TWI296639B - Colored resin composition, color filter, and liqued crystal display - Google Patents

Description

1296639 发明Invention Description: [Technical Field] The present invention relates to a colored resin composition, a method for producing the same, a color filter, and a liquid crystal display device. More specifically, the present invention relates to the pattern adhesion of the height at the time of excellent transmittance and development, and the low residual rate to the non-image portion after development and when applied by the die coating method. A colored resin composition which suppresses the occurrence of a dry clot at the tip end of the die, a color filter using a pixel formed using the colored resin composition, and a liquid crystal display device having the color filter. [Prior Art] Conventionally, as a method of producing a color filter used for a liquid crystal display device or the like, a pigment dispersion method, a dyeing method, an electrodeposition method, and a printing method in which a pigment dispersion method having an excellent average characteristic are known, in the spectroscopic method From the viewpoints of characteristics, longness, shape and accuracy, the most widely used. The pigment dispersion method is usually carried out according to the following procedure. First, a black base material is formed on a transparent support such as a glass substrate by a metal light-shielding film such as chromium or chromium oxide, and then a coloring matter composition in which a red pigment is dispersed (hereinafter, this composition is sometimes called For "color resist", it is applied to the whole by spin coating or the like, exposed by a photomask, and developed after exposure to obtain red pixels. Regarding the blue and green pixels, the same procedure can be applied to form a three-color element by coating, exposure, and development. In the case where the black base portion is recessed between the pixels, a transparent resin such as an epoxy resin or an acrylic resin is used for smoothing to form a protective film. However, there is a case where a protective film is not provided. 12/Inventive Manual (Supplement)/93-04/93 101159 The light tool is made of Fang Fang-resistant glass-to-tree application image > Table field 6 1296639. Then, a transparent conductive film such as an ITO (Indium Tin Oxide) film is formed on the protective film (in the case where the protective film is not provided, that is, on the pixel and the black substrate) by sputtering or vacuum deposition. Further, in recent years, the above-described pigment dispersion method is often used in the formation of a black matrix. Specifically, a colored resin composition in which a black pigment is dispersed (hereinafter, this composition is referred to as "black photoresist") is applied, exposed, and developed to produce a color filter. In recent years, due to the rapid technological innovation, higher transmittance and higher density are required for color filters. In order to form a highly transmissive color filter, it is necessary to increase the dispersibility of the color material, and therefore, a nitrogen atom-containing dispersant excellent in dispersibility is widely used. In order to form a high-transmission and high-concentration color filter, it is necessary to increase the concentration of the color material in the colored resin composition used, and it is also necessary to simultaneously increase the concentration of the above nitrogen atom-containing dispersant. However, the use of only this dispersant causes problems in that not only the sufficient liquid stability is not obtained, but also the heating step in the production of the color filter is yellowed to lower the transmittance of the pixel. On the other hand, the colored resin composition is usually produced by a step of mixing and dispersing a color material and a dispersing agent to prepare a colored resin composition, and a mixing step of the colored resin composition with a solvent and a binder resin or the like. It is known that, for the binder resin to which the colored resin composition is mixed, a resin having a structure in which a carboxyl group of a carboxyl group-containing resin is added from an epoxy moiety containing an epoxy group-containing unsaturated compound is used (for example, reference) W0 9 6 - 2 3 2 3 Bulletin 7). However, the photosensitive resin composition cannot sufficiently solve the above problems.

Furthermore, the 'relevant device for liquid crystal display' does not correspond to the dynamic display. J 7 312/Inventive Manual (Replenishment)/93-04/93101159 1296639 Increased requirements for high-speed response, with color filters and alignment The tendency of the gap of the substrate to be narrowed is that the amount of liquid crystal per unit area of the liquid crystal cell is small. When a large amount of the nitrogen atom-containing dispersant is contained in the colorant resin composition, after the liquid crystal unitization step, the dispersing agent is dissolved in the liquid crystal by the IT 0 film or the like, and the voltage holding ratio of the liquid crystal is lowered. problem. Further, when the response speeding progresses, as described above, the liquid crystal amount per unit area of the liquid crystal cell is lowered, so that the voltage holding ratio is further lowered. When the voltage holding ratio of the liquid crystal is lowered, it is said that the display is uneven, and the display phenomenon such as the afterimage phenomenon is poor (for example, refer to Japanese Patent Laid-Open No. 2000-92 2902, Special Edition 2 0 0 0 - 3 1 1 2 2 8), especially in high-transmission, high-concentration, two-speed response liquid crystal display devices cause big problems. In order to solve the problem of display unevenness, as for the dispersant contained in the colored resin composition, there has been proposed a method of using a dispersing agent having a decomposition temperature higher than -20 °C higher than the temperature at the step of forming the colored layer. Furthermore, the method defines the decomposition temperature when the colored resin composition containing the dispersant is subjected to heat treatment to form a colored layer, and the organic impurity extraction amount of the colored layer by liquid crystal extraction reaches 10 〇 pp in The heating temperature (for example, refer to Japanese Laid-Open Patent Publication No. 2000-171784). However, in the case where a dispersant containing a II atom is used, the voltage holding ratio is sometimes lowered in accordance with this method, so that the problem of uneven display is more serious. Further, in order to form a high-density color filter, it is necessary to increase the color material concentration of the colored resin composition used. On the other hand, the components that are sensitive to image formation, such as photosensitivity and solubility, are relatively reduced, so that the figure owned by the present invention is lost. /93-04/93 丨01159 1296639 Like the formation property, the undissolved matter of the colored resin composition tends to remain in the non-image portion after development. When the undissolved matter of the colored resin composition remains on the non-pixel portion on the substrate, the obtained color filter is reduced in transmittance or contrast, and when it remains in the edge portion of the pattern, I TO is caused. The peeling of the film, the deterioration of the sealing property at the liquid crystal unitization step, and the like, cause a situation in which the subsequent steps are affected. In order to solve such a problem, a method of adding an organic carboxylic acid compound having a molecular weight of 1 or less to a colored resin composition has been proposed (for example, refer to Japanese Patent Laid-Open No. 3 2 3 3 1 7 1). When this method is used, it is confirmed that the pigment is dispersed by the binder polymer to form a partially colored resin composition, and the effect of reducing the residual of the undissolved material in the non-pixel portion after development has been confirmed. On the other hand, various new technologies have been developed regarding the production methods of color filters and light sheets. In the pixel forming step, for example, with respect to the photoresist coating step, the mainstream method hitherto has been to apply a photoresist to the central portion of the substrate and to homogenize it by spin coating. However, with the increase in the size of the substrate, the increase in the amount of photoresist used, and the limitations of the spinner on the device (such as the ability of the motor, etc.), the coating technology by the die coating method has recently been developed, and some have been developed. However, the technique of applying photoresist by die coating has hitherto been used in the manufacture of, for example, a flexible disk (F 1 ◦ ppy ® D isk ), and is generally suitable for use in photoresists and the like. When the coating liquid is continuously applied to a medium such as a polymer film, in contrast, in the case of coating a leaf of a color filter, the photoresist 3丨2/invention specification (supplement)/93 The coating method of -04/93丨0丨丨59 9 1296639 is a batch coating method, that is, it is moistened and dried at the tip end of the die. When the color photoresist or the black die tip which is dispersed with high concentration pigment is dried, Due to the sharp increase in pigment concentration, clots (agglomerates) are sometimes produced. This clot is attached to the tip of the die, and the step of peeling off from the die tip and moving on the substrate is not easy. Was removed until the last remaining on the substrate clots When the pixel defect of the color filter is defective, the quality of the product is frequently deteriorated, and the yield of the product is lowered. It is considered that one of the phenomena should be avoided. [Invention] The inventors of the present invention found the following facts: The neutron of the nitrogen atom dispersant has a bad influence on the voltage holding ratio; if the nitrogen-containing function is used for decomposition and volatilization due to heating, the voltage holding can be improved instead, and a total amount of residual after heating is used. Low-rate child dispersant. However, the nitrogen-containing powder having a low residual nitrogen content after heating can increase the voltage retention rate, but sometimes the transmittance is insufficient, and depending on the use, the residual ratio of total nitrogen is used. In the case of the addition of the carboxylic acid compound, the addition of the carboxylic acid compound is not limited to the non-image portion, as described in Japanese Patent No. 3 2 3 3 1 7 1 . Adhesiveness will also reduce the adhesion of the image-reducing part, resulting in a narrower range of imaging, and the peeling of the pixel and the whitening (temporary representation of the phenomenon of "no coloring r"). That is, it has become very difficult to simultaneously satisfy the situation of the reduction of the undissolved amount and the good adhesion of the image, in order to maintain the 3 12 / invention specification (supplement) / 93-04 / 93 101159 over the wet photoresist in the raw pigment And in the light, in it. For this reason. Therefore, the nitrogen fraction is easy to be; because the nitrogen-containing atomic atom or the imaging nitrogen-containing atom is organically low, the figure is prone to b whitening.  Resolving the two qualities of quality 1 1296639 has to reduce the yield (yield). Further, the properties obtained for the colored resin composition are not limited to the above-mentioned development characteristics, and include excellent coating properties in conformity with the new coating method represented by the recent die coating method, particularly the suppression property of dry clots. Recently started to be asked. The present invention has been made in view of the above problems, and the object thereof is as follows: (1) Providing a colored resin composition, even in the case of using a nitrogen atom-containing dispersant having a high residual nitrogen content after heating, While satisfying the requirements of high transmission and high concentration, the voltage holding ratio of the liquid crystal is lowered and the display is poor, and the material is indirectly and directly contacted with the liquid crystal layer; (2) a colored resin composition is provided on the substrate. In the upper case, the undissolved matter of the composition rarely remains on the non-image portion on the substrate, and has excellent adhesion to the substrate, and suppresses foreign matter such as dry clots when the die coating method is applied. The result is that a high-density color pixel can be uniformly formed; (3) a high-quality color filter is provided, and the undissolved substance of the colored resin composition does not remain on the non-pixel portion of the substrate and does not remain. Drying and agglomerating the foreign matter causing the cause; (4) Providing a liquid crystal display device of two qualities using the above-described color calender substrate. In order to solve the above problems, the inventors of the present invention have diligently studied and found that when the composition contains a binder resin having a specific structure and the weight ratio of the nitrogen atom-containing dispersant to the color material is within a specific range, even when used In the case of a nitrogen atom-containing dispersant having a high residual nitrogen content after heating, the voltage holding ratio can be prevented from being lowered, and high transmittance and high display can be achieved. ()) /93-04/93丨01159 11 1296639 The fact of the image, thus completing the present invention. It has also been found that when a binder resin having a specific structure and a dispersant having a specific structure are used in combination, it is possible to obtain an excellent adhesion to the substrate without leaving undissolved substances in the non-image portion on the substrate. Further, the present invention can be completed by suppressing the generation of foreign matter such as a dry clot and the formation of a colored resin composition of a high-density color pixel when the die coating method is applied. Further, it has been found that if a resin having a specific configuration which has been used as a binder resin at the time of preparing a colored resin composition is used as a dispersing agent in the preparation of a colored resin composition, the liquid stability of the colored resin composition can be sufficiently improved. At the same time, the photosensitive colored resin composition produced by using the colored resin composition obtains excellent results in terms of developability, substrate fouling, thermal stability, and liquid stability, and is then formed. The fact that the transmittance of the pixel becomes high has thus completed the present invention. That is, the present invention is directed to a colored resin composition characterized in that the binder resin contains a carboxyl group having a carboxyl group-containing resin (a) by an epoxy group containing an epoxy group-containing unsaturated compound (b). The non-nitrogen atom binder resin and the nitrogen atom-containing dispersant are formed, and the weight ratio of the nitrogen atom-containing dispersant to the color material is 0.  0 1 or more 0.  Within the scope of 5. Further, another object of the present invention is to provide a coloring resin composition comprising a coloring material, a solvent, a dispersing agent, and a coloring resin composition of a binder resin, characterized in that / the binder resin is. A resin obtained as follows: (A) an epoxy-containing (fluorenyl) propionate 5~9 0 in ο 1 % and (B) another component freely copolymerizable with the component (A) 12 3 12/I叩11))/93-04/93 101 159 1296639 Furthermore, another object of the present invention is to provide a color filter, a substrate and a color filter formed on the substrate. Some or all of the pixels are formed under the use of the above colored resin. The invention can achieve the following effects 1 . The colored resin composition according to the present invention is a high-density color pixel in which a non-pixel portion which is not dissolved on a substrate and which is not dissolved on a substrate, and which has excellent adhesion to the substrate. Further, at the time of application of the coating method, foreign matter such as dry clots is rarely generated. The formed pixel has high transmittance and, in addition, has little influence on the voltage of the liquid crystal, so that it is difficult to cause display unevenness, afterimage, and the like. 2 . In the color filter of the present invention, the undissolved matter of the colored resin composition remains on the non-pixels on the substrate. Further, the formation has high transmittance, and the influence on the voltage holding ratio of the liquid crystal is difficult to cause display unevenness such as display unevenness or afterimage, which is extremely high. 3 . The liquid crystal display device according to the present invention has an extremely high quality, and a color filter having an extremely high quality has an undissolved substance of a colored resin composition on a non-pixel portion on a substrate, and further, a high density is formed. Transmittance, in addition, the effect on the voltage holding ratio of the liquid crystal is such that display unevenness is difficult to occur. [Embodiment] Hereinafter, the present invention will be described in detail. 3 12/Inventive Manual (Supplement)/93-04/93 101159 When it has its characteristic composition, it is formed in accordance with the mold, and the retention rate is not high, and the quality is not used. The composition of the colored resin composition (photoresist) according to the present invention is based on the color material, the solvent, the dispersant, and the binder resin. The essential component may be blended with other additives other than the above components as necessary. Hereinafter, regarding each component component. To illustrate. [1 - 1 ] The color material refers to the coloring material of the colored resin composition of the present invention. A pigment or a dye can be used as the color material, and a pigment is preferable from the viewpoint of heat resistance, light resistance and the like. As the pigment, a pigment of various colors such as a blue pigment, a green pigment, a red pigment, a yellow pigment, a purple pigment, an orange pigment, a brown pigment, or the like can be used. Further, the structure may include an azo system, a phthalocyanine system, an acridone system, a benzimidazolone system, a different name, a 哚 s 昆 昆 system, a second drinking cultivating system, a loose onion s Kun (yin Dan) Shilin) is an organic pigment such as a naphthalene system. In addition, it is also possible to use various inorganic pigments and the like. Hereinafter, specific examples of the pigments that can be used are shown by the pigment number. The following "C.  I. The meaning of the terms "pigment red 2" and so on is the color index. For the red pigment, C.  I. Pigment red 1, 2, 3, 4, 5. , 6, 7, 8, 9, 12, 14, 15, 16, 17, 21, 22, 23, 31, 32, 37, 38, 41, 47, 48, 48:1, 48:2, 48:3 , 48:4, 49, 49:1, 49:2 > 50:1, 52:1, 52:2, 53, 53:1, 53:2' 53:3, 57, 5 7:1 > 57:2, 58:4, 60, 63, 63: 1 > 63:2, 64, 64:1 ^ 68, 69, 81, 81:1 > 81:2, 81:3, 81:4, 83, 88, 90:1, 101, 1 0 1 Μ, 10 4, 108, 108:1 > 109, 112, 113, 114, 122, 123, 16 3 12/I. ]Description·(Repair)/93-04/93 丨01159 1296639 144, 146, 147, 149, 151, 166, 168, 169, 170, 173, 174, 175, 176, 177, 178, 179, 181 184, 187, 188, 190, 193, 194, 200, 202, 206, 207, 209, 210, 214 > 216, 220, 221, 224, 230 > 231, 233, 235, 236, 237, 238, 239, 242, 243, 245, 249, 250 > 251, 253, 254, 255, 256, 257 > 258, 260, 262, 263, 264, 265, 266, 267, 268, 269, 27 1 , 2 7 2, 2 7 3, 2 7 4, 2 7 5, 2 7 6 〇 in it, to C.  I. Pigment red 4 8 : 1, 1 2 2, 1 6 8 , 1 7 7 , 2 0 2 2 0 7 , 2 0 9 , 2 2 4 , 2 4 2 , 2 5 4 is preferred, and C · I . Pigment red 2 0 9, 224, 254 is further preferred. For the blue pigment, C.  I. Pigment blue 1, 1 : 2, 9, 1 4 15:1, 15:2, 15:3, 15:4, 15:6, 16, 17, 19, 25 2 8, 29, 33, 35, 56, 56:1, 60 > 6 卜 6 ] Μ, 62, 63 67, 68, 71, 72, 73, 74, 75, 76, 78, 79 ° in which, to C.  I. Pigment blue 1 5, 1 5 : 1, 1 5 : 2, 1 5 : 3, 1 5 : 6 is better, and C.  I. Pigment blue 1 5 : 6 is further preferred. For green pigments, C.  I. Pigment green 1, 2, 4, 7, 8 1 3, 1 4, 1 5, 1 7 , 1 8 , 1 9 , 2 6 , 3 6 , 4 5 , 4 8 , 5 0 , 5 1 5 5 , wherein By C.  I. Pigment greens 7, 3 are preferred. For the yellow pigment, C.  I. Pigment Yellow 1, 1 : 1, 2, 3, 6, 9, 1 0, 2, 1 3, 1 4, 1 6 , 1 7 , 2 4 , 3 1 , 3 2 , 3 4 35:1 , 36 , 36:1, 37, 37:1, 40, 41, 42, 43, 48 55, 61, 62, 62:1, 63, 65, 73, 74' 75, 81, 83 3 I 2/calling Ψ: "You Μί1:)/93-04/93 101159 172, 185, 2 0 8, 2 3 2, 2 4 7, 2 5 9 > 2 7 0, 2 0 6 > 177, 15, 27 , , 66, 15:4, 1, 0, 54, 4, 5, 35~ '53 > 17, 87, 1296639 93, 94, 95, 97, 100, 101, 104, 105, 108, 109 , 111, 116, 117, 119, 120, 126, 127, 127:1, 128,: 133, 134, 136, 138, 139, 142, 147, 148, 150, 1 153, 154, 155, 157, 158, 159, 160, 161, 162, 1 164, 165, 166, 167, 168, 169, 170, 172, 173, 1 17 5, 7 6 , 180, 181, 182, 183, 184, 185, 188 1, 190, 191, 191:1 > 192, 193, 194, 195, 196, 197, 199, 200, 202, 203, 204, 205, 206, 207, 208° therein, in C.  I · Pigment Yellow 8 3, 1 1 7 , 1 2 9 , 1 3 8 , 1 3 9 , 1 5 4, 1 5 5, 1 8 0, 1 8 5 Preferably, and C.  I · Pigment Yellow 8 3, 1 3 8 , 1 50 , 1 8 0 is further preferred. For the orange pigment, it can be cited as C.  I. Pigment oranges 1, 2, 5, 13, 16, 6, 20, 21, 22, 23, 24, 34, 36, 38, 39, 43, 46, 4 9, 61, 62, 64, 65, 67 , 68, 69, 70, 71, 72' 73, 7 5, 7 7 , 7 8 , 7 9, of which C.  I. Pigment orange 3 8 and 7 1 are preferred. For the purple pigment, it can be cited as C.  I. Pigment Violet 1,1: 1, 2, 2 ·· 2 3 : 1, 3 ·· 3, 5, 5 : 1, 1 4, 1 5, 1 6 , 1 9 , 2 3 , 2 5 , 2 7 , 31, 32, 37, 39, 42, 44, 47, 49, 50. In it, C.  It is preferred that the material purple 19, 2, 3, and C.  I. Pigment Violet 2 3 is further preferred. Further, examples of the other pigments include barium sulfate, lead sulfate, titanium oxide color chrome, red iron oxide, and chromium oxide. The above various pigments may be used in combination of two or more kinds. For example, for the purpose of color, a pigment, a green pigment and a yellow pigment may be combined, or a blue pigment and a purple pigment may be combined. Press again, this item 3 12 / 丨卩 丨卩] description window (_ pieces) /93-04/93丨Ο Μ 59 [10, 129, 51, 63 ^ 74 > 89, 198, 150, 1 39 > 17, 48, 74, 3, 29, I. Yan and Huang adjust and combine the average particle size of the pigment used in 18 1296639 is usually 1 " in, to Ο.  5 // in is better, and Ο.  2 5 //丨丨〗 The following is further preferred. Further, examples of the dye which can be used as the color material include an azo dye, a dye, a phthalocyanine dye, a quinone dye, a porphyrin dye, a dye, a carbonyl dye, and a methine dye. Wait. For the azo dye, for example, C.  I. Acid yellow 1 1 , C.  I. Acid 7, C.  1 . Acid red 3 7 , C .  I. Acid red 1 800, C.  I. Acid blue 2 9 , direct red 2 8 , C .  I. Direct red 8 3, C.  I. Direct yellow 1 2, C.  I. Straight 2 6 , C .  I. Direct Green 2 8 , C .  I. Direct Green 5 9 , C · I . Reactive Yellow 2, Reactive Red 1 7 , C .  I. Reactive Red 1 2 0, C.  I. Reactive black 5, C.  I. Dispersion: C.  1 . Disperse red 5 8 , C .  I. Disperse blue 1 6 5, C.  I. Authentic blue 4 1 , C · sex red 18, C. I. Mordant red 7, C. I. Mordant yellow 5, C. I. The mord black 7 is an onion K dye, and for example, C.  I. Indigo 4, C.  I. Acid blue C.  1 . Acid Green 2 5, C.  I. Reactive Blue 1 9 , C .  I. Reactive Blue 4 9 , C, Red 6 0, C.  I. Disperse blue 5 6, C.  I. Disperse blue 6 0 and so on. In addition to the above, examples of the phthalocyanine dye include C·I. 瓮, etc., are quinone imine dyes, for example, C.  I. Basic blue 3, C.  Sex blue 9, etc., are porphyrin dyes, for example, C.  I. Solvent Yellow 3 3, Acid Yellow 3, C.  1 . Disperse yellow 6 4 and the like, and be a nitro dye, for example, C.  1 . Acid yellow], C.  I. Acid Orange 3, C.  I, disperse yellow 4 2 and so on. Further, in the case where a colored resin composition is used to form a black matrix of a color filter, a black color material can be used. For black color materials, black color materials can be used alone, or mixed with red, green, blue, etc., and this color material can be appropriately selected from inorganic or organic pigments or dyes. Description·(Repair)/93-04/93 101 159 The following onion 醌 nitro orange C.  I.  Pick up the orange C.  I.  i 5 Λ I · alkali, etc. 40, I. Blue 5 I · alkali C.  I · Can only be a spring:) The purpose of the month is to choose 19 19 19296296. In the case of using inorganic or organic pigments, it is preferred to disperse them so as to have an average particle diameter of less than 1 V m which is usually set.  Use it if 5 / m or less is preferred. Examples of the black color material which may be used alone include carbon black, acetylene black, lamp black, bone black, graphite, iron black, aniline black, cyanine black, and titanium black. Among the above black color materials, carbon black is preferred from the viewpoint of light blocking ratio and image characteristics. Examples of the carbon black include carbon black as described below. For the products manufactured by Mitsubishi Chemical Corporation, MA7, MA8, MA11, MA100, MA100R, MA220, MA230, MA600, #5, #10, #20, #25, #30 >#32,# 33, #40, #44 ' #45 ' #47 , #50 , #52 , #55, #650, #750, #850, #950, #960, #970, #980, #990 ' #1000' #2200' #2300, #2350' #2400, #2600' #3050, #3150' #3250, #3600, #3750, #3950, #4000, #4010, OIL7B, OIL9B, OIL1IB, OIL30B, OIL31B, etc. For products manufactured by Degussa, Printex3, Printex30P, Printex30, Printex300P, Printex40, Printex45, Printex55, Printex60, Printex75, Printex80, Printex85, Printex90, Printex A, Printex L, Printex G, Printex P, Printex U, Printex V, Printex G, Special Black550, Special Black350, Special Black250, Special BlacklOO, Special Black6, Special Black 5, Special Black 4, Color Black FW1, Colo rBlack FW2, Color Black FW2V, Color Black FW18, Color Black FW18 , Color Black FW200 Color Black S160, Color Black S170, etc. 0 20 312/Invention Manual (supplement)/93-04/93101159 1296639 For the products of "Cabot", Monarchl20, Monarch280, Monarch460, Monarch800, Monarch880, Monarch900, MonarchlOOO, MonarchllOO, Monarchl300, Monarch 1400, Monarch4630, REGAL 9 9 , REGAL99R, REGAL415, REGAL415R, REGAL250, REGAL250R, REGAL330, REGAL400R, REGAL55R0, REGAL660R, Black PEARLS480, PEARLS130, VULCAN XC72R, ELFTEX-8, etc. "Columbian Carbon The products manufactured by the company include RAVEN1, RAVEN14, RAVEN15, RAVEN16, RAVEN22, RAVEN30, RAVEN35, RAVEN40, RAVEN410, RAVEN420, RAVEN450, RAVEN500, RAVEN780, RAVEN850, RAVEN890H, RAVEN1000, RAVEN 1 0 2 0, RAVEN 1 0 4 0, RAVEN 1 0 6 0 U, RAVEN 1 0 8 0 U, RAVEN1 1 70, RAVEN1190U, RAVEN 1 2 5 0 , RAVEN 1 5 0 0 , RAVEN2000, RAVEN2500U, RAVEN3500, RAVEN5000, RAVEN5250, RAVEN5750, RAVEN7000, etc. . Further, it is particularly preferable to use a resin-coated carbon black in the production of a resin black substrate having a high optical density and surface resistivity. For the color material which may be used for the preparation of the black color material, Victoria PureBlue (42595), Auram ine (41000), Cat i 1 onBr i 11 antF 1 av i η (inspective 1 3), Rh odam ine 6 G CP ( 4 5 1 6 0 ), Rhodamine B (45170), Safranine OK 70: 100 (50240), Erioglaucine X (42080), No. 120/LionolYellow (21090), Lionolyellow GR0 (21090), 21 312 / invention specification (supplement) /93-04/93101159 1296639 S y in u 1 er F ast Y e 1 1 ow 8 GF ( 2 1 10 5) , B enzidine Y e 1 1 ow 4 T - 5 6 4 D ( 2 1 0 9 5 ) , S y in ulerFastRed 4 015 (12355), Lion 〇lRed7B4401 (15850), F astge η B1u e ΐ G RL ( 7 4 1 6 0 ) , LionolBlueSM (26150), L i ο η o 1 B 1 ue ES (pigment blue 1 5 : 6 ), L i ο η ogen R ed GD (pigment red 168), L i ο η o 1 G reen 2 YS (pigment green 3 6 ), and the like. Press again, the number in the above brackets is the color index (C.  I. ). Furthermore, regarding other pigments that may be mixed, c.  I. Numerical representations include, for example, C · I · yellow pigments 2 0, 2 4, 8 6 , 9 3 , 1 0 9 , ] 1 〇, 117, 125, 137, 138, 147, 148, 153, 154, 166, C.  I. Orange pigment 3 6 , 4 3 , 5 1 , 5 5 , 5 9 , 6 1, C · I . Red pigments 9, 97, 122, 123, 149, 168, 177, 180, 1 9 2, 215, 2 1 6 , 2 1 7 , 2 2 0, 2 2 3, 2 2 4, 2 2 6 , 2 2 7, 2 2 8 , 2 4 0, C · I , purple pigment; [9, 2 3, 2 9 , 3 0, 3 7 , 4 0, 5 0 ' C · I · blue pigment 1 5, 1 5 : 1, 1 5 : 4, 2 2, 6 0, 6 4, C.  I · Green Pigment 7, C.  I. Brown pigment 2 3, 2 5, 2 6 and so on. The ratio of the color material to the total solid content in the colored resin composition is usually set to be 1 wt% or more (preferably 1 〇 wt% or more), and 70 wt% or less (preferably 6 〇 wt% or less). Inside. If the ratio of the color material is too low, the film thickness of the color density becomes too large, and the gap control during liquid crystal cell formation is adversely affected. On the other hand, the ratio of the right color material is too high, and sufficient image formability may not be obtained. Further, in the present invention, the meaning of "all solid fraction" is the total component other than the solvent component described later. [1 - 2 ] Solvent: 22 312 / invention specification (10)) / 93-04/931 ◦ 1159 1296639 Solvent is a coloring material, a dispersing agent, a binder resin and, if necessary, a coloring resin composition of the present invention. A function of dissolving or dispersing a component other than the above to adjust the viscosity. Examples of the solvent include diisopropyl ether, mineral spirits, n-decane, pentyl ether, ethyl decanoate, n-hexane, diethyl ether, isoprene, ethyl isobutyl ether, and butyl stearate. Ester, n-octane, V ars ο 1 # 2, APC〇# 1 8 Solvent, diisobutylene, pentyl acetate, ethyl succinate, APC 0 diluent, dibutyl ether, diisobutyl ketone, methylcyclohexane Refining, hydrazine-based S, C & ί, 12-burning, S 〇C a 1 solvent N 〇.  1 and N〇. 2, yttrium sulphate, dihexyl ether, diisopropanone, S〇lvesso #150, n-butyl acetate, acetic acid second butyl S, acetic acid third butyl S, hexene, S he 1 1 TS 2 8 Solvent, chlorobutane, ethyl amyl ketone, ethyl benzoate, pentane, ethylene glycol diethyl ether, ethyl ortho phthalate, decyl fluorenyl ketone, decyl butyl ketone, fluorenyl Hexyl ketone, decyl isobutyrate, benzonitrile, ethyl propionate, 2-oxoethoxylate, decylisoamyl ketone, decyl isobutyl ketone, propyl acetate, amyl acetate, citric acid Amyl ester, bicyclohexane, diethylene glycol monoethyl ether acetate, p- oxime, 8-diene, decyloxymethylpentanol, methyl amyl ketone, methyl isopropyl ketone, propionic acid Vinegar, propylene glycol tert-butyl ether, mercaptoethyl ketone, 2-oxoethanol, 2-ethoxyethanol, 2-ethoxyethyl acetate, carbitol, cyclohexanone, ethyl acetate, propylene glycol, propylene glycol Monoterpene ether, propylene glycol monoterpene ether acetate, propylene glycol monoethyl ether, propylene glycol monoethyl ether acetate, monohydric (propylene glycol) monoethyl ether, monohydric (propylene glycol) monomethyl ether, monohydric (propylene glycol) monoterpene ether B Ester, 3-oxopropionic acid, 3-ethoxypropionic acid, 3-ethoxypropionic acid vinegar, 3-ethoxypropionic acid vinegar, 3-methoxypropionic acid glycerin, 3-methoxypropionic acid Vinegar, 3 - aziridine, 23⁄4 propyl, 3 - methoxypropionate, bis (2-methoxyethyl ether), ethylene glycol B 3 3 丨 2 / call description _ (supplement) / 93- 04/ς)3丨0丨丨59 1296639 acid ester, ethyl carbitol, butyl carbitol, ethylene glycol monobutyl ether, propylene glycol tert-butyl ether, 3-mercapto-3-oxobutanol , tris(propylene glycol) anthracene ether, 3-mercapto-3-oxobutyl acrylate, and the like. The above solvents may be used singly or in combination of two or more. In the entire coloring resin composition of the present invention, the ratio (content) of the solvent is not particularly limited, but the upper limit is usually set to 9 9 w % or less. In the case where the solvent exceeds 9 9 w %, the content of the color material, the dispersant, etc. becomes too low to be suitable for the formation of a coating film. On the other hand, the lower limit of the solvent content is usually set to be more than 75 wt%, more preferably 80 wt% or more, and more preferably 8 2 wt% or more, in consideration of viscosity or the like suitable for coating. good. []-3] Dispersant: The dispersant in the present invention is a nitrogen atom-containing dispersant, and the residual ratio of total nitrogen after being heated at 30 ° C for 30 minutes (complete nitrogen after heating) The weight ratio of the amount to the total nitrogen amount before heating is usually 9.5 wt% or less, preferably 90 wt% or less, and more preferably 80 wt% or less. Further, the residual ratio of the weight of the nitrogen atom-containing dispersant after being heated at 30 ° C for 30 minutes (the weight ratio of the weight after heating to the weight before heating) is preferably 9.5 wt% or less. Further, it is further preferably 90% by weight or less. In the present invention, under the conditions of a temperature of 60 ° C, a temperature of 48 hours, and a pressure of 10 m in HG, it is dried under reduced pressure to carry out the solvent component before the heating at 203 ° C for 30 minutes. Solid, and use this as a state before drying. Then, it is placed in a heating furnace such as a circulating hot blast stove to perform heating at 203 ° C for 30 minutes. For the measurement of the amount of nitrogen before and after heating, a C Η N meter or the like is generally used. (Supplement V93-04/93101 丨 59 24 1296639 elemental analysis device, and for the measurement of weight, a precision balance is usually used. As the nitrogen atom-containing dispersant, a surfactant, a polymer dispersant, or the like is usually used, and a polymer dispersant is particularly preferable. As the polymer dispersant, it is preferred to contain at least one of the following: an amine hydrazine; An ethyl acetate-based dispersant; a graft copolymer containing a nitrogen atom; and an A-B block composed of a block A having a quaternary ammonium base in a side chain and a block B having no quaternary ammonium base Copolymer and/or B-A-B block copolymer. The present invention can be used in combination with a specific binder resin described later to achieve a coating of a colored resin composition while maintaining dispersion stability. The high adhesion of the film to the substrate and the suppression of the residual of the undissolved material. Further, the dispersing agent may be used singly or in combination of two or more kinds of dispersing agents. In the case of a dispersant, it will be The residual ratio is defined as the residual ratio of each of the nitrogen atom-containing dispersants in the respective mixing ratios. The form of the gas atom containing the II atom dispersant is preferably an amine group or a quaternary salt. Since the base is usually basic and easily coordinated with an acidic group such as a pigment or a pigment derivative, it is used for dispersion stabilization. The amine value of the dispersant is usually 2 to 1 Ο Ο K 0 H mg / g to 3 ~8 Ο K 0丨1 ni g / g is preferred. In the case where the amine price is too low, the alkalinity is insufficient and the dispersion stability is lacking, and in the case where the amine price is too high, the voltage holding ratio of the liquid crystal is caused. It is not suitable for display failure, so it is not suitable. The weight ratio of nitrogen atom dispersant to color material is usually 〇. 〇1 or more, 0.  5 or less. Take 0.  0 2 or more is preferable, and further preferably 0 or less, and 0.  2 is further preferred below. In the case where the ratio of the dispersing agent is too high, 25 3 12/invention description #丨: (supplement)/93-04/93 10丨159 1296639 has a bad influence on the voltage holding ratio, causing uneven display and afterimage If the ratio of the dispersant is too low, the dispersibility cannot be sufficiently exhibited, and high transmittance and high stability of viscosity cannot be achieved. Next, the preferred dispersant will be described in detail. [1 - 3 - 1 ] Amine phthalic acid ethyl ester dispersing agent Amino phthalic acid ethyl ester dispersing agent is preferably one (1) polyisocyanate compound, (2) having one or two hydroxyl groups in the same molecule. The compound, and (3) a dispersion resin obtained by reacting a compound having an active hydrogen and a tertiary amino group in the same molecule. (1) The polyisocyanate compound is exemplified by the above polyisocyanate compound, and examples thereof include p-phenylene diisocyanate, 2,4-nonanyl diisocyanate, and diisocyanate 2,6-indene extension. An aromatic diisocyanate such as phenyl ester, 4, 4'-diphenylmethane diisocyanate, naphthalene 1,5-diisocyanate or toluidine diisocyanate, such as hexa-isoisocyanate or diisocyanate An aliphatic diisocyanate such as methyl amide, diisocyanate 2,4,4-trisulphate, or dimer acid diisocyanate, such as isophorone diisocyanate, 4,4 ' - an alicyclic diisocyanate such as methylene bis(cyclohexyl isocyanate), ω, ω '-dihexyl diisocyanate, such as diisocyanate diisocyanate, diisocyanate α, An aliphatic diisocyanate having an aromatic ring such as α,α',α'-tetraindole or the like, such as an isocyanuric acid triacetate, a 1,6,11-undecyl triisocyanate, 1, 8-diisocyanate-4-isocyanatomethyloctyl ester, triisocyanato 1,3,6-hexadecane ester, bicycloheptane triisocyanate, hydrazine (phenyl decane isocyanate), hydrazine Phenyl cyanate The ester triisocyanate, and terpolymers, water adducts, and polyhydric alcohol adducts thereof. 26 312 / invention specification (supplement) /93-04/93101159 1296639 is a polyisocyanate, preferably a terpolymer of organic diisocyanate S, and a terpolymer of phenyl diisocyanate And the terpolymer of isophorone diisocyanate is most suitable, and the trimer may be used singly or in combination. The method for producing an isocyanate trimer includes a method of using an appropriate trimerization catalyst such as a tertiary amine, a phosphine, an alkoxide, a metal oxide or a carboxyl group for the above polyisocyanate. Partial trimerization of the isocyanate group under acid salt or the like, and after addition of the catalytic agent to stop the trimerization, the unreacted polyisocyanate is removed by solvent extraction and thin film distillation to obtain the target Polycyanate polyisocyanate. (2) A compound having one or two hydroxyl groups in the same molecule is a compound having one or two hydroxyl groups in the same molecule, and examples thereof include polyether glycol, polyester glycol, and polyglycol carbonate. A polyolefin glycol or the like, and a compound in which one terminal hydroxyl group is alkoxylated by substitution of an alkyl group having 1 to 25 carbon atoms, and a mixture of two or more kinds of the compound. The polyether glycol may, for example, be a polyether diol, a polyether ester diol, or a mixture of two or more thereof. The polyether diol is obtained by polymerization or copolymerization of an alkylene oxide alone, and examples thereof include polyethylene glycol, polypropylene glycol, polyethylene-propylene glycol, polyoxytetramethylene glycol, and polyoxyhexamethylene dioxide. An alcohol, polyoxyoctamethylene glycol, and a mixture of two or more thereof. The polyether ester diol is obtained by reacting a mixture of an ether-containing diol or a diol thereof with a dicarboxylic acid or an anhydride thereof or a reaction of an alkylene oxide with a polyester diol. For example, poly(polyoxytetrahydrazide) adipate can be mentioned. The most suitable polyether glycol is polyethylene glycol, polypropylene glycol, polyoxytetramethylene glycol, or a terminal hydroxyl group substituted by an alkyl group having 1 to 25 carbon atoms. Alkoxylated compound. 27 3丨2/ hairpin P Tongming 帯 (supplement V93-04/93 10丨159 1296639 Polyester glycol is derived from dicarboxylic acid (such as succinic acid, glutaric acid, adipic acid, azelaic acid, anti- Butenic acid, maleic acid, citric acid, etc.) or its anhydride with glycol (such as ethylene glycol, monohydrazine (ethylene glycol), triethylene glycol (ethylene glycol), propylene glycol, a condensate (propylene glycol), tris (propylene glycol), 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 3-mercapto-1, 5-pentanediol, neopentyl glycol, 2-mercapto-1,3-propanediol, 2-mercapto-2-propyl-1,3-propanediol, 2-butyl-2-ethyl-1, 3-propanediol, 1,5-pentanediol, 1,6-hexanediol, 2-mercapto-2, 4-pentanediol, 2, 2,4-tris-1,3-pentanediol, 2-ethyl-1,3-hexanediol, 2,5-diindole-2,5-hexanediol, 1,8-octadecylene glycol, 2-methyl-1,8-octadecylene An aliphatic glycol such as a diol or a 1,9-nonanediol, such as an alicyclic glycol such as bishydroxycyclohexane or the like, such as an aromatic diol such as hydrazine diol or bishydroxy ethoxybenzene. For example, an N-alkyl dialkanolamine such as N-mercaptodiethanolamine or the like can be obtained by polycondensation, and examples thereof include polyethylene adipate, polybutylene adipate, and polyhexamethylene. Acid hexamethylene sulfonate S, poly(hexanedicarboxylate), or the like, or the use of the above diol or a carbon number of 1 to 2 5 one of the alcohols as an initiator An alcohol or a poly-lactose monohydric alcohol, such as polycaprolactone diol, polydecyl valerolactone, and a mixture of two or more thereof. The most suitable polyester glycol is a polycaprolactone diol, or a polycaprolactone obtained by using an alcohol having 1 to 25 carbon atoms as an initiator, more specifically, ε-caprolactone The monohydric alcohol is a compound obtained by ring-opening addition polymerization. Examples of the polyglycolic acid-resistant acid include a poly(1,6-extension) carbonic acid, a poly(3-methyl-1,5-pentyl) carbonate, and the like. The polyolefin glycol may, for example, be a polybutadiene diol, a hydrogenated polybutadiene diol or a hydrogenated polyisoprene diol. 28 3 12/Inventive Manual (_piece)/93-04/93丨01159 1296639 Among the compounds having one or two hydroxyl groups in the same molecule, polyether glycol and polyester glycol are particularly preferred. The number average molecular weight of a compound having one or two warp groups in the same molecule is usually from 300 to 1 0,0 0 0, preferably from 5 0 0 to 6 , 0 0 0, and from 1,000 to 4 10,000 is further preferred. (3) A compound having an active hydrogen and a tertiary amino group in the same molecule is an active hydrogen, that is, a hydrogen atom directly bonded to an oxygen atom, a nitrogen atom or a sulfur atom, and examples thereof include a functional group such as a hydroxyl group, an amine group or a thiol group. The hydrogen atom in the middle is preferably a hydrogen atom having an amine group, particularly a primary amine group. The tertiary amine group is not particularly limited, and, for example, a dialkylamine group having an alkyl group having 1 to 4 carbon atoms such as a methyl group, an ethyl group, an isopropyl group or a n-butyl group, or the like may be mentioned. The alkylamine groups are bonded to form a group of the heterocyclic structure, more specifically, a sigmoid ring or a triple sigma ring. Examples of the compound having an active hydrogen and a tertiary amino group in the same molecule are exemplified by ruthenium, osmium bismuth-1,3-propylenediamine, ruthenium, osmium-diethyl-1,3-propane. Diamine, hydrazine, hydrazine _ dipropylene-1,3-propylenediamine, hydrazine, hydrazine-dibutyl-1,3-propylenediamine, hydrazine, hydrazine-dimercaptoethylenediamine, hydrazine, hydrazine-diethyl Ethylenediamine, hydrazine, hydrazine-dipropylethylenediamine, 〜1-dibutylethylenediamine^-dioxa-1,4-butanediamine^-diethyl-1,4-butanediamine, hydrazine , Ν-dipropane-1,4-butanediamine, hydrazine, hydrazine-dibutyl-1,4-butanediamine, and the like. . The tertiary amine group belonging to the nitrogen-containing heterocyclic ring may, for example, be an oxazole ring, an imidazole ring, a triple sigma ring, a tetra sigma ring, a fluorene ring, a sigma ring, a sigma ring, a benzo sigma ring,

a nitrogen-containing heterocyclic 5-membered ring such as a benzotriazole ring, a stupid oxazole ring, a benzothiazole ring, a benzothiadiazole ring, etc., such as an acridine ring, a sorghum ring, a pyrimidine ring, and a three-plow ring a nitrogen-containing 6-membered ring of a porphyrin ring, an acridine ring, an isoindoline ring or the like. In the above, 29 3 丨 2 / invention description running patch) / 93-04 / 93 丨 01 丨 59 1296639 Preferably, the nitrogen-containing heterocyclic ring is an imidazole ring or a triazole ring. Specific examples of the compound having the imidazole ring and the primary amino group include 1-(3-aminopropyl)imidazole, histidine, 2-aminoimidazole, 1-(2-aminoethyl)imidazole and the like. Further, specific examples of the compound having a triazole ring and a primary amino group include 3-amino-1,2,4-tri. Sodium, 5-(2-amino-5- benzene)-3-phenyl-1 Η - 1,2 , 4 -tris(s), 4-amino-4 Η _ 1,2 , 4 -3° Sit-3,5-diol, 3-amino-5-phenyl-1 Η-1,3,4 _ triazole, 5-amino-1,4-diphenyl-1,2,3 -three 17 sit, 3-amino-Ι-^-ΙΗ-2, 4_three 〇 sit. Especially Ν, Ν-dioxin-1,3-propanediamine, hydrazine, hydrazine-diethyl-1,3-dipropylenediamine, 1-(3-aminopropyl)imidazole, 3-amino-1, 2 , 4 - three ° sitting better. The preferred ratio of the raw material of the dispersion resin is 10 to 20 parts by weight based on 100 parts by weight of the polyisocyanate compound, and the compound having 1 or 2 hydroxyl groups in the same molecule is usually 10 to 200 parts by weight. More preferably, it is preferably from 20 to 19 parts by weight, more preferably from 30 to 180 parts by weight, and the compound having active hydrogen and tertiary amino group in the same molecule is usually 0.2. ~ 2 5 parts by weight, preferably 0. 3 to 2 parts by weight. The polystyrene-equivalent weight average molecular weight measured by GPC of the amine phthalate-based dispersion resin of the present invention is usually set at 1,0 0 0 to 2 0 0,0 0 0 (to 2,0 0 0 to 1 0) 0, 0 0 0 is preferred, and 3,0 0 0~5 0 , 0 0 0 is further preferred). When the molecular weight is 1,0 0 or less, poor dispersibility and dispersion stability are obtained, and when the molecular weight is 20,000 or more, the solubility is lowered, and the dispersibility is deteriorated at the same time. It is difficult to control the reaction. The production of the ethyl phthalate-based dispersion resin of the present invention is carried out in accordance with a conventional method for producing an ethyl phthalate resin. For the manufacture of β-enriched solvents, usually 30 3 12/inventive description 拙 (Parts V93-04/93丨0丨159 1296639 use such as acetone, mercaptoethyl ketone, decyl isobutyl ketone, cyclopentanone, ring Ketones such as ketone or isophorone, such as ethyl acetate, esters of acetic acid, ethyl 2-ethoxyethyl acetate, and the like, such as hydrocarbons such as benzene, toluene, diphenylbenzene, and hexane. For example, a part of alcohols such as diacetone alcohol, isopropanol, second butanol, and third butanol, such as a gas of dioxane, gas, etc., such as ethers of tetrahydrofuran, diethyl ether, etc., such as An aprotic polar solvent such as dimercaptoamine, hydrazine-methylpyrrolidone or dimethyl sulfoxide, etc. For the catalyst used in the production, a common amine catalyzed reaction catalyst is used. For example, tin-based such as dibutyltin dilaurate, dioctyltin dilaurate, dibutyltin dioctoate, tin(II) octoate, or the like, such as iron acetoacetate, etc., may be mentioned. a tertiary amine system such as triethylamine or triethylenediamine, etc. The above compound has an active hydrogen and a tertiary amine group in the same molecule, and the amount of the amine is introduced as the amount of the dispersed resin after the reaction. Preferably, it is controlled within the range of 1 to 1 0 0 ni g Κ Ό H / g, and further preferably in the range of 5 to 9 5 mg Κ 0 H / g. If the amine price is below the above range, dispersion The ability is lowered, and if it exceeds the above range, the development property is liable to be lowered. Further, in the case where the above reaction is carried out in the dispersion resin, an alcohol or an amine compound is used. When the isocyanate group is destroyed, the stability of the dispersion resin becomes higher, which is preferable. The content of the above dispersant in the coloring composition is usually 10 to 300% based on the color component. % is preferably from 20 to 1 0 0 wt%, especially from 3 0 to 80 wt%. If the dispersant component is too small, insufficient absorption of the color material occurs, and aggregation cannot be prevented, sometimes causing high Viscosity or gelation, if too much, the film thickness becomes too thick, after the color filter is made, sometimes in the liquid crystal unit 31 3 丨 2 / invention 丨 (supplement) / 93- (Μ/93丨01丨59 1296639 The step of liquid crystal cell gap control is poor, so it is not suitable. [1 - 3 - 2 ] contains nitrogen atoms Branch copolymer· is a graft copolymer containing a nitrogen atom, and preferably has a repeating unit containing a nitrogen atom in the main chain. In particular, it has a repeating unit represented by the formula (I) or a repeating unit represented by the formula (II). Preferably.

(wherein R ! represents an alkylene group having 1 to 5 carbon atoms (including an anthracene group), and A represents a hydrogen atom or any one of the following formulas (I I I ) to (V)). In the above formula (I), a linear or branched alkyl group having 1 to 5 carbon atoms (including an anthracenylene group), such as a fluorenylene group, an ethyl group, a propyl group, or the like, is a carbon atom. The number of 2 to 3 is preferred, and the ethyl group is further preferred. A is a hydrogen atom or any one of the following formulae (I I I ) to (V), and is preferably a formula (I I I ).

In the above formula (1 I ), the definitions of R | and A are the same as those of R ! and A of the formula (I).

In the above formula (1 II ), W ! represents a linear or branched branching group having 2 to 10 carbon atoms, and particularly has a carbon atom number of 4 such as a butyl group, a pentyl group or a hexyl group. The alkylene group of ~7 is preferred. P represents an integer of 1 to 2 0, and is preferably 5 to 1 0 32 3 丨 2 / invention specification (supplement) / 93-04/9310 丨丨 59 (IV) 1296639.

In the above formula (IV), Y i represents a divalent linking group, particularly an alkyl group having a carbon number of from 4 to 4 (including a methylene group) and an ethoxy group such as an exoethyl group. Preferably, a propenyloxy group (including a decylene group) having 1 to 4 carbon atoms, such as a propoxy group, is preferred. W 2 represents a linear or divergent alkyl group having 2 to 10 carbon atoms such as an ethyl group, a propyl group, a butyl group, etc., especially a carbon atom such as an ethyl group or a propyl group. A 2 to 3 alkylene group is preferred. Y 2 represents a hydrogen atom or -CO-RK R·" represents an alkyl group having 1 to 10 carbon atoms such as an ethyl group, a propyl group, a butyl group, a pentyl group or a hexyl group, and particularly an ethyl group, a propyl group and a butyl group. An alkyl group having 2 to 5 carbon atoms such as a pentyl group is preferred). q represents an integer of 1 to 2 0, and is preferably 5 to 10 0.

(V) In the above formula (V), W 3 represents an alkyl group having 1 to 50 carbon atoms or a hydroxyalkyl group having 1 to 5 carbon atoms having 1 to 5 hydroxyl groups, wherein a stearyl group or the like is used. The alkyl group having 10 to 20 carbon atoms, and the hydroxyalkyl group having 1 to 2 carbon atoms having 1 to 2 hydroxyl groups, such as a hydroxystearyl group, are preferred. The content of the repeating unit represented by the formula (I) or (II) in the graft copolymer of the present invention is preferably a high value, usually 5 0 丨 11 ο 1 % or more, and 70 ο ο % or more. Preferably. At the same time, there is a repeating unit represented by the formula (I) and a repeating single 3 12/inventive formula of the formula (II), and the cake patch V93-04/93 101159 33 1296639 may also have a content ratio which is not particularly limited. Preferably, the repeating unit represented by the formula (I) is contained. The total number of repeating units represented by the formula (I) or (II) is usually from 1 to 100, preferably from 10 to 70, and further preferably from 20 to 50. Further, a repeating unit other than the formula (I) and the formula (I I ) may be contained, and other repeating units may, for example, be an alkylene group or an alkyleneoxy group. The graft copolymer of the present invention preferably has -N Η 2 and -R I - N Η 2 (the definition of R I is the same as the above R 1 ). Further, the graft copolymer mainly belonging to the present invention may have a main chain which is linear or branched. The weight average molecular weight of the above dispersing agent as measured by GPC is preferably 3,0 0 0~1 0 0, 0 0 0, and particularly preferably 5,0 0 0~5 0,0 0 0. If the weight average molecular weight is 3 or less, the aggregation of the color material cannot be prevented, and sometimes the viscosity is high or gelatinized. If it exceeds 100,000, the viscosity itself is high, and It is not suitable for causing insufficient solubility in an organic solvent. The content of the above dispersing agent in the coloring composition is usually from 10 to 300% by weight based on the color component, preferably from 20 to 100% by weight, especially from 3 to 80% by weight. Preferably. If the dispersant component is too small, the adsorption of the color material is insufficient to prevent aggregation, and sometimes it causes high viscosity or gelation. On the other hand, if too much, the film thickness becomes too thick, and color filter is formed. After the filming, the gap control of the liquid crystal cell may occur in the liquid crystal cellization step, which is not suitable. For the above-mentioned method for synthesizing the dispersing agent, a conventional method can be employed, for example, the method described in the Japanese Patent Publication No. 63-300075. [1 - 3 - 3 ] consists of a block A with a quaternary ammonium base in the side chain and a quaternary ammonium 34 3 I , 1 K i<||jfh)/93-04/93 101159 1296639 The A-B block copolymer and/or the B-A-B block copolymer Λ-block composed of the segment B are used as the block copolymer of the dispersing agent, and have a quaternary ammonium test, preferably From -Ν - RI a R 2 a R 3 u · Υ _ (wherein R 丨 a, R 2 a, and R 3 a each independently represent a hydrogen atom or a cyclic or chain hydrocarbon group which may have a substituent, or The quaternary ammonium base represented by RI a, R 2 , and R 3 a may be bonded to each other to form a cyclic structure, and Y — represents a pair of anions. The quaternary ammonium base may be directly bonded to the main chain or may be bonded to the main chain by a divalent linking group. The cyclic structure formed by bonding two or more of R 1 u, R 2 a, and R 3 a to each other in -N · R h R 2 ; 1 R ^ can be, for example, 5 to 7 A nitrogen-containing heterocyclic monocyclic ring of a member ring or a condensed ring formed by condensation of two of the rings. The nitrogen-containing heterocyclic ring is preferably a non-aromatic one, and further preferably a saturated ring. Specifically, for example, the following configurations are exemplified:

(In the above formula, R represents any one of R 1 η to R 3 η) The cyclic structure may further have a substituent. Further, R i a to R 3 a in -fT R I a R 2 n R h is further preferably an alkyl group having 1 to 3 carbon atoms which may have a substituent, or a phenyl group which may have a substituent. It is preferable that the block A is a structure having a partial structure represented by a T-plane. 35 1296639 R4a CH2—c—

R

YR 2n (1) (In the above formula (1), R ! a, R 2 a, and R h each independently represent a hydrogen atom or a cyclic or chain hydrocarbon group which may have a substituent, or R ! a, R 2 a, and two or more of Rh may be bonded to each other to form a cyclic structure, R " represents a hydrogen atom or a thiol group, X represents a divalent linking group, and Y ^ represents a pair of anions) In the general formula (1), the divalent linking group X may, for example, be an alkyl group having 1 to 10 carbon atoms (including a methylene group), an exoaryl group, and -C Ο N Η - R "^. -, -C 0 0 - R ; 1 - [wherein R 5 a and R "each independently represent a direct bond, an alkylene group having a carbon number of 1 to 10 (including an anthracenylene group), or a carbon number 1~1 0®® (_ R 7 Μ - 0 - R 8 a - : R 7 ; 1 and R 8 a each independently represent a stretching group (including methylene)], etc. 0 - R 6 - Preferably, the cation of the anion may, for example, be C 1 _, B r' Γ, CI 0 , BF-. > C II ; 3 C Ο Ο , PFr or the like. A part of the structure containing a specific quaternary ammonium base may be contained in one block A or more. In this case, two or more kinds of the quaternary ammonium-containing partial moiety structure may be contained in the block enthalpy in a state of random copolymerization or block copolymerization. Further, the quaternary ammonium base is not contained. A part of the structure may be contained in the block crucible. An example of the structure of the part may be a description of 36 3丨2/fab as described later (_piece)/93-04/93 101丨59 1296639 ( The mercapto group is a part of the structure of the acrylate monomer, etc. The content of the portion containing no quaternary ammonium base in the block A is preferably 0 to 50 wt%, and 0 to 2 0 wt. % is further preferred, but most suitably, such a moiety structure not containing a quaternary ammonium base is not contained in block A. On the other hand, to form block B of the dispersant block copolymer, For example, a polymer structure obtained by copolymerization of the following copolymerization monomers: a styrene monomer such as styrene or α-methylstyrene; and a (meth)acrylic acid (mercapto) ethyl acrylate, (mercapto) acrylic propylene vinegar, (mercapto) acrylic acid isopropyl S, (mercapto) butyl acrylate, (meth) acrylic acid shrinkage Oil vinegar, benzyl sulfonate, hydroxyethyl acrylate, methacrylic acid, glycidyl ethoxide, bismuth acrylate, hydrazine-diethylamine acrylate Monomer; (mercapto) acrylate monomer such as (fluorenyl) propylene helium; such as (fluorenyl) acrylamide, hydrazine-hydroxy decyl acrylamide, hydrazine, hydrazine-dimethyl methacrylate Amine, hydrazine, hydrazine, dimercaptoethyl acrylamide, etc. (mercapto) acrylamide monomer; vinyl acetate; acrylonitrile; allyl glycidyl ether; glycidyl ether of crotonic acid; - Mercaptopropene morpholine and the like. The block oxime is a (fluorenyl) acrylate monomer represented by the following formula (I I ). A part of the structure is particularly preferable. In addition, "( in eth ) acry 1", "( in eth ) acry 1 ate", etc., as used in the specification means "acry 1 or ni ethacry 1", "acry 1 ate or methacrylate", etc., for example. "(Mercapto) acrylic" means "acrylic or mercaptoacrylic". R 9a --ch2-c-- τ ιτ COOR 1〇a (II) 37 3 12/Notes (Supplement)/93-04/93 101159 1296639 (In the above formula (1 I ), R π ··· represents a hydrogen atom or a fluorenyl group, and R μ represents a cyclic or chain alkyl group which may have a substituent, an allyl group which may have a substituent, or an aralkyl group which may have a substituent. The partial structure of the above (fluorenyl) acrylate-based monomer may be contained in one block or more in two or more types. Of course, the block enthalpy may also have a partial structure other than the above partial structure. Where more than two of the monomeric constituents are present in a block enthalpy which does not contain a quaternary ammonium base, the partial structures are contained in the block enthalpy in the form of random copolymerization or block copolymerization. Also. In the case where the block is ordered to have a structure other than the partial structure derived from the above (fluorenyl) acrylate monomer, the content of the moiety other than the (fluorenyl) acrylate monomer is in the block enthalpy. It is preferably from 0 to 50% by weight, more preferably from 0 to 20% by weight, but most suitably, a part of the structure other than the (fluorenyl) acrylate monomer is not contained in the block. B. The dispersing agent used in the present invention is a Λ-B block or a B-A-B block copolymerized polymer compound composed of such a block A and a block B, and such a block copolymer is, for example, Prepared by the living polymerization method shown below. The living polymerization method includes an anionic living polymerization method, a cationic living polymerization method, and a radical living polymerization method. The anionic living polymerization method uses an anion as a polymerization active species, and can be represented, for example, by the following scheme. (Anionic living polymerization method) Monomer-1: h2c=ch Monomer-D: % of h2c=ch

Ar1 Ar2 n h2c=9h " + Organometallic (M) Compound 38 1296639 Monomer 1

Monomer one (D Η

—(3二""川"丨"Μ®I, Ar1 -CH〇—ChP"""""" Μ® L :CH〇—CH-l—CHo—ChP"""""" I ' Ar2" CH2—CH*iJ CH2-CH L Ar ΌΗ2-CH Arl ΌΗ2_CH ίι n+1 n+1 m+1

Ar2

The radical living polymerization method uses a radical as a polymerization active species, and can be expressed, for example, by a flow chart as follows. (Free radical living polymerization method · Niobium method)

Occasion

39 1296639 (Free radical living polymerization method: atrp method) Monomer-1: h2c=ch Monomer 2: h2c=ch Occasion COOR8 COORb h2c=ch COORa. + Organometallic (Me) compound

Me: transitional gold. Body 2, /uvuGHo— I COOR8 , CH2—CH——: COOR* , CH2—CH— -CH2—CH""""Me COOR8 :CH2—CH-1 CH2— CH,"""Me Press again, Lite open ο 1 y id . Andrews II atada , 18,1037 (1987), (1989), (1987), (1985), M acr 〇ni o : In the synthesis of the dispersing agent used in the present invention, Japanese Patent Publication No. -9-62002, P. Lutz, P. Masson et al, Bull. 12, 79 (1984), β·C· Anderson can be used. , G· D. et a 1 , M acrom ο 1e c u1e s, 14,1 6 0 1 (1 9 8 1 ), KK Ute, et al, Poly in. J. 17,977 (19 8 5), (1 9 8 6 ), right hand Hao Yi, Putian Gengyi, polymer processing, 3 β, 3 β 6 Dongcun Min Yan, Ze Benguang male, polymer papers, 4 β,1 8 9 I Kuroki, Τ· Aida, J. Am. Chem. Sic, 1 0 9,4 7 3 7 Ai Tian Zhuo San, Jing Shang Xiang Ping, Organic Synthetic Chemistry, 4 3 , 3 〇〇D . Y . S 〇g 〇h , W . R . H ert 1 ereta 1 , 1 ecu 1 es, 2 0,] 4 7 3 ( ] 9 8 7 ) and other known methods. Dispersant used 'whether it is A, β block copolymer or Β - A - Β 40 3 12 / hair _ « 明 补 补 ) / 93-04/93 101159 1296639 block copolymer, constitutes a copolymer The block A / inset is in the range of 1 / 9 9 or more (especially in the case of 5 / 9 5 or more, which is preferably 6 0 / 40 or less). It has good heat resistance and dispersibility here. Furthermore, the amount of the quaternary ammonium base in the 1 g of the AB block copolymer used in the present invention is usually in the range of (if outside the range, sometimes it is not possible to have both good and normal, usually in such a block copolymer) The amine group produced by hydrazine has an amine price of 1 0 0 mg - the amine value is the same as the basic amine group using an acid to perform the corresponding method, and the 表示 Ο Η 丨 τ ι g number is expressed as a province. Further, the acid value of the block copolymer differs depending on the presence or absence of the type, and is generally lower than 0 mg - K 0 H / g, and the molecular weight is usually more than 1 000 in the case of benzene. The molecular weight of 1 0 0,0 0 0 or less is less than 1 0 0 0, the dispersion stability is 1 0 0,0 0 0, and the graft copolymer of nitrogen atom with reduced imaging and resolution is used. In the present invention, the agent is used in combination with a specific binder to be described later, and the high adhesion formed by the colored resin composition and the residual of the undissolved matter are not included. It is best to contain a wall acid ester type dispersant. The borrowing property becomes better. 3丨2/Invention Manual (supplement)/93-04/93101 59-stage B ratio (weight ratio) is better than 8 0 / 2 0 (except when it is out of range, sometimes it is impossible to mix, Β-Α-Β block copolymerization). 1~1 0 in m ο 1 Good, but heat resistance and dispersion. Sometimes contained in the manufacturing process - Κ Ο H / g degree. Press again, and titrate to compare the acid value with the t value. The acidity of the source of the acid value is preferably, and is usually a ratio of the weight averaged. The block copolymer will decrease, and if it exceeds the tendency. It must be contained in order to suppress the dispersion of the coating film and the substrate while maintaining the dispersion due to this specific dispersion. The block copolymer may be such that the ester 41 1296639 phosphate is one of the mono- to tertiary esters, but a primary ester is preferred from the viewpoint of dispersibility. The structure of the moiety to be bonded to the phosphoric acid may, for example, be a structure having a hydroxyl group at the terminal represented by a polyester (e.g., polycaprolactone or the like) or a polyether (e.g., polyethylene glycol). The part which is combined with phosphoric acid is also a copolymer of polyester and polyether. Further, this portion may have a double bond such as a (fluorenyl) acrylate at one end of the polyester chain and/or the polyether chain, and may form a copolymer with another radical polymerizable compound. Specifically, it is preferably a phosphate ester having a partial structure represented by the following structural formula (3):

For the synthesis of the phosphoric acid ester, for example, it can be produced by the method described in Japanese Patent Publication No. Sho. 50-2 2 5 3 3, and JP-A-59-81-2839. The molecular weight M w of the above-mentioned filler-type dispersing agent is usually in the range of usually 200 or more, and more preferably in the range of usually 5,000 or less, and preferably not more than 1,000. This phosphate type dispersant is originally added for the purpose of imparting imaging solubility, and thus the molecular weight is too high and is not suitable. Further, the content of the phosphate ester-type dispersant is usually 5 parts by weight or more based on 100 parts by weight of the block copolymer (preferably 10 parts by weight or more). 100 parts by weight or less (more preferably 80 parts by weight or less). If the ratio of the phosphate ester is too low, sufficient development solubility may not be exhibited. On the other hand, if the ratio of the phosphate ester is too high, the effect is saturated, and the dispersion may be lowered. 42 312/Invention Manual (Supplement)/93-04/93101159 1296639 [1 _ 4 ] Adhesive Resin The colored resin composition according to the present invention is suitable when a color filter substrate is manufactured by coating on a transparent substrate. Used to act as a coating liquid. Hereinafter, a case where the curable colored resin composition for a color filter is used will be described as an example. The binder resin in the present invention contains any of the following resins. [1 -4- 1 ] In the present invention, a resin having a structure obtained by adding an epoxy moiety containing an epoxy group-containing unsaturated compound (b) to a carboxyl group of the carboxyl group-containing resin (a) may be separately used. Use or use in combination. The resin (a) containing a carboxyl group is not particularly limited, but usually, a polymerizable monomer having a carboxyl group is polymerized to obtain the resin. Examples of the polymerizable monomer having a carboxyl group include (mercapto)acrylic acid, maleic acid or maleic anhydride, crotonic acid, decylene succinic acid, fumaric acid, and 2- (methyl) propylene oxirane ethyl succinic acid, 2-propenyl oxiranium diethyl adipate, 2-(methyl) propylene oxiranium decanoic acid, 2-(methyl) propylene oxirane ethyl Hydrogen phthalic acid, 2-(indenyl) propylene oxirane ethyl maleic acid, 2-(indenyl) propylene oxypropyl succinic acid, 2-propylene oxypropyl adipic acid, 2-( Methyl) propylene oxime propyl hydroquinone, 2-(indenyl) propylene oxypropyl decanoic acid, 2-(methyl) propylene fluorenyl propyl maleate, 2-(indenyl) propylene醯oxybutyl succinic acid, 2-propenyloxybutyl adipate, 2-(methyl) propylene oxy butyl hydroperic acid, 2-(indenyl) propylene oxybutyl phthalic acid, 2- (Meth) propylene oxirane maleic acid, from (meth)acrylic acid and lactones such as £-caprolactone, /3-propiolactone, 7-butyrolactone, 5-valerolactone Monomer, from (曱基) 312 / invention specification (supplement) /93-04/93101159 43 1296639 hydroxy acrylate Esters with succinic acid or anhydride, phthalic acid or phthalic anhydride, maleic acid or maleic anhydride of the acid or anhydride monomer addition. Among them, (meth)acrylic acid and 2-(fluorenyl)acryloxyethyl succinic acid are preferred, and (mercapto)acrylic acid is further preferred. It is also possible to use this monomer in two or more types. The carboxyl group-containing resin (a) may be copolymerized with the above-mentioned carboxyl group-containing polymerizable monomer and another polymerizable monomer having no carboxyl group. The other polymerizable monomer is not particularly limited, and examples thereof include decyl acrylate, ethyl (meth) acrylate, propyl (mercapto) acrylate, and isopropyl (meth) acrylate. Butyl butyl acrylate, isobutyl (meth) acrylate, (mercapto) benzyl acrylate, phenyl (meth) acrylate, cyclohexyl (meth) acrylate, phenoxy acrylate , (mercapto) phenoxymethyl acrylate, 2-ethylhexyl (meth) acrylate, (mercapto) acrylate; ester, 2-hydroxyethyl (meth) acrylate, glycerol mono (曱) Acrylate, (fluorenyl) tetrahydrofuran methyl acrylate, styrene and its derivatives, α-mercapto styrene, such as poly(fluorenyl) decyl acrylate macromonomer, polystyrene macromonomer, multi ( 2-hydroxyethyl acrylate macromonomer, multi-ethylene glycol macromonomer, polypropylene glycol macromonomer, polycaprolactone giant monomer and other macromonomers. In the above, styrene, methyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, 4-hydroxybutyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, ( Mercapto hydroxypropyl acrylate, butyl (meth) acrylate, and isobutyl (meth) acrylate are preferred. This monomer may be used in combination of two or more kinds. Also, in the specification, "(meth)acryl~", 44 312/invention specification (supplement)/93-04/93101159 1296639 "(meth)acrylate", etc. means "acryl ~ or methacryl ~" "acrylate or methacrylate", etc., for example, "(mercapto)acrylic acid" means "acrylic acid or methacrylic acid". The carboxyl group-containing resin (a) is preferably one having a hydroxyl group further from the viewpoint of dispersibility of the pigment. In particular, it contains hydroxyalkyl (meth) acrylate such as 2-hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, etc., glycerol mono (曱) Preferably, the acrylate is a copolymer of a copolymerization component. Specifically, a polymerizable monomer having no hydroxyl group such as decyl methacrylate, benzyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, (A) Base) cyclohexyl acrylate, cycloheximinimide, and the like, and a polymerizable monomer such as (meth)acrylic acid 2-ethyl ester, (meth) hydroxypropyl acrylate, (fluorenyl) A copolymer obtained by copolymerization of (4-hydroxybutyl) acrylate or the like and (fluorenyl) acrylic acid. Further, specific examples of preferred resins include decyl acrylate, decyl (meth) acrylate, decyl (meth) acrylate, and butyl (meth) acrylate. a copolymer of (mercapto) acrylate such as isobutyl acrylate, 2-hydroxyethyl (meth) acrylate and (meth) acrylate; styrene / (mercapto) acrylic copolymer; styrene / α-decyl styrene / (meth) acrylic acid copolymer; cyclohexyl maleimide / (fluorenyl) acrylic acid copolymer. The acid value of the "carboxyl group-containing resin (a)" in the present invention is usually 30 to 500 KOHmg/g, preferably 40 to 350 KOHmg/g, and more preferably 50 to 300 KOHmg/g. Further, the compound is added to the "carboxyl group-containing resin (a) when a compound containing ethyl blister 45 312 / invention specification (supplement) / 93-04/93101159 1296639 and a group and an epoxy group are added. The introduction rate of the carboxyl group is usually set at 10 m ο 1 % or more (more preferably 30 m ο 1 % or more), and 90 m ο 1 % or less (at 80 m ο 1 / /. Within the scope of). When the introduction ratio is too low, the side chain having an ethylenically unsaturated double bond cannot be sufficiently introduced, so that a tendency to obtain sufficient dispersibility is formed, and if it is too high, the solubility of the colored resin composition is deteriorated. In the present invention, the weight average molecular weight of the resin containing a carboxyl group (a) measured by GPC is usually 200 or more (more preferably 3,000 or more, and further preferably 4,000 or more). Preferably, it is in the range of 100,000 or less (preferably 800,000 or less, and further preferably 5,000 or less). If the weight average molecular weight is too small, poor liquid stability is obtained, and if it is too large, the solubility of the colored resin composition tends to deteriorate. The epoxy group-containing unsaturated compound (b) is a compound containing an ethylenically unsaturated group and an epoxy group in one molecule thereof. Examples of the epoxy group-containing unsaturated compound (b) include glycidyl (mercapto)acrylate, allyl glycidyl group, α-ethyl acrylate glycidol, and croton S& glycidol. An acyclic epoxy group-containing unsaturated compound such as a base bond, (iso)crotonate glycidyl ether or 4-hydroxybutyl (meth)acrylate glyceryl ether, but in terms of heat resistance and decomposability, The alicyclic epoxy group-containing unsaturated compound is preferred. Here, examples of the alicyclic epoxy group include 2,3-epoxycyclopentyl group, 3,4-epoxycyclohexyl group, and 7,8-epoxy [tricyclo[5 · 2 · 1 · 0 ] 癸 2 _ base] and so on. Further, it is preferred that the ethylenically unsaturated bond is derived from a (meth) acrylonitrile group. 46 312/Invention specification (supplement)/93-04/93101159 1296639 is a suitable alicyclic epoxy group-containing unsaturated compound, and specific examples thereof include (3,4-epoxycyclohexyl)methyl ( Methyl) acrylate, a compound represented by the following chemical formulas (1) to (15), and the like.

4 represents a hydrogen atom or a sulfhydryl group) (1)

Rib 〇ch2=cc-〇~R2~〇tto° (2) The number of raw carbons is shown in the table b 2 R 曱 or sub-raw nitrogen shows b R Chinese formula 曱 括 / / IV alkyl olefin Carbon indicating table b 2 R hydrazine or sub-raw nitrogen showing the formula b R

RIC II 2 Η C

\, 4 /V number of raw carbon table b 2 R base or sub-raw nitrogen table b R Chinese formula number of raw carbon table b 3 R \J / base group of sub-package / IV base of the base hydrocarbon k or ο shows the number of the whole table 312 / invention manual (supplement) /93-04/93101159 47 1296639

R lb 〇 I 10 II C H2^6 — 0 〇—R 2b k>° (wherein, R lb represents a hydrogen atom or a methyl group of a methyl group (including an anthracenylene group))

RlK 0 R ικ I lb ii I lb CH2 = C — C—N—R01—〇 R 2b .0 (wherein each R lb represents an alkylene group independently representing a hydrogen atom number of 1 to 10 (including sub Methyl CH2mbR2irQ (wherein each Rlb independently represents an alkylene group (including a methylene group) having a hydrogen atom number of 1 to 10) Rlb〇I 10 II C - 0-0-R (wherein Rlb represents Hydrogen atom or sulfhydryl group, alkyl group of R2 (including methylene group)

Μ C H2=C — C-〇-R2bY, p 0 .C-〇-CH2

(wherein Rb represents a hydrogen atom or a methyl group, R2 (5) b represents a carbon atom number of 1 to 10 (6) atoms or a methyl group, R2b represents a))) (7) or a fluorenyl group, and R2b represents a carbon source (8) b represents a carbon number of 1 to 10) (.9) b represents a carbon number of 1 to 1 0 312 / invention specification (supplement) /93-04/93101159 48 1296639 of an alkyl group (including an anthracene group)

R]b0 I Ιϋ II C H2 = C — C 〇 R

2b HO

〇CH2-0-C -〇ο (10) (wherein, Rib represents a hydrogen atom or a methyl group, and R2b represents a stretching group having a carbon number of 1 to 10 (including an anthracenylene group)) R" 0 I lb 11 CH2 =CC-〇-R ~CΗ 2b

HO (11) (wherein Rb represents a hydrogen atom or a fluorenyl group, and R2b represents a stretching group having a carbon number of 1 to 10 (including a methylene group)) Μ CH2=CC~〇7-sc h2-〇x HO/ W\CH2-0/CH^^i Ο (12) (wherein, Rlb represents a hydrogen atom or a sulfhydryl group)

Rlb〇 I II C Η 2 = C — C— Ο .· ΗΟ / O~C Η2 χ 〇- ch2/ch*-Q: 〇 (13) (wherein Rib represents a hydrogen atom or a sulfhydryl group)

Plbll CH〇=C-C~0- R

(14) (wherein Rlb represents a hydrogen atom or a methyl group, and R2b represents an alkylene group having a carbon number of 1 to 10 (including an anthracenylene group)) 312/Invention specification (supplement)/93-04/93101159 1296639

In the above formulae (1) to (15), R2b may, for example, be an anthracene group, an exoethyl group, a propyl group or a butyl group, and a methylene group, an ethyl group and a propyl group are preferred. Among the above formulas (1) to (15), the formula (3) is preferred. Among the above compounds, 3,4-epoxycyclohexyl decyl (meth)acrylate is preferred. The epoxy group-containing unsaturated compound may be used in combination of two or more. In the present invention, a resin having a structure in which an epoxy group containing an epoxy group-containing unsaturated compound (b) is added to a carboxyl group of the carboxyl group-containing resin (a) does not necessarily actually have an epoxy group-containing unsaturated compound. The carboxyl group-containing resin reacts to be produced, that is, the main result has the above configuration regardless of the passage. In order to react the epoxy group containing the epoxy group-containing unsaturated compound (b) with the carboxyl group of the carboxyl group-containing resin (a), a conventional method can be used. For example, the carboxyl group-containing resin (a) and the epoxy group-containing unsaturated compound (b) are in a tertiary amine (such as triethylamine, mercaptomethylamine, etc.), and a quaternary ammonium salt (such as dodecyltrimethyl chloride). In the presence of a catalyst such as ammonium, tetraammonium chloride, tetraethylammonium chloride, tetrabutylammonium chloride, benzyltriethylammonium chloride, etc., acridine or triphenylphosphine, in an organic solvent The epoxy compound is introduced into the carboxyl group of the carboxyl group-containing resin (a) by carrying out the reaction at a reaction temperature of 50 to 150 ° C for several hours to several tens of hours. The binder resin is preferably manufactured such that its acid value is usually 10 to 200 KOHmg/g, preferably 20 to 150 KOHmg/g, and 50 312/invention specification (supplement)/93-04/93101159 1296639 30 to 150 KOHmg/ g is further preferred. The weight average molecular weight (M w ) in terms of styrene in terms of GPC is usually set to 200 or more (preferably more than 4,000, more preferably more than 5,000), and 1 2 〇〇 The following is preferably in the range of 9000 Å or less, more preferably 5,000 Å or less, and particularly preferably 30,000 Å or less. If the weight average molecular weight is too small, poor liquid stability is obtained, and if it is too large, the solubility of the colored resin composition tends to deteriorate. The ratio of the above binder resin to the total solid content of the colored resin composition is usually from 1 〇 to 8 〇 w t %, preferably from 20 to 70 watt %. Further, the ratio of the color material is usually 2 0 to 3 0 w t °/. Preferably, it is preferably 3 0 to 2 0 0 w t %, and further preferably 4 0 to 1 0 0 w t %. [1 -4-2 ] In the present invention, the binder resin other than the above-mentioned nitrogen atom-free resin may be used singly or in combination. A particularly suitable binder resin is constructed by (A) 5 to 90 mol% of an epoxy group-containing (mercapto) acrylate and (B) another radical polymerizable compound 10 copolymerizable with the above component (A). ～9 5 mo 1 % of the copolymer is obtained by adding (C) unsaturated monobasic acid to 1 0 to 1 0 0 m ο 1 % of the epoxy group of the above component (A), and then making the polybasic anhydride ( D) A resin obtained by adding 10 to 10 mol% of a hydroxyl group (produced by the addition of the above component (C)). Hereinafter, such a binder resin will be described. <(A) (A) epoxy group-containing (meth) acrylate> Examples of the epoxy group-containing (meth) acrylate include (meth)acrylic acid glycidyl ester and (meth)acrylic acid 3 , 4-butoxybutyl acrylate, (3,4 epoxycyclohexyl) (meth) acrylate, 4-hydroxybutyl acrylate (meth) acrylate, glycidyl (meth) acrylate Preferably. 51 312/Invention specification (supplement)/93-04/93101159 1296639 The content of the (oxyalkyl) acrylate (A) containing an epoxy group in the monomer for copolymerization is usually set at 5 m ο 1 % or more ( Preferably, it is more preferably 20 m ο 1 % or more, and more preferably 3 0 m ο 1 % or more, and 9 0 m ο 1 % or less (more preferably 80 m ο 1 % or less, and 7 0 m ο 1% or less is further preferred). If the content is too large, the other components are reduced, and the heat resistance or strength is sometimes lowered. If the amount is too small, the addition amount of the polymerizable component and the soluble component is insufficient, and thus it is not suitable. <(B) Other radical polymerizable compound copolymerizable with the component (A)> Further, the component (B) contains a mono(meth)acrylic acid having a structure represented by the following formula (VI) Ester is preferred.

In the above formula (VI), R3 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms such as a methyl group, an ethyl group or a propyl group, and R9 and R!g each independently represent hydrogen. An atom or an alkyl group having 1 to 3 carbon atoms such as a methyl group, an ethyl group or a propyl group, or R 9 and R i 〇 may be bonded to form a ring. By R 9 and R1. The ring formed by the bond is preferably an aliphatic hydrocarbon ring. The aliphatic hydrocarbon ring may be either a saturated ring or an unsaturated ring, and preferably has a carbon number of 5 or 6. Among the above formula (VI), particularly preferred are mono(meth)acrylates of the following formula (VII), (VIII), or (IX):

(VII) (VIII) 52 312/Invention Manual (supplement)/93-04/93101159 1296639

For the conventional use of the mono(methyl)propyl group having the structure represented by the above formula (VI), for example, the following structural formula (X): ^^CH CH2&quot;·-C - C*~〇-R *j2 (X) Ο (In the above formula (X), Rh represents a hydrogen atom or a hydrazine according to the formula (VI)). The mono(indenyl) acrylate has the above formula (VI). The content of the structural monomer is usually set at 10 m ο 1 % or more (preferably), and 90 m ο 1 % or less (more preferably 70 m ο 1 % or less, and further preferably) Within the scope. Due to this configuration, there is heat or strength. The other component (B) is not particularly limited, and is as follows: styrene, styrene a-, o-, m-, p-non-nitro derivative, cyano derivative, guanamine derivative , ester-diene, 2,3-dimethylbutadiene, isoprene, chloroprene; such as methyl (meth) acrylate, n-propyl (meth) acrylate Isopropyl (meth)acrylate, (butyl) propylene (meth)acrylate, butyl (meth)acrylate, amyl (meth)acrylate, (methyl) Propylene (meth) hexyl acrylate, 2-ethylhexyl acrylate (lauryl) acrylate, lauryl (meth) acrylate, (methyl) propylene 312 / invention specification (supplement) / 93-04/93101159 enoate, which can be: R 1 2 indicates that it may increase the resistance to specific examples of the derivative of the compound, such as butene, in the copolymerization of 15 mol% or more and 5 0 m ο 1 % or less. Diene, (meth)propane "n-butyl acrylate, ester, (methyl)" isoamyl ester, (methyl) propyl acid cyclopentyl ester, 53 1296639 (fluorenyl) Cyclohexyl enoate, 2-methylcyclohexyl (meth) acrylate, dicyclohexyl (meth) acrylate, isomeric (meth) acrylate, tricyclo [3 · 3 · 1 · 13 '7 ] decyl ester, allyl (meth) acrylate, propargyl (meth) acrylate, phenyl (meth) acrylate, naphthyl (mercapto) acrylate, lysyl (decyl) acrylate , onion methyl (meth)acrylate, 3,4-methylene dimethacrylate (meth)acrylate, sulphate (meth) acrylate, furyl (meth) acrylate, furfuryl (meth) acrylate , (mercapto) tetrahydrofuran acrylate, (meth) acrylate, methacrylate, phenyl (meth) acrylate, toluene (meth) acrylate, (meth) acrylate 1, 1,1-trifluoroethyl ester, perfluoroethyl (meth) acrylate, perfluoro-n-propyl (meth) acrylate, perfluoroisopropyl (meth) acrylate, triphenyl methacrylate , (decyl) cumene acrylate, 3-(N,N-diguanamine) propyl (meth)acrylate, (methyl) (meth) acrylates such as 2-hydroxyethyl enoate and 2-hydroxypropyl (meth) acrylate; such as (mercapto) acrylamide, (mercapto) propylene hydrazine N, N - decylamine , (meth) propylene oxime N, N - diethylamine, (meth) propylene hydride N, N - dipropylamine, (mercapto) propylene hydrazine N, N - diisopropylamine, (meth) propylene allysamine (meth) acrylamide; such as (fluorenyl) acrylonitrile, (meth) acrylonitrile, acrolein, vinyl chloride, vinylidene chloride, vinyl fluoride, vinylidene fluoride, N - an ethylene compound such as vinylpyrrolidone, vinyl pyridine or vinyl acetate; such as diethyl decyl maleate, diethyl maleate, diethyl fumarate, methylene An unsaturated dibasic acid diester such as diethyl succinate; such as N-phenyl maleic acid monoamine, N-cyclohexane maleic acid monoamine, N-lauric acid N-(meth)acrylic acid oxime 312/N-(4-hydroxyphenyl) maleic acid monoimine, etc. Instruction manual (supplement) /93-04/93101159 54 129 6639 Imine, etc. It is effective to obtain at least one compound selected from the group consisting of styrene, (decyl) decyl acrylate, and maleic acid monoamine as a component (B) for the purpose of obtaining superior heat resistance and strength. . The content of the component (B) in the monomer for copolymerization is usually in the range of usually 10 mol% or more, preferably 20 m ο 1 % or more, more preferably 30 m ο 1 % or more, and further, usually It is preferably 9 5 m 〇 1% or less, preferably 80 ο 1 % or less, and further preferably 70 ο 1 % or less. If the content of the component (B) is too large, the amount of the polymerizable component and the soluble component to be added is insufficient because the component (A) is decreased. On the other hand, if the amount is too small, the heat retention property or the strength is lowered, which is not preferable. &lt;(C) Unsaturated monobasic acid&gt; The (C) unsaturated monobasic acid is added to 10 to 100 mol% of the epoxy group contained in the copolymer of the above component (A) and component (B). For the component (C), a conventional one can be used, and examples thereof include an unsaturated carboxylic acid having an ethylenically unsaturated double bond, and specific examples thereof include acrylic acid, mercaptoacrylic acid, crotonic acid, o-, and - p-vinylbenzoic acid, (mercapto)acrylic acid (3:-position, alkyl, alkoxy, nitro, cyano substituted, etc., etc., especially preferably acrylic or Mercaptoacrylic acid. The addition ratio of the component (C) is based on the epoxy group contained in the copolymer of the component (A) and the component (B), and is usually set at 10 m ο 1 % or more (at 3 m ο 1 % or more is preferable, and more preferably 50 mol% or more, and 100 mol% or less. If the addition ratio is too low, the residual epoxy group may have a bad influence on stability over time and the like. &lt; (D) Polyhydric anhydride&gt; 55 312/Invention specification (supplement)/93-04/93101159 1296639 The epoxy group added to the copolymer of the component (A) and the component (B) from the component (C) The 10 to 100 mol% of the radical generated at the time causes the polybasic anhydride (D) to function as an addition. The use of the polybasic anhydride (D) is intended to impart solubility to the binder resin of the present invention, and a conventional polybasic anhydride can be used for this purpose, and examples thereof include, for example, maleic anhydride, succinic anhydride, and sub-anhydride. Mercaptosuccinic anhydride, phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, 1,4,5,6,7,7-hexachlorobicyclo[2·2·1]-5-heptene-2,3 a dibasic anhydride such as phthalic anhydride; a polybasic anhydride such as trimellitic anhydride, 1,2,4,5-benzenetetraphthalic anhydride, diphenylketone tetraphthalic anhydride or biphenyl tetraphthalic anhydride. Among them, tetrahydrophthalic anhydride or succinic anhydride is preferred. The addition ratio of the polybasic anhydride is based on the molar ratio of the total amount of the hydroxyl groups generated when the component (C) is added to the epoxy group, and is usually set at 10 m 〇 1% or more (at 20 m ο 1 %). Preferably, the above is more preferably 30 m ο 1 % or more, and 1 0 0 m ο 1 % or less (more preferably 9 0 in ο 1 % or less, and further preferably 80 ο 1 % or less). In the range of ) to perform the addition. If the addition rate is too high, the residual film ratio at the time of development may be lowered, and if it is too low, the solubility may be insufficient. &lt;Method for Producing Binder Resin&gt; For the copolymerization reaction between the component (A) and the component (B), a conventional solution polymerization method can be applied. The solvent to be used is mainly inert to the radical polymerization, and is not particularly limited, and an organic solvent which is usually used can be used. For example, specific examples thereof include ethyl acetate, isopropyl acetate, and ethylene glycol monoalkyl ether acetate (e.g., 2-ethoxyethyl acetate, 2-butoxyethyl acetate, etc.). a mono-alkyl ether acetate (eg, ethylene glycol monomethyl ether acetate, carbitol acetate, tetracaine acetate, etc.), 56 312/Invention Manual (supplement)/93-04/93101159 1296639 Propylene glycol monoalkyl ether acetate, ethyl acetate of monohydric (propylene glycol) monoethyl ether acetate; ethylene glycol dialkyl ether Class; a condensed oxime (ethylene glycol) dialkyl ethers (such as carbaryl alcohol, carbitol, tetracaine, etc.); di-tris (ethylene glycol) dialkyl ethers; propylene glycol II Alkyl ethers; monohydric (propylene glycol) dialkyl ethers; ethers (such as 1,4 - di- ethane, tetrahydrofuran, etc.); ketones (such as acetone, methyl ethyl ketone, decyl isobutyl) Ketones, cyclohexanone, etc.); hydrocarbons (benzene, toluene, diphenyl, octane, decane, etc.); petroleum solvents (such as petroleum ether, naphtha, hydrogenated naphtha, solvent naphtha) ); Lactic acid esters (e.g. methyl lactate, ethyl lactate, butyl lactate, etc.); Yue-yl two Yue Amides; N-rattle slightly bite Yue-yl ketone. These solvents may be used singly or in combination of two or more. The solvent is used in an amount of 100 parts by weight based on the weight of the binder resin, usually 30 parts by weight or more (more preferably 50 parts by weight or more), and 1 part by weight (weight). The following (with a weight of 800 parts by weight or less). If it is outside this range, it is difficult to control the molecular weight. The radical polymerization initiator used in the present invention is mainly used to initiate radical polymerization, and is not particularly limited, and an organic peroxide catalyst or an azo compound which is usually used can be used. For example, specific examples thereof can be classified into conventional ketone peroxides, peroxy condensates, hydroperoxides, di-bromo peroxide, bismuth peroxide, peroxyesters, peroxydicarbonates, and further, Azo compounds are also effective. As a specific example, for example, benzammonium peroxide, difenyl peroxide, dicumyl peroxide, ditributyl peroxide, tert-butyl peroxybenzoate, or benzoquinone can be used. Acid hexyl hexyl ester, peroxy-2-ethylhexanoic acid III 57 312 / invention specification (supplement) / 93-04/93101159 1296639 butyl ester, peroxy-2-ethylhexyl trihexyl ester, 1,1-bis(t-butoxy)-3,3,5-trimethylcyclohexane, hydroperoxide 2,5-diindole-2,5 tributylperoxy)hexyl-3,3-iso Propyl, tert-butyl hydroperoxide, difenyl, difenyl hydroperoxide, ethoxylated oxime, peroxybis(4-tert-butylcyclohexyl), diisopropyl peroxydicarbonate Ester, isobutyl, 3, 3, 5 -trimethylhexyl peroxide, laurel, 1,1 double (third butyl peroxy) 3,3,5-trimethylcyclohexane, 1 , 1 double (peroxy) 3,3,5-trimethylcyclohexane, azobisisobutyronitrile, azobis and the like. The amount of the radical polymerization polymerization initiator which is selected according to the polymerization temperature to be an appropriate half-reduction period is based on 100 parts by weight of the total amount of the copolymerization reaction, and is usually set at 0.5 part (weight i (in 1 part) It is preferably (by weight) or more, and is in the range of 20 parts by weight or less (preferably 1 or less). In the polymerization method, the monomer used in the copolymerization reaction and the self-initiating initiator are dissolved in a solvent, and the mixture is heated while being stirred to carry out polymerization, or the monomer to which the radical polymerization initiator is added is added dropwise to the mixed solution. Also in the solvent. The reaction conditions may be in accordance with the target molecular weight. The reaction temperature is usually set at 70 ° C or higher (preferably at 80 ° C or higher): or less (preferably at 130 ° C or lower). Further, the reaction is carried out for a period of 2 hours or longer (preferably 3 hours or longer), and 20 hours for preferably 10 hours or less. In order to add the unsaturated monobasic acid (C) to the above copolymer, a conventional method can be used for the addition of the anhydride (D). Furthermore, in the present invention, in order to improve the light sensitivity, it is also possible to pass-double (peroxy oxycarbonate, third carbon ruthenium) in 312/invention specification (supplement)/93-04/93101159. Amine I hair. Use a single t) above (the weight of the base polymerization reaction is also heated to change, 丨150〇C between the system (to make the polynuclear anhydride 58 1296639 (D) addition, the resulting One part of the carboxyl group, such that the glycidyl (meth)acrylate or the glycidyl ether compound having a polymerizable unsaturated group functions as an addition' or, in order to improve the developability, after the addition of the polybasic anhydride (D), The glycidyl ether compound having no polymerizable unsaturated group is added to one part of the generated carboxyl group. Further, the two may be used in combination. Specific examples of the glycidyl ether compound having no polymerizable unsaturated group Examples include glycidol mystery compounds having a phenyl group or a burnt group ("Nagase Chemical Industry", trade name: Denacol EX-111, Denacol EX-121, Denacol EX-141, Denacol EX-145, Denacol EX-146, Denacol EX-171 , DenacolE X-192), etc. The weight average molecular weight (M w ) of the adhesive resin of the present invention measured by GPC (gel permeation chromatography) is usually set at 200 or more (more preferably 3,000 or more, Further, it is more preferably 5,000 or more, more preferably 100,000 or less (preferably 50,000 or less, further preferably 10,000 or less, particularly preferably 8,000 or less), and the weight average molecular weight is less than 2. When 0 0 0, poor heat resistance and film strength are obtained, and if it exceeds 1 Torr, the solubility in the developing solution is insufficient, so that it is not suitable. In order to prevent the dry coagulation of the tip end of the die at the time of coating from being promoted, it is preferable to set it to 1 or less. Further, the molecular weight distribution (Mw/Μη) is preferably 2 to 5. The content of the agent resin in the total solid content of the colored resin composition of the present invention is usually set at 10% by weight or more (more preferably 20% by weight or more), and 80% by weight or less (less than 7% by weight). In addition, the ratio of color materials is usually set at 20% or more (at 30% by weight) Preferably, it is further preferably 5 wt 0 wt % or less (5 wt 0 wt % or less), and preferably 5 wt 0 wt % or less, and is preferably 50 % % 59 312 / invention specification (supplement) / 93-04 / 93101159 1296639 2 0 0 wt % or less is further preferred). Further, as for the resin structure, it is described in Japanese Patent Laid-Open Publication No. Hei 08-269-36, or JP-A No. 2, However, as described above, it is required to cooperate with a dispersing agent having a specific structure to achieve a desired effect. [1 - 5 ] Organic carboxylic acid, organic carboxylic anhydride The colored resin composition of the present invention may also contain a molecular weight of 1 An organic carboxylic acid and/or an organic carboxylic anhydride of less than 0 0 0. Preferably, when the dispersing agent is an urethane dispersing agent, the organic ferulic acid and/or organic scorpion liver is contained. Specific examples of the acid compound include an aliphatic carboxylic acid or an aromatic carboxylic acid. Examples of the aliphatic carboxylic acid include citric acid, acetic acid, propionic acid, butyric acid, valeric acid, trimellitic acid, and caproic acid. a monocarboxylic acid such as glycolic acid, acrylic acid or mercaptoacrylic acid, such as oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, cyclohexyl dicarboxylic acid, cyclohexene dicarboxylic acid a dicarboxylic acid such as sulfhydryl succinic acid, methyl maleic acid, maleic acid or fumaric acid For example, a tricarboxylic acid such as propylene terephthalic acid or 1,2,3-propylene tridecanoic acid, etc. Further, the aromatic carboxylic acid may be directly bonded to a phenyl group such as benzoic acid or citric acid. a carboxylic acid having a carboxyl group; and a carboxylic acid having a carboxy group bonded to a carboxy group by a carbon bond. Among them, a carboxylic acid having a molecular weight of 6,000 or less, particularly a molecular weight of 50 to 50,000 is preferable, specifically, cis. The enedic acid, succinic acid, and methylene succinic acid are preferred. The organic carboxylic anhydride compound may, for example, be an aliphatic carboxylic anhydride or an aromatic carboxylic anhydride. Specific examples thereof include acetic anhydride and trichloroacetic anhydride. , trifluoroacetic anhydride, tetrahydroanthracene 60 312 / invention specification (supplement) / 93-04/93101159 1296639 anhydride, succinic anhydride, maleic anhydride, methylene succinic anhydride, glutaric anhydride, 1, An aliphatic carboxylic anhydride such as 2-cyclohexene phthalic anhydride, n-octadecyl succinic anhydride or 5-decanethene-2,3-dicarboxylic anhydride, and examples of the aromatic carboxylic anhydride include phthalic anhydride. a trimellitic anhydride, 1,2,4,5-benzenetetracarboxylic anhydride, naphthoic anhydride, etc., particularly preferably a carboxylic anhydride having a molecular weight of 600 or less, particularly a molecular weight of 50 to 500, specifically, a maleene Diacetate, The dianhydride and the methylene succinic anhydride are preferably used. The amount of the organic carboxylic acid and/or the organic carboxylic anhydride (the ratio of the total solids) is usually set at 0. 0 1 to 1 0 wt %. It is preferably in the range of 0.03 to 5 wt%, more preferably 0.05 to 3 wt%. By adding the organic carboxylic acid and/or the organic carboxylic anhydride having a molecular weight of less than 1 000, it is possible to further reduce the residual of the undissolved material of the colored resin composition while maintaining the pattern adhesion of the height. In the patent No. 3 2 3 3 1 7 1 , although a method of adding an organic carboxylic acid compound having a molecular weight of 1 or less to a coloring composition is proposed, as described above, the denseness of the image portion may be caused according to this method. The decrease in the compatibility causes the development range to be narrowed, and the peeling of the pixels is liable to occur, and whitening defects are liable to occur. However, in the combination of the dispersant and the binder resin according to the present invention, even if an organic carboxylic acid and/or an organic carboxylic anhydride is added, such a phenomenon does not occur, and only the effect of reducing the residual of the undissolved matter is exhibited. [1 - 6 ] Photopolymerizable monomer The photopolymerizable monomer is mainly a polymerizable low molecular compound, and is not particularly limited, but is preferably an addition polymerizable compound having at least one ethylenic double bond ( Hereinafter referred to as "ethylene compound"). The ethylenic compound is a compound having an ethylenic double bond, and the double bond causes the resin composition of the invention 61 312 / invention specification (supplement) / 93-04/93101159 1296639 color resin to be irradiated by active light. The photopolymerization initiating system is subjected to addition polymerization to be hardened. Further, the meaning of the monomer of the present invention is a concept opposite to the so-called high molecular substance, and includes the concept of a dimer, a trimer, and an oligomer in addition to a monomer having a narrow meaning. The ethylenic compound may, for example, be as follows: unsaturated taurine; an ester formed from an unsaturated carboxylic acid and a monohydroxy compound; an ester formed from an aliphatic polyhydroxy compound and an unsaturated carboxylic acid; An ester formed by a hydrocarbon compound and an unsaturated carboxylic acid; obtained by esterification of an unsaturated carboxylic acid with a polyvalent carboxylic acid and a polyvalent hydroxy compound (such as the above aliphatic poly-peripheral compound, aromatic poly-peripheral compound, etc.) An ester; an ethyl amide compound having an urethane skeleton obtained by a reaction of a polyisocyanate compound and a hydroxy compound containing a (meth) acrylonitrile group. Examples of the ester formed of the aliphatic polyhydroxy compound and the unsaturated carboxylic acid include ethylene glycol diacrylate, triethylene glycol diacrylate, and trimethylolpropane triacrylate. Trimethylolethane triacrylate, pentaerythritol dipropionate s, isoprenol trisuccinate, isopentanol tetraacrylate, diisopentaerythritol tetraacrylate, two An acrylate such as pentaerythritol pentaacrylate, diisopentyl alcohol hexaacrylate or glycerin acrylate. Further, the methacrylate in which the acrylic acid moiety of the acrylate is partially substituted with methacrylic acid, the fluorenyl succinate partially substituted by methylene succinic acid, is partially crotonic acid. A substituted crotonate or a maleic acid ester substituted with a maleic acid moiety. Examples of the ester formed of the aromatic polyhydrocarbon compound and the unsaturated carboxylic acid include hydroquinone diacrylate, hydroquinone dimethacrylate, resorcinol dipropylene 62 312/invention specification (supplement)/ 93-04/93101159 1296639 Oleate, resorcinol dimethacrylate, 1,2,3-benzenetriol triacrylate, and the like. The ester obtained by the esterification reaction of unsaturated traconic acid with a polybasic acid and a polyvalent compound is not necessarily a single substance but may be a mixture. The representative examples thereof include the following: a condensate formed of acrylic acid, citric acid, and ethylene glycol; a condensate formed of acrylic acid, maleic acid, and monocondensed ethylene glycol; a condensate formed of methacrylic acid, p-citric acid, and pentaerythritol; a condensate formed of acrylic acid, adipic acid, butanediol, and glycerin. In the case of an ethylenic compound having an urethane skeleton obtained by a reaction of a polyisocyanate compound and a (fluorenyl)-based fluorenyl-based hydroxy compound, a polycyanate compound such as an aliphatic diisocyanate (such as hexamethylene fluorene) may be mentioned. Diisocyanate, trimethylhexamethylene diisocyanate, etc.), alicyclic diisocyanate (such as cyclohexane diisocyanate, isophorone diisocyanate, etc.), aromatic diisocyanate (such as methyl benzene diisocyanate, diphenyl decane) Diisocyanate, etc. and the like (meth) propylene sulfhydryl hydroxy compound such as 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 3-hydroxy (1,1,1-tripropenyl fluorenyl) A reactant formed by propane, 3-hydroxy (1,1,1-trimethylpropenylfluorenyl)propane or the like. Further, examples of the ethylenic compound used in the present invention include acrylamides (e.g., ethylene bis acrylamide, etc.), allyl esters (e.g., diallyl citrate, etc.), vinyl-containing compounds (e.g., hydrazine). Acid divinyl ester, etc.) are also useful. The blending ratio of the ethylenic compound is based on the total solid content of the colored resin composition of the present invention, and is usually set to be more than Owt% (preferably 5 wt% or more, more preferably 10 wt% or more). , 80 wt% or less (70 wt% to 63 312 / invention specification (supplement) / 93-04/93101159 1296639 is preferred, and 50 wt% or less is further preferred, especially 40 wt% The following is more appropriate). Furthermore, the ratio of the color material is usually set to 〇wt% or more (preferably 5 wt% or more, more preferably 10 wt% or more, and particularly preferably 20 wt% or more), 2 0 0 It is in the range of wt% or less (preferably 1/10 wt% or less, and further preferably 80 wt% or less). [1 - 7 ] Photopolymerization Initiator In the case where the colored resin composition of the present invention contains an ethylenic compound of a monomer component, it is preferred to incorporate a photopolymerization initiator component which has direct absorption light or A function that is sensitized by light to cause a decomposition reaction or a hydrogen extraction reaction to produce a polymerization active radical. Further, in the present invention, the meaning of the component of the photopolymerization initiator is a mixture of a photopolymerization initiator, an accelerator, and an additive such as a sensitizing dye. The photopolymerization initiator which is a photopolymerization initiator component is exemplified by, for example, Japanese Patent Laid-Open Publication No. Sho 59-150-369, and JP-A-6-151. The ruthenium cyclopentadienide metal complex containing ruthenium cyclopentadiene is described in Japanese Patent Laid-Open Publication No. SHO-58-304, and Japanese Patent Publication No. 4 5 - 3 7 3 7 7 The hexaarylbiimidazole derivative, the halo-s-tri-negative derivative, and the N-aryl-α-amino acid (such as N-) described in the Gazette of the Japanese Patent Laid-Open Publication No. 1-0 - 3 9 5 0 3 "Phenylaminoacetic acid, etc.), Ν-aryl-α-amino acid salts, free radical active agents such as Ν-aryl-α-amino acid esters, "7 7彳&gt; 夂$力小" Dialkyl acetophenone, benzoin, 9-oxodibenzosulfone, as described on pages 16 to 26 of (Fine Chemical) (March 1, 1991, vol. 20, No. 4) In the case of a piperidine derivative, etc., the ruthenium cyclopentadiene which is described in JP-A-2002-242, And 64 312 / invention specification (supplement) /93-04/93101159 1296639 hydroxycyclohexyl phenyl ketone, α- -2 -Phenylphenylacetone, 1-hydroxy-1--(p-isopropyl)one, 1 -hydroxy-1 -(p-dodecylphenyl)one, 2 (4,-(sulfur) An acetophenone derivative such as benzene)-2-morpholine-1-propanone or 1,1,1-trichloropurinone; such as sulfur d-ketone, 2-ethylsulfur plU ketone, and 2 isopropyl sulfide (10) ketone , 2-chloro 2 , 4 - dimethyl thioxanthone, 2,4-diethyl thio-ketone, 2,4-diisopropyl thione derivative; such as ethyl p-diamine benzoate, a diethylamine benzoic acid acetate derivative; such as 9-phenyl acridine, 9-(p-oxime) acridine derivative; such as 9,10-dibenzophenone An onion ketone derivative such as benzoxanone; such as dioxindole cyclopentadienyl titanium, bisbenzoquinone cyclopentadienyl titanium, bis-2,3,4,5,6-pentafluorobenzene- 1-based Cyclopentazone, bis-2,3, phenyl-1-ylcyclopentadiene titanium, bis-2,4,6-trifluorobenzene-1-yl wuqin, 2,6- Dioxene-1-yl-cyclopentaphenone, titanium 2,4-dicyclopentadiene, bis-2,3,4,5,6-pentafluorobenzene-1-ylindole, titanium -2,6-difluorobenzene-1_ylindenylcyclopentadienyltitanium, 2,6-di-n-yl-1-yl)-phenyl-1-yl-wucyclopentadiene, etc. Gas ring 戍 two women's objects; such as 2_ fluorenyl-1*~[4-(methylthio)benzene]-2- phenanthrene-propan-1-ol dimethylamine-1-(4-morpholinylphenyl) )-butanone-1, 4-dimethylamine benzoquinone 4-diguanamine benzoic acid isoamyl ester, 4-diethylamine acetophenone, 4-diphenyl, 1,4-dimethylamine benzoic acid 2 - Ethylhexyl ester, 2,5-bis(4-benzyl)cyclohexanone, 7-diethylamine-3-(4-diethylamine benzamidine) benzo 312/invention specification (supplement)/93- 04/93101159 Methyl ethyl-fluorenyl (p-butylbenzene) thiophene, thione and other esters such as benzopyridinium; 5,6 _ tetra it cyclopentadienyl-1-ylindole Pentadiene fluoride - 3 - (anthracene titanium derivative, 2-benzyl-2-acid ethyl ester, decyl propyl hydrazine diethyl hexanone, 66 1296639 4-(diethylamine) phenyl styryl ketone, etc. Amine alkylphenyl W compound. As the accelerator constituting the photopolymerization initiator component, for example, N,N-dialkylamine benzoic acid, alkyl acetonate such as N,N-dimethylamine benzoate or the like can be used, such as 2- fluorene benzophenone. A heterocyclic ruthenium compound or an aliphatic polyfunctional ruthenium compound, such as σ sigma sigma, 2 - Wei benzo sigma, 2 - benzene, and sigma. The photopolymerization initiator and the accelerator may each be a mixture of two or more kinds. The blending ratio of the photopolymerization initiator component is based on the total solid content of the colored resin composition of the present invention, and is usually set at 0. 1 wt% or more (more preferably 0. 5 wt% or more, and 0). More preferably, 7 wt% or more, and 30 wt% or less (preferably 20 wt% or less, and further preferably 10 wt% or less). If the blending ratio is remarkably low, the sensitivity to the exposure light may be lowered. If the contrast is significantly higher, the solubility of the unexposed portion to the developing solution may be lowered, and the development may be induced. In addition, a photopolymerization initiator and an accelerator may be used in combination of two or more kinds, and a preferred combination of a photopolymerization initiator and an accelerator may, for example, be an imidazole derivative or an α-aminoalkyl phenyl ketone. A compound, and a combination of compounds having a heterocyclic ring. When necessary, the photopolymerization initiator component is blended with a sensitizing dye according to the wavelength of the image exposure light source for the purpose of improving the sensitivity. The sensitizing dyes of the present invention include the ice pigments described in Japanese Patent Laid-Open No. Hei 4 - 2 2 1 9 5 8 and JP-A-4-279.756, and the special Kaiping 3 - 2 3 9 No. 7 0 3, Special Kaiping 5 - 2 8 9 3 3 No. 5 contains the heterocyclic lutein pigment, special Kaiping 3 - 2 3 9 7 0 3, special Kaiping 5 - 2 8 9 3 - keto-oxacin compound described in the Gazettes of 3 3 5, 吼 67 67 312 / invention manual (supplement) / 93-04/93101159 1296639 as described in JP-A-6 - 1 9 2 4 0 Methylene-based pigments, in addition, may be exemplified by the Japanese Patent Laid-Open No. 4 7 - 2 5 2 8 , the special opening 5 4 - 1 5 5 2 9 2 , and the special public 4 5 - 3 7 3 7 7 Special opening 4 8 - 8 4 1 8 3, special opening 5 2 - 1 1 2 6 8 1 , special opening 5 8 - 1 5 5 0 3, special opening 6 0 - 8 8 0 0 No. 5, Special Open No. 5 9 - 5 6 4 0 No. 3, Special Kaiping No. 2-69, Special Open No. 5 7 - 1 6 8 0 8 8 , Special Kaiping 5 - 1 0 7 7 6 1 Kaiping No. 5 - 2 1 0 2 4 0, and a pigment having a dialkylamine benzene skeleton as described in each of the Japanese Patent Publication No. 4 - 2 8 8 8 1 8 . Among the above sensitizing dyes, an amine group-containing sensitizing dye is preferred, and a compound containing an amine group and a phenyl group in the same molecule is more preferred. Particularly suitable examples are as follows: 4, 4'-dimethylamine diphenyl ketone, 4, 4'-diethylamine diphenyl ketone, 2-amine diphenyl ketone, 4-amine diphenyl ketone a diphenyl series compound such as 4,4'-diamine diphenyl fluorene, 3,3'-diamine diphenyl ketone or 3,4-diamine diphenyl ketone; such as 2 - (pair -diampamethylene benzene)benzo pfazole, 2-(p-diethylamine benzene)benzoxazole, 2-(p-diguanamine benzene)benzo[6,7]benzoxazole, 2, 5-bis(p-diethylamine benzene) 1, 3,4-oxazole, 2 _ (p-dimethylaminobenzene) benzothiazole, 2-(p-diethylamine benzene) benzothiazole, 2 - (p-dimethylaminobenzene) benzimidazole, 2-(p-diethylamine benzene) benzimidazole, 2,5-bis(p-diethylamine benzene) 1,3,4-thiadiazole, ( p-Dimethylamine benzene) acridine, (p-diethylamine benzene) acridine, (p-dimethylaminobenzene) porphyrin, (p-diethylamine benzene) porphyrin, (p-diamine benzene) a compound containing a p-dialkylamine phenyl group such as pyrimidine or (p-diethylamine benzene) pyrimidine. The most suitable one among them is 4, 4'-dialkylamine diphenyl ketone. The blending ratio of the sensitizing dye in the colored resin composition of the present invention is based on the total solid content of the colored resin composition, and is usually set at 0 wt% or more (more preferably 0. 2 wt% or more). Further, it is more than 0.5% by weight or more than 68 312/invention specification (supplement)/93-04/93101159 1296639, and a pigment derivative or the like may be added as a dispersing aid. Azo, phthalocyanine, acridone, benzophenone, quinolone, isoindoline, isoporphyrin, system, onion, leeks a sulfonate group, a sulfonamide group and a salt, and a substituent of a derivative derivative of each pigment, etc., may be mentioned as a substituent of a derivative derivative of each pigment. a sulfonium amide group and a quaternary salt thereof, which are bonded to a pigment skeleton directly or by an alkyl group, an aryl group, a heterocyclic group or the like, or a sulfonium amide group and a quaternary salt thereof, The sulfonic acid group is preferred, and the sulfonic acid step is preferred. Further, the substituent is substituted with a plurality of pigments or a compound having a different number of substitutions. The mixture may be a specific example of the pigment, and examples thereof include a sulfonic acid derivative of an azo pigment, a phthalocyanine derivative, a sulfonic acid derivative of a quinolone pigment, and an isosodium oxyfluoride derivative. Hui S Kun pigment continuous acid derivative, ϋ 吖 吖 吖 酮 颜 颜 颜 颜 颜 颜 衍生物 , , , , , 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸 磺酸1 3 8 sulfonate, pigment yellow 1 3 9 sulfonic acid derivative, pigment red 2 5 4 sulfonic acid agricultural pigment red 2 5 5 sulfonic acid derivative, pigment red 2 6 4 sulfonic acid derivative red 2 a sulfonic acid derivative of 7 2, a sulfonic acid derivative of a pigment red 2 0 9 sulfonic acid derivative, a sulfonic acid derivative of a pigment purple 2 3 , and preferably a sulfonic acid derivative of a pigment yellow 1 3 8 , pigment red 2 5 4 organisms. The amount of pigment derivative added is based on the pigment, through 0.1 wt% or more, 30 wt% or less (preferably below 20 wt%, and further below) Good, and further better than 5 wt%) 312 / invention specification (supplement) / 93-04/93101159 for pigment and imidazole diterpenoids, for Yan Qisi The base, etc., is based on a skeleton, a sulfonated pigment material of a derivative material, which is derived from a sulfonate-derived acid, a substance, a pigment, a pigment, and a sulfonic acid derivative in a range of 10 wt ° / 70 70 1296639 If the amount of addition is small, the effect cannot be exerted. On the other hand, if the amount added is too large, the dispersibility and dispersion stability are deteriorated. For the surfactant, an anionic, cationic, nonionic, and amphoteric interface can be used. It is preferable to use a nonionic surfactant in view of various surfactants such as an active agent, and from the viewpoint that the possibility that each property is adversely affected is low. The concentration of the surfactant is based on the total amount of the composition, and is usually used in an amount of 0.001 wt% or more (more preferably 0.005 wt% or more, further preferably O.Ol wt%, and most preferably 0. 03 wt% or more). And a range of 10 wt% or less (preferably 1 wt% or less, further preferably 0. 5 wt% or less, and most preferably 0.3 wt% or less). As the thermal polymerization inhibitor, for example, hydroquinone, p-methoxyphenol, gallicol, catechol, 2,6-tributyl-p-nonylphenol, p-naphthol or the like can be used. The blending amount of the heat polymerization preventing agent is preferably set to be in the range of 0 w t % or more and 3 w t % or less based on the total solid content of the composition. As a plasticizer, for example, dioctyl phthalate, dilauryl citrate, di(triethylene glycol) dioctanoate, dinonyl glycol phthalate, tricresyl phosphate, and hexamethyl phosphate can be used. Dioctyl acid ester, dibutyl sebacate, triethylene glycol glycerin, and the like. When the blending amount of the plasticizer is based on the total solid form of the composition, it is usually in the range of 10% by weight or less. [2] Characteristics of Colored Resin Composition (Photoresist) The colored resin composition (photoresist) according to the present invention has the following characteristics, in particular, by using the specific binder resin and dispersant as described above: excellent transmittance, Excellent image adhesion and few undissolved residue. In addition, it may have the following characteristics if necessary: low viscosity change rate; good re-dissolution 312/invention specification (supplement)/93-04/93101159 71 1296639 solvability, height voltage retention. Hereinafter, each characteristic will be described. [2 - 1 ] Transmittance Regarding the transmittance, the reflectance of each of red, green, and blue pixels was evaluated according to the measured value measured by the method described below. Hereinafter, it will be specifically described. The colored resin composition of the object was applied by spin coating on a 5 cm square glass substrate (Asahi Glass product "AN100"), and heated on a hot plate at 80 ° C for 3 minutes to be comprehensive. After exposure at 100 mJ/cm2, spray imaging was carried out under a water pressure of 0.3 Μ P a for 30 seconds with a 0.1% by weight aqueous solution of sodium carbonate at 23 ° C, and then carried out in a hot air circulating furnace. 2 3 0 °C 3 0 minutes of firing. The film thickness of the colored resin composition after firing is the color coordinate shown by the CIE color system, and the red color can be X = 0. 60, the green color can be y = 0.55, and the blue color can be y = y = 0.14 (all C light sources) as coating conditions. For the measurement of the chromaticity, a spectrophotometer [U 3 5 0 0] manufactured by Hitachi, Ltd. was used. The Y value of the red colored resin composition of the present invention in the C I E color system is within the range shown by any of the following formulas: 2 0 0 y-41. 4 (y &lt; 0. 34) 100y - 7. 4 (y ^ 0. 34) Further, preferably, it is within the range of any of the following formulas: 2 0 0 y - 40. 9 (y &lt; 0. 34) Y^10 0y-6.9 (y^0.34) Further, the Y value of the green colored resin composition of the present invention in the CIE color system is within the range shown by the following formula: 72 312 / invention Specification (supplement) /93-04/93101159 1296639 Υ 2 2 4 0x - 7· 1 Furthermore, preferably, it is within the range shown by the following formula: yg 240χ - 6· 6 Furthermore, the blue of the present invention The Υ value of the color-colored resin composition in the CI Ε color system is within the range of the following formula: 20 χ + 16.2 Further, preferably, within the range shown by the following formula: Υ ^ 20 χ +1 6. 4 Since the coloring resin composition having excellent transmittance of the present invention is used, the transmittance of the color filter is improved, and the luminance of the liquid crystal display device is increased, so that a sharp image can be obtained as an advantage. [2 - 2 ] Image adhesion The development image adhesion was evaluated according to the minimum pattern width measured by the method described below. Hereinafter, it will be specifically described. The colored resin composition of the object is applied to a glass substrate in a dry film thickness of 1. 3 // m, dried at 60 ° C for 1 minute, and then dried by heating at 110 ° C. 2 minutes, under the test mask using a linear opening with a line width of 1 # m scale, after exposure at a distance of 1 500 /zm at an exposure of 300 mJ/cm 2 , using an aqueous solution of 0.1% by weight of sodium carbonate The image was developed at a hydraulic pressure of 2 kg / c m2 at a temperature of 23 ° C for 60 seconds, and then subjected to a water spray treatment at a water pressure of 3 kg / c m 2 for 30 seconds to form a pattern. At the time of measurement, the minimum pattern width remaining in the line image is measured. The minimum pattern width of the colored resin composition of the present invention is 10 // m or less, preferably 8 // m or less. 73 312/Invention Manual (Supplement)/93-04/93101159 1296639 The use of the colored resin composition of the present invention having excellent image adhesion does not cause whitening defects, and can form high-quality color filter. sheet. [2 - 3] Undissolved residue The undissolved residue was evaluated by the spectral reflectance measured by the following method. Hereinafter, it will be specifically described. Regarding the color filter light sheet obtained from the colored resin composition of the object, a portion of the non-pixel portion (on the plain glass) of 3 Ο X 1 0 0 mm is formed of a polyester long fiber having an average of 3 m or less. The cloth (for example, "TRAY RAY" product "TORAYS EEMK Clean Cloth") is wiped at a pressure of lkgf/cm2. The above-mentioned cloth is fixed in advance at the tip end of a resin square material of 1 c m x 1 c m, and is impregnated with 0.1 C c ethanol by a Pasteur pipette for the user. For the 1 c m X 1 c m portion of the cloth after wiping, the spectrophotometer "UV - 3 1 0 0 S" manufactured by Shimadzu Corporation was used to measure the spectral reflectance under the condition of using an integrating sphere. In Table-5, the spectroscopy of = 750 nm (corresponding to red suffocation), 4500 s (corresponding to green scum), and 550 nm (corresponding to blue residual) is shown. Reflectivity. In the above evaluation method of the present invention, the spectral reflectances of red (500 nm), green (450 nm), and blue (550 nm) are each 95% or more, preferably 97% or more. By using the colored resin composition containing the undissolved matter residue of the present invention, a high-quality color filter can be formed, which does not cause a decrease in transmittance or contrast ratio, and is also difficult to cause peeling of the IT 0 film or The sealing property in the liquid crystal cell formation step is deteriorated or the like. [2 - 4 ] Viscosity change rate 74 312/Invention manual (supplement)/93-04/93101159 1296639 Regarding the viscosity change rate, the evaluation was carried out in accordance with the following method. The following is specifically explained. The viscosity of the resin composition of the object immediately after preparation and the viscosity (20 rpm) after standing for 7 days in a constant temperature unit at 23 ° C were used by Toki Sangyo Co., Ltd. The E-type viscometer [RE - 8 0 L ] was measured. The viscosity change of the colored resin composition of the present invention after 7 days (based on the initial viscosity) is preferably 10% or less, more preferably 5% or less, and still more preferably 3% or less. The colored resin composition of the present invention having a low viscosity change rate has an advantage of being able to be used under the same processing conditions for a long period of time because of its excellent storage stability. [2 - 5 ] Resolubility With respect to resolubility, evaluation was carried out in accordance with the following method. The details are explained below. The coloring resin composition of the object was applied to a glass substrate of 50 mm square by a spin coating method at a dry film thickness of 2.5 mm, and air-dried for 60 minutes, and then formed into a colored resin composition. The solvent was immersed in 6.5 g for 3 minutes, and then dispersed again. After 10 minutes from the start of the impregnation, a particle size prepared by NIKKI SO CO., LTD. The distribution measuring device "MicroTrackUPA" was used to measure the particle size distribution, and the volume average particle diameter mv was calculated. The volume average particle diameter mv of the colored resin composition of the present invention in the redispersion is usually 200 nm or less, preferably 150 nm or less. 75 312/Invention Manual (Supplement)/93-04/93101159 1296639 The colored resin composition of the present invention having good resolubility is also difficult to produce dry cohesive foreign matter at the tip end of the die when coated by a die coating method. Therefore, foreign matter defects can be suppressed, and a high-quality color filter light sheet can be formed in a high yield. [2 _ 6 ] Voltage holding ratio Regarding the voltage holding ratio, evaluation was performed according to the following method. The details will be described below. An electrode substrate A was prepared, and an ITO film was integrally formed on one surface of a 2.5 cm square alkali-free glass substrate (AsahiGlass product "AN100"), and an electrode substrate B was attached at 2.5 cm. A 1 cm square ITO film is formed on the central portion of the single-sided glass substrate, and an output electrode having a width of 2 mm is connected thereto, and an alignment film agent ("Nissan Chemical Industries, Ltd.") The product "Sunever7492" is applied to the electrode substrates A and B by spin coating, dried on a hot plate at 1 10 ° C for 1 minute, and then heated at 20 ° in a hot air circulation furnace. In an hour, a coating film having a film thickness of 70 nm was formed. The colored resin compositions of the respective examples were applied by spin coating to an electrode substrate A coated with an alignment film on a hot plate at a temperature of 80 ° C. After heating for 3 minutes, the whole surface is exposed to 100 m J / c m2, and then sprayed with a 0. 1 wt% aqueous solution of sodium carbonate at 23 ° C under a water pressure of 0.3 Μ PA. In seconds, then in a hot air circulating oven at a temperature of 2 30 ° C for 30 minutes The film thickness of the coloring composition after firing can be adjusted to 1.7 #m. The epoxy resin sealant containing the oxidized beads having a diameter of 5 μm is coated under the dispenser. Applied to the outer surface of the electrode substrate B coated with the alignment film 76 312 / invention specification (supplement) / 93-04/93101159 1296639 At the time of dispersion treatment of the color material, it is preferred to use a binder resin or dispersion aid The agent or the like is used in combination as appropriate. With regard to the binder resin used in the dispersion treatment of the color material, it is particularly preferable to use a buffer having an epoxy moiety containing an epoxy group-containing unsaturated compound added to the base containing the ruthenium-based resin. Partially constructed resin. Further, in the case of dispersion treatment using a sand mill, it is preferable to use glass beads having a diameter of 0.1 mm to several mm or yttrium oxide beads. It is usually set above 0 °C (better than room temperature), 10 (below TC (preferably below 80 °C). Also, the dispersion time is based on the composition of the ink liquid (color material) , a solvent, a dispersant having a nitrogen-containing functional group) and The size of the sander device varies depending on the size of the sand mill device, so it is necessary to adjust it appropriately. For the ink-like liquid obtained by the above dispersion treatment, the solvent, the binder resin, and the specified amount of light are added as necessary. The polymerizable monomer, the photopolymerization initiator component, and the components other than the above are mixed to form a uniform dispersion solution. The binder resin mixed with the ink-like liquid is preferably an alkali-soluble resin, and particularly preferably The following is a binder resin having a structure containing a carboxyl moiety containing an epoxy group containing an epoxy group-containing unsaturated compound (b) and which is added to a carboxyl group of the carboxyl group-containing resin (a); (A) is an epoxy group-containing (fluorenyl) acrylate 5 to 90 m ο 1 % and component (B), which is another radical polymerizable compound which can be copolymerized with the above component (A), 10 to 9 5 m ο 1 % of the copolymer formed, the component (C), that is, the unsaturated monobasic acid is added to the epoxy group of the above component (A) by 10 to 1 0 0 mol 1%, and the component (D) is Polyanhydride addition to the addition of component (C) The resulting hydroxyl group is 0 0 to 1 0 0 m ο 1 %, and the photosensitive resin thus obtained has a weight average of 78 312 / invention specification (supplement) / 93-04 / 93101159 1296639 sub-quantity M w is 2 Ο Ο 0~1 Ο Ο Ο 0 resin; and so on. Other resins may be used together. Preferably, the "resin" of the photosensitive colored resin composition is defined as 60% by weight or more of the resin which is more than J by weight of GPC, and the amount of the alkali-soluble resin is less than 60% by weight. In addition, in the soluble resin component, a preferred non-nitrogen-containing binder resin has an epoxy moiety containing an epoxy (b) added to the carboxyl group-containing resin (a). The content of the binder resin is usually 50% by weight or more, and more preferably 80% by weight or more. In some cases, the non-polymerization effect in the above resin may not be exhibited. , causing a decrease in sensitivity. The blending of the resin in the photosensitive colored resin composition is based on the total solid content of the color resin composition, and is usually 10 to 50% by weight. Further, in the dispersion treatment step and the mixing step, fine dust is mixed, and it is preferred to subject the obtained filter or the like to filtration treatment. [4] Manufacture of color filter substrate Next, the color filter according to the present invention is added to the color filter of the present invention, which is characterized in that the pixel formed by using the above colored resin composition [4 - 1] Transparent substrate (support) 312 / invention specification (supplement) / 93-04/93101159, the above resin and f-fat part (in this case, the molecular weight is 1 000. The alkali-soluble resin 〇 is high, the above The base of the unsaturated compound is formed to have a composition of more than 30% by weight, and is less than 30% by weight. The light transmittance of the saturated bond is 5 to 60% by weight, in some cases, due to The ink-like liquid is exemplified. The transparent substrate on which 79 1296639 color filter is formed on the substrate is mainly limited in transparency and appropriate degree, and the material thereof is, for example, a resin ( Such as polyethylene terephthalate (such as polyethylene terephthalate), polyolefin resin (such as polypropylene, etc.), thermoplastic resin (such as polycarbonate, polyacrylonitrile polysulfone, etc.) made of epoxy resin ,Unsaturated polyester resin,】 ) A thermosetting resin sheet of an acrylic resin made by the, or various like. In the heat resistance, the surface of the transparent substrate and the substrate for forming a black substrate (such as adhesion) is improved by using glass or a heat-resistant resin, and if necessary, ozone treatment is applied to the substrate by corona discharge, and decane is used. Various tree film forming treatments such as a coupling agent and an amine phthalate-based resin may be used. The thickness of the transparent substrate is usually set to 〇. or more (for (Κ 1 mm or more), 10 mm or less (with a range of 7 mm or less and 4 or less. Further, in the case of performing film formation treatment of various resins) The film thickness is usually set at 0. 0 1 // m or more (with a range of 0. 0 5 // m or more than 4 1 0 // m (better than 5 // m). [4 - 2 The black matrix is formed by providing a black matrix on the transparent substrate and then forming a pixel image of a red, green, and blue color. The color filter of the present invention can be formed. a coating liquid for forming a photoresist for at least one of red, green, and blue. The substrate is formed on a plain glass surface on a transparent substrate or on a resin black matrix formed on a transparent substrate with respect to red, green, and blue. On the surface of the metal black body formed by using a chromium compound or other light-shielding metal material, coating, heat drying, image exposure, development 312 / invention specification (supplement) / 93-04/93101159 strong polymerization Esterene, ester, U-glass is good. Physical properties, fat The combination of 0 5mm &quot;, &quot;, related color, black color, or chromatic base, 80 1296639 and thermal hardening to form pixel images of various colors. Black based system using a light-shielding metal film Or a black matrix is formed on a transparent substrate by using a photosensitive colored resin composition. For the light-shielding metal material, a chromium compound such as metal chromium, chromium oxide or chromium nitride, an alloy of nickel and tungsten, or the like can be used. The material may be laminated into two or more layers. The above metal light-shielding film is generally formed according to a sputtering method, and after forming a specified pattern by a positive-type photoresist in a film form, An etchant is prepared by mixing (IV) with perchloric acid and/or nitric acid, and an etching solution suitable for the material is used for etching, and the positive photoresist is stripped by a special stripping agent. A black matrix is formed. In this case, first, a film of the above metal or metal/metal oxide is formed on a transparent substrate by a vapor deposition method (vapor deposition method) or a sputtering method. After the coating film of the colored resin composition is formed on the film, the coating film is exposed and developed under the mask having a repeating pattern such as a stripe, an intarsia, or a triangle to form a light group image. Then, A black matrix can be formed by applying an etching treatment to the coating film. In the case of using a colored resin composition for a black substrate, a colored resin composition containing a black coloring material is used to form a black matrix. For example, a black containing a single or plural color is used. Color material (such as carbon black, graphite, iron black, aniline black, black, black, etc.) or black color obtained by mixing red, green, blue, etc., which are appropriately selected from inorganic or organic pigments and dyes. The colored resin composition of the material is formed in the same manner as the pixel image forming method of red, green, and blue described below to form a black matrix. [4 - 3 ] Pixel formation 81 312 / Invention specification (supplement) / 93-04/93101159 1296639 On a transparent substrate provided with a black substrate, a colored material containing any one of red, green and blue is applied. The colored resin composition is dried, and the mask is superposed on the coating film, and the reticle is subjected to image exposure, and the image is subjected to thermal curing or photohardening to form a pixel image to form a layer. In this operation, a color filter image can be formed by performing a separate coloring resin group of three colors of red, green, and blue. The coating of the colored resin composition for the color filter can be carried out by spin coating, the method of flow-coating, the method of flow coating, the method of (slit) die coating, the spraying method, and the like. It. In particular, according to the die coating method (the slit liquid supply is used, the amount of the coating liquid can be greatly reduced, and it is not affected by the moisture adhering to the spinning time, and the like, and the generation of foreign matter can be suppressed. If the thickness of the coating film is too large, the pattern development becomes difficult, and the gap adjustment in the crystal unitization step becomes difficult. On the other side, it is difficult to increase the pigment concentration, sometimes it is impossible. The color of the coating is revealed. Regarding the thickness of the coating film, the film thickness after drying is usually set at //m or more (preferably 0.5 or more, and preferably 0. 8 // m or more). 2 0 // m or less (preferably 1 0 #m or less, and preferably 5 // m or less). [4 - 4 ] After drying the colored resin composition of the coating film on the substrate The drying of the coating film is carried out according to the drying method using a hot plate, an IR oven, and a convection oven. After the preliminary drying, the film is heated and dried again. The conditions of the preliminary drying conditions, the type of the solvent component, the performance of the dryer to be used, etc. Appropriate 312 / invention manual (supplement) /93-04/93101159 color , will, will be colored into a material 离 (off, roll t method) coating method, in the liquid surface if the 0. 2 step is better than a good one can usually choose 82 1296639. Drying temperature and drying time are based on solvent composition The type, the performance of the dryer to be used, etc., specifically, the drying temperature is usually set at 40 ° C or higher (preferably above 50 ° C), below 80 ° C (at 70 ° C) In the range of the following preferred), the drying time is usually set to be more than 15 seconds (preferably 30 seconds or more), and 5 minutes or less (preferably 3 minutes or less). The temperature condition is preferably higher than the initial drying temperature. Specifically, the temperature is usually set at 50 ° C or higher (preferably above 70 ° C), and below 200 ° C (by 16). 0 ° C or less is preferable, especially in the range of preferably 130 ° C or less. The drying time varies depending on the heating temperature, but is usually set to 10 seconds or more (more preferably 15 seconds or more). , 10 minutes or less (preferably less than 5 minutes). The higher the drying temperature, the transparent substrate The adhesion is improved, but if it is too high, the binder resin will decompose, and sometimes the thermal polymerization will be induced to cause poor development. In addition, the drying step of the coating film is used in the decompression chamber without increasing the temperature. Drying and drying under reduced pressure may also be performed by [4 - 5 ] exposure step image exposure by superimposing the negative base pattern on the coating film of the colored resin composition, whereby the reticle pattern is irradiated with ultraviolet rays or In order to prevent the sensitivity of the photopolymerizable layer caused by oxygen from being lowered, an oxygen barrier layer such as a polyvinyl alcohol layer is formed on the photopolymerizable layer, and exposure is performed. can. The light source used for the above image exposure is not particularly limited. Examples of the light source include lamps such as xenon lamps, halogen lamps, tungsten lamps, high pressure mercury lamps, ultrahigh pressure mercury lamps, metal halide lamps, medium pressure mercury lamps, low pressure mercury lamps, carbon arc lamps, fluorescent lamps, and the like. Light source, such as argon 83 312 / invention specification (supplement) / 93-04/93101159 1296639 sub-laser, YAG laser, excimer laser, nitrogen laser, cadmium-emitting laser, semiconductor laser Wait for the laser source, etc. When a light of a specific wavelength is used for use, an optical filter may be used. [4-6] Developing Step The color filter according to the present invention can be produced by a method of applying a light-emitting resin composition using the light source of the present invention to a coating film. After the exposure, an organic solvent or an aqueous solution containing a surfactant and a basic compound is used to perform development, thereby forming an image on the substrate. The aqueous solution may further contain an organic solvent, a buffer, a dismutating agent, a dye or a pigment. The test compound may, for example, be sodium hydroxide, hydroxide If, lithium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, potassium hydrogencarbonate, sodium citrate, potassium citrate, sodium metasilicate, phosphoric acid. Inorganic basic compounds such as sodium, potassium phosphate, sodium hydrogen phosphate, potassium hydrogen phosphate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, ammonium hydroxide, etc., such as ethanolamine, diethanolamine, triethanolamine, decylamine, diamine, trimethylamine Amine, ethylamine, diethylamine, triethylamine, isopropylamine, diisopropylamine, n-butylamine, isopropanolamine, diisopropanolamine, triisopropanolamine, ethylenediamine, tetrahydroanhydride An organic basic compound such as ammonium (TMAH) or bile. The basic compound may be a mixture of two or more basic compounds. Examples of the surfactant include, for example, polyoxoethyl oxime, polyoxyethylidene aryl, polyoxyethylidene ester, and saponin. Nonionic surfactants such as monoglyceride alkyl esters, such as alkylbenzenesulfonates, alkylnaphthalenesulfonates, alkyl sulfates, alkylsulfonates, sulfonates Anionic interfacial activity of succinate salts and the like 312 / invention specification (supplement) / 93-04/93101159 84 1296639 agents, such as amphoteric beet moss, amino acid and the like, an amphoteric surfactant. Examples of the organic solvent include isopropanol, benzyl alcohol, 2-ethoxyethanol, 2-butoxyethanol, 2-phenoxyethanol, propylene glycol, and diacetone alcohol. The organic solvent may be used singly or in combination with an aqueous solution. The conditions of the development processing are not particularly limited, but the development temperature is usually set at 10 ° C or higher (preferably at 15 ° C or higher, and further preferably at 20 ° C or higher), 50 °. C is below (better than 4 5 ° C, more preferably 40 ° C or less). The development method may be any one of methods such as dipping development, spray imaging, brush imaging, and ultrasonic imaging. Further, according to the manufacturing method of the color filter of the present invention, in addition to the above-described manufacturing method, a solvent, a phthalocyanine-based pigment (which functions as a color material), and a polyimine may be used according to (1). The curable colored resin composition of the resin (which acts as a binder resin) is applied to a substrate and is formed by a method of forming a pixel image by etching. For the production method, (2) a method in which a colored resin composition containing a phthalocyanine-based pigment is used as a coloring ink, and a pixel image is directly formed on a transparent substrate using a printing machine, (3) A method in which a colored resin composition containing a phthalocyanine-based pigment is used as an electrode deposition liquid, a substrate is immersed in the electrode deposition liquid, and a colored film is deposited on an IT 0 electrode having a specified pattern. Further, (4) a method in which a film coated with a colored resin composition containing a phthalocyanine-based pigment is attached to a transparent substrate and peeled off, and image exposure and development are performed to form a pixel image, 5) A method in which a colored resin composition containing a phthalocyanine-based pigment is used as a colored ink, and a pixel image is formed using an ink jet printer. The method of producing the color filter is in accordance with the group of colored resin composition for color filter 85 312 / invention specification (supplement) / 93-04/93101159 1296639, and a suitable method is adopted. [4 - 7] Thermal hardening treatment Apply heat hardening to the color filter after development. The thermal hardening treatment conditions in this case are usually at a temperature of 100 ° C or higher (preferably at 150 ° C or higher), and at a temperature of 280 ° C or lower (preferably at 250 ° C or lower). Choose within the range, and the time is selected within the range of 5 minutes or more and 60 minutes or less. After a series of steps as described above, the formation of a graphic image of a color is completed. This series of steps is repeated in turn, and black, red, green, and blue patterns are applied to form a color filter. In addition, the order of the four colors is not limited by the above order. [4 - 8] Formation of Transparent Electrode The color filter according to the present invention directly forms a transparent electrode such as I TO on the image as it is, and is used as part of a part of a color display, a liquid crystal display device, or the like, However, in order to improve the surface smoothness or durability, it is also possible to form a top coat of polyamine, polyimide or the like on the image as necessary. Further, some of the transparent alignment electrodes may not be formed in some applications such as a planar alignment type driving method (IPS mode). [5] Liquid crystal display device (panel) Next, a method of manufacturing a liquid crystal display device (panel) according to the present invention will be described. The liquid crystal display device according to the present invention is generally manufactured as follows: an alignment film is formed on the color filter of the present invention, and after the spacer is spread on the alignment film, the spacer is relatively adhered to form the opposite substrate. In the liquid crystal early, the liquid crystal is injected into the formed liquid crystal early, and the counter electrode is connected to the wire to complete the manufacture. The alignment film is preferably a resin (e.g., polyimine 312/invention specification (supplement)/93-04/93101159 86 1296639, etc.). For the formation of the alignment film, a gravure printing method and/or a relief printing method (F 1 e X 〇 g r a p h i c p r i n t i n g (formerly known as flexographic printing)) may be employed, and the thickness of the alignment film is set to several 10 nm. After the hardening treatment of the alignment film is carried out by a heating firing method, the surface treatment is carried out by irradiation with ultraviolet rays or a rubbing cloth to form a surface state in which the tilt of the liquid crystal can be adjusted. It is suitable to use a spacer having a size corresponding to the gap between the alignment film and the counter substrate, usually in the range of 2 to 8 // m. On the color slab substrate, a lithographic spacer (P S ) of a transparent resin film is formed by photolithography, and this may be used instead of the spacer. For the counter substrate, an array substrate is generally used, and in particular, a TFT (Thin Film Transistor) substrate is suitable. The gap between the opposing substrates (the spacers) is different depending on the use of the liquid crystal display device, but is usually selected within a range of 2/m or more and 8/zm or less. After the alignment film and the opposite substrate are pasted, the portion other than the liquid crystal injection port is sealed with a sealing agent such as an epoxy resin. The sealant is hardened by U V irradiation and/or heating to seal the periphery of the liquid crystal cell. After the liquid crystal cell sealed by the periphery is cut in the panel unit, a reduced pressure state is formed in the vacuum chamber, the liquid crystal injection port is immersed in the liquid crystal, and then discharged into the chamber, whereby the liquid crystal is injected into the liquid crystal cell. The degree of decompression in the liquid crystal cell is usually set to be 1 X 1 0 _ 2 P a or more (preferably 1 X 1 0 _ 3 P a or more), and lx 10_7 Pa or less (preferably 1×10-6 Pa or less). Inside. Further, in the case of decompression, it is preferred to carry out the heating of the liquid crystal cell, and the temperature of the heating is usually set at 30 ° C or higher (preferably at 50 ° C or higher) and below 100 ° C ( In the range of 87 312 / invention specification (supplement) / 93-04 / 93101159 1296639 9 0 ° C or less). The heating retention time during decompression is set in the range of 10 minutes or more and 60 minutes or less. Then (make the liquid crystal cell) immersed in the liquid crystal. The liquid crystal injecting the liquid crystal is sealed by the liquid crystal injection port and the U V hardening resin is hardened to complete the liquid crystal display device (panel). The type of the liquid crystal is not particularly limited, and may be a conventional liquid crystal such as an aromatic liquid crystal, an aliphatic liquid crystal, or a polycyclic compound liquid crystal, and is a lyotropic liquid crystal or a thermotropic liquid crystal ( Any of the rmotropic liquid crystals and the like may be liquid crystal. It is a thermotropic liquid crystal, and a nematic liquid crystal, a smectic liquid crystal, a cholesteric liquid crystal, or the like is known, and any of the liquid crystals may be used. <Examples> Next, the present invention will be further described by way of Production Examples, Examples, and Comparative Examples, but the present invention is not limited by the following examples as long as it does not exceed the gist of the present invention. Further, in the following embodiments, "parts" means "parts (weight)". &lt;Examples 1 to 18 and Comparative Examples 1 to 1 3 &gt;&lt;Synthesis Example 1 &gt; Synthesis of binder resin a 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 20 parts by weight of styrene, 57 parts of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemical" product "FA - 5 1 3 Μ" 8 were added dropwise. 2份(重量) 88 312/发明发明。 2 parts by weight, and then continued to stir at a temperature of 1 2 ° C for 2 hours. Next, the ambient gas in the reaction vessel was changed to air, decylamine phenol 0. 7 parts by weight 88 312 / invention Instruction manual (supplement) /93-04/93101159 1296639 and hydroquinone. 1 2 parts by weight of 2 7 parts by weight of acrylic acid, and continue to react at 1 20 ° C for 6 hours. Thereafter, add four Hydroquinone anhydride (Τ Η PA ) 5 2 parts by weight, triethylamine Ο · 7 parts by weight, and the reaction is carried out at a temperature of 120 ° C for 3.5 hours. The binder resin thus obtained is borrowed by GPC. The weight average molecular weight M w measured was about 1 500. &lt;Synthesis Example 2 &gt; Synthesis of binder resin b 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 10 parts by weight of styrene, 7 parts by weight of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemicals" product "FA-513M" 82 were added dropwise. Parts (by weight), then stirring was continued for 2 hours at a temperature of 120 ° C. Secondly, the ambient gas in the reaction vessel was changed to air, and dimethyl dimethyl phenol phenol (0 9 ) by weight and hydroquinone · 1 5 parts by weight of 3 parts by weight of acrylic acid, and the reaction was continued for 6 hours at a temperature of 120 ° C. Thereafter, tetrahydrophthalic anhydride (THPA) was added in an amount of 65 parts by weight, and triethylamine was 0.8. The weight (weight) was carried out at a temperature of 120 ° C for 3.5 hours. The weight average molecular weight M w of the thus obtained binder resin as determined by GPC was about 17,000. &lt;Synthesis Example 3 &gt; Synthesis of binder resin c 145 parts by weight of propylene glycol monomethyl ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 18 parts by weight of benzyl methacrylate, 10 parts by weight of methyl methacrylate, 7 parts by weight of glycidyl methacrylate, and tricyclodecane were added dropwise. The monoacrylate of the skeleton ("FA - 5 1 3 Μ" of "Hitachi Chemical Co., Ltd.") was fed in a volume of 6 2 parts by weight, and then stirred at a temperature of 120 ° C for 2 hours. Next, change the 89 312/invention manual (supplement)/93-04/93101159 1296639 ambient gas in the reaction vessel to air, and yttrium dimethylamine phenol phenol. 9 parts by weight and hydroquinone · 1 5 The mixture was charged with 34 parts by weight of acrylic acid, and the reaction was continued at a temperature of 1,200 ° C for 6 hours. Thereafter, 6 parts by weight of tetrahydrophthalic anhydride (THP A) and 0.8 parts by weight of triethylamine were added, and the reaction was carried out at 120 ° C for 3.5 hours. The weight average molecular weight Mw of the adhesive resin thus obtained measured by GPC was about 13,000. &lt;Synthesis Example 4 &gt; Synthesis of binder resin d 145 parts by weight of propylene glycol monomethyl ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 30 parts by weight of styrene and 34 parts by weight of methacrylic acid were added dropwise, followed by stirring at a temperature of 1,200 ° C for 2 hours. Next, the ambient gas in the reaction vessel was changed to air, and 0.9 parts by weight of decylamine phenol and 0.15 parts by weight of hydroquinone were put into 5 parts of acrylate (3,4-epoxycyclohexyl) decyl ester. (Weight), the reaction was continued at a temperature of 1 20 ° C for 6 hours. The weight average molecular weight Mw of the adhesive resin thus obtained measured by GPC was about 18,000. &lt;Synthesis Example 5 &gt; Synthesis of binder resin e 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. 5 parts by weight of benzyl methacrylate, 40 parts by weight of methyl propyl decanoate and 26 parts by weight of methyl acrylate were added dropwise thereto, and then continued at a temperature of 120 ° C. Stir for 2 hours. Next, the ambient gas in the reaction vessel was changed to air, and the decylamine phenol quinone 0.9 parts by weight and the hydroquinone 0 · 15 parts by weight were put into the acrylic acid (3,4-epoxycyclohexyl). The methyl ester was 40 parts by weight, and the reaction was continued at a temperature of 1,200 ° C for 6 hours. The weight average molecular weight Mw of the adhesive resin thus obtained measured by GPC is about 312/invention specification (supplement)/93-04/93101159 90 1296639 1 6 0 0 0 ° &lt;Synthesis Example 6 &gt; Synthesis of binder resin a ' 145 parts by weight of propylene glycol monoterpene ether acetate was scrambled under a nitrogen atmosphere and heated to 1,200 °C. 20 parts by weight of styrene, 57 parts of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemical" product "FA - 5 1 3 Μ" was added dropwise thereto. 8 parts by weight, and then stirring at a temperature of 140 ° C for 2 hours. Secondly, the ambient gas in the reaction vessel was changed to air, and the hydrazine diamine phenol was 0.7 parts by weight and hydrogen.醌0 · 1 2 parts by weight of 2 7 parts by weight of acrylic acid, and the reaction is continued for 6 hours at a temperature of 120 ° C. Thereafter, tetrahydrophthalic anhydride (Τ Η PA ) 5 2 parts by weight is added. And triethylamine 0 · 7 parts by weight, and the reaction was carried out at a temperature of 120 ° C for 3.5 hours. The weight average molecular weight M w of the thus obtained binder resin was about 5 as determined by GPC. 0 0 0. &lt;Synthesis Example 7 &gt; Synthesis of binder resin b ' 145 parts by weight of propylene glycol monomethyl ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 10 parts by weight of styrene, 7 parts by weight of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemicals" product "FA-513M" 82 were added dropwise. Parts (by weight), and then stirring at a temperature of 140 ° C for 2 hours. Secondly, the ambient gas in the reaction vessel was changed to air, and dimethyl dimethyl phenol phenol was 0 · 9 parts by weight and hydroquinone 0 · 1 5 parts by weight of 3 parts by weight of acrylic acid, and the reaction was continued for 6 hours at a temperature of 120 ° C. Thereafter, tetrahydrophthalic anhydride (THPA) was added in an amount of 65 parts by weight, and triethylamine was 0.8. (weight), and the reaction is carried out at a temperature of 120 ° C for 3 · 5 hours. The weight of the adhesive resin thus obtained 91 312 / invention specification (supplement) / 93-04 / 93101159 1296639 average molecular weight Mw determined by GPC The result is about 6,000. &lt;Synthesis Example 8 &gt; Synthesis of binder resin c ' 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 20 parts by weight of styrene, 57 parts by weight of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemicals" product "FA-513M" 82 were added dropwise. Parts (by weight), and then stirring at a temperature of 1 2 ° C for 2 hours. Secondly, the ambient gas in the reaction vessel is changed to air, and dimethyl dimethyl phenol phenol is 0 · 7 parts by weight and hydroquinone 0 · 1 2 parts by weight of 27 parts by weight of acrylic acid, and the reaction was continued for 6 hours at a temperature of 120 ° C. Thereafter, tetrahydrofurfuric anhydride (THPA) 52 parts by weight, triethylamine 0 was added. 7 parts by weight, and the reaction was carried out at a temperature of 120 ° C for 3.5 hours. The weight average molecular weight M w of the thus obtained binder resin was about 1 500 as determined by GPC. &lt;Synthesis Example 9 &gt; Synthesis of binder resin d ′ 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen gas and heated to 1,200 °C. To this, 10 parts by weight of styrene, 7 parts by weight of glycidyl methacrylate, and a monoacrylate having a tricyclodecane skeleton ("Hitachi Chemicals" product "FA-513M" 82 were added dropwise. Parts (by weight), then stirring at a temperature of 1 2 ° C for 2 hours. Secondly, the ambient gas in the reaction vessel was changed to air, dimethyl dimethyl methoxide 0. 9 parts by weight and hydroquinone 0 1 5 parts by weight of 3 parts by weight of acrylic acid, and the reaction was continued for 6 hours at a temperature of 120 ° C. Thereafter, tetrahydrofurfuric anhydride (THPA) was added in an amount of 65 parts by weight, and triethylamine was 0.8. (weight), and the reaction is carried out at a temperature of 120 ° C for 3 · 5 hours. The weight of the binder resin thus obtained 92 312 / invention specification (supplement) / 93-04 / 93101159 1296639 average molecular weight Mw determined by GPC The result is about 1 700. &lt;Synthesis Example 1 0 &gt; Synthesis of binder resin e ' 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To this, 30 parts by weight of styrene and 34 parts by weight of methacrylic acid were added dropwise, and then stirring was continued for 1 hour at 14 °C. Secondly, the ambient gas in the reaction vessel was changed to air, and叁 曱 曱 曱 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸The reaction was continued for 6 hours at a temperature of C. The weight average molecular weight of the thus obtained binder resin was measured by GPC, and the result by GPC was about 8000. &lt;Synthesis Example 1 1 &gt; Synthesis of binder resin f ' 145 parts by weight of propylene glycol monoterpene ether acetate was stirred under nitrogen atmosphere and heated to 1,200 °C. To the mixture, 5 parts by weight of benzyl methacrylate, 40 parts by weight of decyl methacrylate and 26 parts by weight of methacrylic acid were added dropwise, followed by stirring at a temperature of 140 ° C for 2 hours. Next, the ambient gas in the reaction vessel was changed to air, and yttrium dimethylamine phenol (0.9 parts by weight) and hydroquinone 0 · 15 parts by weight were put into acrylic acid (3,4-epoxycyclohexyl). The methyl ester was 40 parts by weight, and the reaction was continued at a temperature of 1,200 ° C for 6 hours. The weight average molecular weight M w of the binder resin thus obtained was determined by G P C to be about 8,000. &lt;Synthesis Example 1 2 &gt; Synthesis of polycaprolactone 5 parts by weight of lauryl alcohol, 9 parts by weight of caprolactone, and dibutyl laurate 0. 0 0 parts by weight And heated to 1 60 °C within 1 hour. When a solids content of 99% was obtained, the addition reaction was immediately terminated. 93 312/Invention Manual (supplement)/93-04/93101159 1296639 &lt;Synthesis Example 1 3 &gt; Synthesis of polycaprolactone The reaction was carried out under the same conditions as in Synthesis Example 12 except that the lauryl alcohol of Synthesis Example 12 was changed to decyl alcohol. &lt;Synthesis Example 1 4 &gt; Synthesis of urethane-based dispersion resin A terpolymer of toluene diisocyanate ("Mitsubishi Chemical" product "MAITEC GP 7 5 0 A", resin solid content 5 0 Pt %, 2,4 - diisocyanate phenyl ester: 2,6 _ diisocyanate phenyl ester = 8 : 2 mixture, butyl acetate solution) 3 2 parts by weight and act as catalyst Dibutyltin dilaurate 0. 0 1 part by weight was diluted and dissolved using PGMEA (propylene glycol monomethyl ether acetate) 47 parts by weight. To this end, a polycaprolactone having a lauryloxy group (manufactured by Synthesis Example 12) having an average molecular weight of 2,0 0 0 was added dropwise with stirring, and 14.4 parts by weight and an average molecular weight of 1 were added dropwise with stirring. After the mixture of 9,000 parts of polyoxytetramethylene glycol 9 6 parts by weight, the reaction was carried out at 70 ° C for 3 hours. Next, 1 part by weight of N,N-diindole-1,3-propylenediamine was added, and the reaction was further carried out at a temperature of 40 ° C for 1 hour. The amine value of the thus obtained solution containing the dispersion resin was determined by neutralization titration to be 3 2 mgKOH/g. Further, the resin content was determined by dry-drying (heating at a temperature of 150 ° C for 30 minutes to remove the solvent and calculating the resin concentration from the amount of change in weight) to obtain a resin content of 40 w %. &lt;Synthesis Example 1 5 &gt; Synthesis of urethane-based dispersion resin A polycaprolactone having an average molecular weight of 2,000 having a lauryloxy group formed at one end of Synthesis Example 14 was changed to be formed at one end. In the same manner as in Synthesis Example 14, except that the polycaprolactone having an average molecular weight of 2,0 0 (the one obtained by Synthesis Example 13) having a nonyloxy group was synthesized, the following structure 94 312 / Disclosure resin made by the invention specification (supplement)/93-04/93101159 1296639. The acid value of this resin is 3 2 m g Κ Ο Η / g, and the resin content is 4 0 w t % 〇 &lt;Synthesis Example 1 6 &gt; Synthesis of Amino Acryl Ester-Based Dispersing Resin In addition to the polycaprolactone having an average molecular weight of 2,000 having a lauryloxy group formed at one end of Synthesis Example 14 was changed to one end Polycaprolactone having an average molecular weight of 2,0 0 (formed by Synthesis Example 13) and having N,N-diindole-1,3-propylenediamine changed to a 3-amino group Extrusion was carried out in the same manner as in Synthesis Example 14 except that the -1,2,4-three-degree sitting was carried out to obtain a dispersion resin. The acid value of this resin was 3 2 m g Κ Ο H / g, and the resin content was 40 w %. The configuration of the urethane-based dispersing agent prepared in Synthesis Example 1 4 to 16 is as follows:

H3c In the above formula, each R independently represents any of the groups shown by R in Table-1. 95 312/Invention Manual (Supplement)/93-04/93101159 1296639 Table-1 R Mobi Ratio Synthesis Example 14 - NHC-^OCHaCHzCHzCHz-^-OH 0 4 —NHC-f〇CH2CH2CH2CH2CH2--CU〇C12H25 ο δ / 3 CH —nhcnh-ch2ch2ch2-n^ 3 o ch3 8 Synthesis Example 15—NHC 十CH2CH2CH2CH OH 0 4 —NHg-^OCH2CH2CH2CH2CH2-{^OCH3 0 0 3 xch3 —nhcnh-ch2ch2ch Wide nC 〇CH3 8 Synthesis Example 1 6 —NHg 十CH2CH2CH2CH2^-OH o 4 —NHC-JoC^CHzCHzCHzCHz-C-JpOCHa 3 -nhcnh^nh O Nia/ 4 *n = 14,m=16,1 = 17 (average value) &lt;Synthesis Example 1 7 &gt; Synthesis of Dispersant A' gives 50 parts by weight of polyethylenimine having a molecular weight of about 5,000 and 40 parts by weight of polycaprolactone having n = 5 and 300 parts by weight of propylene glycol monomethyl ether acetate (weight) The mixture was stirred and stirred at a temperature of 150 ° C for 3 hours under a nitrogen atmosphere. The thus synthesized dispersant has a weight average molecular weight M w of about 9000 as measured by GPC. &lt;Synthesis Example 18 &gt; Dispersant Β 'Synthesis gives a polyethylenimine 50 having a molecular weight of about 5,000. Parts by weight, η = 5 polycaprolactone 40 parts by weight, and stearic acid 6 parts by weight mixed with propylene glycol monomethyl ether acetate 300 parts by weight, while at 15 Stir at a temperature of 0 ° C for 3 hours under a nitrogen atmosphere. The weight average molecular weight Mw measured by GPC of the dispersant thus synthesized was about 930. 96 312 / Inventive specification (supplement) /93-04/93101159 1296639 &lt;Synthesis Example 1 9 &gt; Dispersant C 'Synthesis 50 parts by weight of polyethylenimine having a molecular weight of about 1 000 , η: 40 parts by weight of polycaprolactone, and 6 parts by weight of stearic acid and 450 parts by weight of dimethyl ether acetate, and at a temperature of 150 ° C and &gt; Stir under a gaseous atmosphere for 3 hours. The dispersant thus synthesized has a weight average molecular weight Mw of about 1 9000 by GPC. &lt;Preparation of Red Pigment Dispersion&gt; C _ I · Pigment Red serving as a color material 1 7 7 1 0 · 0 0 parts by weight, propylene glycol monoterpene ether acetate 3 3 · 7 5 parts (by weight), used as a dispersing agent in Dispersion Table-1, 6 · 25 parts by weight, and a diameter of 0 · 5 m zirconia beads, 180 parts by weight, filled in a stainless steel container, made with a painter The dispersion was allowed to stand for 6 hours to prepare a red pigment dispersion. &lt;Preparation of Blue Pigment Dispersion&gt; C · I · Pigment Blue 1 5 : 6 1 0 · 0 0 (by weight) as a color material, propylene glycol monomethyl ether acetate S as a solvent 33.75 parts by weight Served as a dispersing agent of 2.6 parts by weight as described in Table-1 and 180 parts by weight of zirconia beads of 0 Å filled in a stainless steel container and dispersed by an oil squeegee A blue pigment dispersion was prepared for 6 hours. &lt;Preparation of Green Pigment Dispersion&gt; C·I·Pigment Green 3 6 1 0·0 0 (by weight) serving as a color material, and 33.75 parts by weight of a propylene glycol monomethyl bond acetate serving as a charge Dispersing agent - 2 to 4 - Dispersing agent: 6. 5 parts by weight, and 0 parts by weight of zirconia beads, 180 parts by weight, filled in a stainless steel container, and dispersed by an oil sitter for 6 hours , and a green pigment dispersion was prepared. 312 / invention specification (supplement) / 93-04 / 93101159 = 5 alcohol single &amp; nitrogen measured when the shaking of the solvent m acts as a powder 5 mm paint shake as a solvent. 5 mm paint shake 97 1296639 Table - 2 A Dispersant BC synthesized in Synthesis Example-3 Dispersant synthesized in Synthesis Example-4 Dispersant synthesized in Synthesis Example-5 DE "Byk-Chemie" product "Disperbyk-2000" (denatured coupon, force block Copolymer) "Disparlonda-325" (Nanthene amine salt) Table-3 Formula (I) content in dispersant graft copolymer (m ο 1 % ) Ri A ( m 0 1 % ) ] [Molecular weight Mw Ο yCieH37 , c, II 0 H Α, 100 C2H4 10 0 90 9 0 0 0 Β, 100 C2H4 10 2 88 9 3 0 0 __ C, 100 C2H4 10 2 88 19000 A D, " Byk-Chemie's product "Disperbyk-2000ι" is also a product of the company "DISPARLONDA - 325" (amine salt of polyether phosphate). Table-4 Dispersant Structure or trade name: commercially available product: block structure unit derived from mercapto acrylate (block B) and in methacrylic acid The side chain has a quaternary ammonium salt of the following formula: the block structure unit (block A) of the AB block copolymer xh3 - N + polyphenylene conversion weight average molecular weight: 4000 | ^ cH3 H2C four Amount of ammonium base: dispersant per gl. 75 mmol Acid value: Omg-KOH/g pj) Amine value: 4 mg-K0H/g B, the phosphate H3C, 0~ shown in the following structural formula.丫~丫~^ 〇〇HO 0H C" "DISPARLONDA - 325" ("Alkyl salt of polyether phosphate") <Preparation of coloring composition> According to Table _ 5 to Table -9 Composition, the other pigment components were mixed with the other components to prepare Examples 1 to 18.8, Comparative Example 1 to Comparative Example 98.

312/Invention Manual (Supplement)/93-04/93101159 1296639 1 3 The curable resin composition. Further, in Comparative Example 9, in addition to the components of Tables 5 and 6, a succinic acid serving as an organic carboxylic acid component was added in an amount of 0.33 parts by weight. Table - 5 Ingredients of the composition of the components of the composition of the amount of the component (weight) of the pigment material of the above pigment dispersion 10. 0 Solvents of the above pigment dispersion + propylene glycol monoterpene ether acetate 127. 0 dispersant of the above pigment dispersion 6. 25 Adhesive Resin The following table shows the structure of 6.5. Organic carboxylic acid, organic carboxylic acid The following table shows the compounds described in the following table. Photopolymerizable monomer 1 Ethyl compound (a) 3. 25 Photopolymerizable single Body 2 Ethylene compound (b) 3. 25 Photopolymerization initiator component 1 2-M benzothiazole 0. 83 Photopolymerization initiator component 2 p-dioxamic acid oxime oxime ester 0. 83 photopolymerization Initiator component 3 Miclotone 0. 83 [Note] (1) The ethylenic compound (a) is a compound represented by the following structural formula [V]:]. (2) The ethylenic compound (b) is trishydroxypropyl propane triacrylate. Table - 6 Dispersant binder resin Organic carboxylic acid, organic carboxylic anhydride type Adding amount (by weight) Example 1 A a succinic anhydride 0.35 Example 2 B a succinic anhydride 0. 35 Example 3 C a succinic anhydride 0.35 Example 4 A b maleic anhydride 0. 35 Example 5 C b cis-butanyl dianhydride 0. 35 Example 6 A c maleic anhydride 0. 35 Comparative Example 1 C d succinic anhydride 0. 35 Comparative Example 2 C e succinic anhydride 0. 35 Comparative Example 3 D b succinic anhydride 0. 35 Comparative Example 4 E b No 0 Comparative Example 5 D e None 0

CH2=CH-C-〇-CH2-C-CH2-〇 OH OH o- 分 Pq_ ch3 Η ——ch2-c-ch2-o-c-ch=ch2 [VI]

I II OH 0 99 312/Invention Manual (Supplement)/93-04/93101159 1296639 Table - 7 Adhesive Resin (A) (B) Copolymer Raw Material Monomer (m〇l%) Ingredient (C) (Add Yield component (D) (addition rate 2 &gt;) Ingredient (A) Ingredient (B) Glycidyl methacrylate, tricyclodecyl methacrylate, styrene benzyl methacrylate, decyl acrylate, methacrylate, acrylic acid, tetra argon Citrate a 40 40 20 0 0 0 88 86 b 50 40 10 0 0 0 90 82 c 50 30 0 10 10 0 90 82 d 0 0 60 0 0 403) 0 0 e 0 0 0 30 30 40° 0 0 1 The addition ratio (m〇i%) of the component (C) based on the epoxy group contained in the (A) (B) copolymer 2) is the hydroxyl group generated when the component (C) is added Addition ratio of the component (D) of the reference (m〇i%) 3) Adding (3, 4-epoxycyclohexyl) decyl acrylate to 70 mol% of mercaptoacrylic acid 4) Making acrylic acid (3, 4- Epoxycyclohexyl) decyl ester added to thioglycolic acid 55mol0 / 〇 Table 8 Binder resin Weight average molecular weight (Mw) (A) (B) Copolymer raw material monomer (mol%) Ingredient (C) (plus Yield °) Component (D) (Addition rate 2)) Component (A) Component (Β) Glycidyl methacrylate δ, tricyclodecyl acrylate, styrene methyl methacrylate, methyl methacrylate, methacrylic acid, acrylic acid, tetrazos, k s a. 5000 40 40 20 0 0 0 88 86 b, 6000 50 40 10 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 1) The addition ratio (mol%) of the component (c) based on the epoxy group contained in the (A) (B) copolymer 2) based on the hydroxyl group generated when the component (C) is added Addition ratio (mol%) of component (D) 3) Adding (3, 4-epoxycyclohexyl)methyl acrylate to 70 mol% of mercaptoacrylic acid 4) Making acrylic acid (3, 4-epoxy ring) Addition of hexyl)methyl ester to methacrylic acid 55 mol % 100 312 / invention specification (supplement) /93-04/93101159 1296639

Dispersant Adhesive Resin Example 1 A a Example 2 B a Example 3 C a Example 4 A b Example 5 C b Example 6 A c Example 7 A, a Example 8 B, a Example 9 C, a Example 1 0 A, b Example 1 1 B, b Example 1 2 A, c Example 1 3 A" a, Example 1 4 A丨丨b, Example 1 5 An + B n ( Weight ratio 2 : 1 ) a, Example 1 6 A &quot; + B π (weight ratio 2 : 1 ) b, Example 1 7 An + B &quot; (weight ratio 2 : 1 ) c, Example 1 8 A n + B &quot; (weight ratio 2: 1) d, Table-9 (continued)

Dispersant binder resin Comparative Example 1 C d Comparative Example 2 C e Comparative Example 3 D b Comparative Example 4 E b Comparative Example 5 D e Comparative Example 6 A, d Comparative Example 7 A, e Comparative Example 8 D, b Comparative Example 9 A, d Comparative Example 1 0 A π + Β π (weight ratio 2 : 1 ) e , Comparative Example 1 1 A &quot; + Β &quot; (weight ratio 2 ·· 1 ) f, Comparative Example 1 2 C&quot; a Comparative Example 1 3 C&quot; b, &lt;Example 1 9 to 2 7 and Comparative Example 1 4,1 5 &gt;&lt;Synthesis Example 2 0 &gt; Synthesis of Adhesive Resin (a&quot;)

35 parts of propylene glycol monomethyl ether acetate, 8.8 parts of 1-oxo-2-propanol, 312/invention specification (supplement)/93-04/93101159 101 1296639 and azo polymerization initiator ("Huangguang pure Waco Chemical Industries, Ltd. product "V-59") 1.5 parts of the container, heated to 80 ° C under nitrogen atmosphere, for 2 hours to add benzyl methacrylate 9. 5 parts, methyl methacrylate 6. 3.5 parts of 2-hydroxyethyl methacrylate, and decyl acrylate 10.7 were then stirred for 4 hours to obtain a polymerization reaction liquid. To the above polymerization solution, propylene glycol monomethyl ether acetate fraction, p-oxime oxyphenol 0.5 parts, and triphenylphosphine 0.3 parts were added, so that after the addition of acrylic acid (3, 4 - Epoxycyclohexyl) oxime ester 17. 7 parts of the reaction at a temperature of 8 5 ° C for 24 hours, to obtain a resin solution having an ethylenically unsaturated group in the side chain (hereinafter referred to as binder resin (a&quot;)) . The binder resin (a&quot;) has a polymerization average molecular weight measured by GPC in terms of polyphenylene value of 1 800. Further, the acid value obtained by performing neutralization titration with K 0 Η is 50. The carboxyincorporation rate of (3,4-epoxycyclohexyl)methyl acrylate was found to be 6 6 °/〇 from the acid value before and after the reaction. &lt;Synthesis Example 2 1 &gt; Synthesis of Binder Resin (b&quot;) 35 parts of propylene glycol monoterpene ether acetate, 1, 1-oxo-2-propanol 8.8, and an azo polymerization initiator ("Waguang Pure Waco Chemical Industries, Ltd. product "V-59") 1.5 parts of the container, heated to 80 ° C under nitrogen atmosphere, for 2 hours to add benzyl methacrylate 10 parts, methyl methacrylate, and 1.9 parts of methacrylic acid, and then stirred for 4 hours to polymerize the reaction liquid (hereinafter referred to as binder resin (b&quot;)). The obtained binder (bn) is measured by GPC and the average molecular weight of the polymer is converted according to polystyrene. 312/Invention Manual (supplement)/93-04/93101159

Pure, 5 parts, part, 25. 5 Dissolved, baked in the roasted fruit, the acid, the pure 7.5, the obtained tree value is 102 1296639 1 2 0 0 0, again, Use Κ Η 施 to perform a neutralization titration of 1 20 . &lt;Synthesis Example 2 2 &gt; Synthesis of binder resin (c π ) First, 145 parts of propylene glycol monoterpene ether acetate was stirred and heated to 1,200 °C. To this, 55 parts of glycidyl glycidyl ester was added dropwise, and the mixture was continuously stirred for 2 hours at a temperature of 8 2 ° C with a tricyclodecane ester ("Hitachi Chemical" product "FA - 5 1 3 Μ". The ambient gas in the reaction vessel was changed to acid 27.1 parts, decylamine phenol phenol 0.77 parts, and the reaction was carried out at &gt;5, and the reaction was continued at the temperature of 1 20 ° C for 6 hours. (ΤΗΡΑ) 52.0 parts, 0.7 parts of triethylamine, and reacted for 3.5 hours to obtain a polymerization reaction liquid (hereinafter (cn)). The obtained binder resin (cn) was measured by GPC. The conversion value is 15000. The types of dispersing agents used in the following examples are shown as follows. Further, the addition of the dispersing agent and the measurement of the heating weight loss are carried out according to the following methods, and the results are shown in the table &lt;Dispersant Determination of the amount of heat and nitrogen reduction&gt; The dispersant is weighed at about 50 to 100 mg and placed under a condition of 50 m 1 1 0 0 mm H g under reduced pressure for 48 hours to make the sample before dry heat. The dried solid dispersant is heated for 30 minutes under hot air circulation. This is called a sample after heating. The powder is used in "PERKINELMER" company. 312 / invention manual (supplement) / 93-04/93101159, the acid price obtained with nitrogen gas under I 20 parts, methyl propyl skeleton of the mono-acrylic acid, and then in the 1 2 0 air The propylene L hydroquinone was subjected to 0.1 part by weight. Thereafter, the measurement of the thermal nitrogen reduction amount in Table 10 under the polymerization average molecular weight of the binder resin was carried out at a temperature of 4 to 120 °C. Beaker, at 60 ° C, solid. This is called the furnace inside the temperature of 2 3 0 °C before and after heating _ PE 2 4 0 0" series 103 1296639 C Η NS / 0 analyzer under the elemental analysis The amount of the whole atmosphere is measured. The amount of nitrogen is the ratio of the total amount, and this is multiplied by the weight before and after the heating measured by the following method to calculate the absolute amount. &lt;Measurement of heating and weight reduction of the dispersing agent&gt; The dispersant is obtained by the same method as above, and the weight is measured using a precision balance. Table - 1 0 Dispersant Total Nitrogen Weight Before Heating (wt%) After Heating (wt%) Residual Rate (°/〇) Before Heating (g) After heating (g) Residual rate (%) Zeneca product "SOLSPERSE34750" 4. 50 4. 35 97 0.0752 0.0705 94 By k-Chemie product "DisperBYK_161" 8. 10 7. 25 90 0. 0618 0.0566 92 Byk-Chemie product "DisperBYK-2001" 3. 04 1. 53 50 0. 1044 0.0711 68 &lt;Preparation of pigment dispersion&gt Use C · I · Pigment Green (C · I · Ρ · G · ) as a color material 3 6 and C. I · Pigment Yellow (C · I · Ρ · Υ · ) 1 3 8, propylene glycol as a solvent Ether acetate (PG Μ EA ), the dispersant listed in Table -1 0, the above-mentioned binder resins (a) and (b) are given in the weight ratios shown in Table-1 1 and Table-1 2 mixing. On the other hand, zirconia beads (0.5 m in diameter) were mixed in an amount of 3 times the total weight, and then filled in a stainless steel container, and dispersed by a paint shaker for 6 hours to prepare a green pigment dispersion. 104 312/Invention Manual (Supplement)/93-04/93101159 1296639 Table - 1 1 Color Material Solvent Dispersant Adhesive Name Needle Lipid CIPG 36 Weight Ratio (%) CIPY 138 Weight Ratio (%) PGMEA Weight Ratio (%) Type weight ratio (%) Type weight ratio (%) Example 19 5.0 5.0 83.0 Zeneca product "SOLSPERSE34750" 2.0 Adhesive resin (a) &quot; 5.0 Example 20 5.0 5.0 82.0 Zeneca product "SOLSPERSE34750" 3.0 Adhesive resin (a)&quot; 5.0 Example 21 5.0 5.0 82.0 Byk_Chemie product "DisperBYK-161" 3.0 Adhesive resin (a) &quot; 5.0 Example 22 5.0 5.0 81.0 Byk-Chemie product "DisperBYK-161" 4.0 Adhesive resin (a)&quot; 5.0 Example 23 5.0 5.0 83.0 Byk-Chemie product rDisperBYK-2001j 2.0 Adhesive resin (a)&quot; 5.0 Example 24 5.0 5.0 81.0 Byk-Chemie product "DisperBYK-2001" 4.0 Adhesive resin (a)&quot; 5.0 Table 12 Color solvent Solvent dispersant 4 Sealing grease CIPG 36 Weight ratio (%) CIPY 138 Weight ratio (%) PGMEA Weight ratio (90 kinds of weight ratio %) Type weight ratio (%) Example 25 5.0 5.0 84.0 Zeneca product "SOLSPERSE34750" 6.0 No 0.0 Comparative example 14 5.0 5.0 82.0 Zeneca product "SOLSPERSE34750" 3.0 Adhesive resin (6)&quot; 5.0 Comparative example 26 5.0 5.0 84.0 Byk- Chemie's product "DisperBYK-161" 6.0 No 0.0 Comparative Example 15 5.0 5.0 82.0 Byk-Chemie product "DisperBYK-161" 3.0 Adhesive Resin (6)&quot; 5.0 Example 27 5.0 5.0 79.0 Byk-Chemie product "DisperBYK-161" 6.0 Adhesive Resin (a) &quot; 5.0 &lt;Preparation of Colored Resin Composition&gt; The above pigment dispersion was mixed with other components to prepare a colored resin composition having a solid content ratio as shown in Table 13. Further, the colored resin composition of this item was diluted with propylene glycol monomethyl ether acetate, and was formulated so that the total solid content concentration could be 20 w %. 105 312/Inventive manual (supplement)/93-04/93101159 1296639 Table-1 3 Ingredients of the type of the component Details of the solid content (%) Raw material dispersion The above pigment dispersion liquid 53. 0 Adhesive resin adhesive resin (c )&quot; 23. 5 Photopolymerizable monomer 1 Ethylene compound (d) n 7.8 Photopolymerizable monomer 2 Ethylene compound (e) n 3. 9 Photopolymerization initiator component 1 2-indole benzothiazole 3. 9 photopolymerization initiator component 2 p-dioxamic acid decyl phthalate 3. 9 photopolymerization initiator component 3 mitoxone 3. 9 Table-1 3 Ethylene compounds ((1) "is a compound represented by the following chemical formula (17), and the ethylenic compound (e) π is trihydroxymercaptopropane triacrylate

(17) Η —ch2-c-ch2-〇-c-ch=ch2 OH Ο &lt;Production of color filter&gt; Metal chromium is formed into a film by sputtering to have a length of 370 mm and a width of 470 mm. On a glass substrate with a thickness of 0.7 mm (Asahi Glass, AN100), after using a positive photoresist to form a matrix pattern, a mixture of ammonium nitrate (IV) and perchloric acid is used. Under the etching solution, etching of a chromium film is performed. Finally, a positive resist was peeled off with a 5% aqueous sodium hydroxide solution to form a black matrix. On the thus obtained glass substrate with a black substrate, a colored resin composition containing a red color material was applied under the use of a die coater. Press again, for the die coater, use a stainless steel die coater with a width of 3 60 mm long, and 106 312 / invention manual (supplement) /93-04/93101159 1296639 set its die spacing to 2 Ο Ο μ m, the gap between the surface and the glass substrate is set to 100/zm. At the time of coating, the discharge amount of the ink-like coating liquid was adjusted so that the dry film thickness was 1.3/zm. Thereafter, after drying at 6 (TC temperature for 1 minute, it was dried by heating at a temperature of 110 ° C for 2 minutes. Subsequently, a distance between 30 #m, vertical 330#m, and horizontal 110#m was used. The negative photomask is subjected to exposure treatment with a 2 k W high-pressure mercury lamp at an exposure amount of 300 m J / c m 2 . Thereafter, regarding the development treatment, a 0.1 wt % aqueous solution of sodium carbonate is used. Next, the image is imaged at a temperature of 2 3 ° C. Then, under a water pressure of 3 kg / c m 2 , a spray water treatment is performed for 30 seconds to form a red pixel. Then, at 2 3 0 The heat hardening treatment was carried out for 7 minutes at a temperature of ° C. Next, the colored resin composition containing the blue pigment and the colored resin composition containing the green pigment were separately coated, preliminarily dried, and dried by heating in the same manner as described above. Each of the processes of exposure, development, development, water washing, and heat hardening sequentially forms a color pattern to obtain a color filter. Thus, each of the first to third embodiments, the comparative example 1 to the comparative example 1 9 is used. Under the curable resin composition, each of the 100 color filters is prepared. Example 1 9 to 30 and Comparative Example 1 4 to 1 7 A single color filter was produced using only the green colored resin composition, and only the blue coloring was carried out with respect to Example 3 1 and Comparative Example 18 and 19. A resin composition was used to produce a color filter of a single color for evaluation as described later. <Evaluation of whitening defect of color filter> Regarding the obtained color filter, it was measured whether or not a white-induced defect was caused. The whitening defect generation rate is shown in Table-14. In Table-14, the meaning of red, blue, and green is that there is whitening in the pixels of each color. Press again, 107 312/Invention Manual (Supplement) /93-04/93101159 1296639 The white-out defect is defined as the square root of [(long diameter) 2+ (short diameter) 2] is 40/zm or more, and the white-induced defect generation rate is defined as any color. The number of color filters with white-defective defects is divided by the number of manufactured chips (100 pieces). The evaluation results are shown in Table - 14. 4. Non-pixel portion of color filter Evaluation of Undissolved Matter (Residue)&gt; Regarding the obtained color filter, a product of "To ray" company "TORAYS" was used. EE-ΜK-Clean Cloth") The operation of reciprocating the portion of the non-pixel portion (on the plain glass) by 10 0 X 1 0 0 mm. The above-mentioned cloth "T0RAYSEE-MK-Clean Cloth" is fixed at the tip end of a resin square material of lcmxlcm, and is impregnated with a Papillon pipette to 0.1 C c ethanol. If it is visually recognized that the pigment adheres to the panel, it is evaluated as "〇", and when recognized, even if the amount of adhesion is small, it is evaluated as "X". Further, for the 1 c m X 1 c m portion of the cloth after wiping, the spectral reflectance was measured under the condition of using an integrating sphere by a _ spectrophotometer U V - 3 1 0 0 S manufactured by Shimadzu Corporation. In Table-14, the spectral reflectances of λ = 500 nm (corresponding to the red residue), 4500 ns (corresponding to the green residue), and 550 nm (corresponding to the blue residue) are shown. Further, the limit of the 〇X determination at the time of visual evaluation is equivalent to 95% of the spectral reflectance. 108 312/Invention Manual (supplement)/93-04/93101159 1296639 Table - 1 4 Evaluation of white-defective residue red (s) Blue (s) Green (s) Production rate (%) Visual spectroscopic reflectance (%) 500 nm 450 nm 550 nm Example-1 0 0 0 0 〇98 99 98 Example-2 0 0 0 0 〇99 99 99 Example-3 0 0 0 0 〇99 99 98 Example-4 0 0 0 0 〇98 99 99 Example-5 0 0 0 0 〇99 99 99 Example -6 0 0 0 0 〇98 99 99 Example -7 0 0 0 0 〇99 98 97 Example -8 0 0 0 0 〇99 99 98 Example-9 0 0 0 0 〇98 99 98 Example _10 0 0 0 0 〇99 98 99 Example -11 0 0 0 0 〇99 99 98 Example -12 0 0 0 0 〇98 99 97 Example -13 0 0 0 0 〇98 99 97 Example-14 0 0 0 0 〇99 99 98 Example -15 0 0 0 0 〇99 98 98 Example-16 0 0 0 0 〇98 99 99 Example-17 0 0 0 0 〇98 98 99 Embodiment -18 0 0 0 0 〇98 99 98 Example -19 — A 0 0 〇 99 — Example -20 — — 0 0 〇 — 98 — Example-21 — — 0 0 〇— 99 — Example-22 — 0 0 〇 — 98 — Implementation Example -23 - A 0 〇 98 98 例 Example-24 — — 0 0 〇 99 99 — Example-2 5 —— 0 0 〇 — 98 — 109 312 / Invention Manual (supplement) / 93-04 / 93101159 1296639 Table _ 1 4 (continued) Evaluation of white-defective residue red (s) Blue (s) Green (s) Production rate «) Visual spectroscopic reflectance (%) 500 nm 450 nm 550 nm Example -26 - a 0 0 〇一98 - Example -27 - A 0 0 〇 - 99 An embodiment -28 - 0 0 〇 99 - Example _29 - 0 0 〇 99 - Example -30 一 一 0 0 〇 - 99 — Example-31 — 0 — 0 〇 — A 99 Comparative Example-1 0 0 0 0 X 85 77 80 Comparative Example-2 I 2 1 5 8 〇99 98 98 Comparative Example-3 0 0 0 0 X 82 72 77 Comparative Example-4 0 0 0 0 X 74 67 71 Comparative Example-5 3 1 4 8 X 75 68 70 Comparative Example-6 0 0 0 0 X 77 70 74 Comparative Example-7 2 1 5 8 〇99 99 98 Comparison Example-8 0 0 0 0 X 81 83 80 Comparative Example-9 2 2 6 10 〇98 99 99 Comparative Example-10 0 0 0 0 X 78 82 81 Comparative Example-11 4 1 4 9 〇99 98 98 Comparative Example - 12 0 0 0 0 X 77 79 80 Comparative Example-13 0 0 0 0 X 74 76 79 Comparative Example _14 — A 0 0 〇— 99 — Comparative Example -15 ———· 0 0 〇— 99 A Comparative Example-16 — — 0 0 〇— 99 A Comparative Example -17 — — 0 0 X — 70 - Comparative Example -18 0 - 0 - 99 Comparative Example -19 - 0 - 0 X - One 75 According to the contents of Table - 14 above, the incidence of white-out defects of each embodiment is 0%, No residue was found according to the visual and spectral reflectance. On the other hand, whitening defects were found in Comparative Examples 1 to 13, 3, and 19 or the presence of residue was observed according to the visual observation and spectral reflectance of 110 312/invention specification (supplement)/93-04/93101159 1296639. In Comparative Examples 1 4 to 16 and 18, no whitening defects or residual liquids were observed, but the transmittance (described later) was inferior. &lt;Evaluation of Transmittance (Measurement of Chromaticity)&gt; The colored resin composition of each of the examples and the comparative examples was applied by spin coating to a glass substrate of 5 cm square (Asahi Glass product "AN100" l % P a的水压。 On the hot plate is heated at 80 ° C for 3 minutes, after a full exposure of 100 00 J / cm 2 , with a concentration of 0 ° l °% sodium carbonate aqueous solution at 0. 3 Μ P a water pressure Spray imaging was performed for 30 seconds. Thereafter, 2 3 (TC 30 minute firing) is performed in the hot air circulation furnace. The film thickness of the colored resin composition after firing is the color coordinate shown by the CIE color system, and the red color can conform to x = 0.60. The green color can be adjusted to y = 0.55, and the blue color can be adjusted to y = 0.14 (all C light sources). For the determination of the color, a spectrophotometer "U 3 5 0" manufactured by Hitachi, Ltd. is used. 0. The chromaticity of each colored resin composition is shown in Table-15. 111 312/Invention Manual (Supplement)/93-04/93101159 1296639 Table-1 5 Chroma (C Light Source) RGBX y YX y YX y Y Example-1 0. 600 0.291 17. 3 0. 210 0. 550 44. 0 0. 137 0. 140 19. 3 Example-2 0. 600 0. 291 17.4 0.210 0. 550 44. 1 0 137 0. 140 19.2 Example-3 0. 600 0. 291 17. 3 0.210 0. 550 43. 9 0. 137 0. 140 19.2 Example - 4 0. 600 0. 291 17. 4 0. 210 0 550 44. 2 0. 137 0. 140 19. 3 Example-5 0. 600 0. 291 17. 2 0. 210 0. 550 44. 1 0. 137 0. 140 19. 3 Example-6 0 600 0.291 17.4 0. 210 0. 550 44. 0 0. 137 0. 140 19. 3 Example-7 0. 600 0. 291 17.4 0.210 0. 550 44. 1 0. 137 0. 140 19. 2 Example-8 0. 600 0. 291 17. 3 0.210 0. 550 44. 2 0. 137 0. 140 19. 2 Example -9 0. 600 0.291 17. 3 0.210 0. 550 44. 0 0. 137 0. 140 19. 3 Example-10 0. 600 0. 291 17.2 0.210 0. 550 43. 9 0. 137 0. 140 19. 3 Example-11 0. 600 0. 291 17.4 0. 210 0. 550 44. 0 0. 137 0. 140 19. 2 Example-12 0. 600 0.291 17.4 0.210 0. 550 44. 1 0. 137 0. 140 19.2 Example-13 0. 600 0. 291 17. 4 0. 210 0. 550 43. 9 0. 137 0. 140 19. 3 Example-14 0. 600 0. 291 17.3 0.210 0. 550 44. 1 0. 137 0. 140 19. 3 Example-15 0. 600 0. 291 17.2 0.210 0. 550 44. 0 0. 137 0. 140 19. 2 Example-16 0. 600 0. 291 17.4 0.210 0 550 44. 1 0. 137 0. 140 19· 3 Example-17 0. 600 0. 291 17. 2 0. 210 0. 550 44. 0 0. 137 0. 140 19. 2 Example-18 0 600 0. 291 17. 3 0. 210 0. 550 44. 1 0. 137 0. 140 19. 3 Example -19 - One 0.310 0. 550 67. 9 One - Example -20 - One 0.310 0. 550 68.0 — — — Example-21 — A — 0.310 0. 550 67. 6 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — 310 0. 550 68. 3 a - an embodiment -25 - 0.310 0. 550 67. 9 - one 112 312 / invention specification (supplement) /93-04/93101159 1296639 is not within the scope of the above formula, Regarding the comparative examples 4, 1, 2, 1, 3, 18, and 1, the chromaticity of each blue pixel is not within the range of the above formula. [2 - 2 ] Development adhesiveness The colored resin composition of each of the examples and the comparative examples was applied to a glass substrate so that the dry film thickness was 1.3/m, and dried at a temperature of 60 ° C. After a minute, it was dried by heating at a temperature of 110 ° C for 2 minutes, and exposed to a linear mask having a line width of 1 V m under a test mask at a gap of 150//m at 300 mJ/cm 2 . After the exposure, the liquid was applied for 2 seconds at a temperature of 23 ° C at a temperature of 23 ° C at a temperature of 23 ° C for 60 seconds, followed by a water spray at a water pressure of 3 kg / c m 2 . At the time of forming a pattern for 30 seconds, the minimum pattern width remaining in the line image was measured. The results are shown in Table-16. 114 312/Invention Manual (Supplement)/93-04/93101159 1296639 Table-1 6 Red Green Blue Example-1 7 6 7 Example-2 6 5 6 Example-3 6 6 6 Example-4 7 6 6 Example-5 6 6 7 Example-6 7 5 6 Example-7 7 5 7 Example-8 6 6 7 Example - 9 6 5 6 Example-1 0 7 5 6 Example-1 1 7 6 7 Example-1 2 6 6 6 Example-1 3 7 6 6 Example-1 4 7 5 7 Example-1 5 6 6 7 Example-1 6 7 6 7 Example-1 7 7 6 7 Example-1 8 7 5 7 Example-1 9 - 6 - Example-2 0 - 5 - Example - 2 1 - 5 - Example-2 2 - 5 - Example-2 3 - 6 Example _ 2 4 - 5 - Embodiment - 2 5 - 6 - Embodiment - 2 6 - 6 - Embodiment 2 - 7 1 - 5 - Embodiment - 2 8 | | - 5 - Example - 2 9 I - 5 - Example - 3 0 - 6 - Example-3 1 - 6 Unit: ju m

312/Invention Manual (Supplement)/93-04/93101159 115 1296639 Table-1 6 (Continued) Red Green Blue Comparative Example - 1 7 6 6 Comparative Example-2 15 18 13 Comparative Example - 3 6 5 6 Comparative Example -4 6 6 7 Comparative Example-5 14 20 14 Comparative Example-6 7 6 7 Comparative Example - 7 14 20 15 Comparative Example-8 6 5 6 Comparative Example - 9 12 18 13 Comparative Example-1 0 6 5 6 Comparative Example -1 1 16 19 15 Comparative Example 1 2 6 5 7 Comparative Example - 1 3 7 6 6 Comparative Example - 1 4 - 5 - Comparative Example - 1 5 - 5 - Comparative Example - 1 6 - 6 A Comparative Example - 1 7 — 5 一比车交 i&quot;列一1 8一一六6 Compare You I 1-1 — 6 Unit: ju m According to Table-1 above, the minimum of red, green and blue in each embodiment The pattern width is 1 0 /zm or less. On the other hand, the minimum pattern width of Comparative Examples 2, 5, 7, 9, and 11 is more than 10//m. &lt;Evaluation of viscosity change rate&gt; The viscosity of the colored resin composition immediately after preparation and the viscosity (20 rpm) after standing at 7 ° C in a constant temperature unit were used in "Toki Industry" (Toki) It was measured under the E-type viscometer "RE-80L" manufactured by Sangyo Co., Ltd.). The viscosity of the colored resin composition of each of the examples and the comparative examples and the viscosity change rate during the 7-day period are shown in Table-1. 116

312/Invention Manual (Supplement)/93-04/93101159 1296639 Table-1 7 RGB initial viscosity mPa · s 7曰 viscosity mPa · s rate of change % initial viscosity mPa · s viscosity after 7 days mPa · s rate of change % Initial viscosity mPa . s Viscosity after 7 days mPa · s Rate of change % 1.0 Example-1 6.03 6· 09 1.0 7.50 7.56 0.8 6. 24 6· 30 Example-2 6. 24 6. 27 0.5 7.32 7.41 1.2 6.42 6.51 1.4 Example-3 6.33 6.39 0.9 I 7.26 7.35 1.2 6.36 6.45 1.4 Example _4 6.18 6.18 0.0 | 6.99 7.05 0.9 6.21 6. 27 1.0 Example-5 6.21 6. 33 1.9 1 7.47 7. 53 0.8 6.18 6.18 0.0 Example-6 6.03 6. 03 0.0 7.20 7. 32 1.7 6.27 6.33 1.0 Example-7 6.21 6.18 -0.5 7. 02 7.11 1.3 5. 97 6.03 1.0 Example-8 6. 24 6· 30 1.0 7. 32 7.35 0.4 6.30 6. 36 1.0 Example-9 6.15 6.21 1.0 7. 20 7. 32 1.7 6. 27 6.27 0.0 Example-10 6.66 6. 72 0.9 7· 35 7.41 0.8 6.87 6.96 1.3 Example-11 6.54 6.54 0.0 7.29 7.41 1.6 6.51 6.60 1.4 Example-12 6.09 6.18 1.5 6. 96 7. 02 0.9 6.21 6.24 0.5 Example-13 6.39 6.42 0.5 7.05 7.08 0.4 6.12 6.15 0.5 Example-14 6.51 6· 51 0.0 7.35 7.38 0.4 6.21 6.24 0.5 Example-15 6.36 6. 33 -0.5 7. 29 7.41 1.6 6.36 6.39 0.5 Example-16 6.45 6.51 0.9 7.11 7.08 -0.4 6.51 6. 57 0.9 Implementation Example-17 6.36 6. 42 0.9 7. 50 7.56 0.8 6.33 6.39 0.9 Example-18 6. 54 6.51 -0.5 6. 93 6. 99 0.9 6. 66 6. 69 0.5 Example -19 — I — 7. 86 7.95 1.1 - - Example -20 - - 7.44 7.47 0.4 _ I - Example-21 - A - 7.56 7. 56 0.0 - - - Example-22 - - - 7.11 7.14 0.4 - - - Example -23 — — — 7. 62 7.71 1.2 ——— Example-24 — — — 6. 93 6. 93 0.0 ——— Example-25 — — — 6.87 6.90 0.4 — — — 117 312/Inventive Manual (Supplement Pieces) /93-04/93101159 1296639 Table-1 7 (continued) RGB initial viscosity mPa · s viscosity after 7 days mPa · s change rate initial viscosity mPa · s 7曰 viscosity mPa · s rate of change % initial viscosity mPa s 7 days after the viscosity mPa · s rate of change % Example -26 - a 6. 75 6. 75 0.0 - an example -27 — — — 6.42 6.42 0.0 - Example -28 - - 8.22 8. 34 1.5 - - - Example -29 - - 8.40 8.52 1.4 - Example -30 - A - 8.31 8.52 2.5 - - Example - 31 - One - — a 7.53 7.71 2.4 Comparative Example-1 6.18 6. 45 4.4 7. 44 7.59 2.0 6.78 6.90 1.8 Comparative Example-2 7.14 7.56 5.9 7. 77 7. 92 1.9 6.57 6.69 1.8 Comparative Example-3 7. 62 7.83 2.8 8. 64 8.85 2.4 8.01 8. 22 2.6 Comparative Example-4 8.10 9. 54 17.8 8. 94 10.82 21.0 7. 65 9.18 20.0 Comparative Example-5 7. 28 7.50 3.0 7. 68 7.92 3.1 6· 27 6.60 5.3 Comparative Example -6 6.57 6.66 1.4 7.14 7.14 0.0 6.27 6. 30 0.5 Comparative Example-7 6. 33 6.33 0.0 6· 81 6. 87 0.9 6.36 6.45 1.4 Comparative Example-8 7.02 7.05 0.4 7· 44 7.56 1.6 6.48 6.51 0. 5 Compare Example-9 6.84 6. 87 0.4 7. 32 7. 38 0.8 6.90 6.93 0.4 Comparative Example-10 6.21 6.27 1.0 7. 23 7.26 0.4 6.00 6.06 1.0 Comparative Example-11 6.42 6.51 1.4 | 6.87 6.96 1.3 6.21 6.21 0.0 Comparative Example - 12 8. 04 10.53 31.0 ! 8.88 9. 54 7.4 8.22 9.96 21· 2 Comparative Example-13 7. 74 9.24 19.4 8.55 10.11 18.2 8.16 10. 80 32.4 Comparative Example-14 — — 8.25 9.87 19.6 一—Comparative Example -15 — — — 8.13 9.66 18.8 — I—Comparative Example-16 — One — 12. 24 16.74 36.8 — — — tt! Comparative Example -17 — One — 6· 78 6.78 0.0 1 - Comparative Example -18 — — — — — 13.39 18.21 36.0 Comparative Example -19 ——— — — — 6.42 6.45 0.5 118 312/Invention Manual (Supplement)/93-04/93101159 1296639 According to the above table - In the content of 1 7 , the viscosity change rates obtained in each of the examples in red, green, and blue are all 10% or less. On the other hand, the viscosity change rate of Comparative Example 4, 1 2 to 16 and 18 was more than 10%. &lt;Evaluation of foreign matter defects of color filter&gt; The color filter obtained was measured for whether or not foreign matter defects were generated, and the rate of occurrence of foreign matter defects was shown in Table-18. In Table-18, the meaning of red, blue, and green is that there is a white change in the pixels of each color. In addition, as for the definition of the foreign matter defect, the square root of [(long diameter) 2 + (short diameter) 2 ] is defined as a foreign matter, and a color filter having a foreign matter defect in any color is defined. The number of sheets divided by the number of manufactured sheets (100 sheets) is defined as the defect generation rate. The evaluation results are shown in Table-18. &lt;Evaluation of Resolubility&gt; The colored resin compositions of the respective examples and the comparative examples were each applied to a 50 mm square glass substrate by a spin coating method at a dry film thickness of 2.5/m, and air-dried 6 0. minute. Then, it was immersed in the solvent for forming the colored resin composition in 6.2 g for 3 minutes, and then dispersed again. After 10 minutes from the start of the impregnation, the company was used by NIKKISO CO. The particle size distribution measuring device "M ic ο T rack UPA" manufactured by LTD.) measures the particle size distribution to calculate the volume average particle diameter mv. The results obtained are shown in Table-1-8. Further, the foreign matter defect generation rate of 0% corresponds to a volume average particle diameter m v of resolubility of 2 0 0 n m or less. 119 312/Invention Manual (supplement)/93-04/93101159 1296639 Table _18 Resolute foreign matter defect red (nm) Blue (nm) Green (nm) Red (a) Blue (a) Green (a) Production Rate Example-1 110 150 90 — — — — Example-2 110 140 90 — — — — Example-3 120 160 100 — — — — Example-4 120 140 90 — I — Implementation 丨j - 5 130 150 100 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — Example-10 110 130 90 — — — — Example -11 120 140 90 — — — — Example -12 130 130 100 — — — — — — — — — — — — — — — — — — — — — — 14 120 130 90 0 0 0 0 Embodiment-15 110 150 100 0 0 0 0 Embodiment-16 120 140 100 0 0 0 0 Embodiment-17 270 280 270 1 2 6 9 Example-18 260 300 250 2 1 5 8 Embodiments_19 — 130 One — — — — Example -20 — 130 — One - One Embodiment - 21 - 140 — One by one — Example-22 - 130 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - — — — — — Example -27 — 140 — — — — Example -28 — 130 — — — — 实施 -29 — 140 — — — — — 实施 -30 — 130 — — — — — 4歹丨j - 31 — — 100 — — — — Table-18 (continued) Resolute foreign matter defect red (nm) Blue (nm) Green (nm) Red (a) Blue (a) Green (a) Production rate comparison example-1 110 130 100 — — a — than board example-2 120 140 90 — one — — comparative example 280 290 240 — — — — than ΐδ/ί歹, j-4 180 220 210 — — ——— Compared with i 丨 - j - 5 300 290 270 one — one than ΐ 4-6 120 130 100 — — one to one · ^ example _7 110 140 90 one — — one ratio * example -8 310 290 220 — — — — 比 交 -9 ～ 110 140 90 — — 一 一 一 一 -10 280 280 250 1 0 2 3 Comparative Example-11 110 140 100 0 0 0 0 比♦ 交例-12 210 230 240 2 1 4 7 Comparative Example-13 210 220 210 1 1 3 5 than i 仓丨丨)-14 — 130 — — — 0 0 ♦ ♦ -15 - 130 One - 0 0 ratio iS / i 歹丨) -16 - 130 - one - 0 0 ratio _ cross example -17 - 130 one - one 0 0 ratio _ cross -18 - one 100 one 0 - 0 comparison example -19一—90 一 0 — 0 120 312/Invention Manual (Supplement)/93-04/93101159 1296639 According to Table-1 above, Examples 1~1 6 and 3 1 do not produce foreign matter defects, that is, It is also excellent in die coating application. &lt;Measurement of Voltage Retention Rate&gt; The electrode substrate A is prepared by forming an ITO film on one surface of an alkali-free glass substrate (Asahi Glass product "AN100") of 2.5 cm square. And an electrode substrate B in which a 1 cm square ITO film is formed on a central portion of a single surface of a 2.5 cc square glass substrate, and an output electrode having a width of 2 mm is connected thereto. After applying an alignment film ("Nissan Chemical Industries, Ltd." product "Sunever7492") to the electrode substrates A and B by spin coating, 1 1 0 ° C was applied to the hot plate. After drying for several minutes, it was heated in a hot air circulating oven at a temperature of 200 ° C for 1 hour to form a coating film having a film thickness of 70 nm. The colored compositions of the respective examples were applied by spin coating to the electrode substrate A coated with the alignment film, and heated on a hot plate at 80 ° C for 3 minutes to be fully pressed at 100 m J / After c m2 exposure, spray development was carried out for 30 seconds using a 0.1 wt% aqueous solution of sodium carbonate at 23 ° C under a water pressure of 0.3 Μ PA. Then, it was fired in a hot air circulating oven at a temperature of 230 ° C for 30 minutes. The coating condition can be adjusted so that the film thickness of the colored composition after firing can be 1. 7 // m. An epoxy resin sealant containing cerium oxide beads having a diameter of 5 // m is applied to the outer periphery of the electrode substrate B coated with the alignment film agent under the use of a dispenser to be colored with the electrode substrate A. The outer edge portion of the surface of the composition was placed at a position offset by 3 mm, and heated in a hot air circulating furnace at a temperature of 180 ° C for 2 hours while being held in compression.份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份5 parts of methyl methacrylate, 2.5 parts of 2-hydroxyethyl methacrylate, and 0.7 parts of methacrylic acid, and then stirred for 4 hours to obtain a polymerization reaction liquid. To the polymerization reaction solution, 5.3 parts of propylene glycol monomethyl ether acetate, 0.5 parts of p-methoxyphenol, and 0.3 parts of triphenylphosphine were added to dissolve the acrylic acid after the dissolution. 3,4-epoxycyclohexyl) decyl ester 1 7.5 parts, and the reaction was carried out at a temperature of 85 ° C for 24 hours to obtain a resin solution having an ethylenically unsaturated group in the side chain. The obtained polymer of the binder was measured by GPC to have a polymerization average molecular weight of 1 800 in terms of polystyrene. Further, the result of neutralization titration with KOH was obtained, and the acid value was 50. The introduction rate of the (3,4-epoxycyclohexyl) decyl acrylate to the carboxylic acid was found to be 66% from the acid value before and after the reaction. &lt;Example 2 8 &gt; The pigment green 3 6 (acting as a pigment) 9 · 4 parts by weight, the resin solution obtained in Synthesis Example 2 3 2. 4 parts (resin solid fraction 9.4 parts), and served as The solvent propylene glycol monomethyl ether acetate 42.4 parts was dispersed in a paint conditioner equipped with zirconia beads for 5 hours to obtain a green ink (colored resin composition). The liquid properties of this colored resin composition are shown in Table - 0. To the thus obtained green ink, 0.1 parts, a photosensitive resin composition prepared by further mixing was prepared, and the resin solution obtained in Synthesis Example 23 was 5.5 parts, which was used as a photopolymerizable monomer of diisoprene. 0.73 parts of alcohol hexaacrylate, bisimidazole serving as a photopolymerization initiator 0.26 parts, 0.18 parts of 4,4 '-bis(diethylamine) diphenyl ketone (EABF) serving as a sensitizer, acting as a chain transfer 2-酼benzothiazole (2ΜΒΤ)0·05 parts, fluorine-based surfactant (“Sumitomo 3M” 123 312/invention manual (supplement)/93-04/93101159 1296639 company product “FC - 4 3 Ο Ο Ο Ο Ο 1 part, and 8.8 parts of propylene glycol monomethyl ether acetate serving as a solvent, and mixed to obtain a green photosensitive resin composition. The green photosensitive colored resin composition was spin-coated on a glass substrate ("Asa Seiko" product "AN 6 3 5"), and dried by heating at 70 ° C to obtain a thickness of 1.5 mM. Photosensitive green layer. The coating film was irradiated with ultraviolet rays of 200 m J / c m 2 under an ultra-high pressure mercury lamp. Then, the alkali imaging solution was applied for showering for 120 seconds, and the water was washed with ultrapure water for 10 seconds to form a green pattern. The pattern obtained after the development is based on the observation that the pattern of the line shape and the adhesion are good. Further, the substrate was exposed to the unexposed portion after the development, and the substrate was visually observed to be contaminated. Those who did not see the base fouling were judged as 〇, those who were slightly white were judged as △, those who were white were judged as X, and the results were shown in Table -20. Further, the measurement results of the Y value in the chromaticity (x, y) of the CIE color system are shown in Table-2. &lt;Example 2 9 &gt; In addition to the use of Pigment Green 3 6 (acting as a pigment) 9 · 4 parts by weight, the resin solution obtained in Synthesis Example 2 2 2 4 parts (resin solid fraction 9.4 parts) was used as The dispersing aid was formed in the same manner as in Example 28 except that the sulfonic acid derivative of the pigment yellow 1 3 8 was 0.4 parts by weight and the propylene glycol monomethyl ether acetate 4 4 serving as a solvent. Green ink (colored resin composition). The liquid properties of this colored resin composition are shown in Table - 0. Under the use of the obtained green ink, the photosensitive colored resin composition was chemically formed in the same manner as in the description of Example 28, and a green pattern was formed in the same manner. The obtained image 124 312 / invention specification (supplement) / 93-04/93101159 1296639 The following pattern is based on the observation that the shape and adhesion of the line are good. Further, the substrate contamination of the unexposed portion of the substrate after development is shown in Table -20. Furthermore, the Y value of the obtained pixel is shown in Table-. &lt;Example 3 0 &gt; Pigment Green 3 6 (acting as a pigment (9 · 4 parts by weight and Synthesis Example 2 Resin solution 2 3. 4 parts (resin solid fraction 9.4 parts) in a homogenizer The mixture was evaporated, and the solvent was evaporated at a temperature of 80 ° C for 1 hour to obtain a kneaded colored resin composition. The obtained colored resin composition was kneaded and kneaded for 5 hours to obtain a colored pigment dispersion. The temperature was controlled to 80 ° C. For the resulting colored pigment dispersion 1 8. Add 4.4 parts of propylene glycol monomethyl ether acetate to allow swelling for 12 hours and stir for 3 hours using a homogenizer. And make a mill (dispersion);! For the mill base thus obtained, 0, 3mm 4 of zirconia beads are treated by a bead mill device according to the retention time of the bell, and a green color is formed: 3⁄4 Under a paint conditioner equipped with zirconia beads, it was subjected to separation for 5 hours to obtain a green ink (colored resin composition). The liquidity of the lipid composition is shown in Table - 0. The obtained green color: under the same method as that described in Example 28, the photosensitivity was obtained. The composition of the resin composition resin is formed into a green form by the same method, and the pattern obtained after the development is obtained according to the observation that the pattern of the shape of the line is good. Further, the substrate after the development is not The substrate was exposed to staining, and the results are shown in Table - 0. Further, the obtained pixel values are shown in Table-21. 312 / Invention specification (supplement) / 93-04/93101159

Figure 3 will be the result of the -21 get premixed machine 8 parts, 3 minutes b ink. Disperse color tree; Y 125 1296639 &lt;Comparative Example 1 6 &gt; In addition to the resin, benzyl methacrylate-methacrylic acid copolymer (weight average molecular weight 1 500) was used. A colored resin composition was obtained in the same manner as in Example 28 except that the acid value was 90. The liquid properties of the obtained colored resin composition are shown in Table - 0. Then, the photosensitive colored resin composition was subjected to physical development in the same manner as in Example 28, and development was carried out, but even at 300 s, the unexposed portion was not melted. The Y value of the obtained pixel is shown in Table - 2 1 &lt;Comparative Example 1 7 &gt; The same as Example 28 except that the commercially available urethane dispersant X sold for the resin was used. This step gives a colored resin composition. The liquid properties of the resulting colored resin composition are shown in Table-2. Then, a green pattern was formed in the same manner as in Example 28. The pattern obtained after the image is obtained is a pattern in which the line shape and the adhesion are good. Further, regarding the substrate fouling of the unexposed portion of the substrate after development, the results are shown in Table-20. Further, the Y value of the obtained pixel is shown in Table-21. Table-2 0

Resin Liquid M Imaging Residue Example 28 Synthesis Example 23 〇〇 Example 29 Synthesis Example 23 〇〇 Example 3 0 Synthesis Example 23 〇〇 Comparative Example 1 6 Benzyl methacrylate methacrylate copolymer (weight average) Molecular weight 1 5000, acid value 90) X - Comparative Example 1 7 Amine phthalate dispersant X 〇X * 1 : Viscosity of colored resin composition 低: low viscosity △ slightly thickened 126 312 / invention manual (supplement ) / 93-04 / 93101159 1296639 X : tackifying table - 2 1 resin Y (x = 0.234, y = 0.472) Example 28 Synthesis Example 2 3 56. 9 Example 29 Synthesis Example 23 58. 0 Example 30 Synthesis Example 23 57. 0 Comparative Example 1 6 benzyl methacrylate methacrylate copolymer (weight average molecular weight 15000, acid value 90) 55. 3 Comparative Example 1 7 urethane dispersant X 56. 1 &lt;Example 3 1 &gt; The pigment blue 1 5 : 6 (acting as a pigment) 9 · 4 parts by weight, the resin solution obtained in Synthesis Example 2 3 3 4 parts (resin solid fraction 9.4 parts), And 4,4 parts of propylene glycol monomethyl ether acetate serving as a solvent is dispersed in a paint conditioner equipped with zirconia beads for 10 hours. To blue ink (colored resin composition). The liquid properties of the obtained colored resin composition are shown in Table-2. Then, a blue ink was formed in the same manner as in Example 28. The pattern obtained after the development is based on the observation that the shape and adhesion of the line are good. Further, regarding the substrate contamination of the unexposed portion of the substrate after development, the results are shown in Table-22. Further, the Y value of the obtained pixel is shown in Table-23. &lt;Comparative Example 1 8 &gt; In addition to the use of a benzyl methacrylate methacrylate copolymer (weight average molecular weight 1 4 0 0 0, A colored resin composition was obtained in the same manner as in Example 28 except for the acid value of 5 2 . The liquid properties of the obtained colored resin composition are shown in Table-2. Then, development was carried out in the same manner as in Example 28, but even at 300 s, the unexposed portion was not melted. The Y values of the obtained pixels are shown in Table-23. 127 312/Invention specification (supplement)/93-04/93101159 1296639 &lt;Comparative Example 1 9 &gt; The same as Example 28 except that the commercially available polymer dispersant Y was used for the resin. The step gives a colored resin composition. The liquid properties of the obtained colored resin composition are shown in Table-2. Then, a blue pattern was formed in the same manner as in Example 28. The pattern obtained after the development was observed as a pattern having a good line shape and adhesion. Further, regarding the substrate fouling of the unexposed portion of the substrate after development, the results are shown in Table-22. Further, the enthalpy values of the obtained pixels are shown in Table-23.

Table-22

Resin liquid μ development residue Example 31 Synthesis Example 23 〇〇Comparative Example 18 Benzyl methacrylate methacrylate copolymer (weight average molecular weight 1 40 00, acid value 52) X - Comparative Example 1 9 Amino acid formic acid Ester-based dispersant Y 〇X * 1 : Viscosity of colored resin composition 〇: low viscosity △ slightly thickened X: thickened

Table - 2 3 Resin Υ (χ = 0. 134, y = 0· 121) Example 31 Synthesis Example 23 15. 1 Comparative Example 18 Mercapto styrene-mercaptoacrylic acid copolymer (weight average molecular weight 1 4000, Acid value 52) 14. 7 Comparative Example 19 Amino phthalic acid ethyl ester dispersing agent Υ 14. 9 Further, in Examples 28 to 31 and Comparative Examples 1 to 1 9 and Examples 1 to 2 7 or In the same manner as in Comparative Examples 1 to 15, the transmittance, the developmental adhesion, the whitening defect, the undissolved matter residue, the viscosity change rate, the resolubility, and the voltage holding ratio were evaluated. The results are shown in Table-14 to Table-19. Based on the above results, the results of Examples 1 to 3 (the 128 312/invention specification (supplement)/93-04/93101159 1296639 colored resin composition of the present invention) and Comparative Examples 1 to 1 were compared. When the results of 9 are compared, it is apparent that the following facts can be known. (1) The colored resin composition according to the present invention is a highly transmissive, high-concentration substance. (2) After the development of the colored resin composition according to the present invention, the amount of undissolved material remaining in the non-pixel portion on the substrate is small. (3) The colored resin composition according to the present invention exhibits excellent image adhesion at the time of development, and is suppressed from whitening defects. (4) The colored resin composition of the present invention is suppressed from being whitened by the application of the die coating method. (5) The viscosity change rate of the colored resin composition of the present invention is low. (6) The colored resin composition of the present invention has little influence on the voltage holding ratio of the liquid crystal. Although the present invention has been described in detail or with reference to the specific embodiments thereof, various changes and modifications may be made without departing from the spirit and scope of the invention. For the sake of the sake. In addition, the present invention is based on a Japanese patent application filed in Japan on July 18, 2002 (Special Wish 2 0 0 2 - 2 1 0 0 6 5), February 7, 2002 Japanese Patent Application (Japanese Patent Application No. 2003-30954), filed on February 24, 2002, filed on Jan. 24, 2002, filed on Jan. 25, 2002, filed on Japanese Patent Application (Japanese Patent Application No. 2000-47) Japan 129 filed in Japan on the 28th

312/Inventive Manual (supplement)/93-04/93101159 1296639 Patent application (Special Wish 2 Ο Ο 3 - 1 2 4 2 9 1 ) and 2 Ο Ο 2 years 1 October 2nd application in 曰本The Japanese patent application (Japanese Patent Application No. 2 0 0 3 - 3 6 6 1 0 0), the entire contents of which is incorporated by reference. &lt;Industrial Applicability&gt; The present invention achieves the following useful effects, and its industrial use value is extremely high. 1. When the colored resin composition of the present invention is applied onto a substrate, undissolved matter does not remain on the non-pixel portion on the substrate, and a high-density color pixel having excellent adhesion to the substrate can be uniformly formed. . Further, when coating according to the die coating method, foreign matter such as dry clots is rarely generated. Further, since the influence on the voltage holding ratio of the liquid crystal is small, it is difficult to cause display defects such as display unevenness and afterimage. 2. In the color filter according to the present invention, the non-pixel portion on the substrate does not remain undissolved in the colored resin composition. Further, since the influence on the voltage holding ratio of the liquid crystal is small, it is difficult to cause display defects such as display unevenness and afterimage, that is, the quality is extremely high. 3. The liquid crystal display device according to the present invention has extremely high quality, because a color filter having an extremely high quality is used, and the non-pixel portion on the substrate does not remain undissolved in the colored resin composition, and The effect of the voltage holding ratio of the liquid crystal is small and it is difficult to cause display unevenness. 130 312/Invention Manual (supplement)/93-04/93101159

Claims (1)

129605 FEB 1 5 2001 Replace this yn lip with a pick-up range 1. A colored resin composition containing a color material, a solvent, a dispersant, and a binder resin, characterized by The binder resin is a resin obtained by copolymerizing (A) 5 to 90 mol% of an epoxy (fluorenyl) acrylate and (B) a copolymerizable component (A) and other radical polymerizable compounds 10 to 9 5 mol 1 % of the copolymerization reaction, adding 10 to 100 mol% of the epoxy group contained in the obtained copolymer to (C) an unsaturated monobasic acid, and 1 for the hydroxyl group produced when the above component (C) is added 0 to 1 0 0 m ο 1 %, addition (D) polybasic acid anhydride; and the dispersant contains at least one of: (E) an urethane dispersant; (F) a graft containing a nitrogen atom a copolymer; and (G) an AB block copolymer and/or a BAB block copolymer composed of a block A having a quaternary ammonium base in a side chain and a block B having no quaternary ammonium salt. 2. The coloring resin composition of claim 1, wherein the (E) urethane dispersing agent is one or two hydroxyl groups in the same molecule of (1) a polyisocyanate compound or (2). The compound and (3) a dispersion resin obtained by reacting a compound having an active hydrogen and a tertiary amino group in the same molecule. 3. The colored resin composition of claim 1, wherein the (F)-containing nitrogen-containing graft copolymer has a repeating unit containing a nitrogen atom in a main chain of the graft copolymer. 4. The colored resin composition of claim 1, wherein (F) a graft copolymer containing a nitrogen atom has a repeating unit represented by the following formula (I) or / and a formula (II) Repeat unit: 131 326\total file\93\93101159\93101159 (replace)·4 1296639 (I) (wherein, R! represents an alkylene group having 1 to 5 carbon atoms, and A represents a hydrogen atom or III) to (V); (wherein (II, 1^ represents an alkylene group having 1 to 5 carbon atoms, A represents a hydrogen atom or any one of the following I) to (V);) (an integer in the formula; (In the formula, an alkyl group of an alkyl group, Yi represents a divalent linking group, W2 represents a carbon number of 2 to 10, Y2 represents a hydrogen atom or -C0-R2 (R2 represents a carbon number of 1 to 10), (1) Indicates an integer from 1 to 20;) 132 326 聪 \\93\93101159\93101159 (replacement)-4 1296639 \/W3 II (7) ο (wherein, w3 represents an alkyl group having 1 to 50 carbon atoms or has 1 to 5 5. A colored resin composition having a carbon atom number of 1 to 50. 5. A colored resin composition according to claim 1, wherein (G) consists of a block A having a quaternary ammonium base in a side chain and The block A of the AB block copolymer and/or the BAB block copolymer composed of the block B having a quaternary ammonium salt contains a partial structure represented by the following formula (1): 3a Y (In the above formula (1), Rla, R2a, and R3a each independently represent a hydrogen atom or a cyclic or chain hydrocarbon group of 1 to 7 carbon atoms which may also be substituted; or, R ia, R Two or more of 2 a and R 3 a may be bonded to each other to form a cyclic structure having a carbon number of 1 to 7; R 4a represents a hydrogen atom or a fluorenyl group, X represents a divalent linking group, and Y_ represents a counter anion). 6. The colored resin composition of claim 1, wherein the component (Β) of the binder resin contains a mono(indenyl) acrylate having a structure represented by the following formula (V I ): R9 R10 R3 r4 (VI) 133 326\general file\93\93101159\93101159 (replacement)-4 1296639 (In the above formula (VI), R3 to R8 each independently represent a hydrogen atom or a carbon number of 1 to The alkyl group of 3, 1?9 and R1() each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; or R 9 and R! 〇 are bonded to form a ring). 7. The colored resin composition of claim 1, wherein the phosphate-type dispersant is further contained as a dispersing agent. 8. The colored resin composition of claim 7, wherein the phosphate type dispersant comprises a partial structure represented by the following formula (3): 9. The colored resin composition of claim 1, wherein the organic carboxylic acid having a molecular weight of 1,000 or less and/or an organic carboxylic anhydride is contained. The colored resin composition of claim 1, wherein the photopolymerizable monomer is contained. The colored resin composition of claim 1, wherein the photopolymerization initiating component is contained. 1 2. A red colored resin composition, which is a colored resin composition of the first application of the patent scope, and the color of the colored resin composition is such that the color of the CIE color system is X = 0.60. After coating for 30 minutes at a temperature of 2300 ° C, the Y value of the color system is within the range of any of the following formulas (1) and (2): Y ^ 2 0 0 Y-41. 4(y &lt; 0. 34) ( 1 ) 100y-7. 4(y ^ 0. 34) (2) (wherein, Y and y each represent the reflectance and color of the CIE color system Degree;) 134 326\total file\93\93101159\93101159 (replacement)-4 1296639 When using this colored resin composition to form a pattern, the minimum pattern width remaining in the line image is 1 0 // m or less; and, using a cloth composed of polyester long fibers dipped in an average of 3 &quot; m of ethanol O.lcc/cm2, a 1 cm X 1 cm surface of the cloth, at a pressure of lkgf/cm2 When the non-pixel portion (on the plain glass) having an area of 10 cm 2 was wiped, the spectral reflectance at 500 nm of the pigment adhering portion was 95% or more. A green colored resin composition is a colored resin composition of the first application of the patent scope, and the colored resin composition is obtained by a film thickness of y = 55. After coating, the Y value of the color system after firing at 230 ° C for 30 minutes is within the range of the following formula: 2 4 0 χ - 7. 1 (wherein, Υ and X each represent CI Ε Reflectance and chromaticity of the color system;) When the colored resin composition is used to form a pattern, the minimum pattern width remaining in the line image is 1 〇 Am or less; and, using the impregnation with ethanol 0.1 a piece of polyester long fiber of cc/cm2 with an average of 3&quot;m below, and a non-pixel portion of 10 cm2 (on plain glass) with a pressure of lkgf/cm2 on a 1 cm X 1 cm surface of the cloth. When the pigment adhesion portion has a spectral reflectance of 450% or more at 450 nm. 1 . A blue colored resin composition which is a colored resin composition of the first application of the patent scope, wherein the colored resin composition has a chromaticity of y = 0.14 by a CIE color system. After coating, the Y value of the color system after firing at 30 ° C for 30 minutes is within the range of the following formula: Y ^ 20x + l 6. 2 (wherein Y and X are different Represents the reflectance and chromaticity of the C IE color system;) 326\total file\93\93101159\93101159 (replacement)-4 135 1296639 When using the colored resin composition to form a pattern, a line image The minimum remaining pattern width is 1 0 // m or less; and, using a piece of polyester long fiber impregnated with an average of 3 cc/cm 2 of ethanol below 0.1 cm/cm 2 , the cloth is 1 cm X On the 1 cm surface, when the non-pixel portion (on the plain glass) having an area of 10 cm 2 was wiped by the pressure of lkgf/cm 2 , the spectral reflectance of the 50 5 nm of the pigment adhesion portion was 95% or more. The colored resin composition according to any one of claims 1 to 4, wherein the viscosity change rate at the temperature of 23 ° C for 7 days is 10% or less with respect to the initial viscosity. . The colored resin composition according to any one of claims 1 to 4, which contains a color material, a solvent, and a binder resin, is impregnated with a dry film formed by the colored resin composition. In the case of dispersing the solvent in the solvent constituting the colored resin composition, the volume average particle diameter mv in the redispersion liquid is 200 nm or less. The colored resin composition according to any one of claims 1 to 4, which is a coloring material, a solvent, and a binder resin, and a coating film formed by the colored resin composition and a liquid crystal. After the annealing treatment is performed in the contact state, the voltage holding ratio when a voltage is applied to the liquid crystal via the colored resin layer is 80% or more. A color filter substrate characterized in that it is formed using the colored resin composition of the first item of the patent application. A liquid crystal display device characterized by being formed by using a color filter substrate of the 18th patent of the patent application. 136 326\total file\93\93101159\93101159 (replace)-4