1^.59889 九、發明說明： 【發明所屬之技術領域】 j本發明係有關於一種光觸媒合成纖維成型方法及其 製品，尤指一種利用光觸媒絨毛之光觸媒合成纖維成型 方法及其製品。 【先前技術】1^.59889 IX. Description of the invention: [Technical field to which the invention pertains] j The present invention relates to a photocatalyst synthetic fiber molding method and a product thereof, and more particularly to a photocatalytic synthetic fiber molding method using photocatalyst fluff and a product thereof. [Prior Art]
思著工業與科技的發展，人們的生活水準雖已獲得 長足的改善，但是環境卻也因而受到污染，光觸媒技術 :有效處理7乂中的氯苯有機物、氯盼化合物、氰化物及 金屬離子等污毕必j 甘U # 寻可木物其也可處理空氣中的氧化氮 X Kb硫（SQX)等污染物’而在光觸媒反應中， 光觸媒僅是催化劑而不會祐喷 m ,, .k ^ * ， 環谙祕’因此非常適用於居家 —二氣、水、除臭、殺菌及預防髒污的材料。 •铁ί 通常為了隔絕陽光直曬而裝設窗簾， 二自簾便與外界空氣最直接的接觸，而為了消除空氣 中的污染物，除了裝^# '、二八 佈3 有觸媒功能的空調，在窗簾上 式有兩種··、—，=的方式。f知朗媒窗簾的製作方 布上，雖然製作上相當便利 =好心簾 但是通常光觸媒不易附 =眾也可自行製作’ 故使得光觸媒附著在窗簾^ 且由於噴灑的緣 九觸媒为染物、殺 " 便仔 種則是將窗簾布浸泡入光觸二 =果不甚理想；另-滿光觸媒，因此效杲^觸媒丄射，可使窗簾布上佈 布上脫落的問題存在Χ ’但是部同樣有光觸媒由窗簾 ，而且浸泡過光觸媒的窗簾布在外 觀顏色上會與原本的顏罝 —種方法以解決 弁: 、。口此本發明人提出 【發明内容】 戚布製作上的問題。 本發明的主要目的，在於趄 成型方法及，置可八2供一種光觸媒合成纖维 ..μ ，、 其可令光觸媒穩固的附著在製。Μ 表面上，並均勻且敏來 ]有隹衣η 口的 觀顏辛也不會改變製品原本外 〜 ib °增加光觸媒的面積以增強S觸媒的效果。 為了達到上述目的，本發明提供一 維成型方法，其步驟包括：種先觸媒合成纖 提供一絨毛絲； 切割該絨毛絲成複數小段絨毛； 浸=該等小段絨毛於-分散劑及—靜電劑之混合液 浸泡該等小段絨毛於一光觸媒凝膠中； 提供一基材，並塗佈接著劑於該基材上；以及 黏附該等小段絨毛於該基材上。 如此可使光觸媒穩固的附著在基材的表面上並均句且緻 密的分佈’也不會改變基材原本外觀顏色，藉由織毛择 加表面積以增加光觸媒的作用面積，進而增加光觸媒^ 本發明另提供一種光觸媒合成纖維製品，其包括一 基材；以及一層光觸媒絨毛，係黏附在該基材上；其中 該光觸媒Μ毛賴毛上具有光觸媒。㈣光觸媒織毛穩 固的附著在基材的表面上並均勻且緻密的分佈，而且基 1359889 色並不會被絨毛改變，並藉由光觸媒絨毛姆加 先觸媒的作用面積，以增加光觸媒的效果。、加 為使忐更進一步瞭解本發明之特徵及技術内容，4 發明之詳細說明與附圖’然而所附圖式ί提 供多考與祝日月用，並非用來對本發明加以限制者。^ 【實施方式】 請參閱第-圖至第五圖，本發明提供—種光人 成纖維成型方法，其主要步驟包括： 、5 提供一絨毛絲1 ; 切割該絨毛絲1成複數小段絨毛11; 浸泡該等小段絨毛11於一分散劑2及一靜電劑3之 混合液中； ^泡該等小段絨毛！ 2於—架橋劑4 (Mnd…中； =泡該等小段絨毛1j於一光觸媒凝膠5中； 提供-基材6，並塗佈接著劑6 i於該基材上；以及 __ 黏附該等小段絨毛1 1於該基材6上。 在提供一絨毛絲1的步驟中，其所提供的絨毛絲i可為 一尼龍纖維絲一達克龍纖維絲或—壓克力纖維絲等合 成纖維絲或是將上述合成纖維絲與天然纖維絲，如羊毛 纖維絲、棉㈣料等H纖維絲複合製成的複合纖維 絲。之後収將上騎提供㈣毛絲h成複數小段織 毛1 1。然後再將小段絨毛i i浸泡入含有一分散劑2 及:靜電劑3的混合溶液中，以讓分散劑2與靜電劑3 附著於小絨毛1 1的表面。接下來，則將該等已經附 1309889 著有分散劑2與靜電劑3的小段絨毛1 1浸泡入架橋劑 4中，以讓架橋劑4附著於小段絨毛1 1的表面而在分 散劑2與靜電劑3的外面形成一層架橋劑4。之後再將 已浸泡過架橋劑4後的小段絨毛1 1浸泡入光觸媒凝膠 . 5中’以使小段絨毛1 1的最外面形成一層光觸媒凝膠 5。接著，提供一基材6，並在基材6的一表面上塗佈 一層接著劑βΐ。最後將塗佈接著劑6i的基材6與該 荨附著有光觸媒凝膝5的小段絨毛1 1置放於一電場8 中，由於該等小段絨毛1 1附著有靜電劑3，因此其帶 有靜電荷而會受到電場8的牽引往正電的方向移動，而 將基材6放置在電場8的正電側，並將接著劑6 ;[面向 該等小段絨毛1 1，並藉著電場8的作用使小段絨毛工 1得以貼附在接著劑6丄上，而進一步黏附在基材6的 表面上。如此即可得到一具有光觸媒絨毛層的製品。藉 由架橋劑4的作用，使光觸媒得以穩固的附著在架橋劑 4上進而附著在小段絨毛丄丄的外層。而藉由靜電劑 _ 3、接著劑6 1與電場8的作帛，使小段絨毛i丄得以 穩固並緻密时佈在基材6的—表面上，@此基材6的 -表面佈滿小段絨M i而另—表面則為基材6原本的 外觀。另外小段絨毛i i使得基材6佈滿小段域毛工丄 .的-面之表面積增加’使得光觸媒的作用面積增加，而 能夠增加光觸媒的功能。 而本發明之光觸媒合成纖維成型方法進一步包含下 列步驟： 烘乾該等浸泡過該混合液的小段絨毛丄 1359889 烘乾該等浸泡過該架橋劑4的小段絨毛1 1 ; 供乾該荨浸泡過光觸媒凝膠5的小段絨毛1 1。 上述的二個步驟分別係於浸泡該等小段絨毛1 1於一分 散劑2及一靜電劑3之混合液中、浸泡該等小段絨毛1 1於一架橋劑4中及浸泡該等小段絨毛1 1於一光觸媒 凝朦5中’三個步驟之後’以烘乾該等小段絨毛1工， 以使分散劑2、靜電劑3、架橋劑4及光觸媒凝膠5得 以穩固的附著在小段絨毛1 1的表面上。 在本發明中，架橋劑4的濃度，可為〇%〜1〇〇 ^對於水的重量百分比濃度，也就是說，當架橋劑4的 濃度為1 〇% ，即代表架橋劑4與水的重量百分比分別 為10%與90% 。而當架橋劑4的濃度為〇% ，換句 話說就是不添加架橋劑4，因此本發明光觸媒合成纖維 成型方法可以變更為如第一圖所示的步驟，其缺少「浸 泡該等小段絨毛1 於一架橋劑4 (binde〇中」及「供 乾該等浸泡過該架橋劑4的小段絨毛i丄」，而所製成的 光觸媒的小段絨毛i i也就不具有架橋劑4這一層。架 橋劑4的功能係增加光觸媒結晶的附著能力，因二即使 不添加架橋劑4，光觸媒依舊能夠附著於 的表面’只是其附著的程度較差。 又絨毛11 方』九圖’為本發明之光觸媒合成纖維成形 ::用標準的乙酸丁酷氣體測定先觸媒:=;品: 化工虱的能力。其所操作的變因為架橋劑 將光觸媒合成纖維製品是否經由水洗。 /又 ^由弟六圖及第七 1359889 .】觸知當架橋劑4的濃度為20%時，本發明的 維製品具有最佳的淨化空氣能力 確疋木橋劑4的濃度最佳為2Q% 。另外再 第九圖可以得知’本發明的 = ;=將其供乾的空氣淨化能力二 維製品，這是由於水洗的步驟可以沖洗掉Thinking about the development of industry and science and technology, people's living standards have been greatly improved, but the environment has been polluted. Photocatalyst technology: effective treatment of chlorobenzene organic compounds, chlorine-promoting compounds, cyanide and metal ions in 7乂污毕必j Gan U # 寻 可木物 It can also treat nitrogen oxides such as X Kb sulfur (SQX) in the air'. In the photocatalytic reaction, the photocatalyst is only a catalyst and will not spray m , , .k ^ * , 谙 谙 secret 'is therefore very suitable for home - two gas, water, deodorant, sterilization and prevent soiling materials. • Iron ί is usually installed to protect the sun from direct sunlight. The second curtain is the most direct contact with the outside air. In order to eliminate the pollutants in the air, in addition to the ^# ', two eight cloth 3 with catalyst function Air conditioning, there are two ways of ··, —, = in the curtain. f knowing that the fabric of the ceremonial curtain is made on the fabric, although it is quite convenient to make it = good heart curtain, but usually the photocatalyst is not easy to attach = the public can also make it by itself, so that the photocatalyst is attached to the curtain ^ and because the sprayed rim is the dye, kills " The seed is soaked in the curtain cloth into the light touch two = fruit is not ideal; another - full of light catalyst, so the effect of the 触 ^ 丄 丄 , , , , , 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 窗帘 但是 但是 但是 但是 但是 但是 但是There are also photocatalysts made up of curtains, and the curtain fabrics soaked in photocatalysts will be compared with the original ones in terms of the color of the appearance to solve the problem: The present inventors have proposed [invention] The problem in the manufacture of crepe cloth. The main object of the present invention is to form a bismuth molding method and to provide a photocatalyst synthetic fiber ..μ, which can firmly adhere the photocatalyst. Μ On the surface, it is even and sensitive. There is no change in the original appearance of the product. ~ ib ° increases the area of the photocatalyst to enhance the effect of the S catalyst. In order to achieve the above object, the present invention provides a one-dimensional molding method, the steps comprising: providing a fluff yarn by a first catalyst synthetic fiber; cutting the pile yarn into a plurality of small piles; dipping = the small pieces of fluff in a dispersing agent and - static electricity The mixture of the agents soaks the small pieces of fluff in a photocatalyst gel; providing a substrate and applying an adhesive to the substrate; and adhering the small pieces of fluff to the substrate. In this way, the photocatalyst can be firmly adhered to the surface of the substrate and the uniform and dense distribution does not change the original appearance color of the substrate, and the surface area of the photocatalyst is increased by the woven fabric to increase the photocatalyst, thereby increasing the photocatalyst. Further provided is a photocatalyst synthetic fiber product comprising a substrate; and a layer of photocatalyst fluff adhered to the substrate; wherein the photocatalyst has a photocatalyst on the hair. (4) The photocatalyst woven wool is firmly adhered to the surface of the substrate and uniformly and densely distributed, and the color of the base 1359889 is not changed by the fluff, and the photocatalyst fluffing plus the area of the first catalyst is added to increase the photocatalytic effect. The detailed description of the present invention and the technical content of the present invention are provided for the purpose of further understanding of the invention. [Embodiment] Please refer to the first to fifth figures, the present invention provides a method for forming a human optical fiber, the main steps of which include: 5, providing a pile 1; cutting the pile 1 into a plurality of small piles 11 Soaking the small pieces of fluff 11 in a mixture of dispersing agent 2 and an electrostatic agent 3; ^ soaking the small pieces of fluff! 2 in the bridging agent 4 (Mnd...; = soaking the small pieces of fluff 1j in a photocatalyst gel 5; providing - a substrate 6 and applying an adhesive 6 i on the substrate; and __ adhering the The small piece of fluff 1 1 is on the substrate 6. In the step of providing a pile yarn 1, the pile yarn i provided may be a nylon fiber yarn, a Dylon fiber or an acrylic fiber. The fiber filament is a composite fiber yarn made by combining the above-mentioned synthetic fiber yarn with natural fiber yarn, such as wool fiber yarn, cotton (four) material and the like. After that, it is provided to provide (four) wool yarn h into a plurality of small-length woven wool 1 1 Then, the small piece of fluff ii is soaked into a mixed solution containing a dispersing agent 2 and an electrostatic agent 3 to adhere the dispersing agent 2 and the electrostatic agent 3 to the surface of the small fluff 1 1. Next, then 1309889 A small length of fluff 1 1 with dispersing agent 2 and electrostatic agent 3 is soaked into bridging agent 4 to allow bridging agent 4 to adhere to the surface of small piece of fluff 1 1 to form a layer of bridging on the outside of dispersing agent 2 and electrostatic agent 3. Agent 4. Then, the small piece of fluff 1 1 after soaking the bridging agent 4 is soaked into the photocatalyst. 5 'to form a photocatalyst gel 5 on the outermost surface of the small section 1 1 . Next, a substrate 6 is provided, and a layer of an adhesive β ΐ is applied on one surface of the substrate 6. Finally, an adhesive is applied. The substrate 6 of 6i and the small piece of fluff 1 1 to which the photocatalyst is attached to the crucible 5 are placed in an electric field 8. Since the small pieces of the fluff 1 1 are attached with the electrostatic agent 3, they are electrostatically charged and subjected to an electric field. The traction of 8 moves in the positive direction, while the substrate 6 is placed on the positive side of the electric field 8, and the adhesive 6; [facing the small segments 1 1 and the small section of the pile by the action of the electric field 8 1 can be attached to the adhesive 6 , and further adhered to the surface of the substrate 6. Thus, an article having a photocatalyst fluff layer can be obtained. By the action of the bridging agent 4, the photocatalyst can be firmly attached to the bridge. The agent 4 is further attached to the outer layer of the small-sized fluff, and by the electrostatic agent_3, the adhesive agent 61 and the electric field 8, the small-sized fluff is stabilized and densely coated on the surface of the substrate 6. On, the surface of this substrate 6 is covered with a small section of velvet M i and the other surface is The original appearance of the substrate 6. In addition, the small length of the fluff ii causes the substrate 6 to be filled with a small area to increase the surface area of the surface, so that the active area of the photocatalyst is increased, and the function of the photocatalyst can be increased. The photocatalyst synthesis of the present invention The fiber forming method further comprises the steps of: drying the small-sized fluff 1359889 soaked through the mixed liquid, drying the small pieces of fluff 1 1 soaked through the bridging agent 4; and drying the small portion of the photocatalyst gel 5 Fluff 1 1 . The above two steps are respectively immersed in the mixture of the small pieces of fluff 1 1 in a dispersing agent 2 and an electrostatic agent 3, soaking the small pieces of fluff 1 1 in a bridging agent 4 and soaking the The small piece of fluff 1 1 is dried after the 'three steps' in a photocatalyst gel 5 to dry the froth, so that the dispersant 2, the electrostatic agent 3, the bridging agent 4 and the photocatalyst gel 5 are firmly adhered. On the surface of the small section of fluff 1 1 . In the present invention, the concentration of the bridging agent 4 may be 重量%~1〇〇^ for the weight percentage concentration of water, that is, when the concentration of the bridging agent 4 is 1%, which represents the bridging agent 4 and water. The weight percentages are 10% and 90%, respectively. When the concentration of the bridging agent 4 is 〇%, in other words, the bridging agent 4 is not added, the photocatalyst synthetic fiber forming method of the present invention can be changed to the step shown in the first figure, which lacks "soaking the small pieces of fluff 1 In a bridge agent 4 (binde〇中) and "drying the small section of the bristle agent 4 soaked", the small fluff of the photocatalyst produced does not have the layer of bridging agent 4. The function of the agent 4 is to increase the adhesion ability of the photocatalyst crystal, because even if the bridging agent 4 is not added, the photocatalyst can still adhere to the surface 'only the degree of adhesion is poor. The fluff 11 square "nine figure" is the photocatalyst synthesis of the present invention. Fiber Forming:: Determination of the first catalyst with standard acetic acid gas: =; Product: The ability of the chemical industry. The operation is changed by the bridging agent whether the photocatalyst synthetic fiber product is washed by water. Seventh 1359889.] It is known that when the concentration of the bridging agent 4 is 20%, the dimension of the invention has the best air purifying ability, and the concentration of the rafting agent 4 is preferably 2Q%. '= The present invention; = dry air for its purification ability of two-dimensional articles, which is due to the water washing step may be washed away
作，可，而水洗後的洪乾動 入了乂將在光觸媒合成纖維製品表面的溶劑揮發心 王，因而能夠減少淨化空氣能力的耗費， :凡 媒合成纖維製品淨化空氣的能力。f進而k幵光觸 圖至媒合成纖維成型方法可用於製造如第十 j媒合成纖維製品7係在—基材6(如第五圖所= 上黏附上複數具有光觸媒的小段絨毛. 為如第十圖至第十二圖所示的為一竹簾72:、36可 =7 3或τ鞋墊74 ’並在其上佈設一層光觸ς域： ’如此則可讓竹簾7 2或汽車遮陽塾7 3、淨 :氣的功能，而鞋墊74具有除臭的功能。而 :觸媒合成纖維製品7可以等效應用於如窗簾布Τ月 口罩（圖略）#與外界接觸的日常用品， = ，某合成纖維製品7只在基材6的—面植上光觸媒 7 1，因此對於具有外觀與内裡的物品，如鞋 、喊 ，物（圖略）等更適合用光觸媒絨毛7丄來進行；、 殺囷’如此光觸媒域毛7!得以被廣泛的運用在日當^ 活的用品中，使得生活環境更加乾淨與舒適。 丄 以 本發明之專二本發明之較佳可行實施例，非因此侷限 所為運用本發明說明書及圖示内容 斤為之專效㈣變化，均包含於本發明之範圍内。 【圖式簡單說明】 第明光觸媒合成纖维成型方法不添加架橋 第二圖係本發明光觸媒合成纖維成型方法之完 圖。 12本發㈣觸媒合成纖維成型方法切割賊毛絲 不思圖。 第四圖係本發明光觸媒合成纖維成型方法小 之不意圖。 第發！光觸媒合成纖維成型方法小段絨毛黏 於暴材的不意圖。 第六圖係本發明光觸媒合成 圖。 整流程 劑 之 段織毛成品 附 纖維製品的功能測試結果 第：圖t本發明光觸媒合成纖維製品在經過水洗後的功 能測試結果圖。 ^ 第=圖係ί發明在架橋劑濃度1Q%下經水洗與未經水 洗的功此效果比較圖。 第九圖穌發明在架橋劑濃度2 Q%下經水洗與未經水 洗的功能效果比較圖。 第十圖係本發明光觸媒合成纖維製品第-實施例之分解 圖。 11 13-59889 第十一圖係本發明光觸媒合成纖維製品第二實施例之分 解圖。 第十二圖係本發明光觸媒合成纖維製品第三實施例之分 解圖。 【主要元件符號說明】 1 絨毛絲 11 小段絨毛 2 分散劑However, the water-washed squirting squirts the solvent that will volatilize the solvent on the surface of the photocatalyst synthetic fiber product, thereby reducing the cost of purifying the air: the ability of the synthetic fiber product to purify the air. f, k 幵 触 至 至 至 至 至 至 至 至 至 可 至 至 至 至 至 至 至 可 可 可 可 可 可 可 可 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十 第十The tenth to twelfth figures show a bamboo curtain 72:, 36 can be = 7 3 or τ insole 74' and a layer of light touches is placed on it: 'This allows the bamboo curtain 7 2 or the car Sunshade 7 3, net: gas function, and insole 74 has the function of deodorization. And: catalyst synthetic fiber products 7 can be equivalently applied to such as curtains, moon masks (figure) # everyday items in contact with the outside world , = , a synthetic fiber product 7 only on the surface of the substrate 6 planted with photocatalyst 7 1, so for items with appearance and lining, such as shoes, shouting, objects (figure), etc. are more suitable for photocatalyst villi 7丄To carry out; killing 'such a photocatalyst domain hair 7! has been widely used in the daily necessities to make the living environment more clean and comfortable. 较佳 丄 本 本 本 本 本 本 较佳 较佳 较佳 较佳 较佳 较佳 较佳 较佳, and therefore is not limited by the use of the specification and the content of the present invention. The variations are all included in the scope of the present invention. [Simplified description of the drawings] The photocatalyst synthetic fiber molding method does not add a bridge. The second figure is a complete diagram of the photocatalyst synthetic fiber molding method of the present invention. 12 (4) Catalyst Synthesis The fiber forming method cuts the thief's hair and does not think about it. The fourth picture shows that the photocatalyst synthetic fiber forming method of the present invention is not intended to be small. The first! Photocatalyst synthetic fiber forming method is not intended to stick to the explosive material. Inventive Photocatalyst Synthetic Map The functional test result of the finished woven fabric of the finished woven fabric with the fiber product is as follows: Fig. t The functional test result of the photocatalytic synthetic fiber product of the present invention after washing with water. ^ The first figure is the invention of the bridging agent concentration Comparison of the effects of washing and unwashing at 1Q%. Figure 9 compares the functional effects of water washing and non-washing at a bridging agent concentration of 2%. The tenth is the photocatalyst synthetic fiber of the present invention. An exploded view of the first embodiment of the article. 11 13-59889 The eleventh drawing is an exploded view of a second embodiment of the photocatalyst synthetic fiber product of the present invention. FIG twelve lines exploded view of a third embodiment of the present invention photocatalyst synthetic fiber article. The main element REFERENCE NUMERALS 1 wire fluff fluff subparagraphs 2 11 Dispersant
3 靜電劑 4 架橋劑 5 光觸媒凝膠 6 基材 6 1 接著劑 7 光觸媒合成纖維製品 71 光觸媒絨毛 7 2 竹簾 73 汽車遮陽墊 7 4 鞋墊 8 電場 123 Electrostatic agent 4 Bridging agent 5 Photocatalyst gel 6 Substrate 6 1 Adhesive 7 Photocatalyst synthetic fiber 71 Photocatalyst fluff 7 2 Bamboo curtain 73 Car sunshade 7 4 Insole 8 Electric field 12