TWI328282B - Complementary metal-oxide-semiconductor (cmos) image sensor and fabricating method thereof - Google Patents
Complementary metal-oxide-semiconductor (cmos) image sensor and fabricating method thereof Download PDFInfo
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UMCD-2006-0218 21287twf.doc/e 九、發明說明: 【發明所屬之技術領域】 本發明疋有關於-種影像感測器及其 ^有關於-紅補式錢铸體影縣·及^ 法。 【先前技術】 互補式金氧半導體影像感測器(CMOS image sensor as)與互赋錢半導_ ==2 周邊電路整合在同一曰H t 口此很备易與其他 器的成切及雜近年;巾得低影像感測 互補式金氧跑》彡像_ :增進而使得互補式金氧半導體影像 互補式金氧半導體影像感測器 — :電晶體所構成,其中光二極體由;體與多 底形成之Ρ-η接面所構成,而電晶 與P型基 晶體(n,lyNM0S)。目前,互補式 的η型電 的結構包括有3.Τ架構以及4_τ架+導縣像感測器 =指互補式金氧半導體影像感測器構架 體收)、源極_器電晶體(Dx)、選,曰=括重置電晶 ?J(PD) ’而4·τ架構是指互補式金氣:二:)及:光二 的結構包括轉移電晶體(Τχ)、重置 導㈣像感測器 晶體、選擇電晶體及一光二極塒曰曰體、源極隨耦器電 現階段,互補式金氧影像鐵測器普遍會存在產 1328282 UMCD-2006-0218 21287twf.doc/e 生漏電流(leakage)的問題。一般而言,互補式金氧半導體 影像感測器中的光二極體以及電晶體皆會產生漏電流。= 述漏電流的問題將會使得互補式金氧半導體影像感測器產 生相當大的暗電流(dark euirent),導致讀出的雜訊增加二 及影響影像品質,而降低元件之效能。UMCD-2006-0218 21287twf.doc/e IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an image sensor and its related information - red-filled money casting body shadow county and ^ law. [Prior Art] Complementary CMOS image sensor as and mutual money semi-conducting _ ==2 The peripheral circuits are integrated in the same 曰H t port, which is easy to be cut and miscellaneous with other devices. In recent years; the towel has a low image sensing complementary metal oxygen running" image: reinforced: a complementary CMOS image complementary MOS image sensor - : a transistor composed of a photodiode It is composed of a Ρ-η junction formed by a multi-bottom, and an electro-crystal and a P-based crystal (n, lyNM0S). At present, the complementary n-type electrical structure includes a 3.Τ structure and a 4_τ frame + guide image sensor = a complementary MOS image sensor frame body), a source _ transistor (Dx) ), select, 曰 = include resetting the crystal? J (PD) ' and the 4 · τ architecture refers to the complementary gold gas: two:) and: the structure of the light two includes the transfer transistor (Τχ), reset guide (four) image The sensor crystal, the selection transistor and a photodiode body, the source follower is in the electric phase, and the complementary gold-oxygen image iron detector generally has a production of 1328282 UMCD-2006-0218 21287twf.doc/e Leakage problem. In general, the photodiode and the transistor in a complementary MOS image sensor generate leakage current. = The problem of leakage current will cause the complementary MOS image sensor to generate a relatively large dark current (dark euirent), which will increase the read noise and affect the image quality, and reduce the performance of the component.
山持別是,對4-T架構的互補式金氧半導體影像感測器 而5,互補式金氧半導體影像感測器中大部分的暗電漭θ 因轉移電晶體的漏電流問題而造成。因此,如 = 感測器的漏電流已成為目前業界發展的重要課題之一二 【發明内容】 ° 有 半導體 流問題 效能。 f於此,本發明的目的就是在提供一種互補式金 如像感心及其製造方法,能夠降低電晶體的漏雷 ’以及避免暗電流的產生,以提高影像品質與元^The mountain is different from the complementary MOS image sensor of the 4-T architecture. 5, most of the dark 漭 θ in the complementary MOS image sensor is caused by the leakage current of the transfer transistor. . Therefore, the leakage current of the sensor has become one of the important topics in the development of the industry. [Inventive content] ° There are semiconductor flow problems. In view of this, the object of the present invention is to provide a complementary gold image sensing center and a manufacturing method thereof, which can reduce the leakage of the transistor and avoid the generation of dark current to improve image quality and quality.
造方f f # ^錄半導體影像❹彳器的製 ώ 去為先提供一基底,此基底具有一井咸 區,在J晶體元件區之基底;形: 晶石夕層。接著底上依序形成介電層以及未接雜多 分電曰俨开杜r ^成弟一罩幕層’以覆蓋住光感測區盥邛 件區的未摻雜多晶石夕層。隨後,進行第 中=形成,多晶抑,接著移 幕2 =層 形成第二罩幕層,薦芏早忝層。繼之, 子植入製程型多晶糾'然後,進行第二離 、Pi#禮人所曝露出的未摻雜多晶石夕層 6 UMCD-2006-0218 21287twf.doc/e 中,以形成P型多晶矽層,接著移除第二罩幕層。之後, 定義介電層、η型多晶矽層與p型多晶矽層,以於電晶體 元件區之ρ型井區上形成多個η型閘極結構與一 ρ型閘極 結構。隨後,於光感測區之基底中形成光二極體。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的η型閘極結構是轉移電晶體、 重置電晶體、源極隨耦器電晶體與選擇電晶體其中之三的 閘極結構’ ρ型閘極結構是其中另一的電晶體之閘極結構。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的η型閘極結構是重置電晶體、 源極隨耦器電晶體與選擇電晶體其中之二的閘極結構·,ρ 型閘極結構是其中另一的電晶體之閘極結構。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的η型摻質例如是磷(Ρ)或砷(As)。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的η剞換質的劑量介於1χ10]4〜 5X101S ion/cm2 之間。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的P型摻質例如是硼(B)或二氟化 棚(BF2)。 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的P型換質的劑量介於lx 1〇13〜 5><1015 ion/cm2 之間。 依照本發明的實施例所述之互補式金氧半導體影像 1328282 UMCD-2006-0218 2l287twf.doc/e 上述的光二極體的形成方法例如是進 感測器的製造方法 行一摻雜製程。 ,、本發明另提出—種互補式金氧半導體影像感測器的 衣le方法,此方法為先提供一基底,基底具有一光感測區 f -電晶體7〇件區。‘然後’在電晶體元件區之基底中形成 p 3L井區。之後,在基底上依序形成一介電層以及一未 捧雜多晶石夕層。接著,進行第-離子植入製程,將η型捧 貝《植=未#雜多^夕層中,以形成η型多砂層。隨後, 形成^罩幕層,以曝露出光感測區與部分電晶體元件區的 晶料。繼之,輯第二離子植人製程,植入ρ型 ‘二曝露出的η型多晶石夕層轉變成ρ型多晶石夕層。 電曰I#疋杜^電層、η型多晶石夕層與ρ型多晶石夕層,以於 型閘極、^構型井區上形成多個η型’結構與一 Ρ &义後,於光感測區之基底中形成光二極體。 感測器實施騎述之互補式金氧半導體影像 重詈雷曰驶。 上述的n型閘極結構是轉移電晶體、 閘極处構,p :極隨㈣電晶體與選擇電晶體其中之三的 極結構是其中另一的電晶體之閘極結構。 感測器的製實施綱述之互補式金氧半導體影像 源極_ W結構是重置電晶體、 型閘極結構擇_體其中之二關極結構,P /、中另—的電晶體之閘極社谨。 感測器實闕所述之互補^金氧半導體影像 、方法,上述的η型摻質例如是磷或砷。 8 1328282 UMCD-2006-0218 21287twf.doc/e 依照本發明的實施例所述之互補式金氧半導體影像 感測器的製造方法,上述的η裂推質的劑量介於1χ1〇ι4〜 5χ1015 ion/cm2 之間。‘ 依照本發明的實施例所述之互補式金氧半導體赘像 感測器的製造方法,上述的p蜇摻質例如是硼或二氟化硼 依照本發明的實施例所述之互補式金氧半導體景 感測器的製造方法,上述的p型摻質的劑量介於^ t造方f f # ^ Recording semiconductor image 的 ώ 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为Then, a dielectric layer is formed on the bottom and an undoped polysilicon layer is disposed to cover the undoped polycrystalline layer of the photo sensing region. Subsequently, the middle = formation, polycrystalline suppression, and then the movement 2 = layer to form a second mask layer, recommended early layer. Subsequently, the sub-implantation process type polycrystalline correction is then performed in the undischarged polycrystalline layer 6 UMCD-2006-0218 21287 twf.doc/e exposed by the second and Pi# rituals to form The P-type polysilicon layer is then removed, and the second mask layer is removed. Thereafter, a dielectric layer, an n-type polysilicon layer and a p-type polysilicon layer are defined to form a plurality of n-type gate structures and a p-type gate structure on the p-type well region of the transistor element region. Subsequently, a photodiode is formed in the substrate of the photo sensing region. According to the manufacturing method of the complementary MOS image sensor according to the embodiment of the present invention, the n-type gate structure is a transfer transistor, a reset transistor, a source follower transistor, and a selection transistor. Three of the gate structures 'p-type gate structure are the gate structure of the other transistor. According to a method of fabricating a complementary MOS image sensor according to an embodiment of the invention, the n-type gate structure is a reset transistor, a source follower transistor, and a selected transistor. Gate structure · The p-type gate structure is the gate structure of the other transistor. According to a method of fabricating a complementary MOS image sensor according to an embodiment of the present invention, the n-type dopant is, for example, phosphorus (phosphorus) or arsenic (As). According to the method of fabricating a complementary MOS image sensor according to an embodiment of the invention, the dose of the η剞 metamorphism is between 1χ10]4 and 5×101S ion/cm2. According to a method of fabricating a complementary MOS image sensor according to an embodiment of the present invention, the P-type dopant is, for example, boron (B) or a difluoride shed (BF2). According to a method of fabricating a complementary MOS image sensor according to an embodiment of the present invention, the P-type metamorphism has a dose of between lx 1 〇 13 〜 5 >< 1015 ion/cm 2 . Complementary MOS image according to an embodiment of the present invention 1328282 UMCD-2006-0218 2l287twf.doc/e The above-described photodiode formation method is, for example, a method of manufacturing a sensor, and a doping process. The present invention further provides a method for fabricating a complementary MOS image sensor. The method provides a substrate having a photo sensing region f-electrode 7 germanium region. A 'p'L well region is formed in the substrate of the transistor element region. Thereafter, a dielectric layer and a non-heteropolycrystalline layer are sequentially formed on the substrate. Next, a first ion implantation process is performed to form an n-type multi-sand layer in the n-type "Planting" layer. Subsequently, a mask layer is formed to expose the crystal of the photo sensing region and a portion of the transistor component region. Following this, the second ion implantation process was carried out, and the p-type ‘n exposed exposed n-type polycrystalline stone layer was transformed into a p-type polycrystalline stone layer. The electric 曰I#疋杜^ electric layer, the η-type polycrystalline shi layer and the p-type polycrystalline shi layer form a plurality of n-type structures and a Ρ &; on the shaped gate and the ^ configuration well area After the sense, a photodiode is formed in the substrate of the photo sensing region. The sensor implements the complementary CMOS image of the rider. The n-type gate structure described above is a transfer transistor, a gate structure, and a p-pole with a (four) transistor and a three-pole structure of the selected transistor is the gate structure of the other of the transistors. The complementary MOS image source _ W structure of the sensor implementation is a reset transistor, a gate structure, a two-pole structure, and a P/, a medium-sized transistor. The gate is very good. The sensor is substantially complementary to the MOS image, and the n-type dopant is, for example, phosphorus or arsenic. 8 1328282 UMCD-2006-0218 21287 twf.doc/e According to a method for fabricating a complementary MOS image sensor according to an embodiment of the invention, the dose of the η cleavage is between 1χ1〇ι4 and 5χ1015 ion Between /cm2. According to a method of fabricating a complementary MOS sensor according to an embodiment of the present invention, the p-doped dopant is, for example, boron or boron difluoride, in accordance with an embodiment of the present invention. The manufacturing method of the oxygen semiconductor scene sensor, the dose of the above p-type dopant is in the range of
ion/cm2 之間。 、'S〜 依照本發明的實施例所述之互補式金氧半旦 方法,上述的光二極體的形成方法例二 明又提4 —種互献金氧半導體影像感測器,财 乳半導體影像感測器包括基底、光二極體、1 U構衫個n型閘極結構。其中,基底具有1 以及1電晶體兀件區。光二極體配置於光感測區之Between ion/cm2. </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> The sensor includes a substrate, a photodiode, and an n-type gate structure. Among them, the substrate has 1 and 1 transistor element regions. The light diode is disposed in the light sensing area
雜,,構配置於電晶體元件區之基底上。 、本發明的貫施例所述之互補式金氧半旦 述的_閘極結構是轉 ‘象 源極隨輪器電晶體與選擇雷a _ 置电曰曰體、The structure is disposed on the substrate of the transistor component region. The complementary MOS gate structure described in the embodiment of the present invention is a turn-to-source source-wheeled transistor and a selected Ray a _ electric body,
型閘極結構是j:中$ :日*之二的閘極結構,I 依照結構》 感測器’上述的„型_*:是之重互置口氧=偉 電晶體與選擇電晶體其中之二的開極結;二型閘 9 1328282 UMCD-2006-0218 21287twf.doc/e 是其中另一的電晶體之閘極結構。 依照本發明的實施例所述之互補式金氧半導體影像 感測器’上述的光二極體為一 p-η接面區。 本發明再提出一種互補式金氧半導體影像感測器。此 互補式金氧半導體影像感測gf包括基底、光二極體以及多 個η型電晶體。其中,基底具有一光感測區以及一電晶$ 凡件區。光二極體配置於光感測區之基底中。多個η型電 晶體配置於電晶體元件區之基底上,其中這些η型電晶^ 的閘極結構包括一 ρ型閘極結構與多個η型閘極結構阳 —依照本發明的實施例所述之互補式金氧半導體影像 感測益,上述的η型閘極結構是轉移電晶體、重置雷晶體、 =極隨_電晶體與選擇電晶體其中之三的閘極結構 3L閘極結構是其中另一的電晶體之閘極結構。 咸制!1照本發_實_所述之互補式金氧半導體影像 電晶:食型閘極結構是重置電晶體 '源極隨耦器 是二另:的電。型_ 感測金氧半導體影像 電曰之互補式金氧半導體影像感測11是將習知η型 (P-poly)取代,因 U 型閘極結構 可避免習知因互補:金晶體的漏電流問題,如此-來 導致讀出的雜訊增—影;==== 1328282 UMCD-2006-0218 21287twf.doc/e 為讓本發明之上述和其他目的、特徵和優點能更明顯 易懂,下文特舉實施例,並配合所附圖式,作詳細說明如' 下。 ° 〇 【實施方式】 ^本發明可適用於具有3·Τ架構或4-Τ架構之互補式金 氧半導體影像感測器,然並不限於此,本發明還可適用於 φ 其他具有多個電晶體結構之互補式金氧半導體影像感測 器。 〜 圖1為依照本發明之一實施例的互補式金氧半導體影 • 像感測斋的上視示意圖。圖2緣示為圖1沿ΑΑ,剖面線之 剖面示意圖。 請同時參照圖1與圖2 ’ 4-Τ架構之互補式金氧半導 體影像感測器100是由基底101、光二極體1〇6、一個ρ 型閘極結構108以及多個η型閘極結構110、112、114所 構成。其中’基底101例如是梦基底或其他半導體美底。 • 在基底101中具有一隔離結構105,以界定出光感測區_1〇2 與電晶體元件區104,上述隔離結構1〇5例如是淺溝渠隔 離結構(sti)或其他隔離結構。另外,在電晶體元件區1〇4 之基底101中還配置有Ρ型井區103,在此Ρ型井區1〇3 上會配置有多個η型電晶體(NMOS),於後將會做詳細說 明。 光二極體106是配置於光感測區102之ρ型井區1〇3 與基底101中。光二極體106是一 ρ-η接面區,其作用為 1328282 UMCD-2006-0218 21287twf.doc/e 接受光源,並將光能轉變為電能。光二極體1〇6可由光感 測區102之P型基底以及一 n型摻雜區(未繪示)所構 成0 。P型閘極結構108配置於電晶體元件區1〇4之p型井 區103上。p型閛極結構1〇8是由p型多晶矽層1〇8&以及 介電層116所組成’其中p型多晶矽層1〇8a是當作p型閘 ,(P-P〇ly),介電層116是當作閘氧化層。在此實施例中, 是以P型閘極結構108為轉移電晶體(Τχ)的閘極結構當作 例子來做說明。 η型閘極結構配置於電晶體元件區1〇4 之P型井區103上。每一個!!型閘極結構11〇、112、114 分別是由η型多晶矽層110a、n2a、114&和介電層116所 組成,其中η型多晶矽層n〇a、〗12a、】14a是當作n型閘 極(n-poly),介電層116是當作閘氧化層。上述,n型閘極 結構110、112、114分別是重置電晶體(Rx)、源極隨麵器 電晶體(Dx)及選擇電晶體(Sx)的閘極結構。 另外,互補式金氧半導體影像感測器100還包括n型. 源極/沒極區118 ’其配置於η型閘極結構ι10、n2、114 及ρ型閘極結構108兩側的ρ型基底1〇3中。因此可形成 p-poly NMOS的轉移電晶體以及n_p〇iy 的重置電晶 體、源極隨耦器電晶體與選擇電晶體。 本發明並不以上述實施例之多個電晶體的位置為限 制,其位置排列可視電路設計或製程需要而調整。 在另一實施例中,互補式金氧半導體影像感測器1〇〇 12 1328282 212S7twf,doc/eThe gate structure is j: the gate structure of $: day*2, I according to the structure "sensor" above the type _*: is the weight of the mutual oxygen = the transistor and the selected transistor The open junction of the second type; the second type gate 9 1328282 UMCD-2006-0218 21287twf.doc/e is the gate structure of the other transistor. The complementary MOS image sense according to the embodiment of the present invention The photodiode of the detector is a p-n junction region. The invention further provides a complementary MOS image sensor. The complementary MOS image sensing gf comprises a substrate, a photodiode and a plurality of The n-type transistor, wherein the substrate has a photo sensing region and a transistor region, and the photodiode is disposed in the substrate of the photo sensing region. The plurality of n-type transistors are disposed in the transistor region. On the substrate, wherein the gate structure of the n-type transistor includes a p-type gate structure and a plurality of n-type gate structures, the complementary MOS image sensing benefits according to embodiments of the present invention, The above-mentioned n-type gate structure is a transfer transistor, a reset thunder crystal, and a The gate structure of the body and the selected transistor 3L gate structure is the gate structure of the other transistor. The salty system is made up of the complementary MOS image of the present invention. The shape of the gate structure is a reset transistor 'source coupler is two: the type of electricity _ sensing CMOS image 曰 complementary MOS image sensing 11 is the conventional η type ( P-poly) substitution, because the U-type gate structure can avoid the conventional complementary: the leakage current problem of the gold crystal, so - to cause the noise increase of the read-up; ==== 1328282 UMCD-2006-0218 21287twf The above and other objects, features, and advantages of the present invention will become more apparent and understood. The present invention is applicable to a complementary MOS image sensor having a 3·Τ structure or a 4-Τ structure. However, the present invention is not limited thereto, and the present invention is also applicable to φ other complementary gold having a plurality of transistor structures. Oxygen semiconductor image sensor. FIG. 1 is a complementary gold in accordance with an embodiment of the present invention. Semiconductor shadow • The schematic diagram of the top view of the sensing sensation. The edge of Fig. 2 is a cross-sectional view along the ΑΑ, cross-section of Figure 1. Please also refer to Figure 1 and Figure 2 'Complementary MOS image sensing of 4-Τ architecture The device 100 is composed of a substrate 101, a photodiode 1〇6, a p-type gate structure 108, and a plurality of n-type gate structures 110, 112, 114. The substrate 101 is, for example, a dream substrate or other semiconductor substrate. • An isolation structure 105 is defined in the substrate 101 to define a photo-sensing region 〇2 and a transistor device region 104, such as a shallow trench isolation structure (sti) or other isolation structure. In addition, a 井-type well region 103 is disposed in the substrate 101 of the transistor element region 〇4, and a plurality of n-type transistors (NMOS) are disposed on the 井-type well region 1〇3, and will be thereafter Do a detailed description. The photodiode 106 is disposed in the p-type well region 1〇3 of the photo sensing region 102 and the substrate 101. The photodiode 106 is a ρ-η junction region, which functions as 1328282 UMCD-2006-0218 21287twf.doc/e to receive the light source and convert the light energy into electrical energy. The photodiode 1〇6 may be formed by a P-type substrate of the photo sensing region 102 and an n-type doping region (not shown). The P-type gate structure 108 is disposed on the p-type well region 103 of the transistor element region 1〇4. The p-type drain structure 1〇8 is composed of a p-type polysilicon layer 1〇8& and a dielectric layer 116. The p-type polysilicon layer 1〇8a is used as a p-type gate, (PP〇ly), dielectric layer. 116 is used as a gate oxide layer. In this embodiment, the gate structure in which the P-type gate structure 108 is a transfer transistor (Τχ) is taken as an example. The n-type gate structure is disposed on the P-type well region 103 of the transistor element region 1〇4. Every! ! The gate structure 11〇, 112, 114 is composed of an n-type polysilicon layer 110a, n2a, 114& and a dielectric layer 116, respectively, wherein the n-type polysilicon layer n〇a, 12a, 14a is regarded as an n-type. The gate (n-poly), the dielectric layer 116 acts as a gate oxide layer. In the above, the n-type gate structures 110, 112, and 114 are gate structures of a reset transistor (Rx), a source follower transistor (Dx), and a selection transistor (Sx), respectively. In addition, the complementary MOS image sensor 100 further includes an n-type source/no-polar region 118' which is disposed on the p-type of the n-type gate structures ι10, n2, 114 and the p-type gate structure 108. In the substrate 1〇3. Therefore, a transfer transistor of p-poly NMOS and a reset transistor of n_p〇iy, a source follower transistor and a selection transistor can be formed. The present invention is not limited by the position of the plurality of transistors of the above embodiment, and the positional arrangement is adjusted depending on the circuit design or process requirements. In another embodiment, the complementary MOS image sensor 1 〇〇 12 1328282 212S7twf, doc/e
UMCD-2006-021S 亦可以P型閘極結構108為重置電晶體、源極隨耦器電晶 體與選擇電晶體其中之一的閘極結構,而η型閘極結構 110、112、114是其餘三個電晶體之閘極結構。 當然,在又一實施例中,3-Τ架構之互補式金氧半導 肢衫像感測器的重置電晶體、源極隨轉器電晶體與選擇電 晶體其中之一的閘極結構可以是ρ型閘極結構,而其餘二 個電晶體之閘極結構為η型閘極結構。 如上述實施例,4-Τ架構之互補式金氧半導體影像感 測器中的轉移電晶體為i>-p〇ly NMOS,由於p-p〇ly NMOS 的功函數差(work function different)大於 n_p〇汐 NM〇s 的 功函數差,在元件操作期間,關閉電晶體時,p_p〇ly NM〇s 的轉移電晶體會在基底與閘氧化層界面累積電洞(h〇le),如 此I降低轉移電晶體的漏電流問題。另一方面,開啟電晶 體%τ ’在P-p〇lyNMOS的轉移電晶體下方會產生埋入式通 道(buried channel) ’以降低電荷轉移的阻障,因此有助於 降低漏電流的問題。 以下’列舉二實施例來說明互補式金氧半導體影像感 測器100的製造方法。圖3A至圖3F為依照本發明一實施 例所繪不之互補式金氧半導體影像感測 器的製造方法之流 程剖面示意圖。 首先’請參照圖3A,提供一基底301,基底301例如 疋矽基底或其他半導體基底。在基底301中可形成一隔離 &構303 ’以界定出光感測區3〇2與電晶體元件區3〇4,其 中離結構3 0 3例如是淺溝渠隔離結構或其他隔離結構。 13 1328282 UMCD-2006-0218 21287twf.doc/e 日日肢7M午區304的基底3〇1中 區308。|)型井區308的形成方法 '基㈣上形成-光阻層(未繪示 入d,於電晶體元件區3〇4的基底3〇 他合適之p型摻質,之後再移除掉光阻層。^ (在)ίς 在整個基底301中形成“區 心例中,於Ρ型井區308形成之前,可在 形成一層犧牲氧化層3〇6, 土 -〕上 及進行井區的離子植人製程時受到刪染 除犧口it:,型井區规之後,移 31〇,其材質例如s '土 & 3〇1上形成一層介電層 層未摻雜多晶石夕丨‘石夕。在介電層310上形成— 例如是化學氣相沈積法;0=雜夕晶石夕層312的形成方法 感測區:2 :::圖】。曰’形成-罩幕層314,以覆蓋住光 晶體的區域)的未^夕曰曰體70件區3〇4(即預定形成轉移電 阻層。之後進_:雜多晶石夕層312。罩幕層314例如是光 露出的未摻雜多1丁豸子植入製程,將η型掺質植入所曝 其中,η型摻質η型多㈣316。 於1Χ1014〜5xini5. &(Ρ)或砷(As),n型掺質的劑量介 ^ ion/cm2 之問。 繼之,請參照图 移除罩幕声314 ^ ,在η型多晶矽層316形成之後, 罩幕層3二型多晶麥層训上形成一層 s 318例如是光阻層。接著,進行一離 1328282 UMCD-2006-02] 8 21287twf.doc/e ^直入製程,將?雜質植人曝露㈣未 中,以形成p型多晶矽層320。其令,刑夕日日矽層312 或二氟化硼(BF2),p型摻質的兩摻質例如是硼(B) ion/cm2 之間。 ;1 ; 〜5、xl〇13 隨後’請參照圖3E,在p型多a 移除罩幕層训。然後,定義介電層二、成之後, 與P型多轉層320,以於電晶體 層316 3〇8上形成多個n型閘極結構似、^04之P型井區 極結構322。上述,定義介電層31〇 y28曰與—P型間 P型多晶石夕層320的方法例如是it彳f-彳層316與 其中,P型閘極結構322者作是餹# /知”蝕刎製程。 而鳴結構324、二 隨輕器電晶體及選擇電晶體的閑極】構了置電晶體、源極 盘基於光感測區302之p型井區规 接面區,其形成方法是進行: 為一ρ-η Ρ型井區通巾,以形成之τΛ雜將η型摻質植入 遞^在^二極體33(3形成之後,還包括於Ρ型井區 =====:型源極,一的 之η型捧質植人將植入卿)或其他合適 圖4 A至圖4 F為依照本發明另 式金”導體影像感測器的製造方法Μ二補 百先’凊麥照圖4Α ’提供一基底·,基底4〇1例如 15 !328282 UMCD-2006-0218 21287twf.doc/e 疋石夕基底或其他半導體基底。在基底巾可形成一隔離 結構彻’以界定出光感測區術與電晶體元件區4〇4,其 中隔離結構403例如是淺溝渠隔離結構或其他隔離結構。 然後’在電晶體元件區404的基底4〇1中形成p型井 型井區的形成方法例如是’在光感測區402 、ς & 4〇1上形成-雜層(未㈣),然後進行—離子植 ^程’於電晶體元件區撕的基底中植入石朋或其他 σ k之ρ型摻質’之後再移除掉光阻層。當嫉 是在整個基底401中形成p型井、區。。在另 形:播4,於13型井區408形成之前,可在基底401上 氣化層406 ’以防止基底401表面受到污染 呤播f著’請參照圖4β ’在形成p型井區408之後,移 二隨後,於基底401上形成一層介電層 層未摻雜多晶繼^’在介電層物上形成一 例如是化學氣才目沈積法。备雜夕晶石夕層412的形成方法 然後,請參,明圖 摻質植入未摻雜多晶石夕’ ^丁:離子植入製程,將η型 仙。其中,㈣二層412 _,以形成η型多晶石夕層UMCD-2006-021S may also be a P-type gate structure 108 which is a gate structure of one of a reset transistor, a source follower transistor and a selected transistor, and the n-type gate structure 110, 112, 114 is The gate structure of the remaining three transistors. Of course, in another embodiment, the complementary transistor of the 3-inch structure of the complementary MOSFET is like a reset transistor of the sensor, the source follower transistor, and the gate structure of one of the selected transistors. It may be a p-type gate structure, and the gate structures of the other two transistors are an n-type gate structure. As in the above embodiment, the transfer transistor in the complementary MOS image sensor of the 4-turn structure is i>-p〇ly NMOS, since the work function different of the pp〇ly NMOS is greater than n_p〇 The work function difference of 汐NM〇s, when the transistor is turned off during the operation of the device, the transfer transistor of p_p〇ly NM〇s accumulates a hole (h〇le) at the interface between the substrate and the gate oxide layer, thus reducing the transfer. The leakage current problem of the transistor. On the other hand, turning on the transistor %τ' creates a buried channel under the transfer transistor of the P-p〇lyNMOS to reduce the barrier of charge transfer, thus contributing to the problem of reducing leakage current. Hereinafter, a method of manufacturing the complementary MOS image sensor 100 will be described with reference to two embodiments. 3A-3F are schematic cross-sectional views showing a process of fabricating a complementary MOS image sensor according to an embodiment of the invention. First, referring to Fig. 3A, a substrate 301, such as a germanium substrate or other semiconductor substrate, is provided. An isolation &303' can be formed in the substrate 301 to define the photo-sensing region 3〇2 and the transistor element region 3〇4, wherein the structure 3003 is, for example, a shallow trench isolation structure or other isolation structure. 13 1328282 UMCD-2006-0218 21287twf.doc/e The base 3〇1 mid-region 308 of the Japanese limpode 7M noon zone 304. |) Forming method of well region 308. Forming a photoresist layer on the base (four) (not shown in d, the substrate 3 in the transistor element region 3〇4 is suitable for its p-type dopant, and then removed. The photoresist layer. ^ (in) ς is formed in the entire substrate 301. In the case of the core region, before the formation of the 井-type well region 308, a layer of sacrificial oxide layer 3〇6, soil-] can be formed and the well region can be formed. In the ion implantation process, it is decontaminated except for the sacrifice mouth: after the well pattern, it is moved 31〇, and its material such as s 'soil & 3〇1 forms a dielectric layer undoped polycrystalline stone 'Shi Xi. Formed on the dielectric layer 310 - for example, chemical vapor deposition method; 0 = formation method of the oligolithite layer 312 sensing region: 2 ::: Fig.] 曰 'formation - mask layer 314, to cover the region of the photonic crystal) 70 regions 3〇4 (ie, a transfer resistance layer is formed to be formed. Afterward _: heteropolycrystalline layer 312. The mask layer 314 is, for example, light. The exposed undoped polystyrene seed implantation process is implanted into the exposed n-type dopant, and the n-type dopant is n-type (tetra) 316. On 1Χ1014~5xini5. &(Ρ) or arsenic (As), The dose of n-type dopants Ion/cm2. Then, please refer to the figure to remove the mask sound 314 ^. After the formation of the n-type polysilicon layer 316, the mask layer 3 type 2 polycrystalline layer is formed to form a layer s 318, for example, a photoresist layer. Then, proceed to the process of directing the impurity implants (4) to form the p-type polycrystalline germanium layer 320. The order is 312. Or boron difluoride (BF2), the two dopants of the p-type dopant are, for example, boron (B) ion / cm2. ; 1 ; ~ 5, xl 〇 13 subsequently 'please refer to Figure 3E, in p-type a The mask layer is removed. Then, after the dielectric layer is formed, the P-type multi-transfer layer 320 is formed to form a plurality of n-type gate structures on the transistor layer 316 3〇8, and the P layer is formed. The well region polar structure 322. The method for defining the dielectric layer 31〇y28曰 and the P-type P-type polycrystalline layer 320 is, for example, an it彳f-彳 layer 316 and a P-type gate structure 322 therein. The 作 / / / / / / / / / / / / / / / / / 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 324 District control area, The formation method is carried out: for a ρ-η Ρ type well area towel, to form the τ doping η type dopant is implanted in the ^ diode 33 (after formation of 3, also included in the Ρ type well area = ====: type source, one of the n-type implants will be implanted) or other suitable Figure 4 A to Figure 4 F is a method for manufacturing a gold-like conductor image sensor according to the present inventionΜ二补百先' '凊麦照图4Α' provides a substrate, substrate 4〇1 such as 15 !328282 UMCD-2006-0218 21287twf.doc/e 疋石夕 substrate or other semiconductor substrate. An insulating structure can be formed in the substrate towel to define a photo sensing region and a transistor element region 4, 4, wherein the isolation structure 403 is, for example, a shallow trench isolation structure or other isolation structure. Then, the formation method of forming a p-type well region in the substrate 4〇1 of the transistor element region 404 is, for example, 'forming a hetero layer (not (four)) on the photo sensing region 402, ς & Then, the ion implantation process is performed by implanting a stone or other σ k-type p-type dopant in the substrate of the transistor element region, and then removing the photoresist layer. When 嫉 is a p-type well, a region is formed throughout the substrate 401. . In the other form: broadcast 4, before the formation of the type 13 well 408, the layer 406 ' may be vaporized on the substrate 401 to prevent the surface of the substrate 401 from being contaminated. Please refer to FIG. 4β for forming the p-type well region 408. Thereafter, the second step is followed by forming a dielectric layer on the substrate 401. The undoped polycrystals are formed on the dielectric layer, for example, by chemical gas deposition. Forming the method of preparing the celestial crystal layer 412 Then, please refer to the Mingtu dopant implanted in the undoped polycrystalline stone ’ ̄ ^: ion implantation process, the η type 仙. Wherein, (4) two layers of 412 _ to form an n-type polycrystalline layer
IxlO14〜5><1〇15^貝^如是鱗或碎,―推質的劑量介於 —ιοη/cm2 之間。 、’遽之’请參照圖4D,犯rrl·、 $ . 感測區402以及部分#也成—罩幕層418 ’以曝露出光 晶體的區域)的”/;:=件區4G4(即預定形成轉移電 曰日夕層416,罩幕層418例如是光阻 16 UMCD-2006-0218 2l287twf.doc/« i出的:刑X丁::子植入製程’植入p型摻質,使所曝 T)靜所=Γ 16轉變成P型多晶石夕層420。立中, 〜硼或二氟化心型摻質的劑量介於⑽13 〜2iI£__ion/cm2 之間。 - ^ ^ $ -s- a 、、、 在P型多晶矽層420形成之後, 移除罩幕層418。然後, ^風後 與p型多晶矽展錢層1〇、n型多晶石夕層416 ’、 g ,以於電晶體元件區404之p型井@ 408上形成多個n型閑1干匕U4之P1井區 極結構422。上述,定I :!思426、428與一 P型問 剞少曰々恳 義"电層410、η型多晶矽層416與 Ρ型夕日日矽層420的方法例如η/ 且中,D 疋進行—微影與#刻製程。 二當作是轉移電晶義閘極結構, 以極、’、口構424 ' 426、428當作是重置雨曰雕、祕 隨搞器^晶體及選擇電晶體的開極^ 脰、源極 接者,請參照圖4F,於古式、Β, Γ~ 與基底401中形成 、=感,區402之P型井區桃 垃而戸甘H成先一極體43〇。光二極體430為一 P-n p型井是進行—摻雜製程,將n型摻質植入 P型井£ 408中,以形成之。 同樣地,在光二極體43〇形成之 區408中形成i源極/ 叉 H 戍極£ 440 ° n型源極/汲極區440 =如Γ子植入法’將植入鱗或其他合適之-摻 質植入ρ型井區408中。 綜上所述,本發明是將互補式 中的η型電晶體的η型閘描…, 令_傢以Κ° 於D-poly NMOS的功函數差°少Ρ,閉極結構取代。由 刀口被差大於n-p〇Iy NM〇S的功函數 27 1328282 UMCD-2006-0218 21287twf.d〇c/e 差,在元件操作期間,關閉電晶體時,p_p〇ly NM〇S的電 晶體會在基底與閘氧化層界面累積電洞,如此可降低雷曰 體的漏電流問題。另一方面,開啟電晶體時,在p卞 NMOS的電晶體下方會產生埋入式通道,以降低電荷轉/ 的阻障,因此有助於降低漏電流的問題。 夕IxlO14~5><1〇15^Bei ^If it is scale or broken, the dose of the push substance is between -ιοη/cm2. Please refer to FIG. 4D, and the rr··, the sensing area 402 and the part #also become the mask layer 418 'to expose the area of the photo crystal) "/;:= the area 4G4 (ie, predetermined) Forming a transfer power layer 416, the mask layer 418 is, for example, a photoresist 16 UMCD-2006-0218 2l287twf.doc/« i out: the penalty X:: sub-implantation process implanted p-type dopant, so that Exposure T) Static = Γ 16 is converted into P-type polycrystalline layer 420. In the center, the dose of ~ boron or difluorinated core type dopant is between (10) 13 ~ 2iI £ __ion / cm 2 . - ^ ^ $ -s- a , , , after the formation of the P-type polysilicon layer 420, the mask layer 418 is removed. Then, after the wind, the p-type polycrystalline germanium layer 1 〇, the n-type polycrystalline layer 416 ', g, A P1 well region pole structure 422 of a plurality of n-type idle 1 U4 is formed on the p-type well @ 408 of the transistor element region 404. In the above, I: 思 426, 428 and a P-type 剞 剞The method of the electric layer 410, the n-type polysilicon layer 416 and the Ρ-type solar layer 420, for example, η/ and, D 疋 - lithography and # etch process. Structure, with pole, ', mouth structure 424 ' 426, 42 8 is to reset the rain eagle carving, the secret with the device ^ crystal and select the opening of the transistor ^ 脰, the source of the receiver, please refer to Figure 4F, in the ancient, Β, Γ ~ and the base 401 formed, = Sense, the P-type well area of the area 402 is Taolu and the Gan-H is the first-pole body 43. The photodiode 430 is a Pn-p-well is a doping process, and the n-type dopant is implanted into the P-type well. Similarly, in the region 408 where the photodiode 43 is formed, an i source/cross H is formed in the region 408. The 440 ° n source/drain region 440 = Γ implant method 'Injecting scales or other suitable dopants into the p-type well region 408. In summary, the present invention is to describe the n-type gate of the n-type transistor in the complementary mode. ° The difference in work function of the D-poly NMOS is less than 闭, and the closed-pole structure is replaced by the work function of the knife edge is greater than np〇Iy NM〇S 27 1328282 UMCD-2006-0218 21287twf.d〇c/e difference, in During the operation of the device, when the transistor is turned off, the transistor of p_p〇ly NM〇S accumulates holes at the interface between the substrate and the gate oxide layer, thus reducing the leakage current problem of the Thunder body. On the other hand, when the transistor is turned on, Bian p NMOS transistor below the buried channel is generated in order to reduce charge-to / barrier, thus helping to reduce leakage current problem. Tokyo
雖然本發明已以實施例揭露如上,然其並非用以阳〜 本發明,任何熟習此技藝者,在不麟本㈣之 = 圍内,當可作些許之更動與潤飾’因此本發明之 巳 當視後附之申請專利範圍所界定者為準。 、躞乾圍 .【圖式簡單說明】 _圖1為依照本發明之一 像感測器的上視示意圖。 實施例的互補式金氧半 導體影 、、-曰示為圖1沿AA,剖面線之剖面示 片圖3A至圖3F為依照本發明一實施例所给:、、 金氧半導體景彡像感測H的製造方法之流=之互補式Although the present invention has been disclosed in the above embodiments, it is not intended to be used in the present invention. Anyone skilled in the art may make some modifications and refinements in the absence of the present invention. This is subject to the definition of the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS [Fig. 1 is a top plan view of an image sensor according to the present invention. The complementary oxymethylene film of the embodiment, - is shown in Figure 1 along AA, and the cross-sectional line of the cross-sectional view. Figures 3A to 3F are given according to an embodiment of the present invention: Measuring the manufacturing method of H = complementary
圖4A至圖4F為依照本發明另—實施2圖。 式金氧半導體影像感測器的製造方法之 ^、、胃不之互補 【主要元件符號說明】 王Μ面示意圖。 100 :互補式金氧半導體影像感測器 101、 301、401 :基底 102、 302、402 :光感測區 103、 308、408 : Ρ 型井區 104、 304、404:電晶體元件區 105、 303 :隔離結構 1328282 UMCD-2006-0218 21287twf.doc/e 106、330、430 :光二極體 108、322、422 : p型閘極結構 108a、320、420 :. p型多晶矽層 428 : η 110、112、114、324、326、328、424、426、 型閘極結構 110a、112a、114a、316、416 : η 型多晶矽層 116、310、410 :介電層 118、340、440 : η型源極/汲極區 306、406 :犧牲氧化層 312、412 :未摻雜多晶矽層 314、318、418 :罩幕層 194A through 4F are views showing another embodiment 2 in accordance with the present invention. The method of manufacturing the MOS image sensor is not complementary to the stomach [Description of the main components]. 100: Complementary MOS image sensor 101, 301, 401: substrate 102, 302, 402: light sensing area 103, 308, 408: Ρ type well area 104, 304, 404: transistor element area 105, 303: isolation structure 1328282 UMCD-2006-0218 21287twf.doc/e 106, 330, 430: photodiode 108, 322, 422: p-type gate structure 108a, 320, 420: p-type polysilicon layer 428: η 110 , 112, 114, 324, 326, 328, 424, 426, gate structure 110a, 112a, 114a, 316, 416: n-type polysilicon layer 116, 310, 410: dielectric layer 118, 340, 440: n-type Source/drain regions 306, 406: sacrificial oxide layers 312, 412: undoped polysilicon layers 314, 318, 418: mask layer 19
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