TWI360585B - Apparatus and method for electroless plating - Google Patents
Apparatus and method for electroless plating Download PDFInfo
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- TWI360585B TWI360585B TW096111852A TW96111852A TWI360585B TW I360585 B TWI360585 B TW I360585B TW 096111852 A TW096111852 A TW 096111852A TW 96111852 A TW96111852 A TW 96111852A TW I360585 B TWI360585 B TW I360585B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1619—Apparatus for electroless plating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1675—Process conditions
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1675—Process conditions
- C23C18/168—Control of temperature, e.g. temperature of bath, substrate
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1675—Process conditions
- C23C18/1683—Control of electrolyte composition, e.g. measurement, adjustment
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Chemically Coating (AREA)
Description
1360585 九、發明說明: 【發明所屬之技術頜域】 本發明與無電電锻設備及方法相關。 【先前技術】1360585 IX. Description of the invention: [Technical jaw region to which the invention pertains] The present invention relates to an electroless forging device and method. [Prior Art]
無電電鍍指的是一種不需使用電力而是藉由化學反應 完成的鍍覆類型。一般來說,鍍覆時常使用利用電力完成 的電鍍,但對諸如環氧樹脂與其他塑膠的材質而言,材質 不容許電傳導,以致於無法執行電鍍。在這類例子中,鍍 覆係利用無電電鍍完成。無電電鍍可分成1)還原鍵覆類型 與2)置換鍍覆類型》 還原艘覆類擊(reduction plating type)是一 ·糧藉由還 原反應而.沉積金屬的鍵覆.類型,而置換鍵覆類型 (substitution plating type)則是一種利用氧化/還原力差異 的鍍覆類型。置換鍍覆類型典型的例子是鎳/金(Ni/Au)鍵 覆。Electroless plating refers to a type of plating that is completed by a chemical reaction without using electricity. In general, electroplating is often used for plating, but for materials such as epoxy resins and other plastics, the material does not allow electrical conduction, so that electroplating cannot be performed. In such an example, the plating is accomplished using electroless plating. Electroless plating can be divided into 1) reduction bond type and 2) displacement plating type. "Reduction plating type" is a type of bond, which is replaced by a reduction reaction. The substitution plating type is a type of plating that utilizes the difference in oxidation/reduction force. A typical example of a displacement plating type is a nickel/gold (Ni/Au) bond.
此類無電電鍵類型會被應用成在製造印刷電路板中執 行表面處理的方法。例如,以無電電鍍大約5微米高的鎳 在印刷電路板的銅層上,來表面處理印刷電路板接著以 無電電鍍鍍覆大約0.03微米高的金。 然而以此方式在印刷電路板上執行無電鍍鎳,鎳链 覆層的低可罪度引發了問題。當鎳鍍覆層的可靠度由於不 致的锻覆環境而降低時,在利用置換反應形成金鐘覆層 的過程中(在锻覆錄之後)發生局部鎳被過度置換’使得金 5 1360585 錢覆層的厚度變得過度’造成材料成本的損失。 第1圖是根據先前技術所插述之無電電鍍設備的透視 圖。參照第1圖,無電電鍍設備之操作(根據先前技術)如 下所述。This type of electroless type is applied as a method of performing surface treatment in the manufacture of printed circuit boards. For example, electroless plating of approximately 5 microns high nickel on a copper layer of a printed circuit board to surface treat the printed circuit board followed by electroless plating of approximately 0.03 micron high gold. However, in this way, electroless nickel is performed on a printed circuit board, and the low suspicion of the nickel chain coating causes problems. When the reliability of the nickel plating layer is lowered due to the unwrapped forging environment, the local nickel is excessively replaced during the process of forming the golden bell coating by the displacement reaction (after the forging), so that the gold 5 1360585 is covered. The thickness of the layer becomes excessive 'causing a loss of material cost. Figure 1 is a perspective view of an electroless plating apparatus interposed in accordance with the prior art. Referring to Fig. 1, the operation of the electroless plating apparatus (according to the prior art) is as follows.
當鍍覆液透過兩個管件30被噴灑向鍍覆槽1〇底部 時,锻覆液提供錄離子給置於籃狀物2〇内的電路板(未顯 示)’然後流過遮蔽膜50到達輔助槽70。鍍覆液流向輔助 槽70係藉由具有110 °C表面溫度的熱交換器40(位在鍍覆 槽10側邊)提供能量而完成。 供以能量的鍍覆液經由辅助槽70的出水口 72流出, 然後穿過一循環構造再次被移至管件30»同時,一送風機 60配置在鄰近熱交換器4〇的位置以便散熱。 在以此類構造運轉的無電電鍍設備中,由於鍍覆槽内 莫名的構造/運轉環境引發鍍覆環境的誤差,因此相較於周 圍’高溫出現在喷嘴與熱交換器(位在側邊)附近。When the plating solution is sprayed through the two tubes 30 to the bottom of the plating tank 1 , the forging liquid supplies the recording ions to the circuit board (not shown) placed in the basket 2 ' and then flows through the mask film 50 to reach Auxiliary tank 70. The flow of the plating solution to the auxiliary tank 70 is accomplished by supplying energy by a heat exchanger 40 having a surface temperature of 110 °C (located on the side of the plating tank 10). The energized plating solution flows out through the water outlet 72 of the auxiliary tank 70, and is again moved to the tube member 30» through a circulation configuration, while a blower 60 is disposed adjacent to the heat exchanger 4 to dissipate heat. In the electroless plating equipment operating in this type of configuration, the inaccurate construction/operating environment in the plating tank causes an error in the plating environment, so that the nozzle and the heat exchanger (on the side) appear in comparison with the surrounding 'high temperature. nearby.
再者’由於喷向鍍覆槽底部的喷嘴構造引發的漩渦, 使得接近電路板的鍍覆液之流速與溫度偏差招致誤差。 此外’由於鍍覆液被供以能量(當其流向輔助槽時), 出現高的溫度損失,以致熱交換器必須運轉至1 1 〇 t好維 持鍍覆過程的必須溫度80。(:,又因為接近熱交換器的高溫 而出現锻覆液分解的高度可能性。 因此,需要一種可使鍍覆環境一致,以便改善鍍覆層 可靠度的方法。 6 1360585 【發明内容】 本發明的一態樣係提供一無電電鍍的設備與方法,其 中鍍覆槽構造被修改,好讓鍍覆環境變—致。 本發明的一態樣會提供一無電電鍍設備包括:一鍍覆 槽,設置在接近鍍覆槽底面的熱交換器;一設置在接近熱 交換器的供應部件,對鍍覆槽内部提供鍍覆液;以及一設置 在鍍覆槽内的籃狀物,用以支撐鍍覆標的物。Furthermore, the vortex caused by the nozzle structure sprayed toward the bottom of the plating tank causes an error in the flow rate of the plating solution close to the circuit board and the temperature deviation. Furthermore, since the plating solution is supplied with energy (when it flows to the auxiliary tank), a high temperature loss occurs, so that the heat exchanger must be operated to a temperature of 80 Å to maintain the necessary temperature of the plating process. (:, because of the high possibility of decomposing the forging liquid due to the high temperature of the heat exchanger. Therefore, there is a need for a method that can make the plating environment uniform in order to improve the reliability of the plating layer. 6 1360585 [Summary] An aspect of the invention provides an apparatus and method for electroless plating, wherein the plating bath configuration is modified to allow the plating environment to change. One aspect of the present invention provides an electroless plating apparatus comprising: a plating bath a heat exchanger disposed near the bottom surface of the plating tank; a supply member disposed adjacent to the heat exchanger to provide a plating solution to the inside of the plating tank; and a basket disposed in the plating tank for supporting Plated subject matter.
可額外形成一循環部件,好重 槽内的鍍覆液給供應部件。 、述供應於鐘覆 該供應部件會提供鍍覆液給熱交換 被設置在接近熱交換器的一端上。、,且供應部件會 同時,該熱交換器會被塑形成—平 應的鍍覆液係沿著熱交換器表面移動。’且供應部件供 供應部件會由多數個喷嘴部件而紐 有設置在接近熱交換器上表面的第—、 。例如’可能會 接近熱交換器下表面的第二喑 嘴。卩件’與設置在 貝方邵件,士An additional circulation component can be formed to supply the components with the plating solution in the tank. The supply is supplied to the clock cover. The supply unit supplies plating liquid to the heat exchange and is disposed on one end close to the heat exchanger. At the same time, the heat exchanger is molded - the flat plating fluid moves along the heat exchanger surface. And the supply parts supply parts are provided by a plurality of nozzle parts and are arranged close to the upper surface of the heat exchanger. For example, a second nozzle that may be near the lower surface of the heat exchanger. ’' and set in Beifang Shao, Shishi
提供的鍍覆液會沿著熱交換器 第一噴嘴部件所 巧上表面移叙 嘴部件所提供的鍍覆液則將^ 動’而由第二喷 σ有热交換器的T * 熱交換器表面溫度會是”^至 卜表面移動。 本發明的另一態樣提供一 。 硬韁由提供蚀 而來實施無電電鍍的方法, '、裁覆液給標的物 言•在錢霜Μ上 從鍍覆槽底面供應鍍覆液,供 僧中提供標的物, 伢愿熱能給缺磨 此供以熱能的鍍覆液給標的物。 。X覆液,以及提供 熱能供應係以設置在餹 峨復糟底面 的熱交換 器執行,且 7 1360585 鍍覆液被供應朝向熱交換器。 鍍覆液供應^ ^ , , 係从第—喷嘴部件(設置接近熱交換器的 _表第二嘴嘴部件(設置接近熱交換器的下表面)執 订喷嘴部件所提供的鍵覆液會沿著熱交換器的上 表面移動’而由第二噴嘴部件所提供的鍍覆液則將沿著熱 交換器的下表面移動。 本發明額外的態樣與優點,一部分將在下述中提出,The plating solution provided will move the plating solution provided by the nozzle member along the upper surface of the first nozzle member of the heat exchanger, and the T* heat exchanger having the heat exchanger by the second spray σ The surface temperature will be "^ to the surface of the surface. Another aspect of the present invention provides one. The hard enamel is provided by etching to provide electroless plating, ', and the liquid is given to the target. The plating tank is supplied with a plating solution on the bottom surface of the plating tank, and the target material is supplied in the crucible. The heat is required to give the target material to the coating liquid which is supplied with heat energy. X coating liquid, and providing heat energy supply system to be set in the complex The heat exchanger on the bottom surface is executed, and 7 1360585 plating solution is supplied toward the heat exchanger. The plating liquid supply ^ ^ , , is from the first nozzle part (the second nozzle part is set close to the heat exchanger) Providing a lower surface close to the heat exchanger) the key coating provided by the dispensing nozzle component moves along the upper surface of the heat exchanger and the plating fluid provided by the second nozzle component will follow the heat exchanger The lower surface moves. Additional aspects and advantages of the present invention, Will be set forth in part in the following,
另-部分則係可由說明中明顯推知的,或可以由發明的實 踐獲悉。 【實施方式】 依據本發明某些具體 ,在每一圖申,相同 接下來將參照附圖更清楚地描述 實施例的無電電鍍設備及方法,其中 元件被賦予相同元件號碼,且不重複說明The other part is clearly inferred from the description or can be learned from the practice of the invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS In accordance with the present invention, in each of the drawings, the same, the electroless plating apparatus and method of the embodiment will be more clearly described with reference to the accompanying drawings, wherein the elements are given the same element numbers, and the description is not repeated.
第2圖是根據本發明第一揭示的實施例所描述之無電 電鍍設備的透視圖。第2圖中描述了一鍍覆槽u〇,一擱 板112,數個籃狀物!20a、12〇b , _供應部件n〇,一第 一喷嘴部件131,一第二喷嘴部件132,數個噴嘴i3u、 132a,一熱交換器140, 一輔助槽17〇以及一出水口 172。 鍍覆槽1 1 〇是一個容納鍍覆液的空間以便執行鍍覆。 上述不同的组件會設置在鍍覆槽11〇内,諸如藍狀物 120a、120b,供應部件130以及熱交換器mo等等。 籃狀物120a、12 0b係支撐諸如電路板(未顯示)的鍍覆 標的物之構件。雖然只有兩個籃狀物12〇a、12〇b描述於第 8 1360585 2圓中’籃狀物120a、120b的數量與形狀會隨著鍍覆標的 物而改變》 供應部件130是提供鍍覆液至鍍覆槽110内的構件。 第2圖中’第一噴嘴部件13ι與第二喷嘴部件132被視作 是供應部件130。藉由運用數個喷嘴部件當作供應部件 ^〇,可調整供給鍍覆液的數量與供應方向等等。這個供應 部件130會設置在鍍覆槽u〇内的底層好供應鍍覆液。Fig. 2 is a perspective view of an electroless plating apparatus described in accordance with an embodiment of the first disclosed embodiment of the present invention. Figure 2 depicts a plating tank u〇, a shelf 112, and several baskets! 20a, 12〇b, _ supply part n〇, a first nozzle part 131, a second nozzle part 132, a plurality of nozzles i3u, 132a, a heat exchanger 140, an auxiliary tank 17A and a water outlet 172. The plating tank 1 1 〇 is a space for accommodating the plating liquid to perform plating. The above different components are disposed in the plating tank 11, such as the blue bodies 120a, 120b, the supply member 130, the heat exchanger mo, and the like. The baskets 120a, 120b are members that support a plated object such as a circuit board (not shown). Although only two baskets 12〇a, 12〇b are described in the 8 1360585 2 circle, the number and shape of the baskets 120a, 120b may vary with the plating target. The supply member 130 is provided with plating. The liquid is applied to the components in the plating tank 110. In Fig. 2, the first nozzle member 13i and the second nozzle member 132 are regarded as the supply member 130. By using a plurality of nozzle parts as supply parts, the number of supply plating solutions and the supply direction can be adjusted. This supply member 130 is provided with a plating solution which is disposed in the bottom layer of the plating tank.
同時’為了提供熱能給鍍覆液(從供應部件130供 應)’熱交換器140會被設置在鍍覆槽110的底面,靠近供 應部件130。熱交換器丨4〇是一提供熱能給鍍覆液的構件, 好讓供應於鍍覆槽11〇内的鍍覆液達到適合鍍覆步驟的溫 度。 因為這個熱交換器140被設置在鍍覆槽110的底面, 靠近供應部件130,所以熱能會被直接地提供給供應於链 覆槽110内的鑛覆液,而能增進運轉效能。At the same time, in order to supply thermal energy to the plating liquid (supplying from the supply member 130), the heat exchanger 140 is disposed on the bottom surface of the plating tank 110, adjacent to the supply member 130. The heat exchanger 丨4〇 is a member for supplying thermal energy to the plating liquid so that the plating liquid supplied into the plating tank 11〇 reaches a temperature suitable for the plating step. Since this heat exchanger 140 is disposed on the bottom surface of the plating tank 110, close to the supply member 130, heat energy is directly supplied to the mineral deposit supplied to the chain groove 110, and the running efficiency can be improved.
並且’使鍍覆液達到適合鍍覆步驟溫度的熱交換器 140’不需被設定去具有過高的表面溫度,因此可以避免鍵 覆液的分解(發生於接近熱交換器14〇)。 例如,為了使鍍覆液(從熱交換器14〇接收熱能之後) 在錢覆標的物之電路板(未顯示)附近,保持適合鍍覆步帮 的溫度8(TC,熱交換器140的表面溫度會設定至9〇t到 1 〇 〇 °c之間。 這是因為設定低於90C的溫度會使得鍵覆液在電路 板附近難以保持80C,因而會在平順地執行鍍覆過程中弓丨 9 發錯誤,當溫 換器140處分 同時,供 直接地向熱交 式從熱交換器 參照第2 供鑛覆液給平 換器1 4 〇的表 器140接觸。 有效率被執行 再者,於 器140上以垂 第3圖中的箭 除此,為 法與供應部件 同時,當 一噴嘴部件1 一-第二噴嘴部 面,以致其可 供锻覆夜給熱 的箭號表示鍵 因此,由 換器140的上 覆液將沿著熱 度設定超過loot會導致鍍覆液在接近熱交 解。 應部件130會提供鍵覆液給熱交換器14〇。 換器14 0提供鍍覆液,以便以更有效率的方 140供應熱能給鍍覆液。 圖’當供應部件130從熱交換器14〇側邊提 板狀的熱交換器140時,鍍覆液將沿著熱交 面移動,然後鍍覆液有更多機會去與熱交換 因此,從熱交換器140至鍍覆液的熱能傳導 〇 第3圖中描述,供應部件丨3 〇照例從熱交換 直的方向提供鍍覆液給熱交換器14〇表面。 號表示鑛覆液的供應方向。 達此目的而直接提供鍍覆液給熱交換器的方 的設置等等,在必要時可有不同的修改方式。 應用數個喷嘴部件於供應部件130時,一第 Π會設置在接近熱交換器140的上表面,且 件132會設置在接近熱交換器丨4〇的下表 各自以平行於熱交換器14〇表面的方向來提 交換器140,如第2圖所描述者。第2圖中 覆液的供應方向。 第一喷嘴部件131供應的鍍覆液將沿著熱交 表面移動’且由第二喷嘴部件132供應的鍵 交換器140的下表面移動,以便使熱能傳導 10 1360585 的效率達到最大化。 同時,設置一循環部件,用以循環已參與過鍍覆步驟 的鍍覆液。參照第2圖,當新的鍍覆液係透過鍍覆槽11〇 底面的供應部件130供應時,已參與過錢覆步驟的鍍覆液 將相對地被移至鍍覆槽11〇較高的部分。 之後’富鍍覆液元全填滿鐘覆槽11〇内部時,在鍍覆. 槽110較高部分的鍍覆液,經由擱板112(形成在鍍覆槽11〇 較高部分的一側)流向輔助槽17〇。供應给輔助槽17〇的鍍 覆液再透過出水口 172排出,而排出的鍵覆液透過管道等 等被提供給供應部件130,因此會再次運用於鍍覆步驟中。 再處理步驟也會被執行於循環步驟中,以移除包含於 鍍覆液中的雜質等等》 根據本發明的另一態樣之無電電鍍方法係參照第4圖 而描述。第4圖是根據本發明的另一態樣所描述之無電電 鍍法的流程圖。Further, the heat exchanger 140' which makes the plating liquid reach the temperature suitable for the plating step does not need to be set to have an excessively high surface temperature, so that the decomposition of the key liquid (which occurs close to the heat exchanger 14) can be avoided. For example, in order to make the plating solution (after receiving heat energy from the heat exchanger 14), in the vicinity of the circuit board (not shown) of the money-covered object, the temperature 8 (TC, surface of the heat exchanger 140) suitable for the plating step is maintained. The temperature will be set between 9 〇t and 1 〇〇 °c. This is because setting a temperature lower than 90C makes it difficult to maintain the key coating near the board, so it will be smooth during the plating process. 9 error occurs, when the temperature changer 140 is disengaged at the same time, for direct contact with the heat exchanger from the heat exchanger with reference to the second supply and delivery liquid to the flattener 140 of the flattener 14 4 . The efficiency is executed again, The upper portion of the nozzle 140 is divided by the arrow in FIG. 3, and the nozzle member 1 is a second-nozzle portion surface so that it can be used for forging the hot-headed arrow. The overcoat liquid from the converter 140 will be set to exceed the luot along the heat, which will cause the plating solution to approach the heat. The component 130 will provide a key coating to the heat exchanger 14〇. The converter 14 0 provides the plating solution. In order to supply thermal energy to the plating solution with a more efficient side 140. When the component 130 is lifted from the side of the heat exchanger 14 to the plate-shaped heat exchanger 140, the plating solution will move along the heat interface, and then the plating liquid has more opportunities to exchange heat with the heat exchanger. 140 to the thermal conductivity of the plating solution, as described in Fig. 3, the supply member 丨3 提供 provides a plating solution from the direction of heat exchange to the surface of the heat exchanger 14 〇 as usual. The number indicates the supply direction of the ore coating. The purpose is to directly provide the setting of the plating solution to the heat exchanger side, etc., and may have different modifications as necessary. When a plurality of nozzle parts are supplied to the part 130, a second turn is set in the proximity heat exchanger 140. The upper surface, and the member 132 is disposed adjacent to the heat exchanger 丨4〇 in the direction parallel to the surface of the heat exchanger 14 to extract the exchanger 140, as depicted in Fig. 2. In Fig. 2 The supply direction of the liquid coating. The plating liquid supplied from the first nozzle member 131 will move along the heat exchange surface and move the lower surface of the key exchanger 140 supplied by the second nozzle member 132 to allow the heat energy to pass the efficiency of 10 1360585. Maximize. At the same time, set one a circulating component for circulating the plating solution that has participated in the plating step. Referring to FIG. 2, when the new plating liquid is supplied through the supply member 130 of the bottom surface of the plating tank 11 , it has participated in the step of covering the money. The plating solution will be relatively moved to the higher portion of the plating bath 11 。. After the 'rich plating liquid element fills the inside of the bell jar 11 , inside, the plating. The higher part of the plating solution of the tank 110 And flowing to the auxiliary tank 17A via the shelf 112 (the side formed on the upper portion of the plating tank 11). The plating liquid supplied to the auxiliary tank 17〇 is discharged through the water outlet 172, and the discharged key liquid is permeated. A pipe or the like is supplied to the supply member 130 and thus is again used in the plating step. The reprocessing step is also performed in the recycling step to remove impurities contained in the plating solution, etc. Another embodiment of the electroless plating method according to the present invention is described with reference to Fig. 4. Figure 4 is a flow chart of the electroless plating method described in accordance with another aspect of the present invention.
首先’標的物被提供於鍍覆槽110中(sl〇)。雎然標的 物可以直接地被提供於鍍覆槽中,但可提供於鍍覆槽 110内而支撐於鍍覆槽110内的籃狀物l2〇a、i2〇b,以避 免標的物與供應部件130或熱交換器140等等接觸。在標 的物提供給鍍覆槽110之前,將以一定量的鍍覆液填滿鍍 覆槽11 0内部。 然後’鍍覆液係提供於鍍覆槽110底面(s20),且提供 熱能給所供應的鍍覆液(s30)。鐘覆液的供應與熱能的供應 係藉由上述無電電鍍設備的供應部件130與熱交換器140 11 1360585 來執行。換言之,如描述於第2圖中,在將熱交換器140 設置於鍍覆槽110底面且將供應部件130設置於熱交換器 140側邊之後,才會提供鍍覆液會給熱交換器140。 在鍍覆步驟之前,藉由直接提供熱能給鍍覆液(供應於 鍍覆槽110内),而增加了熱效能。並且,使鍍覆液達到適 合鍍覆過程溫度的熱交換器140,不需要被設定成具有過 高的表面溫度,因此可避免鍍覆液於接近熱交換器140處 被分解。First, the subject matter is provided in the plating tank 110 (sl〇). The ruthenium object may be directly provided in the plating tank, but may be provided in the plating tank 110 to support the baskets l2a, i2〇b in the plating tank 110 to avoid the object and supply. The component 130 or the heat exchanger 140 is in contact. Before the target is supplied to the plating tank 110, the inside of the plating tank 110 is filled with a certain amount of plating liquid. Then, the plating liquid is supplied to the bottom surface of the plating tank 110 (s20), and heat energy is supplied to the supplied plating liquid (s30). The supply of the bell coating and the supply of thermal energy are performed by the supply member 130 of the electroless plating apparatus described above and the heat exchanger 140 11 1360585. In other words, as described in FIG. 2, after the heat exchanger 140 is disposed on the bottom surface of the plating tank 110 and the supply member 130 is disposed on the side of the heat exchanger 140, the plating liquid is supplied to the heat exchanger 140. . Prior to the plating step, thermal performance is increased by directly supplying thermal energy to the plating solution (supplied in the plating tank 110). Further, the heat exchanger 140 which makes the plating solution reach the temperature suitable for the plating process does not need to be set to have an excessive surface temperature, so that the plating solution can be prevented from being decomposed near the heat exchanger 140.
例如,為了使在鍍覆標的物之電路板附近的鍍覆液(從 熱交換器140接收熱能之後)保持適合鍍覆步驟的溫度80 °C,熱交換器140的表面溫度會設定在90°C到l〇〇°C之間, 如上所述。 將鍍覆液提供給熱交換器。可直接地向熱交換器140 提供鍍覆液,以便以更有效率的方式從熱交換器140供應 熱能給鍍覆液。For example, in order to maintain a temperature suitable for the plating step of 80 ° C after the plating solution in the vicinity of the board of the plating target (after receiving heat energy from the heat exchanger 140), the surface temperature of the heat exchanger 140 is set at 90 °. C to l ° ° C, as described above. The plating solution is supplied to the heat exchanger. The plating solution can be supplied directly to the heat exchanger 140 to supply thermal energy from the heat exchanger 140 to the plating solution in a more efficient manner.
如第2圖中描述,當供應部件1 3 0從熱交換器1 4 0側 邊提供鍍覆液給平板狀的熱交換器140時,鍍覆液將沿著 熱交換器140的表面移動,使得從熱交換器140至鍍覆液 的熱傳導可更有效率,如上所述。 當已使用上述方式供給熱能的鍍覆液,被提供給標的 物時(s40),即執行了無電電鍍。 根據如上提出本發明的某些具體例,藉由將熱交換器 置於鍍覆槽的底部且使鍍覆液排出方向面對熱交換器可以 達成鍍覆環境一致且改善鍍覆層的可靠度。 12 1360585 雖然參照特定的具體實施例詳盡地描述本發明的精 神,但所揭示具體實施例僅當作描述用途而非用以限制本 發明。熟悉技術人士應知,其可在不悖離發明的範圍與精 神下變形或修改本發明實施例。 【圖式簡單說明】 第1圖是根據先前技術所描述之無電電鍍設備的透視 圖。As described in FIG. 2, when the supply member 130 provides a plating solution to the flat heat exchanger 140 from the side of the heat exchanger 140, the plating solution will move along the surface of the heat exchanger 140. The heat transfer from the heat exchanger 140 to the plating solution can be made more efficient, as described above. When the plating liquid which has supplied the thermal energy in the above manner is supplied to the target (s40), electroless plating is performed. According to some specific examples of the present invention as set forth above, it is possible to achieve a uniform plating environment and improve the reliability of the plating layer by placing the heat exchanger at the bottom of the plating tank and facing the heat exchanger in the discharge direction of the plating solution. . Although the spirit of the present invention has been described in detail with reference to the specific embodiments thereof, the particular embodiments disclosed herein It will be apparent to those skilled in the art that the present invention may be modified or modified without departing from the scope and spirit of the invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view of an electroless plating apparatus according to the prior art.
第2圖是根據本發明第一揭示具體例所描述之無電電 鍍設備的透視圖。 第3圖是根據本發明第二揭示具體例所描述之無電電 鍍設備的透視圖。 第4圖是根據本發明另一態樣所描述之無電電鍍方法 的流程圖。 13 1360585Fig. 2 is a perspective view of an electroless plating apparatus according to a first embodiment of the present invention. Figure 3 is a perspective view of an electroless plating apparatus according to a second disclosed embodiment of the present invention. Fig. 4 is a flow chart showing an electroless plating method according to another aspect of the present invention. 13 1360585
【主要元件符號說明】 10、110 鍍覆槽 30 導管 50 遮蔽膜 70、1 70 輔助槽 112 擱板 131、23 1 第一喷嘴部件 131a ' 132a 喷嘴 S10 ' S20 > S30 ' S40 步驟 20、120a、120b 籃狀物 40、140 熱交換器 60 送風機 72、172 出水口 130 ' 230 供應部件 132 ' 232 第二喷嘴部件 14[Main component symbol description] 10, 110 plating tank 30 conduit 50 shielding film 70, 1 70 auxiliary groove 112 shelf 131, 23 1 first nozzle member 131a ' 132a nozzle S10 ' S20 > S30 ' S40 step 20, 120a 120b basket 40, 140 heat exchanger 60 blower 72, 172 water outlet 130' 230 supply part 132' 232 second nozzle part 14
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TWI485286B (en) | 2011-11-16 | 2015-05-21 | Ebara Corp | Electroless plating and electroless plating |
CN103602963A (en) * | 2013-12-03 | 2014-02-26 | 昆山亿诚化工容器有限公司 | Novel electroplating facility |
KR101816028B1 (en) | 2015-01-23 | 2018-01-08 | 코닝정밀소재 주식회사 | Metal bonded substrate |
CN107231754B (en) * | 2017-06-29 | 2019-10-22 | 深圳崇达多层线路板有限公司 | It is a kind of to improve the undesirable method of plated through-hole generated in assist side manufacturing process |
CN110408916B (en) * | 2019-08-26 | 2021-08-17 | 惠州市安泰普表面处理科技有限公司 | Chemical nickel plating method |
CN115595566B (en) * | 2022-11-17 | 2024-05-28 | 西华大学 | Environment-friendly, energy-saving, efficient and flexible chemical plating device and method |
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CN2601259Y (en) * | 2003-01-30 | 2004-01-28 | 中国第一汽车集团公司 | Water bath heating chemical plating plant |
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