TWI284746B - High heat resistant reflective coating, and laminated body using the reflective coating - Google Patents

Abstract

The invention provides a high heat resistant reflective coating. The coating is formed of an Ag alloy material having a composition where Ag is contained as a principal component and 0.1-3.0 wt.% of Au, Pd and Ru are added and further 0.1-3.0 wt.% of at least one or more elements among Cu, Ti, Cr, Ta, Ni, Mo and Al are added. Further this coating is composed of a monolayer or multilayer according to purposes. By this method, temperature stability and chemical stability can be provided, and application for various purposes is made possible.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a highly heat-resistant reflective layer for producing a reflector or a reflective wiring electrode of a liquid crystal display device, for building glass, A laminate or a reflective layer of a liquid crystal display device. More specifically, the present invention relates to a silver alloy reflective layer having high reflectance, a laminate formed by the reflective layer, and a liquid crystal display device having the reflective layer or laminated layer. Description of the Prior Art Many materials are used for the reflective layer, including reflectors or reflective wiring electrodes for producing liquid crystal display devices, and reflective layers for architectural glass, reflective infrared rays, and thermal radiation. In addition, laminates of these reflective layers have been developed to increase the reflectance index and to improve the function of these products. These products with improved reflective layers have been used in various fields and in various applications. A typical material of the reflective layer is aluminum, aluminum alloy containing aluminum as a main component, silver, a silver alloy containing silver as a main component (e.g., silver-palladium), and a gold alloy. The reflective layer formed of these materials has a high reflectance at optical wavelengths ranging from 400 to 4000 nm, including visible and infrared regions. Aluminum has high reflectivity and is very inexpensive and practical. Aluminum and aluminum alloys are commonly used for reflectors of reflective liquid crystal display devices and reflective wiring electrodes. Such liquid crystal display devices are used for portable terminal devices, such as 40NDA200104TW; P1P2000284TW 1 ^paper scale is applicable to Chinese national standards (CNS) ) A4 specification (210 X 297 public) (Please read the note on the back to write this page) Write a traitor --------- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1284746 Ministry of Economic Affairs Intellectual Property Bureau staff Consumer Cooperatives Print A7 B7___ V. Invention Description (Work) Mobile Phone. When aluminum alloys are used, problems associated with pure aluminum, such as layer irregularities, referred to as hills, and deterioration of the reflector and reflective wiring electrode surfaces can be overcome. When the reflectance of the reflector and the reflective wiring electrode is high, the power supplied to the light source is lowered, and the brightness of the liquid crystal display device is increased by about 20%. Silver has the highest reflectance in many metal elements in the range of wavelengths of 400 to 4000 nm, and therefore, silver has good characteristics for the reflective layer. Among the visible, infrared, and ultraviolet rays emitted by the sun, aluminum, aluminum alloys, silver, and silver alloys transmit visible light and reflect infrared rays and heat rays. Visible light is directly related to illumination. The reflection of infrared rays and heat rays is useful for preventing outside light from entering the room, and therefore, the above materials are used for architectural glass such as window glass. However, conventionally, a reflective layer formed of aluminum, an aluminum alloy, silver, a silver alloy including silver-palladium, gold, a gold alloy, and a reflector formed of the reflective layer, a reflective wiring electrode, and an architectural glass have The following questions. Aluminum and aluminum alloys are chemically unstable, and a liquid resist composed of an organic material is applied to an aluminum layer or an aluminum alloy layer, and a pattern is formed thereon. When the patterned layer is rinsed with an alkaline solution to remove the resist, the surface of the layer may become rough and may reduce the reflectance or scattering of the surface to light. Further, when a resin substrate such as polymethylmethacrylate (PMMA) and a silicone polymer are used, aluminum may react with a gas generated by the resin substrate. Aluminum can only be used to produce a substrate with very little gas, thus limiting the materials available to the substrate. When the reflective layer containing aluminum is in contact with the resin substrate in use, there will be 40NDA200104TW; P1P2000284TW 2 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). Order -------- (Please read the note on the back ^^ fill this page) 1284746 A7 B7 V. Description of invention (4) The reflectivity of silver or silver alloy in the visible region, that is, 400 to 800 nm The area between the wavelengths of light is the highest. However, in a region where the wavelength of light is lower than 450 nm, the absorption and absorption coefficient of silver increase, and the intensity of yellow reflected light increases, and therefore, a liquid crystal display device formed of a reflective layer containing silver, and a liquid crystal display device The portable terminal device of the device has a poor appearance and turns yellow with time. Furthermore, silver is not good in weather resistance. When placed in the air, silver absorbs moisture (especially water) in the air and turns yellow. As the silver-containing reflective layer is formed on the glass substrate or the resin substrate for a long time, the high reflectance characteristics of silver are impaired. Silver palladium alloy, including silver and 1-3 weight percent palladium, silver gold alloy, including silver and 1-10 weight percent gold, and silver iridium alloy, including silver and 1-10 weight percent 钌 'is known to have a tubular resistance A binary silver alloy that is resistant to corrosion and high heat resistance. However, when the waterproof test is carried out under high temperature and high humidity, even in the alloy layer formed of these silver alloys, black stains are found. Under an optical microscope, it was confirmed that the black stain was a blackened portion, and became prominent after the palladium reached the limit of the solid solution with respect to hydrogen dissolution. When used as architectural glass, the above binary alloy lacks long-term stability in the moisture region or when exposed to condensed water droplets. Silver-gold alloys are known to be stable alloys in which silver and gold are perfectly mixed in a solid state. Silver-gold alloys are not very resistant to halogen elements such as chlorine, which combine with chlorine or iodine in the air introduced during the test to produce black stains. 40NDA200104TW; P1P2000284TW 4 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back* - write this page) Rape--------- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1284746 A7 B7 V. Invention Description (S) In addition to aluminum and silver, the reflectivity of gold is also high. However, gold is very expensive and it is not practical to use a reflector of a liquid crystal display device or a reflective layer of architectural glass. SUMMARY OF THE INVENTION It is an object of the present invention to provide a reflective layer that maintains high optical reflectivity '迨 is a property of gold' and has improved material stability, including heat resistance and weather resistance. Another object of the present invention is to provide a laminate comprising a cover layer such that the laminate maintains a high optical reflectivity of a reflective layer comprising gold and a lower absorbance at low wavelengths. Another object of the present invention is to provide a laminate comprising a base film which enhances adhesion between a reflective layer comprising silver and a substrate. A further object of the present invention is to provide a liquid crystal display device having the above reflective layer or laminated layer. A reflective layer of the present invention comprises silver as a main component; a first element, which is 0.1 to 3.0% by weight, and is selected from the group consisting of gold, palladium and rhodium; and a second element, which constitutes 〇·1 to 3.0 weight percent, and is selected from the group consisting of copper, titanium, chromium, molybdenum, molybdenum, nickel, aluminum, rhodium, gold, palladium, and rhodium; the second element is different from the first element. The first layer comprises a substrate and a reflective layer deposited on the substrate, the reflective layer comprising: silver as a main component; a first element, 0.1 to 3.0% by weight, and selected from the group consisting of gold, palladium and rhodium ; 40NDA200104TW; P1P2000284TW 5 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back to write this page) tr>--------- Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1284746 A7 B7 V. Invention Description (ο ) i) Silver as a main component; ii) A first element, 0.1 to 3.0% by weight, and selected from gold, palladium and rhodium And iii) a second element, 〇1 to 3.0% by weight, and selected from the group consisting of copper, titanium, chromium, giant, molybdenum, nickel, aluminum, lanthanum, gold, palladium, and lanthanum A group in which the second element is different from the first element. Add gold, palladium or rhodium to silver to improve the weatherability of silver under high temperature and high humidity conditions. The main component, silver, has a very high thermal conductivity, absorbs heat easily, and quickly reaches thermal saturation at the atomic level. Gold, palladium and rhodium reduce the thermal conductivity of silver and inhibit the movement between atoms. Gold, palladium and rhodium form the entire solid solution. The content of gold, palladium and rhodium is preferably from 0.7 to 2.3% by weight, most preferably 0.9% by weight. Copper, titanium, chromium, giant, molybdenum, nickel, aluminum, or rhenium, two or more of gold, palladium, and rhodium may be included in the reflective layer to improve the heat resistance and weather resistance of the reflective layer. In the reflective layer of the present invention, the movement of the surface particles is not good compared to the reflective layers of pure aluminum and pure silver. In other words, the self-diffusion energy of silver in the reflective layer of the present invention is lowered upon heating, and therefore, the reflective layer of the present invention resists self-diffusion, which improves the heat resistance of the reflective layer. The reflective layer is heated during the manufacturing process or under a specific climatic condition. In the reflective layer of the present invention, the decrease in reflectance is prevented. In particular, when the reflective layer is heated by more than 100 ° C, the visual change (into the blurred white) due to self-diffusion in the reflective layer, and the increase in light absorption due to surface deformation are prevented. 40NDA200104TW; P1P2000284TW : ^The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) " ' ____________ (please read the back note first)

* V •ϋ ϋ 1 §m§ IB-1 1 J,JI mmMMm —i «1 i^i I Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Clothing 1284746 A7 B7 V. Invention Description (u) As shown in Figure 1 As shown, a portable terminal device 1 includes a liquid crystal display device 2. The liquid crystal display device 2 is formed by a reflector on a glass substrate, a color filter, a polarizing layer, a liquid crystal layer, a polarizing layer, a transparent conductive layer, and an upper glass substrate which are sequentially laminated. The laminate of the present invention, which is a reflector for this purpose, is protected from the alkaline material produced by the color filter manufacturing process. This laminate also has a higher reflectance and a lower optical absorbance than a reflector of pure aluminum or aluminum alloy, and the liquid crystal display device 2 having this laminate suffers less optical loss. The brightness of the liquid crystal display device 2 having the laminate of the present invention is higher than that of the liquid crystal display device having a pure aluminum or aluminum alloy reflector. The portable terminal device 1 having such a liquid crystal display device 2 has an improved display, and therefore, the quality of the product is further improved. EXAMPLES Comparative Example A silver alloy reflective layer was produced from a binary silver alloy, and binary means two elements, that is, silver as a main component, and gold, palladium (Pd) or ruthenium (Ru). The content of gold, palladium or rhodium is from 0.1 to 4.0% by weight. First, a silver target and a palladium target are mounted in a magnetron sputtering apparatus. The discharge to the silver and palladium targets is controlled to a specific radio frequency alternating current. Argon gas is selectively set in the range of 0.1 to 3.0 Pa. These two metallic elements are simultaneously sputtered to form a binary silver alloy layer comprising palladium in several different layers. At the same time, it also produces 40NDA200104TW containing gold or several different classes; P1P2000284TW 11 This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back first ---- ---- Me write this page) --r ϋ ϋ 1 ϋ ϋ 1 I"-, —i ϋ 1 ^1 ^1 - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1284746

V. Description of the invention (\ι) Silver alloy layer. The quartz substrate, having a size of 100 mm x 100 mm x 1. lt, is used as the base substrate. The temperature of the substrate during the sputtering process is room temperature (about 25 ° C). The stupid gas was used as the sole sputtering gas in a high vacuum atmosphere with a final vacuum of 3xl 〇E-6 Pa, and a silver alloy layer was deposited on the quartz substrate such that the layer had a thickness of 20 nm. The reason why the silver alloy layer is deposited under a high vacuum pressure is to prevent the impure gas from staying in the layer to make the layer tight. Therefore, the desired properties of the silver alloy material can be ensured. The resulting silver alloy layer was held on a hot plate for about two hours, and then the layers were observed to check for visual appearance changes (dull white) and when visual changes occurred. The hot plate was raised to 250 ° C at a temperature increase rate of 20 ° C per minute, and the reflectance of the silver alloy layer before and after heating was examined. The results are shown in Table 1. (Please read the notes on the back and write this page)

--τν • ·ϋ ·ϋ ϋ ϋ ϋ ·ϋ 2rJ0 ϋ 1 a— 1 aBBl 1 mmmmm I Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Table 1 Material Composition (wt%) After heating at 250 °C, layer The surface state changes visually before and after heating. The change in reflectance (wavelength 800 nm) Ag The blur white is 100 °C -25 % Ag99.9Pd0.1 on the surface. The blurred white is 100 °C on the surface. -22 % Ag99 .5Pd0.5 Blurred white on the surface 100 ° C -22 % Ag99.0Pdl.0 Blurred white on the surface 120 ° c -21 % Ag98.5Pdl.5 Blurred white on the surface 120 ° C -21 % Ag98.0Pd2.0 blurred white on the surface 130 ° C -20 % Ag97_5Pd2.5 blurred white in the middle part 150 ° C -7.4% (measurement not

40NDA200104TW; P1P2000284TW 12 This paper size is applicable to China National Standard (CNS) A4 specification (210 297 297 mm) 1284746 A7 B7 Description of invention (\3) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed area changed) Ag97.0Pd3. 0 Light white around 150 °C -6.5 % around the middle part (measured unaltered area) Ag96.5Pd3.5 Light white around the middle part l5〇t -6.1 % (measure unaltered area) Ag96.0Pd4. 0 pale white around the middle part 150°C -6.1% (measured unchanged area) Ag99.9AuO. 1 blurred white on the surface 100°C -22 % Ag99.5 AuO.5 blurred white on the surface Ioo°c -22 % Ag99_0Aul .0 Blurred white on the surface _12〇〇C -21 % Ag98.5 Aul .5 Blurred white on the surface ^120 °C -21 % Ag98.0Au2.0 Blurred white On the surface _L3〇°c -21 % Ag97.5Au2.5 Blurred white on the surface 15 (TC -7.0 % (measured unaltered area) Ag97.0Au3.0 Light white around the middle part 15 (TC -6.5 % (measured unchanged area) Ag96.5 Au3.5 pale white around the middle part 150 ° C -6.0 % (measured Unchanged area) Ag96.0Au4_0 Light white around the middle part I50°c -6.0% (measured unaltered area) Ag99.9RuO. 1 Blurred white on the surface 100°C -22 % Ag99.5Ru0. 5 blurred white on the surface 100. -22 % Ag99.0Rul .0 blurred white on the surface I2〇〇c -21 % Ag98.5Rul .5 blurred white on the surface J20 °C -20 % Ag98. 0Ru2.0 blurred white on the surface _l3〇〇c -20% Ag97.5Ru2.5 blurred white on the surface 1503⁄4 -7.4% (measured unchanged area) Ag97.0Ru3.0 pale white in the middle part I50°c -6.5 % around (measured unaltered area) Ag96.5Ru3.5 light white around the middle part 150. -6.1 % (measured unaltered area) Ag96.0Ru4.0 light white in the middle part Around 15 (TC -6.1% (measured unaltered area) As shown in Table 1, in the binary silver alloy layer containing gold, palladium or rhodium, as the layer of pure silver, the change in layer surface vision is not inhibited It can be assumed that these binary layers are not exposed to outdoor temperature or sunlight, without 40NDA200104TW; P1P2000284TW 1 3 The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back first? ^ Write this page) Write a female ^--------- 1284746 A7 B7 V. Description of invention (\10) Method W heat' and is unstable. The reflectance of the heated binary silver alloy layer is improved by only about 2 to 3% compared to the pure silver layer after heating, and therefore, it is impossible to confirm the effect of surface diffusion resistance by adding gold, palladium, and rhodium. Example 1 The silver alloy reflective layer of the present invention is produced from a bismuth silver alloy, the ternary representing two elements, that is, silver as a main component; and a first element selected from the group consisting of a gold and a crucible; A second element selected from the group consisting of copper, titanium, tantalum, niobium, molybdenum, nickel, aluminum, lanthanum, gold, palladium, and lanthanum, wherein the second element is different from the first element. The content of the first element and the second element is from 〇·ΐ to 3·ο% by weight. First, a silver target and a target of the first element and the second element are mounted in a magnetron sputtering apparatus. These three metal elements are simultaneously sputtered to form a silver alloy layer. As in the comparative example, a quartz substrate having a size of 100 mm x 100 mm x. It was used as a substrate, and the temperature of the substrate during sputtering was maintained at room temperature (about 25 ° C). Argon gas was used as the sole sputtering gas in a vacuum atmosphere with a final vacuum of 3 x 10E_6 Pa, and a silver alloy layer was deposited on the quartz substrate such that the thickness of the layer was 200 nm. The resulting silver alloy layer was held on a hot plate for about two hours, and then the layers were observed to check for visual appearance changes (dull white) and when visual changes occurred. The hot plate was raised to 250 ° C at a temperature increase rate of 20 ° C per minute, and the reflectance of the silver alloy layer before and after heating was examined. The results are shown in Table 2. 40NDA200104TW; P1P2000284TW 14 ------------ (Please read the notes on the back 11^ to write this page) • ϋ 1 1 0 n H ϋ ϋ ϋ 1 · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Printed paper scale applies to China National Standard (CNS) A4 specification (21〇x 297 public 1' 1284746 A7 _B7 V. Invention description (\5) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Table 2 Material Composition ( Wt%) The change in reflectance of the surface state of the layer after heating at 250 °C (wavelength 800 nm) Ag99.8Pd0.1Cu0.1 No change observed - -1.1 % Ag98.4PdO.lCul .5 No change observed - -1.0 % Ag96.9Pd0.1Cu3.0 No change observed - -1.0 % Ag98.4Pdl.5CuO" No change observed - -0.9 % Ag97.0Pdl.5Cul.5 No change observed — -0.7 % Ag95.5Pdl.5Cu3.0 No change observed - -0.7 % Ag96.9Pd3.0Cu (Kl No change observed - -1.0 % Ag95.5Pd3.0Cul.5 No change observed - -0.5 % Ag94 .0Pd3.0Cu3.0 No change observed - -0.4 % Ag99.8Pd0.1Ti0.1 No change observed - -1.1 % Ag98.4PdO.lTil.5 Not No change was observed - -1.0 % Ag96.9Pd0.1Ti3.0 No change observed - -1.0 % Ag98.4Pdl.5Ti0.1 No change observed - -0.9 % Ag97.0Pdl.5Til.5 No change observed - 0.7 % Ag95.5Pdl.5Ti3.0 No change observed - -0.7 % Ag96.9Pd3.0Ti0" No change observed - -1.0 % Ag95.5Pd3.0Til.5 No change observed - -0.5 % Ag94.0Pd3. 0Ti3.0 No change observed - -0.4 % Ag99.8Pd0.1Ti0.1 No change observed - -1.1 % Ag98.4PdO.lCrl.5 No change observed - -1.0 % Ag96.9Pd0.1Cr3.0 Not observed To change - -1.0 % Ag98.4Pdl.5Cr0.1 No change observed - -0.9 % Ag97.0Pdl.5Crl.5 No change observed - -0.7 % Ag95.5Pdl.5Cr3.0 No change observed - -0.7 % Ag96.9Pd3.0Cr0" No change observed - -1.0 % Ag95.5Pd3.0Crl.5 No change observed - -0.5 % Ag94.0Pd3.0Cr3.0 No change observed - -0.4 % Ag99.8Pd0.1Cr0 .1 No change observed - -1.1 % Ag98.4PdO.lTal.5 No change observed - -1.0 % Ag96.9Pd0.1Ta3.0 No change observed - -1.0 % Ag98.6Pdl.5Ta0.1 Not observed Change - -0.9 % Ag97.0Pdl.5T Al.5 No change observed - -0.7 % Ag95.5Pdl.5Ta3.0 No change observed - -0.7 % 40NDA200104TW; P1P2000284TW 15 I ΜΜ Ι··Ι Ml· _ I MB Η·· II Η··· ΜΗ · (Please read the note on the back to write this page) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 _B7 V. Description of the invention (\U) Table 2 (continued) Economy Ministry of Intellectual Property Bureau employee consumption cooperative printed material composition (wt%) After heating at 250 °C, the surface state of the layer changes visually. The change of reflectivity before and after heating (wavelength 800 nm) Ag98.4Pd0.1Ni0.1 No change was observed - -1.1 % Ag98.4PdO.lNil.5 No change observed - -1.0 % Ag96.9Pd0.1 Ni3.0 No change observed - -1.0 % Ag98.4Pdl.5 NiO.l Not observed Change - -0.9 % Ag97.0Pdl.5 Nil.5 No change observed - -0.7 % Ag95.5Pdl.5 Ni3.0 No change observed - -0.7 % Ag96.9Pd3.0Ni 0.1 No change observed - -1.0 % Ag95.5Pd3.0 Nil.5 No change observed - -0.5 % Ag94.0Pd3.0Ni 3.0 No change observed - -0.4 % Ag99.8Pd0.1A10 .1 No change observed - -1.1 % Ag98.4Pd0.1 All.5 No change observed - -1.0 % Ag96.9Pd0.1 A13.0 No change observed - -1.0 % Ag98.4Pdl.5 A10.1 No change observed - -0.9 % Ag97.0Pdl.5 All.5 No change observed - -0.7 % Ag95.5Pdl.5 A13.0 No change observed - -0.7 % Ag96.9Pd3.0 A10.1 Not observed To change - -1.0 % Ag95.5Pd3.0 All.5 No change observed - -0.5 % Ag94.0Pd3.0 A13.0 No change observed - -0.4 % Ag99.8Pd0.1 NbO.l No change observed — -1.1 % Ag98.4Pd0.1 Nbl.5 No change observed - -1.0 % Ag96.9Pd0.1 Nb3.0 No change observed - -1.0 % Ag98.4Pdl.5 NbO.l No change observed - 0.9 % Ag97.0Pdl.5 Nbl.5 No change observed - -0.7 % Ag95.5Pdl.5 Nb3.0 No change observed - -0.7 % Ag96.9Pd3.0 NbO.l No change observed - -1.0 % Ag95.5Pd3.0 Nbl.5 No change observed - -0.5 % Ag94.0Pd3.0 Nb3.0 No change observed - -0.4 % 40NDA200104TW; P1P2000284TW 16 (Please read the note on the back to write this page) ^- --------

No change was observed in Ag96.9Pd3.0Ta0.1 - -1.0 % Ag95.5Pd3.OTal.5 No change observed - -0.5 % Ag94.0Pd3.0Ta3.0 No change observed - -0.4 % This paper size applies to China National Standard (CNS) A4 Specification (210 X 297 mm) 1284746 A7 B7 V. Description of Invention (VI) Table 2 (Continued) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed Materials Composition (wt%) at 250 ° C After heating, the surface state of the layer changes visually. The change in reflectance before and after heating (wavelength 800 nm) Ag99.8PdO.lMoO" No change observed - -1.1 % Ag98.4PdO.lMol.5 No change observed - No change was observed in 1.0% Ag96.9Pd0.1Mo3.0 - -1.0 % Ag98.4Pdl.5Mo0.1 No change observed - -0.9 % Ag97.0Pdl.5Mol.5 No change observed - -0.7 % Ag95.5Pdl .5Mo3.0 No change observed - -0.7 % Ag96.9Pd3.0Mo0" No change observed - -1.0 % Ag95.5Pd3.0Mol.5 No change observed - -0.5 % Ag94.0Pd3.0Mo3.0 Not observed To change - -0.4 % Ag99.8Pd0.1Au0.1 No change observed - -1.1 % Ag98.4Pd0.1 Aul.5 No change observed - -1.0 % No change was observed for Ag96.9Pd0.1 Au3.0 - -1.0 % Ag98.4Pdl.5 AuO.l No change observed - -0.9 % Ag97.0Pdl.5 Aul.5 No change observed - -0.7 % Ag95. No change was observed in 5Pdl.5 Au3.0 - -0.7 % Ag96.9Pd3.0 AuO.l No change observed - -1.0 % Ag95.5Pd3.0 Aul.5 No change observed - -0.5 % Ag94.0Pd3. 0 Au3.0 No change observed - -0.4 % Ag99.8Au0.1Ru0.1 No change observed - -1.0 % Ag98.4AuO. IRul .5 No change observed - -0.8 % Ag96.9Au0.1Ru3.0 Not Change observed - -0.5 % Ag98.4Aul.5Ru0.1 No change observed - -1.0 % Ag97.0Aul.5Rul.5 No change observed - -0.3 % Ag95.5Aul.5Ru3.0 No change observed - No change was observed in 0.6 % Ag96.9Au3.0Ru0.1 - -0.8 % Ag95.5Au3.0Rul .5 No change observed - -0.5 % Ag94.0Au3.0Ru3.0 No change observed - -0.8 % Ag99.8Au0 .1Ru0.1 No change observed - -1.0 % Ag98.4Pd0.1 Rul.5 No change observed - -0.9 % Ag96.9Pd0.1 Ru3.0 No change observed - -1.0 % Ag98.6Pdl.5 RuO .l No change observed - -0.9 % Ag97.0Pdl.5 Rul.5 Not observed To change - -0.8 % Ag95.5Pdl.5 Ru3.0 No change observed - -0.7 %

40NDA200104TW; P1P2000284TW 17 Please read the note on the back first.

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I Order > II •4 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Invention Description (\Name) Table 2 (Continued) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed

AgAuXb material composition (wt%) After heating at 250 °C, the surface state of the layer changes visually. The change of reflectance before and after heating (wavelength 800 nm) Ag99.8Au0.1Cu0.1 No change observed - -0.9 % Ag98.4AuO.lCul.5 No change observed - -0.8 % Ag96.9Au0.1Cu3.0 No change observed - -0.8 % Ag98.4Aul.5Cu0.1 No change observed - -0.7 % Ag97.0Aul.5Cul .5 No change observed - -0.6 % Ag95.5Aul.5Cu3.0 No change observed - -0.5 % Ag96.9Au3.0Cu0" No change observed - -0.8 % Ag95.5Au3.0Cul .5 No change observed — -0.5 % Ag94.0Au3.0Cu3.0 No change observed - -0.6 % Ag99.8Au0.1Ti0.1 No change observed - -0.9 % Ag98.4Au0.1Ti 1.5 No change observed - -0.6 % Ag96. No change was observed for 9Au0.1Ti 3.0 - -0.3 % Ag98.4Aul.5Ti 0.1 No change observed - -0.5 % Ag97.0Aul.5Ti 1.5 No change observed - -0.8 % Ag95.5Aul.5Ti 3.0 No change observed No change was observed for -0.6% Ag96.9Au3.0Ti 0.1. - -0.9 % Ag95.5Au3.0Ti 1.5 No change observed - -1.1 % Ag94.0Au3.0Ti 3.0 No change was observed - 1.0% Ag99.8Au0.1Cr0.1 No change observed - -0.8 % Ag98.4Au0.1Cr 1.5 No change observed - -1.0 % Ag96.9Au0.1Cr 3.0 No change observed - -0.6 % Ag98.4Aul.5Cr 0.1 No change observed - -0.9 % Ag97.0Aul.5Cr 1.5 No change observed - -0.4 % Ag95.5Aul.5Cr 3.0 No change observed - -1.1 % Ag96.9Au3.0Cr 0.1 Not observed To change - -0.8 % 40NDA200104TW: P1P2000284TW 18 (Please read the note on the back first to write this page) Write female ^---------

Ag96.9Pd3.0 RuO.l No change observed - -1.0 % Ag95.5Pd3.0 Rul.5 No change observed - -0.6 % Ag94.0Pd3.0 Ru3.0 No change observed - -0.4 % Paper The scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Description of invention (13⁄4)

No change was observed for Ag95.5Au3.0Cr 1.5 - -0.9 % Ag94.0Au3.0Cr 3.0 No change observed - -0.7 % Ag99.8Au0.1Ti0.1 No change observed - -0.5% Ag98.4AuO.lTi 1.5 Not No change was observed - -0.6 % Ag96.9AuO.lTi 3.0 No change observed - 1.1 % Ag98.6Aul.5Ti 0.1 No change observed - -0.4 % Ag97.0Aul.5Ti 1.5 No change observed - -0.9 % Ag95. 5Aul.5Ti 3.0 No change observed - -0.8 % Ag96.9Au3.0Ti 0.1 No change observed - -0.5 % Ag95.5Au3.0Ti 1.5 No change observed - -1.0 % Ag94.0Au3.0Ti 3.0 No change observed — -0.6 % Table 2 (continued) (Please read the notes on the back to write this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed Materials Composition (wt%) After heating at 250 °C, the surface state of the layer occurs Change in reflectivity before and after heating (wavelength 800 nm) Ag99.8Au0.1Mo0.1 No change observed - -0.7 % Ag98.4AuO.lMol.5 No change observed - -1.1 % Ag96.9AuO. 1M 〇3.0 No change observed - -0.8 % Ag98.4Aul.5Mo0.1 No change observed - -0.4 % Ag97.0Aul .5Mo l .5 No change observed - -0.8 % No change observed in Ag95.5Aul.5Mo3.0 - -0.3 % Ag96.9Au3.0Mo0.1 No change observed - -0.9 % Ag95.5Au3.0Mol .5 Not observed To change - -1.1 % Ag94.0Au3.0Mo3.0 No change observed - -1.0 % Ag99.8Au0.1Na0.1 No change observed - -0.5 % Ag98.4AuO.lNal.5 No change observed - -1.1 No change was observed in % Ag96.9Au0.1Na3.0 - -0.8 % Ag98.4Aul.5Na0.1 No change observed - -0.4 % Ag97.0Aul.5Nal.5 No change observed - -1.0% Ag95.5Aul. No change was observed in 5Na3.0 - -0.7 % Ag96.9Au3.0Na0.1 No change observed - -0.9 % Ag95.5Au3.0Nal.5 No change observed - -0.6% Ag94.0Au3.0Na3.0 Not observed To change - -0.8 % Ag99.8AuO. 1A10.1 No change observed - -1.09 % 40NDA200104TW; P1P2000284TW 19 This paper size applies to China National Standard (CNS) A4 specification (210 297 297 mm) t----- ---- 1284746 A7 B7 V. Invention Description (>〇)

No change was observed in Ag98.4AuO.lAl 1.5 - -1.1 % Ag96.9AuO.lAl 3.0 No change observed - -0.7 % Ag98.4Aul.5Al 0.1 No change observed - -0.9 % Ag97.0Aul.5Al 1.5 Not observed To change - -0.5 % Ag95.5Aul.5Al 3.0 No change observed - -0.4 % Ag96.9Au3.0Al 0.1 No change observed - -0.8 % Ag95.5Au3.0Al 1.5 No change observed - -1.0 % Ag94. 0Au3.0Al 3.0 No change observed - -1.1 % Ag99.8Au0.1Nb0.1 No change observed - -1.1% Ag98.4AuO.lNbl.5 No change observed - -1.0 % Ag96.9Au0.1Nb3.0 Not Change observed - -0.9 % Ag98.6Aul.5Nb0.1 No change observed - -0.8 % Ag97.0Aul.5Nbl.5 No change observed - -0.7 % Ag95.5Aul.5Nb3.0 No change observed - No change was observed in 0.8 % Ag96.9Au3.0Nb0.1 - -1.0 % Ag95.5Au3.0Nbl.5 No change observed - -0.4 % Ag94.0Au3.0Nb3.0 No change observed - -0.4 % Table 2 ( Continued) Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative

AgRuX material composition (wt%) After heating at 250 °C, the surface state of the layer changes visually. The change of reflectance before and after heating (wavelength 800 nm) Ag99.8Ru0.1Cu0.1 No change observed - -0.9 % No change was observed in Ag98.4RuO.lCul.5 - -0.8% Ag96.9Ru0.1Cu3.0 No change observed - -0.7 % Ag98.4Rul.5Cu0.1 No change observed - -0.7 % Ag97.0Rul.5Cul .5 No change observed - -0.6 % Ag95.5Rul .5Cu3.0 No change observed - -0.5 % Ag96.9Ru3.0Cu0.1 No change observed - -0.7 % Ag95.5Ru3.0Cul.5 Not observed Change - -0.5 % Ag94.0Ru3.0Cu3.0 No change observed - -0.6 % Ag99.8Ru0.1Ti0.1 No change observed - -0.9 % Ag98.4Ru0.1 Ti 1.5 No change observed - -0.6% 40NDA200104TW; P1P2000284TW 20 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -ϋ I ϋ II ·ϋ One: °J ϋ 1_1 1 n ϋ ϋ I (Please read the notes on the back first. This page) 1284746 A7 B7 V. Invention Description (>υ

No change was observed for Ag96.9Ru0.1 Ti 3.0 - -0.4% Ag98.4Rul.5 Ti 0.1 No change observed - -0.5 % Ag97.0Rul.5 Ti 1.5 No change observed - -0.8% Ag95.5Rul.5 No change was observed in Ti 3.0 - -0.5 % Ag96.9Ru3.0 Ti 0.1 No change observed - -0.9 % Ag95.5Ru3.0 Ti 1.5 No change observed - -1.1% Ag94.0Ru3.0 Ti 3.0 Not observed Change - -1.0 % Ag99.8Ru O.lCrO.l No change observed - -0.8 % Ag98.4 Ru0.1Crl.5 No change observed - -1.0 % Ag96.9 Ru0.1Cr3.0 No change observed - -0.6 % Ag98.4 Rul.5Cr0.1 No change observed - -0.8 % Ag97.0 Rul.5Crl.5 No change observed - -0.4 % Ag95.5 Rul.5Cr3.0 No change observed - -1.0 % Ag96.9 Ru3.0Cr0.1 No change observed - -0.8 % Ag95.5 Ru3.0Crl.5 No change observed - -0.9 % Ag94.0 Ru3.0Cr3.0 No change observed - -0.8 % Ag99 .8Ru0.1Ta0.1 No change observed - -0.9 % Ag98.4Ru0.1Ta 1.5 No change observed - -0.8 % Ag96.9Ru0.1Ta 3.0 No change observed - -0.7 % Ag98.6Rul.5Ta 0.1 Not observed To change - -0.7 % Ag97.0Rul.5Ta 1.5 No change observed - -0.6 % Ag95.5Rul.5Ta 3.0 No change observed - -0.5 % Ag96.9Ru3.0Ta 0.1 No change observed - -0.7 % Ag95.5Ru3.0Ta 1.5 No change observed - -0.6 % Ag94.0Ru3.0Ta 3.0 No change observed - -0.6 % (Please read the note on the back to write this page) Writer · 11111111 Φ4. Table 2 (continued) Material composition (wt%) After heating at 250 ° C The surface state of the layer undergoes a visual change. The change in reflectance before and after heating (wavelength 800 nm) Ag99.8Ru0.1Mo0.1 No change observed - -0.8 % Ag98.4RuO.lMol.5 No change observed - -1.0 % Ag96.9Ru0.1Mo3.0 No change observed - -0.6 % Ag98.4Rul ·5Μ〇0· 1 No change was observed -0.7% Ag97.0Rul.5Mol.5 No change observed - -0.4 % Ministry of Economy Intellectual Property Bureau employee consumption cooperative printed 40NDA200104TW; P1P2000284TW 21 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Invention description (》)

No change was observed in Ag95.5Rul.5Mo3.0 - -1.1 % Ag96.9Ru3.0Mo0.1 No change observed - -0.8 % Ag95.5Ru3.OMol.5 No change observed - -0.7 % Ag94.0Ru3.0Mo3 .0 No change observed - -0.6 % Ag99.8Ru0.1Ni0.1 No change observed - -1.0 % Ag98.4RuO.lNi 1.5 No change observed - -1.1 % Ag96.9RuO.lNi 3.0 No change observed - -0.8 % Ag98.4Rul.5Ni 0.1 No change observed - -0.8 % Ag97.0Rul.5Ni 1.5 No change observed - -0.5 % Ag95.5Rul.5Ni 3.0 No change observed - -0.5 % Ag96.9Ru3.0Ni 0.1 No change observed - -0.7 % Ag95.5Ru3.0Ni 1.5 No change observed - -1.0 % Ag94.0Ru3.0Ni 3.0 No change observed - -1.1 % Ag99.8Ru 0.1A10.1 No change observed - 1.0 % Ag98.4 Ru0.1A11.5 No change observed - -1.1 % Ag96.9 Ru0.1A13.0 No change observed - -0.7 % Ag98.4 Rul.5A10.1 No change observed - -0.9 % No change was observed for Ag97.0 Rul.5A11.5 - -0.5 % Ag95.5 Rul.5A13.0 No change observed - -0.5 % Ag96.9 Ru3.0A10.1 No change observed - -0.8 % Ag95. 5 Ru3.0A11.5 not seen To change - -1.0 % Ag94.0 Ru3.0A13.0 No change observed - -1.1 % Ag99.8Ru0.1Nb0.1 No change observed - -1.1 % Ag98.4RuO.lNbl.5 No change observed - No change was observed in 1.0 % Ag96.9Ru0.1Nb3.0 - -0.8 % Ag98.6Rul.5Nb0.1 No change observed - -0.8 % Ag97.0Rul.5Nbl.5 No change observed - -0.7 % Ag95.5Rul .5Nb3.0 No change observed - -0.7 % Ag96.9Ru3.0Nb0.1 No change observed - -1.0 % Ag95.5Ru3.0Nbl.5 No change observed - -0.5 % Ag94.0Ru3.0Nb3.0 Not Observed changes - -0.4% (please read the notes on the back to write this page) -------- ·#· Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing Although silver alloy layer was observed in the comparative example The change in surface and the accompanying decrease in reflectance were not observed in any of the compositions examined in the silver alloy layer of Example 1, as shown in Table 2. 40NDA200104TW; P1P2000284TW 22 The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing clothing A7 B7 V. Invention description (Work 3) Again, 'quartz base , depositing various silver alloy layers thereon and heating to 250 C ' was placed on a hot plate at 400 ° C for two hours, no surface change was observed in the silver alloy layer of any of the examined compositions. And a decrease in reflectance (data not shown). Producing a silver alloy reflective layer comprising silver and 0.1-3.0 weight percent copper, titanium, chromium, molybdenum, molybdenum, nickel, aluminum or niobium but not containing gold, palladium or rhodium, as described, the silver alloy is simultaneously splashed It was plated and deposited on a quartz substrate so that the thickness of the layer was 15 nm. When observed at 250 ° C and 400 ° C, the layers were whitened with a change in visual characteristics over time, and the reflectance was lowered (data not shown). Taken together, the silver alloy layer containing silver as a main component, a first element, and a second element has more improved heat resistance and maintains high reflectance. Embodiment 2 In this embodiment, the effect of the ternary silver alloy layer as a reflector of a reflective liquid crystal display device and a reflective wiring electrode is investigated.

The anti-corrosion test for chemical stability was performed, and the conventional metal layer (pure aluminum, aluminum alloy, silver, binary silver alloy) and the ternary silver alloy layer of the present invention were compared. A liquid resist was applied to the reflective layer and patterned thereon, and then the reflective layer was rinsed with an alkaline solution (5% potassium hydroxide aqueous solution) to remove the uranium-resistant agent. The surface of the layer was observed and the results are shown in Table 3. 40NDA200104TW; P1P2000284TW This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back _ fill out this page) Write too · 11111111 1284746 Α7 Β 7 V. Invention description (Table 3 Economy Ministry of Intellectual Property Bureau employees consumption cooperatives printed materials composition (Wt%) alkaline solution A1 complete reaction A196.0 Mg 4.0 complete reaction covered with acrylic resin aluminum partial reaction Ag98.0Pd2.0 many black stains Ag97.0Pd3.0 Moderate black stain Ag99.8 Pd 0.1 Cu 0.1 No change Ag99.4 Pd 0.5 Cu 0.1 No change Ag98.1 Pd 0.9 Cu 1.0 No change Ag98.9 Pd 1.0 Cu 0.1 No change Ag97.9 Pd 2.0 Cu 0.1 No change Ag96 .9 Pd 3.0 Cu 0.1 No change Ag96.5 Pd 3.0 Cu0.5 No change Ag94.0 Pd 3.0 Cu 3.0 No change Ag99.8 Pd 0.1 Ti 0.1 No change Ag99.4 Pd 0.5 Ti 0.1 No change Ag98.1 Pd 0.9 Ti 1.0 does not change Ag98.9 Pd 1.0 Ti 0.1 does not change Ag97.9 Pd 2.0 Ti 0.1 does not change Ag96.9 Pd 3.0 Ti 0.1 does not change Ag96.5 Pd 3.0 Ti 0.5 does not change Ag94.0 Pd 3.0 Ti 3.0 does not change Ag99 .8 Pd 0.1 Cr 0.1 No change Ag99.4 Pd 0.5 Cr 0.1 No change Ag98.1 Pd 0.9 Cr 1. 0 No change Ag98.9 Pd 1.0 Cr 0.1 No change Ag97.9 Pd 2.0 Cr 0.1 No change Ag96.9 Pd 3.0 Cr 0.1 No change Ag96.5 Pd 3.0 Cr0.5 No change Ag94.0 Pd 3.0 Cr 3.0 No change Ag99 .8 Pd 0.1 Ta 0.1 No change Ag98.4 Pd 0.1 Ta 1.5 No change Ag96.9 Pd 0.1 Ta 3.0 No change Ag98.4 Pd 1.5 Ta 0.1 No change Ag97.0 Pd 1.5 Ta 1.5 No change Ag95.5 Pd 1.5 Ta 3.0 No change Ag96.9 Pd 3.0 Ta 0.1 No change Ag95.5 Pd 3.0 Ta 1.5 No change Ag94.0 Pd 3.0 Ta 3.0 No change 40NDA200104TW; P1P2000284TW 24 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 () Please read the notes on the back to write this page. Write female 111111. 1284746 A7 B7 V. Invention description us) Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative

Ag99.8 Pd 0.1 Mo 0.1 No change Ag98.4 Pd 0.1 Mo 1.5 No change Ag96.9 Pd 0.1 Mo 3.0 No change Ag98.4 Pd 1.5 Mo 0.1 No change Ag97.0 Pd 1.5 Mo 1.5 No change Ag95.5 Pd 1.5 Mo 3.0 did not change Ag96.9 Pd 3.0 Mo 0.1 did not change Ag95.5 Pd 3.0 Mo 1.5 did not change Ag94.0 Pd 3.0 Mo 3.0 did not change Ag99.8 Pd 0.1 Ni 0.1 did not change Ag98.4 Pd 0.1 Ni 1.5 did not change Ag96 .9 Pd 0.1 Ni 3.0 No change Ag98.4 Pd 1.5 Ni 0.1 No change Ag97.0 Pd 1.5 Ni 1.5 No change Ag95.5 Pd 1.5 Ni 3.0 No change Ag96.9 Pd 3.0 Ni 0.1 No change Ag95.5 Pd 3.0 Ni 1.5 No change Ag94.0 Pd 3.0 Ni 3.0 No change Ag99.8 Pd 0.1 A1 0.1 No change Ag98.4 Pd 0.1 A1 1.5 No change Ag96.9 Pd 0.1 A1 3.0 No change Ag98.4 Pd 1.5 A1 0.1 No change Ag97. 0 Pd 1.5 A1 1.5 No change Ag95.5 Pd 1.5 A1 3.0 No change Ag96.9 Pd 3.0 A1 0.1 No change Ag95.5 Pd 3.0 A1 1.5 No change Ag94.0 Pd 3.0 A1 3.0 No change Ag99.8 Pd 0.1 NbO. l No change Ag98.4 Pd 0.1 Nb 1.5 No change Ag96.9 Pd 0.1 Nb 3.0 No change Ag98.4 Pd 1.5 Nb 0.1 No change Ag97.0 Pd 1.5 Nb 1.5 No change Ag95.5 Pd 1.5 Nb 3.0 No change to Ag96. 9 Pd 3.0 Nb 0.1 No change Ag95.5 Pd 3.0 N b 1.5 No change Ag94.0 Pd 3.0 Nb 3.0 No change Ag99.8 Pd 0.1 AuO.l No change Ag98.4 Pd 0.1 Au 1.5 No change Ag96.9 Pd 0.1 Au 3.0 No change Ag98.4 Pd 1.5 Au 0.1 No change Ag97.0 Pd 1.5 Au 1.5 has not changed 40NDA200104TW; P1P2000284TW 25 This paper size is applicable to China National Standard (CNS) A4 specification (210 297 297 mm) (Please read the note on the back first to write this page)

,· Γ -I 1 _1 ϋ ϋ ·ϋ ϋ ϋ -ϋ ϋ I 1284746 A7 B7 V. Invention Description (Ire) Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative

Ag95.5 Pd 1.5 Au 3.0 No change Ag96.9 Pd 3.0 Au 0.1 No change Ag95.5 Pd 3.0 Au 1.5 No change Ag94.0 Pd 3.0 Au 3.0 No change Ag99.8 Pd 0.1 AuO.l No change Ag98.4 Pd 0.1 Au 1.5 No change Ag96.9 Pd 0.1 Au 3.0 No change Ag98.4 Pd 1.5 Au 0.1 No change Ag97.0 Pd 1.5 Au 1.5 No change Ag95.5 Pd 1.5 Au 3.0 No change Ag96.9 Pd 3.0 Au 0.1 No change Ag95.5 Pd 3.0 Au 1.5 No change Ag94.0 Pd 3.0 Au 3.0 No change Ag99.8 Pd 0.1 RuO.l No change Ag98.4 Pd 0.1 Ru 1.5 No change Ag96.9 Pd 0.1 Ru 3.0 No change Ag98.4 Pd 1.5 Ru 0.1 did not change Ag97.0 Pd 1.5 Ru 1.5 did not change Ag95.5 Pd 1.5 Ru 3.0 did not change Ag96.9 Pd 3.0 Ru 0.1 did not change Ag95.5 Pd 3.0 Ru 1.5 did not change Ag94.0 Pd 3.0 Ru 3.0 did not change

AgAuX Table 3 (continued) Material composition (wt%) Alkaline solution Ag98.0Au2.0 Many black stains Ag97.0Au3.0 Moderate black stain Ag99.8AuO. 1 CuO. 1 No change Ag99.4Au0.5Cu0.1 No change Ag98.1Au0.9Cul.0 No change Ag98.9Aul.0Cu0.1 No change Ag97.9Au2.0Cu0" No change Ag96.9Au3 .OCuO. 1 No change Ag96.5Au3.0Cu0.5 No change Ag94.0Au3. 0Cu3.0 does not change Ag99.8Au0.1Ti0.1 does not change Ag99.4Au0.5Ti0.1 does not change Ag98.1Au0.9Til.0 does not change 40NDA200104TW; P1P2000284TW 26 (please read the back note before writing this page) This paper The scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Invention Description (Jl/]) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing

Ag98.9Aul.0Ti0.1 does not change Ag97.9Au2.0Ti0.1 does not change Ag96.9Au3.0Ti0.1 does not change Ag96.5Au3.0Ti0.5 does not change Ag94.0Au3.0Ti3.0 does not change Ag99.8Au0.1Cr0 .1 did not change Ag98.4AuO.lCrl.5 did not change Ag96.9Au0.1Cr3.0 did not change Ag98.4Aul.5Cr0.1 did not change Ag97.0Aul.5Crl.5 did not change Ag95.5Aul .5Cr3.0 did not change Ag96 .9Au3.0Cr0.1 has not changed Ag95.5Au3.0Crl .5 has not changed Ag94.0Au3.0Cr3.0 has not changed Ag98.4AuO.lTal.5 has not changed Ag96.9Au0.1Ta3.0 has not changed Ag98.4Aul.5Ta0. 1 No change Ag97.0Aul .5Tal .5 No change Ag95.5Aul.5Ta3.0 No change Ag96.9Au3.0Ta0.1 No change Ag95.5Au3.0Tal.5 No change Ag94.0Au3.0Ta3.0 No change Ag99. 8Au0.1Mo0.1 did not change Ag98.4AuO. IMol .5 did not change Ag96.9Au0.1Mo3.0 did not change Ag98.4Aul.5Mo0.1 did not change Ag97.0Aul.5Mol.5 did not change Ag95.5Aul.5Mo3.0 Ag96.9Au3.0Mo0.1 has not changed Ag95.5Au3.0Mol .5 has not changed Ag94.0Au3.0Mo3.0 has not changed Ag99.8Au0.1Ni0.1 has not changed Ag98.4AuO.lNil.5 has not changed Ag96.9Au0 .1Ni3.0 did not change Ag98.4Aul.5NiO. 1 did not change Ag97.0Aul.5Nil.5 did not change Ag95.5Aul.5Ni3.0 did not change Ag96.9Au3.0Ni0.1 did not change Ag95.5Au3.0Nil.5 No Change Ag94.0Au3.0Ni3.0 No change Ag99.8Au0.1A10.1 No change 40NDA200104TW; P1P2000284TW 27 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back to write this page) Writer trA- -------- 1284746 A7 B7 V. Description of the invention (Work 8)

Ag98.4AuO.lAll.5 has not changed Ag96.9Au0.1A13.0 has not changed Ag98.4Aul.5A10.1 has not changed Ag97.0Aul.5All.5 has not changed Ag95.5Aul.5A13.0 has not changed Ag96.9Au3.0A10 .1 has not changed Ag95.5Au3.0All.5 has not changed Ag94.0Au3.0A13.0 has not changed Ag99.8Au0.1Nb0.1 has not changed Ag98.4AuO.lNbl.5 has not changed Ag96.9Au0.1Nb3.0 has not changed Ag98 .4Aul.5Nb0.1 No change Ag97.0Aul.5Nbl.5 No change Ag95.5Aul.5Nb3.0 No change Ag96.9Au3.0Nb0.1 No change Ag95.5Au3.0Nbl.5 No change Ag94.0Au3.0Nb3. 0 No change (please read the note on the back first to write this page) Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs

AgRuX Table 3 (continued) Material composition (wt%) Alkaline solution Ag98.0Ru2.0 Many black stains Ag97.0Ru3.0 Moderate black stain Ag99.8Ru0.1Cu0.1 No change Ag99.4Ru0.5Cu0.1 No Change Ag98.1Ru0.9Cul.0 No change Ag98.9Rul.0Cu0.1 No change Ag97.9Ru2.0Cu0.1 No change Ag96.9Ru3.0Cu0.1 No change Ag96.5Ru3.0Cu0.5 No change Ag94.0Ru3. 0Cu3.0 did not change Ag99.8Ru0.1Ti0.1 did not change Ag99.4Ru0.5Ti0.1 did not change Ag98.1Ru0.9Til.0 did not change Ag98.9Rul.0Ti0.1 did not change Ag97.9Ru2.0Ti0" did not change Ag96 .9Ru3.0Ti0] Ag96.5Ru3.0Ti0.5 has not changed Ag94.0Ru3.0Ti3.0 has not changed 40NDA200104TW; P1P2000284TW 28 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1111111 · « 1284746 A7 B7 V. Description of invention (>q) Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative

Ag99.8Ru0.1Cr0.1 has not changed Ag98.4RuO.lCrl.5 has not changed Ag96.9Ru0.1Cr3.0 has not changed Ag98.4Rul.5Cr0.1 has not changed Ag97.0Rul.5Crl.5 has not changed Ag95.5Rul .5Cr3 .0 No change Ag96.9Ru3.0Cr0.1 No change Ag95.5Ru3.0Crl.5 No change Ag94.0Ru3.0Cr3.0 No change Ag98.4RuO.lTal.5 No change Ag96.9Ru0.1Ta3.0 No change Ag98 .4Rul.5Ta0.1 No change Ag97.0Rul.5Tal.5 No change Ag95.5Rul.5Ta3.0 No change Ag96.9Ru3.0Ta0.1 No change Ag95.5Ru3.0Tal .5 No change Ag94.0Ru3.0Ta3. 0 No change Ag99.8Ru0.1Mo0.1 No change Ag98.4RuO.lMol.5 No change Ag96.9Ru0.1Mo3.0 No change Ag98.4Rul.5Mo0.1 No change Ag97.0Rul.5Mol.5 No change Ag95. 5Rul .5M〇3.0 No change Ag96.9Ru3.0Mo0.1 No change Ag95.5Ru3.0Mol.5 No change Ag94.0Ru3.0Mo3.0 No change Ag99.8Ru0.1Ni0.1 No change Ag98.4RuO.lNil.5 No change Ag96.9Ru0.1Ni3.0 No change Ag98.4Rul.5Ni0.1 No change Ag97.0Rul.5Nil.5 No change Ag95.5Rul.5Ni3.0 No change Ag96.9Ru3.0Ni0.1 No change Ag95.5Ru3 .0Nil.5 No change Ag94.0Ru3.0Ni3.0 No change Ag99.8Ru0.1A10.1 No change Ag98.4RuO.lAll.5 No change Ag96.9Ru0.1A13.0 No change Ag98.4Rul.5A10.1 No Change Ag97.0Rul.5All.5 No Change Ag95.5Rul.5A13.0 No change 40NDA200104TW: P1P2000284TW 29 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the back note before writing this page) Write too — — — — — — — — 1284746 A7 ~-------B7 V. Description of invention (3〇)

Ag96.9Ru3.0A10.1 has not changed Ag95.5Ru3.0All.5 has not changed Ag94.0Ru3.0A13.0 has not changed Ag99.8Ru0.1Nb0.1 has not changed Ag98.4RuO.lNbl.5 has not changed Ag96.9Ru0.1Nb3 .0 No change Ag98.4Rul.5Nb0.1 No change Ag97.0Rul.5Nbl.5 No change Ag95.5Rul.5Nb3.0 No change Ag96.9Ru3.0Nb0.1 No change Ag95.5Ru3.0Nbl.5 No change Ag94 .0Ru3.0Nb3.0 has not changed as shown in Table 3, in the silver alloy layer of any of the components of the present invention, no decrease in reflectance is observed, and therefore, the ternary silver alloy layer is more alkaline than the conventional layer. The solution is more stable and the quality of the inventive layer is superior to conventional layers. Next, the reflectance at 500 nm and 800 nm is measured, and the range from 500 to 800 nm (565 nm) is a standard optical wavelength range of the liquid crystal display device. As shown in Table 4, the reflectance of the ternary silver alloy layer of the present invention was improved by 0.5 to 3.0% as compared with the inscription, silver alloy, silver, and binary silver alloy layers. (Please read the notes on the back first _ ϋ ϋ II ϋ I ϋ^OJ·1111—I _ this page) • Line φφ_ Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Table 4 Material Composition (wt%) 500mm Wavelength 800mm Wavelength reflectance (%) Reflectance (%) A1 87.2 84.5 A196.0 Mg 4.0 83.1 82.3 Aluminum covered with acrylic resin 79.4 76.6 Ag 98.2 98.8 Ag98.0Pd2.0 91.3 94.5 Ag97.0Pd3.0 86.9 92.1 Ag99.8 Pd 0.1 Cu 0.1 98.0 ~ 98.4 Ag99.4 Pd 0.5 Cu 0.1 98.0 98.4 Ag98.1 Pd 0.9 Cu 1.0 97.8 98.0 40NDA200104TW; P1P2000284TW 30 ^ Paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

Ag98.9 Pd 1.0 Cu 0.1 94.4 97.6 Ag97.9 Pd 2.0 Cu 0.1 91.4 94.6 Ag96.9 Pd 3.0 Cu 0.1 87.5 93.4 Ag96.5 Pd 3.0 Cu0.5 87.3 92.7 Ag94.0 Pd 3.0 Cu 3.0 84.7 91.1 Ag99.8 Pd 0.1 Ti 0.1 98.0 98.6 Ag99.4 Pd 0.5 Ti 0.1 98.0 98.4 Ag98.1 Pd 0.9 Ti 1.0 97.6 97.9 Ag98.9 Pd 1.0 Ti 0.1 94.4 97.6 Ag97.9 Pd 2.0 Ti 0.1 91.4 94.6 Ag96.9 Pd 3.0 Ti 0.1 87.5 93.4 Ag96.5 Pd 3.0 Ti 0.5 87.0 92.5 Ag94.0 Pd 3.0 Ti 3.0 87.0 90.7 Ag99.8 Pd 0.1 Cr 0.1 94.6 94.7 Ag98.4 Pd 0.1 Cr 1.5 91.7 91.7 Ag96.9 Pd 0.1 Cr 3.0 89.3 89.7 Ag98.4 Pd 1.5 Cr 0.1 91.5 90.7 Ag97.0 Pd 1.5 Cr 1.5 86.8 86.8 Ag95.5 Pd 1.5 Cr 3.0 84.2 84.2 Ag96.9 Pd 3.0 Cr 0.1 85.6 85.6 Ag95.5 Pd 3.0 Cr 1.5 83.5 83.5 Ag94.0 Pd 3.0 Cr 3.0 82.7 82.7 Ag99 .8 Pd 0.1 Ta 0.1 94.6 94.7 Ag98.4 Pd 0.1 Ta 1.5 91.7 91.7 Ag96.9 Pd 0.1 Ta 3.0 89.3 89.7 Ag98.4 Pd 1.5 Ta 0.1 91.5 91.7 Ag97.0 Pd 1.5 Ta 1.5 86.8 86.8 Ag95.5 Pd 1.5 Ta 3.0 84.2 84.2 Ag96.9 Pd 3.0 Ta 0.1 85.6 85.6 Ag95.5 Pd 3.0 Ta 1.5 83.5 83.5 Ag94.0 Pd 3.0 Ta 3.0 82.7 82.7 Ag99.8 Pd 0.1 Mo 0.1 94.6 94.7 Ag98.4 Pd 0.1 Mo 1.5 91.7 91.7 Ag96.9 Pd 0.1 Mo 3.0 89.3 89.7 Ag98.4 Pd 1.5 Mo 0.1 91.5 91.7 Ag97.0 Pd 1.5 Mo 1.5 86.8 86.8 Ag95.5 Pd 1.5 Mo 3.0 84.2 84.2 Ag96.9 Pd 3.0 Mo 0.1 85.6 85.6 Ag95.5 Pd 3.0 Mo 1.5 83.5 83.5 Ag94.0 Pd 3.0 Mo 3.0 82.7 82.7 Ag99.8 Pd 0.1 Ni 0.1 96.1 96.1 Ag98.4 Pd 0.1 Ni 1.5 95.6 95.6 Ag96.9 Pd 0.1 Ni 3.0 94.3 94.8 40NDA200104TW; P1P2000284TW 31 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) I i_i a-1.^1 I ϋ One: OJ ϋ 1 an ei ϋ (Please read the back first Note on this page) Write the line ΦΦ· 1284746 A7 B7 V. Description of the invention (31) Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

Ag98.4 Pd 1.5 Ni 0.1 92.7 93.7 Ag97.0 Pd 1.5 Ni 1.5 91.2 92.1 Ag95.5 Pd 1.5 Ni 3.0 88.9 90.7 Ag96.9 Pd 3.0 Ni 0.1 86.1 88.9 Ag95.5 Pd 3.0 Ni 1.5 84.6 86.2 Ag94.0 Pd 3.0 Ni 3.0 82.7 84.6 Ag99.8 Pd 0.1 A1 0.1 98.1 98.7 Ag98.4 Pd 0.1 A1 1.5 98.1 98.4 Ag96.9 Pd 0.1 A1 3.0 97.6 98.1 Ag98.4 Pd 1.5 A1 0.1 96.5 97.6 Ag97.0 Pd 1.5 A1 1.5 95.3 96.8 Ag95 .5 Pd 1.5 A1 3.0 93.5 95.9 Ag96.9 Pd 3.0 A1 0.1 91 94.6 Ag95.5 Pd 3.0 A1 1.5 88.6 93 Ag94.0 Pd 3.0 A1 3.0 86.1 91.7 Ag99.8 Pd 0.1 NbO.l 95 95.3 Ag98.4 Pd 0.1 Nb 1.5 94.4 94.8 Ag96.9 Pd 0.1 Nb 3.0 93.8 94.2 Ag98.4 Pd 1.5 Nb 0.1 92.4 92.7 Ag97.0 Pd 1.5 Nb 1.5 90.8 91.4 Ag95.5 Pd 1.5 Nb 3.0 89.5 90.2 Ag96.9 Pd 3.0 Nb 0.1 86.7 87.9 Ag95 .5 Pd 3.0 Nb 1.5 84.6 85.9 Ag94.0 Pd 3.0 Nb 3.0 82.7 84.7 Ag99.8 Pd 0.1 AuO.l 96.7 97.0 Ag98.4 Pd 0.1 Au 1.5 95.4 96.8 Ag96.9 Pd 0.1 Au 3.0 95.8 96.1 Ag98.4 Pd 1.5 Au 0.1 92.3 94.5 Ag97.0 Pd 1.5 Au 1.5 92.1 94.3 Ag95.5 Pd 1.5 Au 3.0 92.4 95.0 Ag96.9 Pd 3.0 Au 0.1 85.1 85.3 Ag95.5 Pd 3.0 Au 1.5 83.2 83.3 Ag94.0 Pd 3.0 Au 3.0 82.0 1 82.8 Ag99.8 Pd 0.1 AuO.l 96.6 97.1 Ag98.4 Pd 0.1 Au 1.5 96.3 96.7 Ag96.9 Pd 0.1 Au 3.0 95.8 96.1 Ag98.4 Pd 1.5 Au 0.1 92.4 94.4 Ag97.0 Pd 1.5 Au 1.5 92.1 94.3 Ag95.5 Pd 1.5 Au 3.0 92.4 95.0 Ag96.9 Pd 3.0 Au 0.1 85.1 85.3 Ag95.5 Pd 3.0 Au 1.5 83.2 83.2 Ag94.0 Pd 3.0 Au 3.0 82.0 82.8 Ag99.8 Pd 0.1 RuO.l 96.7 97.1 40NDA200104TW; P1P2000284TW 32 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back to write this page) ----I---订- --------

1284746 A7 B7 V. Description of invention (33⁄4)

Ag98.4 Pd 0.1 Ru 1.5 96.4 96.6 Ag96.9 Pd 0.1 Ru 3.0 95.8 96.5 Ag98.4 Pd 1.5 Ru 0.1 82.3 93.5 Ag97.0 Pd 1.5 Ru 1.5 92.0 94.3 Ag95.5 Pd 1.5 Ru 3.0 92.3 95.0 Ag96.9 Pd 3.0 Ru 0.1 85.0 85.3 Ag95.5 Pd 3.0 Ru 1.5 83.3 83.3 Ag94.0 Pd 3.0 Ru 3.0 82.1 82.5 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing

AgAuX Table 4 (continued) Material Composition (wt%) 500mm Wavelength 800mm Wavelength Reflectance (%) Reflectance (%) Ag98.0 Au 2.0 87.3 92.2 Ag97.0 Au 3.0 86.1 91.3 Ag99.8 Au 0.1 Cu 0.1 98.2 98.8 Ag99.4 Au 0.5 Cu 0.1 98.1 98.5 Ag98.1 Au 0.9 Cu 1.0 97.6 98.0 Ag98.9 Au 1.0 Cu 0.1 96.5 97.6 Ag97.9 Au 2.0 Cu 0.1 95.2 96.9 Ag96.9 Au 3.0 Cu 0.1 93.7 96.1 Ag96.5 Au 3.0 Cu0.5 91.1 94.7 Ag94.0 Au 3.0 Cu 3.0 85.6 91.8 Ag99.8 Au 0.1 Ti 0.1 98.0 98.5 Ag99.4 Au 0.5 Ti 0.1 97.8 98.2 Ag98.1 Au 0.9 Ti 1.0 97.3 97.9 Ag98.9 Au 1.0 Ti 0.1 96.6 97.5 Ag97.9 Au 2.0 Ti 0.1 95.5 97.1 Ag96.9 Au 3.0 Ti 0.1 93.9 96.3 Ag96.5 Au 3.0 Ti 0.5 92.3 95.2 Ag94.0 Au 3.0 Ti 3.0 86.4 90.8 Ag99.8 Au 0.1 Cr 0.1 94.6 94.7 Ag98.4 Au 0.1 Cr 1.5 93.4 93.6 Ag96.9 Au 0.1 Cr 3.0 91.9 92.4 Ag98.4 Au 1.5 Cr 0.1 90.2 90.7 Ag97.0 Au 1.5 Cr 1.5 88.5 89.3 Ag95.5 Au 1.5 Cr 3.0 86.1 86.6 Ag96.9 Au 3.0 Cr 0.1 84.9 85.2 Ag95 .5 Au 3.0 Cr 1.5 83.4 83.8 Ag94.0 Au 3.0 Cr 3.0 82.6 82.6 Ag99.8 Au 0.1 Ta 0.1 95.1 95.3 Ag98.4 Au 0.1 Ta 1.5 94.6 95.0 40NDA200104TW: P1P2000284TW 33 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 297 297 mm) (please read the notes on the back first. I ϋ ϋ ϋ n^OJI i 1 ϋ Write this page) 1284746 A7 B7 V. Description of invention (3+) Printed by the Consumers' Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs

Ag96.9 Au 0.1 Ta 3.0 93.4 94.1 Ag98.4 Au 1.5 Ta 0.1 91.8 92.5 Ag97.0 Au 1.5 Ta 1.5 90.4 91.2 Ag95.5 Au 1.5 Ta 3.0 88.7 89.9 Ag96.9 Au 3.0 Ta 0.1 85.9 87.6 Ag95.5 Au 3.0 Ta 1.5 84.5 85.9 Ag94.0 Au 3.0 Ta 3.0 82.8 84.2 Ag99.8 Au 0.1 Mo 0.1 94.8 95.1 Ag98.4 Au 0.1 Mo 1.5 94.2 94.7 Ag96.9 Au 0.1 Mo 3.0 93.5 94.0 Ag98.4 Au 1.5 Mo 0.1 92.3 92.9 Ag97 .0 Au 1.5 Mo 1.5 90.6 91.5 Ag95.5 Au 1.5 Mo 3.0 89.7 90.3 Ag96.9 Au 3.0 Mo 0.1 86.8 88.6 Ag95.5 Au 3.0 Mo 1.5 84.6 86.4 Ag94.0 Au 3.0 Mo 3.0 82.7 84.5 Ag99.8 Au 0.1 Ni 0.1 95.7 95.9 Ag98.4 Au 0.1 Ni 1.5 95.2 95.4 Ag96.9 Au 0.1 Ni 3.0 93.9 94.6 Ag98.4 Au 1.5 Ni 0.1 92.3 93.5 Ag97.0 Au 1.5 Ni 1.5 90.8 91.9 Ag95.5 Au 1.5 Ni 3.0 88.7 90.6 Ag96. 9 Au 3.0 Ni 0.1 85.9 88.8 Ag95.5 Au 3.0 Ni 1.5 84.4 86.1 Ag94.0 Au 3.0 Ni 3.0 82.6 84.5 Ag99.8 Au 0.1 A1 0.1 98.0 98.6 Ag98.4 Au 0.1 A1 1.5 97.9 98.3 Ag96.9 Au 0.1 A1 3.0 97.5 98.0 Ag98.4 Au 1.5 A1 0.1 96.4 97.5 Ag97.0 Au 1.5 A1 1.5 95.2 96.7 Ag95.5 Au 1.5 A1 3.0 93.4 95.8 Ag96.9 A u 3.0 A1 0.1 90.8 94.4 Ag95.5 Au 3.0 A1 1.5 88.4 92.8 Ag94.0 Au 3.0 A1 3.0 85.9 91.5 Ag99.8 Au 0.1 NbO.l 94.8 95.1 Ag98.4 Au 0.1 Nb 1.5 94.3 94.7 Ag96.9 Au 0.1 Nb 3.0 93.5 94.1 Ag98.4 Au 1.5 Nb 0.1 92.1 92.6 Ag97.0 Au 1.5 Nb 1.5 90.5 91.3 Ag95.5 Au 1.5 Nb 3.0 89.2 90.1 Ag96.9 Au 3.0 Nb 0.1 86.4 87.8 Ag95.5 Au 3.0 Nb 1.5 87.3 85.7 Ag94.0 Au 3.0 Nb 3.0 82.4 84.5 40NDA200104TW; P1P2000284TW 34 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back to write this page) t-------- - line 4

1284746 A7 B7 V. INSTRUCTIONS (35) Printed by the Consumers' Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs

AgRuX Table 4 (continued) Material Composition (Wt%) 500mm Wavelength 800mm Wavelength Reflectance (%) Reflectance (%) Ag98.0 Ru 2.0 86.3 91.2 Ag97.0 Ru 3.0 86.0 91.3 Ag99.8 Ru 0.1 Cu 0.1 98.1 98.8 Ag99.4 Ru 0.5 Cu 0.1 98.0 98.6 Ag98.1 Ru 0.9 Cu 1.0 97.6 98.1 Ag98.9 Ru 1.0 Cu 0.1 96.5 97.5 Ag97.9 Ru 2.0 Cu 0.1 95.2 96.8 Ag96.9 Ru 3.0 Cu 0.1 93.7 96.0 Ag96.5 Ru 3.0 Cu0.5 91.1 94.7 Ag94.0 Ru 3.0 Cu 3.0 85.6 91.7 Ag99.8 Ru 0.1 Ti 0.1 98.0 98.4 Ag99.4 Ru 0.5 Ti 0.1 97.7 98.2 Ag98.1 Ru 0.9 Ti 1.0 97.2 97.9 Ag98.9 Ru 1.0 Ti 0.1 96.5 97.5 Ag97.9 Ru 2.0 Ti 0.1 95.4 97.1 Ag96.9 Ru 3.0 Ti 0.1 93.8 96.3 Ag96.5 Ru 3.0 Ti 0.5 92.1 95.2 Ag94.0 Ru 3.0 Ti 3.0 86.4 90.8 Ag99.8 Ru 0.1 Cr 0.1 94.6 94.7 Ag98.4 Ru 0.1 Cr 1.5 93.4 92.6 Ag96.9 Ru 0.1 Cr 3.0 91.9 92.4 Ag98.4 Ru 1.5 Cr 0.1 90.5 91.7 Ag97.0 Ru 1.5 Cr 1.5 88.2 88.3 Ag95.5 Ru 1.5 Cr 3.0 86.1 86.6 Ag96.9 Ru 3.0 Cr 0.1 84.8 84.2 Ag95 .5 Ru 3.0 Cr 1.5 83.3 83.8 Ag94.0 Ru 3.0 Cr 3.0 82.4 82.6 Ag99.8 Ru 0.1 Ta 0.1 95.0 95.3 Ag98.4 Ru 0.1 T a 1.5 94.6 95.0 Ag96.9 Ru 0.1 Ta 3.0 93.4 94.1 Ag98.4 Ru 1.5 Ta 0.1 91.8 92.5 Ag97.0 Ru 1.5 Ta 1.5 90.4 91.2 Ag95.5 Ru 1.5 Ta 3.0 88.7 89.9 Ag96.9 Ru 3.0 Ta 0.1 85.9 87.6 Ag95 .5 Ru 3.0 Ta 1.5 84.5 85.9 Ag94.0 Ru 3.0 Ta 3.0 82.6 84.2 Ag99.8 Ru 0.1 Mo 0.1 94.7 95.1 40NDA200104TW; P1P2000284TW 35 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) - ------- book --------- line gas (please read the notes on the back to write this page)

1284746 A7 B7 V. Invention Description UL)

Ag98.4 Ru 0.1 Mo 1.5 94.1 94.7 Ag96.9 Ru 0.1 Mo 3.0 93.3 94.0 Ag98.4 Ru 1.5 Mo 0.1 92.2 92.9 Ag97.0 Ru 1.5 Mo 1.5 90.5 91.5 Ag95.5 Ru 1.5 Mo 3.0 89.9 91.3 Ag96.9 Ru 3.0 Mo 0.1 86.8 88.6 Ag95.5 Ru 3.0 Mo 1.5 84.8 86.3 Ag94.0 Ru 3.0 Mo 3.0 82.6 84.5 Ag99.8 Ru 0.1 Ni 0.1 96.7 97.2 Ag98.4 Ru 0.1 Ni 1.5 96.5 96.9 Ag96.9 Ru 0.1 Ni 3.0 96.1 96.3 Ag98 .4 Ru 1.5 Ni 0.1 95.3 95.8 Ag97.0 Ru 1.5 Ni 1.5 93.7 94.7 Ag95.5 Ru 1.5 Ni 3.0 91.2 93.3 Ag96.9 Ru 3.0 Ni 0.1 88.4 91.7 Ag95.5 Ru 3.0 Ni 1.5 85.0 87.2 Ag94.0 Ru 3.0 Ni 3.0 83.5 85.6 Ag99.8 Ru 0.1 A1 0.1 98.0 98.4 Ag98.4 Ru 0.1 A1 1.5 97.9 98.2 Ag96.9 Ru 0.1 A1 3.0 97.5 98.1 Ag98.4 Ru 1.5 A1 0.1 96.4 97.5 Ag97.0 Ru 1.5 A1 1.5 95.2 96.5 Ag95. 5 Ru 1.5 A1 3.0 93.4 95.8 Ag96.9 Ru 3.0 A1 0.1 90.8 94.4 Ag95.5 Ru 3.0 A1 1.5 88.4 92.7 Ag94.0 Ru 3.0 A1 3.0 85.4 91.5 Ag99.8 Ru 0.1 NbO.l 94.7 95.2 Ag98.4 Ru 0.1 Nb 1.5 94.3 94.7 Ag96.9 Ru 0.1 Nb 3.0 93.4 94.1 Ag98.4 Ru 1.5 Nb 0.1 92.1 92.5 Ag97.0 Ru 1.5 Nb 1.5 90.2 91.3 Ag95.5 Ru 1.5 Nb 3.0 88.1 90.0 Ag96.9 Ru 3.0 Nb 0.1 85.2 87.8 Ag95.5 Ru 3.0 Nb 1.5 84.1 85.7 Ag94.0 Ru 3.0 Nb 3.0 82.4 84.5 (Please read the back note to write this page) ^----- ----麓

Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives. Therefore, it can be seen that the silver alloy layer of the present invention is very suitable for use as a reflector or a reflective wiring electrode of a reflective liquid crystal display device. 40NDA200104TW; P1P2000284TW 36 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). 1284746 A7 B7 V. Inventive Note (say) Chemical stability against resin substrate under conditions. In order to confirm the chemical stability of the ternary reflective layer of the present invention, a 15 nm thick reflective layer was deposited by ternary simultaneous sputtering on PMMA, PET, PC, decane resin and similar resin layers. These layers were maintained at high temperature and high humidity for 24 hours. Check the appearance and reflection characteristics over time. Table 5 Material Composition (wt%) High-temperature and high-humidity test results Chemical characteristics change (reflectance reduction) Visual change into blurred white, peeling off with substrate Ag98.0 Pd 2.0 Many black stains peeled off Ag97.0 Pd 3.0 Moderate Black stains peeled off Ag99.8 Pd 0.1 Cu 0.1 No change in color Change Ag99.4 Pd 0.5 Cu 0.1 No change No love Ag98.1 Pd 0.9 Cu 1.0 No change No change Ag98.9 Pd 1.0 Cu 0.1 No change No change Ag97 .9 Pd 2.0 Cu 0.1 No change No change Ag96.9 Pd 3.0 Cu 0.1 No change No Ag96.5 Pd 3.0 Cu0.5 No change No change Ag94.0 Pd 3.0 Cu 3.0 No change No change Ag99.8 Pd 0.1 Ti 0.1 No change, no change, Ag99.4 Pd 0.5 Ti 0.1 No change, no change, Ag98.1 Pd 0.9 Ti 1.0 No change, no change, Ag98.9 Pd 1.0 Ti 0.1 No change, no change, Ag97.9 Pd 2.0 Ti 0.1 No change, no change, Ag96. 9 Pd 3.0 Ti 0.1 No change No change Ag96.5 Pd 3.0 Ti 0.5 No change No change Ag94.0 Pd 3.0 Ti 3.0 No change No change Ag99.8 Pd 0.1 Au 0.1 No change No change Ag98.4 Pd 0.1 Au 1.5 No No change Ag96.9 Pd 0.1 Au 3.0 No change No change Ag98.4 Pd 1.5 Au 0.1 No No change Ag97.0 Pd 1.5 Au 1.5 No change No change Ag95.5 Pd 1.5 Au 3.0 No change No change 40NDA200104TW; P1P2000284TW 38 This paper size applies to Chinese National Standard (CNS) A4 size (210X297 mm) (Please read the back first Note on the horse page)

Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Co., Ltd. 1284746 A7 _B7 V. Invention Description (Μ) Printed by the Intellectual Property Office of the Ministry of Economic Affairs

Ag96.9 Pd 3.0 Au 0.1 No change No change Ag95.5 Pd 3.0 Au 1.5 No change No change Ag94.0 Pd 3.0 Au 3.0 No change No change Ag99.8 Pd 0.1 Cr 0.1 No change No change Ag98.4 Pd 0.1 Cr 1.5 No change No change Ag96.9 Pd 0.1 Cr 3.0 No change No change Ag98.4 Pd 1.5 Cr 0.1 No change No change Ag97.0 Pd 1.5 Cr 1.5 No change No change Ag95.5 Pd 1.5 Cr 3.0 No change No change Ag96 .9 Pd 3.0 Cr 0.1 No change No change Ag95.5 Pd 3.0 Cr 1.5 No change No change Ag94.0 Pd 3.0 Cr 3.0 No change No change Ag99.8 Pd 0.1 Ta 0.1 No change No change Ag98.4 Pd 0.1 Ta 1.5 No change, no change, Ag96.9 Pd 0.1 Ta 3.0 No change, no change, Ag98.4 Pd 1.5 Ta 0.1 No change, no change, Ag97.0 Pd 1.5 Ta 1.5 No change, no change, Ag95.5 Pd 1.5 Ta 3.0 No change, no change, Ag96. 9 Pd 3.0 Ta 0.1 No change No change Ag95.5 Pd 3.0 Ta 1.5 No change No change Ag94.0 Pd 3.0 Ta 3.0 No change No change Ag99.8 Pd 0.1 Mo 0.1 No change No change Ag98.4 Pd 0.1 Mo 1.5 No No change Ag96.9 Pd 0.1 Mo 3.0 No change No change Ag98.4 Pd 1.5 Mo 0.1 No change No change Ag97.0 Pd 1.5 Mo 1.5 No change No change Ag95.5 Pd 1.5 Mo 3.0 has not changed, Ag96.9 Pd 3.0 Mo 0.1 has not changed, Ag95.5 Pd 3.0 Mo 1.5 has not changed, Ag94.0 Pd 3.0 Mo 3.0 has not changed, Ag99.8 Pd 0.1 Ni 0.1 has not changed Ag98.4 Pd 0.1 Ni 1.5 No change No change Ag96.9 Pd 0.1 Ni 3.0 No change No change Ag98.4 Pd 1.5 Ni 0.1 No change No change Ag97.0 Pd 1.5 Ni 1.5 No change No change Ag95.5 Pd 1.5 Ni 3.0 No change No change Ag96.9 Pd 3.0 Ni 0.1 No change No change Ag95.5 Pd 3.0 Ni 1.5 No change No change Ag94.0 Pd 3.0 Ni 3.0 No change No change Ag99.8 Pd 0.1 A1 0.1 No change No change Ag98 .4 Pd 0.1 A1 1.5 No change No change 40NDA200104TW; P1P2000284TW 39 · 1· ·1 II ^1 I ϋ ϋ One 0, I i^i ^1- in Hi «^1 ϋ I (Please read the notes on the back first) Fill in this page again)

f This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing A7 B7 V. Invention description (4〇)

Ag96.9 Pd 0.1 A1 3.0 No change No change Ag98.4 Pd 1.5 A1 0.1 No change No change Ag97.0 Pd 1.5 A1 1.5 No change No change Ag95.5 Pd 1.5 A1 3.0 No change No change Ag96.9 Pd 3.0 A1 0.1 No change No change Ag95.5 Pd 3.0 A1 1.5 No change Ag94.0 Pd 3.0 A1 3.0 No change No change Ag99.8 Pd 0.1 NbO.l No change No change Ag98.4 Pd 0.1 Nb 1.5 No change No change Ag96 .9 Pd 0.1 Nb 3.0 No change No change Ag98.4 Pd 1.5 Nb 0.1 No change No change Ag97.0 Pd 1.5 Nb 1.5 No change No change Ag95.5 Pd 1.5 Nb 3.0 No change No change Ag96.9 Pd 3.0 Nb 0.1 No change No change Ag95.5 Pd 3.0 Nb 1.5 No change No change Ag94.0 Pd 3.0 Nb 3.0 No change No change Ag99.8 Ru 0.1 Au 0.1 No change No change Ag98.4 Ru 0.1 Au 1.5 No change No change Ag96. 9 Ru 0.1 Au 3.0 No change No change Ag98.4 Ru 1.5 Au 0.1 No change No change Ag97.0 Ru 1.5 Au 1.5 No change No change Ag95.5 Ru 1.5 Au 3.0 No change No change Ag96.9 Ru 3.0 Au 0.1 No Change No change Ag95.5 Ru 3.0 Au 1.5 No change No change Ag94.0 Ru 3.0 Au 3.0 No change No change Ag99.8 Pd 0.1 Ru 0.1 No change No change Ag98.4 Pd 0.1 Ru 1.5 No change No change Ag96.9 Pd 0.1 Ru 3.0 No change No change Ag98.4 Pd 1.5 Ru 0.1 No change No change Ag97.0 Pd 1.5 Ru 1.5 No change No change Ag95.5 Pd 1.5 Ru 3.0 No change No change Ag96 .9 Pd 3.0 Ru 0.1 No change No change Ag95.5 Pd 3.0 Ru 1.5 No change No change Ag94.0 Pd 3.0 Ru 3.0 No change No change 40NDA200104TW; P1P2000284TW 40 镳μ·· ΜΗ xav One port, an ϋ ϋ ϋ -^1 ϋ I (Please read the note on the back to fill out this page) f Fill in the paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1284746 A7 _B7 V. Description of invention (4A)

AgAuX Table 5 (continued) Material Composition (wt%) High-temperature and high-humidity test results Chemical characteristics change (reflectance reduction) Chemical property change (reflectance reduction) Ag98.0 Au 2.0 Many black stains peeled off Ag97.0 Au 3.0 moderate black stain peeling Ag99.8 Au 0.1 Cu 0.1 No change No change Ag99.4 Au 0.5 Cu 0.1 No change No change Ag98.1 Au 0.9 Cu 1.0 No change No change Ag98.9 Au 1.0 Cu 0.1 No change No change Ag97.9 Au 2.0 Cu 0.1 No change No change Ag96.9 Au 3.0 Cu 0.1 No change No change Ag96.5 Au 3.0 Cu0.5 No change No change Ag94.0 Au 3.0 Cu 3.0 No change No change Ag99.8 Au 0.1 Ti 0.1 No change No change Ag99.4 Au 0.5 Ti 0.1 No change No change Ag98.1 Au 0.9 Ti 1.0 No change No change Ag98.9 Au 1.0 Ti 0.1 No change No change Ag97.9 Au 2.0 Ti 0.1 No change No change Ag96.9 Au 3.0 Ti 0.1 No change No change Ag96.5 Au 3.0 Ti 0.5 No change No change Ag94.0 Au 3.0 Ti 3.0 No change No change Ag99.8 Au 0.1 Cr 0.1 No change No change Ag98.4 Au 0.1 Cr 1.5 No change No change Ag96.9 Au 0.1 Cr 3.0 No change No change Ag98.4 Au 1.5 Cr 0 .1 No change No change Ag97.0 Au 1.5 Cr 1.5 No change No change Ag95.5 Au 1.5 Cr 3.0 No change No change Ag96.9 Au 3.0 Cr 0.1 No change No change Ag95.5 Au 3.0 Cr 1.5 No change Ag94.0 Au 3.0 Cr 3.0 No change No change Ag99.8 Au 0.1 Ta 0.1 No change No change Ag98.4 Au 0.1 Ta 1.5 No change No change Ag96.9 Au 0.1 Ta 3.0 No change No change Ag98.4 Au 1.5 Ta 0.1 No change No change Ag97.0 Au 1.5 Ta 1.5 No change No change Ag95.5 Au 1.5 Ta 3.0 No change No change Ag96.9 Au 3.0 Ta 0.1 No change No change Ag95.5 Au 3.0 Ta 1.5 No change No change 40NDA200104TW ; P1P2000284TW 41 I 1 1 H 1 One-to-one, I n 1 ϋ ϋ 1 ϋ ϋ I (Please read the notes on the back and fill out this page)

鹄 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing A7 B7 V. Invention description (43⁄4

Ag94.0 Au 3.0 Ta 3.0 No change No change Ag99.8 Au 0.1 Mo 0.1 No change No change Ag98.4 Au 0.1 Mo 1.5 No change No change Ag96.9 Au 0.1 Mo 3.0 No change No change Ag98.4 Au 1.5 Mo 0.1 No change No change Ag97.0 Au 1.5 Mo 1.5 No change No change Ag95.5 Au 1.5 Mo 3.0 No change No change Ag96.9 Au 3.0 Mo 0.1 No change No change Ag95.5 Au 3.0 Mo 1.5 No change No change Ag94 .0 Au 3.0 Mo 3.0 No change No change Ag99.8 Au 0.1 Ni 0.1 No change No change Ag98.4 Au 0.1 Ni 1.5 No change No change Ag96.9 Au 0.1 Ni 3.0 No change No change Ag98.4 Au 1.5 Ni 0.1 No change No change Ag97.0 Au 1.5 Ni 1.5 No change No change Ag95.5 Au 1.5 Ni 3.0 No change No change Ag96.9 Au 3.0 Ni 0.1 No change No change Ag95.5 Au 3.0 Ni 1.5 No change No change Ag94. 0 Au 3.0 Ni 3.0 No change No change Ag99.8 Au 0.1 A1 0.1 No change No change Ag98.4 Au 0.1 A1 1.5 No change No change Ag96.9 Au 0.1 A1 3.0 No change No change Ag98.4 Au 1.5 A1 0.1 No Change No change Ag97.0 Au 1.5 A1 1.5 No change No change Ag95.5 Au 1.5 A1 3.0 No change No change Ag96.9 Au 3.0 A1 0.1 No change No change Ag95.5 Au 3. 0 A1 1.5 No change No change Ag94.0 Au 3.0 A1 3.0 No change No change Ag99.8 Au 0.1 NbO.l No change No change Ag98.4 Au 0.1 Nb 1.5 No change No change Ag96.9 Au 0.1 Nb 3.0 No change No change Ag98.4 Au 1.5 Nb 0.1 No change No change Ag97.0 Au 1.5 Nb 1.5 No change No change Ag95.5 Au 1.5 Nb 3.0 No change No change Ag96.9 Au 3.0 Nb 0.1 No change No change Ag95.5 Au 3.0 Nb 1.5 No change No change Ag94.0 Au 3.0 Nb 3.0 No change No change 40NDA200104TW: P1P2000284TW 42 ;- I- ϋ ϋ ϋ ϋ ϋ ϋ^OJI n ϋ I» ϋ ^1 ii I (Please read the back of the note first) ^: Fill in this page)

PI This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Description of invention (^3)

AgRuX Table 5 (continued) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printing Materials Composition (wt%) High-temperature and high-humidity test results Chemical characteristics change (reflectance reduction) Chemical characteristics change (reflectance reduction) Ag98. 0 Ru 2.0 Many black stains peeled off Ag97.0 Ru 3.0 Moderate black stains peeled off Ag99.8 Ru 0.1 Cu 0.1 No change Ag99.4 Ru 0.5 Cu 0.1 No change No change Ag98.1 Ru 0.9 Cu 1.0 No change No change Ag98.9 Ru 1.0 Cu 0.1 No change No change Ag97.9 Ru 2.0 Cu 0.1 No change No change Ag96.9 Ru 3.0 Cu 0.1 No change No change Ag96.5 Ru 3.0 Cu0.5 No change No change Ag94.0 Ru 3.0 Cu 3.0 has not changed, Ag99.8 Ru 0.1 Ti 0.1 has not changed, Ag99.4 Ru 0.5 Ti 0.1 has not changed, Ag98.1 Ru 0.9 Ti 1.0 has not changed, Ag98.9 Ru 1.0 Ti 0.1 has not changed No change Ag97.9 Ru 2.0 Ti 0.1 No change No change Ag96.9 Ru 3.0 Ti 0.1 No change No change Ag96.5 Ru 3.0 Ti 0.5 No change No change Ag94.0 Ru 3.0 Ti 3.0 No change No change Ag99.8 Ru 0.1 Cr 0.1 No change, no change, Ag98.4 Ru 0.1 Cr 1.5 No change, no change, Ag96 .9 Ru 0.1 Cr 3.0 No change No change Ag98.4 Ru 1.5 Cr 0.1 No change No change Ag97.0 Ru 1.5 Cr 1.5 No change No change Ag95.5 Ru 1.5 Cr 3.0 No change No change Ag96.9 Ru 3.0 Cr 0.1 No change, no change, Ag95.5, Ru 3.0 Cr 1.5, no change, no change, Ag94.0, Ru 3.0, Cr 3.0, no change, no change, Ag99.8, Ru 0.1 Ta 0.1, no change, no change, Ag98.4, Ru 0.1 Ta 1.5, no change, no change, Ag96. 9 Rd 0.1 Ta 3.0 No change No change Ag98.4 Ru 1.5 Ta 0.1 No change No change Ag97.0 Ru 1.5 Ta 1.5 No change No change Ag95.5 Ru 1.5 Ta 3.0 No change No change Ag96.9 Ru 3.0 Ta 0.1 No Change No change Ag95.5 Ru 3.0 Ta 1.5 No change No change 40NDA200104TW; P1P2000284TW 43 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) · ϋ ϋ ϋ ϋ ϋ i^i ϋ 0, I ϋ ϋ ϋ n Βϋ >ϋ ϋ I (please read the notes on the back and fill out this page) β 1284746 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed A7 B7

V. Description of invention (AAO

Ag94.0 Ru 3.0 Ta 3.0 has not changed, Ag99.8 Ru 0.1 Mo 0.1 has not changed, Ag98.4 Ru 0.1 Mo 1.5 has not changed, Ag96.9 Ru 0.1 Mo 3.0 has not changed, Ag98.4 Ru 1.5 Mo 0.1 No change No change Ag97.0 Ru 1.5 Mo 1.5 No change No change Ag95.5 Ru 1.5 Mo 3.0 No change No change Ag96.9 Ru 3.0 Mo 0.1 No change No change Ag95.5 Ru 3.0 Mo 1.5 No change No change Ag94 .0 Ru 3.0 Mo 3.0 No change No change Ag99.8 Ru 0.1 Ni 0.1 No change No change Ag98.4 Ru 0.1 Ni 1.5 No change No change Ag96.9 Ru 0.1 Ni 3.0 No change No change Ag98.4 Ru 1.5 Ni 0.1 No change No change Ag97.0 Ru 1.5 Ni 1.5 No change No change Ag95.5 Ru 1.5 Ni 3.0 No change No change Ag96.9 Ru 3.0 Ni 0.1 No change No change Ag95.5 Ru 3.0 Ni 1.5 No change No change Ag94. 0 Ru 3.0 Ni 3.0 No change No change Ag99.8 Ru 0.1 A1 0.1 No change No change Ag98.4 Ru 0.1 A1 1.5 No change No change Ag96.9 Ru 0.1 A1 3.0 No change No change Ag98.4 Ru 1.5 A1 0.1 No Change No change Ag97.0 Ru 1.5 A1 1.5 No change No change Ag95.5 Ru 1.5 A1 3.0 No change No change Ag96.9 Ru 3.0 A1 0.1 No change No change Ag95.5 Ru 3. 0 A1 1.5 No change No change Ag94.0 Ru 3.0 A1 3.0 No change No change Ag99.8 Ru 0.1 NbO.l No change No change Ag98.4 Ru 0.1 Nb 1.5 No change No change Ag96.9 Rd 0.1 Nb 3.0 No change No change Ag98.4 Ru 1.5 Nb 0.1 No change No change Ag97.0 Ru 1.5 Nb 1.5 No change No change Ag95.5 Ru 1.5 Nb 3.0 No change No change Ag96.9 Ru 3.0 Nb 0.1 No change No change Ag95.5 Ru 3.0 Nb 1.5 No change No change Ag94.0 Ru 3.0 Nb 3.0 No change No change 40NDA200104TW: P1P2000284TW 44 t------ (Please read the note on the back first: W: Fill in this page) ·11111111 f This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) 1284746 A7 B7 Five Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Description (+5) As shown in Table 5, after 24 hours ternary silver alloy reflective layer No changes were observed. When the reflectance of the ternary reflective layer on various resin substrates was measured using a spectrophotometer, no decrease in reflectance at a wavelength of 565 nm was observed, which was useful for a reflective liquid crystal display device; no reflectance was observed at 400 nm to A reduction between 4/m is necessary for architectural glass (data not shown). The ternary reflective layer of the present invention proves to have high chemical stability against the resin, and unlike conventional layers, is not limited to a particular substrate material. Example 4 The adhesion between the ternary reflective layer of the present invention and various substrates was examined, as well as the base film, which was placed between the reflective layer and the substrate for the subsequent effect. First, the reflective layer is deposited directly onto PMMA, PET, PC, siloxane resin, acrylic, non-alkaline glass, low-alkaline glass, borosilicate glass, and quartz glass substrates by radio frequency sputtering to form a layer. Integral. Attach a Japanese industrial standard cellophane tape to the reflective layer. The peeling of the reflective layer from the substrate was observed when the tape was torn at a given tension. Further, the laminate was cut into small pieces by a cutter and immersed in pure water in a beaker, and ultrasonic waves were applied to pure water at a frequency of 50 kHz and an electric power of 100 W. After the ultrasonic wave was used, the peeling of the reflective layer was observed under a 40-fold microscope, and the necessity of the base film was examined. 40NDA200104TW: P1P2000284TW 45 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). ------ (Please read the note on the back first ^5: fill this page) f Fill 11111111 f Economy Ministry of Intellectual Property Bureau employee consumption cooperative printed 1284746 Α7 Β7 5, invention description (β) Table 7 material wavelength 565.00 nm. Wavelength ^ 450.00 nm wavelength 500.00 nm wavelength · 550.00 nm : 'wavelength · 565.00 nm reflectance (%) reflectivity (%) Reflectance (%) Reflectance (%) Reflectance (%) _Pure Ag 94.80 96.60 97.70 97.90 98.00 AgPd 92.30 94.05 95.12 95.32 95.42 AgPdCu 91.50 92.40 93.60 94.10 93.36 A^PdTi - 88.90 90.59 91.62 91.81 91.90 A^PdCr 88.40 90.08 91.11 91.29 91.38 A^PdTa 88.30 89.98 91.00 91.19 91.28 A^PdMo 88.00 89.67 90.69 90.88 90.97 A^PdNi 88.20 89.77 90.89 90.98 91.17 A^PdAl 88.90 90.49 91.61 91.70 91.79 A^PdNb 88.80 90.38 91.51 91.60 91.79 AgAu 92.80 94.56 95.64 95.83 95.93 A^AuCu 92.46 94.22 95.29 95.48 95.58 A^AuTi 88.44 ^ 90.12 91.15 91.33 91.43 A^AuCr 88.56 90.24 91.27 91.46 91.55 AgAuTa 88.30 89.98 91.00 91.19 91.28 A^AuNi 88.00 89.67 90.69 90.88 90.97 AgAuMo 88.10 89.77 90.80 90.98 91.07 A^AuPd 89.00 90.69 91.72 91.91 92.00 AgAuAl 88.70 , 90.39 91.41 91.60 91.69 A^AuNb 88.60 90.28 91.31 91.50 91.59 AgRu 89.00 90.69 91.72 91.91 92.00 AgRuCu , , 88.45 90.13 91.16 91.34 91.44 AgRuTi / 88.34 90.02 91.04 91.23 91.32 AgRuCr 88.76 90.45 91.48 91.66 91.76 AgRuTa 88.23 89.91 90.93 91.12 91.21 AgRuNi 87.80 89.47 90.49 90.67 90.76 A^RuMo 88.44 90.12 91.15 91.33 91.43 AgRuPd •87.67 89.34 90.35 90.54 f 90.63 AgRuAl 88.97 90.66 91.69 91.88 ! 91.97 AgRuNb 87.9S 89.65 90.67 90.86 90.95 40NDA200104TW; P1P2000284TW 48 Install I (please read the note on the back) Fill in this page 11111111 f This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. INSTRUCTIONS (4^) In particular, titanium dioxide, bismuth pentoxide, chromium dioxide, indium trioxide, tin dioxide, antimony pentoxide, and magnesium oxide based films have high reflectivity and low absorption. Rate, as shown in Table 8 Representative of indium trioxide-penta pentoxide. Variations in the optical properties of the refractive index are prevented in these films. Table 8 I - . · 'Ιη203· 15wt%Nb2 ΙΠ·2〇3· 12.5\vt%Nb2 〇, I Π·2〇3· 10wt%Nb2 0, Ιϋ2〇3· 7.5wt%Nb, 0, Ιη203· 5wt%Nb205 Reflectance• Reflectance Reflectance<Reflectance. Reflectance 40 0 2.34 2.32 2.34 2.30 2.34 45 0 2.26 2.25 2.26 2:23 2.26 50 .0 2.22 2.21 2.21 2.18 2.20 55 0 2.19 2.18 2.18 2.16 2.17 56 0 2.19 2.18 2.17- 2.15 2.17 .^1 ϋ 1 1 Βϋ 1 一1, ii ϋ n (Please read the phonetic note on the back 3) (Insert this page) Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Printed Example 5 I Check Coverage The effect of the layer on the heat resistance and reflectivity of the reflective layer. Depositing a coating layer on the conventional silver reflective layer (pure silver or binary silver alloy) or the ternary reflective layer of the present invention, comprising indium trioxide as a main component and tin dioxide, antimony pentoxide, tin dioxide At least one of magnesium oxide and bismuth pentoxide to form a layer of the body. The laminate was tempered at 250 ° C, which is the temperature applied to the substrate during the manufacture of the liquid crystal display device. 40NDA200104TW; P1P2000284TW , 1 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Inventive Note (s〇) In the absence of a cover layer, the optical absorption of the reflective layer is Increased after tempering, which leads to the deterioration of the layer, as shown in Table 9. The experimental data of the optical absorption rate of the cover layer used for heat resistance are shown in Tables 10 to 12. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed without Cover Material Tempered as-depo Wavelength Wavelength Wavelength Wavelength • Wavelength Wavelength Wavelength Wavelength Wavelength 400.00 450.00 500.00 550.00 565.00 400.00 450.00 500.00 550.00 565.00 nm nm nm nm nm nm nm nm nm nm Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Port 1 Yield Absorption rate Absorption rate (%) (%) (%) 1 (%) (%) (%) (%) (%) (% (%) pure Ag 5.2 3.6 2.8 2.8 1.9 5 3.2 2.1 2.6 1.8 Ag?d 6.4 5.5 6.3 5.5 5.1 6.0 5.2 6.1 5.4 5.0 A^PdCu 6.6 5.7 6.5 5.8 5.5 6.5 5.6 6.2 5.7 5.1 A^PdTi 6.9 5.9 6.6 5.7 5.5 6.7 5.8 6.4 5.6 5.3 AgPdCr 6.8 5.9 6.5 5.7 5.3 6.6 5.8 6.3 5.5 5.0 AgPdTa 6.6 5.8 6.6 5.8 5.3 6.4 5.5 6.3 5.6 5.0 AgPdMo 6.8 6.9 6.4 5.5 5.5 6.6 6.7 6.3 5.5 5.2 AgPdNi 6.7 5.7 6.2 5.5 5.4 6.4 5.7 5.9 5.5 5.1 AgPdAl 6.6 6.6 6.4 5.5 5.2 6.5 6.5 6.2 5.5 5.1 AgPdNb 6.7 5.8 6.3 5.7 5.1 6.5 5.7 6.3 5.4 4.9 AgAu 6.3 5.3 6.2 5.3 5.0 6.0 5.1 6.0 5.2 5.0 AgAuCu 7.4 6.7 7.2 6.2 6.2 7.1 6.5 7.0 6.1 6.0 AgAuTi 6. 6 5.8 6.4 5.7 5.3 6.4 5.2 6.3 5.6 5.2 AgAuCr 6.8 5.9 6.6 5.8 5.5 6.7 5.8 6.4 5.6 5.3 AgAuTa 6.9 5.9 6.5 5.7 5.3 6.6 5.8 6.3 5.6 5.2 AgAuNi 6.8 5.9 6.3 5.7 5.4 6.5 5.8 6.1 5.6 5.2 AgAuMo 6.7 6.8 6.4 5.6 5.4 6.6 6.7 6.3 5.5 5.2 AgAuPd 7.5 6.3 7.5 6.3 6.2 7.1 6.1 7.0 6.2 6.0 AgAuAl 6.7 6.7 6.5 5.6 5.4 6.6 6.5 6.3 5.5 5.2 AgAuNb 6.8 5.9 6.4 5.7 5.2 6.6 5.8 6.3 5.5 5.0 AgRu 6.3 5.4 6.2 5.3 5.2 6.1 5.1 6.0 5.3 5.1 AgRuCu 6.8 5.9 6.4 5.7 5.2 6.4 5.5 6.3 5.6 5.0 AgRuTi 6.7 5.9 6.5 5.6 5.2 6.6 5.8 6.3 5.5 5.0 AgRuCr 6.7 5.9 6.6 5.7 5.3 6.5 5.7 6.3 5.5 5.0 AgRuTa 6.5 5.8 · 6.7 5.7 5.2 6.4 5.5 6.3 5.6 5.0 . AgRuNi 7.3 , 6.6 7.5 6.3 6.3 6.4 7.0 6.1 6.0 AgRuMo 7.3 6.8 7.3 6.2 6.2 7.1 6.3 7.1 6.1 6.0 AgRuPd 6.7 6.8 6.4 5.5 5.3 6.6 6.6 6.2 5.4 5.2 AgRuAl 6.8 6.9 6.4 5.6 5.3 6.6 6.7 6.3 5.5 5.2 AgRuNb 6.8 6.9 6.3 5.6 5.4 6.5 6.6 6.1 5.5 5.2 40NDA200104TW; P1P2000284TW 50 Pack ------- (Please read the note on the back first and then fill out this page) — — — — — — — — — 鳟本纸Zhang scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7

V. Description of the invention (sU Table 10

Si〇9/Ag Alloy Ministry of Economics Intellectual Property Bureau Staff Consumer Cooperative Printed Materials Si (X tempered SiO·; as*depo Wavelength 400.00 nm Wavelength 450.00 nm Wavelength 500.00 nm Wavelength 550.00 nm Wavelength 565.00 nm Wavelength 400.00 nm Wavelength 450.00 nm Wavelength 500.00 nm wavelength 550.00 nm wavelength 565.00 nm absorption rate (%) absorption rate (%) absorption rate (%) absorption rate (%) absorption rate (%) absorption rate (%): absorption rate (%) absorption rate (%) absorption Rate (%) Absorption rate (%) pure Ag 26.5 11.65 4.92 4.72 5.02 34.5 16.64 5.81 5.71 5.05 A^Pd 26.8 12.59 5.68 5.23 6.96 27.8 14.59 8.68 6.23 8.98 A^PdCu 27.09 13.06 8.94 6.77 6.28 35.8 18.64 11.91 8.74 8.Q5 A ^PdTi 36.5 17.54 11.45 8.58 7.59 36.8 17.68 11.85 8.76 8.00 A^PdCr 35.5 18.45 10.59 8.58 7.96 35.9 18.65 10.69 8.75 8.04 A^PdTa 36.1 18.44 11.34 8.50 7.58 36.2 18.54 11.54 8.54 8.02 A^PdMo 36.4 18.57 11.15 8.41 7.21 36.5 18.67 11.59 8.45 7.25 A^PdNi 35.78 18.21 11.07 8.29 7.37 36.29 18.55 10.94 8.25 7.11 AgPdAl 35.89 18.15 10.8 8.33 7.64 36.58 18.41 11.39 8.42 7.76 A^PdNb 35.88 18.13 10.86 8. 29 6.93 36.99 18.53 11.08 8.26 7.1 A^Au 26.2 12.31 5.50 5.10 7.99 27.7 14.45 8.52 6.12 8.85 A^AuCu 36,1 17.53 11.45 8.58 7.25 36.5 18.66 11.25 8.25 7.36 A^AuTi 35.4 18.40 10.59 8.58 7.96 36.3 17.67 11.80 8.73 8.00 A^ AuCr 36.0 18.32 11.34 8.50 7.58 36.2 18.64 10.25 8.75 8.04 AgAuTa 36.3 18.44 11.15 8.41 7.21 36.5 18.53 11.55 8.54 . 8.00 A^AuNi 36.0 18.31 11.32 8.50 7.58 36.4 18.66 11.20 8.41 7.25 . AgAuMo 36.0 18.35 11.58 8.50 7.58 36.8 17.65 11.84 8.73 8.00 AgAuPd 36.3 18.58 11.14 8.41 7.21 37.0 18.61 10.21 8.74 8.02 A^AuAl 36.1 18.24 11.05 •8.45 7.85 36.7 18.51 11.52 8.56 8.00 AgAuNb 36.1 18.25 11.11 8.41 7.14 37.1 18.62 11.21 8.41 7.24 A^Ru 26.5 12.45 5.55 5.25 7.96 27.7 14.59 8.75 6.35 8.99 A^RuCu 36.0 17.52 11.45 8.58 7.25 36.4 17.66 11.81 8.73 7.56 A^RuTi 35.3 18.49 10.59 8.58 7.96 36.2 18.64 10.24 8.75 7.35 A^RuCr 35.8 18.30* 11.34 8.50 7.58 36.1 18.52 11.55 8.54 8.00 . AgRuTa 36.2 18.42 11.15 8.41 7.21 36.4 18.65 11.21 8.42 7.52 A ^RuNi 36.1 18.35 11.33 8.50 7.5 8 36.9 17.64 11.84 8.71 8.01 A^RuMo 36.1 18.34 11.58 8.50 7.58 36.8 18.60 10.22 8.72 8.02 AgRuPd 36.2 18.59 11.28 8.41 7.21 37.1 18.50 11.51 8.51 7.96 AgRuAl 36.3 18.55 11.18 8.41 7.21 36.5 18.61 11.20 8.42 7.24 AgRuNb 36.5 18.24 11.11 8.41 7.21 37.2 18.41 10.12 8.85 8.12 40NDA200104TW; P1P2000284TW 51 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). Packing - I! (Please read the note on the back to fill out this page) £ 订-- ·# 1284746 A7 B7 V. Inventive Note (5X) Table 11 Ιη203-15Μ)205/Α$ Printed by the Intellectual Property Bureau of the Ministry of Economy and Economy

Hi-R 3 fire _ Hi-R as-depo material wavelength • wavelength wavelength wavelength wavelength wavelength wavelength wavelength wavelength 400.00 450.00 500.00 550.00 565.00 400.00 450.00 500.00 550.00 565.00 nm nm nm nm nm nm nm nm nm absorbance absorbance absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate Absorption rate (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) pure 13.27 3.48 2.57 2.35 2.25 19.84 7.03 3.21 4.28 4.24 A^Pd 15.77 5.34 3.93 3.90 3.802 22.15 8.83 4.57 5.80 5.78 AgPdCu 16.57 6.24 4.67 4.68 4.49 22.89 9.69 5.30 6.56 6.43 A^PdTi 19.1—7 9.16 7.64 7.65 7.47 25.29 12.51 8.25 9.47 9.35 A^PdCr 19.67 9.72 8.21 8.22 8.04 25.75 13.05 8.82 10.03 9.91 A^PdTa 19.77 9.84 8.33 8.34 8.15 25.85 13.16 8.93 10.14 10.02 A^PdMo 20.07 10.17 8.67 8.68 8.50 26.12 13.48 9.27 10.48 10.36 AgPdNi 19.85 10.07 8.42 8.47 8.31 26.01 13.37 9.01 10.33 10.22 AgPdAl 19.16 9.3 7.63 7.7δ 7.49 25.36 12.63 8.36 9.56 9.34 AgPdNb 19.25 9.38 7.73 7.87 7.6 25.46 12.74 8.46 9.66 9.54 A^Au 15.27 4.78 3.18 3.19 3.00 21.69 8.28 3.82 5.10 4.98 AgAuCu 15.61 5.16 3.57 3.58 3.39 22.00 8.65 4.21 5.48 5.36 A^AuTi 19.63 9.68 8.17 8.IS 7.99 25.72 13.01 8.78 9.99 9.8+7 A^AuCr 19.51 9.54 8.03 8.04 7.86 25.61 12.88 8.64 9.85 9.73 A^AuTa 19.77 9.84 8.33 8.34 8.15 25.85 13.16 8.93 10.14 10.02 A^AuNi 20.07 10.17 8.67 8.68 8.50 26.12 13.48 9.27 10.48 10.36 A^AuMo 19.97 10.06 8.56 8,56 8.38 26.03 13.37 9.16 10.37 10.25 A^AuPd 19.07 9.05 7.53 7.54 7.35 25.20 12.40 8.14 9.36 9.24 AgAuAl 19.37 9.39 7.87 7.88 7.70 25.48 12.72 8.48 9.70 9.58~ A^AuNb 19.47 9.50 7.98 7.99 7.81 25.57 12.83 8.59 9.81 9.69 A^Ru 19.07 9.05 7.53 7.54 7.35 25.20 12.40 8.14 9.36 9.24 9.9 AgRuCu 19.62 9.67 8.16 8.16 7.98 25.71 12.99 8.76 9.98 9.86 A ^RuTi 19.73 9.79 8.28 8.29 8.11 25.81 13.11 8.89 10.10 9.98 AgRuCr 19.31 9.32 7.80 7.81 7.63 25.42 12.66 8.41 9.63 9.51 A^RuTa 19.84 9.92 1 8.41 8.42 8.23 25.91 13.23 9.01 10.22 10.10. A^RuNi 20.27 10.40 8.90 8.91 8.73 26.31 13.70 9.50 10.70 10.58 . A^RuMo 19.63 9.68 8.17 8.18 7.99 25.72 1 3.01 8.78 9.99 9.87 A^RuPd 20.40 10.55 9.05 9.06 8.88 26.43 13.84 9.65 10.85 10.73 AgRuAl 19.10 9.08 7.56 7.57 7.39 25.23 12.43 8.17 9.39 9.27 A^RuNb 20.09 10.20 8.69 8.70 8.52 26.14 13.50 9.30 10.50 10.38 40NDA200104TW; P1P2000284TW 52 ----- ---Book---------· (Please read the notes on the back and fill out this page)

This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Invention Description (S3) Table 12 IT〇/Ag Alloy Economics Department Intellectual Property Bureau Staff Consumer Cooperative Print*Material IT〇 Tempered ITO as*depo wavelength 400:00 nm wavelength 450.00 nm wavelength 500.00 nm wavelength 550.00 nm wavelength 565.00 nm wavelength 400.00 nm wavelength 450.00 nm wavelength 500.00 nm wavelength 550.00 nm wavelength 565.00 nm absorption rate (%) absorption rate (%) V absorption Rate (%) Absorption rate (%), 丨 absorption rate (%) 'Absorption rate (%) Absorption rate (%): Absorption rate (%) 1 Absorption rate · (%) Absorption rate (%) Pure Ag 15.56 4.87 3.63 4.64 1.82 19.05 4.27 1.77 1.52 5.02 AgPd 18.06 7.69 6.49 7.47 4.73 21.55 7.23 4.81 4.57 7.95 AgPdCu 18.86 8.59 7.40 8.37 5.66 22.35 8.18 5.78 5.54 8.89 AgPdTi 21.46 11.52 10.37 11.31 8.68 24.95 11.26 8.94 8.71 11.94 AgPdCr 21.96 12.09 10.94 11.87 9.27 25.45 11.85 9.54 9.31 12.53 AgPdTa 22.06 12.20 11.05 11.99 9.38 25.55 11.97 9.67 9.44 12.65 AgPdMo 22.36 12.54 11.40 12.32 9.73 25.85 12.32 10.03 9.80 13.00 AgPdNi 22.1 4 12.42 11.15 12.11 9.54 25.74 12.21 9.77 9.65 12.86 AgPdAl 21.45 11.66 10.37 11.4 8.64 25.04 11.4 9.07 8.83 11.96 AgPdNb 21.54 11.75 10.46 11.53 8.82 25.14 11.52 9.19 8.92 12.14 AgAu 17.56 7.13 5.92 6.90 4.15 21.05 6.64 4.20 3.96 7.36 AgAuCu 17.90 7.51 6.30 7.29 4.54 21.39 7.04 4.61 4.37 7.76 AgAuTi 21.92 12.04 10.89 11.83 9.22 25.41 11.80 9.50 9.27 12.48 AgAuCr 21.80 11.91 10.76 11.69 9.08 25.29 11.66 9.35 9.12 12.34 AgAuTa 22.06 12.20 11.05 11.99 9.38 25.55 11.97 9.67 9.44 12.65 AgAuNi 22.36 12.54 11.40 12.32 9.73 25.85 12.32 10.03 9.80 13.00 AgAuMo 22.26 1^.43 '11.28 '12.21 9.62 25.75 12.20 9.91 9.68 12.88 AgAuPd 21.36 11.41 10.25 11.19 8.57 24.85 11.14 8.82 8.58 11.83 AgAuAl 21.66 11.75 10.60 11.53 8.92 25.15 11.49 9.18 8.95 12.18 AgAuNb 21.76 11.86 10.71 11.65 9.03 25.25 11.61 9.30 9.07 12.30 AgRu 21.36 11.41 10.25 11.19 8.57 24.85 11.14 8.82 8.58 11.83 AgRuCu 21.91 12.03 10.88 11.82 9.21 25.40 11.79 9.48 * 9.25 12.47 AgRuTi 22.02 12.15 11.01 11.94 9.34 25.51 11. 92 9.62 9.39 12.60 AgRuCr 21.60 11.68 10.53 11.47 8.85 25.09 11.42 9.11 8.88 12.11 AgRuTa 22.13 12.28 11.13 12.06 9.46 25.62 12.05 9.75 9.52 12.73 AgRuNi 22.56 12.76 11.62 12.55 9.96 26.05 12.56 10.27 10.04 13.23 AgRuMo 21.92 12.04 10.89 11.83 9.22 25.41 11.80 9.50 9.27 12.48 AgRuPd 22.69 12.91 11.77 12.70 10.12 26.18 12.71 10.43 10.20 13.39 AgRuAl 21.39 11.44 10.29 11.23 8.60 24.88 11.17 8.85 8.62 11.86 AgRuNb 22.38 12.56 11.42 12.35 9.75 25.87 12.34 10.05 9.82 13.02 .yH! 40NDA200104TW; P1P2000284TW 53 Pack -------- Order -- ------- f This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1284746 A7 B7 V. Inventive Note (se Table 11 shows the reflective layer together with the cover layer of the present invention, optics The absorption rate after tempering is much lower than that of the reflective layer without the cover layer. The In2〇3-15wt% Nb205 cap layer of the present invention in Table 11 has a lower absorption rate than the ceria cap layer in Table 10 and the ITO cap layer in Table 12. Table 13 shows the optical properties of the three-layer laminate including the base film, the reflective layer, and the cover layer after tempering at about 250 ° C. Similar to those shown in Tables 9 to 12, the adhesion of the laminate is also the same. The laminates in Table 6 are just as good. The three-layer structure laminate is excellent in both optical properties and adhesion. The optical properties of the three-layer laminate are not deteriorated by the use of the cover layer. Conversely, when a cover layer is used which includes indium trioxide as a main component and -30 wt% of Nb2O5, the reflectance is increased by 1-6. %, and the absorption rate is reduced after tempering at about 250 ° C. Table 14 shows that even with a thinner cover layer, a more improved reflectance and good optical properties can be obtained. ___________%Year-- !- (Please read the note on the back and fill out this page) « — — — — I — • il. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Print 40NDA200104TW: P1P2000284TW 54 This paper size applies to China Standard (CNS) A4 specification (210 X 297 mm) 1284746 A7 B7 V. Description of invention (ss) Table 13 Absorption rate (〇/〇) · Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative

In90.r5wt% Nb2〇^1Unheated_ 2 150 〇C 3 300°C 566 10.88 10.24 15.3 564 10.67 10.04 15.06 550 9.38 8.829 13.6 500 7.104 7.071 8.297 450 13.42 14.38 7.922 400 26.96 27.49 19.93 In?O, r10wt% Nb2 〇5 1 not heated 2 150 〇C 3300 °C 566 11.13 12.39 13.11 564 10.91 12.16 12.88 550 9.639 10.71 11.42 500 7.113 7.166 7.236 450 12.72 11.8 9.97 400 27.29 26.6 24.28 In?0.r15wt°/〇Nb〇Os (D not Heating 2150 〇C 3300 〇C 566 15.97 18.42 20.29 564 15.74 18.17 20.04 550 14.32 16.69 18.63 500 9.059 10.57 12.36 450 7.363 7.168 7.21 400 17.19 16.56 13.33 40NDA200104TW; P1P2000284TW 55 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ^------ (Please read the note on the back first: W: fill out this page) Order --------- · # A7 5128746 ____B7 _____' Description of the invention Table 14 Change In20 , Nb205 cover layer thickness after reflection layer reflectivity change degree 5 nm 49 nm 1 70 nm 74 nm A inm] heating before heating, heating before heating, heating before heating, heating after heating 1 556 92.99 91 85.61 8S.6S 83.15 91.32 95.27 554 92.91 90.85 85.62 88.69 83.18 91.29 95.28 552 92.84 90.74 85.63 88.67 83.2 91.39 95.28 ^ 550 92.92 90.74 85.69 88.72 83.35 91.5 95.33 500 90.88 87.82 85.22 88.37 83.56 91.47 95.13 450 85.71 79.83 82.88 85.02 80.93 87.77 93.56 400 74.72 70.22 80.63 84.96 79.47 85.35 83.23 85 : nm 90 : nm 100 nm λ Before heating, after heating, before heating, before heating. After heating 556 86.8 93.4 S1.44 91.28 83.36 91.97 — 554 86.78 93.36 81.47 91.29 83.3 91.97 552 86.81 93.37 81.5 91.39 83.31 92.04 _ 550 86.89 93.43 81.61 91.52 83.39 92.14 500 86.02 92.9S 81.96 92.18 81.36 92.04 450 81.58 88.19 78.5 88.9 71.91 87.01 400 74.11 81.17 6S 82.7 39.88 70.18 (Please read the notes on the back and fill out this page)

The above-described embodiments and the specific embodiments of the invention are not limited to the details, and may be modified without departing from the scope of the appended claims. And within the equality.

40NDA200104TW; P1P2000284TW This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm)

Claims (1)

1284746. VI. Patent application scope A8 B8 -Cl· D8 Announcement 95. 1.6 Replacement page 2006/1/6 Case No. 90107568 Patent application scope 1. A reflective layer containing: .... ' * : / Silver, as the main component ; . . . . One. One element: elemental gold, ·Occupy: 0:.1 to 3:0% by weight.; and '. •• One Taxis element, accounted for · 0 · 1 to 3: 0 weight ·Divided, · and selected from the group consisting of: copper, titanium, tungsten, tungsten, tungsten, nickel, bismuth, and sulphide. · 2, • Root 'According to the patent application.. Range / item 1 of the reflective layer:,. The reflective layer system. · , , · .... ♦ * · • formed by broadcast '· ·,; ·········' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _,···· . : . . . . . . 4 . A layer of mirror i,.铒杳.:· : . ·· _··. ' ' A base i and ·: \ • · ·:, ··· . . . . _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ And a second element, which is from 0.1 to 3.0% by weight, and is selected from the group consisting of copper, titanium, chromium, ruthenium, molybdenum, nickel, ruthenium and iridium. Bureau of Industry and Commerce Consumers Co., Ltd. 5. A laminate according to item 4 of the patent application, wherein the substrate is a resin substrate. 6. The laminate according to item 4 of the patent application, wherein the substrate is a glass substrate. 7. A laminate comprising: a substrate; '' a base film deposited on the substrate, wherein the base film is made of 矽, 巨, * · 40NDA200104TW; P1P2000284TW 57 This paper scale applies to the Chinese National Standard (CMS) A4 size (210 X 297 mm) A« B8 C8 D8 1284746. VI. Patent application replacement page 2006/1/6 Case number 90107568 Titanium, molybdenum, chromium, aluminum, ITO, zinc oxide, cerium oxide, titanium dioxide, At least one of bismuth pentoxide, zirconium dioxide, indium trioxide, tin dioxide, antimony pentoxide, or magnesium oxide; and a reflective layer comprising silver deposited on the base film The reflective layer comprises: silver, strontium as a main component; ^, - · · , a first - 兀 prime gold, 〇 1 1 to 3. 〇 weight percentage; and • ·: V.. a second _ ,: Ό.Ό. to .3.0 weight. Percentage, and is selected from the group consisting of · · · · , - . · Copper,: edge:, :: network,: sale:, group, nickel,鈪, and 钌 group. ... . . . . . . . . . . . . according to the scope of the patent scope of the '7, the m contains a cover layer ..... ... · ' . On the reflective layer, wherein the cover layer comprises indium trioxide as a main component, and tin dioxide, tantalum pentoxide, ruthenium dioxide, ..... . . . At least one of magnesium oxide and bismuth pentoxide. 9. The laminate according to claim 7, wherein the substrate is a glass substrate. The laminate according to the seventh aspect of the patent application, wherein the base film is made of at least one of bismuth, giant, titanium, molybdenum, chromium or aluminum. 11. The laminate according to claim 7, wherein the base film is made of ITO, zinc oxide, cerium oxide, titanium dioxide, bismuth pentoxide, cerium oxide, indium oxynitride, tin dioxide, and five. Made of at least one of bismuth oxide or magnesium oxide. 12. The laminate according to claim 11, wherein the substrate is a resin substrate. 13. - Laminated body, comprising: a reflective layer comprising silver, containing silver as a main component; a first 40NDA200104TW; P1P2000284TW This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Note S t Page Economy · Ministry of Education, Bureau of Staff and Workers, Consumer Cooperatives Printed 58 A8B8C8D8 1284746 VI. Application for Patent Range Replacement Page 2006/1/6 Case No. 90107568 Elemental gold, accounting for .0.1 to 3..0 weight percent; a second element, from 0. Ί to 3.0% by weight, and selected from the group consisting of copper, titanium, chromium, group, molybdenum, nickel, niobium, and tantalum; and two haze: on the reflective layer The cover layer, wherein the cover layer comprises three · · · oxygen · · · =: indium as a whole component ·, and nickel dioxide, bismuth pentoxide ·, - ········· · · Dioxin · · Magnesium oxide is at least one of bismuth pentoxide. • ·- . . . . . . . . . . . . . . . . . . . . . . : Patent: Range 4, 7, 7 or 13: The layered body, where the • · ········. .·························································································· .··· ·································································璋>......····:,.. • t · . * , * 16. —Liquid crystal display device, according to the patent application No. 4 to 7, with . . . . · · · · - and 10 to Π. The laminated body of any one of them. ·,. 17. ·- Portable terminal installation i, with the application of patent scope 1, 5 or 16 Liquid crystal display device. ' . 18. —Reflecting 麿, containing: silver, as the main component;. • * · · Printing a first element of palladium by the Intellectual Property Office Staff Consumer Cooperative, accounting for 0.1 to 3.0 weight percent; And a fifth element, which is from 0.1 to 3.0% by weight, and is selected from the group consisting of giant, molybdenum, nickel, niobium, and tantalum. 19. a layer of integrated body comprising: a * substrate; and a reflective layer, Deposited on the substrate, Wherein the reflective layer comprises: silver as a main component; 59 40NDA200104TW; P1P2000284TW The paper scale applies to the Chinese National Standard (CNS) A4 gauge (210 X 297 mm) A8 B8 08 D8 1284746 Printed by the Intellectual Property Office of the Ministry of Economic Affairs, Employees' Consumption Cooperatives _ Patent Application: Replacement Page 2006/1/6 Case No. 90107568 A first element of palladium, accounting for 1 to 3 〇 weight percent; and a second element, accounting for 0 • 1 to 3.0 parts by weight, and selected from the group consisting of ': - t sister, molybdenum, nickel, ruthenium, and osmium. .20. One product: body, · contains ·, ···'. • ; · A base warm T· deposited on the base, where the base is made of 矽, 钽, $目<_ Ming_:,, ιτο, Zinc Oxide: V2O2, · Titanium Dioxide, V. · · · · · · · · · · · · · Oxygen: Li suspected > :?:: Oxidation cone bismuth trioxide , tin oxide ·, pentoxide · ···· · ··· · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · , ., . . . . . . . . ·, · * Silver, 祚 祚 主# component;.:::_.··,·... * .········ . . . • -:_.··· . . . . . . , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . From 0! Γ to 3:0 weight percent, and is selected from the group consisting of /·.丨_ _.钽, molybdenum: nickel, ruthenium, osmium and iridium. . . . • 21·—The hoarding body, containing: .'· A silver-containing reflective layer containing silver as a main component, a first element of palladium, 〇·1 - 3·〇 by weight, and a a two-element, which is from 1 to 3.0% by weight, and is selected from the group consisting of molybdenum, molybdenum, nickel, niobium, and tantalum; and " a cover layer deposited on the reflective layer, wherein The cover layer contains indium trioxide as a main component, and at least one of tin dioxide, tantalum pentoxide, silica sand, magnesium oxide, and tantalum pentoxide. 22. — Reflective layer, containing: · Silver, as the main seed; * 40NDA200104TW; P1P2000284TW 6 〇 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) A8 B8 C8 D8 1284746 Six: ·! ···11..·' .1.·.:·· · · · ·__ ••\ Person.·/ J ^ ^ ^ ^ ^ ^ ^ Patent Application: Replacement Page 2006/1/6 Case No. 90107568 a first element lanthanum, accounting for 0.1 to 3.0 weight percent; and a second element, accounting for 0.1 to 3.0 weight percent, and is selected from. Included " * : / copper, chromium, lanthanum, molybdenum, nickel, aluminum Groups of 铌, 金, gold, and palladium. .23·Two threats: · Body, · Contain ··: :·:: · · · · · ·:··············································· , wherein the reflective layer comprises: silver. '·· as the main component, / ·. . . · · · · · · · · · · · · · · A: U • stupid: rainbow ', accounted for .. QV to 3.0% by weight; 'and.······. ' · · ·.. an estimate: 0, 1 ' to 3: 0 weight percent, and is selected from the group containing _ ·..·.. ······ · _ .· ,······ · Groups of copper, chromium/macro, molybdenum, nickel, aluminum: tantalum, gold, and palladium. · - · · · . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ··· · · · - - a base film, sinking on the substrate, wherein the base film is made of yttrium, .. molybdenum, ' · · · · · · molybdenum, chromium: aluminum, iT 〇, Made of at least one of zinc oxide, cerium oxide, titanium dioxide, bismuth pentoxide, zirconium dioxide, indium trioxide, z: tin oxide, antimony pentoxide, or magnesium oxide; and a silver anti-fe layer deposited on the base film, the reflective layer comprising: .β . . silver as a main component; # . , a first element 钌: 0.1 to 3.0% by weight; and a second element , from 0.1 to 3.0% by weight, and selected from the group consisting of copper, chromium, giant, molybdenum, nickel, aluminum, ruthenium, gold, and palladium. 25. —Lamination/contains: A silver-containing reflective layer containing as a main component silver, a first element 钌, accounting for 0.1萆3·〇 by weight; and 40NDA200104TW; P1P2000284TW 61 This paper scale applies to Chinese national standards XCNS) A4 size (210 X 297 mm) 1284746 880Q99 ABaD. VI. Patent application area replacement page 2006/1/6 Case number 90107568 A second element, accounting for 0.1. to 3.0% by weight, and selected from copper , chrome, group, molybdenum, nickel, aluminum, bismuth, gold, and · group; ': . / . and U - hoarding: the covering layer on the reflective layer, wherein the covering layer contains three. · · · Indium oxide as a main component, ··· and two-loaded tin, antimony pentoxide, cerium oxide: 敬·., magnesium oxide, at least one of molybdenum pentoxide. * · · * · · ..·:····································································· : The 靡射: 层:... ... · . ··; V :.;:··· · ' : v · · : . . · · ... 27. - LCD Μ 装置 具有 具有Patent scopes 19 to 21, * *. · . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2S. — Portable display device. It has a liquid crystal display device according to Shen Xiao's patent scope 26 or • t * . * : · * 27 .. / · • ' .:···· .. .... ·· 29. 29.--Reflective layer ·, ·Reflected for architectural glass or liquid crystal display device. Body or reflective wiring electrode, containing: . Silver, as the main component; 'One first The element, which is 0.1 to 3.0% by weight, is selected from the group consisting of gold, palladium, and deficient; and **j, a second element, which is 0.1 to 3.0% by weight, and is selected from the group consisting of copper, chromium, and giant. a group of molybdenum, nickel, aluminum, lanthanum, gold, palladium, and lanthanum, wherein the second element is different from the first element ·, and the surface of the reflective intellectual property bureau employee consumption cooperative printed on the surface after heating at 250 ° C, there is no visually dull white '. · * 'color change. 30. — layered body, used for architectural glass Or the reflector or reflective wiring electrode of the liquid crystal display device, including: 62 40NDA200104TW; P1P2000284TW This paper scale is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1284746. 6. Patent Application Replacement Page 2006/ 1/6 Case No. 90107568 a substrate; and a reflective layer hoarded on the substrate, wherein the reflective layer comprises: • · · · t · ·- silver, as a main component; · · · ··· . First: the element, which accounts for il· to 3.0% of the child, and is selected from the group consisting of: gold, palladium, and bismuth: ·;, and ·Λ • _ ·····.- · · One: !! Alizarin, which accounts for 0,1 to 3.0% by weight, and is selected from the group consisting of • ························································ Group, • True: Medium: Kill Qin 3: Beam Suspension · Same as the first element, and the reflection ·. The heat of the layer: 25〇π; ί, visually no dull white _ _ · .. . . . . . . . . . . · · '..·*' , . ' . . 31. —Lamination, for building glass or liquid crystal. Display I device. Reflector or .. reflective wiring electrode, including: ' .. .. ································································································ , at least one of aluminum, ITO, zinc oxide, cerium oxide, titanium dioxide, bismuth pentoxide, zirconium dioxide, indium trioxide, tin dioxide, bismuth oxide, or magnesium oxide. Cheng; and·· « . A reflective layer containing silver is printed on the base film by the Intellectual Property Bureau employee consumption cooperative. The reflective layer contains: silver as the main component; a first element, accounting for 0.1 to 3.0 % by weight, and selected from the group consisting of gold, palladium, and rhodium; and 'a second element, from 0.1: to 3.0 weight percent, and selected from the group consisting of copper, chromium, giant, molybdenum, nickel, aluminum, a group of 铌, gold, palladium, and 钌, wherein the second element is different from the first element, and the reflection • ·: 40NDA200104TW; P1P2000284TW 63 The paper size applies to the Chinese National Standard '(CNS) A4 Specification (210 X 297 mm) A8B8C8D8 1284746 ./, Patent Application Range: Replacement Page 2006/1/6 Case No. 90107568 The surface of the layer is heated 25 After 〇°C, there is no visually dull white change. .: ..:· • : - ·· · 32· —Laminated body, used for reflectors or repellency of architectural glass or liquid crystal display devices: ·Connecting electrodes.., including::' ... * - · · · 'The reflection layer of a pack of males: silver containing ·············································· Self-contained: Gold?·(, Pavilion (3⁄4釭之 group: 啩; Friend: A g-g靡? % 0· 1: to: 3:0 weight percent V and selected. Self-contained copper, Ming Qin' : 满··· Mirror:, .ig, 铌;, gold, palladium, and 钌 group, where the second element is not confined to the first element, and the surface of the reflective layer is at _ ♦ 25 〇 ° C Thereafter, there is no blur (dull) white color change; and...,, .* - * * ········. a cover layer deposited on the reflective layer, wherein the cover layer Package: containing three indium oxide as a raw material, and at least one of tin dioxide, antimony pentoxide, antimony oxide, magnesium oxide and molybdenum pentoxide. 33·-liquid crystal display device, Has the reflection according to item 29 of the patent application scope - 34. A liquid crystal display device having the laminate according to any one of claims 30 to 32. 35 - a portable terminal device having a basis according to claim 33 or 34 Liquid crystal display device 64 40NDA200104TW; P1P2000284TW This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)