TWI230698B - Impregnated glass fiber strands and products including the same - Google Patents

Abstract

The present invention provides an at least partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and lamellar particles having a thermal conductivity of at least 1 Watt per meter K at a temperature of 300K. The present invention also provides an at least partially coated fiber strand comprising a plurality of fibers, the coaling comprising an organic component and non-hydratable, lamellar particles. The present invention further provides an at least partially coated fiber strand comprising a plurality of fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said fibers, the resin compatible coating composition comprising: (a) a plurality of discrete particles formed from materials selected from non-heat expandable organic materials, inorganic polymeric materials, non-heat expandable composite materials and mixtures thereof, the particles having an average particle size sufficient to allow strand wet out: (b) at least one lubricious material different from said plurality of discrete particles: and (c) at least one film-forming material. The present invention also provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coating composition comprising: (a) a plurality of lamellar, inorganic particles having a Mohs' hardness value which does not exceed the Mohs' hardness value of said glass fibers: and (b) at least one polymeric material. The present invention further provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coaling composition comprising: (a) a plurality of hollow, non-heat expandable organic particles; and (b) at least one lubricious material different from the at least one hollow organic particle.

Description

1230698 A7

1230698 A7 B7 V. Description of the invention (2) Method for removing sizing material, such as water washing and / or chemical removal. However, such methods generally require a significant re-sizing of the sizing composition to be compatible with such water washing and / or chemical removal, and are generally less effective than thermal removal in removing all incompatible materials. In addition, because the weaving process is quite abrasive to fiberglass yarns, the yarns used as warp yarns generally undergo a second coating step before weaving, which is commonly referred to as "sizing yarn" and is coated with a wear-resistant coating Warp yarns (commonly known as sizing yarns) to help minimize the abrasion of glass fibers. Sizing of sizing is usually applied to a first sizing previously applied to glass fibers during a fiber forming operation. However, since typical sizing of a sizing yarn is also generally not compatible with polymeric matrix materials, it must also be removed from the woven fabric before the resin is added. In addition, in order to improve the abrasion between the degreased or deoiled fabric and the polymer resin, the final slurry (typically a silane coupling agent and water) is applied to the fabric in another processing step to recoat the glass fiber (commonly referred to as & quot Trim "). All of these have no added cost processing steps: ㈣, degreasing or degreasing, and finishing, increasing fabric manufacturing cycle time and cost. In addition, they often require significant investments in capital equipment and labor. In addition, the additional fabric treatments accompanying these treatment steps cause fabric damage and reduced quality. Efforts have been made to improve the efficiency or effectiveness of some of these processing steps. However, the coating still continues to fulfill one or more of the following requirements: · To suppress the abrasion of glass fiber = break; compatible with a wide range of matrix materials; and to provide good wetting and wetting of the substrate material. In addition, it is particularly advantageous if the coating is compatible with modern air-jet weaving devices to increase productivity. In addition, exclude extra processing steps in the fabric J operation, while maintaining the electronic support should be 297 mm) Order & Zhang scale home fresh (CNS) A4 specifications ⑵〇_; 1230698

It is advantageous to use the desired fabric quality and provide good lamination properties. When reading in conjunction with the drawings, you can better understand the detailed description of the above-mentioned preferred embodiments. In the drawings: 1. FIG. 1 is a front view of a coated fiber strand that is at least partially coated with a coating composition according to the invention ¢ 1; α FIG. 2 is a sizing composition and on at least a portion Front view of a coated fiber strand at least partially coated with a second coating composition according to the present invention on a pulp composition; FIG. 3 is at least partially coated with a sizing composition on at least a portion Front view of the second coating composition on the sizing composition and the coated fiber strands of the third coating composition according to the present invention on at least a portion of the second coating composition; FIG. 4 is a top plan view of a composite product according to the present invention; FIG. 5 is a top plan view of a fabric according to the present invention; FIG. 6 is a schematic diagram of a method for combining fabrics and forming a laminate according to the present invention; 8 and 9 are cross-sectional views of alternative embodiments of the electronic support according to the present invention; and FIG. 10 is a method of forming a laminate in a fabric layer of the electronic support. A schematic view; Figure 11 is the end view of the drill bit, which describes the first cutting edge; Figure 12 is the drill The illustrated pattern; and FIG. 13 is a graph of a circuit pattern. -6- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

(Please read the precautions on the back before filling this page) -------- Order --------- line "Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 V. Description of the invention (4 ) The fiber strand of the present invention has a unique coating, which not only better inhibits the abrasion and breakage of the fiber I during processing, but also provides at least one or more of the following properties when forming a composite. Good wetting, wetting and dispersion nature. As detailed below, Tian'an '’s stock contains multiple individual weaving dimensions, that is, at least two weaving dimensions. The composite used indicates a combination of the coated fiber strands of the present invention and additional materials, such as, but not limited to, adding one or more layers to the coated fiber'quasi-monthly fabric combination polymer matrix material to form a layer组合。 The compound. Good lamination strength, good thermal stability, good hydrolytic stability (that is, resistance to water moving along the fiber / polymer matrix material interface), high humidity, presence of reactive acids and bases < low corrosion and Reactivity and interaction with various polymeric matrix materials / phases (which can eliminate the need to remove the coating before lamination, especially hot or pressurized water π), are coated fiber strands that can be coated by the present invention Other required characteristics presented. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Preferably, the coated fiber strand of the present invention provides good weaving and knitting processing power. Low fine hairs and loops, low broken filaments, low strand tension, high floating force and low insertion time are the better individual or combined features provided by the coated glass fiber strands of the present invention, which are better for weaving and knitting , And consistently mention i, fabrics for printed circuit board applications with few surface defects. In addition, the coated fiber strands of the present invention are suitable for use in an air jet weaving process. As used herein, "'air jet weaving" means a weaving pattern in which a filling yarn (weft) is inserted into a warp shed with strong compressed air from one or more air jet nozzles. The coated fiber strands of the present invention preferably have a unique coating that facilitates heat conduction along the coated surface of the fibers. When the paper is used as a continuous strong paper standard for electronic circuit boards, the national standard of TP (c A4 specifications ⑽χ 297 Public Love-'1230698 Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 B7 V. Invention description (5) The coated glass fiber of the present invention can provide a mechanism for promoting heat dissipation from a heat source (such as a wafer or a circuit) along the reinforcement to conduct heat away from the electronic component, thereby inhibiting the electronic component, glass fiber, and polymer matrix material. Thermal degradation and / or degradation. The coated fiber strands of the present invention preferably provide a thermally conductive phase that is higher than the matrix material, that is, a preferred path for heat dissipation and distribution, thus reducing the thermal expansion and crimp difference of the electronic circuit board and improving Reliable welding The coated glass fiber strands of the present invention preferably reduce or eliminate the need to add a thermally conductive material to the matrix resin, which improves laminate manufacturing operations and reduces the need for expensive matrix material supply tank flushing and maintenance. Coated fiber strands are preferably high-strength open. "High-strand openness" as used herein means that the strand has a large cross-sectional area and the fiber of the strand. Not tightly bonded to each other. The high openness of the strands can facilitate the penetration or wetting of the strands by the matrix material. The composites, especially laminates, made of the fiber strands of the present invention preferably exhibit at least one of the following properties : Low thermal expansion coefficient; good flexural strength; good interlayer bonding strength; and good hydrolytic stability, that is, resistance to the movement of water along the fiber / matrix interface. In addition, the present invention made from a fiber strand according to the present invention Electronic supports and printed circuit boards preferably have at least one of the following properties: good drilling force; and resistance to metal movement (also known as cathode-anode filament formation or CAF). See Microelectronics by Tummala (editor) and others Packaging Handbook, (1989) pages 896-897, and IPC-TR-476B, " Electrochemical Migration: Electrochemically Induced Failures in Printed Wiring -8-This I sheet is applicable to China National Standard (CNS) A4 (210 x 297) (Gongai) (Please read the precautions on the back before filling this page)-= & · -line "1230698 V. Invention Description U)

Boards and Assemblies ", (1997), which is specifically incorporated herein by reference. The fiber strand with good drilling force according to the present invention has at least one of low tool wear and good drilling position accuracy when drilling holes. As mentioned above, typical fabric forming operations involve subjecting fiberglass yarns and fabrics made therefrom to many additional processing steps, such as sizing, heat removal, and trimming. The present invention preferably provides a method for forming a fabric, a laminate, an electronic support, and a printed circuit board, which eliminates no additional processing steps from the fabric formation process, and also provides a method suitable for electronic packaging applications. Quality fabric. Other advantages of the preferred embodiments of the present invention include reduced production cycle time, exclusion of capital equipment, reduced fabric handling and labor costs, good fabric quality, and good final product properties. The present invention also provides a method for suppressing abrasion of the fiber strands due to contact with other solid objects (such as a part of a rolling, weaving or knitting device) or due to abrasion between filaments by selecting the fiber strands having the unique coating of the present invention. . For the purpose of this specification, it should be understood that, except in the operating examples, or where specified, the quantities of all indicated ingredients, reaction conditions, etc. used in this specification and the scope of patent applications are in all cases by the term " about "Modifications. Unless stated to the contrary, the quantitative parameters set forth in the following description and the scope of the attached patent application are approximate, and may vary depending on the desired properties sought by the present invention. At least, and not by way of limitation, the scope of patent application For the application of physical science, each quantity parameter should be considered at least in terms of the number of reported major digits and the application of the general rounding technique. Although the broad scope and parameters of the present invention are approximate, it is necessary to consider It is possible to accurately report the numbers described in specific examples. However, any number -9- This paper size is applicable to the Chinese National Standard (CNS) A4 specification 7210 ^ 297 mm) 1230698 A7 B7 V. Description of the invention (inherently The standard deviation found in each of its test measurements must be used to generate the error. Now refer to Figure 1, where Yin Xiang, & (Please First read the notes on the back before filling this page), the door type < fool code indicates the same element, and the coated fiber strand 10 according to the present invention containing a plurality of fibers 12 is shown in FIG. 1. Used here • • Strands ·· means multiple individual fibers, that is, at least two fibers *, and the month may also include fibers made from different fiberizable materials. (The fiber j bundle may also be referred to as yarn). The term " fiber " Represents individual filaments. Although not limiting the present invention, the fibers 12 preferably have an average nominal fiber diameter ranging from 3 to 35 microns. Preferably, the average nominal fibers of the present invention are directly tied to 5 microns and larger. For " Spinning " application, the average nominal fiber diameter is preferably in the range of 5 to 7 microns. The printed fiber 12 of the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs can be formed from any type of fiberizable material known to those skilled in the art, which Includes fiberizable inorganic materials, fiberizable organic materials, and mixtures of any of the above. Inorganic and organic materials can be artificial or naturally occurring materials. Those skilled in the art should understand that fiberizable inorganic and Organic materials can also be polymeric materials. The term " polymeric materials " as used herein refers to materials formed from macromolecules composed of long chain atoms bonded together and mixed in a solution or solid phase. 1. Used herein The term " fibrillable " means a material that can form substantially continuous filaments, fibers, strands, or yarns. Preferably, the fiber 12 is formed of an inorganic, fiberizable glass material. The fiberizable glass material used in the present invention This includes, but is not limited to, Inorganic Polymers ^ Prentice Hall Polymer Science and Engineering Series by " E_Glass " James Mark et al. (1992), page 1, which is incorporated herein by reference. • 10 · This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by A7, Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs, 5. Description of invention u, “A glass” C-glass ", D-glass ", " R-glass ", " s-glass ", and E-glass derivatives for the preparation of fiberizable glass compositions. The use of "" E-glass derivative "herein means a glass breaking composition comprising a small amount of fluorine and / or boron, and preferably fluorine-free and / or boron-free. In addition, as used herein, "a small amount of fluorine" means less than 0.5% by weight of fluorine, preferably less than 0% by weight of fluorine, and " a small amount of boron "means less than 5% by weight of boron, preferably Less than 2% by weight I shed. Basalt and mineral wool are examples of other fiberizable glass materials used in the present invention. Preferred glass fibers are formed from glass or & glass derivatives. This composition is known to those skilled in the art, and further discussion of this composition is believed to be unnecessary for the purposes of the present invention. The glass fibers of the present invention can be formed by any suitable method known in the art for forming glass fibers. For example, glass fibers may be formed in a direct-melt fiber-forming operation or an indirect or marble-melt fiber-forming operation. In the direct melting fiber forming operation, the raw materials are combined, melted, and homogenized in a vitrification furnace. The molten glass moves from the furnace to the forehearth and enters the forming device, where the molten glass is thinned into continuous glass fibers. In the marble-melting fiber forming operation, a glass sheet or marble 'having the final desired glass composition is previously formed and fed into a liner, where it is melted and thinned into a continuous glass fiber. If a pre-melter is used, the marbles are first fed into the pre-melter and melted, and then the molten glass is fed into the fiber forming device where the glass is thinned to form continuous fibers. In the present invention, the glass fibers are preferably formed by a direct dissolving fiber forming operation. For additional information on the glass-breaking composition and the method of forming glass fibers', see The Manufacturing Technology of K. Loewenstein, Continuous FiWc (No. 3 • 11- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Love) (Please read the notes on the back before filling this page)

1230698 A7 B7 V. Description of the Invention (9th edition, 1993) pages 30-44, 47-103, and 115-165; US patents 4,542,106 and 6,789,329; and IPC-EG-140 " Specification for

Finished Fabric Woven from Έ * Glass for Printed Board " page 1, The Institute for Interconnecting and Packaging Electronic Circuits publication (June 1997), which is specifically incorporated herein by reference. Non-limiting examples of suitable non-glass fiberized inorganic materials include ceramic materials such as silicon carbide, carbon, graphite, mullite, alumina, and piezoelectric ceramic materials. Non-limiting examples of suitable fiberizable organic materials include cotton, cellulose, natural rubber, linen, ramie, hemp, ramie, and wool. Non-limiting examples of suitable fiberizable organic polymeric materials include polyamines (such as nylon and aromatic amines), thermoplastic polyesters (such as polyethylene terephthalate and polyethylene terephthalate) , Propionyl (such as polyacrylonitrile), polyfluorene, polyurethane, and vinyl polymers (such as polyvinyl alcohol) formed. Non-glass-fiberized materials for use in the present invention and methods of making and processing such fibers are discussed in detail in Encyclopedia of Polymer Science and Technology, Vol. 6 (1967), pages 505-712, which is specifically incorporated herein by reference . It will be understood that if desired, a blend or copolymer of any of the above materials and a combination of fibers formed from any of the above materials can be used in the present invention. In addition, the noun strand contains at least two different fibers made from different fiberizable materials. In a preferred embodiment, the fiber strand of the present invention contains at least one glass fiber, although it may contain other types of fibers. The present invention is now generally discussed about the content of glass fiber strands, although those skilled in the art should understand that the strand 10 may include the technique known from the above discussion-12 X 297 mm) Please read the note on the back of t # to write this page Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative Cooperative 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7. The material forms a weak aggregate and fiber 12. Therefore, the following discussion of glass fiber I applies broadly to the other fibers discussed above. With continued reference to FIG. 1, in a preferred embodiment, the fiber strands 10 to y of the present invention (and preferably all the fibers 12 have a coating composition (which is preferably a coating M compound residue) on the fibers 12 A layer 14 on at least a portion 17 of the surface 16 to protect the fiber surface 16 from abrasion and inhibit fiber breakage I during processing. Preferably, the layer 14 is present on the entire outer surface M or the periphery of the fiber 12. The coating composition of the present invention is preferably an aqueous coating composition, and more preferably an aqueous resin compatible coating composition. Although it is not good for safety reasons, the coating composition may contain a volatile organic solvent as required , Such as alcohol or acetone, but preferably without such a solvent. In addition, the coating composition of the present invention can be used as the first sizing composition and / or the second sizing or coating composition. In the example, the terms "upper size", "Slzed" or "sizing" used herein refer to any coating composition that is applied to the fibers after the fibers are formed. Nouns, No. Second size sec〇ndary size ,,,, the second size sizing "Or " second coating" means a coating composition that is applied to the fibers after the first coating is applied. The term " third upper material tertiary size ", " third upper mask material tertiary sizing " or " a third coating, which means a coating composition that is applied to the fibers after the second sizing is applied. For example, by coating a fabric, these coatings can be applied before the fibers are added to the fabric In the fiber 'or it can be applied to the fiber after the fiber is added to the fabric. In alternative embodiments, the noun, sizing size π sizing sized " or, sizing sizing' 'also refers to the Thermal or chemical treatment removes at least a part, and -13- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

123〇698 V. Description of the invention (11) and preferably all of the conventional Chinese chives 4 red dagger non-tree phosphine grain sizing composition, then apply to the fiber coating composition (also known as, • trimming ㈣ "), that is, trim the bare glass fiber coated with the polymer and added to the fabric form. The use of "Name 4 Xiaozhi Compatibility" here means that the coating composition applied to the glass fiber is compatible with the matrix material added to the glass fiber, so that the coating (or the selected coating component) obtains at least- The following properties: In addition: Matrix material (no need to remove before (such as degreasing or degreasing), good wetness and wet penetration of the matrix material during the conventional processing, and generate the required physical properties and hydrolytic stability The final composite product. The coating composition of the present invention comprises one or more, and preferably a plurality of particles 18 ′ which adhere to at least one fiber 23 when coated on at least one fiber 23 of the plurality of fibers 12. The outer surface 16 provides one or more clearance spaces 21 between adjacent glass fibers 23, 25 of the strand iq, as printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs' 1 7TT. These clearance spaces 21 Approximately the size 19 of the particles 18 located between adjacent fibers. The particles 18 of the present invention are preferably discontinuous particles. As used herein, the term "discontinuous" means that the particles do not tend to coalesce under conventional processing conditions. Or combined Continue the film, but rather retain its individual differences, and generally retain its individual shape or form. The discontinuous particles of the present invention can be sheared during the conventional fiber treatment, that is, to remove a layer or a piece of atoms in the particles, Necking, that is, second-order phase transfer between at least two particles, and partial coalescence, and can still be considered as "discontinuous," particles. The particles 18 of the present invention are preferably dimensionally stable. Used herein The noun, 'size stable particles', refers to the force generated between adjacent fibers under conventional fiber processing conditions, such as weaving, spinning, and other processing operations, usually dimension -14-1223698 A7 B7 V. Description of the invention (l2 maintains its average particle size and shape, and maintains the gap between adjacent fibers 23, 25 ^ 21 'under typical slope glass fiber treatment conditions, such as exposure: up to 25 ° C, preferably up to 1⑽. C Moreover, it is more preferable to reach 14rc = 2 size. The stable particles preferably do not collapse, dissolve, or deform in the coating composition to form the largest size foot particles having a size smaller than their selected average size. In addition, in glass Fiber Under the conditions, and more: under the treatment conditions of the compound with a degree exceeding 150, the size of the particles 18 should not increase or expand. Here the term "quote used for particles should only be qualitatively unchanged" means that The particles should not swell or increase during processing. Their initial size is three times. In addition, the term "size-sized particles" used herein refers to crystalline and amorphous particles. Preferably, the coating combination of the present invention The substance is essentially non-thermally expandable. This means that Γ thermally expandable particles " mean filling or containing a certain material: fruit, granules, which swell when the temperature of the material is sufficient to make the material volatilize or! =: These Γ expand The granules therefore swell due to the phase change of the material (: 'name: agent) in the granules under normal processing conditions. The term 'non-heat-expandable particle' refers to a particle that swells from the decay of the material in the particle under normal virtual conditions, and in the specific example of the present invention, the coating composition contains at least one non-thermal-expandable particle . Generally, the thermally expandable particle is a non-limiting embodiment with a central cavity. The cavity may be at least part of the material, such as a gas, liquid, and / or gel. ^ Solid The term used in this article, "substantially no heat-expandable particles" means less than 50% by weight of heat-expandable particles, more preferably less than two: the most secure example is solid

Clear material solid content L ____- 15- This paper is also suitable for the national standard (CNS) A4 specifications of the country of wealth ⑽χ 297 Public Love 1 1230698 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of invention (I3)%. More preferably, the coating composition of the present invention is essentially free of thermally expandable particles. The term π as used herein is essentially thermally expandable particles "means that the sizing composition contains less than 20% by weight of thermally expandable particles, more preferably less than 5% by weight, and most preferably less than o.ooi% by weight. The particles 18 are preferably non-soily. The term π non-butterfly-like means that the material forming the particles is non-waxy. The term " wax-like " as used herein means that the material is mainly composed of an immiscible hydrocarbon chain having an average carbon chain length ranging from 25 to 100 carbon atoms 2'3. In a preferred embodiment of the invention, the particles 18 of the invention are discontinuous, dimensionally stable, non-wax particles. The particles 18 may have any desired shape or configuration. Although not limited in the present invention, examples of suitable particle shapes include spherical (e.g., granules, particles, or hollow spheres), cubes, plates, or needles (long or fibrous). Further, the particles 18 may have a hollow, porous, or non-porous internal structure, or a combination thereof, such as a hollow center and a porous or solid wall. For more information on suitable particle characteristics, see Η. Katz et al. (Eds.), Handbook of Fillers and Plastics (1987), pages 9-10, which are specifically incorporated herein as 2 L. H. Sperling's Introduction of Physical Polymer Science. John Wiley and Sons Corporation (1986) at pages 2-5, which are specifically incorporated herein by reference. 3 W. Pushaw et al. `` Use of Micronised Waxes and Wax Dispersions in Waterborne Systems " Polymers. Paint. Colours Journal, Vol. 189, No. 4412, January 1999, pages 18-21, which are specifically incorporated herein For reference. -16- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

-ϋ -I hi «1 n ϋ a -0, ϋ I ϋ n ϋ n ϋ I 1230698 Α7 Β7 5. The invention description (14) is for reference. The particles 18 may be formed of a material selected from the group consisting of polymeric and non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and any combination thereof. The term " polymeric inorganic material " as used herein refers to a polymeric material having a backbone repeating unit mainly composed of elements other than carbon. For more information, see page 5 of E. Mark, which is specifically incorporated herein. For reference, the term "polymeric organic material" as used herein refers to synthetic polymeric materials, semi-synthetic polymeric materials, and natural polymeric materials with carbon-based backbone repeating units. The π organic material used herein means a carbon-containing compound, in which carbon is generally bonded to itself and hydrogen, and often to other elements, and excludes binary compounds such as carbon oxides, carbides, carbon disulfide, etc .; such as Ternary compounds of metal cyanide, metal carbonyl, phosgene, carbonyl sulfur, etc .; and carbon ion-containing compounds such as metal carbonates, such as calcium carbonate and sodium carbonate. See R. Lewis, Sr., Hawlevfs Condensed Chemical Dictionary. (12th edition, 1993) pp. 761-762, and M. Silberberg's Chemistry Um Molecular Nature of Matter and Change (1996) p. 586, which are particularly This is incorporated as a reference. The term "inorganic material π" used herein means any material that is not an organic material. The term "composite material" used herein means a combination of two or more different materials. Particles formed from a composite material usually have a surface different from The hardness of the internal hardness of the particles below its surface. More particularly, the surface of the particles can be modified by any method known in the art, including but not limited to using techniques known in this technology to chemically or physically change the surface characteristics of the particles such that -17- This paper size applies to Chinese National Standard (CNS) A4 (21〇χ 297 public love) Please read the notes on the back first

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Corruption and Economics 1230698 A7 V. Description of the invention (l5) The surface hardness is equal to or less than the hardness of glass fiber, and the surface hardness is greater than the hardness of glass fiber. For example, granules may be formed from a first material, coated, protected, or packaged with one or more second materials to form particles with a softer surface. In another alternative embodiment, the particles formed of the composite material may be formed from ~ a material, which is coated, protected or encapsulated in the form of unpleasant * ~ 罘-material. For more information on the particles used in the present invention, see G. Wypych ^ Handk00k ^. FilI ^, 2nd edition (1999), page, which is specifically incorporated herein by reference. Representative non-polymeric inorganic materials used to form particles 18 of the present invention include those selected from the group consisting of graphite, metal, oxide, carbide, nitride, pendant, sulfide, silicate, carbonate, sulfate, and hydroxide Inorganic materials: A non-limiting example of a suitable inorganic nitride that forms the particles 18 is boron nitride, which is a preferred embodiment of the present invention. Boron nitride having a hexahedral crystal structure is particularly preferred. A non-limiting example of a useful inorganic oxide is zinc oxide. Suitable inorganic sulfides include molybdenum disulfide, button disulfide, tungsten disulfide, and zinc disulfide. Useful inorganic silicates include aluminum silicate and magnesium silicate, such as vermiculite. Suitable metals include molybdenum, platinum, free, nickel, Ming, copper, gold, iron, silver, any of the above alloys and mixtures. In a non-limiting embodiment of the invention, the particles 18 are formed from a solid lubricant material. The term "solid lubricant" as used herein means any solid used between two surfaces to provide protection from damage during relative movement and / or reduce friction and wear. In a specific embodiment, a solid lubricant It is an inorganic solid lubricant. As used herein, "inorganic solid lubricant" means that a solid lubricant has the characteristic crystallization habit of causing it to cut into thin, flat plates, which is easy to use.-This paper size applies to Chinese National Standards (CNS) A4 size (210 X 297 mm) (Please read the notes on the back before filling this page)

-------- Order --------- Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 1230698 A7 _B7____ V. Description of the Invention 〇6) Slide on each other, so the fiber surface (preferably Glass fiber surface) and anti-friction lubrication effect between adjacent solid surface, at least one of which moves. See R. Lewis, Sr., Hawlev, Condensed Chemical Dictionary. (12th edition, 1993) at page 712, which is specifically incorporated herein by reference. Friction is the resistance of solids to sliding against each other. F. clauss, Solid Lubricants and Self-Lubricating Solids (1972), page 1, which is specifically incorporated herein by reference. In a non-limiting embodiment of the present invention, the particles 18 have a thin flat structure. The particles having a thin flat structure are composed of atomic sheets or plates of a hexahedral array, which have strong bonds in the sheets and weak Van der Waals bonds between the sheets, and provide low shear strength between the sheets. A non-limiting example of a thin flat structure is a hexahedral crystal structure. K. Ludema, Friction, Wear, Lubrication (1996) p. 125, Solid Lubricants and Self-Lubricating Solids 19-22, 42-54, 75-77, 80-81, 82, 90-102, 113-120 and 128; and " Solid Lubricants " by W. Campbell, Boundary Lubrication: An Appraisal of World Literature. ASME Research Committee on Lubrication (1969), pages 202-203, which are specifically incorporated herein by reference. Inorganic solid particles having a thin flat fullerene (large sphere) structure can also be used in the present invention. Non-limiting examples of suitable materials having a thin flat structure that can be used to form the particles 18 of the present invention include boron nitride, graphite, metal dichalcogenides, mica, talc, gypsum, kaolin, calcite, cadmium iodide, silver sulfide, and A mixture of any of the above. Preferred materials include boron nitride, graphite, metal dichalcogenides, and mixtures of any of the above. Applicable metal dichalcogenide -19 · This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) Please read the notes on the back first

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the People's Republic of China 1230698 A7 B7 V. Description of the invention (17) Compounds include molybdenum disulfide, molybdenum diselenide, light disulfide, dimagnetized Zhao, tungsten disulfide, tungsten diselenide, and A mixture of any of the above. In a specific embodiment, the particles 18 are formed of an inorganic solid lubricant material having a thin flat structure. A non-limiting example of an inorganic solid lubricant material having a thin flat structure for use in the coating composition of the present invention is boron nitride, preferably boron nitride having a hexahedral crystal structure. Particles formed from boron nitride, zinc sulfide, and microcrystalline kaolinite also provide good whiteness in composites with a polymeric matrix material such as nylon 6,6. Non-limiting examples of particles formed from boron nitride suitable for use in the present invention are POLARTHERM® 100 series 歹 ij (PT 120, PT 140, PT 160 and PT 180); 300 series (PT 350) and 600 series (PT 620 , PT 630, PT 640, and PT 670) boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. " PolarTherm® Thermally Conductive Fillers for Polymeric Materials · ', Technical Bulletin of Advanced Ceramics Corporation, Lakewood, Ohio (1996), which is specifically incorporated herein by reference. These particles have a temperature of 25 ° C per meter. K 250-300 watts of heat transfer, a dielectric constant of 3.9 and a volume resistivity of 1015 ohm-cm. 100 series powder particles have an average particle size ranging from 5 to 14 microns, 300 series powder particles have an average particle size ranging from 100 to 150 microns, and 600 series powder particles have an average particle size ranging from 15 to more than 200 microns. In particular, as reported by its suppliers, POLARTHERM 160 particles have an average particle size of 6 to 12 microns, a particle size range of sub-microns to 70 microns, and the following particle size distribution: -20- This paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) Please read the notes on the back first

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 Α7 Β7 V. Description of invention (i8)% 10 50 90 Size (micron :) 18.4 7.4 0.6 According to this distribution, 10% of the measured POLARHERM® 160 boron nitride particles have Average particle size greater than 18.4 microns. As used herein, "average particle size π" refers to the average particle size of the particles. The average particle size of the particles according to the invention can be measured according to known laser scattering techniques. In a non-limiting specific embodiment of the invention, the particle size is measured using a Beckman Coulter LS 230 laser diffraction particle sizer, which uses a laser beam with a wavelength of 750 nm to measure the particle size, and assuming that the particles have a spherical shape, that is, π refers to the smallest pellet that completely encapsulates the pellet. For example, the particles of POLARHERM® 160 boron nitride particles measured using a Beckman Coulter LS 230 particle size analyzer have an average particle size of 11.9 microns, the particle range is from submicrons to 36 microns, and have the following particle distribution:% 10 50 90 size ( Micron) 20.6 11.3 4.0 According to this distribution, the POLARHERM⑧160 boron nitride particles are measured at 10 ° /. Has an average particle size greater than 20.6 microns. In another non-limiting embodiment of the invention, the particles 18 are formed of a non-hydratable inorganic material. As used herein, '' non-hydratable 'means that the inorganic particles do not react with water to form a hydrate, and do not contain water of hydration or crystallization. "Hydrate π is based on water molecules and substances in which the H-0H bond does not break. -21-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before reading) (Fill in this page) -------- Order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 ___B7___ V. Description of Invention (l9) Reaction Manufacturing 0 See R · Lewis Hawley's Condensed Chemical Dictionary. (12th edition, 1993), pages 609-610, and S. Perros, Chemistry. (1967), pages 186-187, which are specifically incorporated herein by reference. In the formula, the addition of water molecules is represented by a central point, for example, 3MgO * 4Si〇2 * H2〇 (talc), Al2O3.2SiO2.2H2O (kaolin). Structurally, the hydratable inorganic material is in a layer The crystal lattice includes at least one hydroxyl group (but does not include hydroxyl groups on the surface plane of the unit structure of a material that absorbs water by capillary action on its surface plane), for example, such as J. Mitchell's Fundamentals of Soil Behavior (1976), page 34, page 34 The structure of kaolin shown in Figure 3.6 and As shown in the structure of the 1: 1 and 2: 1 layers of minerals shown in Figures 18 and 19 on page 62 of H. van Olphen, Clav Colloid Chemistry. (2nd edition, 1977), which is specifically incorporated herein as Reference. A " layer " Combination 0 of a lattice (a combination of atomic planes) of a sheet (see Minerals in Soil Environments. Soil Science Society of America (1977) pages 196-199, which are specifically incorporated herein (For reference). The aggregation of layers and interlayer materials (such as cations) is called the unit structure. Hydrates contain coordination water, which coordinates the cations in the hydrated material without the structure and / or structured water (which occupies the structure) The gaps are removed by increasing the electrostatic energy without disrupting the charge balance). R. Evnas Μ Introduction to Crvstal Chemistrv Π948) page 276, which is specifically incorporated herein by reference. Generally, the coating composition contains no more than 50 % By weight of hydratable particles. In a non-limiting embodiment of the present invention, the coating composition is preferably essentially free of hydratable particles. The term π used herein is essentially free of hydratable particles " indicates a coating composition Thing Containing less based on the total solids of this paper -22- scale applicable Chinese National Standard (CNS) A4 size (210 X 297 mm) please first read the note on the back of reading matter

Page Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7

5. Description of the invention (20) The hydratable particles at 20 wt.% / 0, more preferably less than 5 wt.%, And most preferably less than 0.001 wt.%. In a specific embodiment of the invention, the particles 18 are formed of a non-hydratable inorganic solid lubricant material. In place of or in addition to the non-hydratable inorganic materials discussed above, the coating composition according to the present invention may contain particles formed from hydratable or hydrated inorganic materials. Non-limiting examples of such hydratable inorganic materials are clay ore phyllosilicates, which include mica (such as muscovite), talc, microcrystalline kaolinite, kaolin, and gypsum. As explained above, the particles formed from such hydratable or hydrated inorganic materials usually have a composition not exceeding 50% by weight of the particles in the coating composition. In another embodiment of the present invention, the particles 18 may be non-polymeric Organic materials are formed. Non-polymeric organic materials useful in the present invention include, but are not limited to, stearates (such as zinc stearate and aluminum stearate), carbon black, and stearylamine. Printed by the Consumer Affairs Agency of the Intellectual Property Office of the Ministry of Economic Affairs. In another embodiment of the present invention, the particles 8 may be formed of an inorganic polymer material. Non-limiting examples of useful inorganic polymeric materials include polyphosphine, polysilane, polysiloxane, polygermane, polysulfide, polyselenium, polysiloxane, and mixtures of any of the above. A specific, non-limiting example of particles formed from an inorganic polymeric material suitable for use in the present invention is TOSPEARL4, which is a particle formed from a cross-linked siloxane, and is commercially available from Toshiba Polysilicon, Japan. In another embodiment of the invention, the particles 18 may be formed from a synthetic organic polymeric material. Suitable organic polymeric materials include, but are not limited to, thermoset materials and thermoplastic materials. Suitable thermosetting materials include thermosetting polyesters, vinyl esters, epoxy materials, phenolic, amine-based plastics, thermosetting polyamines 23-1230698 A7 B7 5. Description of the invention (21 formate, and any mixture of the above. A specific, non-limiting example of a preferred synthetic polymeric particle formed from an epoxy material is an epoxy microgel particle. Please read the precautions on the back before filling out this page. The Ministry of Economic Affairs, Intellectual Property Bureau, Employee Consumer Cooperatives, and other suitable thermoplastic materials include thermoplastic polymers. Esters, polycarbonates, polyolefins, propylene polymers, polyamides, thermoplastic polyurethanes, vinyl polymers, and mixtures of any of the above. Preferred thermoplastic polyesters include, but are not limited to, polyphthalic acid. Ethyl esters, polybutylene terephthalate and polybutylene terephthalate. Preferred polyolefins include, but are not limited to, polyethylene, polypropylene, and polyisobutylene. Preferred acrylic polymers include phenethylpyrene and propylpyrene Copolymers of acid monomers and polymers containing fluorinated propionic acid. A non-limiting example of synthetic polymeric particles formed from propylene copolymers is RHOPLEX® B-855, which is impervious Non-crosslinked solid propylene particle emulsion, ROPAQUE® HP-10556, an opaque, non-film-forming styrene-propylene polymer synthetic pigment with a particle size of 1.0 micron, a solid content of 26.5% by weight and a pore volume of 55%, ROPAQUE® OP-967 With ROPAQUE® HP-543P8, it is the same opaque, non-film-forming styrene-propylene polymer synthetic pigment dispersion with a particle size of 0.5.5 microns and a solid content of 30.5% by weight, and ROPAQUE® OP_62 L09, which also has a particle size of 0.40 microns And an opaque, non-film-forming styrene-propylene polymer synthetic pigment dispersion with a solid content of 36.5% by weight. Each designated particle is commercially available from Rohm and Haas Company of Philadelphia, PA. 4 See " Applications for Cross-Linked by R. J_ Perry Siloxane Particles " Chemtech · February 1999, pages 39-44. 5 See " Chemicals for the Textile Industry " available from Rohm and Haas, Philadelphia, Pennsylvania, September 1987. 6 See Rohm, available from Philadelphia, Pennsylvania and Haas company's product nature sheet, -24 · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A 7 B7 V. Description of the Invention (22) Title ... "ROPAQUE® HP-1055, Hollow Sphere Pigment for Paper and Paperboard Coatings" October 1994, page 1, which is incorporated herein by reference. 7 See product technical bulletin from Rohm and Haas, Philadelphia, PA, title: " Architectural Coatings- ROPAQUE® OP-96 · The All Purpose Pigment · 1 April 1997, page 1, which is incorporated herein by reference Reference. 8 ROPAQUE® HP-543P and ROPAQUE® OP-96 are the same material; this material is considered ROPAQUE® HP-543P in the paint world and ROPAQUE® OP-96 in the coating world. 9 See product technical bulletin from Rohm and Haas, Philadelphia, PA, title: " Architectural Coatings- ROPAQUE® OP-96 · The All Purpose Pigment " April 1997, page 1, which is hereby incorporated as reference. The particles 18 according to the invention may also be formed from semi-synthetic organic polymeric materials and natural polymeric materials. "Semi-synthetic materials" used herein are chemically modified naturally occurring materials. Suitable semi-synthetic organic polymeric materials from which particles 18 can be formed include, but are not limited to, cellulose, such as methyl cellulose and cellulose acetate; and modified starches, such as starch acetate and starch hydroxyethyl ether. Suitable natural polymeric materials from which particles 18 can be formed include, but are not limited to, glycans, such as starch; polypeptides, such as casein; and natural hydrocarbons, such as natural rubber and gutachal. In a non-limiting embodiment of the present invention, the polymeric particles 18 are formed of a hydrophobic polymeric material to reduce or limit water absorption by the coating strand. Such a -25- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public love) (Please read the precautions on the back before filling this page) -------- Order --- ------ line; printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 B7 V. Description of the Invention (23) Non-limiting examples of water-based polymer materials include, but are not limited to, polyethylene, polypropylene, polystyrene, and poly Methyl methacrylate. Non-limiting examples of polystyrene copolymers include ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62 L0 pigments (as discussed above). In another non-limiting embodiment of the present invention, the polymeric particles 18 are formed of a polymeric material having a glass transition temperature (Tg) and / or melting point of greater than 25 ° C and preferably greater than 50 ° C. In another non-limiting embodiment of the present invention, the particles 18 may be hollow particles formed of a material selected from the group consisting of polymeric and non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and any combination thereof. Non-limiting examples of suitable materials from which hollow particles are formed are as described above. Non-limiting examples of hollow polymeric particles used in the present invention are ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62LO pigments (as discussed above). For other non-limiting examples of hollow particles used in the present invention, see H. Katz et al. (Eds.) (1987) at 437-452, which is specifically incorporated herein by reference.

The particles 18 used in the coating composition of the present invention may be a dispersion, suspension or emulsion in water. If desired, other solvents, such as mineral oil or alcohol (preferably less than 5% by weight) may be included in the dispersion, suspension, or emulsion. A non-limiting example of a preferred dispersion of particles formed from inorganic materials is ORPAC BORON NITRIDE RELEASECOAT-CONC, which is a 25% by weight dispersion of boron nitride particles in water, and is commercially available from ZYP Coatings, Oak Ridge, Tennessee the company. " ORPAC BORON -26-This paper size applies to Chinese National Standard (CNS) A4 (210 χ 297 mm) (Please read the precautions on the back before filling this page) -IIIIIII Order----I! * 5 ^ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, 1230698 A7 ___B7__ V. Description of Invention (24) NITRIDE RELEASECOAT-CONC ", the technical bulletin of ZYP Coatings, specifically incorporated herein by reference. According to this technical bulletin, this product The boron nitride particles have an average particle size of less than 3 microns and include 1% magnesium-aluminosilicate to adhere the boron nitride particles to the dispersion-coated substrate. ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Nitriding Independent testing of boron using a Beckman Coulter LS 230 particle size analyzer found an average particle size of 6.2 microns, with particle sizes ranging from sub-microns to 35 microns, and having the following particle distribution: Please read the precautions on the back first

Greed 10 50 90 Size (micron) 10.2 5.5 2.4 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs according to this distribution, 10% of the measured ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles have an average greater than 10 · 2 microns granularity. Other commercially available products from ZYP Coatings include BORON NITRIDE LUBRICOAT® coatings, and BRAZE STOP and WELD RELEASE products. Specific non-limiting examples of emulsions and dispersions of synthetic polymeric particles formed from propylene polymers and copolymers include: RHOPLEX® B-85 propylene emulsion (as discussed above), RHOPLEX® GL-62310, which has 45% by weight Full propylene hard polymer emulsion with solid content and glass transition temperature of 98 ° C; EMULSIONE-232111, which is a hard methylpropionate polymer with a solid content of 45 weight ° / 〇 and a glass transition temperature of 105 ° C Emulsion; ROPAQUE® OP-96 and ROPAQUE® HP-543P (such as -27- this paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 1230698 printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs B7 V. Invention description (discussed in (25)), which is supplied as a dispersion with a particle size of 0.55 micron and a solid content of 30.5% by weight; ROPAQUE® OP · 62 LO (as discussed above), which has 0 · 40 micron particle size and 36.5% by weight solids dispersion; and ROPAQUE® HP-1055 (as discussed above), which is supplied as a dispersion with 26.5% by weight solids content; all commercially available from Philadelphia's Rohm and Haas Company. 10See the property sheet from Rohm and Haas, Philadelphia, PA, heading: "Rhoplex® GL-623, Self-Crosslinking Acrylic Binder of Indrustrial Nonwovens", March 1997, which is incorporated herein by reference. 11 See the property sheet from Rohm and Haas, Philadelphia, PA, titled: " Building Products Industrial Coatings- Emulsion E-2321, f, 1990, which is incorporated herein by reference. Particularly preferred embodiments of the present invention In the examples, the coating composition includes at least one inorganic particle (especially boron nitride, and more specifically a nitriding test obtained under the brand name POLARTHERM® and / or ORPAC BORON NITRIDE RELEASECOAT-COMC) and at least one thermoplastic material ( Especially copolymers of styrene and propylene monomers, and more specifically mixtures of copolymers obtained under the trade name ROPAQUE (R). Particles 18 are selected to obtain an average particle size 19 sufficient to achieve the required spacing between adjacent fibers. For example, The average particle size 19 of the particles 18 added to the sizing composition (which is coated on the fibers 12 treated in an air jet loom) is preferably selected, Provide space between at least two adjacent fibers sufficient for air jet transport of 10 strands of fiber through the loom. “Air Jet Weaving Fabric-28” used here-This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back before filling this page)

1230698 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (26) The machine "indicates that the yarn filling (weft yarns) ) The weaving pattern of the fabric inserted into the warp shed. In another example, the particle size 19 of the particle M added with the sizing composition (coated on the fiber 12 impregnated with the polymeric matrix material) is selected to be at least The space between two adjacent fibers is sufficient to wet and soak the fiber strands 10 well. Although not limiting the present invention, the particles 18 preferably have an average particle size of more than 1000 microns measured using laser scattering technology, and more preferably An average particle size of 0.001 to 100 microns, and most preferably 25 microns. In a specific non-limiting embodiment of the present invention, the average particle size 19 of the particles 18 is at least 01 microns, preferably at least 0.05 microns, and The range is from 0.1 micrometers to 5 micrometers, and preferably G 5 micrometers to 2 micrometers. In this example, the particles 18 have an average of the fibers 12 that are usually coated more than the coating composition. straight Small average particle size 19. It has been observed that interlaced yarns made from fiber strands 10 having a layer of 14 first sizing composition (containing particles 18 having an average particle size 19 discussed above) residues are polymerized based on the base material In the case of a secondary collapse, it is advantageous to provide sufficient air-jet weaving power between adjacent fibers 23, 25 (that is, air-jet transport through the loom), while holding the integrity of the fiber strand 10 and providing Accepts the interval of wet through and wetness characteristics. In another specific non-limiting embodiment of the present invention, the average particle size 19 of the particles 18 is at least 3 microns, preferably at least 5 microns, and ranges from 3 microns to 100. Micron, preferably from $ μm to 1000 μm, and from 10 to 25 μm. In this specific embodiment, it is also preferred that the particle L · ------ 29 Fresh (CNS) k4 specification (210 X 297 mm) ---- (Please read the precautions on the back before filling out this page) »: Fill in the filling — — — — — — — — ---- III — — 0 1230698 A7 B7

V. Description of the invention (average particle size 19 of η 18 is roughly equivalent to the average nominal diameter of glass fibers. It has been observed that when impregnated with a polymeric matrix material, fabrics made with particle strands within 1% of the above size appear good. Wetting and wetting characteristics. Those skilled in the art will appreciate that a mixture of one or more particles 18 having different average particle sizes 19 may be added to the coating composition according to the present invention to impart fiber strands 10 and then The quality and processing characteristics required for products made therefrom. More particularly, particles of different sizes can be combined in appropriate amounts to provide strands with air jet transport properties, and to provide fabrics that exhibit good wet through and wet characteristics. Fibers are abraded due to contact with the rough surfaces of adjacent solid and / or glass fibers during the formation and subsequent processing (such as weaving or spinning) of other solid objects or materials. As used herein, "wear" means The friction contacts the particles, edges or whole of the material that is hard to damage the fiber, while scraping or cutting a little fiber surface or breaking the fiber. See K ^ Ludema, page 129, In particular, it is incorporated herein as a reference. The abrasion of the strands has a deleterious effect on the fiber strands, such as the strands being broken during processing and the products such as woven fabrics and composites: surface: depression, which increases waste and manufacturing costs. The Intellectual Property Bureau employee consumer cooperative prints during the forming step, for example, fibers, especially glass fibers, are contacted with solid objects such as metal collection blocks and moving tables or coil springs before being wound into a package. In fabric assembly operations, If knitting or weaving, the glass fiber strand contacts an object such as a fiber assembly (e.g., a loom or knitting device), which wears the surface M of the glass fiber 12 in contact. The fiberglass loom that contacts the glass fiber Some examples include air jets and weaving shuttles. The rough surface of these solid objects with a hardness greater than that of glass fiber can cause glass

1230698

V. Description of the invention (28) Many parts of the glass fiber woven frame, loom, and knitting device are formed of a metal material such as steel, which has a Mohs hardness of 85i2. The abrasion of the glass fiber strands due to the rough surface contacting these concrete objects causes the strands to be broken during processing and surface defects of products such as woven fabrics and composites, which increase waste and manufacturing costs. '12 Handbook of Chemistry and Physics on page F-22. In order to minimize abrasion, in a non-limiting embodiment of the present invention, the particles 18 have a hardness 値 not exceeding (i.e., less than or equal to) the hardness 値 of the broken glass fiber. The hardness 値 of the particles and glass fibers can be measured by any conventional hardness measurement method, such as Vickers or Brine 丨 丨, but it is preferably measured according to the original Mohs hardness scale, which indicates that the surface of the material is relatively resistant from 丨 to 10 Sex. The Mohs hardness 値 of glass fiber is usually 45 to 65, and is usually 6. Handbook of Ch ^ ietrv and £ 11 ^ by R. Weast (editor), 0 foot 0? 1 ^ 8 (1975) p. 22, which is specifically incorporated herein by reference. In this specific embodiment, the particle 18 Mohs hardness 値 is preferably in the range of 0.5 to 6. The Mohs hardness of many non-limiting examples of particles formed from inorganic materials suitable for use in the present invention is shown in Table A below. (Please read the notes on the back before filling this page)

-------- Order --------- Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7B7 V. Description of the invention (29) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics A. Mohs hardness of granular materials, (original scale) Boron nitride 213 Graphite 0.5-114 Molybdenum disulfide I15 Talc 1.1.516 Mica Kaolin 2.0-2.518 gypsum 1.6-219 calcite (calcium carbonate) 320 calcium fluoride 421 zinc oxide 4.522 aluminum 2.523 copper 2.5-324 iron 4-525 gold 2.5-326 nickel 527! Bar 4.828 platinum 4.329 silver 2.5-430 zinc sulfide 3.5- 431 13 K. Ludema, Friction. Wear, Lubrication, (1996) page 27, its -32- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 4 (Please read the note on the back first Please fill in this page again for matters) 1230698 Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (30) is incorporated herein by reference. 14 R. Weast (editor), Handbook of Chemistry and Physics. CRC Press (1975) at F-22. 15 R. Lewis, Sr., Hawlev's Condensed Chemical Dictionary, (12th edition 1993) p. 793, which is incorporated herein by reference. 16 Hawley ^ Condensed Chemical Dictionary. (12th edition 1993) p. 1113, which is incorporated herein by reference. 17 Hawley's Condensed Chemical Dictionary, (12th edition 1993) p. 784, which is incorporated herein by reference. 18 Handbook of Chemistry and Physics on page F-22. 19 Handbook of Chemistry and Physics on page F-22. 20 Friction, Wear. Lubrication p. 27. 21 Friction. Wear. Lubrication p. 27. 22 Friction, Wear. Lubrication p. 27. 23 Friction, Wear. Lubrication p. 27. 24 Handbook of Chemistry and Physics on page F-22. 25 Handbook of Chemistry and Physics, page F-22. 26 Handbook of Chemistry and Physics, page F-22. 27 Handbook of Chemistry and Physics, page F-22. 28 Handbook of Chemistry and Physics, page F-22. 29 Handbook of Chemistry and Physics, page F-22. 30 Handbook of Chemistry and Physics, page F-22. 31 R. Weast (editor), Handbook of Chemistry and Physics, CRC Press (71st Edition 1990), p. 4-158. -33- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1 ---------- ^ installed -------- order ------ --- line j (please read the precautions on the back before filling in this page) 1230698 Surface or package, the particles can be the first surface or package, A7 V. Description of the invention (31) As mentioned above, the Mohs hardness scale is related Material · Lamp &h; scratchability. The present invention is therefore more intended to have particles having a hardness on the surface which is different from the surface hardness of the particles. More specifically, and as discussed above, the surface of the particles can be modified by any method known in the art, including Θ, including but not limited to chemically changing the surface characteristics of the particles using techniques known in this technology, so that the surface of the particles The hardness is less than or equal to the hardness of the glass fiber, and the hardness of the particles under the surface is greater than the hardness of the glass fiber. As another alternative, particles may be formed from a first material ' which is coated with one or more second materials to form a composite material having a softer surface. Or Material Forming 'which is coated with a first material in a different form to form a composite material with a softer surface. In examples, and without limiting the invention, inorganic particles formed from inorganic materials such as silicon carbide or aluminum nitride may have silica, carbonate or nanoclay to form useful composite particles. In another non-limiting example, a silane coupling agent with an alkyl side chain can react the surface of inorganic particles 2 formed from an inorganic oxide to provide useful composite particles having a " softer " surface. Other examples include surfaces, envelopes or coated particles formed from a non-polymeric or polymeric material and a different non-polymeric or polymeric material. A specific, non-limiting example of such composite particles is DUALITE, a synthetic polymeric particle coated with calcium carbonate, commercially available from Pierce and Stevens, Buffalo, NY. In a specific embodiment of the invention, the particles 18 are thermally conductive, i.e., preferably have a thermal conductivity of at least 0.2 watts per meter κ, more preferably at least 0.5 watts per meter K at a temperature of 300K. In a non-limiting specific embodiment, the particle u has a temperature of 300K measured at least i watts per meter, more preferably -34-meter per meter. Applicable to China National Standard (CNS) A4 specifications (210 X 297). I (Please read the precautions on the back before filling out this page) -------- Order --------- line "Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698

Description of the invention (32 Heat transfer of at least 5 watts. In a preferred embodiment, the thermal conductivity of the particles is measured at a temperature of 300K to be at least 25 watts per meter, more preferably at least 30 watts per meter, and even More preferably, it is at least 100 watts per meter. In another preferred embodiment, the thermal conductivity of the particles is measured at a temperature range of 300 κ from 5 to 2000 watts per meter, preferably κ 25 per meter. To 2000 watts, more preferably 30 to 2,000 watts per meter, and most preferably 100 to 2000 watts per meter κ. The thermal conductivity used herein refers to its ability to describe its heat transfer by itself The granular nature. See H. Lev., Con. R. Lewis, Sr., Condensed Chemical Dictionary, (12th edition, 1993), p. 305, which is specifically incorporated herein by reference. Materials printed by employees of the Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Cooperative The thermal conductivity can be measured by any method known to those skilled in the art. For example, if the thermal conductivity of the material being tested ranges from κ 0.001 watts per meter to 100 watts per meter, then the temperature can be 300K according to ASTM C-177 -85 (which is specifically incorporated herein by reference) is preferred The thermal conductivity of the material is measured by the off-plate method. If the thermal conductivity of the material under test ranges from κ 20 watts per meter to 1200 watts per meter, it may be in accordance with ASTM C-518-91 (which is specifically incorporated herein by reference ) Use the isolated heat flux induction method to measure the thermal conductivity of the material. In other words, if the thermal conductivity ranges from 0.001 watts per meter to 20 watts per meter K, use the isolated heating plate method. If the thermal conductivity ranges from more than 100 K per meter Watt, use the isolated heat flux induction method. For the range of 20 to 100 watts per meter, either method can be used. In the isolated heating plate method, one with an isolated heating unit, two auxiliary heating plates, two Cooling unit, edge insulation, temperature control second isolation, and temperature sensor reading system of the isolation heating plate device, test two -35-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) &quot; &quot; '1230698 A7 B7 V. Description of the invention (33 Essentially the same sample. Place the detailed liver sample on either side of the isolation heating unit, the opposite surface of the sample P mouth contacts 4 pills,, and w. Susuke Early position. Then heat the device to the required test temperature and keep getting enchanted in time. <Once the steady state condition is reached, record the g σΑ, k-like ice flow with the hammer. (Q) and the temperature of the sample (ΔΤ). Then use the following formula (I) to calculate the average thermal conductivity (Ktc) of the sample:

Ktc = ql / A * AT where L is the average thickness of the sample and A is the average of the combined area of the sample. According to L, the material with higher thermal conductivity dissipates quickly in the hole area during the operation of Jidong, generating the certificate mutual,… to become a long-term drill brother. The thermal conductivity of selected materials in Table A is included in Table B. Alternative Although Not Necessary 'In another embodiment of the present invention, the q particles are electrically insulated or have a high resistivity, that is, a resistivity greater than 100 cm. For conventional electronic circuit board applications, use high-resistance (preferably particles to suppress signal loss due to conduction of electrons through reinforced materials. Materials are expected to be used in money stoves, non-interference and electromagnetic interference-free applications. No particles with high resistivity are required. The resistivity of the selected materials in Table A is included in Table B. Ordered by electricity and electricity I_ 36-Dimensions China Fresh (cns) A4 1230698 A7 B7 V. Description of the invention (34) Table B Thermal conductivity of inorganic solid materials Mohs hardness (IN / mK at 300K) (micro-ohm-cm) (original scale) Boron nitride 20032 1.7 X 1〇1933 234 Boron phosphide 35035 9.536 Aluminum phosphide 13037 • Aluminum nitride 20033 greater than 101939 940 gallium nitride 17041 • gallium phosphide 10042 silicon carbide 27043 4 X 105 to 1 X 1〇644 larger than 945 silicon nitride 3046 1109 to 102047 948 barium oxide 24049 _ 950! ---- I ----- 丨 Repair · II (Please read the precautions on the back before filling this page) I. 32 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs Chem. Solids (1973, Vol. 34, Page 322, which is incorporated herein by reference. 33 A. Weimer (editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) at 654. 34 Friction, Wear, Lubrication at 27. 35 G. Slack, MNonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (1973 ^ Vol. 34, p. 325, which is incorporated herein by reference. R. Lewis, Sr., Hawlev's Condensed Chemical Dictionary · (p.l2 Edition l &quot; 3) page 104, which is incorporated herein by reference. -37- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)-丨 Line: Consumption by Employees, Bureau of Intellectual Property, Ministry of Economic Affairs Printed by the cooperative 1230698 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of invention (35) 37 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J Phvs. Chem. Solids Π973) Vol. Page 333, which is incorporated herein by reference. 38 G. Slack, ^ Nonmetallic Crystals with High Thermal Conductivity, J. Phvs · Chem. Solids (1973, Vol. 34, p. 329, which is incorporated herein by reference. 39 A. Weimer (editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 654. 40 Friction, Wear. Lubrication p. 27. 41 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem · Solids Π973, Vol. 34 , Page 333. 42 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π973 ^ Volume 34, page 321, which is incorporated herein by reference. 43 Microelectronics Packaging Handbook No. 3th 44 A. Weimer (editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 653, which is incorporated herein by reference. 45 Friction. Wear. Lubrication p. Page 27. 46 Microelectronics Packaging Handbook Page 3ό, which is incorporated herein by reference. 47 A. Weimer (editor), Ca rbide, Nitride and Boride Materials Synthesis and Processing, (1997) page 654 0 -38- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling in this page)

-Install -------- Order --------- Line L 1230698 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (36) 48 Friction. Wear. Lubrication No. 27 page. 49 Microelectronics Packaging Handbook on page 905, which is incorporated herein by reference. 50 Hawley's Condensed Chemical Dictionary, (12th edition 1993) p. 141, which is incorporated herein by reference. Table B (continued) Thermal conductivity of inorganic solid materials (IN / mK at 300K) Resistance (microohm-cm) Mohs hardness (original scale) Zinc oxide 26 4.551 Zinc sulfide 2552 2.7 X 105 to 1.2 X 1〇1253 3.5- 454 Diamond 230055 2.7 X 105 55 1057 Silicon 8458 10.059 ^ 60 Graphite up to 200061 10062 0.5-163 Molybdenum 13864 5.265 5.566 Ship 6967 10.668 4.369 Shba 7〇70 10.871 4.872 Tungsten 20073 5.574 7.575 51 Friction · Wear · Lubrication% 27 pages . 52 Handbook of Chemistry and Physics. CRC Press (1975) pp. 12-54. 53 Handbook of Chemistry and Physics, CRC Press (71st Edition 1 &quot; 0) at page 12 · 63, which is incorporated herein by reference. -39- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). --- Line j (Please read the notes on the back before filling this page) 1230698 Printed by A7 B7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs, V. Invention Note (37) 54 Handbook of Chemistry and Physics. CRC Press (p. 71 Edition 1990) pp. 4-158, which is incorporated herein by reference. 55 Microelectronics Packaging Handbook page 3. 56 Handbook of Chemistry and Physics. CRC Press (71st Edition 1990) page 12.63, which is incorporated herein by reference. 57 Handbook of Chemistry and Physics, page F_22. 58 Microelectronics Packaging Handbook p. 174. 59 Handbook of Chemistry and Physics, page F-166, which is incorporated herein by reference. 60 Friction, Wear, Lubrication p. 27. 61 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (^ 1973 ^ Vol. 34, p. 322, which is incorporated herein by reference. 62 See W. Callister, Materials Science and Engineering An Introduction, (2nd edition 1991) p. 637, which is incorporated herein by reference. 63 Handbook of Chemistry and Physics. P. F-22. 64 Microelectronics Packaging Handbook p. 174. 65 Microelectronics Packaging Handbook p. 37 66 According to &quot; Web Elements'1 http://www.shef.ac.uk/~chem/web·elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998 "67 Microelectronics Packaging Handbook, page 174. 68 Microelectronics Packaging Handbook, page 37. -40- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm); ------- Line j (Please read the precautions on the back before filling out this page) 1230698 Printed by A7 B7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs V. Invention Description (38) 69 Handbook of Chemistry and Physics. F-22 Page 70 Handbook of Chemistry and Physics, page 37. 71 Microelectronics Packaging Handbook page 37. 72 Handbook of Chemistry and Physics. Page F-22. 73 Handbook of Chemistry and Physics. Page 37. 74 Microelectronics Packaging Handbook page 37 pages. 75 According to &quot; Web Elements'1 http://www.shef.ac.uk/~chem/web-elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998 ) 0 Table B (continued) Thermal conductivity of inorganic solid materials (W / mK at 300K) Resistance (micro-ohm-cm) Mohs hardness (original scale) Nickel 9276 6.877 578 Aluminum 20579 4.380 2.581 Chrome 6682 2083 9.084 Copper 39885 1.786 2.5 -387 Gold 29788 2.289 2.5-390 Iron 74.591 992 4-593 Silver 41894 1.695 2.5-496 76 Microelectronics Packaging Handbook page 174 〇77 Microelectronics Packaging Handbook page 37. 78 Handbook of Chemistry and Physics, page F-22. -41- This paper is compliant with China National Standard (CNS) A4 (210 x 297 mm) (Please read the notes on the back before filling this page)

1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (39) 79 Microelectronics Packaging Handbook p. 174. 80 Microelectronics Packaging Handbook p. 37. 81 Friction. Wear. Lubrication p. 27. 82 Microelectronics Packaging Handbook p. 37. 83 Microelectronics Packaging Handbook p. 37. 84 Handbook of Chemistry and Physics, page F-22. 85 Microelectronics Packaging Handbook p. 174. 86 Microelectronics Packaging Handbook p. 37. 87 Handbook of Chemistry and Physics, page F-22. 88 Microelectronics Packaging Handbook p. 174. 89 Microelectronics Packaging Handbook p. 37. 90 Handbook of Chemistry and Physics. Page F-22. 91 Microelectronics Packaging Handbook p. 174. 92 Handbook of Chemistry and Physics. CRC Press (1975) at page D-171, which is incorporated herein by reference. 93 Handbook of Chemistry and Physics. Page F-22. 94 Microelectronics Packaging Handbook p. 174. 95 Microelectronics Packaging Handbook p. 37. 96 Handbook of Chemistry and Physics. Page F-22. Those skilled in the art will appreciate that the particles 18 of the coating composition of the present invention may include any combination or mixture of particles 18 discussed above. More particularly, and without limiting the invention, the particles 18 may include any combination of additional particles made from any of the foregoing materials. Therefore, all the particles 18 need not be the same; they may be chemically different and / or chemically the same but the configuration or -42- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please (Read the notes on the back before filling out this page)

1230698 A7 V. Description of the invention (40 The properties are the same. The extra particles usually contain at most one-half of the particles 18, preferably 15% of the particles at most. In the known examples, the particles include coatings based on the total solids. _ To 99% by weight of the layer composition, preferably 50 to 99% by weight, and more preferably 75 to 99% by weight. In this embodiment, a particularly good coating includes, but is not limited to, 1) containing an organic component And a coating of thin flat particles having a thermal conductivity of 300 to κ per meter at a temperature of 300 κ; η) a coating containing organic components and non-hydratable thin flat particles; m) containing at least one Coating of boron-free thin flat particles having a thermal conductivity of at least 1 watt per meter K at 300K; iv) containing thin flat particles having a thermal conductivity of at least 1 watt per meter κ at 300K (ie, on fibers Residual flow of an aqueous composition of thin flat particles); and v) water content comprising unmarkable non-hydratable particles having a thermal conductivity of at least ι watts per meter at a temperature of 300 K (ie, aluminum-free non-hydratable particles on fibers) The composition remains clear. In another embodiment, the particles 18 comprise 0.001 to 99% by weight, preferably 1 to 80% by weight, and more preferably 1 to 40% by weight based on the total solids of the coating composition. Further, in a specific embodiment in which the particles 18 are non-hydratable inorganic particles, the particles preferably include i to 50% by weight, and more preferably at most '2:% by weight based on the total solids of the coating composition. In another embodiment, the 'particles 18' contain more than 20 weight based on total solids. /. Preferably, Fanyuan is 20 to 99% by weight, more preferably in the range of 25 to 80% by weight, and most preferably Fanyuan is 50 to 60% by weight. In this specific embodiment, the special coating includes a resin-compatible coating composition. _ -43- 'The paper size applies the Zhongguanjia Standard (CNS) A4 specification (210 X 297 public love) (Please read the back Note for this page, please fill in this page) Order-丨 i Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 123〇698

It contains at least one particle selected from inorganic particles, organic hollow particles, and composite particles based on a total solids of greater than 20% by weight. The at least one particle has a Mohs hardness of not more than at least one glass fiber. . In another specific embodiment, the particles 18 comprise i to 80% by weight, preferably i to 60% by weight, based on the total solids. In a specific embodiment, the coating composition contains 20 to 60% by weight of particles based on the total solids, and preferably 35 to 55% by weight, and more preferably 30 to% by weight ❶ / ❶. A better coating of this embodiment includes a resin-compatible coating comprising a plurality of discontinuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof. It has an average particle size sufficient to moisten the strand without external heat application; 至少 at least one kind of lubricating material different from the plurality of discontinuous particles, and ⑷ at least-a film forming material. The coating composition preferably contains one or more film-forming materials, such as organic, inorganic, and natural polymeric materials. Useful organic materials include, but are not limited to, polymeric materials selected from synthetic polymeric materials, semi-synthetic polymeric materials, natural polymeric materials, and mixtures of any of the foregoing. Synthetic polymeric materials include, but are not limited to, thermoplastic materials and thermoset materials. Preferably, the polymer film-forming material forms a substantially continuous film when coated on the surface 16 of the glass fiber. Generally, the amount of the film-forming material is in the range of 1 to 99% by weight based on the total solids of the coating composition. In a specific embodiment, the amount of the film-forming material is preferably 1 to 50% by weight, and more preferably i to 25% by weight. In another specific embodiment, the amount of the film-forming material ranges from 2 () to 99 weight _ -44- This paper size applies to China National Standard (CNS) A4 (210 χ 297 public love) ----- ----- Installation (Please read the precautions on the back before filling this page) · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -n I n-1230698 V. Description of the invention (42) / 〇 and more preferably 60 To 80% by weight. In another specific embodiment, the amount of the core material is preferably in the range of 20 to 10% by weight of the coating composition, and more preferably ^ weight / 0 °. In this specific embodiment, 'Specially good coating comprises a film, material comprising at least one particle selected from inorganic particles, organic hollow particles and composite particles based on the total solids ft greater than 20% by weight. Fortunately, it has no more than at least A glass fiber has a Mohs hardness 値 Mohs hardness 値. In another specific embodiment, the amount of the polymer film-forming material ranges from 1 to 60% by weight, preferably 5 to %% by weight, based on the coating composition. It is more preferably 10 to 30 wt. . A better coating of this embodiment includes a resin compatible coating comprising a plurality of materials formed from a material selected from the group consisting of non-heat-swellable organic materials, polymer materials for planters, non-heat-swellable composite materials and mixtures thereof. Continuous particles having an average particle size sufficient to wet the strand without external heat application; (b) at least one lubricating material different from the plurality of discontinuous particles; and at least one film-forming material. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In a non-limiting embodiment of the present invention, a thermosetting polymer film forming material is a preferred polymer film forming material for coating a coating composition of glass fiber strands. This material is compatible with a thermosetting matrix material that is a laminate of a printed circuit board, such as FR-4 epoxy resin, which is a polyfunctional epoxy resin, and is a difunctional group in a specific embodiment of the present invention. Brominated epoxy resin. See Electronic Materials Handbook ™ ASM International (1989) at 534_537, which is specifically incorporated herein by reference. -45- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (43) Available thermosetting materials include thermosetting polyester, epoxy materials, vinyl esters, phenols , Amine-based plastics, thermosetting polyurethanes, and mixtures of any of the above. Suitable thermosetting polyesters include STYPOL polyester &apos;, which is commercially available from Cook Composites and Polymers, Kansas, Missouri, and NEOXIL polyester, which is commercially available from DSM Beta V., Como, Italy. A non-limiting example of a thermosetting polymeric material is an epoxy material. Useful epoxy materials are polyglycidyl ethers containing at least one epoxy or ethylene oxide group, such as a polyhydric alcohol or thiol, in one molecule. Examples of suitable epoxy film-forming polymers include Epon® 826 and Epon® 880 epoxy resins, commercially available from Shell Chemical Company of Houston, Texas. Useful thermoplastic polymeric materials include ethylene polymers, thermoplastic polyesters, polyamides, polyamides (eg, aliphatic polyamines or aromatic polyamines such as aromatic donkey amines), thermoplastic polyurethanes , Acrylic polymer (such as polyacrylic acid), and a mixture of any of the above. In another non-limiting embodiment of the present invention, the preferred polymer film forming material is an ethylene polymer. The available ethylene polymers of the present invention include, but are not limited to, polyvinylpyrrolidone, such as PVP K-15, PVP K-30, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this PVP K-60 and PVP K-90, each commercially available from International Specialty Products Chemicals, Wayne, New Jersey. Other suitable ethylene polymers include RESYN 2828 and RESYN 1037 vinyl acetate copolymer emulsions, commercially available from National Starch and Chemical Company of Bridgewater, New Jersey, and other polyvinyl acetates, such as commercially available from B.B. Fuller Air Products and -46-Allentown, Pennsylvania- This standard is applicable to China National Standard (CNS) A4 (210 x 297 mm) 1230698 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs (44)

Chemicals Corporation, and Polyacetol, which are also available from Air Products and Chemicals. 0 The thermoplastic polyesters used in the present invention include DESMOPHEN 2000 and DESMOPHEN 2001KS, both of which are commercially available from Bayer Corporation of Pittsburgh, PA. Preferred polyesters include RD-847A polyester resin, which is commercially available from Borden Chemicals, Columbus, Ohio, and DYNAKOLL Si 100, which has been chemically modified, and is commercially available from Eka Chemicals AB, Sweden. Useful polyamides include VERSAMID products, which are commercially available from Cognis, Inc. of Cincinnati, Ohio, and EUREDOR products, from Ciba Geigy, Belgium. Useful thermoplastic polyurethanes include WITCOBOND® W-290H, commercially available from CK Witco, Greenwich, Connecticut, and RUCOTHANE® 2011L polyurethane latex, commercially available from Hicksville, New York. Ruco Polymer. The coating composition of the present invention may comprise a mixture of one or more thermosetting polymeric materials and one or more thermoplastic polymeric materials. In a non-limiting specific embodiment of the present invention specifically for laminates for printed circuit boards, the polymeric material of the aqueous sizing composition includes RD-847A polyester resin, PVPK-30 polyvinylpyrrolidone, DESMOPHEN 2000 polymer Mixture of ester and VERSAMID polyamide. In alternative non-limiting specific embodiments suitable for laminates for printed circuit boards, the polymeric material of the aqueous sizing composition comprises PVP K-30 polyvinylpyrrolidone, optionally combined with EPON 826 epoxy resin . Semi-synthetic polymeric materials suitable as polymeric film-forming materials include, but are not limited to -47- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm): 1 --------- ^ pack -------- Order --------- Line '(Please read the notes on the back before filling this page) 1230698 A7 V. Description of the invention (45)

I ί cost cellulose, such as propyl cellulose, and modified starches, such as KOLLOTEX 1250 (based on ethylene oxide etherified low viscosity low amylose potato chips), its commercial starch Available from AVEBE, Netherlands. Natural polymeric materials that are suitable as polymeric film-forming materials include, but are not limited to, starches prepared from potato, corn, wheat, waxy corn, sago, rice, millet, and any mixtures thereof. It should be understood that depending on the nature of the starch, starch can be used as a particle and / or a film-forming material. More specifically, some starches are completely soluble in solvents, especially water, and serve as film-forming materials, while others are not completely soluble and maintain a specific particle size and serve as granules 18. Although powders (natural and semi-synthetic) can be used in accordance with the present invention, the coating composition of the present invention is preferably a substantially starch material. The term "substantially starch-free material" as used herein means that the coating composition comprises a starch material of less than 50% by weight, preferably less than 35% by weight based on the total solids of the coating composition. More preferably, The layer composition of the present invention is essentially starch-free. The term "essentially starch material" as used herein means that the coating composition contains a total solids based on the coating composition-less than 2G% by weight 'preferably less At 5% by weight, it is more preferable to be a powder-free material. A typical starch-containing first sizing composition coated on fiber strands of a laminate incorporated into a printed circuit board is not resin compatible and must be removed before adding a polymeric matrix material. As previously discussed, it is preferred that the coating compounds of the present invention are resin compatible and need not be removed from the fiber strands or fabrics prior to fabric treatment. More preferably, the coating composition of the present invention and the matrix material (discussed below) for manufacturing printed circuit boards are M, and most preferably epoxy resin phase-dimensional uncoated bodyless fiber: ------- -t --------- line. (Please read the precautions on the back before filling this page) ▲ I ___- 48- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

I 1230698 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-49 V. Description of the invention (46 The capacitive polymer film forming material can be water-soluble, emulsifiable, dispersible and / or hardenable. Π water-soluble used here "Properties" means that the polymeric material can be essentially uniformly blended and / or molecularly or ionicly dispersed in water to form a solid solution. See Hawley ^ page 1075, which is specifically incorporated herein by reference. "May "Emulsifying" means that the polymeric material can form an essentially stable mixture or suspension in water in the presence of an emulsifier. See Hawlev 1 s, page 461, which is specifically incorporated herein by reference. Non-limiting examples of suitable emulsifiers are described in "Dispersible" means that any component of the polymeric material can be distributed as finely divided particles in all water, such as latex. See Hawley, p. 435 'which is specifically incorporated herein by reference. The average dispersion of the dispersion can be It is increased by the addition of wetting, dispersing or emulsifying agents (surfactants) discussed below. "Hardenable" means that polymer materials and other ingredients of the sizing composition can coalesce Film forming or cross-linking each other to change the properties of polymer materials. See H ^ ley, s p. 331, which is specifically incorporated herein by reference. In addition to or in place of the film forming materials discussed above, the coating combinations of the present invention The material preferably contains one or more glass fiber coupling agents, such as an organic silane coupling agent, a transition metal coupling agent, a phosphoric acid coupling agent, an aluminum coupling agent, an amine-containing coupling agent 'and any mixture thereof. These coupling agents— It generally has a dual function. Each metal or silicon atom has _ or more radicals connected, which can directly react or be compatible with the components of the fiber surface and / or resin matrix. The term &quot; compatible &quot; used herein means The base is chemically connected (for example, 2 polar, wet or solvent) but does not bond the components of the fiber surface and / or the coating composition. In a non-restricted financial towel, each metal cutting atomic device: Private paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public love (please read the precautions on the back before filling this page) -install -------- order --------- line "1230698 A7 B7 V. Invention Description (47) One or more can The reaction surface of the glass fiber coupling agent may be of hydrolyzable groups, and one or more reactive functional groups allow coupling agent attached to the resin matrix component of the Examples of the hydrolyzable group include:. Ο Η 0 R3

II I II I -OR1, -OC-R2, -N ... C-R2, -0_N = C-R4, -〇_N = CR5, and monohydroxyl and / or 1, 2- or 1, 3 · diol Ring C: rC3 residue, where r1 is C1-C3 pit group; R2 is fluorene or C1-C4 group; R3 and R4 are independently selected from fluorene, Ci-CU alkyl or C5-C6 aryl group; and R5 is C4-C7 elongated base. Examples of suitable compatible or functional groups include epoxy, dehydroglyceryl, hydrogenthio, cyano, allyl, tiger, aminoamino, self-based, isocyanate, urea, Imidazolyl, vinyl, propionate, methacrylic, amine, or polyamine. Functional organosilane coupling agents are preferred for use in the present invention. Examples of useful functional organic silane coupling agents include γ-aminopropyltrialkoxysilane, γ-isocyanatopropyltriethoxysilane, vinyltrialkoxysilane, dehydrated glycerylpropyl Trialkoxysilanes and ureidopropyltrialkoxysilanes. Preferred functional organosilane coupling agents include A-187 γ-dehydrated glycerylpropyltrimethoxy stone sulfonate, A-174 γ-methylpropionyloxypropyltrimethoxysilane syrup, and a_1100 γ-amine Propyltriethoxysilane coupling agent, A-11108 aminosilane coupling agent, and A-1160 γ · ureidopropyltriethoxysilane (each commercially available from CK Witco, Tarrytown, NY). The organic silane coupling agent can be hydrolyzed at least partially with water before being applied to the fiber, preferably 1: 1 stoichiometry-50-This paper size is applicable to Zhongguan Standard (CNS) A4 (210 X 297 public love) ( (Please read the precautions on the back before filling this page) -------- Order --------- line j Printed by the Intellectual Property Bureau Employee Consumption Cooperative of the Ministry of Economy 1230698 Employee Consumption of Intellectual Property Bureau of the Ministry of Economic Affairs Cooperatives printed A7 B7 V. Description of the invention (48) Amount ratio, if required, or applied in unhydrolyzed form. The pH of water can be modified by addition of acids or bases to initiate or accelerate the hydrolysis of the coupling agent, as is known in the art. Suitable transition metal coupling agents include titanium, hammer, yttrium and chromium coupling agents. Suitable titanate coupling agents and #acid coupling agents are commercially available from Kenrich Petrochemical. Suitable complex complexes are commercially available from E. DuPont de Nemours, Wilmington, Delaware. Amine-containing Werner type coupling agents are complex compounds in which an organic acid having an amine functional group is coordinated, such as a trivalent nuclear atom of chromium. Other metal clamps and coordination type coupling agents known to those skilled in the art can be used here. The amount of coupling agent usually ranges from 1 to 99% by weight based on the total solids of the coating composition. In specific embodiments, the amount of the coupling agent ranges from 1 to 30% by weight, preferably from 1 to 10% by weight, and more preferably from 2 to 8% by weight based on the total solids. The coating composition of the present invention may further include one or more softeners or surfactants, which impart a uniform charge to the surface of the fibers, cause the fibers to repel each other and reduce friction between the fibers to act as a lubricant. Although not necessary, it is preferred that the softener is chemically different from the other ingredients of the coating composition. Such softeners include cationic, nonionic or anionic softeners and mixtures thereof, such as amine salts of fatty acids, alkylimidazoline derivatives (such as CATION X, commercially available from Rhone Poulenc, Princeton, New Jersey / Rhodia), acid-dissolved fatty acids fluorene, fatty acids and polyethyleneimine, and fluorene-substituted polyethyleneimines (such as EMERY® 6717, some fluorinated polyethyleneimines) are commercially available. Cognis -51 from Cincinnati, Ohio-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back before filling this page)

Order --------- Line I 1230698 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Condensate of Invention Description (49) Company. Although the coating composition may contain up to 60% by weight of the softener ', it is preferred that the coating composition contains less than 20% by weight and more preferably less than 5% by weight of the softener. For more information on softeners, see A; Hall ^ Textile Finishing ,. 2nd Edition (1957), page 15, which is specifically incorporated herein by reference. The coating composition of the present invention may further include one or more lubricating materials that are chemically different from the polymer materials and softeners discussed above to impart the desired processing characteristics to the fiber strands during weaving. Suitable lubricating materials may be selected from oils, waxes, greases, and mixtures of any of the above. Non-limiting examples of wax materials used in the present invention include water-soluble, emulsifiable or dispersible wax materials such as vegetables, animals, minerals, synthetics, or petroleum spirits, such as paraffins. The oils used in the present invention include natural oils, semi-synthetic oils and synthetic oils. Generally, the amount of wax or other lubricating material ranges from 0 to 80% by weight based on the total solids, preferably from 1 to 50% by weight, more preferably from 20 to 40% by weight, and most preferably from 25 to 35% by weight.

Preferred lubricating materials include waxes and oils having polar characteristics, and more preferably include highly crystalline waxes having polar characteristics and a melting point higher than 35 ° C and more preferably higher than 45X :. Comparing fiber strands coated with a sizing composition containing waxes and oils having no polar characteristics, this material is believed to improve the wetting and penetration of polar resins on fiber strands coated with a size composition containing such a polar material. Preferred polar lubricating materials include esters formed by reacting: ⑴ monocarboxylic acids and (2) monohydroxy alcohols. Non-limiting examples of such fatty acid esters for use in the present invention include the preferred cetyl palmitate (eg, KESSCO 653 or STEPENTE-52- Stepan scale from Stepan Company, Maywood, New Jersey). Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ------------- install -------- order --------- line one (Please read the phonetic on the back? Matters before filling out this page) 1230698 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (50)

653), serine myristate (also available from STEPANLUBE 654 from Stepan), cetyl laurate, stearyl laurate, stearyl myristate, stearyl myristate, and stearic acid Stearyl ester. Other fatty acid esters and lubricating materials used in the present invention include trimethylolpropane trinonanoate, natural cetyl wax, and triglycerides, such as but not limited to soybean oil, linseed oil, epoxidized soybean oil, and epoxidized sesame oil. Lubricating materials may also include water-soluble polymeric materials. Non-limiting examples of useful materials include polyalkylene polyols and polyoxyalkylene polyols such as MACOL E-300, commercially available from BASF Corporation, Parsippany, New Jersey, and CARBOWAX 300 and CARBOWAX 400, commercially available Union Carbide, Danbury, Connecticut. Another non-limiting example of a useful lubricating material is POLYOX WSR 301, which is commercially available from Connecticut

Poly (ethylene oxide) from Union Carbide of Danbury. Instead of or in addition to the lubricating materials discussed above, the coating composition of the present invention may additionally include one or more other lubricating materials, such as non-polar petroleum wax. Non-limiting examples of non-polar petroleum waxes include MICHEM® LUBE 296 microcrystalline wax, POLYMEKON® SPP-W microcrystalline wax, and PETROLITE 75 microcrystalline, each commercially available from Michelman Corporation of Cincinnai, Ohio, and Cumming, Georgia. Baker Petrolite, Polymer Division. Generally, the amount of this pattern is up to 10% by weight of the total solids of the sizing composition. The coating composition of the present invention may also include a resin-reactive diluent to further improve the process of the present invention by reducing the possibility of fine hair, pore loops, and broken filaments in this manufacturing operation, while maintaining resin compatibility. Coated fiber strand-53- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) — — &lt; — — — — — — 1 — · IIIIIII — — — — — — — I · (Please read the precautions on the back before filling this page) 1230698 A7 ___B7__ V. Lubrication of the invention description (51), and provide good processing power in weaving and knitting. As used herein, "resin-reactive diluent" means that the diluent includes functional groups that can chemically react with the same resin that is compatible with the coating composition. The diluent can be any one that has one or more reactive with the resin system The functional group of the lubricating material is preferably a functional group that reacts to an epoxy resin system, and more preferably a functional group that reacts to an FR_4 epoxy resin system. Non-limiting examples of suitable lubricants include amine groups, alcohol groups, and anhydrides. -Based, acid-based or epoxy-based lubricants. A non-limiting example of an amine-based lubricant is a modified polyethylene diamine, for example, EMERY 6717, which is part of the Cognis company commercially available from Cincinnati, Ohio. Aminated polyethyleneimine. A non-limiting example of an alcohol-based lubricant is polyethylene glycol, for example, CARBOWAX 300, which is a polyethylene commercially available from Union Carbide, Danbury, Connecticut. Alcohols. Non-limiting examples of lubricants with acid groups are fatty acids, such as stearic acid and salts of stearic acid. Non-limiting examples of lubricants with epoxy groups include epoxidized soybean oil and epoxidized flax For example, FLEXOL LOE, which is an epoxidized linseed oil, and FLEXOL EPO, which is an epoxidized soybean oil, both of which are commercially available from Union Carbide Corporation, Danbury, Connecticut, and LE-9300 epoxidized polyoxygenated emulsion, It is commercially available from CK Witco, Inc. of Tarrytown, New York. Although not limiting in the present invention, the sizing composition may include up to 15 weights based on the total solids of the sizing composition. Resin reactivity as discussed above in an amount of / 0 The diluent. The coating composition may additionally include one or more emulsifiers to emulsify or disperse the ingredients of the coating composition, such as particles 18 and / or lubricating materials. Non-limiting examples of suitable emulsifiers or surfactants include Polyoxyalkylene block total-54- This paper size is applicable to Chinese National Standard (CNS) A4 specification (21〇X 297 public love) Please first read the precautions of the back © and win! Printed by the Property Cooperative Consumer Cooperative 1230698 A7 B7 V. Description of the Invention (52) Polymers (such as PLURONIC ™ F-108 polyoxypropylene-polyethylene oxide copolymers, commercially available from Parsippany, New Jersey BASF (PLURONIC ™ F-108 copolymer is available in Europe under the trade name SYNPERONIC F-108), ethoxylated phenols (such as IGEPA CA-630 ethoxylated octylphenoxyethanol, commercially available from Wayne, New Jersey GAF Corporation), polyethylene oxide octylphenyl glycol ether, ethylene oxide derivatives of anthocyanin esters (such as TMAZ 81, commercially available from BASF Corporation, Parsippany, New Jersey), polyethylene oxide Chemical vegetable oils (such as ALKAMULS EL-719, commercially available from Rhone-Poulenc / Rhodia), ethoxylated (such as MACOL OP-10 SP, which is also commercially available from BASF), and nonyl surfactant ( For example, MACOL NP-6 and ICONOL NP-6, which are also commercially available from BASF, and SERMUL EN 668, which are commercially available from CON BEA, Benelux). Generally, the amount of emulsifier ranges from 1 to 30% by weight, preferably from 1 to 15% by weight, based on the total solids of the coating composition. Cross-linked materials, such as melamine formaldehyde, and plasticizers, such as phthalates, trimellits, and adipates, can also be included in the coating composition. The amount of the cross-linking agent or the plasticizer ranges from 1 to 5% by weight based on the total solids of the coating composition. Other additives may be included in the coating composition, such as polysiloxanes, fungicides, bactericides, and antifoam materials, which are usually in an amount of less than 5% by weight. Organic and / or inorganic acids or bases sufficient to provide a pH of 2 to 10 of the coating composition may also be included in the coating composition. A non-limiting example of a suitable silicone emulsion is LE-9300 epoxy silicone emulsion, commercially available from CK Witco, Tarrytown, NY. An example of a suitable bactericide is: 55- private leaf scale applicable to China National Standard (CNS) A4 (210 X 297 public love) &quot; (Please read the precautions on the back before filling this page) ------ --Order --------- Line j Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 1230698

V. Description of the Invention (53 The BIOMET 66 antimicrobial compound printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs has been deposited with M &amp; T Chemicals, Rahway, New Jersey. Examples of suitable antifoam materials Is a sag material commercially available from CK Witco, Greenwich, Connecticut, and MAZU DF-136, commercially available from BASF, ρ_ρρ— New Jersey. Ammonium hydroxide can be added to the coating if needed The composition has a stable coating. Preferably, water, and more preferably deionized water, is included in the coating composition in an amount sufficient to facilitate the application of a substantially uniform coating on the strand. The solids weight% of the coating composition Usually the range is from 1 to 20% by weight. In a specific embodiment, the coating composition of the present invention is substantially free of glass material. The substantially glass-free material used herein means that the coating composition contains less than 50 vol. The glass matrix material forming the glass composite is preferably less than 35% by volume. In a more specific embodiment, the coating composition of the present invention is essentially free of glass materials. The "essence" used herein The above glass-free material means that the coating composition contains less than 20 vol.% Of the glass matrix material forming the glass composite, preferably less than 5% by volume, and more preferably a glass-free material. Such a glass matrix Examples of materials include black glass ceramic matrix materials or indium silicate matrix materials, as known to those skilled in the art. In a specific embodiment of the present invention, a fiber strand comprising a plurality of fibers to contain an organic component and having a mass at 300K A coating of thin flat particles having a thermal conductivity of at least 1 watt per meter K is at least partially coated. In another embodiment, a fiber strand comprising a plurality of fibers includes organic components and a non-hydratable thin flat The coating of the particles is at least partially coated. In these embodiments, the organic component and the thin flat particles may be selected from the coating components discussed above. The organic components and the thin flat particles may be the same or different, and the coating may be For water-based coating-56- This paper has passed the Ning National Standard (CNS) A4 specification (21〇χ 297 mm) ^ Packing -------- Order --------- Line (Please read the notes on the back before filling out this page) 12306 98 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Invention Description (54) Layer composition residue or powder coating composition. In another specific embodiment, a fiber strand comprising a plurality of fibers to contain at least one A coating having a thermal conductivity of at least 1 watt per meter K at 30 ° I. Shedless thin flat particles is at least partially coated. In another embodiment, a 'fiber strand comprising a plurality of fibers to contain Aqueous composition residues of boron-free thin flat particles having a thermal conductivity of at least 1 watt per meter K at 300 κ are coated at least partly. In another specific embodiment, a plurality of fibers are included The fiber strands are at least partially coated with an aqueous composition residue containing aluminum-free non-hydratable particles having a thermal conductivity of at least 1 watt per meter of kappa at a temperature of 300 kappa. The components in these embodiments may be selected from the coating components discussed above, and other components may also be selected from those listed above. In another embodiment of the present invention, a fiber comprising a plurality of fibers is at least partially coated with a resin-compatible coating composition on at least a portion of a surface of at least one of the salt fibers, and the resin phase The coating composition includes: (a) discontinuous particles formed from materials that cannot be thermally expanded organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof, and the particles have an average particle size sufficient to make the strands moist (B) at least one lubricating material different from the plurality of non-connected% particles; and ⑷ at least one film-forming material. & The ingredients in some embodiments may be selected from the coating ingredients discussed above. In another specific embodiment, a plurality of discontinuous particles provide interstitial space between at least one of the fibers and one adjacent fiber. In another specific embodiment, a fiber strand containing a plurality of fibers is coated with a resin-compatible coating composition on the surface of at least one of the fibers. (Please read the precautions on the back first.) Fill out this page again} -------- Order --------- line j

1230698 V. Description of the invention (55) Partially coated, this resin-compatible coating granule contains at least one soil to (a) particles / organic particles formed from organic materials; and (in At least one particle formed from a material selected from the group consisting of boron nitride, graphite, and metal dichalcogenide, in which the particles &lt; Machinery, · 仏, &quot;, and Zhongxi have at least one kind of average particle sufficient to make the strand moist Forming materials. Unexpectedly (lubricating materials; and (〇 ；;; :: In the embodiment, a fiber strand containing a plurality of fibers is at least partially coated with a resin-compatible coating on the fiber surface. Ground coating, this name is called, and the mouth-to-mouth absorption of this resin-compatible coating composition includes: (a) a plurality of materials selected from the group consisting of organic materials; The materials r, n, dagger and granules of the composite material and its mixture have an average particle size of two microns measured according to laser scattering technology, at least-a kind of lubricating material different from the plurality of unconnected particles; and ⑷ at least one film forming material ^ Another-a resin-compatible coating specifically described above Combination: 20 to 60% by weight based on total solids, preferably 35 to 55% by weight and more preferably 30 to 50% by weight of discrete particles; (b) 0 based on total solids To 80% by weight, preferably! To 50% by weight, and more preferably at least one lubricating material of 20 to 40% by weight of horse, and · based on the body horse 12 to 60% by weight, preferably At least one film-forming material is 5 to 50% by weight, and more preferably 10% to 30% by weight. In another specific embodiment of the present invention 4, the fiber-containing strand comprising a plurality of fibers is at least one of the fibers. At least a part of the surface is coated with a resin-compatible acoustic layer, and the composition is at least partially coated. The resin-compatible coating composition includes: 多个 a plurality of materials formed from materials selected from organic materials, composite materials, and mixtures thereof 1 _______ -58- 2 This Λ Zhang scale is applicable to China's national standard (cns) A4 specifications (Q X tear public love) 1230698 V. Description of the invention (56 discontinuous non-bad pieces of jealousy garden is M to 5 micrometers) Γ The particles have a range-average particle size measured in accordance with laser scattering technology, and (b) at least one type of lubricant different from the plurality of non-linked alpha particles In another aspect of the present invention, the fiber is at least: solid. In a specific embodiment, a fiber composition including a plurality of fibers is at least partially coated with a resin-compatible coating on the surface of the resin. In addition, this resin-compatible coating composition includes particles that are based on ~ Guo Xiaodou is larger than King and /, and is selected from inorganic particles and organic particles, and this at least one particle has no more than at least- Mohs hardness 値 of this fiber 値. (Another embodiment, a fiber comprising a plurality of fibers = = of: at least-a resin-compatible coating on a part of the surface / »卩Knowingly, at least one of this resin-compatible coating combination has no more than at least one, ⑻, main / money (Mohs' hardness 値 of Mohs is also `` flat machine particle; and (b) at least one Polymeric material. In an additional specific embodiment of the present invention, at least-to ... of the fibers are coated with a resin-compatible coating group on the surface of the fiber strands, and the resin-compatible coating is applied. The layer composition includes: 至少 at least one hollow non-heat-expandable organic particle; and ㈨ a lubricating material which is at least different from at least one hollow organic particle. The components in each of the above specific embodiments are selected from the coating components discussed above, and other components may also be selected from the above. Knife In a specific embodiment of the invention, the fiber coating comprises a composition of an organic component and a thin, granular composition having a thermal conductivity of at least 1 watt per meter of k at a temperature of 30K. In another specific embodiment, the fiber-coated coated organic composition _ _ 59-This paper size is such as ㈣ @ 家 标准 (CNS) A4 Secret (X 297 ^ J &quot; Ϊ230698 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 5. Description of the invention (57) A composition that divides non-hydratable thin flat particles. In another specific embodiment, the fiber coating comprises at least one having a thermal conductivity of at least 1 watt per meter κ at a temperature of 30 ° K. Composition of boron-free thin flat particles. In another specific embodiment, a fiber coating composition comprising thin flat particles having a thermal conductivity of at least 1 watt per meter of k at a temperature of 30oK. In another specific embodiment, In an embodiment, the fiber coating comprises a composition of unmarkable non-hydratable inorganic particles having a thermal conductivity of at least 1 watt per meter k at a temperature of 300K. In another embodiment of the present invention, the fiber coating includes the following Composition: (a) a plurality of discontinuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials and mixtures thereof, the particles having sufficient Wet average particle size; at least one lubricating material different from the plurality of discontinuous particles; and ⑷ at least one film forming material. In another embodiment, the fiber coating comprises the following composition: (a) a plurality of particles Comprising at least one I particle formed from an organic material; and (ii) at least one particle formed from an inorganic material selected from the group consisting of boron nitride, graphite, and a metal dichalcogenide, wherein a plurality of particles have Average particle size; (b) at least one lubricating material different from the plurality of non-continuous particles; and ⑷ at least one film forming material. In another specific embodiment, the fiber coating comprises the following composition: (a) more Discontinuous particles formed of a material selected from the group consisting of organic materials, inorganic polymeric materials, composite materials, and mixtures thereof, the particles having an average particle size of 0 to 5 micrometers as measured by a laser scattering technique; Lubricating material for the plurality of discontinuous particles; and at least one film-forming material. -60- This paper size applies to China National Standard (CNS) A4 (21〇χ 29 7 mm) (Please read the notes on the back before filling in this page)

1230698 A7

1230698 A7 B7 V. Description of the invention (59) (Please read the notes on the back before filling in this page) EPON 826 epoxy film forming material, PVP K-30 polyvinyl pyrrolidone, A-187 epoxy function Organic organosilane coupling agent, ALKAMULS EL-719 polyoxyethylated vegetable oil, IGEPAL CA-630 ethoxylated octylphenoxyethanol, KESSCO PEG 600 polyethylene glycol monolaurate (commercially available from Illinois Stephan Company in Chicago), and EMERY® 6717 Partially Aminated Polyethylene Diimide Aqueous Coating Composition. In another non-limiting embodiment of the present invention for woven fabrics, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with POLARHERM® 160 boron nitride powder and / or BORON NITRIDE RELEASECOAT dispersion RD-847A Polyester, PVP K-30 Polyvinylpyrrolidone, DESMOPHEN 2000 Polyester, A-174 Propylene Functional Organosilane Coupling Agent, A-187 Epoxy Functional Organosilane Coupling Agent, PLURONIC Dry residue of an aqueous sizing composition of F-108 polyoxypropylene-polyoxyethylene copolymer, MACOL NP-6 nong interfacial surfactant, VERS AMID 140, and LE-9300 epoxy polysiloxane emulsion. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion, PVP K-30 polyvinyl pyrrolidone, A-174 acryl-functional organosilane coupling agent, A-187 epoxy-functional organosilane coupling agent, ALKAMULS EL-719 Polyoxyethylated vegetable oil, EMERY® 6717 Partially Aminated Polyethylene Diimide, RD-847A Polyester, DESMOPHEN 2000 Polyester, PLURONIC F-108 Polypropylene Oxide-Polyethylene Oxide Copolymer, ICONOL -62- This standard is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (60) (Please read the precautions on the back before filling this page) NP-6 alkane An aqueous coating composition of nonoxynol and SAG 10 antifoam material. If desired, this particular embodiment may optionally include ROPAQUE® HP-1055 and / or ROPAQUE® OP-96 styrene-propylene copolymer hollow spheres. In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with POLARTHERM® PT160 boron nitride powder and / ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion, RD-847A polyacetate, PVP K-30 polyvinylpyrrolidone, DESMOPHEN 2000 polyester, A-174 acrylic functional organosilane coupling agent, A-187 epoxy Organic functional silane coupling agent, PLURONIC F-108 polyoxypropylene-polyoxyethylene copolymer, VERSAMID 140 polyamide, and an aqueous sizing composition of MACOL NP-6 nong. If desired, this particular embodiment may optionally include ROPAQUE® HP-1055 and / or ROPAQUE® OP_96 styrene-propylene copolymer hollow pellets as appropriate. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In another non-limiting embodiment of the present invention for weaving laminated printed circuit board fabrics, at least a part of at least one of the fibers of the fiber strand of the present invention Coated hollow pellets containing ROPAQUE® HP-1055 and / or ROPAQUE® OP-96 acetophenone · propylene copolymer, PVP K-30 polyethylpyrrolidone, A-174 acrylic functional organosilane coupling agent Derived from ethylene oxide with A-187 epoxy-functional organosilane coupling agent, EMERY® 6717 partially fluorinated poly (ethylene diimide), STEPENTEX 653 cetyl palmitate, TMAZ 81 anisocyanate Materials, MACOL OP-10 ethoxylate test, and MAZU DF-136 anti-foam material, the first coating composition of water-based residue -63- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 5. Description of the invention (61) Slag. Although not necessary, this particular embodiment preferably includes POLARTHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion. In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with DESMOPHEN 2000 polyester, A-174 acrylic functionalities Based organic silane coupling agent, A-187 epoxy functional organic silane coupling agent, PLURONIC F-108 poly (propylene oxide) -poly (ethylene oxide) copolymer, VERSAMID 140 polyamine, and MACOL NP-6 nonylphenol, POLYOX WSR 301 poly (ethylene oxide), and an aqueous coating composition of DYNAKOLL Si 100 turpentine. In addition, this particular embodiment further includes POLARTHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion.

In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with DESMOPHEN 2000 polyester, A-174 acrylic functionalities Organic silane coupling agent, A-187 epoxy-functional organic silane coupling agent, SYNPERONIC F-108 polyoxypropylene-polyoxyethylene copolymer, EUREDUR 140 polyamide, MACOL NP-6 nong, SERMUL EN 668 An aqueous coating composition of ethoxylated nonylphenol, POLYOX WSR 301 poly (ethylene oxide), and DYNAKOLL Si 100 Matsuki. Furthermore, this particular embodiment further includes ROPAQUE® HP-1055 and / or ROPAQUE® OP-96 styrene-propylene copolymer hollow pellets, and / or POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON -64- This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) (Please read the precautions on the back before filling this page) -----: ---- Order ---- -----, Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, A7. 5. Description of Invention (62) NITRIDE RELEASECOAT-CONC 25 dispersion. Although unsatisfactory, fiber strands having a coating composition similar to that described above can be produced in accordance with the present invention. In particular, it is intended according to the present invention to include one or more film-forming materials, such as PVP K-30 polyethylene cheloridone; one or more silane coupling agents, such as A_174 propenyl-functional organic silane coupling The mixture is compatible with A-187 epoxy-functional organosilane coupling agent; and based on the total solids, at least 25% by weight of the sizing composition, at least 25% by weight of a lubricating material with polar characteristics, such as STEPANTEX 653 cetyl palmitate resin compatible coating层 组合 物。 Layer composition. Those skilled in the art should further understand that according to the present invention, the fiber strands of the resin-compatible coating composition without particles 18 can be woven into fabrics and made into electronic supports and electronic circuit boards (as described below). The coating composition of the present invention can be prepared by any suitable method, such as mixing by a method known to those skilled in the art. Preferably, the ingredients discussed above are diluted with water to have the desired solids weight percent and mixed together. The particles 18 may be premixed with water, emulsified, or added to one or more of the components of the coating composition prior to mixing the remaining components of the coating. The coating composition according to the present invention can be applied in many ways, for example, by contacting the filaments with a roller or a belt applicator, spraying or other means. The coated fibers are preferably dried at 1: warm or high temperature. The dryer removes excess water from the fibers and, if present, hardens any hardenable sizing composition ingredients. The temperature and time for drying the glass fibers depend on variables such as the% solids in the coating composition, the composition of the coating composition, and the fiber type. The term "hardening" as used herein with respect to a composition, such as &quot; hardening composition &quot;, means at least partially crosslinking any crosslinkable component of the composition. In ___ —___ -65- This paper size applies to China National Standard (CNS) A4 (21G X 297) quotation &quot; &lt; Please read the precautions on the back before filling this page)

1230698 A7 B7 V. Description of the invention (63) (Please read the notes on the back before filling this page) In a specific embodiment of the present invention, the crosslink density of the crosslinkable components, that is, the degree of crosslink, the range is completely Cross-linking of 5% to 100%. In other embodiments, the crosslinking density ranges from 35% to 85% of the fully crosslinked. In other specific embodiments, the crosslinking density ranges from 50% to 85% of the complete crosslinking. Those skilled in the art should understand that the existence and extent of cross-linking, that is, the cross-linking density, can be determined by many methods, such as dynamic mechanical thermal analysis (DMTA) using a Poimer Laboratories MK III DMTA analyzer under nitrogen. This method determines the glass transition temperature and crosslink density of the free film of the coating or polymer. These physical properties of the hardened material are related to the structure of the interconnected road. According to this point, the length, width, and thickness of the sample to be analyzed are measured first, the sample is tightly mounted in the Polymer Laboratories MK III device, and the dimensional measurement is input into the device. A thermal scan was performed at a heating rate of 3 ° C / min, a frequency of 1 Hz, a strain of 120%, and a static force of 0.01 N, and a sample measurement occurred every 2 seconds. According to this method, the deformation mode, glass transition temperature, and crosslinking density of the sample can be determined. Higher crosslink density 値 indicates a higher degree of crosslink in the coating. The amount of the coating composition present on the fiber stock printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is preferably less than 30% by weight, more preferably less than 10% by weight, and most preferably 0.1 to 5% by weight, such as Ignition loss (L0I) is measured. The coating composition on the fiber strands may be a water-based coating, a composition residue or a powder coating composition. In a specific embodiment of the invention, L0I is less than 1% by weight. The term "ignition loss π" as used herein means the weight% of the dry coating composition present on the surface of the fiber strand as determined by Equation 1. -66- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698

V. Description of the invention (μ) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, LOI = 1〇00 [[W dry one W naked] / W dry] (Equation l) where W dry is at 220 T (about 104t) The weight of the fiber strands after drying in the oven plus the weight of the coating composition and the fiber strands were added to the oven at 115 ° C (about 621 ° C) for 2 minutes and cooled to room temperature in a dryer. Bare fiber strand weight. After the first sizing is applied, that is, the first sizing is applied after the fibers are formed, the fibers are aggregated into strands having 2 to 15,000 fibers per share, and preferably 100 to 1600 fibers per share. The first coating composition can be applied to the first sizing agent in an amount sufficient to coat or impregnate the portion of the strand, for example, by immersing the coated strand in a bath containing the second coating composition, The second coating composition is sprayed onto the coated strand or is contacted with the coated strand by the applicator discussed above. The coated strand can be removed from the excess coating composition by a die and / or dried for a time sufficient to at least partially dry or harden the second coating composition, as discussed above. The method and apparatus for applying the second coating composition to the strand are determined in part by the configuration of the strand material. The strands are preferably dried after applying the second coating composition in a manner known in the art. Suitable second coating compositions may include one or more of the film-forming materials, lubricants, and other additives discussed above. The second coating is preferably different from the first coating composition, that is, it contains at least one component that is chemically different from the composition of the public composition; or (2) is the same as that contained in the sizing composition The amount of the ingredients contains at least one ingredient. Including polyurethane suitability ____ _ 67-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) &quot;-: ------------ --- r --- Order --------- line (please read the note on the back? Matters before filling out this page) 1230698 A7 ----------- B7___ V. Invention System (65) ~: ~ A non-limiting example of a second coating composition is disclosed in US Patent 4,762,751, which is specifically incorporated herein by reference. Referring now to FIG. 2 ′ In an alternative embodiment in accordance with the present invention, the glass fibers 212 of the coated fiber strand 210 may be coated with the first layer 214 of the first sizing composition, including any of the above-mentioned amounts in the amounts discussed above. ingredient. Examples of suitable sizing compositions are described on pages 237-291 (3rd edition, 1993) and U.S. Patents 4,390,647 and 4 795 678, each of which is specifically incorporated herein by reference. The second layer 215 of the second coating composition is applied to at least a portion of the first layer 214, and preferably the entire outer surface. The second coating composition includes one or more types of particles 216, as discussed in detail above with particle 18. In a specific embodiment, the second coating is a residue of an aqueous first coating composition on at least a portion of the second layer, particularly a residue of an aqueous second coating composition comprising thin flat particles. In another embodiment, the second coating is a powder coating composition on at least a portion of the first coating, particularly a powder coating composition comprising thin flat particles. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In an alternative embodiment, the particles of the second coating composition include hydrophilic inorganic solid particles that absorb and retain water in the gaps between the hydrophilic particles. Hydrophilic inorganic solid particles can absorb or swell when exposed to water or participate in chemical reactions with water, for example, forming a viscous colloidal solution that prevents or inhibits water from entering the gaps of communication cables reinforced with coated glass fiber strands. As used herein, &quot; absorption &quot; means that water penetrates the internal structure or interstices of the hydrophilic material and remains substantially in it. See page 3 of Hawley's Condensed Chemical Dictionary, which is specifically incorporated herein by reference. &quot; Expansiveness "means the size or volume expansion of hydrophilic particles. See Webster's New -68- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7-______B7___ V. Description of the invention (66 ) £ ail ^ te. Dictionary (1977) p. 1178, which is specifically incorporated herein by reference. It is preferred that the hydrophilic particles swell to at least one and a half times their original dry weight after contact with water, and more It is preferably two to six times its original dry weight. Non-limiting examples of swelling hydrophilic inorganic solid lubricating particles include montmorillonites such as vermiculite and microcrystalline glausite, absorbent zeolites, and inorganic absorbent gels. . Che Fujia is' these hydrophilic particles are coated in powder form on a viscous sizing or other viscous second coating material. In a specific embodiment of the present invention, a fiber strand comprising a plurality of fibers is Resin compatible & layer composition is at least partially coated on at least a portion of the surface of the V fibers' This resin compatible coating composition has a sizing composition on at least a portion of the surface of at least one fiber First coating, and A second coating of an aqueous coating composition residue (which includes at least one discontinuous particle) is applied to at least a portion of the first coating of the sizing composition. In a preferred embodiment, at least A discontinuous particle is selected from hydrophilic particles that absorb and retain water in the interstices of the hydrophilic particles. In addition to these specific examples, the amount of particles in the second coating composition may range from 1 to 99% by weight based on the total solids, compared to It is preferably 20 to 90, more preferably 25 to 80% by weight, and even more preferably 50 to 60% by weight. In the alternative embodiment shown in FIG. 3, the third layer 320 of the third coating composition may be Coated on at least a part of the surface of the second layer 312, and preferably the entire surface, that is, the fiber strand 312 has a first layer 314 of a first sizing, and a second layer 315 of a second coating composition. And the third outer layer 320 of the third coating composition. The third coating of the coated fiber strand 310 is preferably different from the first sizing composition and the second coating composition, that is, the third coating Group • 69- (Please read the notes on the back before filling out this page) ----- r --- Order · --- ----- Line · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, the Consumer Cooperatives This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) &quot; ~ &quot; 1230698 Print A7 ---_ B7 V. Description of the invention (67) Compound (1) contains at least ~ 20% of the silk chemically different from the components of the first sizing and the second coating composition, called or (2) Containing at least one component in an amount different from that of the same components in the first size and the second coating composition. In this specific embodiment, the second coating composition includes one or more hydration materials, such as polyurethane, and the third powdery coating composition is above the original text. Word of mouth &lt; solid particles such as POLARTHERM® boron nitride particles and medium 2 particles such as ROPAQUE® pigments. Preferably, the coating is applied by passing &lt; the strand having the liquid-sensitive second coating composition through a fluidized bed or a spraying device to adhere powder particles to the adhesive-like second coating composition. coating. Alternatively, the strands may be combined into a fibrous material 912 before coating the layers of the third coating layer 920, as shown in FIG. The composite or laminate 910 of the composite fabric 912 and the resin 914 also includes a conductive layer 922, which is similar to the structure shown in Fig. 8 in more detail below. The weight percent of the powdery solid particles adhered to the coated fiber strands may range from 0 "to 75% by weight based on the total weight of the dry strands, and is preferably from 0" to 30% by weight. The second powder coating may also include one or more of the polymeric materials discussed above, such as propylene polymers, epoxides, or polyolefins. Conventional stabilizers and other modifiers known in this coating technology are It is preferably in the form of a dry powder. In a specific embodiment, 'a fiber strand comprising a plurality of fibers is at least partially sizing at least a portion of the surface of at least one of the first coating fibers of the sizing composition to a second coating composition including a polymeric material. Coating at least a portion of the first composition and coating at least a portion of the second coating with a third coating composition comprising discrete particles. In another specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with a first coating of a sizing composition. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm); ----- Γ --- Order --------- Thread (Please read the notes on the back before filling this page) 1230698 A7 V. Description of the invention (68 At least one of the fiber Part of the surface, coating at least a portion of the first composition with a first coating composition comprising a polymeric material, and coating at least a portion of a second coating with a third coating composition including thin flat particles In a preferred embodiment, at least one coating in each of the above embodiments is different. In another preferred embodiment, at least two coatings in each of the above embodiments are different In addition, the third coating may be an aqueous emulsion residue of a private coating composition. The coating composition includes one or more of the coating ingredients discussed above. Each implementation of the coated fiber strands discussed above Examples can be used as continuous stocks or further processed into various products, such as short-cut stocks, trading Strands, spinning tops, and / or fabrics such as woven fabrics, non-woven fabrics (including single-phase fabrics), knitted fabrics, and knitted fabrics. In addition, the coated fiber strands of the warp and weft (ie, filling) strands of the fabric may be non-interlaced (Also known as non-interlaced or non-interlaced), or interwoven before weaving, and the fabric may include various combinations of interwoven and non-interlaced warp and weft strands. Preferred embodiments of the present invention include at least partially coating A fabric comprising at least one fiber strand comprising a plurality of fibers discussed in detail above. Accordingly, in the present invention is intended to be an at least partially coated fabric made from each of the disclosed fiber strands comprising a plurality of fibers. For example The preferred embodiment of the present invention relates to a fabric that is at least partially coated, which includes fiber strands containing at least a plurality of fibers, which contains organic components and has a temperature of 300K at least watts per meter κ! The thermal conductivity of the thin flat particles. In the specific implementation of the present invention, the coating composition according to the present invention is distributed to individual fibers. In another specific embodiment, the coating is coated on 71 woven fabric Dimensional (Please read the note on the back? Matters and then fill out 4 ------- ^ --------- this page) This paper size applies the Zhongguanjia Standard (CNS) A4 specification (21G X 297 Public Love · 1230698 A7 B7 V. Description of the Invention (69) At least one fiber strand. In another specific embodiment, the coating composition according to the present invention is applied to a fabric. These alternative specific embodiments are described in This is discussed in detail below. Although the above discussion is generally about coating the coating composition of the present invention directly on glass fibers after fiber formation, and then adding the fibers to the fabric, the present invention also includes the coating composition of the present invention. Specific examples of application to a fabric. For example, by applying a coating to a fiber strand before fabric is made, or by applying a coating to a fabric after having been made using various techniques known in the art. The coating composition is applied to a fabric. Depending on the fabric, the coating composition of the present invention may be applied directly to the glass fibers in the fabric, or another coating already on the glass fibers and / or the fabric. For example, 'glass fibers can be coated with a conventional starch-on-oil slurry after being formed and woven into a fabric. The fabric is then treated to remove the starch-oil sizing before coating the coating composition of the present invention. This sizing removal can be accomplished using techniques known in the art, such as heat treating or cleaning the fabric. In this case, the coating composition directly coats the fiber surface of the fabric. If any portion of the sizing composition originally applied to the glass fibers is not removed after formation, the coating composition of the present invention is applied to the remaining portion of the sizing composition rather than directly on the fiber surface. In another specific embodiment of the present invention, the selected ingredients of the coating composition of the present invention can be applied to glass fibers immediately after formation, and the remaining ingredients of the coating composition can be applied to Fabric. In a manner similar to that discussed above, some or all of the selected components may be removed from the glass fibers before coating the fibers and fabric with the remaining components. As a result, the rest of the ingredients were directly printed (please read the precautions on the back before filling this page).

1230698 A7 B7 V. Description of the invention (70. Fiber-coated fish carp coated with fabric &amp; + ^ ^ VIII Paper quasi-surface or coating is not removed from the fiber surface.

In another specific embodiment according to the present invention, it includes at least. The fabric of the strands of fiber is at least partially coated with a first coating I = 0Γ, at least-partially with a second coating, and the "layer pack = = job <temperature is greater than watts per meter κ In another specific embodiment, the thermal conductivity of the inorganic material branch includes at least one part containing a plurality of fibers and is partially coated with the following coating: ⑷ thin flat inorganic &quot;, and no more than at least one glass fiber And (b) a film-forming material. In another embodiment, a fabric comprising at least one strand comprising a plurality of fibers is at least partially coated with a coating comprising : ⑷ metal particles 'having a Mohs hardness of at least one glass fiber 値 Mohs hardness 线' This metal particle is selected from the group consisting of indium, rhenium, tin, gold and silver, and rhenium film forming materials. In an embodiment, a fabric comprising at least one fabric comprising a plurality of fiber strands is at least partially coated with a first coating, and a second coating is coated on at least a portion of the first coating. Absorbs and retains the hydrophilicity of water in the interstices of hydrophilic particles In another embodiment, a fabric comprising at least one strand comprising a plurality of fibers has a resin-compatible coating composition on at least a portion of a surface of the fabric, and the resin-compatible coating composition includes ： Multiple materials selected from non-heat-swellable organic materials, inorganic polymeric materials, non-heat-swellable gland composite materials and I-73- This paper size applies to China National Standard (CNS) A4 (210 X 297 Public Love 1230698 A7

The material of the mixture is not far from 1 to 1 uncle, and the particles have an average particle size measured in accordance with the laser scattering technique ranging from 0.1 to 5 Aya, 1 ^ η 芏 5 锨; and (b) At least one kind of lubricating material different from the plurality of discontinuous particles, and at least one kind of film forming material. In another specific embodiment, a fabric comprising at least one strand comprising a plurality of fibers has a resin compatible coating composition on at least a portion of the surface of the fabric, and the resin compatible coating composition includes, A plurality of discontinuous discontinuous particles formed from a material selected from organic materials, composite materials and mixtures thereof, and (b) to y kinds of lubricating materials different from a plurality of discontinuous particles. In another specific embodiment, a fabric comprising at least one strand containing a plurality of fibers has a resin compatible coating composition on the surface of at least _ but γ eight main ^ flying milk U y ^, the resin phase The coating composition comprises: a plurality of hollow organic particles; and (b) at least one polymer material different from the hollow organic particles. In another specific embodiment of the present invention, a woven fabric containing at least one strand containing a plurality of fibers, which has a resin phase at least in part

Capacitive coating, which has an ignition loss of 0.1 to M, and a gas permeability measured in accordance with ASTM D 737 of not more than 10 standard cubic inches per minute. As used herein, "breathability" refers to the air permeability of the fabric for air circulation. The air permeability can be measured according to the ASTM D 737 standard test method for air permeability of textile fabrics, which is specifically incorporated herein by reference. Therefore, the ingredients used in these specific embodiments may be selected from the coating ingredients discussed above 'and the other ingredients may also be selected from those listed above. In a preferred embodiment of the present invention, a method including the following steps is adopted. I __- 74-This paper size is applicable to the National Standard (CNS) A4 specification, Q χ tear public love-

1230698 A7

1230698 A7 B7 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (73) (C) At least a part of the sliding glass fiber strands contacts the rough surface of the solid object, and this rough surface has more than at least one glass The hardness 値 of the fibers 値 allows the at least one glass fiber of the at least one glass fiber strand to be prevented from being worn by the rough surface of the solid object by the coating composition. As above, the coating ingredients used in these specific embodiments may be selected from the coating ingredients discussed above, and the other ingredients may be selected from those listed above. Coated fiber strands 10,210,310 and products formed therefrom, such as the coated fabrics listed above, can be used in a wide range of applications, but are preferably formed as composites as a reinforcement 410 to reinforce the polymeric matrix material 412 414, as shown in FIG. 4, which is discussed in detail below. Such applications include, but are not limited to, laminates for printed circuit boards, reinforcements for communication cables, and various other composites. The coated strands and fabrics of the present invention are preferably compatible with the typical polymeric matrix materials used to make electronic supports and printed circuit boards. In addition, the coated fiber strands are suitable for use in air-jet loom commonly used to make reinforced fabrics for such applications. Conventional coatings on fibers spun using air-jet loom. High-end compositions include ingredients such as powder and oil that are not normally compatible with this resin system. It has been observed that the weaving characteristics of the fiber strands coated with the reed-coating composition containing the particles M according to the present invention are close to the coating of conventional starch / oil-based i, and the weaving characteristics of the fiber strands of the composition are similar to those of the FR_4 ring. Oxygen resin phase valley. Although it is not meant to be limited by any particular theory, it is believed that the 18 of the present invention, when treated and air jet weaving, is similar to the starch component of the conventional pulp composition by providing: the required fiber separation and air resistance This method works, but by providing and epoxy tree ______- 76- ^ paper size applies Chinese National Standard (CNS) A4 regulations; public hair ------------ ^ equipment ---- ---- Order --------- line (please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 123〇698 A7 ^^ ~ ----- V. Description of the invention (74) &quot;-'-Compatibility of the lipid system without acting in a manner different from conventional compositions. For example, particles 18 promote the dry, powdery characteristics of the dry lubrication characteristics of coatings similar to powder coatings. In the coated strands of the present invention, the particles may advantageously provide a gap between the fibers of the strands, which facilitates faster flow of the matrix material therebetween and / or even thirsts and drenches the fibers of the strands. In addition, the strands preferably have high strand openness (discussed above), which also anticipates the flow of matrix material in the bundle. Surprisingly, in certain embodiments, the amount of particles can exceed 20% by weight of the total solids of the coating composition applied to the fibers, while still properly adhering to the fibers and providing a coating having at least a particle free coating. Shares with similar processing characteristics. Referring now to FIG. 8, the coated strand of the present invention has the advantage that a laminate 810 made from a fabric 812 incorporating the coated strand can have a good coupling at the interface between the fabric 812 and the polymeric matrix material 8H. Good coupling ^ The electronic support 81S towel made from laminate SU) provides good hydrolytic stability and resistance to metal movement (discussed above). In another non-limiting specific embodiment shown in FIG. 5, the coated strand 510 made in accordance with the present invention can be used as a warp and / or weft strand 514 and 516 in a knitted or woven fabric 512 reinforcement, and is preferably formed Laminates for printed circuit boards (see Figure 7-9). Although not necessary, warp strands can be interwoven prior to use by any conventional weaving technique known to those skilled in the art. One such technique uses an interlaced frame to give the father weave of 0.5 to 3 turns per inch. The reinforcing fabric 512 preferably includes 5 to 100 warp strands per cm (approximately 13 to 254 warp strands per inch), and more preferably 6 to 50 weft strands per cm (approximately 15 per inch) To about 27 weft strands). Zhi-77 · This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public love) ~ '_ I ---— II ^ · 1111111 ·' (Please read the precautions on the back before filling this page ) 1230698 A7 B7 5. Description of the invention (75 plain weaves or grids (as shown in Figure 5), although any other weaving pattern known to the dagger artisan can be used, such as interlaced weaving or satin is more and more fibrous. The &quot; combined woven reinforced fabric buckle of the invention in the case may be formed by using any conventional loom known to those skilled in the art, such as a heart loom, air jet loom, or rapier weaving Cloth looms, but is preferably formed using air-jet looms. The preferred air jet looms are commercially available from Tsudakoma, Japan, Model 103, 1031, 1033, or ZAX. SUlZer RUti Model L-5_, Yi or L- 5200, which is commercially available from Zurich, Switzerland, Sulzer Brothers; and Toyoda model JAT610.} As shown in the figure, air jet weaving refers to the type of fabric weaving using an air jet loom (such as Figure 6), as discussed above, from a The strong compressed air 614 of more air jet nozzles 618 inserts the filling yarn (weft yarn) 610 into the warp shed (as shown in Figure 6 and Figure 仏). The filling yarn is pushed by the compressed air through the width 624 of the fabric 628 (about 10%). To about 60 inches), and more preferably 0.91 meters (about 36 inches). The gas jet filling system may have a single main nozzle 616, but preferably also has multiple auxiliary relay nozzles 62 along the warp shed 612 〇To provide strong auxiliary air 622 to the filling yarn 61, and maintain the air pressure required for the yarn 610 to cross the width 624 of the fabric 628. The air pressure (inner gauge) supplied to the main air nozzle 616 is preferably in the range of 1〇 3 to 413 仟 Baska (kP a) (about 15 to about 60 tellurium (psi) per square inch), and more preferably 310 kPa (about 45 ps 0 ° The preferred type of main air nozzle 616 is Sulzer Ruti Needle air-78- The paper size is applicable to China National Standard (CNS) A4 (21〇χ 297 mm) f Please read the precautions on the back before filling this page)

| -------- Order --------- line J Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698

= Shot unit model 044 455 001, which has a diameter of 2 mm 617 and a blade length of 621 &lt; an air jet groove inside the nozzle outlet pipe 619 (commercially available from Sulzer Ruti Company, Spartanburg, NC). Preferably, the air injection filling system has 15 to 20 auxiliary air nozzles 62o, which supply auxiliary air in the transverse direction of the filling yarn mo to help push the yarn 61o across the loom 626. The air pressure (gauge) supplied to each auxiliary air nozzle 62 is preferably in the range of 3 to 6 bar. The feeding system 632 draws the filling 610 from the supply package 630 at a feed rate of 180 to 5500 meters per minute, and preferably 274 meters (about 300 yards) per knife clock. The filling yarn 61 is fed into the main nozzle 618 through the splint. Strong air forces a yarn of a predetermined length (approximately equal to the desired fabric width) through the tube guide. When the insertion is completed, the yarn end at the end of the main nozzle 618 is cut by the cutter 634. The compatibility and aerodynamic properties of different yarns and air jet weaving processes can be determined by the following methods, which are roughly referred to herein as &quot; air jet transport resistance, &quot; test methods. Use air jet transport resistance to measure the force of attraction or pulling exerted on the yarn ("resistance,") when pulling the yarn into the air jet nozzle with the force of air spray. In this method, at 310 仟 Baska ( About 45 crabs per square inch) It's gas pressure, feed each yarn sample through the Sulzer Ruti needle air nozzle nozzle unit model 044 455 001 at a rate of 274 meters (about 300 yards) per minute, which An air jet groove (commercially available from Sulzer Ruti Corporation of Spartanburg, NC) with a nozzle exit tube 619 having a diameter of 617 mm and a length of 621 2 cm in diameter of 2 mm. The tensiometer contacts the yarn before the yarn enters the air injection nozzle. Tension The gauge provided yarn is pulled to the air jet-79- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm)

1230698

Mi

、 Explanation of the invention (At the angle of 77 °, the measurement of the gram force (resistance) of air spray on the yarn. The resistance per unit mass can be used as the basis for the relative comparison of the yarn samples. For the relative comparison, the resistance of the yarn of 1 cm in length will be passed The measurement is standardized. The gram mass of a yarn of 1 cm length can be determined according to Equation 2: gram mass = (7c (d / 2) 2) (N) (p material) (1 cm of yarn) (Equation 2) where d is The diameter of a single fiber in the yarn bundle, n is the number of fibers in the yarn bundle, and P is the density of glass at 25 ° C (about 2.6 grams per cubic centimeter). Table c lists many typical glass fiber yarn products. Fiber Diameter and Quantity in Yarn 〇Type of Fiber Diameter (cm) 9 X 10 'Quantity of Fiber in Bundle Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Employee Consumption Cooperative G75 400

For example, the gram mass of a G75 yarn with a length of 1 cm is (π (9 x 1〇 / 2) 2) (4〇0) (2.6 grams per cubic centimeter) (1 cm of yarn) = 6 62 χ 1 〇-4 g mass. For D450 yarns, the gram mass is 34 × 10-4 gram mass. Calculate the relative resistance per unit mass by measuring the resistance (gram force) measured by the tensiometer (gram force) divided by the gram mass of the type of yarn tested ("Air jet transportation resistance • 80- This paper size applies to China National Standard (CNS) A4 Specifications (210 X 297 public love 1 ---- * one----, ------------------ order --------- line ( Please read the notes on the back before filling this page) 1230698 A7 B7 V. Invention Description (78) (Please read the notes on the back before filling this page) Force "). For example, for G75 yarn, if the resistance is measured by tension If the amount is 68.5, the air jet transport resistance per gram of mass of yarn is equal to 68 $ divided by 6.62 X 1〇-4 = 103,474 grams of force. Measured in accordance with the air jet transport resistance test method discussed above to form The air jet transport resistance of the yarn of the invention-laminated textile fabric is preferably greater than 100,000 gf per gram of yarn, more preferably in the range of 100,000 to 400,000 gf per gram of yarn, and even more preferably The range is from 120,000 to 300,000 grams of force per gram of yarn. The fabric of the invention is preferably suitable for use in electronics Type textiles for laminates for support or printed circuit boards, as disclosed in "Fabrics Around the World", which is a technical bulletin from Clark-Schwebel, Anderson, SC (1995), which is specifically incorporated herein For reference, the laminate can be a unidirectional laminate in which most of the fibers, yarns, or strands of each layer of fabric are oriented in the same direction. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, for example, using E225 E-glass The non-restricted fabric type of fiber yarn is type 2116, which has 118 warp yarns and 114 filling yarns (or weft yarns) per 5 cm (60 warp yarns and 58 filling yarns per inch); use 7 22 ΐχΟ (E225 1 / 0) warp and filling yarn; has a nominal fabric thickness of 0.094 mm (about 0.037 inches); and a fabric weight (or basis weight) of 103.8 grams per square meter (about 3.06 ounces per square yard). Use G75 E -Non-limiting example of the fabric type of glass fiber yarn is 7628, which has 87 warp yarns and 61 filling yarns per 5 cm (44 warp yarns and 31 filling yarns per inch); use 9 68 1x0 G75 1/0 ) Warp and filling yarn; with 0.173 mm (about 0. 0068 inches) of nominal fabric thickness; and 203.4 grams per square meter (approximately 600 ounces per square yard) of weaving -81-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Invention Description (79) Material weight. A non-limiting example of a fabric type using D450 E-glass fiber yarn is the 1080 type, which has 118 warp yarns and% fill yarns for each 5 cm (60 warp yarns and 47 fill yarns); 5ii1x〇 (D45〇1 / 〇) warp and filling yarn; with a nominal fabric thickness of 0.053 mm (about 0.0021 inches); and a fabric weight of 46.8 grams per square meter (about 138 ounces per square yard). A non-limiting example of a fabric type using D900 E-glass fiber yarn is the 106 type, which has 110 warps and 110 fillings per 5 cm (56 warps and 56 fillings per inch); use 5 5 5 lx〇 (D9〇1 / 1 /) warp and filling yarn; has a nominal fabric thickness of 0.033 mm (about 0.013 inches); and a fabric weight of 24.4 grams per square meter (about 0.72 ounces per square yard) . Another non-limiting example of a fabric type using D900 E-glass fiber yarn is the 108 type, which has 118 warp yarns and 83 filling yarns per 5 cm (60 warp yarns and 47 filling yarns per inch); use 555lx2 (D9〇1 / 1 /) warp and filling yarn; has a nominal fabric thickness of 0.06 mm (about 0.0024 inches); and a fabric weight of 47.5 grams per square meter (about 丨 40 ounces per square yard) . A non-limiting example of a fabric type using D225 and D450 E_glass fiber yarn is type 2113, which has ι18 warp yarns and 110 fillers every 5 cm (60 warps and 56 fillers per inch); use 7 22 1x〇 (D225 1 / 〇) warp yarn and 5 11 lx0 (D450 1/0) filling yarn; has a nominal fabric thickness of 0.079 mm (approximately 0.0031 inches ...); and 780 g per square meter (each Square yards approximately 23 ounces) &lt; Fabric weight. A non-limiting example of a fabric type using G50 and G75 E_glass fiber yarn is type 7535, which has 87 warp yarns and 57 filling yarns (44 per inch) Warp yarns and 29 filling yarns); 9 68 1χ〇 (G75 1/0) warp yarns and 9 99 1χ〇 (G50 / 1 / 〇) filling yarns; with 〇02mm-82-lx 297mm) · -------- Order --------- Line 1 (Please read the notes on the back before filling this page) 1230698 A7 B7 V. Description of the invention (80) (about 0.0079) Inches) of nominal fabric thickness; and a fabric weight of 232.3 grams per square meter (approximately 6.85 ounces per square yard). (Please read the notes on the back before filling this page) These and other available fabric type specifications are shown in IPC-EG-140 &quot; Specification for Finished Fabric Woven from Έ1 Glass for Printed Boards &quot;, The Institute for Interconnecting and Packaging Electronic The Circuits publication (June 1997), which is specifically incorporated herein by reference. Although the aforementioned fabric types use interlaced yarns, it is intended to make these or other fabrics that use zero-interlaced yarns or spunbonds in combination with or instead of interlaced yarns in accordance with the present invention. In a specific embodiment of the present invention, some or all of the warp yarns in the fabric may have fibers coated with the first resin-compatible sizing composition, and some or all of the filling yarns may have a coating that is different from the first composition. The fiber of the second resin-compatible coating, that is, the second composition (1) contains at least one component that is chemically different from or in some forms different from that of the first sizing composition; or (2) is different from the first A sizing composition contains the same ingredient in an amount of at least one ingredient. 0 Referring now to FIG. 7, by coating and / or dipping with a matrix material, it is better to print as The polymeric film forms a thermoplastic or thermoset matrix material 716, and the fabric 712 can be used to form a composite or laminate 714. The complex or laminate 714 is suitable as an electron support. As used herein, "electronic support" refers to a structure that mechanically supports and / or electrically cross-links elements. Examples include, but are not limited to, active electronic components, passive electronic components, printed circuits, integrated circuits, semiconductor devices, and other hardware incorporating such components, including, but not limited to, connectors, sockets, clips, and heat sinks Device. -83- This paper size is in accordance with China National Standard (CNS) A4 specification (21 × 297 mm) 1230698 A7 _________B7_____ V. Description of the invention (SI) The preferred embodiment of the invention I relates to the reinforced composite, which contains to A portion of the fibers detailed above is coated with fiber strands. The invention is therefore intended to be a reinforced composite made from each disclosed fiber strand comprising a plurality of fibers. For example, a preferred embodiment of the present invention relates to a reinforced composite comprising a matrix material and at least one partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and having a temperature at 300 k Thin flat particles with a thermal conductivity of at least 1 watt per meter of K. Another preferred embodiment of the present month relates to a reinforced composite comprising at least partially coated fiber strands comprising a plurality of fibers, a coating comprising at least one thin flat particle, and (b) a matrix material. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least partially coated fiber strands comprising a plurality of glass-breaking fibers, a coating comprising a residue of an aqueous composition comprising a plurality of Non-continuous particles formed from a material selected from organic materials, inorganic polymeric materials, composite materials, and mixtures thereof; (η) at least one lubricating material different from the plurality of discontinuous particles; and (111) at least one film-forming material ; And (b) a matrix material. Another preferred embodiment of the present invention relates to a reinforced composite, which comprises at least one fiber strand and a matrix material, wherein the reinforced composite further comprises a residue of an aqueous composition, which comprises (a) a plurality of selected from organic materials, Discontinuous particles formed from materials of inorganic polymeric materials, composite materials, and mixtures thereof; (b) at least one lubricating material different from the plurality of discontinuous particles; and ⑷ at least one film-forming material. Another preferred embodiment of the present invention relates to a reinforced composite, which comprises at least partially coated fiber strands containing a plurality of glass fibers. -84-This paper size is applicable to China National Standard (CNS) A4 (Issued by 21CU 297)-&quot; .II '---.-------% C Please read the notes on the back before filling in this page) Order --------- line · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Continuous female, the particle has a Mohs hardness 値 of at least one of the glass fibers; and (b) a matrix material. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least one fiber strand and a matrix material comprising a plurality of glass fibers, wherein the reinforced composite further comprises a residue of an aqueous composition, which comprises greater than 20% by weight of discontinuous particles having a Mohs hardness 至少 of at least one of the glass fibers. An additional embodiment of the present invention relates to a reinforced composite comprising: at least one fiber strand comprising a plurality of glass fibers, and the coating of the strand comprises a plurality of fibers selected from the group consisting of organic materials, inorganic polymeric materials, composite materials, and mixtures thereof. A resin-compatible composition of discontinuous particles formed from a material, wherein the discontinuous particles have an average particle size of less than 5 microns; and ⑻ matrix material. Specifically, the plurality of discontinuous particles are formed of a material selected from any of the non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof. The components of the coating and resin-compatible composition used in the above specific embodiments of the reinforced composite may be selected from the coating components discussed above, and other components may also be selected from those listed above. Preferred matrix materials for use in the present invention include thermosetting materials, such as thermosetting polymers, ethyl acetate, epoxides (containing at least one epoxy or ethylene oxide group in the molecule, such as a polyhydric alcohol or sulfur Polyglycidyl ethers of alcohols), phenols, amine-based plastics, thermosetting polyurethanes, derivatives of any of the above, and mixtures of any of the above. Form a laminate for printed circuit boards-The paper size of the 85 sheet is applicable to China National Standard (CNS) A4 (210 X 297 mm) --I-, ------------- --Order --------- line (please read the notes on the back before filling this page) 1230698 A7 B7 V. Description of the invention (83) (Please read the notes on the back before filling this page) Preferred matrix materials are FR-4 epoxy resin (which is a multifunctional epoxy resin such as a difunctional brominated epoxy resin), polyimide, and a liquid crystal polymer. Such compositions are suitable for those skilled in the art. Is known. If further information on such a composition is required, see Electronic Materials Handbook ™, ASM International (1989) pages 534-537, which are specifically incorporated herein by reference. Non-limiting examples of suitable polymeric thermoplastic matrix materials include polyolefins, polyamides, thermoplastic polyurethanes and thermoplastic polyesters, ethylene polymers, and mixtures of any of the foregoing. Other examples of useful thermoplastic materials include polyimide, polyether, polyphenylene, polyetherketone, polyphenylene oxide, polyphenylene sulfide, polyacetal, polyethylene gas, and polycarbonate. ester. Preferred matrix material formulations include EPON 1120-A80 epoxy resin (commercially available from Shell Chemical, Houston, Texas), dicyandiamide, 2-methylimidazole, and DOWANOL PM glycol ether (commercially available from Michigan) The Dow Chemical Company, Midland, PA). Other components that can be included in the polymeric matrix materials and reinforcing materials in the printed consumer composites of the Intellectual Property Bureau of the Ministry of Economic Affairs include colorants or pigments, lubricants or processing aids, ultraviolet stabilizers, antioxidants, other Fillers and admixtures. In a preferred embodiment, the polymeric matrix material includes an inorganic material. These inorganic materials include ceramic materials and metallic materials, and may be selected from the inorganic materials detailed above. Fabric 712 may be coated and impregnated by dipping fabric 712 in a bath of polymeric matrix material 716, for example, as discussed in Microelectronics Packaging Handbook, (1989), R. Tummala (eds.), Pages 895-896, which Specifically incorporated herein by reference. More often, by hand or by yourself -86- This paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (84) The mixing device will cut short or continuous fibers The strand reinforcing material is dispersed in the base II, which distributes the reinforcing material substantially to all polymer matrix materials. The reinforcing material can be dispersed in the polymeric matrix material by „Yangxue”. Depending on the type of the polymeric matrix material used, the polymer matrix material 716 can be formed into a composite by many methods. Composites or laminates—for example, 'for thermoset matrix materials, composites can be compressed or injection molded, crushed, filament wound, manually stacked, money, or sheet molded or volume molded and then compressed or injection molded. Plastic. The thermosetting polymeric matrix material can be hardened by, for example, the matrix material including a crosslinking agent and / or applying heat. Suitable crosslinking agents for crosslinking the polymeric matrix material are as discussed above. The thermosetting polymeric matrix material The temperature and curing time depend on factors such as, but not limited to, the polymeric matrix material used, other additives in the matrix system, and the thickness of the composite. For thermoplastic matrix materials, suitable methods for forming the composite include direct molding or extrusion Compounding followed by injection molding. The method and device for forming a compound by the above methods are discussed in I. Rubin's Handbook of Plastic Welcome iMm〇k ^ (1990) 955-1062, l179-1215 and 122 Hong 1271 'which are specifically incorporated herein by reference. Additional specific embodiments of the present invention pertain to reinforcing laminates suitable for use in electronic supports, which include at least partially A coated fabric comprising at least one fiber strand in more detail. Therefore, the present invention is intended to be a reinforced laminate suitable for an electronic support made from each of the disclosed fabrics comprising at least one fiber strand. For example, the present invention The preferred embodiment is about -87- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm I *, · II I ---- III I ---- ^ ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by A7. It comprises a matrix material and at least one partially coated fabric comprising at least one fiber strand. This coating contains organic ingredients and thin flat particles with a thermal conductivity of at least 1 watt per meter K at a temperature of 300K. In it In other embodiments, the coating is compatible with a matrix material in a reinforced laminate suitable for use in electronic supports. An additional embodiment of the present invention relates to a reinforced laminate suitable for use in electronic supports. The composition comprises (a) a matrix material, and (b) at least one non-defatted fabric comprising at least one fiber strand, at least one portion of at least one fabric having a coating, and the reinforcement suitable for the electronic support. The matrix materials in the laminate are compatible. Another embodiment of the present invention relates to a reinforced laminate suitable for use in an electronic support, the laminate comprising a rhenium matrix material, and (b) at least one comprising at least one A fabric having fibrous strands and an unfinished resin-compatible coating composition on at least a portion of the surface of the fabric. Herein, a non-defatted fabric is used, which is a fabric which has not been subjected to a conventional fiber treatment for removing a non-resin-compatible sizing material from the fabric. As discussed above, in addition to washing, heat removal and water jet cleaning are examples of such conventional fiber treatments. As used herein, "untrimmed" resin-compatible coating composition refers to a resin-compatible coating composition discussed above that is not used in conventional fiber conditioning processes. For example, an untrimmed resin-compatible coating composition refers to the first, first, and / or third coating compositions discussed above, but does not refer to a typical trimmed sizing agent. For example, by Shi Xiyu coupling agent and water Manufactured and applied to fibers after degreasing. However, the present invention does intend the coating to include a resin compatible coating according to the present invention with a finishing paste applied to the coating. Another specific embodiment of the present invention is related to the formation of an electronic support. 88. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 public love) -----.---- ----------- Order --------- Line \ (Please read the notes on the back before filling this page) 1230698 A7 B7 V. Description of the invention (86) The method includes the steps of: (a) obtaining at least one filling yarn comprising a plurality of fibers by weaving and having a first resin-compatible coating on at least a portion of the at least one filling yarn, and at least one A fabric suitable for reinforcing electronic supports formed by a warp yarn comprising a plurality of fibers and having a second resin-compatible coating on at least a portion of at least one warp yarn; (b) coated with a matrix material resin at least in part At least a portion of the fabric; (c) at least partially hardening the at least partially coated fabric to form a prepreg layer; and (d) forming two or more prepreg layers together Suitable for laminates of electronic supports. The composition used for the coating of the above specific embodiments of the reinforcing laminate may be selected from the coating ingredients discussed above, and the other ingredients may be selected from the above. The specific embodiment of the additional car maker printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is related to the use of electrical pre-supports containing at least partially coated fabrics (including at least one of the fiber strands discussed in more detail). Dip yarn. Therefore, the present invention is intended to be a prepreg yarn for an electronic support made from each of the disclosed fabrics including at least one fiber strand. Another specific embodiment of the present invention relates to a prepreg yarn for an electronic support, the prepreg yarn comprising a ⑻ matrix material; and ⑻ at least one non-defatted fabric comprising at least one fiber strand, at least a portion of at least one fabric The coating has a coating that is compatible with the matrix material in the prepreg used in the electronic support. Another specific embodiment of the present invention is about the use of electronic support ~ 89-This paper size is applicable to China National Standard (CNS) A4 specifications. $ ------ A7

1230698 V. Description of the invention (87) Dip yarn, the prepreg yarn comprises a ⑷ matrix material; and ⑻ at least one type comprising at least one fiber strand and having an unfinished resin-compatible coating composition on at least a part of the surface of the fabric Fabric. As mentioned above, the components used for the coatings of the above specific embodiments may be selected from the coating components discussed above, and the other components may also be selected from those listed above. In the specific, non-limiting embodiment shown in FIG. 8, the composite or complex 810 includes a fabric impregnated with a compatible matrix material 814. The impregnated fabric is then squeezed between a set of metering rollers to leave a measurable matrix material and dried to form an electronic support in the form of a semi-hardened substrate or prepreg. The conductive layer 820 may be disposed along the side 822 of one part of the prepreg in the manner discussed in the following description, and the prepreg may be hardened to form an electronic support 818 having a conductive layer. In another embodiment of the invention, and more often in the electronics support industry, two or more prepreg yarns are combined with one or more conductive layers' and laminated in a manner known to those skilled in the art Together and hardened to form a multilayer electronic support. For example, without limitation, the present invention, prepreg yarn stacks can be laminated by compression stacking, for example, between polished steel plates' at a high temperature and pressure for a predetermined length of time to harden the polymeric matrix and form a laminate of a desired thickness. A portion of one or more of the prepreg yarns may have a conductive layer and harden before or after lamination such that the resulting electronic support is a laminate having at least one conductive layer along an exposed surface (below) It is called "surface-protecting laminate 11). The circuit is then formed from a single or multiple layers of electronic support using a technique known in the art to form an electronic support in the form of a printed circuit board or printed wiring board (in the following Roughly called "electronic circuit board". -90- ^ Paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) --------- Please read the note above first

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (88) Electronic support (which contains at least one fiber strand discussed in more detail), and electronic circuit boards. Therefore, the present invention is intended to manufacture electronic support bodies and electronic circuit boards from each disclosed fabric comprising at least one fiber strand. Another aspect of the present invention A specific embodiment relates to an electronic support, comprising: at least one non-defatted fabric comprising at least one fiber strand, at least a portion of at least one non-defatted fabric having a matrix material compatible coating; and At least one base material on at least a part of at least one fabric in the body. Additional specific embodiments relate to electronic braces, which comprise (a) to ^ containing at least one fiber strand and on at least a portion of the surface of the fabric Fabric with untrimmed resin-compatible coating composition; and at least one fabric in the electronic support At least one matrix material on at least one point. Another embodiment of the present invention is related to a method of forming an electronic support. The method includes steps. (A) Obtaining at least one filler containing a plurality of fibers by weaving Yarn and has a first resin-compatible coating on at least a portion of at least one filler yarn, and at least one warp yarn comprising a plurality of fibers and at least one blade of at least one warp yarn with a resin-compatible coating, And a fabric suitable for strengthening the electronic support; (b) at least partially coating at least part of the fabric with a matrix material resin; (c) at least partially hardening the coating to at least a part of the fabric to form a pre-form Dipping layer; and (d) laminating one or more prepreg layers with one or more conductive layers at-, ---.-------------- -Order --------- Line (Please read the precautions on the back before filling this page) -91-

1230698

V. Description of the invention (of) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs to form an electronic support. In a more preferred embodiment, &apos; at least one fabric and at least one matrix form a first composite layer in the electronic support. In another preferred embodiment, the electronic support further includes a second composite layer different from the first composite layer. An additional preferred embodiment relates to an electronic circuit board comprising a ⑷electronic support, which comprises ⑴at least one non-defatted fabric containing at least one fiber strand, and at least a portion of the at least one non-defatted fabric has a matrix material compatible A coating, and (ii) at least one matrix material on at least a portion of at least one fabric in the electronic support; and (b) a conductive layer, the support and the conductive layer are contained in the electronic circuit board. An additional preferred embodiment relates to an electronic circuit board comprising (a) an electronic support comprising (i) at least one containing at least one fiber strand and having unmodified resin compatibility on at least a portion of the surface of the fiber The fabric of the coating composition, and (ii) at least one matrix material on at least a portion of at least one fabric in the electronic support; and (b) the conductive layer, the support and the conductive layer are contained in an electronic circuit board. In a more preferred embodiment, a conductive layer is disposed in a selected portion of an adjacent electronic support. In another more preferred embodiment, at least one fabric and at least one matrix form a first composite layer. In another specific embodiment, the electronic support further includes a second composite layer different from the first composite layer. Preferably, a conductive layer is disposed on a selected portion of the first and / or second composite layer of the adjacent electronic support. Another specific embodiment of the present invention relates to a method for forming a printed circuit board. The method includes steps: -92- The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 丨 |; --- , --------------- Order --------- Line 0 (Please read the precautions on the back before filling this page) 1230698 A7 Β7

⑷ Get hunting by weaving at least one part containing at least one and at least one stuffing yarn with first-night and at least one mesh-containing coating with multiple fibers, and-partly With at least ^ layers of the second resin-compatible coating warp yarn, one or more of the electronic supports are formed to form a printed circuit board. <Patternized for: The specific implementation of the electronic support and electronic circuit board above is selected from the components discussed above, and other components can also be selected from the following. If desired, any convenient method known by this art may include, but is not limited to, mechanical drilling and laser drilling, to form perforations or holes (also known as, vias, etc.) in the electronic support to make The electrical support and / or components on the opposite surface of the electronic support are electrically interconnected. More specifically, referring to FIG. 1 (), the perforated contact extends through at least one layer 1062 of the fabric 1012 of the electronic support 1054 of the present invention. The coated fiber strand contains a plurality of glass fibers having layers compatible with various polymeric matrix materials. As shown herein, when the perforations 1060 are formed, the electronic support 1054 is placed in a perforation forming device, such as Drill cone or laser head. By using a drill cone or laser to form a perforation 1060 through a portion 1066 of at least one layer 1062 of the fabric 1012. In a preferred embodiment, 0.46 mm is used ( 0.018 inch) diameter tungsten carbide drill bit with a density of 62 holes per square centimeter (400 holes per square inch) and a plate load of 0.001 through a stack of 3 laminates I____ -93 -This paper size is suitable for _Home Standard (CNS) A4 size ⑵G χ Publication:.. -------- ^ --------- (Please read the notes on the back before filling this page) 1230698 A7 B7 V. Description of the invention (91) Drill 2000 holes Thereafter, the laminate has an error distance of no more than 36 microns. In additional embodiments, a 0.46 mm (0.018 inch) diameter carbide drill bit is used at 62 holes per square centimeter (400 holes per square inch) ) Hole density and plate load of 0.001, after drilling 2000 holes through a stack of 3 laminates, the laminate has a drill tool wear percentage of not more than 32%. In other specific embodiments, it will include inorganic lubrication The fluid flow of the agent is distributed near the perforation forming device, so that the inorganic lubricant contacts at least a part of the interface between the perforation forming device and the electronic support. Preferably, the inorganic lubricant is selected from the inorganic lubricants detailed above. The present invention Another specific embodiment relates to a method for forming a perforation of a fabric layer of an electronic system support through an electronic circuit board, comprising: (1) placing an electronic system support including a fabric layer (which is included in at least a portion of the fabric) Resin compatible on part surface A portion of the coated fiber strand of the layer composition, wherein the perforation is formed by a perforation forming device; and (2) the perforation is formed in the layer portion of the fabric. After the perforation is formed, a layer of conductive material is deposited on the perforated wall or Fill the perforations with a conductive material to facilitate the required electrical cross-linking and / or heat dissipation between one or more conductive layers (not shown in FIG. 10) on the surface of the electronic support 1054. The path partially or completely passes The electronic support and / or printed circuit board extends, which may be exposed on one or both surfaces of the electronic support and / or printed circuit board, or it may be completely hidden or contained in the electronic support and / or printed circuit board (Π hides the pathway ,,). The conductive layer 820 shown in FIG. 8 can be known to those skilled in the art ——_— ____- 94- This paper size towel _ home standard (CNS) A4 specification ⑽χ (Please read the precautions on the back before filling this page) Order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698

Invention Description (92) (Please read the note on the back? Matters before filling out this page) method. For example, without limitation, the present invention, the conductive layer may be formed by laminating a thin sheet of metal material or a pig on at least a part of a side surface of a semi-hardened or hardened prepreg or laminate. As an alternative, the conductive layer can be deposited using at least a portion of a semi-hardened or hardened prepreg or laminate by using known techniques, including but not limited to electroplating, electroless plating, or spraying. On the side. Suitable metal materials for the conductive layer include, but are not limited to, copper (preferably), silver, copper, gold, tin, tin-tin alloy, palladium, and combinations thereof. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In another non-limiting specific embodiment of the present invention, the electronic support may be a combination of Layers (the above) and / or one or more prepregs (the above) are laminated together to form a multilayer electronic circuit board. If desired, additional conductive layers can be added to the electronic support, for example, exposing the sides along a portion of a multilayer electronic circuit board. Furthermore, if desired, additional circuits may be formed from the conductive layer in the manner discussed above. It should be understood that, depending on the relative positions of the layers of a multilayer electronic circuit board, the board may have internal and external circuits. As previously discussed, additional perforations that partially or completely pass through the board are formed to electrically interconnect the layers at selected locations. It should be understood that the 'produced structure may have some perforations extending entirely through the structure, some only perforations through the structure, and some perforations entirely within the structure. Preferably, the thickness of the laminate forming the electron support 254 is greater than 0.051 mm (about 0.002 inches), and more preferably in the range of 0.13 mm (about 0.005 inches) to 2.5 mm (about 0.1 inches). For an eight-layer laminate of type 7628 fabric, the thickness is typically 1.32 mm (about 0.052 inches). The number of layers of fabric in the laminate may vary based on the desired thickness of the laminate. -95- This paper is compatible with China National Standard (CNS) A4 (210 X 297 mm) &quot; &quot; &quot; 1230698 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of Invention (93) The resin content of the substance is preferably in the range of 35 to 80% by weight, and more preferably 40 to 75% by weight. The amount of fabric in the laminate is preferably in the range of 20 to 65% by weight, and more preferably 25 to 60% by weight. For laminates formed from woven E-glass fabric and using FR-4 epoxy resin matrix with a minimum glass transition temperature of 110 ° C, according to IPC-4101 &quot; Specification for Base Materials for Rigid and Multilayer Printed Boards &quot; 20 pages, The Institute for Interconnecting and Packaging Electronic Circuits (December 1997), with a preferred minimum flexural strength greater than 3 X across the machine or width direction (approximately vertical to the longitudinal axis of the fabric, ie, in the filling direction) 107 kg / m2, more preferably greater than 3.52 X 107 kg / m2 (approximately 50 kpsi), and even more preferably greater than, 4.9 X 107 kg / m2 (approximately 70 kpsi). IPC-4101 is specifically incorporated herein by reference. In the longitudinal direction, the required minimum pull strength in the longitudinal direction (substantially parallel to the longitudinal axis of the fabric, that is, in the warp direction) is preferably greater than 4 X 107 kg / m2, and more preferably greater than 4.23 X 107 kg / Square meters. Flexural strength is measured in accordance with ASTM D-790 and IPC-TM-650 Test Methods Manual of the Institute for Interconnecting and Packaging Electronic Circuits (December 1994) (which is specifically incorporated herein by reference), and by following IPC -4101 section 3.8.2.4 completely removes the metal surface. The advantages of the electronic support of the present invention include high flexural strength (tensile and compressive strength) and high modulus, which can reduce the deformation of circuit boards (including laminates). According to the IPC test method 2.4.4.1 (which is specifically incorporated herein by reference), the electronic support in the form of a copper-based FR-4 epoxy-based laminate of the present invention-96- This paper standard is applicable to Chinese national standards (CNS ) A4 size (210 X 297 mm)-(---------- ^ install -------- order --------- line (please read the first Note: Please fill in this page again.) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 --------- B7 ------ V. Description of Invention (94) The z-direction (,, Z-CTE ''), that is, the thickness across the laminate, has a thermal expansion coefficient of from 50 ° C to 288. (: is from 0.001 to 5.0% by weight. Each The laminate is preferably an eight-layer 7628-type fabric, although, but not limited to, types such as 106-, 10-8, 1080, 2113, 2116, or 7535 fabrics may be used. In addition, laminates may be added to these Combination of fabric types. Laminates with a low coefficient of thermal expansion are generally less likely to expand and shrink and minimize board distortion. The present invention is more intended for the manufacture of multilayer laminates and electronic circuit boards, including at least one according to this The composite layer manufactured by the method, and at least one composite layer manufactured by a method different from the composite layer shown here, for example, 'using conventional glass fiber composite technology. More specifically and as familiar to those skilled in the art It is known to traditionally include starch / oil sizing agents including some or all of dextrinized or amylose starches, hydrogenated vegetable oils, cationic humectants, emulsifiers, and water, including but not limited to Loewenstein No. As disclosed in pp. 237-244 (3rd edition, 1993), which is specifically incorporated herein by reference, to process the fibers in the continuous glass fiber strands used to weave the fabric. The solution is then treated with a solution before weaving. Warp yarns made from these strands to protect the strands from abrasion during the weaving process, for example, poly (vinyl alcohol), as disclosed in U.S. Patent No. 4,530,876, Block 3, Lines 67 to 4, and Line 11, which are specifically disclosed in This is incorporated by reference. This operation is commonly referred to as yarn. Poly (acetalcohol) and powder / oil on beam materials are generally not compatible with the polymeric matrix materials used by the composite maker, so the fabric is removed to impregnate Self-breaking before weaving The glass fiber surface removes essentially all organic materials. It can be done in many ways, for example, by washing fabrics, or more often known by this technique --- --------------- Loading -------- Order --------- Line Win (Please read the precautions on the back before filling this page) -97-

1230698 A7 B7 V. Description of Invention (95) (Please read the precautions on the back before filling out this page) The method printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs heat-treated fabrics. As a result of the cleaning operation, there was no suitable interface between the polymeric matrix material used to impregnate the fabric and the surface of the cleaned glass fiber, making it necessary to apply a coupling agent to the surface of the glass fiber. This operation is sometimes called trimming by those skilled in the art. The coupling agent most commonly used in dressing operations is silicon sintering, which includes, but is not limited to, those disclosed in Silane Coupling Agents (1982), pp. 146 Plueddemann, which is specifically incorporated herein by reference. See also Loewenstein, pages 249-256 (3rd ed., 1993). After treatment with silane, the fabric is impregnated with a compatible polymeric matrix material, squeezed between a set of metering rollers, and dried to form a semi-cured prepreg yarn, as discussed above. It should be understood that the nature of the slurry, the removal operation, and / or the trimming step are considered in the present invention. One or more prepreg yarns incorporating conventional glass fiber composite technology can then be combined with one or more prepreg yarns incorporating the present invention to form the electronic supports discussed above, particularly multilayer laminates or electronic Circuit board. For more information on electronic circuit board manufacturing, see Electronic Materials Handbook ™, ASM International (1989) pages 113-115, Microelectronics Packaging Handbook by R. Tummala (editor), (1989) pages 858-861 and 895-909 MW Jawitz, Printed Circuit Board Handbook (1997), pages 9.1-9.42, and CF Coombs, Jr. (editor), Printed Circuits Handbook. (3rd edition, 1988), pages 6.1-6.7, which in particular It is incorporated herein by reference. The composites and laminates forming the electronic support of the present invention can be used to form packages for the electronics industry, more particularly the first, second and / or third layer packages, as disclosed in Tummala pages 25_43, which are particularly Ground is incorporated herein by reference. In addition, the present invention can also be applied to other packaging layers. -98- This standard is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1230698 A7 V. Description of the invention (% In a non-limiting specific embodiment, according to the present invention, 8 layers of prepreg yarn (which Manufactured from% 28 type, E • glass fabric, and fr_4 polymer resin with 14.0%) and in accordance with IPC_TM_65〇, No. 2 · 4 · 4 (which is specifically incorporated herein by reference) The flexural strength of the unprotected laminate tested is preferably greater than ιοο'οοο pounds per square inch (approximately 690 million pascals) when tested in the warp direction of four parallel objects, and in In the filling direction, it is preferably greater than 80,000 pounds (approximately 552 million pascals). In another specific embodiment of the present invention, according to the present invention, 8 layers are pre-π, ...: , E-glass fabric and fr_hepan resin with 14.0I), and use a span length to thickness ratio of 5 according to ASTM D 2344_84 (which is specifically incorporated herein by reference) Unprotected for the test The short-strand shear strength of the surface laminate is relatively low when the warp direction of the parallel fabric is 4¾. Pay more than% mash (about $ 1 million Baska) per square inch, and when tested in parallel with the filling direction of the fabric, preferably greater than 5600 pounds per square inch (about 39 million Baska) Thread In another specific embodiment of the present invention, according to the present invention, 8 layers of prepreg yarn (which is composed of 7628 type, E-glass fabric and FR with 1401 It is made of 4 poly mouth resins), and uses a span length to thickness ratio of 5 and a short beam shear strength of the unprotected laminate in accordance with ASTM D 2344-84 test after immersion in boiling water for 24 hours. For parallel fabrics, the warp direction is preferably greater than 5000 pounds per square inch (approximately 34 million psi), and for parallel fabrics, the fill direction is preferably greater than 4200 per square inch. Pounds (approximately 30 million Baska). The present invention also includes a method of strengthening the matrix material to form a composite. This method • 99-1230698 A7 B7

I. _ t --------- (Please read the notes on the back before filling this page) The method includes: (1) At least one of the first, second, and / or salty second coatings discussed in more detail A layer composition (containing particles that provide interstitial spaces between adjacent fibers of the strand) is applied to a fiber strand reinforcing material, (2) the coating is dried to form a coating on the reinforcing material; (3) the reinforcing material is combined with the matrix Materials; and, at least partially hardening the matrix material to provide a reinforced composite. Although not limiting the invention, the reinforcing material may be combined with a polymeric matrix material, for example, by dispersing it in the matrix material. Preferably, the coating forms a substantially uniform coating on the reinforcing material when dried. In a non-limiting embodiment of the invention, the particles comprise a size composition of at least 20% by weight based on total solids. In another non-limiting embodiment, the particles have a minimum average particle size of at least 3 microns, and preferably at least 5 microns. In other non-limiting embodiments, the particles have a Mohs hardness 小于 smaller than the Mohs hardness 値 of any glass-breaking fiber contained in the fiber strand. The present invention also includes a method for inhibiting adhesion between adjacent fibers of a fiber strand, comprising the steps of ... at least one of the second and / or third coating compositions discussed in more detail (which are included in the fiber phase of the strand) Provide space between the core particles) and apply to the fiber strands, and (2) dry the coating to form a coating on the fibers of the fiber strands so as to suppress adhesion between adjacent fibers of the strands. Comparison: For the coating to form a substantially homogeneous sentence on the reinforcing material when dried, the invention comprises a granular sizing composition of 20% by weight based on the total solids. In another non-limiting In the application, the particles have at least 3 micrometers' and preferably at least 5 micrometers.] The average particle size. For example, in the case of spherical particles, the particle diameter is the most equivalent. For example, in rectangular particles, the minimum flat == the average particle length, Width or height. In other non-restricted paper sizes, timely close the home (CNS) A4 secret (210 100-1230698 A7 B7 V. Description of the invention (98 embodiment, the particles have less than any broken glass contained in the fiber strands) The Mohs hardness of fibers 値 The Mohs hardness 値. The present invention also includes a method for inhibiting the hydrolysis of the matrix material of the fiber-reinforced composite. This method includes: (1) at least one of the first, second, and / or more detailed discussions A third coating composition (comprising discontinuous particles of greater than 20% by weight based on total solids) is applied to a fiber strand reinforcement material, (2) the coating layer is dried to form a coating on the reinforcement material; (3) combined reinforcement Materials and matrix materials; and (4) at least partially hardening the matrix materials to provide a reinforcing composite. Preferably, the coating forms a substantially uniform coating on the reinforcing material when dried. As discussed above, the reinforcing material may The matrix material is combined by, for example, dispersing the reinforcing material in the matrix material. In a non-limiting embodiment of the present invention, the fabric is preferably woven into a 7628 type fabric with less than 10 cubic feet per minute, and More preferably, a breathability of less than 5 cubic feet per minute, as measured by the ASTM D 737 standard test method for breathability of textile fabrics. Although not limited in the present invention, 'Comparing a variety of conventional fabrics made using sizing warp yarns, it is believed The elongation cross section and high openness of the warp yarn of the present invention (discussed in detail below) reduce the breathability of the fabric of the present invention. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, as previously discussed, in the conventional application of electronic bracing During the operation, the warp yarn is generally coated with sizing before the weaving to help prevent the warp yarn from sticking when weaving is too private. The sizing composition for sizing is generally The warp yarns are coated by passing the warp yarns through an immersion tray or bath containing sizing on a poly yarn and then passing one or more sets of squeeze rollers to remove any excess material. A typical sizing composition for a sizing yarn may include, For example, film-forming materials, plasticizers and lubricants. Commonly used in sizing yarns -101- this paper 7 Chinese National Standard (CNS) A4 specification (21G X 297 public love) &quot; --- 1230698 A7 B7 V. Description of the invention (99 ) (Please read the notes on the back before filling this page) The film forming material of the sizing composition is polyvinyl alcohol. After sizing, the warp yarn is dried and wound on the weaving shaft. The number and interval of warp yarn ends are determined by The type of textile fabric is determined. After drying, due to the combination of the first and the sizing yarn, the warp yarn of the sizing yarn generally has an ignition loss of more than 2.0%. Generally speaking, sizing on sizing and starch / oil on sizing are usually not compatible with the polymer resin materials of composite manufacturers when fabrics are used as reinforcements of electronic supports, making it necessary to impregnate textiles. The fabric is removed before the fabric to remove essentially all organic material from the surface of the glass fiber. This can be done in many ways, for example, by washing the fabric, or more often by heat treating the fabric by methods known in this technique. As a result of the cleaning operation, there was no suitable interface between the polymer matrix material used to impregnate the fabric and the surface of the cleaned glass fiber, making it necessary to apply a coupling agent to the surface of the glass fiber. This operation is sometimes called trimming by those skilled in the art. In general, trims provide a LOI of fabrics less than 0.1. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. After finishing with finishing slurry, the fabric is impregnated with a compatible polymeric matrix material, squeezed between a set of metered light, and dried to form a semi-cured prepreg yarn, such as Discussed above. For more information on the manufacture of electronic circuit boards, see Electronic Materials Handbook ™, ASM International (1989) pages 113-115, R. Tummala (ed.) Microelectronics Packaging Handbook. (1989) pages 858-861 and 895-909 M. W. Jawitz, Printed Circuit Board Handbook (1997), pp. 9.1-4.42, and C. F. Coombs, Jr. (editor), Printed Circuits Handbook. (3rd edition, 1988), 6. Pages 1-6 · 7, which are specifically incorporated herein by reference. -102- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) '1230698 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -103- A7 V. Description of the invention (100) A relatively thick coating is placed on the warp yarns, the yarns are harder and less flexible than the unsized warp yarns. Sizing on sizing yarns tends to hold the yarns together to form a tight bundle with a generally circular cross-section. Although it is not intended to limit the present invention, it is believed that such a yarn structure (i.e., a tight bundle and a substantially circular cross-section) may prevent the polymer resin material from penetrating the warp bundle when the processing step is continued, even if After removing the size from the sizing. 2. Although many yarns are not harmful to the present invention, sizing is not good. Therefore, in a preferred embodiment of the present invention, the warp yarn does not undergo the sizing step before weaving, and the sizing residue on the sizing yarn is substantially broadcast. The term "substantially none" as used herein means that the warp yarn has less than 20% by weight, and more preferably less than 5% by weight of beam residue on the yarn. In a more preferred embodiment of the present invention, the warp yarns are not subjected to the sizing step before weaving, and the essence ± no sizing yarn + aggregate material is left. The use of the I noun "essentially absent" herein means that the warp yarn has less than 0.5% by weight on its surface, more preferably less than (U% by weight, and most preferably "wt% I sizing residue on sizing yarn. However If the warp yarn is subjected to a second coating operation before weaving, it is preferable that the amount of the second coating layer applied to the surface of the warp yarn before weaving is less than 0.7% by weight of the sizing warp yarn. In specific embodiments, when weaving, the ignition loss of the warp yarn is preferably less than 2.5% by weight, more preferably less than 15% by weight, and most preferably less than 0.8% by weight. In addition, the fabric of the present invention is preferably In order to have a total ignition loss ranging from 0.1 to 1.6%, more preferably from 0.4 to 3%, and even more preferably from 0.6 to 1%. In another non-limiting embodiment of the invention, the warp yarns are Jiawei has a long cross-section and high openness. The term used here &quot; long cross 2 This paper size applies to China National Standard (CNS) A4 specifications (21G X 297 public love \. ------ -^ --------- (Please read the precautions on the back before filling out this page) Employees of Intellectual Property Bureau, Ministry of Economic Affairs, Consumption Printed by the agency 1230698 A7 ______ B7___ V. Description of the invention (101) Face •• indicates that the warp yarn has a substantially flat or oval cross-section shape. The open fibers of the high-stranded yarns discussed above are not held tightly together 'And the open space between one or more individual fibers facilitates the penetration of the matrix material into the bundle. The warp of the sizing yarn (as discussed above) usually has a circular cross section and low openness, which is not conducive to it. This penetration. Although not limited in the present invention, it is believed that by reducing or excluding the path of moisture entering the laminate and the electronic support, a good resin penetrates into the warp bundle at the time of lamination (ie, 'good' The resin wet through) can improve the total hydrolytic stability of the laminate and the electronic support manufactured in accordance with the present invention. It is useful for reducing the printed circuit board made of such a laminate and the electronic support due to exposure to wet conditions. The formation of conductive anode filaments under a bias voltage and the tendency of electrical short circuit failure can also have a positive effect. The degree of openness of the strand can be measured by the F-index test. In the F_index test, The yarn to be measured is arranged by a series of vertically aligned rollers, and a horizontally arranged sensing device adjacent to the light-emitting surface and the opposite photosensitive surface is arranged so that the vertical axis of the yarn is aligned with the light-emitting and photosensitive surface approximately in parallel. The sensing device is installed on the It is approximately half the vertical height between the vertically aligned rollers, and the horizontal distance between the yarn and the sensing device is controlled by moving the roller toward or away from the sensing device. As the yarn passes through the roller (generally about 30 meters per minute), Depending on the openness of the strand, one or more portions of the yarn can shield a portion of the light from the light-emitting surface, thereby triggering a response in the photosensitive device. Then the length of the special yarn (generally about 10 meters) ) The number of masks is tabulated, and the generated ratio (ie, the number of masks per unit length) is regarded as a measure of the openness of the stock. According to the tight warp structure of the fabric from the conventional sizing glass fiber yarn and ... -------- ^ --------- (Please read the precautions on the back before filling this page)

1230698 A7

I f Fee Five. Description of the invention (102) The low openness of this type of yarn (as discussed above) results in these conventional fabrics and have better fabrics than the present invention (preferably including long-shaped ❹faces and The experience: openness) high air permeability. In the non-limiting specific embodiment of the present invention, as measured by ASTMD 737 standard test method, the fabric has a sigh of no more than 1G standard cubic per square per minute. It is less than about 0.05 standard cubic meters per square meter per minute, more preferably not more than 5 cubic meters per square meter per minute (1.52 standard cubic meters per square meter per minute), and the best round per square meter per minute Breathability is not greater than 3 cubic sighs (about 0.91 standard cubic meters per square meter per minute). In another specific embodiment of the present invention, the fabric is woven into a fabric, and if A and D 737 Measured by the standard test method, with a sigh of less than ^ standard cubic British absorption per minute, more preferably not more than ϋ million British absorption per square per minute, and most preferably not more than a square foot per square per minute 3 feet Theoretical limit or limit in any way, it is claimed that warp yarns with long or average cross-sections can also improve copper mismatch performance in laminates made of warp yarns. More particularly, due to long cross-section warp yarns The intersecting point between the warp yarn and the filling yarn in the fabric is lower than that of the conventional fabric with a circular cross-section warp yarn. The cone of the woven fabric contacts very little glass fiber when drilling holes, so less wear occurs. As discussed previously, in the specific embodiment of the present invention, it is preferred that the warp yarn filling yarns each have a resin-compatible first coating composition that is applied during formation. Coating = yarn ^ fat compatible The coating composition may be the same as that of the resin phase coated with the filler yarn, or the layer composition, or it may be different from the resin coated with the resin. ----- (Please read the notes on the back before filling this page) ---- ^ --------- L ------- · 105-(CNS) A4 ^ (210 χΒΤϋι

I 1230698 V. Description of the invention (103) Compatible with the first coating composition. The term "resin-compatible first coating composition coated on warp yarns" is used herein to refer to the "resin-compatible first coating composition coated on warp yarns" meaning "the first coating applied to warp yarns" At least one component of the composition is present in an amount different from the first coating composition applied to the filling yarn, or at least one of the first coating composition applied to the warp yarn is not present in the coating applied to the filling In the first coating composition of the yarn, or at least one component applied to the first coating composition of the yarn-coating composition is not present in the first coating composition applied to the warp yarn. In another non-limiting embodiment, the glass fiber of the fabric is E_glass fiber with a density of less than 2.60 grams per cubic centimeter. In another non-limiting embodiment, when weaving into a ⑽-type fabric 'E-glass fiber yarns are manufactured with parallel warp yarns and tensile strength in the direction which are greater than the strength (warp direction) of the same type of conventional heat-cleaning toilet dressing fabrics. In another non-limiting embodiment of the present invention, it is preferred that the fat-compatible first coating composition is substantially free of &quot; adhesive &quot; film-forming material, that is, the first coating composition contains preferably Based on total solids less than 10% by weight, and more preferably based on total solids less than 5% by weight. Printed in a preferred embodiment of the resin-compatible coating composition in the preferred embodiment of the Intellectual Property Bureau of the Ministry of Economic Affairs. "Adhesive" film-forming material, that is, the first coating composition contains preferably less than 1% by weight based on total solids, more preferably less than% by weight based on total solids, and most preferably based on total solids. "% By weight of the adhesive film-forming material. Adhesive film-forming materials are harmful to the weaving power of the coated yarns because they reduce the air jet transport force of the yarn filling and cause the warp yarns to stick to each other. A specific, non-limiting example of an adhesive film-forming material is a soluble ring _______-106-κ paper size applicable to China National Standard (CNS) A4 specifications (21〇χ 297 mm 1230698 V. Description of the invention (ι〇4) oxygen Resin film-forming materials. See #Almost know the alternative method of fabrics used in the present invention to form fabrics for electronic supports. This method includes the steps of ... obtaining at least one filler yarn containing a plurality of glass fibers, and at least _ Partly apply a first resin-compatible coating; (2) Obtain at least one warp yarn comprising a plurality of glass fibers, and apply a second resin-compatible coating on at least a portion of the warp yarn; At least one filling yarn and at least one warp yarn to form a fabric having an ignition loss of less than 25% by weight, suitable for strengthening an electronic support. A method for forming a laminate suitable for an electronic support is now generally discussed. This method includes By weaving at least one filler yarn containing a plurality of glass fibers, and coating at least a portion of the first resin-compatible coating, and at least one warp yarn containing a plurality of glass fibers, and A second resin-compatible coating is applied on the portion; and the first step of forming the fabric, wherein the warp yarn has an ignition loss of less than 2.5% by weight during weaving. In a non-limiting specific embodiment of the present invention, the fabric essence is preferred No yarn is loaded on the top. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the conventional sizing composition coated on glass fiber and / or yarn in a typical fabric forming operation as previously discussed (ie The first sizing composition and the sizing composition are not resin compatible, so the fabric must be removed before the fabric is impregnated with a polymeric resin material. As discussed above, it is most often done by weaving Finished by thermal removal of the fabric. However, thermal removal degrades the strength of the glass fibers (and therefore the yarns and fabrics formed from it) and causes the glass to thicken. It does not require removal of the coating on the warp yarns before weaving and / Or the yarn-filled resin-compatible coating of the present invention, thereby eliminating the need for thermal removal. Therefore, in a preferred non-limiting specific embodiment of the present invention, the fabric is heat-treated and heat-reduced prior to impregnation— • 丄 'I paper size Be applicable China National Standard (CNS) A4 specification χ 297 Gong Chu 107 _ 1230698

Explanation of invention (105). In addition, in the process of fabric formation, after removing the upper group by heat removal (please read the precautions on the back before filling this page), you must apply the finishing slurry to the fabric before dipping. Improve compatibility between fabrics and polymeric resins. By applying a fat-compatible coating to the warp and / or filling before the weaving of the present invention, fabric trimming is also excluded. Therefore, in another preferred embodiment of the present invention, the fabric is preferably a solid residue from the second coating and / or finishing slurry, that is, less than 15% by weight, and more preferably less than 1 0% by weight of the money comes from the first coating and / or finishing coat. In a more specific implementation of the present invention, the residues from the second coating and / or trimming are broadcast on the property. The term "essentially" as used herein means that the fabric has less than 5% by weight, more preferably less than 0.5% by weight of residue from the second coating and / or finishing sizing. The invention is now described by the following specific non-limiting specific examples. Example 1 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The ingredients described in Table 1A were mixed in a manner similar to that discussed above to form an aqueous sizing composition according to the present invention. Less than 1% by weight of acetic acid is included in each composition. Aqueous sizing compositions A-F were applied to E-glass fiber strands. Each sizing-forming composition had 25% by weight solids. In a similar manner using a conventional interlacing device, each coated glass fiber strand is interlaced to form a yarn and wound on a bobbin. Sample Bva was coated with an aqueous polymeric composition B. , But dry at about 190 T for about 46 hours. Samples A-F each had less than 1 weight. /. The ignition loss is rampant. Samples Chi and Dhl each had ignition losses 1.5 of 1.59 and 1.66% by weight. -108 · This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 issued)-1230698 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (106)

Table 1A Ingredients% by weight based on total solids Sample composition ABCDEF RD-847A97 28.6 29.1 31.58 50.71 0 0 DESMOPHEN 200098 43.7 39.1 0 0 0 0 EPI-REZ 3522-W-6699 0 0 21.05 0 0 0 EPON 826100 0 0 0 0 16.12 63.54 PVP-K30101 0 9.7 15.79 15.21 1.31 5.18 A-187102 2.3 2.3 8.42 8.11 3.17 12.51 A-174103 4.7 4.8 0 0 0 0 A-1100104 0 0 8.42 8.11 0 0 PLURONIC F-108105 10.7 5.6 0 0 0 0 IGEPAL CA- 630106 0 0 4.74 6.39 1.63 6.44 VERSAMID 140107 4.8 4.8 0 0 0 0 ALKAMULS EL-719108 0 0 0 0 1.63 6.44 KESSCO PEG 600109 0 0 0 0 0.79 3.11 MACOLNP-6110 3.6 3.6 4.74 6.39 0 0 97 RD-847A polyester resin It is commercially available from Borden Chemicals, Columbus, Ohio, 0 98 DESMOPHEN 2000 polyethylene adipate, and is commercially available from Bayer, Pittsburgh, PA. 99 EPI-REZ 3522-W-66 commercially available from Shell Chemical Company of Houston, Texas 0 -109- This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm)-; ---,- ------ Cloth -------- Order --------- Line 0 (Please read the precautions on the back before filling this page) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Manufacturing A7 B7 V. Description of Invention (107) 100 EPON 826, commercially available from Shell Chemical Company of Houston, Texas. 1G1 PVP-K30 Polyethylpyrrolidone, commercially available from ISP Chemicals, Wayne, New Jersey 0 1G2 A-187 γ-dehydrated glycerylpropyltrimethoxysilane, commercially available from Tarrytown, New York CK Witco. 1G3 A-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York 0 1G4 A-1100 amine functional organic silane coupling agent, commercially available from Tarrytown, New York CK Witco Corporation 0 1G5 PLURONIC ™ F-108 poly (propylene oxide) polyethylene oxide copolymer commercially available from BASF Corporation of Parsippany, New Jersey 0 1G0 IGEPAL CA-630 ethoxylated octyl phenoxyethanol, commercially available Available from GAF Corporation of Wayne, New Jersey. 107 VERSAMID 140 Polyamine, commercially available from Cognis, Inc. of Cincinnati, Ohio ° 1Q8 ALKAMULS EL-719 polyoxyethylated vegetable oil, commercially available from Phone-Poulenc, Inc. 1G9KESSCO PEG 600 polyethylene glycol monolaurate Commercially available from Stepan Corporation of Chicago, Illinois. 11G MACOL NP_6 Nonyl Surfactant, commercially available from BASF Corporation, Parsippany, New Jersey 0-no- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------ _--------------- Order --------- line (please read the notes on the back before filling this page) 1230698 A7 ___B7 V. Description of the invention (1〇 8) Table 1A (continued) Ingredients% by weight based on total solids Sample composition ABCDEF EMERY 6717111 0 0 0 0 0.40 1.56 EMERY 6760112 0 0 4.21 4.06 0 0 POLYOX WSR-301113 0.6 0 0 0 0 0 POLARTHERM PT 160 114 1.0 1.0 0 0 74.78 1.00 RELEASECOAT-CONC 25115 0 0 1.05 1.01 0 0 (Please read the notes on the back before filling out this page) 111 EMERY⑧6717 Part of amidated poly (ethylene diimide), commercially available from Cognis, Inc. of Cincinnati, Ohio. 112 EMERY® 6760 lubricant, commercially available from Cognis, Inc. of Cincinnati, Ohio 0 113 POLYOX WSR-301 Poly (ethylene oxide), commercially available from Union Carbide, Danbury, Connecticut 〇114 POLARTHERM® PT 160 Boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. 0 Printed by ORPAC BORON NITRIDE RELEASECOAT-CONC 25, by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy. 25 Boron nitride granules in an aqueous dispersion. Commercially available from ZYP Coatings, Oak Ridge, Tennessee. Comparative samples of commercial products 631 and 633 D-450 coated starch and oil yarns; comparative samples of 690 and 695 coated starch-oil yarns, and comparative samples of 1383 G-75 yarns were also commercially available from PPG Industries. In addition, three comparisons were also tested for each coating of the same water-forming composition X described in Table IB below. -111- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) '1230698 A7 B7 V. Description of the invention (109) (Please read the notes on the back before filling this page) Samples XI, X2 and X3. Comparative sample XI had a solids content of 2.5% by weight. Comparative sample X2 had 4.9% by weight solids and was air-dried at 25 ° C for about 8 hours. Comparative sample X3 had a solids content of 4.6% by weight.

Table 1B Ingredients% by weight based on total solids Ingredient sample X RD-847A116 28.9 DESMOPHEN 2000117 44.1 A-187118 2.3 A-174119 4.8 PLURONIC F-108120 10.9 VERSAMID 140121 4.8 MACOL NP-6122 3.6 POLYOX WSR-301123 0.6 ii () RD- 847A polyester resin, commercially available from Borden Chemicals, Columbus, Ohio, printed by 117 DESMOPHEN 2000 Polyethylene Adipate, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs, commercially available from Bayer, Pittsburgh, PA 0 118 A-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 119 A-174 Gamma-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 12Q PLURONIC ™ F-108 Polyoxypropylene Polyethylene Oxide Copolymer, commercially available from BASF Corporation, Parsippany, New Jersey 0 -112- This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm) ) 1230698 A7 B7 V. Description of the invention (110) 121 VERSAMID 140 Polyamine, which is commercially available from Cognis Corporation of Cincinnati, Ohio 0 122 MACOL NP-6 nonylphenol surfactant, which is commercially available from Parsippany, New Jersey BASF company. 123 POLYOX WSR-301 Poly (ethylene oxide), commercially available from Union Carbide, Danbury, Connecticut. Assess the ignition loss (LOI) of the yarns of the sample AF and the comparative samples and use the "Air Jet Transport Resistance" test method discussed in detail above to evaluate the air jet compatibility (Air Drag). Each yarn sample was subjected to Sulzer Ruti needle air Spray unit model 044 455 〇001, which has an air spray slot inside a nozzle outlet pipe 619 with a diameter of 2 mm 617 and a length of 621 20 cm (commercially available from Sulzer Ruti, Spartanburg, NC) at 310 仟 Baska (Pay 45 pounds per square) The air pressure of the gauge is fed at a rate of 274 meters (300 yards) per minute. The tensiometer contacts the yarn before the yarn enters the air jet nozzle. The tension needle provides the yarn and is pulled to the air jet nozzle During the measurement of the gram force (resistance) of the air jet applied to the medium, these 値 are described in Table 1C below. -----, --------------- Order ---- ----- Line (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -113- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) 1230698 A7 B7 V. Description of Invention (111) Ministry of Economic Affairs Printed by the Consumer Property Cooperative of the Intellectual Property Bureau 1C Sample number Yarn type LOI (%) Resistance (gram force) Air jet transportation resistance (gram force per gram mass) A G-75 0.35 68.5 103,474 B G-75 0.30 84.9 128,248 B vac G-75 0.35 95.0 143,587 c D-450 0.52 37.33 278,582 D D-450 0.40 47.1 351,493 E G-75 0.35 79.3 119,789 F G-75 0.35 83.2 125,680 Comparative sample 631 * D-450 1.6 21.45 160,075 633 * D- 450 1.3 38.1 284,328 690 * G-75 1.0 108.23 163,489 695 * G-75 1.0 100.46 151,752 1383 G-75 0.75 14.47 21,858 XI G-75 0.33 36.4 54,85 X2 G-75 0.75 19.0 28,701 X3 D-450 1.37 12.04 89,851 Chi D -450 1.59 9.00 67,164 Chi D-450 1.66 10.43 77,836 Coated starch-oil sizing formula. As shown in Table 1C above, each coated polymer matrix material phase according to the present invention is -114- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm), '--------- --- r --- Order --------- line (please read the notes on the back before filling in this page) 1230698 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (η2 ) The yarn AF containing the sizing composition has an air jet transportation resistance 値 greater than 100,000. Commercial stocks sizing only with starch-oil have air jet transport resistances greater than 100,000, which are generally not compatible with the polymeric matrix materials discussed above. The sample yarns Chl and Dhl with a polymer matrix compatible coating have an air jet transportation resistance of more than 100,000 due to the high coating content on the yarn (ie, an ignition loss of more than 1.5%), which suppresses fiber separation by air spray Or the fibrillation of yarn. In order to evaluate the strength of the laminates, each of the samples of 695, Sample B and Sample Bvac G-75 seconds (discussed above) was formed into a Type 7628 fabric (the pattern parameters discussed above). Eight layers of each fabric sample were laminated with EPON 1120-A80 epoxy resin (commercially available from Shell Chemical, Houston, Texas), dicyandiamide, 2-methylimidazole, and DOWANOL PM glycol ether (commercially available from dense The Dow Chemical Co., Midland, Wis.) To form a laminate. The flexural strength (maximum damage) of each laminate was evaluated in accordance with ASTM D-790 and IPC-TM-650 Test Methods Manual of the Institute for Interconnecting and Packaging Electronics (December 1994), which is specifically incorporated herein by reference. Stress), which completely removes the metal finish by partially etching in accordance with IPC-4101, 3.8.2.4, and in accordance with ASTM D-2344, which is specifically incorporated herein by reference, using 15.9 mm (5/8 inches) ) Span and crosshead velocity of 1.27 mm (0.05 inch) per minute to evaluate laminate shear strength (short beam shear strength). The results of these evaluations are shown in Table 1D below. -115- ^ Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) —, —--------------- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 '-------- B7 V. Description of Invention (1U)

斫 Jingyou consists of a pair of conventional tension measuring devices (having a fixed chromium column of about $ cm (2 inches) in diameter that is installed in place of the 5 mm knife in a straight path between the tension measuring devices) at a distance of 274 meters per minute ( The sample was pulled at a rate of 300 yards, a tension of 30 grams was applied to each yarn sample, and samples A and B and comparative samples 1383 and friction were evaluated. The acrylic force difference is described in Table IE below. The friction force test is intended to simulate the friction force that the yarn receives during weaving operations. Abrasion testers were also used to evaluate the broken filaments of samples A and B and comparative samples 1383 and XI. When each test sample was pulled at a rate of 046 meters (18 inches) per minute through a wear test device for 5 minutes, a tension of 200 g was applied to each test sample, and two tests of each sample and comparative samples were evaluated, and the fibers were broken. The average number of filaments is reported in Table 1E below. The wear tester consists of two parallel rows of steel reeds, each row spaced 丨 inch apart. Each test yarn sample spiraled between two adjacent reeds in the first row of reeds, and then spiraled between two adjacent reeds in the second row of reeds, but shifted half an inch 忖 -116 between the two rows of reeds. · This paper size applies to China National Standard (CNS) A4 specification (21〇X 297 mm) --- ------ ^ --------------- Order --- ------ line (Please read the note on the back? Matters before filling out this page) A7

1230698 V. Description of Invention (II4) Distance. Reed at a rate of 240 revolutions per minute, parallel to the direction of yarn traverse, and back and forth at a length of 4 inches. Sample AB Comparative No. 1383 23.9 Comparative Sample No. XI 38.1 Friction (grams) 24.7 18.3 per yard Number of broken filaments of the yarn 2.0 1.0 3.8 1.0 As shown in Table 1E, when comparing the comparative samples, the samples A and b coated with the boron nitride-containing size composition according to the present invention had fewer broken fibers and Low friction. Example 2 The ingredients in the amounts described in Table 2A were mixed in a manner similar to that discussed above to form size compositions G and Η according to the present invention, and comparative samples. Acetic acid is included in each composition at less than 1 weight 0/0 based on the total weight. The aqueous sizing compositions ε and F in Example 1 of Table 1A, and the comparative sample Y of Table 2A were coated on a G-75 E-glass fiber strand. Each sizing composition has 6 to 25% by weight solids. ---------------------- Order --------- line · (Please read the precautions on the back before filling this page) Ministry of Economy Wisdom Printed by the Consumer Affairs Cooperative of the Property Bureau -117- This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (115) Table 2A Based on the total solids content by weight% Sample composition G Η Comparative samples Υ EPON 826124 16.12 63.54 60.98 PVP K-30125 1.31 5.18 4.97 ALKAMULS EL-719126 1.63 6.44 6.18 IGEPAL CA-630127 1.63 6.44 6.18 KESSCO PEG 600128 0.79 3.11 2.98 A-187129 3.17 12.51 12.00 EMERY 6717130 0.40 1.56 1.50 PROTOLU HD131 0 0 4.61 POLARTHERM PT 160132 0 0 0 RELEASECOAT-CONC 25133 74.78 1.00 0 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 124 EPON 826, which is obtained from Houston, Texas Shell Chemical Company. 125 PVP K-30 polyvinyl pyrrolidone, commercially available from ISP Chemicals, Wayne, New Jersey 0 120 ALKAMULS EL-719 polyethylene oxide vegetable oil, commercially available from Rhone-Poulenc, Inc. 127 IGEPAL CA -630 ethoxylated octylphenoxyethanol, commercially available from GAF Company 0 128 KESSCO PEG 600 polyethylene glycol monolaurate, Wayne, New Jersey, commercially available from Stepan Company, Chicago, Ill. -118-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (ιι〇129 A-187 γ-dehydrated glycerylpropyltrimethoxysilane, which Commercially available from CK Witco, Tarrytown, NY. (Please read the notes on the back before filling out this page.) 13G EMERY® 6717 Partially aminated poly (ethylene diimide), commercially available from Cognis, Cincinnati, Ohio. 131 PROTOLUBE HD high density polyethylene emulsion commercially available from Sybron Chemicals, Birmingham, New Jersey. 132 POLARTHERM® PT 160 boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. 133 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride particles in an aqueous dispersion, commercially available from ZYP Coatings, Oak Ridge, Tennessee. Interlacing each coated glass fiber strand to form a yarn and winding it in a similar manner using conventional interlacing devices On the bobbin. Samples F and Yarn of the Yarn showed minimal slipping when interlaced, and Samples E and G showed serious severity when interlaced. The slurry is falling off. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to evaluate the air resistance of the yarns of sample E-Η and comparative sample 以 in a manner similar to Example 1 above, except that the two spool samples are measured at the pressure shown in Table 2B. The air resistance 値. Use Shirley 84 041L broken filament detector, commercially available from SDL International, UK, to evaluate the average number of broken filaments per 1200 meters of yarn at 200 meters per minute. These 値Represents the average of the measurements made on the four spools of each yarn. Portions taken from all spools (136 g (3/10 lb) and 272 g (6/10 lb) of yarn unwound from the spool) were reported to be broken The filament tension is also evaluated. The tension of each yarn is also evaluated, and the test is described in Table 2B below. By -119- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1230698 A7 B7 V. Invention Explanation (in) 200 m / min. Unthread the yarn sample from the bobbin, spiral the yarn through a series of 8 parallel ceramic needles, and pass the yarn through the Shirley Broken Filament Detector discussed above to calculate the number of broken filaments. tension Measure the number of broken filaments 0-, ------------------- Order --------- line (Please read the precautions on the back before filling in this Page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -120- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of Invention (iu) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Consumption Cooperative Printed Table 2B Sample rupture filaments per meter of yarn EFG Η Comparative samples Υ All spools 0.887 0.241 greater than 10 0.065 0.192 136 g (3/10 lb) 0.856 0.017 greater than 10 0.013 0.320 272 g (3/10 Pound) 0.676 0.030 greater than 10 0.101 0.192 Gate tension (rounds per meter) Gate 2-0.039 _ 0.0235 0.721 Gate 3-0.025-0.028 0.571 Gate 4-0.0125-0.068 0.4795 Gate 5-0.015 0.093 0.85 Gate 6-0.0265-0.118 0.993 Gate 7-0.0695 Surface 0.31 1.0835 Gate 8-0.117-0.557 1.81 Air resistance (grams) 25 psi Spool 1-10.420-10.860 11.610 Spool 2-10.600-7.850 11.610 30 psi Spool 1-11.690-12.500 13.680 Spool 2-12.200 -8.540 13.850 35 psi line Shaft 1-13.490-14.030 15.880 Spool 2-13.530-9.570 15.630 40 psi Spool 1-14.740-14.110 17.560 Spool 2-14.860-11.010 17.610 45 psi Spool 1-16.180-16.390 19.830 Spool 2-16.680-12.700 18.950 50 psi Spool 1-17.510-19.280 22.410, spool 2-17.730-14.000 20.310 55 psi spool 1-19.570-23.350 29.350 spool 2-19.660-20.250 26.580 -121- This paper size applies to China National Standard (CNS) A4 (210 X 297 male) (Please read the notes on the back before filling this page) 1230698 A7 V. Description of the invention (II9) Although the test results shown in Table 2B clearly show that the sample E-Η according to the present invention has approximately higher gamma than the comparative sample γ It is believed that these results are not deterministic, as the polyethylene emulsion composition of Comparative Sample γ (not present in Sample E-Η) is believed to contribute to the abrasive properties of the yarn. Example 3 The ingredients are mixed in the amounts described in Table 3A to form the aqueous sizing compositions K to N according to the present invention. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 3A was applied to 2G_i8 E_ glass fiber strands. Each sizing-forming composition had 10% by weight solids. --------------------- Order --------- line (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumption Cooperatives -122- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (21〇χ 297mm) 1230698 A7 ___B7 V. Description of the invention (12) Table 3A The weight percentage of a certain solid component 1 product component K L Μ Ν Comparative sample 2 Thermoplastic polyurethane film-forming polymer 134 34.4 34.2 33.4 31.35 34.5 Thermoplastic polyurethane film-forming polymer 135 51.5 51.2 50.18 46.9 51.7 Polyoxyalkylene Polyol copolymer 0.3 0.3 0.3 0.3 0.33 Epoxidized polyester lubricant 7.2 7.1 7.0 6.55 7.22 γ-aminopropyltriethoxy crushing coupling agent 2.7 2.7 2.7 2.5 2.76 γ_pulsylpropyltriethoxygen Burning coupling agent 3.3 3.3 3.2 3.0 3.34 Amine functional organosilane coupling agent 0.1 0.1 0.1 0.1 0.14 RELEASECOAT-CONC 25136 0.1 1.0 2.9 9.1 0 Ignition loss (%) 1.11 1.14 1.05 1.08 1.17 (Please read the precautions on the back before filling (This page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 134 thermoplastic polyester based polyurethane aqueous emulsion with 65% solids, anionic particle charge, particle size of about 2 microns, pH of 7.5, and viscosity of 400 centipoise at 25 Ό (Brookfield LVF) . 135 thermoplastic polyester-based polyurethane aqueous emulsion has a solids content of 62%, a pH of about 10, and a particle size ranging from about 0.8 to about 2.5 microns. 136 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride particles in an aqueous dispersion commercially available from ZYP Coatings, Oak Ridge, Tennessee.

Composite samples and comparative samples of each of the above coated glass fiber samples Z -123- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (121) at 270 ° C was extruded at 7 MPa (975 psi) for 48 seconds to make a 254 X 254 X 3.175 mm (10 X 10 X 0.125 inch) board. Evaluate each sample at the glass content specified below ... Tensile strength, tensile elongation, and tensile modulus in accordance with ASTM method D-638; flexible strength and functional modulus in accordance with ASTM method D-790; and in accordance with ASTM method D -256 notched and unnotched Izod impact strength. Table 3B presents the results of tests performed on composites formed using conventional nylon 6,6 matrix resins. (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -124- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 __ _ B7 V. Description of the invention (m) Table 3B Sample unit KLMN Comparison of bred samples z Tensile strength kpsi 27.1 27.6 27.3 27.4 26.2 MPa 186.9 190.34 188.27 188.96 180.68 Tensile elongation 3.32 3.37 3.36 3.42 3.32 Tensile modulus mpsi 1.48 1.55 1.47 1.44 1.51 GPa 10.2 10.7 10.1 9.9 10.4 Flexible strength kpsi 44.6 46.3 45.7 45.5 44.0 MPa 307.6 319.3 315.2 313.8 303.4 Flexible modulus mpsi 1.52 1.56 1.54 1.54 1.5 GPa 10.5 10.7 10.6 10.6 10.6 Notched Izod impact ft lb / in 1.86 2.24 1.94 1.63 1.16 kJ / m2 7.89 9.50 8.23 6.91 4.92 Unnotched Izod impact ft lb / in 21.8 22.9 21.1 20.5 22.0 kJ / m2 92.43 97.10 89.46 86.92 93.28 Glass content% 32.9 32.6 32.4 32.3 32.4 As shown in Table 3B, the comparison is compared with similar components Samples (which are in (please read the precautions on the back before filling out this page) When the production bureau's consumer cooperative printed the resistance to boron nitride in the 6,6 reinforcement, the glass fiber strand (sample K_N) coated with boron nitride particles according to the present invention showed improved tensile strength and notch Impact properties, and similar tensile elongation and modulus, flexural strength and modulus, and notched Izod impact properties. No improvement in tensile strength and notched Izod impact properties was observed when nylon 6 resin was evaluated under similar conditions. -------- 125- Standard paper size (CNS) A4 size (x 297) (1230698 A7)

B. Description of the Invention (l23) Example 4 (Please read the precautions on the back before filling this page) Mix the ingredients in the amounts described in Table 4A to form the aqueous sizing composition P to S according to the present invention . Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 4A was applied to G-31 E-glass fiber strands. Each sizing-forming composition had 10% by weight solids.

Table 4A Ingredients% by weight based on total solids Sample composition P QRS Thermoplastic polyurethane film-forming polymer 137 23 28.75 28.75 23 Thermoplastic polyurethane film-forming polymer 138 34.45 43.1 43.1 34.45 Polyoxyalkylene Polyol copolymer 0.22 0.27 0.27 0.22 Epoxidized polyester lubricant 4.8 6.0 6.0 4.8 γ-aminopropyltriethoxy petrolatum coupling agent 1.84 2.3 2.3 1.84 γ-cholylpropyl triethoxy petrolatum coupling agent 2.22 2.78 2.78 2.22 Amine-functional organosilane coupling agent 0.1 0.12 0.12 0.1 POLARTHERMPT 160 139 33.3 16.7 0 0 Printed as a 137 thermoplastic polyester-based polyurethane emulsion based on the printing of 137 thermoplastic polyester by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. % Solids, anionic particle charge, particle size of about 2 microns, pH of 7.5, and viscosity of 400 centipoise at 25 ° C (Brookfield LVF). 138 thermoplastic polyester-based polyurethane aqueous emulsion, which has 62% solids, a pH of about 10, and granules ranging from about 0.8 to about 2.5 microns. 126- This paper applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 ΚΙ_Β7_ V. Description of the invention (l24) degrees. 139 POLARTHERM® PT 160 boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. Table 4A (continued) Composition weight based on total solids ° / 〇 Sample composition PQRS VANTALC 2003 140 0 0 16.7 33.3 Ignition loss (% ) 0.52 0.81 0.80 0.64 14G VANTALC 2003 talc powder particles, commercially available from R · T. Vanderbilt, Norwalk, Connecticut 0 Composite samples and comparative samples of each of the above coated glass fiber samples Z Extrusion molding was performed under the conditions described above to make 400 X 400 X 2.5 mm (16 X 16 X 0.100 inch) boards. Each sample was evaluated at the glass contents specified below: tensile strength, tensile elongation, tensile modulus, notched and unnotched Izod impact strength, as discussed in Example 3 above. The color test was performed on a compound having a thickness of 3.175 mm (1/8 inch) and a diameter of 76.2 mm (3 inches) using a Hunter colorimeter D25-PC2A. To evaluate material handling characteristics, funnel flow tests were performed on chopped glass fiber samples. The funnel is 18 inches long and has a 17 inch diameter opening at the top and a 2 inch opening at the bottom. The funnel was shaken and the time it took for 20 pounds of sample material to flow through the funnel was recorded. The PD-104 test evaluates the resistance of chopped glass fiber samples to fibrillation. 60 grams of samples, 140 grams of -127- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------------------- Order --------- line &quot; ^ · (Please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of the invention (125) Abrasive material (ground walnut bark particles 6 / view , Both of which

Hammon Products), and the conventional foam-type antistatic drying gas was self-closing in a 4 liter stainless steel beaker, and used RedDevU coating 22 = 54 for 6 minutes. Use No. 5 and No. 6 American Standard Test Sieves: Select warped materials. The weight% of fine wool material collected on the sieve is reported below as a percentage of the original sample. Table 4B presents the results of tests performed on composites formed using sample P_S and comparative sample z using nylon 6,6 matrix resin. ---.------------------ ^ --------- Line (Please read the notes on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 128- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (l26)

Table 4B Sample unit PQRS comparison hybridized sample z Tensile strength kpsi 29.5 28.6 28.7 27.7 29.6 Mpa 203.5 197.2 197.9 191.0 204.1 Tensile elongation 3.03 3.05 2.98 2.97 3.01 Tensile modulus kpsi 1866 1779 1720 1741 1748 Gps 12.86 12.26 11.86 12.0 12.05 Notched Izod Impact ftlb / in 2.10 1.96 1.94 1.78 2.26 kJ / m2 8.90 8.31 8.23 7.55 9.58 Unnotched Izod impact ftlb / in 24.9 23.4 22.8 22.2 26.4 kJ / m2 105.58 99.22 96.67 94.13 111.94 Actual ignition loss% 0.81 0.52 0.80 0.64 1.17 PD 104% 1.3 0.7 0.1 1.4 0.1 Funnel flow seconds 13.8 15.2 15.4 23.5 13.0 Whitening index -15.1 -12.0 -17.6 -18.5 -18.2 Yellowing index 40.0 37.5 42.5 43.4 43.6 Glass content% 33.30 33 \ 32.90 31.70 33.80 As shown in Table 4B, When comparing a comparative sample Z having similar composition (which does not contain nitride 1 in the resistant 6,6 reinforcement), the glass fiber strand (sample PS) coated with boron nitride particles according to the present invention showed an improvement Whitening and yellowing, and similar tensile strength, elongation and modulus, flexural strength and modulus, and notched and unnotched S impact properties. -129-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)-? ------------------ Order ------ --- Line (please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of the Invention (l27) Example 5 Mix the ingredients in the amounts described in Table 5 to form the aqueous formulation according to the present invention. Pulp compositions T and U. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Table 5 A proposes whitening and yellowing tests on composites formed using nylon 6,6 matrix resin using samples T, U and comparative samples Z (as discussed in Table 3A of Example 3 and repeated below) result. The color test was performed on a compound having a thickness of 3.175 mm (1/8 inch) and a diameter of 76.2 mm (3 inch) using a Hunter colorimeter D25-PC2A. (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Consumption Cooperatives Table 5 Based on the total solids content% by weight Sample composition T U Comparative sample Z Thermoplastic polyurethane film formation polymerization 141 31.35 28.75 34.5 Thermoplastic polyamine film-forming polymer 142 46.9 43.1 51.7 Polyoxyalkylene polyol copolymer 0.3 0.27 0.3 Epoxidized polyester lubricant 6.55 6.0 7.22 γ-aminopropyltriethoxy Keystone oxane coupling agent 2.5 2.3 2.76 γ-Pyrimylpropyltriethoxy stone oxane coupling agent 3.0 2.78 3.34 Amine functional organosilane coupling agent 0.1 0.12 0.14 RELEASECOAT-CONC 25143 9.1 16.7 0 Whitening index -16.3 -15.0- 20.7 Yellowing Index 39.3 38.1 42.7 -130- The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (128) (Please read the precautions on the back before filling in this Page) 141 thermoplastic polyester-based polyurethane aqueous emulsion, which has 65% solids, anionic particle charge, particle size of about 2 microns, pH of 7.5, and A viscosity of 400 centipoise at 5 ° C (Brookfield LVF). 142 thermoplastic polyester is a main polyurethane aqueous emulsion having 62 solids%, a pH of about 10, and a particle size ranging from about 0.8 to about 2.5 microns. 143 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles as an aqueous dispersion are available from ZYP Coatings (Oak Ridge, Tennessee). As shown in Table 5, samples T and U, each of which was coated with a boron nitride-containing particle size composition according to the present invention, had similar formulations in nylon 6,6 than comparative sample Z (which does not include nitrogen Boron) low whitening index. Example 6 An ADFLO-C ™ needle-shaped chopped fiberglass web printed with five layers stacked by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics was commercially obtained from PPG Industries to form a product having 4,614 grams per square meter (per square inch). About 15 ounces) of surface weight. The thickness of each sample was 25 mm (about 1 inch). Four 8-inch square samples of this mesh were heated to a temperature of 649 ° C (approximately 1200 T) to remove essentially all sizing components from the sample. Two uncoated samples were used as comparative samples ("comparative samples"). The other 2 samples (&quot; Sample X &quot;) were immersed in 1150 ml of ORPAC BORON NITRIDE RELEASECOAT-CONC (a dispersion of 25% by weight of boron nitride particles in water) and 150 ml of A-187 γ-go Water glycerylpropyltrimethoxysilane in a 5% by weight aqueous solution of an aqueous coating composition in a bath • 131-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 V. Invention Note (l29) (Please read the notes on the back before filling this page) and it is saturated. The total solids of the aqueous coating composition was 18.5% by weight. The amount of boron nitride particles coated on each mesh sample was 120 g. The coated web samples were dried in air at 25 ° C overnight and heated in an oven at 150 ° C for 3 hours. According to ASTM method C-177, which is specifically incorporated herein by reference, the thermal conductivity and heat resistance of each group of samples at a temperature of 300K (about 70 ° F) were evaluated. The thermal conductivity and heat resistance of each sample are described in Table 6 below. Table 6 Sample X Comparative sample thickness (pair) 1.09 1.0 (cm) 2.77 2.54 Temperature (° F) 75.62 74.14 (° C) 24.23 23.41 Thermal conductivity square foot per hour ° Fibtu inches 0.373 0.282 Watts per meter K 0.054 0.041 Heat resistance 2.92 square feet per hour of BTU 2.66 3.66 square meters per watt K 0.515 0.626 Reference Table 6 printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the test sample for coating boron nitride particles according to the present invention is 300K. The thermal conductivity at temperature is greater than the thermal conductivity of a comparative sample that is not coated with boron nitride particles. -132- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (130) Example 7 A G-75 yarn of size G and a sample of 1062 glass fiber yarn commercially available from PPG Industries were used to prepare a cylindrical composite of wound filaments. A cylinder is prepared by extracting 8 yarn ends from a yarn supply, coating the yarn with a matrix material described below, and winding the yarn filaments into a cylindrical shape using a conventional filament winding device. Each cylinder is 12.7 cm (5 inches) tall, has an inner diameter of 14.6 cm (5.75 inches), and a wall thickness of 0.635 cm (0.25 inches). The matrix material is 100 parts of EPON 800 resin (commercially available from Shell Chemical, Houston, Texas), 80 parts of AO220J methyltetrahydro S tetraacid (commercially available from Anhydrides and Chemicals, Newark, New Jersey), and 1 part mixture of ARALDITE® DY 062 benzyldimethylamine accelerator (commercially available from Ciba-Geigy). The filament winding cylinder was hardened at 100 ° C for 2 hours and then at 150 ° C for 3 hours. The radial direction of each test sample in air was measured by exposing one side of the cylinder wall of the sample to a 6.4 仟 Joule flashlight, and using a CCD array infrared camera to detect temperature changes on the opposite side at a rate of 2000 frames per second. Thermal diffusivity (thermal conductivity / (heat capacity X density)). The thermal diffusivity 测定 is also measured along the length of the yarn (circle) and along the length or height of the cylinder (axial). The test results are described in Table 7 below. -133- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order ------- --Line (Please read the precautions on the back before filling this page) 1230698 A7 V. Description of the invention (131) Table 7 Thermal diffusivity (mm2 / s) Sample around the radial axis 0.37 0.33 0.49 Comparative sample 0.38 0.38 0.57 Referring to Table 7, the thermal diffusivity of the test sample (which is coated with a small amount of boron nitride) is smaller than that of a comparative sample that is not coated with boron nitride. Air holes in the filament winding cylinder and small test sample area are factors that affect these results. Example 8 Lamination of 7628 fabrics each containing 8 layers of Bvac-coated yarn (discussed in Example 1) and 695 powder-oil-coated yarn (discussed in Example 丨) (control) Coefficient of thermal expansion ("Z_CTE") of the laminate in the z-direction (ie, across the thickness of the laminate). Laminates were prepared using the FR-4 epoxy resin discussed in Example 1 and were in accordance with the ipc test method 2.4.41, which is specifically incorporated herein by reference with a copper finish. The thermal expansion coefficient of each laminate sample in the ζ-direction of 288 was evaluated according to the IPC test method 2.4.41. The evaluation results are shown in Table 8 below. (Please read the precautions on the back before filling this page) --------- Order ---------. Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -134- Paper size applicable China National Standard (CNS) A4 Specification (210 X 297 mm) 1230698 A7 V. Description of Invention (I32) Sample Sample Bvac Sample U (Retry) Sample Bvac Sample Bvac2 (Retry) Inlet Bvac Sample Bvac3 (Retry ) Control 2 as shown in the table

It is shown that the thermal expansion coefficient in the z-direction for the laminate according to the present invention is smaller than that of the control samples 1 and 2. 4〇〇4 ^ 06ill 4 ^ 26 5.4 Preparation of A1-A3, laminated oil-coated yarn (please read the precautions on the back before filling this page) Example of printing printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 9 Mixed form The ingredients are in the amounts described in 9A to form the aqueous first sizing compositions AA, BB and CC according to the present invention. Each aqueous first sizing composition was prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 9A was coated on G-75 E-glass fiber strands. Each coated fiber strand was dried, interlaced in a similar manner using conventional interlacing equipment to form a yarn, and wound on a bobbin. The sizing composition-coated yarns exhibited minimal shedding when woven. -135- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 public love) 1230698 A7 ___B7 V. Description of the invention (l33) Table 9A Based on the total solids content by weight% Sample composition AA BB CC PVP Κ-30144 14.7 14.7 13.4 STEPANTEX 653145 30.0 29.9 27.3 A-187146 1.8 1.8 1.6 A-174147 3.7 3.7 3.3 EMERY 6717148 2.4 2.4 2.2 MACOL ΟΡ-ΙΟ149 1.6 1.6 1.5 TMAZ-81150 3.3 3.3 3.0 MAZUDF-136151 0.2 0.2 0.2 ROPAQUE HP-1055152 0 42.4 0 ROPAQUE OP-96153 42.3 0 38.6 REKEASECIAT-CONC 25154 0 0 6.3 POLARTHERMPT 160155 0 0 2.6 — ·· ——--------------- Order --------- line (Please read the notes on the back before filling out this page) Printed 144 PVP K-30 Polyvinylpyrrolidone by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy, commercially available from ISP Chemicals, Wayne, New Jersey 0 145 STEPANTEX 653, commercially available from Stepan Corporation of Maywood, New Jersey. 140Α-187γ-Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 147 A-174 γ-methacryloxypropyltrimethoxysilane, commercially available from New York CK Witco Company, Tarrytown, 0 -136- This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (134) 148 EMERY® 6717 Partially Aminated Polyethylene Diimide, commercially available from Cognis Corporation of Cincinnati, Ohio 0 149 MACOL OP-10 ethoxylated phenol; this material is similar to MACOL OP-10 SP, except for MACOL OP-10 SP Post-treatment to remove catalyst; MACOL OP-10 is no longer commercially available. The 15G TMAZ-81 anisocyanate cyclic gas ethane derivative is commercially available from BASF Corporation, Parsippany, New Jersey. 151 MAZU DF-136 antifoam, commercially available from BASF Corporation, Parsippany, New Jersey. 152ROPAQUE® HP-1055, a 1.0 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 153 ROPAQUE® OP-96, 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 154 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, commercially available from ZYP Coatings, Oak Ridge, Tennessee. 155POLARTHERM ™ PT 160 boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. When using a Sulzer Ruti Model 5200 air jet loom to weave a Model 7628 fabric, various sizing compositions (AA, BB With CC) sizing yarn as filling yarn. Interlaced G-75 E-glass fiber strands 156 of fiber coated with different resin compatible sizing composition. The fabric was then pre-impregnated with a FR-4 epoxy resin (codename 4000-2 resin from Nelco International, Inc., Anaheim, CA) with a Tg of 140 Ό. The sizing composition was not removed from the fabric before prepreg. By stacking 8 layers of prepreg between 2 layers of 1 ounce copper, and -137 · This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --'----- ------------- Order --------- Line (Please read the notes on the back before filling this page) 1230698 A7 ___ ^ _____ V. Description of the Invention (l35) ( Please read the notes on the back before filling this page.) Laminate it at a pressure of 300 pounds per square inch (approximately 2.1 million Baska) at a temperature of 355 ° F (about 179 ° C). Laminates were prepared together for 159 minutes (total cycle time). The thickness of the laminate without copper ranges from 0.043 inches (about 0.11 cm) to 0.050 inches (about 0.13 cm). After formation, the laminates were tested as shown in Table 9B below (the fiber strands from which they are made are referred to as AA, BB, and CC). At the time of the test, when the first laminate made of glass fiber yarn was coated with a sizing composition sample AA (hereinafter referred to as a laminate sample AA1), the laminate BB was simultaneously tested. Later, when a second laminate made of glass fiber yarn was coated with a sizing composition sample CC (hereinafter referred to as a laminate sample AA2), the laminate CC was simultaneously tested.

Table 9B Laminate sample test unit AA1 * BB * AA2 ** CC ** average thickness inch 0.048 0.048 0.053-0.055 0.053-0.055 solder float seconds 409 386 235 253 solder immersion seconds 320 203 243 242 flexural strength Warp yarn direction 157 kpsi 99 102 91 90 Flexible strength Weft yarn direction 158 kpsi 86 81 73 72 Based on 2 samples. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 45 based on 3 samples. This warp yarn is a commercially available fiberglass yarn product 'code G-75 glass fiber yarn from PPG Industries, which is coated with an adhesive from PPG Industries. 157

Per IPC-TM-650 &quot; Flexural Strength of Laminates (At Ambient _138 * This paper size applies to China National Standard (CNS) A4 (21〇 x 297 mm) 1230698

V. Description of the Invention (l36) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Temperature) &quot;, 12/94, revision B. 158 same chapter. By floating a 4 inch by 4 inch square (10 16 cm by 1016 cm) copper cladding laminate in a 550 T (approximately 288 ° eutectic lead_tin tin bath) until observed Solder float test until blistering or separation. Then record the time in seconds until the first blistering or separation. By cutting the sample of the laminate, remove the copper from the sample by etching, and polish the cut edge of the sample. Smooth and the solder immersion test was performed by placing the sample in a pressure cooker at 25 τ (about 121 and 15 pounds per square inch (about 0.1 million Baska)) for 60 minutes. This test is shown in the table below The so-called pressure cooker test. After 60 minutes of exposure, remove the sample from the pressure cooker, pat it dry and immerse it in a 55 ° F (about 288 C) eutectic lead-tin solder bath until blistering or separation is observed. Then record until The time in seconds for the first foaming or separation. The flexibility test was performed in accordance with the IPC standard shown. Laminates ΑΑ, ΒΒ and CC made from the fiber strands on each of the sizing compositions ΑΑ, Β, and cc have the following functions: Acceptable properties of electronic supports for printed circuit boards (as shown in Table 9B). The following tests were performed on samples ΑΑ, ΒΒ and CC, and are described in Table 9C. -139- This paper size applies the Chinese National Standard (CNS) A4 specification (21〇X 297 mm). -------- Order --------- Thread # (Please read the notes on the back before filling this page) 1230698 A7 ____B7 V. Description of the invention (137) __ Table 9C Sample test unit AA BB CC Tg by DSC 0/30 / 60 min ° C 141/140/139 140/141/141 138/140/139 Water absorption of pressure cooker 0.37 0.37 0.38 Water resistance 159 Weight increase 0.12 0.09 0.09 Weight increase of DMF resistance 0.35 0.27 0.29 MeC12 Antibiotic 16 () Weight increase % 0.77 0.82 0.68 Copper peel strength 161 (warp / filled yarn) pounds 11.8 / 11.0 12.1 / 11.1 11.2 / 11.4 interlayer adhesion strength 102 pounds per inch 12.8 14.2 15.4 (please read the precautions on the back before filling in this Page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 159 According to IPC-TM-650, No. 2.6.2.1, &quot; Water Absorption, Metal Clad Plastic Laminates &quot;, 5/86, Revised Version A. According to IPC-TM- 650, No. 2 · 3 · 4 · 3 · &quot; Chemical Resistance of Core Materials to Methylene Chloride &quot;, 5/86 ·

161 According to IPC-TM-650, No. 2.4.8, 'Teel Strength: As Received, After Thermal Stress, After Process Chemicals &quot;, 1/86, Rev. B 0 162 According to IPC-TM-650, No. 2.4. 40, "Inner Layer Bond Strength of Multilayer Printed Circuit Boards", 10/87 o Example 10 The ingredients in the amounts described in Table 10 were mixed to form the aqueous sizing compositions DD, EE, and FF according to the present invention. Acetic acid was included in each composition at less than 0.5% by weight based on the total weight. • 140 · The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1230698 A7 __B7 V. Description of the invention (I38) Table 10 Weight percentage based on the total solid content Sample composition DD EE FF PVP K-30163 12.3 11.7 12.3 STEPANTEX 653164 25.0 23.9 25.0 TMAZ81165 3.5 3.9 2.7 MACOL OP-10166 1.8 2.0 1.4 POLARTHERMPT 160167 2.4 2.3 2.4 EMERY 6717168 2.0 2.0 2.0 A-174169 3.1 2.9 3.1 A-187170 1.5 1.4 1.5 RELEASECOAT-CONC 25171 5.7 5.5 5.6 MAZUDF-136172 0.2 0.2 0.2 ROPAQUE OP-96173 35.2 33.7 35.3 FLEXOL LOE174 7.3 10.5 0 FLEXOL EPO175 0 0 7.3 ------.--------------- Order ------- --Line (please read the notes on the back before filling this page) Printed l63PVP K-30 polyvinylpyrrolidone by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, commercially available from ISP Chemicals, Wayne, New Jersey 0 164STEPANTEX 653, commercially available from Stepan Corporation of Chicago, Illinois. 165TMAZ 81 Ethylene oxide derivative of anthocyanin, commercially available from BASF Corporation, Parsippany, New Jersey 0 166MACOL ΟΡ-ΙΟethoxyphenol; this material is similar to MACOL ΟΡ-ΙΟ -141-Paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1230698 A7 B7 V. Description of the invention (139) SP, except for MACOL OP-10 SP which undergoes post-processing to remove catalyst; MACOL 〇P_10 is no longer commercially available . (Please read the notes on the back before filling out this page.) 167POLARTHERM® PT 160 Boron Nitride powder particles are commercially available from Advanced Ceramics, Lakewood, Ohio. 168EMERY® 6717 partially fluorinated poly (ethylene diimide) is commercially available from Cognis Corporation of Cincinnati, Ohio. 1ό9Α-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 17GA-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 171ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 172 MAZU DF-136 P square foam, commercially available from BASF Corporation, Parsippany, New Jersey. 173ROPAQUE® OP-96, a 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 174FLEXOL LOE Epoxidized Linseed Oil, printed by 174FLEXOL LOE Epoxidized Linseed Oil, commercially available from Union Carbide, Danbury, Connecticut. 175FLEXOL EPO Epoxidized Soybean Oil, commercially available from Union Carbide, Danbury, Connecticut. Company ° -142- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 V. Description of the invention (140) Table 10 (continued) Based on the total solids component weight% Sample component solids weight%

LOI

DD 3.4 0.42

EE 3.5 0.39

FF 3.4 0.30 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and using the aqueous sizing composition of Table 10 to coat glass fibers to form G-75 E_Glass fiber strands · Drying each coated glass fiber strand, It is known that the X weaving device is interwoven in a similar manner to form a yarn and wound on a bobbin. The yarn of sample DD was evaluated by comparing this coated yarn with a yarn coated with a similar sample DD but without an epoxidized linseed oil sizing composition (hereinafter referred to as &quot; comparative sample i &quot;). This comparison included a visual inspection of the appearance of the 7628 fabric woven by the air jet loom. The woven fabric used sample DD as the filler yarn. The interwoven G_75 E-glass fiber strands 176 coated with different resin-compatible sizing compositions were used as warp yarns. When comparing fabrics coated with the yarn of the comparative sample 丨, it was observed that the fabrics spun with the yarn coated with the sample DD showed less loose hairs on the fabric, and less contact points were collected on the loom Fine hair, especially in yarn accumulators. Since the &lt; fine hair high starting amount was observed on the loom, the non-woven fabric was added with the fibers of the coating sample EE or FF, and, &gt; weaving. This condition is believed to be the result of a lower LOI level than required to prevent excessive hair formation. In the present invention, it is expected that the sizing composition discussed above requires a LOI of at least 0.40 to reduce fine hair formation during weaving. m This warp yarn is a commercially available fiber glass yarn product code “G_75 glass fiber yarn from PP (} Industries”, which is coated with PPG Industries ’__-143-• The sheet size is applicable to China National Standard (CNS) A4 — (21G x 297 public hair) ------ — l · &gt; -------- Order --------- line # (Please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of the invention (⑷) 13 83 Adhesive. Example 11 Evaluation of many physical properties of samples AA, BB and CC and comparative sample 2177 (coated yarn / slurry on yarn), such as ignition loss ( L〇i), air jet compatibility (air resistance) and friction. The results are shown in Table u. Ignition loss of each sample (solids forming the sizing composition divided by the total weight of glass and drying forming the sizing composition The weight%) is described in Table u. By a checked thread tensiometer (which applies tension to the yarn), and 138 kpa (20 pieces per square inch) Wenqi Ruti's 2 mm diameter air nozzle, 274 per knife clock Meters (300 yards) control the feed rate and feed the yarn to evaluate the air resistance or tension of the yarn. Tension measuring device (having a fixed chromium column with a diameter of about 5 cm from the straight path between the tension measuring device installed instead of 5 cm from a straight path between the tension measuring devices) pulling the sample at a rate of 274 meters (300 yards) per minute, A tension of 20 g was applied to each yarn sample, and the frictional force of the sample and the comparative sample 2 was evaluated. The acrylic force difference is described in Table u below. Friction test The intention is to simulate the friction force that the yarn receives during weaving operations. In the test, when the first portion of the glass fiber yarn was coated with the sizing composition sample AA (hereinafter referred to as sample AA3), the sample bb and the comparative sample 2 were simultaneously tested, and the second portion of the glass fiber yarn was coated. When sizing composition sample AA (hereinafter referred to as sample AA4), the sample was tested simultaneously. Sample 177 This warp yarn is a commercially available fiber glass yarn of the company PPG Industries, code G-75 glass fiber yarn, which is coated with a 5 powder / oil binder from PPG Industries. • 144. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm 1230698 A7

: -------- ^ --------- (Please read the notes on the back before filling out this page) 1230698 A7 _ B7 V. Description of the invention (143) (Sometimes called brake tension Device) through a series of 8 ceramics in a serpentine shape; and the number of broken filaments calculated by the Shirley broken filament detector \ 釺, different needle disk settings change the interval between the needles on the tension device to Different tension levels. This particular test was made using a UTC_2003 tension device commercially available from South Carolina ^ for Steel Heddie. Broken filaments are reported as the number of broken filaments in a two meter yarn. The test results of samples AA, BB and CC and comparative sample 2 are described in Table 12 below. In a method similar to that discussed in Example n above, when the first portion of the glass fiber yarn coated sizing composition sample AA (hereinafter referred to as sample AA5) was tested at the same time, sample BB and comparative sample 2 were tested at the same time. When the second portion of the glass fiber yarn coated sizing composition sample AA (hereinafter referred to as sample AA6), the sample cc was tested simultaneously. : -------- Order --------- line Γ ^ Read the back of Jing &#; intent ## before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -146- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7

B V. Description of the invention (l44) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 12 Sample ΑΑ5 Β2 2 ΑΑ6 CC Air resistance (grams) 15 psi 46.10 42.50 42.23 47.47 42.33 20 psi 56.20 51.20 52.94 58.84 53.18 25 psi 67.33 60.30 64.13 69.45 67.66 30 psi 77.34 70.84 75.74 75.29 77.63 35 psi 89.42 89.96 85.96 83.70 82.74 40 psi 104.97 101.21 98.48 87.23 92.18 45 psi 113.41 107.74 110.34 99.91 102.91 Test 1 All bobbins 0.170 0.882 0.032 0.160 0.048 1.735 0.066 lb. 0.904 0.075 4540 g (10 lbs) 0.098 1.348 0.008 0.518 0.022 Test 2 setting 2 0.683 5.017 0.119 0.372 0.011 Setting 3 0.753 4.772 0.083 0.450 0.017 Setting 4 0.713 3.753 0.147 0.367 0.017 Setting 5 1.267 4.025 0.150 0.811 0.061 Setting 6 1.608 8.383 0.322 0.286 0.044 Setting 7 4.128 6.517 0.611 0.403 0.058 Setting 8 4.472 14.800 0.978 0.406 0.128 -147- --------- Order --------- line (please (Please read the notes on the back before filling this page) This paper size applies to Chinese national standards Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7_ V. Description of the invention (l45) As can be seen from Table 12, the sizing samples AA, BB and CC have compatible Comparative air resistance of Comparative Sample 2 (starch / oil binder). Example 13 An electronic grade laminate made from prepreg yarn added to a fabric having yarns with different sizing compositions was tested to evaluate its hole-drilling properties, and more specifically (i) was used to drill through the laminate Drilling of holes * Abrasion of drills, and (ii) Positional accuracy of holes drilled through laminates. The control GG and sample HH were laminates added to the 7628 fabric previously discussed. The control GG fabric was a thermally cleared and silane-trimmed fabric commercially available from Clark Schwebel Corporation 7628-718. The fabric in Sample HH was woven from yarns containing glass fibers (coated with resin compatible sizing shown here and shown in Table 13A). It is believed that this fabric also includes sample HH as warp. However, the warp yarns are commercially available fiberglass yarn products of 1383 from PPG Industries. The glass fiber woven into sample HH had an ignition loss of 0.35%. .

Table 13A Ingredients% by weight based on the total solid weight of the slurry on sample HH Ingredient sample HH RD-847A178 27.0 DESMOPHEN 2000179 36.2 PVP K-30180 9.0 A-187181 2.1 A_174182 4.4 mRD-847A polyester resin, commercially available from Columbus, Ohio

Borden Chemicals °° -148- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) II ---, --- --- ------ Line · (Please read the notes on the back before filling this page) 1230698 A7 _B7_ V. Description of the Invention (I46) 179DESMOPHEN 2000 Polyethylene adipate glycol, commercially available from Pittsburgh, PA Bayer Corporation 0 (Please read the notes on the back before filling out this page) 180PVP K-30 Polyvinylpyrrolidone, commercially available from ISP Chemicals, Wayne, New Jersey. 181A-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 182A_174 Gamma-methacryloxypropyltrimethoxysilane, commercially available from Tarrytown, New York CK Witco. Table 13A (continued) Composition sample HH PLURONIC F-108183 9.0 VERS AMID 140184 4.4 MACOL NP-6185 5.4 POLARTHERMPT 160186 0.9 RELEASECOAT-CONC 25187 1.5 Acetic acid &lt; 0.1 183PLURONIC ™ F-108 polyoxypropylene-polyoxyethylene copolymer, which Commercially available from BASF Corporation, Parsippany, New Jersey. 0 Printed by the Consumers' Cooperative of the Intellectual Property Office of the Department of Economics. Printed as 184 VERS AMID 140 polyamine. Commercially available from Cognis, Inc. of Cincinnati, Ohio. 185 MACOL NP-6 Nonyl Surfactant. Is commercially available from BASF Corporation, Parsippany, New Jersey. 186POLARTHERM PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. 0-149- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm). 1230698 Employees of Intellectual Property Office, Ministry of Economic Affairs Printed by the Consumer Cooperative A7 B7 V. Description of the Invention (I47) 187ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron Nitride Dispersion, which is a dispersion of approximately 25% by weight of boron nitride particles in water, commercially available from Oak Ridge, Tennessee ZYP Coatings. Pre-infiltrated yarn was prepared by a hand product procedure, and the standard FR-4 epoxy resin (EPON 1120-A80 resin, available from Shell Chemical Company) was applied to the fabric by brush coating. The resin-saturated fabric was immediately "dried" and stage B in an oven with hot air at 163 ° C (about 325 ° F), until the desired gelation time at 171 ° C (about 340 ° F) was 124 seconds. until. The pre-infiltrated yarn was modified into a 46 cm x 46 cm (18 inch x 18 inch) portion and weighed to determine the resin content. Only pre-infiltrated yarns with a resin content of 44 ± 2% can be used in subsequent lamination procedures. The pre-infiltrated yarn was stacked in 8 layers and molded in a Wabash roll of 177 Newtons / cm 2 (500 psi). All laminates were molded without copper foil. Laminates show various air capture volumes. This condition is believed to be beneficial in the absence of airspace and temperature changes during the stacking period. Tool wear analysis The first series of tests were performed to evaluate the wear of the drill. Bit wear is calculated as “bit wear percentage” using the following formula: Bit wear percentage = 100 X (Pi-PfVPi where Pi = initial width of the first cutting edge)

Pf = Width of the first cutting edge after drilling the distribution hole Referring to FIG. 11, the width 1170 of the first cutting edge 1172 of the drill 1174 is measured around the edge of the drill. Use a single-head drill to drill copper. Drilling holes with a size of 0.203mm-150- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public love ^ ----- ~ --------------- Order --------- Line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 V. Description of Invention (HS) (〇 · _ 英 忖) thick inscription Entrance and h88 mm (0 074 inches) thick paper core coated with high stack of 3 laminates (discussed above). The abrasion% of two drill diameters is measured: 〇35 mm (〇〇138) (English) and 0.46 mm (0.018 inches). Both drill bits are obtained from Tuion m-series carbonized drill bits of California— &amp;. The plate load during drilling to keep the tools fixed at 0.001. In The "plate load" used here refers to the ratio of the bit insertion rate measured in inches per minute to the spindle speed measured in revolutions per minute (rpm). For 0.35 mm drill bits, the spindle speed is 100,000 rpm And the insertion rate is 100 inches (254 cm) per minute. For 0.46 mm drills, the mandrel speed is 80,000 rpm and The feed rate is 80 inches (203 cm) per minute. Keep the tool diameter fixed at a contraction rate of 2.54 meters (1000 inches) per minute and a bit limit above 165 mm (〇65 inches). Use here “•, drill limit” means the distance to withdraw the drill on the upper surface of the laminate. Based on the 500-hole drilling pattern shown in Figure 12, the drill wear ❶ / () was determined, which included 391 0.636 cm by 10.16 cm ( 0 25 inches by 4 inches) (Shaofen 1280) drill holes, then 100 holes in the 10 by 10 hole pattern (part 1282), then 9 by 3 3 hole pattern (section 1284). The holes in each section are drilled at a hole density of 62 holes per square centimeter (400 holes per square inch). The pattern is repeated three more times for a total of 2000 holes. .Uniline 2000 single-head drilling machine was used to complete the drilling of Tests 1 and 2, and CNC-7 single-head drilling machine was used to complete the drilling of Test 3. Both machines were obtained from Esterline Technologies, Bellevue, Washington.- 151- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) --- * --- ; ------------ r --- Order --------- line (Please read the note on the back? Matters before filling out this page} 1230698 A7 V. Description of the invention ( l49) Table 13B shows that the grinding of the 0.35 and 0.46 mm diameter cans in the pattern discussed above was performed on the control GG and the sample after 2,000 holes were drilled. Each test started with a new drill cone. Table 13B

Sample ΗΗ Test 1 Average drill wear% Tool number 0.35 mm diameter drill Test 2

0.46mm diameter drill bit | average hoe waste cup% 〇46mm diameter drill bit test 3 (Please read the precautions on the back before filling out this page). ¾ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, as shown in Table 13B, The samples of tests 1 and 2 (which includes glass fiber filaments coated with a slurry of 7F compatible with the laminate matrix resin) after a hole is more dominant than the control GG (which includes Coated with glass fiber filaments (hot-cleared glass fiber filaments) containing Shiba burned and trimmed before the abrasion. Test 3 showed only a slight improvement in bit wear%, but it is believed to be due to the older CNC-7 drilling machine used for this test, and to provide a better test for the hole test than Uniline 2000 used for tests 1 and 2. Caused by the fact that there are few controls for the hole boring machine. Position Correctness A common matrix used to evaluate the drilling performance of laminates is hole correctness. This test measures the deviation of the actual hole position from its intended position. This test is taken from the lower surface of the laminate under the three laminate stacks, and the drill bit leaves the laminate stack, because it is expected that the location of this hole is away from the intention or "Zheng Zheng," hole 152-order ----- ----_ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 1230698 A7 _B7_ V. Description of the invention (15) The position has the largest difference. This difference is evaluated by "deviation distance", that is, the hole is drilled on the surface of the laminate The actual distance from the exact center to the intended center of the hole. The bias distance is measured after repeating the 500 hole sequence discussed above 4 times, that is, after each tool drills a total of 2000 holes. For the last 100 drilled The hole pattern measures the error distance, that is, the last drilled portion 582. Use the 0.46 mm (0.018 inch) diameter 508 series of holes from Tulon Corporation discussed above. As used in the tool abrasion test, for With a plate load of 0.001, the mandrel speed of the drill was 80,000 rpm, and the insertion rate was 80 inches per minute. For each control GG and sample HH, the test was repeated 8 times, and each test started with a new drill. Table 13C shows the control GG And sample HH in the drill Results of position accuracy test after 2,000 holes.

Table 13C The number of holes drilled by the HG of the control GG sample 8 8 Average deviation distance (micron) 38 28 As can be seen, the sample HH exhibits a lower deviation distance than the control GG. It uses a laminate as an electron that adds a large number of holes and circuits. This is particularly important when supporting a body. It is in accordance with the data of the wear bit% data shown in Table 13B above. More specifically, the laminates that are expected to exhibit a lower% wear of the drill bit are also expected to exhibit smaller deviation distances because the drill bit is sharper after a large number of holes have been drilled. Example 14 In Example 14, another drill wear percentage test was performed. Test electronic grade laminate control JJ and samples added with 7628 type fabric as described above -153- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm ^ -----, --- ------------ Order --------- line (please read the notes on the back before filling this page) 1230698 A7 B7 V. Description of the invention (151) AA, BB and KK drill wear%. The fabric in Comparative JJ is 7628-718 fabric from Clark_Schwebel. The fabrics in samples AA, BB and KK are shown in Table 9A and Table 14 below, which include each coating example 9. Resin-compatible sizing glass fiber filling yarns, and warp textiles with glass fibers coated with different polymeric matrix material compatible coating composition 188. 188 This warp yarn is a commercially available fiber glass yarn product from PPG hidustries , Code G-75 glass fiber yarn, which is coated with PPG Industries adhesive. -----, --------------- Order --------- line (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -154- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (152)

Table 14A Composition weight percentage of the slurry based on total solids used for sample KK Weight composition weight based on total solids ° / 〇 Sample composition KK PVP KK-30189 13.4 Α-187190 1.9 Α-174191 3.8 EMERY 6717192 1.9 SAG 10193 0.2 RELEASECOAT- CONC 25194 3.8 POLARTHERMPT 160195 5.9 RD-847A196 23.0 DESMOPHEN 2000197 31.0 PLURONIC F-108198 8.4 ALKAMULS EL-7191 &quot; 2.5 ICONOL NP-6200 4.2 LOI (%) 0.35 189PVP K-30 polyvinylpyrrolidone, commercially available from New Zealand ISP Chemicals, Inc., Wayne, Jersey, 0 19QA-187 γ-desglycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 191Α_174 γ-fluorenylpropoxypropyltrimethoxysilane, commercially available from -155- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back first (Fill in this page) -------- Order --------- line · 1230698 Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (l53) CK Witco, Tarrytown, New York the company. 192EMERY® 6717 Partially Aminated Polyethylene Diimide, commercially available from Cognis Corporation of Cincinnati, Ohio. 193SAG 10 P square foam material, commercially available from CK Witco, Greenwich, Connecticut. 194ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 195POLARTHERM® PT 160 boron nitride powder particles are commercially available from Advanced Ceramics Corporation of Lakewood, Ohio. 190RD-847A polyester resin, commercially available from Borden Chemicals, Columbus, Ohio. 197 DESMOPHEN 2000 polyethylene adipate, commercially available from Bayer, Pittsburgh, PA. 198PLURONIC ™ F-108 poly (propylene oxide) -poly (ethylene oxide) copolymer, commercially available from BASF Corporation, Parsippany, New Jersey. 199 ALKAMULS EL-719 polyethylene oxide vegetable oil, commercially available from Rhone-Poulenc Company 02 GQICONOL NP-6 alkoxylated nonylphenol, commercially available from BASF Company, Parsippany, New Jersey. The fabric then formed a prepreg with FR-4 epoxy resin (codename 4000-2 resin from Nelco International, Inc., Anaheim, CA) with a Tg of 140 X :. The sizing composition was not removed from the fabric before prepreg. By stacking 8 layers of prepreg material and 4 layers of 1 ounce copper (as shown below), and applying the Chinese National Standard (CNS) A4 specification (210 &gt; &lt; 297 public ^ 1 IL- --.--------------- Order --------- Line · (Please read the precautions on the back before filling this page) 1230698

V. Description of the Invention (I54) The temperature of 355 (about We) printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the pressure of 碡 300 平方 (approximately 2million basca) per square inch will be laminated At 15Q minutes (total cycle time), the thickness of the laminate and the thickness of the laminate and copper ranges from ㈣52 inch pairs (about om cm) to _English leaves (about _ cm). When forming the laminate, eight prepreg yarns were stacked in the following copper layers. One 1 ounce / square foot polished copper layer Three prepreg layers One 1 ounce / square foot RTF (prepared treated network) copper layer Two prepreg yarn layers One 1 ounce / square foot RTF copper layer Three prepreg layers, one 1 ounce / square inch absorbent and polished copper layer, were trimmed to a thickness of 40.6 cm by 50.8 cm (16 inches by 20 inches). A Uniline 2000 single-head drilling machine was used. Drilling holes are performed on a high stack (discussed above) of 3 laminates with a 001-inch (0.254mm) aluminum inlet and a 01-inch (2.54mm) thick aluminum facing particle board gasket . The 80% drill wear of the Tu Series 80 Series tungsten carbide drills from Gardenia, Calif., With a tool diameter of 34 mm (0.0135 inches) was determined. The plate load during drilling was kept constant at 0.001, the spindle speed was 95,000 rpm and the insertion rate was 95 inches (241 cm) per minute. The drill shrinkage rate was 90 inches (2.29 meters) per minute and the upper drill limit was 0.059 inches (ι · 5 mm). The drill abrasion% was determined based on 1500 and 2500 hole patterns. The holes in each part are 28 holes per square centimeter (178 holes per square inch) -157- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---- -; --------------- Order --------- line (Please read the precautions on the back before filling out this page> 1230698 Employee Consumption of Intellectual Property Bureau, Ministry of Economic Affairs Cooperative printed A7 ---------- --- V. Description of the invention (155) Drilling and drilling. ~, JJ and samples AA, BB and KK are drilling 1500 and 2500 holes The wear of the drill bit afterwards is%. The test of each group starts with a new drill cone, and each laminate stack has ten 15,000 hole groups and ten 2500 hole groups. The earth type is used to drill a hole in a laminate stack. This makes it possible to measure the drill bit abrasion% of 30 drill bits for each sample.

Glass fiber filaments that were thermally removed before the silane was trimmed onto the slurry) The small drill wears 0 /. . After 2500 holes, the abrasion wear percentages of samples aa, BB and KK were still less than the control jj, but were less significant. This is expected to occur as a result of most of the tool wear in the early drilling of the groups rather than in the final drilling. Based on the above, although not limited in the present invention, it is preferred that the prepreg yarn made of glass fiber fabric coated with the polymer matrix compatible sizing material shown here has no more than 32%, more preferably no more than 30 %, And the best bit abrasion is not more than 25%. For example, in a stack of 3 laminates (each laminate includes 8 prepreg yarns), use 0.46 mm (about 0.018 inches) diameter carbonization performance -158 -This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) ί! —-------- Order- ---- 1 --- i ^ w (Please read the Please fill in this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 -----___ B7 _ V. Description of the Invention (156) &quot; 'Head' with a hole density of 400 holes per square inch And 00000 plates were measured after drilling 2000 holes. In addition, based on the above, although it is not limited in the present invention, it is preferred that the material made of glass fiber fabric coated with sizing (polymer matrix compatible sizing material) has a size of not more than 36 microns, and more preferably not more than 33 micrometers, and the optimal distance is not greater than 31 micrometers. For example, use a 46mm (about 0.018 inch) tungsten carbide drill in a stack of 3 laminates (each laminate includes 8 prepreg yarns). Measured after drilling 2000 holes with a hole density of 400 holes per square inch and a plate load of 0.001. Although: it is not meant to be limited by any particular theory, it is believed that solid lubricants are disclosed here 7FI The presence of glass fiber coating compositions, and in certain embodiments, the presence of boron nitride helps to improve the copper-drilling properties of the laminates of the present invention. More specifically, solid lubricants help the bit Reduced abrasion and improved iron hole location accuracy. The improved drilling properties of the laminates made of the fiberglass fabrics coated with the polymer I materials shown here provide many advantages. First, the longer The drill life indicates that each drill Drill more holes before sharpening or discarding. In addition, because the location of the holes drilled through the laminate of the present invention is more accurate than the conventional laminate, it is expected that more than 3 laminates can be stacked to The stacking of the three laminates gives the same correctness while drilling holes. The result of these advantages is a more cost-effective drilling operation. In addition, the correctness of the location of the holes in the laminate is improved, so that improvements are added to improve The quality of the electronic support of the laminate. _____-159- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ^ -------- -^ (Please read the notes on the back before filling this page) 1230698 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (I57) Example 15 The sample in Table 15 below represents an additional specific implementation of the present invention Example. Coated sample LL manufactured but not tested. Coated sample MM-QQ has not been manufactured. Table 15 Composition weight% based on total solids Sample composition LL MM NN 00 PP QQ POLYOX WSR 301201 0.56 0.55 0.61 0.43 0.47 0.34 A-174202 3.68 4.31 4.74 3.32 3.68 2.61 A-1872 03 1.74 2.08 2.29 1.60 1.78 1.26 DYNAKOLL SI 100204 26.60 26.58-20.46-16.08 SERMULEN668205 3.33----DESMOPHEN2000206 40.58 39.93 43.92 30.75 34.14 24.15 SYNPERONIC F-108207 9.98--one POLARTHERMPT 160208 5.46 5.45-ED -UR PLURONIC F-108210 • 9.83 10.81 7.56 8.40 5.94 MACOL NP-6211-3.28 3.60 2.52 2.80 1.98 VERSAMED 140212-4.36 4.80 3.36 3.73 2.64 2G1POLYOX WSR 301 Poly (ethylene oxide), commercially available from Union, Danbury, Connecticut Carbide Corporation ° 2G2A-174 γ-fluorenylpropoxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 2G3A-187 γ-dehydrated glycerylpropyltrimethoxysilane, which is commercially available from New-160- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) _-^ --- : --------------- Order --------- line (Please read the precautions on the back before filling out this page) 1230698 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs System A7 B7 V. Description of Invention (I58) CK Witco Company, Tarrytown, California. 204DYNAKOLL SI 100 turpentine is commercially available from Eka Chemicals AB, Sweden. 205SERMUL EN 668 ethoxylated nonylphenol, which is commercially available from CON ΒEA, Benelux 02G6DESMOPHEN 2000 polyethylene adipate, and commercially available from Bayer Company of Pittsburgh, PA. 2G7SYNPERONIC F-108 polyoxypropylene-polyethylene oxide copolymer, which is the European counterpart of PLURONIC F-108. 2G8POLARTHERM PT 160 boron nitride powder particles are commercially available from Advanced Ceramics Corporation of Lakewood, Ohio. 2G9EUREDUR 140 is a polyamide resin, commercially available from Ciba Geigy, Belgium, 21010 PLURONIC F-108 polyoxypropylene-polyethylene oxide copolymer, and commercially available from BASF, Parsippany, New Jersey. 211MACOL NP-6 nonylphenol surfactant, which is commercially available from BASF Corporation, Parsippany, New Jersey, 212 VERSAMID 140, and commercially available from Cognis, Inc. of Cincinnati, Ohio ° -161- This paper is in accordance with Chinese national standards (CNS) A4 specification (210 X 297 mm) -----; --------------- Order --------- line (please read the first Please fill out this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230698 A7 ____B7 V. Description of the invention (159) Table 15 (continued) Weight percentage based on the total solid content Sample composition LL MM NN 00 PP QQ RELEASECOAT-CONC 25213 3.64 3.63--4.00 4.00 ROPAQUE OP-96214--29.23 30.00 35.00 35.00 Estimated% solids in coating 5.4 5.6 5.1 7.3 6.5 9.3 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is about 25% by weight nitrogen A dispersion of boron particles in water is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 214ROPAQUE® OP-96, a 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. Example 16_ An unprotected laminate was made using the materials and methods described in Example 9, except that copper was not used in the lamination. Each unprotected laminate was then cut into 52 1-inch X 1 / 2-inch (about 2.54 cm x about 1.27 cm) rectangular pieces. About half of the pieces are cut parallel to the warp direction, and about half of the pieces are cut parallel to the filling direction. Then, 26 rectangles (13 parallel warp direction cuts and 13 parallel fill direction cuts) obtained from each laminate were placed in a water recirculation device and the water was boiled. Boil water for 24 hours. After 24 hours, the tablets were removed from water and wiped dry. The remaining 26 tablets from each laminate did not boil. An unprotected control laminate made of the conventional heat-removing and finishing fabric was also manufactured in the same manner as the test laminate of Example 9 above, and tested in accordance with the above steps. -162- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) II ---------------------- Order ------- --Line Φ (Please read the precautions on the back before filling this page) 1230698 Α7 Β7 V. Description of the invention (160) Then measure the short beam shear strength of boiling and non-boiling tablets according to ASTM D 2344-84. The test results are shown in Table 9. The uncovered samples AA, BB, and CC correspond to laminates made using fabrics (described in Example 9) each having fibers sizing the above-sizing compositions aa, BB, and CC. As discussed above, the control samples were made using conventional heat removal and conditioning fabrics. The thickness of the test laminates (unfaced samples AA, BB, and CC) ranged from 0.050 inches (about 0.127 cm) to 0.063 inches (about 016 cm). During the test, the ratio of span length to sample thickness was 5. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -163- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 A7 B7 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives. 5. Description of the invention (Ml) Table 16 Test unit AA BB CC Controlled short beam shear strength, not pounds per square inch 7787 8477 7769 7382 Direction of boiling warp yarns (million basca ) (54) (56) (54) (51) Sample thickness N = 13 inches 0.060 0.050 0.056 0.055 (cm) (0.152) (0.127) (0.142) (0.140) Short beam shear strength, not per square inch Pound 6626 7594 7118 5506 Number of boiling yarn filling directions (million pascals) (46) (52) (49) (38) Sample thickness N = 13 inches 0.061 0.050 0.060 0.055 (cm) (0.155) (0.127) (0.152) (0.140) Short beam shear strength 24 pounds per square inch 5695 6522 5081 4929 Hours of boiling warp yarn direction (million basca) (39) (45) (35) (34) Sample thickness N = 13 inches 0.061 0.051 0.057 0.057 (cm) (0.155) (0.130) (0.145) (0.145) Short Beam Shear Strength 24 pounds per square inch 5266 5832 5179 4116 hours boiling filling direction (million basca) (36) (40) (36) (28) sample thickness N = 13 inches 0.063 0.051 0.062 0.056 (cm ) (0.160) (0.130) (0.157) (0.142) In this test, the short-strand shear strength of the test laminates (unfaced samples ΑΑ, Β, and CC) in the warp and weft directions was tested with water before boiling. Later than that of the control sample, south was observed. Example 17 A gauze manufactured from E-glass fiber strands coated with the sizing composition CC shown in Table 9A of Example 9 and 1383 Commercial-164 by PPG Industries was used. This paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) --1 ---- 1 --------------- Order --------- line (Please read the precautions on the back first (Fill in this page again) 1230698 A7 V. Description of the Invention (I62) The warp yarns produced by the fiberglass yarn products printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs were shot with air nozzles on the loom and I became 7628 type fabrics. The fabric is then prepreged and laminated to form a steel facing compound, as described in Example 9 above. Then, the copper surface is scrapped, and the layered material CC (as described in Example 9 above) is processed (P iron / same% boat and patterned) into a test plate with multiple test patterns to test the metal moving performance. . More specifically, each board includes three groups: a layer circuit pattern mo 'is shown in FIG. — The group pattern is oriented along the χ_ axis of the board, the other group is along the γ_ axis of the board, and the third group is the price across the board. Each road pattern 13Η) includes 50 rows of five holes 1312, each of which has a diameter of 13 ′ and a center between the holes of adjacent rows of 40 to 54.7 mil. When the gate is separated from these holes, The two plates are stacked together so that they are drilled in a -drilling operation. The staggered rows of holes in each pattern are interconnected by bus bars 1314 and leads 1316 along the main surface of the board, as shown in FIG. Solder leads to each bus to connect to a power source. Each circuit also includes ικ ohm surface resistance 1322 to ensure that if one circuit board is damaged, power to the remaining circuits is maintained. Each plate was immersed in 76.7. (: (170 ° F) deionized water for minutes to remove any solder flux residue and dry. Then place the board in a 85 C (185 F) and 85% relative humidity slot and apply a DC current of 13.5 volts continuously to the pattern The slot is closed and opened every 200 hours ... The door is set to stabilize the pattern to the surrounding laboratory temperature, and the insulation resistance of each pattern is measured. There are two sample CCs and two control boards. The control board is the same as the CC Manufactured in the same way, but using conventional heat removal and trimming. Each board includes 21 circuit patterns (that is, three groups of seven-layer circuit patterns). Middle single 10 is woven in the floor. * -------- itr --------- ΜΦ (Please read the precautions on the back before filling in this page> -165- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698

V. Description of the invention (163); CC and test board are tested for a total of 42 circuits. The following table 17 shows (please read the precautions on the back before filling this page). The results of 400 and 1000 hours, among which the table 値 is the number of patterns with the specified resistance. Insulation resistance ___ Sample CC control__〇HMS 200 Hrs ^ 400 Hrs 1000 hrs 400 Hrs Short 1 0 1 7 42 105 —---- 1 4 2 0 106 1 1 1 0 107 0 2 0 0 108 1 0 1 0 109 3 2 1 0 &gt; 1010 36 32 30 0 The sample CC board had less short circuits than the control board after 200 hours of exposure. After 400 hours of exposure, all control plate patterns were damaged. For the purpose of this test sample, "short circuit" means an insulation resistance of less than 105 ohms. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Example 18 Mix the ingredients in the amounts described in Table 18A to form a component in accordance with this standard. The water-based resin of the invention is compatible with the first sizing sample RR. Included in the composition is less than 1% by weight of acetic acid. The sample RR is coated on glass fibers forming g_75 E-glass fiber strands. The interlacing device interweaves the coated glass fiber strands in a similar way to form an interlaced yarn, and is wound on a bobbin. The coated yarn has a LOI of 0.35%. -166- This paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 male 3Π 1230698 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (164)

Table 18 A: The weight percentage of the total solid content of the sample RR. Sample RR RD-847A215 27.0 DESMOPHEN 2000216 36.2 PVP K-30217 9.0 A_187218 2.1 A-174219 4.4 PLURONIC F-108220 9.0 VERS AMID 140221 4.4 MACOL NP-6222 5.4 POLARTHERM PT 160223 0.9 RELEASECOAT-CONC 25224 1.5 Acetic acid &lt; 0.1 215RD-847A polyester resin, commercially available from Columbus, Ohio

Borden Chemicals Corporation 0 216DESMOPHEN 2000 polyethylene adipate glycol, commercially available from Bayer Company, Pittsburgh, PA. 217PVP K-30 polyvinylpyrrolidone, which is commercially available from ISP Chemicals, Inc., Wayne, New Jersey 0 218A-187 γ-dehydroglycerylpropyltrimethoxysilane, which is commercially available from OSi, Tarrytown, New York Specialties. 219A-174 gamma-methacryloxypropyltrimethoxysilane, commercially available from OSi Specialties, Tarrytown, New York. -167- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -----? --------------- Order ------ --- line (please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of the Invention (l65) 22QPLURONIC F-108 Poly (propylene oxide) / poly (ethylene oxide) copolymer, commercially available from New Jersey BASF Company, Parsippany, State. 221VERSAMID 140 Polyamine, commercially available from General Mills Chemicals Inc. 222MACOL NP-6 Nonyl Surfactant, commercially available from BASF Corporation, Parsippany, New Jersey. 223POLARTHERM® PT 160 boron nitride powder particles, commercially available Available from Advanced Ceramics, Lakewood, Ohio. 224ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is a dispersion of approximately 25% by weight of nitriding particles in water, is commercially available from ZYP Coatings, Oak Ridge, Tennessee. The ingredients are mixed in the amounts described in Table 18B to form an aqueous resin compatible first sizing sample SS according to the present invention. The sample SS was coated on glass fibers forming G-75 E-glass fiber strand fibers, and the strands were not interwoven. The coated un-interlaced yarn had 0.7 ° /. LOI. II ---: ------- ΦΜ -------- Order --------- lineΦ (Please read the notes on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs The paper size printed by the Bureau's Consumer Cooperatives applies the Chinese National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 1230698 A7 _B7_ V. Description of the Invention (I66)

Table 18B Per 100 gallons of sample SS ingredients in pounds SS MAPEG 600 DOT225 9.24 ALUBRASPIN 226226 1.9 A-174227 10.9 A-187228 5.45 A_110229 2.41 EPON 880230 91.1 PLURONIC F-108231 9.11 ALKAMULS EL-719232 9.11 MACOL OP- IO-SP233 4.57 EPIREZ 3 5 2 2 234 20.9 Acetic acid 2.6 225 is ethoxylated ditallow obtained from BASF. 226 ALUBRASPIN 226 partially fluorinated poly (ethylene diimide) commercially available from BASF Corporation, Parsippany, New Jersey. 227 Α-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarry town, New York. 228A-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 229A-1100 Amine-functional organosilane coupling agent, commercially available from CK Witco, Tarrytown, New York. 230EPON 880 epoxy tree month purpose, which is commercially available from Houston, Texas -169- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) &quot; — '· — ^ ----- ---------- Order --------- Line (Please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of Invention (i67)

Chemical Company 0 (Please read the notes on the back before filling this page) 231PLURONIC ™ F-108 Polyoxypropylene-Polyethylene Oxide Copolymer, commercially available from BASF Corporation, Parsippany, New Jersey. 232ALKAMULS EL-719 polyethylene oxide vegetable oil, commercially available from Rhone-Poulenc Company 0 233MACOL OP-10 SP ethoxylate g, commercially available from BASF Company, Parsippany, New Jersey. 234EPIREZ 3522 A dispersion of solid biphenol A diglycidyl ether epoxy resin commercially available from Sell Chemical Company of Houston, Texas. The sizing yarns of samples RR and SS were used as warp and filling yarns (or weft yarns), and were woven into 7628 type fabrics. The control yarn was also woven into a Type 7628 fabric, which is a coated sizing fiber of PPG 695 and commercially available G-75 E-interlaced yarn from PPG Industries of Pittsburgh, PA. The sizing warp yarn and the filling yarn have a LOI of 1%. Before weaving, the warp yarn is slit with a polyvinyl alcohol composition, which increases the LOI of the warp yarn to about 2 to about 2.5%. The resulting fabric has a LOI in the range of 1.6 to 1.9%. Printed by the Ministry of Economic Affairs and Intellectual Property Bureau, Consumer Co., Ltd. Test the breathability of each fabric in accordance with the standard test method for breathability of textile fabrics according to ASTM D 737. The average air permeability of the fabrics is shown in Table 18C below. -170- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 1230698 A7 _B7 V. Description of Invention (l68)

Table 18C Air permeability (standard cubic feet per minute per square foot) Control sample 41 Sample RR 2.8 Sample SS 1.6 As seen in Table 18C, the air permeability of the textile fabrics added with samples A and B is much lower than the control sample Textile fabric. Example 19 Table 19 includes additional non-limiting sizing formulations coated on glass fibers, which are then woven into a fabric. Each composition contains less than 1% by weight of acetic acid. 0 Table 19 Weight% of ingredients based on total solids Ingredient Sample TT Sample UU Sample XX Sample YY PVP K-30235 13.7 13.5 15.3 14.7 STEPANTEX 653236 27.9 13.6 A-187237 1.7 1.9 1.9 1.8 … PVP K-30 polyvinylpyrrolidone, commercially available from ISP Chemicals, Inc., Wayne, New Jersey 0 236 STEPANTEX 653, commercially available from Maywood, New Jersey

Stepan company. 237 A-187 r-Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. -171- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) — l · ---; --------------- Order ----- ---- Line · (Please read the precautions on the back before filling this page) 1230698 A7 B7 V. Description of the invention (169) Table 19 (continued) Ingredient sample TT sample UU sample XX sample YY A-174238 3.4 3.8 3.8 3.7 EMERY 6717239 2.3 1.9 2.5 2.4 MACOL ΟΡ-ΙΟ240 1.5 1.7 1.6 TMAZ-81241 3.0 3.4 3.3 MAZUDF-136242 0.2 0.3 0.2 ROPAQUE OP-96243 39.3 43.9 42.3 RELEASECOAT-CONC 25244 4.2 6.4 POLARTHERMPT 160245 2.7 2.6 SAG 10246 0.2 RD-847A247 23.2 DESMOP 2000248 31.2 PLURONIC F-108249 8.5 238 A-174 r-fluorenylpropoxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. --r --- 1 --------------- Order --------- line (Please read the notes on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs The Bureau ’s Consumer Cooperative printed 239EMERY® 6717 partially aminated poly (ethylene diimide), commercially available from Cognis, Inc. of Cincinnati, Ohio. 240 MACOL OP-10 ethoxylated alkylphenol; this material is similar to MACOL OP-10 SP, except that MACOL OP_10 SP is subjected to post-treatment to remove the catalyst; MACOL OP_10 is no longer commercially available. An ethylene oxide derivative of 241 TMAZ-81 anisolate, commercially available from BASF Corporation, Parsippany, New Jersey. 242 MAZU DF-136 anti-foaming agent, commercially available from Parsippany, New Jersey -172- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1230698 Member of the Intellectual Property Bureau of the Ministry of Economic Affairs. Industrial Consumption Cooperative printed A7 _B7___ V. Description of invention (Π〇) BASF company. 243 ROPAQUE® OP-96, 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA 0 244 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride dispersion, which is about 25% by weight boron nitride particles The dispersion in water is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 245 POLARTHERM PT® 160 boron nitride powder particles are commercially available from Advanced Ceramics, Inc. of Lakewood, Ohio ° 246 SAG 10, and are commercially available from CK Witco, Greenwich, Connecticut. 247 RD-847A polyester resin, commercially available from Borden Chemicals, Columbus, Ohio, 0 248 DESMOPHEN 2000 polyethylene adipate, commercially available from Bayer, Pittsburgh, PA. 249 PLURONIC ™ F_108 polyoxypropylene-polyethylene oxide copolymer commercially available from BASF Corporation, Parsippany, New Jersey. Table 19 (continued) Ingredient Sample TT Sample UU Sample XX Sample YY ALKAMULS EL-719250 3.4 ICONOL NP-6251 3.4 FLEXOL Ε0252 13.6 30.0 ALKAMULS EL-719 polyethylene oxide vegetable oil, commercially available from

Rhone-Poulenc Corporation 251 ICONOL NP-6 alkoxylated nonylphenol, which is commercially available from New Jersey -173- This paper size applies to China National Standard (CNS) A4 (21G X 297 public love) &quot;-^---; ------------- r --- order --------- line (please read the precautions on the back before filling this page) 1230698

V. Invention Description (Π1)

Parsippany by BASF. FLEXOL EPO epoxidized soybean oil is commercially available from Union Carbide, Danbury, Connecticut. From the description above, it can be seen that the present invention provides glass fiber strands with abrasion-resistant coatings, which provide good thermal stability, low corrosion and reactivity in the presence of high humidity, reactive acids and alkalis, and various polymeric substrates. Material compatibility. These strands can be interwoven or chopped to form a sliver, chopped mesh or continuous strand, or woven or knitted into a fabric 'for a wide variety of application towels, such as composite reinforcement of printed circuit boards. Those skilled in the art should understand that the specific embodiments described above can be changed without departing from the broad concept thereof. Therefore, it should be understood that the present invention is not limited to the specific embodiments disclosed, but is intended to be encompassed within the spirit and scope of the present invention. The modification is as defined in the scope of the attached patent. I, ----: ------- ΦΜ -------- Order --------- Line-φ (please first Read the note on the back? Matters need to be completed on this page} Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -174-

Claims (1)

3® @ (§9115361 f Tiger patent application j93 · 9 · 3 date of revision / • a fabric comprising at least one fiber strand comprising a plurality of fibers, and having a resin-compatible honeycomb composition on at least a part of the surface of the fabric, the resin-compatible coating The layer composition comprises: (a) a plurality of at least one selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, thin flat particles having a thermal conductivity of at least 丨 watts per meter K at a temperature of 300K, and non-thermally expandable composite materials Discontinuous particles made of material, the particles having an average particle size sufficient to wet the strands; (b) at least one lubricating material different from the plurality of discontinuous particles; and (c) at least one film-forming material. 2. The fabric according to item i of the application, wherein the resin-compatible coating composition is a residue of an aqueous coating composition. 3. The fabric according to item 1 of the scope of the patent application, wherein the resin-compatible coating group is a powder coating composition. 4. The fabric according to item 1 of the patent application, wherein at least one fiber strand contains at least one glass fiber. 5. The fabric according to item 1 of the Shenyan patent scope, wherein at least one fiber strand comprises a plurality of glass fibers. 6. The fabric according to item 5 of the patent claim, wherein the plurality of glass fibers are selected from the group consisting of glass fibers, D-glass fibers, S-glass fibers, Q-glass fibers, and E-glass derivative fibers. 7. The fabric according to item 6 of the application, wherein a plurality of glass fibers are E-glass fibers. 8. The fabric according to item 6 of the scope of the patent application, in which a number of glass fiber paper sheets are used in the Zhongguanjia Standard (CNS) M specification (⑽> &lt; 29? Public Manager) 1230698 A8 B8 C8 _____ —__; __ D8 ____ 6. The scope of patent application is E-glass derivative fiber. 9. The fabric according to item 丨 of the application, wherein the organic material is selected from the group consisting of thermosetting materials, thermoplastic materials, and mixtures thereof. 10. The fabric according to item 9 of the scope of patent application, wherein the organic material is a thermosetting material selected from the group consisting of thermosetting polyester, vinyl ester, epoxy material, phenolic, amine-based plastic thermosetting polyurethane, and any mixture thereof material. 1 i. The fabric according to item 1 of the scope of patent application, wherein the organic material is selected from the group consisting of thermoplastic polyester, polycarbonate, polyolefin, propylene polymer, polyamide, thermoplastic polyurethane, vinyl polymer , And any mixture of the above thermoplastic materials. 12. The fabric according to item 1 of the scope of the patent application, wherein the inorganic polymeric material is selected from the group consisting of polyphosphine, polysilane, polysiloxane, polygermane, polysulfide, polylithium, polysiloxane, and any of the above mixture. 13 · According to the scope of patent application! According to the scope of the application for patents, the thin flat particles are free of 14. The fabrics according to the scope of the application for patents No.14, thorium disulfide, Shixihua Group, tungsten disulfide, and 0-13, wherein the thin flat particles are selected from graphite, diselenium Molybdenum, disulfide button, one ~ 丨 丨 · two stone western tungsten, and any combination of the above15. According to the fabric of the scope of the patent application, the composite material is selected from the inside of the particle having a particle different from the subsurface Hard sound particles. Eighteen 16. The fabric according to item 15 of the scope of patent application, in which the composite material is selected -2- 1230698 Particles formed from the first material covering, covering or encapsulating at least one second material. Π π. The fabric according to item 15 of the scope of the patent application, wherein the composite material is selected from the group consisting of particles formed of a first material covered, covered or enveloped by a first material in a different form. 18. A fabric according to item i of the application, wherein a plurality of discrete particles provide a gap between at least one fiber and at least one adjacent fiber. 19. The fabric according to item 1 of the scope of patent application, wherein a plurality of discontinuous particles have an average particle size ranging from 01 to 5 microns as measured by a laser scattering technique. 20. The fabric according to item i of the application, wherein the plurality of discontinuous particles comprise 1 to 80% by weight based on the total solids as the resin-compatible coating composition. 21. The fabric according to item 20 of the application, wherein the plurality of discontinuous particles comprise 20 to 60% by weight of the resin-compatible coating composition based on the total solids. 22 · According to the scope of patent application! Item, wherein at least one lubricating material is selected from the group consisting of oil, butterfly, and grease. 23. According to the scope of patent application! Item of fabric, wherein at least one lubricating material comprises 1 to 50% by weight of the resin-compatible coating composition based on the total solids. 24. The fabric according to item 1 of the scope of patent application, wherein at least one lubricating material contains 20 to -3- based on the total solids as a resin-compatible coating composition. This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X (297 mm) Binding 1230698 40% by weight. 25 · According to the scope of patent application 申请! Item of fabric, wherein at least one film-forming material is selected from the group consisting of organic polymer materials, inorganic polymer materials, and natural polymer materials. 26. The fabric according to item 25 of the application, wherein at least one film-forming material is selected from a thermoplastic material and a thermosetting material. 27. The fabric according to item 26 of the scope of patent application, wherein the thermosetting material is selected from the group consisting of thermosetting polyoxetane, epoxy resin, vinyl vinegar, phenol-based, amine-based plastic, thermosetting polyurethane, and any combination thereof. 2M The fabric according to item 26 of the patent application, wherein the thermoplastic material is selected from the group consisting of vinyl polymers, thermoplastic polyesters, polyolefins, polyamides, thermoplastic polyurethanes, propylene polymers, and any of the above mixture. 29 · According to the scope of patent application! Item of fabric, wherein at least one film-forming material comprises 5 to 50% by weight based on the total solids of the rolling-compatible coating composition. 30. The fabric according to item 29 of the application, wherein at least one film-forming material comprises 10 to 30% by weight of the resin-compatible coating composition based on the total solids. 31. The fabric of claim i, wherein the resin compatible coating comprises a resin reactive diluent. 32. The fabric according to item 31 of the application, wherein the resin-reactive diluent comprises one or more resins which can react with the epoxy resin system and is selected from the group consisting of amine, alcohol, anhydride, acid and ring Functional group Binding 4 A8 B8 no 1230698 lubricant. &gt; 'a fiber strand comprising a plurality of fibers, a part of which has a resin-compatible coating group ~ a fabric comprising at least one and at least a part of the composition of the fabric' this resin-compatible coating composition Comprising: 0) a plurality of particles comprising at least one particle formed of at least one organic material; and (ii) at least one particle formed of at least one inorganic material selected from the group consisting of boron nitride, graphite and metal dichalcogenide Wherein the plurality of particles have an average particle size sufficient to make the strand moist; (b) at least one lubricating material different from the plurality of discontinuous particles; and (c) at least one film-forming material. 34. The fabric according to item 33 of the application, wherein at least one organic material is a polymeric organic material. 35. The fabric according to item 34 of the application, wherein the polymeric organic material is a thermoplastic material selected from the group consisting of vinyl polymers, thermoplastic polyesters, polyolefins, polyamides, thermoplastic polyurethanes, and propylene polymers 36. The fabric according to item 35 of the application, wherein the polymeric organic material is a propylene copolymer selected from a copolymer of styrene and a propylene monomer. 37. A fabric according to item 33 of the application, wherein a plurality of particles have an average particle size ranging from 0.1 to 5 micrometers as measured by a laser scattering technique. / 38. The fabric of claim 33, wherein the plurality of particles comprise 1 to 80% by weight of the resin-compatible coating composition based on the total solids. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1230698-Jt &o; C8 D8 VI. Application scope of patent 39. According to the 38th scope of the patent scope of application, the multiple particles include The solids are 20 to 60% by weight of the resin-compatible coating composition. 40. The fabric according to item 33 of the application specialty, wherein at least one lubricating material comprises 1 to 50% by weight of the resin-compatible coating composition based on the total solids. %. 41. The fabric according to item 40 of the patent application, wherein at least one lubricating material comprises 20 to 40% by weight of the resin-compatible coating composition based on the total solids. 42. The fabric according to item 33 of the application, wherein at least one film-forming material comprises 5 to 50% by weight of the resin-compatible coating composition based on the total solids. 43. The fabric according to item 42 of the application, wherein at least one film-forming material comprises 10 to 30% by weight of the resin-compatible coating composition based on the total solids. 44. A fabric comprising at least one fiber strand comprising a plurality of fibers and having a resin-compatible coating composition on at least a portion of a surface of the fabric, wherein the resin-compatible coating composition has a range of 0.1 to 1.6 The ignition loss, and the air permeability of not more than 10 standard cubic feet per square foot per minute measured according to ASTM D737. 45. The fabric according to item 44 of the patent application, wherein at least one fiber strand comprises at least one fiber. 46. The fabric according to item 44 of the patent application, wherein at least one fiber strand comprises a plurality of fibers. -6- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1230698 A8 B8 —— C8 ^ __ D8 / 、, patent application ^-According to the 46th area of the patent application scope, The plurality of glass fibers are selected from E-glass fibers, D_glass fibers, &amp; glass fibers, Q_glass fibers, and E-glass derivative fibers. The fabric according to item 47 of the stated scope of expertise, wherein a plurality of glass fibers are E-glass iron. 49. The fabric according to item 47 of the application, wherein the plurality of glass fibers are E-glass derivative fibers. 50. The fabric according to item 1 of the patent application, wherein the resin-compatible coating composition comprises a plurality of particles. According to the application, the scope of the patent is 50, in which the particles are formed of a material selected from the group consisting of a polymeric inorganic material, a non-polymeric inorganic material, a polymeric organic material, a non-polymeric organic material, a composite material, and any mixture thereof. 52. The fabric according to item 51 of the application, wherein the polymeric inorganic material is selected from the group consisting of polyphosphine, polysilane, polysiloxane, polygermane, polysulfide, polylithium, polysiloxane, and any mixture thereof . 53. The fabric according to item 51 of the scope of patent application, wherein the non-polymeric inorganic material is selected from graphite, metal, oxide, carbide, nitride, boride, sulfide, silicate, carbonate, sulfate, hydroxide And any mixture of the above. 54. The fabric according to item 51 of the application, wherein the polymeric organic material is selected from the group consisting of thermosetting materials and thermoplastic materials. 55. The fabric according to item 51 of the application, wherein the polymeric organic material is selected from the group consisting of thermosetting polyester, epoxy materials, vinyl esters, phenols, and amino groups 1230698 A8 B8 C8