TWI313068B - - Google Patents

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TWI313068B
TWI313068B TW95127667A TW95127667A TWI313068B TW I313068 B TWI313068 B TW I313068B TW 95127667 A TW95127667 A TW 95127667A TW 95127667 A TW95127667 A TW 95127667A TW I313068 B TWI313068 B TW I313068B
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Taiwan
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transparent
solar energy
oxide
conversion device
film
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TW95127667A
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Chinese (zh)
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TW200807736A (en
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Liann Be Chang
Michael Lu
Gwo Mei Wu
A P Chiu
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Chang Gung Universit
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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1313068 九、發明說明: 【發明所屬之技術領域】 本發明係有關一種太陽能電池系統,特別是有關一種透 陽能電池系統。 不 【先前技術】 在石油、煤礦、天然氣等等天然能源日漸短缺的今日, 新型的替代能源便成為相當重要的科技發展目標,同時,為了 免發生重蹈石化材料對環境所造成嚴重污染的覆轍,所尋找^ 代能源材料必須為-種可兼具有高潔淨度、可長久使用等特徵, 因此’取之不盡的太陽能便成為最佳的選擇。 而太陽能電池系統的發展係源自1954年由美國貝爾實驗 首先提出此-技術’至今,雖然已有相當多的太陽能電池系 麵’但仍是多以多晶體⑪、非晶體梦、__、銅銦録二碼、 錫碲薄膜、光敏化祕等材_製成者,社述之材料的共 色係為所製成的太陽能電池系統均為深色且透光率極差之電池系 統,,因此’若欲將現行的太陽能電池系統直接使用树築結構上: 通將具有廣大面積、沉重重量的太陽能電池系統置於鼓 人使用的翻’且-旦·天災,如職、龍捲風時’裝設在^ 頂上的太陽能m制f可能被吹落而造成公眾的危險,而若將 現行的太陽能電池祕取代—般住家的玻朝、窗,磐因為太 陽能電池隸本身的遮光效應,而使得賴物内部缺乏陽光,以 致需耗費更多的照明能源;另外’絲將現行的太陽能電池系統 直接應用在現有的交ifjl具上時,由於為了可提供足夠的能量, 相對於單-個交虹具的整體重量而言,所裝設的太陽能電池系 ,係佔據;了幾乎-半的整體重量,而使得交虹具所需消耗的能 量較未裝設太陽能電池祕之前惟更多。且,—般而言,以上述 之多晶财、非晶解、㈣膜、銅銦鎵u蹄薄膜、光敏 5 1313068 化染料等材料所製成的太陽能電池系統,由於受限於材料本身的 限制’僅能吸收波長落於較長波長範圍内之光線,相對地,使得 可自太陽光能轉換而得電能量的效率始終無法有效地提昇。 許多有關太陽能電池系統的研究,在近年來已大量地在進 行’例如,在我國專利第239657號中係提供一種太陽電池單元及 其模組’請參考第一圖所示,其中,係由任意組合的複數個太陽 電池單元而成,單一太陽電池單元係包含有陽極層61〇、光電轉 換層630、陰極層620以及阻隔層640,陽極層610與陰極層620 φ 挾持光電轉換層630並分別突出於光電轉換層630的邊緣,一個 以上的阻隔層640係設置於光電轉換層63〇的侧邊以封住光電轉 換層630,在利用串聯或並聯的方式連接多個太陽電池單元,來 組成太陽電池模組。然而,上述之技術仍係基於現有之材料,對 於太陽能電池系統的實際應用層面並無法提昇。 基於上述的缺失,本發明係提出―種透明太陽能電池系統, 其係利用不_材_使義太陽能電_統可具有透光的性 質,因而使得透明太陽能電池系統可吸收大量的短波長光源,如: 的吸收,姐,亦由於本發明所提出之義太陽能電池系 =為,此’可|設在各個需要玻璃或是透明隔間的 位置,以k咼太險能源的實用性與便利性。 【發明内容】 本發明之主要目的,係提出—種透明太陽能電池純 可提供一重量輕、結構簡單且可吸 八 長範圍内之光源,例如:紫外波長洛於較短波 旦艎領域,且更可藉由大面積的設置以 相^有助於解決目前太陽能電池難以量化之困難乳產成本 本發明之另-目的’贿出—種透明太陽能m统,主要 1313068 ,結構係為-種兼具有可透光之太陽_換裝置與不 ,量轉換裝置之混成式太陽能轉換裝置。因此,本發明 二=電池系統係可大幅地提高能量轉換的效率,並擴大本^ =之躺’,㈣納嫩太嶋換裝㈣使 為達上述之目的,本發明提供—種透明太陽能電 係包括:-可透光之太陽能轉換I置, =/、 第-電極、-透明光伏元件與一第二電極,其 =可為玻璃、石英、透明歸、Mf石基板或透明可 等4,而透明光伏元件係由透明導電氧彳物 2 7 光伏元件包括有H透明導所第構導= 膜,以第-型透明導電薄膜係為—種透明p型 : ίί: m體材料係包括有:触氧化物、銅鎵氧化物、銅 ί ί=明銅銦氧化物、銅嫩物或銀銦氧化物… 專等的透叫電氧化物材料,同時,第二型翻導㈣膜 :透明Ν型半導體材料,此透明Ν型半導體材料係包括有:氧 料、祕轉、氧化銦錫...等等的透明導電氧化物材 材=可互換。且’上述之所有結構由下往上係 == :電,、第-型透明導電薄膜、第二型透明導電薄膜與第二電極, 故,透過可透光之太陽騎換裝置係可吸收太陽絲巾的波長較 短的光源,例如,其係可吸收光波波長係介在35〇 I米到_夺 ^之間=光源;此外,亦可將上述之可透光之太陽能轉換裝置與 二不可透光之太·轉換裝置相她合以形成—混成式太陽能轉 換裝置,其中’此不透叙太陽能轉換裝置係可由多晶體砍、非 晶體石夕、石夕薄膜、銅銦鎵二砸、編碲薄膜、光敏化染料、_族 化5物或丨ll_V&化合物等材料所構成,故,除了可透過可透光之 1313068 太陽能轉換裝置係可吸收太陽光源中的較短長的光源外,亦可利 用不可透光之太陽能轉換裝置係可吸收太陽光源中其他波長範圍 内的光源。而無論上述單獨的可透光之鴻輯換^或是混成 式的太陽能轉換裝置’鋪由導相與平衡單元、週邊元件電性 連接後,便完成本㈣之透社電池系統,而藉由本發明之 透明太陽能電池祕係可有效轉換太陽光源並產生較有效 電能,並且’ _翻的外觀設計,使得本發明之透明太^ 池系統可取代玻璃或是其他材料的使用,不但可 本,亦不會造成光線阻絕的情形。 -產印之成 底下藉由具體實麵配合朗棚式詳加說明, 解本發明之目的、技術内容、特點及其所達成之功效: ” 【實施方式】 相對於銅銦鎵二砸太陽能電池系統、辦薄膜 統與染料敏化太陽能電池祕在廢棄之後對環境所造成之傷宝',、 :此二I?气同時提供能源且又要降低對於環境的破壞:衝 擊,太“疋一個相當受到重視的目標。然而,目前一陽心 電池之共同特色係皆使_色不透光之材料,因此,絲直接ς 用在現有的生活環境中,係碰多的不便與實際施= 困難。基於此些因素’本發明係揭露—種透明太陽能^ ' 及較具有泛用性的太陽能電池系統 I圖式加I詳㈣之不同的實施態樣,同時,佐以適當 轉二圖二圖 有:一透板 12' 包括 -第二電極142,且透明#件分杜仏〆透月先伙件16以及 161 1313068 料係可使用一般的玻璃、石英 可撓性的材料等等,第1極141與第:以藍寶石基板或是透明 使用導電性良好的金屬,科 ==142之材料則是可 明導電薄膜162之組成皆屬於透明膜⑻與第二型透 的氧化P型半導體、透明的氧化N =物材料,例如:透明 的氧化半導體材料為例,當第 導=,於此係以上述透明 p型半導體材料時,用於翻膜⑹為-種透明 銅銘氧化物、鋼鎵氧化物、銅銳氧料中常見的材料有: ^銅峨物或銀銦氧化物·.·等等的透化物、銅銦氧化 ~ ’第二型透明導電薄膜162列m導電乳化物材料,同 料’此透明n型半導體材料中常見的i料= 透明N型料體材 乳化銦辞、氧化銦錫...等等的透電乳化鋅、氧化錫、 此第一型透明導電薄膜彳電氧化物材料;除此之外, 對換,也就S說,當第—明導電薄膜彳62係可相互 導體材料時,第二型透明導為一種透明N型半 體材料。此外,本發明 、b係可為一種透明P型半導 透明基底12 λ依X序料第陽能轉換裝置10之結構係在 膜上形成第二電極 、最後則疋在第二透明導電薄162 不同的材料特性以靡χ =形成上述每—結構之方法則是可依據 第二電極^而法’·:對於第一電極141與 式以形也而對^為金屬時,則可利用電鍍的方 臈162而言,較^ 3與第二型透明導電薄 之材料可能知’由於除了第一電極141與第二電極142 型透明導電薄膜^光^之外’其他的結構如透明基板12、第-的材料,秋而,^ 弟二型透明導電薄膜啦皆屬於可透光性 第-電極142卻又是位於可透光之太陽能轉換裝 9 1313068 置1〇之整體結構的最頂部,因此,#所使用的電極材料 透光的材料時’為了避免_此—可透光之太陽能轉錄置為扣二 收光源的路徑般可將電極的形狀製作成指狀 故,請繼續參考第二圖與第三圖,其中,第三圖係為本有 梳狀電極之太陽能轉換裝置之俯視圖,其係提供具有梳狀電極 I透光之太陽能轉換裝置1〇。在本實施態樣中,第—電極⑷盘 第-電極142雖以交錯制的方式,然,在其他的實_樣了 第-電極141鮮二電極142之排列方式並不呈現交錯之情 形0 上述皆為有關於本發明之可透光之太陽能轉換裝置之介紹, 然而’若,完成-完整的透明太陽能電池系統,則應將上述之可 ,,之太陽能轉換裝置與儲能裝置、功率調節器、、固定結構裝置· 等等的=衡單元進行電性連接,使得來自太陽能轉換裝置所擷取 到之旎量得以進行進一步地儲存與使用。而上述的太陽能轉換裝 置與平衡單元之間的電性連接,係可透過導線的連接以完成,其 中,導線的材料係可使用銅、銀、金和鋁…等具有高導電性之金 ,。因此,對於本發明之完整的透明太陽能電池系統而言,在其 等效之電路中,可透光之太陽能電池系統10係可視為電源供應, 且其係與電池20與電阻30共同組成一電路,本發明之透明太陽 能電池系統之等效電路圖係如第四圖所示。 此外,本發明更提供一種混成式之太陽能轉換裝置,其係由 可透光之太陽能轉換裝置與不可透光之太陽能轉換裝置共同組合 而成。有關此混成式太陽能轉換裝置之介紹將敘述如下。 請參考第五圖所示,其係為本發明之混成式之太陽能轉換裝 置之外觀示意圖。在此混成式之太陽能轉換裝置5〇中,係將可透 光之太陽能轉換裝置係置1〇於不可透光之太陽能轉換裝置40的 上方,因而使得太陽光源701在經過可透光之太陽能之轉換裝置 1313068 10後,太陽光源701中的部分較短波長的光源在經過可透光之太 陽能轉換裝f 10後’便被吸收並進行能量的轉換,剩下波長較長 的光源702則穿透過可透光之太陽能轉換裝置1〇以進入到不可透 光之太陽月匕轉換裝置40中’藉由不可透光之太陽能轉換裝置4〇 係可吸收波長較長的光源702並進行能量的轉換。 相同地’上述係為侧於本發明之混成式之太陽能轉換裝置 之介紹,然而’若欲完成-完整的混成式太陽能電池系統,則應 將上述之混成式之太陽能轉換裝置與儲能裝置、功率調節器、固 構裝置".料的平衡單搞行f性連接,使得來自太陽能轉 換裝置所擷取到之能量得轉行進—步地儲存與制。而上述的 混成式太陽_難置與平解元之_躲連接,係可透過導 ,的連接以完成,其中,導線的材料係可使關、銀、金和紹… 等具有高導電性之金屬。 ,外㈣本發明之可透光之太陽能電池彡制起始電壓大 從波長350奈米賴0奈米,而在波長500奈米時,對於可透 也系統而言’可見光的透射率在4〇%左右,而紅外 、止农冋、’率約在70%左右,因此,就整體而言,本發明之可透 光之太陽能電池系統的發電效率約達到彳2%。 rii述可知’畲本發明之透明太陽能電池系統係僅以一可 電池系統做為域時,係可_其可透光、重量輕 提供電磁防護之作用…等等的特徵,可以廣泛地 ’卜,μ*冰又f豕、、辦公室、工廠或是交通工具玻璃門、窗的設計 • 細具有簡單 補W成本因此,可藉由大量的應用以提昇 i月G斑」。除此之外,本發明之可透光之太陽能電池系 式之:透光之太陽能電池系統相互配合,以形成一混成 工 匕電池糸統,因此,係可將更廣泛之波長範圍内的光源 11 1313068 ΐίΓ源同時佐以紅外線_節溫度的功能,則 ==光_效報昇至5G%左右,且,此混成式之太陽 ^電^祕巾的不可透光之太陽能電池㈣巾,由於大部分且有 的域長絲’齡:料光,錢人至不可透光之太陽 ^電^統前便已經被可透光之太陽能電池系統吸收,因此,可 ifΐ外光對於不可透光之太陽能電池系統中材料的破壞,以延 長本卷明之混成式之太陽能電池系統的使用壽命。 上所麟㈣實施舰明本發日狀獅,其目的在使孰習 ::二:其他未脫離本發明所揭示之精神所完成之等效ί 飾或修改,仍應包含在以下所述之申請專利範圍中。寻机 【圖式簡單說明】 第一圖為習知之太陽電池單元結構之截面剖視圖。 第=圖為本發明之可透光之太陽能轉換裝置之截面剖視圖。 U圖為為本發明具有梳狀電極之可透光之太陽能轉縣置之俯 第四圖為本發明之可透光之太陽能電池祕之等效電。 第五圖為本發明之混成式之太陽能轉換裝置之外觀示意圖。 【主要元件符號說明】 U 。 610陽極層 612透明導電層 621玻璃 623催化反應層 631染料光敏化層 611玻璃 620陰極層 622玻璃 630光電轉換層 632電解質 640阻隔層 10可透光之太陽能轉換裝置 12透明基板 141第一電極 12 1313068 142第二電極 16透明光伏元件 161第一型透明導電薄膜 162第二型透明導電薄膜 20電池 30電阻 40不可透光之太陽能轉換裝置 50混成式之太陽能轉換裝置 701太陽光源 702波長較長的光源1313068 IX. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a solar cell system, and more particularly to a solar cell battery system. No [previous technology] In the current shortage of natural energy such as oil, coal, natural gas, etc., new alternative energy sources have become a very important scientific and technological development goal, and at the same time, in order to avoid serious pollution caused by petrochemical materials. The energy source that we are looking for must be characterized by high cleanliness and long-term use, so 'inexhaustible solar energy is the best choice. The development of solar cell systems originated from the 1954 American Bell experiment first proposed this technology - so far, although there are quite a lot of solar cell systems - but still more polycrystalline 11, amorphous dreams, __, copper Indium recording two-code, tin-bismuth film, photosensitization secrets, etc. _ Producer, the co-color system of the materials described in the system is a battery system in which the solar cell systems are dark and have poor transmittance. Therefore, if you want to use the current solar cell system directly on the tree structure: the solar cell system with a large area and heavy weight is placed in the drums used by the drums, and the natural disasters, such as the job, the tornado The solar energy system f placed on the top of the ^ may be blown down and cause public danger. If the current solar cell secret is replaced by the glass, the window, and the solar cell, because of the shading effect of the solar cell itself, The lack of sunlight inside the object requires more lighting energy; in addition, 'the current solar cell system is directly applied to the existing IJJ, because in order to provide enough energy, Compared with the overall weight of a single-crossing rainbow, the installed solar battery system occupies almost half of the overall weight, so that the energy required to pay the rainbow is lower than that of the solar battery. Only more before. Moreover, in general, the solar cell system made of the above-mentioned polycrystalline, amorphous, (four) film, copper indium gallium u-hoof film, photosensitive 5 1313068 dye, etc., is limited by the material itself. The limitation 'only absorbs light whose wavelength falls within a longer wavelength range, and the efficiency of the electric energy that can be converted from solar energy can never be effectively improved. Many studies on solar cell systems have been carried out in large numbers in recent years. For example, in the Chinese Patent No. 239657, a solar cell unit and its module are provided. Please refer to the first figure, wherein The plurality of solar cells are combined, and the single solar cell unit comprises an anode layer 61, a photoelectric conversion layer 630, a cathode layer 620, and a barrier layer 640. The anode layer 610 and the cathode layer 620 φ hold the photoelectric conversion layer 630 and respectively Projecting on the edge of the photoelectric conversion layer 630, one or more barrier layers 640 are disposed on the side of the photoelectric conversion layer 63〇 to enclose the photoelectric conversion layer 630, and are connected in series or in parallel to form a plurality of solar cells. Solar battery module. However, the above-mentioned technology is still based on existing materials, and the practical application level of the solar cell system cannot be improved. Based on the above-mentioned deficiencies, the present invention proposes a kind of transparent solar cell system, which utilizes the properties of the solar cell, so that the transparent solar cell system can absorb a large number of short-wavelength light sources. Such as: absorption, sister, also because of the meaning of the solar cell system of the present invention =, this 'can be|located in each position requiring glass or transparent compartment, k p too dangerous energy practicality and convenience . SUMMARY OF THE INVENTION The main object of the present invention is to provide a transparent solar cell that can provide a light source, a simple structure, and a light source that can absorb eight wavelengths, for example, the ultraviolet wavelength is in the field of shorter wavelengths, and The large-area setting can help solve the difficult problem of the current solar cell, which is difficult to quantify. The other purpose of the present invention is to use a transparent solar energy system, mainly 1313068, and the structural system is There is a condensable solar _ change device and a non-quantity conversion device for the hybrid solar energy conversion device. Therefore, the second=battery system of the present invention can greatly improve the efficiency of energy conversion, and expand the lie of the lie, and (4) the reversal of the nano-nano (4). For the above purpose, the present invention provides a transparent solar power. The system comprises: - a light-transmissive solar energy conversion I, = /, a first electrode, a transparent photovoltaic element and a second electrode, which can be glass, quartz, transparent, Mf stone substrate or transparent, etc. The transparent photovoltaic element is composed of a transparent conductive oxygen oxide. The photovoltaic element includes a transparent guide structure, a film, and the first type of transparent conductive film is a transparent p type: ίί: m body material includes : Touch oxide, copper gallium oxide, copper ί 明 copper indium oxide, copper tender or silver indium oxide... Specially permeable electric oxide material, and the second type of transducing (four) film: transparent A germanium-type semiconductor material, the transparent germanium-type semiconductor material includes transparent conductive oxide materials of: oxygen, secret, indium tin oxide, etc. = interchangeable. And 'all of the above structures are from bottom to top ==: electricity, the first-type transparent conductive film, the second-type transparent conductive film and the second electrode, so that the sun can be absorbed through the permeable solar riding device The light source having a shorter wavelength of the silk scarf, for example, the wavelength of the absorbable light wave is between 35 〇 1 m and _ ^ ^ = the light source; in addition, the above-mentioned light-transmissive solar energy conversion device can also be opaque The light-to-light conversion device is combined to form a hybrid solar energy conversion device, in which 'this non-transparent solar energy conversion device can be multiplexed by polycrystalline cleavage, amorphous shi shi, Shi Xi film, copper indium gallium bismuth, braided The film, the photosensitizing dye, the _ group 5 or the 丨ll_V& compound, etc., so that in addition to the permeable light 1313068 solar energy conversion device can absorb the shorter long light source in the solar light source, The use of a non-transmissive solar energy conversion device absorbs light sources in other wavelength ranges in the solar source. Regardless of the above-mentioned separate light-transparent red-switching or hybrid solar-power conversion device, the conductive phase is connected to the balancing unit and the peripheral components, and then the (4) transparent battery system is completed, and The transparent solar cell system of the invention can effectively convert the solar light source and generate more effective electric energy, and the design of the transparent liquid crystal system can replace the use of glass or other materials, not only can be used, but also Does not cause light to block. - The purpose of the invention is to explain the purpose, technical content, characteristics and effects achieved by the specific solid surface in conjunction with the slogan: "Embodiment" Relative to the copper indium gallium germanium solar cell The system, the thin film system and the dye-sensitized solar cell are secretly damaged by the environment after being discarded. ',: The two I gas simultaneously provide energy and reduce the damage to the environment: shock, too A goal that is valued. However, at present, the common features of a Yangxin battery are opaque materials. Therefore, the silk is directly used in the existing living environment, and it is difficult to touch the inconvenience and the actual application. Based on these factors, the present invention discloses a transparent solar energy system and a different embodiment of the solar cell system I with a versatility, and a different embodiment of the method (see Figure 4). : a transparent plate 12' includes - a second electrode 142, and a transparent # piece is divided into a scorpion permeable member 16 and a 161 1313068 material system can use a general glass, quartz flexible material, etc., the first pole 141 and the first: a sapphire substrate or a transparent conductive metal is used, and the material of the group == 142 is a transparent conductive film 162 which is a transparent film (8) and a second type of oxidized P-type semiconductor, transparent Oxidation N = material, for example, a transparent oxidized semiconductor material, when the first conductivity = the above transparent p-type semiconductor material, used for the film (6) is a transparent copper oxide, steel gallium oxide Common materials in copper and copper oxides are: ^Transparent of copper or silver indium oxide, etc., copper indium oxidation~ 'Second type transparent conductive film 162 column m conductive emulsion material, the same Material 'this kind of transparent n-type semiconductor material is common i material = transparent N-type material emulsified indium, indium tin oxide, etc., galvanic emulsified zinc, tin oxide, this first type of transparent conductive film 彳 electrical oxide material; in addition, swap, also S It is said that when the first conductive film 彳 62 is a mutually conductive material, the second type transparent conductive material is a transparent N-type half material. In addition, the present invention, b can be a transparent P-type semi-transparent transparent substrate 12 λ X-ray material, the structure of the solar energy conversion device 10 is formed on the film to form a second electrode, and finally, the second transparent conductive film 162 The different material properties are 靡χ = the method of forming each of the above-mentioned structures can be based on the second electrode ^ method: for the first electrode 141 and the shape is also the same as the metal, then the electroplating can be used In the case of the square 162, a thinner material than the second type and the second type of transparent conductive material may be known as 'other structures such as the transparent substrate 12 except for the first electrode 141 and the second electrode 142 type transparent conductive film. The first material, the autumn, the second type of transparent conductive film is the opaque first electrode 142 but the top of the overall structure of the permeable solar energy conversion device 9 1313068, so When using the material of the electrode material that is transparent to the light, the shape of the electrode can be made into a finger shape, so as to avoid the _ _ _ _ _ _ _ _ _ _ _ _ _ _ And the third picture, wherein the third picture is A top view of a solar energy conversion device of a comb electrode is provided with a solar energy conversion device 1 having a comb-shaped electrode I. In the present embodiment, the first electrode 142 of the first electrode (4) is in an interlaced manner, and the arrangement of the second electrode 142 of the first electrode 141 is not interlaced. All of the above are introductions to the light-transmissive solar energy conversion device of the present invention. However, if the complete-transparent transparent solar cell system is completed, the above-mentioned solar energy conversion device and energy storage device and power adjustment should be adopted. The unit, the fixed structure device, and the like, are electrically connected such that the amount of energy extracted from the solar energy conversion device can be further stored and used. The electrical connection between the solar energy conversion device and the balancing unit can be accomplished by a wire connection, wherein the material of the wire can be made of gold having high conductivity such as copper, silver, gold, and aluminum. Therefore, for the complete transparent solar cell system of the present invention, in its equivalent circuit, the permeable solar cell system 10 can be regarded as a power supply, and it is combined with the battery 20 and the resistor 30 to form a circuit. The equivalent circuit diagram of the transparent solar cell system of the present invention is as shown in the fourth figure. Further, the present invention further provides a hybrid solar energy conversion device which is a combination of a light transmissive solar energy conversion device and a non-transmissive solar energy conversion device. An introduction to this hybrid solar energy conversion device will be described below. Please refer to the fifth figure, which is a schematic view of the appearance of the hybrid solar energy conversion device of the present invention. In the hybrid solar energy conversion device 5, the light-transmissive solar energy conversion device is placed above the non-transmissive solar energy conversion device 40, thereby causing the solar light source 701 to pass through the permeable solar energy. After the conversion device 1313068 10, a part of the shorter wavelength light source in the solar light source 701 is absorbed and converted into energy after passing through the permeable solar energy conversion device f 10, and the light source 702 having a longer wavelength is passed through. The light-transmissive solar energy conversion device 1 进入 enters into the opaque solar enthalpy conversion device 40. The light-transmissive solar energy conversion device 4 can absorb the light source 702 having a longer wavelength and convert the energy. Similarly, the above is an introduction to the hybrid solar energy conversion device of the present invention. However, if the complete hybrid solar cell system is to be completed, the above-described hybrid solar energy conversion device and energy storage device should be The balance of the power conditioner and the solid-state device makes a f-connection, so that the energy extracted from the solar energy conversion device can be transferred and stored in a step-by-step manner. The above-mentioned hybrid solar _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ metal. (4) The light-emitting solar cell of the present invention has a starting voltage of from 350 nm to 0 nm, and at a wavelength of 500 nm, the transmittance of visible light is 4 for the permeable system. 〇% or so, and the infrared, stop farming, 'rate is about 70%, therefore, on the whole, the power generation efficiency of the light-permeable solar cell system of the present invention is about 彳2%. Rii said that the transparent solar cell system of the present invention is only a battery system as a domain, and can be used for light transmission and light weight to provide electromagnetic protection, etc., and can be widely used. , μ* ice and f豕, office, factory or vehicle glass door, window design • thin and simple to make up the cost of W, therefore, can be used to enhance the i-month G spot by a large number of applications. In addition, the light-transmissive solar cell system of the present invention: the light-transmitting solar cell system cooperates with each other to form a hybrid process cell system, thereby enabling a light source in a wider range of wavelengths. 11 1313068 ΐίΓ Source is also equipped with the function of infrared _ section temperature, then == _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Most of the domain filaments are 'aged: light, the sun is not opaque to the sun, and the electricity is absorbed by the permeable solar cell system. Therefore, it can be used for opaque light. Destruction of materials in solar cell systems to extend the useful life of the hybrid solar cell system of this disclosure. The above-mentioned syllabus (4) is implemented in the following: Apply for a patent. Looking for a machine [Simple description of the drawing] The first figure is a cross-sectional view of a conventional solar cell unit structure. Fig. = is a cross-sectional view showing the light-transmissive solar energy conversion device of the present invention. U is a light-transmissive solar energy with a comb electrode according to the present invention. The fourth figure is the equivalent of the transparent solar cell of the present invention. The fifth figure is a schematic view of the appearance of the hybrid solar energy conversion device of the present invention. [Main component symbol description] U . 610 anode layer 612 transparent conductive layer 621 glass 623 catalytic reaction layer 631 dye photosensitization layer 611 glass 620 cathode layer 622 glass 630 photoelectric conversion layer 632 electrolyte 640 barrier layer 10 permeable solar energy conversion device 12 transparent substrate 141 first electrode 12 1313068 142 second electrode 16 transparent photovoltaic element 161 first type transparent conductive film 162 second type transparent conductive film 20 battery 30 resistance 40 non-transmissive solar energy conversion device 50 hybrid solar energy conversion device 701 solar light source 702 long wavelength light source

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Claims (1)

13130681313068 修正本 申請專利範園 1·一種可透光之太陽能轉換裝置,包括: 一透明基板; 一第一電極,其係形成於該透明基板上; -透明光伏it件,其係形成於該第-電極上,該透 係由透明導電氧化物所組成,且該透明光伏元件係包括: 牛 一第一型透明導電薄膜,其係形成於該第一電極上; 上「ίΐ型透明導電薄膜’其係形成於該第一型透明導電薄膜 一第二電極,其係形成於該透明光伏元件上。 „申請專利範圍第1項所述之可透光之太陽能轉換 复 型透明導電薄膜係為透明ρ型半導體薄膜,則該第1透明 係為透明Ν型半導體薄膜;或該第一型透明導電薄 導料導體薄膜,則該第二透明導電_係為透明Ρ型半 專2項所述之可透光之太陽能轉換裝置,其中, 物、鋼銳氧化t H膜之材質係選自於銅銘氧化物、銅鎵氧化 氧化物等咖導電錄、_祕物、敏氧化物或銀銦 =2專=範導m項所述之可透光之太陽能轉換裝置,其中, 鋅、氧化銦錫等透明導選自於氧化鋅、氧化錫、氧化銦 5. 如申請專利範圍笛4 該透明基板之材皙^項所述之可透光之太陽能轉換裝置,其中, 板或透明可撓性村^可選自於玻璃、石英、透明塑膝、藍寶石基 6. 如申請專利範圍坌 該第-電極係為透所述之可透光之太陽能轉換裝置,其中, 14 1313068 ---- 产工㈣叫(更)正替換頁 修正本 置,其中 述之可透光之太陽能卿 以—述透光之太陽,轉換裝置,其中’ 該第=====光之雜轉換裝置’其中, m可透光之太 震置係包^:透光之太陽讀触置,每—該可透光之太陽能轉換 —透明基板; :第-電極=其係位在該透板上; 由透明透綠在該電極上,該翻絲元件係 化物敝成,且贿日絲伏元件係包括: —1_里透明導電薄膜,其係位在該第-電極上; 上;1透踢電薄膜,其係位在該第-型透明導電薄膜 極1其係位在該透狀伏元件上;以及 轉換裝其係彻至少—導線以無可透光之太陽能 項所述之可透光之太陽能儲料統,其 膜係為半該第—型透明導電^ 型半導體_。 1該第二透電薄難為透明P 撕述之可透光之太陽能雛系統,其 』路乳化物銅銦乳化物、銅釔氧化物或銀 15 月L (更;正替換頁 修正本 l3l3〇68 鋼氧化物等透明導電氧化物。 化鱗售銦電之=剛於氧化鋅、氧化錫、氧 1 中4.5月二^二二項所述之可透光之太陽能儲能系統’其 石基板材^可選自於賴、石英、透卿、藍寳 物級概鍋統,其 級鳩糊統,其 销叙可透光之太陽雜齡統,其 狀。X料係為不翻電極,且其形狀係為指狀、網狀或梳 1 中第2項所述之可透光之太陽能儲能系統,其 狀。W -料係為不透明_,且其形狀係為指狀、網狀或梳 19·如申ϋ利巧第1Q項所述之可透光之太陽能儲能系統 Γ 太陽轉魏置佩有電磁防護。 中所ί之可透光之太陽能儲能系統,其 〇. 括儲鲍裝置、功率調節器、固定結構裝置。 麻刪統,其 述能, 23.—種混成式太陽能轉換裝置,包括: 至夕可透光之太陽此轉換裝置,每一該可透光之太陽能轉換 i ' 1 " __ %年修(更)正替換頁 修正本 1313068 裝置係包括: 一透明基板; 一第一電極,其係位在該透明基板上; 一透明光伏元件,其係位在該第一電極上,該透明光伏元件係 由透明導電氧化物所組成,且該透明光伏元件係包括: 一第一型透明導電薄膜,其係位在該第一電極上; 一第二型透明導電薄膜,其係位在該第一型透明導電薄膜 上; ^ 一第二電極,其係位在該透明光伏元件上;以及 陽处至μ!一壯不可透光之太陽能轉換裝置’其係設置於該可透光之太 換裝置之下方’以接收穿透過該可透光之太陽能轉換裝置 之无綠。 專利範圍第23項所述之混成式太陽能轉換裝置,其中, ί電電薄膜係為透明p型半導體薄膜,則該第二透明 ^迦係為翻_半導體或 成式场能轉鮮置,其中, --,^::y 氧化物等透日釋電氧化物。 峰職触減物或銀銦 織崎繼,其中, 辞、氧化銦錫等透 辞 '氧化鎮、氧化銦 板或透明可繞性材料。^、破璃、石英、透明塑膠、藍寳石基 1313068 I牌ι月w修(更)正替換i 修正本 28.—種混成式太陽能電池系統,包括: 至夕一可透光之太陽能轉換裝置’每一該可透光之太陽能轉換 裝置係包括: 一透明基板; 一第一電極,其係位在該透明基板上; 、一透明光伏元件,其係位在該第一電極上,該透明光伏元件係 由透明導電氧化物所組成,城透明光伏元件係包括: 二第一型透明導電薄膜,其係位在該第一電極上;The invention discloses a solar energy conversion device capable of transmitting light, comprising: a transparent substrate; a first electrode formed on the transparent substrate; - a transparent photovoltaic element formed on the first On the electrode, the transmissive system is composed of a transparent conductive oxide, and the transparent photovoltaic element comprises: a bovine-type first transparent conductive film formed on the first electrode; and a "ΐ-type transparent conductive film" Formed on the first type of transparent conductive film, a second electrode, which is formed on the transparent photovoltaic element. „The transparent light-transmissive transparent conductive film described in claim 1 is transparent ρ. The first transparent film is a transparent germanium type semiconductor film; or the first transparent conductive thin conductive film film is made of a transparent germanium type semi-specialized item The light-transmissive solar energy conversion device, wherein the material of the steel and the sharply oxidized tH film is selected from the group consisting of copper oxide oxide, copper gallium oxide oxide, etc., _ secret, sensitive oxide or silver indium = 2 Special = The light-transmissive solar energy conversion device according to the item m, wherein zinc, indium tin oxide, and the like are transparently selected from the group consisting of zinc oxide, tin oxide, and indium oxide. 5. As claimed in the patent scope, the transparent substrate is 皙The permeable light-transmissive solar energy conversion device, wherein the plate or the transparent flexible member is selected from the group consisting of glass, quartz, transparent plastic knee, and sapphire base. 6. The scope of the application is 第Through the said opaque solar energy conversion device, wherein, 14 1313068 ---- the production worker (four) is called (more) positive replacement page correction of the device, wherein the opaque solar energy is said to , conversion device, wherein 'the first =====light miscellaneous conversion device', wherein m can be transmitted through the shocking package ^: light transmissive solar reading, each - the light transmissive solar energy conversion - a transparent substrate;: a first electrode = its position on the transparent plate; a transparent transparent green on the electrode, the turned element is formed, and the bristle element comprises: - 1_ transparent a conductive film which is tied to the first electrode; an upper; a transflective film The first type-type transparent conductive film electrode 1 is positioned on the transparent element; and the conversion device is adapted to at least the wire to be permeable to the solar energy storage system as described in the non-transmissive solar energy item. The film system is a semi-type transparent conductive type semiconductor. 1 The second electro-optical thin film is difficult to be transparent P to tear the opaque solar energy system, its road emulsion copper indium emulsion, copper bismuth oxide or silver 15 L (more; positive replacement page revision lll3〇 68 Transparent oxide oxides such as steel oxides. Ingots sold in indium = just in the zinc oxide, tin oxide, oxygen 1, the light-transmissive solar energy storage system described in the second paragraph of the second paragraph The plate ^ can be selected from the Lai, Quartz, Trans-Qing, and Blue Treasure-level pots, and its grades are succinct, and its sales are transparent to the sun, and its shape is X. The shape is a light-transmissive solar energy storage system as described in item 2 of the finger shape, the mesh shape or the comb 1. The W-material system is opaque _, and its shape is a finger shape or a mesh shape. Or comb 19· such as the light-transmissive solar energy storage system described in the 1st item of Shenli Liqiao Γ The sun is turned to have electromagnetic protection. The solar energy storage system of permeable light, including Abalone storage device, power conditioner, fixed structure device. Ma Buduan, said energy, 23.-mixed solar energy conversion device, package : The sun can illuminate the sun, this conversion device, each of the opaque solar energy conversion i ' 1 " __ % year repair (more) is replacing the page correction 1313068 device system includes: a transparent substrate; a first An electrode that is ligated on the transparent substrate; a transparent photovoltaic element that is tied to the first electrode, the transparent photovoltaic element is composed of a transparent conductive oxide, and the transparent photovoltaic element includes: a transparent conductive film which is tied to the first electrode; a second transparent conductive film which is tied to the first transparent conductive film; ^ a second electrode which is tied to the transparent photovoltaic element And the solar energy conversion device 'which is disposed below the permeable translating device' to receive the green light that has passed through the permeable solar energy conversion device. The hybrid solar energy conversion device according to Item 23, wherein the second electro-optical film is a transparent p-type semiconductor film, and the second transparent film is turned into a semiconductor or a semiconductor field. --, ^::y oxides and other anti-daily discharge oxides. Peak duty reduction or silver indium weaving, in which, words, indium tin oxide, etc. through the word 'oxidation town, indium oxide plate or transparent can be wound Material. ^, broken glass, quartz, transparent plastic, sapphire base 1313068 I brand ι月 w repair (more) is replacing i Amendment 28. A hybrid solar cell system, including: The solar energy conversion device includes: a transparent substrate; a first electrode that is tied to the transparent substrate; and a transparent photovoltaic element that is tied to the first electrode The transparent photovoltaic component is composed of a transparent conductive oxide, and the transparent photovoltaic component comprises: a first transparent conductive film, which is tied to the first electrode; 一第二型透明導電薄膜’其係位在該第一型透明導電薄膜 上; -=二電極’其餘在該翻光伏元件上; 不可透光之太陽能轉換裝置,其係設置於該可透光之太 夕裝置之下方,以接收穿透過該可透光之太陽能轉換裝置 之九線,以及 換單A ’其係利用複數導線以與該可透光之太陽能轉 不可透光之太陽能轉換裝置電性連接。a second type of transparent conductive film 'which is tied to the first type of transparent conductive film; -= two electrodes' remaining on the turned-off photovoltaic element; a non-transmissive solar energy conversion device, which is disposed in the light transmissive Below the Taixi device, to receive the nine lines that have passed through the permeable solar energy conversion device, and to change the order A', which utilizes a plurality of wires to electrically switch to the opaque solar energy opaque solar energy conversion device. Sexual connection. 該第-圍第28項所述之混成式太陽能電池系統,其中, Ϊ電薄腺mi電薄膜係為透明P型半導體薄膜,則該第二透明 為透明N型半^2半導體薄膜;或該第—型透明導電薄膜係 導體薄膜。體相’則該第二透明導電薄麟為透明P型半 第29項所述之混成式太陽能電池祕,其中, 物、銅魏化物’膜之材㈣選自於她氧化物、銅鎵氧化 氧化物等透絡氧化物、銅銦氧化物、航氧化物或銀銦 31 "in由上士 _ 化物0 該透明第29項所述之混成式太陽能電池系統,其中, 體溥膜之材質係選自魏化鋅、氧化錫、氧化鋼 修正本 1313068 |^7月7^]修(文)正替澳賀;' -一一.. ..丨 _ Λ .丨 _j • 鋅、氧化銦錫等透明導電氧化物。 32_如申請專利範圍第28項所述之混成式太陽能電池系統,其中, 該透明基板之材質係可選自於玻璃、石英、透明塑膠、藍寶石基 板或透明可撓性材料。The hybrid solar cell system according to Item 28, wherein the thin electric thin film is a transparent P-type semiconductor film, and the second transparent is a transparent N-type semiconductor film; or The first type transparent conductive film is a conductor film. The bulk phase is the second transparent conductive thin lining which is a hybrid P-type solar cell of the P-type half item 29, wherein the material, the copper-Wide compound film (four) is selected from the group consisting of oxides and copper gallium oxide. Oxide oxide such as oxide, copper indium oxide, aerospace oxide or silver indium 31 "in by sergeant _ _ 0. The transparent solar cell system described in the 29th item, wherein the material of the ruthenium film It is selected from the group consisting of Wei Zinc, Tin Oxide, and Oxidized Steel. This 1313068 |^July 7^] repair (text) is for the sake of Australia; '-一一.. ..丨_ Λ .丨_j • Zinc, oxidation A transparent conductive oxide such as indium tin. The hybrid solar cell system of claim 28, wherein the material of the transparent substrate is selected from the group consisting of glass, quartz, transparent plastic, sapphire substrate or transparent flexible material. 1919
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