TWI283634B - Method for manufacturing a permeable web - Google Patents
Method for manufacturing a permeable web Download PDFInfo
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1283634 五、發明說明(1) ------ 本發明係有關於一種透氣通孔材料及其製造方法,特別是 有,於一種具有不織布(Non—woven)層之透氣通孔及 其製造方法。 發明背景 由於透氣通孔材料之應用很廣,因此目前已開發出多種利 用不同材質或技術而製成之透氣通孔材料。一 ^傳統所採 用之技術,例如使用壬相容之材料,並將 利用萃取方式將不相容材料中之某一成分材後以^ 此膜中產生複數個孔洞,而形成通孔的透氣結構。然而, 運用此技術所製造之透氣通孔薄膜,其製程較複雜且涉及 使用不環保的遂^,沒完全萃取出之殘餘添加物對後續應 用可能形成為不必要的污染源,再者通孔透氣性結構不易 控制,於透氣膜製程上於成型後,於後段工程上就無法再 另外’ 一種習知技術則係在製程中,將氧化鋁(A 1 203 )、 碳酸鈣(CaC03)、或氧化鈦(Ti02)等数惠添加劑均勻 地摻入有機高分子材料,例如聚乙烯(p〇lyethylene; PE) 及或聚丙烯(Polypropylene; PP),中,再利用例如擠壓 射出或延伸拉張機拉伸等方式製成薄膜,利用多相材料結 構不相谷原理’製造上於加工溫度接近材料軟化點時,進 行薄膜拉伸之加工處理。雖然,運用此技術能製造出具有1283634 V. INSTRUCTION DESCRIPTION (1) ------ The present invention relates to a venting through-hole material and a method of manufacturing the same, and more particularly to a venting through-hole having a non-woven layer and its manufacture method. BACKGROUND OF THE INVENTION Due to the wide variety of applications of vented through-hole materials, a variety of vented through-hole materials have been developed which utilize different materials or techniques. A technique conventionally used, for example, the use of a compatible material, and the use of an extraction method to produce a plurality of holes in the incompatible material to form a plurality of holes in the film to form a through-hole permeable structure . However, the ventilated through-hole film manufactured by this technology has a complicated process and involves the use of environmentally-friendly 遂^, and the residual additive which is not completely extracted may form an unnecessary source of pollution for subsequent applications, and the through-hole is ventilated. The structure is not easy to control. After forming on the gas permeable membrane process, it can not be used in the latter stage of engineering. Another conventional technique is in the process of alumina (A 1 203 ), calcium carbonate (CaC03), or oxidation. Titanium (Ti02) and other additives are uniformly incorporated into an organic polymer material, such as polyethylene (PE) and or polypropylene (PP), and then used, for example, by extrusion or stretching. The film is formed by stretching or the like, and the process of film stretching is performed when the processing temperature is close to the softening point of the material by the principle of non-phase of the multi-phase material structure. Although, using this technology can make
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五、發明說明(2)V. Description of the invention (2)
目前, 缔材料 卻輪上 於具有 為提昇 織網布 其上製 透氣通 喷等方 或聚對 合方式 透氣通 於織網 工過程 制不易 織布的製程大 下自擠壓射出 最後厚度之不 ,於製程上其 持透氣特性, 質當作承載材 薄膜。請參照 構的剖面圖。 方式將融熔聚 乙酯(PET)等才 網布層1 2而成 構。此透氣通 力強度不足, 用而有延伸變 大小不一、及 微小孔洞之透氣通孔薄膜, 時品質控制不易、薄膜之孔 質不穩定等缺點,另外該類 也疋應用上不純物污染源, 氣材料結構,會因材料上需 厚度不均現象且掉粉現象更 市場上之不 於融熔狀態 ’再壓製成 兩度延伸性 性且保 等透氣性材 成透氣通孔 孔材料之結 式,藉融噴 苯二甲酸二 ’噴塗於織 孔材料之結 布層1 2之張 張力拉伸作 、孑L洞尺寸 但其具有製造成本過高、加工 洞大小難以控制、以及薄膜品 粉末添加劑於應用過程之掉落 且右欲製成具有南透氣率之透 要高度延伸而有伴生斷膜與膜 嚴重現象。 ' 織布成品’此一不織布由 張〜力控制就非常之重要, 尚有一種利用類纖維布或 料層,將不織布材料融喷 第1圖,其所繪示為習知 此透氣通孔材料将 r 7寸货、利用融 乙烯(PE)、聚内烯( 十料或使用單一材料 一不織布層10,而完 孔材料雖然會透氣 在 因此於加工過程2总但由 形現象、其張力I易雙加 加工操作性差等缺點r 發明目的及概述:At present, the material of the association is on the wheel, and the process of making the ventilating and venting of the woven mesh cloth or the merging method is not easy to woven. It has a gas permeable property in the process and is used as a carrier film. Please refer to the sectional view of the structure. The method is to form a mesh layer 12 such as melted polyethylene (PET). The ventilating strength is insufficient, and there are disadvantages such as ventilated through-hole film with different lengths and small holes, difficult quality control, unstable pore quality of the film, and the like, and the application of the impurity source, gas material. The structure will be due to the uneven thickness of the material and the phenomenon of falling powder is not in the melt state on the market', and then pressed into a two-degree extension and the gas-permeable material is formed into a venting through-hole material. The melt-spray phthalic acid is sprayed on the knot layer of the woven material, and the tension of the layer is stretched, and the size of the 孑L hole is too high, the manufacturing cost is too high, the processing hole size is difficult to control, and the film powder additive is applied. The process falls and the right is made to have a high degree of extension of the south air permeability and a serious phenomenon of accompanying film and film. 'Weaving finished product' This non-woven fabric is very important to be controlled by Zhang ~ force. There is still a kind of fiber-like cloth or material layer to melt the non-woven material. Figure 1 shows the conventional venting through-hole material. R 7 inch goods, using ethylene (PE), polyene (six materials or using a single material - non-woven layer 10, while the hole material will be permeable, so in the process 2, but by the shape phenomenon, its tension I Disadvantages of easy double processing and poor processing operability r Purpose and summary of the invention:
1283634 五、發明說明(幻 "' __ 鑒於上述之發明背景中,習知透氣通孔材料呈 變化大、張力控制不易且製程加工不易等缺點, 明提供一種具有較強之機械抗張強度且加工方 =^ ^ 孔材料與製造方法。 透氣通 本發明的主要目的之一係提供一種複合透氣通孔材料盘 造方法,其係利用淋模、塗佈、輾壓等技術綜合應用&於 基材層上形成一通孔透氣性結構材料層,接續再爿2藉融喷 技術之不織布層依據不同之需求,而形成於此基材之一表 面或是上、下兩表面。因此,本發明之複合透氣通孔材料 具有高抗張力,且具吸震及吸音等特性。 本發明之再一目的係提供一種透氣通孔材料,其係在一具 有表揮之基材上形成不織布層,其中此基材之纟且成可依據 不同之需求而有多種選擇,此基材可以是塑性材料層,例 如高分子材料,如聚酯類(polyester)、聚乙稀 (polyethylene, PE)、聚丙烯(polypropylene, PP)、乙 烯苯乙烯共聚合物(ethylene-styrene copolymer,ES)、 環狀烯共聚合物(cyclo olefin)、聚對苯二甲酸二乙酯 (polyethylene terephthalate, PET)、聚乙烯醇 (polyvinyl alcohol, PVA)、乙浠乙酸乙酉旨 (ethylene-vinyl acetate, EVA)或 SurlynTM (Dupont i onomer離子型高分子化合物之商標名)、聚乙二醇對萘二1283634 V. Invention Description (Fantasy "' __ In view of the above-mentioned invention background, the conventional venting through-hole material has the advantages of large variation, difficulty in tension control, and difficulty in processing, etc., and provides a strong mechanical tensile strength and Processing side = ^ ^ hole material and manufacturing method. Ventilation One of the main purposes of the present invention is to provide a composite venting through-hole material disk manufacturing method, which utilizes a combination of techniques such as showering, coating, rolling, etc. A through-hole gas permeable structural material layer is formed on the substrate layer, and the non-woven fabric layer of the melt-spraying technology is formed on one surface or the upper and lower surfaces of the substrate according to different requirements. Therefore, the present invention The composite venting through-hole material has high tensile strength and is shock absorbing and sound absorbing. A further object of the present invention is to provide a venting through-hole material which is formed on a substrate having a veneer, wherein the substrate is formed. Then, the substrate can be variously selected according to different needs. The substrate can be a plastic material layer, such as a polymer material, such as polyester (polyester), polyethylene (p). Olyethylene, PE), polypropylene (PP), ethylene-styrene copolymer (ES), cycloolefin, polyethylene terephthalate , PET), polyvinyl alcohol (PVA), ethylene-vinyl acetate (EVA) or SurlynTM (trade name of Dupont i onomer ionic polymer compound), polyethylene glycol to naphthalene
第7頁 1283634 五、發明說明(4) 甲酸酉旨(polyethylene naphthalate,PEN)、聚醚酮(poly ether ether ketone, PEEK)、聚碳酸酉旨(polycarbonate, PC)、聚楓(polysulfone)、聚亞醮胺(polyimide,PI)、 聚丙浠氰(polyacrylonitrile, PAN)、苯乙烯丙烯氰共聚 合物(styrene acrylonitrile, SAN)、聚胺醋 (polyurethane,PU)、合成紙(synthetic paper,南亞公 司產。口)、5^稀煙類含浸纖維膜(polyolefin impregnated f iber web)、玻璃紙(giassine paper)、紙等。本發明中 膜之材質可以採用具有透明性或者是半透明甚至是不透明 之材質等單層材料或由其中組合而成之多層複合材料,或 可為塑膠材料/紙之组合、趟腺好祖/ ^ Μ Γ 塑膠材枓/玻璃纖維布或可為塑 膠材料/金屬之組合,其中斑金屬式i 曰的,力私姐糾# β ,、盒屬或其他導電材料組合的Page 7 1283634 V. INSTRUCTIONS (4) Polyethylene naphthalate (PEN), polyether ether ketone (PEEK), polycarbonate (PC), polysulfone, poly Polyimide (PI), polyacrylonitrile (PAN), styrene acrylonitrile (SAN), polyurethane (PU), synthetic paper (produced by South Asia) . mouth), 5^, thin tobacco impregnated f iber web, giassine paper, paper, etc. The material of the film in the present invention may be a single layer material having a transparency or a translucent or even opaque material or a multilayer composite material composed of the same, or a combination of a plastic material/paper, a scorpion granule/ ^ Μ 塑胶 Plastic 枓/glass fiber cloth or a combination of plastic material/metal, in which the plaque metal type i 曰, 力私姐纠# β , , box or other conductive material combination
目的 在於^ 5亥透氣通孔複合不继t _I_L (static η 織布材料具有靜電消散 (stat1C charge dlsslpation)、熱傳 conduction and dissipati〇n)與電The purpose is to ^ 5 Hai vent through-hole composite non-continuous t _I_L (static η woven fabric material with static dissipation (stat1C charge dlsslpation), heat transfer conduction and dissipati〇n) and electricity
Shi⑴ing)的功能,較常用之金屬電材磁料皮干擾遮蔽⑽! 發明之複合透氣通孔材料的 金屬。由於本 因此應用極廣。 ^ J依所需,靈活變化, 複合透氣通孔材料之透氣通孔基 ^動化需求下尤其以前者 土必杭一 ‘ 平乂具經濟效益,其中之對 4 輪組或對壓平台組中之一輪或一;:、r濟 狀結構(圖中未示),此尖 2 D之表面具複數 得:(1)以電鍍方法脸古π 士狀Γ構可藉由下述方法 壓設備可以採用連續式對壓輪組或製程所需之振 式,於自動化需求下尤其以箭去:批:人式對壓平台組方 壓 表面具複數個尖 製 突 匕括天然或人造合成鑽 將高硬度材質包括I扯Shi (1) ing) function, more commonly used metal electrical material magnetic material interference interference (10)! The metal of the composite breathable through-hole material of the invention. Because of this, it is extremely widely used. ^J, according to the needs, flexible change, the ventilated through-hole foundation of the composite venting through-hole material, especially in the former, the soil will be a 'flat 乂 economic benefit, which is in the 4 wheel set or the pressure platform group One wheel or one;:, r-shaped structure (not shown), the surface of the tip 2 D has a plurality of: (1) by the plating method, the surface of the π-shaped structure can be pressed by the following method The continuous vibration type required for the pressure wheel set or the process is especially for the arrow under the automation requirement: batch: the human pressure platform has a plurality of pointed protrusions including natural or synthetic synthetic drills. Hardness material includes I pull
1283634 五、發明說明(5) 石、氣化爛(Borazon,CBN)或碳化矽等多面體顆粒粉末或 高硬度之類似顆粒粉末均勻鍵著於表面上;(2)以雷射切 割方式將硬質高分子、金屬或陶竟材料雕刻(engraving) 而成具有均勻複數尖突狀結構之輾壓面,例如雷射切割而 成之陶竟anilox roll輪子;(3)利用機械壓型(t〇〇Hng) 加工方式’將一適當硬度之金屬表面壓型成所需之表面均 勻尖凸結構,隨後再施以表面硬化處理(hardening treatment)而成最後所需之輾壓面;(4)將一金屬表面進 行化學電解蚀刻成均勻尖凸結構後,再進行表面硬化處理 成硬質輾壓面。另外與輾壓輪相對應之對壓輪或對壓面材 料可以是具適當硬度之金屬、塑鋼或陶瓷等材料。如上面 所述無論使用電鍍鑽石輪、機械壓型(tool ing)加工輪或 |表面雷射雕刻之輾壓輪’此藉輾壓加工製程使得透氣通 孔基材層上具有複數個永久透氣通孔結構。此處可依實際 需求,使該被輾壓基材層上具有所需之透氣通孔大小與密 度以符合其透氣特性’其中可藉選擇適當材料與配合不同 之輾壓輪、輾壓機構與條件而得一最佳組合,此處本發明 之被輾壓基材層上也可以因實際需求具有不同之輾壓透氣 通孔分佈設計,例如可為全面性分佈、局部區域性分佈、 規則性分佈、或者是不規則性分佈。為消除該通孔結構材 料層之土憶效應例如局分子材料於被輾壓後其通孔結構於 受輾壓變形伴生之殘餘應力,可於輾壓輪組中提高外加輾 歷溫度使通孔結構附近伴生之殘餘應力得以消除且結構上 得以永久變形’材料結構也較穩定其透氣通孔品質亦較穩1283634 V. Description of invention (5) Polyhedral granular powder such as stone, gasified rotten (Borazon, CBN) or tantalum carbide or similar powder of high hardness is uniformly bonded to the surface; (2) hard high by laser cutting Molecular, metal or ceramic material engraving into a rolling surface with a uniform complex cusp structure, such as a laser-cut ceramic anilox roll; (3) using mechanical compression (t〇〇Hng The processing method 'forms a metal surface of a suitable hardness into a desired uniform surface convex structure, and then applies a hardening treatment to form the final desired pressing surface; (4) a metal After the surface is chemically etched into a uniform pointed structure, the surface is hardened to a hard surface. In addition, the pressing wheel or the pressing surface material corresponding to the rolling wheel may be a metal, plastic steel or ceramic material having a suitable hardness. As described above, whether using an electroplated diamond wheel, a mechanical stenciling wheel or a surface laser engraving squeezing wheel, the embossing process has a plurality of permanent venting through-hole structures on the permeable through-substrate substrate layer. . Here, according to actual needs, the pressed substrate layer has the required venting through-hole size and density to conform to its gas permeable characteristics, wherein the pressing wheel and the rolling mechanism can be selected by selecting appropriate materials and combinations. The optimal combination of the conditions, the laminated substrate layer of the present invention may also have different rolling venting through-hole distribution design according to actual needs, for example, comprehensive distribution, local regional distribution, regularity Distribution, or irregularity distribution. In order to eliminate the earthy effect of the through-hole structural material layer, for example, the local molecular material is subjected to the residual stress associated with the rolling deformation after being pressed, and the external temperature can be increased in the rolling wheel set to make the through hole The residual stress associated with the structure is eliminated and the structure is permanently deformed. The material structure is also stable, and the quality of the venting through hole is also stable.
第9頁 1283634 五、發明綱⑹ ' ,’至於材料之實際使用時機與應用機構,則端視複合透 氣通孔材料最後應用場所而定。 依據上述目的,本發明更提供了一種透氣通孔材料之製造 方法,此方法至少包括:提供一具有塑性之基材;輾壓此 ^材,藉以在此基材上形成複數個孔洞,而形成透氣通孔 結構;以融噴方式在基材之表面形成不織布層;最後再輾 壓此基材及不織布層之複合結構,以獲得所需之最後厚度 或密度。 & 其中’為了使融喷不織布層更易附著在透氣通孔基材層表 面’可先對透氣通孔基材層表面進行處理,例如以凹版塗 佈輪(Gravure Coater)、繞線棒塗佈輪(Meyer bar)、噴 塗(Spray Coater)將適當之黏著性改質劑(adhesi〇n promoter, primer),例如偶合劑(coupling agent)、螯 合劑(chelate)或架橋劑(crossiinking agent)等塗佈在 此透氣通孔基材層上以提昇此透氣通孔基材層的黏著性, 或製程上利用連線表面處理設備,於融喷不織布材料層至 透氣通孔基材層表面先對透氣通孔基材層表面進行處理亦 可和:昇其附著性,例如電暈法(C 0 r 0 n a )、火焰燃燒法 (Flame)、及電漿法(Plasffla)等。 依據上述目的’本發明更提供了一種透氣通孔材料,此透 氣通孔材料至少包括:一具有支撐之透氣通孔基材、一或 兩層不織布層位於此基材之表面,其中若為兩層不織布Page 9 1283634 V. Invention Outline (6) ' , ' As for the actual use timing and application mechanism of the material, it depends on the final application location of the composite gas permeable through hole material. According to the above object, the present invention further provides a method for manufacturing a permeable through-hole material, the method comprising: providing at least a substrate having plasticity; and pressing the material to form a plurality of holes on the substrate to form A vented through-hole structure; a non-woven layer is formed on the surface of the substrate by melt-blown; finally, the composite structure of the substrate and the non-woven layer is rolled to obtain a desired final thickness or density. & where 'in order to make the melt-blown non-woven layer more easily adhere to the surface of the permeable through-hole substrate layer', the surface of the permeable through-hole substrate layer can be treated first, for example, a Gravure Coater, a wire bar coating wheel (Meyer bar) Spray Coater applies a suitable adhesive agent, such as a coupling agent, a chelate or a crossiinking agent, to the air. The surface of the through-hole substrate layer is raised to improve the adhesion of the permeable through-hole substrate layer, or the surface treatment device is used in the process, and the surface of the permeable through-hole substrate layer is first treated on the surface of the fused-non-woven material layer to the surface of the permeable through-hole substrate layer: Increase its adhesion, such as corona method (C 0 r 0 na ), flame combustion method (Flame), and plasma method (Plasffla). According to the above object, the present invention further provides a venting through-hole material, the permeable through-hole material comprising at least: a permeable through-hole substrate having a support, one or two layers of non-woven fabric on the surface of the substrate, wherein if the two layers are non-woven
翻 1283634 五、發明說明(7) 層,則此基材係位於此兩層不織布層之間,其中此基材之 組成可依據不同之需求而有多種選擇,此基材可以是塑性 材料層,例如高分子材料,如聚酯類(polyester)、聚乙 稀(polyethylene, PE)、聚丙烯(polypropylene, PP)、 乙烯苯乙烯共聚合物(ethylene-styrene copolymer, ES)、環狀烯共聚合物(CyCl〇 olefin)、聚對苯二曱酸二 乙酯(polyethylene terephthalate, PET)、聚乙稀醇 (polyvinyl alcohol, PVA)、乙烯乙酸乙酯 (ethylene-vinyl acetate, EVA)或 SurlynTM (Dupont ionomer離子型高分子化合物之商標名)、聚乙二醇對萘二 曱酸醋(polyethylene naphthalate,PEN)、聚醚酮(poly ether ether ketone,PEEK)、聚碳酸酉旨(polycarbonate, PC)、聚楓(polysulfone)、聚亞醯胺(polyimide,PI)、 聚丙烯氰(polyacrylonitrile, PAN)、苯乙烯丙烯氰共聚 合物(styrene acrylonitrile,SAN)、聚胺酉旨 (polyurethane, PU)、合成紙(synthetic paper,南亞公 司產品)、聚浠烴類含浸纖維膜(polyolefin impregnated fiber web)、玻璃紙(glassine paper)、紙等單層之材料 層或其組成之多層複合材料、塑膠材料/玻璃纖維布、塑 膠材料/紙之組合、或塑膠材料/金屬之組合,其中與金屬 或其他導電材料組合的目的,在於提供該透氣通孔複合不 、'哉布材料具有靜電消散(static charge dissipation)、 熱傳導散熱(heat conduction and dissipation)與電磁 波干擾遮蔽(EMI shielding)的功能,較常用之金屬材料Turning 1283634 5, invention description (7) layer, the substrate is located between the two layers of non-woven fabric, wherein the composition of the substrate can be selected according to different needs, the substrate can be a plastic material layer, For example, polymer materials, such as polyester, polyethylene (PE), polypropylene (PP), ethylene-styrene copolymer (ES), cyclic olefin copolymerization (CyCl〇olefin), polyethylene terephthalate (PET), polyvinyl alcohol (PVA), ethylene-vinyl acetate (EVA) or SurlynTM (Dupont) Ionomer ionic polymer compound brand name), polyethylene glycol to polyethylene naphthalate (PEN), polyether ether ketone (PEEK), polycarbonate (polycarbonate, PC), Polysulfone, polyimide (PI), polyacrylonitrile (PAN), styrene acrylonitrile (SAN), polyamine (polyu) Rethane, PU), synthetic paper (product of South Asia), polyfluorene-incorporated fiber web (polyolefin impregnated fiber web), glass paper (paper), paper, etc. , plastic material/glass fiber cloth, plastic material/paper combination, or plastic material/metal combination, wherein the purpose of combining with metal or other conductive material is to provide the venting through hole composite, 'the crepe material has static dissipative (static charge dissipation), heat conduction and dissipation, and EMI shielding, more commonly used metal materials
1283634 五、發明說明(8) 如銘金屬。 圖式簡單說明: 本發明的較佳實施例將於往後之說明文字中輔以下列圖形 做更詳細的闡述,其中: 第1圖為繪示習知透氣通孔材料之結構的剖面圖;1283634 V. Description of invention (8) Ru Ming Metal. Brief Description of the Drawings: The preferred embodiment of the present invention will be explained in more detail in the following description with reference to the following figures, wherein: Figure 1 is a cross-sectional view showing the structure of a conventional venting through-hole material;
第2圖為繪示本發明之一較佳實施例之透氣通孔材料之結 構的剖面圖; 第3圖為繪示本發明之另一較佳實施例之透氣通孔材料之 結構的剖面圖,以及 第4圖為本發明之一較佳實施例之透氣通孔材料的製造流 程圖。 圖號對照說明:2 is a cross-sectional view showing the structure of a gas permeable through-hole material according to a preferred embodiment of the present invention; and FIG. 3 is a cross-sectional view showing the structure of a gas permeable through-hole material according to another preferred embodiment of the present invention. And Figure 4 is a flow chart showing the manufacture of a vented through-hole material in accordance with a preferred embodiment of the present invention. Figure number comparison description:
1 0不織布層 1 2 織網布層 20 基材22 不織布層 24 不織布層30 提供一基材 3 2輾壓基材成透氣通孔材料 3 4 形成不織布層 3 6 輾壓基材與不織布複合層 發明詳細說明:10 0 non-woven layer 1 2 woven mesh layer 20 substrate 22 non-woven layer 24 non-woven layer 30 provides a substrate 3 2 pressed substrate into a permeable through-hole material 3 4 forms a non-woven layer 3 6 rolled substrate and non-woven composite layer Detailed description of the invention:
第12頁 1283634 五、發明說明(9) 本發明揭露一種透氣通孔材料及其製造方法與相關應用, 其結構上係結合一具有抗張力械強強度佳承載透氣通孔基 材層之不織布複合層來取代習知技術中常被使用之不織 布’其製程上係運用表面具複數個高硬度之類似尖突狀結 構振壓輪’且以不同顆粒大小及密度與不同輾壓壓力及輾 壓溫度來利控制孔洞尺寸,因此本發明之透氣通孔材料之 整體之機械抗張強度大,且对高溫,使其加工操作性佳較 傳統不織布製程簡單與製得產品品質佳。 請參照第2圖,其所繪示為本發明之一較佳實施例之透氣 通孔材料之結構的剖面圖,且請一併參照第3圖,其所繪 示為本發明之另一較佳實施例之透氣通孔材料之結構的剖 面圖。本發明之透氣通孔材料包括基材20及不織布層22, 或更可包括另一不織布層24,且基材2 0介於不織布層2 2與 不織布層24之間。其中基材20之材質,需至少包括一塑性 材料,例如高分子材料,如聚酯類(P 〇 1 y e s t e r )、聚乙烯 (polyethylene, PE)、聚丙烯(polypropylene, PP)、乙 烯苯乙稀共聚合物(ethylene-styrene copolymer, ES)、 環狀烯共聚合物(cyclo olefin)、聚對苯二甲酸二乙酯 (polyethylene terephthalate, PET)、聚乙烯醇 (polyvinyl alcohol, PVA)、乙烯乙酸乙酯 (ethylene-vinyl acetate, EVA )或 Sur1ynTM (Dupont i onomer離子型高分子化合物之商標名)、聚乙二醇對萘二Page 12 1283634 V. INSTRUCTION DESCRIPTION (9) The present invention discloses a venting through-hole material, a method for fabricating the same, and a related application, the structure of which is replaced by a non-woven composite layer having a tensile-resistant mechanical strength and a good permeable through-hole substrate layer. Non-woven fabrics commonly used in the prior art are used to control the holes with different particle sizes and densities and different rolling pressures and rolling temperatures. Dimensional, therefore, the overall mechanical tensile strength of the vented through-hole material of the present invention is large, and for high temperature, the processing operability is better than that of the conventional non-woven fabric and the quality of the obtained product is good. Please refer to FIG. 2, which is a cross-sectional view showing the structure of a venting through-hole material according to a preferred embodiment of the present invention, and please refer to FIG. 3 together, which is another comparison of the present invention. A cross-sectional view of the structure of the permeable through-hole material of the preferred embodiment. The permeable through-hole material of the present invention comprises a substrate 20 and a nonwoven layer 22, or may comprise another nonwoven layer 24, and the substrate 20 is interposed between the nonwoven layer 22 and the nonwoven layer 24. The material of the substrate 20 needs to include at least a plastic material, such as a polymer material, such as polyester (P 〇1 yester), polyethylene (polyethylene, PE), polypropylene (PP), ethylene styrene. Ethylene-ethylene styrene (ES), cycloolefin, polyethylene terephthalate (PET), polyvinyl alcohol (PVA), ethylene acetate Ethylene-vinyl acetate (EVA) or Sur1ynTM (trade name of Dupont i onomer ionic polymer compound), polyethylene glycol to naphthalene
第13頁 1283634 五、發明說明(ίο) 甲酸酉旨(polyethylene naphthalate,PEN)、聚醚酮(poly ether ether ketone,PEEK)、聚碳酸酉旨(polycarbonate, PC)、聚楓(polysulfone)、聚亞醯胺(polyimide,PI)、 聚丙烯氰(polyacrylonitrile, PAN)、苯乙烯丙浠氰共聚 合物(styrene acrylonitrile, SAN)、聚胺酯 (polyurethane, PU)、合成紙(synthetic paper,南亞公 司產品)、聚稀烴類含浸纖維膜(polyolefin impregnated fiber web)、玻璃紙(glassine paper)、塑膠材料/玻璃 纖維布、塑膠材料/紙之組合等,或者是塑性材料所組成 之第一材料層及紙或金屬,例如紹,所組成之第二材料層 形成之複合材料層,或者是三層塑性材料,即第一材料 層、第二材料層、與第三材料層,所構成之複合材料層。 基材之材料可依不同用途需求,而做不同的選擇搭配 請參照第4圖,其所繪示為第2圖中本發明之一較佳實施例 之透氣通孔材料的製造流程圖。形成此透氣通孔材料時, 首先如同步驟30,提供如上所述之基材,並依需求選擇基 材之材料。再如同步驟3 2,利用例如表面具複數個高硬产 之類似尖突狀結構輾壓輪來輾壓此基材,而在此具有抗& 力械強強度佳承載透氣通孔基材層上形成複數個孔洞,以 形成透氣通孔結構,其中這些孔洞的尺寸可藉由調整 輪上尖突狀結構不同顆粒大小及密度與不同輾壓壓力 壓溫度來利控制孔洞尺寸,且此基材之厚度亦可藉由 輾壓輪與相對應之對壓輪或對壓板之間距來調整。此^卜,Page 13 1283634 V. Invention Description (ίο) Polyethylene naphthalate (PEN), polyether ether ketone (PEEK), polycarbonate (PC), polysulfone, poly Polyimide (PI), polyacrylonitrile (PAN), styrene acrylonitrile (SAN), polyurethane (PU), synthetic paper (product of South Asia) , a polyolefin impregnated fiber web, a glasse paper, a plastic material/glass fiber cloth, a combination of a plastic material/paper, or a first material layer and paper or a plastic material A metal, for example, a composite material layer formed by a second material layer, or a composite material layer composed of a three-layer plastic material, that is, a first material layer, a second material layer, and a third material layer. The material of the substrate can be differently selected according to different application requirements. Referring to Figure 4, there is shown a flow chart for manufacturing a venting through-hole material according to a preferred embodiment of the present invention in Figure 2. When forming the permeable through-hole material, first as in step 30, the substrate as described above is provided, and the material of the substrate is selected as desired. Further, as in step 32, the substrate is pressed by, for example, a plurality of high-hardness-like spike-like structure rolling wheels on the surface, and is formed on the layer of the gas-permeable through-hole substrate. a plurality of holes to form a permeable through-hole structure, wherein the size of the holes can be controlled by adjusting different particle sizes and densities of the cusp structure on the wheel and different pressures of different pressures, and the thickness of the substrate It can also be adjusted by the pressing wheel and the corresponding pressing wheel or the distance between the pressing plates. This ^bu,
第14頁 1283634 1、發明說明(11) " 1^—— 為^使隨後之不織布更容易附著在此基材之表面,可先 透氣通孔基材層表面進行處理,例如以凹版塗佈輪 (Gravure Coater)、繞線棒塗佈輪(Meyer bar)' 噴塗 (Spray Coating)將適當之黏著性改質劑(adhesi〇n promoter, primer),例如偶合劑(coupling agent)、螯 合劑(chelate)、架橋劑(cr0SSHnking agent)或黏膠等 塗佈在此透氣通孔基材層上以提昇此透氣通孔基材層的勘 著性’或製程上利用連線表面處理設備,於融喷不織布材 料層至透氣通孔基材層表面先對透氣通孔基材層表面進行 處理亦可提昇其附著性,例如電暈法(C〇rona)、火焰燃燒 法(Flame)、及電漿法(piasma)等,來處理。接著,如同 步驟34,以例如融喷方式或上膠貼合方式,將不織布材料 喷塗在基材之表面,以形成具不織布層之透氣通孔材料。 然後’如同步驟3 6,輾壓此複合透氣通孔材料,即基材與 不織布層,並調整輾壓輪與相對應之對壓輪或對壓板之間 的間距,以形成厚度符合所需之透氣通孔材料。 由於高分子材料如聚酯類(polyester)、聚乙烯 (polyethylene, PE)、聚丙稀(polypropylene, PP)、乙 烯苯乙烯共聚合物(ethylene-styrene copolymer,ES)、 環狀浠共聚合物(cyclo olefin)、聚對苯二曱酸二乙酯 (polyethylene terephthalate, PET)、聚乙烯醇 (polyvinyl alcohol, PVA)、乙烯乙酸乙酯 (ethylene-vinyl acetate, EVA)或 SurlynTM (DupontPage 14 1283634 1. Description of the Invention (11) " 1^—— To make the subsequent non-woven fabric easier to adhere to the surface of the substrate, the surface of the through-hole substrate layer can be first treated, for example, with a gravure coating wheel ( Gravure Coater), Meyer bar' Spray Coating, appropriate adhesives, such as coupling agents, chelates Applying a brixant agent (cr0SSHnking agent) or a glue to the permeable through-hole substrate layer to enhance the grading of the permeable through-hole substrate layer or using a wire surface treatment device to melt the non-woven material layer to the gas permeable The surface of the through-hole substrate layer can be treated by first treating the surface of the permeable through-hole substrate layer, such as corona (C〇rona), flame combustion (Flame), and plasma (piasma). Next, as in step 34, the nonwoven fabric material is sprayed on the surface of the substrate by, for example, melt-blown or sizing, to form a vented through-hole material having a nonwoven layer. Then, as in step 3 6, press the composite venting through-hole material, that is, the substrate and the non-woven layer, and adjust the spacing between the pressing wheel and the corresponding pair of pressing wheels or the pressing plate to form a thickness to meet the required Breathable through hole material. Due to polymer materials such as polyester, polyethylene (PE), polypropylene (PP), ethylene-styrene copolymer (ES), cyclic ruthenium copolymer ( Cyclo olefin), polyethylene terephthalate (PET), polyvinyl alcohol (PVA), ethylene-vinyl acetate (EVA) or SurlynTM (Dupont)
第15頁 1283634 五、發明說明(12) i ο η 〇 m e r離子型高分子化合物之商標名)、聚乙二醇對萘二 甲酸酉旨(polyethylene naphthalate,PEN)、聚醚酮(poly ether ether ketone,PEEK)、聚碳酸酉旨(polycarbonate, PC)、聚楓(polysulfone)、聚亞醯胺(polyimide, PI)、 聚丙晞氰(polyacrylonitrile, PAN)、苯乙浠丙浠氰共聚 合物(styrene acrylonitrile, SAN)、聚胺酯 (polyurethane, PU)、合成紙(synthet i c paper, 南亞公 司產口口)、聚浠煙類含浸纖維膜(p〇ly〇lefin impregnated fiber web)等塑化 鋁,可遮蔽電磁波 震與吸音功能,支 與耐燃等特性,此 材料上之透氣率與 此,本發明之透氣 磁波、及當作隔熱 發明之透氣通孔f 狀來運用’或折叠 換0 材料具有熱塑性,且 、導熱與導靜電,不 撐之基材層則依實際 外於製作時,再加上 孔洞大小和密度極易 通孔材料可應用來過 襯墊等,其應用性極 料捲成例如圓桶狀、 在一起使用,依用途 金屬材料,例如 織布材料層具有吸 需求可具有财1¾溫 製程上該透氣通孔 控制及調整。因 濾、防塵、防蔽電 廣。另外,可將本 圓柱狀、及同心圓 之不同可靈活變Page 15 1283634 V. Description of the invention (12) i ο η 〇mer ionic polymer compound brand name), polyethylene glycol for naphthalene dicarboxylic acid (PEN), polyether ketone (poly ether ether) Ketone, PEEK), polycarbonate (PC), polysulfone, polyimide (PI), polyacrylonitrile (PAN), acetophenone propylene cyanide ( Styrene acrylonitrile, SAN), polyurethane (PU), synthetic paper (synthet ic paper, Nanya company mouth), polythene fiber impregnated fiber web (p〇ly〇lefin impregnated fiber web) and other plasticized aluminum, Shading electromagnetic wave shock absorption and sound absorbing function, supporting characteristics such as flame resistance, air permeability on the material, and the ventilating magnetic wave of the present invention, and the ventilated through hole f as a heat insulating invention, are applied or folded to have a thermoplastic material. And, the heat conduction and the static conduction, the substrate layer which is not supported is actually produced in addition to the actual size, and the hole size and density are extremely easy to be used for the through-hole material, and the application is extremely high. For example drum-like, used together, by use of the metal material, for example having a layer of woven fabric material which may have a demand suction ventilating hole control and fiscal 1¾ temperature adjustment process. Due to filtration, dustproof, and shielded power. In addition, the difference between the cylindrical shape and the concentric circle can be flexibly changed.
本發明之一優點為 表面上形成不織布 較’可應需求而具 較佳之加工操作性 提供一種透氣通孔材 層’其中基材層具有 有耐南溫與耐燃特性 料’其係在基材之 局抗張機械強度 ’並且提供製程上One of the advantages of the present invention is that a non-woven fabric is formed on the surface to provide a permeable through-hole material layer in which the substrate layer has a south temperature-resistant and flame-resistant characteristic material. Bureau tensile mechanical strength' and provide process
第16頁 1283634 五、發明說明(13) 本發明之另一優點為提供一種透氣通孔材料之製造方法, 其係利用例如電鍍高硬度具複數個尖突狀結構材質輾壓輪 在基材上形成孔洞透氣結構,而透氣通孔材料之孔洞尺 寸、密度及厚度可依需求調整,因此透氣通孔材料之品質 可依需求獲得均勻控制。 本發明之再一優點為提供一種透氣通孔材料,可依不同用 途,變換基材之材料,因此本發明之透氣通孔材料應用極 為廣泛。Page 16 1283634 V. INSTRUCTIONS (13) Another advantage of the present invention is to provide a method for manufacturing a venting through-hole material by using, for example, electroplating a high hardness material having a plurality of pointed structures on a substrate. The hole venting structure is formed, and the hole size, density and thickness of the venting through hole material can be adjusted according to requirements, so the quality of the venting through hole material can be uniformly controlled according to requirements. Still another advantage of the present invention is to provide a venting through-hole material which can be used to change the material of the substrate for different purposes. Therefore, the vented through-hole material of the present invention is extremely widely used.
如熟悉此技術之人員所瞭解的,以上所述僅為本發明之較 佳實施例而已,並非用以限定本發明之申請專利範圍;凡 其它未脫離本發明所揭示之精神下所完成之等效改變或修 飾,均應包含在下述之申請專利範圍内。The above description is only for the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention as defined by the present invention; Modifications or modifications are intended to be included in the scope of the claims below.
第17頁 1283634 圖式簡單說明Page 17 1283634 Schematic description
第18頁Page 18
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CN115122727A (en) * | 2021-03-24 | 2022-09-30 | 三芳化学工业股份有限公司 | Artificial leather structure and manufacturing method thereof |
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CN115122727A (en) * | 2021-03-24 | 2022-09-30 | 三芳化学工业股份有限公司 | Artificial leather structure and manufacturing method thereof |
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