TW557286B - Impregnated glass fiber strands and products including the same - Google Patents

Abstract

The present invention provides an at least partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and lamellar particles having a thermal conductivity of at least 1 Watt per meter K at a temperature of 300K. The present invention also provides an at least partially coated fiber strand comprising a plurality of fibers, the coating comprising an organic component and non-hydratable, lamellar particles. The present invention further provides an at least partially coated fiber strand comprising a plurality of fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said fibers, the resin compatible coating composition comprising: (a) a plurality of discrete particles formed from materials selected from non-heat expandable organic materials, inorganic polymeric materials, non-heat expandable composite materials and mixtures thereof, the particles having an average particle size sufficient to allow strand wet out; (b) at least one lubricious material different from said plurality of discrete particles; and (c) at least one film-forming material. The present invention also provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coating composition comprising: (a) a plurality of lamellar, inorganic particles having a Mohs' hardness value which does not exceed the Mohs' hardness value of said glass fibers; and (b) at least one polymeric material. The present invention further provides an at least partially coated fiber strand comprising a plurality of glass fibers having a resin compatible coating composition on at least a portion of a surface of at least one of said glass fibers, the resin compatible coating composition comprising: (a) a plurality of hollow, non-heat expandable organic particles; and (b) at least one lubricious material different from the at least one hollow organic particle.

Description

557286 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (1) The present invention relates generally to coated fiber strands used to reinforce composites, and more particularly to compatibility with matrix materials added to the strands. Coated fiber strands. ', In thermosetting molding operations, good "wet penetration" (polymeric lining or fiber) and "wet, moist" (polymer matrix material penetrates the view or fabric; individual fiber bundles or strands; ) The nature is hopeful. In contrast, good dispersion properties (i.e., the good distribution of fibers within the thermoplastic material) are a major concern in typical thermoplastic molding operations. W In the case of weaving a composite or laminate formed from fiber strands into a fabric, in addition to providing good wet penetration and good wetting properties, it is hoped that the coating on the surface of the fiber strands protects the fibers from abrasion during processing, providing Good weaving power, especially in air jet loom, and compatible with polymer matrix materials added to the fiber strands. However, many upper paddle components are not compatible with the polymeric matrix material and negatively affect the adhesion between the glass fibers and the polymeric matrix material. For example, starch, which is a commonly used sizing ingredient for textile fibers, is generally not compatible with polymeric matrix materials. As a result, these incompatible materials must be removed from the fabric before being impregnated with a polymeric matrix material. The removal of such non-resin-compatible sizing materials, that is, degreasing or degreasing the fabric, can be accomplished by a variety of techniques. Removal of these non-resin-compatible sizing materials is most often accomplished by prolonged exposure of the textile fabric to high temperatures to thermally decompose the sizing (often referred to as thermal removal). The conventional heat removal process involves heating the fabric at 380 C for 60-80 hours. However, this heat removal step is detrimental to the strength of the glass fibers, and it has not always been possible to successfully remove non-grain materials and pulp decomposition products to further contaminate the fabric. Already tried other — — — — — — — — II — ^ .1 --------- Order --------- line win f Please read the notes on the back before filling this page )-^ 1 1 1 ^ 1 -4. ^ The paper size is applicable to the Chinese National Standard (CNS) A4 (21 × 297 mm) 557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Invention Description (2) Methods for removing sizing material, such as water washing and / or chemical removal. However, this method usually requires that the sizing composition be heavily reconstituted to be compatible with such washing and / or chemical removal, and is generally not as effective as thermal removal in removing all incompatible materials. In addition, because the weaving process is quite abrasive to fiberglass yarns, the yarns used as warp yarns generally undergo a second coating step before weaving, which is commonly called &quot; sizing &quot;, and is coated with a wear-resistant coating Warp yarns (commonly referred to as "sizing on sizing yarns") to help minimize the abrasion of glass fibers. Sizing of sizing yarns is typically applied to the first sizing previously applied to the glass fibers during the fiber forming operation. However, since the typical sizing of the sizing yarn is also generally not compatible with the polymeric matrix material, it must also be removed from the textile fabric before adding the resin. In addition, in order to improve the wear between the degreased or deoiled fabric and the polymeric resin, The processing step coats the final size (usually a silane coupling agent and water) on the fabric to recoat the glass fiber (commonly referred to as &quot; finishing &quot;). All of these have no additional processing steps: sizing, degreasing or degreasing, and finishing, increasing fabric manufacturing cycle time and cost. In addition, they often require significant investments in capital equipment and labor. In addition, the additional fabric treatments accompanying these treatment steps cause fabric damage and reduced quality. Efforts have been made to improve the efficiency or effectiveness of some of these processing steps. However, the coating continues to fulfill one or more of the following requirements: to suppress wear and tear of glass fibers; to be compatible with a wide variety of matrix materials; and to provide good wetting and wetting of the matrix material. Furthermore, it is particularly advantageous if the coating is compatible with modern air-jet weaving devices to increase productivity. In addition, the elimination of no additional processing steps in the fabric forming operation, while maintaining the electronic support should — — ilk'J — f »— — — — — III l · III ^« — — — — — I (Please Read the notes on the back before filling out this page) -11 -5-557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Invention Description (4 The invention &lt; The fiber stock has a unique coating 'It is not only better In the process of inhibiting fibers (abrasion and cracking), it also provides at least one of the following 1 ± quality, good wet through, wet and disperse properties when forming a composite. As detailed below, the “疋 义 版” contains multiple individual Weaving dimension, that is, at least two weaving dimensions. The compound used herein refers to a combination of the coated fiber strands of the present invention and additional materials, such as, but not limited to, adding one or more layers to the coated Fiber strands <fabric combined polymer matrix materials to form laminates. Good lamination strength Good thermal stability, good hydrolytic stability (ie, resistance to water moving along the fiber / polyester matrix material interface), high Degree, low acidity and reactivity in the presence of reactive acids, and compatibility with various polymeric matrix materials (which can eliminate the need to remove the coating before lamination, especially hot or pressurized water) ) Are other desirable characteristics that can be exhibited by the coated fiber strands of the present invention. Preferably, the coated fiber strands of the present invention provide good weaving and knitting processing power. Silk, low strand tension, high floating power, and low insertion time are the preferred individual or combined features provided by the coated glass fiber strands of the present invention, which are better for weaving and knitting, and provide consistently with fewer surface defects It is used for printed circuit board applications. In addition, the coated fiber strands of the present invention are suitable for air jet weaving. As used herein &quot; air jet weaving &quot; Air jet nozzle &lt; Strong weaving air inserts the filling yarn (weft yarn) into the warp shed. The coated fiber strand of the present invention preferably has a unique feature that facilitates heat conduction along the coated surface of the fiber. Coating. As a continuous strength for electronic circuit boards (please read the precautions on the back before filling out this page) — — — — — — — — — — — — — III l · III — — — — — — — — — -—7

——__-~ —---- B7___ V. Description of the invention (5) &quot; ---- Chemical time, 'Birthday, ^ ^ ^ Also this kind of coated glass fiber can be provided along the reinforcement to promote the talk ': ,, source (such as wafer, or circuit) heat dissipation to conduct heat away from electronic components and thus suppress the heat of J-electronics, components, glass fiber and polymeric matrix materials: deconstruction and degradation. The coated fiber strand of the present invention preferably provides a preferred path of thermal conduction phase, that is, heat dissipation and distribution, than the material at the base, thereby reducing the thermal expansion and curl of the 4 f daughter circuit board and improving soldering reliability. The first and second coated glass fiber strands in this issue are preferably to reduce or eliminate the need to add a thermally conductive material to the substrate tree, which improves the laminate manufacturing operation and reduces the expensive substrate material supply tank flushing and maintenance. The coated fiber strands of the present invention preferably exhibit high openness. As used herein, "high strand openness" means that the strands have a large cross-sectional area and the filaments of the strands are not closely combined with each other. The high strand openness can facilitate the penetration or wetting of the strands by the matrix material. The fiber of the present invention The composite of the present invention made of strands, especially the laminate, preferably exhibits at least one of the following properties: low thermal expansion coefficient; good flexible strength; good interlayer bonding strength; and good hydrolytic stability. Resistance to the movement of water along the fiber / matrix interface. In addition, the electronic support and printed circuit board of the present invention made from fiber strands according to the present invention preferably have at least one of the following properties: good drilling force; and metal movement ( Also known as cathode-anode filament formation or CAF) resistance. See Tummala (ed.) Microelectronics Packaging Handbook, (1989) pages 896-897, and IPC-TR-476B, &quot; Electrochemical Migration: Electrochemically Induced Failures in Printed Wiring This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) (Please read the phonetic on the back? Then fill out this page) - - - - - - b, J Ik I I I I I I I I l · I I a - - - - - - - - ▲ Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed -i · 557286 A7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. "Instructions on Boards and Assemblies", (1 &quot; 7), which are specifically incorporated herein by reference. When a fiber strand with good drilling power according to the present invention has holes Low tool wear and good drilling position accuracy at least one. As mentioned above, a typical fabric forming operation involves subjecting fiberglass yarns and fabrics made from them to many non-additive processing steps such as sizing, heat removal and Trimming. The present invention preferably provides a method for forming a fabric, a laminate, an electronic support, and a printed circuit board, which eliminates no additional processing steps from the fabric formation process, and at the same time provides a method suitable for electronic packaging applications. Fabrics. Other advantages of preferred embodiments of the present invention include reduced production cycle time, exclusion of capital equipment, reduced fabric handling and labor costs, good fabric quality, and good end product properties. The present invention also provides a choice by The fiber strand with the unique coating of the present invention inhibits the fiber strand from contacting other solid objects such as rolling A part of the weaving or knitting device) or abrasion due to abrasion between filaments. For the purpose of this specification, it should be understood that it is used in this specification and applications except in operating examples or at designated places. All the quantities in the patent scope indicating ingredients, reaction conditions, etc. are modified in all cases by the term "about". Therefore, unless stated to the contrary, the quantitative parameters set forth in the following description and the scope of the appended patent applications are approximate, and may vary depending on the desired properties sought to be obtained by the present invention. At a minimum, and not to limit attempts to apply physiology such as patent application parks, each quantitative parameter should be considered at least in terms of the number of reported major digits and the application of general round-off techniques. Although the quantitative ranges and parameters of the broad description of the present invention are approximate, the numbers described in the specific examples are reported as accurately as possible. However, any data (please read the notes on the back before filling this page)

r --- ^ --------- II -J0 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 557286

5. Description of the invention (7) inherently contains certain errors necessarily generated by the standard deviation found in each of its experimental measurements. Reference is now made to FIG. 1, where the same numbers indicate the same elements. In FIG. 1, a coated fiber strand 10 according to the present invention comprising a plurality of fibers 12 is shown. As used herein, &quot; strand &quot; means a plurality of individual fibers, that is, at least two fibers, and the strand may contain fibers made of different fiberizable materials. (Fiber bundles may also be referred to as &quot; yarn &quot;). "Fiber" means individual filaments. Although not limiting the invention, the fiber 12 preferably has an average nominal fiber diameter of 3 to 35 microns. Preferably, the average nominal fiber diameter of the present invention is 5 m or more. For "spinning" applications, the average nominal fiber diameter is preferably in the range of 5 to 7 microns. The fibers 12 may be formed from any type of fiberizable material known to those skilled in the art, including fiberizable inorganic materials, fiberizable organic materials, and mixtures of any of the foregoing. Inorganic and organic materials can be man-made or naturally occurring materials. Those skilled in the art should understand that inorganic and organic materials that can be fiberized can also be polymeric materials. As used herein, the term "polymeric material" means a material formed of macromolecules 1 composed of long-chain atoms bonded together in a solution or solid phase. The term &quot; fibrillable &quot; as used herein means a material that can form substantially continuous filaments, fibers, strands, or yarns. Preferably, the fibers 12 are formed of an inorganic, fiberizable glass material. Fibrous glass materials include, but are not limited to, Inorganic Poly mers. Prentice Hall Polymer Science and Engineering Series, such as "glass" James Mark et al. (1992), page 1, which is incorporated herein by reference. This paper standard applies China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ----- r --- Order --------- Line | Economy Printed by the Consumer Cooperative of the Ministry of Intellectual Property Bureau-1. 557286 A7 ----___ B7 V. Description of Invention (8), &quot; A_glass &quot;, "C-glass &quot;, &quot; D-glass", "R_Glass", "S_Glass", and the producer of fiberizable glass compositions with E-glass derivatives. "E_Glass derivatives" as used herein means a small amount of fluorine and / or boron, Moreover, it is preferably a fluorine-free and / or boron-free glass composition. In addition, "less" used here "Amount of fluorine" means less than 0.5% by weight of fluorine, preferably less than oj by weight. /? Of fluorine, and "a small amount of boron" means less than 5% by weight of boron, preferably less than 2% by weight of boron. Basalt and mineral wool are examples of other fiberizable glass materials used in the present invention. Preferred glass fibers are formed from E-glass or E-glass derivatives. This composition is known to those skilled in the art, and further discussion of this composition is not considered necessary for the purposes of the present invention. The glass fibers of the present invention can be formed by any suitable method known in the art for forming glass fibers. For example, glass fibers can be formed in a direct melting fiber forming operation or an indirect or marble-dissolving fiber forming operation. In a direct dissolving fiber formation operation, the raw materials are combined, melted, and homogenized in a vitrification furnace. The molten glass moves from the furnace to the forehearth and enters the forming device, where the molten glass is thinned into continuous glass fibers. In the marble-melting fiber forming operation, a glass sheet or marble having a final desired glass composition is previously formed and fed into a liner, where it is melted and thinned into continuous glass fibers. If a pre-melter is used, the marbles are first fed into the pre-melter, melted, and then the molten glass is fed into the fiber forming device where the glass is thinned to form continuous fibers. In the present invention, the glass fibers are preferably formed by a direct melting fiber forming operation. For additional information on glass compositions and methods of forming glass fibers, see K. Loewenstein's The Manufacturing Technology of Continuous Glass Fibres (3-11)-This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) ) (Please read the precautions on the back before filling out this page) ---- l · --- Order --------- Line _ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-i. 557286 Economy Printed by the Intellectual Property Bureau of the Ministry of Consumers and Consumer Cooperatives A7 B7 V. Invention Description (9) Edition, 1993) Pages 30-44, 47-103, and 115-165; US Patents 4,542,106 and 6,789,329; and IPC-EG-140 &quot; Specification for

Finished Fabric Woven from Έ * Glass for Printed Board ’, page 1, The Institute for Interconnecting and Packaging Electronic Circuits publication (June 1997), which is specifically incorporated herein by reference. Non-limiting examples of suitable non-glass fiberized inorganic materials include ceramic materials such as silicon carbide, carbon, graphite, mullite, alumina, and piezoelectric ceramic materials. Non-limiting examples of suitable fiberizable organic materials include cotton, cellulose, natural rubber, linen, ramie, hemp, ramie, and wool. Non-limiting examples of suitable fiberizable organic polymeric materials include polyamines (such as nylon and aromatic amines), thermoplastic polyesters (such as polyethylene terephthalate and polybutylene terephthalate), Formers of acryl (such as polyacrylonitrile), polyolefin, polyurethane and acetamyl polymers (such as polyethylene glycol). The non-glass fiberized materials used in the present invention and methods for making and processing such fibers are discussed in detail in Encyclopedia of Polymer Science and Technology, Vol. 6 (1967), pages 505-712, which is specifically incorporated herein by reference . It should be understood that if desired, a blend or copolymer of any of the above materials and a combination of fibers formed from any of the above materials can be used in the present invention. In addition, the noun strand contains at least two different fibers made from different fiberizable materials. In a preferred embodiment, the fiber strand of the present invention contains at least one glass fiber, although it may contain other types of fibers. The present invention is now generally discussed about the content of glass fiber strands, although those skilled in the art should understand that the strand 10 may contain the technique known from the above discussion. -12- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the phonetic on the back? Matters before filling out this page)

557286 A7 Fifth, the description of the invention (10) fiber 12 formed of a fiberizable material. Therefore, the following discussion of glass fibers applies broadly to the other fibers discussed above. Continue to refer to the figure! In a preferred embodiment, at least one of the fiber strands 10 of the present invention-and preferably all of the fibers 12 have a coating composition (which is preferably a residue of the coating composition) on at least a portion of the surface 16 of the fiber 12 Part 17 has an I layer 14 to protect the fiber surface 16 from abrasion and inhibit fiber breakage during processing. Preferably, the layer 14 is present on the entire outer surface 16 or the periphery of the fiber 12. The coating composition of the present invention is preferably an aqueous coating composition, and more preferably an aqueous resin-compatible coating composition. Although it is not preferable for safety reasons, the coating composition may contain a volatile organic solvent, such as alcohol or acetone, as desired, but it is preferably free of such a solvent. In addition, the coating composition of the present invention can be used as a first sizing composition and / or a second sizing or coating composition. In a preferred embodiment, the terms &quot; sizing &quot;, sizing &quot;, or &quot; sizing Sizillg &quot; as used herein refer to any coating composition that is applied to the fibers after the fibers are formed. The term "second sizing secondary" refers to the "secondary sizing" or, "second coating", which refers to the coating of fibers after the first sizing is applied.层 组合 物。 Layer composition. The term "third sizing tertiary size", "third sizing tertiary sizing", or "third coating" means a coating composition that is applied to the fibers after the first coating is sized. For example, by coating the fabric, these coatings may be applied to the fiber &apos; before the fiber is added to the fabric or it may be applied to the fiber after the fiber is added to the fabric. In alternative embodiments, the noun, size size, or "size sizing" or "sizing sizing" additionally means that at least a portion has been removed by heat or chemical treatment, and (please first (Read the notes on the back and fill in this page) ------ ^ ---- Order --------- line * Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-X. -13- 557286 A7 --- ~ _-- V. Description of the invention (11) and preferably all conventional non-resin compatible sizing compositions are applied to the fiber coating composition (also known as, trimming) "Sizing"), that is, trimming the bare glass fibers that are applied to the fabric form. The term "resin compatible" as used herein means that the coating composition applied to the glass fiber is compatible with the matrix material to which the glass fiber is added, so that the coating composition (or selected coating component) has at least one of the following Properties: It does not need to be removed before adding the matrix material (such as degreasing or degreasing), it is good for the good wetting and penetration of the matrix material during the conventional processing, and it can produce the final composite product with the required physical properties and hydrolytic stability. The coating composition of the present invention comprises one or more, and preferably a plurality of particles 18, which adhere to the outer surface 16 of at least one fiber 23 when applied to at least one fiber 23 of a plurality of fibers 12, and One or more interstitial spaces 21 are provided between adjacent glass fibers 23, 25 of the strand 10, as shown in Fig. 1. These interstitial spaces 21 are roughly equivalent to the size 19 of particles 18 located between adjacent fibers. The present invention The particles is preferably discontinuous particles. The term "π discontinuity" as used herein means that the particles do not tend to agglomerate or combine to form a continuous film under conventional processing conditions, but essentially retain their Individual differences and often retain their individual shape or form. The discontinuous particles of the present invention can be sheared during the conventional fiber treatment, that is, removing a layer or a piece of atoms in the particles, necking, that is, second-order phase transfer between at least two particles, and partial coalescence. And can still be regarded as "discontinuous" particles. The particles 18 of the present invention are preferably dimensionally stable. The term "size-stable particles" as used herein means that the particles are under conventional fiber processing conditions, such as weaving, spinning The force generated between adjacent fibers during strip processing and other processing operations. Generally, the dimensions of the dimension paper are applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)- ---- r --- Order --------- line * Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-1. V. Description of the invention (u) 2 Its average particle size and shape, while maintaining relative phase The gap between adjacent fibers 23 and 25 is changed. In other words, under typical glass fiber processing conditions, such as exposure to up to 25. (:, preferably $ 100r, and more preferably up to i4oec temperature $, The size-stable particles are preferably formed in the coating composition without dissolving or qualitatively deforming. Particles smaller than the maximum size of the selected average particle size. In addition, under glass fiber processing conditions, and more preferably in composite processing conditions where the degree exceeds 150 × :, the size of the particles M should not be qualitatively larger. Or swell. The term "particles" used here should be substantially unchanged in size. • indicates that the particles should not be swelling or increased in size during processing: beyond their initial size <three times. In addition, the term used here The term &quot; size-safe particle &quot; encompasses both crystalline and amorphous particles. Preferably, the coating composition of the present invention is substantially free of thermally expandable particles. ^ The term used herein &quot; thermally expandable particles &quot; means filled or A 'grain' containing a certain material becomes larger when exposed to a temperature sufficient to volatilize the material. These heat-swellable particles therefore swell due to the phase change of the material in the particles (oral agent) under normal processing conditions. . Knot = noun non-thermally expandable particles &quot; refers to particles that do not swell due to the phase change of the material in the particles under normal processing conditions'; and in the embodiment of the present invention, the coating composition contains at least one non-thermally expandable particle:, Often, thermally expandable particles are hollow particles with a central cavity. In a non-limiting specific embodiment of the present invention, cavities, materials, such as gas, liquid, and / or gel. The term “filling non-solid materials with wounds” is “substantially no thermally expandable particles” means thermally expandable particles at 5G% by weight based on the total solid M V, more preferably less than 5% by weight 557286 A7 B7 V. Description of the Invention (13) (Please read Note S on the back before filling out this page)%. More preferably, the coating composition of the present invention is essentially free of thermally expandable particles. The term "essentially thermally expandable particles" as used herein means that the sizing composition contains less than 20% by weight of thermally expandable particles based on total solids, more preferably less than 5% by weight, and most preferably less than 0.001% by weight. The particles 18 are preferably non-wax. The term &quot; non-wax-like &quot; means that the material forming the particles is non-soily. The term &quot; 壌 -like &quot; as used herein means that the material is mainly composed of an immiscible hydrocarbon chain having an average carbon chain length ranging from 25 to 100 carbon atoms 2'3. In a preferred embodiment of the present invention, the particles 18 of the present invention are discontinuous, dimensionally stable, non-wax particles. The particles 18 may have any desired shape or configuration. Although in the present invention Without limitation, examples of suitable particle shapes include spherical (such as particles, particles, or hollow spheres), cubes, plates, or needles (long or fibrous). In addition, the particles 18 may have a hollow, porous, or non-porous shape. Internal structure, or a combination of 'for example', 2 central and porous or solid walls. For more information on particle characteristics see Η. Katz et al. (Eds.) Handbook of Fillers and Plastics (1987) p. 9.10, It is specifically incorporated here as the Printing of 2 LH Sperling's Introduction of Physical Polymer Science, John Wiley and Sons Company (1986) pages 2-5. 3 W. Pushaw et al. &Quot; Use of Micronised Waxes and Wax Dispersions in Waterborne Systems1 丨 Polymers. Paint. Colours JournaL, Vol. 189, No. 4412, 18-21 January 1999 Page, which is specifically incorporated herein by reference. -16- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557286 A7 B7_ V. Description of the invention (l4) for reference. (Please first Read the note on the back? Matters and then fill out this page) Particles 18 may be formed of materials selected from the group consisting of polymeric and non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and any mixtures thereof. The term "polymeric inorganic" used herein Material &quot; means a polymeric material with a backbone repeating unit mainly composed of elements other than carbon. More information can be found on page 5 of the answer by L K. Mark, which is specifically incorporated herein by reference. The term 'polymeric organic material' as used herein refers to synthetic polymeric materials, semi-synthetic polymeric materials, and natural polymeric materials with carbon-based backbone repeating units. "Organic materials" as used herein refers to carbon-containing compounds, of which carbon Generally bonded to itself and hydrogen, and often to other elements, and excludes binary compounds such as carbon oxides, carbides, carbon disulfide, etc .; ternary such as metal cyanide, metal carbonyl, phosgene, carbonyl sulfur, etc. Compounds; and carbon-containing ionic compounds such as metal carbonates, such as calcium carbonate and sodium carbonate. See R. Lewis, Sr., Hawlev's Condensed Chemical Dictionary, (12th edition, 1993), pages 761-762, and M. Silberberg's Chemistry IM Molecular Nature of Matter and Change (p.996), page 58, which is specifically incorporated herein by reference. The term "inorganic materials" as used herein means any material that is not an organic material and is consumed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative printed materials. The term "composite material" as used herein means a combination of two or more different materials. Particles formed from composite materials usually have a hardness on their surface that is different from the internal hardness of the particles below the surface. More specifically, the surface of the particles can be modified by any method known in the art, including but not limited to using technical chemistry known in the art Change the surface characteristics physically or physically, so that the __- of the particles 17- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 A7

557286 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (l6) slides on each other, so the anti-friction lubrication effect is produced between the fiber surface (preferably glass fiber surface) and the adjacent solid surface, where At least one moves. See R. Lewis, Sr., Hawlev, Condensed Chemical Dictionary. (12th edition, 1993) at page 712, which is specifically incorporated herein by reference. Friction is the resistance of solids to sliding against each other. F. Clauss, Solid Lubricants and Self-Lubricating Solids (1972), page 1, which is specifically incorporated herein by reference. In a non-limiting specific embodiment of the invention, the particles 18 have a thin flat structure. The particles having a thin flat structure are composed of atomic sheets or plates of a hexahedral array, which have strong bonds in the sheets and weak Van der Waals bonds between the sheets, and provide low shear strength between the sheets. A non-limiting example of a thin flat structure is a hexahedral crystal structure. Friction by K. Ludema, Wear, Lubrication (1996) p. 125, Solid Lubricants and Self-Lubricating Solids 19-22, 42-54, 75-77, 80-81, 82, 90-102, 113-120 and 128 pages; and `` Solid Lubricants '' by W. Campbell, Boundary Lubrication: An Appraisal of World Literature, ASME Research Committee on Lubrication (1969), pages 202-203, which are specifically incorporated herein by reference. Inorganic solid particles having a thin flat fullerene (large sphere) structure can also be used in the present invention. Non-limiting examples of suitable materials having a thin flat structure that can be used to form the particles 18 of the present invention include boron nitride, graphite, metal dichalcogenides, mica, talc, stone bone, kaolin, calcite, cadmium cracking, silver sulfide, And any mixture of the above. Preferred materials include boron nitride, graphite, metal dichalcogenides, and mixtures of any of the above. Suitable metal disulfide-19- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page) ------ ^ ---- Order --------- line | IV—-557286 A7 B7 V. Description of the invention (17) Compounds include molybdenum disulfide, molybdenum diselenide, giant disulfide, lithium diselenide, two Tungsten sulfide, tungsten diselenide, and mixtures of any of the above. (Please read the notes on the back before filling this page.) In a specific embodiment, the particles 18 are formed of an inorganic solid lubricant material with a thin flat structure. A non-limiting example of an inorganic solid lubricant material having a thin flat structure for use in the coating composition of the present invention is boron nitride, preferably boron nitride having a hexahedral crystal structure. Particles formed from boron nitride, zinc sulfide, and microcrystalline kaolinite also provide good whiteness in composites with a polymeric matrix material such as nylon 6,6. Non-limiting examples of particles formed from boron nitride suitable for use in the present invention are printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics, which are POLARHERM® 100 series (PT 120, PT 140, PT 160, and PT 180); 300 series (PT 350) and 600 series (PT 620, PT 630, PT 640, and PT 670) boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. 0 `` PolarTherm® Thermally Conductive Fillers for Polymeric Materials, '' Ohio Technical Bulletin by Advanced Ceramics of Lakewood (1996), which is specifically incorporated herein by reference. These particles have a heat transfer at 25 ° C per meter. K 250-300 watts of heat transfer, a dielectric constant of 3.9 and 1015 Ohm-centimeter volume resistivity. 100 series powder particles have an average particle size ranging from 5 to 14 microns, 300 series powder particles have an average particle size ranging from 100 to 150 microns, and 600 series powder particles have a range from 15 to Average particle size greater than 200 microns. In particular, as reported by its supplier, POLARTHERM 160 particles have an average particle size of 6 to 12 microns, with submicrons to 7 0 micron particle size range, and the following particle size distribution: -20- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557286 A7 B7 V. Description of the invention (is% 10 50 90 Size (micron ) 18.4 7.4 0.6 According to this distribution, 10% of POLARTHERM (g) 16 boron nitride particles have an average particle size greater than 18.4 microns. As used herein, “average particle size” refers to the average particle size of the particles Size. The average particle size of the particles according to the present invention can be measured according to known laser scattering techniques. In a non-limiting embodiment of the present invention, the particle size is measured using a Beckmai] Coulter LS 230 laser diffraction particle size analyzer, which uses 75 〇 Nanometer wavelength laser beam measurement particle size, and assuming that the particles have a spherical shape, that is, &quot; particle size &quot; refers to the smallest sphere that completely encapsulates the particles. For example, it was found that the pOLARTHER was measured using a Beckman Coulter LS 23〇 particle size analyzer. Nitrided particles have an average particle size of U.9 microns, the particle size range is from sub-microns to 36 microns, and have the following particle distribution: According to this distribution, the measured POLARTHER 10% of boron nitride particles have an average particle size greater than 20.6 microns. In another non-limiting embodiment of the invention, the particles M are formed from a hydrated inorganic material. As used herein, "Non-J .. J-shirts do not have particles and do not react with water to form hydrates, and do not contain hydrated water or 'water." "Hydrate" does not break through the water molecule and the Η-〇Η bond in it. 2 __ _21_ $ Applicable to China National Standard (CNS) A4 specification (210 X 297) — (Please read the precautions on the back before filling this page) --------- ^ ------ --- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (19) Reaction Manufacturing 0 See R. Lewis, Sr., Hawley's Condensed Chemical Dictionary, ( 12th edition, 1993) pages 609-610, and T. Perros Chemistry &gt; (1967) pages 186-187, which are specifically incorporated herein by reference. In the formula for hydrates, the addition of water molecules Conventionally, it is represented by a central point, for example, 3Mg0.4Si〇2.H2〇 (talc), Al2O3.2SiO2.2H2O (kaolin). Structurally, the hydratable inorganic material includes at least one hydroxyl group in a layer of a lattice (but not Unit structure surface including material that absorbs water by capillary action on its surface plane Planar hydroxyl), for example, as shown in the structure of kaolin as shown in Figure 3.6, J. Mitchell's Fundamentals of Soil Behavior (1976), page 34, and Clav Colloid Chemistry, each by H. van Olphen. Edition, 1977) The structure of the 1: 1 and 2: 1 layers of minerals shown in Figures 18 and 19 on page 62 is specifically incorporated herein by reference. A "layer of π lattice is a sheet (which is Combination of atomic planes) 0 (see Minerals in Soil Environments. Soil Science Society of America (1977) pp. 196-199, which is specifically incorporated herein by reference). The aggregation of layers and interlayer materials (such as cations) is called a unit structure. Hydrates contain coordination water that coordinates cations in the hydrated material and cannot be removed without breaking up the structure and / or structured water (which occupies gaps in the structure to increase electrostatic energy without disrupting charge balance). An Introduction to Crystal Chemistry by R. Evnas Π948 ^ p. 276, which is specifically incorporated herein by reference. Generally, the coating composition contains no more than 50% by weight of hydratable particles. In a non-limiting embodiment of the invention, the coating composition is preferably essentially free of hydratable particles. As used herein, the term "essentially free of hydratable particles" means that the coating composition contains less than -22-based on total solids. Table paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) · (Please (Please read the notes on the back before filling this page) ------ r --- Order --------- line j 557286 A7, invention description (2) B7 employee consumption of Intellectual Property Bureau, Ministry of Economic Affairs Cooperatives are printed on 20% by weight of hydratable granules, more preferably less than 5% by weight 0/0, and the best horse is less than 0.001% by weight. In the specific embodiment of the present invention, Granules: formed of a non-hydratable inorganic solid lubricant material. The coating composition according to the present invention may be replaced by or in addition to the non-hydratable inorganic materials discussed above. ... formed from a hydrated or hydrated inorganic material: granules. This A non-limiting example of a hydratable inorganic material is a clay mineral sheet that includes mica (such as muscovite), talc, microcrystalline kaolinite, kaolin, and stone. As explained above, formed from such hydratable or hydrated inorganic materials The particles usually have a composition not exceeding that of the coating composition 50 weight of the granules 0/000 In another specific embodiment of the present invention, the granules 18 may be formed of a non-polymeric organic material. The non-polymeric organic materials of the present invention include, but not less than, stearates (such as stearates). Zinc acid and aluminum stearate) 'carbon black and stearylamine. In another specific embodiment of the present invention, the particles 18 may be formed from an inorganic polymeric material. Non-limiting examples of useful inorganic polymeric materials include tritium Dreamane, polyoxygen, polythioxan, polysulfide, polyhabit, polyoxygen, and any mixture of the above. A specific, non-limiting example of particles formed from an inorganic polymeric material suitable for use in the present invention is TOSPEARL4 , Which is a particle formed from cross-linked siloxane, and is commercially available from Toshiba Polysilicon, Japan. In another embodiment of the present invention, the particle 18 may be formed from a synthetic organic polymer material. Suitable organic polymer material Including but not limited to thermosetting materials and thermoplastic materials. Suitable thermosetting materials include thermosetting polyester, ethyl acetate, epoxy material, hope system, amine-based plastic, thermosetting polyamine. 23 This paper applies National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) n ϋ I .1 ϋ ϋ ϋ J1 · -l · L ------- ---- r --- order -------- line '557286 A7 B7 V. Description of the invention (21) Formate, and any mixture of the above. Better synthetic polymeric particles formed from epoxy materials Specific non-limiting examples are epoxy micelle particles. Suitable thermoplastic materials include thermoplastic polyesters, polycarbonates, polyolefins, propylene polymers, polyamides, thermoplastic polyurethanes, vinyl polymers, and A mixture of any of the above. Preferred thermoplastic polyacetates include, but are not limited to, poly (ethylene terephthalate), poly (butylene terephthalate), and poly (ethylene terephthalate). Preferred polyolefins include, but are not limited to, polyethylene, polypropylene, and polyisobutylene. Preferred propylene polymers include copolymers of styrene and acrylic monomers and polymers containing methacrylic acid. A non-limiting example of a synthetic polymeric particle formed from a propylene copolymer is RHOPLEX® B-855, which is an opaque, non-crosslinked solid propylene particle emulsion, ROPAQUE® HP-10556, which has a particle size of 1.0 microns and 26.5% by weight solids Content and 55% pore volume of opaque, non-film-forming styrene-propylene polymerized synthetic pigments, ROPAQUE® OP-967 and ROPAQUE® HP-543P8, which are the same opaque, non-film-forming with a particle size of 0.55 micrometers and a solid content of 30.5% by weight Styrene acryl polymer synthetic pigment dispersion liquid, and ROPAQUE® OP-62 L09, which is also an opaque, non-film-forming styrene acryl polymer synthetic pigment dispersion liquid with a particle size of 0.40 microns and a solid content of 36.5% by weight. Each designated particle is commercially available from Rohm and Haas, Philadelphia, PA 0 4 See R.J. Perry, 'Applications for Cross-Linked Siloxane Particles &quot; Chemtech, February 1999, pages 39-44 0 5 See also from the guest "Chemicals for the Textile Industry" by Rohm and Haas, Inc., Philadelphia, September 1987. 6Refer to the property sheet from Rohm and Haas Company of Philadelphia, PA, -24- The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back first? Matters to be filled out (This page)

----- r --- Order --------- Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Invention Description (22) Title: &quot; ROPAQUE® HP-1055 , Hollow Sphere Pigment for Paper and Paperboard Coatings &quot; October 1994, page 1, which is here (please read the precautions on the back before filling this page) for reference. 7 See product technical bulletin from Rohm and Haas, Philadelphia, PA, title: &quot; Architectural Coatings · ROPAQUE® OP-96. The All Purpose Pigment ·· 1 &quot; April 7, page 1, which is available in This is incorporated as a reference. 8 ROPAQUE® HP-543P and ROPAQUE® OP-96 are the same material; this material is considered ROPAQUE® HP-543P in the paint world and ROPAQUE® OP-96 in the coating world. 9 See product technical bulletin from Rohm and Haas, Philadelphia, PA, title: &quot; Architectural Coatings- ROPAQUE® OP-96 · The All Purpose Pigment &quot; 1 April, page 1, which is hereby incorporated herein Included as reference 0 The particles 18 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs may be formed from semi-synthetic organic polymer materials and natural polymer materials. "Semi-synthetic materials" as used herein are chemically modified naturally occurring materials. Suitable semi-synthetic organic polymeric materials from which particles 18 can be formed include, but are not limited to, cellulose, such as methyl cellulose and cellulose acetate; And modified starches, such as starch acetate and starch hydroxyether. Suitable natural polymeric materials from which particles 18 can be formed include, but are not limited to, glycans such as starch; peptides such as casein; and natural hydrocarbons such as natural rubber and paleo In the non-limiting specific embodiment of the present invention, the polymer particles 18 are formed of a hydrophobic polymer material to reduce or limit the water absorption by the coating strand. This kind of paper is -25- This paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) 557286 A7 B7 V. Description of the invention (23) Non-limiting examples of water-based polymeric materials include, but are not limited to, polyethylene, polypropylene, polystyrene, and polymethacrylate Non-limiting examples of polystyrene copolymers include ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62 L0 pigments (as discussed above). In another non-limiting embodiment of the invention, the polymeric particles 18 are formed of a polymeric material having a glass transition temperature (Tg) and / or melting point of greater than 25 ° C and preferably greater than 50 ° C. In another aspect of the invention In a non-limiting specific embodiment, the particles 18 may be hollow particles formed of a material selected from the group consisting of polymeric and non-polymeric inorganic materials, polymeric and non-polymeric organic materials, composite materials, and any mixtures thereof. Non-limiting examples of materials are as described above. Non-limiting examples of hollow polymeric particles used in the present invention are ROPAQUE® HP-1055, ROPAQUE® OP-96, ROPAQUE® HP-543P, and ROPAQUE® OP-62LO pigments (each as (Discussed above). For other non-limiting examples of hollow particles used in the present invention, see H. Katz et al. (Ed.) (1987) at 437-452, which is specifically incorporated herein by reference. Bureau of Intellectual Property, Ministry of Economic Affairs Printed by employee consumer cooperatives (please read the precautions on the back before filling this page)

The particles 18 used in the coating composition of the present invention may be present as a dispersion, suspension or emulsion in water. If desired, other solvents, such as mineral oil or alcohol (preferably less than 5% by weight) may be included in the dispersion, suspension, or emulsion. A non-limiting example of a preferred dispersion of particles formed from an inorganic material is ORPAC BORON NITRIDE RELEASECOAT-CONC, which is a 25 weight ° / ° dispersion of boron nitride particles in water, and is commercially available from Oak Ridge, Tennessee ZYP Coatings. 'ORPAC BORON • 26- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 V. Invention Description (24) NITRIDE RELEASECOAT-CONC · · The technical bulletin of ZYP Coatings, specifically incorporated herein by reference. According to this technical bulletin, the boron nitride particles in this product have an average particle size of less than 3 microns and include 1% magnesium-aluminosilicate to bond the boron nitride particles to the dispersion-coated substrate. ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron Nitride Independent tests using a Beckman Coulter LS 230 particle size analyzer found an average particle size of 6.2 microns, with particles ranging from sub-microns to 35 microns, and having the following particle distribution:% 10 50 90 size ( Micron) 10.2 5.5 2.4 According to this distribution, 10% of the measured ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles have an average particle size greater than 10.2 microns. Other commercially available products from ZYP Coatings include BORON NITRIDE LUBRICOAT® coatings, and BRAZE STOP and WELD RELEASE products. Specific non-limiting examples of emulsions and dispersions of synthetic polymeric particles formed from propylene polymers and copolymers include: RHOPLEX® B-85 propylene emulsion (as discussed above), RHOPLEX® GL-62310, which has 45% by weight Full acrylic hard polymer emulsion with solid content and glass transition temperature of 98 ° C; EMULSION E-232111, which is a hard methacrylate polymer emulsion with 45% solids content and glass transition temperature of 105 ° C; ROPAQUE® ΟΡ · 96 and ROPAQUE® HP-543P (such as -27 · This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm).… — — — — —-III l · III 一： 0 'a — — — — — — — — (Please read the note on the back? Matters before filling out this page) 557286 A7 B7 V. Description of the invention (25) (Please read the notes on the back before filling out this page) (Discussed above), which is supplied as a dispersion having a particle size of 0.55 micron and a solid content of 30.5% by weight; ROPAQUE® OP-62 LO (as discussed above), which has a particle size of 0.40 micron and a solid content of 36.5% by weight Dispersion Supplied; and ROPAQUE® HP-1055 (as discussed above), which as a dispersion having a solids content of 26.5 wt% of the supplied; both of which are commercially available from Rohm and Haas of Philadelphia, Pennsylvania company. 1Q See product property sheet from Rohm and Haas, Philadelphia, PA, title: &quot; Rhoplex® GL-623, Self-Crosslinking Acrylic Binder of Indrustrial NonwovensM, March 1997, incorporated herein by reference 0 11 See the property sheet from Rohm and Haas, Philadelphia, Pennsylvania, titled: "Building Products Industrial Coatings- Emulsion E-2321", 1 &quot; 0, which is incorporated herein by reference. Employees ’Consumption, Intellectual Property Office Printed by a cooperative In a particularly preferred embodiment of the present invention, the coating composition comprises at least one inorganic particle (especially boron nitride, and more particularly obtained under the brand name POLARTHERM® and / or ORPAC BORON NITRIDE RELEASECOAT-COISTC Nitriding shed) and a mixture of at least one thermoplastic material (especially a copolymer of styrene and propylene monomers, and more particularly a copolymer obtained under the trade name ROPAQUE®). The particles 18 are selected to obtain sufficient space between adjacent fibers. The average particle size required for the desired interval is 19. For example, it is preferably selected to add a sizing composition (which is applied to Machine-treated fibers 12), with an average particle size 19 of particles 18, to provide a space between at least two adjacent fibers sufficient to transport the strands of air 10 through the loom. "Air-jet weaving fabrics" used herein 28- &gt; Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557286 Printed by A7 of the Consumer Property Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (26) Machine π indicates that it is familiar with the artist The known method inserts the filling yarns (weft yarns) into the warp shed with strong compressed air from one or more air jet nozzles &lt; weaving pattern. In another example, the average particle size 19 of particles 18 added to a sizing composition (coated on fibers 12 impregnated with a polymeric matrix material) is selected to provide a sufficient amount of fiber strands 10 between at least two adjacent fibers Good moisturizing and soaking interval. Although not limiting the present invention, the particles 18 preferably have an average particle size of not more than 1000 micrometers as measured using laser scattering technology, more preferably 0.001 to 100 micrometers, and most preferably 0 to 25 micrometers. Average granularity. In a specific, non-limiting embodiment of the present invention, the average particle size 19 of the particles 18 is at least 0.1 micron, preferably at least 0.05 micron, and ranges from 0.1 micron to 5 micron, and preferably 0.5 Micrometer to 2 micrometers. In a specific embodiment of the invention, the particles 18 have an average particle size 19 which is generally smaller than the average diameter of the fibers 12 coated by the coating composition. It has been observed that interwoven yarns made from fiber strands 10 with the residue of a layer of the first superior composition (which contains particles 18 with an average particle size of 19 as discussed above) 10 can be beneficial when impregnated with a polymeric matrix material Provide sufficient space between adjacent fibers 23, 25 to allow 2 nozzles to shoot weaving power (ie, air jet transport through the loom), while maintaining the integrity of the fiber strands 10 and providing acceptable wet through and wetness characteristics . In another non-limiting specific embodiment of the present invention, the particle μ = the average particle size 19 is at least 3 microns, preferably at least 5 microns, and the range: horse 3 microns to 100 microns, preferably 5 microns to Micrometers, and more preferably ... micrometers. In this specific embodiment, it is also preferable that the particles are ___ -29- The paper size is suitable ^? ^ Standard (CNS) A4 χ Nomm · 11 l · J l · L .-------- --- r --- Order --------- line (Please read the precautions on the back before filling this page) 557286 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

557286 A7 V. Description of the invention (28) Wear of glass fiber. For example, many parts of interlaced frames, looms, and knitting devices are formed of a metal material such as steel, which has a Mohs hardness up to 8.5ΐ2. The abrasion of the glass fiber strands due to the rough surface contacting these solid objects causes the strands to be broken during processing and surface defects of products such as woven fabrics and composites, which increase waste and manufacturing costs. 12

Handbook of Chemistry and Physics on page F-22. To minimize abrasion, in a non-limiting specific embodiment of the present invention, the particles 18 have a hardness 値 that does not exceed (i.e., less than or equal to) the glass fiber hardness 玻璃. The hardness 値 of particles and glass fibers can be measured by any conventional hardness measurement method, such as Vickers or Brinell hardness, but it is preferably measured according to the original Mohs hardness scale, which indicates the relative scratch resistance of the surface of the material from 1 to 10. The Mohs hardness 値 of glass fiber is usually in the range of 4.5 to 6.5, and is usually 6. R. Weast (ed.) Handbook of Chem ^ try and £ 11, £ 1, 01 ^? 88 (1975), page 1 ^ 22, which is specifically incorporated herein by reference. In this specific embodiment, the particle 18 Mohs hardness 値 is preferably in the range of 0.5 to 6. The Mohs hardness of many non-limiting examples of particles formed from inorganic materials suitable for use in the present invention is shown in Table A below. (Please read the notes on the back before filling this page)

.----- r --- Order --------- Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 31- This paper size applies to China National Standard (CNS) A4 (210 X 297) (Mm) 557286 AB7 V. Description of the invention (29) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics. Table A Mohs hardness of granular materials, (original scale) Nitrided shed 213 Graphite 0.5-114 Molybdenum disulfide I15 Talc 1.1.516 Mica 2.8-3.217 Kaolin 2.0-2.518 Gypsum 1.6-219 Calcite (Calcium Carbonate) 320 Calcium Fluoride 421 Zinc Oxide 4.522 Jiang Lu 2.523 Copper 2.5-324 Iron 4-525 Gold 2.5-326 Nickel 527! Bar 4.828 Platinum 4.329 Silver 2.5- 430 Zinc sulfide 3.5-431 13 K Ludema, Friction, Wear, Lubrication, (1996), page 27, its -32- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) BU- £ — 1 — 1— I — I — — — — (Please read the notes on the back before filling out this page) 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (3〇) Reference. 14 R. Weast (editor), Handbook of Chemistry and Physics. CRC Press (1975) at page F-22. 15 R. Lewis, Sr., Hawley's Condensed Chemical Dictionary, (12th edition 1993) p. 793, which is incorporated herein by reference. 16 Hawley's Condensed Chemical Dictionary, (12th edition 1993) p. 1113, which is incorporated herein by reference. 17 Hawley's Condensed Chemical Dictionary, (12th edition 1993) p. 784, which is incorporated herein by reference. 18 Handbook of Chemistry and Physics page F_22. 19 Handbook of Chemistry and Physics on page F-22. 20 Friction. Wear · Lubrication p. 27. 21 Friction, Wear. Lubrication p. 27. 22 Friction, Wear. Lubrication p. 27. 23 Friction · Wear · Lubrication p. 27. 24 Handbook of Chemistry and Physics on page F-22. 25 Handbook of Chemistry and Physics, page F-22. 26 Handbook of Chemistry and Physics, page F-22. 27 Handbook of Chemistry and Physics, page F-22. 28 Handbook of Chemistry and Physics, page F-22. 29 Handbook of Chemistry and Physics, page F_22. 30 Handbook of Chemistry and Physics, page F-22. 31 R. Weast (editor), Handbook of Chemistry and Physics, CRC Press (71st Edition 1990), p. 4-158. -33- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 χ 297 mm). — — — — III h III (Please read the precautions on the back before filling out this page) 557286 A7 Can be the first material The surface or package, the particles can be the first surface or package. V. Description of the invention (31 As mentioned above, the scratch resistance of the material related to the Mohs hardness scale. The internal hardness of the particles. More specifically, as described above, the surface of the particles can be modified by any method known in the art, which includes but is not limited to the use of known techniques. The technology chemically changes the surface characteristics of the particles so that the surface hardness of the particles is less than or equal to the hardness of the glass fibers, and the particle size below the surface is greater than the hardness of the glass fibers. As for another alternative to form the particles, it is replaced by one or more second The material is coated to form a composite material with a softer surface. Or the material is formed to be coated with a first material in a different form to form a composite material with a softer surface. In examples, and without limiting the invention, inorganic particles formed from inorganic materials such as carbon cuts or nitrides may have silica, carbonate or nanoclay to form useful composite particles. In another non-limiting example, Silane coupling agents with alkyl side chains can react the surface of inorganic particles 2 formed from inorganic oxides to provide useful composite particles with &quot; softer &quot; surfaces. Examples of these include non-polymeric or polymeric materials and different Non-polymeric or polymeric materials for the formation, encapsulation or coating of particles. A specific, non-limiting example of such composite particles is DUALITE, a synthetic polymer particle coated with calcium carbonate, commercially available from Pierce and Buffalo, NY Stevens Company. In a specific embodiment of the present invention, the particles IS are thermally conductive, that is, they preferably have a heat transfer measured at 300 K of at least 0 2 watts per meter k, and more preferably at least 0.5 watts per meter K. In a non-limiting specific embodiment, the particle μ has a temperature of 300K measured at least 1 watt per meter κ, and more preferably per meter ------ ΦM ---- l ------ ------- Line · (Please read the back first Please fill out this page before printing} Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

A7

557286 5. Description of the invention (32) K has a heat transfer of at least 5 watts. In a preferred embodiment, the thermal conductivity of the particles is measured at a temperature of 300K as at least 25 watts per meter, more preferably at least 30 watts per meter, and even more preferably at least 100 watts per meter. In another preferred embodiment, the thermal conductivity of the particles ranges from 5 to 2000 watts per meter at a temperature of 300 κ, preferably 25 to 2000 watts per meter, and more preferably 30 watts per meter. To 2000 watts' and optimally 100 to 2000 watts per meter. As used herein, "thermal conductivity" means the nature of a particle that describes its ability to transfer heat through itself. See R. Lewis, Sr., Hawlev ^ RQndenRpH Chemical Dictionary, (12th edition, 1993) at page 305, which is specifically incorporated herein by reference. The thermal conductivity of a material can be determined by any method known to those skilled in the art. For example, if the thermal conductivity of the material under test ranges from 0.001 watts per meter to 100 watts per meter, it can be used at a temperature of 300K in accordance with ASTM C-177-85 (which is specifically incorporated herein by reference) The preferred method of isolating the heating plate measures the thermal conductivity of the material. If the thermal conductivity of the material under test ranges from κ 20 watts per meter to 1200 watts per meter κ, the thermal conductivity of the material can be measured using an isolated heat flux induction method in accordance with ASTM C_518_91 (which is specifically incorporated herein by reference). In other words, if the thermal conductivity ranges from 0.001 watts per metre to 20 watts per metre, use an isolated heating plate method. If the thermal conductivity range is more than 100 watts per meter, use the isolated heat flux sensing method. For the range of κ 20 to 100 watts per meter, either method can be used. In the isolated heating plate method, an isolated heating plate device including one isolated heating unit, two auxiliary heating plates, two cooling units, edge insulation, a second temperature control isolation, and a temperature sensor reading system was used to test two -35- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) First read the note on the back? Matters and then fill out this page) Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 5. Inventive Note (33) Essentially the same sample Place the sample on either side of the isolated heating unit with the opposite surface of the sample in contact with the auxiliary heating unit. The device is then heated to the required test temperature and maintained for the time required to obtain a thermally stable state. Once the steady state conditions are reached, record the heat flow (Q) through the sample and the temperature (ΔΤ) through the sample. The average thermal conductivity (KTC) of the sample is then calculated using the following formula:

Ktc = QL / A.AT where L is the average thickness of the sample and A is the average of the combined area of the sample. It is believed that materials with higher thermal conductivity dissipate faster from the hole area during drilling operations, resulting in extended drill life. The thermal conductivity of the selected materials in Table 8 is included in Table B. Although not necessary, in another embodiment used in the present invention, the particles are electrically insulating or have a high resistivity, that is, a resistivity greater than a microohm · cm. For conventional electronic circuit board applications, it is better to use particles with high resistivity to suppress the loss of electrical signals due to electron conduction through the reinforcement. For special applications, such as circuit boards used in microwave oven's radio frequency interference and electromagnetic interference suppression applications, particles with high resistivity are not required. The resistivity of the selected materials in Table A is included in Table B. Specifications of this paper: National Fresh (CNS) A4 (21〇-36-297 ^ 7 1) Jul ----------- r ---- Order --------- (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 557286 A7 __ —_B7 V. Description of Invention

Table B Thermal conductivity of inorganic solid materials Mohs hardness (IN / mK at 300K) (microohm-cm) (original scale) Boron nitride 20032 1.7 X 1〇1933 234 Boron phosphide 35035 9.536 Aluminum phosphide 13037 _- Aluminium nitride 20033 greater than 1019939 940 gallium nitride 17041 _-gallium phosphide 10042-silicon carbide 27043 4 X 105 to 1 X 1〇644 greater than 945 silicon nitride 3046 1109 to 102047 948 barium oxide 24049-950 32 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π 973, Vol. 34, p. 322, which is incorporated herein by reference. 33 A · Weimer (editor), Carbide, Nitride and Boride Materials

Synthesis and Processing, (1997) p. 654 0 34 Friction, Wear, Lubrication p. 27. 35 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (1973 ^ Vol. 34, p. 325, which is incorporated herein by reference. 36 R. Lewis, Sr., Hawley ^ Condensed Chemical Dictionary. (12th edition 1993) p. 104, which is incorporated herein by reference. -37- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

ItlhJtL ---------- ^ ---- Order --------- line (please read the notes on the back before filling this page) 557286 A7 B7 V. Description of the invention 37 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π973, Vol. 34, p. 333, which is incorporated herein by reference. 38 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (1973) Vol. 34, p. 329, which is incorporated herein by reference. ^ Q · Weimer (editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 654 0 40 Friction, Wear, Lubrication H 27. 41 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids 0973 ^ Vol. 34, p. 333. 42 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids Π973, Vol. 34, p. 321, which is incorporated herein by reference. 43 Microelectronics Packaging Handbook page 3, which is incorporated herein by reference. 44 A. Weimer (ed.), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) p. 653, which is incorporated herein by reference. 45 Friction. Wear. Lubrication p. 27. 46 Microelectronics Packaging Handbook H 3ό page, which is incorporated herein by reference. 47 A. Weimer (editor), Carbide, Nitride and Boride Materials Synthesis and Processing, (1997) page 654 0 -38- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (please first Read the notes on the back and fill out this page)--ill! Order! !! Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (36) 48 Friction, Wear, Lubrication, page 27, 49 Microelectronics Packaging Handbook page 905, It is incorporated herein by reference. 50 Hawlev's Condensed Chemical Dictionary, (12th edition 1993) page M1, which is incorporated herein by reference. Table B (continued) Thermal conductivity of inorganic solid materials Mohs hardness (IN / mK at 300K) (microohm-cm) (original scale) Zinc oxide 26 4.551 Zinc sulfide 2552 2 · 7 X 105 to 1.2 X 101253 3.5-454 diamond 230055 2.7 X 105 55 1057 silicon 8458 10.059 j60 graphite up to 200061 10062 0.55163 molybdenum 13864 5.265 5.566 platinum 6967 10.668 4 · 369 1 bar 7070 10.871 4.872 tungsten 20073 5.574 7.575 51 Friction , Wear. Lubrication p. 27. 52 Handbook of Chemistry and Physics, CRC Press (1975) pp. 12-54. 53 Handbook of Chemistry and Physics · CRC Press (71st Edition 199〇), pages 12_63, which are incorporated herein by reference. -39- This paper size is applicable to China National Standard (CNS) A4 specification (210 χ 297 mm) ----------- r-- 丨 order --------- line (please First read the phonetic on the back? Matters and then fill out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the Invention (37) 54 Handbook of Chemistry and Physics, CRC Press (71st Edition 1990) Section 4- Page 158, which is incorporated herein by reference. 55 Microelectronics Packaging Handbook page 3. 56 Handbook of Chemistry and Physics · CRC Press (71st Edition 1990) pages 12-63, which are incorporated herein by reference. 57 Handbook of Chemistry and Physics, page F-22. 58 Microelectronics Packaging Handbook p. 174. 59 Handbook of Chemistry and Physics. Page F-166, which is incorporated herein by reference. 60 Friction, Wear, Lubrication p. 27. 61 G. Slack, &quot; Nonmetallic Crystals with High Thermal Conductivity, J. Phvs. Chem. Solids (1973, Vol. 34, p. 322, which is incorporated herein by reference. 62 See W. Callister, Materials Science and Engineering An Introduction, (Second Edition 1 &quot; 1), page 637, which is incorporated herein by reference. 63 Handbook of Chemistry and Physics, page F_22. 64 Microelectronics Packaging Handbook, page 174. 65 Microelectronics Packaging Handbook, page 37. 66 According to &quot; Web Elements &quot; http: //www.shef·ac.uk/~chem/web-elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998). 67 Microelectronics Packaging Handbook, page 174. 68 Microelectronics Packaging Handbook, page 37. -40- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 11 BU — — — I · III BU — — I — 1 — _ (Please read the note on the back? Matters before filling out this page) 557286 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (38) 69 Handbook of Chemistry and Physics, page F-22. 70 Handbook of Chemistry and Physics. Page 37. 71 Microelectronics Packaging Handbook page 37. 72 Handbook of Chemistry and Physics. Page F-22. 73 Handbook of Chemistry and Physics. Page 37. 74 Microelectronics Packaging Handbook p. 37. 75 According to "Web Elements" http: //www.shef. Ac.uk/~chem/web·elents/nofr-image-l/hardness-minerals-l.html (February 26, 1998) 0 Table B (Continued) Thermal conductivity of inorganic solid materials (W / mK at 300K) Resistance (microohm-cm) Mohs hardness (original scale) Nickel 9276 6.877 578 Aluminum 20579 4.380 2.581 Chrome 6682 2083 9.084 Copper 39885 1.786 2.5-387 Gold 29788 2.289 2.5-390 Iron 74.591 992 4_593 Silver 41894 1.695 2.5-496 76 Microelectronics Packaging Handbook page 174. 77 Microelectronics Packaging Handbook page 37. 78 Handbook of Chemistry and Physics. Page F-22. -41 · — — — — — III l · I --— — — — — — — II (Please read the precautions on the back before filling out this page) Code A4 s) N (c Appropriate rule paper for standard national and national schools 210 χ 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of Invention (39) 79 Microelectronics Packaging Handbook page 174. 80 Microelectronics Packaging Handbook page 37. 81 F riction, Wear, Lubrication page 27. O f \

Microelectronics Packaging Handbook p. 37. 83 Microelectronics Packaging Handbook p. 37. 84 Handbook of Chemistry and Physics. Page F_22. 85 Microelectronics Packaging Handbook p. 174. 〇 zr

Microelectronics Packaging Handbook M 37 pages. 87 Handbook of Chemistry and Physics, page F-22. 88 Microelectronics Packaging Handbook p. 174. 89 Microelectronics Packaging Handbook M 37 pages. 90 Handbook of Chemistry and Physics, page F_22. 91 Microelectronics Packaging Handbook p. 174. 92 Handbook of Chemistry and Physics. CRC Press (1975) at page D-171, which is incorporated herein by reference. 93 Handbook of Chemistry and Physics, page F-22. 94 Microelectronics Packaging Handbook p. 174. 95 Microelectronics Packaging Handbook p. 37. 96 Handbook of Chemistry and Physics, page F-22. Those skilled in the art will appreciate that the particles 18 of the coating composition of the present invention may include any combination or mixture of particles 18 discussed above. More particularly, and without limiting the invention, the particles 18 may include any combination of additional particles made from any of the foregoing materials. Therefore, all the particles 18 need not be the same; they may be chemically different and / or chemically the same but the configuration or -42- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1 Ί l · Ji If L ----------- ^ ---- Order --------- line (Please read the note on the back? Matters before filling out this page) 557286

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The extra particles usually comprise at most one-half of the particles 18, preferably 15% of the particles at most. In a specific embodiment, the particles 18 comprise 0.001 to 99% by weight, preferably 50 to 99% by weight, and more preferably 75 to 99% by weight based on the total solids of the coating composition. In this specific embodiment, a particularly good coating includes, but is not limited to: 0 a coating containing organic components and thin flat particles having a thermal conductivity of at least 1 watt per meter k at a temperature of 300 k; u) containing Coating of organic ingredients and non-hydratable thin flat particles; Out) contains at least one boron-free thin flat particle having a thermal conductivity of at least watts per meter K at a temperature of 300K; iv) contains a temperature of 300K Aqueous composition residues of thin flat particles (ie, thin flat particles on fibers) having a thermal conductivity of at least 1 watt per meter of k; and v) comprising a thermal conductivity of at least 1 watt per meter of k at a temperature of 30 ° K Degrees of water-based composition residues of unnamed non-hydratable particles (ie, aluminum-free non-hydratable particles on fibers). In another specific embodiment, the particles 18 comprise 0.001 to 99% by weight, preferably i to 80% by weight, and more preferably 1 to 40% by weight based on the total solids of the coating composition. Further, in a specific embodiment in which the particles µ are non-hydratable inorganic particles, the particles preferably contain 1 to 50% by weight, and more preferably up to 25% by weight based on the total solids as the coating composition. In another specific embodiment, the particles 18 comprise greater than 20% by weight based on total solids, preferably in the range of 20 to 99% by weight, more preferably in the range of 25 to 80% by weight, and most preferably in the range of 50 to 60% by weight. In this specific embodiment, the particularly good coating includes a resin-compatible coating composition. -43- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) — — — — · I-- -r-I-11111111 (Please read the notes on the back before filling out this page} 557286 A7 B7 V. Description of the invention (4!) It contains more than 20% by weight of particles, organic hollow particles and composite particles based on total solids Granules, I at least = inorganic: Mohs hardness of not more than at least one glass-breaking fiber 値 Mohs = = In another specific embodiment, the granules 18 contain up to 80% by weight, and #g, χ M is preferably 1 It is 1 to 60% by weight. In the specific embodiment, == 20 to 60% by weight based on total solids == and 35 to 55% by weight of Yima, and more preferably 30 to 50% by weight. The good coating includes a resin compatible coating, which contains ❶ discontinuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-cuttable = swell compound = materials and mixtures thereof. The average particle size of heat applied to wet the strands; (dagger) at least one A lubricating material different from the plurality of discontinuous particles; and at least one film-forming material. In addition to the particles, the coating composition preferably contains one or more film-forming materials, such as organic, inorganic, and natural polymeric materials. Available Organic materials include, but are not limited to, polymeric materials selected from synthetic polymeric materials, semi-synthetic polymeric materials, natural polymeric materials, and mixtures of any of the above. Synthetic polymeric materials printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs include but are not limited to thermoplastic And thermosetting materials. Preferably, the polymer film-forming material forms a substantially continuous film when coated on the surface 16 of the glass fiber. Usually, the amount of the film-forming material ranges from 1 to 99 based on the total solids of the coating composition. % By weight. In a specific embodiment, the amount of the film-forming material is preferably from 1 to 50% by weight, and more preferably from 1 to 25% by weight. In another specific embodiment, the amount of the film-forming material ranges from 20%. Weight to 99-44- National paper standard (CNS) A4 size (210 X 297 public love) of this paper size 557286 A7 B7 V. Description of invention (42%, and more It is preferably 60 to 80% by weight. In another embodiment, the amount of the film-forming material is preferably in the range of * based: the total solids are 20 to 75% by weight of the coating composition, and more preferably 40 to 50% by weight. In this specific embodiment, a particularly preferred coating includes a film-forming material, which includes at least one particle selected from inorganic particles, organic hollow particles, and composite particles based on a total solids content of greater than 20% by weight. The particles have a Mohs hardness 値 of at least one glass fiber. In another embodiment, the amount of the polymer film-forming material ranges from 1 to 1 based on the total solids of the coating composition. 60% by weight, preferably 5 to 50% by weight per ton, and more preferably 10 to 30% by weight. A better coating of this embodiment includes a resin-compatible coating comprising a plurality of discontinuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, drill polymer materials, non-thermally expandable composite materials, and mixtures thereof. The particles have an average particle size sufficient to wet the strand without external heat application; (1?) At least one lubricating material different from the plurality of discontinuous particles; and ⑷ at least one film-forming material. In a non-limiting embodiment of the present invention, the thermosetting polymer film-forming material is a preferred polymer film-forming material for coating a coating composition of glass fiber strands. This material is compatible with a thermosetting matrix material as a laminate of a printed circuit board, such as FR-4 epoxy resin, which is a multifunctional epoxy resin, and is a difunctional group in a specific embodiment of the present invention. Brominated epoxy resin. See Electronic Materials Handbook ™ ASM Intematicmal (1989) pages 534-537, which are specifically incorporated herein by reference. • 45- This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) 1 Ί r 11 μ ------ 0M -------- ^ ------- -(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives of the Ministry of Economic Affairs and Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives of the Ministry of Economic Affairs 557286 A7 B7 Thermosetting polyesters, epoxy materials, vinyl esters, phenolic, amine-based plastics, thermosetting polyurethanes, and mixtures of any of the above. Suitable thermosetting polyesters include STYPOL polyester, commercially available from Cook Composites and Polymers, Kansas, Missouri, and NEOXIL polyester, commercially available from DSM Β · V ·, Como, Italy. A non-limiting example of a thermosetting polymeric material is an epoxy material. Useful epoxy materials are polyglycidyl ethers containing at least one epoxy or ethylene oxide group, such as a polyhydric alcohol or thiol, in one molecule. Examples of suitable epoxy film-forming polymers include Epon® 826 and Epon® 880 epoxy resins, commercially available from Shell Chemical Company of Houston, Texas. Useful thermoplastic polymeric materials include ethylene polymers, thermoplastic polyesters, polyolefins, polyamides (e.g., aliphatic polyamides or aromatic polyamides such as aromatic polyamides), thermoplastic polyurethanes, A propylene polymer (such as polyacrylic acid), and a mixture of any of the above. In another non-limiting embodiment of the present invention, the preferred polymer film forming material is an ethylene polymer. Useful ethylene polymers of the present invention include, but are not limited to, polyvinylpyrrolidone, such as PVP K-15, PVP K_30, PVP K-60 and PVP K90, each commercially available from International Specialty Products Chemicals, Wayne, New Jersey the company. Other suitable ethylene polymers include RESYN 2828 and RESYN 1037 vinyl acetate copolymer emulsions, commercially available from National Starch and Chemical Company of Bridgewater, New Jersey, and other polyvinyl acetates, such as commercially available from H. B_ Fuller Air Products and -46-Allentown, Penn.- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) Ί Ί Γ 1 --- Γ ----------- --Order --------- line (please read the precautions on the back before filling this page) 557286 A7 B7 V. Description of the invention (44)

Chemicals, Inc., and polyethylene glycol, which are also available from Air Products and Chemicals. The thermoplastic polyesters used in the present invention include DESMOPHEN 2000 and DESMOPHEN 2001KS, all commercially available from Bayer, Pittsburgh, PA. Preferred polyesters include RD-847A polyester resin, commercially available from Borden Chemicals, Columbus, Ohio, and DYNAKOLL Si 100 chemically modified turpentine, commercially available from Eka Chemicals AB, Sweden. Useful polyamides include VERSAMID products, which are commercially available from Cognis, Inc. of Cincinnati, Ohio, and EUREDOR products, from Ciba Geigy, Belgium. Useful thermoplastic polyurethanes include WITCOBOND® W-290H, commercially available from CK Witco, Greenwich, Connecticut, and RUCOTHANE (R) 2011L polyurethane latex, commercially available from Ruco, Hicksville, New York Polymer Company 0 The coating composition of the present invention may comprise a mixture of one or more thermosetting polymeric materials and one or more thermoplastic polymeric materials. In a non-limiting embodiment of the present invention specifically for laminates for printed circuit boards, the polymeric material of the aqueous sizing composition includes RD-847A polyester resin, PVPK-30 polyvinylpyrrolidone, DESMOPHEN 2000 polymer Mixture of ester and VERSAMID polyamide. In alternative non-limiting specific embodiments suitable for laminates for printed circuit boards, the polymeric material of the aqueous sizing composition comprises PVP K-30 polyvinylpyrrolidone, optionally combined with EPON 826 epoxy resin . Semi-synthetic polymeric materials suitable as polymeric film-forming materials include, but are not limited to -47- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ϋ 1 H ϋ ϋ ϋ ϋ ^ (Please read first (Notes on the back then fill out this page)

-1-! — Ί 丨 order-!!! · Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7, Invention Description (45) on cellulose, such as Hydroxypropyl cellulose, and modified starches such as KOLLOTEX 1250 (based on ethylene oxide etherified low viscosity and low amylose stable potato chips) are commercially available from AVEBE in the Netherlands. Natural polymeric materials suitable as polymeric film-forming materials include, but are not limited to, starches prepared from potato, corn, wheat, waxy corn, sago, rice, millet, and any mixtures thereof. It should be understood that depending on the nature of the starch, starch may be used as the granules 18 and / or the film-forming material. More specifically, some starches are completely soluble in solvents, especially mashed water, and serve as film-forming materials, while others are not completely dissolved and maintain a specific particle size and serve as granules 18. Although starch (natural and semi-synthetic) can be used in accordance with the present invention, the coating composition of the present invention is preferably substantially free of starch material. The term "substantially starch-free material" as used herein means that the coating composition contains less than% by weight, preferably less than 35% by weight, starch material based on the total solids of the coating composition. More preferably, In the present invention, the coating material is a starch material. The term used herein, essentially starch-free material, means that the coating composition contains a total solids based on the coating composition. % By weight 'preferably less than 5% by weight, and more powdery materials. Π', the typical sizing-containing composition of fiber strands coated on laminates added to printed circuit boards is not resin compatible, In addition, it must be added for the purpose of resin compatibility, and it is not necessary to remove the fiber before the fabric is processed. Better Jiama 'The coating composition of the present invention is compatible with the substrate material of the brushed road board, discussed below. _ The best is the ring: = phase electricity ^ appropriate size (please read the precautions on the back before filling this page) )

557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ------ B7 ▼ ^ ------- V. Description of Invention (46) Capacitive. The polymeric film-forming material may be water-soluble, emulsifiable, dispersible, and / or hardenable. The "water purity" used here is essentially syntactic

Blended and / or molecularly or ionicly divided into knives and dispersed in water to form a solid solution. See No. 1075 W, which is specifically incorporated herein by reference. &quot; Emulsifiable &quot; means that a polymeric material can form an essentially stable mixture or suspension in water in the presence of an emulsifier. See page 461, which is specifically incorporated herein by reference. Non-limiting examples of suitable emulsifiers are described below. &quot; Dispersible &quot; Table * Any component of the polymeric material can be distributed as finely divided particles in all water 'such as latex. See ^ page 435, which is specifically incorporated herein by reference. The average degree of dispersion can be increased by the addition of wetting, dispersing or emulsifying agents (surfactants) as discussed below. Hardenable &quot; Table 7F The polymer material and other ingredients of the sizing composition can be coalesced to form a film or cross-linked with each other to change the physical properties of the polymer material. See page 331, which is specifically incorporated herein by reference. In addition to or in place of the film-forming materials discussed above, the coating composition of the present invention preferably includes one or more glass fiber coupling agents, such as an organic silane coupling agent, a transition metal coupling agent, a phosphoric acid coupling agent, an aluminum coupling agent, Amine-containing Werner coupling agents, and mixtures of any of the above. These coupling agents generally have a dual function. Each metal or silicon atom has one or more radical linkages, which can react directly or be compatible with the components of the fiber surface and / or resin matrix. The term "compatible," as used herein, means that the radicals are chemically connected (eg, by polarity, wetting, or solvent) but do not bond the components of the fiber surface and / or the coating composition. In a non-limiting embodiment, Each metal or silicon atom has Ί Ί J -------- 1® ^ -------- order --------- line (please read the precautions on the back before filling in this Page) -49- 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (47) One or more hydrolyzable groups that can react the coupling agent on the surface of glass fiber, and one or more hydrolyzable groups The coupling agent reacts the functional group of the resin matrix component to be connected. Examples of the hydrolyzable group include: 〇 Η 0 R3

II I II I -OR1, -0_C_R2, -N -_- C-R2, -〇-N = C-R4, -0_N = CR5, and monohydroxyl and / or 1,2_ or 1,3-diol A circular C2-C3 residue, wherein R1 is Ci-C3; R2 is fluorene or CVC4 alkyl; R3 and R4 are independently selected from fluorene, Ci_C4 alkyl or C5-C6 aryl; and R5 is C4_C7 alkyl. Examples of suitable compatible or functional groups include epoxy, dehydroglyceryl, hydrothio, cyano, allyl, alkyl, carbamate, phenyl, isocyanate, urea, imidazole Linyl, vinyl, acrylic, methacrylic, amine or polyamine. Functional organosilane coupling agents are preferred for use in the present invention. Examples of useful functional organic silane coupling agents include γ-aminopropyltrialkoxysilane, γ-isocyanatopropyltriethoxysilane, vinyltrialkoxysilane, dehydrated glycerylpropyl Trialkoxysilanes and ureidopropyltrialkoxysilanes. Preferred functional organic silane coupling agents include A-187 γ-dehydrated glycerylpropyltrimethoxysilane, A-174 γ-methacryloxypropyltrimethoxysilane, a-1100 γ-aminopropyltriethyl Oxysilane coupling agent, A-1108 amine silane coupling agent, and A-1160 γ-ureidopropyltriethoxysilane (each commercially available from CK Witco, Tarrytown, NY). The organic silane coupling agent can be hydrolyzed at least partially with water before being applied to the fiber, preferably 1: 1 stoichiometry -50-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Ί Ί r Ί 1 L --------------- Order --------- line (please read the precautions on the back before filling out this page) Staff Consumption of Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative 557286 A7 B7 V. Description of the invention (48) Amount ratio, if required, or applied in unhydrolyzed form. The pH of water can be modified by addition of acid or base to initiate or accelerate the hydrolysis of the coupling agent, as is known in the art. Suitable transition metal coupling agents include “zirconium, gas, and chromium coupling agents. Suitable titanate coupling agents and caperate coupling agents are commercially available from Kenrich Petrochemical. A suitable chromium complex is commercially available from E.I. DuPont de Nemours, Wilmington, Delaware. The amine-containing Werner type coupling agent is a complex compound in which an organic acid having an amine functional group is coordinated, such as a trivalent nuclear atom of chromium. Other metal clamps and coordination type coupling agents known to those skilled in the art can be used here. The amount of coupling agent usually ranges from 1 to 99% by weight based on the total solids of the coating composition. In a specific embodiment, the amount of the coupling agent ranges from 1 to 30% by weight based on the total solids of the coating composition, preferably from 1 to 10% by weight, and more preferably from 2 to 8% by weight. The coating composition of the present invention may further include one or more softeners or surfactants, which impart a uniform charge to the surface of the fibers, causing the fibers to repel each other and reducing friction between the fibers to act as a lubricant. Although not necessary, it is preferred that the softener is other ingredients that are chemically different from the coating composition. Such softeners include cationic, non-ionic or anionic softeners and mixtures thereof, such as amine salts of fatty acids, and calcined derivatives such as CATION X, commercially available from Princeton, New Jersey Rhone Poulenc / Rhodia), acid-dissolved fatty acid amidine, fatty acids and polyethyleneimine, and ammonium substituted polyethyleneimine (such as EMERY® 6717, some ammonium-polyethyleneimine Cognis -51, commercially available from Cincinnati, Ohio. This paper is sized for China National Standard (CNS) A4 (210 X 297 mm). Ί Ί ui 11 ------------- Order --------- Line (Please read the notes on the back before filling out this page) 557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Invention Description (49) Company) &lt; Condensate. Although the coating composition may contain up to 60% by weight of the softener, preferably, the coating composition contains less than 20% by weight and more preferably less than 5% by weight of the softener. For more information on softeners, see Hall 2nd Edition (1957), page 1081115, which is specifically incorporated herein by reference. The coating composition of the present invention may further include one or more lubricating materials that are chemically different from the polymer materials and softeners discussed above to impart the desired processing characteristics to the fiber strands during weaving. Suitable lubricating materials may be selected from the group consisting of oil, grease, grease, and mixtures of any of the foregoing. Non-limiting examples of the hafnium material used in the present invention include water-soluble, emulsifiable or dispersible wax materials such as vegetable, animal, mineral, synthetic or petroleum waxes, such as paraffins. The oils used in the present invention include natural oils, semi-synthetic oils and synthetic oils. Generally, the amount of wax or other lubricating material ranges from 0 to 80% by weight based on the total solids of the sizing composition, preferably from 1 to 50% by weight, and more preferably from 20 to 40% by weight. /. And more preferably 25 to 35 weight 0 / 〇.

Preferred lubricating materials include ants and oils with polar characteristics, and more preferably include high crystalline waxes with polar characteristics and melting points higher than 35 t and more preferably higher than 45 t. Comparing fiber strands coated with a sizing composition containing waxes and oils having no polar characteristics, this material is believed to improve the wetting and penetration of polar resins on fiber strands coated with a size composition containing such a polar material. Preferred polar lubricating materials include esters formed by reacting: (1) monocarboxylic acids and (2) monohydroxy alcohols. Non-limiting examples of such fatty acid esters for use in the present invention include the preferred cetyl palmitate (eg, KESSCO 653 or STEPANTEX from Stepan Company, Maywood, New Jersey -Ί.—Ί 1 --- I — I —！ · — — Order _ — ！！ (Please read the precautions on the back before filling this page)

557286 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs_B7___ V. Invention Description (50) 653), Cetyl Myristate (also available from STEPANLUBE 654 from Stepan), Cetyl Laurate, Laurel Stearyl stearate, stearyl myristate, stearyl palmitate, and stearyl stearate. Other fatty acid esters and lubricating materials used in the present invention include trimethylolpropane trinonanoate, natural cetyl wax and triglycerides, such as, but not limited to, soybean oil, linseed oil, epoxidized soybean oil, and epoxidized sesame oil. Lubricating materials may also include water-soluble polymeric materials. Non-limiting examples of useful materials include polyalkylene polyols and polyoxyalkylene polyols such as MACOL E-300, commercially available from BASF Corporation, Parsippany, New Jersey, and CARBOWAX 300 and CARBOWAX 400, commercially available Union Carbide, Danbury, Connecticut. Other non-limiting examples of useful lubricating materials are POLYOX WSR 301, which is commercially available from Union Carbide of Danbury, Connecticut (Ethylene Oxide). Instead of or in addition to the lubricating materials discussed above, the coatings of the present invention The composition may additionally include one or more other lubricating materials, such as non-polar petroleum wax. Non-limiting examples of non-polar petroleum waxes include MICHEM® LUBE 296 microcrystalline wax, POLYMEKON® SPP-W microcrystalline wax, and PETROLITE 75 microcrystalline ants, each commercially available from Michelman Corporation of Cincinnai, Ohio, and Cumming, Georgia Baker Petrolite, Polymer Division. Generally, the amount of this type of wax is up to 10% by weight of the total solids of the sizing composition. The coating composition of the present invention may also include a resin-reactive diluent to further improve the process of the present invention by reducing the possibility of fine hairs, rings, and broken filaments in this manufacturing operation, while maintaining resin compatibility. Coated Fiber Stock -53- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Read the notes on the back before filling out this page IIIII Order ▲ 557286 Printed by the Employees ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Lubrication of the invention (M), and provide good processing power in weaving and knitting. As used herein • Resin Reactive Diluent &quot; means that the diluent includes functional groups that chemically react with the same resin that is compatible with the coating composition. The diluent may be any lubricating material having one or more functional groups capable of reacting with the resin system, preferably the functional group of the reactive oxygen resin system, and more preferably the functional group of the FR_4 epoxy resin system. Non-limiting examples of suitable lubricants include lubricants having amine, alcohol, anhydride, acid or epoxy groups. A non-limiting example of an amine-based lubricant is a modified polyethylene diamine, for example, emery 6717 &apos;, which is a partially aminated poly (ethylene diimide) commercially available from the Cognis Company of Cincinati, Ohio. A non-limiting example of an alcohol-based lubricant is polyethylene glycol, such as CARBOWAX 300, which is a polyethylene glycol commercially available from Union Carbide, Danbury, Connecticut. Non-limiting examples of acid-based lubricants are fatty acids, such as stearic acid and salts of stearic acid. Non-limiting examples of lubricants having epoxy groups include epoxidized big oil and epoxidized linseed oil, for example, FLEXOLOE, which is an epoxidized linseed oil, and FLEXOL EPO, which is an epoxidized soybean oil, which Both are commercially available from Union Carbide, Danbury, Connecticut, and LE-9300 epoxidized polysiloxane emulsion, commercially available from CK Witco, Tarry Town, NY. Although not limiting in the present invention, the sizing composition may include the resin reactive diluent discussed above based on the total solids in an amount of up to 15% by weight of the sizing composition. The coating composition may additionally include one or more emulsifiers to emulsify or disperse ingredients of the coating composition, such as particles 18 and / or lubricating materials. Non-limiting examples of suitable emulsifiers or surfactants include polyoxyalkylene block co-54- private paper sizes Applicable to China National Standard (CNS) A4 specifications (21〇x 297 public love) ϋ ϋ ϋ ϋ ϋ ϋ ^ 1 ϋ ^ ^ ^ 1 Ί 1— FIIIII-^ 1 ^ 1 I ϋ ^ ^ 1 II 1 ^ ^ ϋ ϋ ^ ^ IA (Please read the notes on the back before filling out this page) 557286 A7 B7 V. Description of the invention (52) Polymers (such as PLURONIC ™ F-108 polyoxypropylene-polyethylene oxide copolymer, which is commercially available from BASF Corporation, Parsippany, New Jersey (PLURONIC ™ F-108 copolymer in Europe under the trade name SYNPERONIC F- 108)), ethoxylated alkylphenols (such as IGEPA CA-630 ethoxylated octylphenoxyethanol, commercially available from GAF Company, Wayne, New Jersey), polyethylene oxide octylphenyl glycol ether, flowers Ethylene oxide derivatives of methyl alcohol esters (such as TMAZ 81, commercially available from BASF, Parsippany, New Jersey), and polyoxyethylene vegetable oils (such as ALKAMULS EL-719, commercially available from Rhone-Poulenc / Rhodia company), acetic acid pits (such as MACOL OP-10 SP, which is also commercially available from BASF company ), And nonanol surfactants (such as MACOL NP-6 and ICONOL NP-6, which are also commercially available from BASF, and SERMUL EN 668, which are commercially available from CON BEA, Benelux). Generally, the amount of emulsifier ranges 1 to 30% by weight, preferably 1 to 15% by weight, based on the total solids of the coating composition. Crosslinked materials, such as melamine formaldehyde, and plasticizers, such as phthalates, trimellits, and adipates It can also be included in the coating composition. The amount of the cross-linking agent or plasticizer ranges from 1 to 5% by weight based on the total solids. Other additives can be included in the coating composition, such as polymer Broken oxygen, fungicides, bactericides and anti-foaming materials, usually in an amount of less than 5% by weight. Organic and / or inorganic acids or bases sufficient to provide the pH of the coating composition 2 to 10 may also be included in In a coating composition, a non-limiting example of a suitable silicone emulsion is LE-9300 epoxidized silicone emulsion, which is commercially available from CK Witco, Tarrytown, NY. An example of a suitable biocide is -55- Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (please first Read the notes on the back and fill out this page) -½¾ -------- Order --------- line * Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives Printed 557286 A7

5. Description of the invention (53) BIOMET66 antimicrobial compound, commercially available from M &amp; T Chemicals, Rahway, New Jersey. Examples of suitable anti-foaming materials are SAG materials, commercially available from CK Witco, Greenwich, Connecticut, and MAZU DF-136, commercially available from BASF, Parsippany, New Jersey. If desired, ammonium osmium oxide can be added to the coating composition to stabilize the coating. Preferably, water, and more preferably deionized water, is included in the coating composition in an amount sufficient to facilitate application of a substantially uniform coating on the strand. The solids% by weight of the coating composition is usually from 1 to 20% by weight. In a specific embodiment &apos; the coating composition of the present invention is substantially free of glass material. As used herein, "substantially glass-free material" means that the coating composition contains less than 50% by volume of a glass composite-forming glass matrix material, preferably less than 35% by volume. In a more preferred embodiment, the coating composition of the present invention is essentially glass-free. As used herein, the essentially glass-free material π means that the coating composition contains less than 20% by volume of a glass composite-forming glass matrix material, preferably less than 5% by volume, and more preferably a glass-free material. Examples of such glass matrix materials include black glass ceramic matrix materials or aluminosilicate matrix materials, as known to those skilled in the art. In a specific embodiment of the present invention, a fiber strand comprising a plurality of fibers is at least partially coated with a coating containing organic components and thin flat particles having a thermal conductivity of at least 1 watt per meter K at a temperature of 300K. In another embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with a coating comprising an organic component and non-hydratable thin flat particles. In these embodiments, the &apos; organic ingredients and thin flat particles may be selected from the coating ingredients discussed above. The organic composition and thin flat particles can be the same or different, and the coating can be water-based. -56- This paper size is applicable to China National Standard (CNS) A4 (21〇χ 297 mm) 1 Ί h 11 L .-- ------------ Order --------- Line · (Please read the precautions on the back before filling out this page) 557286 Five A7 B7, invention description (54) layer composition Residual or powdery coating composition. In another specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with a coating comprising at least one boron-free thin flat particle having a thermal conductivity of at least 1 watt per meter K at a temperature of 300K. In another specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with an aqueous composition residue comprising boron-free thin flat particles having a thermal conductivity of at least 1 watt per meter K at 300K. In another specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with an aqueous composition comprising aluminum-free non-hydratable particles having a thermal conductivity of at least 1 watt per meter k at a temperature of 300K. . The components in these embodiments may be selected from the coating components discussed above, and other components may be selected from the above. In another specific embodiment of the present invention, a fiber strand comprising a plurality of fibers is at least partially coated with a resin-compatible coating composition on at least a portion of a surface of at least one of the fibers, the resin being compatible The coating composition includes: (a) a plurality of discontinuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials and mixtures thereof, the particles having an average particle size sufficient to make the strands wet (B) at least one lubricating material different from the plurality of discontinuous particles; and ⑷ at least one film-forming material. &amp; The ingredients in some embodiments may be selected from the coating ingredients discussed above. In another embodiment, a plurality of discontinuous particles provide an interstitial space between at least one of the fibers and at least one adjacent fiber. In another specific embodiment, a fiber strand comprising a plurality of fibers is coated with a resin compatible coating composition on at least a part of the surface of the fiber to Ί.1 Γ Ί 1 l · II I--in ---- Order ------ I--line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

X 297 mm) 557286 Printed by A7 of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the invention description (55) is partially coated. This resin is compatible. (A) a plurality of particles, one of which is formed of an organic material family; and at least one of which is formed of an inorganic material selected from the group consisting of boron nitride, black stone, and 1 to a monochalcogen compound (particles of which "Multiple particles" ,, ... This # ▲ has an average particle size sufficient to make the strand moist, (b) to v — different from the multiple not less than-film-forming materials. _Particles &lt; lubricating materials; and In another specific embodiment, the fiber strands of the fiber are coated with a resin-compatible coating composition at least partially on the surface of the fiber The resin-compatible coating composition includes: ⑷ a plurality of materials selected from the group consisting of organic materials, inorganic polymeric materials, rhenium, composite materials, and mixtures thereof, which are discontinuous particles, and the particles have Measurement range = average particle size of 0.1 to 5 microns; (b) at least-species A lubricating material on the plurality of discontinuous particles; and at least one film-forming material. In another specific embodiment, the resin-compatible coating composition described above contains 20 to 60% by weight based on total solids, It is preferably 35 to 55% by weight, and more preferably 30 to 50% by weight of a plurality of discontinuous particles; 〇 0 to 80% by weight based on the total solids, more preferably] to 50% by weight. And more preferably 20 to 40% by weight of at least one lubricating material; and ⑷ based on the total solids of 1 to 60% by weight, preferably 5 to 5% to 5% by weight of at least-the amount of film-forming material / 〇, Furthermore, in another specific embodiment of the present invention, a fiber strand including a plurality of fibers is coated with a resin compatible coating on at least a part of the surface of the fiber to ^ ^ YyV ^ m / ^ The resin-compatible coating composition includes: ⑷ a plurality of materials selected from the group consisting of organic materials, composite materials, and mixtures thereof _ 58 _ paper rule money specification ⑽ X 297 mm ） — — — — — · · 11 — IIII Order (Please read the notes on the back first (Fill in this page again.) 5. Description of the invention (56) = ㈣-shaped particles, this particle has an average particle size according to the measurement range of laser scattering technology: · to 5 microns; and ⑼ at least-different from the plurality of non-continuous particles The lubricating material of this month. In another embodiment of the present invention, at least a portion of the "fibers containing a plurality of fibers"% to »is coated at least partly with a resin-compatible coating. This resin The compatible coating composition comprises at least one particle selected from the group consisting of inorganic particles, organic particles, and composite particles based on a solid content of more than 20% by weight, and the at least one particle has a Mohs hardness of at least one of the fibers. The hardness is 値. 2 The present invention (another embodiment of a 'fiber comprising a plurality of fibers = at least of the fibers-at least-part of the surface is coated with a resin compatible coating, the heart is at least partially coated, this resin phase The coating composition comprises: 至少 at least-having a Mohs hardness of the fiber 値 Mohs hardness 値 m machine particles; and (b) at least-a polymeric material. ^ Is an additional specific implementation of the present invention For example, a fiber strand comprising a plurality of fibers is at least partially coated with a resin-compatible coating composition on at least a portion of the surface of at least one of the fibers. 'This resin-compatible coating composition includes: 至少 at least -A hollow non-heat-expandable organic particle; and at least-a lubricating material different from at least one hollow organic particle. The components in each of the above specific embodiments are selected from the coating components discussed above, and other components may also be selected from the above. In the present invention (a specific embodiment, the fiber coating comprises an organic component and thin flat particles having a thermal conductivity of at least 1 watt per meter k at a temperature of 3 ° (group mouthpiece). In another specific embodiment Medium The coating contains an organic component 557286 A7 V. Composition of the invention (57) and non-hydratable thin flat particles. In another specific embodiment, the fiber coating contains at least one Composition of boron-free thin flat particles with a thermal conductivity of 1 watt. In another embodiment, a fiber coating composition comprising thin flat particles with a thermal conductivity of at least 1 watt per meter at a temperature of 300K: In another specific embodiment, the 'fiber coating comprises a composition of aluminum-free non-hydratable inorganic particles having a thermal conductivity of at least 1 watt per kilogram at a temperature of 30 ° K. In another specific embodiment of the present invention In the fiber coating, the following composition is included: (a) a plurality of non-continuous particles formed of a material selected from the group consisting of non-thermally expandable organic materials, inorganic polymer materials, non-thermally expandable composite materials, and mixtures thereof, the particles having sufficient moisture to make the strands moist Average particle size; (b) at least one lubricating material different from the plurality of discontinuous particles; and ⑷ at least one film forming material. In another specific embodiment, the fiber coating includes the following Composition: (i) a plurality of particles comprising: (ii) at least one particle formed from an organic material; and (ii) at least one particle formed from an inorganic material selected from the group consisting of boron nitride, graphite, and a metal dichalcogen compound, wherein Each particle has an average particle size to make the strand moist; (b) at least-a lubricating material different from the plurality of discontinuous particles; and (c) at least one film-forming material. In another embodiment, the fiber The coating comprises the following composition: (a) discontinuous particles formed of a material selected from the group consisting of organic materials, inorganic polymeric materials, composite materials and mixtures thereof, the particles having a measurement range of 0.1 to 5 according to laser scattering technology The average particle size of micrometers; and (b) at least one kind of lubricating material different from the plurality of discontinuous particles; and (c) at least-a film-forming material. -60- This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm (Please read the notes on the back before filling this page) ---------------- 9 ^ ------- —Order ----- ---- Line * Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (58) Another specific embodiment of the composition of the present invention: (a) a plurality of materials selected from the group consisting of organic materials: human resources: Discontinuous and non-continuous, and the measurement range of its mixture shooting technique is from 0.1 to ^, and there are different discontinuous particles according to the laser scattering _ L <average particle size 'and (b) at least one contact Grain &lt; Lubricant. In the example, the fiber coating contains a specific embodiment of the fat-compatible coating composition, which contains based on <,,,, and 5 substances. , There are ❶ 至 to Xiban ^ vocational secondary particles and composite particles of the protection, 4 particles have no more than the fiber in the hair ... / hardness 値 Mohs hardness 値. In another specific embodiment of the present invention, the fiber coating package composition: (a) at least one thin flat A ^ material. In another embodiment of the present invention, the fiber coating includes the following composition: (a) a plurality of hits τ | U 1 1 2 non-thermally expandable organic particles and y — species A polymeric material that is different from at least one Zhongguo, Jiagong organic particles. In the present invention (additional specific embodiments, a fiber-coated resin compatible coating composition having a first coating of a sizing composition on at least a portion of the surface of the fiber and comprising an aqueous coating composition Residual second coating, the composition includes a plurality of discontinuous particles coated on at least a part of the first coating of the sizing composition. The ingredients in each of the above specific embodiments are selected from the ones discussed above. The coating component, and other components may be selected from the above. In a non-limiting specific embodiment of the present invention, at least a part of at least one of the fibers of the fiber strand of the present invention is coated with pLARTHER] v ^ 16 ° Nitrided rot powder and / or BORON NITRIDE RELEASECOAT dispersion, ΊΊΓΊΙμ ------ ΦΜ -------- Order --------- line # (Please read the (Please fill in this page again)

Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the invention (59) EPON 826 epoxy-based film forming material, PVP K-30 polyvinyl pyrrolidone, A-187 epoxy-functional organosilane Coupling agent, ALKAMULS EL-719 polyoxyethylated vegetable oil, IGEPAL CA-630 ethoxylated octylphenoxyethanol, KESSCO PEG 600 polyethylene glycol monolaurate (commercially available from Stephan, Chicago, Illinois Co., Ltd.), and EMERY® 6717 Partially Aminated Polyethylene Diimide Aqueous Coating Composition. In another non-limiting embodiment of the present invention for weaving, at least a portion of at least one of the fibers of the fiber strand of the present invention is coated with a POLARHERM® 160 boron nitride powder and / or a BORON NITRIDE RELEASECOAT dispersion RD-847A Polyester, PVP K-30 Polyvinylpyrrolidone, DESMOPHEN 2000 Polyester, A-174 Acrylic Functional Organosilane Coupling Agent, A-187 Epoxy Functional Organosilane Coupling Agent, PLURONIC Dry residue of an aqueous sizing composition of F-108 polyoxypropylene-polyoxyethylene copolymer, MACOL NP-6 nonylphenol surfactant, VERS AMID 140, and LE · 9300 epoxy polysiloxane emulsion.

In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with POLARTHERM® PT160 boron nitride powder and / ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion, PVP K-30 polyvinylpyrrolidone, A-174 propenyl-functional organosilane coupling agent, A-187 epoxy-functional organosilane coupling agent, ALKAMULS EL- 719 Polyoxyethylated Vegetable Oil, EMERY® 6717 Partially Aminated Polyethylene Diimide, RD-847A Polyester, DESMOPHEN 2000 Polyester, PLURONIC F-108 Polypropylene Oxide-Polyethylene Oxide Copolymer, ICONOL -62- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------------- -Order --------- line * Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Α7 Β7 V. Description of the invention (60) Water-based coating of NP-6 alkoxynonylphenol and SAG 10 antifoam material层 组合 物。 Layer composition. If desired, this particular embodiment may optionally include ROPAQUE (R) HP-1055 and / or ROPAQUE® OP-96 styrene-propylene copolymer hollow spheres. In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 dispersion, RD-847A polyester, PVP K-30 polyvinylpyrrolidone, DESMOPHEN 2000 polyester, A-174 acrylic functional organosilane coupling agent, A-187 epoxy A functional sizing composition of a functional organosilane coupling agent, PLURONIC F_108 polyoxypropylene · polyoxyethylene copolymer, VERSAMID 140 polyamidamine, and MACOL NP-6 nonylphenol. If desired, this particular embodiment may optionally include ROPAQUE® HP-1055 and / or ROPAQUE® OP-96 styrene-propylene copolymer hollow pellets as appropriate. In another non-limiting embodiment of the present invention for weaving a fabric for a laminated printed circuit board, at least a portion of at least one of the fibers of the fiber strand of the present invention is coated with ROPAQUE® HP-1055 and / Or ROPAQUE® OP-96 styrene-propylene copolymer hollow pellets, PVP K-30 polyvinylpyrrolidone, A-174 propionyl functional organosilane coupling agent and A-187 epoxy functional organosilane Couplings, EMERY® 6717 Partially Aminated Polyethylene Diimide, STEPENTE 653 Cetyl Palmitate, TMAZ 81 Ethylene Oxide Derivatives of Anisocyanate, MACOL OP · 10 Ethoxylate Test, and MAZU DF-136 Residue of water-based first coating composition of anti-finishing material • 63- &gt; Paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm ^ 1 1 i ^ · I Ik II ϋ · ϋ ϋ 1 ϋ ^ 1 ϋ ϋ ^ 1 1 ^ 1 ϋ I -1 (Please read the note on the back? Matters before filling out this page) 557286 A7 B7 V. Description of the invention (61) Slag. Although not necessary, this specific Specific embodiments preferably include POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with DESMOPHEN 2000 polyester, A-174 Acryl-functional organosilane coupling agent, A-187 epoxy-functional organosilane coupling agent, PLURONIC F-108 polyoxypropylene-polyoxyethylene copolymer, VERSAMID 140 polyamide, and MACOL NP-6 nonylphenol, POLYOX WSR 301 poly (ethylene oxide) and DYNAKOLL Si 100 turpentine coating composition. In addition, this particular embodiment further includes POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Dispersions.

In another non-limiting embodiment of the fabric for electronic circuit boards of the present invention, at least a portion of at least one of the fibers of the fiber strands of the present invention is coated with DESMOPHEN 2000 polyester, A-174 acrylic functionalities Organosilane coupling agent, A-187 epoxy-functional organosilane coupling agent, SYNPERONIC F-108 polyoxypropylene-polyoxyethylene copolymer, EUREDUR 140 polyamide, MACOL NP · 6 nonylphenol, SERMUL ENE 668 B An aqueous coating composition of nonoxynol, POLYOX WSR 301 poly (ethylene oxide), and DYNAKOLL Si 100 Matsuki. In addition, this specific embodiment further includes ROPAQUE® HP_1055 and / or ROPAQUE® OP-96 styrene-acrylic copolymer hollow pellets, and / or POLARHERM® PT 160 boron nitride powder and / or ORPAC BORON -64- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) _ί-ί-ί · Order ------ line, Ministry of Economic Affairs wisdom Printed by the Consumer Cooperative of the Property Bureau 557286 A7 -------- 2Z ___---- 5. Description of the invention (62) NITRIDE RELEASECOAT-CONC 25 dispersion. Although unsatisfactory, fiber strands having a coating composition similar to the particleless 18 described above can be prepared according to the present invention. In particular, it is intended according to the present invention to include one or more film-forming materials, such as ρνρ κ · 30 polyvinylpyrrolidone; one or more silane coupling agents, such as A_174 propenyl functional organosilane coupling Mixture with A-187 epoxy-functional organosilane coupling agent; and at least 25% by weight of the sizing composition based on the total solids of a lubricating material with polar characteristics, such as the resin phase coating of STEPANTEX 653 cetyl palmitate层 组合 物。 Layer composition. Those skilled in the art should further understand that according to the present invention, the fiber strands of the resin-compatible coating composition without particles 18 can be woven into fabrics and made into electronic supports and electronic circuit boards (as described below). The coating composition of the present invention may be prepared by any suitable method, such as mixing, as is known to those skilled in the art. Preferably, the ingredients discussed above are diluted with water to have the desired solids weight percent and mixed together. The particles 18 may be premixed with water, emulsified, or added to one or more of the components of the coating composition prior to mixing the remaining components of the coating. The coating composition according to the present invention can be applied in many ways, for example, by contacting the filaments with a roller or a belt applicator, spraying or other means. The coated fiber is preferably dried at room temperature or high temperature. The dryer removes excess water from the fibers and, if present, hardens any hardenable sizing composition ingredients. The temperature and time for drying the glass fibers depend on the solids in the coating composition, the components of the coating composition and the variables of the fiber type. The term "hardening" used herein with respect to the composition, such as "hardening composition" means to at least partially cross-link any crosslinkable components of the composition. At -65- This paper standard applies to China Standard (CNS) A4 Specification (21〇X 297 mm) (Please read the note on the back? Matters before filling out this page) -If Ordered --------- Line · Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Cooperative Print 557286

Description of the Invention (64) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs LOI = 100 χ r (w ^-w ^ / W 1

Uw dry) (Equation 〇

Wherein dry is the weight of the fiber strands after drying in an oven at 220 T (about 104 q for 60 minutes plus the weight of the coating composition), and bare fiber is heated in an oven at 1150 T (about 621.0 for 20 minutes and The weight of the bare fiber strands after cooling to room temperature in a desiccator. After coating the first-size, that is, for the first time after the fiber is formed, the mass is aggregated into fibers having a weight per share of 2 to 15. 〇 (M solid fiber strands, and preferably 100 to W00 fibers per share. #Second coating, the composition can be coated on the first-most popular material in an amount sufficient to cover or impregnate the strand portion. , By immersing the coated strand in a bath containing the second coating composition, spraying the second coating composition on the coated strand, or by: contacting the coated strand with the applicator discussed above The coated strands can be removed from the excess coating composition by the die and / or as discussed above, for a time sufficient to at least dry or harden the second coating composition. The second coating = composition The method and device for coating the strands are determined in part by the configuration of the strand material. The strands are preferably after the second coating composition is applied This method is known to dry. Suitable second coating compositions may include one or more of the film-forming materials, lubricants, and other additives discussed above. The second coating is preferably different from the first sizing combination. That is, it contains at least one ingredient that is chemically different from the ingredients of the sizing composition; or (2) contains at least one ingredient in an amount different from the same ingredient contained in the sizing composition. Includes a polyamine group Formic acid ester M l · ί L .----------- r --- order --------- line (Please read the precautions on the back before filling this page) -67- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 _________B7___ V. Description of Invention (65) A non-limiting example of a second coating composition is disclosed in US Patent 4,762,751, which is specifically incorporated herein as Reference. Referring now to FIG. 2, in an alternative embodiment in accordance with the present invention, the glass fibers 212 of the coated fiber strands 210 may be coated with the first sizing composition 2 first-layer 214, including the amounts discussed above Any sizing composition. Examples of suitable sizing compositions are described on pages 237-291 (page 3 (1993) and U.S. Patent Nos. 4,390,647 and 4 795 678, each of which is specifically incorporated herein by reference. The second layer 215 of the second coating composition is coated on at least a portion of the first layer 214, and is preferably Is the entire outer surface. The second coating composition includes one or more types of particles 216, as discussed in detail above with particles 18. In a specific embodiment, the second coating is on at least a portion of the first coating Residues of aqueous second coating composition, especially residues of aqueous second coating composition containing thin flat particles. In another specific embodiment, the second coating is at least a portion of the first coating. Powdery coating compositions, especially powdery coating compositions comprising thin flat particles. In alternative embodiments, the particles of the second coating composition include hydrophilic inorganic solid particles that absorb and retain water in the interstices of the hydrophilic particles. Solid particles of hydrophilic seeders can absorb or swell when exposed to water or participate in chemical reactions with water, for example, forming a viscous colloidal solution that prevents or inhibits water from entering the gaps of communication cables reinforced with coated glass fiber strands. As used herein, "absorption" means that water penetrates the internal structure or interstices of a hydrophilic material and remains substantially within it. See Hawley ^ Condensed Chemical DLctionary, page 3, which is specifically incorporated herein by reference. &Quot; "Swelling" means that the size or volume of the hydrophilic particles is expanding. See Webster ^ New -68-This paper size is applicable to Chinese National Standard (CNS) A4 (210 χ 297 mm) Ί M l · i 11 ----- r --- Order -------- -Line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 ---- B7 V. Description of Invention (66)

Collegiate Dictionary. (1977) p. 1178, which is specifically incorporated herein by reference. Preferably, the hydrophilic particles swell to at least one and a half times their original dry weight after contact with water, and more preferably two to six times their original dry weight. Non-limiting examples of the expanded hydrophilic inorganic solid lubricant particles include montmorillonites such as vermiculite and microcrystalline kaolinite, absorbent zeolites, and inorganic absorbent gels. Preferably, these hydrophilic particles are applied in powder form to a viscous sizing agent or other viscous second coating material. In a specific embodiment of the present invention, a fiber strand including a plurality of fibers is at least partially coated with a resin-compatible coating composition on at least a portion of a surface of at least one fiber. The resin-compatible coating composition is At least a portion of the at least one fiber has a first coating of the sizing composition on the surface, and a second coating comprising a residue of the aqueous coating composition (which includes at least one discontinuous particle) is applied to the sizing composition On at least a portion of the first coating. In a preferred embodiment, at least one discontinuous particle is selected from hydrophilic particles that absorb and retain water in the interstices of the hydrophilic particles. Except for these specific examples, the amount of particles in the second coating composition may range from 1 to 99% by weight, preferably 20 to 90, more preferably 25 to 80% by weight, and even more preferably 50 based on total solids. To 60% by weight. In the alternative embodiment shown in FIG. 3, the third layer 320 of the third coating composition may be applied to at least a part of the surface of the second layer 312, and preferably the entire surface, that is, the fiber strand 312 has a first layer 314 of a first sizing, a second layer 315 of a second coating composition, and a third outer layer 320 of a third coating composition. The third coating of the coated fiber strand 310 is preferably different from the first sizing composition and the second coating composition, that is, the third coating group -69- This paper size applies to the Chinese National Standard (CNS) A4 size (210 X 297 mm) 'Ί Ί l · Η-1 L ----------- r --- order --------- line (please read the first (Please fill in this page again)

: Object (1) contains at least one component that is chemically different from the ingredients of the first sizing agent and the second coating composition; or is different from that contained in the first sizing agent and the second coating composition. The amount of the ingredients contains at least one ingredient. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In this embodiment, the second coating composition contains one or more of the above-mentioned &lt; polymer materials, such as polyurethane, and a third powder The coating composition comprises the solid particles discussed above, such as POLARTHERM® boron nitride particles, and hollow particles such as RopAQUE (R) pigments. Preferably, the powdery coating is applied by passing the coated strands having the liquid second coating composition through a fluidized bed or a spraying device to adhere the powder particles to the adhesive second coating composition. . Alternatively, the strands can be combined into a fibrous material 912 before coating the third coating layer 92, as shown in FIG. The composite or laminate 910 of the composite fabric 912 and the resin 914 also includes a conductive layer 922, which is similar to the structure shown in Figure 8 discussed in more detail below. The weight percentage of the powdery solid particles adhered to the coated fiber strands 31 may range from 0.01 to 75% by weight of the total weight of the dry strands, and is preferably 0 to 30% by weight. The third powder coating may also include one or more of the polymeric materials discussed above, such as propylene polymers, epoxides, or polyolefins. Conventional stabilizers and other modifiers known in this coating technology are It is preferably in the form of a dry powder. In a specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated on at least a portion of the surface of at least one of the first coating fibers of the sizing composition to a second coating composition comprising a polymeric material. Coating at least a portion of the first composition and coating at least a portion of the second coating with a third coating composition comprising discrete particles. In another specific embodiment, a fiber strand comprising a plurality of fibers is at least partially coated with a first coating of a sizing composition. The size of the paper is applicable to China National Standard (CNS) A4 (210 X 297 mm). 17 — 1 ----------- r --- Order --------- Line · (Please read the notes on the back before filling out this page) 557286 A7 B7 V. Description of the invention ( 68 Intellectual staff consume at least one or two coating compositions of at least one of the fibers, including at least one part of the 4th composition of the polymer material, and at least one part of the composition, and the coating composition including thin particles ... At least a part of the second coating is applied to the substrate. In the preferred embodiment, at least one of the above embodiments is different. In the other preferred embodiment, each of the above is different. At least two octahedrons in the examples have different coatings A. In addition, the third coating may be an aqueous emulsion of the coating composition. The coating composition contains-or more The coating composition in question. One = The specific embodiments of the coated fiber strands discussed above can be treated as continuous months or further processed into various For private ... Cut, interlaced, spun, and: weaving: such as fabrics, non-wovens (including single-phase fabrics), knitted fabrics and braids Η "The warp and weft of fabrics = Dimensions can be non-interlaced (also known as non-interlaced or zero-interlaced), or interlaced, and the fabric can include various combinations of interlaced and non-interlaced warp and weft strands. = A preferred embodiment of the Ming includes at least partially Coated fabrics, m to / from fiber strands containing a plurality of fibers discussed in detail above. In the present invention, it is intended to make at least a materially coated fabric from each disclosed fiberboard containing a plurality of fibers. For example, The preferred embodiment of the present invention relates to a fabric that is at least partially coated, which comprises at least a fiber strand containing a plurality of fibers, the coating of which contains an organic component and has a temperature of at least 3 K per meter K丨 The thermal conductivity of the thin flat particles. In the specific embodiment of the invention, the coating composition cloth according to the present invention; individual fibers. In another specific embodiment, the coating is applied to a more woven fabric. Wei Wei has a place in ΙΓ — ί --- ------ Order --------- Line ·! (Please read the phonetic on the back? Matters before filling out this page) I----71- National Standard of National Standard (CNSM4) Specifications (210 x 297)

I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 557286

At least one fiber strand. In another embodiment, a coating composition according to the present invention is applied to a fabric. These alternative embodiments are discussed in detail below. Although the above discussion is generally about directly coating the coating composition of the present invention on glass fibers after fiber formation, and then adding the fibers to the fabric, the present invention also includes coating the coating composition of the present invention on the fabric. The specific embodiment. For example, the coating composition is applied to the fabric by applying the coating to the fiber before manufacturing the fabric, or by applying the coating to the fabric after manufacturing using various techniques already known in the art. Depending on the fabric, the coating composition of the present invention may be applied directly to glass fibers in the fabric or to another coating already on the glass fibers and / or fabric. For example, glass fibers can be coated with a conventional starch-on-oil slurry after being formed and woven into a fabric. The fabric is then treated to remove the starch-oil sizing before coating the coating composition of the present invention. This sizing removal can be accomplished using techniques known in the art, such as heat treating or cleaning the fabric. In this case, the coating composition directly coats the fiber surface of the fabric. If any part of the sizing composition originally applied to the broken glass fibers is not removed after formation, the coating composition of the present invention is applied to the remaining part of the sizing composition rather than directly on the fiber surface. In another embodiment of the present invention, the selected ingredients of the coating composition of the present invention can be applied to glass fibers immediately after formation, and the remaining ingredients of the coating composition can be applied to the fabric after manufacturing. . In a manner similar to that discussed above, some or all of the selected components may be removed from the glass fibers before coating the fibers and fabric with the remaining components. As a result, the remaining ingredients are directly -72-

--------- Order --------- Line (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210 297 (Mm) 557286 Printed A7 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ----- ^ V. Description of the invention (70) '~ The coated fiber surface or the selected points that have not been removed from the fiber surface According to another specific embodiment of the present invention, a fabric containing up to 71% of a plurality of fiber strands is at least partially coated with a first coating, and a first coating (at least a portion is coated with a second coating) Coating, the second coating comprises inorganic particles having a thermal conductivity of κ greater than watts per meter at a temperature of 300 K. In another specific embodiment, the at least one strand I fabric comprising a plurality of fibers is at least partially The coating comprises the following coating: (magic thin flat inorganic particles having a Mohs hardness 値 of at least one glass fiber; and (b) a film-forming material. In another embodiment, A fabric comprising at least one strand comprising a plurality of fibers is at least partially coated Contains the following coatings: (a) metal particles' having a Mohs hardness of at least one glass fiber, a Mohs hardness, of a metal particle selected from the group consisting of indium, thorium, tin, gold and silver, and (b ) A film-forming material. In another embodiment, a fabric comprising at least one fabric comprising a plurality of fiber strands is at least partially coated with a first coating, and at least a portion of the first coating is coated with a second coating Layer, the second coating, a plurality of hydrophilic particles that absorb and retain water in the gaps between the hydrophilic particles. In another embodiment, a fabric comprising at least one strand comprising a plurality of fibers is in at least a portion of the fabric A resin-compatible coating composition on the surface 'This resin-compatible coating composition contains: (a) a plurality of materials selected from the group consisting of non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and _-73- ______ this paper Standards are applicable to China National Standard (CNS) A4 specifications (21 × 297 mm) • Ί Ί l · T 1 1% ----------- r --- order ------- -线 # (Please read the notes on the back before filling this page) 557286 A7

Ι Ί I Ί 1 I, ----- r I--order --------- line · C Please read the precautions on the back before filling this page) (C) At least sliding glass fiber strands A part of the rough surface contacting the solid object, the rough surface having a hardness greater than the hardness 至少 of at least one glass breaking fiber, so that the coating composition inhibits at least one glass fiber of at least one glass fiber strand from contacting the solid. Wear of the rough surface of the object. As mentioned above, the coating ingredients used in these embodiments may be selected from the coating ingredients discussed above, and the other ingredients may be selected from those listed above. Coated fiber strands 10,210,310 and products formed therefrom, such as the coated fabrics listed above, can be used in a wide range of applications, but are preferably formed as composites as a reinforcement 410 to reinforce the polymeric matrix material 412 414, as shown in FIG. 4, which is discussed in detail below. Such applications include, but are not limited to, laminates for printed circuit boards, reinforcements for communication cables, and various other composites. The coated strands and fabrics of the present invention are preferably compatible with typical polymeric matrix materials used to make electronic supports and printed circuit boards. In addition, coated = strands are suitable for use in air-jet looms commonly used to make reinforced fabrics for such applications. Conventional coating of fibers spun using an air-jet loom. Sizing compositions include ingredients such as starch and oils that are generally not compatible with such resin systems. It has been observed that the weaving characteristics of the fiber strands coated with the coating composition according to the present invention, the particle composition 18 are close to the weaving characteristics of the fiber strands coated with the conventional starch / oil-based sizing composition 'and are similar to those of the FR_4 ring. Oxygen resin is compatible. Consumption does not mean that it is limited by any specific theory. It is believed that the rice 18 of the present invention is similar to the conventional powder by providing the fiber separation and air resistance required for the air jet weaving operation during processing and air jet weaving. &quot; It acts by the starch component of the polymer composition, but by providing with the ring 76- this New Zealand standard applies the Chinese National Standard (CNS) A4 grid (21G X 297 public Eding 557286 employee consumption of Intellectual Property Bureau of the Ministry of Economic Affairs) Cooperative printed A7 ------ 2Z______ V. Description of the invention (74) The compatibility of the lipid system does not act in a manner different from the conventional composition. For example, granule 18 promotes the drying of the coating similar to a starch coating Dry, powdery characteristics of lubricating characteristics. In the coated strands of the present invention, the particles can advantageously provide gaps between the fibers of the strands, which facilitates faster flow of the matrix material and / or uniformly wets and wets the strands. In addition, the strands preferably have high strand openness (discussed above), which also facilitates the flow of the matrix material in the bundle. Surprisingly, in specific embodiments, the amount of particles can exceed the amount coated on the fibers 20% by weight of the total solids of the coating composition, while still properly adhering to the fibers and providing strands with processing characteristics that are at least comparable to those of particle-free coatings. Referring now to FIG. 8, the present invention is coated The advantage of the strands is that the laminate 810 made from the coated fabric 812 can have a good coupling at the interface between the fabric 812 and the polymeric matrix material 814. A good coupling can be made from the laminate 810 The electronic support 818 provides good hydrolytic stability and resistance to metal movement (discussed above). In another non-limiting embodiment shown in FIG. 5, the coated strand 510 made in accordance with the present invention may be knitted in Or woven fabric 512 reinforcement as warp and / or weft strands 514 and 516, preferably to form a laminate for printed circuit boards (as shown in Figure 7_9). Although not necessary, the warp strands can be borrowed before use. Any conventional weaving technique known to those skilled in the art of interweaving. One such technique uses an interweaving frame to impart interlacing of 5 to 3 turns per inch. The reinforcing fabric 512 preferably includes 5 to 100 per cm. Warp strands (each There are about 13 to 254 warp yarn strands in the English flag, and preferably each cm: 6 to 50 weft yarns (about 15 to about 127 weft yarns per inch). Woven reed M l · Ί --- ·- ---------- r --- Order --------- line (please read the notes on the back before filling out this page) -77- 557286 Employees' Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs A7 is printed. 5. Description of the invention (75) The dynamic structure can also be a regular plain weave or a grid (as shown in Figure 5), but it can be used for any other known to those skilled in the art. Weaving type. U h weaving or satin in a specific embodiment of the invention is suitable for weaving and strengthening the fabric 512 can be formed by using any conventional weaving machine, such as weaving weaving, Cloth looms, air jet looms, or rapier looms,.. And 疋 are preferably formed using more air jet looms. The preferred air jet loom is commercially available from Japanese Tsudakoma company model 103, 1031, 1033, or ZZ tester Ruti model L_5000, L-5 or L_52〇00, which is commercially available from Sulzer, Zurich, Switzerland. Brothers Limited; and TOYODA model JAT610 〇 As shown in the figure, air jet weaving refers to the use of air jet loom 626 (weaving type of fabric (as shown in Figure 6), as discussed above, The filling yarn (weft) 610 is inserted into the warp shed with strong compressed air 614 from one or more air jet nozzles 618 (as shown in FIGS. 6 and 6a). The filling yarn 61 is pushed through the fabric 628 by the compressed air. A width of 624 (about 10 to about 60 inches), and more preferably 0.91 meters (about 36 inches). The 2 gas jet filling system may have a single main nozzle 616, but preferably also has multiple along the warp shed 612 The auxiliary relay nozzle 620 provides strong auxiliary air 622 to the filling yarn 61 and maintains the air pressure required for the yarn 610 to cross the width 624 of the fabric 628. The air pressure (gauge) supplied to the main air nozzle 616 is preferably Fan Garden is 103 to 413 仟 Baska (kPa) (per square Inches from about 15 to about 60 pounds (psi)), and more preferably 310 kPa (about 45 Psi). The preferred type of main air nozzle 616 is Sulzer Ruti needle air 78-ten ... ---- l · ——Order --------- Line · C Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (21〇x 297 557286 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7. V. Description of the invention (76) Mouth-shooting unit model 044 455 001, which has a nozzle outlet pipe 619 with a diameter of 617 mm and a diameter of 20 cm and a diameter of 621 mm Tank (commercially available from Sulzer Ruti, Spartanburg, NC). Preferably, the air-jet filling system has 15 to 20 auxiliary air nozzles 620 which supply auxiliary air in the transverse direction of the filling yarn 610 to help push the yarn 61 through the loom 626. The air pressure (gauge) supplied to each auxiliary air nozzle 62 is preferably in the range of 3 to 6 bar. The feeding system 632 draws the filling yarn 610 from the supply package 63 at a feed rate of 180 to 550 meters per minute, and preferably 274 meters (about 300 yards) per minute. The filler 610 is fed into the main nozzle 618 via a splint. Strong air forces a yarn of a predetermined length (approximately equal to the desired fabric width) through the tube guide. When the insertion is completed, the yarn end at the end of the main nozzle 618 is cut with a cutter 634. The compatibility and aerodynamic properties of different yarns and air jet weaving processes can be determined by the following methods, which are roughly referred to herein as the "air jet transport resistance" test method. Use air jet transport resistance to measure the force of attraction or pulling exerted on the yarn when pulling the yarn into the air jet nozzle with the force of air jet (,, resistance &quot;). In this method, each yarn sample is fed through a Sulzer Ruti needle air nozzle at an air pressure of 310 仟 Baska (about 45 pounds per square inch) at a rate of 274 meters (about 300 yards) per minute. Jet Nozzle Unit Model No. 044 455 001 'It has an air jet groove inside a nozzle outlet pipe 619 with a diameter of 2 mm 617 and a length of 621 20 cm (commercially available from Sulzer Ruti, Spartanburg, NC). The tensiometer touches the yarn before it enters the air jet nozzle. The tensiometer provides the yarn is pulled to the air jet spray -79- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm)-* — "&gt;: 11 · --------- --r --- Order --------- line · (Please read the note on the back? Matters before filling out this page) 5 5 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Description of the invention (77) The measurement of the gram force (resistance) of the air jet applied to the yarn while in the mouth. The resistance per unit mass can be used as the basis for a relative comparison of yarn samples. For relative comparison, the resistance measurement through a yarn of 1 cm length is standardized. The gram mass of a yarn of 1 cm length can be determined according to Equation 2: gram mass = (π ((1/2) 2) (N) (ρ _) (yarn of 1 cm length) (Equation 2) where d is the yarn bundle The diameter of a single fiber, N is the number of fibers in the yarn bundle, and P is the density of glass at 25 ° C (approximately 2.6 grams per cubic centimeter). Table C lists the fibers in many typical glass fiber yarn products. Diameter and teaching volume.

For example, the gram mass of a G75 yarn with a length of 1 cm is (π (9 χ ιο · 4/2) 2) (4〇ο) (2.6 grams per cubic centimeter) (ι cm of yarn) =: 6 62 x 10-4 g mass. For D450 yarn, the gram mass is 1.34 X 10-4 gram mass. Calculate the relative resistance per unit mass by measuring the resistance (gram force) measured by the tensiometer (gram force) divided by the gram mass of the tested yarn type ("Air Jet Transport Resistance -80-This paper standard applies to China National Standard (CNS) A4 Specifications (210 χ 297 mm) (Please read the notes on the back before filling this page) ----- »---- Order --------- line. 557286

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of Invention (78) Power &quot;). For example, for a G75 yarn, if the resistance tensiometer measures 68 · 5, the air jet transport resistance per gram of mass of yarn is equal to 68 5 divided by 6.62 X 10.4 · ι = 3,474 grams of force. Measured in accordance with the air jet transport resistance test method discussed above, the air jet transport resistance used to form the yarn for the textile fabric used in the laminate according to the present invention is preferably greater than 100,000 grams of force per gram of yarn, more preferably The circle is 100,000 to 400,000 gram-force per gram of yarn, and even more preferably ranges from 120,000 to 300,000 gram-force per gram of yarn. The fabric of the present invention is preferably woven with a type suitable for an electronic support or a laminate for a printed circuit board, as disclosed in "Fabrics Around the World", which is a technical bulletin of Clark_Schwebel Company of Anderson, South Carolina ( 1995), which is specifically incorporated herein by reference. The laminate may be a unidirectional laminate in which most of the fibers, yarns or strands in each layer of fabric are oriented in the same direction. For example, the unrestricted fabric type using E225 E-glass fiber yarn is type 2116, which has 118 warp yarns and 114 filling yarns (or weft yarns) every 5 cm (60 warp yarns and 58 filling yarns per inch); Using 7 22 lx0 (E225 1/0) warp and filling yarns, with a nominal fabric thickness of 0.094 mm (about 0.037 inches); and a fabric weight of 103.8 grams per square meter (about 3.06 ounces per square yard) ( Or basis weight). A non-limiting example of a fabric type using G75 E-broken fiber yarn is type 7628, which has 87 warp and fillets per 5 cm (44 warp and 31 fillets per inch); use 9 68 1χ〇 1/0) warp and filling yarn; a nominal fabric thickness of 0.173 mm (approximately 0.0068 inches); and a 'woven fabric l · Ί 11 of 203.4 grams per square meter (approximately 600 ounces per square yard) 11 .----------- r --- Order --------- Line · (Please read the notes on the back before filling this page) -81- 557286 Intellectual Property Bureau of the Ministry of Economic Affairs Printed by employee consumer cooperative A7 ——————— B7 V. Description of invention (79) Material weight. A non-limiting example of a fabric type using D450 E-glass fiber yarn is the 1080 type, which has 118 warp yarns and% fill yarns per 5 cm (60 warp yarns and 47 fill yarns per inch); use 5 u 1 × 〇 (D45〇 &quot; ... warp and filling yarn; has a nominal fabric thickness of 53 mm (about G_English); and a fabric weight of 46.8 grams per square meter (about 138 ounces per square yard). Use D900 E. Non-limiting example of the fabric type of glass fiber yarn is 106 type, which has 110 warp yarns and 110 filling yarns every 5 cm (56 warp yarns and 56 filling yarns per inch); use 5 5 5 1χ 〇 (D9〇〇1 / 〇) warp and filling; a nominal fabric thickness of 0.033 mm (about 0.013 inches); and a fabric of 24.4 grams per square meter (about 72 ounces per square yard) Weight. Another non-limiting example of a fabric type using D900 E-glass fiber yarn is type 108, which has 118 warp yarns and 83 filling yarns per 5 cm (60 warp yarns and 47 filling yarns per inch); use 5 5 5 1χ2 (D9〇1 / 1 /) warp and filling yarn; has a nominal fabric thickness of 0.061 mm (about 0.0024 inches) And a fabric weight of 47.5 grams per square meter (approximately 14 ounces per square yard). A non-limiting example of a fabric type using D225 and D450 E-glass fiber yarn is type 2113, which has 118 warps and 11 per 5 cm. Filling yarn (60 warp yarns and 56 filling yarns per inch); filling with 7 22 1x〇 (D225 1 / 〇) warp and 5 11 1x0 (D450 1/0); with 0 079 mm (approximately 0.00) 〇31 inch) the nominal fabric thickness; and 78.0 grams per square meter (approximately 23 ounces per square yard) fabric weight. A non-limiting example of the fabric type using G50 and G75E-glass fiber yarn is 7535 type, each 5 cm with 87 warp yarns and 57 filling yarns (44 warp yarns and 29 filling yarns per inch); 9 68 1x〇 (G75 1/0) warp yarns and 9 99 1x0 (G50 1/0) yarn fillings; With 〇2〇1 mm-82- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) '--VMLT1I .---------- l · --- Order --------- Line · (Please read the note on the back? Matters before filling out this page) 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (80) (about 0.0079 British ) The nominal fabric thickness; and 232.3 grams per square meter (approximately 6.85 ounces per square yard) fabric weight. These and other available fabric type specifications are shown in IPC-EG-140, fSpecification for Finished Fabric Woven from Έ1 Glass for Printed Boards &quot;, The Institute for Interconnecting and Packaging Electronic Circuits (June 1997), which is specifically incorporated herein by reference. Although the above-mentioned fabric patterns use interlaced yarns, it is intended to make these or other fabrics that use zero-interlaced yarns or spunbonds to combine or replace interlaced yarns in accordance with the present invention. In a specific embodiment of the present invention, some or all of the warp yarns in the fabric may have fibers coated with the first resin-compatible sizing composition, and some or all of the filling yarns may have a coating different from the first composition. Two resin-compatible coating fibers, that is, the second composition (1) contains at least one component that is chemically different from or in some forms different from the first sizing composition; or (2) is different from the first composition The sizing composition contains at least one component in an amount equal to the amount of the same component. Referring now to FIG. 7, by coating and / or impregnating with a matrix material, preferably a polymeric film, a thermoplastic or thermosetting matrix material is formed. 712 may be used to form a composite or laminate 714. The complex or laminate 714 is suitable as an electron support. As used herein, "electronic support" refers to a structure that mechanically supports and / or electrically cross-links an element. Examples include, but are not limited to, active electronic components, passive electronic components, printed circuits, integrated circuits, semiconductor devices, and other hardware incorporating such components, including, but not limited to, connectors, sockets, clips, and heat sinks Device. -83-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Ί M l · T ^-· ----------- r --- order --- ------ Line (please read the precautions on the back before filling this page) / ZδΟ Α7 Β7 V. Description of the invention () The invention is better and the body sound benefits A 丨 μ less -w Regarding the strengthening compound, It contains up to 0n gj Λ ^. Fiber I coated fiber strands. Therefore, the present invention is therefore a reinforced compound made of the fiber strands of the disclosed winter eve &gt; fP il ^ ^ ^ &gt; f ,! 4 + 〇 eve fibers. For example, the present invention is better and the body # The Hachiman f4 Gan and / or shirt embodiment is about a reinforced composite, which includes a matrix material and at least one thin FF Gandong a coated portion containing fiber and a fiber plate, and the coating includes an organic compound ^. ^ ^} t trowel and thin flat particles with a thermal conductivity of at least 1 watt per K at a temperature of 300K. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least one cut coated with a plurality of fibers and a fiber strand whose coating includes at least one thin flat particle, and (b) Matrix material. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least partially coated fiber strands comprising a plurality of glass fibers, a coating comprising a residue of an aqueous composition comprising a plurality of Discontinuous particles t formed from materials selected from organic materials, inorganic polymeric materials, composite materials and mixtures thereof, (11) to &gt;-a lubricating material different from the plurality of discontinuous particles; and (iii) at least one film Forming material; and (b) a matrix material. Another preferred embodiment of the present invention relates to a reinforced composite, which comprises at least one fiber strand and a matrix material, wherein the reinforced composite further comprises a residue of an aqueous composition, which comprises (a) a plurality of selected from organic materials, Discontinuous particles formed from materials of inorganic polymeric materials, composite materials, and mixtures thereof; (b) at least one lubricant material different from the plurality of discontinuous particles; and (c) at least one film-forming material. Another preferred embodiment of the present invention relates to a reinforced composite, which includes at least partially coated fiber strands containing a plurality of glass fibers. 84- This paper size is applicable to the Chinese National Standard (CNS) A4 specification ( 210 X 297 public love) Ί M l ·, Ί ^ --.----------- r --- order --------- line (please read the precautions on the back first) Refill this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ---- 21____ V. Description of the Invention (82) The coating contains residues of water-based composition, which contains It is greater than 20% by weight based on total solids. Discontinuous particles, the particles having a Mohs hardness 値 of at least one of the glass fibers; and (b) a matrix material. Another preferred embodiment of the present invention relates to a reinforced composite comprising at least one fiber strand and a matrix material comprising a plurality of glass fibers, wherein the reinforced composite further comprises a residue of an aqueous composition, which comprises greater than 20% by weight of discontinuous particles, the particles having no more than at least one Mohs hardness 値 of the glass fiber. An additional specific embodiment of the present invention relates to a reinforced composite, which comprises: at least one fiber strand comprising a plurality of glass fibers, and the coating of the strand comprises a plurality of elements selected from the group consisting of organic materials, inorganic polymeric materials, composite materials, and mixtures thereof. The material of the material forms a resin compatible composition of discontinuous particles, wherein the discontinuous particles have an average particle size of less than 5 microns; and ⑻ matrix material. In particular, the plurality of discontinuous particles are formed of a material selected from any of the non-thermally expandable organic materials, inorganic polymeric materials, non-thermally expandable composite materials, and mixtures thereof. The components of the coating and resin-compatible composition used in the above specific embodiments of the reinforced composite may be selected from the coating components discussed above, and the components may also be selected from those listed above. Preferred matrix materials for use in the present invention include thermosetting materials such as thermosetting polyesters, acetoyl esters, epoxides (containing at least one epoxy or ethylene oxide group in the molecule, such as polyhydric alcohols or thiols). Polyglycidyl ether), phenolic, amino-based plastics, thermosetting polyurethanes, any of the above derivatives, and mixtures of any of the above. Form the laminate for printed circuit boards. Applicable to China National Standard (CNS) A4 specification (210 X 297). &Quot; ---------— (Please read the precautions on the back before filling This page) --- I ---- Order -------- Line ▲ 557286 A7 B7 V. Description of the invention (83) (Please read the precautions on the back before filling this page) It is FR-4 epoxy resin (which is a multifunctional epoxy resin such as a difunctional brominated epoxy resin), polyimide, and a liquid crystal polymer. Such compositions are known to those skilled in the art . If further information on such a composition is required, see Electronic Materials Handbook ™, ASM International (1989) pages 534-537, which are specifically incorporated herein by reference. Non-limiting examples of suitable polymeric thermoplastic matrix materials include polyolefins, polyamides, thermoplastic polyurethanes and thermoplastic polyesters, ethylene polymers, and mixtures of any of the foregoing. Other examples of useful thermoplastic materials include polyimide, polyether, polyphenylene, polyether ketone, polyphenylene oxide, polyphenylene sulfide, polyacetal, polyethylene gas, and polycarbonate. ester. Preferred matrix material formulations include EPON 1120-A80 epoxy resin (commercially available from Shell Chemical Company, Houston, Texas), dicyandiamide, 2-methylimidazole, and DOWANOL PM glycol ether (commercially available from Michigan) The Dow Chemical Company, Midland, PA). The polymer matrix materials and reinforcing materials in the printed consumer composites of the Intellectual Property Bureau of the Ministry of Economic Affairs may include other ingredients including colorants or pigments, lubricants or processing aids, ultraviolet stabilizers, antioxidants, other Fillers and admixtures. In a preferred embodiment, the polymeric matrix material includes an inorganic material. These inorganic materials include ceramic materials and metallic materials, and may be selected from the inorganic materials detailed above. Fabric 712 can be coated and impregnated by dipping fabric 712 in a bath of polymeric matrix material 716, for example, as discussed in Microelectronics Packaging Handbook. (1989) at R. Tummala (eds.), Pages 895-896, which Specifically incorporated herein by reference. More often, use hand or renhe from -86-the scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557286 printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Description of invention (84) The feeding or mixing device disperses the chopped or continuous fiber strand reinforcement material in the base material, which distributes the reinforcement material substantially uniformly throughout the polymeric matrix material. For example, the reinforcing material can be dispersed in the polymeric matrix material by drying and compounding all the ingredients simultaneously or sequentially. Depending on the type of matrix material employed, the polymeric matrix material 716 and strands can be formed into a composite or laminate 714 by many methods. For example, for a thermoset matrix material, the composite may be formed by compression or injection molding, pulverization, filament winding, manual stacking, spraying, or by sheet molding or volume molding followed by compression or injection molding. The thermosetting polymeric matrix material can be hardened, for example, by including a cross-linking agent in the matrix material and / or applying heat. Suitable cross-linking agents for cross-linking polymeric matrix materials are discussed above. The temperature and curing time of the thermosetting polymeric matrix material will depend on factors such as, but not limited to, the polymeric matrix material used, other additives in the matrix system, and the thickness of the compound. For thermoplastic matrix materials, suitable methods for forming composites include direct molding or extrusion composites followed by injection molding. Methods and devices for forming composites by the above methods are discussed in I. Rubin's Handbook of Plastic Materials Sail ^ chnology mQO) rods 955-1062, 1179-1215, and 1225-1271, which are specifically incorporated herein by reference. An additional embodiment of the present invention pertains to a reinforced laminate suitable for use in an electronic support, which comprises an at least partially coated fabric, which comprises at least one fiber strand as detailed above. Accordingly, the present invention is intended to be a reinforced laminate suitable for an electronic support made from each of the disclosed fabrics containing at least one fiber strand. For example, the preferred embodiment of the present invention relates to -87-this, four-sheet scale applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Ί. -ΊΊ 0M .----- --- Order --------- line j (please read the notes on the back before filling out this page) 557286 A7 --------______ 5. Description of the invention (85) (Please read the notes on the back first Please fill in this page again) The reinforced laminate of electronic support, which contains matrix material and at least one partially coated fabric containing at least one fiber strand, this coating contains organic ingredients and has a temperature of 300K per Mi K is a thin flat particle with a thermal conductivity of at least 1 watt. In other embodiments, the coating is compatible with a matrix material suitable for use in a reinforcing laminate for an electronic support. An additional embodiment of the present invention relates to a reinforcing laminate suitable for use in an electronic support, the laminate comprising a rhenium matrix material, and at least one non-defatted fabric comprising at least one fiber strand, at least one of the at least one fabric The compound has a coating that is compatible with a matrix material in the reinforcing laminate suitable for the electronic support. Another embodiment of the present invention relates to a reinforcing laminate suitable for use in an electronic support, the laminate comprising a rhenium matrix material, and (b) at least one component comprising at least one fiber strand and at least one portion of the fabric Fabric with untrimmed resin compatible coating composition on the surface. Printed for use by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, “non-fat fabric” is a fabric that has not been treated with conventional fibers from non-resin-compatible sizing materials removed from the fabric. Removal and water jet cleaning are examples of such conventional fiber treatments. The untrimmed resin-compatible coating composition used herein refers to the resin-compatible coating composition discussed above that is not used in the conventional fiber conditioning process. For example, an untrimmed resin-compatible coating composition refers to the first, second, and / or third coating compositions discussed above, but does not refer to the typical trimming materials, such as those made with a calcined coupling agent and water, And it is applied to the fiber after degreasing. However, the present invention does intend to make the coating include a resin-compatible coating according to the present invention with a trimming material applied to the coating. Another embodiment of the present invention is About the formation of electronic support should be -88 · This paper size is applicable to China National Standard 4 (U% M4 specification (21〇X 297K £ 7 557286 A7)

V. Description of Invention (89) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs to form an electronic support. In a more preferred embodiment, 'at least one fabric and at least one matrix form a first composite layer in an electronic support. In another preferred embodiment, the electronic support further includes a second composite layer different from the first composite layer. An additional preferred embodiment relates to an electronic circuit board, which includes an "electron support" that includes at least one non-defatted fabric containing at least one fiber strand, and at least a portion of the at least one non-defatted fabric has a matrix material compatible A coating, and (ii) &lt; at least one matrix material on at least a portion of at least one fabric in the electronic support; and (b) a conductive layer, the support and the conductive layer being contained in an electronic circuit board. An additional preferred embodiment relates to an electronic circuit board that includes (a) an electronic support, which includes: at least one containing at least one fiber strand and having an unmodified resin compatible coating on at least a portion of the surface of the fiber The fabric of the composition 'and (11) at least one matrix material on at least a part of at least one of the fabrics in the electronic support; and ⑻ the conductive layer, the support and the conductive layer are contained in an electronic circuit board. In a more preferred embodiment, a conductive layer is disposed in a selected portion of an adjacent electronic support. In another more preferred embodiment, at least one fabric and at least one matrix form a first composite layer. In another embodiment, the electronic support further includes a second composite layer different from the first composite layer. Preferably, a conductive layer is disposed on a selected part of the first and / or second composite layer of the adjacent electronic support. Another specific embodiment of the present invention relates to a method for forming a printed circuit board. The method includes steps. : This paper uses Chinese National Standards (CNS) A4 for each week. $ ---- (Please read the precautions on the back before filling this page} -L? Order --------- line-557286 A7 V. Description of the invention (90) to Γ1 By: weaving at least one filling yarn containing a plurality of fibers and having a first resin-compatible coating on at least a part of the: filling yarns, and one or two- A warp yarn comprising a plurality of fibers and having a second resin-compatible coating on at least one part of at least one warp yarn, resulting in an envelope: a conductive layer and at least one electronic support for a fabric suitable for reinforcing an electronic support Here, at least one of the conductive layers of the electronic support is patterned to form a printed circuit board. The components of the coating used in the above specific embodiments of the electronic support and the electronic circuit board may be selected from the above The ingredients in question, and other ingredients can be selected from the following: If necessary, any convenient method known in the art can be used, including but not limited to mechanical drilling and laser drilling, to form a perforation or hole in the electronic support (scarcely called a "channel") to make the electronic support Electrical connections between circuits and / or components on opposite surfaces. More specifically, referring to FIG. 10, perforations 1060 extend through at least one layer 1062 of fabric 1012 of electronic support 1054 of the present invention. Fabric 1012 includes a coated fiber strand comprising Multiple glass fibers with layers compatible with various polymeric matrix materials, as shown here. When forming the perforation 1060, the electronic support ι54 is placed in a perforation forming device, such as a drill cone 1064 or a laser head By forming a perforation 1060 through a portion 1066 of at least one layer 1062 of the fabric 1012 by using a drill cone 1064 or laser. In a preferred embodiment, using a 0.46 mm (0.018 inch) direct-controlled carbonized drill bit With a hole density of 62 holes per square centimeter (400 holes per square inch) and a plate load of 001, pass through a stack of 3 laminates (please read the precautions on the back before filling this page)

-1® ^ -------- Order --------- line I Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

557286 A7 V. Description of the invention (91 After 2000 holes are drilled, the laminate has an error distance of not more than 36 microns. In additional specific embodiments, when using 046 mm (0018 inches) (please read first Note on the back, please fill in this page again) Diameter tungsten carbide drill, pass through 3 layers with a hole density of 62 holes per square centimeter (400 holes per square inch) and a plate load of 0.001 After 2,000 holes are drilled in the stack of the composite, the laminate has a drill tool abrasion% of not more than 32%. In other specific embodiments, the fluid flow containing the inorganic lubricant is distributed near the perforation forming device. The agent contacts at least a part of the interface between the perforation forming device and the electronic support. Preferably, the inorganic lubricant is selected from the inorganic lubricants detailed above. Another embodiment of the present invention relates to the use of an electronic circuit board. A method of perforating a fabric layer of an electronic system support, comprising: (1) arranging an electronic system support including a fabric layer (which includes a coated coating comprising a resin-compatible coating composition on at least one surface of the fabric; Fiber-covered strands), in which perforations are formed by perforation forming devices; and (2) perforations are formed in the fabric layer. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs after the perforation is formed, a layer of conductive material is deposited The perforation wall or the perforation is filled with a conductive material to facilitate the required electrical cross-linking and / or heat dissipation between one or more conductive layers (not shown in Figure 10) on the surface of the electronic support 1054. The path is partially Extending through or completely through the electronic support and / or the printed circuit board 'it may be exposed on one or both surfaces of the electronic support and / or the printed circuit board, or it may be completely hidden or contained in the electronic support and / or Inside the printed circuit board (&quot; hidden path π). The conductive layer 820 shown in Fig. 8 can be obtained by anyone who is familiar with this technique. 94- This paper size applies the Chinese National Standard (CNS) A4 specification (21〇χ 297 mm) 557286 A7 B7 V. Description of the invention (93) The resin content of the laminate is preferably in the range of 35 to 80% by weight, and more preferably 40 to 75% by weight. The amount of fabric in the laminate is better For Fan Yuan is 20 to 65% by weight, It is more preferably 25 to 60% by weight. For a laminate formed of a woven E · glass fabric and a FR-4 epoxy resin matrix having a minimum glass transition temperature of 110 ° C, it is in accordance with IPC-4101 &quot; Specification for Base Materials for Rigid and Multilayer Printed Boards &quot; page 20, The Institute for Interconnecting and Packaging Electronic Circuits publication (December 1997), traversing the machine or width direction (generally vertical to the longitudinal axis of the fabric, i.e. in the filling direction) The preferred minimum flexural strength is greater than 3 X 107 kg / m2, more preferably greater than 3.52 X 107 kg / m2 (about 50 kpsi), and even more preferably greater than, 4 · 9 X 107 kg / m2 ( About 70 kpsi). IPC-4101 is specifically incorporated herein by reference. In the longitudinal direction, the required minimum flexural strength in the longitudinal direction (generally parallel to the longitudinal axis of the fabric, that is, in the warp direction) is preferably greater than 4 X 107 kg / m2, and more preferably greater than 4.23 X 107 kg / Square meters. Flexural strength is measured in accordance with ASTM D-790 and IPC-TM-650 Test Methods Manual of the Institute for Interconnecting and Packaging Electronic Circuits (December 1994) (which is specifically incorporated herein by reference), and by following IPC_4101 Section 3.8.2.4 completely removes the metal finish. The advantages of the electronic support of the present invention include high flexural strength (tensile and compressive strength) and high modulus, which can reduce the deformation of the circuit board (including the laminate). According to the IPC test method 2.4.4.1 (which is specifically incorporated herein by reference), the electronic support of the FR-4 epoxy-based laminate of the copper surface of the present invention is 96-scale applicable to China National Standard (CNS) A4 Specifications (210 X 297 mm) (Please read the precautions on the back before filling this page) -1® ^ -------- Order --------- line ▲ Intellectual Property Bureau, Ministry of Economic Affairs Printed by the employee consumer cooperative 557286 A7 B7_______ 5. The description of the invention (94) is preferably in the z_ direction of the laminate (&quot; Z_CTE.), That is, the thickness across the laminate 'has to 50 ° C to 288 Ό is a thermal expansion coefficient of 0.01 to 5.0 weight ❶ /. Each such laminate is preferably a 7628 type fabric containing eight layers, although or can be used, for example but not limited to 106, 108, 1080, 2113 , 2116, or 7535 fabric types. In addition, laminates can be added to the combination of these fabric types. Laminates with a low thermal expansion coefficient are generally less susceptible to expansion and shrinkage and minimize board distortion. The present invention is more intended as a multilayer layer And electronic circuit boards, including at least one composite layer manufactured in accordance with the instructions herein, and A composite layer made in a method different from the composite layer shown here, such as' using conventional glass fiber composite technology. More specifically and as known to those skilled in the art, traditionally, Part or all of dextrinized starch or amylose, hydrogenated vegetable oil, cationic humectant, emulsifier, and water powder / oil on ingredients' which include but are not limited to Loewenstein pp. 237-244 (3rd edition, As disclosed in 1993), which is specifically incorporated herein by reference for the treatment of fibers in continuous glass fiber strands for weaving fabrics. Warp yarns made from these strands are then treated with a solution to protect the strands from weaving before weaving Wear during the weaving process, for example, poly (acetol), as disclosed in U.S. Patent 4,530,876, column 3, lines 67 through 4, and line 11, which is specifically incorporated herein by reference. This operation Commonly referred to as sizing. Poly (vinyl alcohol) and starch / oil sizing are generally not compatible with the polymeric matrix materials used by the composite maker, so the fabric is removed to remove essentially the surface of the glass fiber before impregnating the textile fabric all Organic materials. It can be done in many ways, for example, by washing fabrics, or more often by this technique. • 97- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) ( Please read the precautions on the back before filling this page) -------- Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 V. Description of Invention (97 The method includes: (i) coating at least one of the first, second, and / or third coating compositions discussed in detail above (which includes particles that provide gaps between adjacent fibers of the strand) to a fiber strand reinforcing material (2) drying the coating to form a coating on the reinforcing material; (3) combining the reinforcing material with a matrix material; and (ii) at least partially hardening the matrix material to provide a reinforced composite. Although not limiting the invention, the reinforcing material may be combined with a polymeric matrix material, for example, by dispersing it in the matrix material. Preferably, the coating forms a substantially uniform coating on the reinforcing material when dried. In a non-limiting specific embodiment of the present invention, the particles comprise at least 20% by weight of the coating composition based on total solids. In another non-limiting embodiment, the particles have a minimum average particle size of at least 3 microns, and preferably at least 5 microns. In other non-limiting examples, the particles have a Mohs hardness 小于 smaller than the hardness 値 of any glass fiber contained in the fiber strand. The present invention also includes a method for inhibiting adhesion between fiber strands and fibers. The method includes the steps of: ⑴ at least one of the first, first, and / or third coating compositions discussed in detail above, which are included in adjacent fibers of the strand Particles that provide interspaces) are applied to the fiber strands, and the coating is dried to form a coating on the fiber strand's dimension so as to inhibit adhesion between adjacent fibers of the strands. Preferably, the coating is substantially uniformly coated on the reinforcing material at the time of the coating. In a non-limiting specific embodiment of the present invention, the particles comprise a sizing composition of V 20 weight /% based on total solids. In another non-limiting embodiment, the particles have a minimum average particle size of at least 3 micrometers, and preferably i less than $ micrometers. For example, in spherical particles, the smallest average particle size is relative to the particle diameter. For example, in rectangular particles, the minimum average particle size is the length, width, or length of the particles. In other non-restricted concrete entities, Mo Gap fiber is small to small (please read the precautions on the back before filling this page)

-------- Order --------- Line I L _______- loo- This paper size is applicable to Zhongguanjia Standard (CNS) A4 specifications ⑵G χ tear public shame y 5. Description of the invention (98) In the embodiment, the particles have a Mohs hardness 小于 smaller than the Mohs hardness 値 of any glass-breaking fiber contained in the fiber strand. The invention also includes a method for inhibiting the hydrolysis of the matrix material of the fiber-reinforced composite. This method comprises: (1) applying at least one of the first, second, and / or third coating compositions discussed in detail above (which contains discontinuous particles greater than 20% by weight based on total solids) to fiber strand reinforcement (3) drying the coating to form a coating on the reinforcing material; (3) combining the reinforcing material with a matrix material; and (4) at least partially hardening the matrix material to provide a reinforcing composite. Preferably, the coating is on A substantially uniform coating is formed on the reinforcing material upon drying. As discussed above, the reinforcing material can be combined with the matrix material by, for example, dispersing the reinforcing material in the matrix material. In a non-limiting embodiment of the present invention The fabric is preferably woven into a 7628-type fabric and has an air permeability of less than 10 cubic feet per minute, and more preferably less than 5 cubic feet per minute, as measured by the ASTMD 737 standard test method for air permeability of textile fabrics. Although not limited in the present invention, comparing various conventional fabrics made using sizing warp yarns, it is believed that the elongation cross-section and high openness of the warp yarns of the present invention are reduced (discussed in detail below) The breathability of the fabric of the present invention. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. As previously discussed, in the conventional weaving operation of the electronic support application, the warp yarn is generally coated with sizing on the sizing yarn before weaving. Helps prevent warp yarns from sticking during weaving. Sizing sizing compositions typically remove any excess by passing the warp yarns through a dipping tray or bath containing the sizing of the sizing yarn and then through one or more sets of squeeze rollers And sizing. Typical sizing composition can include, for example, film-forming materials, plasticizers, and lubricants. Commonly used in sizing-101-This paper applies Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 A7

V. Description of the Invention (101) The printed surface of the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs "indicates that the warp yarn has a substantially flat or oval cross-section shape. The open fibers of the high-stranded yarns discussed above are not tightly individual fibers Keep together, and the open space between one or more individual fibers facilitates the penetration of the matrix material into the bundle. The warp of the sizing yarn (as discussed above) usually has a circular cross section and low openness, It is therefore not conducive to this penetration. Although not limited in the present invention, it is believed that by reducing or excluding the path of moisture entering the laminate and the electronic support, a good resin penetrates into the warp bundle during lamination ( That is, good resin penetration) can improve the total hydrolytic stability of the laminates and electronic supports manufactured in accordance with the present invention. It is useful for reducing the printed circuit boards manufactured from such laminates and electronic supports due to exposure to Under humid conditions, the formation of conductive anode filaments under a bias voltage and the tendency of electrical short circuit failure can also have a positive effect. The degree of openness of the strand can be measured by the F-index test. In the f-finger In the test, the yarn to be measured was placed through a series of vertically aligned rollers, and a horizontally arranged sensing device adjacent to the light emitting surface and the opposite photosensitive surface was arranged so that the vertical axis of the yarn was aligned substantially parallel to the light emitting and photosensitive surface. The horizontal distance between the yarn and the sensing device is controlled by making it approximately half the vertical height between the vertically aligned rollers, and by moving the roller toward or away from the sensing device. As the yarn passes through the roller (generally about 3 per minute) M), depending on the openness of the strand, one or more parts of the yarn can shield a part of the light from the light-emitting surface, thus triggering the reaction in the photosensitive device. Then for a specific yarn length (generally about 10 M) The number of masks is used as a table, and the generated ratio (ie, the number of masks per unit length) is regarded as a measure of the openness of the strand. According to the tight warp structure of the fabric from the conventional sizing glass fiber yarn-1 ^ \- ---- r --- order --------- line (please read the precautions on the back before filling this page) -104- 557286 A7 B7 V. Description of Invention (I〇2): = Put Sex (as discussed above), As a result, these conventional fabrics have better breathability than the fabrics of the present invention (preferably including long '<warp yarn openness), and good elasticity and permeability. In the non-restrictive material of the present invention and measured by the ASTMDW standard test method, weaving = = square British ... at 10 standard cubic-= ... .05 standard cubic meters), and more preferably not greater than 5 cubic cubic inches ( 152 standard cubic meters per square meter per minute ^ min per square inch ... breathability of 3 cubic meters per minute (^ 1 standard cubic meter per minute per minute). In another aspect of the present invention 7 == weaving fabric Molded fabric, and as measured by D 737 & quasi-test method set in H) furnace jinshi, war] the amount I has a small absorption per square inch per minute: w &quot; ruler 'is better More than 5 The best is more than 3 cubic inches per square inch per minute. ^ However, it does not mean that it is limited by any particular theory or in any way. Wang Zhang has a long or average cross section of the warp yarn laminate. Improved iron steel performance. More specifically, the intersecting point between the warp yarns and the filling yarns in the two fabrics has a lower shape than that of the conventional fabrics: the material cuts the warp yarns with a cut surface, and the material fabrics have the least contact with glass when used in iron. The fiber, therefore, occurs less frequently as discussed in the foregoing. In the present invention, it is preferred that both the warp yarn and the filling yarn have a resin-compatible first coating composition applied during formation. The coating-compatible resin-coating composition of the yarn can be the same as the coating composition of the resin phase of the yarn filling, or it can be different from the resin of the yarn filling. L ______- 105-This paper Standards for Financial Affairs ¥ Fresh (CNS) A4 Secret 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 —-------- sz________ V. Invention Description (103) &quot; 一 &quot; &quot; — Compatible with -Coating composition. Reference is made here to the term used in the resin-compatible coating-coating composition coated on the warp yarn, which is different from the resin-compatible coating-coating composition coated on the warp yarn- " At least one component of the coating composition is present in an amount different from the first coating composition applied to the filling yarn, or at least one component of the first coating composition applied to the warp yarn is not present in the applied In the first coating composition of the yarn filling, or at least one component applied to the yarn filling composition is not present in the first coating composition applied to the warp yarn. In another non-limiting embodiment of the present invention, the glass fiber of the yarn of the fabric is an E-glass fiber having a density of less than 26 grams per cubic centimeter. In another non-limiting embodiment, when woven into a loop-type fabric, E-glass fiber yarns are made of fabrics having parallel warp direction tensile strength greater than the strength (warp direction) of conventional heat-clearing and trimming fabrics of the same type. In another non-limiting embodiment of the present invention, it is preferable that the fat-compatible first coating composition is substantially free of &quot; adhesive &quot; film-forming material, that is, the first coating composition includes It is preferably less than 10% by weight based on total solids, more preferably less than 5% by weight based on total solids. In a preferred embodiment, the resin-compatible first coating composition is essentially free of an "adhesive" film-forming material, that is, the first coating composition preferably contains less than 1% by weight based on total solids, more It is preferably less than 0.05% by weight based on total solids, and most preferably less than 0.01% by weight based on total solids. Adhesive film-forming materials are harmful to the weaving power of the coated yarns because they reduce the air jet transport force of the yarn filling and cause the warp yarns to stick to each other. A specific, non-limiting example of an adhesive film-forming material is a water-soluble ring: 丨-^, 1,-, ----------- r --- order -------- -Line (Please read the precautions on the back before filling this page} -106-557286 A7 B7 V. Description of the invention (106)

Table 1A Ingredients% by weight based on total solids Sample composition ABCDEF RD-847A97 28.6 29.1 31.58 50.71 0 0 DESMOPHEN200098 43.7 39.1 0 0 0 0 EPI-REZ 3522-W-66 &quot; 0 0 21.05 0 0 0 EPON 826100 0 0 0 0 16.12 63.54 PVP-K30101 0 9.7 15.79 15.21 1.31 5.18 A-187102 2.3 2.3 8.42 8.11 3.17 12.51 A-174103 4.7 4.8 0 0 0 0 A-1100104 0 0 8.42 8.11 0 0 PLURONIC F-108105 10.7 5.6 0 0 0 0 IGEPAL CA- 630106 0 0 4.74 6.39 1.63 6.44 VERSAMTD 140107 4.8 4.8 0 0 0 0 ALKAMULS EL-719108 0 0 0 0 1.63 6.44 KESSCO PEG 600109 0 0 0 0 0.79 3.11 MACOL NP-6110 3.6 3.6 4.74 6.39 0 0 RD-847A polyester resin , Its business was obtained from Columbus, Ohio (Please read the notes on the back before filling out this page) Printed on a moderately large piece of paper on a standard paper printed by the employee ’s consumer cooperative of the Ministry of Economy ’s Intellectual Property Bureau

Borden Chemicals Corporation 0 98 DESMOPHEN 2000 polyethylene adipate glycol, commercially available from Bayer Company, Pittsburgh, PA. 99 EPI-REZ 3522-W-66 Commercially available from Shell Chemical Company of Houston, Texas 0-109-G4 A4 S) (210 χ 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the Invention (107) 100 EPON 826, commercially available from Shell Chemical, Houston, Texas. 1G1 PVP-K30 polyvinylpyrrolidone, commercially available from ISP Chemicals, Inc., Wayne, New Jersey 0 102 A-187 γ-dehydroglycerylpropyltrimethoxysilane, commercially available from Tarrytown, New York CK Witco. ιω A-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco Corporation, Tarrytown, New York. 1G4 A-1100 amine-functional organosilane coupling agent, commercially available from CK Witco, Tarrytown, New York. 1G5 PLURONIC ™ F-108 polyoxypropylene-polyethylene oxide copolymer is commercially available from BASF Corporation, Parsippany, New Jersey. 1G0 IGEPAL CA-630 ethoxylated octylphenoxyethanol, commercially available from GAF Corporation of Wayne, New Jersey 0 1G7 VERSAMID 140 polyamine, commercially available from Cognis Corporation of Cincinnati, Ohio ° 1G8 ALKAMULS EL-719 Polyoxyethylated vegetable oil, which is commercially available from Phone_Poulenc, Inc. 01G9KESSCO PEG 600 polyethylene glycol monolaurate, and is commercially available from Stepan, Chicago, Ill. 11G MACOL NP_6 Nonyl Surfactant, commercially available from BASF Corporation, Parsippany, New Jersey. -no- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). 丨 丨 —-rul ------------ r --- order ----- ---- 线 # (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the invention (108) Table 1A (continued) Composition of total solids Weight% Sample Composition AB c DEF EMERY 6717111 0 0 0 0 0.40 1.56 EMERY 6760112 0 0 4.21 4.06 0 0 POLYOX WSR-301113 0.6 0 0 0 0 0 POLARTHERM PT 160114 1.0 1.0 0 0 74.78 1.00 RELEASECOAT-CONC 25115 0 0 1.05 1.01 0 0 111 EMERY® 6717 partially fluorinated poly (ethylene diimide), commercially available from Cognis Corporation of Cincinnati, Ohio. 112 EMERY® 6760 lubricant commercially available from Cognis Corporation of Cincinnati, Ohio. 113 POLYOX WSR-301 poly (ethylene oxide), commercially available from Union Carbide, Danbury, Connecticut 0 114 POLARTHERM® PT 160 boron nitride powder particles, commercially available from Advanced Ceramics, Lakewood, Ohio. 115 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride particles in an aqueous dispersion commercially available from ZYP Coatings, Oak Ridge, Tennessee. Comparative samples of commercial products 631 and 633 D-450 coated starch-oil yarns; comparative samples of 690 and 695 coated starch-oil yarns, and comparative samples of 1383 G-75 yarns were also commercially available from PPG Industries. In addition, three comparisons of applying the same water-forming composition X described in Table IB below are also tested -111-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 丨 ^- \ 1, ------------- r --- Order --------- line (please read the notes on the back before filling this page) 557286 A7 B7 V. Invention Instructions (109) (Please read the notes on the back before filling out this page) Samples XI, X2 and X3. Comparative sample XI had a solids content of 2.5% by weight. Comparative sample X2 had 4.9% solids by weight and was air-dried at 25 ° C for about 8 hours. Comparative sample X3 had a solids of 4.6% by weight.

Table 1B Ingredients% by weight based on total solids Ingredient sample X RD-847A116 28.9 DESMOPHEN 2000117 44.1 A-187118 2.3 A-174119 4.8 PLURONIC F-108120 10.9 VERSAMID 140121 4.8 MACOL NP-6122 3.6 POLYOX WSR-301123 0.6 116 RD-847A polymer Ester resin, commercially available from Borden Chemicals, Columbus, Ohio. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 117 DESMOPHEN 2000 Polyethylene adipate, commercially available from Bayer Company, Pittsburgh, PA. 118 A-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 119 Α-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 12G PLURONIC ™ F-108 polyoxypropylene polyethylene oxide copolymer, commercially available from New Zealand BASF, Parsippany, Jersey. -112- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 557286 A7 B7 V. Description of Invention (ill) Printed on the 1C Sample Number Yarn Type LOI ( %) Resistance (gram force) Air jet transport resistance (gram force per gram of mass) AG-75 0.35 68.5 103,474 B G-75 0.30 84.9 128,248 Bvac G-75 0.35 95.0 143,587 C D-450 0.52 37.33 278,582 D D-450 0.40 47.1 351,493 E G-75 0.35 79.3 119,789 F G-75 0.35 83.2 125,680 Comparative sample 631 * D-450 1.6 21.45 160,075 633 * D-450 1.3 38.1 284,328 690 * G-75 1.0 108.23 163,489 695 * G-75 1.0 100.46 151,752 1383 G-75 0.75 14.47 21,858 XI G-75 0.33 36.4 54,85 X2 G-75 0.75 19.0 28,701 X3 D-450 1.37 12.04 89,851 Chi D-450 1.59 9.00 67,164 Cm D-450 1.66 10.43 77,836 coated with starch-oil Sizing formula. As shown in Table 1C above, each coated polymeric matrix material phase in accordance with the present invention is -114- ------------------ r --- order ------- --Line (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 A7 B7 Description of invention (113) Flexural strength Flexural modulus Short Beam Shear Strength Baska psi Baska psi Baska psi Β 4.9 X 106 71534 2.4 X 1010 3465000 2.6 X 1〇7 3742 Bvac 5.0 X 106 72215 2.4 X 1010 3450600 2.5 X 1〇7 3647 695 4.3 X 106 62959 2.3 X 1010 3360 800 2.3 X 1〇7 3264 (please read the precautions on the back before filling this page) liy π \ Xiao'gan, also called / double / double: when it comes to the laminate sample that is difficult to prepare 'Laminate samples B and BVac prepared according to the present invention have higher flexural strength and modulus 値 and similar short beam shear strength. Also by passing a pair of conventional tension measuring devices with fixed chromium posts of about 5 cm (2 inches) in diameter installed in place of 5 cm from a straight path between the tension measuring devices at a distance of 274 meters (300 Code) Rate Pull Sample 'A tension of 30 grams was applied to each yarn sample, and the frictional forces of samples A and B and comparative samples 1383 and XI were evaluated. The acrylic force difference is described in Table IE below. The friction force test is intended to simulate the friction force that the yarn receives during weaving operations. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Also used the Moulin tester to estimate the broken filaments of samples A and B and comparative samples 1383 and XI. When each test sample was pulled at a rate of 046 meters (18 inches) per minute for 5 minutes through a wear test device, a tension of 200 g was applied to each test sample, and two tests of each sample and comparative samples were evaluated, and the fibers were broken. The average number of filaments is reported in Table 1E below. Wear tester: Includes two parallel steel reeds 歹, each row is 1 inch apart. Samples of each test yarn were spiraled between the first and second reeds, and then spiraled between the second row of springs and the two adjacent reeds, but shifted by half an inch between the two rows of reeds. Paper -116--Meaning + ^ iST (CNS) A4 specification (210 X 297 male 557286 A7 B7 V. Description of the invention (114) Distance. Reed 240 IS &gt; per minute, go to f τ 蠖 40 circles Catch rate, in parallel to the transverse direction of the yarn, the direction of the imitated child friction force in grams of 4 inches long Yan (grams) the number of broken filaments per yard of yarn AB comparative --- ^^ j comparative sample number 1383 Sample No. 24 · 7 18.3 23.9 ---- ^ 38.1 2.0 1.0 _ 3.8 ------- ^ 1.0 As shown in Table 1E, when comparing comparative samples, according to the present invention to include boron nitride above Samples A and B coated with the pulp composition had fewer broken fibers and low friction. Example 2 A method similar to that discussed above was used to mix the ingredients in amounts described in Table 2A to form a size composition in accordance with the present invention G and S 'and comparative samples. In each composition, less than 1% by weight of acetic acid was included based on the total weight. Sizing compositions E and F 'and comparative sample Y of Table 2A were coated on G-75 E-glass fiber strands. Each sizing composition had 6 to 25% by weight solids.--VI-- ---- r --- Order --------- Line ί Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -117- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public love) 557286 A7 B7 V. Description of invention (ll5) Table 2A Based on the total solids content by weight% Sample composition G Η Comparative sample Υ EPON 826124 16.12 63.54 60.98 PVP K-30125 1.31 5.18 4.97 ALKAMULS EL-719126 1.63 6.44 6.18 IGEPAL CA-630127 1.63 6.44 6.18 KESSCO PEG 600128 0.79 3.11 2.98 A-187129 3.17 12.51 12.00 EMERY 6717130 0.40 1.56 1.50 PROTOLUBE HD131 0 0 4.61 POLARTHERMPT 160132 0 0 RELEASECOAT- 74.78 1.00 0 (Please read the Zhuyin on the back? Please fill in this page again) 124EPON 826, commercially available from Shell Chemical Company of Houston, Texas 0 Printed by PVP K-30 Polyvinylpyrrolidone in Intellectual Property Bureau Employee Consumer Cooperative, Ministry of Economy, commercially available from New Jersey Wayne's ISP Chemicals. 126 ALKAMULS EL_719 polyoxyethylated vegetable oil, commercially available from Rhone-Poulenc Company 127 IGEPAL CA-630 ethoxylated octylphenoxyethanol, commercially available from GAF Company, Wayne, New Jersey. 128 KESSCO PEG 600 polyethylene glycol monolaurate, commercially available from Stepan Company, Chicago, Erie #. • 118- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 557286 A7 B7. 5. Description of the invention (116) 129 Α-187 γ-water removal Glycerylpropyltrimethoxysilane, which is commercially available from CK Witco, Inc. of Tarrytown, New York, 0 13Q EMERY® 6717 Partially Aminated Polyethylene Diimide, and is commercially available from Cognis, Inc. of Cincinnati, Ohio. 131 PROTOLUBE HD high density polyethylene emulsion, commercially available from Sybron Chemicals, Birmingham, New Jersey. 132 POLARTHERM® PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. 133 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride particles in an aqueous dispersion, commercially available from ZYP Coatings, Oak Ridge, Tennessee. Each coated glass fiber strand is interlaced to form a yarn and wound on a bobbin in a similar manner using a conventional interlacing device. Samples F and Yarn showed minimal slurry shedding when interlaced, and samples E and G exhibited serious pulp shedding when interlaced. The air resistance of the yarns of Sample E-Η and Comparative Sample Υ was evaluated in a similar manner to Example 1 above, except that the air resistance 値 of the two bobbin samples was measured at the pressure shown in Table 2B. A Shirley 84 041L broken filament detector, commercially available from SDL International, UK, was used to evaluate the average number of broken filaments per 1200 meters of yarn at 200 meters per minute. These marks represent the average of the measurements made on the four spools of each yarn. Fractured filaments were reported from the entire spool (136 g (3/10 lb) and 272 g (6/10 lb) of yarn unwound from the spool). The brake tension of each yarn was also evaluated. The tests are described in Table 2B below. By using -119- this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1 -----; -------------- r --- order- -------- Thread (please read the precautions on the back before filling this page) 557286 A7 B7 V. Description of the invention (117) Untwist the yarn sample from the bobbin at 200 m / min, and pass the yarn spiral through a series of 8 Two parallel ceramic needles, and passing the yarn through the Shirley broken filament detector discussed above to calculate the number of broken filaments, and measure the number of broken filaments according to the brake tension method ° --- ·; ---.---- ------ l · --- Order --------- Line · (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -120- This Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557286 A7 B7 V. Description of invention (118) Table 2B printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs per sample of broken filaments per meter of yarn EFG Η Comparative samples Υ All spools 0.887 0.241 greater than 10 0.065 0.192 136 grams (3/10 pounds) 0.856 0.017 greater than 10 0.013 0.320 272 grams (3/10 pounds) 0〇676 0.030 greater than 10 0.101 0 Λ92 Gate tension (rounds per meter) Gate 2 0.039 0.0235 0.721 Gate 3 _ 0.025 _ 0.028 0.571 Gate 4 0.0125-0.068 0.4795 Gate 5 0.015 0.093 0.85 Gate 6-0.0265-0.118 0.993 Gate 7-0.0695-0.31 1.0835 Gate 8 0.117 0.557 1.81 Air resistance (grams) 25 psi spool 1 10.420 10.860 11.610 spool 2 10.600-7.850 11.610 30 psi spool 1 11.690 12.500 13.680 spool 2 12.200 8.540 13.850 35 psi spool 1 13.490 14.030 15.880 spool 2-13.530-9.570 15.630 40 psi spool 1-14.740 Clear 14.110 17.560 Spool 2 14.860-11.010 17.610 45 psi Spool 1 16.180-16.390 19.830 Spool 2 16.680 12.700 18.950 50 psi Spool 1 17.510 Sun 19.280 22.410 Spool 2 17.730-14.000 20.310 55 psi Spool 1-19.570-23.350 29.350 Spool Axis 2 19.660 20.250 26.580 This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) • 121- ------------------- r --- Order --------- line i ^ w. (Please read the notes on the back before filling this page) 557286 A7 V. Description of the invention (119) Although The test results shown in Table 2B clearly show that the sample E-Η according to the present invention has approximately higher abrasion resistance than the comparative sample γ. It is believed that these fruits are not deterministic because it is believed that the comparative sample ¥ Ethylene emulsion ^ (not present in sample E_H) contributes to the abrasive properties of the yarn. iiLi mixes the ingredients in the amounts described in Table 3A to form the aqueous sizing compositions K to N according to the present invention. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 3A was applied to 2G-18 E_glass fiber strands. Each sizing-forming composition has 10% by weight solids. ----.-------------- r --- order --------- line (please read the notes on the back before filling this page) Printed by the Bureau of Property and Consumer Cooperatives -122- This paper size is applicable to the Chinese National Standard (CNS) A4 (21 × 297 mm) 557286 A7 B7 V. Description of the invention (121) at 270 ° C at 7 MPa (975 psi ) Extrusion molding for 48 seconds to make a 254 X 254 X 3.175 mm (10 X 10 X 0.125 inch) board. Each sample was evaluated at the glass content specified below: tensile strength, tensile elongation, and tensile modulus in accordance with ASTM method D-638; flexible strength and functional modulus in accordance with ASTM method D-790; and in accordance with ASTM method D- Notched and unnotched Izod impact strength of 256. Table 3B presents the results of tests performed on composites formed using conventional nylon 6,6 matrix resins. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 124- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 A7 B7 V. Invention Explanation (122) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 3B Sample unit KLMN Comparative sample Z Tensile strength kpsi 27.1 27.6 27.3 27.4 MPa 186.9 190.34 188.27 188.96 180.68 Tensile elongation 3.32 3.37 3.36 3.42 3.32 Tensile modulus mpsi 1.48 1.55 1.47 1.44 1.51 GPa 10.2 10.7 10.1 9.9 10.4 Flexural strength kpsi 44.6 46.3 45.7 45.5 44.0 MPa 307.6 319.3 315.2 313.8 303.4 Flexible modulus mpsi 1.52 1.56 1.54 1.54 1.5 GPa 10.5 10.7 10.6 10.6 10.6 Notched Izod impact ftlb / in 1.86 2.24 2.24 1.94 1.63 1.16 kJ / m2 7.89 9.50 8.23 6.91 4.92 Unnotched Izod impact ft lb / in 21.8 22.9 21.1 20.5 22.0 kJ / m2 92.43 97.10 89.46 86.92 93.28 Glass content_% 32.9 32.6 32.4 32.3 32.4 As shown in Table 3B, in comparison Comparative samples with similar composition (which is,- When the reinforcement does not contain boron nitride, the glass-breaking fiber strand (sample KN) coated with boron nitride particles according to the present invention exhibits improved tensile strength and notched Izod impact properties, and similar tensile elongation and modulus. , Flexible strength and modulus, and notched Izod impact properties. When using nylon resin under similar conditions to evaluate, no change in tensile strength and notched Izod impact properties 6 was observed (please read the note on the back? Matters before filling out this page) ^ Paper size suitable financial item-⑽ -125 -X 29 "mm" — 557286 A7 B7 V. Description of the Invention (l23) Example 4 (Please read the notes on the back before filling out this page) Mix the ingredients in the amounts described in Table 4A to form the product according to the invention The aqueous forming sizing compositions P to S. Each aqueous forming sizing composition was prepared in a manner similar to that discussed above. Included in each composition was acetic acid based on the total weight of less than 1% by weight. The sizing compositions were coated on G-31 E-glass fiber strands. Each sizing composition had a solids content of 10% by weight.

Table 4A Ingredients% by weight based on total solids Sample composition P QRS Thermoplastic polyurethane film-forming polymer 137 23 28.75 28.75 23 Thermoplastic polyurethane film-forming polymer 138 34.45 43.1 43.1 34.45 Polyoxyalkylene Polyol copolymer 0.22 0.27 0.27 0.22 Epoxidized polyester lubricant 4.8 6.0 6.0 4.8 γ-aminopropyltriethoxy petrolatum coupling agent 1.84 2.3 2.3 1.84 γ · cholylpropyl triethoxy petrolatum coupling agent 2.22 2.78 2.78 2.22 Amine-functional organosilane coupling agent 0.1 0.12 0.12 0.1 POLARTHERMPT 160 139 33.3 16.7 0 0 Printed by the Consumer Property Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs 137 thermoplastic polyester-based polyurethane emulsion, which has 65 % Solids, anionic particle charge, particle size of about 2 microns, pH of 7.5, and viscosity of 400 centipoise at 25 ° C (Brookfield LVF). 138 thermoplastic polyester-based polyurethane aqueous emulsion, which has 62% solids, a pH of about 10, and granules ranging from about 0.8 to about 2.5 microns -126- This paper size applies to Chinese National Standards (CNS) A4 size (210 X 297 mm)

557286 5. Description of the invention (125) Abrasive material (ground walnut bark particles No. 6/10, which is commercially available from Hammon Products), and the conventional foam-type antistatic desiccant sheet are enclosed in a 4 liter stainless steel beaker, And use Red Devil paint shaker Model 5400E3 for 6 minutes. Use No. 5 and No. 6 American standard test sieve to select the vibrating material. The following reports the weight% of fine wool material collected on the screen as a percentage of the original sample. Table 4B presents the results of tests performed on composites formed using Samples P-S and Comparative Samples z using a 6,6 matrix resin. --- 1 ------------------ Order --------- line (Please read the notes on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by Bureau Consumers Cooperative

557286 A7 B7 V. Description of the Invention (ιπ) Example 5 The ingredients in the amounts described in Table 5 were mixed to form the aqueous sizing compositions T and U according to the present invention. Each aqueous sizing composition is prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Table 5 A proposes whitening and yellowing tests on composites formed using nylon 6,6 matrix resin using samples T, U and comparative samples Z (as discussed in Table 3A of Example 3 and repeated below) result. The color test was performed on a compound having a thickness of 3.175 mm (1/8 inch) and a diameter of 76.2 mm (3 inch) using a Hunter colorimeter D25-PC2A. (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employee Consumption Cooperatives Table 5 Based on the total solids content% by weight Sample composition T U Comparative sample Z Thermoplastic polyurethane film formation polymerization 141 31.35 28.75 34.5 Thermoplastic polyurethane film-forming polymer 142 46.9 43.1 51.7 Polyoxyalkylene polyol copolymer 0.3 0.27 0.3 Epoxidized polyester lubricant 6.55 6.0 7.22 γ-aminopropyltriethoxy Glycosane coupling agent 2.5 2.3 2.76 γ-lunyl propyl triethoxy stone cocoon coupling agent 3.0 2.78 3.34 Amine functional organosilane coupling agent 0.1 0.12 0.14 RELEASECOAT-CONC 25143 9.1 16.7 0 Whitening index -16.3 -15.0 -20.7 Yellowing index 39.3 38.1 42.7 -130- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 Α7 Β7 V. Description of the invention (128) 141 thermoplastic polyester based polyurethane aqueous emulsion, which has 65% solids, anionic particle charge, particle size of about 2 microns, pH of 7.5, and 25 ° C, a viscosity of 400 centipoise (Brookfield LVF). The I42 thermoplastic polyester is a main polyurethane aqueous emulsion having a solids content of 62%, a pH of about 10, and a particle size ranging from about 0.8 to about 2.5 microns. 143 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 boron nitride particles in an aqueous dispersion are available from ZYP Coatings (Oak Ridge. Tennessee). As shown in Table 5, samples T and U, each of which was coated with a boron nitride-containing particle size composition according to the present invention, had similar formulations in nylon 6,6 than comparative sample Z (which does not include nitrogen Boron) low whitening index. Example 6 A five-ply ADFLO-C ™ needle-like chopped glass fiber web, commercially available from PPG Industries, to form a web having a surface weight of 4,614 grams per square meter (about 15 ounces per square inch). The thickness of each sample was 25 mm (about 1 inch). Four 8-inch square samples of this mesh were heated to a temperature of 649 ° C (about 1200 ° F) to remove essentially all sizing components from the sample. Two uncoated samples were used as comparative samples ("comparative samples"). The other 2 samples (Sample X '') were immersed in 1150 ml of ORPAC BORON NITRIDE RELEASECOAT-CONC (a dispersion of 25% by weight of boron nitride particles in water) and 150 ml of A-187γ-dehydrated glycerol Propyltrimethoxy stone yakaya in a 5% by weight aqueous solution of an aqueous coating composition bath -131- This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) ---.---- ---------- r --- Order --------- line (please read the note on the back? Matters before filling out this page) 557286 A7 B7 V. Description of the invention (129) ( Please read the notes on the back before filling out this page) and saturated. The total solids of the aqueous coating composition was 18.5% by weight. The amount of boron nitride particles coated on each mesh sample was 120 g. The coated mesh samples were dried in air at 25 ° C overnight and heated in an oven at 150 ° C for 3 hours. According to ASTM method C-177, which is specifically incorporated herein by reference, the thermal conductivity and heat resistance of each group of samples at a temperature of 300K (about 70 ° F) were evaluated. The thermal conductivity and heat resistance of each sample are described in Table 6 below. Table 6 Sample X Comparative sample thickness (忖) 1.09 1.0 (cm) 2.77 2.54 Temperature (° F) 75.62 74.14 (° C) 24.23 23.41 Thermal conductivity square foot per hour ° Fibtu inches 0.373 0.282 Watts per meter K 0.054 0.041 Heat resistance square feet per BTU 2.92 3.66 square meters per watt K 0.515 0.626 Reference Table 6 printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the test samples for coating boron nitride particles according to the present invention are at 300K The thermal conductivity at temperature is greater than the thermal conductivity of a comparative sample that is not coated with nitriding shed particles. -132- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the invention (130) Example 7 A G-75 yarn of size G and a sample of 1062 glass fiber yarn commercially available from PPG Industries were used to prepare a cylindrical composite of wound filaments. A cylinder was prepared by extracting 8 yarn ends from a yarn supply, coating the yarn with a matrix material described below, and winding the yarn filaments into a cylindrical shape using a conventional filament winding device. Each cylinder is 12.7 cm (5 inches) tall, has an inner diameter of 14.6 cm (5.75 inches), and a wall thickness of 0.635 cm (0.25 inches). The matrix material was 100 parts of EPON 800 resin (commercially available from Shell Chemical, Houston, Texas), 80 parts of AC-220J methyltetrahydroacetic anhydride (commercially available from Anhydrides and Chemicals, Newark, New Jersey), and 1 part mixture of ARALDITE® DY 062 benzyldimethylamine accelerator (commercially available from Ciba-Geigy). The filament winding cylinder was hardened at 100 ° C for 2 hours and then at 150 ° C for 3 hours. The radial direction of each test sample in the air was measured by exposing one side of the cylinder wall of the sample to a 6.4 ShJ flash, and using a CCD array infrared camera to detect temperature changes on the opposite side at a rate of 2000 frames per second. Thermal diffusivity (thermal conductivity / (heat capacity X density)). The thermal diffusivity 値 is also measured along the length (circle) of the yarn and along the length or height (axial) of the cylinder. The test results are described in Table 7 below. -133- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---, -------------- r --- order ----- ---- Line (please read the notes on the back before filling this page) 557286 A7 V. Description of the invention (m)

Referring to Table 7, the thermal diffusivity of the test sample (which is coated with a small amount of the nitrided side) is smaller than that of the uncoated boron nitride comparative sample. Air holes in the filament winding cylinder and small test sample area are factors that affect these results. Example 8 Laminates of type 7628 fabrics prepared from samples containing 8 layers of B_coated yarn (discussed in Example i) and starch / oil-coated yarn (discussed in Example 1) (control) Sample, and evaluate the thermal expansion coefficient (&quot; Z-CTE ',) in the direction of the laminate (ie, across the thickness of the laminate). The laminate was prepared using FR-4 oxycoated resin as discussed in Example 1 and was specifically incorporated herein by reference in accordance with the IPC test method 2.4.41 ', with a copper finish. The thermal expansion coefficient of each laminate sample in the zeta-direction of 288 t was evaluated according to the IPC test method 2.4.41. The evaluation results are shown in Table 8 below. ---''--------- 11--r I--order --- ml-- i ^ w. (Please read the precautions on the back before filling out this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative -134 · This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

V. Description of the invention (132) As shown in Table 8, for the laminate according to the present invention, mouth LeA3, the laminate &lt; z-universal thermal expansion coefficient is less than the control made from 695 starch still / coated yarn Samples 1 and 2. Example 9 The ingredients are mixed in the amounts described in Table 9A to form a first aqueous sizing composition AA, BB and CC according to the present invention. Each aqueous first polymerization composition was prepared in a manner similar to that discussed above. Acetic acid is included in each composition at less than 1% by weight based on the total weight. Each of the aqueous sizing compositions of Table 9A was coated on G-75 E-glass fiber strands. Each coated fiber strand was dried, interlaced in a similar manner using conventional interlacing equipment to form a yarn, and wound on a bobbin. The sizing composition-coated yarns exhibited minimal slipping when interlaced. -135- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --- ^ --------------: ---- Order ---- ----- Line (please read the precautions on the back before filling this page) 557286 A7B7 V. Description of the invention (133) Table 9A Based on the total solid content by weight% Sample composition AA BB CC PVP K-30144 14.7 14.7 13.4 STEPANTEX 653145 30.0 29.9 27.3 Α187146 1.8 1.8 1.6 Α_174147 3.7 3.7 3.3 EMERY 6717148 2.4 2.4 2.2 MACOL OP-10149 1.6 1.6 1.5 TMAZ-81150 3.3 3.3 3.0 MAZUDF-136151 0.2 0.2 0.2 ROPAQUE HP-1055152 0 42.4 0 ROPAQUE OP-96153 42.3 0 38.6 REKEASECIAT-CONC 25154 0 0 6.3 POLARTHERMPT 160155 0 0 2.6 (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 144 PVP K-30 polyvinylpyrrolidone, which Commercially available from ISP Chemicals Corporation 0 145 STEPANTEX 653, Wayne, New Jersey, commercially available from Stepan Corporation, Maywood, New Jersey. 146 A-187 Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York. 147 Α-174 γ-methylpropionyloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 -136- This paper is sized to the Chinese National Standard (CNS) A4 (210 χ 297) (Mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the invention (134) 148 EMERY® 6717 Partially aminated poly (ethylene diimide), commercially available from Cognis, Inc. of Cincinnati, Ohio. 149 MACOL OP-10 ethoxylated alkylphenol; this material is similar to MACOL OP-10 SP, except that MACOL OP-10 SP is subjected to post-treatment to remove the catalyst; MACOL OP-10 is no longer commercially available. 15G TMAZ-81 Anisocyanate derivative of anisocyanate, commercially available from BASF, Parsippany, New Jersey 0 151 MAZU DF-136 antifoam, commercially available from BASF, Parsippany, New Jersey . 152ROPAQUE® HP-1055, a 1.0 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 153ROPAQUE® OP · 96, 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 154 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, commercially available from ZYP Coatings, Oak Ridge, Tennessee. 155POLARTHERM ™ PT 160 boron nitride powder granules, commercially available from Advanced Ceramics, Lakewood, Ohio. When using a Sulzer Ruti Model 5200 air jet loom to weave a Model 7628 fabric, various sizing compositions (AA, BB With CC) sizing yarn as filling yarn. Interlaced G-75 E-glass fiber strands 156 coated with different resin-compatible sizing compositions for the fibers. The fabric was then pre-impregnated with a FR-4 epoxy resin (codename 4000-2 resin from Nelco International, Inc., Anaheim, CA) with a Tg of 140 X :. The sizing composition was not removed from the fabric before prepreg. By stacking 8 layers of prepreg between 2 layers of 1 ounce copper, and -137- this paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------- -------- r --- order --------- line (please read the precautions on the back before filling this page) 557286 A7 B7 V. Invention Description (135) (Please read first Note on the back, fill in this page again) Laminate them together at a temperature of 355 ° F (approximately 179 ° C) at a pressure of 300 pounds per square inch (approximately 2.1 million bska) (Total cycle time) and a laminate is prepared. The thickness of the laminate without copper ranges from 0.043 inches (about 0.11 cm) to 0.050 inches (about 0.13 cm). After formation, the laminate was tested as shown in Table 9B below (the fiber strands from which it is made are referred to as AA, BB, and CC). At the time of the test, when the first laminate made of glass fiber yarn was coated with a sizing composition sample AAA (hereinafter referred to as a laminate sample AAA1), the laminate KB was simultaneously tested. Later, when the second laminate made of glass fiber yarn was coated with a sizing composition sample CC (hereinafter referred to as laminate sample AAA2), the laminate CC was simultaneously tested. Table 9B Laminate sample test unit AA11 BB1 AA22 CC2 average thickness inch 0.048 0.048 0.053-0.055 0.053-0.055 solder float seconds 409 386 235 253 solder immersion seconds 320 203 243 242 flexural strength warp yarn direction 157 kpsi 99 102 91 90 Flexural weft direction 158 kpsi 86 81 73 72 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 Based on 2 samples. 2 Based on 3 samples. 156 This warp yarn is a commercially available fiberglass yarn product of PPG Industries, code G-75 glass fiber yarn, which is coated with a PPG Industries adhesive. 157 Per IPC-TM-650 &quot; Flexural Strength of Laminates (At Ambient -138-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (136)

Temperature) ", 12/94, Revised Version B. 158 Same chapter. By floating 4 inches by 4 inches square (10.6 cm by ι 16 cm) of copper finish laminate at 550 T (Approximately 288. 0 in the eutectic lead · tin solder bath 'until a blistering or separation is observed, a solder float test is performed. Then the time in seconds until the first blistering or separation is recorded. By cutting the laminate For the sample, remove copper from the sample by etching, smooth the cut edge of the sample by polishing, and place the sample in a pressure cooker at 250 (about 121 X :) and 15 pounds per square inch (about 0.1 million Baska). After 60 minutes, the solder immersion test was performed. This test is the pressure cooker test described in the table below. After 60 minutes of exposure, the sample was removed from the pressure cooker, patted dry and immersed in 55F (about 288 C) eutectic lead. -In a solder bath until foaming or separation is observed. Then record the time in seconds until the first foaming or separation. Flexibility test is performed according to the IPC standard shown. Use each of the above slurry compositions AA, BB and Laminates AA, BB, and CC made of fiber strands on CC are used as printed circuit boards Acceptable properties of electronic supports (as shown in Table 9B). The following tests were also performed on samples AA, BB and CC, and are described in Table 9C 〇, ^ I ----- r --- order --- ------ Line (Please read the precautions on the back before filling this page) -139- 557286 A7 V. Description of the invention (137) Sample test unit AA BB CC Tg by DSC 0/30/60 min ° C 141 / 140/139 140/141/141 138/140/139 Pressure cooker absorbs water 〇 / 〇0.37 037 0.38 Water resistance 159 Weight increase 0.12 0.09 0.09 DMF resistance weight increase ° / 〇0.35 0.27 0.29 MeC12 Antibiotic 16C} Weight increase 0.77 0.82 0.68 Copper peel strength 161 (warp / filled yarn) lbs 11.8 / 11.0 12.1 / 11.1 11.2 / 11.4 Adhesive strength between layers 102 102 每 12.8 14.2 15.4 (Please read the precautions on the back before filling this page) According to IPC-TM-650, No. 2 · 6 · 2 · 1, &quot; Water Absorption, Metal Clad Plastic Laminates &quot;, 5/86, Rev. A. 160 According to IPC-TM-650, No. 2.3.4.3. &Quot; Chemical Resistance of Core Materials to Methylene Chloride ,,, 5/86 ·

161 According to IPC-TM-650, No. 2.4.8, &quot; Peel Strength: As Received, After Thermal Stress, After Process Chemicals '', 1/86, Rev. B 0 Printed by Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs 162 In accordance with IPC-TM-650, No. 2.4.40, &quot; Inner Layer Bond Strength of Multilayer Printed Circuit Boards · ', 10/87 o Example 10 The ingredients in the amounts described in Table 10 were mixed to form a composition according to the present invention Aqueous sizing composition DD, EE and FF. Included in each composition is acetic acid based on the total weight of less than 0.5% by weight. -140- This paper size applies to China National Standard (CNS) A4 (210 X 297) %) 557286 A7B7 V. Description of the invention (138) Table 10 Based on the total solids content by weight% Sample composition DD EE FF PVP K-30163 12.3 11.7 12.3 STEPANTEX 653164 25.0 23.9 25.0 ΤΑΑ81165 3.5 3.9 2.7 MACOL ΟΡ-10166 1.8 2.0 1.4 POLARTHERMPT 160167 2.4 2.3 2.4 EMERY 6717168 2.0 2.0 2.0 A-174169 3.1 2.9 3.1 A-187170 1.5 1.4 1.5 RELEASECOAT-CONC 25171 5.7 5.5 5.6 MAZUDF-136172 0.2 0.2 0.2 ROPAQUE OP-96173 35.2 3 3.7 35.3 FLEXOL LOE174 7.3 10.5 0 FLEXOL EPO175 0 0 7.3 --- ^ -------------- ^ ---- order --------- line (please read first Note on the back, please fill in this page again.) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, 163PVP κ_30 polyethylpyrrolidone, commercially available from ISP Chemicals Company, Wayne, New Jersey, 0164STEPANTEX 653, commercially available from Stepan Company, Chicago, Illinois. 165TMAZ 81 Ethylene oxide derivative of anisocyanate, commercially available from BASF Corporation, Parsippany, New Jersey. 0 166 MACOL OP-10 ethoxylated phenol; this material is similar to MACOL OP- 10 -141- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 χ 297 mm) 557286 A7 B7 V. Description of the invention (139) SP, except for MACOL OP_10 SP which undergoes post-processing to remove catalyst; MACOL OP_10 does not Commercially available. (Please read the notes on the back before filling out this page.) 167POLARTHERM® PT 160 boron nitride powder particles are commercially available from Advanced Ceramics, Lakewood, Ohio. 168EMERY® 6717 partially fluorinated poly (ethylene diimide) is commercially available from Cognis Corporation of Cincinnati, Ohio. 1ό9Α-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 17GA-187 γ-dehydrated glycerylpropyltrimethoxysilane, commercially available from New York CK Witco Corporation of Tarrytown. 171ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 172 MAZU DF-136 P square foam, commercially available from BASF Corporation, Parsippany, New Jersey. 173ROPAQUE® OP-96, a 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 174FLEXOL LOE Epoxidized Linseed Oil, printed by 174FLEXOL LOE epoxidized linseed oil, commercially available from Union Carbide, Danbury, Connecticut. 175FLEXOL EPO epoxidized soybean oil, commercially available from Union Carbide, Danbury, Connecticut. Company 0 -142- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286

A7 V. Description of the invention (140) Table 10 (continued) Based on the total solids content% by weight Sample composition DD EE FF solids% by weight 3.4 3.5 3.4 LOI 0.42 0.39 0.30 The glass fiber is coated with each of the aqueous sizing compositions of Table 10 Formation of G_75E-glass fiber strands. Each coated glass fiber strand was dried, interwoven in a similar manner using a conventional interlacing device to form a yarn, and wound on a bobbin. The yarn of sample DD was evaluated by comparing this coated yarn with a yarn coated with a similar sample DD but without epoxidized linseed sizing composition (hereinafter referred to as "comparative sample i &quot;). This comparison Includes visual inspection of the appearance of Type 7628 fabric woven by air jet loom. The textile fabric uses sample DD as the filling yarn and interlaced G-75 E-glass fiber strand 170 coated with different resin compatible sizing compositions. As warp yarns. When comparing fabrics woven with the yarn coated with Comparative Sample 1, it was observed that the fabrics woven with the yarn coated with Sample DD showed less loose hairs on the fabric and collected at the contact points on the loom. Fewer fine hairs, especially in yarn accumulators. Because of the high starting amount of fine hairs observed on the loom, non-woven fabrics are woven using yarns with fibers coated with samples EE or FF. It is believed that this situation is better than The result is a low degree of LOI required to prevent excessive hair formation. In the present invention, it is expected that the sizing composition discussed above requires a LOI of at least 0.40 to reduce fine hair formation during weaving. 170 This warp yarn is a product of PPG Industries Commercially available Glass fiber yarn product, code G_75 glass fiber yarn, which is coated with -143- of PPG Industries. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). ---- l · I-- I ------- I l · I — I ^ --------- line (Please read the precautions on the back before filling out this page} Printed by the Intellectual Property Bureau Employee Consumer Cooperatives, Ministry of Economic Affairs 557286 A7 Explanation of the invention (142) AA3, AA4 and BB are 2.8% by weight solids. Sample CC is 3.1% by weight ° / 0 solids. Comparative sample 2 is 5.9% by weight solids. Consumer Cooperatives, Bureau of Intellectual Property, Ministry of Economic Affairs Printing ---- Xingkoukou Xing n Xing Q q Comparative air resistance compared to comparative sample 2 (starch / oil adhesive). In addition, when comparing volume with comparative sample 2, the comparison of samples ΑΑ, ΒΒ and CC Low friction especially indicates that the yarn is easier to remove from the loom accumulator when weaving. Example 12 The air resistance of samples AA, BB, and cc and comparative sample 2 was evaluated in a similar manner to that of Example η above, except as shown in Table 12. The pressure shown is used to measure the air resistance of the bobbin sample. Shirley 84 041L broken filament detector is also used. From the UK's SDL ―Fine 丨 嶋〗 company, the average number of broken filaments per 1200 meters of yarn per meter is evaluated in meters per minute (shown as Test 1 in Table 12). The broken fibers and filaments are made from silk cypress Spools after removing 227 grams of yarn and yarn spools after removing 4,540 grams (1G 碡) of yarn from the thread, part of the report obtained from all the spools. Further evaluation of each yarn's increasing tension and wear The number of broken filaments at the time (shown as Test 2 in Table 12). In 2, the yarn was unwound from the bobbin at 200 meters / minute, and the Chinese National Standard (CNS) was applied in the uniform tension control device __145. A4 &amp; (21〇X 297) f Please read the notes on the back before filling out this page} --------- tl --------- line. 557286 A7 V. Invention Explanation (⑷) (sometimes referred to as the brake tension device) is passed through a series of 8 ceramic needles in a serpentine shape and passed through the Shirley Rupture Filament Detector to calculate the number of broken filaments. Use different needle dial settings to change the needle interval on the tension device to provide different degrees of tension to the yarn. This particular test was made using a UTC_2003 tension device commercially available from Steel Heddle Corporation of South Carolina. Broken filaments are reported as the number of broken filaments per meter of yarn. The test results of samples AA, BB and CC and comparative sample 2 are described in Table 12 below. In a method similar to that discussed in Example n above, when the first portion of the glass fiber yarn coated sizing composition sample AA (hereinafter referred to as sample AA5) was tested at the same time, Sample BB and Comparative Sample 2 were tested at the same time. When the second portion of the glass fiber yarn coated sizing composition sample AA (hereinafter referred to as sample AA6), the sample cc was simultaneously tested. 146- The paper size is applicable _ Home Standard (CNS) A4 (210 X 297 public love) 557286 A7 B7 V. Description of the invention (144) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 12 Sample ΑΑ5 ΒΒ 2 ΑΑ6 CC Air Resistance (grams) 15psi 46.10 42.50 42.23 47.47 42.33 20 psi 56.20 51.20 52.94 58.84 53,18 25 psi 67.33 60.30 64.13 69.45 67.66 30 psi 77.34 70.84 75.74 75.29 75.29 77.63 35 psi 89.42 89.96 85.96 83.70 82.74 101.97 101.74 40.74 101. psi 113.41 107.74 110.34 99.91 102.91 Test 1 All spools 0.170 0.882 0.032 1.735 0.066 227 grams (0.5 pounds) 0.160 0.648 0.041 0.904 0.075 4540 grams (10 pounds) 0.098 1.348 0.008 0.518 0.022 Test 2 settings 2 0.683 5.017 0.119 0.372 0.011 settings 3 0.753 4.772 0.083 0.450 0.017 Setting 4 0.713 3.753 0.147 0.367 0.017 Setting 5 1.267 4.025 0.150 0.811 0.061 Setting 6 1.608 8.383 0.322 0.286 0.044 Setting 7 4.128 6.517 0.611 0.403 0.058 Setting 8 4.472 14.800 0.978 0.406 0.128 -147- (Please read the precautions on the back first fill (This page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 557286 A7 __ B7__ V. Description of the invention (146) 179DESMOPHEN 2000 Polyadipate Ethyl diol, which is commercially available from Bayer, Pittsburgh, PA 0-880ρνρ κ-30 polyvinylpyrrolidone, and is commercially available from ISP Chemicals, Wayne, New Jersey 0 181A-187 γ-dewater Glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 182A-174 γ-methacryloxypropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 Table 13A (continued) Composition sample HH PLURONIC F-108183 9.0 VERS AMID 140184 4.4 MACOL NP-6185 5.4 POLARTHERM PT 160186 0.9 RELEASECOAT-CONC 25187 1.5 Acetic acid &lt; 0.1 183PLURONIC ™ F-108 polyhydrogenated polyethylenic acid polymer Property, commercially available from BASF, Parsippany, New Jersey, 0 184 VERS AMID 140 polyamid, commercially available from Cognis, Cincinnati, Ohio, 185 MACOL NP-6 nonylphenol interface Active agent, commercially available from BASF Company 0 186POLARTHERM PT 160 boron nitride powder particles in Parsippany, New Jersey, commercially available from Advanced Ceramics Company, Lakewood, Ohio. -149- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --- ^ -------------- ^ ---- Order ---- ----- line &quot; ^^ · (Please read the precautions on the back before filling this page) 557286 A7 B7

II --------- tr ---------_ (Please read the precautions on the back before filling this page) 187 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron Nitride Dispersion 'It is A dispersion of about 25% by weight of boron nitride particles in water is commercially available from ZYP Coatings, Oak Ridge, Tennessee. The pre-infiltrated yarn was prepared by a hand product procedure, and the standard fr_4 epoxy resin (EPON 1120-A80 resin, available from Shell Chemical Company) was applied to the fabric by brush coating. The resin-saturated fabric was immediately dried in a 163 t (approximately 325 τ) oven with hot air &quot; drying &quot; and stage B until the desired gelation time at 171 ° C (approximately 340 ° F) was 124 seconds .Modify the pre-infiltrated yarn into 46 cm x 46 cm (18 inches x 18 inches) and weigh to determine the resin content. Only pre-infiltrated yarns with a resin content of 44 ± 2% can be used in subsequent lamination procedures. The pre-infiltrated yarn was stacked in 8 layers and molded in Wabash rolling of 177 x: (35〇τ) and 345 Newtons / cm 2 (50OpSi). All laminated boards were molded without copper foil The laminated board shows various air capture amounts. It is believed that this condition is beneficial in the absence of airspace and temperature changes during lamination. Tool wear analysis Performs the first series of tests to evaluate the wear of the drill. The wear of the drill is calculated using the following formula "Drill wear percentage": Drill wear percentage = 100 X where Pi = initial width of the first cutting edge

Pf-the width of the first cutting edge after drilling the distribution hole With reference to FIG. 11, the width 1117 of the first cutting edge 1172 of the drill 1174 is measured around the edge of the drill. Use a single-head drill to drill copper. Drilling holes in the range of 0 · 203mm-150 · • This paper size is applicable ® Family Standard (CNS) A4 specification (il0χ 297 public shame "557286 A7 V. Description of the invention (l48) (Please read the note on the back first Please fill in this page again) (0.008 inches) thick aluminum inlet and L88 € m (0 074 inches) thick paper cores are implemented on a high stack of 3 laminates (discussed above) coated with phenol. Bit abrasion of drill bit diameter%: 0.35 mm (0.0138 inches) and 0.46 mm (0.018 inches). Both drill bits are 508 series tungsten carbide drill bits from Tulon Company of California. The plate load when drilling a hole is different from each tool. The "plate load" used here means that the drill bit insertion rate is measured in inches per minute and the number of turns per minute is less than 1) Measured mandrel speed ratio. For a 35 mm drill bit, the mandrel speed is 100,000 rpm and the insertion rate is 100 inches (254 cm) per minute. For a 0.46 mm drill bit, the mandrel speed is 80,000. 〇rpm and insertion rate is 80 inches per minute (203 cm). Keep the tool diameter constant The drill bit limit is above a contraction rate of 2.54 meters (1000 inches) per minute and 165 mm (0065 inches). Used here, the drill bit limit, means to withdraw the drill on the upper surface of the laminate * The distance of the head is determined based on the 500-hole drilling pattern shown in Figure 12. The drill bit abrasion% includes 391 stamps printed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs at 0.635 cm by 10.16 cm (0 25 inches by 4 inches). Production area (Shaofen 1280) drilled holes 'then 100 holes in the 丨 〇 by 丨 0 hole pattern (Shao 1282)' and then 9 holes in the 3 by 3 hole pattern (part 1284) Holes. The holes in each Shaofen were drilled at a density of 62 holes per square centimeter (400 holes per square inch). The pattern was repeated three more times for a total of 2000 holes. Uniline 2000 single-head drilling machine Drilling holes for Tests 1 and 2 and drilling holes for Test 3 using a CNC-7 single-head drilling machine. Both machines were obtained from Esterline Technologies, Bellevue, Washington. -151- This paper size applies to Chinese national standards ( CNS) A4 size (210 X 297 mm) 6- 8 72 Wisdom of the Ministry of Economic Affairs Printed by the Consumer Bureau of the Production Bureau A7 ______________ Description of the invention (l49) Table 13B shows tf 〇35 and 〇46 mm diameter drill bits in the pattern discussed above for the control GG and the sample after boring 2000 holes in% Each test starts with a new drill cone. Table 13B Control GG sample ΗΗ Test 1 Number of tools 3 3 0 · 35 mm diameter drill bit average wear of the drill 28.8 22.2 Test 2 Number of tools 20 20 0 · 46 mm diameter drill bit wear of the average drill 3% 24.4 Test 3 Number of tools 10 10 0.46 mm diameter drill bit average drill wear% 30.8 29.3 As seen in Table 13B, the samples ηη of tests 1 and 2 (which includes coatings shown here with the laminate matrix resin phase The glass fiber filaments of the above size) after 2000 holes showed a much smaller wear of the drill than the control GG (which includes glass fiber filaments that must be thermally cleared before coating with a size-adjusted upper size slurry). Test 3 showed wear on the bit. / ❶ There are only minor improvements, but it is believed to be due to the older CNC-7 drilling rig used for this test, and it provides less drilling test than the Uniline 2000 drilling rig used for tests 1 and 2. Caused by facts of control. Location Correctness A common matrix used to evaluate the drilling performance of laminates is hole location accuracy. This test measures the deviation of the actual hole position from its intended position. This measurement is taken from the lower surface of the laminate under the three laminate stacks, and the drill bit leaves the laminate stack because it is expected that the location of this hole is from the intended or "眞 正" hole -152- This paper size is applicable to the country of China Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling out this page)-I I--Order-丨! Ί! 557286 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs System A7 _B7_____ V. Description of the invention (150) The position has the largest difference. This difference is evaluated by "deviation distance", that is, the actual center of the hole drilled on the surface of the laminate to the center of the hole's intended center Distance. The error distance was measured after the 500 hole sequence discussed above was repeated 4 times, that is, after each tool drilled a total of 2000 holes. The deviation distance was measured on the last drilled 100 hole pattern, that is, the last drilled portion 582. Use the 0.46 mm (0.018 inch) diameter 508 series bores from Tulon Corporation discussed above. As used in the tool abrasion test, the spindle speed of the drill was 80,000 rpm and the insertion rate was 80 inches per minute for a plate load of o.ooi. The test was repeated 8 times for each control GG and sample HH, and each test was started with a new drill. Table 13C shows the results of the position accuracy test of the control GG and the sample HH after 2,000 holes were drilled.

Table 13C Control GG sample 次数 Number of holes 8 8 Average deviation distance (micron) 38 28 As you can see, the sample HH exhibits a lower deviation distance than the control GG. It uses a laminate as an electron that adds a large number of holes and circuits. This is particularly important when supporting a body. It is consistent with the drill wear ❶ / ❶ data shown in Table 13B above. More specifically, it is expected that laminates exhibiting a lower bit wear% will also exhibit smaller bias distances' because after a large number of holes, the bit is sharper. Examples. In Example 14, another drill wear percentage test was performed. Test electronic-grade laminate comparison; j and the employment-added fabric product as described above _____ _153_ This paper size is applicable to China National Standard (CNS) A4 (21〇χ 297 mm) —''---- ---------- ^ ---- Order 丨 ———— line i ^ w. (Please read the notes on the back before filling out this page) 557286 A7 B7 V. Description of the invention (151) AA, Wear of BB and KK drills. The fabric in Control JJ was a 7628-718 fabric available from Clark_Schwebel. The fabrics in samples AA, BB, and KK were filled with glass fibers containing resin-compatible sizing as shown in Table 9A and Table 14 below for each coating example 9, and compatible with coatings with different polymeric matrix materials Warp spinning of glass fiber of coating composition 188. 188 This warp yarn is a commercially available fiberglass yarn product of PPG Industries, code G_75 glass fiber yarn, which is coated with an adhesive from PPG Industries. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -154- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 Intellectual Property of the Ministry of Economic Affairs A7 B7 printed by the Bureau's Consumer Cooperatives V. Invention Description (152)

Table 14A Ingredient weight% based on total solids of the slurry used for sample KK Sample ingredients KK PVP K-30189 13.4 A-187190 1.9 A-174191 3 · 8 EMERY 6717192 1.9 SAG 10193 0.2 RELEASECOAT- CONC 25194 3.8 POLARTHERM PT 160195 5.9 RD-847A196 23.0 DESMOPHEN 2000197 31.0 PLURONIC F-108198 8.4 ALKAMULS EL-7191 &quot; 2.5 ICONOL NP-6200 4.2 LOI (%) 0.35 189 PVP K-30 polyvinylpyrrolidone, which is commercially available ISP Chemicals, Inc., Wayne, New Jersey 0 19GA-187 γ-desglycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 191A-174 γ-methylpropanyloxypropane Trimethoxysilane, which is commercially available from -155- --- ^ ---------- r --- order --------- line-. ^ W (Please read the note 2 on the back before filling in this page) X 10 (2 grid rule A4 dark (C quasi standard home country secret rule paper 297 mm) 557286 A7 Β7 V. Description of the invention (157) Example 15 (Please read the notes on the back before filling out this page) The samples in Table 15 below represent additional aspects of the invention Specific examples. The coating sample LL is manufactured but not tested. The coating sample MM_QQ has not been manufactured. Table 15 Composition weight% based on total solids Sample composition LL MM NN 00 PP QQ POLYOX WSR301201 0.56 0.55 0.61 0.43 0.47 0.34 A_174202 3.68 4.31 4.74 3.32 3.68 2.61 A-187203 1.74 2.08 2.29 1.60 1.78 1.26 DYNAKOLL SI ΙΟ204 204.60 26.58-20.46-16.08 SERMULEN668205 3.33-_ _ DESMOPHEN 2000206 40.58 39.93 43.92 30.75 34.14 24.15 SYNPERONIC F-108207 9.98-_6.00-6.00-4.6-6.00-6.00 140209 4.43-PLURONIC F-108210-9.83 10.81 7.56 8.40 5.94 MACOL NP-6211-3.28 3.60 2.52 2.80 1.98 VERSAMED 140212-4.36 4.80 3.36 3.73 2.64 201POLYOX WSR 301 Poly (ethylene oxide), commercially available from Connecticut Union Carbide Corporation of Danbury ° Printed 2G2A-174 γ-methacryloxypropyltrimethoxysilane produced by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy, commercially available from CK Witco, Tarrytown, New York. 2G3A_187 γ-dehydrated glycerylpropyltrimethoxysilane, which is commercially available from New-160- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 A7 B7 V. Description of the invention (158 ) CK Witco, Tarrytown, Ill. (Please read the notes on the back before filling this page) 2G4DYNAKOLL SI 100 turpentine, which is commercially available from Eka Chemicals AB, Sweden. 205SERMUL EN 668 ethoxylated nonylphenol, commercially available from CON ΒΕΑ, Benelux ° 2G6DESMOPHEN 2000 polyethylene adipate glycol, commercially available from Bayer, Pittsburgh, PA. 2G7SYNPERONIC F-108 polyoxypropylene-polyethylene oxide copolymer, which is the European counterpart of PLURONIC F-108. 2G8POLARTHERM PT 160 boron nitride powder particles are commercially available from Advanced Ceramics Corporation of Lakewood, Ohio. 2G9EUREDUR 140 is a polyamide resin commercially available from Ciba Geigy, Belgium, 21 GLURONIC F-108 polyoxypropylene-polyethylene oxide copolymer, and commercially available from BASF, Parsippany, New Jersey. 211MACOL NP-6 nonanol surfactant, commercially available from BASF Corporation, Parsippany, New Jersey. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economy, 212VERSAMID 140 Polyamide, which is commercially available from Cognis, Inc. of Cincinnati, Ohio ° -161- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 A7 B7 V. Description of the invention (l59) Table 15 (continued) Based on the total solids content by weight% Sample composition LL MM NN 00 PP QQ RELEASECOAT-CONC 25213 3.64 3.63-4.00 4.00 ROPAQUE OP-96214-29.23 30.00 35.00 35.00 In the coating Estimated% solids 5.4 5.6 5.1 7.3 6.5 9.3 213 ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron Nitride Dispersion, which is a dispersion of approximately 25% by weight of boron nitride particles in water, commercially available from ZYP Coatings, Oak Ridge, Tennessee the company. 214ROPAQUE® OP-96, a 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. Example 16 An unprotected laminate was prepared using the materials and methods described in Example 9, except that copper was not used in the lamination. Each unfaced laminate was then cut into 52 1-inch X 1 / 2-inch (about 2.54 cm x about 1.27 cm) rectangular pieces. About half of the pieces are cut parallel to the warp direction, and about half of the pieces are cut parallel to the filling direction. Then, 26 rectangles (13 parallel warp direction cuts and 13 parallel fill direction cuts) obtained from each laminate were placed in a water recirculation device and the water was boiled. Boil water for 24 hours. After 24 hours, the tablets were removed from water and wiped dry. The remaining 26 tablets from each laminate did not boil. An unprotected control laminate made from the conventional heat-clearing and trimming fabric was also manufactured in the same manner as the test laminate as in Example 9 above, and tested in accordance with the above steps. -162- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page) ------ ^ ---- Order-- ------- Line · Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (m) Then measure the stagnation according to ASTM D 2344-84 And unshear strength. The test results are shown in Table 9, where the uncovered samples BB and CC correspond to laminates made using fabrics (described in Example 9) each having fibers sized above the composition MU. As discussed above, the control samples were made using conventional heat removal and conditioning fabrics. The thickness of the test laminates (unfaced samples AA, BB, and cc) ranged from 0.050 cm (about 0.127 cm) to 0.063 cm (about 0 cm). In the test, the ratio of the span length to the thickness of the sample was 5. -163- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 A7 B7 V. Description of the invention (⑹) Table 16 Test unit AA BB CC Control Short beam shear strength, not broken per square inch 7787 8477 7769 7382 Boiling warp yarn direction (million basca) (54) (56) (54) (51) Sample thickness N = 13 Inches 0.060 0.050 0.056 0.055 (cm) (0.152) (0.127) (0.142) (0.140) Short beam shear strength, not pounds per square inch 6626 7594 7118 5506 Number of boiling filling yarn directions (million basca) (46) (52 ) (49) (38) Sample thickness N = 13 inches 0.061 0.050 0.060 0.055 (cm) (0.155) (0.127) (0.152) (0.140) Short beam shear strength 24 碡 5695 6522 5081 4929 hours per square inch Number of boiling warp threads (million basca) (39) (45) (35) (34) Sample thickness N = 13 inches 0.061 0.051 0.057 0.057 (cm) (0.155) (0.130) (0.145) (0.145) short Beam Shear Strength 24 pounds per square inch 5266 5832 5179 4116 hours boiling filling direction (million basca) (36) (40) (36) (28) Sample thickness N = 13 inches 0.063 0.051 0.062 0.056 (cm) (0.160) (0.130) (0.157) (0.142) In this test, the test laminate (unprotected For the surface samples AA, BB and CC), the short beam shear strength in the warp and weft directions was observed to be higher than that of the control sample before and after water boiling. Example 17 A gauze made from E · glass fiber strands coated with the sizing composition CC shown in Table 9A of Example 9 was applied, and 1383 Commercial-164 by PPG Industries was used. This paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) —: --------------: ---- Order --------- line i ^ w. (Please read the first Note: Please fill in this page again.) 557286 A7 B7 V. Description of the invention (l62) The warp yarns made from fiberglass yarn products can be woven with air jet loom into 7628 type fabric. The fabric is then prepreged and laminated to form a copper facing laminate, as described in Example 9 above. The copper finish laminate CC (as described in Example 9 above) was then processed (i.e., drilled, plated, and patterned) into a test plate with multiple test patterns to test metal migration performance. More specifically, each board includes three groups of seven-layer circuit patterns 1310, as shown in FIG. One set of patterns is oriented along the X-axis of the board ', the other set is along the Y-axis of the board, and the third set is across 45 of the board. . Each circuit pattern 1310 includes 50 rows of five drill holes 1312, each of which has a diameter of 13.5 mil, and the center-to-center spacing between adjacent rows of holes ranging from 40 to 54.7 mil. When drilling these holes, the two plates are stacked together so that they are drilled in a single drilling operation. The staggered rows of holes in each pattern are interconnected along the first major surface of the board by bus bars 1314 and leads 1316, as shown in FIG. Solder leads to each bus to connect to a power source. Each circuit also includes 1K ohm surface resistance 1322 to ensure that if one circuit board is damaged, power to the remaining circuits is maintained. Immerse each plate in 76.7 ° C (170 T) deionized water for 10 minutes to remove any solder flux residue and dry. The plate was then placed in a tank at 85 C (185 ° F) and 85% relative humidity, and a DC current of 13.5 volts was continuously applied to the pattern. Close the slot every 200 hours, open the slot door to stabilize the pattern to the surrounding laboratory temperature, and measure the insulation resistance of each pattern. There are two sample CCs and two control plates. The control panel was made in the same manner as Sample CC, but the fabric was cleaned and trimmed using conventional heat. Each board includes 21 circuit patterns (that is, three groups of seven-layer circuit patterns), -165- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 male f) (Please read the precautions on the back before filling (This page) ------ Γ --- Order --------- Line · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557286 ---- ~ _SI ___ V. Description of the Invention (163) —- A total of 42 circuits were tested on the sample CC and the control board. Table η below shows the results for 200, 400 and 100 hours, where Table 値 is the number of patterns with the specified resistance. Table 17 Insulation resistance --- sample CC pair, OHMS 200 Hrs 400 Hrs 1000 hrs 400 Hrs short circuit 0 1 7 42 105 1 4 2 〇 106 1 1 1 0 107 0 2 0 0 108 1 0 1 0 109 3 2 1 0 &gt; 1010 36 32 30 0 (Please read the precautions on the back before filling this page) The sample CC board printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs has less short circuits than the control board after 200 hours of exposure. After 400 hours of exposure, all control plate patterns were damaged. For the purpose of this test sample, &quot; short circuit &quot; refers to an insulation resistance of less than 105 ohms. Example 18 The ingredients were mixed in the amounts described in Table 18A to form an aqueous resin compatible first sizing sample RR according to the present invention. Acetic acid is included in the composition at less than 1% by weight based on the total weight. Sample RR was coated on glass fibers forming a G_75 E-glass fiber strand. The coated glass fiber strands were interwoven in a similar manner using a conventional interlacing device to form an interlaced yarn, and wound on a bobbin. The coated yarn had a LOI of 0.35%. -166- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 A7B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (164)

Table 18A Ingredients% by weight based on total solids of sample RR Ingredient sample RR RD-847A215 27.0 DESMOPHEN 2000216 36.2 PVP K-30217 9.0 A-187218 2.1 A-174219 4.4 PLURONIC F-108220 9.0 VERS AMID 140221 4.4 MACOL NP-6222 5.4 POLARTHERM PT 160223 0.9 RELEASECOAT-CONC 25224 1.5 Acetic acid &lt; 0.1 215RD-847A polyester resin, commercially available from Columbus, Ohio

Borden Chemicals Corporation 216 DESMOPHEN 2000 Polyethylene Adipate Glycol, commercially available from Bayer Corporation Pittsburgh, PA 0 217 PVP K-30 polyvinyl pyrrolidone, commercially available from ISP Chemicals, Wayne, New Jersey Company 0 218A-187 γ-Glycerylpropyltrimethoxysilane, commercially available from OSi Specialties, Tarrytown, New York Company 0 219A-174 γ-methylpropanyloxypropyltrimethoxysilane, commercially available Available from OSi Specialties, Tarrytown, New York. • 167- This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) —h -------------- ^ ---- Order ------ --- line i ^ w. (Please read the notes on the back before filling out this page) 557286 A7 B7 V. Description of the invention (165) 22GPLURONIC F-108 Polypropylene oxide-polyethylene oxide copolymer, commercially available from New Zealand BASF, Parsippany, Jersey. 221 VERS AMID 140 Polyamine, commercially available from General Mills Chemicals. 222MACOL NP-6 nonyl surfactant, commercially available from BASF, Parsippany, New Jersey. 223POLARTHERM⑧PT 160 boron nitride powder particles are commercially available from Advanced Ceramics, Lakewood, Ohio. 224ORPAC BORON NITRIDE RELEASECOAT-CONC 25 Boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water, is commercially available from ZYP Coatings, Oak Ridge, Tennessee. The ingredients are mixed in the amounts described in Table 18B to form an aqueous resin compatible first sizing sample SS according to the present invention. Sample SS was coated on glass fibers forming G-75 E-glass fiber strand fibers, and the strands were not interwoven. The coated uninterlaced yarn had a LOI of 0.7%. (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives -168-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperative 557286 A7 ___B7 V. Description of Invention (166)

Table 18B Per pound composition of SS on 100 gallon samples SS MAPEG 600 DOT225 9.24 ALUBRASPIN 226226 1.9 A-174227 10.9 A-187228 5.45 A-1 10229 2.41 EPON 880230 91.1 PLURONIC F-108231 9.11 ALKAMULS EL-719232 9.11 MACOL OP-10-SP233 4.57 EPIREZ 3522234 20.9 Acetic acid 2.6 225 is ethoxylated ditallow obtained from BASF. 226ALUBRASPIN 226 partially fluorinated poly (ethylene diimide), commercially available from BASF Corporation, Parsippany, New Jersey 0 227A-174 γ-methacryloxypropyltrimethoxysilane, commercially available from Tarrytown, New York CK Witco, Inc. 0 228A-187 γ-desglycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, NY. 229A · 1100 Amine functional organosilane coupling agent, which is commercially available from CK Witco Company, Tarrytown, New York, 0 230EPON 880 epoxy resin, which is commercially available from Houston, Texas, Shell 169- This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------------- ^ ---- order --------- line (Please read the precautions on the back first (Fill in this page again) 557286 A7 B7 V. Description of Invention (167)

Chemical Company 0 (Please read the notes on the back before filling this page) 231PLURONIC ™ F-108 Polyoxypropylene-Polyethylene Oxide Copolymer, commercially available from BASF Corporation, Parsippany, New Jersey. 232ALKAMULS EL-719 polyoxyacetic acid vegetable oil, commercially available from Rhone-Poulenc Company 233 MACOL OP-10 SP ethoxylated phenol, commercially available from BASF Company Parsippany, New Jersey 0 234EPIREZ 3522 solid biphenol A A dispersion of diglycidyl ether epoxy resin is commercially available from Sell Chemical Company of Houston, Texas. The sizing yarns of samples RR and SS were used as warp and filling yarns (or weft yarns), and woven into 7628 type fabrics. The control yarn was also woven into a Type 7628 fabric, which is a fiber with a coated PPG 695 sizing and is commercially available from PPG Industries of Pittsburgh, PA. The sizing warp yarn and the filling yarn have a LOI of 1%. Before weaving, the warp yarn is slit with a polyvinyl alcohol composition, which increases the LOI of the warp yarn to about 2 to about 2.5%. The resulting fabric has a LOI in the range of 1.6 to 1.9%. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Test the air permeability of each fabric in accordance with ASTM D 737 standard test method for air permeability of textile fabrics. The average air permeability of the fabrics is shown in Table 18C below. -170- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 557286 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (168)

Table 18C Air permeability (standard cubic feet per square foot per minute) Control sample 41 Sample RR 2.8 Sample SS 1.6 As seen in Table 18C, the air permeability of the textile fabrics added with samples A and B is much lower than that of the control sample Textile fabric. Example 19 Table 19 includes additional non-limiting sizing formulations coated on glass fibers, which are then woven into a fabric. Each composition includes less than 1% by weight of acetic acid. Table 19 Ingredients% by weight based on total solids Ingredient Sample TT Sample UU Sample XX Sample YY PVP K-30235 13.7 13.5 15.3 14.7 STEPANTEX 653236 27.9 13.6 A-187237 1.7 1.9 1.9 1.8 235 PVP K-30 polyvinylpyrrolidone, commercially available from ISP Chemicals Corporation 0236 STEPANTEX 653, Wayne, New Jersey, and commercially available from Stepan Corporation, Maywood, New Jersey. 237 A-187 r · Dehydrated glycerylpropyltrimethoxysilane, commercially available from CK Witco, Tarrytown, New York 0 -171- This paper is sized for the Chinese National Standard (CNS) A4 (210 X 297 mm) ) — ^ ---------------------- Order --------- line i ^ v. (Please read the notes on the back before filling this page) 557286 A7 B7 V. Description of the invention (169) Table 19 (continued) Composition sample TT sample UU sample XX sample YY A-174238 3.4 3.8 3.8 3.7 EMERY 6717239 2.3 1.9 2.5 2.4 MACOL ΟΡ-ΙΟ240 1.5 1.7 1.6 TMAZ-81241 3.0 3.4 3.3 MAZU DF-136242 0.2 0.3 0.2 ROPAQUE OP-96243 39.3 43.9 42.3 RELEASECOAT-CONC 25244 4.2 6.4 POLARTHERMPT 160245 2.7 2.6 SAG 10246 0.2 RD-847A247 23.2 DESMOPHEN2000248 31.2 PLURONIC F-108249 8.5 238 A-174 r -methacryloxypropyl Trimethoxysilane, commercially available from CK Witco, Tarrytown, NY 0 ----------------- = ---- Order --------- Line i ^ w. (Please read the precautions on the back before filling out this page) Printed on a moderately large piece of paper Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 239 EMERY® 6717 partially fluorinated poly (ethylene diimide), commercially available from Cognis Corporation of Cincinnati, Ohio. 240 MACOL OP-10 ethoxylated alkylphenol; this material is similar to MACOL OP-10 SP, except that MACOL OP-10 SP is subjected to post-treatment to remove the catalyst; MACOL OP_10 is no longer commercially available. An ethylene oxide derivative of 241 TMAZ-81 anisolate, commercially available from BASF Corporation, Parsippany, New Jersey. 242 MAZU DF-136 Antifoam, commercially available from Parsippany, New Jersey, 172-Chinese National Standard (CNS) A4 Specification (210 x 297 mm) 557286 Table 19 (continued) A7 B7 V. Description of the Invention (170 ) BASF Company. 243 ROPAQUE® OP_96, 0.55 micron particle dispersion, commercially available from Rohm and Haas, Philadelphia, PA. 244 ORPAC BORON NITRIDE RELEASECOAT_CONC 25 Boron nitride dispersion, which is a dispersion of about 25% by weight of boron nitride particles in water. It is commercially available from ZYP Coatings, Oak Ridge, Tennessee. 245 POLARTHERM PT® 160 boron nitride powder particles are commercially available from Advanced Ceramics, Lakewood, Ohio. 240 SAG 10 antifoam material commercially available from CK Witco, Greenwich, Connecticut. 247 RD-847A polyester resin, commercially available from Borden Chemicals, Columbus, Ohio. 248DESMOPHEN 2000 polyethylene adipate glycol, commercially available from Bayer, Pittsburgh, PA. 249PLURONIC ™ F-108 Polyoxypropylene Polyethylene Oxide Copolymer, commercially available from BASF Corporation, Parsippany, New Jersey 0 Ingredient Sample TT Sample UU Sample XX Sample YY ALKAMULS EL-719250 3.4 ICONOL NP-6251 3.4 FLEXOL ΕΡ0252 13.6 30.0 Referred to as ALKAMULS EL-719 polyethylene oxide vegetable oil, it is commercially available from Rhone-Poulenc Company ° ICONOL NP-6 alkoxylated nonylphenol, and it is commercially available from New Jersey -173- This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) ---: -------------- r --- order --------- line (please read the note on the back first) ? Please fill out this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

Claims (1)

557286-Patent Application No. ~ 〇mt ^ 359 A8 Public #Wenli Scope Replacement (92, July 1997) B8 ^ 18 D8 Application, application range L-a reinforced laminate suitable for electronic support, this laminate contains: (a)-a matrix material; and ㈨ at least-a non-defatted fabric 纟 纟 contains at least one fiber ( Strands, wherein at least a portion of the fabric has a coating compatible with the matrix material suitable for the strengthening laminate, wherein the phase: the coating comprises a plurality of particles selected from a polymeric inorganic material, a non-polymeric inorganic material , Polymeric organic materials, non-polymeric organic materials, composite materials, and any mixture of the above. 2 Reinforced laminates according to the application for patent _1, where ... the organic material is selected from polyphosphine ' Dream oxy-fired, poly-fired, sulfur, poly-selenium, poly-silicone, and any mixture of the above. 3. Reinforced laminates according to the scope of patent application 帛 1, wherein the non-polymeric inorganic material is selected from graphite, metal, Oxides, carbides, nitrogen: compounds, borides, sulfides, silicates, carbonates, sulfates, hydroxides and any mixture of the above. 4. According to the scope of the patent application, page P of the reinforced laminate, Where poly The organic material is selected from the group consisting of thermosetting materials, thermoplastic materials, and mixtures thereof. 5. The reinforced laminate according to item 4 of the scope of patent application, wherein the polymeric organic material is selected from the group consisting of thermosetting polyester, ethyl acetate, epoxy material, phenol Series, amine-based plastic, thermosetting polyurethane, and any mixture of the above. 6. Reinforced laminate according to item 4 of the scope of patent application, wherein the organic polymeric material is selected from the group consisting of thermoplastic polyester, poly Carbonate, Polyolefin, Acrylic Polymer, Polyamide, Thermoplastic Polyurethane, Vinyl Polymer O: \ 65 \ 65553-920718DOC \ LAN —7 public reply) 557286 A8 Materials, and mixtures of any of the above. 7 · According to the scope of patent application 申请! The reinforcing laminate of this item is selected from particles having a surface having a hardness different from that of the composite material in the surface below the surface. Fruit 4 Inner Shore Hardness &amp; Reinforcement layer according to item 7 of the scope of patent application 枓 selected from the group consisting of a first material covered, covered or enveloped with at least one second material. 9. The reinforced laminate according to item 7 of the scope of the patent application, wherein the composite material is selected from the group consisting of particles of the first material covering, covering, or encapsulating the first material in different forms. The reinforced laminate according to item (i) of the scope of the patent application, in which the particles have a thermal conductivity of at least one kilowatt per meter at a temperature of 300K. 8. 11. The reinforced laminate according to item 1 of the scope of patent application, wherein the particles have a Mohs hardness value ^ Mohs hardness value not exceeding any glass fiber in at least one strand. 12 A reinforced laminate according to item 丨 of the patent application scope, wherein the particles have an average particle size sufficient to wet the strands. 13. The reinforced laminate according to item 丨 of the patent application range, wherein the particles have an average particle size in the range of 0.1 to 5 microns as measured by a laser scattering technique. W. The reinforced laminate according to the scope of the patent application, wherein the compatible coating further comprises at least one kind of lubricant material different from a plurality of particles. 15_ The reinforced laminate according to item 1 of the application, wherein the compatible coating further comprises at least one film-forming material. -2- O: \ 65 \ 65553-920718 DOOLAN This paper is suitable for the standard ® ® Fresh Food (CNS) A4 (210X297) * --------- is / 286 A8 B8 ---- -C8, Shen --- * --- a: It is claimed: The reinforced laminate of item 1 of the patent scope, which is compatible with the combustion loss of Tu Yu, Kuo a around 0.1 to h6, and according to ASTM D 37 Measured as no more than 10 standard cubic feet per minute per square foot &lt; breathability. The reinforced laminate of item # 6 of the six patents, wherein the resin phase valley coating further contains a resin reactive diluent. Declaration of patent scope! The fabric of item 7, wherein the resin-reactive thin pen sword comprises one or more resins capable of reacting with an epoxy resin system, and consisting of amine, alcohol, fluorenyl, acid, and epoxy groups. Group of functional group lubricants. 19. · A method of forming a reinforced laminate suitable for an electronic support, comprising: (a) by weaving at least one filling yarn comprising a plurality of fibers and having a first Resin compatible coating, and up to V warp yarns containing a plurality of fibers and having a second resin compatible coating on the soil V component of at least one warp yarn, to obtain a fabric suitable for strengthening an electronic support, wherein the compatible coating Contains a plurality of particles formed from a material selected from the group consisting of a polymeric inorganic material, a non-polymeric inorganic material, a polymeric organic material, a non-polymeric organic material, a composite material, and any mixture thereof; (b) a matrix material resin at least partially Coat at least a portion of the fabric; (c) At least partially harden the at least partially coated fabric to form a prepreg sheet; and O: \ 65 \ 65553-920718 DOC \ LAN This paper standard applies to China National Standard (CNS) A4 (2i0x 297 cm) 557286 A8 Βδ 2. Laminate two or more prepreg layers together to form a laminate suitable for use as an electronic support. 2 (1 A prepreg for an electronic support, comprising: U) a matrix material; and (b) at least one non-absorbent fabric comprising at least one strand of a plurality of fibers, wherein At least a part has a coating that is compatible with the matrix material in the reinforced laminate suitable for electronic support, wherein the phase coating comprises a plurality of particles selected from the group consisting of polymeric inorganic materials, and non-poly 2 inorganic materials. , Polymeric organic materials, non-polymeric organic materials, composite: materials, and any mixture of the above materials. 21. The prepreg according to item 20 of the scope of the patent application, wherein the polymeric inorganic material is selected from the group consisting of polyphosphine, polypyrene, polypyrene, polypyrene, polysulfide, polyselen, polysiloxane, and more Any mixture. 21 The prepreg according to item 2G of the patent application, wherein the non-polymeric inorganic material is selected from the group consisting of graphite, metal, oxide, carbide, nitride, boride, sulfide, oxalate, carbonate, sulfate , Oxides and mixtures of any of the above. According to the prepreg according to item 2G of the patent application, the polymer organic material is selected from thermosetting materials, thermoplastic materials, and mixtures thereof. 24. The prepreg according to item 23 of the scope of patent application, wherein the polymeric organic material is selected from the group consisting of thermosetting polyesters, ethylene esters, epoxy materials, phenolic 'amine-based plastics, thermal-eye polyurethane, and A thermosetting material in any of the above mixtures. 25. The prepreg according to item 23 of the patent application, in which the organic polymer material is O: \ 65 \ 65553-920718 DOQLAN λ This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 557286 The material is a thermoplastic material selected from the group consisting of plastic polyester, polycarbonate, polycarbonate, propylene polymer, polyurethane, thermoplastic polyurethane, ethoxylated polymer, and any mixture thereof.预 The prepreg according to item 20 of the patent application scope, wherein the composite material is selected from hard &amp; particles having a surface having a hardness different from the internal hardness of the particles below the surface. 27. The prepreg according to item 26 of the scope of the patent application, wherein the composite material is selected from particles formed by the first material covered, covered or enveloped with a second material of soil V. 2 &amp; The prepreg according to item 26 of the scope of the patent application, wherein the composite material is selected from particles formed by the first material covering, covering or encapsulating the first material in a different form. • The prepreg according to item 20 of the scope of the patent application, wherein the particles have a thermal conductivity of at least 1 watt per meter of k at a temperature of 300K. The blade is a prepreg according to item 20 of the patent application range, wherein the particles have a Mohs hardness value not exceeding the Mohs hardness value of any glass fiber in at least one strand. 31. The prepreg according to claim 20 of the application, wherein the particles have an average particle size sufficient to make the strands moist. The prepreg according to Item 20 of the patent application range, wherein the particles have an average particle size ranging from 0.01 to 5 microns according to a laser scattering technique. 33. The prepreg according to claim 20 of the application, wherein the compatible coating further comprises at least one kind of lubricating material different from a plurality of particles. O: \ 65 \ 65553-920718 DOC \ LAN This paper size is applicable to China National Standard (CNS) A4 size 7 ^ 10X297 mm) 557286 Scope of patent application The prepreg according to claim 20, wherein the compatible coating layer includes at least one film-forming material. According to the prepreg sheet No. 20 of the patent application scope, the compatible coating j has a burning loss in the range of 0.1 to 1.6, and it is not more than 1 per square foot per minute measured in accordance with ASTM D 73. Standing power of standard cubic feet. An electronic support comprising (a) ^^ non-fat-free fabrics comprising at least one strand containing more than 4 fibers, wherein at least a portion of the fabric has a coating that is compatible with the surface of the matrix material i, wherein The coating comprises a plurality of particles formed from a material selected from the group consisting of a composite inorganic material, a non-polymeric inorganic material, a polymeric organic material, a non-a organic material, a composite material, and any mixture thereof; and (b) at least one A base material on at least a portion of at least one fabric.电子 The electronic support according to item 36 of the application, wherein the particles have an average particle size sufficient to make the strand moist. 3 &amp; The electronic support according to item 36 of the patent application range, wherein the particles have an average particle size ranging from 0 "to 5 microns as measured by laser scattering technology. 39. The electronic support according to item 36 of the application, wherein the compatible coating further comprises at least one kind of lubricant material different from a plurality of particles. The electronic support according to item 36 of the patent application, wherein the compatible coating further comprises at least one film-forming material. O: \ 65 \ 65553-920718 DOC \ LAN -6-^ 57286 Patent application for patent application for patent application No. 36 of electronic patent application for the patent application range-there is a range of (U to!. 6 of the burning ancestors' which is compatible with broad coating 737 is measured as a few pounds per square per minute, and the air permeability according to ASTMD. Ruler is not more than 10 standard cubic inches of suction ^ A method of forming an electronic support, the package of which is woven by weaving at least one-including multiple: less At least one of a yarn filling ~ ,,, &lt; yarn filling and at least one of which contains a plurality of compatible coatings, at least a part of which has a warp yarn reinforced electronic bribe on the ground &gt; pure It is said that the coating layer is suitable, and the compatible coating contains a plurality of particles, and the material is formed of a material, a non-polymeric inorganic material, a polymer organic, a non-polymeric organic material, a composite material, and a composite material. This part (b) at least partially coats at least a portion of the fabric with a matrix material resin, at least partially hardens at least a portion of the fabric, and is coated with a prepreg sheet; and (d) one or more Prepreg layers are laminated with one or more conductive layers 43. — An electronic circuit board comprising (a) an electronic support comprising (1) at least one non-greased fabric comprising at least one strand comprising a plurality of fibers, wherein at least a portion of the fabric Has a coating compatible with the matrix material, wherein the compatible coating contains a plurality of particles, which is selected from O: \ 65 \ 65553-920718 DOC \ LAN This paper size applies to the CNS A4 specification ^ (210X297 mm) 557286 A8 B8 C8 D8 VI. Patent application scope Polymer material, non-polymeric inorganic material, polymer organic material, non-hydrated organic material, composite material, and any mixture of the above materials; and (11) at least A matrix material on at least a portion of at least one fabric; and (b) the hazardous layer, the support, and the conductive layer are contained in an electronic circuit board. 44. The electric circuit board according to item 43 of the scope of patent application, wherein the particles have an average particle size sufficient to wet the strands. 45. The electronic circuit board according to item 43 of the scope of patent application, wherein the particles have an average particle size ranging from 0.1 to 5 microns as measured according to laser scattering technology.牴 The electronic circuit board according to item 43 of the patent application scope, wherein the compatible coating layer further comprises at least one kind of lubricant material different from a plurality of particles. 47. The electronic circuit board according to item 43 of the application, wherein the compatible coating further comprises at least one film-forming material. 4 &amp; Electronic circuit board according to item 43 of the scope of patent application, wherein the compatible coating has a burning loss in the range of Oi to 1.6, and is measured in accordance with asmdd 737 to be not more than 10 standard cubic feet per square foot per minute. Breathability. 49. A method of forming a printed circuit board, comprising: 0) obtaining at least one filling yarn comprising a plurality of fibers by weaving and having a first resin-compatible coating on at least a portion of at least one filling yarn, And at least one warp yarn comprising a plurality of fibers and having a second resin compatible coating on at least a portion of the at least one warp yarn, = formed L_ This paper size applies to China 557286 A8 B8 C8 D8 6. The patent application scope includes an electronic support that contains one or more conductive layers and at least one fabric suitable for strengthening the electronic support, where the compatible coating contains multiple particles Which is formed of a material selected from the group consisting of a polymeric inorganic material, a non-polymeric inorganic material, a polymeric organic material, a non-polymeric organic material, a composite material, and any mixture thereof; and (b) conducting one or more of the electronic supports At least one of the layers is patterned to form a printed circuit board. O: \ 65 \ 65553-920718 DOC \ LAN ~ 9 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 557286 557286 Patent Application No. 089115359 Chinese Schematic Replacement Page (May 1992 ! 则 —Δ]-»* I = 1 -ίπτ ;: Μ4Ϊ- J‘ 1 __ 丨 丨 丨 鼸 一-= 1-: Ί Ί ▲▲ Fu Deng], mi · 肖 1 • Ί Π m