TWI415569B - 含有疏水性農藥活性化合物之液體農藥組成物 - Google Patents
含有疏水性農藥活性化合物之液體農藥組成物 Download PDFInfo
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- TWI415569B TWI415569B TW97103415A TW97103415A TWI415569B TW I415569 B TWI415569 B TW I415569B TW 97103415 A TW97103415 A TW 97103415A TW 97103415 A TW97103415 A TW 97103415A TW I415569 B TWI415569 B TW I415569B
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 95
- 239000007788 liquid Substances 0.000 title claims abstract description 68
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 25
- 239000012872 agrochemical composition Substances 0.000 title abstract 3
- 239000003905 agrochemical Substances 0.000 title description 2
- -1 polyoxyethylene Polymers 0.000 claims abstract description 51
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 34
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 claims abstract description 32
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229940116423 propylene glycol diacetate Drugs 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 13
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- 230000000361 pesticidal effect Effects 0.000 claims description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 8
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- 239000013543 active substance Substances 0.000 abstract 2
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- 229940125807 compound 37 Drugs 0.000 description 17
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 16
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- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- YWBFPKPWMSWWEA-UHFFFAOYSA-O triazolopyrimidine Chemical compound BrC1=CC=CC(C=2N=C3N=CN[N+]3=C(NCC=3C=CN=CC=3)C=2)=C1 YWBFPKPWMSWWEA-UHFFFAOYSA-O 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- 229940035893 uracil Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本發明係關於含有疏水性農藥活性化合物之液體農藥組成物。
含有疏水性農藥活性化合物的液體農藥製劑之代表性例，包含乳劑及可流動劑(flowables)。當要噴施乳劑或可流動劑時，其等係以大量的水稀釋而做為水稀釋溶液來使用。在這種水稀釋溶液中，疏水性農藥活性化合物是由於表面活性劑的作用而成為分散於水中之微小油滴或固體粒子，而由於這種狀態在熱力學上是不安定的狀態，故含有疏水性農藥活性化合物的油滴放久後會分離，當疏水性農藥活性化合物是固體時，則在有些情況下固體粒子會沉澱而沉積。
在日本專利文獻JP 2003－128501A中揭示一種液體農藥製劑，其含有快伏草(qulzalofop－p－ethyl)，其係疏水性農藥化合物、聚氧乙烯苯乙烯基苯基醚、十二烷基苯磺酸鹽(dodecylbenzene sulfonate)、Solvesso 200(芳香烴溶劑，美國埃克森美孚化工公司產品)、及1,3－二甲基－2－咪唑啶酮(1,3－dimethyl－2－imidazolidinone)；但此種液體農藥組成物在水稀釋狀態並不一定會安定。
在上述情況下，本發明人為了要得到在水稀釋狀態下安定的含有疏水性農藥活性化合物的液體農藥製劑而進行
研究，並完成了本發明。
本發明係提供：(1)一種液體農藥組成物，係包括：0.5至30重量%的一種或更多種疏水性農藥活性化合物；1至20重量%之選自下列(A)群的一種或更多種非離子性表面活性劑；0至10重量%之一種或更多種陰離子性表面活性劑；6至60重量%之丙二醇二醋酸酯；及20至75重量%的1,3－二甲基－2－咪唑啶酮；(A)群：聚氧乙烯聚氧丙烯嵌段共聚物，聚氧乙烯聚氧丙烯烷基醚，聚氧乙烯聚氧丙烯烷基酚(phenol)，-聚氧乙烯聚氧丙烯聚苯乙烯基苯基醚，聚氧乙烯聚氧丙烯蓖麻油，聚氧乙烯烷基醚，聚氧乙烯烷基苯基醚，聚氧乙烯聚苯乙烯基苯基醚，聚氧乙烯蓖麻油，聚氧乙烯加氫蓖麻油，聚氧乙烯去水山梨醇脂肪酸酯，及聚氧乙烯脂族醇；(2)如上述(1)之液體農藥組成物，其中，非離子性表面活
性劑是選自下列(B)群者：(B)群：聚氧乙烯聚氧丙烯嵌段共聚物，聚氧乙烯聚氧丙烯烷基醚，聚氧乙烯聚氧丙烯烷基酚，聚氧乙烯聚氧丙烯聚苯乙烯基苯基醚，及聚氧乙烯聚氧丙烯蓖麻油；(3)如上述(1)或(2)之液體農藥組成物，其中，非離子性表面活性劑係聚氧乙烯聚氧丙烯嵌段共聚物；(4)如上述(1)至(3)任一項之液體農藥組成物，其中，陰離子性表面活性劑之量在1至10重量%之間；(5)如上述(4)之液體農藥組成物，其中，陰離子表面活性劑為烷基苯磺酸鹽；及(6)一種水稀釋溶液，係將上述(1)至(5)任一項之液體農藥組成物以10至10,000倍量的水稀釋而得者。
本發明之液體農藥組成物(以下有時稱為本液體農藥組成物)在水稀釋狀態下是安定的。
本發明中的疏水性農藥活性化合物是指對水不溶或難溶的農藥活性化合物，在25℃下對水的溶解度通常不高於0.5g/L，較佳為不高於0.1g/L，並在25℃下可以是固體或是液體之任何形式。
農藥活性化合物之例包含殺草活性化合物、殺真菌活性化合物(fungicidal active compound)、殺蟲(殺蟎)活
性化合物、及植物生長調節性化合物，並特別可例舉下列化合物為例。
殺草活性化合物之例，包含：二羧亞胺(dicarboxyimide)殺草活性化合物：氟胺草酯(flumiclorac－pentyl)[殺草性化合物1]，丙炔氟草胺(flumioxazin)[殺草性化合物2]，酮草酯(cinidon－ethyl)[殺草性化合物3]等；噠嗪酮(pyridazinone)殺草活性化合物：氟噠草酯(flufenpyr－ethyl)[殺草性化合物4]，溴吡啦酮(brompyrazone)[殺草性化合物5]等；尿嘧啶殺草活性化合物：氟丙嘧草酯(butafenacil)[殺草性化合物6]，除草定(bromacil)[殺草性化合物7]，氟普羅帕爾(flupropacil)[殺草性化合物8]，苯芬地酮(benzofendizone)[殺草性化合物9]等；三唑酮(triazolone)殺草活性化合物：唑酮草酯(carfentrazone－ethyl)[殺草性化合物10]，甲磺草胺(sulfentrazone)[殺草性化合物11]等；二苯基醚殺草活性化合物：乳氟禾草靈(lactofen)[殺草性化合物12]，必芬諾(bifenox)[殺草性化合物13]，氯硝苯酮(chlornitrophenone)[殺草性化合物14]，甲氧基護谷(chlomethoxynil)[殺草性化合物15]等；磺醯尿素(sulfonylurea)殺草活性化合物：磺醯磺隆(sulfosulfuron)[殺草性化合物16]，依速隆(imazosulfuron)[殺草性化合物17]，咽嘧磺隆
(nicosulfuron)[殺草性化合物18]，氟嘧磺隆(primisulfuron－methyl)[殺草性化合物19]，琳磺隆(rimsulfuron)[殺草性化合物20]，氯吡嘧磺隆(halosulfuron－methyl)[殺草性化合物21]，氟磺隆(prosulfuron)[殺草性化合物22]，吩磺隆(thifensulfuron－methyl)[殺草性化合物23]等；苯氧丙酸殺草活性化合物：克寄普(cloazifop)[殺草性化合物24]，禾草畏(diclofop)[殺草性化合物25]，伏寄普(fluazifop)[殺草性化合物26]等；三唑并嘧啶(triazolopyrimidine)殺草活性化合物：滴克速爛(diciosulam)[殺草性化合物27]，氯酯磺草胺(cloransulam)[殺草性化合物28]，唑嘧磺草胺(flumetsulam)[殺草性化合物29]，平速爛(penoxsulam)[殺草性化合物30]，吡速爛(pyloxsulam)[殺草性化合物31]，磺草唑胺(metosulam)[殺草性化合物32]等；苯胺殺草活性化合物：氟草胺普草克(picolinafen)[殺草性化合物33]，氟草胺(flufenacet)[殺草性化合物34]，滅芬草(mefenacet)[殺草性化合物35]等；三嗪(triazine)殺草活性化合物：草脫淨(atrazin)[殺草性化合物36]，嗪草酮(metribuzin)[殺草性化合物37]等；尿素殺草活性化合物：氟草隆(fluometuron)[殺草性化合物38]，異丙隆(isoproturon)[殺草性化合物39]，汰草龍(dymron)[殺草性化合物40]等；咪唑啉(imidazoline)殺草活性化合物：咪唑比(imazapyr)
[殺草性化合物41]，咪唑酸(imazaquin)[殺草性化合物42]，咪唑乙煙酸(imazethapyr)[殺草性化合物43]等；氯乙醯胺(chloroacetamide)殺草活性化合物：普拉草(pretilachlor)[殺草性化合物44]，丁基拉草(butachlor)[殺草性化合物45]等；胺甲酸硫醇酯(thiolcarbamate)殺草活性化合物：殺萘丹(benthiocarb)[殺草性化合物46]，禾草畏(esprocarb)[殺草性化合物47]，禾大壯(molinate)[殺草性化合物48]等；醯胺殺草活性化合物：溴芬諾(bromobutide)[殺草性化合物49]，敵稗(propanil)[殺草性化合物50]，唑草胺(cafenstrole)[殺草性化合物51]等；苯甲醯吡唑(benzoylpyrazole)殺草活性化合物：芐草唑(pyrazoxyfen)[殺草性化合物52]，吡草酮(benzofenap)[殺草性化合物53]等；及{2－氯－4－氟－5－[5,6,7,8－四氫－3－側氧基－1H,3H－[1,3,4]噻二唑并[3,4－a]噠嗪－1－亞基胺基]苯基硫基}乙酸甲酯(methyl{2－chloro－4－fluoro－5－[5,6,7,8－tetrahydro－3－oxo－1H,3H－[1,3,4]thiadiazolo[3,4－a]pyridazin－1－y lideneamino]phenylthio}acetate)[殺草性化合物54]，N－苯甲基－2－(α,α,α,4－四氟－間－甲苯氧基)丁醯胺(N－benzyl－2－(α,α,α,4－tetrafluoro－m－tolyloxy)butylamide)[殺草性化合物55]，及2－(2,4－二氯－5－丙－2－炔基氧苯基)－5,6,7,8－四氫－1,2,4-三唑并[4,3－a]吡啶
－3(2H)－酮(2－(2,4－dichloro－5－prop－2－ynyloxyphenyl)－5,6,7,8－tetrahydro－1,2,4－triazolo[4,3－a]pyridine－3(2H)－one)[殺草性化合物56]。
有關殺真菌活性化合物，其例包含：氮唑(azole)殺真菌活性化合物：丙可納唑(propiconazole)[殺真菌性化合物1]，三泰隆(triadimenol)[殺真菌性化合物2]，撲克拉(prochloraz)[殺真菌性化合物3]，平克座(penconazole)[殺真菌性化合物4]，得克利(tebuconazole)[殺真菌性化合物5]，護矽得(flusilazole)[殺真菌性化合物6]，烯唑醇(diniconazole)[殺真菌性化合物7]，溴可納唑(bromconazole)[殺真菌性化合物8]，環氧可納唑(epoxyconazole)[殺真菌性化合物9]，待克利(difenoconazole)[殺真菌性化合物10]，環克座(cyproconazole)[殺真菌性化合物11]，滅特座(metconazole)[殺真菌性化合物12]，賽福座(triflumizole)[殺真菌性化合物13]，四克利(tetraconazole)[殺真菌性化合物14]，邁克尼(myclobutanil)[殺真菌性化合物15]，晴苯唑(fenbuconazole)[殺真菌性化合物16]，菲克利(hexaconazole)[殺真菌性化合物17]，氟喹唑(fluquinconazole)[殺真菌性化合物18]，特利可納唑(trityconazole)[殺真菌性化合物19]，比多農(bitertanol)[殺真菌性化合物20]，依滅列(imazalil)
[殺真菌性化合物21]，護汰芬(flutriafol)[殺真菌性化合物22]等；嗎福林(morpholine)殺真菌活性化合物：芬普福(fenpropimorph)[殺真菌性化合物23]，三德芬(tridemorph)[殺真菌性化合物24]，芬普福(fenpropimorph)[殺真菌性化合物25]，達滅芬(dimethomorph)[殺真菌性化合物26]等；苯并咪唑(benzimidazole)殺真菌活性化合物：貝芬替(carbendazim)[殺真菌性化合物27]，免賴得(benomyl)[殺真菌性化合物28]，噻苯達唑(tiabendazole)[殺真菌性化合物29]，甲基多保淨(thiophanate－methyl)[殺真菌性化合物30]等；甲氧基丙烯酸酯(strobilurin)殺真菌活性化合物：亞托敏(azoxystrobin)[殺真菌性化合物31]，肟菌酯(trifloxystrobin)[殺真菌性化合物32]，啶氧菌酯(picoxystrobin)[殺真菌性化合物33]，百克敏(pyraclostrobin)[殺真菌性化合物34]，醚菌胺(dimoxystrobin)[殺真菌性化合物35]，氟嘧菌酯(fluoxastrobin)[殺真菌性化合物36]，苯氧菌胺(metominostrobin)[殺真菌性化合物37]，肟醚菌胺(orysastrobin)[殺真菌性化合物38]等；二羧亞胺殺真菌活性化合物：撲滅寧(procymidone)[殺真菌性化合物39]，依普同(iprodione)[殺真菌性化合物40]，乙烯菌核利(vinclozolin)[殺真菌性化合物41]等；
羧醯胺(carboxyamide)殺真菌活性化合物：福拉比(furametpyr)[殺真菌性化合物42]，滅普寧(mepronil)[殺真菌性化合物43]，福多寧(flutolanil)[殺真菌性化合物44]，噻氟菌胺(trifluzamide)[殺真菌性化合物45]等；苯胺并嘧啶(anilinopyrimidine)殺真菌活性化合物：嘧菌環胺(cyprodinil)[殺真菌性化合物46]，嘧黴胺(pyrimethanil)[殺真菌性化合物47]，滅派林(mepanipyrim)[殺真菌性化合物48]等；苯基吡咯(phenylpyrrole)殺真菌活性化合物：拌種咯(fenpiclonil)[殺真菌性化合物49]，咯菌腈(fludioxonil)[殺真菌性化合物50]等；胺基甲酸酯(carbamate)殺真菌活性化合物：纈霉威(iprovalicarb)[殺真菌性化合物51]，苯噻菌胺(benthiavalicarb)[殺真菌性化合物52]，乙黴威(diethofencarb)[殺真菌性化合物53]等；吡啶殺真菌活性化合物：白克列(boscalid)[殺真菌性化合物54]，扶吉胺(fluazinam)[殺真菌性化合物55]等；及(z)－2’－甲基乙醯苯4,6－二甲嘧啶－2－基腙，1－(甲氧羰基)＝2－(1－甲基乙基)－4－(2,6－二氯苯基)－5－胺基－1H－吡唑－3－酮(1－(methoxycarbonyl)＝2－(1－methylethyl)－4－(2,6－dichlorophenyl)－5－amino－1H－pyrazole－3－one)[殺真菌性化合物56]，1－[(乙基硫基)羰基]－2－(1－甲基乙基)－4－(2,6－二氯苯基)
－5－胺基－1H－吡唑－3－酮[殺真菌性化合物57]，1－[(2－丙烯基硫基)羰基]－2－(1－甲基乙基)－4－(2－甲苯基)－5－胺基－1H－吡唑－3－酮[殺真菌性化合物58]，5－甲基－1,2,4－三唑并－[3,4－b][1,3]苯並噻唑[殺真菌性化合物59]，及1,2,5,6－四氫吡咯并[3,2,1－ij]喹啉－4－酮，3－烯丙氧基－1,2－苯并噻唑1,1－二氧化物(3－allyloxy－1,2－benzothiazole 1,1－dioxide)[殺真菌性化合物60]。
有關殺蟲性(殺蟎性)活性化合物，其例包含：有機磷殺蟲活性化合物：撲滅松(fenitrothion)[殺蟲性化合物1]，大利松(diazinon)[殺蟲性化合物2]，陶斯松(chlorpyrifos)[殺蟲性化合物3]等；胺甲酸鹽殺蟲活性化合物：免扶克(benfuracarb)[殺蟲性化合物4]，安丹(propoxur)[殺蟲性化合物5]，丁基加保扶(carbosulfan)[殺蟲性化合物6]，加保利(carbaryl)[殺蟲性化合物7]，得滅克(aldicarb)[殺蟲性化合物8]，苯硫威(fenothiocarb)[殺蟲性化合物9]等；除蟲菊精類(pyrethroid)殺蟲活性化合物：依芬寧(etofenprox)[殺蟲性化合物10]，芬化利(fenvalerate)[殺蟲性化合物11]，益化利(esfenvalerate)[殺蟲性化合物12]，芬普寧(fenpropathrin)[殺蟲性化合物13]，賽滅寧(cypermethrin)[殺蟲性化合物14]，百滅寧(permethrin)[殺蟲性化合物15]，賽洛寧(cyhalothrin)[殺蟲性化合物16]，第滅寧(deltamethrin)[殺蟲性化合
物17]，乙腈菊酯(cycloprothrin)[殺蟲性化合物18]，福化利(fluvalinate)[殺蟲性化合物19]，畢芬寧(bifenthrin)[殺蟲性化合物20]，合芬寧(halfenprox)[殺蟲性化合物21]，特多寧(tralomethrin)[殺蟲性化合物22]，矽護芬(silafluofen)[殺蟲性化合物23]，酚丁滅蝨(d－phenothrin)[殺蟲性化合物24]，賽芬寧(cyphenothrin)[殺蟲性化合物25]，異列滅寧(d－resmethrin)[殺蟲性化合物26]，阿納寧(acrinathrin)[殺蟲性化合物27]，賽扶寧(cyfluthrin)[殺蟲性化合物28]，七氟菊酯(tefluthrin)[殺蟲性化合物29]，拜富寧(transfluthrin)[殺蟲性化合物30]，胺菊酯(tetramethrin)[殺蟲性化合物31]，亞列寧(allethrin)[殺蟲性化合物32]，右旋炔丙菊酯(prallethrin)[殺蟲性化合物33]，擬除蟲菊酯(enpenthrin)[殺蟲性化合物34]，炔咪菊酯(imiprothrin)[殺蟲性化合物35]，右旋炔呋菊酯(d－furamethrin)[殺蟲性化合物36]等；類尼古丁(nicotinoid)殺蟲活性化合物：可尼丁(clothianidin)[殺蟲性化合物37]，益達胺(imidacloprid)[殺蟲性化合物38]，噻滅多安(thiamethoxiam)[殺蟲性化合物39]，噻蟲啉(thiacloprid)[殺蟲性化合物40]等；苯甲醯苯尿素(benzoylphenylurea)殺蟲活性化合物：克福隆(chlorfluazuron)[殺蟲性化合物41]，得福隆(teflubenzuron)[殺蟲性化合物42]，氟芬隆
(flufenoxuron)[殺蟲性化合物43]，雙三氟蟲脲(bistrifluron)[殺蟲性化合物44]，布芬淨(buprofezin)[殺蟲性化合物45]，三福隆(triflumuron)[殺蟲性化合物46]等；吡唑殺蟲活性化合物：乙酞蟲臘(acetoprole)[殺蟲性化合物47]，乙硫蟲腑(ethiprole)[殺蟲性化合物48]，芬普尼(fipronil)[殺蟲性化合物49]，白克松(pyraclofos)[殺蟲性化合物50]等；保幼激素(juvenile hormone)殺蟲活性化合物：百利普芬(pyriproxyfen)[殺蟲性化合物51]，芬諾克(fenoxycarb)[殺蟲性化合物52]等；及(RS)－5－三級丁基－2－[2－(2,6－二氟苯基)－4,5－二氫－1,3－唑－4－基]苯基乙基醚[(RS)－5－tertiarybutyl－2－[2－(2,6－difluorophenyl)－4,5－dihydro－1,3－oxazol－4－yl]phenetole][殺蟲性化合物53]，及2,6－二氯－4－(3,3－二氯烯丙氧基)苯基3－[5－(三氟甲基)－2－吡啶氧基]丙基醚[殺蟲性化合物54]。
有關植物生長調節性化合物，其例包含氮唑(azole)植物生長調節性化合物：烯效唑－P(uniconazole－P)[植物生長調節性化合物1]，巴克素(paclobutrazol)[植物生長調節性化合物2]等：及(RS)－4’－氯－2’－(α－羥苯甲基)異尼古丁苯胺[(RS)－4’－chloro－2’－(α－hydroxybenzyl)isonicotineanilide][植物生長調節性化合物3]。
上述農藥活性化合物在已知文獻，例如農藥手冊(Pesticide Manual)第13版(英國作物保護委員會在1987年出版)或類似出版物等已有說明。
本液體農藥組成物可含有一種或更多種該等疏水性農藥活性化合物，而在本液體農藥組成物中，疏水性農藥活性化合物之總量在0.5至30重量%之間，以0.5至25重量%較佳。
在本液體農藥組成物中，就算是很難溶解於芳香族烴溶劑(具體而言，在25℃下於二甲苯中的溶解度不超過10g/L)之固體疏水性農藥活性化合物也可製成具有實用性濃度的液體農藥製劑。
在本發明中，選自(A)群的非離子性表面活性劑(以下稱為本非離子性表面活性劑)可單獨或組合使用，在本液體農藥組成物中，本非離子性表面活性劑的總量在1至20重量%之間，以1至15重量%較佳，而以1至12重量%更佳。
本非離子性表面活性劑具有來自聚氧乙烯構造的部分構造(CH2
CH2
O)n
，n在部分構造中通常介於4至60之間。除此之外，在本非離子性表面活性劑中，在來自聚氧乙烯構造的部分構造(CH2
CH2
O)p
、與來自聚氧丙烯構造的部分構造(CH(CH3
)CH2
O)q
中，p：q之比值宜在1：0.5至2.0之間。
在本發明中，非離子性表面活性劑係以聚氧乙烯聚氧丙烯嵌段共聚物為佳。
有關聚氧乙烯聚氧丙烯嵌段共聚物，可使用市售的表面活性劑，例如Teric PE 64(Huntsman公司產品)。
有關聚氧乙烯聚氧丙烯烷基醚，可使用市售的表面活性劑，例如Antarox BO/327(均為Rhodia Nicca公司產品)。
有關聚氧乙烯烷基苯基醚，可使用市售的表面活性劑，例如Solpor T26(東邦(Toho)化學工業公司產品)。
有關聚氧乙烯蓖麻油，可使用市售的表面活性劑，例如Alkamuls OR40、Alkamuls BR(均為Rhodia Nicca公司產品)。
有關聚氧乙烯加氫蓖麻油，可使用市售的表面活性劑，例如NIKKOL HCO－20(Nikko化學公司產品)。
有關聚氧乙烯烷基醚，可使用市售的表面活性劑，例如Newcol 1100、Newcol 1105(均為日本乳化劑公司產品)。
在本發明中，陰離子表面活性劑之例可為選自下列(C)群之陰離子表面活性劑，其可單獨使用或組合使用。在本液體農藥組成物中，陰離子表面活性劑之總量在0至10重量%之間，以0至8重量%較佳，以1至7重量%更佳。
(C)群：芳基磺酸鹽，例如十二烷基苯磺酸鹽等；聚氧乙烯(聚)芳基芳基醚硫酸鹽，例如聚氧乙烯二苯乙烯基苯基醚硫酸鹽等；聚氧乙烯(聚)芳基芳基醚磷酸鹽，例如聚氧乙烯三苯乙烯基苯基醚磷酸鹽等；聚氧乙烯烷基芳基磷酸鹽；及聚氧乙烯烷基磷酸鹽。
一般而言，磺酸鹽、硫酸鹽及磷酸鹽之實例包含鈉鹽、鉀鹽及銨鹽。
本農藥乳劑所包含之丙二醇二醋酸酯之量在6至60
重量%之間，以15至60重量%為佳。
本液體農藥組成物所包含之1,3－二甲基－2－咪唑啶酮之量在20至75重量%之間，以25至50重量%為佳。
在本發明中，有關丙二醇二醋酸酯及1,3－二甲基－2－咪唑啶酮，可使用市售產品。
在本液體農藥組成物中，丙二醇二醋酸酯與1,3－二甲基－2－咪唑啶酮之重量比以在10：90至50：50之間為佳。除此之外，相對於1重量份之疏水性農藥活性化合物，1,3－二甲基－2－咪唑啶酮通常不低於1.5重量份。
本液體農藥組成物之具體例如下所示：一種液體農藥組成物，其係包括：疏水性農藥活性化合物0.5至30重量%，選自(B)群之非離子性表面活性劑1至20重量%，陰離子表面活性劑0至10重量%，丙二醇二醋酸酯6至60重量%，及1,3－二甲基－2－咪唑啶酮20至75重量%；一種液體農藥組成物，實質上係由下列物所製成：疏水性農藥活性化合物0.5至30重量%，選自(B)群之非離子性表面活性劑1至20重量%，陰離子表面活性劑0至10重量%，丙二醇二醋酸酯6至60重量%，及1,3－二甲基－2－咪唑啶酮20至75重量%，其中，丙二醇二醋酸酯及1,3-二甲基－2－咪唑啶酮之重量比係在10：90至50：50之間，及相對於1重量份之疏水
性農藥活性化合物，1,3－二甲基－2－咪唑啶酮不低於1.5重量份；一種液體農藥組成物，其係包括：疏水性農藥活性化合物0.5至30重量%，聚氧乙烯聚氧丙烯嵌段共聚物1至20重量%，陰離子表面活性劑0至10重量%，丙二醇二醋酸酯6至60重量%，及1,3－二甲基－2－咪唑啶酮20至75重量%；一種液體農藥組成物，其係包括：疏水性農藥活性化合物0.5至25重量%，選自(B)群之非離子性表面活性劑1至15重量%，陰離子表面活性劑0至8重量%，丙二醇二醋酸酯15至60重量%，及1,3－二甲基－2－咪唑啶酮25至50重量%；一種液體農藥組成物，其係包括：疏水性農藥活性化合物0.5至25重量%，聚氧乙烯聚氧丙烯嵌段共聚物1至15重量%，陰離子表面活性劑0至8重量%，丙二醇二醋酸酯15至60重量%，及1,3－二甲基－2－咪唑啶酮25至50重量%；本液體農藥組成物，視需要可包含用於製劑之輔助劑，例如抗氧化劑、著色劑、香料、增效劑、藥物反應緩和劑(drug－induced suffering－alleviating agents)等。
抗氧化劑之例包含3－/2－三級丁基－4－羥基茴香醚
(3－/2－t－butyl－4－hydroxyanisole)、丁基化羥基甲苯(butylated hydroxytoluene)等，而著色劑之例包含玫瑰紅B(Rhodamine B)、黃色4號、藍色1號、紅色2號等。
在本液體農藥組成物中，製劑輔助劑之總量在0至5重量%之間。
本液體農藥組成物可藉由下述方法製造：例如將疏水性農藥活性化合物、本非離子性表面活性劑、以及視需要之陰離子表面活性劑及製劑輔助劑加入丙二醇二醋酸酯與1,3－二甲基－2－咪唑啶酮之混合溶劑中，如需要則加熱(不超過80℃)，將混合物攪扮至成為均勻溶液為止，必要時過濾該溶液。
本液體農藥組成物是實質上由一連續相形成之均勻液體。
本液體農藥組成物是以水稀釋而使用。本液體農藥組成物通常係以水將液體農藥組成物稀釋至10至10,000倍後使用，以20至5,000倍較佳。一般而言，使用的水可以是硬水(含有大量的鈣離子及/或鎂離子之水；水中的鈣離子及鎂離子之總量是以其對應碳酸鹽之ppm作為硬度表示)或軟水(含有小量鈣離子及/或鎂離子之水)，或可為視情況添加例如擴展劑、無機鹽等輔助劑之水。
於本液體農藥組成物以10至10,000倍量之水稀釋後所得之水稀釋溶液(下面稱為本水稀釋溶液)中，疏水性農藥活性化合物與本非離子性表面活性劑係溶解於水中，或成為含有疏水性農藥活性化合物的小液滴，其具有夠小的
顆粒直徑，故該溶液外觀與習知農藥乳劑之水稀釋液大不相同。亦即，不含著色物的本水稀釋溶液具有透明或帶灰藍色透明外觀。
舉例而言，液體農藥組成物以100倍量之水稀釋後，立即以550nm波長之透射光所測定的吸光度通常在0.001至1之間，而習知農藥乳劑的水稀釋溶液在相同條件下的吸光度大於2，由此可將本液體農藥組成物與習知農藥乳劑加以區別。吸光度之測定可用紫外光及可見光分光光度計(例如島津公司的UV－2500 PC型)。
以下將以實施例、試驗例等詳細說明本發明，但本發明不限於該等實施例。
在20℃下，秤取殺真菌性化合物58(含有5.00g活性成分)，十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液1)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙
二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液2)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(45.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(下文稱之為本溶液3)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(55.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液4)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(65.0g)於100ml容量瓶中，以丙
二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液5)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(75.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液6)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(6.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(6.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(45.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液7)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(6.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(6.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(55.0g)於100ml容量瓶中，以丙
二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液8)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(6.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(6.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(65.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液9)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(6.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(6.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(75.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液10)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯脂族醇(3.00g，Akzo Nobel公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋
酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液11)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯三苯乙烯基苯基醚(3.00g，Rhodia Nicca公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液12)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯烷基醚(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液13)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯蓖麻油(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為
本發明之液體農藥組成物(以下稱之為本溶液14)。
在20℃下，秤取殺蟲性化合物37(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯去水山梨醇單油酸酯(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液15)。
在20℃下，秤取殺草性化合物2(含有5.00g活性成分)、十二烷基苯磺酸鈣(3.00g，Huntsman公司產品)、聚氧乙烯聚氧丙烯嵌段共聚物(3.00g，Stepan公司產品)及1,3－二甲基－2－咪唑啶酮(35.0g)於100ml容量瓶中，以丙二醇二醋酸酯將總體積調整為100ml，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液16)。
在附有瓶蓋的100ml量筒中加入99ml的CIPAC標準硬水D(CIPAC standard water D)(342ppm)，在定溫水浴中保持溫度於30℃一段時間。然後將本溶液1至16各取1ml添加於量筒中，將該量筒以每2秒一次的速率上下反轉10次，再把量筒放在30℃定溫水浴中保持溫度30℃達2小時。然後觀察每一支量筒中稀釋溶液的狀態，發現本液體
農藥組成物1至16全部都保持安定的狀態，有透明的外觀。
在20℃下，秤取殺草性化合物2(含有3.00g活性成分)、聚氧乙烯去水山梨醇單月桂酸酯(15.00g，Rhodia Nicca公司產品)、1,3－二甲基－2－咪唑啶酮(67.0g)、及丙二醇二醋酸酯(15.0g)，將此混合物攪拌成均勻溶液，成為本發明之液體農藥組成物(以下稱之為本溶液17)。
在20℃下，秤取殺草性化合物2(含有3.00g活性成分)、聚氧乙烯去水山梨醇單月桂酸酯(15.00g，Rhodia Nicca公司產品)、1,3－二甲基－2－咪唑啶酮(67.0g)及丙二醇單甲基醚(15.0g)，將此混合物攪拌成均勻溶液，成為比較液體農藥組成物(下文稱之為比較溶液1)。
在附有瓶蓋的100ml量筒中加入99ml的CIPAC標準硬水D(342ppm)，在定溫水浴中保持溫度於30℃一段時間。然後將本溶液17及比較溶液1各1ml添加於量筒中，將該量筒以每2秒一次的速率上下反轉10次，再把量筒放在30℃定溫水浴中保持溫度30℃達2小時。然後觀察每一支量筒中溶液的狀態，發現本溶液17保持安定的狀態，有灰藍色(pale bluish)透明的外觀。另一方面，比較溶液1則有大量結晶沉積於量筒底部。
如上所述，本發明之液體農藥組成物在水稀釋狀態下是非常安定的，係有用的含有農藥活性化合物的製劑。
Claims (6)
- 一種液體農藥組成物，係包括：0.5至30重量%的一種或更多種疏水性農藥活性化合物；1至20重量%之選自下列(A)群的一種或更多種非離子性表面活性劑；0至10重量%之一種或更多種陰離子性表面活性劑；6至60重量%之丙二醇二醋酸酯；及20至75重量%的1,3-二甲基-2-咪唑啶酮；(A)群：聚氧乙烯聚氧丙烯嵌段共聚物，聚氧乙烯聚氧丙烯烷基醚，聚氧乙烯聚氧丙烯烷基酚(phenol)，聚氧乙烯聚氧丙烯聚苯乙烯基苯基醚，聚氧乙烯聚氧丙烯蓖麻油，聚氧乙烯烷基醚，聚氧乙烯烷基苯基醚，聚氧乙烯聚苯乙烯基苯基醚，聚氧乙烯蓖麻油，聚氧乙烯加氫蓖麻油，聚氧乙烯去水山梨醇脂肪酸酯，及聚氧乙烯脂族醇。
- 如申請專利範圍第1項之液體農藥組成物，其中，該非離子性表面活性劑是選自下列(B)群者： (B)群：聚氧乙烯聚氧丙烯嵌段共聚物，聚氧乙烯聚氧丙烯烷基醚，聚氧乙烯聚氧丙烯烷基酚，聚氧乙烯聚氧丙烯聚苯乙烯基苯基醚，及聚氧乙烯聚氧丙烯蓖麻油。
- 如申請專利範圍第1項之液體農藥組成物，其中，該非離子性表面活性劑為聚氧乙烯聚氧丙烯嵌段共聚物。
- 如申請專利範圍第1項之液體農藥組成物，其中，該陰離子性表面活性劑之量係在1至10重量%之間。
- 如申請專利範圍第4項之液體農藥組成物，其中，該陰離子表面活性劑為烷基苯磺酸鹽。
- 一種水稀釋溶液，係將申請專利範圍第1項之液體農藥組成物以10至10,000倍量的水稀釋而得者。
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| TW200838419A (en) | 2008-10-01 |
| CN101233850A (zh) | 2008-08-06 |
| JP2008184457A (ja) | 2008-08-14 |
| TR200800530A2 (tr) | 2008-09-22 |
| BRPI0800159A (pt) | 2008-09-16 |
| CA2618971A1 (en) | 2008-07-31 |
| ITTO20080061A1 (it) | 2008-08-01 |
| AR065064A1 (es) | 2009-05-13 |
| GB2446288B (en) | 2012-02-22 |
| MX2008001473A (es) | 2009-02-24 |
| GB0801705D0 (en) | 2008-03-05 |
| DE102008006997A1 (de) | 2008-08-21 |
| US20080182754A1 (en) | 2008-07-31 |
| CN101233850B (zh) | 2013-02-06 |
| DE102008006997B4 (de) | 2018-10-04 |
| ES2324453B1 (es) | 2010-05-31 |
| AU2008200451B2 (en) | 2013-03-28 |
| KR20080071928A (ko) | 2008-08-05 |
| FR2911757B1 (fr) | 2012-12-07 |
| AU2008200451A1 (en) | 2008-08-14 |
| FR2911757A1 (fr) | 2008-08-01 |
| GB2446288A (en) | 2008-08-06 |
| ZA200801040B (en) | 2008-12-31 |
| JP5092428B2 (ja) | 2012-12-05 |
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