis conditions of a current density of 100 A/dm ² or less, when the amount of ruthenium coating per one time is 2 g/m ² or less, the lead is less likely to adhere and the catalyst layer is increased. The effective area is achieved to improve durability and reduce oxygen generation overvoltage.

However, in recent years, for the sake of quality improvement of the article, and to impart special properties, and according to ^{300A / dm 2 ~ 700A / dm} 2 or higher current density electrolysis purposes is also the case when there is common. Such a high current is considered not to flow through all the anodes installed in the industrial electrolysis apparatus, but to the special properties of the products obtained by electrolysis, and is set as an auxiliary anode in a specific place under high-load electrolysis conditions.

Under such high current density electrolysis, since the load on the electrode catalyst layer is increased and current concentration is likely to occur, the consumption of the electrode catalyst layer becomes fast, and organic matter and impurities are added for stabilization of the product. The element, thus causing various electrochemical reactions and chemical reactions, leads to an increase in the concentration of hydrogen ions (pH lowering) derived from the reaction of oxygen, resulting in more consumption of the electrode catalyst. In view of the above-mentioned two patent application inventions proposed by the inventors of the present invention, it is not possible to sufficiently achieve an increase in durability and a reduction in oxygen generation overvoltage by increasing the effective area of the catalyst layer.

[Previous Technical Literature] [Patent Literature]

Patent Document 1: Japanese Patent Laid-Open Publication No. 2002-275697 (Patent No. 3654204)

Patent Document 2: Japanese Patent Laid-Open Publication No. 2004-238697 (Patent No. 3914162)

Patent Document 3: Japanese Patent Laid-Open Publication No. 2007-146215

Patent Document 4: Japanese Patent Laid-Open Publication No. 2009-293117 (Patent No. 4516617)

Patent Document 5: Japanese Patent Laid-Open Publication No. 2010-1556 (Patent No. 4516618)

In order to solve the above problems, the present invention provides: under high load conditions, by increasing the effective surface area of the electrode catalyst layer, improving the current distribution of the electrode catalyst layer, suppressing electrode catalyst consumption, and improving electrode catalyst durability. An anode for high-resistance oxygen generation which has excellent durability under high-load electrolysis conditions and a method for producing the same.

In order to achieve the above object, the first aspect of the present invention provides an anode for oxygen generation, comprising: a conductive metal substrate; and a catalyst layer formed on the conductive metal substrate and containing ruthenium oxide; the catalyst layer per one volume of iridium coated 2g / m ² or more, calcined at higher temperature heating purposes region 430 ℃ ~ 480 ℃ in to form a catalyst layer containing amorphous iridium oxide, the amorphous subsequently comprising The above-mentioned catalyst layer of the cerium oxide is post-baked in a higher temperature region of 520 ° C to 600 ° C, and the cerium oxide in the catalyst layer is slightly crystallized.

The second object of the present invention is to provide an anode for oxygen generation, comprising: a conductive metal substrate; and a catalyst layer containing ruthenium oxide formed on the conductive metal substrate; The amount of ruthenium coating per one time of the catalyst layer was 2 g/m ² or more, and the degree of crystallization of cerium oxide in the catalyst layer after the post-baking was set to 80% or more.

The third aspect of the present invention provides an anode for oxygen generation, comprising: a conductive metal substrate; and a catalyst layer containing ruthenium oxide formed on the conductive metal substrate; The amount of ruthenium coating per one time of the catalyst layer is 2 g/m ² or more, and the oxidized twin crystal grain size in the catalyst layer is set to 9.0 nm or less.

According to a fourth aspect of the present invention, in an object of the present invention, there is provided an anode for oxygen generation comprising: a conductive metal substrate; and a catalyst layer formed on the conductive metal substrate and containing ruthenium oxide; Before forming the catalyst layer, it is convenient to use arc ion plating on the conductive metal substrate Hereinafter, the "AIP" method is used to form an AIP undercoat layer containing bismuth and titanium components.

According to a fifth aspect of the present invention, in order to achieve the above object, a method for producing an anode for generating oxygen is provided on a surface of a conductive metal substrate, and the amount of ruthenium coating per one time of the catalyst layer is set to 2 g. /m ² or more, and using a calcination in a relatively high temperature region of 430 ° C to 480 ° C to form a catalyst layer containing amorphous cerium oxide, and then the catalyst layer containing amorphous cerium oxide is 520 ° C Post-baking is performed in a higher temperature region of ~600 ° C, and the cerium oxide in the catalyst layer is slightly crystallized.

According to a sixth aspect of the present invention, in order to achieve the above object, a method for producing an anode for generating oxygen is provided on a surface of a conductive metal substrate, and the amount of coating of the catalyst layer per one time is set to 2 g. /m ² or more, and using a heating zone calcined in a relatively high temperature region of 430 ° C to 480 ° C to form a catalyst layer containing amorphous cerium oxide, and then the catalyst layer containing amorphous cerium oxide is 520 The post-baking is performed in a higher temperature region of °C to 600 °C, and the degree of crystallization of cerium oxide in the catalyst layer is more than 80%.

According to a seventh aspect of the present invention, in a method for producing an anode for oxygen generation, which is to achieve the above object, the amount of ruthenium coating per one time of the catalyst layer is set to 2 g/m ² or more, and 430 is used. Heating and calcining in a relatively high temperature range of °C~480°C to form a catalyst layer containing amorphous cerium oxide, and then performing the catalyst layer containing amorphous cerium oxide at a higher temperature region of 520 ° C to 600 ° C After baking, the cerium oxide crystal grain size in the catalyst layer is 9.0 nm or less.

In order to achieve the above object, a method for producing an anode for oxygen generation according to the present invention includes: a conductive metal substrate; and a catalyst layer containing ruthenium oxide formed on the conductive metal substrate A method for producing an anode for oxygen generation; and forming an AIP undercoat layer containing a bismuth and titanium component by the AIP method on the conductive metal substrate before forming the catalyst layer.

In the present invention, in the formation of an electrode catalyst layer containing ruthenium oxide, the amount of ruthenium coating per one time of the catalyst layer is set to 2 g/m ² or more, instead of 500 ° C or more, which is based on the complete precipitation temperature of cerium oxide crystals. The calcination is repeated, and the calcination is carried out according to the two stages. First, the calcination is carried out in a relatively high temperature region of 430 ° C to 480 ° C to form a catalyst layer containing amorphous cerium oxide, and then, at a higher temperature of 520 ° C to 600 ° C. The area is post-baking, and the particle size of the cerium oxide in the electrode catalyst layer is suppressed to be small, preferably the crystal grain size is below 9.0 nm, and most of the cerium oxide is crystallized, preferably crystallization. The crystallization of more than 80% of the degree of crystallization can suppress the growth of the crystal grain size of the cerium oxide and increase the effective surface area of the catalyst layer. Therefore, according to the present invention, it is possible to suppress the growth of the crystal grain size of cerium oxide. The reason for this is considered to be calcination in two stages, because the coating and calcination are repeatedly carried out in a relatively high temperature region of 430 ° C to 480 ° C, so that even after The post-baking is carried out in a higher temperature region of 520 ° C to 600 ° C, and the crystal grain size does not become larger than a certain degree in the case where the crystal grain size is subjected to high-temperature calcination from the beginning as in the conventional method. Accordingly, the crystal grain size growth of cerium oxide is suppressed, and the smaller the crystal grain size, the more the effective surface area of the catalyst layer is increased, thereby reducing the oxygen generation overvoltage of the electrode, promoting oxygen generation, and suppressing lead. A reaction in which PbO ₂ is formed in ions. Therefore, it is possible to prevent the adhesion of PbO _{2 to} the electrode.

Further, according to the present invention, by increasing the effective surface area of the catalyst layer, the current distribution is dispersed, and current concentration can be suppressed, the consumption of the catalyst layer due to electrolysis can be suppressed, and the durability of the electrode can be improved.

Further, according to the present invention, by setting the amount of ruthenium coating per one time of the catalyst layer to 2 g/m ² or more, the quality of the product can be improved and special properties can be imparted, so that even at 300 A/dm ² to 700 A / dm ² current density at or above the electrolysis purposes, or for the time obtained by electrolysis products impart special properties, becomes a specific place in the high load condition as auxiliary anode electrolysis provided, can lessen the electrode catalyst layer The load can prevent current concentration and suppress the consumption of the electrode catalyst layer.

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. In the present invention, in order to suppress the adhesion reaction of lead oxide on the surface of the electrode, it has been found that increasing the effective surface area of the electrode catalyst layer can reduce the overvoltage of oxygen generation, thereby promoting oxygen generation and suppressing adhesion of lead oxide. reaction. Further, in the present invention, at the same time, the durability of the electrode can be improved, and it is considered that the cerium oxide of the catalyst layer must be mainly crystalline, and the present invention has been completed through repeated experiments.

The invention performs calcination according to two stages, firstly calcining to form a catalyst layer containing amorphous IrO _{2 in} a relatively high temperature region of 430 ° C to 480 ° C, and then performing post-baking at a higher temperature region according to 520 ° C to 600 ° C, and The cerium oxide of the catalyst layer is slightly crystallized.

According to experiments by the inventors, it has been found that although the catalyst layer containing amorphous cerium oxide can greatly increase the effective surface area, the consumption of amorphous cerium oxide due to electrolysis is relatively fast, and the durability is relatively lowered. That is, it is considered that if the cerium oxide of the catalyst layer is not crystallized, the durability of the electrode cannot be improved. Therefore, the object of the present invention is to increase the effective surface area of the electrode catalyst layer and reduce the overvoltage of the electrode. The present invention can control the oxidation of the catalyst layer by performing two-stage calcination of high temperature calcination + high temperature post-baking. The twin crystal grain size can precipitate smaller cerium oxide crystals than the conventional ones, and the effective surface area of the electrode catalyst layer can be increased compared with the conventional ones, thereby reducing the overvoltage.

In the present invention, the surface of the conductive metal substrate is heated and calcined in a relatively high temperature region of 430 ° C to 480 ° C to form a catalyst layer containing amorphous cerium oxide, and then the amorphous cerium oxide is further formed. The catalyst layer is post-baked in a higher temperature region at 520 ° C to 600 ° C, and the cerium oxide of the catalyst layer is slightly completely crystallized.

By setting the amount of the cerium oxide catalyst layer of the present invention to 2 g/m ² or more per liter, the quality of the product can be improved and the special properties can be imparted, so that even at 300 A/dm ² to 700 A/dm ² or When the above current density is subjected to electrolysis, or special properties are imparted to the product obtained by electrolysis, and the auxiliary anode is disposed at a specific place under high-load electrolysis conditions, the load on the electrode catalyst layer can be alleviated, and It can prevent current concentration and suppress electrode catalyst layer consumption.

Furthermore, according to the present invention, the calcination temperature in the higher temperature region is 430 ° C to 480 ° C, and the post-baking temperature in the higher temperature region is in the range of 520 ° C to 600 ° C according to the crystallization of yttrium oxide formed in the catalyst layer. The particle size and the degree of crystallization can be obtained, and a catalyst layer having a low oxygen overvoltage and excellent corrosion resistance can be formed in accordance with the above temperature range.

In the present invention, the particle size of the cerium oxide in the electrode catalyst layer is suppressed to be small, and it is preferable to set the crystal grain size to 9.0 nm or less, and most of the cerium oxide is crystallized, preferably depending on the crystallization. Crystallization is carried out at a degree of 80% or more, whereby the crystal grain size growth of cerium oxide can be suppressed, and the effective surface area of the catalyst layer can be increased.

Further, when an AIP undercoat layer containing a bismuth and a titanium component is provided on the conductive metal substrate before the formation of the catalyst layer, interfacial corrosion of the metal substrate can be further prevented.

Further, instead of the AIP undercoat layer, an undercoat layer composed of a TiTaO _x oxide layer may be formed instead.

The titanium substrate was coated with AIP, and an aqueous solution of IrCl ₃ /Ta ₂ Cl ₅ was used as a coating liquid, and applied at a rate of 3 g-Ir/m ² per one time, and then subjected to partial crystallization at a temperature of IrO ₂ . Calcination (430 ~ 480 ° C), so that the formation of a catalyst layer. The coating/calcination step was repeated until the necessary catalyst loading amount was reached, and then post-baking was performed at a higher temperature (520 ° C to 600 ° C) for 1 hour to prepare an electrode sample. The catalyst layer IrO ₂ crystallinity, oxygen generation overvoltage, electrode electrostatic capacitance, etc., and sulfuric acid were measured by XRD. Evaluation of gelatin electrolysis and lead adhesion test.

As a result, although most of the IrO ₂ formed in the catalyst layer is crystalline, the crystal grain size becomes small, and the effective surface area of the electrode can be increased. The accelerated electrolytic life evaluation was carried out, and as described later, the sulfuric acid electrolytic life was about 1.4 times as long as the conventional one, and the gelatin electrolytic life was about 1.5 times as long as the conventional one, and the durability improvement effect was confirmed.

Hereinafter, the experimental conditions and methods of the present invention will be described. In order to investigate the formation temperature of amorphous yttrium oxide and the post-baking temperature range after crystallization, the samples shown in Table 1 were prepared, and X-ray diffraction analysis, cyclic voltammetry, and oxygen generation overvoltage were measured. .

The preparation method of the sample is as follows.

The surface of the JIS I titanium plate was subjected to a dry blasting treatment using an iron mesh (G120 size), and then subjected to a pickling treatment in a boiling concentrated aqueous hydrochloric acid solution for 10 minutes to carry out a washing treatment of the electrode metal substrate. The cleaned electrode metal substrate is attached to an arc ion plating apparatus using a Ti-Ta alloy target in an evaporation source, and a surface of the electrode metal substrate is coated with a titanium alloy undercoat layer. The coating conditions are shown in Table 1.

Next, the above-mentioned coated and treated metal substrate was subjected to heat treatment at 530 ° C for 180 minutes in an air circulating electric furnace.

Next, antimony tetrachloride and antimony pentachloride are dissolved in concentrated hydrochloric acid to form a coating liquid, which is applied onto the coated metal substrate, dried, and then subjected to an air circulating electric furnace according to the temperature shown in Table 2. After 15 minutes of thermal decomposition coating, an electrode catalyst layer composed of a mixed oxide of cerium oxide and cerium oxide was formed. The amount of the coating solution is set based coating thickness per one coating solution, in terms of iridium metal by substantially 3.0g / m ² state, repeating the operation of coating and firing count 9, it is obtained by iridium The electrode catalyst layer of about 27.0 g/m ^{2 was} converted into metal.

Next, the sample coated with the catalyst layer was baked in an air circulating electric furnace at a temperature shown in Table 2 for 1 hour, and an electrode for electrolysis was obtained. Further, for comparison, samples were prepared without post-baking.

The calcination temperature and post-baking temperature list of each sample are shown in Table 2.

Evaluation of experimental projects (1) Determination of crystallinity and crystal grain size

The catalyst layer in accordance with the measured X-ray diffraction method and IrO ₂ crystalline grain size. The degree of crystallization is estimated from the diffraction peak intensity.

(2) Electrostatic capacitance of the electrode Cyclic voltammetry

Electrolyte: 150g/LH ₂ SO ₄ aq.

Electrolysis temperature: 60 ° C

Electrolytic area: 10 × 10mm ²

Auxiliary electrode: Zr plate (20mm × 70mm)

Reference electrode: mercury sulphide electrode (SSE)

(3) Determination of oxygen overvoltage

Current interrupt method

Electrolyte: 150g/LH ₂ SO ₄ aq.

Electrolysis temperature: 60 ° C

Electrolytic area: 10 × 10mm ²

Auxiliary electrode: Zr plate (20mm × 70mm)

Reference electrode: mercury sulphide electrode (SSE)

The change in crystallinity of IrO ₂ caused by the calcination temperature and the post-baking temperature is as follows.

The crystallization degree is estimated by setting the intensity of the crystal diffraction peak (θ=28°) of the conventional material to 100, and the ratio of the intensity of the same crystal diffraction peak (θ=28°) of each sample to the intensity of the conventional material. Set to crystallinity. The results are shown in Table 2. Further, a graph made based on the data relating to the degree of crystallization shown in Table 2 is shown in Fig. 1.

It is known from Table 2 and FIG. 1 that the embodiment of the invention (430 ° C ~ 480 ° C higher temperature Samples 2~4 and 6~8 of the high-temperature calcination in the region + post-baking in the higher temperature region of 520 ° C ~ 600 ° C, after crystallization, the crystallization degree of cerium oxide is more than 80%. On the other hand, the electrode catalyst layer (sample 1) was produced by calcination at 430 ° C without performing post-baking, and no clear peak of cerium oxide was observed, and it was confirmed that the catalyst layer of the sample was formed of amorphous cerium oxide. . The electrode catalyst layer (sample 5) prepared by calcination at 480 ° C without a post-baking was 72% crystallinity, and a large amount of amorphous cerium oxide remained. Further, the sample 9 belonging to the conventional product was completely crystallized, and the degree of crystallization was 100%, but the crystal grain size was a large value of 9.1 nm. Therefore, the static capacitance was a low value of 7.6, and the effective surface area was small.

That is, according to the change in the degree of crystallization caused by the high-temperature post-baking, after calcination at 430 ° C, and then baking at a higher temperature, the sharp peak of IrO ₂ belonging to the electrode catalyst layer can be found, and it is known that after using the high temperature baking, the amorphous IrO ₂ catalyst layer is converted to a crystalline mass. Further, it was found that the peak intensity was the same as that of the conventional one regardless of any baking temperature, and no amorphous IrO ₂ remained. On the other hand, it is known that the 480 ° C calcined product is baked at a higher temperature to increase the degree of crystallization. However, it is known that after post-baking at 520 ° C and 560 ° C, a small amount of amorphous IrO ₂ remains. On the other hand, the degree of crystallization of IrO ₂ after baking at 600 ° C was substantially the same as that of the conventional one, and it was found that it was completely crystallized.

Next, the calculation of the crystal grain size was carried out by X-ray diffraction analysis. The results are shown in Table 2. Further, a pattern produced based on the correlation data of the crystal grain size shown in Table 2 is shown in Fig. 2.

Since the amorphous IrO ₂ was formed by calcination at 430 ° C without performing post-baking, the crystal grain size was set to "0". If it is baked after the application, the amorphous IrO ₂ is crystallized, and it is found that the crystal grain size of the crystal is smaller than that of the conventional one. Moreover, there is almost no dependence between the post-baking temperature and the IrO ₂ crystal grain size.

On the other hand, it was found that the calcined product of 480 ° C which was baked after the execution was not related to the post-baking temperature, and the crystal grain size formed was smaller than that of the conventional one. That is, by post-baking, the degree of crystallization of IrO _{2 in the} catalyst layer formed by low-temperature calcination increases, but the increase in the grain size of IrO ₂ is suppressed.

2 and 4 and 6 to 8 of the examples of the present invention (high temperature calcination in a relatively high temperature region at 430 ° C to 480 ° C + post-baking in a higher temperature region at 520 ° C to 600 ° C), as shown in Table 2 and FIG. The cerium oxide crystal grain size after post-baking is 9.0 nm or less. On the other hand, the electrode catalyst layer (sample 1) was produced by calcination at 430 ° C without performing post-baking, and no clear peak of cerium oxide was observed, and it was confirmed that the catalyst layer of the sample was formed of amorphous cerium oxide. . The electrode catalyst layer (sample 5) prepared by calcination at 480 ° C was not subjected to post-baking, and the crystal grain size was 9.3 nm. Further, in the sample 9 belonging to the conventional material, the crystal grain size of cerium oxide was 9.1 nm which was large.

Next, the high-temperature calcination in a relatively high temperature region of 430 ° C to 480 ° C + a higher temperature region of 520 ° C to 600 ° C is measured, and the effective surface area of the electrode catalyst layer is changed.

The electrostatic capacitance of the electrode calculated by cyclic voltammetry is shown in Table 2. The electrostatic capacitance of the electrode is proportional to the effective surface area of the electrode, which means that if the electrostatic capacitance is increased, The effective surface area is also large. According to the data of Table 2, the relationship between the calcination conditions of the catalyst layer and the electrostatic capacitance is shown in FIG.

2 and 4 and 6 to 8 of the examples of the present invention (high temperature calcination in a relatively high temperature region of 430 ° C to 480 ° C + post-baking in a higher temperature region at 520 ° C to 600 ° C), as shown in Table 2 and FIG. The electrostatic capacitance of the electrode is as high as 11.6 or more. On the other hand, IrO ₂ (Sample 1) in which the catalyst layer was formed by calcination at 430 ° C without performing post-baking was the largest effective surface area (static capacitance) because it was amorphous. It is known that after baking after the implementation, since IrO ₂ is crystallized, the effective surface area (static capacitance) is reduced, but higher than that of the conventional one. This phenomenon is considered to be caused by the crystal grain size formed being smaller than that of the conventional one. Further, it has been found that the increase in the post-baking temperature tends to reduce the effective surface area (static capacitance) of the electrode.

Furthermore, when post-baking was performed after calcination at 480 ° C (samples 5 to 8), the effective surface area (static capacitance) was approximately the same regardless of the post-baking temperature, but if compared with the conventional one, I learned that it increased by 2 times. This phenomenon is considered to be caused by the fact that the IrO ₂ crystal grain size is smaller than that of the conventional one and the amorphous IrO ₂ remains in a small amount. Also, even if the post-baking temperature is raised, the effective surface area (static capacitance) of the electrode does not change.

The oxygen generation overvoltage (V vs. SSE @100A/dm ² ) of each sample was measured. The results are shown in Table 2. Moreover, the dependence between the calcination conditions and the oxygen generation overvoltage is as shown in FIG. The pattern change of Fig. 4 tends to be opposite to that of Fig. 3, and there is a tendency for the oxygen generation overvoltage of the sample to decrease as the effective surface area of the electrode increases. This phenomenon is thought to be caused by an increase in the effective surface area of the electrode, which can cause the current distribution to be dispersed and reduce the actual current.

The 430 ° C calcined product having the largest effective surface area but not post-baking exhibited the lowest oxygen overvoltage, but the reduction in the effective surface area due to post-baking caused the oxygen overvoltage to rise. The dependence between the oxygen overvoltage of the 480 ° C calcined product and the post-baking temperature was found to have the same tendency. Further, it was found that the oxygen overvoltage of the samples was higher than that of the conventional materials. This phenomenon is considered to be caused by an increase in surface area compared with conventional ones.

It can be seen from Table 2 and FIG. 4 that the examples of the present invention (high temperature calcination in a relatively high temperature region of 430 ° C to 480 ° C + after baking in a higher temperature region of 520 ° C to 600 ° C) are sample 2~4 and 6~ 8, oxygen generation overvoltage is reduced.

As described above, the electrode prepared by the high-temperature calcination in the relatively high temperature region of 430 ° C to 480 ° C + the calcination method after baking in the higher temperature region of 520 ° C to 600 ° C is compared with the IrO of the catalyst layer under the conventional material. _{2 The} crystal is small, which increases the surface area of the electrode. These samples can disperse the current distribution under high load conditions and reduce the actual current load. Therefore, the catalyst consumption is greatly suppressed, and it is considered that durability can be expected to be improved.

[Examples]

Next, the embodiments of the present invention will be described, but the present invention is not limited to the above.

<Example 1>

The surface of the JIS I titanium plate was subjected to dry blasting using an iron mesh (G120 size), followed by a 10-minute pickling in a boiling concentrated aqueous hydrochloric acid solution. The treatment of the electrode metal substrate is performed. The washed electrode metal substrate was attached to an arc ion plating apparatus using a Ti-Ta alloy target in an evaporation source, and an AIP undercoat layer containing ruthenium and titanium was applied to the surface of the electrode metal substrate. The coating conditions are shown in Table 1.

Next, the above-mentioned coated and treated metal substrate was subjected to heat treatment at 530 ° C for 180 minutes in an air circulating electric furnace.

Next, antimony tetrachloride and antimony pentachloride were dissolved in concentrated hydrochloric acid to form a coating liquid, which was applied onto the coated metal substrate, dried, and then subjected to 480 ° C for 15 minutes in an air circulating electric furnace. The thermal decomposition coating forms an electrode catalyst layer composed of a mixed oxide of cerium oxide and cerium oxide. An amount of coating solution per one line is set to a coating thickness of the coating solution, in terms of iridium metal by substantially 3.0g / m ² state, repeating the operation of coating and firing count 9, it is obtained by iridium genus An electrode catalyst layer of about 27.0 g/m ^{2 was} converted.

X-ray diffraction was applied to the sample. As a result, although a clear peak of cerium oxide belonging to the electrode catalyst layer was found, the peak intensity was lower than that of Comparative Example 1, and it was found that the crystalline IrO ₂ was partially precipitated.

Next, the sample coated with the above-mentioned catalyst layer was further subjected to post-baking at 520 ° C for 1 hour in an air circulating electric furnace to prepare an electrode for electrolysis.

X-ray diffraction analysis was performed on the post-baked sample. As a result, it was found that the IrO ₂ sharp peak belonging to the electrode catalyst layer was higher than the post-baking, but still lower than that of Comparative Example 1. From this, it is understood that the degree of crystallization of the catalyst layer formed by the coating step of the low-temperature calcination increases before the baking at a high temperature, but the amorphous IrO ₂ partially remains.

For the electrode for electrolysis produced in accordance therewith, two kinds of life evaluation tests (a pure sulfuric acid solution and a sulfuric acid solution with added gelatin addition) shown in Table 3 were carried out. The results are shown in Table 4. Compared with Comparative Example 1 (conventional material) of Table 4, the sulfuric acid electrolysis life was 1.7 times and the gelatin electrolysis life was 1.1 times, and thus it was found that the durability against both sulfuric acid or organic additives was improved.

<Example 2>

The evaluation electrode was produced in the same manner as in Example 1 except that the post-baking temperature in the air circulation type electric furnace was set to 560 ° C, and the same electrolysis evaluation was performed.

After the post-baking, X-ray diffraction analysis was carried out, and it was found that the IrO ₂ crystallinity and crystal grain size of the catalyst layer were the same as in Example 1.

As shown in Table 4, compared with Comparative Example 1 (conventional material) of Table 4, the electrolysis life of sulfuric acid was 1.5 times, and the electrolysis life of gelatin was 1.3 times, so that the durability against sulfuric acid or organic additives was known. Improved.

<Comparative Example 1>

The calcination temperature and the calcination time in the air circulating electric furnace of Example 1 were changed to 520 ° C for 15 minutes to carry out thermal decomposition coating to form an electrode catalyst layer composed of a mixed oxide of cerium oxide and cerium oxide. The electrode prepared in accordance with this was subjected to the same X-ray diffraction analysis and electrolytic evaluation as in Example 1 without performing post-baking.

When X-ray diffraction was applied to the sample, it was found that the yttrium oxide peak belonging to the electrode catalyst layer was sharp, and it was confirmed that IrO ₂ of the catalyst layer was crystalline.

The same life evaluation as in Example 1 was carried out. From the results shown in Table 4, it was confirmed that the catalyst layer formed by low-temperature calcination + high-temperature post-baking was proposed in the present invention, and the durability under high-load conditions was improved.

<Comparative Example 2>

The evaluation electrode was produced in the same manner as in Example 1 except that the post-baking was not performed, and the same electrolysis evaluation as in Example 1 was carried out.

As shown in Table 4, the electrode which was calcined at 480 ° C in the case where post-baking was not performed, the sulfuric acid electrolysis life and the gelatin electrolysis life were the same as those of the comparative example 1, and the durability improvement effect was not found.

(industrial availability)

The present invention relates to an oxygen generating anode used in various industrial electrolysis and a method for producing the same; more specifically, electrolytic copper foil production such as electrolytic copper foil, power supply in aluminum liquid, continuous electrogalvanizing steel sheet manufacturing, metal taking, etc. It has excellent durability under high-load electrolysis conditions and can be effectively utilized as an anode for generating oxygen for high load resistance.

Fig. 1 is a graph showing changes in the degree of crystallization of cerium oxide (IrO ₂ ) in a catalyst layer caused by a calcination temperature and a post-baking temperature.

Fig. 2 is a graph showing the change in particle size of cerium oxide (IrO ₂ ) crystals of the catalyst layer caused by the calcination temperature and the post-baking temperature.

Figure 3 is a graph showing changes in electrode electrostatic capacitance caused by calcination temperature and post-baking temperature.

Fig. 4 is a graph showing the dependence of the calcination conditions on the oxygen overvoltage.

Claims (2)

A method for producing an anode for generating oxygen, which is a method for producing an anode for oxygen generation having a catalyst layer composed of ruthenium oxide and ruthenium oxide on a surface of a conductive metal substrate, characterized in that: (1) the above-mentioned conductive material The coating liquid containing the raw material salt of the above-mentioned cerium oxide and cerium oxide in the surface of the metal substrate is 2 g/m ² or more in terms of metal in terms of the coating amount per cerium oxide in the catalyst layer. a step of repeating the coating; (2) repeating the heating and baking of the conductive metal substrate in a temperature range of 430 ° C to 480 ° C for each application of the coating liquid to make the raw material a step of converting all the bismuth components in the salt into amorphous cerium oxide to form a catalyst layer composed of amorphous cerium oxide and cerium oxide; and then, (3) the conductive metal substrate is at 520 ° C. The high-temperature region of 600 ° C is post-baked in an oxidizing atmosphere, and 80% or more of the amorphous cerium oxide is crystallized, and the crystallized cerium oxide crystal grain size is set to 9.0 nm or less. The method for producing an anode for oxygen generation according to the first aspect of the invention is characterized in that the anode for oxygen generation is provided with a conductive metal substrate and a catalyst layer formed on the conductive metal substrate and containing cerium oxide and cerium oxide. A manufacturing method; wherein, before forming the catalyst layer, an arc ion plating undercoat layer containing a bismuth and titanium component is formed on the conductive metal substrate by arc ion plating.