TWI283255B - Impregnated glass fiber strands and products including the same - Google Patents

Abstract

The present invention provides an at least partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and lamellar particles having a thermal conductivity of at least 1 Watt per meter K at a temperature of 300K. The present invention also provides an at least partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and non-hydratable, lamellar particles. The present invention further provides an at least partially coated fiber strand comprising a plurality of fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said fibers, the resin compatible coating composition comprising: (a) a plurality of discrete particles formed from materials selected from non-heat expandable organic materials, inorganic polymeric materials, non-heat expandable composite materials and mixtures thereof, the particles having an average particle size sufficient to allow strand wet out: (b) at least one lubricious material different from said plurality of discrete particles: and (c) at least one film-forming material. The present invention also provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coating composition comprising: (a) a plurality of lamellar, inorganic particles having a Mohs' hardness value which does not exceed the Mohs' hardness value of said glass fibers: and (b) at least one polymeric material. The present invention further provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coating composition comprising: (a) a plurality of hollow, non-heat expandable organic particles; and (b) at least one lubricious material different from the at least one hollow organic particle.

Description

1283255 A7 V. INSTRUCTION DESCRIPTION (i) The present invention relates to coated fiber strands for reinforcing composites, and more particularly to coated fibers = strands which are compatible with the matrix material to which the strands are added. , 'In the thermosetting molding operation, good "wet " (polymeric matrix material penetrates the lining or fiber) and "wet" (polymeric matrix material penetrates the individual fiber bundles in the lining or fabric) Or the nature of the stock is hopeful. In contrast, good dispersion properties (i.e., good distribution properties of the fibers within the thermoplastic material) are a major concern in the 2 thermoplastic molding operation. ... in the case of spinning a composite or laminate formed of fiber strands into a fabric, in addition to providing good wettability and good wetting properties, it is desirable that the coating on the surface of the fiber strand protects the fibers from abrasion during handling, providing Good weaving power, especially in air jet looms, and compatible with the polymeric matrix material to which the fiber strands are added. However, many of the upper paddle components are not compatible with the polymeric matrix material and negatively affect the adhesion between the glass fibers and the polymeric matrix material. For example, starch, which is a common sizing component for textile fibers, is generally not compatible with polymeric matrix materials. As a result, these incompatible materials must be removed from the fabric prior to being impregnated with the polymeric matrix material. The removal of such non-resin compatible sizing materials, i.e., degreasing or deoiling the fabric, can be accomplished by a variety of techniques. The removal of these non-resin-compatible sizing materials is most often accomplished by exposing the woven fabric to elevated temperatures for prolonged thermal decomposition of the granules (often referred to as heat removal). The conventional heat removal process is involved in 380. (: The fabric is heated for 60-80 hours. However, this heat-clearing step is harmful to the strength of the glass fiber, and it has not been possible to successfully remove the incompatible material and the 0 sizing decomposition product to further contaminate the fabric. -4- Table paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public love (please read the note on the back and fill in this page) ▼ Install-----r---book---- ------. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 B7 V. Description of invention (2) In addition to sizing materials - methods such as washing and / or chemical removal. However, this method is usually The sizing composition needs to be heavily reconstituted to be compatible with such water washing and/or chemical removal, and is generally not as effective as heat removal in removing all incompatible materials. Furthermore, due to the weaving process, the fiberglass yarn is quite worn. Sex, as a warp yarn, generally accepts a second coating step prior to weaving, which is commonly referred to as, sizing ", while the warp yarn is coated with a wear resistant coating (commonly referred to as "sizing sizing)) To help minimize the abrasion of the glass fiber. Applied to the first sizing previously applied to the glass fibers during the fiber forming operation. However, since typical sizing sizing is generally not compatible with polymeric matrix materials, it must also be self-woven prior to the addition of the resin. In addition, in order to improve the abrasion between the degreased or deoiled fabric and the polymeric resin, the final upper slurry (generally a decane coupling agent and water) is applied to the fabric to recoat the glass fiber in another processing step (usually Called “trimming”. All of these have no additional price 値 processing steps: sizing, degreasing or degreasing, and trimming, increasing fabric manufacturing cycle time and cost. In addition, they often require significant capital investment in capital equipment and labor. The fabric additional treatment of these treatment steps results in fabric damage and reduced quality. Efforts have been made to improve the efficiency or effectiveness of some of these treatment steps. However, the coating continues to fulfill one or more of the following requirements: inhibiting the abrasion of the glass fiber and Rupture; compatible with a wide variety of matrix materials; and provides good wetting and wetting through the matrix material. It is particularly advantageous to have a coating that is compatible with modern air jet weaving devices to increase productivity. In addition, there is no additional price in the fabric forming operation. The processing step is maintained while maintaining the electronic support (please read the precautions on the back). This page) _装-----^----订---- Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative

1283255 Sewing Ministry Intellectual Property Manager X Consumer Cooperative Print A7 ----______ V. Invention Description (3) It is advantageous to use the quality of the fabric and provide good lamination properties. The above summary, as well as the following detailed description of the preferred embodiments, are in the In the drawings: Figure 1 is a front elevational view of a coated fiber strand at least partially coated with a coating composition in accordance with the present invention; Figure 2 is a top pulp composition and at least a portion of the sizing composition A front view of the coated fiber strands at least partially coated with a second coating composition in accordance with the present invention; FIG. 3 is a at least partially coated sizing composition, at least partially loaded with a combination [The second coating composition, and a front view of the coated fiber strands of the third coating composition according to the present invention on at least a portion of the second coating group of the panicle; FIG. 4 is in accordance with Figure 5 is a top plan view of a fabric in accordance with the present invention; Figure 6 is a pictorial view of a method of combining a fabric and forming a laminate in accordance with the present invention; Figure 7 is an electronic view in accordance with the present invention; FIG. 8 and FIG. 9 are cross-sectional views of an alternative embodiment of an electronic support according to the present invention; FIG. 1 is a schematic view of a method of forming a laminate in a fabric layer of an electronic support. Figure 11 is a rear view of the drill bit, which depicts the first cutting edge; Figure 12 is a drill An illustration of a hole pattern; and Figure 13 is a chart of a Go-road pattern. -----------Install-----r---订--------- (Please read the notes on the back and fill in this page) 1283255 Ministry of Economic Affairs Intellectual Property Bureau Employees' Consumption Cooperatives Print A7 V. INSTRUCTIONS (4) The enamel fiber strands of the present invention have a unique coating which not only preferably treats fibers when they are treated, but also provides at least one type of ruthenium when forming a composite. Under the m poor · good wet through, moist and dispersed properties. As defined below and in the field definition, the stock contains a plurality of individual weaving dimensions, i.e., at least two weaving dimensions. The composite used represents the coated fiber strands of the present invention and additional materials, such as, but not limited to, one or more layers added to the coated fiber i fabric to form a polymeric matrix material to form a layer. Good lamination strength, good thermal stability, good hydrolysis stability (ie resistance to water migration along the fiber/polycarbonate material interface), low corrosion in the presence of high humidity, reactive acids and bases Reactivity, and with various polymeric matrix materials < morbidity (which may eliminate the need to remove the coating prior to lamination, particularly in hot or pressurized water removal), may be presented by the coated fiber strands of the present invention Other required features. The car owner provides good woven and knit processing power for the coated fiber strands of the present invention. Low fine and perforated rings, low rupture filaments, low strand tension, high pulsating power and low insertion time are preferred individual or combination features of the coated glass fiber strands of the present invention, which are preferred for weaving and knitting And consistently provide fabrics for printed circuit board applications with minimal surface defects. Further, the coated fiber strand of the present invention is suitable for use in air jet weaving. As used herein, "air jet weaving" means a fabric weaving pattern in which a filler (weft) is inserted into a warp shed with strong compressed air from one or more air jet nozzles. The coated fiber strands of the present invention preferably have a unique coating that facilitates thermal conduction along the coated surface of the fiber. Applicable to China National Standard (CNS) A4 specification (21G X 297 public------------------r---^ as a continuous strong paper scale for electronic circuit boards) --------- {:Please read the phonetic transcription on the back? Please fill out this page again} Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printing Agriculture 1283255 A7 ___B7__ V. Invention Description (5) When the compound, Ben· The coated glass fiber of the present invention can provide a mechanism for thermally dissipating heat from a heat source (such as a wafer or a circuit) to conduct heat away from the electronic component, thereby suppressing electronic components, glass fibers, and polymeric matrix materials. Thermal degradation and/or degradation. The coated fiber strands of the present invention preferably provide a higher thermal conductivity than the matrix material, i.e., a preferred path for heat dissipation and distribution. Thus, the thermal expansion and curl of the electronic circuit board are reduced and improved. Soldering Reliability The coated glass fiber strands of the present invention preferably reduce or eliminate the need to incorporate a thermally conductive material into the matrix resin, which improves the laminate manufacturing operation and reduces the need for expensive matrix material supply tank rinsing and maintenance. The coated fiber strand of the invention is preferably In order to present high openness, the “high-openness” used herein means that the strand has a large cross-sectional area and the filaments of the strand are not tightly bonded to each other. The high-openness of the strand may facilitate the penetration of the matrix material into the strand or Wetting. The composite of the present invention, particularly a laminate, produced from the fiber strands of the present invention preferably exhibits at least one of the following properties: low coefficient of thermal expansion; good flexural strength; good interlaminar bonding strength; and good hydrolysis. Stability, that is, resistance to movement of water along the fiber/matrix interface. Further, the electronic support and printed circuit board of the present invention made from the fiber strands according to the present invention preferably have at least one of the following properties: a good drill hole Force; and metal movement (also known as cathodic-anode filament formation or CAF) resistance. See Tummala (editor) et al., Microelectronics Packaging Handbook, (1989) pp. 896-897, and IPC-TR-476B," Electrochemical Migration: Electrochemically Induced Failures in Printed Wiring This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- ^ ---- --------- ----- booked (please read the back of the precautions to fill out this page) 1283255

V. Description of the invention (6 Printed by the Consumers' Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs

Boards and AsSemblies&quot;, (1997), which is specifically incorporated herein by reference. The fiber strands having good drilling power according to the present invention have at least one of low tool wear during drilling and good drilling position correctness. As noted above, typical fabric forming operations involve subjecting the fiber crepe yarn to fabrics made therefrom with a number of no additional cost processing steps such as sizing, heat removal and conditioning. The present invention preferably provides a method of forming fabrics, laminates, electronic supports and printed circuit boards that eliminates the costly processing steps from the fabric forming process while providing a quality I fabric suitable for use in electronic packaging applications. Other advantages of preferred embodiments of the invention include reduced production cycle time, elimination of capital equipment, reduced fabric handling and labor costs, good fabric quality, and good end product properties. The present invention also provides a method of inhibiting abrasion of fiber strands by contact with other solid objects (such as a portion of a rolling, weaving or knitting device) or by abrasion between filaments by selecting fiber strands having a unique coating of the present invention. . For the purposes of this specification, it should be understood that, in the context of operation, or where specified, the meaning of Modification. Accordingly, the numerical parameters set forth in the following description and the appended claims are intended to be <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; At the very least, and not as an attempt to limit the application of the subject matter of the patent application, the quantitative parameters should be considered at least as far as the number of primary digits reported and the application are generally omitted. Notwithstanding that the numerical ranges and parameters of the invention are broadly described, the number recited in the particular examples can be accurately reported as much as possible. However, any number -9- of this paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) &quot; -----------Install-----^-- --Book-----I--- (Please read the notes on the back and fill out this page)

1283255

Inevitably generated - inherently contains - the standard deviation specific error found in its various test measurements. Referring now to Figure 1 ', wherein the same number is used for the I-silver & the weightlessness of the components, a plurality of fibers 12 are shown in Figure 1 in accordance with the coated fiber strands 10. As used herein, &quot;strand&quot; means a plurality of individual fibers, i.e., at least two fibers&apos; and the strands may comprise fibers made from different fiberizable materials. (The fiber bundle may also be referred to as &quot;yarn. The term &quot;fiber&quot; denotes an individual filament. Although not limiting, the fiber 12 preferably has an average nominal fiber diameter ranging from 3 to 35 microns. The average nominal fiber diameter of the present invention is 5 microns and greater. For &quot;spun&quot; applications, the average nominal fiber diameter preferably ranges from 5 to 7 microns. The fibers 12 can be of any type known to those skilled in the art. A fibrous material is formed comprising a fiberizable inorganic material, a fiberizable organic material, and a mixture of any of the above. The inorganic and organic materials may be artificial or naturally occurring materials. Those skilled in the art will appreciate that fiberizable inorganic and organic materials The material may also be a polymeric material. The term "polymeric material" used herein refers to a material formed by macromolecules composed of long-chain atoms that are bonded together and mixed in a solution or solid phase. "Fiberable" means a material that forms a substantially continuous filament, fiber, strand or yarn. Preferably, the fiber 12 is formed from an inorganic, fiberizable glass material. Fibrillar glass materials for use in the present invention include, but are not limited to, by, for example, "glass" 1 James Mark, Tnorganic P〇 [7men Prentice Hall Polymer Science and Engineering Series, (1992), brother 1 page, Into the reference ^ 10- This paper scale applies to the Chinese National Standard (CNS) A4 specifications (210x 297 public ") ------------ loaded-----r--丨--- -I---- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed 1283255

Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing 5, Inventions (8), • 'A-glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass, glass A producer of a glassy derivative of a fiberizable glass composition. As used herein, "E-glass derivative" means a glass composition comprising a small amount of fluorine and/or boron, and preferably a fluorine and/or boron-free glass. Further, as used herein, a small amount of fluorine" means less than 0.5% by weight of fluorine, preferably less than 〇j by weight. /〇 of fluorine, and ''a small amount of boron' means less than 5% by weight of boron, Preferably less than 2% by weight of boron. Basalt and mineral wool are examples of other fiberizable glass materials useful in the present invention. Preferred glass fibers are formed from E-glass or glass derivatives. Such compositions are known to those skilled in the art, and further discussion of the present invention is not believed to be necessary. The glass fibers of the present invention can be formed by any suitable method known in the art for forming glass fibers. For example, the glass fibers can be formed in a direct melt fiber forming operation or an indirect or marbled melt fiber forming operation. In the direct melt fiber forming operation, the raw materials are combined, melted, and homogenized in a vitrification furnace. The molten glass is moved from the furnace to the forehearth and into the forming apparatus where the molten glass is tapered into continuous glass fibers. The glass flakes or marbles having the final desired glass composition are preformed in the bead melt fiber forming operation and fed into the liner where they melt and thin into continuous glass fibers. If a pre-melt is used, the marbles are first fed into the pre-melter, melted, and then the molten glass is fed into a fiber forming device where the glass is tapered to form continuous fibers. In the present invention, the glass fibers are preferably formed by a direct melt fiber forming operation. For additional information on glass compositions and methods of forming glass-fibre, see K. Loewenstein's The Manufacturing: Technology 〇f Continuous Glass Fibres (3rd -11-Too 缺 湳 湳 中 中 掬谂 掬谂 掬谂 (9) 0 x 2Q7 公兹^ --- ----------- Pack-----· I--book--丨丨丨-丨I - (Please read the notes on the back and fill in this Page) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Printed V. Inventions (9) . Edition, 1993) - pages 30-44, 47-103, and 115-165; US patents - 4,542,106 and 6,789,329 ; and IPC-EG-140 &quot;Specification for

Finished Fabric Woven from Glass· Glass for Printed Board&quot;, page 1, of the Institute for Interconnecting and Packaging Electronic Circuits (June 1997), which is specifically incorporated herein by reference. Non-limiting examples of suitable non-glass-fibrous inorganic materials include ceramic materials such as tantalum carbide, carbon, graphite, mullite, alumina, and piezoelectric ceramic materials. Non-limiting examples of suitable fiberizable organic materials include cotton, cellulose, natural rubber, linen, ramie, hemp, kenaf and wool. Non-limiting examples of suitable fiberizable organic polymeric materials include polyamines (such as nylon and aromatic decylamine), thermoplastic polyesters (such as polyethylene terephthalate and butyl butyl phthalate), A propylene group (such as polyacrylonitrile), a polyolefin, a polyurethane, and a vinyl polymer (such as polyethylene glycol) are formed. Non-glass fibrillated materials for use in the present invention and methods of making and treating such fibers are discussed in detail in Encyclopedia of Polymer Science and Technology, Vol. 6 (1967) at pages 505-712, which is specifically incorporated herein by reference. . It will be appreciated that any combination of any of the above materials or copolymers and fibers formed from any of the above materials can be used in the present invention, if desired. In addition, the noun shares contain at least two different fibers made from different fiberizable materials. In a preferred embodiment, the fiber strands of the present invention comprise at least one glass fiber, although it may contain other types of fibers. The present invention is now generally discussed in relation to the content of fiberglass strands, although it will be appreciated by those skilled in the art that strand 10 may comprise the Chinese National Standard (CNS) A4 specification known from the art discussed above. 210 X 297 砮) -----------Install-----..----Book--------- (Please read the note on the back? Fill in this page) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Employees Consumer Cooperatives Printed V. Inventions (10) Fibers formed from the secret material. Therefore, the theory of the glass fiber is generally applied to the other fibers discussed above. With continued reference to Figure 1, in a preferred embodiment, at least one and preferably all of the fibers 12 of the present invention have a coating composition (which is preferably a coating composition residue) on the surface of the fiber 12 The layer 14 on at least a portion of the portion 17 protects the fiber surface 16 from abrasion and inhibits fiber breakage during processing. Preferably, layer 14 is present on all outer surfaces 16 or the periphery of fibers 12. The coating composition of the present invention is preferably an aqueous coating composition, and is preferably an aqueous resin compatible coating composition. Although it is not preferable for safety reasons, the coating composition may contain a volatile organic solvent such as an alcohol or acetone as required, but it is preferred to have no such solvent. Further, the coating composition of the present invention can be used as the first sizing composition and/or the second sizing or coating composition. In a preferred embodiment, the term "upper slurry", "slurry" or "slurry" refers to any coating combination applied to the fiber after formation. "No." second upper paste sec〇ndary to Han,,, ''Second upper slurry secondary sizing' or "second coating" means applied to the fiber after coating the first upper slurry Coating composition. Noun &quot;Third upper sizing&quot;, "third sizing matter sizing" or "third coating", indicating coating on the second sizing after coating the fiber Coating composition. For example, by coating the fabric, the coatings can be applied to the fibers before the fibers are added to the fabric or they can be applied to the fibers after the fibers are added to the fabric. In an alternative embodiment, the noun π upper paste size &quot;, &quot; upper slurry sized, or "upper slurry sizing" external finger has been removed by heat or chemical treatment to remove at least a portion, and - 13- Too paper ruler Tang i commercial China national standard 聿 specifications (210 X 297 cm) --------II-------^----^ · 11--- III (please first Read the note on the back? Please fill out this page again! !283255 Ministry of Intellectual Property Bureau Consumer Cooperative Printed 5, Invention Description (U) and preferably as a conventional non-resin compatible sizing composition, coated The fiber-coated coating composition (also known as "trimming the upper slurry"), that is, the trimmed upper slurry is applied to the bare glass fibers added to the fabric form. The use of the term "resin compatible" herein means that the coating composition applied to the glass fibers is compatible with the matrix material to which the glass fibers are added, such that the coating composition (or selected coating composition) results in at least one of the following: Properties: no need to remove (such as by degreasing or deoiling) before adding the matrix material, good wetting and wetting of the matrix material in the conventional treatment, and the formation of the final composite product with the desired physical properties and hydrolysis stability. . The coating composition of the present invention comprises one or more, and preferably a plurality of particles 18 which adhere to at least one outer surface 16 of the fibers 23 when applied to at least one of the fibers 23 of the plurality of fibers 12, and One or more gap spaces 21 are provided between adjacent glass fibers 23, 25 of the strands, as shown in the figure! Shown. These interstitial spaces 21 correspond approximately to the size 19 of the particles 18 located between the fibers of the phase. The particles 18 of the present invention are preferably discontinuous particles. The term &quot;discontinuous&quot; as used herein means that the particles do not tend to coalesce or combine under known processing conditions to form a continuous film, but substantially retain their individual differences, and typically retain their individual shape or form. The discontinuous particles of the present invention can be sheared during the treatment of conventional fibers, i.e., removing the layer or layer of atoms in the particles, necking, i.e., 'the at least two of the particles: level = transfer, and Cohesion, and still can be regarded as &quot;discontinuous&quot; particles. The particles 18 of the present invention are preferably dimensionally stable. In the name of (4), "Dimensional stability particles" means that the particles are produced under the conditions of conventional fiber processing, such as the force generated by the adjacent fibers during the processing operation of the moving and spinning strips. -----^---------^9— (Please read the notes on the back and fill out this page) J__- 14- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public Chu) !283255 A7 B7 V. Invention Description (U) With its average reduction and shape, the entire space of 23,25 adjacent fibers. In other words, under typical glass fiber processing conditions, preferably, up to 10 〇l and more preferably: ί:,: the granules preferably do not collapse in the coating composition, dissolve on the Η deformation Instead, particles having a maximum size less than their selected average particle size are formed. In addition, under the conditions of glass fiber treatment, and more preferably, the composition of the composite material of rc, the size of the particles 18 should be substantially constant or large. The term "large substantially unchanged" is used herein to mean that the particles should not swell or increase in size to more than three times their original size. Further, the term "size-stabilizing particles" as used herein encompasses both crystalline and amorphous particles. Preferably, the coating composition of the present invention is substantially free of thermally expandable particles. The term "hot expandable particles" as used herein. • A surface filled or containing particles of a material that expands to a temperature at which the volatilization of the material is volatilized. The size of the thermally expandable particles is therefore due to the material in the particles (eg, 'foaming agent'). The result is a change in the phase under normal processing conditions. The result 'noun&quot; non-thermally expandable particle&quot; refers to a particle that does not expand due to the phase change of the material in the particle under normal processing conditions, and is embodied in the present invention. In the example, the coating composition comprises at least one non-thermally expandable particle. Typically, the thermally expandable particle is a hollow particle having a central cavity. In a non-limiting embodiment of the invention, the cavity may be at least partially filled with a non-solid Materials such as gases, liquids, and/or gels. As used herein, the term "substantially free of heat-expandable particles" means that the total amount of heat is less than jo_% by weight. Expanded particles, more preferably less than 35 weights ___ - 15- This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 public) ----------^----- ---- (Please read the precautions on the back and fill in this page) 1283255 A7 B7 V. Inventions (13) (Please read the notes on the back and fill out this page) %. More preferably &gt;, the present invention The coating composition is essentially free of thermally expandable particles. The term "essentially non-thermally expandable particles" as used herein means that the sizing composition comprises less than 20% by weight of thermally expandable particles based on total solids, more It is preferably less than 5% by weight, and most preferably less than 0.001% by weight. The particles 18 are preferably non-waxy. The term "non-waxy" means that the material forming the particles is non-waxy. The term "wax" as used herein means that the material consists essentially of 1'2 of a non-hybrid hydrocarbon chain having an average carbon chain length ranging from 25 to 100 carbon atoms. In a preferred embodiment of the invention, the particles 18 of the present invention are continuous, dimensionally stable, non-waxy particles. The particles 18 can have any desired shape or configuration. Although not limited in the present invention, examples of suitable particle shapes include spheres (e.g., granules, granules or hollow spheres), cubes, plates or needles (long or fibrous). Additionally, the particles 18 can have a hollow, porous or void-free internal structure, or a combination thereof, such as a hollow central and porous or solid wall. For more information on particle characteristics, see H. Katz et al. (eds.), Handbook of Fillers and Plastics (1987), pp. 9-10, which is specifically incorporated herein as the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, Printed 1 L. H. Sperling, Introduction of Physical Polymer Science. John Willey and Sons, Inc. (1986), pp. 2-5, which is hereby incorporated by reference in its entirety. 2 W. Pushaw et al. &quot;Use of Micronised Waxes and Wax Dispersions in Waterborne Systems&quot; Polymers. Paint. Colours Journal, Vol. 189, No. 4412, January 18-21, 1999 Into as a reference. -16· This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 B7 V. Invention Description (14) Reference particle 18 can be selected from polymerization Formed with non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and materials of any of the foregoing. As used herein, the term "π-polymeric inorganic material" means a polymeric material having a backbone repeating unit based on elements other than carbon. For more information, see L_E. Mark et al., page 5, which is specifically incorporated herein by reference. The term "polymeric organic material" as used herein refers to a synthetic polymeric material having a carbon-based backbone repeating unit, a semi-synthetic polymeric material, and a natural polymeric material. As used herein, "organic material" means a carbon-containing compound in which carbon is generally bonded to itself and hydrogen, and often to other elements, and excludes binary compounds such as carbon oxides, carbides, carbon disulfide, and the like; a ternary compound of cyanide, metal carbonyl, phosgene, carbonyl sulfide, etc.; and a carbon-containing ionic compound such as a metal ruthenate such as cesium carbonate and carbonic acid steel. See R. Lewis, Sr., Hawlev丨s Condensed Chemical Dictionary (12th ed. 1993), pp. 761-762, and M. Silberberg, Chemistry The Molecular Nature of Matter and Change Π 996, page 58, which specifically This is incorporated herein by reference. The term "inorganic material" as used herein means any material that is not an organic material. The term "composite" as used herein means a combination of two or more different materials. The particles formed from the composite material generally have a hardness on the surface that is different from the internal hardness of the particles below the surface. More particularly, the particles The surface may be modified by any method known in the art including, but not limited to, chemically or physically altering its surface characteristics using techniques known in the art such that the particle size of the paper is applicable to the Chinese National Standard (CNS) A4 specification ( 21〇X 297 公爱) I----丨丨丨————•丨丨----订·!——丨丨丨—- (Please read the notes on the back and fill out this page) 1283255 A7 B7 5. Description of the invention (15 surface hardness, etc. - at or below the hardness of the glass fiber, and the degree of the surface is greater than the hardness of the glass fiber. For example, the material may be formed from the first material; it is coated with one or more second materials Covering, facing or encapsulating to form: particles having a softer surface. In another alternative embodiment, particles formed from the composite material may be formed from the first material, which are coated in different first material forms, Protection Surface or package. For more information on the particles of the present invention, see G. Wypych, 2nd Edition (1999), pp. 15°_2〇2, which is hereby incorporated by reference in its entirety. Representative non-polymeric inorganic materials of 18 include inorganic materials selected from the group consisting of graphite, metals, oxides, carbides, nitrides, borides, sulfides, sulphates, carbonates, sulfates, and hydroxides. A non-limiting example of a suitable inorganic nitride is boron nitride, which is a preferred embodiment of the invention. Boron nitride having a hexahedral crystal structure is particularly preferred. A non-limiting example of an inorganic oxide can be zinc oxide. Suitable inorganic sulfides include molybdenum disulfide, disulfide knobs, tungsten disulfide and zinc disulfide. Useful inorganic niobates include aluminum niobate and magnesium niobate, such as vermiculite. Suitable metals include molybdenum, platinum, palladium. , nickel, aluminum, copper, gold, iron, silver, any of the above alloys and mixtures. In a non-limiting embodiment of the invention, the particles 18 are formed from a solid lubricant material. The term "solid lubricant" is used herein. table Any solid that is used between the two surfaces to provide protection against damage and/or reduce friction and wear during relative movement. In a particular embodiment, the solid lubricant is an inorganic solid lubricant. Inorganic solid lubricant, which means that the solid lubricant has the characteristic crystallization habit of shearing into a thin, flat plate, and its easy 18- paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 __B7____ V. Invention description (10) sliding on each other&gt;, thus producing an anti-friction lubrication effect between the fiber surface (preferably the surface of the glass fiber) and the adjacent solid surface, wherein Move at least one. See R. Lewis, Sr., Hawley, Condensed Chemical Dictionary, (12th ed., 1993) at page 712, which is hereby incorporated by reference in its entirety. Friction is the resistance of solids to each other. F. Clauss, Solid Lubricants and Self-Lubricating Solids (1972), page 1, which is hereby incorporated by reference in its entirety. In a non-limiting embodiment of the invention, the particles 18 have a thin flat structure. Particles having a thin flat structure are composed of atomic sheets or plates of a hexahedral array which have strong bonds in the sheet and weak van der Waals bonds between the sheets to provide low shear strength between sheets. A non-limiting example of a thin flat structure is a hexahedral crystalline structure. K. Ludema, Friction, Wear, Lubrication (1996) p. 125, Solid Lubricants and Self-Lubricating Solids 19-22, 42-54, 75-77, 80-81, 82, 9 (M02, 113-120 and 128 pages; and W. Campbell &quot;Solid Lubricants&quot;, Boundary Lubrication: An Appraisal of World Literature. ASME Research Committee on Lubrication (1969) pp. 202-203, which is hereby incorporated by reference in its entirety. Inorganic solid particles of the fullerene structure can also be used in the present invention. Non-limiting examples of suitable materials having a thin flat structure that can be used to form the particles 18 of the present invention include boron nitride, graphite, metal dichalcogenides, mica, Talc, gypsum, kaolin, calcite, cadmium iodide, silver sulfide, and any mixture of the above. Preferred materials include nitride feathers, graphite, metal dichalcogenides, and mixtures of any of the above. Suitable metal disulfide Family-19- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) -------IIII · III l· III Ding·111 — 111 *^^^— (Please read first Precautions on the back side Fill in this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _B7 V. Invention Description (17) Compounds include - molybdenum disulfide, molybdenum diselenide, antimony disulfide, di-capacity, --Tungsten disulfide, tungsten disilicide, and mixtures of any of the above. In a particular embodiment, the particles 18 are formed from an inorganic solid lubricant material having a thin flat structure. The coating composition of the present invention has a thin A non-limiting example of a flat structure inorganic solid lubricant material is boron nitride, preferably boron nitride having a hexahedral crystal structure. Particles formed from boron nitride, zinc sulfide and microcrystalline kaolinite are also A good whiteness is provided in the composite of the polymeric matrix material of nylon 6,6. A non-limiting example of a particle formed from boron nitride suitable for use in the present invention is the POLARTHERM® 100 series (PT 120, PT 140, PT 160) And PT 180); 300 series (PT 350) and 600 series (PT 620, PT 630, PT 640 and PT 670) boron nitride powder particles, commercially available from Advanced Ceramics, Inc., Lakewood, Ohio, 0 &quot;PolarTherm® Th Ermally Conductive Fillers for Polymeric Materials&quot;, Technical Bulletin of Advanced Ceramics, Inc., Lakewood, Ohio (1996), which is incorporated herein by reference in its entirety. These granules have a per metre at 25 °C. K 250-300 watts of heat transfer, 3.9 dielectric constant and 1015 ohm-cm volume resistivity. The 100 series powder particles have an average particle size of 5 to 14 microns, the 300 series powder particles have an average particle size ranging from 100 to 150 microns, and the 600 series powder particles have an average particle size ranging from 15 to more than 200 microns. In particular, as reported by its suppliers, the POLYTHERM 160 particles have an average particle size of 6 to 12 microns, a submicron to 70 micron particle size, and a particle size distribution as follows: -20- This paper scale applies to the Chinese National Standard (CNS). A4 size (210 X 297 mm) -----------Install-----:----Book---------^9. (Please read the back Note: Please fill out this page again) 1283255 A7 B7 V. INSTRUCTIONS (IS) -% 10 50 90 Size (μm) 18.4 7,4 0.6 According to this distribution, 10% of the measured POLARHERM® 160 boron nitride particles are larger than Average particle size of 18.4 microns. As used herein, "average particle size" refers to the average particle size of the particles. The average particle size of the particles according to the invention can be measured in accordance with known laser scattering techniques. In a non-limiting embodiment of the invention, the particle size is measured using a Beckman Coulter LS 230 laser diffraction particle sizer, which uses a laser beam having a wavelength of 750 nm to measure the particle size, and assuming that the particles have a spherical shape, ie, "particle size" Refers to the smallest pellet of fully encapsulated particles. For example, it has been found that particles of POLARHERM® 160 boron nitride particles measured using a Beckman Coulter LS 230 particle size analyzer have an average particle size of 11.9 microns, a particle size ranging from submicron to 36 microns, and have a particle distribution of: % 10 50 90 size ( Micron) 20.6 11.3 4.0 (Please read the note on the back and then fill out this page) One installation ϋ ϋ H One OJI · ϋ n ϋ n ϋ Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed according to this distribution, measured 10% of the POLARTHERM 8160 boron nitride particles have an average particle size greater than 20.6 microns. In another non-limiting embodiment of the invention, the particles 18 are formed from a non-hydratable inorganic material. As used herein, "non-hydratable" means that the inorganic particles do not react with water to form a hydrate, and do not contain water or water of crystallization. Hydration*1&quot; by means of water molecules and substances in which H-0H bonds are not broken - This paper scale applies to China National Standard (CNS) A4 specification &lt;210 X 297 mm) 1283255 A7 B7 V. Description of invention (19) (Please read the notes on the back and fill out this page) Reaction Manufacturing. - See R. Lewis, Sr., Hawley's Condensed Chemical Dictionary. (12th ed. 1993) pp. 609-610, and T. Perros Chemistry. (1967) pp. 186-187, which is hereby incorporated by reference in its entirety. In the hydrated formula, the addition of water molecules is conventionally represented by a central point, for example, 3Mg0.4Si02 H20 (talc) , Al203.2Si0r2H20 (kaolin). Structurally, the hydratable inorganic material includes at least one hydroxyl group in a layer of crystal lattice (but does not include the hydroxyl group of the surface plane of the unit structure of the material which absorbs water by capillary action on its surface plane), for example , as shown by the structure of kaolin shown in Figure 3.6 on page 34 of J. Mitchell's Fundamentals of Soil Behavior (1976), and Clay Colloid Chemistry. (2nd edition, 1977) No. 62 by H. van Olphen. Page 18 and 1 The structure of the 1:1 and 2:1 layers of minerals shown in Figure 9 is specifically incorporated herein by reference. A &quot;layer&quot; lattice is a combination of sheets (which are combinations of atomic planes). See Minerals in Soil Environments. Soil Science Society of America (1977) pp. 196-199, which is hereby incorporated by reference in its entirety in its entirety. The sizing of layers and inter-layer materials (such as cations) is referred to as unit structure. Bureau employees' consumption cooperatives print hydrates containing coordinating water, which cations are located in hydrated materials and cannot be removed by breaking structural and/or structural water (which occupies gaps in the structure to increase electrostatic energy without destroying charge balance). An Introduction to Crystal Chemistry (1948), page 276, to R. Evnas, which is incorporated herein by reference in its entirety. In general, the coating composition contains no more than 50% by weight of hydratable particles. In a particular embodiment, the coating composition is preferably substantially free of hydratable particles. The term "essentially non-hydratable particles" as used herein means that the coating composition comprises less than total solids - 22-12 83255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing _ _ This paper size is suitable for Gill family standard (CNS) A4 specification (10) X 297 public hair five, invention description (2 〇 20% by weight) hydration particles, better It is less than 5 weights. /❶, and preferably less than 〇·(9)1% by weight. In a particular embodiment of the invention, the particles 18 are formed from a non-hydratable inorganic solid lubricant material. In lieu of or in addition to the non-hydratable inorganic materials discussed above, the coating compositions in accordance with the present invention may comprise particles formed from hydratable or hydrated inorganic materials. A non-limiting example of such a hydratable inorganic material is a clay mineral silicate, which includes mica (e.g., muscovite), talc, microcrystalline kaolinite, kaolin, and gypsum. As explained above, the composition of particles formed from such hydratable or hydrated inorganic materials does not exceed the weight percent of the particles in the coating composition. 0 In another embodiment of the invention, the particles 18 may be non-polymeric organic. Material formation. Non-polymeric organic materials useful in the present invention include, but are not limited to, stearates such as zinc stearate and aluminum stearate, carbon black and stearylamine. In another embodiment of the invention, the particles 18 can be formed from an inorganic polymeric material. Non-limiting examples of useful inorganic polymeric materials include polyphosphorazines, polydecanes, polyoxyalkylenes, polydecanes, polysulfides, polyselenides, polyoxyxides, and mixtures of any of the foregoing. A specific non-limiting example of a granule formed from an inorganic polymeric material suitable for use in the present invention is TOSPEARL4, which is a granule formed from crosslinked decane, and is commercially available from Toshiba Polyoxo Co., Japan. In another embodiment of the invention, the particles 18 can be formed from a synthetic organic polymeric material. Suitable organic polymeric materials include, but are not limited to, thermoset materials and thermoplastic materials. Suitable thermosetting materials include thermosetting polyfluorene, vinyl vinegar: epoxy materials, laboratory, amine-based plastics, thermosetting polyamines-23-----------------Γ-^ ---------^9. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 ___B7___ V. Invention Description (21) Formic acid S, and - a mixture of any of the above. A preferred non-limiting example of a preferred polymeric particle formed from an epoxy material is an epoxy microgel particle. Suitable thermoplastic materials include thermoplastic polyesters, polycarbonates, polyfluorenes, propene polymers, polyamines, thermoplastic polyurethanes, ethylenic polymers, and mixtures of any of the foregoing. Preferred thermoplastic polyesters include, but are not limited to, poly(p-butyl phthalate), poly(p-butyl phthalate), and poly(ethylene terephthalate). Preferred polyolefins include, but are not limited to, polyethylene, polypropylene, and polyisobutylene. Preferred propylene polymers include copolymers of styrene and propionate monomers and polymers containing methacrylic acid. A non-limiting example of a synthetic polymeric particle formed from a propylene copolymer is RHOPLEX® B-855, which is an opaque, non-crosslinked solid propylene particle emulsion, ROPAQUE® HP-10556, which has a particle size of 1.0 micron and a solidity of 26.5% by weight. An opaque, non-film-forming styrene-propylene polymerized synthetic pigment with a content of 55% pore volume, ROPAQUE® OP-967 and ROPAQUE® HP-543P8, which are the same opaque, non-film forming with a 0.55 micron particle size and a 30.5 wt% solids content. A styrene propylene polymerization synthetic pigment dispersion, and ROPAQUE® OP-62 L09, which is also an opaque, non-film-forming styrene propylene polymerization synthetic pigment dispersion having a 0.40 micron particle size and a 36.5 weight percent solids content. Each of the designated pellets was commercially available from Rohm and Haas of Philadelphia, Pennsylvania. 4 See RJ Perry &quot;Applications for Cross-Linked Siloxane Particles&quot; Chemtech·February 1999, pp. 39-44. 0 5 See &quot;Chemicals for the Textile Industry&quot; from Rohm and Haas, Philadelphia, 1987 September. 6 See the product list of Rohm and Haas Company of Philadelphia, Pennsylvania, -24- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) --:----- ----·装-----Γ---订--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 __B7 V. INSTRUCTIONS (22) Title: &quot;ROEAQUE8HP-1055, HollowSpherePigmentfo(R) Paper_-and Paperboard Coatings", October 1994, page 1, which is incorporated herein by reference. 7 See Product Technical Bulletin from Rohm and Haas, Inc., Philadelphia, Pa., Title: &quot;Architectural Coatings- ROPAQUE® OP-96. The All Purpose Pigment&quot; April 1997, page 1, incorporated herein as Reference 〇8 ROPAQUE® HP-543P and ROPAQUE® OP-96 are the same materials; this material is considered ROPAQUE® HP-543P in the coatings industry and ROPAQUE® OP-96 in the coatings industry. 9 See Product Technical Bulletin from Rohm and Haas, Inc., Philadelphia, Pa., Title: &quot;Architectural Coatings- ROPAQUE® OP-96· Tbe All Purpose Pigment&quot; April 1997, page 1, incorporated herein as reference. The granules 18 in accordance with the present invention may also be formed from semi-synthetic organic polymeric materials and natural polymeric materials. As used herein, "semi-synthetic material" is a chemically modified material that is naturally occurring. Suitable semi-synthetic organic polymeric materials from which particles 18 can be formed include, but are not limited to, celluloses such as methylcellulose and cellulose acetate; and modified starches such as starch acetate and starch hydroxyethyl ether. Suitable natural polymeric materials from which the particles 18 can be formed include, but are not limited to, polysaccharides such as starch; polypeptides such as casein; and natural hydrocarbons such as natural rubber and ancient papa gel. In a non-limiting embodiment of the invention, polymeric particles 18 are formed from a hydrophobic polymeric material to reduce or limit water absorption by coating the strands. This kind of paper--this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -----------#装------ ---^9. (Please read the note on the back and then fill out this page.) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 ___B7___ V. Invention description (23). Non-limiting examples of water-based polymer materials include However, it is not limited to polyethylene, polypropylene, polystyrene, polystyrene, and polymethyl methacrylate. Non-limiting examples of polystyrene copolymers include ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62 L0 pigments (each discussed above). In another non-limiting embodiment of the invention, polymeric particles 18 are formed from a polymeric material having a glass transition temperature (Tg) and/or a melting point of greater than 25 ° C and preferably greater than 50 ° C. In another non-limiting embodiment of the invention, the particles 18 can be hollow particles formed from materials selected from the group consisting of polymeric and non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and mixtures of any of the foregoing. Non-limiting examples of suitable materials from which hollow particles are formed are as described above. Non-limiting examples of hollow polymeric particles for use in the present invention are ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62LO pigments (each discussed above). Other non-limiting examples of hollow particles useful in the present invention are described in H. Katz et al. (eds.) (1987) pp. 437-452, which is incorporated herein by reference in its entirety.

The granules 18 used in the coating composition of the present invention may be present in a dispersion, suspension or emulsion in water. Other solvents, such as mineral oil or alcohol (preferably less than 5% by weight), may be included in the dispersion, suspension or emulsion, if desired. A non-limiting example of a preferred dispersion of particles formed from an inorganic material is ORPAC BORON NITRIDE RELEASECOAT-CONC, which is a dispersion of 25 weight percent boron nitride particles in water, and is commercially available from ZYP, Oak-Ridge, Tennessee. Coatings company. 'ORPAC BORON -26· This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) --------- armored i丨丨—丨定·丨丨丨丨丨— (Please read the notes on the back and fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Print A7 B7 V. Inventions (24) . NITRIDE REiEASECOAT-CONC·,, Technology of ZYP Coatings - Announcement, It is specifically incorporated herein by reference. The boron nitride particles in this product have an average particle size of less than 3 microns and include 1% magnesium-aluminum silicate to bond the boron nitride particles to the dispersion coated substrate. ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride An independent test using a Beckman Coulter LS 230 particle size analyzer found an average particle size of 6.2 microns, with particles ranging from submicron to 35 microns, and with the following particle distribution: % 10 50 90 size ( Micron) 10.2 5.5 2.4 According to this distribution, 10% of the measured ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles have an average particle size greater than 10·2 microns. Other commercially available products from ZYP Coatings include BORON NITRIDE LUBRICOAT® coatings, and BRAZE STOP and WELD RELEASE products. Specific non-limiting examples of emulsions and dispersions of synthetic polymeric particles formed from a propylene polymer and a copolymer include: RHOPLEX® B-85 propylene emulsion (as discussed above), RHOPLEX® GL-62310, which has a weight of 45 % propylene hard polymer emulsion with % solids and glass transition temperature of 9 S ° C; EMULSION E-232111, which is a hard methyl methacrylate polymer having a solids content of 45 wt% and a glass transition temperature of 105 °C Emulsion; iQPAQUE® OP-96 and ROPAQU3E® HP-543P (for -27- this paper size applicable to National Standard (CNS) A4 (210 X 297 mm) ----------- Pack-----r---book--------- (please read the notes on the back and fill out this page) 1283255 A7 B7 V. Inventions (25) . Discussed above) Provided as a dispersion having a particle size of 0.55 micrometers and a solids content of 30.5 weight percent; ROPAQUE® OP-62 LO (as discussed above), such as a dispersion having a particle size of 0.40 micrometers and a solids content of 36.5 weight percent. Supply; and ROPAQUE® ΗΡ-1055 (as discussed above), such as a dispersion having a solids content of 26.5% by weight Supply; all of them are commercially available from Rohm and Haas of Philadelphia, Pennsylvania. 10 See Product Properties Sheet from Rohm and Haas, Inc., Philadelphia, Pa., &quot;Rhoplex® GL-623, Self-Crosslinking Acrylic Binder of Indrustrial Nonwovens&quot;, March 1997, incorporated herein by reference . 11 See product listings from Rohm and Haas, Inc., of Philadelphia, Pa., &quot;Building Products Industrial Coatings- Emulsion E-2321&quot;, 1990, which is incorporated herein by reference. In a particularly preferred embodiment of the invention, the coating composition comprises at least one inorganic particle (particularly boron nitride, and more particularly a nitriding shed obtained under the trade names POLARTHERM® and/or ORPAC BORON NITRIDE RELEAS3ECOAT-CONC) And a mixture of at least one thermoplastic material, in particular a copolymer of styrene and propylene monomer, and more particularly a copolymer obtained under the trade name ROPAQUE8. The granules 18 are selected to provide an average particle size 19 sufficient to provide the desired spacing between adjacent fibers. For example, the average particle size 19 of the granules 18 of the sizing composition applied to the fibers 12 treated by the air jet loom is preferably selected to provide sufficient fiber strands between at least two adjacent fibers. 〇Air jet transports the interval between overnight weaving machines. As used herein, Air Jet Weave -28 - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) ----- ^----订---1 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 B7 V. Invention Description (26) Machine H indicates that it is from one or more airs in a manner known to those skilled in the art. The strong compressed air of the jet nozzle inserts the fill yarn (weft) into the woven pattern of the fabric in the warp shed. In another example, the average particle size 19 of the granules 18 of the sizing composition applied to the fibers 12 impregnated with the polymeric matrix material is selected to provide sufficient fiber strands 10 between at least two adjacent fibers. Well wet and wet interval. Although not limiting to the invention, the particles 18 preferably have an average particle size of not more than 1000 microns as measured using a laser scattering technique, more preferably from 〇_〇〇1 to 100 microns, and most preferably from 0.1 to 25 microns. . In a particular non-limiting embodiment of the invention, the average economic ministry of the granules 18 of the Intellectual Property Office staff consumption cooperative prints a particle size of 19 of at least 0.1 micron, preferably at least 微米5 microns, and a range of 〇.1 micron. Up to 5 microns, and preferably from 05 microns to 2 microns. In a particular embodiment of the invention, the granules 18 have an average particle size 19 which is generally less than the average diameter of the fibers 12 coated by the coating composition. It has been observed that an interwoven yarn made from a fiber strand 10 having a layer 14 of a first sizing composition comprising particles 16 having an average particle size 19 as discussed above can advantageously be used when impregnated with a polymeric matrix material. Adjacent fibers 23, 25 provide a spacing sufficient to allow air jet weaving power (i.e., air jet transport through the loom) while maintaining the integrity of the fiber strands 10 and providing acceptable wet and wet characteristics. In another specific non-limiting embodiment of the invention, the particles 18 have an average particle size 19 of at least 3 microns, preferably at least 5 microns, and a range of from 3 microns to 100 microns, preferably from 5 microns to 1 inch. 〇〇 micron, and more preferably 1CL to _ 25 microns. In this particular embodiment, it is also preferred that the particles _____ -29- This paper scale has been used in China National Standard (CNS) A4 specification (21() 297 297 public interest) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 ____ B7 --------- --- V. Description of the invention (27) &quot;' The average grain size of 18 is roughly equivalent to the average nominal diameter of the glass fiber. It has been observed that fabrics made from granule strands within 2 inches discussed above exhibit good wet through and wetting characteristics when impregnated with a polymeric matrix material. Those skilled in the art will appreciate that one or more mixtures of particles 18 having different average particle sizes of 19 may be added to the coating composition in accordance with the present invention to impart to the fiber strands 10 and, in turn, products made therefrom. Nature and processing characteristics. More particularly, particles of different sizes may be combined in suitable amounts to provide a strand having S gas jet transport properties and to provide a fabric that exhibits good wet and wet characteristics. The fibers are abraded by contact with the rough surfaces of adjacent solid fibers and/or glass fibers that are in contact with other solid objects or materials that are in contact with subsequent processing (e.g., weaving or spun). As used herein, "wearing" means scraping or cutting a small amount of fiber surface or breaking a fiber due to rubbing contact with particles, edges or the entirety of the material that is damaged by the fiber. See K. Ludema 竿 129, special This is incorporated herein by reference. The wear of the strands has a detrimental effect on the fiber strands, such as breakage of the strands during processing and surface defects such as woven fabrics and composites, which increase waste and manufacturing costs. For example, fibers, particularly glass fibers, contact solid objects such as metal collecting blocks and moving tables or coil springs prior to being wound into a package. In fabric combining operations, such as knitting or weaving, fiberglass strand contacts, such as fiber combinations. An object of a portion of the device (e.g., a loom or knitting device) that is worn to contact the surface 16 of the glass fiber 12. Examples of the loom portion that contacts the fiberglass include air jets and weaving shuttles. Surface roughness of solid objects larger than the hardness of glass fiber can cause 戚-30- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 ^)-----r---^-----I--- (Please read the notes on the back and fill out this page) 1283255

Grinding of glass fiber - 粍. For example, many of the interlacing frames, looms, and knits are formed of a metallic material such as steel having a Mohs hardness of 8π. The abrasion of the glass fiber strands due to the contact of the rough surfaces of these solid objects results in breakage of the strands during processing and surface defects of the products such as woven fabrics and composites, which adds waste and manufacturing costs. 12

Handbook of Chemistry and Physics page F-22. In order to minimize wear, in a non-limiting embodiment of the invention, the particles 18 have a hardness of no more than (i.e., less than or equal to) the hardness of the glass fiber. The hardness of the granules and glass fibers can be determined by any conventional hardness measurement method, such as Vickers or Brinell hardness, but is preferably measured in accordance with the original Mohs hardness scale, which indicates that the surface of the material has a relative scratch resistance of from 1 to 1 Torr. The Mohs hardness 玻璃 of glass fibers typically ranges from 4.5 to 6.5 and is typically 6. R. Weast (editor) Handbook of Ch^mjRtrv and £]1 public 1^, €1^? Yang 8 (1975)? Pp. 22, which is hereby incorporated by reference in its entirety. In this embodiment, the particle 18 Mohs hardness 値 is preferably in the range of 0.5 to 6. A number of non-limiting examples of Mohs hardness of particles formed from inorganic materials suitable for use in the present invention are shown in Table A below. -----------^-----r----------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed

This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 B7 V. Invention description (29) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing - Table A Particle material Mohs hardness, ( Original scale) Boron nitride 213 Graphite 0.5-114 Molybdenum disulfide I15 Talc 1-1.516 Mica 2.8-3.217 Kaolin 2.0-2.518 Gypsum 1.6_219 Calcite (calcium carbonate) 3 20 Calcium fluoride 421 Zinc oxide 4.522 Aluminum 2.523 Copper 2.5-324 Iron 4-525 Gold 2.5-326 Nickel 527 4.828 Platinum 4.329 Silver 2.5-430 Zinc Sulfide 3.5-431 13 K. Ludema, Friction. Wear. Lubrication. (1996) Page 27, its -32- This paper scale applies to China Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) Pack----l.. Order---- Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _B7_ V. Inventive Note (30) is incorporated herein by reference. 14 R· Weast (editor), Handbook of Chemistry and Physics. CRC Press (1975), pp. F-22. 15 R. Lewis, Sr., Hawley's Condensed Chemical Dictionary, (12th Edition, I9%), page 7%, which is incorporated herein by reference. 16 Hawley^ Condensed Chemical Dictionary, (12th Ed. 1993), page 1113, which is incorporated herein by reference. 17 Hawley's Condensed Chemical Dictionary (12th Ed. 1993) at page 784, which is incorporated herein by reference. 18 Handbook of Chemistry and Physics page F-22. 19 Handbook of Chemistry and Physics page F-22. 20 Friction. Wear. Lubrication Page 27. 21 Friction. Wear. Lubrication Page 27. 22 Friction. Wear. Lubrication Page 27. 23 Friction. Wear. Lubrication Page 27. 24 Handbook of Chemistry and Physics page F-22. 25 Handbook of Chemistry and Physics, page F_22. 26 Handbook of Chemistry and Physics, page F_22. 27 Handbook of Chemistry and Physics, page F_22. 28 Handbook of Chemistry and Physics, page F-22. 29 Handbook of Chemistry and Physics, page F-22. 30 Handbook of Chemistry and Physics, page F-22. 31 R. Weast (editor), Handbook of Chemistry and Physics, CRC Press (71: 1990), pp. 4_158. -33- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page). Pack----l·---book---- #· 1283255 Compliance or packet, the granules can be covered by the first cover or the package, 1________ -34 The paper ruler (4) Cai _ home standard (CNS) A4 secret (10) A7 Five 'invention description (31) As mentioned above - 彡 hardness The scale is related to the scratch resistance of the material. The invention is therefore more intended to be particles having a hardness on the surface which is different from the internal hardness of the particles below the surface thereof. More particularly, and as discussed above, the surface of the particles can be modified by any method known in the art including, but not limited to, the use of: techniques known in the art to chemically modify the surface characteristics of the particles such that the surface hardness of the particles is less than or equal to The hardness of the glass fiber, while the particle under the surface = the degree is greater than the hardness of the glass fiber. As a further alternative, particles may be formed from the first material, which is coated with one or more second materials to form a composite having a softer surface. Or a material is formed that is coated with a different form of the first material to form a composite having a softer surface. In the examples, and without limiting the invention, inorganic particles formed from inorganic materials such as tantalum carbide or aluminum nitride may have crushed stone, carbonate or nano-adhesive to form useful composite particles. In another non-limiting example, a decane coupling agent having an alkane side chain can be reacted with an inorganic oxide shaped particle 70, to provide a useful composite particle having a &quot;softer&quot; surface 1 = examples include by non-polymerization or Polymeric materials and different non-polymeric or polymeric materials = formed facing, encapsulated or coated particles. A specific non-limiting example of such a composite particle is DUALITE, which is a synthetic polymeric particle coated with calcium carbonate commercially available from Pierce aild Stevens of Buffalo, New York. In a particular embodiment of the invention, the particles 18 are thermally conductive, i.e., preferably have a temperature of 300 K measured at least 〇2 watts per metre, more preferably every metre to &gt; 0.5 watts (degree of heat transfer) In a non-limiting embodiment, the particles are measured at a temperature of 3 warmth - at least !!! per metre, more preferably; 3-4 - ------------ ---r---订--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 -------- - B7 V. Inventive Note (32) K is at least 5 watts - the degree of heat transfer. In a preferred embodiment, the heat conduction of the particles, once measured at a temperature of 300 K is at least 25 watts per metre, more preferably every metre. κ is at least 30 watts, and even more preferably at least 100 watts per metre. In another preferred embodiment, the thermal conductivity of the particles is measured at a temperature of 300 K ranging from K5 to 2000 watts per meter, preferably per meter. The meter K is 25 to 2000 watts, more preferably 30 to 2000 watts per meter, and most preferably 100 to 2000 watts per meter. The "thermal conductivity" used herein indicates the ability to transfer heat by itself. Graininess See also R. Lewis, Sr., Hawley 1 ^ Con H ^ n Q ^ H Chemical Dictionary, (12th ed., 1993), page 305, which is hereby incorporated by reference in its entirety. Any method known for determination. For example, if the thermal conductivity of the material to be tested ranges from K 0.001 watts per meter to K 100 watts per meter, it can be in accordance with ASTM C-177-85 at a temperature of 300 K (which is specifically incorporated herein). As a reference) the thermal conductivity of the material is determined using the preferred insulated heating plate method. If the thermal conductivity of the material to be tested ranges from κ 20 watts per metre to 1200 watts per metre, it may be in accordance with ASTM C-518-91 (its special – The insulative heat flux sensing method is used to determine the thermal conductivity of a material. In other words, if the thermal conductivity ranges from 0.001 watts per metre to 20 watts per metre, an isolated heating plate method is used. Use an isolated heat flux sensing method for a range of more than 100 watts per meter. For any meter of 20 to 100 watts per meter, use either method. In the isolated heating plate method, use an isolated heating unit. , two auxiliary heating plates, Isolation heating plate unit for cooling unit, edge insulation, temperature control second isolation, and temperature sensor reading system, test two-35- This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) I----------------- III l· III ^ ·11111111 (Please read the note on the back and fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description ( 33), essentially the same I sample. Place the sample on either side of the isolated heating unit -- the opposite surface of the sample is in contact with the auxiliary heating unit. The device is then heated to the desired test temperature and maintained for the time required to obtain a thermally stable state. Once the steady state condition is reached, the heat flow through the sample (Q) and the temperature through the sample (ΔΤ) are recorded. Then calculate the average thermal conductivity (KTC) of the sample using the following formula (1):

KTC = QL / AAT where L is the average thickness of the sample and A is the average of the combined area of the sample. According to the fact that the material having a souther thermal conductivity dissipates faster, the heat generated by the hole region during the drilling operation generates an extended bit life. The thermal conductivity of the selected materials in Table A is included in Table B. Although not necessary, in another embodiment for use in the present invention, the particles are electrically insulating or have a high electrical resistivity, i.e., have a resistivity greater than 1 〇〇〇 micro ohm. For conventional electronic circuit board applications, it is preferred to use particles having a high resistivity and to suppress electrical signal loss due to conduction of electrons through the reinforcement. For special applications, such as those used in microwave ovens, wireless frequency interference, and electromagnetic turbulence applications, particles with high resistivity are not required. The resistivity of the selected materials in Table A is included in Table 8. II------I---0 K-----r---book---------^9. (Please read the notes on the back and fill in this page) -36 - 1283255 A7B7 Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Co., Ltd. V. Instructions for Invention (34)

~ Table B Thermal conductivity of inorganic solid materials (IN/mK at 300K) Resistance (micro ohm·cm) Mohs hardness (original scale) Boron nitride 20032 1.7 X 101933 234 Phosphorus phosphide 35035 - 9.536 Aluminium phosphide 13037 - - Aluminum nitride 200238 is greater than 101939 940 Gallium nitride 17041 - - Gallium phosphide 10042 - Tantalum carbide 27043 4 X 105 to 1 X 106 44 Greater than 945 Tantalum nitride 3046 1019 to 102047 948 Tantalum oxide 24049 - 950 32 G· Slack, &quot;Nonmetallic Crystals with High Thermial Conductivity, J, Phvs. Chem. Solids ^ 1973 ^ vol. 34, pp. 322, incorporated herein by reference. 33 A·Weimqr (Editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 654. 34 Friction, Wear, Lubrication, p. 27. 35 G. Slack, &quot;Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Γ 1973, Vol. 34, page 325, which is hereby incorporated by reference. 36 R. Lewis, Sr., Hawley^ Condensed Chemical Dictionary. (1st Edition, l&quot;f), page 164, which is incorporated herein by reference. -37- This paper size is applicable to China National Standard (CNS) A4 specification (210 297 297 mm) nmnnn II n ϋ a — — ai ϋ ϋ n I i I — eJI n I ϋ I ni^i ί I (please first Read the notes on the back and fill out this page.) 1283255 A7 B7 V. INSTRUCTIONS (35) 37 G. Slack, &quot;i^onmetallic Crystals with High Thermal Conductivity, T Phvs. Chem. Solids (1973) Vol. 34, No. Page 333, which is incorporated herein by reference. 38 G. Slack, &quot;Nonmetallic Crystals with High Thermal Conductivity, T Phvs. Chem. Solids (1973^), vol. 34, pp. 329, incorporated herein by reference. 39 A. Weimer (Editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) Page 654 0 40 Friction. Wear. Lubrication Page 27. 41 G. Slack, ''Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π 973), Vol. 34, p. 333. 42 G. Slack, &quot;Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π 973, Vol. 34, pp. 321, incorporated herein by reference. 43 Microelectronics Packaging Handbook, page 3, which is hereby incorporated by reference. 44 A. Weimer (Editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 653, which is incorporated herein by reference. 45 Friction. Wear. Lubrication ^ 27 pages. 46 Microelectronics Packaging Handbook, page, which is incorporated herein by reference. 47 A. Weimer (Editor), Carbide, Nitride and Boride Materials Synthesis afld Processing, (1997) p. 654. -38 - This paper size is applicable to China National Standard (CNS) A4 specification (210 297 297 mm) (please read the notes on the back and fill out this page)

装-----r I--book--I I #Import Ministry Intellectual Property Bureau employee consumption cooperative printing 1283255 Table B (continued) A7 B7 V. Inventions (36) 48 Friction. Wear, Lubrication Page 27. 49 Microelectronics Packaging Handbook - page 905, which is hereby incorporated by reference. 50 Hawley's Condensed Chemical Dictionary, (12th Ed. 1993), page 141, which is incorporated herein by reference. Inorganic solid material thermal resistance resistance Mohs hardness (IN/mK at 300K) (micro ohm·•cm) (original ruler winter zinc oxide 26 - 4.551 zinc sulfide 2552 2·7 X 105 to 1·2 X l〇i2 53 3.5-454 Diamond 230055 2·7 X 105 55 1057 矽8458 10.059 γ60 Graphite 200061 10062 0.5-163 Molybdenum 13864 5.265 5.566 Platinum 6967 10.668 4.369 凑巴7〇70 10.871 4.872 Iron 20073 5.574 7.575 51 Friction. Wear. Lubrication 27 pages. 52 Handbook of Chemistry and Physics, CRC Press (1975) pp. 12-54. 53 Handbook of Chemistry and Physics· CRC Press (71st edition - -* 1990), pp. 12-6-3, This is incorporated by reference. -39- The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) • 丨:---------#-装 (Please read the back of the note first) Matters fill out this page) Order --- Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed Economy Ministry Intellectual Property Bureau Staff Consumer Cooperatives Printed 1283255 A7 _ B7 _ V. Invention Description (37 ) 54 Handbook of Chemistry and Phvsics· CRC Press (71st edition 1990), 4-158 This is hereby incorporated by reference. 55 Microelectronics Packaging Handbook Page 36. 56 Handbook of Chemistry and Physics. CRC Press (Release 71, 1990) pp. 12-63, which is incorporated herein by reference. 57 Handbook of Chemistry And Physics, page F-22. 58 Microelectronics Packaging Handbook, page 174. 59 Handbook of Chemistry and Physics. Page F-Ιόό, which is incorporated herein by reference. 60 Friction, Wear, Lubrication, p. 61 G. Slack, &quot;Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (; 1973, Vol. 34, p. 322, incorporated herein by reference. 62 See W. Callister, Materials Science and Engineering An Introduction, (2nd ed. 1991), page 637, which is incorporated herein by reference. 63 Handbook of Chemistry and Physics. Page F-22. 64 Microelectronics Packaging Handbook Page 174. 65 Microelectronics Packaging Handbook Page 37 66 Follow &quot;Web Elements&quot; http://www. shef.ac.uk/~chem/web_ elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998)° 67 Microelectronics Packaging Handbook Page 174. 68 Microelectronics Packaging Handbook Page 37. -40- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 297 297 mm) -------------- --„----订--------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Inventions (38) 69 Handbook of Chemistry and Physics. 22 pages. 70 Handbook of Chemistry and Phys Ics, page 37. (Please read the note on the back and fill out this page) 71 Microelectronics Packaging Handbook % 37. 72 Handbook of Chemistry and Physics. Page F-22. 73 Handbook of Chemistry and Physics·第37页74 Microelectronics Packaging Handbook Page 37. 75 According to &quot;Web Elements" http://www.shef.ac.uk/~ctiem/web·elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998). (Continued) Thermal conductivity of inorganic solid materials Mohs hardness (W/mK at 300K) (micro ohm-cm) (original scale) Nickel 9276 6.877 578 20579 4.380 2.581 Chromium 6682 2083 9.084 Copper 39885 1.786 2.5-387 Gold 29788 2.289 2.5-390 Iron 74.591 992 4·593 Silver 41894 1.695 2.5-496 76 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing

Microelectronics Packaging Handbook Page 174. 77 Microelectronics Packaging Handbook Page 37. 78 Handbook of Chemistry and Physics. Page F-22. -41- This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm) Printed by the Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative 1283255 A7 _B7___ V. Invention Description (39) 79 Microelectronics Packaging Handbook Page 174. 80 Microelectronics Packaging Handbook Page 37. 81 Friction. Wear. Lubrication Page 27. 82 Microelectronics Packaging Handbook Page 37. 83 Microelectronics Packaging Handbook Page 37. 84 Handbook of Chemistry and Physics. Page F-22. 85 Microelectronics Packaging Handbook Page 174. 86 Microelectronics Packaging Handbook Page 37. 87 Handbook of Chemistry and Physics. Page F-22. 88 Microelectronics Packaging Handbook Page 174. 89 Microelectronics Packaging Handbook Page 37. 90 Handbook of Chemistry and Physics. Page F-22. 91 Microelectronics Packaging Handbook Page 174. 92 Handbook of Chemistry and Physics. CRC Press (1975), page D-171, which is incorporated herein by reference. 93 Handbook of Chemistry and Physics, page F-22. 94 Microelectronics Packaging Handbook Page 174. 95 Microelectronics Packaging Handbook Page 37. 96 Handbook of Chemistry and Physics. Page F-22. Those skilled in the art will appreciate that the particles 18 of the coating composition of the present invention may comprise any combination or mixture of particles 18 discussed above. More particularly, and without limiting the invention, the particles 18 may comprise any combination of additional particles made from any of the above materials. Therefore, all of the particles 18 do not have to be the same 1 which can be chemically different and/or chemically identical but configured or -42- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -- ---------Install-----:----Book--------- (Please read the notes on the back and fill out this page) 1283255 A7 ____B7 __ V. Invention Note (40) The properties are the same. The additional particles typically comprise at most one half of the plurality of particles 18, preferably 15% of the at most particles 18. In a particular embodiment, the granules 18 comprise from 0.001 to 99% by weight, preferably from 50 to 99% by weight, based on the total solids, and more preferably from 75 to 99% by weight of JL. In this embodiment, particularly preferred coatings include, but are not limited to: i) a coating comprising an organic component and a thin flat particle having a thermal conductivity of at least 1 watt per meter K at a temperature of 300 K; comprising an organic component and a coating of non-hydratable thin flat particles; comprising: at least one boron-free thin ten-grain coating having a thermal conductivity of at least 1 watt per metre K at a temperature of 300 K; iv) comprising a temperature at 300 K An aqueous group residue of a thin flat particle (i.e., a thin flat particle on the fiber) having a thermal conductivity of at least 1 watt per metre; and ν) comprising a thermal conductivity I having a temperature of 300 至少 of at least 10,000 watt per metre. Aqueous composition residue of aluminum-free non-hydratable particles (i.e., aluminum-free hydrated particles on the fibers). In another embodiment, the granules 18 comprise from 0.001 to 99% by weight, preferably from i to 8% by weight, and more preferably from 1 to 40% by weight, based on the total solids. In addition, in the case where the granules 18 are printed by the Intellectual Property Department of the Ministry of Economic Affairs, the Intellectual Property Bureau, the Consumers' Cooperatives-----C, please read the f-face 浲 浲 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦 麦Preferably, the particles comprise from 1 to 50 weight I of the coating composition based on the total solids. / ^ 重量 / 〇 ' and more preferably up to 25% by weight 〇 In another embodiment, the granules 18 comprise more than 20% by weight based on the total solids, preferably in the range of 2 〇 i % by weight, more preferably The range is 25 to 8 wt%, and the best is 50 to 60 wt% of the Jiama Fanyuan. In this embodiment, a particularly good coating composition, a special coating composition,

1283255 A7 B7 V. INSTRUCTIONS (W): Contains: The total solids are greater than 2. At least one weight % selected from the group consisting of inorganic =, organic hollow particles and composite particles, the at least one particle having a Mohs hardness of no more than at least one glass fiber, in another embodiment, The particles 18 comprise from i to 8% by weight, based on the total solids, preferably from 1 to -(d). In a particular embodiment, the coating composition contains particles from 2Q to 6Q% by weight based on total solids, and is from 35 to 55% by weight, and more preferably from 30 to 50% by weight, of the parent. A preferred coating of this embodiment comprises a resin compatible coating comprising (4) a plurality of discrete particles formed from a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof, the particles A lubricating material having an average particle size sufficient to wet the strands without the need for external heat application, at least one different from the plurality of discrete particles; and at least a film forming material. In addition to the granules, the coating composition preferably comprises - two more film forming materials such as organic, inorganic and natural polymeric materials. Useful organic materials include, but are not limited to, polymeric materials selected from the group consisting of synthetic polymeric semi-synthetic polymeric materials, natural polymeric materials, and mixtures of any of the foregoing. Synthetic polymeric materials include, but are not limited to, thermoplastic materials and thermoset materials. More preferably, when applied to the surface 16 of the glass fiber, the polymeric film forming material = forms a substantially continuous film. Generally, the amount of the film-forming material ranges from 1 to 99% by weight based on the total solids of the coating composition. In a specific embodiment, the film-forming material is preferably from 1 to 50% by weight. And more preferably from i to 25% by weight. In another embodiment, the amount of film forming material ranges from 2 〇 to 99 重量, _一鹤 44- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 公 Λ · Μ - - --------t---------0.. (Please read the notes on the back and fill out this page) 1283255 A7 B7 42 V. Invention description (% 'and more 6 〇至8〇重量❶/❶. In another embodiment, the amount of film forming material preferably ranges from 2〇 to 75% by weight, and more preferably from 40 to 50, based on the total solids of the coating composition. % by weight. In this embodiment, a particularly preferred coating comprises a film forming material comprising at least one particle selected from the group consisting of granules, organic hollow particles and composite particles based on total solids, at least one The particles have a Mohs hardness 値 of no more than the Mohs hardness of at least one glass fiber. In another specific embodiment, the amount of polymeric film forming material ranges from i to 6% by weight of the coating composition based on the total solids. Preferably, it is 5 to % by weight /., and more preferably 1 to 3 % by weight. A more preferred coating comprises a resin compatible coating comprising (4) a plurality of discrete particles formed from a material selected from the group consisting of non-thermally swellable organic materials, organic polymeric materials, non-thermally expandable composite materials, and mixtures thereof, the particles having An average particle size sufficient to wet the strands without the need for external heat application; ((1) at least one lubricating material different from the plurality of discrete particles; and (4) at least one film forming material. In a non-limiting embodiment of the invention, The thermosetting polymeric film forming material is a preferred polymeric film forming material for coating a glass fiber strand coating composition. The material is in phase with a thermosetting matrix material as a laminate of a printed circuit board, such as FR-4 1 An oxygen resin, which is a polyfunctional epoxy resin, and is a difunctional brominated epoxy resin in the present invention (particularly a specific embodiment. See Electronic Materials Handb00kTM ASM Internati〇nai (1989) 5th 537 stomach, It is specifically hereby incorporated by reference. I.__________-----^---------(Please read the notes on the back and fill out this page) Consumer Cooperatives Printed -45- 1283255 A7 B7 V. INSTRUCTIONS (43) Usable thermosetting materials include thermosetting polyester, epoxy, acetamidine, phenolic, amine-based plastics, thermosetting polyamines Acid esters, and mixtures of any of the above. Suitable thermosetting polyesters include STYPOL polyester, commercially available from Cook Composites and Polymers of Kansas, Missouri, and NEOXIL polyester, commercially available from Como, DSM, Italy. V. Company. A non-limiting example of a thermoset polymeric material is an epoxy material. Useful epoxy materials contain at least one epoxy or oxirane group in one molecule, such as a polyglycidyl ether of a polyhydric alcohol or a thiol. Examples of suitable epoxy-based film forming polymers include ΕΡΟΝ® 826 and ΕΡΟΝ® 880 epoxies commercially available from Shell Chemical Company of Houston, Texas. Useful thermoplastic polymeric materials include acetamyl polymers, thermoplastic polyesters, polyolefins, polyamines (eg, aliphatic polyamines or aromatic polyamines such as aromatic guanamine), thermoplastic polyurethanes. , a propylene polymer (such as polyacrylic acid), and a mixture of any of the above. In another non-limiting embodiment of the invention, the preferred polymeric film forming material is an ethylene polymer. Useful ethylene polymers of the present invention include, but are not limited to, polyvinylpyrrolidone, such as PVP K-15, PVP K-30, PVP K-60, and PVP K-90, each commercially available from Wayne, New Jersey. International Specialty Products Chemicals. Other suitable ethylene polymers include RESYN 2828 and RESYN 1037 vinyl acetate g copolymer emulsions, commercially available from National Starch and Chemical Company of Bridgewater, Jersey, and other polyvinyl acetates, such as commercially available from Η· B. Fuller Company and Air Products and -46- of Allentown, Pennsylvania This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) Intellectual Property Bureau Staff Consumption Cooperatives Ministry of Printing and Economy Ministry Intellectual Property Bureau Staff Consumer Cooperatives Printing Clothing 1283255 A7 ___B7__ V. Invention Description (44) '

Chemicals, and polyvinyl alcohol, also available from Air Products ancT Chemicals, Inc. 0 The thermoplastic polyesters used in the present invention include DESMOPHEN 2000 and DESMOPHEN 2001 KS, both of which are commercially available from Bayer Corporation of Pittsburgh, Pa. Preferred polyesters include RD-847A polyester resin commercially available from Borden Chemicals, Columbus, Ohio, DYNAKOLL Si 100, chemically modified rosin, commercially available from Eka Chemicals AB, Sweden. Useful polyamines include the VERSAMID product, commercially available from Cognis Corporation of Cincinnati, Ohio, and the EUREDOR product from Ciba Geigy, Belgium. Useful thermoplastic polyurethanes include WITCOBOND® W-290H, commercially available from CK Witco of Greenwich, Connecticut, and RUCOTHANE® 2011L polyurethane latex, commercially available from Hicksville, New York. Ruco Polymer The coating composition of the present invention may comprise a mixture of one or more thermoset polymeric materials and one or more thermoplastic polymeric materials. In a non-limiting embodiment of the invention particularly useful for laminates of printed circuit boards, polymeric materials for aqueous sizing compositions include RD-847A polyester resin, PVPK-30 polyvinylpyrrolidone, DESMOPHEN 2000 poly A mixture of ester and VERSAMID poly 8 amide. In an alternative non-limiting embodiment of a laminate suitable for use in a printed circuit board, the polymeric material of the aqueous sizing composition comprises PVP K-30 polyvinylpyrrolidone, optionally combining EPON 826 epoxy resin . Semi-synthetic polymeric materials suitable as polymeric film forming materials include, but are not limited to - 47- This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) ί ϋ ϋ ϋ ·ϋ ϋ ϋ ϋ ^1 I aaLi w MB w IBM (please read the notes on the back and fill out this page) 1283255

For cellulose 7 such as hydroxypropyl cellulose, and modified starches such as KOLLOTEX 1250 (low viscosity low amylose potato chips based on ethylene oxide), commercially available from AVEBE in the Netherlands the company. Knives. Natural polymeric materials suitable as polymeric film forming materials include, but are not limited to, powders prepared from potato, corn, wheat, waxed corn, sago, rice, Milo, and mixtures of any of the foregoing. It will be appreciated that depending on the nature of the starch, starch can be used as the particulate 18 and/or film forming material. More particularly, some starches are completely soluble in the solvent, especially in water, and as a film forming material, while others do not completely dissolve and maintain a particular particle size and act as particles 18 . Although starch (natural and semi-synthetic) can be used in accordance with the present invention, the coating composition of the present invention is preferably substantially free of starch material. As used herein, the term "substantially free of starch material" means that the coating composition comprises less than 5% by weight, based on the total solids of the coating composition, of starch material, preferably less than 35% by weight. More preferably The coating composition of the present invention is substantially free of starch material. As used herein, the term "essentially free of starch material" means that the coating composition comprises less than 20% by weight, based on the total solids of the coating composition, preferably. It is less than 5% by weight, and more preferably is a starch-free material. The typical starch-containing starch coated on the fiber strands of the laminates added to the printed circuit board is not resin-compatible and must be removed prior to the addition of the polymeric matrix material by the Ministry of Economics, the Intellectual Property Administration, and the Consumers' Co., Ltd. As previously discussed, it is preferred that the coating composition of the present invention be resin compatible and need not be removed from the fiber strands or fibers prior to fabric treatment. More preferably, the coating composition of the present invention is compatible with the matrix material (discussed below) for manufacturing a printed circuit board, and is preferably an epoxy resin. The paper size is applicable to the Chinese National Standard 7&quot;CNS) A4 Specification (10) X 297 Public meal)---- A7

1283255 V. Description of invention (46) Capacitive. The polymeric film forming material can be water soluble, emulsifiable, dispersible, and/or hardenable. &quot;Water Soluble&quot; as used herein means that the polymeric material can be substantially uniformly blended and/or molecularly or ionically dispersed in water to form a tamping solution. See Ha Mey's, page 1, page 75, which is hereby incorporated by reference in its entirety. &quot;Emulsifying&quot; means that the polymeric material can form a negative ampule mixture or suspension in water in the presence of an emulsifier. See Hawlev&apos;s page 461, which is hereby incorporated by reference in its entirety. Non-limiting examples of suitable emulsifiers are summarized below. Any component that can be dispersed to indicate a polymeric material can be distributed throughout the water, such as latex, as finely divided particles. See,Hawlev, 435 pages, which is hereby incorporated by reference in its entirety. The uniformity of the dispersion can be increased by the addition of wetting, dispersing or emulsifying agents (surfactants) as discussed below. By "hardenable" is meant that the polymeric material and other components of the sizing composition can be formed into a film or crosslinked to each other to alter the physical properties of the polymeric material. See Hawley's page 331, which is incorporated herein by reference in its entirety. In addition to or in lieu of the film forming materials discussed above, the coating composition of the present invention preferably comprises one or more glass fiber coupling agents, such as organic; ^ entertainment ^ horse mixture, transition metal coupling agent, phosphoric acid coupling agent, aluminum A coupling agent, an amine-containing Werner coupling agent, and a mixture of any of the above. These couplers have a dual function. Each metal or germanium atom has one or more base linkages which are directly reactive or compatible with the fiber surface and/or the components of the resin matrix. The term "compatible" as used herein refers to a chemically bonded (eg, by polarity, wetting or solvent combination) but does not bond the surface of the fiber and/or the composition of the coating composition - in a non-limiting embodiment. , each metal or germanium atom has -49- This paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) — — — — — — — — — I · III l· III « — — — — — — I— Awl (Please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed A7 B7 V. Invention Description (47) More than -% allows the coupler to react with the hydrolyzable group on the surface of the glass fiber' and one or more of the functional groups of the coupler reactive resin matrix component. Examples of hydrolyzable groups include: 〇Η 0 R3 II I II I 5 ^ -OR1, -OC-R2, -Ν...C-R2, -0-N=C-R4, -〇-N=CR, and monohydroxy and/or 1,2- or 1,3- a cyclic C2-C3 residue of a diol wherein R1 is CVC3 alkyl; R2 is hydrazine or CrQ alkyl; R3 independently of r4 From oxime, CVC4 alkyl or C5-C6 aryl; and R5 is C4-C7 alkyl. Examples of suitable compatible or functional groups include epoxy, diglycidyl, arsenyl, cyano, olefin a propyl group, an alkyl group, an aminocarboxylic acid group, a self-based group, an isocyanato group, a ureido group, an imidazolinyl group, a vinyl group, an acryl group, a methacryl group, an amine group or a polyamine group. A functional organic decane coupling agent Preferred for use in the present invention. Examples of useful functional organodecane coupling agents include γ-aminopropyltrialkoxydecane, γ-isocyanatopropyltriethoxysulfonium, vinyltrialkoxy Terpine, deglyceryl propyl trialkoxy decane, and ureidopropyl trialkoxy decane. Preferred functional organic sinter coupling agents include Α-187 γ-dehydroglyceryl propyl trimethoxy hydride Calcined, Α-174 γ-methacryloxypropyltrimethoxyacetate, a-1100 γ-aminopropyldiethoxy oxyalkylene coupling agent, A-1108 amine based sinter coupling agent, and A- 1160 γ-ureidopropyl triethoxy decane (commercially available from CK Witco, Tarrytown, NY). Organic decane coupling agents can be used in fiber applications At least partially hydrolyzed with water, preferably 1 · 1 chemistry - 50 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 gong*) -n ϋ in — ϋ n MMmae in «1 I · ϋ βϋ nn ϋ n 03⁄4. · ϋ n ϋ ϋ n I ·ϋ 1 (Please read the note on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed 1283255 A7 _ B7__ V. Description of invention ( 48) Amount ratio, as required by j or in unhydrolyzed form. The pH of the water can be modified by the addition of an acid or a base to initiate or accelerate the hydrolysis of the coupling agent, as is known in the art. Suitable transition metal coupling agents include pitch, error, dry and complex coupling agents. Suitable titanate couplers and citrate couplers are commercially available from Kenrich Petrochemical. A suitable complex is commercially available from E.I. DuPont de Nemours, Wilmington, Delaware. The amine group-containing Werner type coupling agent is a complex compound in which a trivalent nuclear atom such as chromium is coordinated with an organic acid having an amino functional group. Other metal chelating agents and coordination type coupling agents known to those skilled in the art can be used herein. The amount of coupling agent will generally range from 1 to 99% by weight of the coating composition based on the total solids. In a particular embodiment, the amount of coupling agent ranges from 1 to 30% by weight, preferably from 1 to 10% by weight, and more preferably from 2 to 8% by weight, based on the total solids of the coating composition. The coating composition of the present invention may further comprise one or more softeners or surfactants which impart a uniform charge to the surface of the fibers, causing the fibers to repel each other and reduce friction between the fibers to act as a lubricant. Although not necessary, it is preferred that the softening agent be chemically different from the other components of the coating composition. Such softeners include cationic, nonionic or anionic softeners and mixtures thereof, such as amine salts of fatty acids, alkyl imidazoline derivatives (such as CATION X, commercially available from New York: Rhone Poulenc of Princeton, Jersey) /Rhodia Company), soluble acid fatty acid decylamine, fatty acid and poly(ethyleneimine) and decylamine-substituted bis-diimide (such as EMERY® 6717, part of the amide-densified polyethylene-2) Commercially available from Cognis -51- Cincinnati, Ohio - This paper scale applies to the Chinese National Standard (CNS) A4 specification mo X 297 mm) 1^1 B^in ϋ ϋ βϋ n ϋ al·— HI 0 i ϋ ϋ flal· Nn ϋ ---------- (Please read the notes on the back and fill out this page) 1283255 A7

Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printing, five, invention description (49) company) condensate. While the coating composition may comprise up to 6% by weight of softening agent, preferably the coating composition comprises less than 2% by weight and more preferably less than 5% by weight of softener. For more information on softeners, see A j Hall, Textile Finishings, 2nd Edition (1957), pp. 108-115, which is hereby incorporated by reference in its entirety. The coating composition of the present invention may further comprise one or more lubricating materials which are chemically different from the polymeric materials and softeners discussed above to impart the desired processing characteristics to the fiber strands during weaving. Suitable lubricating materials can be selected from the group consisting of oils, ants, months EJ, and mixtures of any of the foregoing. Non-limiting examples of the crucible material used in the present invention include water-soluble, emulsifiable or dispersible wax materials such as vegetables, animals, minerals, synthetic or petroleum ants, for example, bonded hydrocarbons. The oil used in the present invention includes natural oils, semi-synthetic oils, and synthetic oils. Typically, the amount of wax or other lubricating material ranges from 〇 to 8 〇 weight/〇, preferably from 1 to 50% by weight, more preferably from 20 to 40% by weight, based on the total solids of the sizing composition, and most preferably 25 to 35 wt%. Preferred lubricating materials include waxes and oils having polar characteristics, and more preferably include southern crystal creeps having a polar character and a melting point higher than 35 X: and more preferably higher than 45 °C. The fiber strands coated with a sizing composition comprising a butterfly and oil having no polar character are compared, which is believed to improve the wetting and wetting of the polar resin on the fiber strands of the pulp composition containing the polar material. A preferred lubricating material having a polar character includes an ester formed by the reaction below.

(1) a monocarboxylic acid and (2) a monohydric alcohol. Non-limiting examples of such fatty acid esters for use in the present invention include preferred cetyl palmitate (e.g., KESSCO 653 or STEPANTEX ____ -52 from Stepan Corporation, Maywood, New Jersey). National Standard (CNS) A4 Specification (21〇χ 297 mm) - I---r---^ ---- 111 — » (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Employee consumption cooperative printed 1283255 A7 _^_B7___ _ V. Invention description (50)

653 ), nutmeg - cetyl ester (also available from STEPANLUBE 654 from StePan), cetyl laurate, octadecyl laurate, octadecyl myristate, octadecyl citrate, and hard Octadecyl citrate. Other fatty acid esters and lubricating materials useful in the present invention include trimethylolpropane tridecanoate, natural cetyl and triglycerin such as, but not limited to, soybean oil, linseed oil, epoxidized soybean oil, and epoxidized sub- sesame oil. The lubricating material may also include a water soluble polymeric material. Non-limiting examples of useful materials include polyalkylene polyols and polyoxyalkylene polyols, such as MACOL E-300, commercially available from BASF Corporation of Parsippany, New Jersey, and CARBOWAX 300 and CARBOWAX 400, commercially available from Union Carbide, Danbury, Connecticut. Another non-limiting example of a usable lubricant is POLYOX WSR 301, which is commercially available from Connecticut.

Polybury (Union Carbide) from Danbury. Instead of or in addition to the lubricating materials discussed above, the coating compositions of the present invention may additionally comprise one or more other lubricating materials, such as non-polar petroleum waxes. Non-limiting examples of non-polar petroleum waxes include MICHEM® LUBE 296 microcrystalline wax, POLYMEKON® SPP-W microcrystalline wax, and PETROLITE 75 microcrystalline silicon, each of which is commercially available from Michelman of Cincinnai, Ohio, and Cumming, Georgia. Baker Petrolite, Polymer Division. Typically, the amount of this type of wax is up to 10% by weight of the total solids of the sizing composition. The coating composition of the present invention may also include a resin reactive diluent to reduce fine hair, pores and pores by the manufacturing operation herein. The possibility of rupturing the filament while maintaining the resin compatibility, and further improving the coated fiber strand-53- of this invention applies the Chinese National Standard (CNS) A4 specification (21〇x 297 mm) (please Read the notes on the back and fill out this page) | Pack---I L----Book i! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _B7__ V. Invention Description (51) Lubrication, and _ Weaving and knitting provide good handling. As used herein, a resin reactive diluent &quot; means that the diluent comprises a functional group that chemically reacts with the same resin that is compatible with the coating composition. The diluent may be any lubricating material having one or more functional groups reactive with the resin system, preferably a functional group of the reactive epoxy resin system, and more preferably a functional group of the reactive FR-4 epoxy resin system. . Non-limiting examples of suitable lubricants include those having an amine group, an alcohol group, an anhydride group, an acid group or an epoxy group. A non-limiting example of a lubricant having an amine group is a modified polyethylene diamine, for example, EMERY 6717, which is a partially amided poly(ethyleneimine) commercially available from Cognis Corporation of Cincinnati, Ohio. A non-limiting example of a lubricant having an alcohol group is polyethylene glycol, for example, CARBOWAX 300, which is a polyethylene glycol commercially available from Union Carbide Corporation of Danbury, Connecticut. Non-limiting examples of lubricants having an acid group are fatty acids, for example, salts of stearic acid and stearic acid. Non-limiting examples of lubricants having epoxy groups include epoxidized soybean oil and epoxidized linseed oil, for example, FLEXOL LOE, which is an epoxidized linseed oil, and FLEXOL EP0, which is an epoxidized soybean oil, all commercially available from Union Carbide, Inc. of Danbury, Connecticut, and LE-9300 epoxidized polyoxylized emulsion, commercially available from CK Witco, Inc. of Tarrytown, OH. Although not limiting in the present invention, the sizing composition may comprise a resin reactive diluent as discussed above in an amount of up to 15% by weight based on the total solids of the sizing composition. The coating composition may additionally comprise one or more emulsifiers to emulsify or disperse components of the coating composition, such as particles 18 and/or lubricating materials. Non-limiting examples of suitable emulsifiers or boundary active agents include polyoxyalkylene alkyl blocks -54- This paper scale applies to the Chinese National Standard &lt;CNS) A4 specification (210 X 297 mm) (please read the back first) Note: Please fill out this page) - Installed and ordered - 丨丨丨丨 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (52) . Polymer (such as PLURONICTM F-108 polyoxypropylene-polyethylene oxide copolymer _ · _, commercially available from BASF of Parsippany, New Jersey (PLURONICTM F-108 copolymer is available under the trade name SYNPERONIC F-108 in Europe), ethoxylated Alkanols (such as IGEPAL CA-630 ethoxylated octylphenoxyethanol, commercially available from GAF, Wayne, New Jersey), polyoxyethylene octyl phenyl glycol ether, and epoxy resin Ethane derivatives (eg TMAZ 81, commercially available from BASF, Parsippany, Jersey), polyoxyethylated vegetable oils (eg ALKAMULS EL-719, commercially available from Rhone-Poulenc/Rhodia), ethoxylation Dress up (such as MACOL OP-10 SP, which is also commercially available from BAS F company), and phenolic surfactants (such as MACOL NP-6 and ICONOL NP-6, which are also commercially available from BASF Corporation, and SERMUL EN 668, commercially available from CON BEA, Benelux). Usually, emulsifiers The amount ranges from 1 to 30% by weight, preferably from 1 to 15% by weight, based on the total solids. Crosslinked materials such as melamine formaldehyde, and plasticizers such as phthalate, trimellitate and The diester may also be included in the coating composition. The amount of the crosslinking agent or plasticizer may range from 1 to 5% by weight based on the total solids of the coating composition. Other additives may be included in the coating composition. Such as polyoxygen, bactericide, bactericide and antifoam material, which is usually less than 5% by weight. Organic and / or inorganic acid or alkali sufficient to provide the pH of the coating composition 2 to 10 Included in the coating composition. A non-limiting example of a suitable polyoxynoxy emulsion is LE-9300 epoxidized polyoxyxide emulsion, commercially available from Tarrytown, NY, CK Witco, Inc. Examples of suitable bactericides are -55- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ---------- &quot; ^ set --------- -------- installed (Read the back of the precautions to fill out this page) 1283255 A7 B7

The company is from M&amp;TChemicals, Inc. of Rahway, Jersey. An example of a suitable anti-mu material is full material 'commercially available from Connecticut (3) (4) (3) chest. The company, and MAZU DF.136, is commercially available from Jersey Co., Ltd. (4). If desired, the oxyhydrogen can be applied to the enamel coating. Preferably, &apos;water, and more preferably deionized water, is included in the coating composition in an amount sufficient to facilitate coating a substantially uniform coating on the strands. The solids by weight of the coating composition typically ranges from i to 2% by weight. BIOMET 66 Technical Microbial Compound, Commercial Intelligence Department Intellectual Property Officer X Consumer Cooperative Printed In a specific embodiment, the coating composition of the present invention is substantially free of glass material. As used herein, &quot;substantially no glass material&quot; means that the coating composition comprises &gt; at 50% by volume of the glass-forming matrix material forming the glass-breaking composite, preferably less than 35% by volume. In a more preferred embodiment, the coating composition of the present invention is substantially free of glass material. As used herein, "there is essentially no glass material" means that the coating composition comprises less than 2% by volume of the glass-forming matrix material forming the glass composite, preferably less than 5% by volume, and more preferably no glass. Materials. Examples of such glass matrix materials include black glazed ceramic matrix materials or aluminosilicate matrix materials, as is known to those skilled in the art. In a particular embodiment of the invention, fiber strands comprising a plurality of fibers are A coating comprising an organic component and thin flat particles having a thermal conductivity of at least 1 watt per meter K at a temperature of 300 K is at least partially coated. In another embodiment, a fiber strand comprising a plurality of fibers is included The coating of the organic component and the non-hydratable thin flat particles is at least partially coated. In these embodiments, the organic component and the thin flat particles may be selected from the coating components discussed in the soil. The organic component and the thin flat particles may be Same or different' and the coating can be water-based coating ----------------------------------------------------------------- National Standard (CNS) A4 Specification (21〇X 29 7 mm) 1283255 Ministry of Economic Affairs Intellectual Property Office employee consumption cooperation Du printing A7 B7 V. Invention Description (54) Layer composition residue-slag or powder coating composition. In another embodiment, including multiple The fiber strands of the fibers are at least partially coated with a coating comprising at least one boron-free thin flat particle having a thermal conductivity of at least 1 watt per metre at a temperature of 30 〇 K. In another embodiment, The fiber strands of the plurality of fibers are at least partially coated with an aqueous composition residue comprising boron-free thin flat particles having a thermal conductivity of at least 1 watt per metre at a temperature of 300 Torr. In another embodiment, The fiber strands of the plurality of fibers are at least partially coated with an aqueous composition residue comprising aluminum-free, non-hydratable particles having a thermal conductivity of at least 1 watt per metre at a temperature of 300 Torr. The ingredients of these embodiments are optional. The coating composition discussed above, and the additional ingredients may also be selected from the above. In another embodiment of the invention, the fiber strand comprising the plurality of fibers is at least a portion of the surface of at least one of the fibers. on At least partially coated with a resin compatible coating composition comprising: (a) a plurality selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof a discontinuous particle formed by the material, the particle having an average particle size sufficient to wet the strand; (b) at least one lubricating material different from the plurality of discrete particles; and (4) at least one film forming material. Selected from the coating components discussed above. In another embodiment, the plurality of discrete particles provide a gap space between at least one of the fibers and at least one adjacent fiber. In another embodiment, comprising more The fiber strands of the fibers are at least a portion of the surface of the fiber with a resin compatible coating composition to x 297 mm) I I--IIII -----..----^ --I I----- (Please read the notes on the back and fill out this page) 5 52 3 82 A7B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 5, Inventions (55) A small part of the province , the resin compatible coating composition α · (a) a plurality of particles, each of which (1) at least one particle formed of an organic material; and (ii) at least one inorganic material selected from the group consisting of boron nitride, graphite, and a metal dichalcogenide a granule formed, wherein the plurality of granules have an average particle size sufficient to wet the strand; (b) at least one lubricating material different from the plurality of discrete particles, and (4) at least one film forming material. In another embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with a resin compatible coating composition on at least a portion of a surface of at least a portion of the fibers. The article comprises: (a) a plurality of discontinuous particles formed of a material selected from the group consisting of organic materials, inorganic polymeric materials, composite materials, and mixtures thereof, the particles having an average particle size ranging from 0.1 to 5 microns in accordance with a laser scattering technique; (b) at least one lubricating material different from the plurality of discontinuous particles; and (c) at least one film forming material. In another embodiment, the above-described resin-compatible coating composition contains (4) from 20 to 60% by weight, preferably from 35 to 55% by weight, and more preferably from 30 to 50% by weight, based on the total solids. a discontinuous particle; (b) at least one lubricating material based on the total solids to 80% by weight, preferably from 1 to 50% by weight, and more preferably from 20 to 40% by weight; and (c) based on total solids 1 to 60% by weight, preferably 5 to 50% by weight, and more preferably 10 to 30% by weight of at least one film forming material. In another embodiment of the present invention, a fiber strand comprising a plurality of fibers is at least partially coated with a resin compatible coating composition on at least a portion of a surface of at least one of the fibers, the resin being compatible The coating composition comprises: (a) a plurality of materials selected from the group consisting of organic materials, composite materials and mixtures thereof - 58- This paper scale applies to the Chinese National Standard &lt;CNS) A4 specification (210 X 297 mm) )-----r---book--------- ^•1 (Please read the notes on the back and fill out this page) 1283255, invention description (56) discontinuous non-symptomatic particles The particles have an average particle size ranging from 0.1 to 5 microns in accordance with a laser scattering technique; and (3⁄4) at least one lubricating material different from the plurality of discrete particles. In another embodiment of the present invention, a fiber strand comprising a plurality of fibers is at least partially coated with a resin compatible coating composition on at least a portion of a surface of at least one of the fibers, the resin being compatible The coating composition comprises at least one particle selected from the group consisting of inorganic particles, organic hollow particles and composite particles based on total solids, the at least one particle having a Mohs hardness of no more than at least one Mohs hardness of the fiber value. In another embodiment of the present invention, a fiber strand comprising a plurality of fibers is at least partially coated with a resin compatible coating composition on at least a portion of a surface of at least one of the fibers of the child, the resin being compatible The coating composition comprises: (4) at least one thin flat inorganic particle having a Mohs hardness of not more than at least one Mohs hardness of the fiber; and (b) at least one polymeric material. In an additional embodiment of the present invention, the fiber-optic strand comprising a plurality of fibers has at least a portion of the surface of at least one of the fibers of the enamel fiber as a resin-compatible coating composition. Partially coated, the resin compatible coating composition comprises: (a) at least one hollow non-thermally expandable organic particle; and (8) at least one lubricating material different from at least one hollow organic particle. The ingredients in each of the above specific examples are selected from the coating components discussed above, and the other ingredients may also be selected from the above. In a particular embodiment of the invention, the fiber is coated with a composition comprising an organic component and a thin flat particle having a thermal conductivity of at least 1 watt per meter K at a temperature of 300 K. In another embodiment, the fiber coating Contains organic into -59-

Combination:::... compound. In another case, Zhao Shiyuan I Fiber Coating: Contains at least one composition of boron-free thin flat particles having a working temperature of κ 芏 V1 wattage per square meter. In another embodiment, the fiber coating comprises having a temperature of 3 cans: solid: at least! A composition of thin flat particles of thermal conductivity of the tile. In another embodiment, the fiber coating comprises a grade having a thermal conductivity of from κ' to 1400 watts per metre and no aluminum non-hydratable inorganic particles. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1283255 In another exemplary embodiment of the present invention, fiber coating: comprising a composition: (4) a plurality of (four) self-expandable organic materials, materials, non-heatable expanded composite materials The material shape of the mixture and the mixture thereof: the continuous H particles have an average particle size sufficient to wet the strands; (9) at least one lubricating material different from the plurality of discontinuous particles; and (4) at least a film forming material. In another embodiment, the fiber coating package comprises: (4) a plurality of particles comprising (1) at least one of cerium particles formed from an organic material; and (8) at least one selected from the group consisting of nitriding, graphite And particles formed of an inorganic material of a metal dichalcogenide wherein the plurality of particles have an average particle size sufficient to wet the strand; (b) at least one lubricating material different from the plurality of discrete particles; and (c) at least Film forming material. In another specific embodiment, the fiber coating comprises a composition comprising: (a) a plurality of discrete particles formed from a material selected from the group consisting of organic materials, inorganic polymeric materials, composite materials, and mixtures thereof, the particles having a The scatter technique measures the average grain size of 范. to 5 microns; and (b) at least - a lubricating material different from the plurality of discontinuous particles; and (c) at least - forming a material 匕.

-60- 1283255

In another embodiment of the present invention, the composition: (8) a plurality of discontinuous (four) (four) particles formed of a material selected from the group consisting of organic materials, complex materials:: I, below (please read the notes on the back) Fill in this page) The shooting technology measurement range is...^micron level: there is a lubricating material that is different from the plurality of discontinuous particles according to the laser dispersion. In another embodiment, the fiber-coated composition comprising the resin-compatible coating composition comprises a lipid-compatible coating composition comprising at least 20% by weight based on total weight, selected from inorganic particles, organic hollow Granules and composite particles, the particles having a Mohs hardness 不 not exceeding the Mohs hardness of the fibers. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed In another embodiment of the invention, the fiber coating comprises a composition comprising: (a) at least one thin flat inorganic particle; and (b) at least one polymeric material. In another embodiment of the invention, the fibers are coated with a composition comprising: (a) a plurality of hollow non-thermally expandable organic particles; and (7) at least one polymeric material different from at least one hollow organic particle. In an additional embodiment of the invention, a fiber coated resin compatible coating composition having a first coating of a sizing composition on at least a portion of the surface of the fiber and comprising an aqueous coating composition A second coating comprising a plurality of discrete particles coated on at least a portion of the first coating of the sizing composition. The ingredients in each of the above specific examples are selected from the coating components discussed above, and the other ingredients may also be selected from the above. In a non-limiting embodiment of the invention, at least a portion of at least one of the fibers of the fiber strands of the present invention comprises P0LARTH3ERM® 160 boron nitride powder and/or BORON NITRIDE RELEASECOAT dispersion, • 61 - Ben Paper scale applicable to China National Standard (CNS) A4 specification (21〇χ 297 mm) 1283255 A7 B7 V. Invention description (59), EPON 826 ring oxy-film forming material, PVP K-30 polyvinylpyrrolidine. -monoketone, A-187 epoxy functional organodecane coupling agent, ALKAMULS EL-719 polyoxyethylated vegetable oil, IGEPAL CA-630 ethoxylated octylphenoxyethanol, KESSCO PEG 600 polyethylene glycol Lauric acid ester (commercially available from Stephan Corporation of Chicago, Ill.), and EMERY® 6717 partially amided agglomerated aqueous coating composition. In another non-limiting embodiment of the present invention for woven fabric, at least a portion of at least one of the fibers of the fiber strand of the present invention is coated with a POLARTHERM® 160 boron nitride powder and/or a BORON NITRIDE RELEASECOAT dispersion. , RD-847A polyester, PVP K-30 polyacetylpyrrolidone, DESMOPHEN 2000 polyester, A-174 propylene functional organodecane coupling agent, and A-187 epoxy functional organodecane coupling agent, Dry residue of aqueous sizing composition of PLURONIC F-108 poly(propylene oxide)-polyoxyethylene copolymer, MACOL NP-6 decyl phenol surfactant, VERS AMID 140, and LE-9300 epoxidized polyfluorenone emulsion.

In a non-limiting specific embodiment of another fabric for an electronic circuit board of the present invention, at least a portion of at least one of the fibers of the fiber strand of the present invention is coated with POLARTHERM® PT 160 boron nitride powder and/or Or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion, PVP K-30 polyvinylpyrrolidone, A-174 propylene functional organodecane coupling agent, A-187 epoxy functional organodecane coupling agent, ALKAMULS EL- 719 polyoxyethylated vegetable oil, EMERY® 6717 partially amided poly(ethyleneimine), RD-847A polyester, DESMOPHEN 2000 polyester, PLURONICLF-108 polyoxypropylene-polyoxyethylene copolymer, ICONOL - 62- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back and fill out this page). Order---- Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 _B7__ V. Description of invention (6〇) NP-6 alkoxylated phenol, and SAG 10 anti-foaming material aqueous coating composition. If desired, this particular embodiment may additionally include ROPAQUE® HP-1055 and/or ROPAQUE® OP-96 styrene-propylene copolymer hollow spheres. In a non-limiting embodiment of another fabric for an electronic circuit board of the present invention, at least a portion of at least one of the fibers of the fiber strand of the present invention is coated with POLARTHERM® PT 160 boron nitride powder and/or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Dispersion, RD-847A Polyester, PVP K-30 Polyvinylpyrrolidone, DESMOPHEN 2000 Polyester, A-174 C#-Based Functional Organic Decane Coupler, A-187 Epoxy An aqueous functional octane coupling agent, a PLURONIC F-108 polyoxypropylene-polyoxyethylene copolymer, VERSAMID 140 polyamide, and an aqueous sizing composition of MACOL NP-6 nonylphenol. If desired, this particular embodiment may optionally include ROPAQUE® HP-1055 and/or ROPAQUE® OP-96 styrene-propylene copolymer hollow spheres. In a non-limiting embodiment of the fabric for woven laminated printed circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with ROPAQUE® HP-1055 and/or Or R0PAQUE® OP-96 styrene-propylene copolymer hollow spherule, PVP K-30 polyvinylpyrrolidone, A-174 propyl #yl functional organodecane coupling agent and A-187 epoxy functional organic Decane coupling agent, EMERY® 6717 partially amidedized polyethyleneimine, STEPANTEX 653 palmitate palmitate, TMAZ 81 decyl alcohol ester ethylene oxide derivative, MACOL OP-10 ethoxylated alkylphenol, And M^ZU DF-136 anti-foam material aqueous first coating composition residual -63- This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) --------- --装-----„----订---------^9. (Please read the notes on the back and fill out this page) 1283255 Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative A7 B7 V. INSTRUCTIONS (61) ^ Slag. Although 1 is not necessary, this particular embodiment preferably includes -POLARTHERM8 PT 160 boron nitride powder and / or ORPAC BORON NITR IDE RELEASECOAT-CONC 25 Dispersion. In a non-limiting embodiment of another fabric for an electronic circuit board of the present invention, at least a portion of at least one of the fibers of the fiber strand of the present invention comprises a DESMOPHEN 2000 poly Ester, A-174 propylene functional organodecane coupling agent, A-187 epoxy functional organodecane coupling agent, PLURONIC F-108 polypropylene oxide-polyethylene oxide copolymer, VERSAMID 140 polyamide, and MACOL An aqueous coating composition of NP-6 nonylphenol, POLYOX WSR 301 poly(ethylene oxide), and DYNAKOLL Si 100 rosin. In addition, this specific embodiment further includes POLARTHERM® PT 160 boron nitride powder and/or ORPAC. BORON NITRIDE RELEASECOAT-CONC 25 dispersion.

In a non-limiting embodiment of another fabric for an electronic circuit board of the present invention, at least a portion of at least one of the fibers of the fiber strand of the present invention comprises a DESMOPHEN 2000 polyester, an A-174 propylene functional group. Organic decane coupling agent, A-187 epoxy functional organodecane coupling agent, SYNPERONIC F-108 polyoxypropylene-polyoxyethylene copolymer, EUREDUR 140 polyamide, MACOL NP-6 decyl, SERMUL EN 668 An aqueous coating composition of cerium oxide, POLYOX WSR 301 poly(ethylene oxide), and DYNAKOLL Si 100. In addition, this particular embodiment further includes ROPAQUE® HP-1055 and/or ROPAQUE8 OP-96 styrene-acrylonitrile copolymer hollow spheres, and/or POLARTHERY® PT 160 boron nitride powder and/or ORPAC BORON-64 - This paper size is applicable to China National Standard (CNS) A4 specification (210 297 297 mm). • 装 订 订 丨丨 暴 ( 请 请 请 请 ( 请 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( 1 1 1 1 1 1 1 1 1 1 1 The Consumer Cooperative is printed on A7 V. Inventive Note (62) NITRIDE RELEASECOAT-CONC 25 Dispersion. Although not preferred, fiber strands having a coating composition similar to that described above without particles 18 can be prepared in accordance with the present invention. In particular, it is intended in accordance with the invention to produce one or more film forming materials, such as PVP K-30 polyethylpyrrolidone; one or more decane coupling agents, such as A-174 propylene functional organodecane a coupling agent and an A-187 epoxy functional organodecane coupling agent; and a lubricating material having a polar character based on a total solids of at least 25% by weight of the sizing composition, such as STEPANTEX 653 palmitic acid cetyl ester resin compatible Coating composition. It will be further appreciated by those skilled in the art that fiber strands of the resin compatible coating composition having the granules 18 can be woven into fabrics and formed into electronic supports and electronic circuit boards (as described below) in accordance with the present invention. The coating compositions of the present invention can be prepared by any suitable method, as is known in the art. Preferably, the ingredients discussed above are diluted with water to have the desired solids weight percent and mixed together. The granules 18 may be premixed, emulsified, or added to one or more of the coating compositions prior to mixing the remaining ingredients of the coating. The coating composition in accordance with the present invention can be applied in a number of ways, for example, by contacting a filament, spray or other tool with a roller or belt applicator. The coated fibers are preferably dried at room temperature or elevated temperature. The dryer removes excess moisture from the fibers and, if present, hardens any of the hardenable sizing composition components. The temperature and time at which the glass fibers are dried are determined by the % solids in the coating composition, the composition of the coating composition, and the fiber type. The term "hardening" as used herein with respect to the composition, such as &quot;hardening composition&quot;, means that any crosslinkable component of the composition is at least partially crosslinked - 65 - mechanical scale Standard (CNS) A4 specifications (210 X 297 public ------------ installed-----r---book--------- (please read the back) Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _ B7__ V. Invention Description (63). In the specific embodiment of the present invention, the crosslink density of crosslinkable components, - - that is, the degree of crosslinking, ranging from 5% to 100% of complete crosslinking. In other embodiments, the crosslinking density ranges from 35% to 85% of complete crosslinking. In other embodiments The cross-linking density ranges from 50% to 85% of complete cross-linking. Those skilled in the art will appreciate that the presence and extent of cross-linking, i.e., cross-linking density, can be determined by a variety of methods, such as using Polymer Laboratories MK under nitrogen. Dynamic mechanical thermal analysis by a DMTA analyzer (DM D) This method determines the glass transition temperature and cross-linking of a free film of a coating or polymer. The physical properties of the hardened material are related to the structure of the interconnected network. According to this point, the length, width, and thickness of the sample to be analyzed are first measured, and the sample is closely mounted on the Polymer Laboratories MK III device, and the dimensional measurement is input into the device. The thermal scan is performed at a heating rate of 3 ° C / min, a frequency of 1 Hz, a strain of 120%, and a static force of 0.01 N, and a sample measurement occurs every 2 seconds. According to this method, the deformation mode of the sample can be determined. Glass transition temperature, and crosslink density. Higher crosslink density _ 値 indicates a higher degree of crosslinking in the coating. The amount of the coating composition present on the fiber strand is preferably less than 30% by weight, more preferably It is less than 10% by weight, and most preferably from 0.1 to 5% by weight, as measured by the ignition loss (L0I). The coating composition on the fiber strands may be an aqueous coating composition residue or a powder coating composition. In a particular embodiment of the invention, L0I is less than 1% by weight. The term "ignition loss π" as used herein refers to the weight of the dried coating composition present on the surface of the fiber strand as determined by Equation 1. -66- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ----------- Attack-----r---订----- ----^9. (Please read the notes on the back and fill out this page)

1283255 V. INSTRUCTIONS (64) LOI=1〇〇X[(W^ W.)/W,] (Equation 1)

Where W# is the weight of the fiber strand after drying for 60 minutes in a 220 T (about l〇4. oven) plus the weight of the coating composition, and heating the fiber strands in an oven at 115 〇T (about 621 C) 2 The weight of the bare fiber strand after 〇 minutes and cooling to room temperature in a desiccator. After coating the first sizing slurry, that is, coating the substrate for the first time after the fiber is formed, the fiber is aggregated to have 2 to each 15, a strand of fiber, and preferably from 100 to 1600 fibers per second. The second coating composition may be applied to the first sizing slurry in an amount sufficient to coat or impregnate the strand portion, for example Coating the second coating composition onto the coated strand by dipping the coated strand in a bath containing the second coating composition, or by contacting the coated strand with the applicator discussed above The coated strands may be removed from the excess coating composition by the mold and/or dried as discussed above, sufficient to at least partially dry or harden the second coating composition. The second coating composition The method and apparatus for coating the strands are determined in part by the configuration of the strand material. The strands are preferably coated with a second coating composition. It is then dried by methods known in the art. Suitable second coating compositions may include one or more of the film forming materials, lubricants, and other additives discussed above. The second coating is preferably different from the first. A slurry composition, i.e., (1) contains at least one component that is chemically different from the components of the sizing composition; or (2) contains at least one component in an amount different from the amount of the same component contained in the sizing composition. Including the content of polyamimethine-67- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) —.---------Install------- -Book--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255

</ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Referring now to Figure 2, in an alternative embodiment in accordance with the present invention, the glass fibers 212 of the coated fiber strands 210 can be coated with a first layer 214 of a first sizing composition, which includes any of the amounts discussed above. Pulp composition. Examples of suitable t-polypolymer compositions are described in pp. 237-29, pp. (3rd edition, 1993), and U.S. Patent Nos. 4,391,647 and 4,795, each incorporated herein by reference. A second layer 215 of the second coating composition is applied to the first layer 214 (at least a portion, and preferably all of the outer surface. The second coating composition comprises one or more types of particles 216, such as The particles 18 are discussed in detail. In a particular embodiment, the second coating is an aqueous second coating composition residue on at least a portion of the first coating, particularly an aqueous second coating combination comprising thin flat particles. Residue. In another embodiment, 'the second coating is a powder coating composition on at least a portion of the first coating', particularly a powder coating composition comprising thin flat particles. In a specific embodiment, the particles of the second coating composition comprise hydrophilic inorganic solid particles that absorb and retain water in the gap between the hydrophilic particles. The hydrophilic inorganic solid particles can absorb water when exposed to water or participate in a chemical reaction of water. Expanding, for example, to form a viscous gelatinous solution that hinders or inhibits the entry of water into the gap of a communication cable reinforced with coated glass fiber strands. The &quot;absorption&quot; as used herein refers to the internal structure of water penetrating hydrophilic materials. or Gap, and substantially remains therein. See Hawlevfs Condensed Ch^tnical DLctionary, page 3, which is hereby incorporated by reference in particular. "Expansion" means a hydrophilic surname, a particle size or a volume of an enlarged gland. See Webster's New - 68 - This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------Installation-----r---订------ --- (Please read the phonetic transcription on the back? Please fill out this page again) 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (67) Compound (1) contains less than one chemically different a component of a component of the first upper slurry and the second coating composition; or (2) containing at least one component in an amount different from the same component contained in the first upper slurry and the second coating composition In this particular embodiment, the second coating composition comprises one or more of the polymeric materials discussed above, such as a polyurethane, and the third powder coating composition comprises the solid particles discussed above, Such as POLARTHERM® boron nitride particles, and hollow particles, such as ROPAQUE® pigments. Preferably, by coating The strand having the liquid second coating composition is passed through a fluidized bed or spraying device to adhere the powder particles to the adhesive second coating composition to coat the powder coating. Alternatively, the strand may be coated in the third layer. The layer of coating 92 is combined into a fiber 912, as shown in Figure 9. The composite or laminate 910 of the combination fabric 912 and resin 914 also includes a conductive layer 922, similar to that discussed in more detail below. The configuration shown. The weight % of the powdery solid particles adhered to the coated fiber strands 31 &lt;) may range from 1 to 5% by weight of the total dry weight, and preferably from 〇 to 3 〇 ❶ / Hey. The third powder coating may also include one or more of the polymeric materials discussed above, such as propylene polymers, epoxides, or polyfluorenes, conventional stabilizers and other modifiers known in the coating art. It is preferably in the form of a dry powder. In a specific embodiment, the fiber strand comprising the plurality of fibers at least partially coats at least a portion of the surface of at least one of the fibers of the first coating of the above pulp composition to comprise a second coating composition of polymeric material A portion of the first composition is applied, and a portion of the second coating is coated with a third coating composition comprising discrete particles. In another embodiment, the fiber strand comprising the plurality of fibers is at least partially coated with the first coating of the above pulp composition ------------------- -^--------- Hua (please read the notes on the back and fill out this page) -70- 1283255 A7 B7 V. INSTRUCTIONS (68 At least one part of the surface of the fiber, at least one part, At least a portion of the first composition is applied with a second coating composition comprising a polymeric material, and a portion of the second coating is applied with a third coating composition comprising thin flat particles. In a preferred embodiment, at least one of the coatings of the above specific embodiments is different. In another preferred embodiment, at least two of the coatings of the above specific embodiments are different. The third coating can be an aqueous emulsion residue of the powder coating composition. The coating composition comprises - or more of the coating components discussed above. Each of the specific embodiments of the coated fiber strands discussed above can be used as Continuous strands or further processed into various products such as chopped strands, interwoven strands, spun yarns and/or fabrics such as fabrics, non-woven fabrics (including Single-phase fabrics, knits and knits. In addition, the coated fiber strands of the warp and weft (ie, yarn-filled) strands of the fabric may be non-woven (also known as uninterwoven or zero interwoven), or Prior to moving, the I fabric comprises various combinations of interwoven and non-interwoven warp and weft strands. Preferred embodiments of the invention include at least partially coated fabrics comprising at least one of the more detailed discussions The fiber strands of the fibers. =, = The invention is intended to be a fabric comprising a plurality of fibers comprising a plurality of fibers, as well as a fabric coated with a fabric. For example, preferred embodiments of the invention relate, at least in part, to Coated fabric, comprising " fiber strands comprising a plurality of fibers, the temperature of which is applied to the lotus is at least watts of thermal conductivity ^ thin into equal parts ^ in the specific embodiment of the invention, The invention is applied/coated to individual fibers. In another embodiment, the coating will be coated with I =------------ 71-tgaa# χ 297 public)

(Please read the precautions on the back and then fill out this page) I---------------- II. Hua 1283255 A7 I______B7 ___ V. Invention description (69) At least one 縢雉In another embodiment, a coating composition in accordance with the present invention is applied to a fabric. These alternative embodiments are discussed in detail below. While the above discussion relates generally to coatings of the present invention after fiber formation. The composition is applied directly to the glass frit, which in turn is incorporated into the fabric. The invention also includes specific embodiments in which the coating composition of the invention is applied to a fabric. For example, by applying a fabric prior to fabricating the fabric. The layer is applied to the fiber strands' or the coating composition is applied to the fabric by applying the coating to the fabric after being manufactured using various techniques known in the art. Depending on the treatment of the fabric, the present invention The coating composition can be applied directly to the glass fiber in the fabric or to another coating already on the glass fiber and/or fabric. For example, the glass fiber can be coated after being formed and woven into a fabric.知殿粉_ Oil on the slurry. The fabric is treated to remove the starch-oil slurry prior to application of the coating composition of the present invention. This upper slurry removal can be accomplished using techniques known in the art, such as heat treating or cleaning the fabric. In this case, the coating combination Directly coating the fiber surface of the fabric. If any sizing composition portion originally applied to the glass fibers is not removed after formation, the coated composition of the present invention is applied to the remainder of the sizing composition a portion rather than directly on the surface of the fiber. In another embodiment of the invention, the selected component of the coating composition of the invention can be applied to the glass fiber immediately after formation, and The remainder of the coating composition is applied to the fabric after manufacture. In a manner similar to that discussed in j above, the second or all of the selected ingredients may be removed from the glass frit fibers prior to coating the fibers and fabric with the remaining ingredients. As a result, the remaining components are directly 1 I__ -72·^ paper size suitable national standard (CNS) A4 specifications (210 X 297 public ^ ' -- -----r---t-------- - (Please read the notes on the back and fill out this page)

1283255

The surface removal is selected as the Ministry of Economic Affairs, the Intellectual Property Office, the employee consumption cooperative, the printed fabric, the fiber surface, or the coated non-fiber segment. In another embodiment according to the present invention, at least one is included. The fabric comprising a plurality of strands of fibers is at least partially coated with a first coating, at least a portion of the first coating is coated with a second coating, and the second coating is:: at a temperature of K Inorganic material particles having a thermal conductivity greater than i watts. In another embodiment, the at least one strand comprising a plurality of fibers is at least partially coated with a coating comprising: (magic flat inorganic particles having no more than at least one glass fiber) Mohs hardness 値 Mohs hardness 値; and (b) film forming material. In another embodiment, the fabric comprising at least one strand comprising a plurality of fibers is at least partially coated with a coating comprising: a) a metal particle having a Mohs hardness of no more than at least one glass fiber 値 'this metal particle is selected from the group consisting of indium, nickel, silver, and silver, and (9) a film forming material. In an embodiment, the fabric comprising at least one fiber strand is at least partially coated with the first coating, and the second coating is applied to at least one of the first coatings. Hydrophilic particles that absorb and retain water in the interstices of the granules. In another embodiment, the fabric comprising at least one strand comprising a plurality of fibers has a resin compatible coating set on at least a portion of the surface of the fabric The resin compatible coating composition comprises (a) a plurality of materials selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and -73- paper size applicable to China National Standard (CNS) A4. Specifications (210 X 297 mm) -----------------·----^---------^9. (Please read the note on the back first) Matters fill out this page) 1283255 A7 B7 71 V. INSTRUCTIONS (The mixture - the discontinuity of the material formation # '1 ' This particle has a measurement range of 0.1 to 5 micrograms according to laser scattering technology. And (b) at least - a lubricating material different from the plurality of discrete particles, and (4) at least a film forming material. In another embodiment, comprising at least one fabric comprising a plurality of fibers At least a portion of the surface of the fabric has a resin compatible coating composition comprising: (4) a plurality of discontinuous non-soil formed from materials selected from the group consisting of organic materials, composite materials, and mixtures thereof Shaped particles, and (b) at least one lubricating material that is different from a plurality of discrete particles. In another embodiment And comprising at least one strand comprising a plurality of fibers (the fabric is on the fabric (at least a portion of the surface having a resin compatible coating composition, the resin compatible coating composition comprising: (a plurality of hollow organic particles; And (b) at least one polymeric material different from the hollow organic particles.

Another embodiment of the present invention is directed to a fabric comprising at least one strand comprising a plurality of fibers, wherein at least a portion of the fabric has a resin phase valley coating having an ignition loss of from 11 to i6, and The air permeability is not more than 1 inch of standard cubic inch per square inch per minute measured in accordance with ASTM D 737. As used herein, "breathing force" means the breathability of the fabric to circulate air. The permeable force can be measured in accordance with ASTM D 737 Standard Test Method for Textile Fabric Breathing Force, which is incorporated herein by reference in its entirety. These ingredients for use in these specific examples may be selected from the coating compositions discussed above, and additional ingredients may also be selected from the list above. In a preferred embodiment of the present invention, the method comprising the following steps ----- 74. The paper ruler/fig is used in China National Standard (CNS) A4 ^ (210 x 297 ^^ ; --- --------Install-----r---订--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative System 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed Lens Description (72) Manufacture of fabrics suitable for strong and electronic supports: (a) Obtain at least one yarn containing multiple fibers, and at least one fill Having at least a portion of the yarn a first resin compatible coating; (b) obtaining at least one warp yarn comprising a plurality of fibers, and having a second resin compatible coating on at least a portion of the at least one warp yarn; (c) weaving at least one of the yarns and the at least one warp yarn to form a fabric having an ignition loss of less than 2.5% by weight i suitable for strengthening the electronic support. In an additional embodiment of the invention, the fabric is combined by: (4) In the rough surface of the surface of the sliding contact fabric assembly device, the sliding contact is individually a glass fiber strand comprising a plurality of at least a portion of the surface having a glass fiber coated in accordance with any of the preceding embodiments, such that surface wear of the plurality of glass fibers is inhibited, the surface being rough The surface has a Mohs hardness 値 greater than the Mohs hardness 値 of the glass fibers of the first glass fiber strand; and (b) the first glass fiber strand and the second fiber strand are interwoven to form a fabric. Other embodiments of the invention relate to A method of inhibiting abrasion of a fiber strand comprising at least one glass fiber by sliding contact with a surface rough surface of a solid article, comprising: (a) individually or collectively coating a coating composition according to any of the previous embodiments Having at least a portion of the surface of at least one of the glass fiber strands; (b) at least partially drying the composition to form a combination on at least a portion of the surface of at least one of the glass fibers The grain residue is broken with the fiberglass strand; and the one-to-75- paper scale applies to the Chinese national standard &lt;CNS) A4 specification (210x297 mm) ^-----r---^--- ------^9. (Please Read the notes on the back and fill out this page.) 1283255 Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Co., Ltd. Printed A7 B7 V. Inventions (73) (C) Sliding glass, at least part of the glass fiber strands to contact solid objects The surface rough surface having a hardness 大于 greater than the hardness 至少 of at least one glass fiber such that at least one glass fiber of the at least one glass fiber strand is inhibited by the coating composition from contacting the surface rough surface of the solid object Wear. As above, the coating composition used in these embodiments may be selected from the coating compositions' discussed above and the additional ingredients may also be selected from the above. The coated fiber strands 10, 210, 310 and the products formed therefrom, such as the coated fabrics listed above, can be used in a wide variety of applications, but preferably form a composite as a reinforcement 410 of the reinforced polymeric matrix material 412. 414,. As shown in Figure 4, it is discussed in detail below. Such applications include, but are not limited to, laminates for printed circuit boards, reinforcements for communication environments, and various other composites. The coated strands and fabrics of the present invention are preferably compatible with typical polymeric matrix materials used to make electronic supports and printed circuit boards. In addition, the coated fiber strands are suitable for use in air jet looms commonly used to make reinforced fabrics for such applications. Conventional sizing compositions which are applied to fibers woven using air jet looms include ingredients such as starches and oils which are generally not compatible with such resin systems. It has been observed that the weaving characteristics of the fiber strands comprising the coating composition comprising the particles 18 according to the invention are close to the weaving characteristics of the fiber strands coated with the conventional starch/oil-based sizing composition, and Resin compatible. While not being bound by any particular theory, it is believed that the granules 18 of the present invention, when processed and air jet woven, utilize the fiber separation and air resistance required for the operation of the blasting operation by k. Like the function of the starch component of the conventional starch/oil sizing composition, _ I疋 hunting is provided by the epoxy tree _________ -76· This paper is used in China. Standard country x: L--- ------- φ 装-----Γ---订--------- (Please read the notes on the back and fill out this page) !283255

V. INSTRUCTIONS INSTRUCTIONS (74 Ministry of Economic Affairs Intellectual Property Office employees consumption cooperatives print the looseness of the lipid system - not in a manner different from the conventional composition. For example, the granule 18 promotes the dry lubrication of the coating similar to the starch coating. Drying, powder characteristics of the features. In the coated strands of the present invention, the particles advantageously provide a gap between the fibers of the strands which facilitates faster flow of the matrix material and/or uniform wetting and wetting of the fibers therein In addition, the strands are preferably highly open (discussed above) which also facilitates the flow of the matrix material in the bundle. Surprisingly, in certain embodiments, the amount of particulates may exceed that applied to the fibers. 20% by weight of the total solids of the layer composition, while still suitably adhering to the fibers and providing a stock having processing characteristics at least comparable to those of the non-particulate coating. Referring now to Figure 8, the advantages of the coated strands of the present invention are The laminate 810 made from the coated stranded fabric 812 can have a good coupling at the interface between the fabric 812 and the polymeric matrix material 814. A good coupling can be made from the laminate 810. The electron support 818 provides good hydrolysis stability and resistance to metal movement (discussed above). In another non-limiting embodiment illustrated in Figure 5, the coated strands 510 made in accordance with the present invention may be knitted. Or woven fabric 512 reinforcement as warp and/or weft strands 514 and 516, preferably forming a laminate for a printed circuit board (as shown in Figures 7-9). Although not necessary, warp strands 514 may be Prior to use, it is interwoven by any conventional interleaving technique known to those skilled in the art. One such technique uses an interlaced frame to impart X-wovens of 5 to 3 turns per inch. The reinforcing fabric 512 preferably comprises 5 to 5 centimeters per cent. 1 warp yarn strands (approximately 13 to 254 warp strands per inch), and preferably from ό to 5 per centimeter (M electric weft yarn strands (about 15 to about ι 27 weft strands per inch). -----r---订--------- Sr (Please read the note on the back and fill out this page) -77- 1283255 A7 V. Invention description (75) Dynamic structure can also - For regular weave or grid (as shown in Figure 5), any other weave woven known to those skilled in the art may be used. For example, fork weaving or forging, in a particular embodiment, the woven reinforced fabric 512 of the present invention may be formed by using any conventional looms known to those skilled in the art, such as weaving loom, empty A milk jet loom or rapier loom, but preferably formed using an air jet loom. Preferably, the air jet loom is commercially available from Japan's Tsudakoma Corporation Models 103, 1, 31, 1033 or ΖΑχ. The sulzerRutl model L__, L side or L_5 is fine, and it is obtained from Zunch (Sulzer Br〇thers) and τ〇 handsome model JAT610 in Switzerland. As shown in the figure, air jet weaving refers to the use of air jet loom 626. a fabric weave pattern (shown in Figure 6) wherein, as discussed above, the fill yarn (weft) 610 is inserted into the warp shed with strong compressed air 614 from - or more air jet nozzles 618 (Fig. 6 with The figure is as shown). The fill yarn 61 is pushed by the compressed air through the width 624 of the fabric 628 (about 1 Torr to about 6 inches), and more preferably 0.91 meters (about 36 inches). The air jet filling system can have a single main nozzle 616, but preferably has a plurality of auxiliary relay nozzles 62 along the warp shed 612 to provide a strong auxiliary air 622 to the yarn 61 , while maintaining the yarn 61 traversing the fabric 628. The required air pressure of width 624. The air pressure supplied to the main air nozzle 616 is preferably in the range of 1 〇 3 to 413 kPa (kpa) (about 1 to about 6 psi) per square inch, and more preferably It is 31 kPa (about 45 Psi). The preferred type of main helium nozzle 616 is SulzerRuti needle air - 78 - ^ paper ruler Tang extract with Zhonggu Guoding Dejin (ΓΝς) Α 4 broadcast grid (10) heart 7 gongs) —*-------- ---------^—.—I—^9. (Please read the notes on the back and fill out this page)

1283255 V. INSTRUCTIONS (%) Jet unit type - No. 044 455 001 with an air jet of 2 nozzle diameter 617 and a nozzle length 621 of 20 cm length 621 (commercially available from Sulzer Ruti, Spartanburg, North Carolina) the company). Preferably, the air injection filling system has 15 to 20 auxiliary air nozzles 62A that supply auxiliary air in the lateral direction of the yarn filling 610 to help push the yarn 61 to traverse the loom 626. The air pressure (gauge) supplied to each of the auxiliary air nozzles 62 is preferably in the range of 3 to 6 bar. The fill yarn 610 is withdrawn from the supply package 63 by the feed system 632 at a feed rate of 18 to 550 meters per minute, and preferably 274 meters (about 300 yards) per minute. The fill yarn 61 is fed into the main nozzle 618 via a splint. Strong air pushes a predetermined length of yarn (approximately equal to the desired fabric width) through the tube guide. Upon completion of the insertion, the end of the yarn at the tip of the main nozzle 618 is cut by a cutter 634. The compatibility and aerodynamic properties of different yarn and air jet weaving processes can be determined by the following method, which is generally referred to herein as &quot;air nozzle transport resistance, test method. The air jet transport resistance is used to measure the attraction or pulling force (, resistance &quot;) applied to the yarn when the yarn is pulled into the air jet nozzle by the force of the air jet. In this method, the yarn pressure is measured at a rate of 274 meters (about 300 yards) per minute at a flow rate of 310 仟basca (about 45 pounds per square inch) through the Sulzer Ruti needle air nozzle. The spray nozzle unit number 044 455 001 has an air jet groove within the nozzle outlet tube 619 of 2 mm diameter 617 and 20 cm length 621 (commercially available from Sulzer Ruti, Spartanburg, North Carolina). The tensiometer contacts the yarn at a position before the yarn enters the air jet nozzle. Tensiometer provides yarn to air jet spray-79- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) —-----------Install----- ---Order--------- (Please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 V. Invention description (77 mouth, empty - Gas injection is applied to the yarn's gram force (resistance) measurement. The resistance per unit mass can be used as the basis for the relative comparison of the yarn samples. For relative comparison, the resistance measurement of the yarn by 1 cm length will be standardized. The mass can be determined according to Equation 2: gram mass = 〇 (d / 2) 2) (N) (p material) (yarn of 1 cm length) (Equation 2) where d is the diameter of the single fiber of the yarn bundle, and N is the yarn The amount of fiber in the bundle, and P (iv) is the density of the glass at 25 ° C (about 2.6 grams per cubic centimeter). Table c lists the fiber diameters and quantities in the yarns of many typical glass fiber yarn products. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Cooperatives, Printed in the Type of Fiber Diameter Number of fibers (cm) G75 9 X 1〇_4 400 G150 9 X 1〇·4 200 G225 7 X 10-4 200 G450 5.72 X 10'4 200 For example, the mass of G75 yarn of 1 cm length is (π (9 X 10·4/2) 2) (400) (2.6 g per cubic centimeter) (yarn of 1 cm length) = 6.62 X 1 〇 4 g mass. For D450 yarns, the mass is 1.34 X ΗΤ 4 g. The relative resistance per unit mass is calculated by dividing the resistance (gram force) measured by the tensiometer by the gram mass of the tested yarn type. Air Jet Transport Resistance - 80 - Paper Scale Applicable to China National Standard (CNS) A4 Specifications (210 X 297 public) _装-----r---订----- Φ 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperatives printed A7 ------------ -Β7___ V. Invention description (7S) Force··). For example, for a G75 yarn, if the resistance tensiometer is measured as 68.5 ′, the air jet transport resistance per gram of quality yarn is equal to 6S5 divided by 6.62 X ι〇·4 = 1〇3 474 gram force. The air jet transport resistance of the yarn used to form the woven fabric for the laminate according to the present invention is preferably greater than 100,000 gram per gram of mass, more preferably in the range determined by the air jet transport resistance test method discussed above. It is 100,000 to 400,000 gram per gram of yarn, and even more preferably in the range of 12 inches per gram of yarn, up to 300,000 gram. The fabric of the present invention is preferably woven in a form suitable for use in laminates for electronic supports or printed circuit boards, as disclosed by &quot;Fabrics Around the world&quot;, which is a technology of Clark-Schwebel Corporation of Anderson, South Carolina. Bulletin (1995), which is hereby incorporated by reference in its entirety, the disclosure of which is incorporated herein by reference in its entirety in the the the the the the the the the - The non-restricted fabric type of fiberglass yarn is Type 2116, which has 118 warp yarns and 114 yarns (or weft yarns) per 5 cm (60 warp yarns and 58 yarns per inch); 7 22 1 inch ( Ε225 1/0) warp and yarn filling, fabric weight of 公·〇94 mm (approx. 0.037 inch) and fabric weight of 103.8 grams per square meter (approximately 3 〇 6 ounces per square yard) (or basic Weight) A non-limiting example of a fabric type using G75E-glass fiber yarn is Type 7628, which has 87 warp yarns and 61 yarns per 5 cm (44 warp yarns per inch and 31 yarn fills); 68 1χ〇g75 1/0) warp and yarn filling; with 0.173 mm (about 〇 〇〇68 inches 公) nominal fabric thickness; | 203.4 grams per square meter (about 6 ounces per square yard) of woven-81 · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ] -- -------------------^---------^9. (Please read the notes on the back and fill out this page) 1___ - 82 This paper scale applies to the Chinese National Standard &lt;CNS) A4 specification (210 X 297 mm 1283255 V. Inventive Note (79). The weight of the E•glass fiber yarn weave (4) is not a type, There are 118 warp yarns and 50 pieces of warp yarns and 47 crepe yarns per μm, · μ mr ~), using 511 lx0 (D45〇1/〇) and yarn filling; with side millimeters (about 0 0021 inches) The nominal fabric thickness of the pair; and 46.8 grams per square meter (amount per square yard. Non-restricted type 1〇6 of the fabric type using the surface E-glass fiber yarn) has 110 warp yarns and U-strips per 5 cm. Filling (56 warp yarns and 56 yarns per inch); use 55.5lx0 (clear 1/〇) warp yarns and fill in seconds '· have a nominal fabric thickness of 0.033 mm (about 〇加英英); and per square meter 24.4 grams (per flat The fabric weight of the square code is about Q 72. The non-limiting example of the fabric type using the surface E·glass fiber yarn is 1〇8 type, which has 118 warp yarns and 83 yarn fillings per 5 cm (each 60 warp yarns and 47 yarns in the UK; 5 5 5 1χ2 (D9〇〇1/〇) sand and yarn filling; nominal fabric thickness of 0.061 mm (about 〇·_英); and per square The fabric weight of 47.5 grams (about 14 inches per square yard). A non-limiting example of a fabric type with a glass fiber yarn of type 2113 is used, which has 118 warp yarns and ιι 填 yarns (60 warps and 56 yarns per inch) per 5 cm; 22 lx〇 (D225丨(9) warp and 5 11 lx〇 (D450 1/〇) filled; nominal fabric thickness of 〇〇79 mm (approx. 3 ι 吋), and 78 每g per square meter ( Fabric weight of approximately 2 ounces per square yard. A non-limiting example of a fabric type using G50 and G75E_glass fiber yarns is Type 7535, which has a warp yarn and 57 yarns per 5 cm (44 per inch) Warp yarns and 29 yarns); filled with 9邡1χ〇 (G75 1/0) and 9 99 lx0 (G5〇1/〇); with 〇2〇ι mm-82 - - ----- -----^--------- (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _JB7__ V. Invention Description (80) The nominal fabric thickness of 0.0079 Viburnum; and the fabric weight of 232.3 grams per square meter (approximately 6.85 ounces per square yard). These and other available fabric types are shown in IPC-EG-140 f,S Pecification for Finished Fabric Woven from Έ 1 Glass for Printed Boards', published by The Institute for Interconnecting and Packaging Electronic Circuits (June 1997), which is hereby incorporated by reference in its entirety. These or other fabrics that use zero interlaced yarns or spun yarns in combination with or in place of interwoven yarns are made in accordance with the present invention. In particular embodiments of the invention, some or all of the warp yarns in the fabric may have a first resin compatible sizing combination. Fiber of the article, and some or all of the yarn may have fibers coated with a second resin compatible coating different from the first composition, ie, the second composition (1) contains at least one chemically different or in some form a component different from the component of the first sizing composition; or (2) containing at least one component in an amount different from the amount of the same component contained in the first sizing composition. Referring now to Figure 7, by using a matrix material Coating and/or impregnation, preferably a polymeric film forms a thermoplastic or thermoset matrix material 716, which may be used to form a composite or laminate 714. The composite or laminate 714 is suitable as an electron support. As used herein, "electronic support" means a structure that mechanically supports and/or electrically interconnects components. Examples include, but are not limited to, active electronic components, passive electronic components, printing Circuits, integrated circuits, semiconductor devices, and other hardware incorporating such components include, but are not limited to, connectors, sockets, buckles, and heat sinks. -83 - This paper size is applicable to China National Standard (CNS) A4 specification (21〇X 297 mm) --·----------^装-----r--- --------- si (please read the notes on the back and fill out this page) 1283255

DESCRIPTION OF THE INVENTION (81 Ministry of Economic Affairs Intellectual Property Office Employees Consumer Cooperatives Printing Invention I Preferred embodiment relates to a reinforced composite comprising a plurality of coated fiber strands comprising a plurality of fibers detailed above. The invention is therefore intended to be a reinforced composite made from various fiber strands comprising a plurality of fibers. For example, a preferred embodiment of the invention relates to a reinforced composite comprising a matrix material and at least one portion comprising a plurality of fibers The coated, fiber strands' coatings comprise organic components and thin flat particles having a thermal conductivity of at least 1 watt per meter K at a temperature of 3 Å. Another preferred embodiment of the invention relates to reinforced composites. And comprising (a) at least partially coated fiber strands comprising a plurality of fibers, the coating comprising at least one thin flat particle, and (b) a matrix material. Another preferred embodiment of the invention is The reinforced composite comprises (a) an at least partially coated fiber strand comprising a plurality of glass fibers, the coating comprising an aqueous composition residue comprising (1) a plurality selected from the group consisting of organic materials a discontinuous particle formed of a material, an inorganic polymeric material, a composite material, and a mixture thereof; (ii) at least one lubricating material different from the plurality of discrete particles; and (iii) at least one film forming material; and (b) A matrix material. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least one fiber strand and a matrix material, wherein the reinforced composite further comprises an aqueous composition residue comprising (4) a plurality selected from the group consisting of organic materials a discontinuous particle formed of a material of an inorganic polymeric material, a composite material, and a mixture thereof; (b) at least one lubricating material different from the plurality of discrete particles; and (c) at least one film forming material. Another aspect of the present invention Preferred embodiments relate to a reinforced composite comprising (a) a package comprising at least partially coated fiber strands of at least a plurality of glass fibers, -84 - the paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 public Chu) IL---------——l· — — —--------- (Please read the notes on the back and fill out this page) Property Bureau staff consumption Co-published 1283255 V. Description of the invention (82 its coating. KH, compound residue, containing more than 20% by weight of discontinuous particles based on total solids, the particles having no more than at least one of the Boma The Mohs hardness of the fiber 値 Mohs hardness 値; and (8) the matrix material. Another preferred embodiment of the invention relates to a reinforced composite comprising up to V. Fiber strands and matrix of the glass fiber The material, wherein the reinforced composite further comprises an aqueous composition (IV) comprising more than 20% by weight of discontinuous particles based on total weight, the particles having a Mohs hardness of no more than at least one Mohs hardness of the glass fiber 値An additional embodiment of the present invention relates to a reinforced composite comprising (4) at least one fiber strand comprising a plurality of glass fibers, the strand coating comprising from an organic material, an inorganic polymeric material, a composite material and A resin compatible composition of discontinuous particles formed from the material of the mixture, wherein: no: the continuous particles have an average particle size of less than 5 microns; and (8) a matrix material. Specifically, the plurality of discontinuous particles are formed of a material selected from any of the above non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof. The components of the coating and resin compatible compositions used in the above specific examples of the reinforced composite may be selected from the coating components discussed above, and the other ingredients may also be selected from the above. Preferred matrix materials for use in the present invention include thermosetting materials such as thermosetting polyesters, acetamidine vinegars, epoxides containing at least one epoxy or oxirane group in the molecule, such as polyhydric alcohols or thiols. Polyglycidyl _), a desired base, an amine based plastic, a thermosetting polyurethane, any of the above derivatives, and mixtures thereof. Forming a laminate for a printed circuit board---------------r---book--------- (please read the phonetic notes on the back first? Fill in this page again)

1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 5, Invention Note (83) The preferred substrate _ material is FR-4 epoxy resin (which is such as difunctional bromination ^ epoxy resin polyfunctional group Epoxy resins), polyimines, and liquid crystal polymers, such compositions are known to those skilled in the art. For further information on such compositions, see Electronic Materials HandbookTM. ASM International (1989) pp. 534-537, which is incorporated herein by reference in its entirety. Non-limiting examples of suitable polymeric thermoplastic matrix materials include polyolefins, polyamines, thermoplastic polyurethanes and thermoplastic polyesters, ethylene polymers, and mixtures of any of the foregoing. Other examples of thermoplastic materials may be used. Polyimide, polyether oxime, polyphenyl fluorene, polyether ketone, polyphenylene oxide, polyphenylene sulfide, polyacetal, polyethylene, and Polycarbonate. Preferred matrix material formulations include EPON 1120-A80 epoxy resin (commercially available from Shell Chemical Company of Houston, Texas), dicyandiamide, 2-methylimidazole, and DOWANOL PM ethylene glycol ether (commercially available from Michigan) The Dow Chemical Company of Midland). The polymeric matrix materials and reinforcing materials in the composite may include other components including colorants or pigments, lubricants or processing aids, ultraviolet (UV) stabilizers, antioxidants, other fillers, and blending agents. In a preferred embodiment, the polymeric matrix material comprises an inorganic material. These inorganic materials include ceramic materials and metal materials, and may be selected from the inorganic materials detailed above. Fabric 712 can be applied and impregnated by dipping fabric 712 into a bath of polymeric matrix material 716, for example, as discussed in R. Tummala (eds.) Microelectronics Packaging Handbook, (1989) pp. 895-890. It is specifically incorporated herein by reference. More often, by hand or by any from -86 - this paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) — ΙΓΙ — — — — — — III l· III 一 , 11111111 (Please read the notes on the back and fill out this page)

1283255 V. INSTRUCTION DESCRIPTION (84) A dynamic feed or mixing device disperses a chopped or continuous fiber strand reinforcement material in a matrix/material that distributes the reinforcement material substantially uniformly throughout the polymeric matrix material. For example, the reinforcing material can be dispersed in the polymeric matrix material by simultaneously or sequentially drying the blended ingredients. Depending on the type of polymeric matrix material used, the polymeric matrix material 716 and the strands can be formed into a composite or laminate 714 in a number of ways. For example, for a thermoset matrix material, the composite may be formed by compression or injection molding, comminution, filament winding, manual stacking, spraying, or by sheet molding or volume molding followed by compression or injection molding. The thermoset polymeric matrix material can be cured by, for example, including a crosslinking agent in the matrix material and/or applying heat. Suitable crosslinking agents for crosslinking the polymeric matrix material are discussed above. The temperature and hardening time of the thermoset polymeric matrix material will depend, for example, but not limited to, the polymeric matrix material used, other additives in the matrix system, and the thickness of the composite. For thermoplastic matrix materials, suitable methods of forming the composite include direct molding or extrusion compounding followed by injection molding. Methods and apparatus for forming composites by the above methods are discussed in I Rubin, Handbook of Plastic Materials aai TechTiolog (1990), pp. 955-1062, 1179-1215, and 1225-1271, which is incorporated herein by reference in its entirety. Additional embodiments of the present invention are directed to a fortified laminate suitable for use in an electronic support comprising an at least partially coated fabric comprising at least one fiber strand of the above description. Accordingly, the present invention is intended to be a reinforced laminate suitable for use in an electronic support made from a fabric that does not include at least one fiber strand. For example, a preferred embodiment of the present invention is applicable to the Chinese National Standard (CNS) A4 specification (21〇x 297 mm) suitable for -87- this paper scale-&gt;-------- -装--------Book--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 B7 Ministry of Economics Intellectual Property Bureau employee consumption cooperative printing 5, invention description (85) an electronic support layer, comprising a matrix material and at least one partially coated fabric comprising at least one fiber strand, the coating comprising organic components And thin flat particles having a thermal conductivity of at least 1 watt per meter K at a temperature of 300K. In other embodiments, the coating is compatible with the matrix material suitable for use in the reinforced laminate of the electron support. Additional embodiments of the present invention are directed to a reinforced laminate suitable for use in an electron support, the laminate comprising (4) a matrix material, and (8) at least one non-defatted fabric comprising at least one fiber strand, at least one of at least one fabric Portions have a coating that is compatible with the matrix material suitable for use in the reinforced laminate of the electron support. Another embodiment of the invention relates to a reinforced laminate suitable for use in an electron support, the laminate comprising (4) a matrix material, and (b) at least one comprising at least one fiber strand and at least a portion of the fabric A fabric having an unfinished resin compatible coating composition on the surface. As used herein, "non-defatted fabric" is a conventional fiber treated fabric that has not been subjected to fabric removal of non-resin phase inclusions from the fabric. As discussed above, in addition to the washing &apos;thermal removal and nozzle cleaning are examples of such conventional fiber treatments. As used herein, "untrimmed" resin compatible coating composition refers to the resin compatible coating composition discussed above that is not used in conventional fiber conditioning processes. For example, an 'untrimmed resin compatible coating composition refers to the first, second and/or third coating composition discussed above, but does not refer to a typical finishing slurry, for example, made from a decane coupling agent and water, And after being degreased, it is applied to the fiber. However, the present invention does intend to provide a coating comprising a resin compatible coating according to the present invention having a finished upper slurry applied to the coating. A specific embodiment of the present invention relates to the formation of an electronic law body for I_______ ____-88- This paper scale applies to the National Standard (CNS) A4 specification (21〇X 297 public) -^- --------------r---book--------- line (please read the notes on the back and fill in this page) 1283255

, invention description (86), the method of printing a laminate for the employee's consumer cooperative of the Ministry of Intellectual Property of the Ministry of Commerce, the method comprising the steps of: (a) obtaining by woven at least one yarn containing a plurality of fibers and Forming a first resin compatible coating on at least a portion of the at least one yarn, and a warp yarn comprising a plurality of fibers and having a second resin compatible coating on at least a portion of the at least one warp yarn to form Suitable for reinforcing the fabric of the electronic support; (b) at least partially coating at least a portion of the fabric with the matrix material resin; (C) at least partially hardening the at least partially coated fabric to form the pre-diffuse yarn And (d) laminating two or more layers of prepreg to form a laminate suitable for use in an electron support. The composition for the coating of the above specific embodiment relating to the reinforced laminate may be selected from the coating components discussed above, and the other ingredients may also be selected from the above. Additional preferred embodiments of the present invention are directed to prepreg yarns for electronic supports comprising at least partially coated fabrics comprising at least one fiber strand as discussed in detail above. Accordingly, the present invention is intended to be a prepreg for an electronic support made from each of the disclosed fabrics comprising at least one fiber strand. Another embodiment of the invention relates to a prepreg for an electronic support comprising (4) a matrix material, and (b) at least one non-defatted fabric comprising at least one fiber strand, at least one fabric At least a portion has a coating that is compatible with the matrix material in the prepreg for the electronic support. Another specific embodiment of the present invention relates to the use of the Chinese National Standard (CNS) A4 specification (210 X 297 mm) for the pre-89-paper scale for electronic law. &quot; ' --.---- ------Install-----r---book--------- (please read the notes on the back and fill out this page) 1283255

V. Description of the invention (87 Ministry of Economic Affairs, Intellectual Property Office, Staff Cooperatives, Printed Dip 'V, this pre-J Man yarn comprises (4) a matrix material; and (8) at least one comprising at least one fiber strand and having at least a portion of the surface of the fabric The fabric of the resin-compatible coating composition is not trimmed. As above, the components of the coating used in the above specific examples may be selected from the coating components discussed above, and the other components may also be selected from the above. In the particular non-limiting embodiment shown, the composite or complex 810 comprises a fabric 812 impregnated with a compatible matrix material 814. The impregnated fabric is then extruded between a set of metering rolls to leave a measurable The amount of matrix material is dried and formed to form an electronic body in the form of a semi-hardened substrate or prepreg. The conductive layer 820 can be placed along one side 822 of the prepreg in the manner discussed in the following specification, and the prepreg will be The yarn is hardened to form an electronic support 818 having a conductive layer. In another embodiment of the invention, and furthermore, in the electronic support industry, two or more prepregs are combined to one or more conductive Floor Moreover, laminated and hardened to form a multilayer electronic support in a manner known to those skilled in the art. For example, but not limiting of the invention, the pre-spun yarn stack can be laminated by compression stacking, for example, between polished steel sheets. At a high temperature and pressure for a predetermined length of time to harden the polymeric matrix and form a laminate of the desired thickness. One or more portions of the prepreg may have a conductive layer before or after lamination and harden, resulting in generation The electron support is a laminate having at least one conductive layer along a portion of the exposed surface (hereinafter referred to as "face laminate"). The circuit is then formed from a single or multiple layer of electron support using techniques known in the art. The conductive layer is formed to constitute an electronic support in the form of a printed circuit board or a printed wiring board (referred to as an "electronic circuit board" under _..). ' ---------^-- ------- line (please read the notes on the back and fill out this page)

1283255

V. INSTRUCTIONS (88) The Ministry of Economic Affairs, the Intellectual Property Office, the Staff Consumer Cooperative, which prints the invention - an additional preferred embodiment relates to the inclusion of at least partially coated fabrics comprising at least one of the fiber strands discussed in detail above Electronic support and electronic circuit board. Accordingly, the present invention is intended to produce electronic supports and electronic circuit boards from the disclosed fabrics comprising at least one fiber strand. Another embodiment of the invention is directed to an electronic support comprising (4) at least one non-defatted fabric comprising at least one fiber strand, at least a portion of at least one non-defatted fabric having a matrix material compatible coating; b) at least one matrix material on at least a portion of at least one of the fabrics in the electronic support. Additional embodiments relate to an electronic support comprising (a) at least one fabric comprising at least one fiber strand and having an untrimmed resin compatible coating composition on at least a portion of the surface of the fabric; and (9) in the electronic support At least one matrix material on at least a portion of at least one fabric of the body. Another embodiment of the invention is directed to a method of forming an electronic support, the method comprising the steps of: (a) obtaining at least one portion of at least one of the yarns by weaving at least one yarn comprising a plurality of fibers Having a first resin compatible coating layer, and at least one warp yarn comprising a plurality of fibers and having a second resin compatible coating on at least a portion of the at least one warp yarn to form a fabric suitable for reinforcing the electron support; (b) at least partially coating at least a portion of the fabric with a matrix material resin; (c) at least partially hardening the coating into at least a portion of the fabric to form a prepreg layer; and (d) Or ~ more prepreg layers laminated with one or more conductive layers at the paper scale applicable to China National Standard (CNS) A4 (21〇x 297 mm) I h.----- -----装-----r---订--------- (Please read the notes on the back and fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Officer X Consumer Cooperatives Print A7 B7 V. Description of the invention (89) - Forming - an electron support. In a more preferred embodiment, the at least one fabric and the at least one matrix form a first composite layer in the electron support. In another preferred embodiment, the electron support further comprises a second composite layer that is different from the first composite layer. Further preferred embodiments relate to an electronic circuit board comprising (a) an electronic support comprising (1) at least one non-defatted fabric comprising at least one fiber strand, at least a portion of at least one non-defatted fabric having a matrix material phase a coating, and (ii) at least one matrix material on at least a portion of at least one of the fabrics of the electronic support, and (8) a conductive layer, a support and a conductive layer. Included in the electronic circuit board. Further preferred embodiments relate to an electronic circuit board comprising (4) an electronic support comprising (1) at least one fiber comprising at least one fiber strand and having an untrimmed resin compatible coating composition on at least a portion of the surface of the fiber a fabric, and (ii) at least one matrix material on at least a portion of at least one of the electronic supports; and (b) a conductive layer, the support and the conductive layer are contained in the electronic circuit board. In a more preferred embodiment, the selected portion of the adjacent electron support houses a conductive layer. In another preferred embodiment, the at least one fabric and the at least one matrix form a first composite layer. In another embodiment, the electron support further comprises a second composite layer that is different from the first composite layer. Preferably, the selected portion of the first and/or second composite layers of adjacent electron supports are provided with a conductive layer. Another embodiment of the present invention relates to a method of forming a printed circuit board, the method comprising the steps of: -92- _______ The paper size is applicable to the China National Standard (CNS) A4 specification (210 X 297 mm) --- ------------l· 丨丨I ·1111!111 line (please read the notes on the back and fill out this page) 1283255

V. Description of invention (90) Printed by the Consumers' Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs a) Obtained. Having at least one yarn comprising a plurality of fibers and having a first resin compatible coating on at least a portion of the at least one yarn, and at least one warp yarn comprising a plurality of fibers and at least one warp yarn Having a second resin-compatible coating formed thereon, comprising one or more conductive layers and at least one electronic support suitable for reinforcing the fabric of the electron support; (b) one or more of the electron supports At least one of the conductive layers is patterned to form a printed circuit board. The ingredients used in the coatings of the above specific embodiments relating to the electronic support and the electronic circuit board may be selected from the components discussed above, and the other ingredients may be selected from the following. If desired, any convenient method known in the art may be employed, including but not limited to mechanical drilling and laser drilling, forming perforations or holes (also referred to as "vias") in the electronic support to enable the electronic support Electrical interconnection between circuits and/or components on opposite surfaces of the body. More specifically, referring to Fig. 10, perforations 1060 extend through at least one layer 1062 of fabric 1012 of electronic support 1054 of the present invention. Fabric 1012 comprises coated fiber strands comprising a plurality of glass fibers having layers compatible with the various polymeric matrix materials, as illustrated herein. In forming the perforations 1060, the electron support 1〇54 is placed in a perforation forming device such as a drill cone 1064 or a laser head. A perforation 1060 through a portion 1066 of at least one of the layers 1062 of the fabric 1012 is formed by the use of a drill cone 1064 or laser. In a preferred embodiment, a 0. 46 mm (0.018 inch) diameter tungsten carbide drill bit is used, with a hole size of 6.2 degrees per square centimeter (62 holes per square inch) and a sheet of 0.001. Load, through the stack of 3 laminates -93- This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 public f &quot; I ^------------ installed -- ---^----订--------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Officer X Consumer Co., Ltd. Print 5, Invention Description ( 91) After drilling 2000 holes, the laminate has an error distance of no more than 36 microns. In an additional embodiment, a 0.46 mm (0.018 inch) diameter tungsten carbide drill bit is used, with 62 holes per square centimeter (per The hole density of 400 holes per square inch and the plate load of 0.001, after drilling 2000 holes through the stack of 3 laminates, the laminate has a drill wear % of not more than 32% 〇 in other specific examples Medium' distributes the fluid stream containing the inorganic lubricant to the vicinity of the perforation forming device, so that the inorganic lubricant contacts the perforation forming device At least a portion of the interface with the electronic support. Preferably, the inorganic lubricant is selected from the inorganic lubricants detailed above. Another embodiment of the present invention relates to forming an electronic system support fabric for an electronic circuit board. A method of perforating a layer comprising: (1) positioning an electronic system support comprising a fabric layer comprising coated fiber strands comprising a resin compatible coating composition on at least one of the surface of the fabric a part in which a perforation is formed by a perforation forming device; and (2) a perforation is formed in a layer portion of the fabric. After the perforation is formed, a layer of electrically conductive material is deposited on the perforated wall or filled with a conductive material to facilitate the electron support. 1054 required electrical interconnection and/or heat dissipation between one or more conductive layers (not shown in Figure 10). The vias extend partially or completely through the electronic support and/or printed circuit board It can be exposed on one or both surfaces of the electronic support and/or printed circuit board 'or it can be completely hidden or contained in the electronic support and/or printed circuit board (&quot;hidden path&quot;). Where# The conductive layer 820 can be any one known to those skilled in the art-----------------Γ------------- line (please Read the notes on the back and fill out this page.) -94- 1283255 A7 V. Invention Description (92 (Please read the note on the back and fill out this page). Form - If not limiting the invention, $1 It may be formed by laminating a thin sheet of metal material or tantalum on at least a portion of the side of the semi-hardened or hardened prepreg or laminate. Alternatively, the conductive layer may be formed by using known techniques, including but not Limited to electroplating, electro-electric boats or spray boats, a layer of metallic material is deposited on the side of at least a portion of the semi-hardened or hardened prepreg or laminate. Metallic materials suitable as conductive layers include, but are not limited to, copper (preferred), silver, aluminum, gold, tin, tin-lead alloys, palladium, and combinations thereof. In another non-limiting embodiment of the present invention, the electronic support may be formed by combining one or more electronic circuit boards (described above) with one or more facing members (described above) and/or one A plurality of prepreg yarns (described above) are laminated together to form a multilayer electronic circuit board. If desired, an additional conductive layer is added to the electronic support, for example, to expose the side along a portion of the multilayer electronic circuit board. In addition, additional circuitry can be formed from the conductive layer in the manner discussed above, if desired. It will be appreciated that the board may have internal and external circuitry depending on the relative position of the layers of the multilayer electronic circuit board. As discussed previously, additional vias are formed partially or completely through the plates to electrically interconnect the layers at selected locations. It should be understood that the resulting structure may have some perforations printed by the Ministry of Economics, the Department of Economics, and the Consumer Council, X-Drug Co., Ltd., some of which are only partially perforated through the structure, and some perforations that are completely within the structure. Preferably, the thickness of the laminate forming the electron support 254 is greater than 0 051 mm (about 0·002 inch), and more preferably in the range of 〇13 mm (about 〇〇〇5 inches) to 2.5 mm (about 〇.1 miles). The eight layer laminate for the 7628 type fabric typically has a thickness of 1.32 inches (about 52 inches). The number of layers of iron in the laminate can vary depending on the desired thickness of the laminate.

1283255 A7 B7 V. INSTRUCTIONS (93) . (Please read the notes on the back and fill out this page.) The laminate-resin content is preferably in the range of 35 to 80% by weight, and -- a better 40 Up to 75% by weight. The amount of the fabric in the laminate is preferably in the range of 20 to 65% by weight, and more preferably 25 to 60% by weight. Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed on laminates made of woven E-glass fabric and FR-4 epoxy resin matrix with a minimum glass transition temperature of 110 °C, in accordance with IPC-4101 Specification for Base Materials For Rigid and Multilayer Printed Boards&quot;, page 20, The Institute for Interconnecting and Packaging Electronic Circuits (December 1997), traversing machine or width direction (roughly vertical fabric draw, ie, in the filling direction) The minimum minimum flexural strength is greater than 3 X 107 kg/m2, more preferably greater than 3.52 X 107 kg/m2 (about 50 kpsi), and even more preferably greater than, 4·9 X 107 kg/m2 (about 70 Kpsi). IPC-4101 is specifically incorporated herein by reference. In the longitudinal direction, the required minimum flexural strength in the longitudinal direction (substantially parallel to the longitudinal axis of the fabric, i.e., in the warp direction) is preferably greater than 4 x 107 kg/m2, and more preferably greater than 4.23 X 107 kg/ Square meters. The flexural strength is measured in accordance with ASTM D-790 and IPC-TM-650 Test Methods Manual of the Institute for Interconnecting and Packaging Electronic Circuits (December 1994), which is specifically incorporated herein by reference, and by reference to IPC. The 3.S.2.4 part of -4101 completely removes the metal facing. Advantages of the electronic support of the present invention include high flexibility (tension and compressive strength) and high modulus, which can reduce deformation of the board (including laminate). In accordance with IPC Test Method 2.4.4.1 (which is specifically incorporated herein by reference), the copper support FR-4 epoxy-based laminate in the form of an electron support-96- paper scale applies to Chinese national standards ( CNS) A4 specification (210 X 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (94) Preferably in the z-direction of layer-composition (&quot;z-CTE" That is, the thickness of the delaminated laminate has a coefficient of thermal expansion of from 0.01 to 5.0% by weight to 50 ° C to 288 ° C. Each such laminate preferably comprises eight layers of 7628 type fabric, although Or a type of fabric such as, but not limited to, 106, 1〇8, 1080, 2113, 2116 or 7535. Further, laminates may be added to combinations of these fabric types. Laminates having a low coefficient of thermal expansion are generally less prone to swelling. And shrinking and minimizing plate distortion. The invention is more intended to be a multilayer laminate and an electronic circuit board, comprising at least one composite layer fabricated in accordance with the teachings herein, and at least one different from a composite layer produced by the method of presenting the composite layer, for example Conventional fiberglass composite techniques are used, more particularly and as known to those skilled in the art, to include, in part or in whole, a partially or fully dextrinized starch or linear powder, a hydrogenated vegetable oil, a cationic wetting agent, Emulsifier and water starch/oil slurry, including but not limited to those disclosed in Loewenst, pp. 237-244 (3rd edition, 1993), which is specifically incorporated herein by reference for Woven fibers in the continuous glass fiber strands of the fabric. The warp yarns produced from these strands are then treated with a solution prior to weaving to protect the strands from abrasion during weaving, for example, poly(vinyl alcohol), such as U.S. Patent 4,530,876. 3 blocks, lines 67 to 4, the disclosure of which is incorporated herein by reference. Compatible with the polymeric matrix material used by the composite manufacturer, thus removing the fabric to remove substantially all of the organic material from the surface of the glass fiber prior to impregnating the woven fabric. This can be accomplished in a number of ways, such as by washing the fabric, or often With this skill known -97 · This paper scales applicable Chinese National Standard (CNS) A4 size (210 X 297 mm) (Please read the back of the precautions to fill out this page)

dM order---------Part 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention Description (95) Method of heat - fabric. As a result of the cleaning operation, there is no suitable interface between the polymeric matrix material and the surface of the cleaned glass fibers for impregnating the fabric, such that the coupling agent must be applied to the surface of the glass fibers. This operation is sometimes referred to as being trimmed by the skilled artisan. The coupling agent most commonly used in trimming operations is smoldering, including but not limited to those disclosed by E. P. Plueddemann, Silane Coupling Agents (1982), pp. 146-147, which is incorporated herein by reference in its entirety. See also Loewenstein, pp. 249-256 (3rd edition, 1993). After treatment with decane, the fabric is impregnated with a compatible polymeric matrix material, extruded between a set of metering rolls, and dried to form a semi-cured prepreg. Yarn, as discussed above. It will be appreciated that in the present invention, the nature of the slurry, the cleaning operation and/or the finishing step are considered. One or more prepregs incorporating conventional glass fiber composite technology can then be combined with one or more prepregs incorporating the present invention to form the electronic supports discussed above, particularly multilayer laminates or electrons Circuit board. For more information on electronic circuit board manufacturing, see Electronic Materials HandbookTM, ASM International (1989) pp. 113-115, R. Tummala (editor) Microelectronics Packaging Handbook. (1989) 858-861 and 895-909 Page, Printed Circuit Board Handbook by M. W. Jawitz, 1997, pp. 9.1-9.42, and CF Coombs, Jr. (eds.) Printed Circuits Handbook. (3rd edition, 1988), pp. 6.1-6.7, It is specifically incorporated herein by reference. The composites and laminates forming the electronic support of the present invention can be used to form packages for the electronics industry, more particularly first, second and/or third layer packages, as disclosed in Tummala, pp. 25-43. It is specifically incorporated herein by reference. In addition, the invention is also applicable to other encapsulating layers. -98 - This paper size is applicable to China National Standard (CNS) A4 specification <210 X 297 mm) ----------------Installation--------Set-- ------- (Please read the notes on the back and fill out this page) 1283255

In a non-limiting embodiment, in accordance with the present invention, an 8-layer prepreg yarn (which: 7628 type, E-glass fabric, and a 14-inch core 4 polymer tree) U, and in accordance with ipc_TM- 65〇, N〇2 4 4 (which is specifically incorporated herein by reference) the flexural strength of the uncovered laminate tested, preferably greater than one inch per square inch when tested in the direction of the warp yarn of the flat fabric Ιοο'οοο lb (approx. 690 million baska), and when tested in the direction of filling of parallel fabrics, the car is better than 80, _ 碲 (about 552 million baska). And, in another embodiment of the present invention, according to the present invention, 8 layers of pre-twisted yarn (formed of 7628 type, E-glass fabric and FR-4 polymer resin having a Tg of 14 Å) are manufactured and used. The span length to thickness ratio of 5, according to ASTM D 2344-84 (which is specifically incorporated herein by reference), the short bundle shear strength of the uncovered laminate tested, when tested in the warp direction of parallel fabrics, Preferably, it is greater than 74 pounds per square inch (about W million Baska), and when tested in the direction of filling of parallel fabrics, it is preferably greater than 5600 pounds per square inch (about 39 million Baska). . In another embodiment of the present invention I, according to the present invention, an 8-layer prepreg yarn (formed of a 7628 type, an E-glass fabric, and an FR-4 polymer resin having a Tg of 140 X:) is used, and 5 is used. The span length to thickness ratio and the short bundle shear strength of the uncoated laminate according to ASTM D 2344-84 after being immersed in boiling water for 24 hours, preferably in the warp direction of the parallel fabric, preferably The square inch is greater than 5 pounds (about 34 million Bass) and is preferably greater than 4200 pounds per square inch (about 30 million Bass) when tested in the direction of filling of the parallel fabric. The invention also includes a method of strengthening a matrix material to form a composite. This side|_____ -99- This paper ruler _ _ home standard (CNS) A4 gauge &amp; ((10)x 297 male cage II' 0M.--------^---------^9 — (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Inventions (97 Ministry of Economy

The method of I comprises: (1) applying at least one of the first, second and/or second coating compositions discussed in detail above, which comprises particles providing interstitial space between adjacent fibers of the strand, to the fiber strand reinforcing material (2) drying the coating to form a coating on the reinforcing material, (3) combining the reinforcing material with the matrix material; and (4) hardening the matrix material to at least 4 to provide a strengthening composite. While not limiting the invention, the reinforcing material can be combined with a polymeric matrix material, for example, by dispersing it in a matrix material. Preferably, the coating forms a substantially uniform coating on the reinforcing material upon drying. In a non-limiting embodiment of the invention, the granules comprise at least 20% by weight of the oversize composition based on the total solids. In another non-limiting embodiment, the particles have a minimum average particle size of at least 3 microns and preferably at least 5 microns. In other non-limiting embodiments, the particles have a Mohs hardness 値 that is less than any Mohs hardness of the glass fibers contained in the fiber strands. The invention also includes a method of inhibiting adhesion between adjacent fibers of a fiber strand, comprising the steps of: (1) at least one of the first, second and/or second coating compositions discussed in detail above (which are included in the Particles providing interstitial space between adjacent fibers are coated on the fiber strands, and (2) the coating is dried to form a coating on the fibers of the fiber strands such that adhesion between adjacent fibers of the strands is inhibited. Preferably, the coating forms a substantially uniform coating on the reinforcing material upon drying. In a non-limiting embodiment of the invention, the granules comprise at least 20% by weight of the oversize slurry composition based on total solids. In another non-limiting embodiment, the particles have a minimum average particle size of at least 3 microns, and preferably at least 5 microns. For example, in spherical particles, the minimum average particle size is equivalent to the particle diameter. For example, in rectangular particles, the minimum average particle size refers to the average length, width, or height. In the other non-restricted body -100- — I. ---------^i.------- (Please read the note on the back and fill out this page) National Standard (CNS) A4 specification (21G X 297 public i

1283255 V. INSTRUCTION DESCRIPTION (98) In the example, the granules have a Mohs hardness 値 which is less than the Mohs hardness of any glass fiber contained in the fiber strands. The invention also includes a method of inhibiting hydrolysis of a matrix material of a fiber reinforced composite. The method comprises: (1) applying at least one of the first, second and/or third coating compositions discussed in detail above, comprising discrete particles greater than 2% by weight based on total solids, to the fiber strands Reinforcing the material, (2) drying the coating to form a coating on the reinforcing material; (3) combining the reinforcing material with the matrix material; and (4) at least partially hardening the matrix material to provide a reinforced composite. Preferably, the coating forms a substantially uniform coating on the reinforcing material upon drying. As discussed above, the reinforcing material can be combined by, for example, dispersing the reinforcing material in the matrix material. In a non-limiting embodiment of the invention, the fabric is preferably woven into a 7628 type fabric and has a gas permeability of less than 1 inch cubic foot per minute, and more preferably less than 5 cubic feet per minute, such as ASTM D 737. Measured by the standard test method for the wetting force of textile fabrics. Although not limited in the present invention, a variety of conventional fabrics made using sizing warp yarns are believed to be useful, and it is believed that the elongated cross-section of the warp yarns of the present invention and high strand openness (discussed in detail below) reduce the breathability of the fabrics of the present invention. As previously discussed, in conventional weaving operations for electronic support applications, the warp yarns are typically coated with a sizing slurry prior to weaving to help prevent warp yarns from sticking during weaving. The sizing sizing composition is typically applied to the warp yarns by passing the warp yarns through a dipping pan or bath containing the slurry on the sizing yarn and then passing one or more sets of squeezing rolls to remove any excess material. Typical sizing sizing compositions can include 'examples and? Film forming materials, plasticizers and lubricants. Commonly used in sizing-101 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ——---------------l·--- --------- Line Φ- (Please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Η Consumer Cooperative Printed 1283255 A7 B7 V. Invention Description (99) _ (Read first Precautions for the back side Fill in this page) The sizing composition - the film forming material is polyvinyl alcohol. After the sizing, the warp yarns are dried, _ _ dry and wound on the woven shaft. The number and spacing of the ends of the warp yarns depend on the type of fabric to be woven. After drying, the warp yarns of the sizing generally have an ignition loss of greater than 2.0% due to the combination of the first and sizing on the sizing. In general, the sizing slurry, and the starch/oil slurry, when added to the fabric as a reinforcement for the electron support, are generally not compatible with the polymeric resin material of the composite manufacturer, necessitating the impregnation of the textile. The fabric is removed prior to the fabric to remove substantially all of the organic material from the surface of the fiberglass. It can be accomplished in a number of ways, for example, by laundering the fabric, or more often by heat treating the fabric by methods known in the art. As a result of the cleaning operation, there is no suitable interface between the polymeric matrix material used to impregnate the fabric and the surface of the cleaned glass fibers, such that the coupling agent must be applied to the surface of the glass fibers. This operation is sometimes referred to as trimming by those skilled in the art. In general, the trimming slurries provide a LOI of less than 0.1 for the fabric. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives, after the processing of the finished slurry, the fabric is impregnated with a compatible polymeric matrix material, extruded between a set of metering rolls, and dried to form a semi-cured prepreg, As discussed above. For more information on electronic circuit board manufacturing, see Electronic Materials HandbookTM, ASM International (1989), pp. 113_115, R. Tummala (editor), Microelectronics Packaging Handbook, (1989) pp. 858-861 and 895-909. M. W. Jawitz's Printed Circuit Board Handbook (1997) pp. 9.1-9.42, and CF Coombs, Jr. (eds.) Printed Circuits Handbook (3rd edition, 1988), pp. 6.1-6.7, special This is incorporated herein by reference. _ . -102- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) !283255

V. INSTRUCTIONS INSTRUCTIONS (1〇〇) Employees of the Ministry of Economic Affairs, the Ministry of Finance and Industry, Consumers' Printing Co., Ltd. Printed Because the sizing-process places a relatively thick coating on the warp yarns, the yarns are harder and less flexible than the warp yarns. The sizing slurry tends to hold the yarns together into a tight bundle of generally circular cross-sections. While not limiting the invention, it is believed that such a yarn structure (i.e., a tight bundle and a substantially circular cross-section) may interfere with the penetration of the polymeric resin material into the warp yarns during subsequent processing steps, such as pre-impregnation, even if After removing the slurry on the sizing. Although the sizing is not harmful to the present invention, the sizing is not good. Thus, in a preferred embodiment of the invention, the warp yarns are not subjected to the sizing step prior to weaving, and substantially no slurry residue on the sizing. As used herein, the term "substantially absent" means that the warp yarn has a sizing residue on the sizing of less than 2 〇 ❶ / c, more preferably less than 5% by weight. In a more preferred embodiment of the invention, the warp yarns do not accept the sizing step prior to weaving, and are essentially free of slurry residue on the sizing. The term "essentially absent" as used herein means that the warp yarn has less than 〇·5 wt% on its surface, more preferably less than oj wt%, and most preferably 〇% by weight of the sizing residue on the sizing yarn. . However, if the warp yarn is subjected to the second coating operation before weaving, it is preferred that the amount of the second coating applied to the surface of the warp yarn before weaving is less than 0.7% by weight of the sizing warp yarn. In a preferred embodiment of the invention, the warp yarn ignition loss is preferably less than 2.5 weight ❶/ during weaving. , better than less! 5% by weight, and most preferably less than 〇·8% by weight. Further, the fabric of the present invention preferably has a total ignition loss of from 1 to 1.6%, more preferably from 4 to 13%, and even more preferably from 0.6 to 1%. In another non-limiting embodiment of the invention, the warp yarns preferably have an elongated cross face and a high strand openness. The term used here, the long cross-cut _ 103 - I paper scale applies to the country of the country (CNS) A4 specifications (21G X 297 public) _ --Γ---------- -----r---book--------- line (please read the notes on the back and fill out this page) 1283255 A7

V. INSTRUCTIONS (l〇1) The Printed Face of the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs indicates that the warp yarn has a substantially flat or elliptical cross-sectional shape. The high-volume openness discussed above refers to the individual fibers of the yarn or strand that are not closely held together, and the open space between one or more individual fibers facilitates the penetration of the matrix material into the bundle. The sizing warp yarns (as discussed above) typically have round cross-sections and low strand openness, which is detrimental to this penetration. Although not limiting in the present invention, it is believed that by reducing or eliminating the path of moisture entering the laminate and the electron support, a good resin penetrates into the warp yarn bundle during lamination (ie, a good resin is wet through) The total hydrolysis stability of the laminate and the electron support produced in accordance with the present invention can be improved. It also has a tendency to cause an electrical short-circuit failure due to the formation of conductive anode filaments under partial pressure when exposed to wet conditions in a printed circuit board made of such a laminate and an electronic support, and may also have a positive influence. The degree of openness of the shares can be measured by the F-index test. In the F-index test, the measured yarn is placed through a series of vertically aligned rolls and adjacent to the horizontally-configured sensing device comprising the illuminated surface and the opposite photosensitive surface such that the vertical axis of the yarn is aligned substantially parallel to the illuminated and photosensitive surface. . The sensing device is mounted at a vertical height of approximately halfway between the vertically aligned rollers and controls the horizontal distance between the yarn and the sensing device by moving the roller toward or away from the sensing device. When the yarn passes through the roller (typically about 30 meters per minute), depending on the openness of the strand, one or more portions of the yarn can shield a portion of the light from the illuminated surface, thereby triggering the photosensitive device reaction. The amount of shading is then tabulated for a particular yarn length (typically about 10 meters) and the ratio (i.e., the amount of shading per unit length) is taken as a measure of the openness of the strand. It is believed that the tight warp structure of the fabric of the sizing glass fiber yarn and the -104- paper scale are applicable to the Chinese national standard &lt;CNS) A4 specification (210 X 297 mm) ------- -----------r---book--------- (please read the note on the back? Please fill out this page again) 1283255 A7 Ministry of Economic Affairs Intellectual Property Officer X Consumer Cooperative Printing 5, Invention Description (102) The low release of such yarns (as discussed above) results in these conventional fabrics having a fabric that is preferred over the present invention (preferably including long warp cross-sections and High crepe openness) breathable force with high air permeability. In a non-limiting embodiment of the invention, the fabric has a standard cubic inch per square inch per square inch (approximately 0.05 standard cubic meters per minute per square meter) as measured by the ASTM D 737 standard test method. More preferably, it is not more than 5 cubic feet per square inch per minute (152 standard cubic meters per minute per square meter), and is preferably no more than 3 cubic feet per square inch per minute (about every square meter per minute) 0.91 standard cubic meter) of air permeability. In another embodiment of the invention, the fabric is woven into a 7628 type fabric and has a standard cubic inch per square inch per minute as measured by ASTM D 737 standard test method, more preferably Not more than 5 cubic feet per square inch per minute, and optimally no more than 3 cubic feet per square inch per minute. Although not meant to be bound by any particular theory or in any way, it is claimed to have a long or average cross. The cross-section warp yarns can also improve the copper-boring properties in laminates made from fabrics incorporating warp yarns. More particularly, since the intersection between the warp yarn and the yarn in the fabric having the elongated cross-section warp yarn has a lower shape than the conventional fabric having the circular cross-section warp yarn, the drill cone drilled through the fabric contacts the drill hole Very few glass fibers, resulting in less wear. As previously discussed, in a particular embodiment of the invention, it is preferred that both the warp yarn and the yarn have a resin compatible first coating composition that is applied upon formation. The first coating composition applied to the warp-to-resin-compatible resin may be the same as the first coating composition compatible with the coated yarn, or it may be different from the resin coated on the yarn I.. --- II---装-----^----订------1_ (Please read the notes on the back and fill out this page) -105· 1283255 A7

Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperative of the Ministry of Economics. Compatible with the first coating-layer composition. Reference is made herein to the use of a resin-compatible first coating composition applied to a warp yarn, which is equivalent to a resin-compatible first coating composition applied to a yarn filling, and the first coating applied to the warp yarn. At least one component of the composition is present in an amount different from the first coating composition applied to the yarn filling or at least one component of the first coating composition applied to the warp yarn is not present in the coating. At least one component of the first coating composition, or the first coating composition applied to the yarn, is not present in the first coating composition applied to the warp yarn. Another non-limiting specificity of the present invention In an embodiment, the glass fibers of the yarn of the fabric are glass fibers having a density of less than 2.60 grams per cubic centimeter. In another non-limiting embodiment, the E-glass fiber yarn is manufactured to be greater than when the fabric is a 7628 fabric. A fabric of the same type of conventional heat-clearing and dressing fabric strength (warp direction) parallel warp direction tensile strength. In another non-limiting embodiment of the invention, preferably, the resin compatible first coating composition is No Adhesive ,, the like "film-forming material, i.e., a first coating composition comprising preferably less than 1〇 based on the total solids weight ° / square, more preferably less than 5 by weight based on total% solids. In a preferred embodiment, the resin compatible first coating composition is substantially free of &quot;gummy&quot; film forming material, i.e., the first coating composition comprises preferably less than 1% by weight based on total solids. More preferably, it is less than 〇5% by weight based on the total solids, and is preferably a binder-forming material based on a total solids of less than 〇·1 by weight. The adhesive film forming material is such that the air is injected by the lowering of the yarn. The transport force and the warp yarns adhere to each other, and the weaving power of the coated yarn is harmful. A specific non-limiting example of the film forming material is a water-soluble ring ------------ ------r---book--------- line (please read the notes on the back and fill out this page) -106- 1283255 A7 B7

, -----r---book--------- line (please read the note on the back and then fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 ---- -- B7 _ V. Invention Description (Milk) Solution. In addition, after the sizing composition is removed by heat removal, the sizing slurry must be applied to the fabric before impregnation. In order to improve the compatibility between the fabric and the polymer resin, the resin-compatible coating is applied to the warp yarns and/or the yarns before the weaving of the present invention, thereby eliminating the need for fabric finishing. In another preferred embodiment of the invention, the fabric is preferably substantially free of residuals/denier from the second coating and/or the topping slurry, i.e., less than 15% by weight, more preferably less than 1% by weight. The % residue is from the second coating and/or the trimmed slurry. In a more preferred embodiment of the invention, the fabric is essentially free of residue from the second coating and/or the conditioning slurry. The noun &quot;essentially&quot; means that the fabric has a weight less than 丨/〇, more preferably less than 0.5 ❶/. Coating and/or conditioning of the upper slurry. The invention is now described by the following specific non-limiting specific examples.Example 1 The ingredients of the amounts described in Table 1A were mixed in a manner similar to that discussed above to form an aqueous formation in accordance with the present invention. Sizing composition A_F. Less than i% by weight of the foot acetic acid is included in each composition. The aqueous forming sizing composition Af is applied to the E-glass fiber strands. Each of the sizing compositions formed has 25 wt% solids. In a similar manner using a conventional interlacing device, each coated glass fiber strand is interlaced to form a yarn and wound on a bobbin. The sample Bvac is coated with an aqueous forming composition B, but the temperature is hollowed out at 19 Torr. Dry for about 46 hours. Samples AF each have an ignition loss of less than 1 weight ❶/〇. The sample Chl anti-D_hl each has an ignition loss of ι·59 and weight ❶/❶. _____- 108 - This paper scale applies to Chinese national standards (CNS) A4 specification (210 X 297 public) A ' -----r------------ (Please read the note on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Employee consumption cooperative printed 1283255 A7 ___B7 Explain (1〇6)

Table 1A Component weight % based on total solids Sample composition ABCDEF RD-847A97 28.6 29.1 31.58 50.71 0 0 DESMOPHEN200098 43.7 39.1 0 0 0 0 EPI-REZ 3522-W-66&quot; 0 0 21.05 0 0 0 EPON 826100 0 0 0 0 16.12 63.54 PVP-K30101 0 9.7 15.79 15.21 1.31 5.18 Α-187102 2.3 2.3 8.42 8.11 3.17 12.51 Α-174103 4.7 4.8 0 0 0 0 Α-1100104 0 0 8.42 8.11 0 0 PLURONIC F-108105 10.7 5.6 0 0 0 0 IGEPAL CA- 630106 0 0 4.74 6.39 1.63 6.44 VERSAMED 140107 4.8 4.8 0 0 0 0 ALKAMULS EL-719108 0 0 0 0 1.63 6.44 KESSCO PEG 600109 0 0 0 0 0.79 3.11 MACOL NP-6110 3.6 3.6 4.74 6.39 0 0 97 RD_847A polyester resin, Commercially available from Borden Chemicals, Columbus, Ohio, 0 98 DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer Corporation of Pittsburgh, Pa. 99 EPI-REZ 3522-W-66 Commercially available from Shell Chemical, Texas, USA ^ ^ 〇-1Ό9 · This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---I--- -----------^----Order---------Line (please read the notes on the back and fill out this page) Printed by the Intellectual Property Office of the Ministry of Economic Affairs 1283255 A7 _B7 V. INSTRUCTIONS (1〇7) 100 EPON 826, commercially available from Shell Chemicals, Houston, Texas. 1G1 PVP-K30 polyvinylpyrrolidone commercially available from ISP Chemicals, Inc. of Wayne, New Jersey, 0 1G2 Α-187 γ-dehydrated propyl trimethoxy decane, commercially available from Tarrytown, New York. CK Witco. Igω Α-174 γ-methacryloxypropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 1G4 A-1100 Amino-functional organodecane coupling agent commercially available from CK Witco, Tarrytown, New York. 1Q5 PLURONICTM F-108 polyoxypropylene-polyoxyethylene copolymer, commercially available from New Zealand: BASF Corporation of Parsippany, Jersey. 1G6 IGEPAL CA-630 ethoxylated octylphenoxyethanol commercially available from GAF Corporation of Wayne, Jersey. 107 VERSAMID 140 Polyamide, commercially available from Cognis Inc. of Cincinnati, Ohio, 1G8 ALKAMULS EL-719 polyoxyethylated vegetable oil, commercially available from Phone-Poulenc, Inc. 109KESSC〇PEG 000 polyethylene glycol monolaurate Ester, commercially available from Stepan Corporation of Chicago, Ill. 11G MACOL NP-6 phenolic surfactant, commercially available from BASF, Parsippany, New Jersey 0 - 110 - This paper scale applies to the Chinese National Standard &lt;CNS) A4 Specification (210 X 297 mm) I -- -------装--------Book---------^9. (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Description of invention ( (10)) Table 1A (continued) Component weight based on total solids Sample composition AB c DEF EMERY 6717111 0 0 0 0 0.40 1.56 EMERY 6760112 0 0 4.21 4.06 0 0 POLYOX WSR-301113 0.6 0 0 0 0 0 POLARTHERMPT 160114 1.0 1.0 0 0 74.78 1.00 RELEASECOAT-CONC 25115 0 0 1.05 1.01 0 0 111 EMERY® 6717 partially brewed aminated ethylenediimide commercially available from Cognis, Cincinnati, Ohio. 112 EMERY® 6760 Lubricant, commercially available from Cognis, Inc., Cincinnati, Ohio 〇 113 POLYOX WSR-301 poly(ethylene oxide) commercially available from Union Carbide, Danbury, Connecticut. 114 POLARTHERM® PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. 115 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride granules in aqueous dispersions, commercially available from ZYP Coatings, Inc., Oak Ridge, Tennessee 0 also evaluated commercially available products 631 and 633 D-450 coated starch-oil yarns; A comparative sample of starch-oil yarn and 1383 G-75 yarn was applied at 690 and 695, commercially available from PPG Industries. In addition, three comparative -111- coatings of the same aqueous forming composition X described in the following table were also tested (please read the back of the note first and then fill in this page) ί装-----订--- ------ Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printing too much mistakes, Φ 圃圃窒 圃圃窒 Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ Τ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Printed by the employee consumption cooperative. V. Description of invention (109). Samples XI, -X2 and X3. Comparative Sample XI had a solid-integral of 2.5% by weight. Comparative sample X2 had a solid of 4.9% by weight and was air dried at 25 °C for about 8 hours. Comparative Sample X3 had a solid of 4.6% by weight.

Table 1B Component based on total solids wt% Component X RD-847A116 28.9 DESMOPHEN 2000117 44.1 A-187118 2.3 A-174119 4.8 PLURONIC F-108120 10.9 VERSAMID 140121 4.8 MACOL NP-6122 3.6 POLYOX WSR-301123 0.6 116 RD-847A Ester resin, commercially available from Borden Chemicals, Inc. of COlumbus, Ohio. 117 DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer Corporation of Pittsburgh, Pennsylvania. 118 A-187 γ-Glycidylpropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 119 Α-174 γ-Methoxypropoxypropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, Jo.. 12G PLURONICTM F-108 poly(propylene oxide)-polyoxyethylene copolymer, commercially available from BASF, Parsippany, Jersey. -112- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) --:---------------„----订---- -----Line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _ B7 V. Invention Description (111) 1 Table 1C Sample Number Yarn Type LOI (% Resistance (gram force) Air jet transport resistance (grams per gram of mass) A G-75 0.35 68.5 130,474 B G-75 0.30 84.9 128,248 B vac G-75 0.35 95.0 143,587 c D-450 0.52 37.33 278,582 D D- 450 0.40 47.1 351,493 E G-75 0.35 79.3 119,789 F G-75 0.35 83.2 125,680 Comparative sample 631* D-450 1.6 21.45 160,075 633* D-450 1.3 38.1 284,328 690* G-75 1.0 108.23 163,489 695* G-75 1.0 100.46 151,752 1383 G-75 0.75 14.47 21,858 XI G-75 0.33 36.4 5585 X2 G-75 0.75 19.0 28,701 X3 D-450 1.37 12.04 89,851 Chi D-45O 1.59 9.00 67,164 Chi D-450 1.66 10.43 77,836 Coated starch-oil Above slurry formulation. As shown in Table 1C above, each coated polymeric matrix material phase -114- (in accordance with the present invention) Please pay attention to this page.) 装装-----r---订----- ^•1. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed A7 B7 V. Invention Description (112). The sizing combination-object yarn AF has more than 100,000 air jet transport---resistance 値. Only starch-oil sizing Commercial strands have an air jet transport resistance of greater than 100,000, which is generally not compatible with the polymeric matrix materials discussed above. Sample yarns Chl and Dhl having a polymeric matrix compatible coating have a high coating content on the yarn (ie, greater than 1.5% ignition loss) and air jet transport resistance 大于 greater than 100,000, which inhibits the separation of fibers or the fibrillation of the yarn by air injection. To assess laminate strength, samples of each of 695, sample B and sample Bvac G-75 seconds (discussed above) formed a 7628 type fabric (type parameters discussed above). 8 layers of each fabric sample laminated EPON 1120-A80 epoxy resin (commercially available from Shell Chemical Company of Houston, Texas), dicyandiamide, 2-methylimidazole, and DOWANOL PM ethylene glycol ether (commercially self-contained) The FR-4 resin system of The Dow Chemical Company of Midland, West Michigan to form a laminate. Evaluating the flexural strength of each laminate (maximum damage) in accordance with ASTM D-790 and IPC-TM-650 Test Methods Manual of the Institute for Interconnecting and Packaging Electronics (December 1994), which is specifically incorporated herein by reference. Stress), which is completely removed by a partial etching according to 3.8.2.4 of IPC-4101, and in accordance with ASTM D-2344, which is specifically incorporated herein by reference, using 15.9 mm (5/8 inch) The shear strength (short beam shear strength) of the laminate was evaluated by the span and the crosshead rate of 1.27 mm (0.05 inch) per minute. The results of these evaluations are shown in Table 1D below. -115- Scale applies to China's 0 standard (CNS) A4 specifications (210 X 297 mm) ------------Installation--------Set------- -- (Please read the notes on the back and fill out this page) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 5, Invention Description (II3)

Table 1D Sample Flexibility: Strength Flexibility Modulus Short Beam Shear Strength Baska psi Baska psi Baska psi B 4.9 X 106 71534 2.4 X 1〇10 3465000 2.6 X 107 3742 Bvac 5.0 X 106 72215 2.4 X 1〇10 3450600 2.5 X 107 3647 695 4.3 X 106 62959 2.3 X 1〇10 3360800 2.3 X 107 3264 As shown in Table ID, when comparing laminate samples prepared from 695 starch-oil coated glass fiber yarns, Laminate samples B and Bvac prepared in accordance with the present invention have higher flexural strength and modulus 値 and similar short beam shear strength. Also at 274 meters per minute by a pair of conventional tension measuring devices having a fixed column of about 5 cm (2 inches) diameter mounted between them to replace the linear path between the tension measuring devices. The sample was pulled at a rate, and a tension of 30 grams was applied to each of the yarn samples to evaluate the frictional forces of samples a and B and comparative samples 1383 and XI. The difference in gram strength is described in the following table IE. The friction test is intended to simulate the frictional force that the yarn is subjected to during the weaving operation. The fractured filaments of samples A and B and comparative samples 1383 and XI were also evaluated using a wear tester. When each test sample was pulled at a rate of 0 46 m (18 in.) per minute for 5 minutes through a wear test apparatus, a tensile force of 200 g was applied to each test sample, and two tests of each sample and the comparative sample were evaluated, and the fiber was broken. The average number of filaments is reported in Table 1E below. The wear tester consisted of two parallel steel pieces arranged in columns of 1 inch apart. Each test yarn sample is spiraled between two adjacent reeds of the first row of reeds and then spiraled between the two phase reeds of the second row of ridges, but displaced between the two rows of reeds by half-pairs -116 - This paper size is applicable to China® Home Standard (CNS) A4 specification (210 X 297 mm) ~--- «I Γ---------装---- (Please read the notes on the back first) Fill in this page again) Order --- 1283255 A7 V. Description of invention (1H) Distance. Reeds are 240 m per minute; go, participate

, 24 υ 足 足 足 , , , , 足 足 足 足 足 足 足 蠖 足 。 。 。 。 。 。 。 。 。 。 。 (Please read the note on the back and then fill out this page.) As shown in Table 1Ε, when comparing comparative samples, the samples coated with the boron nitride-containing slurry composition have less ruthenium and ruthenium according to the present invention. Cracked fiber and low friction. Example 2 The components of the amounts described in Table 2 were mixed in a manner similar to that discussed above to form a slurry composition G and hydrazine according to the present invention, and a comparative sample. Less than 1% by weight of acetic acid based on the total weight is included in each composition. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumers' Cooperatives. The water-based sizing compositions Ε and F of Table 1 and the comparative sample γ of Table 2A were applied to g-75 E-glass fiber strands. Each of the sizing compositions formed has from 6 to 25% by weight solids. -117- Wood paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 B7 V. Description of invention (ll5) One strict table 2A Based on total solids Weight % Sample composition G Η Comparative sample Υ EPON 826124 16.12 63.54 60.98 PVP K-30125 1.31 5.18 4.97 ALKAMULS EL-719126 1.63 6.44 6.18 IGEPAL CA-630127 1.63 6.44 6.18 KESSCO PEG 600128 0.79 3.11 2.98 A-187129 3.17 12.51 12.00 EMERY 6717130 0.40 1.56 1.50 PROTOLUBE HD131 0 0 4.61 POLARTHERMPT 160132 0 0 0 RELEASECOAT-CONC 25133 74.78 1.00 0 124 EPON 826, commercially available from Shell Chemical Company of Houston, Texas. (Please read the precautions on the back and fill out this page) Install tri-------For the Ministry of Economic Affairs, the Intellectual Property Office, the employee consumption cooperative, print m PVP K-30 polyethyl phenylpyrrolidone, which is commercially available. ISP Chemicals, Inc. of Wayne, New Jersey 0 120 ALKAMULS EL-719 polyoxygenated vegetable oil, commercially available from Rhone-Poulenc Corporation 0 127IGEPAL CA-630 ethoxylated octylphenoxyethanol, commercially available from New York GAF, Wayne, Jersey. 128 KESSCO PEG 600 polyethylene glycol monolaurate commercially available from Stepan Corporation of Chicago, Illinois. -118- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 B7 V. Inventive Note (116), 129 Α-187 γ-dehydroglycerylpropyltrimethoxydecane, Its business is derived from CK Witco, Inc., Tarrytown, Jo.. nG EMERY® 6717 partially amided poly(ethyleneimine) commercially available from Cognis, Inc., Cincinnati, Ohio. 131 PROTOLUBE HD high density polyethylene emulsion commercially available from Sybron Chemicals of Birmingham, New Jersey. 132 POLARTHERM® PT160 boron nitride powder particles commercially available from Advanced Ceramics, Inc., Lakewood, Ohio. 0 133 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride particles in an aqueous dispersion commercially available from ZYP, Oak Ridge, Tennessee Coatings company. Each coated glass fiber strand is interwoven to form a yarn and wound onto a spool in a similar manner using conventional interlacing means. When the sample F and the yam yarn are interlaced, the slurry is peeled off at least, and the sample Ε and G are severely entangled when the interlacing occurs. The air resistance of the yarns of the sample E-Η and the comparative sample was evaluated in a manner similar to that of the above Example 1, except that the air resistance of the two bobbin samples was measured at the pressure shown in Table 2Β. A Shirley 84 041L rupture filament detector, commercially available from SDL International, UK, was used to evaluate the average number of ruptured filaments per 1200 meter of yarn per filament at 200 meters per minute. These 値 represent the average of the measurements taken on the four spools of each yarn. The portion taken from all the spools (136 grams (3/10 lbs) and 272 gram (6/10 lbs) of yarn from the bobbin) reported cracked fibrils. The tension of each gate is also evaluated. The test is described in Table 2B below. By (please read the note on the back and then fill out this page) install tr--------- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -119- 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative System A7 _B7 V. Description of invention (117) The 200 m/min 咱 spool unwinds the yarn sample, spirals the yarn through a series of eight, parallel ceramic needles, and passes the yarn through the Shirley rupture filament detector discussed above. In order to calculate the number of ruptured filaments, the number of ruptured filaments is measured according to the sluice tension method. 0 -12 Ό - 士 secret method J? 痒田士 tear G0 Xuan Huai Huai, OJC:, Δ/1 ϋ v 9CV7 shift, 丨;--- -------Install-----^----Book--------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Invention Description (118 ) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed a table 2B Sample rupture filament number per metre of yarn EFG Η Comparative sample Υ All spools 0.887 0.241 Greater than 10 0.065 0.192 136 g (3/10 lb) 0.856 0.017 Greater than 10 0.013 0.320 272 g (3/10 lb) 0.676 0,030 Greater than 10 0.101 0.192 Brake tension (number of hairs per meter) Gate 2 - 0.03 9 - 0.0235 0.721 Gate 3 - 0.025 - 0.028 0.571 Gate 4 - 0.0125 - 0.068 0.4795 Gate 5 - 0.015 - 0.093 0.85 Gate 6 - 0.0265 - 0.118 0.993 Gate 7 - 0.0695 - 0.31 1.0835 Gate 8 - 0.117 - 0.557 1.81 Air Resistance (g Number) 25 psi Spool 1 - 10.420 - 10.860 11.610 Spool 2 - 10.600 - 7.850 11.610 30 psi Spool 1 - 11.690 - 12.500 13.680 Spool 2 - 12.200 - 8.540 13.850 35 psi Spool 1 - 13.490 - 14.030 15.880 Spool 2 _ 13.530 - 9.570 15.630 40 psi bobbin 1 - 14.740 - 14.110 17.560 bobbin 2 - 14.860 - 11.010 17.610 45 psi bobbin 1 - 16.180 - 16.390 19.830 bobbin 2 - 16.680 - 12.700 18.950 50 psi bobbin 1 - 17.510 - 19.280 22.410 line pumping 2 - 17.730 - 14.000 20.310 55 psi Spool 1 - 19.570 - 23.350 29.350 Spool 2 19.660 - 20.250 26.580 -121 - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill in the form) This page)

1283255 V. INSTRUCTION DESCRIPTION (119) Although the test results shown in Table 显然 clearly show that the sample E-Η according to the present invention has a wear resistance substantially higher than that of the comparative sample γ, it is believed that these results are not deterministic because It is believed that the comparative sample of the polyethyl hydrazine emulsion component (not present in the sample E-Η) contributes to the abrasive properties of the yarn. Example 3 The ingredients in the amounts described in Table 3A were mixed to form aqueous sizing compositions K to N in accordance with the present invention. Each aqueous forming sizing composition was prepared in a manner similar to that discussed above. Acetic acid is included in each composition in an amount of less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 3A was applied to 2G-18E-breaking fiber strands. Each of the sizing compositions formed had a solid weight of 〇/(). ------------t-----r I--book--------- (Please read the note on the back first, then fill out this page, &gt; Economy Ministry of Intellectual Property Bureau employee consumption cooperative printing -122- This paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 ___B7 V. Invention description (l2〇) One production table 3A based on total solids Ingredient% by weight i 1 component KL Μ Ν Comparative sample 2 Thermoplastic polyurethane film forming polymer 134 34.4 34.2 33.4 31.35 34.5 Thermoplastic polyurethane film forming polymer 135 51.5 51.2 50.18 46.9 5L7 Poly Oxidized alkyl polyol copolymer 0.3 0.3 0.3 0.3 0.33 Epoxidized polyester lubricant 7.2 7.1 7.0 6.55 7.22 γ-Aminopropyl triethoxy hydride coupling agent 2.7 2.7 2.7 2.5 2.76 γ-ureidopropyl three Ethoxymontane coupling agent 3.3 3.3 3.2 3.0 3.34 Amino functional organodecane coupling agent 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 A polyurethane emulsion aqueous emulsion having 65% solids Particle charge, particle size of about 2 microns, pH of 7.5, and viscosity of 400 centipoise at 25 °C (Brookfield LVF). (Please read the note on the back and fill out this page) Install tr----- ----Φ. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 135 thermoplastic polyester based polyurethane aqueous emulsion, which has 62% solids, a pH of about 10, and a range of about 0.8 to about 2.5 Micron particle size. 136 ORPAC BORON NITRIDE RELEASECOAT_CONC 25 Boron nitride particles in aqueous dispersions, commercially available from ZYP Coatings, Inc., Oak Ridge, Tennessee

Composite sample of each of the above coated glass fiber samples and comparative sample Z -123- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 _B7___ V. Description of invention (121) at 270 °C was extruded at -7 MPa (975 psi) for 4 « seconds to make a plate of 254 X 254-X 3.175 mm (10 X 10 X 0.125 inch). The samples were evaluated for the glass content specified below: tensile strength, tensile elongation and tensile modulus in accordance with ASTM method D-638; flexural strength and energy modulus in accordance with ASTM method D-790; and in accordance with ASTM method D- 256 notched and unnotched Izod impact strength. Table 3B presents the results of tests conducted on a composite formed using a conventional nylon 6,6 matrix resin. (Please read the notes on the back and fill out this page) -Install-----r---Book----

S Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed -124-1283255 A7 _____B7 V. Description of Invention (122) Table 3B Sample Unit KLMN Comparison of Twin Samples z Tensile Strength kpsi 27.1 27.6 27.3 27.4 26.2 MPa 186.9 190.34 188.27 188.96 180.68 Tensile elongation % 3.32 3.37 3.36 3.42 3.32 Tensile modulus mpsi 1.48 1.55 1.47 1.44 1.51 GPa 10.2 10.7 10.1 9.9 10.4 Flexibility kpsi 44.6 46.3 45.7 45.5 44.0 MPa 307.6 319.3 315.2 313.8 303.4 Flexible modulus mpsi 1.52 1.56 1.54 1.54 1.5 GPa 10.5 10.7 10.6 10.6 10.6 Notched Ehrlich impact fllb/in 1.86 2.24 1.94 1.63 1.16 kJ/m2 7.89 9.50 8.23 6.91 4.92 Unnotched Ehrlich impact ftlb/in 21.8 22.9 21.1 20· 5 22.0 kJ/m2 92.43 97.10 89.46 86.92 93.28 _ Glass content% 32.9 32.6 32.4 32.3 32.4 丨, -----------------..--------I I---- (Please read the notes on the back and fill in this Page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing as shown in Table 3B, when comparing comparative samples with similar composition (which does not contain boron nitride in nylon 6,6 reinforcement) The glass fiber strand (sample KN) coated with boron nitride particles in accordance with the present invention exhibits improved tensile strength and notched impact properties, and similar tensile elongation and modulus, flexural strength and modulus, and no gap Ehrlich impact properties. No improvement in tensile strength and notched impact properties was observed using Nylon 6 resin under similar conditions. - -— —_ - 125 _ This paper size (CNS) A4 size (10) 297 297 public)) --- --- 1283255 A7 B7 V. Description of invention (l23) - Example 4 (Please read the notes on the back and fill in This page mixes the ingredients in the amounts described in Table 4A to form the aqueous forming sizing compositions P to S in accordance with the present invention. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition in an amount of less than 1% by weight based on the total weight. Each of the aqueous forming sizing compositions of Table 4A was applied to G-31 E-glass fiber strands. Each of the sizing compositions formed had a solids content of 10% by weight.

Table 4A Component Weight % Based on Total Solids Sample Composition Ρ QRS Thermoplastic Polyurethane Film Forming Polymer 137 23 28.75 28.75 23 Thermoplastic Polyurethane Film Forming Polymer 138 34.45 43.1 43.1 34.45 Polyoxyalkylene Polyol Copolymer 0.22 0.27 0.27 0.22 Epoxidized Polyester Lubricant 4.8 6.0 6.0 4.8 γ-Aminopropyl Triethoxy Acridine Coupler 1.84 2.3 2.3 1.84 γ-ureidopropyl Triethoxy Acridine Coupler 2.22 2.78 2.78 2.22 Amino-functional organodecane coupling agent 0.1 0.12 0.12 0.1 POLARTHERMPT 16Ό139 33.3 16.7 0 0 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative printed 137 thermoplastic polyester based polyurethane aqueous emulsion with 65 Solid %, anionic particle charge, particle size of about 2 microns, pH of 7.5, and viscosity at 25 X: 400 centipoise (Brookfield LVF). 138 thermoplastic polyester based polyurethane aqueous emulsion with 62% solids, about pH, and a range of about 0.8 to about 2.5 microns. - This paper scale applies to China National Standard (CNS) A4 size (210 X 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 B7 V. Inventions (124) 139 POLARTHERM® PT 160 boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio Company Table 4A (continued) Component Weight Based on Total Solids Sample Component PQRS VANTALC 2003140 0 0 16.7 33.3 Ignition Loss (%) 0.52 0.81 0.80 0.64 140 VANTALC 2003 Talc Particles, Commercially Available from Norwalk, Connecticut Vanderbilt Corporation 0 Composite samples of each of the coated glass fiber samples and comparative sample Z were extrusion molded under the conditions described in Example 3 above to produce 400 X 400 X 2.5 mm (16 X 16 X 0.100 inch) board. Each sample was evaluated for the glass content specified below: tensile strength, tensile elongation, tensile modulus, notched and unnotched Izod impact strength, as discussed in Example 3 above. A color test was carried out on a composite having a thickness of 3.175 mm (1/8 inch) and a diameter of 76.2 mm (3 inch) using a Hunter colorimeter D25-PC2A. To evaluate material handling characteristics, a funnel flow test was performed on samples of chopped glass fibers. The funnel is 18 inches long and has a 17 inch diameter opening at the top and a 2 inch opening at the bottom. Vibrate the funnel and record the time that 20 pounds of sample material flows through the funnel. The PD-104 test evaluated the resistance of chopped glass fiber-like Wu to fibrillation. 60 grams of sample, 140 grams of -127 - ^ paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). · tr--------- (Please read the note on the back first) Fill in this page) A7 1283255 ______B7 V. INSTRUCTIONS (125) Wear material (ground walnut bark granules 6 〇 ' '' commercially available from Hammon Products), and conventional bubble-type antistatic desiccant tablets It was enclosed in a 4 liter stainless steel beaker and shaken for 6 minutes using a Red Devil paint shaker 54 〇 OE3. The vibrating material was selected using a No. 5 and No. 6 U.S. standard test sieve. The following reports report the weight % of fine wool material collected on the screen as a percentage of the original sample. Table 4B presents the results of tests conducted on a composite formed using the sample P-S and the comparative sample z using a resin resistant to 6,6 matrix. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumer Cooperatives Printed 128- 1283255 A7 B7 V. Invention Description (l26) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed ~ Table 4B Sample Unit PQRS Comparison of twin samples z Tensile strength kpsi 29.5 28.6 28.7 27.7 29.6 Mpa 203.5 197.2 197.9 191.0 204.1 Tensile elongation % 3.03 3.05 2.98 2.97 3.01 Tensile modulus kpsi 1866 1779 1720 1741 1748 Gps 12.86 12.26 11.86 12.0 12.05 Notched Ehrlich impact ftlb/in 2.10 1.96 1.94 1.78 2.26 kJ/m2 8.90 8.31 8.23 7.55 9.58 Unnotched Ehrlich impact ftlb/in 24.9 23.4 22.8 22.2 26.4 kJ/m2 105.58 99.22 96.67 94.13 111.94 Actual ignition loss % 0.81 0.52 0.80 0.64 1.17 PD 104 % 1.3 0.7 0.1 1.4 0.1 Funnel flow seconds 13.8 15.2 15.4 23.5 13.0 Whitening index -15.1 -12.0 -17.6 -18.5 -18.2 Yellowing index 40.0 37.5 42.5 43.4 43.6 Glass content% 33.30 33 32.90 31.70 33.80 As shown in Table 4B, in comparison with similar components Comparative sample Z (which does not contain boron nitride in nylon 6,6 reinforcement) At the time, the glass fiber strands (sample PS) coated with boron nitride particles according to the present invention exhibit improved whitening and yellowing, and similar tensile strength, elongation and modulus, flexibility and modulus, and notches and no Notched Ehrlich impact properties. One - ** -129 - This paper size applies to Chinese National Standard CCNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) ▼Binding---- ^•1. 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 5, Invention Description (127) - Example 5 The components of the amounts described in Table 5 were mixed to form aqueous sizing compositions T and U in accordance with the present invention. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition in an amount of less than 1% by weight based on the total weight. Table 5 A presents whitening and yellowing on composites formed using nylon 6,6 matrix resin using samples T, U and comparative sample Z (as discussed in Table 3 A of Example 3 and repeated below) test results. Color testing was performed on a composite having a thickness of 3.175 mm (1/8 inch) and a diameter of 76.2 mm (3 inches) using a Hunter colorimeter D25-PC2A. Table 5 I ^----------------r---book--------- ^•1 (Please read the notes on the back and fill out this page) Component based on total solids % by sample Τ U Comparative sample 热塑性 Thermoplastic polyurethane film forming polymer 141 31.35 28.75 34.5 Thermoplastic polyurethane film forming polymer 142 46.9 43.1 51.7 Polyoxyalkylene Polyol Copolymer 0.3 0.27 0.3 Epoxidized Polyester Lubricant 6.55 6.0 7.22 γ-Aminopropyl Triethoxy Acridine Coupler 2.5 2.3 2.76 γ-Protonylpropyl Triethoxy Broken Coupler 3.0 2.78 3.34 Amino functional organodecane coupling agent 0.1 0.12 0.14 RELEASECOAT-CONC 25143 9.1 16.7 0 Whitening index -16.3 -15.0 -20.7 ~ "Yellowing index 39.3 38.1 42.7 -130- This paper scale applies to China National Standard (CNS) A4 specification &lt;;210 X 297 mm) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A? B7 V. Invention description (l28) 141 thermoplastic poly-ester-based polyurethane aqueous emulsion, which has 65% , anionic particle charge, particle size of about 2 microns, pH of 7.5, and 40 at 25 °C Viscosity of 0 centipoise (Brookfield LVF) 142 thermoplastic polyester based polyurethane aqueous emulsion 'having 62% solids, a pH of about 10, and a particle size ranging from about 0.8 to about 2.5 microns. ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles in aqueous dispersion available from ZYP Coatings, Inc. (Oak Ridge, Tennessee). As shown in Table 5, samples T and U, each coated in accordance with the present invention The nitride-containing particle-on-polymer composition has a whitening index lower than that of the comparative sample Z (which does not include boron nitride) in the case of 6,6. Example 6 Stacking five layers of ADELO-CTM needles A chopped fiberglass web commercially available from PPG Industries to form a web having a surface weight of 4,614 grams per square meter (approximately 15 ounces per square inch). Each sample has a thickness of 25 mm (approximately 1 inch) The four 8-inch square samples of the grid were heated to a temperature of 649 ° C (about 1200 ° F) to remove essentially all of the slurry components from the sample. Two uncoated samples were used as comparative samples ( &quot;Comparative sample"). Immerse the other 2 samples (&quot;Sample X") in a 1150 ml ORPAC BORON NITRIDE RELEASECOAT-CONC (25% by weight dispersion of boron nitride particles in water) and 150 ml of Α-187 γ-dewatered Aqueous coating composition of 5% by weight aqueous solution of glyceryl propyl trimethoxy decane in the bath • 131 · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------- -丨丨-------r III ^ 0 I I------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Description of invention (129) . The total solids of the water-based coating composition was 18.5% by weight. The amount of boron nitride particles coated on each of the net samples was 120 g. The coated web samples were dried in air at a temperature of 25 ° C. Overnight, and heated in an oven at 150 ° C for 3 hours. According to the ASTM method (M77, which is specifically incorporated herein by reference, the thermal conductivity and heat resistance of each group of samples at a temperature of 300 K (about 70 ° F) are evaluated. The thermal conductivity and heat resistance of each sample are described in Table 6 below. Table 6 Sample X Comparative Sample Thickness (忖) 1.09 1.0 (Male ) 2.77 2.54 Temperature (F) 75.62 74.14 CC) 24.23 23.41 Thermal conductivity per square mile T 之 Btu 吋 0.373 0.282 K watts per meter 0.054 0.041 Heat resistance per BTU hour 平方 2.92 3.66 Square watts per watt Meter K 0.515 0.626 Referring to Table 6, the test sample coated with boron nitride particles according to the present invention has a thermal conductivity at a temperature of 300 K greater than that of a comparative sample of uncoated boron nitride particles. -132- This paper scale applies China National Standard (CNS) A4 Specification (210 X 297 mm) — l·----------i — (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Office staff consumption Cooperative printing

1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 B7 V. Inventive Note (130) ~ Example 7 G-75 yarn coated with slurry G above Example 2 and 1062 glass fiber commercially available from PPG Industries A sample of the yarn is prepared to prepare a cylindrical composite of the wound filament. The cylinder is prepared by extracting 8 yarn ends from the yarn supply, coating the yarn with the matrix material described below, and winding the yarn into a cylindrical shape using a conventional filament winding device. Each cylinder is 12.7 cm (5 inches) high with an inner diameter of 14.6 cm (5.75 inch) and a wall thickness of 0.635 cm (0.25 inch). The matrix material was 1 part ΕΡΟΝ 800 resin (commercially available from Shell Chemical Company of Houston, Texas) and 80 parts of AC-220J methyl tetrahydro S too acid (commercially available from Anhydrides and Chemicals, Newark, Jersey). And 1 part of a mixture of ARALDITE® DY 062 dimethyl dimethylamine accelerator (commercially available from Ciba-Geigy). Filament winding The cylinder was hardened at 100 °C for 2 hours and then at 150 °C for 3 hours. The radial direction of each test sample in air was determined by exposing one side of the sample cylinder wall to a 6.4 Torr Joule flash and using a CCD array infrared camera to detect temperature changes on the opposite side at a rate of 2000 sheets per second. Thermal diffusivity (thermal conductivity / (heat capacity X density)). The thermal diffusivity 値 is also measured along the length of the yarn (circumference) and along the length or height (axial direction) of the cylinder. The test results are described in Table 7 below. -133- This paper size applies to China National Standard (CNS) A4 specification &lt;210 X 297 mm)

If —----IIII · I---r III ^ ·1111111» (Please read the note on the back and fill out this page) 1283255 A7 B7 V. Description of invention (131) Table 7 Heat g Dispersion (square Mm/sec) Radial axial surrounding sample 0.37 0.33 0.49 Comparative sample 0.38 0.38 0.57 Referring to Table 7, the thermal diffusivity of the test sample (which is coated with a small amount of boron nitride) is less than that of uncoated boron nitride. Sex sample. The cavity of the filament winding cylinder and the area of the small test sample are factors that affect these results. Example 8 Laminates of Type 7628 fabrics prepared from 8 samples of Bvac coated yarn (discussed in Example i) and (9) Starch-oil coated yarn (discussed in Example 1) (control) Sample, evaluate the thermal expansion coefficient of the laminate &amp; direction (ie, the thickness of the laminate) ("Z-CTE,"). Example of use </ br> FR-4 epoxy resin to prepare the laminate, and according to the neck ρ A ",, test 2.4.41" is specifically incorporated herein by reference, W. The 哉 膨胀 expansion coefficient of each laminate sample in the 288 V, l &lt; z- direction was evaluated in accordance with IPC Test Method 2.4.41. The results of the evaluation are shown in Table 8 below. ... I -----^----^--------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed -134- 1283255 A7 B7 V. Description of invention (m sample sample 3Βλ sample Bm1 (retry) sample sample Bvac2 (retry) sample sample Bvac3 (retry) comparison table 8 Z-CTE (%) 4.10 4.41 4.06 4.28 4.17 4.26 5.0 (Read first Note on the back side of this page) 5.4 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed Control 2 As shown in Table 8, for the laminate Al-A3 according to the present invention, the z-direction thermal expansion coefficient of the layer is less than Control samples 1 and 2 prepared from 695 starch-oil coated yarns. Example 9 The ingredients in the amounts described in Table 9A were mixed to form aqueous first sizing compositions AA, BB and CC according to the present invention. The aqueous first sizing composition is prepared in a manner similar to that discussed above. Each of the compositions comprises less than 1 weight percent per gram of acetic acid based on the total weight. Each aqueous sizing composition of Table 9A is applied to G- 75 E-glass fiber strands. Dry the coated fiber strands and use similar knowledge to match The method is interwoven to form a yarn, and is wound on a bobbin. The yarn coated with the sizing composition exhibits a minimum of slurry shedding during interlacing. -135- The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 public Chu) 1283255 A7 B7 V. Description of invention (U3) Table 9A Based on total solids Weight % Sample composition AA BB CC PVP K-30144 14.7 14.7 13.4 STEPANTEX 653145 30.0 29.9 27.3 A-187146 1.8 1.8 1.6 A-174147 3.7 3,7 3.3 EMERY 6717148 2.4 2.4 2.2 MACOL ΟΡ-ΙΟ149 1.6 1.6 1.5 TMAZ-81150 3.3 3.3 3.0 MAZUDF-136151 0.2 0.2 0.2 ROPAQUE HP-1055152 0 42.4 0 ROPAQUE OP-96153 42.3 0 38.6 REKEASECIAT-CONC 25154 0 0 6.3 POLARTHERMPT 160155 0 0 2.6 ------------装-----Γ---订--------- (Please read the notes on the back and fill out this page) Economy 144 PVP K-30 Polyethylpyrrolidone, commercially available from ISP Chemicals, Inc., Wayne, New Jersey, 0 145 STEPANTEX, which is commercially available from Maywood, New Jersey. Stepan company. 140 Α-187 γ-Glycidylpropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 147 Α-174 γ-Methylpropoxypropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. -136- This paper size applies to China National Standard (CNS) A4 specification (210 297 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 B7 V. Inventions (134) 148 EMERY® Magic 17 Part of Indoleamine Ethylene diimide, commercially available from Cognis, Cincinnati, Ohio. 149 MACOL OP-10 ethoxylated alkanol; this material is similar to MACOL OP-10 SP except that MACOL OP-10 SP is post-treated to remove catalyst; MACOL OP-10 is no longer commercially available. 15G TMAZ-81 a cyclohexane ester of phytosterol ester commercially available from BASF Corporation of Parsippany, New Jersey. 151 MAZU DF-136 antifoam, commercially available from BASF, Parsippany, New Jersey. 152ROPAQUE® HP-1055, a 1.0 micron particle dispersion commercially available from Rohm and Haas, Philadelphia, PA. 153 ROPAQUE® OP-96, a 0.55 micron particle dispersion commercially available from Rohm and Haas, Pa., USA 0 154 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride dispersion commercially available from ZYP, Oak Ridge, Tennessee Coatings company. 155 POLARTHERMTM PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. When the 7628 type fabric was woven using a Sulzer Ruti 5200 air jet loom, the yarn sizing with each sizing composition (AA, BB, and CC) was used as a yarn. The interwoven G-75 E-glass fiber strands 156 were coated with different resin compatible sizing compositions for the fibers. The fabric was then pre-impregnated with FR-4 epoxy resin (No. 4000-2 resin of Nelco International, Anaheim, Calif.) having a Tx of 140 X:. The sizing composition was not removed from the fabric prior to prepreg. By stacking 8 layers of prepreg between 2 layers of 1 ounce of copper, and -137- this paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm)~- ------- ----装-----r---book--------- (please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 - ------B7____ V. INSTRUCTIONS (135) At a temperature of 355 °F (about 179 °C), 300 lbs per square inch (about 1-2 million Pascals), The laminate was prepared by laminating together for 159 minutes (total cycle time). The thickness of the laminate without copper ranges from 0.043 inches (about 11 cm) to 0.050 inches (about 0.13 cm). After the formation, the test laminates (referred to as fiber strands in accordance with the manufacture thereof) are referred to as ruthenium, osmium and CC as shown in Table 9 below. At the time of the test, when the first laminate made of the glass fiber yarn was coated with the sizing composition sample ΑΑ (hereinafter referred to as the laminate sample ΑΑ 1 ), the laminate ΒΒ was simultaneously tested. Later, when the sizing composition sample CC (hereinafter referred to as the laminate sample ΑΑ2) was applied to the second laminate made of the glass fiber yarn, the laminate CC was simultaneously tested. Table 9 属 卜 样品 sample test unit AA1 * ΒΒ * ΑΑ 2** CC** average thickness 吋 0.048 0.048 0.053-0.055 0.053-0.055 Tan Xi floating seconds 409 386 235 253 solder dipping seconds 320 203 243 242 scratch Strength Strength warp direction 157 kpsi 99 102 91 90 Flexibility weft direction 158 kpsi 86 81 73 72 *Based on 2 samples. ** Based on 3 samples. 150 This warp yarn is a commercially available fiberglass yarn product of PPG Industries, &apos; code G-75 fiberglass yarn, which is coated with a PPG Industries adhesive. 157 Per IPC-TM-650 ^Flexural Strength of Laminates (At Ambient -138 - This paper size applies to Chinese National Standard (CNS) A4 size (210 x 297 mm) L----------• -----r---订--------- (Please read the notes on the back and fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7_ V. Invention description ( 136) • Temperature^·, 12/94, Revised B. m Same chapter. Float by 4 inch by 4 inch square (1〇·16 cm by ι〇16 cm) copper cladding laminate Solder float test in a 550 T (about 288 ° C) eutectic lead-tin solder bath until the blistering or separation is observed. Then record the number of seconds until the first blistering or separation. Cutting the sample of the laminate, removing copper from the sample by etching, smoothing the cut edge of the sample ρα, and placing the sample under 25 〇 (about 121 ° C) and 15 pounds per square inch (about 0.1 100) In the pressure cooker of Wanbasa), the soldering test was carried out for 6 minutes. This test is the pressure cooker test referred to in the following table. After 60 minutes of exposure, the pressure cooker In addition to the sample, pat dry and immersed in a fused lead-tin solder bath at 55 °F (about 288 °C) until foaming or separation was observed. Then record the number of seconds until the first foaming or separation. Flexibility tests were carried out in accordance with the IPC standards shown. Laminates AA, BB and CC made using fiber strands on each of the above pulp compositions AA, BB and CC have acceptable properties as electronic supports for printed circuit boards ( As shown in Table 9B. The following tests were also carried out on samples AA, BB and CC, and are described in Table 9C -, -139- This paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) l ·-------—装-----^----订--------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 Ministry of Economics Intellectual Property Bureau employee consumption cooperative printing 5, invention description (137)

~ Table 9C Sample test unit AA BB CC Tg by DSC 0/30/60 min V 141/140/139 140/141/141 138/140/139 Repeater water absorption % 0.37 0.37 0.38 Water resistance 159 Weight increase % 0.12 0.09 0.09 DMF resistance weight increase % 0.35 0.27 0.29 MeC12 Antibiotic 16 () Weight increase % 0.77 0.82 0.68 Copper stripping strength 161 (warp / fill) Number of turns 11.8/11.0 12.1/11.1 11.2/11.4 Interlayer bond strength 162 per inch Fragment 12.8 14.2 15.4 159 In accordance with IPC-TM-650, No. 2.6.2.1, &quot;Water Absorption, Metal Clad Plastic Laminates", 5/86, Amendment A Edition 0 160 in accordance with IPC-TM-650, No. 2.3. 4.3. &quot;Chemical Resistance of Core Materials to Methylene Chloride&quot;, 5/86.

161 In accordance with IPC-TM-650, No. 2.4.8, &quot;Peel Strength: As Received, After Thermal Stress, After Process Chemicals&quot;, 1/86, Amendment B version 0 162 according to IPC_TM_650, No. 2.4.40, &quot Inner Layer Bond Strength of Multilayer Printed Circuit Boards&quot;, 10/87 Example 10 The ingredients of the amounts described in Table 10 were mixed to form aqueous sizing compositions DD, EE and FF in accordance with the present invention. Acetic acid in an amount of 0.5% by weight based on the total weight is included in each composition. -140 - This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) I.----------•装-----r---订---- -- Hey! i (Please read the note on the back and fill out this page) 1283255 A7 _ B7 V. INSTRUCTIONS (138) A table 10 Based on total solids Weight % Sample composition DD EE FF PVP K-30163 12.3 11.7 12.3 STEPANTEX 653164 25.0 23.9 25.0 TMAZ 81165 3.5 3.9 2.7 MACOL OP-10166 1.8 2.0 1.4 POLARTHERMPT 160167 2.4 2.3 2.4 EMERY 6717168 2.0 2.0 2.0 A-174169 3.1 2.9 3.1 A-187170 1.5 1.4 1.5 RELEASECOAT-CONC 25171 5.7 5.5 5.6 MAZUDF-136172 0.2 0.2 0.2 ROPAQUE OP-96173 35.2 33.7 35.3 FLEXOL LOE174 7.3 10.5 0 FLEXOLEPO175 0 0 7.3 I.----------Install-----r---订---------^9 ( Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 163PVP K-30 Polyethylidene Pyrrolidone, commercially available from ISP Chemicals, Inc., Wayne, New Jersey 0 164 STEPANTEX 653 The business was obtained from Stepan Corporation of Chicago, Illinois. An oxirane derivative of 165 TMAZ 81 sterol ester commercially available from BASF Corporation of Parsippany, New Jersey.

166MACOL OP-10 ethoxylated alkanol; this material is similar to MACOL OIMO-141 - Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 __B7___ V. Invention description (139) SP, except for "MACOL OP-10 SP accept post-processing Catalyst removal; MACOL ΟΡ-ΙΟ is no longer commercially available. 167POLARTHERM® PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. 168EMERY® 6717 partially amided poly(ethyleneimine), Commercially available from Cognis, Cincinnati, Ohio. 1ό9Α-174 γ-Methoxypropoxypropyltrimethoxydecane, commercially available from New Zealand: CK Witco, Tarrytown, Jo. 17GA-187 γ-dehydrated glycerol Propyl trimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 171 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, Commercially available from ZYP Coatings, Oak Ridge, Tennessee. 172MAZU DF-136 P foam, commercially available from BASF, Parsippany, New Jersey. 173ROPAQUE® OP- 96, a 0.55 micron particle dispersion commercially available from Rohm and Haas, Pennsylvania, 0 174 FLEXOL LOE epoxidized linseed oil commercially available from Union Carbide, Inc. of Danbury, Connecticut, as a mFLEXOL EPO epoxidized soybean oil. Commercially available from Union Carbide, Inc., Danbury, Connecticut ° -142- This paper size applies to the Chinese National Standard &lt;CNS) A4 Specification (210 X 297 mm) L---------- Pack-- ---r---订--------- (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Description of invention (140) Table 10 (continued) Based on total solids Weight % sample composition

DD

EE

FF solid weight% 3.4 3.5 3.4

LOI 0.42 0.39 0.30 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed using the water-based sizing composition of Table 10 to coat glass fibers to form G-75 E-glass fiber strands. Dry the coated glass fiber strands, use Conventional interlacing devices are interwoven in a similar manner to form a yarn, and wound onto a spool. The yarn of the sample DD was evaluated by comparing the coated yarn with a yarn coated with a slurry similar to the sample DD but without the epoxidized linseed oil composition (hereinafter, comparative sample 丨 &quot;). This comparison includes the visual inspection of the appearance of the 7628 type fabric of the air jet looms. The woven fabric used sample dd as a yarn&apos; fiber as a warp yarn with interwoven G-75 E-glass fiber strands 176 coated with different resin compatible sizing compositions. When comparing the fabrics coated with the comparative sample 1 yarn, it was observed that the fabric woven with the yarn coated with the sample DD exhibited less slack fine hair on the fabric, and less contact points were collected on the loom. Fine hair, especially in the accumulator. Because of the high initial amount of fine hair observed on the loom, the no-woven fabric was spun using a yarn that was coated with the fibers of the coated sample EE or FF. This situation is believed to be the result of a lower LOI than is required to prevent excessive hair formation. In the present invention, it is contemplated that the above slurry composition will require an LOI of at least 0.40 to reduce fines formation during weaving. 176 This warp yarn is a commercial fiberglass yarn produced by PPG Industries, a product, code G-75 fiberglass yarn, which is coated with PPG Indimries 1·--------1· ----··---Book--------- (Please read the notes on the back and fill out this page) • 143 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 ---- ------ Β7 ____ V. Invention Description (141) 1383 Adhesive. Example 11 Evaluation of samples ΑΑ, ΒΒ and CC and comparative sample 2! 77 (coating of starch/oil-slurry yarn) many physical properties such as ignition loss (L〇i), air jet compatibility (air resistance) ) and friction. The results are shown in Table U. The ignition loss of each sample (% by weight of the solids forming the sizing composition divided by the total weight of the sizing composition formed by breaking the glass and drying) is described in Table u. Feeded at 274 m (300 yards) per minute by a checked line tensiometer (which applies tension to the yarn) and a 2 mm diameter air nozzle of 138 kpa (20 psi per square inch) air force Ruti The yarn is fed at a rate to assess the air resistance or tension of the yarn. It is also 274 meters per minute by a pair of conventional tension measuring devices (which have a diameter of about 5 cm installed between them instead of 5 cm from the linear path between the tension measuring devices). The sample was pulled at a rate, and a tension of 20 g was applied to each of the yarn samples to evaluate the frictional force of the sample and the comparative sample 2. The difference in gram strength is described in the following table. The friction test is intended to simulate the friction force that the yarn receives during the weaving operation. At the time of the test, when the first glass fiber yarn was coated with the sizing composition sample AA (hereinafter referred to as sample AA3), the sample BB and the comparative sample 2 were simultaneously tested, and the second portion of the glass fiber yarn was coated. When the sizing composition sample AA (hereinafter referred to as sample AA4), the sample cc was simultaneously tested. Sample 177 This warp yarn is commercially available fiberglass yarn from PPG Industries, code G-75 fiberglass yarn, which is coated with ρρ〇in (justries 695 starch/oil adhesive-L agent. ------ ------Install ------r---book--------- (please read the notes on the back and fill out this page) -144- 1283255 .A7 ---- -§z__- V. Inventive Note (142) AA3, AA4~ and BB are 2.8 wt% solids. Sample CC is 3.1 wt% solids. Comparative sample 2 is 5.9 wt% solids. Table 11 Samples AA3 BB 2 AA4 CC LOI (% by weight) 0.42 0.49 1.11 0.38 0.37 Air resistance (grams) 56.2 51.2 52.9 58.8 53.2 Friction (grams) 53.6 61.5 95.1 48.8 68.9 As seen in Table 11, sizing samples ΑΑ, ΒΒ and CC has air resistance comparable to that of Comparative Sample 2 (starch/oil binder). In addition, when comparing Comparative Sample 2, the lower frictional force of the samples ΑΑ, ΒΒ and CC indicates that the yarn is easier to self-woven during weaving. The loom accumulator was removed. Example 12 The air resistance of the samples ΑΑ, ΒΒ and CC and Comparative Sample 2 was evaluated in a manner similar to Example 11 above, except The air resistance of the spool samples as shown in Table 12. The Shirley 84 041L rupture filament detector, also commercially available from SDL International, UK, evaluates each 1200 m of each yarn at 200 m per minute. The average number of broken filaments of the yarn (shown as Test 1 in Table 12). The broken filaments were removed from the bobbin after removing 227 g (0.5 lb) of yarn from the bobbin and after removing 4540 g (10 lb) of yarn from the bobbin. The spool, a partial report from all spools. Further evaluate the number of broken filaments for each yarn when increasing tension and wear (shown as Test 2 in Table 12). In Test 2, 2 (〇咮) /min from the spool to unwind the yarn, in the uniform tension control device -145- This paper scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note before filling this page) -----r---订--I-- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 --------- V. Invention description (143) ^ ^ &quot; (sometimes Known as the 岵 tension device), it is serpentine shaped through a series of 8 卩 卩 釺 釺, and by Shirley Filaments crack detector to calculate the number of broken filaments | I. using different dial settings to change the tension on the spacing of the needle means to # _ of different yarn tension degrees. This particular test was conducted using a UTC-2003 tensioning device commercially available from South Carolina 丨^ Steel Heddle. The ruptured filaments are reported as the number of ruptured filaments per meter of yarn. The test results of samples AA, BB and CC and Comparative Sample 2 are summarized in Table 12 below. In a method similar to that discussed in Example 11 above, when the first portion of the glass fiber yarn was coated with the sizing composition sample AA (hereinafter referred to as sample AA5), the sample BB and the comparative sample 2 were simultaneously tested, and later, at When the second glass fiber yarn was coated with the sizing composition sample AA (hereinafter referred to as sample AA6), the sample CC was simultaneously tested. ------------·1-----r---tr--------- Γ 先 先 3 3 3 3 3 3 3 3 3 在 在 在 在 经济 经济 经济 经济 经济 经济 经济 经济 经济Ministry of Intellectual Property Bureau employee consumption cooperative printing -146- This paper scale applies China National Standard (CNS) A4 specification (210 X 297 mm) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1283255 A7 B7 V. Invention description (144 &quot; Table 12 Sample ΑΑ5 ΒΒ 2 ΑΑ6 CC Air resistance (grams) 15 psi 46.10 42.50 42.23 47.47 42.33 20 psi 56.20 51.20 52.94 58.84 53.18 25 psi 67.33 60.30 64.13 69.45 67.66 30 psi 77.34 70.84 75.74 75.29 77.63 35 psi 89.42 89.96 85.96 83.70 82.74 40 psi 104.97 101.21 98.48 87.23 92.18 45 psi 113.41 107.74 110.34 99.91 102.91 Test 1 All spools 0.170 0.882 0.032 1.735 0.066 227 grams (0.5 lbs) 0.160 0.648 0.041 0.904 0.075 4540 grams (10 lbs) 0.098 1.348 0.008 0.518 0.022 Test 2 Settings 2 0.683 5.017 0.119 0.372 0.011 Setting 3 0.753 4.772 0.083 0.450 0.017 Setting 4 0.713 3.753 0.147 0.367 0.017 Setting 5 1.267 4.025 0.150 0.811 0.061 Setting 6 1. 608 8.383 0.322 0.286 0.044 Setting 7 4.128 6.517 0.611 0.403 0.058 Setting 8. 4.472 14.800 0.978 0.406 0.128 -147- (Please read the note on the back and fill out this page) This paper size applies to the Chinese National Standard &lt;CNS) A4 specification ( 210 X 297 mm) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 Β7__ V. Invention Description (145) From Table 12, the sizing samples AA, BB and CC have comparable sample 2 (starch) / oil binder) compared to the air resistance. Example 13 An electronic grade laminate made from prepreg yarns added to a fabric having yarns of different sizing compositions was tested to evaluate its hole drilling properties, and more particularly (i) to be drilled through the laminate. The drill bit wear of the hole drill, and (ii) the correct position of the hole drilled through the laminate. Control GG and sample HH were laminates of the previously discussed 7628 fabric. The fabric in the control GG was a heat-removed and decane-trimmed fabric commercially available from Clark Schwebel, 7628-718. The fabric in sample HH was woven from yarn comprising glass fibers coated with a resin compatible slurry as shown herein and shown in Table 13A. It is believed that this fabric also includes sample HH as a warp yarn. However, the warp yarn may be a 1383 commercially available fiberglass yarn product from PPG Industries. The glass fibers woven into the sample HH had an ignition loss of 0.35%.

Table 13A Based on the total solid weight of the slurry above the sample HH, component weight % component sample HH RD-847A178 27.0 DESMOPHEN 2000179 36.2 PVP K-30180 9.0 A-187181 2.1 A-174182 4.4 mRD-847A polyester resin, its commercial Borden Chemicals from Columbus, Ohio ^ ^ ° -148- This paper scale applies to the Chinese National Standard (CNS) A4 specification &lt;210 X 297 mm) -----------Install---- -r---订--------1 (Please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 _ B7 __ V. Invention description (146) 179 desmophTen 2000 poly(ethylene adipate), commercially available from Bayer Corporation of Pittsburgh, Pa. Isopyp K-3 〇 polyvinylpyrrolidone, commercially available from ISP Chemicals, Wayne, New Jersey. mA-187 γ-dehydroglycerylpropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 182Α-174 γ-Methoxypropoxypropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, Johor. 0 Table 13A (continued) Ingredient sample HH PLURONIC F-108183 9.0 VERS AMID 140184 4.4 MACOL NP -6185 5.4 POLARTHERM PT 160186 0.9 RELEASECOAT-CONC 25187 1.5 Acetic acid &lt;0.1 183 PLURONICTM F-108 poly(propylene oxide)-polyethylene oxide copolymer commercially available from BASF Corporation of Parsippany, New Jersey. 184 VERS AMID 140 Polyamide, commercially available from Cognis Corporation of Cincinnati, Ohio as a 0 185 MACOL NP-6 indophenol surfactant commercially available from BASF Corporation of Parsippany, New Jersey. 186 POLARTHERM PT 160 boron nitride powder granules commercially available from Advanced Ceramics, Inc., Lakewood, Ohio. -149- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -----------Install-----r---订------ ---^一^ (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 B7 V. Invention Description (Η7) 187ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron Nitride Dispersion The liquid, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Inc. of Oak Ridge, Tennessee. The pre-invasive yarn was prepared by a hand-folding procedure, and the standard FR-4 epoxy resin (EPON 1120_A80 resin, available from Shell Chemical Co., Ltd.) was applied to the fabric by brushing. The resin-saturated fabric was immediately "dried" and stage B in a hot air oven at 163 ° C (about 325 ° F) until the desired gel time of 171 ° C (about 340 ° F) was 124 seconds. until. The pre-invasive yarn was modified to a 46 cm X 46 cm (18 inch X 18 inch) portion and weighed to determine the resin content. Only pre-invasive yarns with a resin content of 44 ± 2% can be used for subsequent lamination procedures. The pre-invasive yarns were piled up to 8 layers high and molded in Wabash pressure at 177 °C (350 T) and 345 Newtons/cm 2 (500 psi). All laminates were molded without a copper foil layer. The laminate shows a variety of air captures. It is believed that this condition is beneficial in the absence of short-selling and temperature changes during the accumulation period. Tool Wear Analysis The first series of tests were performed to evaluate the wear of the drill bit. Drill wear is calculated using the following formula: "Drill wear percentage": Drill wear percentage = 100 X (Pi-PfVh where Pi = initial width of the first cutting edge)

Pf = width of the first cutting edge after drilling the dispensing aperture. Referring to Figure 11, the width 1170 of the first cutting edge 1172 of the drill 1174 is measured at the peripheral edge of the drill bit. Use a single, - drill machine for drilling copper. The drill hole is available in the 0.203 mm-150 - paper scale for the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -----------Package--------Set- -------- (Please read the notes on the back and fill out this page) 1283255

V. Description of invention (148) Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Consumer Cooperatives (〇·〇〇8 inches), thick entrance and i.88 mm (〇〇74 inches) thick paper core The high stacking of the three laminates (discussed above) was carried out. The bit wear % of the two drill diameters was measured: 〇·35 亳m (〇〇138 inches) and 〇·46 mm (0.018 inches). Both drill bits are from the 508 series tungsten carbide drill bits from Qardeniat Tulon, California. The plate load during drilling is fixed to 〇 001 for each tool. • Plate Load &quot; used here means the ratio of the bit insertion rate per minute to the spindle speed measured in revolutions per minute (rpm). For the 〇·35 mm drill bit, the mandrel speed is 100,000 i: pm and the insertion rate is 100 inches (254 cm) per minute. For a 0.46 钻头 drill bit, the mandrel speed is 80 000 and the insertion rate is 80 inches (203 cm) per minute. The diameter of each tool is fixed at a contraction rate of 2.54 meters (100 inches) per minute and a drill limit of 1 65 mm (0.065 inches). As used herein, "bit limit" means the distance at which the head is drawn back on the upper surface of the laminate. The bit wear % was determined based on the 500-hole drill hole pattern shown in Figure 12, which included 391 holes in the hole of 0.635 cm by 10.16 cm (0.25 inch by 4 inches) (part 1280), followed by 100 holes. A hole in a 10 by 10 hole pattern (part 1282), followed by 9 holes in a 3 by 3 hole pattern (part 1284). The holes in each section were drilled at a hole density of 62 holes per square centimeter (400 holes per square inch). The pattern was repeated three more times for a total of 2000 holes. The drilling holes of tests 1 and 2 were completed using a Uniline 2000 single-head drilling machine, and the drilling holes of the test 3 were completed using a CNC-7 single-head drilling machine. Both machines are available from Esterline Technologies of Beiievu, Washington.一--151- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------Install-----r---book--- ------ (Please read the note on the back and fill in this page) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 5, Invention Description (149) Table 13B shows 0.35 and 0.46 mm diameter The drill bit wears % of the drill after drilling 2000 holes of the control GG and the sample HH in the pattern discussed above. Each test started with a new drill cone.

Table 13B Control GG Sample HH Test 1 Number of Tools 3 3 0.35 mm Diameter Bit Average Bit Wear % 28.8 22.2 Test 2 Number of Tools 20 20 0.46 mm Diameter Bit Average Bit Wear % 34.0 24.4 Test 3 Number of Tools 10 10 0.46 mm Diameter Bit Average Bit Abrasion °/〇30.8 29.3 As seen in Table 13B, samples HH of Tests 1 and 2 (which include glass fiber filaments coated with a slurry that is compatible with the matrix resin of the laminate) are in 2000 holes. It then appears to be much smaller than the control GG (which includes the glass fiber filaments that must be thermally removed prior to coating the decane-containing slurry). Run 3 shows only a slight improvement in bit wear, but it is believed to be due to the older CNC-based rig used in this test and the Uniline 2000 for the drill test compared to Tests 1 and 2. The fact that the drilling machine is less controlled. Positional Correctness A common matrix used to assess the performance of a hole in a laminate is hole position correctness. This test measures the deviation of the actual hole position from its intended position. This measurement is taken from the underlying surface of the laminate under the three laminate stacks, and the drill bit is separated from the one-by-layer stack, since the hole is expected to be located from the intent or "眞正" hole - 152- The paper scale applies to the Chinese National Standard (CNS) A4 specification (2i0 X 297 mm) -----------Install-----r---订--------- ( Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 _— _B7 ______ V. Invention Description (15〇) The position has the most k difference. This difference is evaluated by the deviation distance, that is, the distance from the actual center of the hole on the surface of the laminate to the intended center of the hole. The offset distance is repeated 4 times in the 500 hole sequence discussed above. After the measurement, that is, after each tool has drilled a total of 2000 holes, the offset distance of the last drilled 1 hole pattern is measured, that is, the final drilled portion 582. The above discussion type is obtained from Tulon Corporation. 46 mm (0.018 inch) diameter 508 series bore. As used in the tool wear test, the spindle speed of the o.ooi is 80,000 rpm and the insertion rate is 80 inches per minute. For each control GG and sample HH, the test was repeated 8 times, and each test was started with a new drill bit. Table 13C shows the results of the positional accuracy test of the control Gg and the sample HH after 2000 holes were drilled.

Table 13C Control GG sample HH Drilling holes 8 8 Average deviation distance (μm) 38 28 As can be seen, sample HH exhibits a lower error distance than control GG, which uses laminates as electrons for adding a large number of holes and circuits It is especially important when supporting the body. This is consistent with the bit wear % data shown in Table 13B above. More specifically, it is expected that the laminate exhibiting a lower bit wear % also exhibits a smaller offset distance because the hoe is sharper after a large number of holes are drilled. Example 14 In Example 14, an additional drill wear percentage test was performed. Test electronic grade laminate control jj and sample of %28 type fabric added as before ______ - 153- Private paper scale applicable to China National Standard (CNS) A4 specification (2W x 297 public meal 1 ------ -----------·装----l·—订---------^9. (Please read the notes on the back and fill out this page) 1283255 A7 B7 V , invention description (151) AA, BB KK drilling tool wear %. The fabric in the control JJ is 7628_718 fabric obtained from Clark-Schwebel Company. The fabrics in samples AA, BB and KK are composed of each coating example 9 Table 9A and the filler of the glass fiber of the resin compatible upper slurry shown in Table 14 below, and the warp yarn of the glass fiber coated with the different polymeric matrix material compatible coating composition m. 188 This warp yarn is PPG Industries' commercially available fiberglass yarn product, code G-75 fiberglass yarn, coated with PPG Industries adhesive. i^in an ii 11 I mmmam n · I —ϋ I ^^1 I ί I · ϋ I i^i ir n ·1 ϋ I (Please read the note on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed -154- The paper size is suitable China National Standard (CNS) A4 size (210 X 297 mm) 1283255 Α7Β7 V. Description of the Invention &lt; 152)

Table 14A For the sample above KK, based on the total solids, the component weight % based on the total solids component weight % sample composition KK PVP Κ -30189 13.4 Α-187190 1.9 Α-174191 3.8 EMERY 6717192 1.9 SAG 10193 0.2 RELEASECOAT-CONC 25194 3.8 POLARTHERM PT 160195 5.9 RD-847A196 23.0 DESMOPHEN 2000197 31.0 PLURONIC F-108198 8.4 ALKAMULS EL-7191&quot; 2.5 ICONOL NP-6200 4.2 LOI (%) 0.35 (Please read the note on the back and fill out this page) The Property Bureau Staff Consumer Cooperative printed 189 PVP K-30 polyethylidene pyrrolidone commercially available from ISP Chemicals, Wayne, New Jersey. 19GA-187 γ-Glycidylpropyltrimethoxydecane, commercially available from CIC Witco, Tanyjown, New York. 191Α·174 γ-Methoxypropoxypropyltrimethoxydecane, commercially available from -155- This paper scale applies to China National Standard (CNS) A4 specification (210x 297 mm). Co-operative printing 1283255 A7 _B7_-_ V. Invention description (153) New: CK Witco of Tarrytowii, Johor. 192EMERY® 6717 partially amided poly(ethyleneimine) commercially available from Cognis, Cincinnati, Ohio. 193SAG 10 anti-foam material, commercially available from CK Witco, Greenwich, Connecticut. 194ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, a dispersion of about 25% by weight of boron nitride particles in water, commercially available from ZYP Coatings, Oak Ridge, Tennessee. 195POLARTHERM® PT 160 boron nitride powder particles commercially available from Advanced Ceramics, Lakewood, Ohio. 196RD-847A polyester resin commercially available from Borden Chemicals, Columbus, Ohio. 197DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer Corporation of Pittsburgh, Pennsylvania. 198PLURONICTM F-108 polyoxypropylene-polyoxyethylene copolymer commercially available from BASF Corporation of Parsippany, Jersey, 0 199 ALKAMULS EL-719 polyoxyethyleneated vegetable oil, commercially available from Rhone-Poulenc Corporation 0 200 ICONOL NP -6 alkoxylated phenol, commercially available from BASF Corporation of Parsippany, New Jersey. The fabric was then pre-impregnated with FR-4 epoxy resin (codename 4000-2 resin from Nelco International, Anaheim, CA) having a Tg of 140 °C. The sizing composition was not removed from the fabric prior to pre-impregnation. By stacking 8 layers of prepreg material and 4 layers of 1 ounce of copper (as shown below), and at _ 156-_ this paper scale applies _ national standard &lt;CNS) A4 size &lt;210 X 297 mm) -----------Install-----r---订--------- (Please read the notes on the back and fill in this page) 1283255 Ministry of Economic Affairs Intellectual Property Bureau Employees' consumption cooperatives printed A7 V. Invention description (154) 355 τ (about 179. The temperature of 〇., the pressure per square inch of crushed (about 10,000 million baht), layered it for 150 minutes ( The total cycle time) was prepared to form a laminate. The thickness of the laminate and copper ranged from 0.052 ounces (about 0.132 cm) to 0.065 lbs. \, \ (, 々 0.165 cm). For the first time, 8 prepregs are stacked in the following arrangement: 1 ounce/square inch polished copper layer three prepreg layers 1 ounce/square inch RTF (prepared treated foil) copper layer Two prepreg layers One ounce/square mile RTF copper layer Three prepreg layers One ounce/square inch polished copper layer Finished laminate trimmed to 40.6 cm by 50.8 cm (16 inches) 20 inches). Use Uniline 2000 single-head drilling machine. The drilling hole is made of 〇〇1〇 inch (0.254mm) thick aluminum inlet and oi inch (2 54mm) thick aluminum facing particle board liner. The high stacking of the laminates (discussed above) was carried out. The 80 series tungsten carbide drills from Tulon, Inc., of Gardenia, California, were measured for 钻头34 耄m (0.0135 ft) tool diameter drill wear %. The plate load is fixed at 0.001, the mandrel speed is 95,000 rpm and the insertion rate is 95 inches per minute (241 cm). The bit shrinkage rate is 90 inches per minute (2. 29 meters) and the upper drill limit is 0.059 inches.吋 (1.5 mm) The bit wear is measured based on the 1500 and 2500 hole drilling pattern. The hole in each part is 2S holes per square centimeter (173⁄4 holes per square inch) -157- This paper size Applicable to China National Standard &lt;CNS) A4 Specification (210 X 297 public « ) -----------^ ------— (Please read the notes on the back and fill in this page) 1283255 A7

V. INSTRUCTIONS (155) Density drilling holes. &gt; Table 14B shows no control JJ and samples AA, BB and KK are drilling 1500 and 2500 holes (after the head wear %. Each group test starts with a new iron cone, and each layer a material stack has ten 15GG hole groups) And ten groups of 2 passes. The fabric pattern <two laminates were stacked to drill holes, so that the scale wear of 30 drill bits was measured for each sample. The bit wear % in Table 1 Sample BB 19,5 24,3 As seen in Table 14B, samples AA, BB, and KK (which include glass fiber fibrils coated with a slurry that is compatible with the laminate matrix resin) exhibited a much deeper than the control Jjr after 1500 holes ( It includes a small bit wear % that must be thermally removed before coating the tarane to trim the upper slurry. After 2500 holes, the amount of bit wear of the samples AA, BB and κ is still less than the control JJ, However, it is less noticeable. It is expected that most of the tool wear occurs in the early drilling of each group rather than in the final drilling. Based on the above, although not limited in the present invention, it is preferably coated here. a prepreg yarn made of a glass fiber fabric woven with a polymeric matrix compatible with a slurry It has a drill wear percentage of not more than 32%, more preferably not more than 30%, and most preferably not more than 25%, such as stacking in three laminates (each laminate includes 8, prepreg) 1 [吏Carbonized ruthenium drill with 0.46 亳m (approx. 0.018 inch) diameter -158- This paper scale applies to Chinese National Standard &lt;CNS) A4 Specification (210 X 297 mm) - -----------φ Μ-----r---订--------- C Please read the notes on the back and then fill out this page} Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 A7 ----- -------B7 _ V. Description of Invention (156) The head was measured after drilling a hole of 400 holes per square inch and 2000 holes for a plate load of 0 0〇1. Further, based on the above, although not limited in the present invention, it is preferred that the prepreg made of the glass fiber fabric coated with the polymer matrix compatible with the slurry is not more than 36 μm, more preferably not Greater than 33 microns, and optimally a misalignment distance of no more than 31 microns, such as a 46 mm (about 0.018 inch) diameter tungsten carbide drill bit used in 3 laminate stacks (each laminate including 8 prepregs) It was measured after the hole density of 4 holes per square inch and the hole of 〇·〇〇1 was drilled 2000 holes. While not being bound by any particular theory, it is believed that the presence of a solid lubricant in the glass fiber coating composition disclosed herein, and in certain embodiments, the presence of boron nitride contributes to the improvement of the present invention. The copper-boring properties of the laminate. More specifically, solid lubricants contribute to the reduction in bit wear and the improvement in the correct position of the hole. The improved drill hole properties of the laminates made from the glass fiber fabric coated with the polymeric matrix compatible slurries shown herein provide a number of advantages. First, a longer drill bit indicates that each drill cone can drill more holes before resharpening or discarding. Furthermore, since the positional correctness of drilling through the laminate of the present invention is greater than that of the conventional laminate, it is expected that more than 3 laminates can be stacked to obtain the same stack of the three laminates of the conventional laminate. The correctness is to drill holes at the same time. The result of these advantages is a more cost effective drilling operation. In addition, the correctness of the position of the borehole in the laminate is improved to improve the quality of the electron support added to the modified laminate. -159- This paper size is applicable to China National Standard (CNS) A4 specification <210 X 297 mm) (Please read the notes on the back and fill out this page) · I — I ϋ 1 1_^eJe n ii ϋ n ϋ _ϋ n I , Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1283255 A7 _ B7 __ V. INSTRUCTION DESCRIPTION (157) - EXAMPLE 15 The samples in Table 15 below represent additional specific embodiments of the present invention. The coated sample LL was produced but not tested. The coating sample MM-QQ has not been manufactured. Table 15 Component based on total solids % by weight Sample composition LL ΜΜ ΝΝ 00 ΡΡ QQ POLYOX WSR301201 0.56 0.55 0.61 0.43 0.47 0.34 Α-174202 3.68 4.31 4.74 3.32 3.68 2.61 Α-187203 1.74 2.08 2.29 1.60 1.78 1.26 DYNAKOLL SI 100204 26.60 26.58 - 20.46 _ 16.08 SER3MULEN668205 3.33 - - - - - DESMOPHEN 2000206 40.58 39.93 43.92 30.75 34.14 24.15 SYNPERONIC F-108207 9.98 - - - - A POLARTHERMPT 160208 5.46 5.45 - - 6.00 6.00 EUREDUR 140209 4.43 - One-one - _ PLURONIC F-108210 - 9.83 10.81 7.56 8.40 5.94 MACOL ΝΡ-6211 - 3.28 3.60 2.52 2.80 1.98 VERSAMED 140212 - 4.36 4.80 3.36 3.73 2.64 2G1POLYOX WSR 301 poly(ethylene oxide) commercially available from Union Carbide, Danbury, Connecticut ° 2Q2A-174 γ Methylpropoxypropyltrimethoxydecane, commercially available from CK Witco, Inc. of Tarrytown, OH. 2Q3A-187 γ-Glycidylpropyltrimethoxydecane, commercially available from New Zealand-160- This paper scale applies to the Chinese National Standard &lt;CNS)A4 specification (210 X 297 mm) (please read the back Note: Please fill in this page) Pack-----l· IT--------- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1283255 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention Description (158) CK Witco Corporation 0 204DYNAKOLL SI 100 rosin from Tarrytown, Jo., which is commercially available from Eka Chemicals AB of Sweden. 205 SERMUL ΕΝ 668 ethoxylated phenol, commercially available from CON BEA, Benelux 〇 2G6 DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer, Pittsburgh, Pa. 0 2G7 SYNPERONIC F-108, polyoxypropylene-polyoxidation Ethylene copolymer, a European counterpart of PLURONIC F-108, 2Q8 POLYTHMERM PT 160 boron nitride powder particles commercially available from Advanced Ceramics, Lakewood, Ohio. 2G9E_DUR 140 is a polyamide resin commercially available from Ciba Geigy, Belgium. 210 PLURONIC F-108 polyoxypropylene-polyoxyethylene copolymer commercially available from BASF Corporation of Parsippany, New Jersey. 211 MACOL NP-6 Indophenol Surfactant, commercially available from BASF Corporation of Parsippany, New Jersey. 212 VERSAMED 140 polyamine, commercially available from Cognis, Cincinnati, Ohio. -161 - This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public) -----------^-----r--I ^------ --- (Please read the note on the back and fill out this page) 1283255 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed A7 _ B7 V. Description of Invention (159) Table 15 (Continued) Component Weight Based on Total Solids Sample Ingredient LL MM NN 00 PP QQ RELEASECOAT-CONC 25213 3.64 3.63 - Noodle 4.00 4.00 ROPAQUE OP-96214 - - 29.23 30.00 35.00 35.00 Estimated solids in the coating % 5.4 5.6 5.1 7.3 6.5 9.3 213ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride The dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Inc. of Oak Ridge, Tennessee. 214ROPAQUE® OP-96, a 0.55 micron particle dispersion commercially available from Rohm and Haas, Philadelphia, PA. Example 16 An uncovered laminate was made using the materials and methods described in Example 9, except that copper was not used in lamination. Each uncovered laminate was then cut into 52 1 inch by 1/2 inch (about 2.54 cm x about 1.27 cm) rectangular sheets. About half of the pieces are cut in the direction of the parallel warp yarns, and about half of the pieces are cut in the direction of the parallel filling. Then, 26 rectangles (13 cut warp direction cuts and 13 parallel fill directions cut) from each laminate were placed in a water reflux device and the water was boiled. Let the water boil for 24 hours. After 24 hours, the #片 was removed from the water and dried. The remaining 26 tablets from each laminate did not boil. An uncoated control laminate made using a conventional heat removal and conditioning fabric was also fabricated in the same manner as in the above Example 9 for the production of the test laminate, and was tested according to the above procedure. -162 - This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -----------Install-----r---订------ --- (Please read the note on the back and fill out this page) 1283255 A7 V. INSTRUCTIONS (16 〇) The short beam men's shear strength of the boiled and unboiled sheets is then measured in accordance with ASTM D 2344-84. The test results are shown in Table 9, in which the uncovered samples AA, BB and CC correspond to laminates produced using the fabrics of the fibers having the above sizing compositions AA, bb, cC (described in Example 9). As discussed above, the control samples were made using conventional heat removal and conditioning fabrics. The thickness of the test laminate (non-face samples AA, BB and CC) ranged from 0.050 inches (about 127 127 cm) to ο· 忖 (about 〇 (10) cm). At the time of the test, the ratio of the length of the span to the thickness of the sample was 5. -----------Install-----r---订--------- (Please read the notes on the back and fill in this page) Ministry of Economic Affairs Intellectual Property Office staff Consumer Cooperative Printed -163 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed V. Inventions (161) ~ Table 16 Test Unit AA BB CC Control short bundle shear strength, not pounds per square inch 7787 8477 7769 7382 Number of boiling warp directions (million Baska) (54) (56) (54) (51) Sample thickness N=13吋0.060 0.050 0.056 0.055 (cm) (0.152) (0.127) (0.142) (0.140) Short-shear shear strength, not per square inch 碲6626 7594 7118 5506 Number of boiling fill directions (millions of Baska) (46) (52) (49) (38) Sample thickness N=13 吋0.061 0.050 0.060 0.055 (cm) (0.155) (0.127) (0.152) (0.140) Short beam shear strength 24 per square mile 5695 6522 5081 4929 hours of boiling warp direction (million bahka) (39) (45) (35) (34) sample thickness N = 13 inches 0.061 0.051 0.057 0.057 (cm) ( 0.155) (0.130) (0.145) (0.145) Short-shear shear strength 24 pieces per square inch 5266 5832 5179 4116 hours boiling direction of filling (million Baska) (36) (40) (36) ( 28) Sample thickness N=13 吋0.063 0.051 0.062 0.056 (cm) (0.160) (0.130) (0.157) (0.142) In this test, the test laminate (non-face samples AA, BB and CC) in the warp The short bundle shear strength with the weft direction was observed to be higher than the control sample before and after the water boiled. Example 17 A yarn was produced from the E-glass fiber strand of the sizing composition CC shown in Table 9A of Example 9, and the Chinese National Standard (CNS) A4 was applied by PPG Industries, Inc., 1383 Commercial-164 - This paper scale. Specifications (210 X 297 mm) · ί «1 ϋ a- n βϋ an 1 t III * I μ·! I 蜃 (Please read the notes on the back and fill out this page) 1283255 A7 B7 V. Description of invention (162 The warp yarns made from the fiberglass yarn products can be woven into a 7628 type fabric by air jet looms. The fabric was then pre-impregnated and laminated to form a copper facing laminate as described in Example 9 above. The copper finish laminate CC (as described in Example 9 above) was then treated (i.e., drilled, plated, and patterned) into test panels having multiple test patterns to test metal mobility. More specifically, each panel includes three sets of seven-layer circuit patterns 1310 as shown in FIG. One set of patterns is oriented along the X-axis of the plate, the other set is along the Y-axis of the plate, and the third set is along the 45 of the traverse plate. . Each circuit pattern 1310 includes 50 columns of five bores 1312, each having a straight cast of 13.5 mils and a central center-to-center spacing between adjacent rows of 40 to 54.7 mils. When drilling these holes, the two plates are stacked together so that they are drilled in a single hole operation. The staggered columns of the patterns are interconnected along the first major surface of the board by bus bars 1314 and leads 1316, as shown in FIG. Solder the leads to each busbar to connect to the power supply. Each circuit further includes a 1K ohm surface resistance 1322 to ensure that power to the remaining circuits is maintained if one board is damaged. The plates were immersed in 76.7 ° C (170 T) deionized water for 10 minutes to remove any solder flux residue and dry. The plate was then placed in a 85 C (185 T) and 85% relative humidity bath and a 13.5 volt DC current was applied continuously to the pattern. The trough was closed every 200 hours, the trough door was opened to stabilize the pattern to the surrounding laboratory temperature, and the insulation resistance of each pattern was measured. There are two sample CCs and two control plates. The control panel was fabricated in the same manner as Sample CC, but with conventional heat removal and trimming of the fabric. Each board includes 21 circuit patterns (ie, three sets of seven-layer circuit patterns), -165· This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public). (Please read the notes on the back and fill in the fields. This page)-----r---订----- Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing 1283255 A7 B7 Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing 5, Invention Description (sample A total of 42 circuits were tested for CC and ih, and board. The following table η shows the results of 200, 400 and 1000 hours, where 表 is the number of patterns with the specified resistance. Insulation resistance ------ 1 / - - Sample CC Control OHMS 200 Hrs 400 Hrs 1000 hrs 400 Hrs Short circuit 0 1 7 42 105 1 4 2 0 106 1 1 1 0 107 0 2 0 0 108 1 0 1 0 109 3 2 1 0 &gt;1010 36 32 30 0 The sample CC plate had fewer short circuits than the control plate after 200 hours of exposure. All of the control plate patterns were damaged after 400 hours of exposure. For the purpose of this test sample, 11 short circuit &quot;insulation resistance less than 1 〇 5 ohms Example 18 Mixing the components of the amounts described in Table 18A to form The aqueous resin of the invention is compatible with the first sizing sample RR. The composition comprises less than 1% by weight of acetic acid based on the total weight. The sample RR is applied to the glass fibers forming the G-75 E-glass fiber strand. The conventional interlacing device interweaves the coated glass fiber strands in a similar manner to form an interlaced yarn, and is wound on a bobbin. The coated J yarn has an LOI of 0.35%. -166- This paper scale applies to the Chinese national standard (CNS) A4 size (210 X 297 mm) I-----------β I-----r---^--------- (Please read the back of the note first) Please fill out this page again) 1283255 A7 _B7_ V. Description of invention (164)

— Table 18A Sample on the RR sample based on total solids by weight % Component Sample RR RD-847A215 27.0 DESMOPHEN 2000216 36.2 PVP K-30217 9.0 A-187218 2.1 A-174219 4.4 PLURONIC F-108220 9.0 VERS AMID 140221 4.4 MACOL NP- 6222 5.4 POLARTHERM PT 160223 0.9 RELEASECOAT-CONC 25224 1.5 Acetic acid &lt;0.1 (Please read the note on the back and fill out this page) Pack------r---Book---- Ministry of Economic Affairs Intellectual Property Office staff consumption Co-op printing 215RD-847A polyester resin commercially available from Borden Chemicals, Columbus, Ohio, 〇216DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer, Pittsburgh, Pa. 0 217 PVP K-30 Vinylpyrrolidone, commercially available from ISP Chemicals, Inc. of Wayne, New Jersey, 0 218 Α-187 gamma-dehydroglycerylpropyltrimethoxydecane, commercially available from OSi Specialties, Tarrytown, New York. 219Α-174 γ-methylpropoxypropyltrimethoxydecane, commercially available from I. &quot; New Zealand: OSi Specialties, Tarrytown, Jo.. -167- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7 _B7_ V. Description of invention (165) 220PLURONIC_ F-108 polyoxypropylene-polyoxyethylene copolymer, commercially available from BASF Corporation of Parsippany, New Jersey. 221 VERS AMID 140 Polyamide, commercially available from General Mills Chemicals, Inc. 222 MACOL NP-6 Indophenol Surfactant, commercially available from BASF Corporation of Parsippany, New Jersey, 〇223 POLARTHERM® PT 160 boron nitride powder particles, It is commercially available from Advanced Ceramics, Lakewood, Ohio. 224ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, a dispersion of about 25% by weight of boron nitride particles in water, commercially available from ZYP Coatings, Oak Ridge, Tennessee. The ingredients in the amounts described in Table 18B were mixed to form an aqueous resin compatible first sizing sample SS in accordance with the present invention. Sample SS was applied to the glass fibers forming the G-75 E-glass fiber strands, and the strands were not interwoven. The coated uninterwoven yarn had an LOI of 0.7%. I-----------^-----r------------ (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Office staff The consumption cooperative printed this paper scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (I66)

_ Table 18B Parts per 100 gallons of sample SS on the slurry. Component sample SS MAPEG 600 DOT225 9.24 ALUBRASPIN 226226 1.9 A-174227 10.9 A-187228 5.45 A-1 10229 2.41 EPON 880230 91.1 PLURONIC F-108231 9.11 ALKAMULS EL-719232 9.11 MACOL OP-10-SP233 4.57 EPIREZ 3 5 2 2 234 20.9 Acetic acid 2.6 225 is ethoxylated tallow from BASF. 226ALUBRASPIN 226 Partially amidated polyethylenimine, commercially available from BASF, Parsippany, Jersey. 227 Α-174 γ-Methoxypropoxypropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, Jo.. 22SA-187 γ-Glycidylpropyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. 229A-1100 Amino-functional organodecane coupling agent commercially available from New York State

Tarrytown's CK Witco Company 0 · · 23σΕΡΟΝ 880 Epoxy, commercially available from Houston, Texas Shell -169- This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm) ----- ------Install--------Set-------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1283255 A7 B7 V. Description of invention (167)

Chemical Company 0 231 PLURONICTM F-108 polyoxypropylene-polyoxyethylene copolymer commercially available from BASF Corporation of Parsippany, Jersey, 0 232 ALKAMULS EL-719 polyoxyethyleneated vegetable oil, commercially available from Rhone-Poulenc 0 233 MACOL OP-10 SP ethoxylated alkanol, commercially available from BASF Corporation of Parsippany, New Jersey. 234EPIREZ 3522 dispersion of solid bisphenol A diglycidyl ether epoxy resin commercially available from Sell Chemical Company of Houston, Texas. 0 Use of sample RR and SS sizing yarn as warp and fill (or weft), and textile Made into a 7628 fabric. The control yarn was also woven into a Type 7628 fabric which was a fiber having a coating of PPG 695 and was commercially available from PPG Industries of Pittsburgh, Pa., as a commercially available G-75 E-woven yarn. The sizing warp yarn and the yarn-filled control yarn have an LOI of 1%. The warp yarn is slit with a polyvinyl alcohol composition prior to weaving, which increases the LOI of the warp yarn to from about 2 to about 2.5%. The resulting fabric has an LOI ranging from 1.6 to 1.9%. The air permeability of each fabric was tested in accordance with ASTM D 737 Standard Test Method for Air Penetration of Textile Fabrics. The average air permeability of fabric weaving is shown in Table 1SC 〇-170 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm):-----------Installation--- -----Order---------^91 (Please read the notes on the back and fill in this page) 1283255 A7 B7 V. Invention Description (168)

Table 18C Air permeability (standard cubic inches per square inch per minute) Control sample 41 Sample RR 2.8 Sample SS 1.6 (please read the back note before completing this page) As seen in Table 18C, add sample A and The fabric of B has a much lower air permeability than the fabric woven with the control sample. Example 19 Table 19 includes an additional non-limiting sizing formulation applied to glass fibers which in turn were woven into a fabric. Less than 1% by weight of acetic acid is included in each composition. Table 19 Component weight based on total solids % Component sample TT Sample UU Sample XX Sample YY PVP K-30235 13.7 13.5 15.3 14.7 STEPANTEX 653236 27.9 13.6 A-187237 1.7 1.9 1.9 1.8 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 235 PVP K -30 polyvinylpyrrolidone commercially available from ISP Chemicals, Inc. of Wayne, New Jersey, 0 236 STEPANTEX 653, commercially available from Stepan Corporation of Maywood, New Jersey, 0 237 A-187 r-dehydroglyceryl Propyltrimethoxydecane, commercially available from CK Witco, Tarrytown, New York. -171- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1283255 A7B7 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed V. Inventions (169) Table 19 (continued) Component Sample TT Sample UU Sample XX Sample YY A-174238 3.4 3.8 3.8 3.7 EMERY 6717239 2.3 1.9 2.5 2.4 MACOL ΟΡ-ΙΟ240 1.5 1.7 1.6 TMAZ-81241 3.0 3.4 3.3 MAZU DF-136242 0.2 0.3 0.2 ROPAQUE OP-96243 39.3 43.9 42.3 RELEASECOAT-CONC 25244 4.2 6.4 POLARTHERMPT 160245 2.7 2.6 SAG 10246 0.2 RD-847A247 23.2 DESMOPHEN 2000248 31.2 PLURONIC F-108249 8.5 238 A-174 r-methacryloxypropyltrimethoxydecane, commercially available from New York, CK, Tarrytown, Jo. Witco company. 239EMERY® 6717 is a partially amided poly(ethyleneimine) commercially available from Cognis, Cincinnati, Ohio. 240 MACOL OP-10 ethoxylated alkanol; this material is similar to MACOL OP-10 SP except that MACOL OP-10 SP is post-treated to remove catalyst; MACOL OP-10 is no longer commercially available. 241 TMAZ-81 an alcohol oxide derivative of a sterol ester commercially available from BASF Corporation of Parsippany, New Jersey. 242 MAZU DF-136 antifoaming agent, commercially available from New Jersey i^rsippany-172- This paper size applies to the national standard (CNS) A4 specification (210 X 297 mm) ------ -----^w&gt; ^-----^----^--------- (Please read the note on the back and fill out this page) 1283255 A7 B7_ V. Invention Description ( 170) BASF Corporation. (Please read the note on the back and fill out this page.) 243ROPAQUE® OP-96, a 0.55 micron particle dispersion commercially available from Rohm and Haas, Philadelphia, PA. 244 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, a dispersion of about 25% by weight of boron nitride particles in water, commercially available from ZYP Coatings, Oak Ridge, Tennessee. 245 POLARTHERM PT® 160 boron nitride powder granules commercially available from Advanced Ceramics, Lakewood, Ohio. 246 SAG 10 anti-foam material commercially available from CK Witco, Greenwich, Connecticut. 247 RD-847A polyester resin commercially available from Borden Chemicals, Columbus, Ohio, ° 248 DESMOPHEN 2000 poly(ethylene adipate), commercially available from Bayer Corporation of Pittsburgh, Pa. 249 PLURONICTM F-108 polyoxypropylene-polyoxyethylene copolymer commercially available from New Zealand: BASF, Parsippany, Jersey 0 Table 19 (continued) Ingredient sample TT Sample UU Sample XX Sample YY ALKAMULS EL-719250 3.4 ICONOL NP-6251 3.4 FLEXOL ΕΡ0252 13.6 30.0 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives printed ALKAMULS EL-719 polyoxygenated vegetable oil, which is commercially available from Piioiie-Poiilenc. 251 ICONOL Νί&gt;-6 alkoxylated phenol, commercially available from New Jersey -173- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)

Claims (1)

9 I911536 专利 Patent Application Patent Application Scope Replacement (June 1994) 语申清专利范园 - a partially partially coated fiber strand comprising more than one part: at least a part of the surface The resin-compatible coating composition has a ruthenium fiber, and the resin-compatible coating composition comprises (4) a plurality of discontinuous particles formed of the following materials: (1) selected from the group consisting of thermosetting materials, thermoplastic materials, and mixtures thereof Non-thermally expandable organic material, (ϋ) an inorganic polymeric material selected from the group consisting of polyphosphazene, polymethane, polyoxo-polyalkylene, polysulfide poly selenium, polyfluorene, and any combination thereof, 〇ii a thin flat particle having a thermal conductivity in the range of 1 to 2000 W/mK at a temperature of 3 〇〇K, ((7) is selected from a non-thermal expansion of particles having a hardness of 4 hardness in the particle which is different from the surface thereof. A composite material, and (V) a mixture of any of the above, wherein the particles have an average particle size sufficient to wet the strands; and; (8) - a lubricating material different from the plurality of discrete particles; and 2 (C) at least one film Form the material. 2: Please at least partially coated fiber in the first paragraph of the patent scope: wherein the resin compatible coating composition is the residual of the aqueous coating composition ^ 4 Patent scope No. 1 is at least partially coated The coated fiber 4. The phase resin compatible coating composition is a powder coating composition. The at least partially coated fiber of the scope of claim 1 f ® »^i?(CNS) Amm210 X 297^ 57 The at least partially coated fiber strands of the plate, the intermediate, comprise at least one glass fiber. 5. The at least partially coated fiber according to item 1 of the scope of the patent application. The fiber strands coated with at least a portion of the fiber contain a plurality of glass fibers. 6. At least partially coated fiber according to item 5 of the scope of the patent application, wherein a plurality of glass fibers are selected from the group consisting of E-glass fiber, D-glass fiber, S-glass fiber, Q_glass fiber, and &amp; Glass Derivative Fiber Pack 7. Fiber Jk which is at least partially coated according to Item 6 of the scope of the patent application, wherein the glass fiber is Ε·glass fiber. 8. The fiber strands which are at least partially coated according to item 6 of the patent application, wherein the plurality of glasses and fibers are Ε_glass derivative fibers. '9· According to the t 4* patent param i item, at least partially coated fiber month and 'the non-thermally expandable organic material is selected from the group consisting of thermosetting polystyrene, yoghurt printing% oxygen material, bismuth fraction, amine A thermosetting material of a base plastic m-polyurethane, and a mixture of any of the above. 10. The non-thermally expandable organic material in the at least partially coated fiber plaque according to item i of the scope of the patent application is selected from the group consisting of thermoplastic polyester, poly stone 酉 酉, poly mai, two, knee ac A thermoplastic material that is a mixture of a ruthenium polymer, a polyamidamine, a thermoplastic polyurethane, a methacrylate, or a mixture of any of the above. 11· According to the scope of the patent application! ^弟一员 &lt; At least partially coated fiber strands&apos; wherein the thin flat particles are inorganic. K-scale is suitable for wealthy _) -2- A8 B8 C8 D8 u· at least partially coated fiber strands according to the scope of claim 1 wherein the thin flat particles are selected from the group consisting of boron nitride, molybdenum disulfide, graphite, dirhodium chloride, bismuth disulfide, A double selenization button, tungsten disulfide, tungsten disilicide, and a mixture of any of the above. 13. The at least partially coated fibrous strand of claim 1 wherein the non-thermally expandable composite material is selected from the group consisting of particles formed from a first material covered, protected or encapsulated by at least one second material. 14. The at least partially coated fibrous strands according to claim </RTI> wherein the non-thermally expandable composite material is selected from the group consisting of particles of a first material covered, protected or encapsulated in a different form of the first material. 15. The at least partially coated fiber sheet&apos; in accordance with claim 1 wherein the plurality of discrete particles provide a gap space between the at least one fiber and the at least one adjacent fiber. 16. The at least partially coated fiber version according to claim 1 wherein the plurality of discontinuous particles have an average particle size ranging from 0.1 to 5 microns as measured by laser scattering techniques. 17. The at least partially coated fibrous strands according to the scope of the claims of the invention wherein the plurality of discontinuous particles comprise from 1 to 80% by weight based on the total solids of the resin compatible coating composition. • At least partially coated fiber strands according to the scope of claim 7 wherein the plurality of discontinuous particles comprise from 20 to 60% by weight based on the total solids of the resin compatible coating composition. At least one of the fiber strands at least partially coated according to the scope of claim 1 wherein at least one of the lubricating materials is selected from the group consisting of oils, waxes, and fats. 2〇· According to the application of the at least partially coated fiber of the patent yoke, the at least one lubricating material comprises 1 to 50 of the coating composition based on the total solids. weight%. 21. The at least partially coated fiber according to claim 20, wherein at least one of the lubricating materials comprises from 2 to 40% by weight based on the total solids of the resin phase coating composition. 22. The at least one film-forming material at least one of the film-forming materials according to item 1 of the scope of the patent application is selected from the group consisting of organic polymeric materials, organic polymeric materials, and natural polymeric materials. 23. The at least one film forming material at least one of the film forming materials according to claim 22 of the scope of the patent application is selected from the group consisting of thermoplastic materials and thermosetting materials. 24. At least partially coated fiber strands according to Article 23 of the scope of the patent application, wherein the thermosetting material is selected from the group consisting of thermosetting polyesters, epoxy materials, B-wheat, sizing, amine-based plastics, thermosetting polyamines An acid ester, and a mixture of any of the above. 25. A fiber strand which is at least partially coated according to item 23 of the scope of the patent application, wherein the thermoplastic material is selected from the group consisting of a vinyl polymer, a thermoplastic polyester, a polycarbene, a polyamine, a thermoplastic polycarbamic acid. An ester, a propylene polymer, and a mixture of any of the above. 26· According to the scope of patent application! At least one of the coated fiber strands, wherein at least one of the film forming materials comprises from 5 to 50 weights per ounce of the resin-compatible coating composition based on the total solids. 27· At least partially coated according to the scope of patent application No. 26, 纤 -4- This paper scale applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1283255 The at least one film forming material of the strands contains 10 to 30% by weight based on the total solids of the resin compatible coating composition. 28. The at least partially coated fiber strands according to item i of the scope of the patent application wherein the resin compatible coating comprises a resin reactive diluent. 29. The at least partially coated fiber strand according to claim 28, wherein the resin reactive diluent comprises one or more reactive systems with an epoxy resin and is selected from the group consisting of an amine group and an alcohol group. A lubricant of a functional group of a group consisting of an anhydride group, an acid group, and an epoxy group. 30. An at least partially coated fiber strand comprising a plurality of fibers having a resin compatible coating composition on at least a portion of a surface of at least one of the fibers, the resin compatible coating composition comprising: (a) a plurality of particles comprising (1) at least one particle formed of at least one organic material; and (11) at least one particle formed of at least one inorganic material selected from the group consisting of boron nitride, graphite, and a metal dichalcogenide, Wherein the plurality of particles have an average particle size sufficient to wet the strand; (b) at least one lubricating material different from the plurality of particles; and (C) at least one film forming material. 3. A fiber strand at least partially coated according to item 3 of the scope of the π patent, wherein at least one of the organic materials is a polymeric organic material. 32. A fiber strand which is at least partially coated according to item 31 of the scope of the patent application, wherein the polymer material is selected from the group consisting of an ethylene-based polymer, a thermoplastic polymer, a polyolefin, a polyamine, a thermoplastic Polyurethane, and C Special bribes % 128,3255 ^ δΜ· Ο * Thermoplastic materials for bismuth polymers. 33. According to the application form, the 第#, 干 第 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Polymer. Cloth ', C-female early body "total 34. According to the application of the nose is not | γ _ shares, of which 30 of the younger at least partially coated fiber, w solid particles have a laser scattering according to 1 to 5 microns The average particle size. The dry circumference is 35·« the at least partially coated fiber strand of the third aspect of the patent scope, wherein the plurality of particles comprise from 1 to 80% by weight based on the total solids of the resin compatible coating composition. 36. According to the at least partially coated fiber of the 35th item of the Sino-Indian Patent Park, the plurality of particles comprises 20 to 60% by weight of the resin-compatible coating composition based on the total solids. 37. An at least partially coated fiber strand according to item 3Q of the mid-m patent range, wherein at least one of the lubricating materials comprises from 1 to 50% by weight based on the total solids of the resin compatible coating composition. 38. An at least partially coated fiber strand according to claim 37, wherein the at least one lubricating material comprises from 20 to 40% by weight based on the total solids of the resin compatible coating composition. 39. The at least one film-forming material at least one of the film-forming materials according to claim 30 of the scope of the patent application comprises 5 to 50 by weight of the resin-compatible coating composition based on the total solids. /0. 40. At least partially coated fiber strands according to claim 39 of the scope of the patent application, wherein at least one of the film forming materials comprises a resin based on the total solids -6 - the paper size applies to the Chinese National Standard (CNS) A4 specification ( 210×297 mm) S «25i 12 J % ABCD 10 to 30% by weight of the phase coating composition. 41. An at least partially coated fiber strand comprising a plurality of fibers, at least a portion of which has a resin compatible coating composition on a surface thereof, wherein the coating composition comprises at least one organic component and has a Thin flat particles having a thermal conductivity ranging from 1 to 2000 W/mK. 42. The at least one organic component and the thin flat particles of the at least partially coated fiber strands according to item 41 of the patent application scope are the same. 43. At least one of the at least one organic component and the thin flat particles are different according to the at least partially coated fiber version of claim 41. 44. A fiber strand at least partially coated according to item 43 of the scope of the patent application wherein the thin flat particles are inorganic. 45. The at least partially coated fiber strands according to item 41 of the patent application wherein the thin flat particles have a thermal conductivity in the range of 5 to 2 〇〇 0 W/mK at a temperature of 300K. 46. The at least partially coated fiber according to the scope of claim 4th, wherein the fiber is selected from the group consisting of nitriding, disulfide I, graphite, two molybdenum selenide, disulfide button, Diselenide button, tungsten disulfide, di-halogenated tungsten, and any mixture of the above. 47. An at least partially coated fiber strand comprising a plurality of fibers having a resin compatible coating bait on at least one of the at least one surface of the glass fibers, the resin compatible coating combination The inclusions include (a) a plurality of thin flat inorganic particles having a Mohs hardness value not exceeding the Mohs hardness value of the glass fiber; and the paper size of the product a ® (CNS) A4 specification (靡297 Male cage)-------- 1283255 / Wang Xi - dish preparation, Ho: rr. 48: At least partially coated fibers according to item 47 of the profit margin wherein the thin flat particles have a range of from 0.5 to 6 for the &lt; value. &lt; Mohs hardness stocks; at least one of the coated fibers according to claim 47, wherein at least one of the polymeric materials is selected from the group consisting of organic polymeric materials, polymeric materials, and natural polymeric materials - ..., according to the application Article 49 of the patent scope is at least partially coated with 'at least one of the polymeric materials selected from the group consisting of thermoplastic materials. Covered fiber and thermoset • Fiber strands that are at least partially coated according to item 50 of the patent application' wherein the thermoset material is selected from the group consisting of thermoset polyesters, epoxy materials, B-branched, g-branched, amine-based plastics, Thermoset polyurethane, and mixtures of any of the above. 52. At least partially coated fiber strands according to item 50 of the scope of the patent application wherein the thermoplastic material is selected from the group consisting of an ethylenic polymer, a thermoplastic polyfluorene, a polyfluorene, a polyamine, a thermoplastic polyamine An acid ester, a propylene polymer, and a mixture of any of the above. -8- r^.5 Patent application for I283^55i536 中文 Chinese translation page (September 95) #^月&gt;/曰修'(欢)正换页 Figure 13