1339161 九、發明說明： 【發明所屬之技術領域】， 本發明係關於在與事先於合成樹脂表面進行了印刷之 印刷材進行成形時予以一體化的裝 m μ ,,,.,、，. 衣飾/寻片’及使用於裝飾 /辱片ia k之油墨，以及與裝飾薄片一1339161 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to an assembly of m μ , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Decorating/finding sheets' and using inks for decorative/disgrace ia k, as well as with decorative sheets
【先前技術】 ㈣成H 作為裝飾合成樹脂成形品之表面的方法，已知 措由油墨進行印刷之合成樹脂薄片或薄膜等之印刷材(以 :亦稱為裝飾薄請裝於成形鑄模内，聰成樹脂於 鑄模内而使裝飾薄片與合成體化的合成樹脂之成 形方法（以下亦稱為薄膜嵌入⑴lm咖⑴成形法 此方法係具有可藉由印刷於成形物表面直接施加 的特徵’或即使是難以形成著色或圖樣等之形狀的成形物 亦可施加裝飾的特I再者’由於可將形成於裝飾薄片上 的二p刷層保持於合成樹脂成形品與裝m <基材薄片 或薄膜之間並使其互相密接’故相較於印刷至成形物表面 的方法，除了㈣傷性優越之外，亦具有w發生經年變 化的優點，因而不僅被利用於行動電話、個人電腦等之小 型電子機器，亦被利用於以各種電氣製品、汽車零件等為 首的各種機器表面上的裝飾。 習知，於薄膜嵌入成形法中，在藉印刷形成著色層的情 況下，為了提高形成裝飾層之薄片、著色層形成用油墨二 及成形用所填充之合成樹脂之間彼此的接黏性，而進^ 各種提案。 96135882 5 1339161 印日本專利^,3—285404卜係提案有透過 熱可塑性樹脂薄片上形成 :: 之接黏性。 成之接黏層，以提高與聚兩烯樹脂 ^然：右於藉薄膜嵌入成形法所製造之成形 …亦有凹凸形狀者、㈣層不連續者等。 於此種成形品中，對於僅i留 層之間的接黏性，或著色裝飾薄片基材與著色 面，尚仍不足。例如在提脂之間的接黏性方 徒回了成形用樹脂之色與萝 者上創作性的裝飾薄膜的情況，、:" 的區域，在不存在著色層的部分成著色層 之間的接黏性不充分，而有_狀=㈣與成形用樹脂 情況。 發生上浮等之問題的 之，題在於提供一種裝㈣片，其 飾缚片上之印刷像形狀、或成形品形狀等，褒飾薄= :用樹脂之接黏強度大’不發生剝離等" 好，以及提供使用裝飾薄片之成形品。 、险亦良 【發明内容】 本發明之課題係藉由下述裝㈣片所料 性樹脂所形成之基材薄片藉印刷形、：由，可塑 片中，於基材薄片整面或基材薄片之至曰^裝飾薄 區域上，形成含有與著色層形成用油墨❹二，著色層的 之透明油墨的透明層，並於基材薄片之形二=成為共通 的最外層上形成接黏層。 ^有著色層之側 96135882 6 丄丄ο丄 整=後上t裝飾薄片係於基材薄片面上將透明層形成為 正面狀後，再形成了著色層者。 ^ 上述裝飾薄片+ #透明層係在基材薄片上形成著色層 後形成於至少未存在著色層之部分。 上述f飾薄片中，基材薄片為聚碳酸醋。 桩飾薄片中’基材薄片係含有經進行與著色層之易 處理或易接黏層之形成的熱可塑性樹脂。 另外’將裝飾薄片藉由薄膜嵌入成形而與合成樹脂一體 化的成形，，係在由熱可塑性樹脂所形成之基材薄片的整 —或土材薄片之至少未形成著色層的區域上，形成含有與 著色層开> 成用油墨係、清漆組成為共通之透明油墨的透明 層在形成有I色層之側的最外層上形成接黏層之裝飾薄 片，將經由接黏層而與合成樹脂一體化者。 另外，上述成形品令，裝飾薄片係在將透明層於基材薄 片面上形成為整面狀後，再形成了著色層者。 上述成形品中，透明層係在於基材薄片上形成著色層 後心成在至少不存在著色層的部分上者。 上述成形品中，基材薄片為聚碳酸酯，所一體化之合成 樹脂係含有聚丙烯或聚醯胺之至少任一種。 上述成形品中，基材薄片為形成有易接黏層之聚丙烯， 所一體化之合成樹脂為含有聚丙烯或聚醯胺之至少任一 種。 本發明之裝飾薄片，係在基材薄片上未形成著色層的部 分’形成有與使用於形成著色層之著色油墨係清漆成分為 96135882 7 共通之透明油墨層 面將對於接黏性而 之裝飾薄片，將不 片表面形狀等，而 的接黏性良好的成 ’因此不論是否為著色層之形成部，表 具有一樣的接黏性。因此，藉由本發明 依存於著色層之面積、圖樣、或裝飾薄 可提供與合成樹脂一體化之成形品之間 形品。 【實施方式】 薄：Γ:在使用藉印刷形成了裝飾層之裝錦薄片並藉 使於：：呈:戶::成的成形品中’著眼於下述要點:在即 者作兔：材薄片及接黏層之接黏性良好之特性 色層的油墨的情況下，基材薄片與接黏 門的4丨+/ 又到影響，與裝飾薄片一體化之合成樹脂 品間嶋t/度:呈 :且^見’在未形成著色層之部分，藉由與用於印刷 墨Λ清漆成分為共通之透明油墨而形成透明 薄片與合成樹脂間的剝離強度，遂可解 藉由印刷將圖像形成於裝飾薄片上的印刷油墨，係將與 =使用作為裝飾薄片基材之聚碳酸_、表面處理聚酿薄 接黏1·生良好的清漆與色材予以配合而製造成，例 二Λ將由聚酯多醇系樹脂所製造之清漆中配合既定色材 而製造。 j 於》專膜嵌入成形中 係藉印刷形成著色層後，直接、或 96135882 ^39161 於進一步形成接黏層後，將裝飾薄片安裝於鑄模中並射出 聚碳酸酷等之合成樹脂而鈒造成形體。 ^成著色層之印刷油墨，係考慮與基材薄片間之接黏性 而選擇清漆。又，考慮到成形樹脂與著色層之接黏性，並 為了提高著色層與合成樹脂間之接黏性，作為配置於著色 層上之接黏層係選擇與兩者間之接黏性良好者。 ，然而，於基材薄片、著色層用油墨、接黏層、及用於成 形之合成樹脂的各種材料的選擇中，迄今尚未對於基材薄 片與用於成形之合成樹脂間的接黏性、或基材薄片與接黏 層間之接黏性進行充分的考量。 ，此’於在基材薄片1面上未形成裝飾層的情況下，裝 ^専片與用於成形之合成樹脂間的接黏性不^，而有無法 得到具有充分剝離強度之成形品的情形。 本發明中，為了提升㈣薄片與經成形之合成樹脂間的 f黏性，可於藉印刷將著色層形成在基材薄片上前、藉形 ，與著色層之印刷油墨係清漆成分為共通的透明油墨形 墨層，或者於藉印刷油墨形成著色層後、在未形 =色層：部分或形成了著色層之側的整面上 油墨印刷透明層。 後㈣成明層之形成順序’可為纖透明層 任^ '或於形成著色層後再形成透明層者的 ，兄下㈣以上存在有未形成著色層之區域的情 的：者片之著色層與未形成著色層之部分 形用合成樹脂間的剝離強度，而在於基材薄 96135882 9 ^39161 片上存在有未形成著色層之區域的情況下，將可提高基材 薄片上之形成有著色層的區域、與未形成著色層之部分的 兩者與接黏層的接純，以及接㈣與成形用合成樹脂間 的剝離強度。 另外，本發明中，「整面地形成」係指形成在扣除了印 :中於基材周圍所不可避免地發生之印刷空白、和於成形 °°所不需要之周圍部分之部分的整體上。 *另2，本發明中，所謂「清漆成分為共通」，係指構成 兩者清漆成分的樹脂及溶劑，為同種或具有相同特性者， 且彼此具有較大親和性，並非意指兩者清漆的構成成分之 種類、含有夏均完全一致，而係指即使在調配比等多少有 所不同、或於色材以外之成分上亦具有相異點的情況下， 兩者仍具有高度親和性。 亦即’在混合了色材之著色層形成用的印刷油墨中 較於透明油墨之下’不僅混合了色材，其中亦混合了更多 的在:種情況下’含有共通成分作為構成清 广成刀的树月曰成分及溶劑的情形，將稱為「清漆成分為共 通」。 ” 以下參照圖式說明本發明之裝飾薄片以薄 一體化的成形體。 巾/寻片 圖1Α至1D係說明第丨裝飾薄片及將裝飾薄 第1成形體的剖面圖。 化之 版二Ϊ飾薄片可如圖1A所示般’於基材薄片1上藉網 ‘之方法形成著色層2後，如圖1B所示般’於基 96135882 133^101 =片丄上之未形成有著色層2的部分，形成了與著色層 墨係h漆成分為共通之透明油墨層3,再如圖1(：所 ^ ’於著色層2及透明油墨層3上形成接黏層4，而製 成第1裝飾薄片51。 八圖1D所示般’可將第1裝飾薄片51與成形用 藉由射出成形-體化而製成第1成形體7卜 应二L飾f片中’與成形用合成樹脂接觸之面的整面係 2接黏層相接’且接黏層的整面係與著色層或與構成著色 系清漆成分為共通之透明油墨層相接，因此，不 :在^了著色層的部分、未形成著色層之部分的任一部 刀二均可於基材薄片及接黏層之間得到良好的接黏力。 :而，在將第1裝飾薄片藉嵌入成形等以與樹脂一體化 的成形體。 將了传到裝飾缚片之接黏性良好 第，明第2裂飾薄片及與裝飾薄片一體化之 第Z成形肪^的剖面圖。 第2裝飾薄片係如圖2A所示 版印刷等方法，形成盥荽“η 竹得月i上粕網 通之整面狀的透明?二色Λ形成用油墨係清漆成分為共 油墨層3上依既定心炱，如圖2β所示般，於透明 /上依既疋圖案形成著色層2。 接著，如圖2C所千叙 上形成接黏層4,而?墨層及著色層之整面 从^ 1下成第2裝飾薄片52。 然後’如圖2D所+奴 合成樹脂6藉由射出成可將第2裝倚薄片52與成形用 成形一體化而製成第2成形體72。 96135882 11 1339161 第2裝飾薄片中’係在基材薄片之形成 先將透明油墨層形成為整面狀 ：：上事 ::::於r著色層之形成部分，基4::::有: 成者色層〜黍成分的透明油墨層接觸， 所形成的接黏層之間具有良好接黏性的裝飾薄片…後 其結果係在將第2褒餘薄片藉嵌入成形等以企壯— -化而製造成形體的情況下’可得到裝二 好的成形體。 < 接黏！·生良 圖3A至3D係說明第q1 第3成形體的剖面:她“及與裝飾薄[體化之 版系如圖3A所示般，在基材薄片1上藉網 材…上之未形圖3β所示般，在基 之部分的兩者上，使來成了曰^ Μ '及形成了著色詹2 為共通之透明油墨 接黏層4,而製成第3裝飾薄片:3。® %所不般’形成 然後，如圖3 D戶/f + iia _ ^ , . Q /、：又，可將合成樹脂6藉由射出成形 版化而1成苐3成形體73。 本發明中，於裝飾淫 形狀的熱可塑性薄片 基材，可使用可加工為三次元 此等基材薄片係為了接 — 性，可為於其表面進行油墨的接黏 點居者 …、表面上稭由塗佈裝置或印刷機而形成易接 96135882 具體可舉例如··氣 ;系樹脂、聚侧'聚 本二"吏乙二酯系樹脂、聚:系树脂、聚對 等表面上實施了 2一88)、名丙稀酸猜系樹月身，或於此 性處理者、形成了編層者。 薄，則無法追隨於加 ;^G 5_㈣，若較 發±破裂和皺故之虞。另一方面二T形狀時之延伸而有 度的裝飾…曲部的情況發生’將難以製造高精 化 此等之中，較佳為由聚碳 乙烯系樹脂所形成的薄片 IS曰系樹脂、聚丙烯樹脂、 氯 純…反酸酯系樹脂間之接黏性良好的著色声 用油墨及透明層用，ά累庙田5 & 民丁 J f巴層 θ用油墨應用至聚丙烯製薄片的情況下，敕 佳係於聚丙烯製薄# Μ纟& μ β 1 Η ^ |χ 邱衣4片的表面上，藉由含丙烯基多醇系樹脂 的組成物形成易接黏層者。 ,具租而5 ’作為由丙稀基多醇系樹脂所形成之易接黏層 形成用組成物，可舉例如帝國油墨製。㈢ 另外，作為使用於著色層或透明油墨層之形成的油墨之 清漆f分，可使用下述者：將從由丙烯酸樹脂、胺基甲酸 乙酯樹脂、環氧樹脂、聚酯樹脂、聚醯胺樹脂、醋酸乙烯 酯樹脂、酚樹脂、烯烴、乙烯-醋酸乙烯酯共聚合樹脂、 聚^婦縮酸樹脂、天然橡膠、笨乙稀_ 丁二稀共聚合體、 丙烯腈-丁二烯共聚合體、醋酸乙烯酯-丙烯酸共聚合體、 96135882 1339161 乙烯-丙烯酸乙醋共聚合體、聚醋多醇、聚酯聚胺基甲醆 醋多醇、㈣聚胺基旨多料之樹脂所構成之群組選 出的至少-種，分散、溶解於水、異丙基醇、甲醇、乙醇 :之醇類、醋酸乙酯等之酯類、f基乙基酮等之酮類、甲 苯、二f 苯、Solvesso 丨00、s〇lvess〇 15〇 等之芳香族 烴系溶劑、己烷等之脂肪族烴系溶劑中者。 、 另外’亦可為與此等樹脂__起含有異氰酸n 之硬化劑者。 系寺[Prior Art] (4) As a method of decorating the surface of a synthetic resin molded article, a printing material such as a synthetic resin sheet or a film which is printed by an ink is known (in the case of a decorative film, it is also contained in a molding mold, a method for forming a decorative sheet and a synthetic synthetic resin in Congcheng resin in a mold (hereinafter also referred to as film embedding (1) lm coffee (1) forming method, which has a feature that can be directly applied by printing on the surface of a molded article' or Even in the case of a molded article having a shape in which coloring, patterning, or the like is difficult to form, it is possible to apply a decoration. In addition, the two p-brush layers formed on the decorative sheet can be held in a synthetic resin molded article and a substrate sheet. Or the films are closely connected to each other's. Therefore, in addition to (4) superiority to the surface of the molded article, it has the advantage of changing over the years, so it is not only used in mobile phones, personal computers. Small electronic devices, etc., are also used in the decoration of various machine surfaces including various electrical products, automobile parts, etc. Conventionally, in the film insert molding method. When a coloring layer is formed by printing, various proposals are made to improve the adhesion between the sheet for forming the decorative layer, the ink for forming the colored layer, and the synthetic resin filled for molding. 96135882 5 1339161 Japanese Patent No. 3-285404 proposes to form a bond through a thermoplastic resin sheet:: Adhesive layer is formed to improve the adhesion with the polyene resin: it is manufactured by the film insert molding method. There are also irregularities, (four) layer discontinuities, etc. In such molded articles, the adhesion between only the i-remaining layers, or the colored decorative sheet substrate and the colored surface are still insufficient. The adhesiveness between the greases returns to the case where the color of the molding resin and the decorative film on the radish are created, and the area of the " is between the coloring layers in the portion where the colored layer is not present. The adhesiveness is insufficient, and there is a case where the _ shape = (4) and the resin for molding. The problem of occurrence of floating or the like is to provide a package (four) sheet, which is attached to the printed image shape on the sheet, or the shape of the molded article, etc. Thinning = : with resin The bonding strength is large, 'no peeling, etc.' is good, and a molded article using a decorative sheet is provided. The risk of the invention is the basis of the following (four) sheet-like resin. The sheet is formed by printing, in the plastic sheet, on the entire surface of the substrate sheet or on the thin surface of the substrate sheet to form a transparent ink containing the ink for forming the color layer and the colored layer. a transparent layer, and an adhesive layer formed on the outermost layer of the base sheet = the common outer layer. ^The side having the colored layer 96135882 6 丄丄ο丄 whole = the upper top t decorative sheet is attached to the surface of the substrate sheet After the transparent layer is formed in a front shape, a colored layer is formed. ^ The decorative sheet + #clear layer is formed on the substrate sheet to form a colored layer, and is formed in at least a portion where the colored layer is not present. In the above-mentioned f-finished sheet, the base sheet is polycarbonate. In the pile-fitting sheet, the substrate sheet contains a thermoplastic resin which is subjected to easy treatment with the coloring layer or formation of an adhesive layer. Further, 'the decorative sheet is formed by insert molding into a film and integrated with the synthetic resin, and is formed on a region of the base sheet formed of the thermoplastic resin or at least a region where the colored layer is not formed. A transparent layer containing a transparent ink which is combined with a coloring layer and a varnish and a varnish is formed on the outermost layer on the side on which the I color layer is formed, and a decorative sheet of an adhesive layer is formed, which is synthesized through an adhesive layer. Resin integrator. Further, in the above-mentioned molded article, the decorative sheet is formed by forming a transparent layer on the surface of the substrate sheet and forming a colored layer. In the above molded article, the transparent layer is formed by forming a colored layer on the substrate sheet and then forming the core at least in a portion where the colored layer is not present. In the above molded article, the base material sheet is polycarbonate, and the integrated synthetic resin contains at least one of polypropylene and polyamide. In the above molded article, the base sheet is a polypropylene in which an easy-adhesive layer is formed, and the integrated synthetic resin contains at least either polypropylene or polyamide. The decorative sheet of the present invention is formed on a portion of the substrate sheet on which the color layer is not formed, and is formed with a clear ink layer which is common to the colored ink-based varnish component used for forming the colored layer, and has a transparent ink layer which is common to the adhesive layer. There is no surface shape or the like, and the adhesion is good. Therefore, the table has the same adhesiveness regardless of whether it is a formed portion of the colored layer. Therefore, according to the present invention, depending on the area, pattern, or decorative thinness of the colored layer, a molded article can be provided between the molded article integrated with the synthetic resin. [Embodiment] Thin: Γ: In the case of a molded article in which the decorative layer is formed by the use of the printing, the following points are focused on: And in the case of the ink of the characteristic color layer which is adhered to the adhesive layer, the substrate sheet and the adhesive door are affected by 4丨+/, and the synthetic resin product integrated with the decorative sheet is 嶋t/degree: : and ^ see 'in the portion where the color layer is not formed, the peeling strength between the transparent sheet and the synthetic resin is formed by the transparent ink common to the ink varnish composition, and the image can be formed by printing The printing ink on the decorative sheet is produced by blending with the polycarbonate _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The varnish produced by the ester polyol resin is produced by blending a predetermined color material. j In the special film insert molding, after forming the color layer by printing, directly or 96135882 ^39161 after further forming the adhesive layer, the decorative sheet is mounted in the mold and the synthetic resin such as polycarbonate is injected to form the body. . The printing ink which is a color layer is selected from varnish in consideration of the adhesion to the substrate sheet. Further, in consideration of the adhesion between the molding resin and the coloring layer, and in order to improve the adhesion between the colored layer and the synthetic resin, the adhesive layer disposed on the colored layer is selected to have good adhesion to both. . However, in the selection of various materials such as a base sheet, an ink for a colored layer, an adhesive layer, and a synthetic resin for forming, there has been no adhesion to the base sheet and the synthetic resin for forming, Or the adhesion between the substrate sheet and the adhesive layer is sufficiently considered. In the case where the decorative layer is not formed on the surface of the base sheet 1, the adhesiveness between the mounting sheet and the synthetic resin for forming is not good, and the molded article having sufficient peel strength cannot be obtained. situation. In the present invention, in order to improve the f-adhesion between the (four) sheet and the formed synthetic resin, the colored layer may be formed on the substrate sheet by printing, and may be formed by the printing ink varnish component of the coloring layer. The transparent ink-shaped ink layer or ink is printed on the entire surface of the unformed=color layer: part or the side on which the colored layer is formed after the coloring layer is formed by the printing ink. The formation order of the (4) forming layer can be either a transparent layer or a transparent layer after forming a colored layer, and there is a region in which the color layer is not formed under the brother (four): the color of the film The peeling strength between the layer and the portion where the coloring layer is not formed, and the coloring of the substrate sheet 96133882 9 ^39161 The bonding between the layer region, the portion where the coloring layer is not formed, and the bonding layer, and the peeling strength between the bonding (4) and the molding synthetic resin. Further, in the present invention, the term "formed over the entire surface" means that the printing blank which is inevitably generated around the substrate after the printing is subtracted, and the portion of the peripheral portion which is not required for the molding, is formed as a whole. . * In the present invention, the term "the varnish component is common" means a resin and a solvent which constitute the varnish component of the two, and are of the same kind or have the same characteristics, and have a large affinity with each other, and do not mean that both varnishes are varnished. The type of the constituent components and the summer-containing content are completely identical, and it means that even if the blending ratio is somewhat different or the components other than the color material have different points, the two have high affinity. That is, 'in the printing ink for forming the color layer of the mixed color material, the ink is not only mixed with the color ink, but also mixed with more: in the case of the case, it contains a common component as a composition. The condition of the saplings of the tree and the solvent are called "the varnish components are common". The decorative sheet of the present invention will be described as a thin and integrally formed body with reference to the drawings. Fig. 1A to 1D are sectional views showing the second decorative sheet and the decorative first thin molded body. The decorative sheet can be formed by the method of 'boring the web on the substrate sheet 1' as shown in FIG. 1A, and as shown in FIG. 1B, the base layer is not formed with a colored layer on the substrate 96135882 133^101. In the portion of 2, a transparent ink layer 3 which is common to the coloring layer ink system is formed, and then formed as an adhesive layer 4 on the colored layer 2 and the transparent ink layer 3 as shown in FIG. The first decorative sheet 51. As shown in Fig. 1D, the first decorative sheet 51 can be formed into a first molded body 7 by injection molding, and formed into a second molded article. The entire surface of the surface in contact with the synthetic resin is 2 joints of the adhesive layer and the entire surface of the adhesive layer is in contact with the colored layer or the transparent ink layer which is common to the components constituting the varnish. Therefore, no: The portion of the colored layer and the portion of the portion where the colored layer is not formed can be well connected between the substrate sheet and the adhesive layer. In addition, the first decorative sheet is molded into a molded body that is integrated with the resin by molding or the like. The adhesion to the decorative sheet is good, and the second split sheet and the decorative sheet are integrated. A cross-sectional view of the Z-shaped forming fat of the second forming sheet. The second decorative sheet is formed by a method such as printing as shown in Fig. 2A, and forms a transparent surface of the η 竹 得 得 i i i i ? ? ? ? ? The ink varnish component is a predetermined core layer on the common ink layer 3, and the coloring layer 2 is formed on the transparent/upper 疋 pattern as shown in FIG. 2β. Next, as shown in FIG. 2C, the adhesive layer 4 is formed. Further, the entire surface of the ink layer and the coloring layer is formed into a second decorative sheet 52 from ^1. Then, as shown in Fig. 2D, the slave synthetic resin 6 can be formed by integrating the second loaded sheet 52 with the forming forming. The second molded body 72 is formed. 96135882 11 1339161 In the second decorative sheet, the transparent ink layer is formed into a whole surface in the formation of the base sheet:::::: The formation portion of the r colored layer , Base 4:::: There are: the transparent ink layer of the component layer ~ 黍 component is in contact, and the formed adhesive layer has good connection As a result, in the case where the second remaining sheet is formed by insert molding or the like to produce a molded body, it is possible to obtain a molded body having a good fit. 3A to 3D illustrate the cross section of the q1th third molded body: she is "and thin with the decoration [the embodiment is as shown in Fig. 3A, and the undrawn figure on the substrate sheet 1 is borrowed from the mesh material... As shown by 3β, on both of the base portions, 曰^ Μ ' and a transparent ink adhesive layer 4 formed by coloring Zhan 2 are formed, and a third decorative sheet is formed: 3.® % Then, it is formed as follows, and then, as shown in Fig. 3, D/f + iia _ ^ , . Q /, : Further, the synthetic resin 6 can be formed into a 苐3 formed body 73 by injection molding. In the present invention, in the case of the thermoplastic sheet substrate which is decorative in shape, it is possible to use a substrate sheet which can be processed into a three-dimensional element for the purpose of bonding, and it is possible to carry out the adhesion of the ink on the surface thereof. The straw is formed by a coating device or a printing machine, and is easily connected to a liquid, such as a gas, a resin, a poly-polymer, a polyethylene resin, a poly-resin, a poly-ply, etc. 2:88), the name of the acid is suspected to be the tree body, or the sex processor, formed a layer. Thin, can not follow the addition; ^ G 5_ (four), if more than ± crack and wrinkle. On the other hand, in the case of the two T-shapes, the decorative portion has a degree of decoration. In the case of the curved portion, it is difficult to produce high-refining, and it is preferably a sheet-like enamel resin formed of a polyvinyl carbon-based resin. Polypropylene resin, chlorine pure...Transesterification resin is used for coloring acoustic ink and transparent layer. In the case of 聚丙烯 系 于 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 聚丙烯 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 . The composition for forming an easy-adhesive layer formed of an acryl-based polyol resin, which is rented and 5', may be, for example, an Imperial ink. (3) In addition, as the varnish f of the ink used for the formation of the colored layer or the transparent ink layer, the following may be used: from acrylic resin, urethane resin, epoxy resin, polyester resin, polyfluorene Amine resin, vinyl acetate resin, phenol resin, olefin, ethylene-vinyl acetate copolymer resin, polyacetal resin, natural rubber, stupid ethylene-butadiene copolymer, acrylonitrile-butadiene copolymer a group consisting of vinyl acetate-acrylic acid copolymer, 96135882 1339161 ethylene-acrylic acid acetonitrile copolymer, polyester polyol, polyester polyurethane acetal polyol, and (iv) polyamine-based resin At least one kind, dispersed, dissolved in water, isopropyl alcohol, methanol, ethanol: alcohols, esters such as ethyl acetate, ketones such as f-ethyl ketone, toluene, di-f-benzene, Solvesso 丨00, s〇lvess 〇 15 〇 such as an aromatic hydrocarbon solvent, or an aliphatic hydrocarbon solvent such as hexane. Further, it may be a hardener containing isocyanate n from such a resin. Temple
二異氰酸六 二異氰酸二 具體而言，作為硬化劑，可舉例如二異 (TDI)、二異氰酸4_4，二苯基甲烷酯（MDI)、 亞甲酯（HDI)、異佛爾酮二異氰酸酯（ipDi)、 曱苯酯（XDI)等。 酸㈣含有“多醇㈣脂與作為硬化劑之異氰 醇用於本發明目的之油墨，可使用利用了聚酯多 色=曰與溶劑之帝國油墨製造製之⑽油墨系列的各 / ^，作為者色層形成用油墨及透明油墨。 色Γ或：㈣片係具有接黏層。接黏層係使著 提升的屛，g人形成成形品之合成樹脂間的接黏性Specifically, as the curing agent, diisocyanate diisocyanate 2 may be mentioned, for example, diiso(TDI), diisocyanate 4-4, diphenylmethane (MDI), methylene ester (HDI), or different. Fulcone diisocyanate (ipDi), nonylphenyl ester (XDI), and the like. The acid (iv) contains "polyol (tetra) grease and isocyanol as a hardener. The ink used for the purpose of the present invention can be used in each of the (10) ink series manufactured by Imperial ink using polyester multicolor = hydrazine and solvent. The ink for forming a color layer and the transparent ink. The color or the (4) sheet has an adhesive layer. The adhesive layer is used to enhance the adhesion, and the adhesion between the synthetic resin of the molded article is formed.
Si二由=脂等形成，並可藉由網版印刷等 酸針之巧二：可由含有從由乙烯與順丁烯二 組選出：至：：;順丁稀二酸針改質聚稀煙樹脂所組成群 一 ^種的油墨所形成。 糟由使用此種接赴M , 要站層，則即使在將聚丙烯、聚醯胺等進 96135882 14 ::出成形的情況下，亦可製造出具備充分剝離強度的成 順3::=:稀:，軒的共聚合體’可舉例如乙稀與 他單體的多元共：體以體、乙稀與順丁稀二酸軒與其 聚烯庐料胙：眞丁烯-酸酐改質聚烯烴樹脂’可舉例如於 煙樹二ί:?丁烯二酸肝而予以改質者，作為聚稀 乙烯醋共聚II =烯樹脂、聚丙稀樹脂及乙稀-醋酸 佳為順丁 ί °肢為順丁烯二酸酐改質聚烯烴樹脂，較 聚丙㈣:—酸酐改質聚乙稀樹脂及順τ烯二酸酐改質 ^旦S ^，且較佳係順丁烯二酸改質率為0. 3〜10%、分 里0’00(M 50,000的聚乙烯、聚丙烯。 脂體:舉例如由順丁坤二酸改質聚烤烴樹 J所形成之帝國油墨製造股份有限公司製的 >田墨糸列。 [貫施例] 以下列示實施例、比較例’以說明本發明。 [實施例1 ] 〈考色/由墨之調製〉 •八加0聚酯多醇樹脂（重量平均分子量20,000)35重量 ^旦芳日知烴系溶劑（S〇lvesso 100)25重量份、碳黑14 =伤 ' 芳香族烴系溶劑（s〇lvess〇 15〇)25重量份、聚 系/肖泡劑1重量份、NC〇當量16.5之異氰酸酷1〇重 里如’亚予以均勻混合而調製成著色油墨。 96135882 1339161 〈透明油墨之調製〉 於著色油墨之調製令，除了未渴合 樣地進行而調製透明油墨。 ’其餘均同 〈接黏層用油墨之調製〉 混合順丁烯二酸改質聚丙烯樹 5，、平均分子量：10萬)1〇重量份、酸改質度： 數平均粒子徑重量份、=切粉末（個 (S〇1 vess0 1 00)4〇重量份、環己_ 40重C手、?劑 消泡劑1重量份，而調製成接黏層用油墨/、聚石夕乳系 〈第1裝飾薄片a之製作〉 於縱210_、橫297職、厚〇 5龍之聚 塑勝製戰aaCEEC—】00)上，使用25〇網曰目基的 =中 :? 4之以平面圖所示之著色層2的圖案般，於基材薄片 二30賴、橫50_的尺寸’縱橫分別為3〇_的間 L亚餘方向上3列、縱方向上4段的配置，以 圍之未形成著色層之部分的寬度為均等的方式，形： 層2’於乾燥機中以6(rc進行乾燥6〇分鐘而形成 ΙΠ的者色層。 其次，在未形成著色層的部m字先前所調製之透明 油墨藉由25〇網目之網版進行印刷後，於乾燥機中以6〇 c進行乾燥60分鐘而形成膜厚6/Wm的透明油墨層。 進一步於著色層及透明油墨層上，將先前所調製胃之接黏 層用油墨藉由15 0網目之網版進行印刷後’於乾燥機中以 6〇 C進行乾燥60分鐘，而製成形成了膜厚1〇#m之接黏 96135882 1339161 層的第1裝飾薄片試料a。 〈第1成形體試料a之舉作·〉 將所付之第1裝飾薄片試料a安裝於射出成形機的禱模 中，將作為成形用合成樹脂之聚丙烯（三井化學製之pRIME POLYPRO J707G’溶融流動逮率3〇g/1〇分）依樹脂溫度2〇〇 。(：、鑄模溫度4(TC的條件進行射出成形，製成使成形用 〇成私Hs與第1裝飾薄片試料a —體化的第1成形體試料 a 〇 〈剝離試驗〉 二所衣成的第1成形體試料a製作出縱i 5襲、橫麗 々式k片依JIS-K6854-2的接黏劑-剝離接黏強度試驗 方法進行射出成形樹脂層與裝飾薄片U0度剝離試 驗，並將其結果示於表i。 [實施例2 ] 〈第2裝饰薄片b之製作〉 土^POLICA ACEEC-_上，藉由25G網目的網版， :先^ 斤調製之透明油墨殘留印刷空白而印刷為整面狀 機中以6。t進行乾燥60分鐘而形成膜m 的远明油墨層。 美如圖4之以平面圖所示之著色層2的圖案般，於 二p 依縱30_、橫50_的尺寸，縱橫分別為3〇丽 依橫方向上3列、縱方向上4段的配置，以基 未形成*色層之部分的寬度為均等的方式，形成 96135882 17 1339161 著色層2 ’於乾燥機中以60°C進行乾燥60分鐘而形成膜 厚6 # m的著色層。 進一步於透明油墨層上’將先前所調製之接黏層用油墨 藉由1 50網目之網版進行印刷後，於乾燥機中以6〇〇c進 行乾燥60分鐘’而製成形成了膜厚1 〇以m之接黏層的第 2裝飾薄片試料b。 〈成形體試料b之製作〉 將所得之第2裝飾薄片試料b安裝於射出成形機的铸模 中，將作為成形用合成樹脂之聚丙烯（三井化學製之pRIME POLYPRO J707G’熔融流動速率30g/l〇分）依樹脂溫度2〇〇 °C、鑄模溫度40°C的條件進行射出成形，製成使成形用 &成Μ脂與第2裝飾薄片試料b —體化的成形體試料匕。 〈剝離試驗〉 對所製成的成形體試料b藉實施例1所記載之剝離試驗 方法進行剝離試驗’並將其結果示於表1。 [實施例3] 〈第3裝飾薄片c之製作〉 於縱210mm、橫297mm、厚〇. 5_之聚矽酸酯基材（筒中 塑膠製POUCA ACEEC-100)上，使用25〇網目的網版， 如圖4之以平面圖所示之著色層2的圖案般，於基材薄片 1 一上，依縱30mm、橫50_的尺寸，縱橫分別為3〇_的間 隔，並依橫方向上3列、縱方向上4段的配置，以基材周 圍之未形成著色層之部分的寬度為均等的方式，形成著L 層2，於乾燥機中以60。〇進行乾燥6〇分鐘而形成膜厚6 知35882 18 丄 339161 // m的著色層。 其次’於形成了著色層之部分及未形成著色層之部分的 整面上’藉由250網目的網版’殘留印刷空白而將先前所 调製之透明油墨進行印刷後，於乾燥機中以60。(：進行乾 、中60刀知而形成著色層上之膜厚的透明油墨層。 —進步於透明油墨層上，將先前所調製之接黏層用油墨 猎由⑽網目之網版進行印刷後，於乾燥機中以6(TC進 订乾燥6G分鐘’而製成形成了臈厚10"之接黏層的第 3裝飾薄片試料〇。 〈成形體試料c之製作〉 將所付之第3裝飾薄片試料c安裝於射出成形機的鑄模 Ρητ^作為成㈣合成樹脂之聚丙婦（三井化學製之PRIME RO J707G ’ 融流動速率3〇g/1〇分）依樹脂溫度_ 入=模溫度4(TC的條件進行射出成形，製成使成形用 脂與第3㈣薄片試料c —體化的成形體。 〈剝離試驗> :所製成的成形體試料c製作出縱15_、橫5〇_的試 進—·&+ΓJIS K6854 2的接黏劑—剝離接黏強度試驗方法 進仃射出成形樹脂層與裝倚薄Η ^ ^ ^ I寻片之180度剝離試驗，並將 共結果不於表1。 [實施例4] 〈第4裝飾薄片d之製作〉 片（出光UNITECH公司製 丙烯酸多醇樹脂35重量 除了使用厚0 · 3mm之聚丙歸薄 PIARAY)作為基材薄片，將添加了 96135882 ^39161 6、芳香族烴系溶劑（s〇lvess〇 15〇)5〇重量取^ 系消泡劑1重量份、當量16,5之異氰酸二 而均勻混合的組成物，使用250網目之網版印刷於整： =於乾燥機中以6代進行乾燥6Q分鐘而形成膜厚^ 的易接黏層以外，其餘與實施们同樣 裝飾薄片簡d。 “衣成弟4 〈成形體試料d之製作〉 將所得之第4裝飾薄片試料d安裝於射出成形機的缚模 令，將作為成形用合成樹脂之聚丙烯（三井化學製之卩_ =LYPRO J707G，炫融流動速率3〇g/1 〇分）依樹脂溫度_ 人^ = ί 4Qt的條件進行射出成形，製成使成形用 a成心旨與第4裝飾薄片試料d 一體化的成形體試料仆 並與貫施例1同樣地進行剝離試驗，將其結果示 [實施例5] 將與實施例1同樣地所製成的第】裝飾薄“，安茫於 射出^形機的鑄財，將料成形用合成㈣的聚酿胺 (東鹿衣ALAMINE CM1 007)依樹脂溫度2〇〇。〇、禱模溫戶 4〇的條件進行射出成形而得到成形體試料卜 、- 將所製成的成形體試料6如同實施例1之剝離試驗方法 進行剝離試驗，將其結果示於表】。 [比較例1 ] 除了於在基材薄片上形成著色層後，於形成了著色層之 :分及未形成著色詹之部分的兩者上形成接黏層之外，1 餘均與實施例1同樣地進行而形成自著色層起的為 96135882 20 1339161 1 〇 “ m厚的接黏層’製成比較試料&之裝飾薄片。 、使用所得之比較試料^之裝飾薄片，與實施例i同樣地 進:丁而製成比較成形體試料a，與實施例i同樣地進行剝 離試驗’其結果示於表1。 [比較例2 ] ，了於基㈣片上形成厚1G//m之接黏層之外，其餘均 人貫施例1同樣地進行而製成比較試料b之裝飾薄片。 使用所得之比較試料b之裝飾薄片，與實施例i同樣地 =丁而製成比較成形體試料b，與實施例丄同樣地進行剥 肖隹试驗’其結果示於表1。 ' [表1] 剝離強度 kN/m 貫施例 2.4 實施例 實施例3 實施例4 實施例Si II is formed by = fat, etc., and can be modified by screen printing and the like: it can be selected from the group consisting of ethylene and cis-butene: to::; The resin is formed by a group of inks. The use of this kind of access to M, to station layer, even in the case of polypropylene, polyamide, etc. into the formation of 96135882 14 :: out, can also produce a full peel strength of Cheng Shun 3::= : Rare:, Xuan's copolymers can be exemplified by the diversification of ethylene and other monomers: body, ethylene and cis-succinic acid and its polyene 胙: 眞 butene-anhydride modified poly The olefin resin can be modified, for example, by the tobacco sulphate: as a polystyrene vinegar copolymer II = ene resin, polypropylene resin and ethylene-acetic acid. For maleic anhydride modified polyolefin resin, it is more modified than polypropylene (tetra):-anhydride modified polyethylene resin and cis- enedicarboxylic acid anhydride, and preferably maleic acid modification rate 0. 3~10%, 0'00 (M 50,000 polyethylene, polypropylene. Lipid: for example, Imperial Ink Manufacturing Co., Ltd. formed by the modified succinic acid modified hydrocarbon tree J <Comprehensive Example> The present invention will be described by way of the following examples and comparative examples. [Example 1] <Color of color/modulation by ink> • Eight plus zero Polyol resin (weight average molecular weight 20,000) 35 parts by weight of aromatic hydrocarbon solvent (S〇lvesso 100) 25 parts by weight, carbon black 14 = injury 'aromatic hydrocarbon solvent (s〇lvess 〇 15 〇) 25 weight 1 part by weight of the polymethicone/foaming agent, and the isocyanate of the NC oxime equivalent of 16.5 is as fine as the yt. The yam is uniformly mixed to prepare a colored ink. 96135882 1339161 <Modulation of Transparent Ink> Modification of Coloring Ink The transparent ink is prepared except that it is not thirsty. 'The rest is the same as the ink for the adhesive layer.> Mixed maleic acid modified polypropylene tree 5, average molecular weight: 100,000) 1 part by weight Acid modification: number average particle diameter by weight, = cut powder (one (S〇1 vess0 1 00) 4 〇 parts by weight, cyclohexane _ 40 heavy C hand, 1 part by weight of antifoaming agent) Into the adhesive layer ink /, Ju Shi Xiu system <The production of the first decorative sheet a> In the vertical 210_, Heng 297, thick 〇 5 dragon's plastic wins battle aaCEEC - 00), use 25 〇 The mesh of the mesh base = middle: ? 4 is the pattern of the color layer 2 shown in the plan view, and the substrate sheet is 30 Å, horizontal 50 _ The inch's vertical and horizontal directions are 3 〇 in the direction of the L sub-remains, and the longitudinal direction is 4, and the width of the portion where the colored layer is not formed is equal. Form: Layer 2' in the dryer In the middle of 6 (rc) drying for 6 minutes to form a enamel color layer. Secondly, in the portion of the m-form that has not formed a color layer, the previously prepared transparent ink is printed by a 25-inch mesh screen, in a dryer The film was dried at 6 〇c for 60 minutes to form a transparent ink layer having a film thickness of 6/Wm. Further, on the colored layer and the transparent ink layer, the adhesive layer of the previously prepared stomach was coated with ink by a screen of 150 mesh. After the printing, the film was dried at 6 ° C for 60 minutes in a drier to prepare a first decorative sheet sample a having a thickness of 1 135 161, which was formed to have a thickness of 1 〇 #m. <Preparation of the first molded article sample a> The first decorative sheet sample a to be attached is attached to a prayer mold of an injection molding machine, and polypropylene as a synthetic resin for molding (pRIME POLYPRO J707G by Mitsui Chemicals Co., Ltd.) The melt flow rate is 3〇g/1〇) according to the resin temperature of 2〇〇. (:, mold temperature 4 (the conditions of TC were injection-molded, and the first molded body sample a 〇 <peeling test> for forming the molded 〇 私 H H H H H H H H H H H H H H H H H H H H H H H In the first molded body sample a, the U0 degree peeling test of the injection molding resin layer and the decorative sheet was carried out by the adhesive-peeling adhesion strength test method of JIS-K6854-2. The results are shown in Table 1. [Example 2] <Production of the second decorative sheet b> On the POLICA ACEEC-_, the screen of the 25G mesh was used, and the transparent ink remaining in the printing was blank. The printing is carried out in a full-surface machine at a temperature of 6.t for 60 minutes to form a far-ey ink layer of the film m. As shown in Fig. 4, the pattern of the color layer 2 shown in the plan view is as follows. The size of 50_, the vertical and horizontal directions are 3 rows in 3 directions in the horizontal direction and 4 segments in the vertical direction, and the width of the portion where the * color layer is not formed is equal, forming 96135882 17 1339161 colored layer 2 ' Drying at 60 ° C for 60 minutes in a dryer to form a colored layer having a film thickness of 6 # m. On the ink layer, the previously prepared adhesive layer was printed with a 150 mesh screen and dried in a dryer at 6 ° C for 60 minutes to form a film thickness of 1 〇. The second decorative sheet sample b of the adhesive layer of the m. The production of the molded article b of the molded article is obtained by attaching the obtained second decorative sheet sample b to the mold of the injection molding machine, and using polypropylene as a synthetic resin for molding (Mitsui The chemically produced pRIME POLYPRO J707G' melt flow rate: 30g/l )) is injection-molded according to the resin temperature of 2 ° C and the mold temperature of 40 ° C, and is used to form the molding & The molded article sample of the sheet sample b was subjected to a peeling test. The peeling test was performed on the obtained molded body sample b by the peeling test method described in Example 1 and the results are shown in Table 1. Example 3] <Production of the third decorative sheet c> On a polyphthalate substrate (POUCA ACEEC-100 made of plastic in a cylinder) of a length of 210 mm, a width of 297 mm, and a thickness of 5 mm, a screen of a 25-inch mesh is used. As shown in Fig. 4, the pattern of the color layer 2 shown in the plan view is on the substrate. The sheet 1 has a vertical and horizontal spacing of 3 〇 _, and has an interval of 3 〇 in the horizontal direction and 4 stages in the vertical direction, and the coloring layer is not formed around the substrate. The width of the portion is equal, and the L layer 2 is formed, and dried in a dryer at 60 〇 for 6 〇 minutes to form a coloring layer having a film thickness of 6 and 35,882 18 丄 339,161 // m. The portion of the layer and the entire surface of the portion where the color layer is not formed are printed by the residual printing ink of the 250 mesh screen, and the transparent ink prepared by the printing is 60 in the dryer. (: A transparent ink layer with a film thickness of 60 knives formed on the color layer. - Progressed on the transparent ink layer, the previously prepared adhesive layer was stenciled with the ink of the (10) mesh screen. In the dryer, the third decorative sheet sample 形成 which is formed into a thickness of 10" is formed by 6 (TC is dried for 6 G minutes). <Production of molded article c> The third payment is made. The decorative sheet sample c is mounted on the mold of the injection molding machine Ρητ^ as the (four) synthetic resin of the polypropylene (PRIME RO J707G's melt flow rate of 3 〇g / 1 〇) by resin temperature _ input = mold temperature 4 (The conditions of the TC were injection-molded to obtain a molded body in which the molding grease and the third (four)th sheet sample c were formed. <Peeling test>: The formed molded article c was produced in a longitudinal direction 15_, a horizontal width 5〇_ Trial--&+ΓJIS K6854 2 Adhesive-Release Adhesive Strength Test Method: Injecting and Forming Resin Layer and 180-degree Peel Test with Dependent Thin Film ^ ^ ^ I, and the total result is not [Table 4] [Production of the 4th decorative sheet d] Sheet (Exit UNITECH) The weight of the acrylic polyol resin is 35, and the weight of the polyacrylic acid PIARAY is 0. 3mm. As a substrate sheet, 96135882 ^ 39161 6 is added, and the aromatic hydrocarbon solvent (s〇lvess〇15〇) is added. ^ A composition in which 1 part by weight of an antifoaming agent and an equivalent amount of 16,5 isocyanic acid were uniformly mixed, and printed on a screen using a 250 mesh screen: = dried in a dryer for 6 minutes in 6 passes to form a film. In addition to the easy-adhesive layer of the thickness of the thick layer, the sheet is simply decorated with the same as the embodiment. "Yi Chengdi 4" Production of the molded article d" The attached fourth decorative sheet sample d is attached to the injection molding machine. The polypropylene which is a synthetic resin for forming (manufactured by Mitsui Chemicals Co., Ltd. = LYPRO J707G, the flow rate of the smelting and melting rate of 3〇g/1 〇) is injection-molded according to the conditions of the resin temperature _ person ^ = ί 4Qt. In the same manner as in Example 1, the peeling test was carried out in the same manner as in the first example, and the results were shown in the same manner as in the first embodiment. Made of the first] decorative thin, ampoules in the injection of the ^ machine, In the synthesis of the material (4), the polyamine (Aramine CM1 007) is prepared by injection molding under the conditions of a resin temperature of 2 〇〇 and a prayer mold of 4 温, and a molded body sample is obtained. The molded body sample 6 was subjected to a peeling test as in the peeling test method of Example 1, and the results are shown in the table. [Comparative Example 1] In addition to forming a colored layer on a substrate sheet, a colored layer was formed: Except that the adhesive layer was formed on both of the portions in which the coloring was not formed, one was formed in the same manner as in Example 1 to form a bonding layer of 96135882 20 1339161 1 〇 "m thick" from the colored layer. Compare the sample & In the same manner as in the example i, the comparative molded sample a was prepared in the same manner as in the example i, and the peeling test was carried out in the same manner as in the example i. The results are shown in Table 1. [Comparative Example 2] A decorative sheet of Comparative Sample b was prepared in the same manner as in Example 1 except that an adhesive layer having a thickness of 1 G/m was formed on the base (four) sheet. Using the obtained decorative sheet of the comparative sample b, the comparative molded sample b was prepared in the same manner as in Example i, and the peeling test was carried out in the same manner as in Example ’. The results are shown in Table 1. [Table 1] Peel strength kN/m Example 2.4 Example Example 3 Example 4 Example
比較例1 0. 1 /發明之 /刀，係形成有與I色層係'清漆成分為共通的透明油墨層， 並於此等層上進-步形成接黏層後，在使裝㈣片與合曰 樹脂進行-體化的情況下，與合成樹脂fa1的接n ς不 :存於著色層形成部之尺寸、圖樣、或裝飾薄片表面形狀 =，故可提供與合成樹脂間之接黏性良好的裝飾薄片，並 藉其&供剝離強度較大的成形品。 w 【圖式簡單說明】 圖1A至圖1D係說明第丨裝飾薄片及與裝飾薄轉 之第1成形體的剖面圖。 圖2A至圖2D係說明第2裝飾薄片及與裝飾薄片一體化 96135882 21 1339161 之第2成形體的剖面圖。 圖3A至圖3D係說明第3裝飾薄.片及與裝飾薄片一體化 之第3成形體的剖面圖。 圖4係說明著色層圖案之平面圖。 【主要元件符號說明】 1 基材薄片 2 著色層 3 透明油墨層 4 接黏層 6 成形用合成樹脂 51 第1裝飾薄片 52 第2裝飾薄片 53 第3裝飾薄片 71 第1成形體 72 第2成形體 73 第3成形體 96135882 22Comparative Example 1 0. 1 / Invention / Knife, a transparent ink layer which is common to the I lacquer layer varnish component is formed, and after forming an adhesive layer on the layers, the film is placed in the (four) film. When it is combined with the hydrazine resin, the connection with the synthetic resin fa1 is not: the size of the colored layer forming portion, the pattern, or the surface shape of the decorative sheet =, so that it can provide adhesion to the synthetic resin. A good-quality decorative sheet, and by its & for a peeling strength of the molded article. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1A to Fig. 1D are cross-sectional views showing a first decorative sheet and a first molded body which is thinly rotated. 2A to 2D are cross-sectional views showing the second decorative sheet and the second molded body integrated with the decorative sheet 96135882 21 1339161. 3A to 3D are cross-sectional views showing a third decorative sheet and a third molded body integrated with the decorative sheet. Fig. 4 is a plan view showing a pattern of a colored layer. [Description of main component symbols] 1 base sheet 2 colored layer 3 transparent ink layer 4 adhesive layer 6 synthetic resin for molding 51 first decorative sheet 52 second decorative sheet 53 third decorative sheet 71 first molded body 72 second molding Body 73 third formed body 96135882 22