TWI452656B - Substrate product and method of manufacturing a substrate - Google Patents
Substrate product and method of manufacturing a substrate Download PDFInfo
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- TWI452656B TWI452656B TW100139337A TW100139337A TWI452656B TW I452656 B TWI452656 B TW I452656B TW 100139337 A TW100139337 A TW 100139337A TW 100139337 A TW100139337 A TW 100139337A TW I452656 B TWI452656 B TW I452656B
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Description
本發明係有關於一種基板,尤指一種應用於CIGS、面板、矽晶圓等領域的基板製品及基板的製造方法。The present invention relates to a substrate, and more particularly to a substrate product and a method of manufacturing a substrate applied to the fields of CIGS, panel, germanium wafer, and the like.
按,現今市場上,太陽能電池的種類眾多,例如有以銅銦硒(copper indium selenide,簡稱CIS)三元素組成之材料來製作薄膜太陽能電池,後來為提升轉換效率,演變至使用銅銦鎵硒(copper indium gallium selenide,簡稱CIGS)四元素材料。According to the current market, there are many types of solar cells. For example, a thin-film solar cell is made of a material composed of copper indium selenide (CIS), and later, in order to improve conversion efficiency, copper indium gallium selenide is used. (copper indium gallium selenide, referred to as CIGS) four-element material.
另,半導體裝置要經過薄膜、擴散等方法在矽晶圓的表面上形成裝置層的步驟而製成,矽晶圓擴散製程的應用也相當的廣泛。又,液晶顯示元件(LCD)及發光二極體(LED)也被廣泛運用在電子裝置。In addition, the semiconductor device is formed by a method of forming a device layer on the surface of the germanium wafer by a method such as thin film or diffusion, and the application of the germanium wafer diffusion process is also quite extensive. Further, liquid crystal display elements (LCDs) and light emitting diodes (LEDs) are also widely used in electronic devices.
習知CIGS等基板會在基材的功能面上以各種方式(塗佈、CVD)形成各種反應前驅物層,再利用光或熱使之反應成為功能性鍍層。惟,製程加熱操作時,因反應前驅物層其面積、厚度、傳導與輻射等特性容易造成加熱不均勻,以致後續的製程狀況如濺鍍或擴散等製程皆會受到影響,尤其是溫度之均勻性還需取決於鍍層之均勻性、厚度及表面狀況等諸多因素,因此往往難以控制。雖然可利用加熱源及基板擺放位置的不同稍微的調整,但仍然無法調整至所有基板與基板各位置皆受熱均勻,而使得功能性鍍層之品質不佳或無法整片基板均反應完全。顯然習知基板會有受熱不均勻,不利於後續加工,良率降低等問題,尤其是針對大面積基板更為嚴重。另,其他類型基板製程(例如LCD面板、 矽晶圓擴散、發光二極體等)也有同樣的問題。Conventional substrates such as CIGS form various reaction precursor layers in various ways (coating, CVD) on the functional surface of the substrate, and then react with light or heat to form a functional plating layer. However, during the process heating operation, the heating, such as the area, thickness, conduction and radiation of the precursor layer, tends to cause uneven heating, so that subsequent processes such as sputtering or diffusion are affected, especially the temperature is uniform. Sex also depends on many factors such as the uniformity, thickness and surface condition of the coating, so it is often difficult to control. Although the heating source and the substrate placement position can be slightly adjusted, it is still impossible to adjust to the uniformity of heat at all the substrates and the substrate, so that the quality of the functional plating layer is not good or the entire substrate cannot be completely reacted. Obviously, the conventional substrate may have uneven heating, which is not conducive to subsequent processing, and the yield is lowered, especially for large-area substrates. In addition, other types of substrate processes (such as LCD panels, The same problem arises with wafer diffusion, light-emitting diodes, etc.
本發明之主要目的在於提供一種基板製品及基板的製造方法,使基板對光、熱之吸收均勻,藉以改善基板的受熱均勻性,以提升良率。The main object of the present invention is to provide a substrate product and a method for manufacturing the substrate, which can make the substrate absorb light and heat uniformly, thereby improving the heat uniformity of the substrate to improve the yield.
本發明提供一種基板製品,包括:一基材,該基材具有一功能面及一非功能面;至少一鍍層,該至少一鍍層係以一反應前驅物經由光反應及熱反應中至少一種形成於該基材的功能面上;以及一吸熱層,該吸熱層設於該基材的非功能面上,用以使該反應前驅物形成該鍍層的過程中均勻吸收環境中的光跟熱。The present invention provides a substrate product comprising: a substrate having a functional surface and a non-functional surface; at least one plating layer formed by at least one of a photoreaction and a thermal reaction with a reactive precursor And a heat absorbing layer disposed on the non-functional surface of the substrate for uniformly absorbing light and heat in the environment during formation of the plating precursor.
本發明另提供一種基板的製造方法,包括步驟如下:提供一基材,該基材具有一功能面及一非功能面,該基材的功能面上設置有一反應前驅物;形成一吸熱層在該基材的非功能面上,用以使該反應前驅物能夠均勻吸收環境中的光跟熱;以及進行光反應及熱反應中至少一種於該基材,使該反應前驅物反應成為一鍍層。The invention further provides a method for manufacturing a substrate, comprising the steps of: providing a substrate having a functional surface and a non-functional surface, wherein a reactive precursor is disposed on a functional surface of the substrate; and a heat absorbing layer is formed The non-functional surface of the substrate is configured to enable the reaction precursor to uniformly absorb light and heat in the environment; and to perform at least one of photoreaction and thermal reaction on the substrate to react the reaction precursor into a plating layer .
該吸熱層以附著方式設於該基材的非功能面上,或該吸熱層以粗糙化方式形成於該基材的非功能面上。The heat absorbing layer is provided on the non-functional surface of the substrate in an adhesive manner, or the heat absorbing layer is formed on the non-functional surface of the substrate in a roughened manner.
本發明具有以下有益的效果:本發明在基材非功能面的一面(背面)設置一層對熱吸收良好的結構,使得對光、熱之吸收均勻,使熱均勻的傳導到功能面,藉以改善基板的受熱均勻性,以利後續加熱製程,使良率提升。尤其是針對大面積基板效果更佳。The invention has the following beneficial effects: the invention provides a structure with good heat absorption on one side (back side) of the non-functional surface of the substrate, so that the absorption of light and heat is uniform, and the heat is uniformly transmitted to the functional surface, thereby improving. The uniformity of the substrate is heated to facilitate the subsequent heating process to improve the yield. Especially for large-area substrates, the effect is better.
為使能更進一步瞭解本發明的特徵及技術內容,請參閱以下有關本發明的詳細說明與附圖,然而所附圖式僅提 供參考與說明用,並非用來對本發明加以限制者。In order to further understand the features and technical contents of the present invention, please refer to the following detailed description of the invention and the accompanying drawings. For reference and description, it is not intended to limit the invention.
請參閱圖1及圖2,本發明提供一種基板的製造方法,包括步驟如下:Referring to FIG. 1 and FIG. 2, the present invention provides a method for manufacturing a substrate, including the following steps:
首先,提供一基材1,基材1可以為玻璃、陶瓷或高分子材料等製成,基材1也可具有透光性,較佳地以玻璃製成,基材1的材質並不限制,可因應基板不同的需求而適當的變化。基材1具有一功能面11及一非功能面12,功能面11及非功能面12位於基材1相對的兩表面,通常功能面11及非功能面12分別位於基材1的正面及背面。基材1的功能面11上設有至少一鍍層2,鍍層2的種類及材料並不限制,可因應產品的種類而適當的變化,以便組成符合需求的功能性鍍層如:面板、CIGS薄膜太陽能板、晶圓等。First, a substrate 1 is provided. The substrate 1 can be made of glass, ceramic or polymer material, and the substrate 1 can also have light transmissivity, preferably made of glass. The material of the substrate 1 is not limited. , can be appropriately changed according to the different needs of the substrate. The substrate 1 has a functional surface 11 and a non-functional surface 12. The functional surface 11 and the non-functional surface 12 are located on opposite surfaces of the substrate 1. The functional surface 11 and the non-functional surface 12 are respectively located on the front and back surfaces of the substrate 1. . At least one plating layer 2 is provided on the functional surface 11 of the substrate 1. The type and material of the plating layer 2 are not limited, and can be appropriately changed according to the type of the product, so as to form a functional coating such as a panel, CIGS thin film solar energy. Board, wafer, etc.
而後,在基材1的非功能面12上設有一層對熱吸收良好的材料,藉以構成一吸熱層3;吸熱層3為一以印刷、噴塗、貼附、濺鍍、電鍍、物理沉積(PVD)或化學沉積(CVD)等方式形成之厚膜或薄膜,使吸熱層3以附著方式設於基材1的非功能面12上。吸熱層3的材料可以是碳化物(如SiC)、氮化物(如AlN)、氧化物,吸熱層3的材料也可以是碳、金屬元素或含金屬的化合物。吸熱層3的材料的選擇仍需考慮其吸收光、熱的特性,例如發熱源的光波長、吸收率等。Then, a non-functional surface 12 of the substrate 1 is provided with a layer of heat absorbing material to form a heat absorbing layer 3; the heat absorbing layer 3 is printed, sprayed, attached, sputtered, plated, physically deposited ( A thick film or film formed by PVD) or chemical deposition (CVD) or the like, and the heat absorbing layer 3 is provided on the non-functional surface 12 of the substrate 1 in an adhesive manner. The material of the heat absorbing layer 3 may be a carbide (such as SiC), a nitride (such as AlN), an oxide, and the material of the heat absorbing layer 3 may also be a carbon, a metal element or a metal-containing compound. The material of the heat absorbing layer 3 is still selected in consideration of its absorption of light and heat, such as the wavelength of light of the heat source, the absorption rate, and the like.
該吸熱層3可以安排在製程中形成,然後在某製程中移除或永久保留於基材1之中,可視產品狀況而異。吸熱 層3的厚度t2尺寸並不限制,但吸熱層3的厚度t2尺寸以大於功能面11的鍍層2的厚度t1尺寸為較佳。The heat absorbing layer 3 can be arranged to be formed in the process and then removed or permanently retained in the substrate 1 in a certain process, depending on the product condition. Endothermic The thickness t2 of the layer 3 is not limited in size, but the thickness t2 of the heat absorbing layer 3 is preferably larger than the thickness t1 of the plating layer 2 of the functional surface 11.
請參閱圖2,本發明提供一種基板製品,包括一基材1、至少一鍍層2及一吸熱層3,基材1較佳地以玻璃製成,基材1的材質並不限制。基材1具有一功能面11及一非功能面12。鍍層2設於基材1的功能面11上。吸熱層3設於基材1的非功能面12上,吸熱層3為一以印刷、噴塗、貼附、濺鍍、電鍍、物理沉積(PVD)或化學沉積(CVD)等方式形成之厚膜或薄膜,使吸熱層3以附著方式設於基材1的非功能面12上。吸熱層3的材料可以是碳化物、氮化物、氧化物,吸熱層3的材料也可以是碳、金屬元素或含金屬的化合物。吸熱層3的厚度t2尺寸以大於功能面11的鍍層2的厚度t1尺寸為較佳,以具有較佳的導熱效果。Referring to FIG. 2, the present invention provides a substrate product comprising a substrate 1, at least one plating layer 2 and a heat absorbing layer 3. The substrate 1 is preferably made of glass, and the material of the substrate 1 is not limited. The substrate 1 has a functional surface 11 and a non-functional surface 12. The plating layer 2 is provided on the functional surface 11 of the substrate 1. The heat absorbing layer 3 is disposed on the non-functional surface 12 of the substrate 1, and the heat absorbing layer 3 is a thick film formed by printing, spraying, attaching, sputtering, electroplating, physical deposition (PVD) or chemical deposition (CVD). Or a film, the heat absorbing layer 3 is provided on the non-functional surface 12 of the substrate 1 in an adhesive manner. The material of the heat absorbing layer 3 may be a carbide, a nitride or an oxide, and the material of the heat absorbing layer 3 may also be a carbon, a metal element or a metal-containing compound. The thickness t2 of the heat absorbing layer 3 is preferably larger than the thickness t1 of the plating layer 2 of the functional surface 11 to have a better heat conduction effect.
請參閱圖3,本發明的第二實施例與第一實施例的差異主要在於,吸熱層3’是以不同的方式形成,亦即在基材1的非功能面12利用物理或化學方式進行表面處理,將吸熱層3’以粗糙化方式形成於非功能面12上。Referring to FIG. 3, the second embodiment of the present invention differs from the first embodiment mainly in that the heat absorbing layer 3' is formed in a different manner, that is, in the physical or chemical manner on the non-functional surface 12 of the substrate 1. The surface treatment is performed to form the heat absorbing layer 3' on the non-functional surface 12 in a roughened manner.
本發明在基材1的非功能面12設置一層對熱吸收良好的結構(吸熱層3),使得對光、熱之吸收均勻,使熱均勻的傳導到功能面11及鍍層2等,藉以改善基板的受熱均勻性,以利後續加熱製程,使良率提升,尤其是針對大面積基板效果更佳。The invention provides a structure (heat absorbing layer 3) with good heat absorption on the non-functional surface 12 of the substrate 1 so that the absorption of light and heat is uniform, and the heat is uniformly transmitted to the functional surface 11 and the plating layer 2, thereby improving The uniformity of the substrate is heated to facilitate the subsequent heating process, which improves the yield, especially for large-area substrates.
所述設於基材1的功能面11上的鍍層2及後續製程設置於鍍層2上的材料包括但不限於例如銅銦鎵硒(copper indium gallium selenide,簡稱CIGS)等,該些鍍層2及材料 為習知技術,並非本發明訴求的重點,故不再加以贅述說明。本發明可應用於CIGS、面板、矽晶圓、發光二極體等各種領域的基板製品及基板的製造方法。The plating layer 2 disposed on the functional surface 11 of the substrate 1 and the subsequent processes are disposed on the plating layer 2, including but not limited to, for example, copper indium gallium selenide (CIGS), etc. material The prior art is not the focus of the present invention, and therefore will not be described again. The present invention can be applied to substrate products and substrates in various fields such as CIGS, panels, germanium wafers, and light-emitting diodes.
惟以上所述僅為本發明之較佳實施例,非意欲侷限本發明的專利保護範圍,故舉凡運用本發明說明書及圖式內容所為的等效變化,均同理皆包含於本發明的權利保護範圍內,合予陳明。The above is only the preferred embodiment of the present invention, and is not intended to limit the scope of the invention, and the equivalents of the present invention and the equivalents of the drawings are all included in the present invention. Within the scope of protection, it is given to Chen Ming.
1‧‧‧基材1‧‧‧Substrate
11‧‧‧功能面11‧‧‧ functional surface
12‧‧‧非功能面12‧‧‧Non-functional surface
2‧‧‧鍍層2‧‧‧ plating
3‧‧‧吸熱層3‧‧‧heat absorption layer
3’‧‧‧吸熱層3'‧‧‧heat absorbing layer
t1‧‧‧厚度T1‧‧‧ thickness
t2‧‧‧厚度T2‧‧‧ thickness
圖1為本發明基板的製造方法之流程圖。1 is a flow chart of a method of manufacturing a substrate of the present invention.
圖2為本發明基板製品之平面示意圖。2 is a schematic plan view of a substrate article of the present invention.
圖3為本發明基板製品另一實施例之平面示意圖。3 is a schematic plan view showing another embodiment of the substrate product of the present invention.
1...基材1. . . Substrate
11...功能面11. . . Functional surface
12...非功能面12. . . Non-functional surface
2...鍍層2. . . Plating
3...吸熱層3. . . Heat absorbing layer
t1...厚度T1. . . thickness
t2...厚度T2. . . thickness
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Cited By (1)
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TWI730636B (en) * | 2020-02-24 | 2021-06-11 | 高爾科技股份有限公司 | Double-sided photothermal reaction selective lock and manufacturing method thereof |
Citations (2)
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TWI310956B (en) * | 2005-04-21 | 2009-06-11 | Chien Min Sung | Diamond-like carbon thermoelectric conversion devices and methods for the use and manufacture thereof |
US7741764B1 (en) * | 2007-01-09 | 2010-06-22 | Chien-Min Sung | DLC emitter devices and associated methods |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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TWI310956B (en) * | 2005-04-21 | 2009-06-11 | Chien Min Sung | Diamond-like carbon thermoelectric conversion devices and methods for the use and manufacture thereof |
US7741764B1 (en) * | 2007-01-09 | 2010-06-22 | Chien-Min Sung | DLC emitter devices and associated methods |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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TWI730636B (en) * | 2020-02-24 | 2021-06-11 | 高爾科技股份有限公司 | Double-sided photothermal reaction selective lock and manufacturing method thereof |
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