1301796 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種「可生物分解的環保墊體構造及其製法」，特別是指一 種具有多功能特性的環保墊體構造及其製法，甚至於還能與土壤中之微生物菌 種直接產生生物分解作用，以在自然環境下分解成細微碎片至完全消失為止。 【先前技術】1301796 IX. Description of the Invention: [Technical Field] The present invention relates to a "biodegradable environmentally-friendly cushion structure and a method of manufacturing the same", and more particularly to an environmentally-friendly cushion structure having a multi-functional characteristic and a method for producing the same, and even It can also directly produce biodegradation with microbial strains in the soil to decompose into fine fragments in the natural environment until it completely disappears. [Prior Art]
由於石油化學材料（如塑膠，p V C )用途的廣泛且普及，因此隨之而來 的大量塑膠固體垃圾乃成為環境污染的隱憂。據美國蓋洛普公司的調查，西元 2000年美國城市的固體垃圾量約2.16億噸，其中廢棄塑膠即占了 9.8 % (按 體積計算則更高達30 %以上），台灣更高達15%，對於環境生態而言實是一 大傷害。 目前，具有複合功能的墊體製作技術，係能做出供止滑墊（網）、運動墊、 瑜珈墊、地墊及幼兒學步墊等等來用的墊體，其產品特性皆著重於其耐久性及 韌性，且以長時間持續保持其功能性為目標，因此，墊體的構成多以百分之百 的耐久材料為主，造成其中多含有有毒物質如重金屬Heavy Metals、酚 Phenol、AZO Dyes 偶氮顏料、Cadmium 鎘、Vinyl Chloride Monomer ( VCM ) 乙烯氯化物單體、Nonylphenol氛或Organlctln有機鍚等等，故造成此類廢 棄物在丟棄後對於環境的衝擊可達干年之久。 而造成此類多功能墊體會含有有毒物質的原因，多源自於習知之主要原料 一一一可塑劑，一般習知的可塑劑中必含有鄰苯二甲酸類之物質，而含有此類有 毒物的可塑劑種類就幾乎含括了市面上可塑劑需求量的百分之九十以上，其主 要原因在於鄰苯二甲酸類物質可令塑膠製品於加工過程中柔軟易彎曲成形，所 以，雖然此類可塑劑已被國際間統一認可為含有有害物質’但因價格低廉且易 於製造，所以仍為全球塑膠產業大量運用。 1301796 所述的百分之九十以上的可塑劑種類（含鄰苯二甲酸類）包含： BBP 鄰苯二甲酸苯（benzyl phthalate) . DBP鄰苯二甲酸二丁酯 DEHP 鄰苯二甲酸二（2-乙基乙基）酯（D1(2-ethylhexyl)phtha]ate) DINP 鄰苯二甲酸二異壬酯（Dllsononl phthalate) D0P 鄰苯二甲酸二辛酯（D1-0ctyl Phthalate) DN0P 鄰苯二甲酸二辛酯（DI-N-OCTYL PHTHALATE)Due to the widespread and widespread use of petrochemical materials (such as plastics, p V C ), the large amount of plastic solid waste that comes with it has become a concern for environmental pollution. According to a survey by Gallup in the United States, the amount of solid waste in US cities in 2000 was about 216 million tons, of which waste plastics accounted for 9.8% (up to 30% by volume), and Taiwan was as high as 15%. Environmental ecology is really a big injury. At present, the pad body manufacturing technology with composite function is capable of making a pad body for a sliding pad (mesh), a sports pad, a yoga mat, a floor mat, a toddler toddler pad, etc., and the product characteristics are all focused on Its durability and toughness, and the purpose of maintaining its functionality for a long time, therefore, the composition of the mat is mostly based on 100% durable materials, causing many of them to contain toxic substances such as heavy metal Heavy Metals, Phenol Phenol, AZO Dyes Nitrogen pigments, Cadmium cadmium, Vinyl Chloride Monomer (VCM) ethylene chloride monomer, Nonylphenol atmosphere or Organlctln organic hydrazine, etc., so that the waste can be environmentally impacted after being discarded for many years. The reason why such multifunctional mats contain toxic substances is mostly derived from the well-known main raw materials, plasticizers. Generally, the plasticizers must contain phthalic acid substances, and such The plasticizer type of poison contains almost 90% of the demand for plasticizers on the market. The main reason is that phthalic acid can make plastic products soft and flexible during processing, so although Such plasticizers have been internationally recognized as containing hazardous substances, but they are still widely used in the global plastics industry because of their low price and ease of manufacture. More than 90% of the plasticizer types (including phthalates) described in 1301796 include: BBP benzyl phthalate. DBP dibutyl phthalate DEHP phthalic acid II 2-Ethylethyl) ester (D1(2-ethylhexyl)phtha]ate) DINP Dioxononl phthalate D0P Dioctyl Phthalate (D1-0ctyl Phthalate) DN0P O-Benzene Dioctyl formate (DI-N-OCTYL PHTHALATE)
D0A鄰苯二甲酸二（2-乙基）已酸酯 NBS硬脂酸丁酯 T0TM偏苯三酸三辛酯 另外，若為了達到環保要求而使用環保材料（例如：環保高分子聚酯類可 塑劑Dloctyl alcohol ester，以及天然高分子聚合物（例如澱粉、纖維素等 等天然高分子聚合物Polymer-natural)時，由於以該等環保材料為主體的加 工性都不如習知（即前段所述之含有毒物質之可塑劑）一般可塑劑甚多，因此 在設備控制上，除了系統本身的規劃設定之外，製程中間及後段的相關品質控 制系統之操作及把關更為重要。 因此，如何設計一種具有有益於環境生態以及具有生物可分解特性，並仍 保有一般塑膠使用特性的墊體，乃為本案創作人所欲行克服、解決的一大課 題，以符合未來世界發展趨勢對於環保之需求。 【發明内容】 本發明所提供之可生物分解的環保墊體構造及其製法，藉由特殊的材質及 製法等，以製造出具有多功能效用且還能於丟棄、並經掩埋於土壤中經過〜定 時間之後，透過墊體本身所含有的天然高分子聚合物之營養源來與土壤中之微 6 1301796 生物菌種直接產生生物分解作用（biodegradable)，以在自然環境下以及一定 時間内分解成細微碎片，直至完全消失為止，藉此乃可以減少對於環境之負 擔，確具環保功效。 為解決Jz述諸問題，本發明係在提供一種可生物分解的環保墊體構造，其 包括= 一中央網布，其具有一上表面及一下表面；以及D0A bis(2-ethyl) phthalate phthalate NBS butyl stearate T0TM trioctyl trimellitate In addition, if environmentally friendly materials are used in order to meet environmental requirements (eg environmentally friendly polymer polyester plastic) Dloctyl alcohol ester, as well as natural high molecular polymers (such as starch, cellulose, etc.), the processing properties based on these environmentally friendly materials are not as conventional (ie, as described in the previous paragraph) The plasticizer containing toxic substances) generally has a lot of plasticizers. Therefore, in addition to the planning of the system itself, the operation and control of the relevant quality control system in the middle and the back of the process are more important in the control of the equipment. Therefore, how to design A cushion body that is environmentally friendly and biodegradable, and still retains the characteristics of general plastic use, is a major problem that the creators of the case want to overcome and solve in order to meet the needs of the future world development trend for environmental protection. SUMMARY OF THE INVENTION The biodegradable environmentally-friendly cushion structure and method for the same according to the present invention are manufactured by a special material and system. Etc., in order to produce a nutrient source with a multi-functional effect that can be discarded and buried in the soil for a certain period of time, through the natural high-molecular polymer contained in the mat itself, and the soil in the micro 6 131796 The biological strain directly produces biodegradable, which is decomposed into fine fragments in a natural environment and for a certain period of time until it disappears completely, thereby reducing the burden on the environment and ensuring environmental protection. The problem is that the present invention provides a biodegradable eco-friendly cushion structure comprising: a central mesh having an upper surface and a lower surface;
至少一高分子聚合原料層，係佈設於該中央網布之上下兩表面的其中一表 面’且該高分子聚合原料層係以預定配方所配製而成，其主要係以大比例配置 之高分子天然材料、環保高分子聚酯類可塑劑⑴]octyl alcohol ester)以及 聚氯乙烯所構成。 本發明另提供一種可生物分解的環保墊體製法，其步驟包括： 提供且整平一中央網布，並連續輸出該中央網布； 穿設該中央網布於兩滾輪之間，以傳送該中央網布； 披覆按預定配方配置之高分子聚合原料於該中央網布上； 熱烘該中央網布至高分子聚合原料發泡或硬化；及 冷卻該中央網布以緊實該高分子聚合原料。 【實施方式】 本發明係提供一種可生物分解的環保墊體構造及其製法，其係以聚酯纖維 或天然織材作為支撐骨材，再以預定配方製作的高分子聚合原料（以下簡稱 PER原料）予以披覆之，透過儲有高分子聚合原料的披覆裝置以及内建例如風 壓機的加壓裝置，以分別進行分配覆料、施壓塗佈、高溫乾燥及瞬時降溫緊實 1301796 等步驟，藉以製得該可生物分解的環保墊體。 惟由於所使用的高分子聚合材料（例如澱粉、纖維素等等天然高分子聚合 物Polymer-natural )，並不具有如同塑膠之高度可塑性，且其本身之物性以 及成品使用性的控制更是無法與塑膠材料相比擬，因此，須透過其物性之配比 轉換以及製程之嚴密設定與控管，方得製出本發明—可生物分解的環保墊體 (例如止滑墊、止滑網、運動墊、瑜咖墊、地墊或幼兒學歩墊等等）。At least one polymerized raw material layer is disposed on one surface of the lower surface of the central mesh, and the polymerized raw material layer is prepared by a predetermined formula, and the polymer is mainly disposed in a large proportion. Natural materials, environmentally friendly polymer plasticizer (1)] octyl alcohol ester) and polyvinyl chloride. The invention further provides a biodegradable environmental protection pad system method, the method comprising: providing and leveling a central mesh cloth, and continuously outputting the central mesh cloth; and inserting the central mesh cloth between the two rollers to transmit the central portion a mesh cloth; coating the polymerized raw material disposed in a predetermined formula on the central mesh; thermally drying the central mesh to foam or harden the polymerized raw material; and cooling the central mesh to compact the polymeric raw material . [Embodiment] The present invention provides a biodegradable environmentally-friendly cushion structure and a method for producing the same, which is a polymer polymerization raw material prepared by using a polyester fiber or a natural woven material as a supporting aggregate and then prepared by a predetermined formula (hereinafter referred to as PER). The raw material is covered, and the coating device containing the polymerized raw material and the pressurizing device such as a wind press are built in, respectively, to carry out the distribution coating, the pressure coating, the high temperature drying, and the instantaneous cooling and firming 1301796 The steps are taken to obtain the biodegradable eco-friendly mat. However, due to the use of polymeric materials (such as starch, cellulose and other natural polymer Polymer-natural), it does not have the same high plasticity as plastic, and its own physical properties and control of the usability of the finished product are even more impossible. Compared with plastic materials, it is necessary to produce the present invention - biodegradable environmentally friendly mats (such as anti-slip mats, anti-slip nets, sports) through the conversion of physical properties and the strict setting and control of the process. Pads, yoga mats, floor mats or toddlers, etc.).
請参閱第一圖所的製造π意圖，其製造步驟包括：a、先提供一中央拉 力支撐材，此支撐材可視之為網布（此網布材質之構成可為聚酯纖維之高分子 聚合物，或黃麻（JUTE )、棉、竹碳等天然植物纖維）。b、再提供至少兩滾輪 21、22，其轉動方向相同，且轉速可獨立控制，藉以利於調整網布平整度，該 中央網布11係穿設於該兩滾輪21、22之間，以達到傳送該中央網布11之功 效。c、接著透過裝填有高分子原料的上（下）塗佈機31 (或32)，披覆按預 定配方配置之高分子聚合原料12於已整平之該中央網布11之上以形成半成 品，其中，該上（下）塗佈機31 (或32)係於該中央網布11上下兩表面的至 少其中一表面上設置，而經過塗佈機之送料輪的均勻供料，可使半成品之外觀 及整體構造較為均勻。d、提供一具有預定高溫之熱烘區4來進行乾燥，且係 加熱至該高分子聚合原料發泡或硬化，該熱烘區4包括設置於該半成品上下表 面之高溫單元41和超高溫單元42，該兩單元41、42係可為紅外線燈管加熱 器：此外該預定高溫係控制在攝氏150至220度為主之溫度。e、提供一瞬時 降溫之低溫區5以緊實該高分子聚合原料，該低溫區5係提供以攝氏5度為主 之預定低溫，藉此乃能完成本發明之環保墊體1。f、將該已冷卻緊實之環保 墊體1，透過裁斷機61及自動計數器62之設定運作，以直接裁切成片狀墊體 63。 請參閱第二圖所示，該環保墊體1係包含：具有上下兩表面之中央網布 11、以及佈設於該中央網布11之上下兩表面之高分子聚合原料層12、13;其 1301796 中’該高分子聚合原料層12、13係以預定配方所配製而成，且該預定配方主 要係以大比例配置之高分子天然材料、環保高分子聚酯類可塑劑⑴1〇ctyl alcohol ester)以及聚氯乙烯所構成。Please refer to the manufacturing concept of π in the first figure. The manufacturing steps include: a. First, provide a central tension support material. The support material can be regarded as a mesh cloth. The mesh material can be a polymer of polyester fiber. Polymer, or natural plant fiber such as jute (JUTE), cotton, bamboo carbon). b, further providing at least two rollers 21, 22, the rotation direction is the same, and the rotation speed can be independently controlled, thereby facilitating adjustment of the flatness of the mesh cloth, the central mesh 11 is threaded between the two rollers 21, 22 to achieve The effect of the central mesh 11 is transmitted. c. Next, through the upper (lower) coater 31 (or 32) loaded with the polymer raw material, the polymerized raw material 12 disposed in a predetermined formulation is coated on the centered mesh 11 which has been leveled to form a semi-finished product. Wherein the upper (lower) coater 31 (or 32) is disposed on at least one of the upper and lower surfaces of the center mesh 11 and the semi-finished product can be uniformly supplied through the feeding wheel of the coater. The appearance and overall structure are relatively uniform. d. providing a hot drying zone 4 having a predetermined high temperature for drying and heating to the polymerized raw material for foaming or hardening, the hot drying zone 4 comprising a high temperature unit 41 and an ultrahigh temperature unit disposed on the upper and lower surfaces of the semifinished product 42, the two units 41, 42 can be infrared tube heaters: in addition, the predetermined high temperature is controlled at a temperature of 150 to 220 degrees Celsius. e. Providing a low temperature zone 5 for instantaneous cooling to compact the polymerized raw material, the low temperature zone 5 providing a predetermined low temperature mainly at 5 degrees Celsius, whereby the eco-friendly mat 1 of the present invention can be completed. f. The cooled and compacted green mat 1 is operated by the setting of the cutting machine 61 and the automatic counter 62 to directly cut into the sheet-like cushion body 63. Referring to the second figure, the eco-friendly mat 1 comprises: a central mesh 11 having upper and lower surfaces, and a polymeric material layer 12, 13 disposed on the upper surface of the central mesh 11; 1301796 The polymer polymerization raw material layers 12 and 13 are prepared by a predetermined formulation, and the predetermined formulation is mainly a polymer natural material and an environmentally-friendly polymer polyester plasticizer (1) 1〇ctyl alcohol ester which is disposed in a large proportion. And composed of polyvinyl chloride.
其中，所述的高分子聚合材料係包括至少兩種構成，茲分述如后：其一、 主要由高分子聚酯類可塑劑（Dloctyl alcohol ester)加上聚氯乙烯（pvc) 以及天然高分子聚合物（Polymer-natural，其可為植物膠質、纖維素、或澱 粉）所構成：其二、主要以天然高分子聚合物（P〇]ymer—natura]，其可為植 物膠質、纖維素、或澱粉）為主，再以多元醇（p〇ly〇l )及異氫酸鹽（]s〇cyanate) 或丙烯酸樹酯（Acrylic resin )交鏈（cross-linking )反應，或與聚烯系原 料TP0、TPV (屬於熱塑性彈性體Thermoplastic Elastomer，簡稱TPE之類型 之一）混鏈（ mixing )反應而成。是以，該高分子聚合材料具備之環保債値在 於不含有毒物質’如AZO Dyes偶氮顏料、Cadmium鎘、vinyl Chloride Monomer ( VCM)乙烯氯化物單體、Nonylphenol氛、或Organlctln有機鍚 等等，且還能具有生物可分解功能。 綜上所述，本發明提供之可生物分解的環保墊體構造及其製法，係具有下 述優點：（一）所製成的墊體可作為一般多功能之使用，包括運動用墊、ifi加 墊、幼兒學步墊、止滑地墊及止滑網等等；（二）所製成的墊體於丟棄、並糸至 掩埋於土壤中經過一定時間之後，係可透過墊體本身所含有的天然高分 物之營養源來與土壤中之微生物菌種直接產生生物分解彳乍 (biodegradable)，以在自然環境下以及一定時間内分解成細微碎片，直至完 全消失為止，藉此乃可以減少對於環境之負擔，確具環保功效。 以上所述僅為本發明之較佳可行實施例，非因此即拘限本發明之專利範 圍，故舉凡應用本發明說明書或圖式内容所為之等效變化，均同理皆包含於本 發明之範圍内，以保障發明者之權益，於此陳明。 1301796 【圖式簡單說明】 第一圖為本發明環保墊體之製造方法的製作示意圖 第二圖為本發明環保墊體之構造的示意圖 【主要元件符號說明】 [本發明] 環保墊體 1 中央網布 11 高分子聚合原料（層）12、13 滾輪 21、22 上（下）塗佈機31 (或32) 4 熱烘區 高溫單元 41 超局溫早兀 42 低溫區 5 裁斷機 61 自動計數器 62 片狀墊體 63 10Wherein, the polymer material comprises at least two compositions, and is described as follows: first, mainly by a polymer polyester plasticizer (Dloctyl alcohol ester) plus polyvinyl chloride (pvc) and natural high. Molecular polymer (Polymer-natural, which can be plant gum, cellulose, or starch): Second, mainly natural polymer (P〇] ymer-natura], which can be plant gum, cellulose Or starch), and then cross-linking reaction with polyhydric alcohol (p〇ly〇l) and isohydric acid salt () s〇cyanate) or acrylic resin, or with polyene The raw materials TP0 and TPV (which are one of the types of thermoplastic elastomers Thermoplastic Elastomer, abbreviated as TPE) are reacted by mixing. Therefore, the polymer polymer material has an environmental protection bond that does not contain toxic substances such as AZO Dyes azo pigment, Cadmium cadmium, vinyl chloride monomer (VCM) ethylene chloride monomer, Nonylphenol atmosphere, or Organlctln organic hydrazine, etc. And can also have biodegradable functions. In summary, the biodegradable environmentally-friendly cushion structure and the method for manufacturing the same according to the present invention have the following advantages: (1) The mat body can be used as a general multifunctional, including a sports mat, ifi. Pads, toddler toddler pads, anti-slip mats and anti-slip nets, etc.; (2) After the mats are discarded and buried in the soil for a certain period of time, they can pass through the mat itself. The nutrient source of the natural high-grade material directly produces biodegradable with the microbial strains in the soil, and is decomposed into fine fragments in a natural environment and for a certain period of time until completely disappeared. Reduce the burden on the environment and make it environmentally friendly. The above are only the preferred embodiments of the present invention, and thus the scope of the present invention is not limited thereto, and the equivalent changes of the present invention or the contents of the drawings are all included in the present invention. Within the scope, to protect the rights and interests of inventors, Chen Ming. 1301796 [Simple description of the drawings] The first figure is a schematic diagram of the manufacturing method of the environmental protection pad body of the present invention. The second figure is a schematic view of the structure of the environmental protection pad body of the present invention. [Main component symbol description] [Invention] The environmental protection pad body 1 central Mesh 11 Polymerization raw material (layer) 12, 13 Roller 21, 22 Upper (lower) coater 31 (or 32) 4 Hot drying zone high temperature unit 41 Super temperature early 兀 42 Low temperature zone 5 Cutting machine 61 Automatic counter 62 sheet cushion body 63 10