TWI422542B - A method of making a porous glass substrate using glass powder - Google Patents
A method of making a porous glass substrate using glass powder Download PDFInfo
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- TWI422542B TWI422542B TW098122719A TW98122719A TWI422542B TW I422542 B TWI422542 B TW I422542B TW 098122719 A TW098122719 A TW 098122719A TW 98122719 A TW98122719 A TW 98122719A TW I422542 B TWI422542 B TW I422542B
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- glass powder
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Description
本發明係有關於一種利用玻璃粉末製作多孔性玻璃基材之方法,其係將玻璃粉末與可蝕刻的金屬線材混合,燒結後蝕刻去除金屬線材,而製作多孔性玻璃基材。 The present invention relates to a method for producing a porous glass substrate by using a glass powder, which is obtained by mixing a glass powder with an etchable metal wire, and then etching and removing the metal wire to form a porous glass substrate.
目前有關玻璃粉末陶瓷製造技術,如中華民國公開號第200800843號「玻璃及玻璃陶瓷之粉末注入鑄造」發明專利申請案,雖揭露以玻璃粉末混合熱塑性聚合物或蠟之黏接劑,再予成型、燒結之方法,但其玻璃粉末含量在50%以上,最好是70%以上,而燒結時黏接劑直接氣化,而玻璃粉末係直接軟化塌縮熔黏在一起,因此,燒結後的玻璃孔隙率極低且無法均質化,更難以控制孔隙大小及孔隙率。 At present, the invention relates to the invention of glass powder ceramics, such as the invention patent application of "Glass and Glass Ceramic Powder Injection Casting" of the Republic of China Publication No. 200800843, although it is disclosed that the glass powder is mixed with a thermoplastic polymer or a wax adhesive, and then molded. And sintering method, but the glass powder content is above 50%, preferably more than 70%, and the adhesive is directly vaporized during sintering, and the glass powder is directly softened, collapsed and melted together, therefore, after sintering The porosity of the glass is extremely low and cannot be homogenized, making it more difficult to control pore size and porosity.
換言之,現有技術不能製造出多孔性的玻璃。 In other words, the prior art cannot produce porous glass.
爰此,有鑑於目前玻璃燒結技術不能製造多孔性玻璃基材,故本發明主要係在提供一種利用玻璃粉末製作多孔性玻璃基材之方法,包括下列步驟: Accordingly, in view of the fact that the current glass sintering technology cannot produce a porous glass substrate, the present invention mainly provides a method for producing a porous glass substrate using glass powder, comprising the following steps:
a.混料:將玻璃粉末裝填於一容器中,另將複數金屬線材攙入玻璃粉末形成一混合料,且使每一金屬線材之局部貼抵於上述容器。 a. Mixing: The glass powder is filled in a container, and the plurality of metal wires are poured into the glass powder to form a mixture, and a part of each metal wire is applied to the container.
b.加熱:將混合料加溫至玻璃粉末之熔融溫度,並讓玻璃粉末熔融。 b. Heating: The mixture is warmed to the melting temperature of the glass powder and the glass powder is melted.
c.冷卻:降到常溫。 c. Cooling: drop to normal temperature.
d.蝕刻:將冷卻後之玻璃以蝕刻方式去除金屬線材,形成一多孔隙的玻璃基材。 d. Etching: The cooled glass is etched to remove the metal wire to form a porous glass substrate.
上述金屬線材係選自下列其中之一:鋁、鐵或不銹鋼。 The above metal wire is selected from one of the following: aluminum, iron or stainless steel.
上述步驟a之後,先將混合料成型,再進行步驟b。 After the above step a, the mixture is first molded, and then step b is performed.
上述步驟a係進一步混合有黏合劑,該黏合劑之氣化溫度低於玻璃粉末的熔融溫度者。 The above step a is further mixed with a binder whose vaporization temperature is lower than the melting temperature of the glass powder.
上述步驟a之黏合劑係為蠟。 The binder of the above step a is a wax.
本發明具有下列優點或功效: The invention has the following advantages or effects:
1.可以製造出真正的多孔性玻璃基材。 1. A truly porous glass substrate can be produced.
2.可控制孔隙大小;在燒結過程,因金屬線材尚未氣化,冷卻後再蝕刻才形成孔隙,因此,只要調整金屬線材之線徑大小,即可調整最後孔隙大小。 2. The pore size can be controlled; in the sintering process, since the metal wire has not been vaporized, the pores are formed after cooling and then etched. Therefore, the final pore size can be adjusted by adjusting the wire diameter of the metal wire.
3.可控制孔隙;同前項之理由,只要調整金屬線材對玻璃粉末之比例,即可調整孔隙率。 3. The porosity can be controlled; for the reason of the above, the porosity can be adjusted by adjusting the ratio of the metal wire to the glass powder.
4.可擴充玻璃的應用面;前述的多孔性玻璃基材可以應用於裝飾等玻璃藝術的素材、芳香精油或驅蟲(蚊)劑的容器。 4. The application surface of the glass can be expanded; the aforementioned porous glass substrate can be applied to a glass art material such as decoration, a container of an aromatic oil or an insect repellent (mosquito) agent.
(1)‧‧‧玻璃粉末 (1)‧‧‧ glass powder
(2)‧‧‧容器 (2) ‧ ‧ container
(3)‧‧‧金屬線材 (3)‧‧‧Metal wire
(4)‧‧‧玻璃 (4) ‧‧‧glass
(5)‧‧‧孔隙 (5) ‧ ‧ pores
第一圖係本發明方法之流程方塊圖。 The first figure is a block diagram of the process of the present invention.
第二圖係本發明之流程示意圖。 The second drawing is a schematic flow chart of the present invention.
首先,請參閱第一圖及第二圖所示,本發明實施例係一種利用玻璃粉末製作多孔性玻璃基材之方法,包括下列步驟: First, referring to the first figure and the second figure, the embodiment of the invention is a method for manufacturing a porous glass substrate by using glass powder, comprising the following steps:
a.混料:將玻璃粉末(1)裝填於一容器(2)中,另將複數金屬線材(3)攙入玻璃粉末(1)形成一混合料,且使每一金屬線材(3)之局部貼抵於上述容器(2),先將混合料成型,再進一步混合有黏合劑,該黏合劑之氣化溫度低於玻璃粉末的熔融溫度,而該黏合劑係可為蠟。 a. Mixing: the glass powder (1) is filled in a container (2), and the plurality of metal wires (3) are further poured into the glass powder (1) to form a mixture, and each metal wire (3) is made. Partially adhering to the container (2), the mixture is first molded, and further mixed with a binder, the vaporization temperature of the binder is lower than the melting temperature of the glass powder, and the binder may be a wax.
b.加熱:將混合料加溫至玻璃粉末(1)之熔融溫度,並讓玻璃粉末(1)熔融,同時令黏合劑氣化。 b. Heating: The mixture is warmed to the melting temperature of the glass powder (1), and the glass powder (1) is melted while the binder is vaporized.
c.冷卻:讓含有金屬線材(3)的玻璃(4)降到常溫。 c. Cooling: The glass (4) containing the metal wire (3) is lowered to normal temperature.
d.蝕刻:將冷卻後之玻璃(4)以蝕刻方式去除金屬線材(3),形成一多孔隙(5)的玻璃基材。 d. Etching: The cooled glass (4) is etched to remove the metal wire (3) to form a porous (5) glass substrate.
在步驟a之後,也可先將混合料成型為特定形狀,例如為假山或芳香劑的容器,再進行步驟b。 After step a, the mixture may also be shaped into a specific shape, such as a container of rockery or fragrance, and step b is performed.
本發明方法藉由加入金屬線材(3),而與玻璃粉末(1)燒 結成含金屬線材(3)的玻璃基材,此時,金屬線材(3)與玻璃材料間的相對關係已定,再以蝕刻手段去除金屬線材(3),只保留玻璃材料,就形成多孔隙(5)的玻璃基材。 The method of the invention is fired with glass powder (1) by adding metal wire (3) Forming a glass substrate containing a metal wire (3). At this time, the relative relationship between the metal wire (3) and the glass material is determined, and then the metal wire (3) is removed by etching, and only the glass material is retained to form a porous layer. (5) Glass substrate.
而藉由調整金屬線材(3)的線徑大小,可以調整孔隙(5)之大小,調整金屬線材(3)相對玻璃粉末(1)的比例,可以調整孔隙率,甚至,形塑一些特殊的造形。本發明方法之製成品為多孔隙的玻璃基材,由於本身可吸收液態並慢慢釋放,因此,除了前述的假山外供水或液態肥料外,也可以吸收芳香精油、驅蟲(蚊)劑等,也可因有良好透光性及本身不規則的微結構,而可作為另一種玻璃藝術的素材。 By adjusting the wire diameter of the metal wire (3), the size of the pores (5) can be adjusted, the ratio of the metal wire (3) to the glass powder (1) can be adjusted, the porosity can be adjusted, and even some special shapes can be formed. Shape. The manufactured product of the method of the invention is a porous glass substrate, and since it can absorb liquid liquid and is slowly released, it can absorb aromatic oil, insect repellent (mosquito) agent, etc. in addition to the above-mentioned rockery water supply or liquid fertilizer. It can also be used as another material for glass art because of its good light transmission and its own irregular microstructure.
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TW098122719A TWI422542B (en) | 2009-07-06 | 2009-07-06 | A method of making a porous glass substrate using glass powder |
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TW098122719A TWI422542B (en) | 2009-07-06 | 2009-07-06 | A method of making a porous glass substrate using glass powder |
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TWI422542B true TWI422542B (en) | 2014-01-11 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW345533B (en) * | 1996-11-20 | 1998-11-21 | Dow Chemical Co | Method for making preforms |
TW200516061A (en) * | 2003-11-05 | 2005-05-16 | Neng-Yi Tu | Manufacturing method of glass with holes |
TWI237130B (en) * | 2003-06-26 | 2005-08-01 | Nikon Corp | Method for producing multilayer optical device |
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2009
- 2009-07-06 TW TW098122719A patent/TWI422542B/en not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW345533B (en) * | 1996-11-20 | 1998-11-21 | Dow Chemical Co | Method for making preforms |
TWI237130B (en) * | 2003-06-26 | 2005-08-01 | Nikon Corp | Method for producing multilayer optical device |
TW200516061A (en) * | 2003-11-05 | 2005-05-16 | Neng-Yi Tu | Manufacturing method of glass with holes |
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