TWI388341B - Impression controlling agent - Google Patents
Impression controlling agent Download PDFInfo
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- TWI388341B TWI388341B TW95149417A TW95149417A TWI388341B TW I388341 B TWI388341 B TW I388341B TW 95149417 A TW95149417 A TW 95149417A TW 95149417 A TW95149417 A TW 95149417A TW I388341 B TWI388341 B TW I388341B
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- angle
- skin
- impression
- particle diameter
- control agent
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000000049 pigment Substances 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 20
- 238000000691 measurement method Methods 0.000 claims description 19
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 11
- 239000003086 colorant Substances 0.000 claims description 6
- 239000002649 leather substitute Substances 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 4
- 239000010445 mica Substances 0.000 description 24
- 229910052618 mica group Inorganic materials 0.000 description 24
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 20
- 229910052719 titanium Inorganic materials 0.000 description 20
- 239000010936 titanium Substances 0.000 description 20
- 239000002537 cosmetic Substances 0.000 description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000004040 coloring Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
- 229910001887 tin oxide Inorganic materials 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000000873 masking effect Effects 0.000 description 5
- -1 red 201 Chemical compound 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 4
- 229910000420 cerium oxide Inorganic materials 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 229910000423 chromium oxide Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000004313 glare Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000012780 transparent material Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 208000033962 Fontaine progeroid syndrome Diseases 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000012745 brilliant blue FCF Nutrition 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002506 iron compounds Chemical class 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- ZHWKJMGWTPJJRZ-UHFFFAOYSA-I magnesium pentafluoroaluminum(2-) Chemical compound [F-].[F-].[F-].[F-].[F-].[Mg++].[Al+3] ZHWKJMGWTPJJRZ-UHFFFAOYSA-I 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- ZEYKLMDPUOVUCR-UHFFFAOYSA-N 2-chloro-5-(trifluoromethyl)benzenesulfonyl chloride Chemical compound FC(F)(F)C1=CC=C(Cl)C(S(Cl)(=O)=O)=C1 ZEYKLMDPUOVUCR-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DKKCQDROTDCQOR-UHFFFAOYSA-L Ferrous lactate Chemical compound [Fe+2].CC(O)C([O-])=O.CC(O)C([O-])=O DKKCQDROTDCQOR-UHFFFAOYSA-L 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010039580 Scar Diseases 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 229940010556 ammonium phosphate Drugs 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229960002413 ferric citrate Drugs 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000004225 ferrous lactate Substances 0.000 description 1
- 235000013925 ferrous lactate Nutrition 0.000 description 1
- 229940037907 ferrous lactate Drugs 0.000 description 1
- 229940062993 ferrous oxalate Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical compound [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000004533 oil dispersion Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
Description
本發明係關於可表現肌膚各種印象的印象控制劑。The present invention relates to an impression control agent which can express various impressions of the skin.
作為塗佈於全臉的化妝料,在保護肌膚免於紫外線等損傷、或遮蔽肌膚凹凸或色不均所造成之肌膚缺點等目的下,係使用妝前劑、粉底等。另一方面,作為使臉印象變化者,則存在有眼影、腮紅等塗佈於肌膚一部份之化妝料。為了調整肌膚外觀,並實現目標之印象,習知的化妝係在一連串的化妝中連續使用前者及後者。As a cosmetic applied to the entire face, a pre-makeup agent, a foundation, and the like are used for the purpose of protecting the skin from damage such as ultraviolet rays or covering skin defects caused by unevenness or unevenness of color. On the other hand, as a person who changes the face impression, there are cosmetics such as eye shadow and blush applied to the skin. In order to adjust the appearance of the skin and achieve the impression of the target, the conventional makeup is used continuously in the series of makeup and the latter.
另外,專利文獻1中係提案有一種化妝料,其組合了:第1化妝料,含有具特定色相及彩度、及正反射光強度與擴散反射光強度之比的粉體成分;與第2化妝料,含有具與第1化妝料相異之色相、彩度、及正反射光強度與擴散反射光強度之比的粉體成分;並用於將第1化妝料與第2化妝料重疊塗佈。Further, Patent Document 1 proposes a cosmetic composition comprising: a first cosmetic containing a powder component having a specific hue and chroma, and a ratio of a specular reflected light intensity to a diffuse reflected light intensity; and a second cosmetic; The cosmetic material contains a powder component having a hue, a chroma, and a ratio of the intensity of the specular reflected light to the intensity of the diffuse reflected light, which is different from the first cosmetic, and is used to superimpose the first cosmetic material and the second cosmetic material. .
然而,仍未知有可藉由將一種劑塗佈於全臉,而表現各種肌膚印象的化妝料。However, there is still no known cosmetic material which can express various skin impressions by applying one agent to the entire face.
另一方面,粉底主要係以遮蔽黑班、雀班等色不均和痘疤、毛孔等之凹凸的肌膚缺點為目的而使用。近年來,消費者所需要的不僅止於調整膚色,並期望著可更漂亮地表現肌膚的粉底。On the other hand, the foundation is mainly used for the purpose of masking the unevenness of the skin such as black squad and squad, and the skin defects such as acne scars and pores. In recent years, consumers have not only stopped adjusting their skin tone, but also expect to be able to express the foundation of their skin more beautifully.
粉底中,作為著色劑係使用氧化鈦、氧化鐵、鐵藍、群藍、氧化鉻等之無機顏料,紅色201號、黃色401號、藍色1號、綠色3號等之有機顏料等。使用此等著色顏料、特別是於對膚色進行著色的情況下,若配合具有充分著色力之量的著色顏料,則因著色顏料的光吸收,將有完妝感暗沉和平板有如玩偶般之完妝感的情況。In the foundation, an inorganic pigment such as titanium oxide, iron oxide, iron blue, blue or chrome oxide, or an organic pigment such as red 201, yellow 401, blue 1 or green 3 is used as the colorant. When such a coloring pigment is used, particularly in the case of coloring a skin color, if a coloring pigment having a sufficient coloring power is blended, the light absorption of the coloring pigment will result in a dullness of the makeup and a doll like a doll. The feeling of makeup.
因此,為了實現具透明感和立體感之完妝感,而已提案有使用以雲母鈦為代表之珍珠顏料的方法(專利文獻2、專利文獻3、專利文獻4)。然而,僅使用珍珠顏料,雖可得到具透明感和立體感之完妝感,但在調整肌膚色不均和凹凸、同時表現各種肌膚印象方面,尚嫌不足。Therefore, in order to achieve a feeling of transparency and a three-dimensional finish, a method of using a pearl pigment represented by mica titanium has been proposed (Patent Document 2, Patent Document 3, and Patent Document 4). However, the use of only pearl pigments gives a feeling of transparency and three-dimensional finish, but it is not enough to adjust the unevenness and unevenness of the skin and to express various skin impressions.
(專利文獻1)日本專利特開2005-187417號公報(專利文獻2)日本專利特開平9-95431號公報(專利文獻3)日本專利特開2002-265332號公報(專利文獻4)日本專利特開2005-97218號公報(Patent Document 1) Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Open bulletin 2005-97218
本發明係提供一種肌膚的印象控制劑,其藉測定方法1以入射光角45°、受光角0°及45°所測定之各個彩度C* ab(0)及C* ab(45)的關係為C* ab(45)-C* ab(0)>0,且藉測定方法2所測定之明度L* 為30以上,色相角h為0°~90°,彩度C* ab為5以上。The present invention provides an impression control agent for skin, which is measured by the method 1 for each of the chroma C * ab(0) and C * ab(45) measured by an incident light angle of 45°, an acceptance angle of 0°, and 45°. The relationship is C * ab(45)-C * ab(0)>0, and the brightness L * measured by the measurement method 2 is 30 or more, the hue angle h is 0° to 90°, and the chroma C * ab is 5. the above.
(測定方法1)於黑色人工皮革上,均勻地塗佈該組成物而成為8mg/100cm2 ,使用變角測色計測定依CIE1976L* a* b* 表色系所規定之色彩值。(Measurement Method 1) The composition was uniformly applied to black artificial leather to be 8 mg/100 cm 2 , and the color value defined by the CIE 1976 L * a * b * color system was measured using a variable angle colorimeter.
(測定方法2)將該組成物置入分析管(cell)中,使用測色計對其表面測定依CIE1976L* a* b* 所規定之色彩值。(Measurement Method 2) The composition was placed in a cell, and the color value defined by CIE1976L * a * b * was measured on the surface thereof using a colorimeter.
本發明係關於藉由將一種劑塗佈於全臉,而可表現各種肌膚印象的肌膚之印象控制劑。The present invention relates to an impression control agent for a skin which can express various skin impressions by applying one agent to the entire face.
本發明者等人發現,在將具有特定光學特性、且外觀色為膚色之組成物塗佈於全臉時,將可表現肌膚的各種印象。The inventors of the present invention have found that when a composition having specific optical characteristics and an appearance color is applied to the entire face, various impressions of the skin can be expressed.
本發明之印象控制劑係藉由將其塗佈於全臉,而可表現肌膚的各種印象,且可得到具透明感之明亮妝感。The impression control agent of the present invention can express various impressions of the skin by applying it to the entire face, and can obtain a bright and transparent feeling.
另外,於使用作為粉底的情況下,將此塗佈時,可使肌膚色不均及凹凸不明顯,而得到具透明感之明亮妝感,且可表現肌膚的各種印象。In addition, when it is used as a foundation, when the coating is applied, the unevenness of the skin color and the unevenness of the skin can be made inconspicuous, and a clear and translucent feeling can be obtained, and various impressions of the skin can be expressed.
本發明之印象控制劑中,首先,藉測定方法1以入射光角45°、受光角0°及45°所測定之各個彩度C* ab(0)及C* ab(45)的關係為C* ab(45)-C* ab(0)>0,較佳C* ab(45)-C* ab(0)>1.5。In the impression control agent of the present invention, first, the relationship between the respective chroma C * ab(0) and C * ab(45) measured by the measurement method 1 at an incident light angle of 45°, a light receiving angle of 0°, and 45° is C * ab(45) - C * ab(0) > 0, preferably C * ab(45) - C * ab(0) > 1.5.
此C* ab(45)-C* ab(0)>0係意味著表面反射光之色較擴散反射光更濃,但其為0以下時,將無法使肌膚印象有所變化。This C * ab(45)-C * ab(0)>0 means that the color of the surface reflected light is thicker than the diffuse reflected light, but when it is 0 or less, the skin impression cannot be changed.
於此,測定方法1中,首先於黑色人工皮革上,使用海綿拿取該組成物,以成為8mg/100cm2 之方法輕輕地均勻塗佈於人工皮革上。將此使用變角測定計(例如變角分光測定系統(村上色彩研究所製,GCMS-4)),依入射光角45°、受光角0°及45°進行測定。將此時的2個反射光依CIE1976L* a* b* 表色系予以規定,以受光角0°之彩度作為C* ab(0)、以受光角45°之彩度作為C* ab(45),求得C* ab(45)-C* ab(0)。Here, in the measurement method 1, first, the composition was taken out on a black artificial leather using a sponge, and lightly uniformly applied to the artificial leather by a method of 8 mg/100 cm 2 . This is measured using a variable angle measuring instrument (for example, a variable angle spectrometry system (manufactured by Murakami Color Research Laboratory, GCMS-4)) at an incident light angle of 45° and a light receiving angle of 0° and 45°. The two reflected lights at this time are defined by the CIE1976L * a * b * color system, and the chroma of the light receiving angle of 0° is taken as C * ab(0), and the chroma of the light receiving angle of 45° is taken as C * ab ( 45), find C * ab (45) - C * ab (0).
另外,本發明之印象控制劑中,藉上述測定方法2所測定之明度L* 為30以上,色相角h為0°~90°,彩度C* ab為5以上。Further, in the impression control agent of the present invention, the lightness L * measured by the measurement method 2 is 30 or more, the hue angle h is 0 to 90, and the chroma C * ab is 5 or more.
測定方法2中,首先將該組成物置入分析管中,針對其表面使用測色計測定依CIE1976L* a* b* 表色系所規定之色彩值,亦即,求取明度L* 、色相角h、彩度C* ab。作為測定裝置,為可將對象物置入分析管中,並可測定其外觀色的裝置即可,例如可使用日本電色工業公司製之分光式色差計SE2000等。In the measurement method 2, the composition is first placed in an analysis tube, and a color value defined by the CIE1976L * a * b * color system is measured for the surface thereof, that is, the brightness L * and the hue angle are obtained. h, chroma C * ab. The measuring device may be a device in which an object can be placed in an analysis tube and the appearance color thereof can be measured. For example, a spectroscopic color difference meter SE2000 manufactured by Nippon Denshoku Industries Co., Ltd., or the like can be used.
另外,本發明之印象控制劑中,在於上述同樣地藉測定方法1以入射光角45°、受光角0°所測定之色相角h(0)為40°<h(0)<100°的情況下,亦即在擴散反射光為膚色、表面反射光亦為膚色的情況下,將可表現出華麗印象、或性感印象。Further, in the impression control agent of the present invention, the hue angle h(0) measured by the incident light angle of 45° and the light receiving angle of 0° is 40°<h(0)<100° by the measurement method 1 as described above. In other words, in the case where the diffused reflected light is a skin color and the surface reflected light is also a skin color, a gorgeous impression or a sexy impression can be exhibited.
另一方面,於藉測定方法1以入射光角45°、受光角-60°、0°及45°所測定之各個色度(a* ,b* )中,伴隨受光角-60°至0°的角度變化之a* b* 空間內的色度變化方向、與伴隨受光角-60°至45°的角度變化之a* b* 空間內的色度變化方向之差為10°以上情況,亦即,視所見角度而色相改變的情況下,例如擴散反射光為膚色、表面反射光為紅色的情況下,可表現出可愛印象、女性化印象;於擴散反射光為膚色、表面反射光為綠色的情況下,可表現出成熟印象、夢幻印象;於擴散反射光為膚色、表面反射光為藍色的情況下,可表現出冷靜印象、都會感印象。On the other hand, in the chromaticity (a * , b * ) measured by the measurement method 1 at an incident light angle of 45°, a light receiving angle of -60°, 0°, and 45°, the light receiving angle is -60° to 0. The angle of change of ° is a * b * The direction of chromaticity change in the space, and the difference in chromaticity change direction in the a * b * space with the angle of change of -60° to 45° with the received light angle is 10° or more. In other words, when the hue changes depending on the angle of view, for example, when the diffused reflected light is a skin color and the surface reflected light is red, a cute impression or a feminine impression can be expressed; and the diffused reflected light is a skin color and the surface reflected light is In the case of green, it can show a mature impression and a dreamy impression. When the diffuse reflected light is the skin color and the surface reflection light is blue, it can show a calm impression and a sense of the city.
上述所例舉之表現各印象的詞句,係將依成為各印象之光學特性的方式考量擴散反射光與表面反射光而設計之組成物,塗佈於模特兒全臉,將該化妝臉由專門評審員進行觀察,以所感覺到的印象作為傾向而掌握者。The above-mentioned examples of the expressions of each impression are designed to absorb the reflected light and the surface reflected light in a way that becomes the optical characteristic of each impression, and are applied to the entire face of the model, and the makeup face is specialized. The reviewer observes and grasps the person with the perceived impression.
更具體而言,由藉測定方法1以入射光角45°、受光角-60°、0°及45°所測定之各個色度(a* (-60),b* (-60))、(a* (0),b* (0))及(a* (45),b* (45))、式1及式2所求得之h’(45)及h’(0)的關係為|h’(45)-h’(0)|>10的情況下,將可表現出各種印象。More specifically, each chromaticity (a * (-60), b * (-60)) measured by the measurement method 1 at an incident light angle of 45°, an acceptance angle of -60°, 0°, and 45°, (a * (0), b * (0)) and (a * (45), b * (45)), the relationship between h' (45) and h' (0) obtained by Equations 1 and 2 In the case of |h'(45)-h'(0)|>10, various impressions can be exhibited.
(式1)h’(0)=tan- 1 ((b* (0)-b* (-60))/(a* (0)-a* (-60))) (式2)h’(45)=tan- 1 ((b* (45)-b* (-60))/(a* (45)-a* (-60)))(Formula 1) h'(0)=tan - 1 ((b * (0)-b * (-60))/(a * (0)-a * (-60))) (Formula 2)h' (45)=tan - 1 ((b * (45)-b * (-60))/(a * (45)-a * (-60)))
如此,本發明之印象控制劑可得到塗佈色(擴散反射成分)為膚色、並具透明感之明亮完妝感,且使表面反射光之色變化,藉此將可表現其色特有的印象。As described above, the impression control agent of the present invention can obtain a bright finish feeling in which the applied color (diffuse reflection component) is a skin color and has a transparent feeling, and the color of the surface reflected light is changed, whereby an impression unique to the color can be expressed. .
本發明之印象控制劑係藉由使用例如以下成分(A)、(B)及(C),則可予以製造:(A)平均粒徑5~15 μ m之黃氧化鐵被覆珍珠顏料;(B)平均粒徑5~15 μ m之紅氧化鐵被覆珍珠顏料;(C)平均粒徑20~50 μ m之珍珠顏料。The impression control agent of the present invention can be produced by using, for example, the following components (A), (B) and (C): (A) a yellow iron oxide-coated pearl pigment having an average particle diameter of 5 to 15 μm; B) Red iron oxide coated pearl pigment with an average particle diameter of 5 to 15 μm; (C) a pearl pigment having an average particle diameter of 20 to 50 μm.
本發明中,平均粒徑係以雷射散射式粒度分佈測定裝置(例如,堀場製作所公司製,LA-700型)所測定。In the present invention, the average particle diameter is measured by a laser scattering type particle size distribution measuring apparatus (for example, LA-700 type manufactured by Horiba, Ltd.).
相對地較小粒徑之成分(A)及成分(B)的珍珠顏料,係發色方向性較低,進行低發色。以成分(A)及成分(B)之氧化鐵被覆珍珠顏料製成膚色。The pearl pigment of the component (A) and the component (B) having a relatively small particle diameter is low in color development and low in color development. The skin color is made by coating the pearl pigment with the iron oxide of the component (A) and the component (B).
另一方面,相對地較大粒徑之成分(C)的珍珠顏料,係發色方向性較高,可得到高發色。此相對地較大粒徑之成分(C)的珍珠顏料將製成改變印象的光。如此,藉由並用成分(A)及(B)之相對較小粒徑的珍珠顏料與相對較大粒徑的成分(C)之珍珠顏料,則將上述h’(45)及h’(0)之關係引導為|h’(45)-h’(0)|>10,而可表現出各種印象。On the other hand, the pearl pigment of the component (C) having a relatively large particle diameter is high in color developing direction, and high coloring can be obtained. The pearl pigment of this relatively large particle size component (C) will be made to change the impression light. Thus, by using the pearl pigment of the relatively small particle diameter of the components (A) and (B) together with the pearl pigment of the component (C) of a relatively large particle diameter, the above h' (45) and h' (0) The relationship is guided by |h'(45)-h'(0)|>10, and various impressions can be expressed.
成分(A)係以黃氧化鐵被覆著珍珠顏料表面者,平均粒徑為5~15 μ m,較佳為6~13 μ m。此處所使用之珍珠顏料係以其干涉色為金色系者為佳。The component (A) is coated with yellow iron oxide on the surface of the pearl pigment, and has an average particle diameter of 5 to 15 μm, preferably 6 to 13 μm. The pearl pigment used herein is preferably one in which the interference color is a gold color.
於珍珠顏料表面被覆黃氧化鐵的方法,可使用常法。例如於氯化亞鐵、氯化鐵、硫酸亞鐵、硫酸鐵、硝酸亞鐵、硝酸鐵、草酸亞鐵、草酸鐵銨、硫酸鐵、磷酸鐵銨、檸檬酸鐵、乳酸亞鐵、反丁烯二酸鐵等之無機、有機鐵化合物水溶液中,添加珍珠顏料後,升溫至50~100℃、較佳80~100℃,使其熟成1~10小時,藉此使鐵化合物水解而於珍珠顏料表面析出黃色氧化鐵,於水洗、過濾後,將此於150℃以下進行乾燥,則可予以製造。A method of coating yellow iron oxide on the surface of a pearl pigment can be carried out by a conventional method. For example, ferrous chloride, ferric chloride, ferrous sulfate, ferric sulfate, ferrous nitrate, ferric nitrate, ferrous oxalate, ferric ammonium oxalate, ferric sulfate, ferric ammonium phosphate, ferric citrate, ferrous lactate, and anti-butyl After adding a pearl pigment to an aqueous solution of an inorganic or organic iron compound such as iron olefin dihydrate, the temperature is raised to 50 to 100 ° C, preferably 80 to 100 ° C, and the mixture is aged for 1 to 10 hours to hydrolyze the iron compound to the pearl. Yellow iron oxide is precipitated on the surface of the pigment, and after washing with water and filtering, the mixture is dried at 150 ° C or lower to be produced.
成分(B)係以紅氧化鐵被覆珍珠顏料表面者,平均粒徑為5~15 μ m、較佳6~13 μ m。此處所用之珍珠顏料係以其干涉色為紅色系、紫色系者較佳。The component (B) is coated with red iron oxide on the surface of the pearl pigment, and has an average particle diameter of 5 to 15 μm, preferably 6 to 13 μm. The pearl pigment used herein is preferably one in which the interference color is red or purple.
於珍珠顏料表面被覆紅氧化鐵的方法,可使用常法。例如,至被覆成分(A)之黃氧化鐵為止係利用相同方法,其後以150℃以上、較佳400℃以上進行燒成,藉此可被覆紅氧化鐵。A method of coating red iron oxide on the surface of a pearl pigment can be carried out by a conventional method. For example, the yellow iron oxide to the coating component (A) is subjected to the same method, and then fired at 150 ° C or higher, preferably 400 ° C or higher, whereby red iron oxide can be coated.
與成分(A)及(B)一起使用作為原料的珍珠顏料,係具有上述粒徑,並具有於薄片狀基材上被覆了折射率不同之光學穿透性材料的珍珠光澤者。作為薄片狀基材,可舉例如雲母、合成雲母、二氧化矽片、鋁片、氧化鋁化、氧化鐵片、玻璃片等,由高透明性方面而言,以雲母、合成雲母、玻璃片為較佳。作為被覆薄片狀基材之光學穿透性材料,可舉例如氧化鈦、氧化鋯、氧化鋅、氧化錫、氧化鐵、氧化鉻、二氧化矽、鉻、氮化鈦、鈦、氟化鎂鋁、水鋁石、氧化硼、此等混合物等,由發色之觀點而言,以氧化鈦、氧化錫、氧化鐵、此等混合物為較佳。更具體而言,較佳係以氧化鈦、或氧化鈦與氧化鐵或氧化錫之混合物被覆雲母表面者,例如可適合使用ENGELHARD公司製之Flamenco Satin系列、和ECKART公司製之PreStige Silk系列。The pearl pigment which is used as a raw material together with the components (A) and (B) has the above-mentioned particle diameter, and has a pearl luster which is coated with an optically transparent material having a different refractive index on a sheet-like base material. Examples of the sheet-like base material include mica, synthetic mica, cerium oxide sheet, aluminum sheet, alumina, iron oxide sheet, and glass sheet. From the viewpoint of high transparency, mica, synthetic mica, and glass sheet are used. It is better. Examples of the optically transparent material covering the sheet-like substrate include titanium oxide, zirconium oxide, zinc oxide, tin oxide, iron oxide, chromium oxide, cerium oxide, chromium, titanium nitride, titanium, and magnesium aluminum fluoride. From the viewpoint of color development, titanium oxide, tin oxide, iron oxide, and the like are preferred from the viewpoint of color development. More specifically, it is preferable to coat the surface of the mica with titanium oxide or a mixture of titanium oxide and iron oxide or tin oxide. For example, a Flamenco Satin series manufactured by ENGELHARD Co., Ltd., and a PreStige Silk series manufactured by ECKART Co., Ltd. can be suitably used.
另外,成分(A)及(B)中之氧化鐵的被覆率,係相對於珍珠顏料為1~15質量%,特佳為2~10質量%。若為此範圍之被覆率,則因為可不致使干涉色減弱而使遮蔽色不均的效果成為最適當,故較佳。Further, the coverage of the iron oxide in the components (A) and (B) is 1 to 15% by mass, particularly preferably 2 to 10% by mass, based on the pearl pigment. If the coverage is in this range, it is preferable because the effect of masking color unevenness can be minimized without weakening the interference color.
成分(A)及(B)皆平均粒徑未滿5 μ m時,則無法得到充分的發色效果,而若超過15 μ m,則無法表現自然膚色,而發生眩光,故不佳。When the average particle diameter of the components (A) and (B) is less than 5 μm, a sufficient color development effect cannot be obtained, and if it exceeds 15 μm, the natural skin color cannot be expressed and glare is generated, which is not preferable.
成分(A)及(B)的含量係其合計為總組成中2~15質量%,特佳為3~10質量%,其將可充分得到遮蔽色不均的效果,而完妝感亦自然。The content of the components (A) and (B) is 2 to 15% by mass in total, and particularly preferably 3 to 10% by mass, which can sufficiently obtain the effect of uneven coloration, and the finished makeup is naturally .
另外,成分(A)及(B)的含有比例(質量比)係(A):(B)=2:1~25:1,特佳為3:1~23:1,其粉底外觀及完妝感自然。In addition, the content ratio (mass ratio) of the components (A) and (B) is (A): (B) = 2:1 to 25:1, particularly preferably 3:1 to 23:1, and the appearance and finish of the foundation are The makeup is natural.
成分(C)係平均粒徑20~50 μ m、較佳22~45 μ m之珍珠顏料。於平均粒徑未滿20 μ m時,將無法充分得到表現漂亮肌膚的效果,若超過50 μ m,則因眩光變大而成為不自然完妝感,故不佳。珍珠顏料係具有於薄片狀基材上被覆了折射率不同之光學穿透性材料之珍珠光澤者。作為薄片狀基材,可舉例如雲母、合成雲母、二氧化矽片、鋁片、氧化鋁片、氧化鐵片、玻璃片等,由高透明性方面而言,較佳為雲母、合成雲母、玻璃片。作為被覆薄片狀基材之光學穿透性材料,可舉例如氧化鈦、氧化鋯、氧化鋅、氧化錫、氧化鐵、氧化鉻、二氧化矽、鉻、氮化鈦、鈦、氟化鎂鋁、水鋁石、氧化硼、此等混合物等,由發色之觀點而言,較佳為氧化鈦、氧化錫、氧化鐵、此等混合物。更具體而言,較佳係以氧化鈦、或氧化鈦與氧化鐵或氧化錫之混合物被覆雲母表面者。The component (C) is a pearl pigment having an average particle diameter of 20 to 50 μm, preferably 22 to 45 μm. When the average particle diameter is less than 20 μm, the effect of expressing a beautiful skin cannot be sufficiently obtained. When the average particle diameter exceeds 50 μm, the glare becomes large and the texture is unnaturally finished, which is not preferable. The pearl pigment has a pearl luster which is coated on a sheet-like substrate with an optically penetrating material having a different refractive index. Examples of the sheet-like base material include mica, synthetic mica, cerium oxide sheet, aluminum sheet, alumina sheet, iron oxide sheet, and glass sheet. From the viewpoint of high transparency, mica and synthetic mica are preferable. Glass piece. Examples of the optically transparent material covering the sheet-like substrate include titanium oxide, zirconium oxide, zinc oxide, tin oxide, iron oxide, chromium oxide, cerium oxide, chromium, titanium nitride, titanium, and magnesium aluminum fluoride. From the viewpoint of color development, it is preferably titanium oxide, tin oxide, iron oxide, or the like, and boehmite, boron oxide, and the like. More specifically, it is preferred to coat the surface of the mica with titanium oxide or a mixture of titanium oxide and iron oxide or tin oxide.
作為平均粒徑為20~50 μ m之雲母鈦,可使用例如ENGELHARD公司製之Flamenco系列、Flamenco Summit系列、Merck公司製之TIMIRON SUPER系列、和ECKART公司製之Prestige Silk系列、Prestige Bright系列。As the mica titanium having an average particle diameter of 20 to 50 μm, for example, a Flamenco series manufactured by ENGELHARD, a Flamenco Summit series, a TIMIRON SUPER series manufactured by Merck, a Prestige Silk series manufactured by ECKART, and a Prestige Bright series can be used.
於總組成中含有成分(C)1~15質量%、特別是2~10質量%者,將充分得到表現各種肌膚印象之效果,且可成為無眩光而自然的完妝感,故較佳。In the total composition, the component (C) is contained in an amount of 1 to 15% by mass, particularly 2 to 10% by mass, and the effect of expressing various skin impressions is sufficiently obtained, and a glare-free and natural makeup feeling is obtained, which is preferable.
本發明中,成分(A)、(B)及(C)的含有比例(質量比)為(A)+(B):(C)=1:3~5:1,特別是1:2~4:1者,將可充分兼顧保持自然且掩蓋色不均的效果與表現各種肌膚印象的效果,故較佳。In the present invention, the content ratio (mass ratio) of the components (A), (B), and (C) is (A) + (B): (C) = 1: 3 to 5: 1, especially 1:2. In the case of 4:1, it is preferable to take advantage of the effect of maintaining naturalness and masking unevenness of color and the effect of expressing various skin impressions.
本發明之印象控制劑可再含有(D)平均粒徑1~20 μ m、較佳3~15 μ m之球狀粉體。於此,球狀粉體係指具有抑制正反射及/或散反射(diffuse veflection)之性質者,其形狀包括真球狀、略球狀、旋轉楕圓體,亦包括於表面具凹凸之球狀粉體。The impression control agent of the present invention may further contain (D) a spherical powder having an average particle diameter of 1 to 20 μm, preferably 3 to 15 μm. Herein, the spherical powder system refers to a property having a property of suppressing specular reflection and/or diffuse veflection, and the shape thereof includes a true spherical shape, a slightly spherical shape, a rotating round body, and is also included in a spherical shape having irregularities on the surface. Powder.
若平均粒徑為1~20 μ m,則由於不致埋蓋化妝膜,且可輕易地均勻附著於凹凸部,故有使毛孔、小皺紋等凹凸的境界線模糊而不易見的效果,充分表現「模糊」效果,並使毛孔、小皺紋等凹凸不明顯。特別是藉由將球狀粉體之平均粒徑設為1 μ m以上,則球狀粉體不致埋蓋化妝膜,而使用感柔順良好。When the average particle size is 1 to 20 μm, since the cosmetic film is not covered and can be easily adhered to the uneven portion, the boundary between the pores and the small wrinkles is blurred and the effect is not easy to see. The "blur" effect makes the unevenness such as pores and small wrinkles inconspicuous. In particular, when the average particle diameter of the spherical powder is 1 μm or more, the spherical powder does not bury the cosmetic film, and the feeling of use is good.
作為此種球狀粉體的具體例,可舉例如屬於球狀之SiO2 、Al2 O3 等金屬氧化物;硫酸鋇、碳酸鈣等之無機化合物;聚乙烯、聚甲基丙烯酸甲酯、聚苯乙烯、尼龍、纖維素、聚矽氧樹脂、聚胺基甲酸酯等之高分子化合物。球狀粉體可使用1種或2種以上之混合物。Specific examples of such a spherical powder include, for example, a spherical metal oxide such as SiO 2 or Al 2 O 3 ; an inorganic compound such as barium sulfate or calcium carbonate; polyethylene or polymethyl methacrylate; A polymer compound such as polystyrene, nylon, cellulose, polyoxyxylene resin, or polyurethane. One type or a mixture of two or more types may be used for the spherical powder.
於總組成中含有成分(D)0.1~30質量%、特別是1~20質量%者,係使凹凸不明顯之效果優良,且使用感良好,而為較佳。In the total composition, the component (D) is contained in an amount of 0.1 to 30% by mass, particularly 1 to 20% by mass, and the effect of making the unevenness is not remarkable is excellent, and the feeling of use is good, which is preferable.
本發明中,成分(A)、(B)、(C)、及(D)之含有比例(質量比)為(A)+(B)+(C):(D)=1:4~15:1、特別是1:3~10:1者,由於可無眩光並柔順地掩蓋色不均,且可表現出肌膚的各種印象,故較佳。In the present invention, the content ratio (mass ratio) of the components (A), (B), (C), and (D) is (A) + (B) + (C): (D) = 1: 4 to 15 :1, especially 1:3~10:1, because it is glare-free and softly covers the unevenness of the color, and can express various impressions of the skin, so it is preferable.
成分(A)、(B)、(C)、及(D)之粉體亦可對其表面進行疏水化處理而使用。作為疏水化處理,可舉例如:使油脂吸附至粉體表面,或利用羥基等官能基而引起酯化和醚化,使顏料成為親油性的油脂處理法;使用脂肪酸之鋅鹽和鎂鹽之金屬皂處理法;使用二甲基聚矽氧烷或甲基氫聚矽氧烷之聚矽氧處理法;以具有過氟烷基之氟化合物進行處理之方法等。The powders of the components (A), (B), (C), and (D) may be used by hydrophobizing the surface thereof. The hydrophobization treatment may be carried out by, for example, a method of treating oil and fat by adsorbing oil and fat onto the surface of the powder, or causing esterification and etherification by using a functional group such as a hydroxyl group, and making the pigment lipophilic; and using a zinc salt and a magnesium salt of a fatty acid. Metal soap treatment method; polyoxymethane treatment method using dimethyl polyoxyalkylene or methyl hydrogen polyoxyalkylene; a method of treating with a fluorine compound having a perfluoroalkyl group; and the like.
本發明之印象控制劑中,除了成分(A)、(B)及(C)以外所含之著色劑的含量為3質量%以下、特別是0.5質量%以下者,由於透明感高、表現肌膚各種印象的效果優越,故較佳。再者,最好實質上不含有成分(A)、(B)及(C)以外之著色劑。於此,著色劑係指氧化鈦、氧化鐵、鐵藍、群藍、氧化鉻等之無機白色顏料、著色顏料;紅色201號、黃色401號、藍色1號、綠色3號等之有機顏料等。In the impression control agent of the present invention, the content of the coloring agent contained in addition to the components (A), (B), and (C) is 3% by mass or less, particularly 0.5% by mass or less, and the skin is high in transparency and expression. The effects of various impressions are superior, so they are preferred. Further, it is preferable that the coloring agent other than the components (A), (B) and (C) is not substantially contained. Here, the coloring agent refers to an inorganic white pigment such as titanium oxide, iron oxide, iron blue, group blue, or chromium oxide, or a coloring pigment; an organic pigment such as red 201, yellow 401, blue 1, and green 3. Wait.
若著色劑含量為3質量%以下,則透明感高,可容易表現肌膚之各種印象,故較佳。When the content of the colorant is 3% by mass or less, the transparency is high and the various impressions of the skin can be easily expressed, which is preferable.
本發明之印象控制劑中除了上述成分之外,視使用目的等亦可含有一般化妝料所使用之成分。例如可含有界面活性劑、高分子化合物、油分、體質顏料、保濕劑、防腐劑、藥劑、紫外線吸收劑、抗氧化劑、無機酸鹽或有機酸鹽、香料、嵌合劑、pH調整劑、水等。In addition to the above components, the impression control agent of the present invention may contain components used in general cosmetics depending on the purpose of use and the like. For example, it may contain a surfactant, a polymer compound, an oil component, an extender pigment, a moisturizer, a preservative, a pharmaceutical agent, an ultraviolet absorber, an antioxidant, a mineral acid salt or an organic acid salt, a fragrance, a chimera, a pH adjuster, water, etc. .
本發明之印象控制劑可使用上述成分,依常法予以製造,可作成為粉末固形型、高含油粉末固形型、油分散型、水分散型、油中水乳化液、水中油乳化液等之任意劑型。特別以粉底為較適合。The impression control agent of the present invention can be produced by a usual method using the above components, and can be used as a powder solid type, a high oil-containing powder solid type, an oil dispersion type, a water dispersion type, an oil-in-water emulsion, an oil emulsion in water, or the like. Any dosage form. Especially suitable for foundation.
另外,於作成含有成分(A)~(D)之粉底的情況下,可使用作為可控制印象的粉底。Further, in the case of forming a foundation containing the components (A) to (D), a foundation which can control the impression can be used.
實施例中,測定方法1及測定方法2係依以下方法進行。In the examples, the measurement method 1 and the measurement method 2 were carried out in the following manner.
(測定方法1)於黑色人工皮革(岡本新知公司,CERANUBACK#010)上,使用市售化妝料用海綿(粉底用),以成為8mg/100cm2 之方法均勻塗佈各組成物。將此使用變角測定計(變角分光測定系統(村上色彩研究所製,GCMS-4)),測定依CIE1976L* a* b* 表色系所規定的色彩值。(Measurement Method 1) Each of the compositions was uniformly applied to a black artificial leather (Okamoto Shinchi Co., Ltd., CERANUBACK #010) using a commercially available cosmetic sponge (for foundation) in a method of 8 mg/100 cm 2 . Using a variable angle meter (a variable angle spectrometry system (manufactured by Murakami Color Research Laboratory, GCMS-4)), the color value defined by the CIE1976 L * a * b * color system was measured.
(測定方法2)於圓分析管(反射測定用,日本電色工業公司製;直徑35×高度15mmH石英)中,填充各組成物,使用分光色差計SE2000(日本電色工業公司製),測定依CIE1976L* a* b* 表色系所規定之色彩值。(Measurement Method 2) in a circular analysis tube (for reflection measurement, manufactured by Nippon Denshoku Industries Co., Ltd.; diameter 35 In the case of a height of 15 mmH quartz, each composition was filled, and a color value defined by the CIE1976L * a * b * color system was measured using a spectrophotometer SE2000 (manufactured by Nippon Denshoku Industries Co., Ltd.).
將硫酸鐵n水合物60質量份溶解於離子交換水2000質量份中,將此以0.1mol/L氫氧化鈉水溶液調整為pH2.8,並於此水溶液中加入ENGELHARD公司製之雲母鈦(Flamenco Satin Gold)100質量份,予以充分攪拌使其均勻分散。其次,一邊攪拌此雲母鈦分散液並一邊加熱,使其沸騰6小時。放冷後,予以過濾、水洗,得到以黃氧化鐵所被覆之雲母鈦103質量份。60 parts by mass of iron sulfate n-hydrate was dissolved in 2000 parts by mass of ion-exchanged water, and this was adjusted to pH 2.8 with a 0.1 mol/L sodium hydroxide aqueous solution, and a mica titanium (Flamenco) manufactured by ENGELHARD Co., Ltd. was added to the aqueous solution. 100 parts by mass of Satin Gold), and sufficiently stirred to uniformly disperse. Next, the mica titanium dispersion was stirred while heating to boil for 6 hours. After allowing to cool, it was filtered and washed with water to obtain 103 parts by mass of mica titanium coated with yellow iron oxide.
所得之黃氧化鐵被覆雲母鈦的平均粒徑為7.0 μ m,黃氧化鐵之被覆率係相對於整體為7質量%。The obtained yellow iron oxide-coated mica titanium had an average particle diameter of 7.0 μm, and the yellow iron oxide coating ratio was 7 mass% with respect to the whole.
將硫酸鐵n水合物60質量份溶解於離子交換水2000質量份中,將此以0.1mol/L氫氧化鈉水溶液調整為pH2.8,並於此水溶液中加入ENGELHARD公司製之雲母鈦(Flamenco Satin Red)100質量份,予以充份攪拌使其均勻分散。其次,一邊攪拌此雲母鈦分散液並一邊加熱,使其沸騰6小時。放冷後,予以過濾、水洗,以800℃燒成2小時,得到以紅氧化鐵所被覆之雲母鈦102質量份。60 parts by mass of iron sulfate n-hydrate was dissolved in 2000 parts by mass of ion-exchanged water, and this was adjusted to pH 2.8 with a 0.1 mol/L sodium hydroxide aqueous solution, and a mica titanium (Flamenco) manufactured by ENGELHARD Co., Ltd. was added to the aqueous solution. 100 parts by mass of Satin Red), and thoroughly stirred to uniformly disperse. Next, the mica titanium dispersion was stirred while heating to boil for 6 hours. After allowing to cool, it was filtered, washed with water, and calcined at 800 ° C for 2 hours to obtain 102 parts by mass of mica titanium coated with red iron oxide.
所得之紅氧化鐵被覆雲母鈦的平均粒徑為7.2 μ m,紅氧化鐵之被覆率係相對於整體為7質量%。The average particle diameter of the obtained red iron oxide-coated mica titanium was 7.2 μm, and the coverage of red iron oxide was 7 mass% with respect to the whole.
於製造例1中,除了使用Prestige Silk Gold(ECKART公司製)作為雲母鈦之外,其餘與製造例1同樣進行,得到黃氧化鐵被覆雲母鈦。In the production example 1, except that Prestige Silk Gold (manufactured by ECKART Co., Ltd.) was used as the mica titanium, the yellow iron oxide-coated mica titanium was obtained in the same manner as in Production Example 1.
所得之黃氧化鐵被覆雲母鈦的平均粒徑為12.0 μ m,黃氧化鐵之被覆率係相對於雲母鈦為7質量%。The obtained yellow iron oxide-coated mica titanium had an average particle diameter of 12.0 μm, and the yellow iron oxide coating ratio was 7 mass% with respect to the mica titanium.
於製造例2中,除了使用Prestige Silk Violet(ECKART公司製)作為雲母鈦之外,其餘與製造例2同樣進行,得到紅氧化鐵被覆雲母鈦。In the production example 2, except that a Prestige Silk Violet (manufactured by ECKART Co., Ltd.) was used as the mica titanium, the red iron oxide-coated mica titanium was obtained in the same manner as in Production Example 2.
所得之紅氧化鐵被覆雲母鈦的平均粒徑為12.0 μ m,紅氧化鐵之被覆率係相對於雲母鈦為7質量%。The obtained red iron oxide-coated mica titanium had an average particle diameter of 12.0 μm, and the red iron oxide coverage was 7 mass% with respect to the mica titanium.
製造表1所示組成的印象控制劑,針對性感印象、成熟印象、都會感印象、可愛印象、漂亮地化了妝的感覺、具透明感之完妝感、明亮完妝感進行評價。將結果示於表2。The impression control agent of the composition shown in Table 1 was evaluated for the sexy impression, the mature impression, the impression of the city, the cute impression, the feeling of beautiful makeup, the feeling of makeup with a transparent feeling, and the feeling of bright makeup. The results are shown in Table 2.
(製法)將經加熱至70℃的油相成分((1)~(3))與粉體成份((4)~(15))以分散機(2000rpm、15分鐘)進行攪拌,使其均勻。其次,藉由添加經以70℃使其均勻溶解的水相成分((16~(18)),使其乳化,其後,一邊攪拌一邊冷卻至室溫,最後以均質機(5000rpm、10分鐘)進行攪拌,得到液狀的印象控制劑。(Production method) The oil phase components ((1) to (3)) heated to 70 ° C and the powder components ((4) to (15)) were stirred in a dispersing machine (2000 rpm, 15 minutes) to make them uniform. . Next, the aqueous phase component ((16 to (18)) which was uniformly dissolved at 70 ° C was added, and the mixture was emulsified, and then cooled to room temperature while stirring, and finally homogenized (5000 rpm, 10 minutes). The mixture was stirred to obtain a liquid impression control agent.
(評價方法)由專門評審員14人,針對將各印象控制劑塗佈至全臉時的「性感印象」、「成熟印象」、「都會感印象」、「可愛印象」、「漂亮地上妝感」、「具透明感之完妝感」、「明亮完妝感」進行評價,各項目中均以「如此覺得」為5點、「稍微覺得」為4點、「無法評論」為3點、「稍不覺得」為2點、「不如此覺得」為1點,並以其平均值進行表示。(Evaluation method) For 14 people, the "Sexy Impression", "Mature Impression", "City Impression", "Cute Impression", and "Beautifully Sense of Makeup" when applying the various impression control agents to the entire face "Evaluation of a sense of transparency and a sense of makeup", each item has a "do so feel" of 5 points, a "slightly felt" of 4 points, and "unable to comment" as 3 points. "Slightly do not think" is 2 points, "I don't think so" is 1 point, and it is expressed by the average value.
製造表3所示組成的液狀粉底,針對具透明感之完妝感、明亮完妝感、色不均的掩蓋力、凹凸不明顯度、無眩光完妝感、表現肌膚各種印象的效果(由化妝塗膜之顏色與珍珠顏料所觀察到的色調)、使用感(無粗糙感、柔順度)進行評價。結果示於表4。The liquid foundation of the composition shown in Table 3 is produced, and has a clear feeling of makeup, a bright finish, a masking force of uneven color, an unevenness of unevenness, a glare-free finish, and an impression of various skin impressions ( The color of the cosmetic coating film and the color tone observed by the pearl pigment, and the feeling of use (no roughness, suppleness) were evaluated. The results are shown in Table 4.
(製法)將經加熱至70℃的油相成分((1)~(3))與粉體成份((4)~(15))以分散機(2000rpm、15分鐘)進行攪拌,使其均勻。其次,藉由添加經以70℃使其均勻溶解的水相成分((16~(18)),使其乳化,其後,一邊攪拌一邊冷卻至室溫,最後以均質機(5000rpm、10分鐘)進行攪拌,得到液狀粉底。(Production method) The oil phase components ((1) to (3)) heated to 70 ° C and the powder components ((4) to (15)) were stirred in a dispersing machine (2000 rpm, 15 minutes) to make them uniform. . Next, the aqueous phase component ((16 to (18)) which was uniformly dissolved at 70 ° C was added, and the mixture was emulsified, and then cooled to room temperature while stirring, and finally homogenized (5000 rpm, 10 minutes). ) stirring to obtain a liquid foundation.
(評價方法)由專門評審員14人,針對將各液狀粉底塗佈至肌膚時的「具透明感之完妝感」、「明亮完妝感」、「色不均的掩蓋力」、「凹凸的不明顯度」、「無眩光完妝感」、「表現肌膚印象的效果」、「使用感(無粗糙感、柔順度」進行評價,各項目中均以「良好」為5點、「稍微良好」為4點、「普通」為3點、「稍差」為2點、「差劣」為1點,並以其平均值進行表示。(Evaluation method) For 14 people who have applied liquid foundation to the skin, "transparent makeup feeling", "bright finish", "masking power unevenness", " "Inconspicuousness of unevenness", "no glare finish", "effect of expressing skin impression", "use of feeling (no roughness, suppleness)", each item has "good" as 5 points, " "Slightly good" is 4 points, "Normal" is 3 points, "Slightly worse" is 2 points, and "poor" is 1 point, and is represented by the average value.
實施例5~7之粉底均於各評價項目中顯示良好結果。又,由在將各粉底塗佈至肌膚時的觀感而言,實施例5、7可給予知性且帥氣的高雅印象,實施例6則可給予性感且健康的印象。The foundations of Examples 5 to 7 all showed good results in each evaluation item. Further, Examples 5 and 7 gave an impression of being elegant and handsome, and Examples 6 and 7 gave an impression of being sexy and healthy, and the appearance of each of the foundations was applied to the skin.
依照表5所示組成,將經加熱至70℃的油相成分((1)~(6))與粉體成份((l1)~(15))以分散機(2000rpm、15分鐘)進行攪拌,使其均勻。其次,藉由添加經以70℃使其均勻溶解的水相成分((7)~(10)),使其乳化,其後,一邊攪拌一邊冷卻至室溫,最後以均質機(5000rpm、10分鐘)進行攪拌,得到霜狀粉底。According to the composition shown in Table 5, the oil phase components ((1) to (6)) heated to 70 ° C and the powder components ((l1) to (15)) were stirred by a disperser (2000 rpm, 15 minutes). Make it even. Next, it was emulsified by adding an aqueous phase component ((7) to (10)) which was uniformly dissolved at 70 ° C, and then cooled to room temperature while stirring, and finally, a homogenizer (5000 rpm, 10) Stir) and stir to obtain a creamy foundation.
將實施例8之粉底塗佈至肌膚時,可給予有精神且可愛的印象。When the foundation of Example 8 is applied to the skin, a mental and lovely impression can be given.
依照表6所示組成,於將成分(1)~(7)攪拌混合者中,添加預先加熱的成分(8)及(9),予以混合分散,並以粉碎機進行粉碎,製型成中圓狀,得到固形粉末狀粉底。According to the composition shown in Table 6, the components (8) and (9) which were previously heated were mixed with the components (1) to (7), mixed and dispersed, and pulverized by a pulverizer to prepare a medium. In a round shape, a solid powdery foundation is obtained.
將實施例9之粉底塗佈至肌膚時,可給予知性且帥氣的高雅印象。When the foundation of Example 9 is applied to the skin, an elegant and handsome impression can be given.
依照表7所示組成,於將成分(1)~(8)攪拌混合者中,添加預先加熱的成分(9),予以混合分散,並以粉碎機進行粉碎,予以通過篩網,得到鬆粉狀粉底。According to the composition shown in Table 7, the components (1) which were previously heated were mixed with the components (1) to (8), mixed and dispersed, and pulverized by a pulverizer, and passed through a sieve to obtain pine powder. Foundation.
將實施例10之粉底塗佈至肌膚時,可給予高雅且溫柔的印象。When the foundation of Example 10 is applied to the skin, an elegant and gentle impression can be given.
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CN1241930A (en) * | 1996-12-18 | 2000-01-19 | 普罗克特和甘保尔公司 | Stable high SPF foundation |
JP2003012459A (en) * | 2001-06-25 | 2003-01-15 | Kao Corp | Cosmetic |
JP3798266B2 (en) * | 2001-06-25 | 2006-07-19 | 花王株式会社 | Colored mica titanium |
JP3892775B2 (en) * | 2002-08-22 | 2007-03-14 | 花王株式会社 | Cosmetics |
JP4627960B2 (en) * | 2002-08-22 | 2011-02-09 | 花王株式会社 | Cosmetics |
-
2006
- 2006-12-27 WO PCT/JP2006/326040 patent/WO2007077866A1/en active Application Filing
- 2006-12-27 CN CN2012102800892A patent/CN102813608A/en active Pending
- 2006-12-28 TW TW95149417A patent/TWI388341B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO2007077866A1 (en) | 2007-07-12 |
TW200730193A (en) | 2007-08-16 |
CN102813608A (en) | 2012-12-12 |
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