200846375 , 九、發明說明： 【發明所屬之技術領域】 本發明是有關於一種塑料母粒及其製造方法與應用產 品，特別是指一種結合竹炭與特定塑料單體造粒，並可與 ^ 多種塑料搭配使用的竹炭塑料母粒、其製造方法，及由其 所製得的竹炭塑料產品。 - 【先前技術】 _ 竹備長炭為最自然、環保、健康的養生產品，竹子在 ® 生長過程中，可吸收土壤中的礦物質並將其儲存在其孔隙中 \ ，經高溫1000°C以上燒製出的竹備長炭，可再將所儲藏的 礦物質釋放出來，並能透過其多孔隙的結構特質與本身材質 特性，達到消除空氣中的異味分子、抗菌、調節濕氣、釋放 遠紅線與釋放負離子等功效，因此竹備長炭產品已廣泛地被 製成商業化的產品，並應用於工業、農業、電子、醫藥衛生 、食品加工、環境保護、紡織等領域。 鑑於竹備炭具有除臭、淨化吸收雜質、調節濕氣、釋 放負離子與遠紅外線等功效，目前在塑膠工業所產製的產品 ，也開始將竹備長炭混摻入各種塑膠原料中，以增加所生產 ^ 的產品的特定功效，及進一步提升產品的附加價值。 業界目前普遍的作法是根據最終產品所採用的材質為 聚乙稀（polyethylene，簡稱為 PE)、聚丙稀（polypropylene， 簡稱為PP)、聚苯乙稀（polystyrene，簡稱為PS)、丙浠腈-丁 二烯-苯乙烯共聚物（acrylonitrile-butadiene-styrene，簡稱為 ABS)，聚碳酸酯（polycarbonate，簡稱為PC)，或聚醯胺 5 200846375 (polyamide，簡稱為PA)等，先對應地選用與該等材質相同 的塑料單體與預定比例的竹炭粉粒相混合成一混合物（在該 混合物中，竹炭粉粒的含量一般多設定在1〇 wt%)，並使該 混合物先經密練混合機混合均勻，再經螺桿式押出混煉造粒 機造粒後，製出可相配合使用的特定塑料竹炭母粒，例如， 最終產品是PE材質的塑膠袋時，則必須先以pE單體與竹 炭粉粒相混合製出PE竹炭母粒，再將該等pE竹炭母粒混 摻入PE塑膠原料中以進一步押出成型為竹炭塑膠袋。 雖然該現有製造方法已可製出含有竹炭粉末的竹炭塑 料母粒，並能再與特定的塑膠材料相配合製出具有預定型式 的產品，但實際上仍存有下列缺失： 一、以現有方式製造竹炭塑料母粒時，必須考慮最終 產品的材質，先對應地製出與該最終產品具相同塑料材質的 竹炭塑料母粒，才能順利地將該等竹炭粉末混摻到最終產品 中，使該現有製造方式相董十具有該竹炭塑料母粒的通用性較 差’導致製料間延長、製造效率降低，及經濟效益較差的 缺點。 一、由於以前述方式製造竹炭塑料母粒時，考量到技 術與製造成本，所添加的竹炭粉粒在該混合物中的含量最多 僅能達到lGWt%，使所製成的竹炭塑料母粒中的竹炭含量 也僅有l〇Wt%，當將該等竹炭塑料母粒進一步添加入相同 塑财製成具有預定型式的產品時，最終產品中的竹 里將會更少於1〇wt%，使該現有的竹炭塑料母粒與其 製U方法相對具有使所製得的產品的竹炭含量較低，而無法 200846375 有效發揮竹炭功效的缺點。 【發明内容】 因此，本發明的目的，是在提供一種可與各種不同材 質的塑料通用結合，且實質上竹炭含量相對較高的竹炭塑 料母粒。 本發明的另一目的是在提供一種能夠製出具有高竹炭 - 含量，且可與各種塑料通用結合的竹炭塑料母粒的製造方 ， 法。 ® 此外，本發明還進一步提供使用該竹炭塑料母粒搭配 各種塑料製得的竹炭塑料產品。 於是，本發明竹炭塑料母粒是由一半成品組成物經密 練混合與造粒所製成，該半成品組成物包含以預定比例相 混合的一塑料組份、一竹炭組份、一離子鍵聚合物組份， 及一偶合劑（coupling agent)組份。 該塑料組份是選自熱可塑性的高分子聚合物，並且是 I 一選自於下列群組中的物質··乙烯-丙烯酸丁酯共聚物 (ethylene-butyl-acrylate，簡稱為 EBA)、乙烯-丙烯酸·甲酯 共聚物（ethylene-methyl-acrylate，簡稱為 EMA)、乙烯-丙烯 酸乙酯共聚物（ethylene-ethyl-acrylate，簡稱為EEA)，及乙 烯-辛烯共聚物（poly(octene-ethylene)，或稱為a型烯聚合共 聚物，簡稱為P0E，是一種聚烯烴彈性體（polyolefin elastomer)) 〇 該竹炭組份包括多數個均勻地散布於該塑料組份中的 竹炭粉粒，該等竹炭粉粒是將高溫燒煉的竹備長炭，再進 200846375 一步研磨成超微細粉粒而製成。 該離子鍵聚合物組份是一選自於下列群組中的物質： 鋅離子型聚合物、鈉離子型聚合物，及鋰離子型聚合物。 該偶合劑組份是一選自於下列群組中的物質：石夕院偶 合劑、鈦酸酯偶合劑、鋁酸酯偶合劑、矽鎂偶合劑，及硼 鎮偶合劑。200846375, IX, invention description: [Technical field of invention] The present invention relates to a plastic masterbatch, a manufacturing method thereof and an application product thereof, in particular to a combination of bamboo charcoal and a specific plastic monomer granulation, and Bamboo charcoal plastic masterbatch used in combination with plastic, its manufacturing method, and bamboo charcoal plastic products made therefrom. - [Prior Art] _ Zhuji Changchao is the most natural, environmentally friendly and healthy health product. During the growth of bamboo, bamboo can absorb minerals in the soil and store it in its pores. The fired bamboo charcoal can release the stored minerals, and through its porous structural characteristics and its own material properties, it can eliminate odor molecules in the air, antibacterial, regulate moisture, and release far red lines. With the release of negative ions and other effects, the bamboo long carbon products have been widely used in commercial products, and used in industrial, agricultural, electronics, medical and health, food processing, environmental protection, textile and other fields. In view of the deodorization, purification and absorption of impurities, regulation of moisture, release of negative ions and far infrared rays, the products currently produced in the plastics industry have also begun to blend bamboo long carbon into various plastic materials to increase The specific efficacy of the products produced, and further enhance the added value of the products. The current practice in the industry is based on the materials used in the final product: polyethylene (referred to as PE), polypropylene (PP), polystyrene (PS), acrylonitrile. - acrylonitrile-butadiene-styrene (abbreviated as ABS), polycarbonate (polycarbonate, PC for short), or polyamine 5 200846375 (polyamide, abbreviated as PA), etc. The same plastic monomer as the above materials is mixed with a predetermined proportion of bamboo charcoal powder particles to form a mixture (in the mixture, the content of the bamboo charcoal powder particles is generally set at 1% by weight), and the mixture is firstly compacted. The mixer is uniformly mixed, and then granulated by a screw-type extrusion granulator to produce a specific plastic bamboo charcoal masterbatch which can be used together. For example, when the final product is a PE plastic bag, the pE must be first The body is mixed with bamboo charcoal powder to prepare PE bamboo charcoal masterbatch, and then the pE bamboo charcoal masterbatch is mixed into the PE plastic raw material to be further extruded into a bamboo charcoal plastic bag. Although the existing manufacturing method can produce bamboo charcoal plastic masterbatch containing bamboo charcoal powder, and can be combined with a specific plastic material to produce a product having a predetermined pattern, in fact, the following defects still exist: 1. In the existing manner When manufacturing bamboo charcoal plastic masterbatch, the material of the final product must be considered, and the bamboo charcoal plastic masterbatch having the same plastic material as the final product can be correspondingly produced in order to smoothly mix the bamboo charcoal powder into the final product. The existing manufacturing method has the disadvantage that the versatility of the bamboo charcoal plastic masterbatch is poor, resulting in prolonged production, reduced manufacturing efficiency, and poor economic efficiency. 1. Since the bamboo charcoal plastic masterbatch is manufactured in the foregoing manner, considering the technical and manufacturing costs, the added amount of the bamboo charcoal powder in the mixture can only reach lGWt% at most, so that the prepared bamboo charcoal plastic masterbatch The bamboo charcoal content is also only l〇Wt%. When the bamboo charcoal plastic masterbatch is further added to the same plastic product to produce a product having a predetermined pattern, the bamboo in the final product will be less than 1% by weight, so that The existing bamboo charcoal plastic masterbatch has the disadvantage that the bamboo charcoal content of the obtained product is relatively low, and the 200846375 cannot effectively exert the bamboo charcoal effect. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a bamboo charcoal plastic masterbatch that can be combined with plastics of various materials and has a substantially high bamboo charcoal content. Another object of the present invention is to provide a process for producing a bamboo charcoal plastic masterbatch which has a high bamboo charcoal content and can be combined with various plastics. In addition, the present invention further provides a bamboo charcoal plastic product obtained by using the bamboo charcoal plastic masterbatch together with various plastics. Therefore, the bamboo charcoal plastic masterbatch of the present invention is prepared by closely mixing and granulating a semi-finished composition comprising a plastic component, a bamboo charcoal component, and an ionomer polymerization mixed in a predetermined ratio. The component, and a coupling agent component. The plastic component is a polymer selected from the group consisting of thermoplastics, and is a material selected from the group consisting of ethylene-butyl-acrylate (EBA) and ethylene. -ethylene-methyl-acrylate (EMA), ethylene-ethyl-acrylate (EEA), and ethylene-octene copolymer (poly(octene-) Ethylene), or a type a olefin polymerized copolymer, abbreviated as P0E, is a polyolefin elastomer. The bamboo charcoal component includes a plurality of bamboo charcoal particles uniformly dispersed in the plastic component. These bamboo charcoal powders are made from bamboo charcoal which is smelted at a high temperature and then ground into ultrafine powder in 200846375. The ionomer component is a material selected from the group consisting of zinc ion type polymers, sodium ion type polymers, and lithium ion type polymers. The coupler component is a material selected from the group consisting of: Shi Xi Yuan coupling agent, titanate coupling agent, aluminate coupling agent, barium magnesium coupling agent, and boron town coupling agent.
以該半成品組成物的總重計，該塑料組份的含量是介 於10 wt%〜50 wt%，該竹炭組份的含量是介於1〇 wt%〜85 wt%，該離子鍵聚合物組份的含量介於1〇 wt%〜35 _%，及 該耦合劑組份的含量是介於1 wt%〜7 wt%。 本發明的有益效果在於：藉由使該竹炭組份搭配特定 的塑料組份、離子鍵聚合物組份與偶合劑組份，可製得所 結合的竹炭含量相對較高，並能分別搭配各種不同材質的 塑膠原料使用的高性能與多用途的竹炭塑料母粒，使本發 明該竹炭塑料母粒具有通錄較佳，及竹炭含量較高㈣ 性與優點。 本發明竹炭塑料母粒的製造方法包含下列步驟： 使一塑料組份與一離 ⑴#練混合’於一預定溫度下 子鍵聚合物組份相混合並捏合5〜2G分鐘，待均勻軟化後， 再加入-包括多數個超微細竹炭粉粒的竹炭組份及一偶合 劑組份，繼續加壓密練捏合10〜30分鐘，以形成一半成品 ，成物，且以該半成品組成物的總重計，該竹炭組份的: 董較佳為l〇wt%〜85wt%;及 ⑼造粒，將該半成品組成物送入一押出混煉造粒機 200846375 並具有預定粒 在一預定溫度下，混煉擠押製成呈顆粒狀 徑的竹炭塑料母粒。The content of the plastic component is from 10 wt% to 50 wt%, and the content of the charcoal component is from 1 wt% to 85 wt%, based on the total weight of the semi-finished composition, the ionomer The content of the component is between 1% by weight and 5% by weight, and the content of the couplant component is between 1% by weight and 7% by weight. The beneficial effects of the invention are that: by combining the bamboo charcoal component with a specific plastic component, an ionomer component and a coupling component, the combined bamboo charcoal content can be relatively high, and can be matched with various types. The high-performance and multi-purpose bamboo charcoal plastic masterbatch used in the plastic materials of different materials makes the bamboo charcoal plastic masterbatch of the invention have better recording and higher bamboo charcoal content and advantages. The method for manufacturing the bamboo charcoal plastic masterbatch of the present invention comprises the following steps: mixing a plastic component with a dispersing (1) #, mixing and mixing the sub-bond polymer component at a predetermined temperature for 5 to 2 G minutes, after being uniformly softened, Then add - a bamboo charcoal component and a coupling agent component including a plurality of ultrafine bamboo charcoal powder particles, continue to knead and knead for 10 to 30 minutes to form half of the finished product, the finished product, and the total weight of the semi-finished product composition The bamboo charcoal component: Dong is preferably from 10% by weight to 855% by weight; and (9) granulating, the semi-finished composition is sent to a squeezing and granulating machine 200846375 and having predetermined particles at a predetermined temperature, The bamboo charcoal plastic masterbatch is prepared by mixing and kneading into a granular diameter.
本發明的有益效果在於：藉由使用特定的塑料組份、 離子鍵聚合物組份與偶合劑組份，可容易地與該竹炭組份 相混合形成該半成品組成物’再配合t練混合與造粒就能 順利地製出竹炭含量較高且能與其他不同材質的塑膠原料 結=的通用性較佳的竹炭塑料母粒，使本發明具有可製造 出高性能多用途的竹炭塑料母粒的特性與優點。 本發明由該竹炭塑料母粒所製得的竹炭塑料產品是由 -竹炭塑料混合物經過押出成型、壓延成型、擠壓成型、 射出成型或抽絲成纖維等方式製成，該竹炭塑料混合物包 含多數個如前所述的竹炭塑料母粒，及一與該等竹炭塑料 母粒呈預定比例相混合的塑膠原料。 該塑膠原料是-選自於下列群組中的物質：聚乙稀、 聚丙烯、聚苯乙烯、丙稀腈·丁二稀苯乙烯共聚物、聚碳酸 酉曰、聚醯胺、聚醯胺彈性體，及聚酯。 本發明的有益效果在於：配合使用該等具有高竹炭含 量的竹炭塑料母粒可分別與各種不同材質的塑膠原料相混 合，並經預定的成型方式製出竹炭塑料產品，該竹炭塑料 產品不但可藉由該塑膠原料提供預定的成型效果與結構強 度’還可藉由該竹炭塑料母粒所含的竹炭粉粒提供除臭、 淨化、調濕、保鮮等功效，使本發明該竹炭塑料產品相對 具有可增進環保、自然與健康的功效，而可提升該塑料產 品的附加價值。 200846375 【實施方式】 本發明竹炭塑料母粒、其製造方法，及由其所製得的 竹厌塑枓產品的前述以及其他技術内容、肖點與功效 以下配合參考圖式的一較佳實施例的詳細說明中 楚地明白。 肝了，月The invention has the beneficial effects that: by using a specific plastic component, an ionomer component and a coupler component, the bamboo charcoal component can be easily mixed to form the semi-finished composition. Granulation can smoothly produce bamboo charcoal plastic masterbatch with high bamboo charcoal content and can be combined with other plastic materials of different materials to make the bamboo charcoal plastic masterbatch capable of producing high performance and multipurpose. Features and benefits. The bamboo charcoal plastic product prepared by the bamboo charcoal plastic masterbatch is prepared by extrusion molding, calendering molding, extrusion molding, injection molding or spinning into fibers, and the bamboo charcoal plastic mixture comprises a majority. The bamboo charcoal plastic masterbatch as described above, and a plastic raw material mixed with the bamboo charcoal plastic masterbatch in a predetermined ratio. The plastic material is - a material selected from the group consisting of polyethylene, polypropylene, polystyrene, acrylonitrile-butadiene styrene copolymer, polycarbonate, polyamine, polyamine Elastomers, and polyester. The invention has the beneficial effects that: the bamboo charcoal plastic masterbatch having the high bamboo charcoal content can be separately mixed with the plastic materials of different materials, and the bamboo charcoal plastic product can be prepared by a predetermined molding method, and the bamboo charcoal plastic product can not only be By providing the predetermined molding effect and structural strength of the plastic raw material, the bamboo charcoal powder particles contained in the bamboo charcoal plastic masterbatch can provide deodorization, purification, humidity control, fresh preservation and the like, so that the bamboo charcoal plastic product of the present invention is relatively It has the effect of enhancing environmental protection, nature and health, and can increase the added value of the plastic product. 200846375 [Embodiment] The foregoing bamboo charcoal plastic masterbatch of the present invention, a method for producing the same, and the above-mentioned other technical contents, points and effects of the bamboo disguised plastic product produced therefrom are a preferred embodiment of the following reference drawings. The detailed description of Chu Chu understands. Liver, month
本發明竹炭塑料母粒該較佳實施例是由一半成品組成 物經密練混合與造粒所製成，該半成品組成物包含以預定 比例相混合的-塑料組份、—竹1纟讀、—料鍵聚合物 組份，及一偶合劑組份。 該塑料組份是選自熱可塑性的高分子聚合物，並且是 一選自於下列群組中的物質：乙烯_丙烯酸丁醋共聚物 (EBA)、乙烯-丙稀酸_甲酿共聚物（EMA)、乙烯_丙_酸乙醋 共聚物（EEA)，及乙烯-辛浠共聚物（p〇E)。 其中，為了達到柔韌性佳、熔點高、熱穩定性高、低 溫抗衝擊性、對無機填料的包容力強、極性高且與各種聚 合物的相容性好，改性後熔點黏度不增加，及容易加工等 特性’該塑料組份較佳是選用如前所述的乙烯-丙烯酸酯類 共聚物，最佳是選用乙烯-丙烯酸丁酯共聚物。 該竹炭組份包括多數個均勻地散布於該塑料組份中的 竹炭粉粒，該等竹炭粉粒是將高溫燒煉的竹備長炭，再進 一步研磨成超微細粉粒而製成，且該等竹炭粉粒的粒徑範 圍較佳是介於lnm〜3 # m。 該離子鍵聚合物組份是一選自於下列群組中的物質： 鋅離子型聚合物、鈉離子型聚合物，及鋰離子型聚合物。The preferred embodiment of the bamboo charcoal plastic masterbatch of the present invention is prepared by densely mixing and granulating a semi-finished product composition comprising a plastic component mixed in a predetermined ratio, - bamboo 1 reading, - a binder polymer component, and a coupling component. The plastic component is a polymer selected from the group consisting of thermoplastics, and is a material selected from the group consisting of ethylene-acrylic acid butyl acrylate copolymer (EBA), ethylene-acrylic acid-branched copolymer ( EMA), ethylene-acrylic acid copolymer (EEA), and ethylene-octyl copolymer (p〇E). Among them, in order to achieve good flexibility, high melting point, high thermal stability, low temperature impact resistance, strong tolerance to inorganic fillers, high polarity and good compatibility with various polymers, the viscosity of the melting point after modification does not increase, And the characteristics of easy processing, etc. The plastic component is preferably an ethylene-acrylate copolymer as described above, and an ethylene-butyl acrylate copolymer is preferably used. The bamboo charcoal component comprises a plurality of bamboo charcoal powder particles evenly dispersed in the plastic component, and the bamboo charcoal powder particles are prepared by further grinding the bamboo charcoal charcoal which is smelted at a high temperature into ultrafine powder particles, and the The particle size range of the bamboo charcoal powder is preferably between 1 nm and 3 m. The ionomer component is a material selected from the group consisting of zinc ion type polymers, sodium ion type polymers, and lithium ion type polymers.
10 200846375 由於該離子鍵聚合物組份的分子中含有金屬離子鍵，能使 相鄰極性的高分子聚合物相交聯，因此能達到增加相容性 的作用。 該偶合劑組份是一選自於下列群組中的物質：石夕院偶 合劑、鈦酸酯偶合劑、鋁酸酯偶合劑、矽鎂偶合劑，及硼 鎮偶合劑。由於偶合劑是一種具有二個以上相異反應基的 分子，其分子中的一部分結構可與無機物表面的化學基團 反應並形成牢固的化學鍵，另一部分的基團則具有親和有 機物的特性，而可與有機物分子反應形成化學鍵結或物理 性纏繞’因此可藉由該偶合劑組份使二種不同性質的材質 順利結合’也就是說，可利用該偶合劑組份在該竹炭組份 與該塑料組份表面產生鍵結以提高二者的結合力，界面的 結合能力提高後，還能進一步提高機械強度，藉由該偶合 Μ組伤除了可提局與該塑料組份相結合的竹炭組份的含量 ’而增加該竹炭塑料母粒中的竹炭含量外，還可使所製得 的竹炭塑料母粒配合其他塑料作進一步的製造加工時，容 易結合其他塑料，並能提升最終產品的機械強度。 以該半成品組成物的總重計，該塑料組份的含量較佳 是介於10wt%〜50wt%，該竹炭組份的含量較佳是介於1〇 wt%〜85 wt%，該離子鍵聚合物組份的含量較佳是介於1〇 Wt%〜35 wt%，及該偶合劑組份的含量較佳是介於1 wt%〜7 wt%。進一步地，為了提高該竹炭塑料母粒中竹炭的含量以 增強竹炭的應用特性與功效，以該組成物的總重計，該竹 炭組份的含量較佳是介於3〇 wt%〜85 wt%。 11 200846375 將前述組份經密練混合與造粒所製成的該竹炭塑料母 粒的粒徑範圍較佳是介於lmm〜5mm。進一步地，為了達到 較佳的應用效果，該竹炭塑料母粒的粒徑範圍最佳是介於 2mm〜3mm 〇 參閱圖1，本發明製出該竹炭塑料母粒的製造方法的該 較佳實施例則包含下列步驟： 步驟ιοί-是密練混合，是在73〇c〜145<t的溫度範圍内 ’將該塑料組份與該離子鍵聚合物組份相混合並捏合5〜2〇 刀鐘待均勻軟化後，再加入具有該等竹炭粉粒的竹炭組 份及該偶合劑組份，繼續加壓密練捏合1〇〜3〇分鐘，以形 成w亥半成品組成物。 步驟102是造粒，是將該半成品組成物送入一押出混 煉造粒機，在赋〜靴的溫度範圍下，混煉擠押製成呈 顆粒狀，且粒徑範圍介於1mm〜5mm的通用級竹炭塑料母粒 〇 、該押出混煉造粒機可因應需求使用單螺桿式或雙螺桿 式其中，使用雙嫘桿式押出混煉造粒機可使該半成品組 成物押出混煉的均句度較佳，因气，可達到較佳的使用效 果此外該押出混煉造粒機還具有一形成有多孔穴而能 ;k粒的模頭迴轉刀，該模頭迴轉刀可以採用熱切式或 裒式:计的型式，其中，較佳是使用熱切式模頭迴轉刀 ，當該半成品組成物混煉均勻並擠押至該模頭迴轉刀處時 〜可馬上予以熱切造粒，由於熱切式的模頭迴轉刀具有特 定的冷卻系統，水環式模頭迴轉刀則是利用水冷卻，會使 12 200846375 所製出的竹炭塑料母粒含有水份，導致母粒品質相對較差 。因此’使用熱切式迴轉刀可使所製得的竹炭塑料母粒的 ^ 品質較佳。 - 其中，在步驟101中所形成的該半成品組成物的成分 與含置與前述形成該竹炭塑料母粒的半成品組成物的内容 相同，故在此不再贅述。 藉由前述步驟所製得的竹炭塑料母粒可以進一步被應 • 用，並搭配適當的塑膠原料製成具有額外附加功效的塑料 產品。 因此，本發明竹炭塑料產品該較佳實施例是由一竹炭 塑料混合物經過押出成型、壓延成型、擠壓成型、射出成 型或抽絲成纖維等方式製成，該竹炭塑料混合物包含多數 個依前述步驟製得的竹炭塑料母粒，及一與該等竹炭塑料 母粒呈預定比例相混合的塑膠原料。 該塑膠原料是一選自於下列群組中的物質：聚乙烯、 • 聚丙烯、聚苯乙烯、丙烯腈-丁二烯-苯乙烯共聚物、聚碳酸 酯、聚醯胺、聚醯胺彈性體，及聚酯。 g 4竹厌塑料混合物的總重計，該等竹炭塑料母粒的 含量較佳是介於lwt%〜40wt%，及該塑膠原料的含量較佳是 介於60wt%〜99wt%。其中，該等竹炭塑料母粒與該塑膠原 料依前述比例範圍混合均句後，是在14吖~贿的溫度範 圍内，進行押出成型、壓延成型、擠壓成型、射出成型或 抽絲成纖維荨處理，以進一舟形士、i ^ 少形成預定型式的竹炭塑料產 品0 13 200846375 #X it地’為了再增加該竹炭塑料產品的附加價值，可 在製造該竹炭塑料產品的過程中，再額外地在該竹炭塑料 混合物中添加一添加物組份，且該添加物組份是一選自於 下=群組中的物質：奈綠、奈米氧化辞、奈米二氧化欽 、奈米磁粉、抗靜電劑、抗紫外線劑、光起始劑，以及其 等之組合。藉以賦予最終製品額外的應用功效。 值得說明的是，在該等竹炭塑料母粒中較佳是選用 eba、EMa、eea& p〇E等共聚輸聚合物作為該塑料組 ，的來源’主要是由於此類聚合物的結構中，I有與該塑 膠原料的單體類似的基團’因此使該等竹炭塑料母粒加入 不同的塑膠原料中時，與該塑膠原料之間會有較高的界面 相容性’而有利於該等竹炭塑料母粒均句地分散在該塑膠 原料中，且該塑料組份還有明顯的增韌效果，尤其是透過 其與該塑膠原料的結構相似性’可產生一定的分子間潤滑 作用，使所製得的竹炭塑料產品的加卫流動性也獲得改盖 車乂仫地，該竹炭塑料混合物是進__纟被H _自 下列群組中的竹炭塑料產品：日用傢俱、飯起、碗滨湯 、石占板、保鮮盒、保鮮膜、保鮮袋、茶杯、垃圾袋、垃: 桶、購物袋、衣物保存袋、紡織纖維製品、尼龍紗、聚丨 V牙刷毛、清潔刷毛、奶瓶、玩具、汽車内裝板、扣> 品外殼，及發泡製品。 v 上該竹厌塑料產品除了能夠藉由該塑膠原料達3 容易塑形、加工與具有預定的結構強度的特質，並形成、 14 200846375 供使用的預定結構型式外，還可再透過該等竹炭塑料母粒 中的竹炭粉粒的多孔隙特性，有效地發揮抗菌、除臭、淨 化空氣、調整濕/氣、釋放紅外線與負離子等效果，賦予該 竹炭塑料產品在基本機能外還有額外的健康保健功能。 【具體例】 以下就一個依本發明製造方法製出該竹炭塑料母粒， 及進-步以該竹炭塑料母粒配合一塑膠原料（聚丙婦）製出一 備長炭飯匙的具體例，說明本發明竹炭塑料母粒、其製造 方法，及由其所製得的竹炭塑料產品的特性。 (一）高竹炭含量之竹炭塑料母粒的製備·· (1) 使用密練混合機，並將其溫度設定在1〇5它，加入 160公斤的乙烯-丙烯酸丁酯共聚物、3〇公斤的杜邦沙林 (Surlyn)(離子鍵聚合物組份），捏合約1〇分鐘，待均句軟化 後，再加入約300公斤的竹備長炭粉粒，及9公斤的鈦酸 酯偶合劑〔偶合劑組份），繼續加壓密練捏合2〇分鐘，形成 該半成品組成物。 (2) 將捏合完成的半成品組成物送入一雙螺桿式押出混 煉造粒機，將溫度設定在12(rc，並將造粒粒徑直徑設定^ 2.5mm，進行混煉擠押，就能經由該模頭迴轉刀熱切製得呈 顆粒狀，且粒控為2〜3mm的竹炭塑料母粒。 值得說明的是，在步驟（1)中所使用的該離子鍵聚合物 組份是選自杜邦公司的包裝和工業用熱封及粘合樹脂，主 要是從下列三種商品中擇一使用，以下並列出所用的離子 鍵聚合物組份的商品名及其性能資料： 15 20084637510 200846375 Since the ion-bonding polymer component contains a metal ion bond in the molecule, the polymer of adjacent polar groups can be cross-linked, thereby achieving an effect of increasing compatibility. The coupler component is a material selected from the group consisting of: Shi Xi Yuan coupling agent, titanate coupling agent, aluminate coupling agent, barium magnesium coupling agent, and boron town coupling agent. Since the coupling agent is a molecule having two or more dissimilar reactive groups, a part of the structure of the molecule can react with the chemical group on the surface of the inorganic substance and form a strong chemical bond, and the other part of the group has the property of the affinity organic substance, and It can react with organic molecules to form chemical bonds or physical entanglement 'so that two different properties of the material can be smoothly combined by the coupling agent component', that is, the coupling agent component can be utilized in the bamboo charcoal component and The surface of the plastic component is bonded to increase the bonding force of the two, and the bonding strength of the interface is improved, and the mechanical strength can be further improved. The coupling of the coupling group can not only mention the bamboo charcoal group combined with the plastic component. In addition to increasing the content of bamboo charcoal in the bamboo charcoal plastic masterbatch, the bamboo charcoal plastic masterbatch can be combined with other plastics for further processing and processing, and it is easy to combine other plastics and improve the machinery of the final product. strength. The content of the plastic component is preferably from 10% by weight to 50% by weight based on the total weight of the semi-finished composition, and the content of the bamboo charcoal component is preferably from 1% by weight to 855% by weight. The content of the polymer component is preferably from 1 〇 Wt% to 35 wt%, and the content of the coupler component is preferably from 1 wt% to 7 wt%. Further, in order to increase the content of bamboo charcoal in the bamboo charcoal plastic masterbatch to enhance the application characteristics and efficacy of the bamboo charcoal, the content of the bamboo charcoal component is preferably between 3 〇 wt% and 85 wt% based on the total weight of the composition. %. 11 200846375 The bamboo charcoal plastic masterbatch prepared by densely mixing and granulating the above components preferably has a particle size ranging from 1 mm to 5 mm. Further, in order to achieve a better application effect, the bamboo charcoal plastic masterbatch has an optimum particle size range of 2 mm to 3 mm. Referring to FIG. 1, the preferred embodiment of the method for producing the bamboo charcoal plastic masterbatch of the present invention is described. The example comprises the following steps: Step ιοί- is a close-mixing, mixing the plastic component with the ionomer component in a temperature range of 73〇c~145<t and kneading the 5~2 file After the bell is uniformly softened, the bamboo charcoal component having the bamboo charcoal powder particles and the coupling agent component are further added, and the kneading and kneading is continued for 1 to 3 minutes to form a semi-finished product composition. Step 102 is granulation, and the semi-finished composition is sent to a squeezing and sizing granulator. The mixture is extruded and extruded into a granular shape under the temperature range of the hoisting shoe, and the particle size ranges from 1 mm to 5 mm. The general-purpose bamboo charcoal plastic masterbatch, the extrusion mixing granulator can be used in a single-screw or twin-screw type according to the demand, and the semi-finished extrusion granulator can be used to extrude the semi-finished composition. The uniformity is better, and the better use effect can be achieved due to the gas. In addition, the extrusion mixing granulator also has a die rotary knife formed with a porous hole; the k-shaped die rotary knife can be hot cut. Type or 裒 type: the type of the meter, wherein it is preferred to use a hot-cut die rotary knife, when the semi-finished composition is uniformly kneaded and pushed to the rotary cutter of the die, the hot-cut granulation can be immediately performed due to The eager die cutter has a specific cooling system, and the water ring die cutter uses water cooling, which makes the bamboo charcoal plastic masterbatch produced by 12 200846375 contain water, resulting in relatively poor masterbatch quality. Therefore, the quality of the obtained bamboo charcoal plastic masterbatch can be improved by using a hot-cut rotary knife. - wherein the composition of the semi-finished product formed in the step 101 is the same as that of the semi-finished composition which is formed in the foregoing form of the bamboo charcoal plastic masterbatch, and therefore will not be described herein. The bamboo charcoal plastic masterbatch prepared by the above steps can be further used and used with appropriate plastic materials to make plastic products with additional additional effects. Therefore, the preferred embodiment of the bamboo charcoal plastic product of the present invention is formed by extrusion molding, calendering, extrusion molding, injection molding or spinning into a fiber of a bamboo charcoal plastic mixture, and the bamboo charcoal plastic mixture comprises a plurality of The bamboo charcoal plastic masterbatch prepared in the step, and a plastic raw material mixed with the bamboo charcoal plastic masterbatch in a predetermined ratio. The plastic material is a material selected from the group consisting of polyethylene, polypropylene, polystyrene, acrylonitrile-butadiene-styrene copolymer, polycarbonate, polyamine, and polyamine flexibility. Body, and polyester. The content of the bamboo charcoal plastic masterbatch is preferably from 1 wt% to 40 wt%, and the content of the plastic raw material is preferably from 60 wt% to 99 wt%. Wherein, the bamboo charcoal plastic masterbatch and the plastic raw material are mixed in the above-mentioned ratio range, and are extruded, calendered, extruded, injection molded or drawn into fibers in a temperature range of 14吖~ bribe.荨Processing, to enter a boat shape, i ^ less form a predetermined type of bamboo charcoal plastic products 0 13 200846375 #X it ground 'In order to increase the added value of the bamboo charcoal plastic products, in the process of manufacturing the bamboo charcoal plastic products, the amount An additive component is added to the bamboo charcoal plastic mixture in the field, and the additive component is a substance selected from the group consisting of nai green, nanometer oxidation, nano-dioxide, nano magnetic powder. , an antistatic agent, an ultraviolet ray inhibitor, a photoinitiator, and combinations thereof. In order to give the final product additional application efficacy. It is worth noting that in such bamboo charcoal plastic masterbatch, a copolymerized transport polymer such as eba, EMa, eea & p〇E is preferably used as the source of the plastic group, mainly due to the structure of such a polymer. I has a group similar to the monomer of the plastic raw material. Therefore, when the bamboo charcoal plastic masterbatch is added to different plastic raw materials, there is a high interfacial compatibility with the plastic raw material, which is advantageous for the The bamboo charcoal plastic masterbatch is uniformly dispersed in the plastic raw material, and the plastic component has obvious toughening effect, especially through its structural similarity with the plastic raw material, which can generate certain intermolecular lubrication. The added fluidity of the prepared bamboo charcoal plastic products has also been changed to the rut, and the bamboo charcoal plastic mixture is imported into the bamboo charcoal plastic products from the following groups: daily furniture, rice , bowl of soup, stone plate, crisper, plastic wrap, storage bag, tea cup, garbage bag, garbage: barrel, shopping bag, clothing storage bag, textile fiber products, nylon yarn, poly 丨 V toothbrush, cleaning bristles, Bottle, toy, steam Interior panel buckle > product housing, and the foamed article. v The bamboo dispelling plastic product can be re-transparent through the bamboo charcoal, in addition to being able to be shaped, processed and of predetermined structural strength by the plastic material, and formed into a predetermined structural form for use in 2008. The porous nature of the bamboo charcoal powder in the plastic masterbatch effectively exerts the effects of antibacterial, deodorizing, purifying the air, adjusting the moisture/gas, releasing infrared rays and negative ions, and imparting additional health to the bamboo charcoal plastic product in addition to the basic functions. Health care function. [Specific Example] Hereinafter, a bamboo charcoal plastic masterbatch is prepared according to the manufacturing method of the present invention, and a specific example of preparing a long charcoal rice spoon by using the bamboo charcoal plastic masterbatch with a plastic raw material (polypropylene) is described. The bamboo charcoal plastic masterbatch of the invention, the method for producing the same, and the characteristics of the bamboo charcoal plastic product obtained therefrom. (1) Preparation of bamboo charcoal plastic masterbatch with high bamboo charcoal content · (1) Using a compact mixer, set the temperature to 1〇5, add 160 kg of ethylene-butyl acrylate copolymer, 3 kg Surlyn (Surly Key Polymer), pinch the contract for 1 minute, after the softening of the sentence, add about 300 kg of bamboo charcoal powder and 9 kg of titanate coupling agent. The coupling agent component) was further kneaded by pressurization for 2 minutes to form the semi-finished composition. (2) The kneaded semi-finished product is sent to a twin-screw extrusion mixing granulator, and the temperature is set at 12 (rc, and the granulated particle diameter is set to 2.5 mm, and the mixture is kneaded and squeezed. The bamboo charcoal plastic masterbatch can be granulated and granulated to 2~3 mm by the die rotary knife. It is worth noting that the ionomer component used in the step (1) is selected. DuPont's packaging and industrial heat seal and adhesive resins are mainly used in one of the following three products. The trade names and performance data of the ionomer components used are listed below: 15 200846375
(二）竹炭塑料產品的製造-以竹備長炭飯匙為例： 取l〇〇g的竹炭塑料母粒，與900g的聚丙烯作為該竹 炭塑料產品的塑膠原料，使二者相混合均勻形成該竹炭塑 料混合物後，配合使用一射出成型機，在1 8〇〇C進行射出成 型’就能將該竹炭塑料混合物進一步製成一竹炭塑料產品 Ο 參閱圖2與圖3，該具體例是以該竹備長炭飯匙2作為 該竹炭塑料產品進行說明。該飯匙2包含一握柄21，及一 由該握柄21的一前端往前延伸的盛接體22,該盛接體22 包括相間隔設置的一盛接面221、一底面222,及多數條相 間隔且相平行地突設於該盛接面221的上肋條223、下肋條 224，且該等上、下肋條223、224的間距是大於飯粒顆粒 的粒徑寬度，及該等上肋條223與該盛接面221、該等下肋 條224與該底面222還相配合界定出多數個呈R型倒角斷 面的交界段225、226。 因此，該飯遣2除了利用聚丙稀的塑膠原料2〇〇材質 16 200846375 而有可耐冷（-20。〇與耐熱（120。〇的特性、可直接成型呈具 有預疋形狀與預定強度的結構體，而能利用該盛接體22盛 置飯粒，及利用該等上、下肋條223、224，與經R型倒角 處理的交界段225、226達到不易沾附飯粒的效果外，還可 透過該等竹炭塑料母粒内含，並散佈於該塑膠原料200中 的竹炭粉粒201提供抗菌、消臭與維持米飯美味新鮮不易 變質的功能，使該飯匙2不僅作為方便盛飯的工具，還有 其他有益使用者健康與使用感受的效果。 值得一提的是，該竹炭塑料產品的型式不應該受到限 制，例如，將竹炭塑料母粒配合塑膠原料（例如，pp或PE) 製成竹炭保鮮膜、保鮮袋或保鮮盒時，可利用該等竹炭粉 粒保鮮、調濕與抗菌功效延長存放在其内的魚、肉、蔬果 的保鮮期限，或將竹炭塑料母粒配合PE塑料所製成的竹炭 垃圾袋，具有消臭、去味與抗菌的功效，或者將竹炭塑料 母粒配合PA塑料所製成的毛刷絲可進一步被製成牙刷毛、 清潔刷毛’而具有抗菌、柔韌的功效，或將竹炭塑料母粒 與特定的塑膠原料製成廚房水槽用的濾水網或3C產品外殼 等，都可藉由前述竹炭塑料產品所内含的竹炭粉粒表現出 抗菌、消臭等額外的附加價值。 歸納上述，本發明竹炭塑料母粒、其製造方法，及由 其所製得的竹炭塑料產品可獲致下述的功效及優點，故確 實能達到本發明的目的： 、本發明藉由使用該竹炭組份搭配特定的塑料組份 、離子鍵聚合物組份與偶合劑組份所形成的半成品組成物 17 200846375 藉由所使用的塑料組份、離子鍵聚合物組份與偶合劑組 伤的特性，使該半成品組成物中的竹炭組份含量可相對被 ^ 提高，進而能製得具有比現有塑料母粒竹炭含量高的竹炭 塑料母粒，當使用此種竹炭塑料母粒配合塑膠原料製成竹 炭塑料產品時，使該竹炭塑料產品中的竹炭含量也比現有 市面上一般竹炭塑料產品的竹炭含量高，使本發明除了可 、 t#高竹炭含量的塑料母粒外，冑能進—步配合特定的塑 • 冑原料製成高竹炭含量的塑料產品，使所製得的竹炭塑料 產品相對具有更佳的抗菌、除臭、淨化、釋放紅外線與負 離子等與竹炭特質有關的特性。 、 一本毛明藉由使用該竹炭組份搭配特定的塑料組份 、離子鍵聚合物組份與偶合份所製成的竹炭塑料母粒 ，由於其所選用的該塑料組份具有與各種塑料原料的單體 她义的基團而能形成高相容性的特性，因此能夠分別搭 :己各種不同材質的塑膠原料進一步製成特定的竹炭塑料產 • &，不需要再針對不同的塑膠原料分別再製造與該塑膠原 _ ㈣對應的竹炭塑料母粒，使本發明所製得的該竹炭塑料 ? /、有通用1±車又佳、可應用範圍較廣泛，及可節省製程 時間的特性與優點。 惟以上所述者，僅為本發明之一較佳實施例而已，當 =能以此限；t本發明實施之範圍，即大凡依本發明申請專 ，及發明說明内容所作之簡單的等效變化與修飾，皆 仍屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 18 200846375 圖1疋一說明本發明竹炭塑料母粒製造方法一較佳實 施例的流程圖； 囷疋立體示思圖，說明本發明配合該竹炭塑料母 粒所製得的一竹炭塑料產品呈一飯匙的型式；及 圖3是一剖視示意圖，以該飯匙為例說明該竹炭塑料 產品，藉由混合多數個竹炭塑料母粒與一塑膠原料 夕 數個竹炭粉粒散佈在該塑膠原料的情形。 >(2) Manufacture of bamboo charcoal plastic products - Take bamboo long carbon rice spoon as an example: Take l〇〇g of bamboo charcoal plastic masterbatch, and 900g of polypropylene as the plastic raw material of the bamboo charcoal plastic product, so that the two are mixed uniformly. After the bamboo charcoal plastic mixture is combined with an injection molding machine and injection-molded at 18 ° C, the bamboo charcoal plastic mixture can be further formed into a bamboo charcoal plastic product. Referring to FIG. 2 and FIG. 3, the specific example is The bamboo long carbon rice spoon 2 is described as the bamboo charcoal plastic product. The spoon 2 includes a handle 21 and a receiving body 22 extending forwardly from a front end of the handle 21. The receiving body 22 includes a receiving surface 221 and a bottom surface 222 spaced apart from each other. a plurality of strips are spaced apart from each other and are disposed in parallel with the upper rib 223 and the lower rib 224 of the receiving surface 221, and the pitch of the upper and lower ribs 223, 224 is greater than the particle size width of the rice grain particles, and the like The rib 223 and the receiving surface 221, the lower rib 224 and the bottom surface 222 also cooperate to define a plurality of boundary sections 225, 226 having an R-shaped chamfered section. Therefore, the rice bowl 2 is made of polypropylene plastic material 2〇〇 material 16 200846375 and has cold resistance (-20. 〇 and heat resistance (120. 〇 characteristics, can be directly formed into a structure having a pre-twist shape and a predetermined strength) The body can be used to hold the rice grains by the receiving body 22, and the upper and lower ribs 223 and 224 can be used to achieve the effect of not easily adhering to the rice grains by the boundary sections 225 and 226 which are subjected to the R-type chamfering treatment. The bamboo charcoal powder 201 contained in the bamboo charcoal plastic masterbatch and dispersed in the plastic raw material 200 provides antibacterial, deodorizing and maintaining the delicious and fresh taste of the rice, so that the rice spoon 2 is not only a convenient tool for cooking rice. There are other effects that are beneficial to the health and use of the user. It is worth mentioning that the type of the bamboo charcoal plastic product should not be limited, for example, the bamboo charcoal plastic masterbatch is combined with a plastic material (for example, pp or PE). Bamboo charcoal wrap, fresh-keeping bag or crisper can be used to preserve the freshness, humidity and antibacterial effect of bamboo charcoal powder to extend the shelf life of fish, meat, fruits and vegetables stored in it, or to match bamboo charcoal plastic masterbatch The bamboo charcoal garbage bag made of PE plastic has the functions of deodorizing, deodorizing and antibacterial, or the brush fiber made of bamboo charcoal plastic masterbatch combined with PA plastic can be further made into toothbrush hair and cleaning bristles' The antibacterial and pliable effect, or the bamboo charcoal plastic masterbatch and the specific plastic raw material can be used as the water filter net or the 3C product shell for the kitchen sink, which can be expressed by the bamboo charcoal powder contained in the bamboo charcoal plastic product. Additional added value such as antibacterial and deodorizing. In summary, the bamboo charcoal plastic masterbatch of the present invention, the method for producing the same, and the bamboo charcoal plastic product obtained therefrom can attain the following effects and advantages, so that the present invention can be achieved. OBJECTIVE: The semi-finished composition formed by using the bamboo charcoal component with a specific plastic component, ionomer component and coupling component 17 200846375 by using the plastic component, ionomerization The characteristics of the component of the component and the coupler of the coupler enable the content of the bamboo charcoal component in the semi-finished product composition to be relatively increased, thereby being able to produce a bamboo charcoal containing the existing plastic masterbatch. The high bamboo charcoal plastic masterbatch, when using the bamboo charcoal plastic masterbatch and the plastic raw material to make the bamboo charcoal plastic product, the bamboo charcoal content in the bamboo charcoal plastic product is higher than the bamboo charcoal content of the common bamboo charcoal plastic product on the market. In addition to the plastic masterbatch of t# high bamboo charcoal content, the enamel can be combined with specific plastic and bismuth raw materials to make plastic products with high bamboo charcoal content, so that the prepared bamboo charcoal plastic products have relatively better antibacterial properties. Deodorization, purification, release of infrared ray and negative ions and other characteristics related to bamboo charcoal. A hairy make-up is made by using the bamboo charcoal component with a specific plastic component, ionomer component and coupling component. The bamboo charcoal plastic masterbatch can be made of plastic materials of various materials because it has the characteristics of high compatibility with various monomeric materials of various plastic raw materials. Specific bamboo charcoal plastic production &, no need to re-manufacture the bamboo charcoal plastic masterbatch corresponding to the original plastic _ (four) for different plastic raw materials The present invention charcoal plastic obtained? / 1 ± universal car and a good, can be applied to a wider range, and the features and benefits can save the processing time. However, the above is only a preferred embodiment of the present invention, and can be limited to this; t is the scope of the present invention, that is, the simple equivalent of the application according to the present invention and the contents of the invention. Variations and modifications are still within the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart showing a preferred embodiment of a method for producing a bamboo charcoal plastic masterbatch according to the present invention; and a perspective view showing a method for preparing the bamboo charcoal plastic masterbatch according to the present invention. A bamboo charcoal plastic product is in the form of a rice spoon; and FIG. 3 is a schematic cross-sectional view showing the bamboo charcoal plastic product by using the rice spoon as an example, by mixing a plurality of bamboo charcoal plastic masterbatch and a plastic raw material for a plurality of bamboo charcoal powder The particles are scattered in the case of the plastic material. >
19 200846375 【主要元件符號說明】 2········ •…飯匙 224 …· •…下肋條 21…… —握柄 225 .… •…交界段 22…… …·盛接體 226 …· …·交界段 221 …· •…盛接面 200···· …·塑膠原料 222 …· —底面 201 ·_·· •…竹炭粉粒 223 ···_ .....上肋條 2019 200846375 [Explanation of main component symbols] 2·································································· ...· ...· Junction section 221 ...· •... Sheng junction 200······Plastic material 222 ...· —Bottom surface 201 ·_·· •... Bamboo charcoal powder 223 ···_ ..... Upper rib 20