TWI414319B - Low toxicity nail polish formula - Google Patents
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Abstract
Description
本發明係有關於一種低毒性指甲油配方,特別是指利用低毒性化妝品原料調配製成之指甲油。 The present invention relates to a low toxicity nail polish formulation, and more particularly to a nail polish prepared by blending a low toxicity cosmetic material.
隨著現代女性對於整體造型的注重,指甲造型已經成為今日追求流行的重要元素之一,其中藝人明星的指甲造型已極為普遍,加上傳播媒體的大量報導,帶領起指尖造型的風潮,許多愛美的女性都會擦上指甲油或是做彩繪指甲等,指甲油的顏色、品牌也隨之越來越多,在這龐大的指甲美容市場所帶來的商機背後,卻也隱藏著危害健康的殺手,其關鍵在於指甲油成分中的甲苯(Toluene)、異丙醇(2-Propanol)、乙酸乙酯(Ethyl Acetate)、乙酸丁酯(Butyl Acetate)、丙酮(Acetone)等,此外指甲油中常見的成分還有:甲醛(Formaldehyde)、甲醇(Methyl Alcohol)、鄰苯二甲酸二丁酯(Dibutyl Phthalate)、乙酸(Acetic Acid)、硝化纖維素(Nitrocellulose)等致癌有機溶劑或其他環境荷爾蒙,很容易在消費者塗抹時,由口、鼻吸入,這類物質不僅會影響身體健康,引發癌症,例如乳癌、子宮癌、攝護腺癌等,更會導致孕婦流產、胎兒畸形等等。 With the attention of modern women to the overall shape, nail styling has become one of the important elements of today's pursuit of fashion. Among them, the nail shape of the artist star has become extremely common, coupled with a large number of reports from the media, leading the trend of fingertip styling, many Women who love beauty will wear nail polish or make painted nails. The color and brand of nail polish will also increase. Behind the business opportunities brought by this huge nail beauty market, there are hidden health hazards. The key to the killer is toluene, 2-propanol, ethyl acetate (Ethyl Acetate), butyl acetate (Butyl Acetate), acetone (Acetone), etc. in the nail polish composition, in addition to nail polish. Common ingredients include: Formaldehyde, Methyl Alcohol, Dibutyl Phthalate, Acetic Acid, Nitrocellulose, and other carcinogenic organic solvents or other environmental hormones. It is easy to inhale by the mouth and nose when the consumer applies it. These substances not only affect the health of the body, but also cause cancer, such as breast cancer, uterine cancer, prostate cancer. , But will also lead to miscarriage, fetal malformation and so on.
因此若能利用低毒性化學材料取代化學溶劑應用於指甲油中,將可減少指甲油中毒性對人體所造成的傷害,亦可為指甲油市場帶來 新的契機,因此本發明人秉持不斷創新研發之精神,而開發出一種低毒性指甲油配方,其係混合一重量百分比為30%至60%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物(Cyclopentasiloxane and Trimethylsiloxysilicate)、一重量百分比為30%至60%之添加劑及一重量百分比為8%至12%之油性色素三原色。 Therefore, if low-toxic chemical materials can be used instead of chemical solvents in nail polish, it will reduce the harm caused by the toxicity of nail polish to the human body, and it can also bring to the nail polish market. With the new opportunity, the inventors have developed a low-toxic nail polish formula by mixing the spirit of continuous innovation and research, which is a mixture of 30% to 60% by weight of polyoxyxides and trimethyldecyloxy fluorene. Cyclopentasiloxane and Trimethylsiloxysilicate, 30% to 60% by weight of an additive and 8% to 12% by weight of an oily pigment trichromatic.
進一步,該添加劑係為十甲基環五矽氧烷(Decamethyl Cyclopentasiloxane)、無水酒精、聚乙烯吡咯烷酮(PVP)或蜜蠟任一種或其組合。 Further, the additive is any one or a combination of Decamethyl Cyclopentasiloxane, anhydrous alcohol, polyvinylpyrrolidone (PVP) or beeswax.
其中:Cyclopentasiloxane(and Trimethylsiloxysilicate)是矽化合物之類物質,可作為疏水膜或防水劑,清爽性不黏膩,安全性高,可替代合成酯與植物油,而Decamethyl Cyclopentasiloxane是一種滑順劑,屬於無色無味透明的揮發性矽油,由於其易揮發之特性,常作為化妝品中之載體,幫助其他物質進入肌膚,並能降低表面張力,使產品清爽好塗抹,提昇絲滑觸感,不黏膩,不具刺激性,PVP則具有優良的溶解性、低毒性、成膜性、絡合性、表面活性和化學穩定性,蜜蠟則為天然無毒性物質,用於乳化劑之用途,因此利用這些材料製備新的指甲油配方,降低指甲油的毒性,減少對人體的傷害。 Among them: Cyclopentasiloxane (and Trimethylsiloxysilicate) is a compound such as hydrazine compound, which can be used as a hydrophobic film or water repellent. It is non-sticky and safe. It can replace synthetic esters and vegetable oils. Decamethyl Cyclopentasiloxane is a smoothing agent and is colorless. Odorless and transparent volatile eucalyptus oil, because of its volatile nature, often acts as a carrier in cosmetics, helps other substances to enter the skin, and can reduce the surface tension, so that the product is refreshed and smeared, and the silky touch is improved, not sticky, not Irritant, PVP has excellent solubility, low toxicity, film formation, complexation, surface activity and chemical stability. Beeswax is a natural non-toxic substance used in emulsifiers, so it is prepared by using these materials. A new nail polish formula that reduces the toxicity of nail polish and reduces damage to the human body.
前述低毒性指甲油之調配成份百分比可約略羅列如下: The percentage of the formulated components of the aforementioned low-toxic nail polish can be roughly listed as follows:
A01.混合44%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、44%之十甲基環五矽氧烷及10%之油性色素三原色。 A01. Mixing 44% of a composition of polyoxyxides and trimethyldecyloxydecanoate, 44% of decamethylcyclopentaoxane and 10% of an oily pigment tri primary color.
A02.混合44%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、44%之無水酒精及10%之油性色素三原色。 A02. Mix 44% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 44% of anhydrous alcohol and 10% of oily pigments.
A03.混合59%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、29%之十甲基環五矽氧烷及10%之油性色素三原色。 A03. Mixing 59% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 29% of decamethylcyclopentaoxane and 10% of the oily pigment tri primary colors.
A04.混合29%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、59%之十甲基環五矽氧烷及10%之油性色素三原色。 A04. Mix 29% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 59% of decamethylcyclopentaoxane and 10% of oily pigments.
A05.混合29%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、59%之無水酒精及10%之油性色素三原色。 A05. Mixing 29% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 59% of anhydrous alcohol and 10% of oily pigments.
A06.混合59%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、29%之無水酒精及10%之油性色素三原色。 A06. Mixing 59% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 29% of anhydrous alcohol and 10% of oily pigments.
A07.混合35%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、35%之十甲基環五矽氧烷、18%之無水酒精及10%之油性色素三原色。 A07. Mixing 35% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 35% of decamethylcyclopentaoxane, 18% of anhydrous alcohol and 10% of oily pigments.
A08.混合35%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、18%之十甲基環五矽氧烷、35%之無水酒精及10%之油性色素三原色。 A08. Mixing 35% of a composition of polyoxyxides and trimethyldecyloxydecanoate, 18% of decamethylcyclopentaoxane, 35% of anhydrous alcohol, and 10% of oily pigments.
A09.混合53%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、26%之十甲基環五矽氧烷、4.5%之聚乙烯吡咯烷酮、4.5%之蜜蠟及10%之油性色素三原色。 A09. Mixing 53% of a composition of polyoxyxides and trimethyldecyloxydecanoate, 26% of decamethylcyclopentaoxane, 4.5% of polyvinylpyrrolidone, 4.5% of beeswax and 10 % of the oily pigments of the three primary colors.
A10.混合53%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、26%之無水酒精、4.5%之聚乙烯吡咯烷酮、4.5%之蜜蠟及10%之油性色素三原色。 A10. Mix 53% of the composition of polyoxyxides and trimethyldecyloxydecanoate, 26% of anhydrous alcohol, 4.5% of polyvinylpyrrolidone, 4.5% of beeswax and 10% of oily pigments.
A11.混合26%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、53%之無水酒精、4.5%之聚乙烯吡咯烷酮、4.5%之蜜蠟及10%之 油性色素三原色。 A11. Mixing 26% of polyoxosiloxane and trimethyldecyloxydecanoate composition, 53% anhydrous alcohol, 4.5% polyvinylpyrrolidone, 4.5% beeswax and 10% Oily pigments are three primary colors.
A12.混合56%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物、26%之無水酒精、3%之聚乙烯吡咯烷酮、3%之蜜蠟及10%之油性色素三原色。 A12. Mixing 56% of a composition of polyoxyxides and trimethyldecyloxydecanoate, 26% of anhydrous alcohol, 3% of polyvinylpyrrolidone, 3% of beeswax and 10% of oily pigments.
進一步,前述低毒性指甲油配方係混入一重量百分比為1.8%至2.2%之七彩亮片粉,增加所製成指甲油之豐富性。 Further, the aforementioned low-toxic nail polish formula is mixed with a color percentage of 1.8% to 2.2% of the seven-color sequin powder to increase the richness of the finished nail polish.
本發明主要功效在於:降低一般指甲油毒性對人體所造成的傷害,排除一般指甲油在塗抹時會揮發有毒的氣體,以及其溶劑在與指甲接觸時所產生的毒性對人體的傷害,可提供產業界做為製備低毒性配方指甲油的參考指標。 The main function of the invention is: reducing the damage caused by the general nail polish toxicity to the human body, eliminating the poisonous gas which the general nail polish will volatilize when applied, and the damage caused by the toxicity of the solvent when contacting the nail, and providing The industry uses it as a reference indicator for the preparation of low toxicity formula nail polish.
綜合上述技術特徵,本發明主要功效將可於下述實施例清楚呈現。 Combining the above technical features, the main effects of the present invention will be clearly shown in the following embodiments.
本實施例要說明的是一種低毒性指甲油配方,其係混合一重量百分比為30%至60%之聚矽氧化合物和三甲基矽烷氧基矽酸酯之組成物(Cyclopentasiloxane and Trimethylsiloxysilicate[Silicone 2])、一重量百分比為30%至60%之十甲基環五矽氧烷(Decamethyl Cyclopentasiloxane[Silicone 1])、無水酒精、聚乙烯吡咯烷酮(PVP)或蜜蠟任一種或其組合之添加劑及一重量百分比為8%至12%之油性色素三原色。 This embodiment is to illustrate a low toxicity nail polish formulation which is a mixture of 30% to 60% by weight of a polyxanthene oxide and a trimethylsiloxy phthalate (Cyclopentasiloxane and Trimethylsiloxysilicate [Silicone]. 2]), an additive of 30% to 60% by weight of Decamethyl Cyclopentasiloxane [Silicone 1], anhydrous alcohol, polyvinylpyrrolidone (PVP) or beeswax or a combination thereof And a weight percentage of 8% to 12% of the oily pigment three primary colors.
下表為A01至A12配方依前述比例調製之試驗樣品:
再依各該試驗樣品之調配重量,混入重量百分比為10%之油性色素三原色(依需求顏色作調配)及2%之七彩亮片粉,以增加指甲油之亮度。 According to the blending weight of each test sample, 10% by weight of the oily pigment three primary colors (mixed according to the required color) and 2% of the seven-color sequin powder are added to increase the brightness of the nail polish.
之後,以前述指甲油之試驗樣品進行成膜試驗,係將所製備好的指甲油均勻塗抹在30.5 cm×2.5 cm的玻璃片上,自然乾燥後成膜,每隔5分鐘進行指觸測試,一個試驗樣品測試6次,準確記錄成膜花費時間,並且測試市售快乾型指甲油、一般型指甲油、香水指甲油和水性撕除式指甲油成膜時間作為對照。 Then, the filming test was carried out on the test sample of the aforementioned nail polish, and the prepared nail polish was evenly spread on a glass piece of 30.5 cm×2.5 cm, and the film was naturally dried to form a film, and the finger touch test was performed every 5 minutes. The test samples were tested 6 times, the time taken for film formation was accurately recorded, and the film formation time of commercially available quick-drying nail polish, general nail polish, perfume nail polish, and aqueous tear-off nail polish was tested as a control.
下表為A01至A12試驗樣品之成膜時間試驗結果:
(單位:秒鐘) (Unit: second)
下表為市售指甲油成膜時間試驗結果:
(單位:秒鐘) (Unit: second)
試驗結果發現,含有無水酒精的配方所需的乾燥時間較短,較接近市售指甲油之成膜時間,甚至較市售指甲油之成膜時間快,且無水酒精比例越高,乾燥速度就越快,若只含有Silicone 1及Silicone 2成分,揮發速度較慢,因此所需的乾燥時間較長,故未來生產製造時,可適當增加無水酒精之比例。 The test results show that the formulation containing anhydrous alcohol requires shorter drying time, is closer to the filming time of commercially available nail polish, and even faster than the filming time of commercially available nail polish, and the higher the ratio of anhydrous alcohol, the drying speed The faster, if only the Silicone 1 and Silicone 2 components are contained, the volatilization rate is slow, so the drying time required is long, so the ratio of anhydrous alcohol can be appropriately increased in the future production and manufacture.
接著,進行前述指甲油之試驗樣品之附著力試驗,而由於目前指甲油並未有明確的附著力測試方法,因此本試驗利用油漆和指甲油附著力相似的特性,使用測試油漆附著力的「方格試驗器」進行測試。 Next, the adhesion test of the test sample of the aforementioned nail polish is performed, and since the nail polish does not have a clear adhesion test method, the test uses the similar adhesion property of the paint and the nail polish to test the adhesion of the paint. The tester is tested.
下表為A01至A12試驗樣品之附著力試驗結果:
下表為市售指甲油附著力試驗結果:
實驗結果發現,A01至A08附著力評定點數皆於2~4點之間,與市售一般溶劑型指甲油相較之下,所製備低毒性配方指甲油附著力較差,而A04和A06評定點數為2點,可得知Silicone 2比例較高時,附著力相對較差,但A09至A12附著力評定點數為6,可得知配方內有加入PVP及蜜蠟,附著力較好。 The results of the experiment showed that the adhesion points of A01 to A08 were between 2 and 4 points. Compared with the commercially available general-purpose nail polish, the adhesion of the prepared low-toxic formula nail polish was poor, while the A04 and A06 were evaluated. The number of points is 2 points. It can be known that the adhesion is relatively poor when the ratio of Silicone 2 is relatively high, but the adhesion rating of A09 to A12 is 6. It can be known that PVP and beeswax are added to the formulation, and the adhesion is good.
總結前述試驗結果,適當增加無水酒精成份,可縮短成膜時間,且雖然試驗結果本發明低毒性指甲油附著力較一般溶劑型指甲油附著力差,但適當添加PVP及蜜蠟仍可大幅提昇附著力,故仍然極具市場競爭力,並藉由前述試驗結果,可提供產業界做為製備低毒性配方指甲油的參考指標。 Summarizing the above test results, the appropriate addition of anhydrous alcohol components can shorten the film formation time, and although the test results show that the adhesion of the low-toxic nail polish of the present invention is inferior to that of the general solvent-type nail polish, the proper addition of PVP and beeswax can be greatly improved. Adhesion is still very competitive in the market, and the above test results can provide the industry as a reference indicator for the preparation of low toxicity formula nail polish.
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Citations (4)
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CN1133557A (en) * | 1993-08-27 | 1996-10-16 | 普罗克特和甘保尔公司 | Typical personal care composition containing polysiloxane-grafted adhesive polymer and drying aid |
US20030031637A1 (en) * | 2001-07-24 | 2003-02-13 | Yelena Loginova | Water resistant, wear resistant, and decorative cosmetic for hair |
US20050142079A1 (en) * | 2003-12-26 | 2005-06-30 | Garrison Mark S. | Oil in silicone emulsion and compositions containing same |
TW200946137A (en) * | 2008-03-04 | 2009-11-16 | Avon Prod Inc | Cosmetic compositions for imparting superhydrophobic films |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1133557A (en) * | 1993-08-27 | 1996-10-16 | 普罗克特和甘保尔公司 | Typical personal care composition containing polysiloxane-grafted adhesive polymer and drying aid |
US20030031637A1 (en) * | 2001-07-24 | 2003-02-13 | Yelena Loginova | Water resistant, wear resistant, and decorative cosmetic for hair |
US20050142079A1 (en) * | 2003-12-26 | 2005-06-30 | Garrison Mark S. | Oil in silicone emulsion and compositions containing same |
TW200946137A (en) * | 2008-03-04 | 2009-11-16 | Avon Prod Inc | Cosmetic compositions for imparting superhydrophobic films |
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