TWI357415B - - Google Patents

Description

1357415 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a plastic enamel masterbatch and a pottery ice product, and the soap is protected from a, table & method and application. It is a bamboo charcoal plastic product made by combining bamboo charcoal with a special plastic single enamel, A such as a variety of plastics, and with bamboo fiber charcoal products made of enamel plastic masterbatch and its manufacture. And by its [prior art]

Η , , , , 斗 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ', r in the temporary (four) "prepared bamboo long-wearing, can release the stored minerals, and through the basin /, eve pores,, σ traits and their own properties to achieve air elimination In the middle of the taste of the public j. Soil I, no knife, anti-means, regulate moisture, release red line and release negative ions, ^ ^ ^ q π bamboo 侑 long-wear products have been widely made into commercial products, It is also used in the fields of industry, agriculture, electronics, medical and health, food processing, environmental protection, textiles, etc. In view of the deodorization, purification and absorption of impurities, regulation of moisture, release of negative ions and far infrared rays, the bamboo preparation industry is currently in the plastics industry. The products produced are also blended into various plastic raw materials to increase the specific efficacy of the products produced and further enhance the added value of the products. The current practice in the industry is based on the final products. The materials used are polyethylene (abbreviated as ΡΕ), polypropylene (p〇lypr〇pyiene, abbreviated as PP), polystyrene (p〇lystyrene, abbreviated as .pS), acrylonitrile·丁一妇·本Acrylonitrile-butadiene-styrene (abbreviated as ABS) 'polycarbonate (p〇lycarb〇nate, abbreviated as pc), or polyamine 5 1357415 (polyamide, abbreviated as PA), etc. The plastic monomers of the same material are mixed with the bamboo charcoal powder particles of the proportion of the mixture to form a mixture (in the mixture, the content of the bamboo charcoal powder particles is generally set to I 1 〇 (4)), and the mixture is first subjected to a compact mixer. Mixing and hooking, and then granulating by a screw-type extrusion granulator to produce a specific plastic bamboo charcoal masterbatch that can be used together, for example, when the final product is a PE plastic bag, The pE monomer and the bamboo charcoal powder are mixed to prepare PE bamboo charcoal masterbatch, and the pE bamboo charcoal masterbatch is mixed into the PE plastic raw material to be further extruded into a bamboo charcoal plastic bag. Although the existing manufacturing method can be prepared to contain Bamboo charcoal plastic masterbatch of bamboo charcoal powder And can be combined with a specific plastic material to produce a product with a predetermined type, but in fact, there are still the following defects: First, when manufacturing bamboo charcoal plastic masterbatch in the existing way, must consider the material of the final product, first correspondingly The bamboo charcoal plastic masterbatch having the same plastic material as the final product can be smoothly blended into the final product, so that the existing manufacturing method has poor versatility relative to the bamboo charcoal plastic masterbatch, resulting in process time. The shortcomings of prolonged, reduced manufacturing efficiency, and poor economic efficiency. 1. Since the bamboo charcoal plastic masterbatch is manufactured as described above, considering the technical and manufacturing costs, the added amount of bamboo charcoal powder in the mixture is at most 1 Owt ° / 〇 ' so that the bamboo charcoal plastic masterbatch in the prepared bamboo charcoal content is also only 1 Owt%, when the bamboo charcoal plastic masterbatch is further added to the same material of plastic to make a product with a predetermined type , the bamboo anaesthetic content in the final product will be less than 1 〇wt% 'to make the existing bamboo charcoal plastic masterbatch and its manufacturing method relatively The obtained product has a low bamboo charcoal content and cannot effectively exert the disadvantages of bamboo charcoal efficacy. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a bamboo charcoal plastic masterbatch that can be combined with plastics of various materials and has a substantially high bamboo charcoal content. Another object of the present invention is to provide a process for producing a bamboo charcoal plastic masterbatch which has a high bamboo charcoal content and which can be combined with various plastics. Further, the present invention further provides a bamboo charcoal plastic product obtained by using the bamboo charcoal plastic masterbatch in combination with various plastics. Therefore, the bamboo charcoal plastic masterbatch of the present invention is prepared by closely mixing and granulating a half of the finished product composition, the semi-finished composition comprising a plastic component, a bamboo charcoal component, and an ionic bond mixed in a predetermined ratio. a polymer component, and a coupling agent component. The plastic component is a polymer selected from the group consisting of thermoplastics, and is a material selected from the group consisting of ethylene-butyl-acrylate (EBA) and acetamidine- Acrylic-ethylene-acrylate (abbreviated as EMA), ethylene-ethyl-acrylate (EEA), and acetonitrile-octene copolymer ( Poly(octene-ethylene), or a type a olefin polymerized copolymer, abbreviated as POE, is a polyolefin elastomer) ° The charcoal component includes a plurality of uniformly dispersed in the plastic component. Bamboo charcoal powder, which is made from bamboo charcoal which is smelted at a high temperature and further ground into ultrafine powder. The ionomer component is a material selected from the group consisting of a zinc ion type polymer, a sodium ion type polymer, and a lithium ion type polymer. The coupler component is a material selected from the group consisting of a decane coupler, a titanate coupler, an aluminate coupler, a barium magnesium coupler, and a boron-magnesium coupler. The content of the plastic component is between 10 wt% and 50 wt%, and the content of the charcoal component is between 3 wt% and 85 wt%, based on the total weight of the semi-finished composition. The content of the component ranges from 1% by weight to 35%, and the content of the compounding agent component is from 1% by weight to 7% by weight. The beneficial effects of the invention are that: by combining the bamboo charcoal component with a specific plastic component, an ionomer component and a coupling component, the combined bamboo charcoal content can be relatively high and can be matched separately. The high-performance and multi-purpose bamboo charcoal plastic masterbatch used for various plastic materials of different materials makes the bamboo charcoal plastic masterbatch of the invention have the advantages of versatility and high bamboo charcoal content. The method for manufacturing the bamboo charcoal plastic masterbatch of the invention comprises the following steps: (1) mixing and mixing, mixing a plastic component with an ionomer component at a predetermined temperature and kneading for 5 to 2 minutes, until After uniformly softening, a bamboo charcoal component including a plurality of ultrafine bamboo powders and a coupling agent component are further added, and further kneading and kneading for 1 to 3 minutes to form a half finished product, and The total weight of the semi-finished composition is preferably 10% by weight to 85% by weight of the bamboo charcoal component; and (u) granulation, the semi-finished composition is sent to a squeezing and granulating machine, and the beneficial effect of the invention is 1357415 It is: by using the special ion-bonding polymer component and the coupling agent component, it is easy to: the carbon phase tears form the semi-finished composition, and then: the skin is high, and the wound can be smoothly produced. No::: The versatile bamboo charcoal that can be combined with granulation „ masterbatch=material (4) plastic raw material, bamboo disguised plastic masterbatch, making the invention manufacturable

The characteristics and advantages of bamboo charcoal plastic masterbatch for multi-purpose performance in South. The bamboo charcoal plastic product prepared by the bamboo charcoal plastic masterbatch is made by a bamboo charcoal plastic mixture by extrusion molding, calender molding, extrusion molding, injection molding or spinning into fibers, and the bamboo charcoal plastic mixture comprises a majority. The bamboo charcoal plastic masterbatch as described above, and the plastic raw material mixed with the bamboo charcoal plastic masterbatch in a predetermined ratio. * "Hai plastic raw material is a substance selected from the following groups: Polyethylene baking,

= propylene, polystyrene, acrylonitrile, butadiene styrene copolymer, polycarbonate, polyamide, polyamine elastomer, and polyester. The invention has the beneficial effects that: the bamboo anaplastic plastic masterbatch having the high bamboo charcoal content can be mixed with the plastic materials of different materials, and the bamboo charcoal plastic product is prepared by a predetermined molding method, the bamboo charcoal plastic The ua can be made of the plastic material to provide a predetermined molding effect and structural strength, and the bamboo charcoal powder contained in the bamboo charcoal plastic masterbatch can provide deodorization, purification, humidity control, preservation, etc., so that the bamboo charcoal of the present invention can be used. Plastic products have the same environmental, natural and health benefits, and can add value to the plastic products. [Embodiment] The above-mentioned and other technical contents, features and effects of the bamboo charcoal plastic masterbatch, the retanning process, and the products obtained therefrom are in the following preferred embodiment with reference to the drawings. I understand clearly. T liver J / month The bamboo charcoal plastic masterbatch of the present invention is a preferred embodiment of the semi-finished product by dense mixing and granulation, and the semi-finished composition comprises

Proportionally mixed - plastic component, - bamboo charcoal component, - ionic bond polymerization Φ component, and a coupling component. The plastic component is a high molecular polymer selected from the group consisting of thermoplastics, and is selected from the group consisting of: ethylene-acrylic acid butyl acrylate copolymer (EBA), ethylene-acrylic acid-acrylic copolymer (ema), ethylene-acrylic acid ethylene copolymer (EEA), and ethylene octene copolymer (p〇E).

Among them, in order to achieve good flexibility, high melting point, high thermal stability, low temperature impact resistance, strong tolerance to inorganic fillers, good compatibility with various polymers, and no change in melting point viscosity after modification. And the characteristics of easy processing, the plastic component is preferably an ethylene-acrylate copolymer as described above, and an ethylene-butyl acrylate copolymer is preferably used. The bamboo charcoal component comprises a plurality of bamboo charcoal powder particles evenly dispersed in the plastic component, and the bamboo charcoal powder particles are prepared by further grinding the bamboo charcoal charcoal which is smelted at a high temperature into ultrafine powder particles, and the The particle size range of the bamboo charcoal powder is preferably between 1 nm and 3 m. The ionomer component is a material selected from the group consisting of zinc ion type polymers, sodium ion type polymers, and lithium ion type polymers. 10 1357415 Since the ion-bonding polymer component has a metal ion bond in the hands of the ion-bonding polymer component, the polymer of adjacent polar groups can be cross-linked, thereby achieving an effect of increasing compatibility. The coupling agent component is a substance selected from the group consisting of a decane coupling agent, a titanate coupling agent, an aluminate coupling agent, a barium magnesium coupling agent, and a boron-magnesium coupling agent. Since the coupling agent is a molecule having two or more distinct reactive groups, a part of the structure of the molecule can react with the chemical group φ on the surface of the inorganic substance to form a strong chemical bond, and the other part of the group has the property of an affinity organic substance. However, it can react with organic molecules to form chemical bonds or physical entanglements, so that the coupler components can be smoothly combined to form two different properties, that is, the coupler component can be utilized in the bamboo charcoal component. • The surface of the plastic component is bonded to increase the bonding force of the two components. After the bonding ability of the interface is increased, the mechanical strength can be further improved. In addition to the component of the coupling agent, the plastic component can be improved. The content of the combined bamboo charcoal component increases the bamboo charcoal content in the bamboo charcoal plastic masterbatch, and can also be used to make the (four) carbon plastic masterbatch combined with other plastics for further processing. And can improve the mechanical strength of the final product. β is preferably 10% by weight to 50% 〇/„, based on the total weight of the composition of the sputum, and the content of the bamboo anatomical group is better. At 1〇

The content of the ion-bonding polymer component of Wt%~85 is more than 10 WI35 wt%' and the content of the coupling component is preferably between i-end and 7 t% into the ground to improve the bamboo charcoal plastic. The content of bamboo charcoal in the master batch is to enhance the application characteristics and efficacy of the bamboo charcoal, and the content of the bamboo glutinous component is preferably from 3 Gwt% to 85 wi% based on the total weight of the composition. 11 1357415 The bamboo charcoal plastic masterbatch prepared by blending and granulating the above components preferably has a particle size ranging from 1 mm to 5 mm. Further, in order to achieve a better application effect, the bamboo charcoal plastic masterbatch has an optimum particle size range of 2 mm to 3 mm. Referring to FIG. 1, the preferred embodiment of the method for producing the bamboo charcoal plastic masterbatch of the present invention is described. The method comprises the following steps: Step 101 is a close mixing, mixing the plastic component with the ionomer component in a temperature range of 73 ° c to 145 ° C and kneading for 5 to 20 minutes. After uniformly softening, the bamboo charcoal component having the bamboo charcoal powder particles and the coupling agent component are further added, and the kneading is continued by kneading for 10 to 30 minutes to form the semi-finished product composition. Step 102 is granulation, and the semi-finished composition is sent to a squeezing and granulating machine, and is granulated in a temperature range of TC~19 (rc, and the particle size range is obtained by kneading and extruding. The general-purpose bamboo charcoal plastic masterbatch of lmm~5mm can be used for the single-screw or twin-screw type according to the demand, wherein the semi-finished composition can be obtained by using a twin-screw extrusion mixing granulator. The kneading of the kneading mixture is better, and therefore, the better use effect can be achieved. In addition, the extrusion kneading granulator has a die rotary knife which is formed with a porous hole and can be used for granulation, the mold The head rotary knife can be of a hot cut type or a water type 2 design. Among them, it is preferable to use a hot cut type die rotary knife, and when the semi-finished product composition is kneaded and pushed to the rotary cutter of the die, Hot-cut granulation is immediately carried out. Since the hot-cut die-turning knives have a special cold heading system, the water-ring die-turning knives use water to cool the water containing 12, resulting in a relatively poor quality of the masterbatch. .., 'Rotate the knife to make the bamboo charcoal The masterbatch of the masterbatch should contain two components: the composition of the semi-finished product formed in step 101 is opposite to the content of the semi-finished product of the bismuth bamboo charcoal plastic masterbatch, so it will not be described here. The obtained bamboo charcoal plastic masterbatch can enter

L is combined with a suitable plastic material to make a simple rm 具有 with additional additional effects. Therefore, the preferred embodiment of the bamboo charcoal plastic product of the present invention is formed by extrusion molding, calendering, extrusion molding, and injection of a bamboo charcoal plastic mixture. Or the method of drawing the silk and the like, the bamboo charcoal plastic mixture comprises a plurality of bamboo charcoal plastic masterbatch prepared according to the foregoing steps, and a plastic raw material mixed with the bamboo charcoal plastic masterbatch in a predetermined ratio.

a The raw material of the plastic is - a substance selected from the group consisting of Polyethylene, polypropylene, styrene, acrylonitrile, butadiene, styrene, polycarbonate, polyamide , polyamide elastomers, and polyester. The cerium of the bamboo charcoal plastic masterbatch is preferably between 1% by weight and 4% by weight, and the content of the plastic raw material is preferably between 6 〇wt% and 99% by weight based on the total weight of the bamboo charcoal plastic mixture. . Wherein, the bamboo charcoal plastic masterbatch and the plastic raw material are uniformly mixed in the above ratio range, and are at 14 〇. (: ~ 38 〇. In the temperature range of 〇, extrusion molding, calendering, extrusion molding, injection molding or pumping, 糸 糸 fiber processing, etc., to further form a predetermined type of bamboo charcoal plastic products 0 13 1357415 is preferred In order to increase the added value of the bamboo charcoal plastic product, an additive component may be additionally added to the bamboo charcoal plastic mixture during the process of fabricating the plastic product of the bamboo charcoal plastic, and the additive component is a substance selected from the group consisting of nano silver, nano zinc oxide, nano titanium dioxide, nano magnetic powder, antistatic agent, ultraviolet light inhibitor, photoinitiator, and straight combination. The additional application effect of the product. ' The value of 5 is especially clear, in the lookout / /, in the bamboo and other plastic masterbatch is preferred

A copolymerized vinegar polymer such as Eba, EMA, eea & p〇E as the source of the plastic group = mainly because the structure of such a polymer has a group similar to the monomer of the plastic raw material, thus When the bamboo charcoal plastic masterbatch is added to different plastic raw materials, it is compatible with the original plastic material, and the interface plastic shake masterbatch which is beneficial to the bamboo charcoal mother #^ is uniformly dispersed in the plastic ^ and the plastic (four) is also It has obvious material effect, especially through its structural similarity with the plastic raw material, which can make the bamboo charcoal plastic produced and produce turbidity. The processing fluidity is also improved. The bamboo charcoal plastic mixture is further processed::: Charcoal plastic products: furniture, rice spoons, bowls and spoons, fresh-keeping lids, plastic wrap, storage bags, tea cups, garbage bags, Trash cans, shopping bags, clothing storage bags, bristles, cleaning bristles, bottles, play: nylon yarn, poly-shells, and foamed products. ~, automotive interior panels, redundant production, therefore, the bamboo charcoal plastic products in addition to easy to shape, processing discs and pre-^ through the plastic raw materials to achieve a pre-existing structural strength characteristics, and can be formed 14 1357415 for use In addition to the predetermined structural type, the porous charcoal powder particles in the bamboo charcoal plastic masterbatch can be further utilized to effectively exert antibacterial, deodorizing, purifying air, 'adjusting moisture, releasing infrared rays and negative ions, and the like. Bamboo charcoal plastic products have additional health care features in addition to basic functions. [Specific Example] The bamboo charcoal plastic masterbatch is prepared according to the manufacturing method of the present invention, and further, the bamboo charcoal plastic masterbatch is compounded with a plastic raw material (polypropylene).

Specific examples of the charcoal rice spoon show the characteristics of the bamboo charcoal plastic masterbatch of the present invention, the method for producing the same, and the bamboo charcoal plastic product obtained therefrom. (1) Preparation of bamboo charcoal plastic masterbatch with high bamboo charcoal content: (1) Using a compact mixer and setting the temperature to 1 〇 5 art, adding 160 kg of ethylene-butyl acrylate copolymer, 3 〇 kg DuPont Sarin (SurlynK bond polymer component), pinch contract 1 () minutes to be softened, then add about 300 kg of bamboo charcoal powder, and 9 kg of vinegar coupling agent [coupler group份), continue to pressurize and knead for 2 minutes to form the semi-finished composition.

(2) The kneaded semi-finished composition is sent to a twin-screw extrusion mixing granulator, and the temperature is set at 12 (rc, and the granulated particle diameter is set at 2.5 mm 'into the Kunming refining' The bamboo charcoal plastic masterbatch having a particle size of 2 to 3 mm can be hot-cut through the die cutter, and it is worth noting that the ion-bonded group used in the step (1) is selected from DuPont. The company's packaging and industrial heat sealing and drying resins are mainly used in one of the following two products. The trade names and performance data of the ionomer components used are listed below: 15 1357415 Commodities ^\ 1 Index gram/min Sarin (13) 1-2 Finlin tm (Surlyn®) ------- 11 1650SB Sarin 1M (Surlyn®) 1652SR 5.4 One density g/mm3 0.94 1〇〇81

Melting point °C Vicat softening point

Additive or comonomer 79 Zinc ion type 0.73% Slip agent 0.27% Deodorizer

(II) Manufacture of bamboo charcoal plastic products _ Take bamboo long carbon rice spoon as an example: Take lOOg of bamboo charcoal plastic masterbatch, and the polypropylene of 90 细 h σ h U0g as the plastic raw material of the bamboo disgusting plastic. Make the two, Η 々 々 成. Evenly form the bamboo charcoal plastic I and μ' with the use of injection molding machine, in the coffee. c injection molding 'can be the bamboo charcoal plastic mixture into a 7 bamboo charcoal plastic products 0

Referring to Fig. 2 and Fig. 3, the specific example is described by the bamboo charcoal plastic spoon 2 of the bamboo charcoal plastic product. The rice spoon 2 includes a receiving body 22 extending from a front end of the grip 21, and the receiving body 22 includes spaced-abutting surfaces 221, a bottom surface 222, and a plurality of phases The upper rib 223' lower rib 224 protrudes from the receiving surface 221 at intervals and in parallel, and the pitch of the upper and lower ribs 223, (2) is larger than the particle size width of the rice grain particles and the upper ribs 223 In conjunction with the mating surface 22i, the lower ribs 224 and the bottom surface 222 also define a plurality of intersecting sections 225, 226 that are r-shaped inverted. Therefore, the rice cake 2 has the ability to withstand cold (Russia) and heat (10) in addition to the polypropylene plastic material 200 material 16 1357415. The characteristics of c) can be directly formed into a structure having a predetermined shape and a predetermined strength, and the container n can be used to hold the rice grains, and the upper and lower ribs 223 and 224 can be used to be chamfered by the r-shape. The treatment of the boundary & 225, 226 can not easily adhere to the effect of rice grains, but also through the bamboo plastic mother (four), and scattered in the raw material 200 t of bamboo anti-powder 201 to provide antibacterial, deodorant and Keep the rice delicious and fresh

The function of deterioration makes the key 2 not only as a convenient meal, but also beneficial to the health and use of the user. It is worth mentioning that the type of the bamboo charcoal plastic product should not be limited. For example, when the bamboo charcoal plastic masterbatch is combined with the plastic raw material (for example, pp or printed into a bamboo charcoal wrap, a fresh-keeping bag or a crisper, the Such bamboo charcoal powder preservation, humidity control and antibacterial effect prolong the preservation period of fish, meat, fruits and vegetables stored therein or the bamboo charcoal garbage bag made of bamboo charcoal plastic masterbatch combined with pE plastic has deodorization, taste and The antibacterial effect 'or the bamboo charcoal plastic masterbatch. The PA brush made of PA plastic can be made into the bristles, clean the bristles and has the effect of antibacterial and soft, or the bamboo charcoal plastic masterbatch The special plastic raw material for the water tank of the money room sink or the outer shell of the product: etc.: The bamboo charcoal powder contained in the bamboo charcoal plastic product can exhibit additional added value such as antibacterial and deodorizing. The invention discloses that the bamboo charcoal plastic masterbatch and the bamboo charcoal plastic product obtained by the manufacturer thereof can obtain the following functions and advantages, so that the object of the present invention can be achieved by the following: The present invention is characterized by using the bamboo charcoal component The semi-finished composition 17 1357415 formed by the predetermined plastic component, ionomer component and coupler component is characterized by the plastic component used, the ionomer component and the coupler component. The content of the bamboo charcoal component in the semi-finished product composition can be relatively raised, thereby obtaining a bamboo charcoal plastic masterbatch having a higher content of bamboo charcoal than the existing plastic masterbatch, and using the bamboo charcoal plastic masterbatch with the plastic raw material to make the bamboo anatomy In the case of plastic products, the bamboo charcoal content of the bamboo charcoal plastic product A is also higher than the bamboo charcoal content of the conventional bamboo charcoal plastic products on the market, so that the present invention can further be combined with a specific plastic in addition to the plastic masterbatch which can produce a high bamboo charcoal content. The raw material is made into a plastic product with high bamboo charcoal content, so that the obtained bamboo charcoal plastic product has better characteristics related to bamboo charcoal characteristics such as antibacterial, deodorizing, purifying, releasing infrared rays and negative ions. Bamboo charcoal plastic masterbatch made of bamboo charcoal component with specific plastic component, ionomer component and coupling component, due to its choice The plastic component has similar groups as the monomers of various plastic raw materials and can form high compatibility characteristics, so that it can be separately lapped. The plastic raw materials of various materials f are further processed into specific bamboo charcoal plastic products. The bamboo charcoal (four) masterbatch corresponding to the plastic raw material is not required to be separately manufactured for different plastic raw materials, so that the bamboo charcoal plastic masterbatch prepared by the invention has the advantages of versatility, wide application range, and The characteristics and advantages of the process time are saved. However, the above description is only a preferred embodiment of the present invention, and the scope of the present invention cannot be limited thereto, that is, the scope of the patent application and the description of the invention are generally made. The simple equivalent changes and modifications are still within the scope of the present invention. [Simplified description of the drawings] 18 1357415 FIG. 1 is a flow chart illustrating a method for manufacturing a bamboo charcoal plastic masterbatch of the present invention - a preferred embodiment Figure 2 is a perspective view showing the shape of a bamboo made by the bamboo charcoal plastic granules of the present invention. Figure 2 is a schematic cross-sectional view showing the bamboo charcoal plastic production using the rice spoon as an example. σ, by mixing a plurality of bamboo charcoal plastic masterbatch and a plastic raw material, so that a plurality of bamboo charcoal powder particles are dispersed in the plastic raw material.

19 1357415 [Explanation of main component symbols] 2........ —饭政 224·.··......lower rib 21... grip 225 ·.·. •... junction section 22... •... Body 226...· •... Junction section 221 ···· •... Sheng junction 200·"···Plastic material 222 ·...··Bottom surface 201 ···· •... Bamboo charcoal powder 223 ·. .. •...upper ribs 20

Claims (1)

I35"The 415th Anniversary of the 415th Anniversary of the Tenth, the scope of the patent application: i. A bamboo disgusting plastic masterbatch, which is made up of half of the finished product by careful mixing and granulation. The semi-finished composition contains: a plastic The component is a polymer selected from the group consisting of thermoplastics, and is a material selected from the group consisting of ethylene butyl acrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene methyl acrylate copolymer, and An ethylene-octene copolymer, and the content of the plastic component is between 1 〇 Wt% and 5 〇 wt% based on the total weight of the semi-finished composition; a bamboo charcoal component, including a plurality of uniformly dispersed in the The bamboo charcoal powder particles in the plastic component, and the content of the bamboo charcoal component is between 30 wt% and 85 wt0/, based on the total weight of the semi-finished composition. An ionomer polymer component is a material selected from the group consisting of a zinc ion type polymer 'sodium ion type polymer, and a lithium ion type polymer, and based on the total weight of the semifinished product composition; The ionomer component is contained in an amount of from 1% by weight to 5% by weight; and the coupling agent component is selected from the group consisting of: an anthracene coupling agent, a titanate couple a mixture, an aluminate coupling agent, a bismuth magnesium coupling agent, and a boron-magnesium coupling agent, and the content of the coupling agent component is from 1 Wt% to 7 Wt0/ based on the total weight of the semi-finished composition. . 2. The bamboo charcoal plastic masterbatch according to claim 1, wherein the plastic component is selected from the group consisting of ethylene butyl acrylate copolymer. 3. The bamboo charcoal plastic masterbatch according to claim 1, wherein the bamboo charcoal component is made of bamboo charcoal which is smelted at a high temperature and further ground into ultrafine powder. . 21 1357415 4. The bamboo charcoal plastic masterbatch according to the third paragraph of the patent application scope, wherein the particle size of the bamboo charcoal powder is between 丨1 j // m 〇 5 · according to the scope of the patent application 4 jf you & The bamboo charcoal plastic masterbatch described in the dry solids, wherein the bamboo charcoal plastic masterbatch has a particle size ranging from imm to 5 mm. 6. According to the towel, please refer to the bamboo charcoal plastic masterbatch described in item 5, wherein the bamboo charcoal plastic masterbatch has a particle size ranging from 2 mm to 3 mm. 7. According to the towel, please refer to the bamboo charcoal plastic masterbatch described in item 4, wherein the plastic component is selected from the group consisting of ethylene and butyl acrylate copolymer. 8. The bamboo charcoal plastic masterbatch according to the above-mentioned patent, wherein the particle size of the bamboo charcoal powder is between 1 nm and 3 mm. 9. According to the patent, the bamboo charcoal plastic masterbatch described in item i of the patent range, wherein the bamboo charcoal plastic masterbatch has a particle size ranging from 1 mm to 5 mm. The method comprises the following steps: 10. A manufacturing method for preparing a bamboo charcoal plastic masterbatch: (1) mixing and mixing, mixing the _ plastic component with the ionomer component at a predetermined temperature and kneading 5~ After 20 minutes, after uniformly softening, add a bamboo charcoal component and a coupling agent component having a plurality of ultrafine bamboo charcoal powder particles, and continue to knead and knead for 10 to 30 minutes to form a semi-finished composition; U) granulation, the semi-finished composition is sent to a squeezing and granulating machine, and the bamboo charcoal plastic masterbatch having a predetermined particle size is prepared by mixing and extruding under a predetermined temperature. The method for producing a bamboo charcoal plastic masterbatch according to claim 10, wherein in the step (1), the mixture is densely mixed at a temperature ranging from 73 t to 145 〇 c to 22 1357415. 12. The method for producing a bamboo charcoal plastic masterbatch according to the invention of claim 5, wherein in the step (ii), the semi-finished composition is in a temperature range of from 1 Torr to 190 ° C. Mixing and granulating. 13. The method for producing a bamboo charcoal plastic masterbatch according to claim 12, wherein in the step (ii), a single screw type or twin screw type extrusion mixing granulator is used. 14. The method for producing a bamboo charcoal plastic masterbatch according to the thirteenth patent of the patent application, wherein in the step (ii), a twin-screw extrusion mixing granulator is used. • The method for manufacturing a bamboo charcoal plastic masterbatch according to the above-mentioned patent application (4), wherein the extrusion mixing granulator in the step (Π) has a die rotary knife, and the die rotary cutter can be hot cut Or water ring. 16.··································································· 1 7 ·According to the application of the 12th pavilion of the patent scope of the Qing Dynasty, the method of bamboo charcoal plastic masterbatch returned by the 12th Tudor's 't' in (4) (1)t, (4) semi-finished, the content of the plastic component is between 1〇wt% The content of 50 t weight ° is between w and 85 wt% = 5 Gwt%, and the charcoal component is 3 in the ion-bonding polymer component " at 10 wt〇/o~35 wt%, and i wt% ~ 7 wt%. The content of the hai coupling agent component is the method for manufacturing the bamboo stalk plastic masterbatch according to the scope of the patent application, and the method of making the slab of the scorpion plastic granule in the step (1) The total weight of the composition, 23 1357415 The content of the bamboo charcoal component is between 30% and 85% by weight. 19. According to f, please refer to the manufacturer of the bamboo charcoal plastic masterbatch as described in Item 18, where 'in the step In (1), the plastic component is selected from the group consisting of thermoplastic: Knife <Polymer' and is a material selected from the group consisting of ethylene-acrylic butyric copolymer, ethylene-acrylic acid Tortoise copolymer 'B' _ acrylic methacrylate copolymer, and ethylene octene copolymer. The method for producing a bamboo charcoal plastic masterbatch according to claim 19, wherein in the step (1), the plastic component is selected from the group consisting of ethylene butyl acrylate copolymer. 21. The manufacturer of bamboo charcoal plastic masterbatch according to the scope of claim 2G, wherein in step (1), the bamboo charcoal particles of the bamboo charcoal component are bamboo charcoal which is smelted at a high temperature, and then further Grinded into ultra-fine. The method for producing a bamboo charcoal plastic masterbatch according to claim 21, wherein in the step (1), the particle size of the bamboo charcoal particles is between 1 nm and 3 // m 〇 23. The method for producing a bamboo charcoal plastic masterbatch according to claim 22, wherein in the step (1), the ionomer component is a substance selected from the group consisting of zinc ion type polymers. , sodium ion type polymer, and lithium ion type polymer. The method for producing a bamboo charcoal plastic masterbatch according to claim 23, wherein in the step (i), the coupler component is a substance selected from the group consisting of: a decane coupling agent, A titanate coupling agent, an aluminate coupling agent, a barium magnesium coupling agent, and a boron-magnesium coupling agent. 24 1357415 25. According to the method for producing bamboo charcoal plastic masterbatch according to item 24 of the patent application, in 4(u), the particle size range of the bamboo charcoal plastic masterbatch is from 1 mm to 5 mm. 6 _ According to the method of claim 1, the method for producing a bamboo charcoal plastic masterbatch according to the mountain article, wherein, in the step (1), the plastic component is a polymer selected from the group consisting of thermoplastics and Is a material selected from the group consisting of ethylene-acrylic acid butadiene copolymer, ethylene-acrylic acid copolymer, ethylene· A methyl acrylate copolymer, and an ethylene-octene copolymer. 27. The method for producing a bamboo charcoal plastic mother (four) according to item (4), wherein, in the step (1), the plastic component is selected from the group consisting of ethylene butyl acrylate copolymer. 28. The method for producing a bamboo charcoal plastic masterbatch according to the scope of the patent application, wherein the particle size of the bamboo charcoal particles in the step (1) is between 1 nm and 3 // m. 29. The method for producing a bamboo charcoal plastic masterbatch according to claim 1, wherein in the step (1), the ionomer component is a substance selected from the group consisting of zinc ion polymerization. , sodium ion type polymer, and lithium ion type polymer. The method for producing a bamboo charcoal plastic masterbatch according to the first aspect of the invention, wherein in the step (1), the coupler component is a substance selected from the group consisting of: a decane coupling agent, Titanate coupling agent, aluminate coupling agent, broken lock coupling agent' and boron-magnesium coupling agent. The method for producing a bamboo charcoal plastic masterbatch according to claim 10, wherein in the step (1), the bamboo charcoal plastic masterbatch has a particle size ranging from 25 to 1357415 and between 1 mm and 5 mm. 32. - A bamboo plastic product is made by extrusion molding, calendering, extrusion molding, injection molding or spinning into a fiber. The bamboo charcoal plastic mixture contains: The bamboo charcoal plastic masterbatch described in any one of items 1 to 9; and - the plastic raw material 'is mixed with the bamboo charcoal plastic masterbatch in a predetermined ratio. 33. The bamboo charcoal plastic product according to claim 32, wherein the bamboo charcoal plastic masterbatch is uniformly mixed with the plastic raw material, and is subjected to extrusion molding, calender molding, extrusion molding, and injection in a temperature range of Lt. Molded or drawn into fibers to form a predetermined type of bamboo charcoal plastic product. 34. The bamboo charcoal plastic product according to claim 33, wherein the plastic material is - selected from the group consisting of: polyethylene, polypropylene, polystyrene, acrylonitrile - Butylene-styrene copolymer, polycarbonate, polyamide, polyamide elastomer, and polyester. 35. The bamboo anthrax plastic product according to claim 34, wherein, the total weight of the bamboo charcoal plastic mixture is such that the content of the bamboo charcoal plastic masterbatch is between 1 wt% and 40 wt%, and the plastic raw material The content is between 60% by weight and 99% by weight. 〇36. According to the bamboo charcoal plastic product described in Item 35 of the patent scope, the bamboo charcoal plastic compound is made into a step-by-step selected from the following groups. Bamboo charcoal plastic products: daily time, rice spoon, bowl and spoon, stone plate ' 26 1357415 crisper, plastic wrap, bag, clothing storage bag toothbrush hair, cleaning brush shell, and foam product storage bag, tea cup, Garbage bags, trash cans, purchases, textile fabrics, nylon yarns 'polyester yarns', bottles, toys, automotive interior panels, 3C products 37. According to the bamboo charcoal plastic products mentioned in the patent scope, The bamboo anaplastic plastic corpse further comprises an additive component, and the additive component is - a substance selected from the group consisting of nano silver, nano oxidized, nano titanium dioxide, nano magnetic powder, Antistatic agent, anti-UV agent, light Starting agent, and combinations thereof. 38. The bamboo charcoal plastic product according to claim 37, wherein the bamboo charcoal plastic mixture is further formed into a bamboo plastic product selected from the group consisting of: household ware, rice spoon, tableware Spoons, chopping boards, crisper boxes, plastic wrap, storage bags, tea cups, garbage bags, trash cans, shopping bags, clothing storage bags, textile fabrics, nylon yarns, yarns, bristles, cleaning bristles, bottles, toys, Automotive interior panels, 3c product enclosures, and foamed products. 39. The bamboo charcoal plastic product according to claim 38, wherein the bamboo charcoal plastic mixture is further formed into a rice spoon, and the rice spoon comprises a handle and a front end of the handle a front extending bracket, the receiving body comprising a receiving surface spaced apart from each other, a bottom surface, and a plurality of upper ribs spaced apart from each other and protruding in parallel to the receiving surface, and the upper ribs The spacing is greater than the particle size width of the rice grain particles, and the upper ribs are also associated with the mating surface to define a plurality of junction sections having an R-shaped chamfered section. 27 1357415 40. The bamboo*&J bamboo ash plastic product according to claim 39, wherein the spoon further comprises a plurality of 倏 门 仿 且 且 且 且 且 且 且 且 且The lower ribs are disposed on the bottom surface, and the spacing of the lower ribs is greater than the particle size width of the rice grain particles, and the lower ribs cooperate with the bottom surface to define a plurality of boundary sections of the R-shaped chamfered section. 28