TWI539994B - 自醣類生產多元醇及用於其之觸媒系統 - Google Patents

自醣類生產多元醇及用於其之觸媒系統 Download PDF

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TWI539994B
TWI539994B TW101126858A TW101126858A TWI539994B TW I539994 B TWI539994 B TW I539994B TW 101126858 A TW101126858 A TW 101126858A TW 101126858 A TW101126858 A TW 101126858A TW I539994 B TWI539994 B TW I539994B
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Taiwan
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catalyst
component
group
reaction zone
saccharide
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TW101126858A
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English (en)
Chinese (zh)
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TW201315540A (zh
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約翰Ｑ 陳
湯姆Ｎ 卡尼斯
喬瑟夫Ａ 科卡爾
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環球油類產品有限公司
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Priority claimed from US13/192,907 external-priority patent/US20110312487A1/en
Priority claimed from US13/192,970 external-priority patent/US8222462B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW101126858A 2011-07-28 2012-07-25 自醣類生產多元醇及用於其之觸媒系統 TWI539994B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/192,907 US20110312487A1 (en) 2011-07-28 2011-07-28 Catalyst system for generation of polyols from saccharides
US13/192,970 US8222462B2 (en) 2011-07-28 2011-07-28 Process for generation of polyols from saccharides

Publications (2)

Publication Number Publication Date
TW201315540A TW201315540A (zh) 2013-04-16
TWI539994B true TWI539994B (zh) 2016-07-01

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TW101126858A TWI539994B (zh) 2011-07-28 2012-07-25 自醣類生產多元醇及用於其之觸媒系統

Country Status (6)

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EP (1) EP2736869A4 (fr)
CN (1) CN103608320A (fr)
BR (1) BR112013026705A2 (fr)
CA (1) CA2832741A1 (fr)
TW (1) TWI539994B (fr)
WO (1) WO2013015955A2 (fr)

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WO2014161852A1 (fr) 2013-04-05 2014-10-09 Shell Internationale Research Maatschappij B.V. Procédé pour la préparation de glycols
EP2981516B1 (fr) 2013-04-05 2018-09-26 Shell International Research Maatschappij B.V. Procédé de conversion de charge d'alimentation contenant de la saccharide
WO2014173973A1 (fr) 2013-04-26 2014-10-30 Shell Internationale Research Maatschappij B.V. Procédé de préparation de mono-éthylène glycol
US9745234B2 (en) 2013-08-26 2017-08-29 Shell Oil Company Process for the preparation of glycols
EP3039002B1 (fr) * 2013-08-30 2018-07-25 Shell International Research Maatschappij B.V. Procédé de conversion de produit de départ comprenant un saccharide
WO2015154258A1 (fr) * 2014-04-09 2015-10-15 Petroliam Nasional Berhad (Petronas) Conversion sélective de charge d'alimentation contenant des saccharides en éthylène glycol
CN105523890B (zh) 2014-09-28 2021-04-16 长春美禾科技发展有限公司 一种制备二元醇的方法
CA2973436C (fr) 2015-01-13 2019-06-11 Avantium Knowledge Centre B.V. Procede de preparation d'ethylene glycol a partir d'un hydrate de carbone
CN107438591B (zh) 2015-01-13 2020-10-16 阿凡田知识中心有限公司 从碳水化合物源制备乙二醇的工艺
US10138184B2 (en) 2015-01-13 2018-11-27 Avantium Knowledge Centre B.V. Continuous process for preparing ethylene glycol from a carbohydrate source
EP3245180B1 (fr) 2015-01-13 2020-04-08 Avantium Knowledge Centre B.v. Procédé de préparation d'éthylène glycol à partir d'une source de glucides
RU2720679C2 (ru) * 2015-06-30 2020-05-12 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Процесс получения гликолей
CA2997373C (fr) * 2015-09-07 2023-07-18 Shell Internationale Research Maatschappij B.V. Procede de recuperation d'un composant metallique
BR112018010230A2 (pt) 2015-11-19 2018-11-27 Shell Int Research sistema catalisador e processo para a produção de glicóis
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WO2017085222A1 (fr) * 2015-11-19 2017-05-26 Shell Internationale Research Maatschappij B.V. Système de catalyseur et procédé pour la production de glycols
CA3003633A1 (fr) * 2015-11-19 2017-05-26 Shell Internationale Research Maatschappij B.V. Systeme de catalyseur et procede pour la production de glycols
US10294181B2 (en) 2015-12-09 2019-05-21 Shell Oil Company Process for the preparation of glycols
CN108602738A (zh) 2016-02-09 2018-09-28 国际壳牌研究有限公司 制造亚烷基二醇的方法
EP3426373B1 (fr) * 2016-03-07 2022-06-01 Shell Internationale Research Maatschappij B.V. Procédé de récupération d'un composant métallique
MY193158A (en) * 2016-06-03 2022-09-26 Iowa Corn Promotion Board Continuous processes for the highly selective conversion of aldohexose-yielding carbohydrate to ethylene glycol
WO2018024787A1 (fr) 2016-08-04 2018-02-08 Shell Internationale Research Maatschappij B.V. Procédé de production de glycols
BR112019006226B1 (pt) * 2016-09-29 2022-06-28 Shell Internationale Research Maatschappij B.V. Método para produzir etileno glicol de uma alimentação de carboidrato
CN109843840B (zh) * 2016-10-28 2022-06-03 国际壳牌研究有限公司 二醇的制造方法
BR112021004750A2 (pt) 2018-09-13 2021-06-01 Shell Internationale Research Maatschappij B.V. processo de desligamento para a produção de glicóis
US11485693B2 (en) 2018-09-13 2022-11-01 Shell Usa, Inc. Start-up process for the production of glycols
WO2020212542A1 (fr) 2019-04-17 2020-10-22 Shell Internationale Research Maatschappij B.V. Processus de mélange par injection agitée
WO2023083948A1 (fr) 2021-11-12 2023-05-19 Shell Internationale Research Maatschappij B.V. Procédé de séparation de glycol à partir de diols
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Publication number Publication date
TW201315540A (zh) 2013-04-16
CA2832741A1 (fr) 2013-01-31
EP2736869A4 (fr) 2015-01-07
CN103608320A (zh) 2014-02-26
WO2013015955A2 (fr) 2013-01-31
BR112013026705A2 (pt) 2016-12-27
WO2013015955A3 (fr) 2013-03-21
EP2736869A2 (fr) 2014-06-04

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