TWI473305B - Light emitting diode structure - Google Patents

Light emitting diode structure Download PDF

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TWI473305B
TWI473305B TW100108005A TW100108005A TWI473305B TW I473305 B TWI473305 B TW I473305B TW 100108005 A TW100108005 A TW 100108005A TW 100108005 A TW100108005 A TW 100108005A TW I473305 B TWI473305 B TW I473305B
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light
emitting diode
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phosphor powder
phosphor
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TW201238093A (en
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Formosa Epitaxy Inc
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發光二極體結構 Light-emitting diode structure

本發明係有關於一種發光二極體結構,特別是指一種可增加發光效率並且均勻發光之發光二極體結構。 The present invention relates to a light-emitting diode structure, and more particularly to a light-emitting diode structure which can increase luminous efficiency and uniformly emit light.

照明設備為人類生活中不可或缺,隨著技術的發展,具有更好照度及更省電的照明工具也逐漸應運而生。目前最常使用的照明光源為發光二極體。發光二極體(Light-Emitting Diode,LED)與傳統光源比較,發光二極體係具有體積小、省電、發光效率佳、壽命長、操作反應速度快、且無熱輻射與水銀等有毒物質的污染等優點,因此近幾年來,發光二極體的應用面已極為廣泛。過去由於發光二極體之亮度還無法取代傳統之照明光源,但隨著技術領域之不斷提升,目前已研發出高照明輝度之發光二極體(高功率LED),其足以取代傳統之照明光源。 Lighting equipment is indispensable for human life. With the development of technology, lighting tools with better illumination and more power saving have emerged. The most commonly used illumination source is the light-emitting diode. Light-Emitting Diode (LED) Compared with traditional light source, the light-emitting diode system has small volume, power saving, good luminous efficiency, long life, fast reaction speed, and no toxic substances such as heat radiation and mercury. Pollution and other advantages, so in recent years, the application of light-emitting diodes has been extremely extensive. In the past, the brightness of the light-emitting diodes could not replace the traditional illumination source. However, with the continuous improvement of the technical field, high-luminance LEDs (high-power LEDs) with high illumination brightness have been developed, which are sufficient to replace the traditional illumination sources. .

目前發光二極體的發展,以白光發光二極體與高功率發光二極體為主要方向。在環保需求與高價能源時代即將來臨的今天,白光發光二極體因省電與輕薄短小,並可製作成大尺寸陣列發光模組,將在照明領域成為明日之星。例如,高功率發光二極體光源在汽車上的應用越來越廣泛,包括汽車頭燈、主煞車燈、尾燈、方向燈、倒車燈、牌照燈等。紅綠燈也都慢慢改用LED光源,不僅亮度提高增加安全性,也較省電。 At present, the development of light-emitting diodes is dominated by white light-emitting diodes and high-power light-emitting diodes. In the era of environmental protection demand and high-priced energy, the white light-emitting diodes can be made into large-sized array light-emitting modules due to power saving, light and thin, and will become tomorrow's stars in the field of lighting. For example, high-power light-emitting diode light sources are increasingly used in automobiles, including automobile headlights, main brake lights, tail lights, directional lights, reverse lights, license plate lights, and the like. The traffic lights are also slowly changing to LED light sources, which not only increase the brightness, but also increase the safety and power saving.

請參閱第一圖,其係為習知發光二極體結構之結構示意圖; 如圖所示,習知發光二極體多半於一反射罩5內設置一發光二極體晶片10,發光二極體晶片10上方設置一螢光粉層20,螢光粉層20包含一螢光粉,如以白光發光二極體為例,習知的白光發光二極體以發黃光的釔鋁石榴石螢光粉組合一藍光發光二極體,可製作出高效率的白色發光二極體。然而,發光二極體晶片10在發光時會產生熱能,熱能會傳遞至螢光粉層20之螢光粉,如此會使螢光粉之光轉換效率降低,故發光二極體晶片10的發光效率亦降低,亦會使發光二極體晶片10發光較不均勻。若能降低發光二極體晶片10所產生之熱能對於螢光粉之影響,則必定能提升發光二極體結構之發光效率,亦能使發光二極體結構均勻發光。 Please refer to the first figure, which is a schematic structural diagram of a conventional light-emitting diode structure; As shown in the figure, a conventional light-emitting diode is generally provided with a light-emitting diode chip 10 in a reflector 5, and a phosphor powder layer 20 is disposed above the light-emitting diode chip 10. The phosphor powder layer 20 includes a firefly. For example, in the case of a white light emitting diode, a conventional white light emitting diode is combined with a yellow light yttrium aluminum garnet phosphor powder and a blue light emitting diode to produce a highly efficient white light emitting diode. . However, the light-emitting diode wafer 10 generates heat energy when it emits light, and heat energy is transmitted to the phosphor powder of the phosphor powder layer 20, so that the light conversion efficiency of the phosphor powder is lowered, so that the light-emitting diode wafer 10 emits light. The efficiency is also reduced, which also causes the light-emitting diode wafer 10 to emit less unevenly. If the influence of the thermal energy generated by the LED wafer 10 on the phosphor powder can be reduced, the luminous efficiency of the LED structure can be improved, and the LED structure can be uniformly illuminated.

因此,本發明提供一種發光二極體結構,其係可降低發光二極體晶片所產生之熱能影響螢光粉之發光效率,以提升發光二極體之發光效率,並使發光二極體結構均勻發光,以解決上述之問題。 Therefore, the present invention provides a light emitting diode structure which can reduce the heat energy generated by the light emitting diode wafer and affect the luminous efficiency of the fluorescent powder, thereby improving the luminous efficiency of the light emitting diode and making the light emitting diode structure Uniform illumination to solve the above problems.

本發明之主要目的,在於提供一種發光二極體結構,其係藉由一熱阻隔層設置於一發光二極體晶片與一螢光粉層之間藉由熱阻隔層之厚度介於1微米至10微米之間以降低發光二極體晶片所產生之熱能對於螢光粉層之影響,如此以提升螢光粉層之轉換效率,以讓發光二極體結構均勻發光,進而提升發光二極體結構之發光效率。 The main purpose of the present invention is to provide a light-emitting diode structure which is disposed between a light-emitting diode wafer and a phosphor layer by a thermal barrier layer. The thickness of the thermal barrier layer is between 1 micrometer. Between 10 micrometers to reduce the influence of the thermal energy generated by the light-emitting diode wafer on the phosphor powder layer, so as to improve the conversion efficiency of the phosphor powder layer, so that the light-emitting diode structure can uniformly emit light, thereby improving the light-emitting diode The luminous efficiency of the body structure.

本發明之發光二極體結構包含一發光二極體晶片、一熱阻隔層與一螢光粉層,熱阻隔層設於發光二極體晶片上方且邊緣切齊該發光二極體,螢光粉層設於熱阻隔層上方且邊緣切齊該發光二 極體,螢光粉層之厚度變化小於螢光粉層之厚度之百分之二十。藉由熱阻隔層以降低發光二極體晶片所產生之熱能對於螢光粉層之影響,如此以提升螢光粉層之轉換效率,以讓發光二極體結構均勻發光,進而提升發光二極體結構之發光效率。 The light emitting diode structure of the present invention comprises a light emitting diode chip, a thermal barrier layer and a phosphor powder layer, wherein the thermal barrier layer is disposed above the light emitting diode wafer and the edge is aligned with the light emitting diode, and the fluorescent light The powder layer is disposed above the thermal barrier layer and the edge is aligned with the light-emitting layer The thickness of the phosphor layer is less than 20% of the thickness of the phosphor layer. The thermal barrier layer is used to reduce the influence of the thermal energy generated by the light-emitting diode wafer on the phosphor powder layer, so as to improve the conversion efficiency of the phosphor powder layer, so that the light-emitting diode structure can uniformly emit light, thereby improving the light-emitting diode. The luminous efficiency of the body structure.

5‧‧‧反射罩 5‧‧‧reflector

10‧‧‧發光二極體晶片 10‧‧‧Light Emitter Wafer

20‧‧‧螢光粉層 20‧‧‧Fluorescent powder layer

25‧‧‧反射罩 25‧‧‧reflector

30‧‧‧發光二極體晶片 30‧‧‧Light Emitter Wafer

40‧‧‧熱阻隔層 40‧‧‧ Thermal barrier

50‧‧‧螢光粉層 50‧‧‧Flame powder layer

60‧‧‧封裝層 60‧‧‧Encapsulation layer

第一圖為習知發光二極體結構之結構示意圖;第二圖為本發明較佳實施例之發光二極體結構之結構示意圖;以及第三圖為本發明另一較佳實施例之發光二極體結構之結構示意圖。 The first figure is a schematic structural view of a conventional light emitting diode structure; the second figure is a schematic structural view of a light emitting diode structure according to a preferred embodiment of the present invention; and the third figure is a light emitting light according to another preferred embodiment of the present invention. Schematic diagram of the structure of the diode structure.

茲為使 貴審查委員對本發明之結構特徵及所達成之功效有更進一步之瞭解與認識,謹佐以較佳之實施例及配合詳細之說明,說明如後: In order to provide a better understanding and understanding of the structural features and efficacies of the present invention, the preferred embodiments and detailed descriptions are provided as follows:

請參閱第二圖,其係為本發明較佳實施例之發光二極體結構之結構示意圖;如圖所示,本發明之發光二極體結構係設置於一反射罩25內,發光二極體結構包含一發光二極體晶片30、一熱阻隔層40、一螢光粉層50及一封裝層60,發光二極體晶片30設於反射罩25內,熱阻隔層40設於發光二極體晶片30上方且邊緣切齊該發光二極體,螢光粉層50設於熱阻隔層40上方且邊緣切齊該發光二極體,該封裝層60填滿反射罩25,該封裝層60可為epoxy或silicon,其中,螢光粉層50之厚度變化小於螢光粉層50之厚度之百分之二十,且該熱阻隔層40不含任何螢光粉,其為透光性高分子材料。本發明藉由熱阻隔層40以降低發光二極體晶片30所產 生之熱能對於螢光粉層50之影響,如此以提升螢光粉層50之轉換效率,以讓發光二極體結構均勻發光,進而提升發光二極體結構之發光效率。 Please refer to the second drawing, which is a schematic structural view of a light emitting diode structure according to a preferred embodiment of the present invention; as shown in the figure, the light emitting diode structure of the present invention is disposed in a reflective cover 25, and has a light emitting diode. The body structure comprises a light-emitting diode chip 30, a thermal barrier layer 40, a phosphor layer 50 and an encapsulation layer 60. The LED chip 30 is disposed in the reflector 25, and the thermal barrier layer 40 is disposed on the light-emitting layer The light-emitting diode is disposed above the edge of the polar body wafer 30, and the phosphor layer 50 is disposed above the thermal barrier layer 40 and the edge is aligned with the light-emitting diode. The package layer 60 fills the reflective cover 25, and the package layer 60 may be epoxy or silicon, wherein the thickness of the phosphor layer 50 is less than twenty percent of the thickness of the phosphor layer 50, and the thermal barrier layer 40 does not contain any phosphor, which is translucent. Polymer Materials. The present invention reduces the thickness of the light-emitting diode wafer 30 by the thermal barrier layer 40. The influence of the heat generated by the heat on the phosphor layer 50 is such that the conversion efficiency of the phosphor layer 50 is increased to uniformly illuminate the structure of the light-emitting diode, thereby improving the luminous efficiency of the structure of the light-emitting diode.

當本發明之發光二極體晶片30發光時,發光二極體晶片30之光線將發射至熱阻隔層40,並且透過熱阻隔層40而發射到螢光粉層50。 When the light-emitting diode wafer 30 of the present invention emits light, the light of the light-emitting diode wafer 30 is emitted to the thermal barrier layer 40 and transmitted to the phosphor powder layer 50 through the thermal barrier layer 40.

本發明之發光二極體晶片30所發之光線為一可見光或一紫外光,螢光粉層50為單層或多層結構,藉由單層或多層之螢光粉層50可混合出不同之有色光。螢光粉層50之厚度小於100微米,而發光二極體晶片30與螢光粉層50之寬度大於5微米。本發明可用單晶片搭配螢光粉混光,例如使用藍光之發光二極體晶片30加上釔鋁石榴石螢光粉,或是紫外光之發光二極體晶片30加紅、藍、綠三色螢光粉等混光技術。 The light emitted by the LED chip 30 of the present invention is a visible light or an ultraviolet light, and the phosphor powder layer 50 has a single layer or a multi-layer structure, and the single or multiple layers of the phosphor powder layer 50 can be mixed. Colored light. The thickness of the phosphor layer 50 is less than 100 microns, and the width of the LED array 30 and the phosphor layer 50 is greater than 5 microns. The invention can use a single wafer with fluorescent powder to mix light, for example, a blue light emitting diode chip 30 plus yttrium aluminum garnet phosphor powder, or an ultraviolet light emitting diode chip 30 with red, blue and green color fires. Light mixing technology such as light powder.

熱阻隔層40之材料可為矽膠或是其他材質;矽膠是一種粒狀多孔的二氧化矽水合物,矽膠之熱穩定性在-100到250℃之間能保持穩定性質,對於臭氧和陽光有很好的抗氧化能力,亦具有良好彈性與良好的電絕緣性,故使用矽膠作為熱阻隔層40,可有效的減少發光二極體晶片30之熱能傳導至螢光粉層50。 The material of the thermal barrier layer 40 can be silicone or other materials; the silicone rubber is a granular porous ceria hydrate, and the thermal stability of the silicone can maintain stability between -100 and 250 ° C, for ozone and sunlight. It has good oxidation resistance, good elasticity and good electrical insulation. Therefore, the use of silicone as the thermal barrier layer 40 can effectively reduce the thermal energy of the LED wafer 30 to the phosphor layer 50.

螢光粉層50內具有複數個螢光粉,螢光粉的作用在於光色複合,形成色光,其特性主要包括粒度、形狀、發光效率、轉換效率、穩定性(熱和化學)等,其中,發光效率和轉換效率是關鍵。而隨著溫度上升,螢光粉量子效率降低,出光減少,輻射波長也會發生變化,從而引起發光二極體結構之色溫、色度的變化, 較高的溫度還會加速螢光粉的老化。原因在於螢光粉層50是由環氧或矽膠與螢光粉調配而成,散熱性能較差,當受到紫光或紫外光的輻射時,易發生溫度猝滅和老化,使發光效率降低。此外,高溫下灌封膠和螢光粉的熱穩定性也存在問題。 The phosphor powder layer 50 has a plurality of phosphor powders, and the phosphor powder functions in light color recombination to form color light, and its characteristics mainly include particle size, shape, luminous efficiency, conversion efficiency, stability (heat and chemistry), etc. Luminous efficiency and conversion efficiency are key. As the temperature rises, the quantum efficiency of the phosphor powder decreases, the light emission decreases, and the radiation wavelength also changes, thereby causing a change in color temperature and chromaticity of the light-emitting diode structure. Higher temperatures also accelerate the aging of the phosphor. The reason is that the phosphor powder layer 50 is prepared by epoxy or silicone rubber and fluorescent powder, and has poor heat dissipation performance. When subjected to ultraviolet light or ultraviolet light radiation, temperature quenching and aging are liable to occur, and the luminous efficiency is lowered. In addition, the thermal stability of the potting compound and the phosphor powder at high temperatures is also problematic.

因此若要避免螢光粉受熱之影響,則需對螢光粉做進一步之保護。故本發明藉由熱阻隔層40以減少發光二極體晶片30之熱能傳導至螢光粉層50。故當發光二極體晶片30之光線發射至螢光粉層時,光線會激發螢光粉而發光。而發光二極體晶片30於使用時,發光二極體晶片30將電能轉換成光能時會產生熱能,而這些熱能大部分將傳導至熱阻隔層40,之後在由熱阻隔層40將少部分熱能傳導至螢光粉層50。熱阻隔層40之厚度介於1微米至10微米之間,使整體發光二極體晶片30發光均勻,且因為將熱阻隔以提升其效率。如此減少螢光粉所吸收之熱能,故可提升螢光粉的光轉換效率,以讓螢光粉發出較多的螢光。當螢光粉的光轉換效率提升時,可讓發光二極體晶片30之部分光線與較多的螢光混合,如此可提升發光二極體結構發光的均勻度提升,以提升發光效率。 Therefore, if you want to avoid the influence of the fluorescent powder, you need to further protect the fluorescent powder. Therefore, the present invention uses the thermal barrier layer 40 to reduce the thermal energy of the light-emitting diode wafer 30 to the phosphor layer 50. Therefore, when the light of the LED chip 30 is emitted to the phosphor layer, the light excites the phosphor powder to emit light. When the LED chip 30 is in use, the LED film 30 generates thermal energy when converting electrical energy into light energy, and most of the heat energy will be conducted to the thermal barrier layer 40, and then will be less by the thermal barrier layer 40. Part of the thermal energy is conducted to the phosphor layer 50. The thickness of the thermal barrier layer 40 is between 1 micrometer and 10 micrometers, making the overall light-emitting diode wafer 30 uniform in illumination, and because heat is blocked to increase its efficiency. By reducing the heat energy absorbed by the phosphor powder, the light conversion efficiency of the phosphor powder can be improved, so that the phosphor powder emits more fluorescence. When the light conversion efficiency of the phosphor powder is increased, a part of the light of the LED chip 30 can be mixed with more fluorescent light, so that the uniformity of the illumination of the LED structure can be improved to improve the luminous efficiency.

螢光粉層50之材料包含高分子材料、玻璃纖維材料或高分子材料及玻璃纖維材料之混合。螢光粉能被可見光或紫外光激發,以發出螢光。螢光粉結構不穩定與發光中心易氧化等緣故,因此的螢光粉容易因為受熱或是受光的照射而有明顯老化的問題,因此可於螢光粉的製程中包覆一保護層,保護層例如為氧化鋁。如此可增加螢光粉的使用壽命。 The material of the phosphor layer 50 comprises a polymer material, a glass fiber material or a mixture of a polymer material and a glass fiber material. Fluorescent powder can be excited by visible or ultraviolet light to emit fluorescence. The structure of the phosphor powder is unstable and the center of the luminescence is easily oxidized. Therefore, the phosphor powder is easily aging due to exposure to heat or light, so that a protective layer can be coated in the process of the phosphor powder to protect The layer is for example alumina. This increases the life of the phosphor.

請一併參閱第三圖,其係為本發明另一較佳實施例之發光二極體結構之結構示意圖;如圖所示,此實施例所包含一封裝層60 其設於螢光粉層50上方,其形狀可經由不同的設計以呈現不同之光形。此實施例藉由該封裝層60可讓發光二極體晶片30之部分光線與螢光混合時,較為均勻的擴散出去。 Please refer to the third figure, which is a schematic structural view of a light emitting diode structure according to another preferred embodiment of the present invention; as shown in the figure, this embodiment includes an encapsulation layer 60. It is disposed above the phosphor layer 50 and its shape can be differently designed to present different light shapes. In this embodiment, the encapsulating layer 60 allows a part of the light of the LED chip 30 to be uniformly diffused when it is mixed with the fluorescent light.

綜上所述,本發明之發光二極體結構包含一發光二極體晶片、一熱阻隔層與一螢光粉層,熱阻隔層設於發光二極體晶片上方且邊緣切齊該發光二極體晶片,螢光粉層設於熱阻隔層上方且邊緣切齊該發光二極體晶片,螢光粉層之厚度變化小於螢光粉層之厚度之百分之二十。藉由熱阻隔層之厚度介於1微米至10微米之間以降低發光二極體晶片所產生之熱能對於螢光粉層之影響,如此以提升螢光粉層之轉換效率,以讓發光二極體結構均勻發光,進而提升發光二極體結構之發光效率。 In summary, the LED structure of the present invention comprises a light-emitting diode chip, a thermal barrier layer and a phosphor layer, and the thermal barrier layer is disposed above the LED chip and the edge is aligned with the light-emitting diode. The polar body wafer, the phosphor powder layer is disposed above the thermal barrier layer and the edge is aligned with the light emitting diode chip, and the thickness of the phosphor powder layer is less than 20% of the thickness of the phosphor powder layer. The thickness of the thermal barrier layer is between 1 micrometer and 10 micrometer to reduce the influence of the thermal energy generated by the light-emitting diode wafer on the phosphor powder layer, so as to improve the conversion efficiency of the phosphor powder layer, so that the light-emitting layer The polar body structure uniformly emits light, thereby improving the luminous efficiency of the light emitting diode structure.

故本發明係實為一具有新穎性、進步性及可供產業利用者,應符合我國專利法所規定之專利申請要件無疑,爰依法提出發明專利申請,祈 鈞局早日賜准專利,至感為禱。 Therefore, the present invention is a novelty, progressive and available for industrial use. It should be in accordance with the patent application requirements stipulated in the Patent Law of China, and the invention patent application is filed according to law, and the prayer bureau will grant the patent as soon as possible. For prayer.

惟以上所述者,僅為本發明之一較佳實施例而已,並非用來限定本發明實施之範圍,舉凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 However, the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and the shapes, structures, features, and spirits described in the claims are equivalently changed. Modifications are intended to be included in the scope of the patent application of the present invention.

25‧‧‧反射罩 25‧‧‧reflector

30‧‧‧發光二極體晶片 30‧‧‧Light Emitter Wafer

40‧‧‧熱阻隔層 40‧‧‧ Thermal barrier

50‧‧‧螢光粉層 50‧‧‧Flame powder layer

60‧‧‧封裝層 60‧‧‧Encapsulation layer

Claims (9)

一種發光二極體結構,包含:一發光二極體晶片;一熱阻隔層,設於該發光二極體晶片上方且該熱阻隔層邊緣切齊該發光二極體晶片,該熱阻隔層之厚度介於1微米至10微米之間;以及至少一螢光粉層,設於該熱阻隔層上方且該螢光粉層邊緣切齊該發光二極體晶片,該螢光粉層之厚度變化小於該螢光粉層之厚度之百分之二十。 A light-emitting diode structure comprising: a light-emitting diode wafer; a thermal barrier layer disposed above the light-emitting diode wafer and having the edge of the thermal barrier layer aligned with the light-emitting diode wafer, the thermal barrier layer a thickness of between 1 micrometer and 10 micrometers; and at least one phosphor layer disposed above the thermal barrier layer and the edge of the phosphor powder layer is aligned with the light-emitting diode wafer, and the thickness of the phosphor powder layer is varied. Less than 20% of the thickness of the phosphor layer. 如申請專利範圍第1項所述之發光二極體結構,更包含一封裝層,其設於該螢光粉層上方。 The light emitting diode structure of claim 1, further comprising an encapsulation layer disposed above the phosphor powder layer. 如申請專利範圍第1項所述之發光二極體結構,其中該發光二極體晶片所發之光線為一可見光。 The light-emitting diode structure of claim 1, wherein the light emitted by the light-emitting diode chip is a visible light. 如申請專利範圍第1項所述之發光二極體結構,其中該發光二極體晶片所發之光線為一紫外光。 The light-emitting diode structure of claim 1, wherein the light emitted by the light-emitting diode chip is an ultraviolet light. 如申請專利範圍第1項所述之發光二極體結構,其中該熱阻隔層不包含任何螢光粉。 The luminescent diode structure of claim 1, wherein the thermal barrier layer does not comprise any phosphor powder. 如申請專利範圍第1項所述之發光二極體結構,其中該熱阻隔層為一透明高分子材料。 The light-emitting diode structure according to claim 1, wherein the thermal barrier layer is a transparent polymer material. 如申請專利範圍第1項所述之發光二極體結構,其中該螢光粉層之材料包含高分子材料、玻璃纖維材料或高分子材料及玻璃纖維材料之混合。 The light-emitting diode structure according to claim 1, wherein the material of the phosphor powder layer comprises a polymer material, a glass fiber material or a mixture of a polymer material and a glass fiber material. 如申請專利範圍第1項所述之發光二極體結構,其中該螢光粉層之厚度小於100微米。 The light-emitting diode structure of claim 1, wherein the phosphor powder layer has a thickness of less than 100 micrometers. 如申請專利範圍第1項所述之發光二極體結構,其中該發光二極體晶片與該螢光粉層之寬度大於5微米。 The light emitting diode structure of claim 1, wherein the light emitting diode chip and the phosphor powder layer have a width greater than 5 micrometers.
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* Cited by examiner, † Cited by third party
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US20060091788A1 (en) * 2004-10-29 2006-05-04 Ledengin, Inc. Light emitting device with a thermal insulating and refractive index matching material
TW200941789A (en) * 2008-01-30 2009-10-01 Osram Opto Semiconductors Gmbh Device with encapsulation arrangement
TW201034759A (en) * 2009-03-17 2010-10-01 Kismart Corp Method for spray coating phosphor materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060091788A1 (en) * 2004-10-29 2006-05-04 Ledengin, Inc. Light emitting device with a thermal insulating and refractive index matching material
TW200941789A (en) * 2008-01-30 2009-10-01 Osram Opto Semiconductors Gmbh Device with encapsulation arrangement
TW201034759A (en) * 2009-03-17 2010-10-01 Kismart Corp Method for spray coating phosphor materials

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