TWI270347B - Cockroach bait jelly - Google Patents

Cockroach bait jelly Download PDF

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TWI270347B
TWI270347B TW94106186A TW94106186A TWI270347B TW I270347 B TWI270347 B TW I270347B TW 94106186 A TW94106186 A TW 94106186A TW 94106186 A TW94106186 A TW 94106186A TW I270347 B TWI270347 B TW I270347B
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bait
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pectin
weight percentage
cockroaches
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TW94106186A
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TW200630037A (en
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Hao-Jan Lin
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Sondlin Technology Corp
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Abstract

Higher content of low methoxyl pectin (LMP) is used to form jelly bait for carrying insecticide to kill cockroaches. The LMP jelly bait benefits from maintaining its softness for longer periods of time which result in high yield in killing cockroaches. The LMP jelly bait can be injected with a syringe into the crevices where the female cockroaches and nymphs hide to achieve the best effect in eradication of cockroaches.

Description

1270347 五、發明說明(1) 1 .本技藝所屬之技術領域 本技藝適用於蟑螂毒殺用膠餌,特別適用於以針筒注射 方式,實行縫隙注入以達誘殺蟑螂之目的。 2 .背景說明 、蟑螂屋 蟑螂。至於 裂縫等棲息 進入隙縫内 傳統的處理 螂仍然存 若蟑螂才能 蟑螂隱身棲 年來盛行的 的各蟲期, 蟑螂喜歡棲息於縫隙之中,市面上的捕蟑盒 等,僅能消滅一些自棲息場所出來見食之雄 雌蟑螂、若蟑螂(nymph) 仍多匿居於隙縫’ 場所内;即使採用喷灑式殺蟲劑,能夠喷灑 部的劑量有限,毒殺蟑螂的效果不佳。這些 方式,殺死的多為雄蟑螂,而雌蟑螂及若蟑 活,防治效果大打折扣;只有消滅雌蟑螂及 徹底的撲滅蟑螂族群。因此針對雌蟑螂、若 所處理的「縫隙注入」式殺蟑法,已成為近 蟑螂防治新技術。此種技術,可以殺滅蟑螂 尤其是雌蟑螂與若蟑螂。 3.先前技術 先前技術如美國專利6,0 0 7,8 3 2所述,係初期呈現黏膠狀 膠體,置放於毒殺位置以後逐漸硬化,本技藝則是採用 較高含量之果膠,在一定條件下結膠構成果床狀膠體毒1270347 V. INSTRUCTIONS INSTRUCTIONS (1) 1. TECHNICAL FIELD This technical field is applicable to a cockroach poisoning rubber bait, and is particularly suitable for the purpose of injecting a needle into a syringe injection method to induce cockroach. 2. Background description, 蟑螂屋 蟑螂. As for the traditional treatments such as cracks and inhabiting into the gaps, the cockroaches still exist in the past, and they like to inhabit the gaps. The traps on the market can only eliminate some self-occupation sites. The male and female nymphs that come out to eat are still in the gap's place; even with spray-type insecticides, the dose of the spray can be limited, and the effect of poisoning and killing is not good. In these ways, most of the killings are male, while the females and nymphs are lively, and the control effect is greatly reduced; only the females are eliminated and the scorpions are completely eliminated. Therefore, it has become a new technology for prevention and control of the female sputum and the "slit injection" type of killing method. This kind of technology can kill cockroaches, especially females and cockroaches. 3. Prior Art The prior art, as described in U.S. Patent No. 6,0 0 7,8 3 2, is an initial appearance of a viscose colloid which is gradually hardened after being placed in a poisonous killing position. The present technique uses a higher content of pectin. Under certain conditions, gelatinization constitutes a bed-like colloidal poison

第6頁 1270347 立、發明說明(2) -------__— ::放於毒殺位置以後,仍然以較長 f 1 ΐ別適於蟑螂喜好啃食膠體之&嚴-鼓I嚴 殺效果。 達到較佳之毒 容 内 之 藝 技 本 螂 狀劑璋轉引深觸在快有 凍藥於櫃誘隙接劑分..1如留 果蟑^廚持縫劑藥水螂j,殘 持殺$、維達藥蟑免蟑|體之 保之h洞可噴加殺避合餘洗 間全i孔,劑增及,%.下清 呷安/、所餌/'劑狀其留以 瓦用式角處將口^凍尤會難 TA使I邊動可入—果體不下 / 、ί、活,出果持膠,留 π Μ隙或劑螂效保式食會 毋Μ縫穴膠蟑螂間凍取不 膠一低U種巢凝閉蟑時果全亦 果入it各之本封殺的性完後 基S加彳如螂。膠大長軟會之 氧%再蟑性凝最較此螂硬 甲|處近效處到有。蟑乾 低/餌}敝接長地達以效,, 用膠de隱能之標,可藥言體 利螂ci及可螂在會下去而膠 為蟑ti沒儘蟑時機護失般食 藝引ec出,滅同之保發一取 技誘ns常等殺,螂體揮,被。 本之i經角及處蟑膠速食/未物 i 果膠是為曱基酯化之3 〇 〇〜1 〇 〇 〇個半乳糖酸 (methylated ester of polygalacturonic acid)長鏈構 造’一般商品化的果膠通常由橘子皮或蘋果渣在微酸性 條件下萃取得來,根據FCC (Food Chemicals Codex)定Page 6 1270347 Li, invention description (2) -------__- :: placed in the poisoning position, still with a longer f 1 蟑螂 蟑螂 蟑螂 蟑螂 啃 啃 啃 严 严 严 严 严 严 严 严Severe killing effect. Achieving better toxic content in the art of the 螂 螂 璋 璋 深 深 深 深 深 深 深 深 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快 快, Vida medicine 蟑 蟑 蟑 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 体 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞 洞At the corner of the corner, it will be difficult to freeze the TA. I can move the I side. The fruit does not go down, ί, live, and the fruit stays in the rubber, leaving π Μ 或 或 或 或 或 或 或 或 或 或 或 或 或 或When the frozen is not glued, the low U seed nest is closed and the fruit is also cut into the roots of each of the blocks. The glue is long and soft, and the oxygen is more sturdy than the sputum.蟑 低 / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / 长 长 长 长 长 长 长 长 长 长Lead ec out, destroy the same as the insurance, take a technique to induce ns often kill, scorpion swing, quilt. This is a generalized commercialization of the long-chain structure of methylated ester of polygalacturonic acid, which is a thiol esterified 3 〇〇~1 曱 酯 酯 1 methyl Pectin is usually extracted from orange peel or apple pomace under slightly acidic conditions, according to FCC (Food Chemicals Codex)

1270347 五、發明說明(3) 義:果膠曱氧基化程度超過50%者,稱為高甲氧基化果膠 (High Methoxyl Pectin, HMP);低於50% 者,則稱為低 甲氧基化果膠(Low Methoxyl Pectin, LMP),這兩種果 膠在室溫下均能結成膠體,但結膠條件彼此有很大不 同,HMP需要在高溶質低酸鹼值下才能結膠;而LMP的結 膠條件範圍則相對較為寬容,一般果膠溶質在1 0%以下 0. 6%以上’ pH 1· 0-7. 0,加入二價離子如妈離子,便可 以促使其結膠。低甲氧基化果膠結膠機制?藉助不同半乳 糖酸長鏈之間破氧基(carboxyl group)與二價離子連接 成架橋(bridge junction),此架橋區域容易脫水結晶 化形成不規則狀膠體,一般二價金屬離子皆有此促進凝 膠能力稱為Alginates ,其促膠能力依序鎂離子(Mg2+) &lt;&lt;鈣離子(Ca2+);以及勰離子(Sr2+)〈鋇離子(Ba2+)。 5.實施方式 本技藝所使用的殺緯藥劑(Insecticides),包含硼酸 (Bor ic Acid)、有機磷劑、或是合成菊精,列舉如下: (1 )硼酸(Boric Acid)。 (2) 有機碌劑*陶斯松(chlorpyrifos)、撲滅松 (Fenitrothion)、芬殺松(Fenthi〇n)、馬拉松 (Malation)、亞特松(pirimiph〇s-Methyl)、以及亞培 松(Temephos) 〇 (3) 合成菊精·百列滅寧(Bi〇resmethrin)、賽滅寧1270347 V. INSTRUCTIONS (3) Meaning: Pectin is more than 50% oxidized, called High Methoxyl Pectin (HMP); below 50%, it is called low A Low Methoxyl Pectin (LMP), both pectins can form a colloid at room temperature, but the gelling conditions are very different from each other. HMP needs to be glued under high solute and low pH. The range of gelling conditions of LMP is relatively tolerant. Generally, the pectin solute is below 10% and more than 6%. 'pH 1· 0-7. 0. Adding divalent ions such as mom ions can promote the knot. gum. Low methoxylated pectin gelling mechanism? By means of a bridge group between the long chains of different galactonic acid chains and divalent ions, the bridging region is easily dehydrated and crystallized to form irregular colloids, which are generally promoted by divalent metal ions. The gelling ability is called Alginates, and its gel-promoting ability is sequential magnesium ion (Mg2+) &lt; calcium ion (Ca2+); and barium ion (Sr2+) < barium ion (Ba2+). 5. Embodiments Insecticides used in the art, including Boric acid, organophosphorus or synthetic chrysanthemum, are listed as follows: (1) Boric Acid. (2) Organic agents * chlorpyrifos, Fenitrothion, Fenthi〇n, Malation, pirimiph〇s-Methyl, and Temephos 〇(3) Synthetic Chrysanthemum · Bieleresin (Bi〇resmethrin), Saihuning

第8頁 1270347 五、發明說明(4) (Cypermethrin) ' 第寧滅(Deltamethrin)、百滅寧 (Permethrin)、酴 丁滅蟲(Phenothrin)、列滅寧 (Resmethrin)、右亞列寧(S-Bioallethrin)、治滅寧 (Tetramethrin) 〇 以下僅以硼酸、以及陶斯松(Ch lorpy r i f os )作為主要殺 蟑劑,各舉一例作為範例說明: 5 . 1 實例一:以「蝴酸」為主要毒殺成分Page 8 1270347 V. Inventive Note (4) (Cypermethrin) 'Deltamethrin, Permethrin, Phenothrin, Resmethrin, Right-Lenin (S- Bioallethrin), Tetramethrin 〇The following are only boric acid and trousers (Chlorpy rif os) as the main acaricides, each example is illustrated as an example: 5.1 Example 1: The main poison of "Folic acid" ingredient

「硼酸」膠餌主要成分參見表一 A 藥效測定方法 (1 )供試昆蟲:棕帶蟑螂(台中品系)Supel la 1 ong i pa 1 pa (2 )藥效測定方法 A .設備 壓克力飼育箱2 5 X 1 5 X 1 7 立方公分,内附紗網以防蟑 螂爬出。 方法The main components of the "boric acid" rubber bait are shown in Table A. The efficacy test method (1) Test insects: Brown belt 蟑螂 (Taichung strain) Supel la 1 ong i pa 1 pa (2) Determination of efficacy A. Equipment acrylic Feeding box 2 5 X 1 5 X 1 7 cm ^ 3, with gauze attached to prevent cockroaches from climbing out. method

1270347 五、發明說明(5) I . 供試膠餌1 . 5 克倒入塑膠培養皿中,置於箱内,測 試箱提供飼料水與藏匿處。 II. 將二氧化碳輕度麻醉後之棕帶蟑螂,放入測試箱令 其自由取食,並連續觀察8日,紀錄死亡率。1270347 V. INSTRUCTIONS (5) I. 1.5 g of test rubber bait is poured into a plastic petri dish and placed in a box. The test box provides feed water and a hiding place. II. After the mild anesthesia of carbon dioxide, the brown belt was placed in a test box to allow it to freely feed, and it was observed continuously for 8 days to record the mortality.

C. 結果.·參見表一B 5. 分 實 以「陶斯松」(Chlorpyrifos)為主要毒殺成C. Results. · See Table 1 B. 5. Separate the main poison with "Chlorpyrifos"

陶斯松」膠餌主要成分參見表二AThe main ingredients of Taosson's rubber bait are shown in Table 2A.

藥效測定方法同實例一 結果:參見表二B 本實驗所使用的食物型誘餌其具備充分水溶特性,易與 結膠前的果膠溶液互溶,並且不影響加鈣後結膠能力。 食物型誘餌種類很多,已經前人技藝所揭露,本膠體將 可結合其它 &lt;耳劑例如洋蔥、奶粉、麵粉、糖、肉類,在 不影響加鈣後結膠能力下發揮效果。根據觀察,不同蟑 螂如美洲蟑螂(Periplaneta americana)或德國蟑螂The method for determining the efficacy of the drug is the same as that of the first example. Results: See Table 2B. The food type bait used in this experiment has sufficient water-solubility characteristics, and is easily soluble in the pectin solution before gelation, and does not affect the gelation ability after calcium addition. There are many types of food-based baits, which have been revealed by previous techniques. The gels can be combined with other ear-based agents such as onions, milk powder, flour, sugar, and meat to exert effects without affecting the ability to form calcium after adding calcium. According to observations, different 蟑 such as the American lynx (Periplaneta americana) or German 蟑螂

第10頁 1270347 五、發明說明(6) (Blattella germanica)以及棕帶蟑螂(periplaneta brunnea),對食物型誘餌成分種類選擇性差異不大,反 而傾向於喜好柔軟且含水性高之劑型,因此本測試果膠 餌劑應對其他種類蟑螂亦有良好誘引性。 硼酸(Bo r i c Ac i d )為低水溶性物質,作為殺蟲成分已有 多年歷史,其殺蟲機制可分為兩類:第一類接觸性毒殺 方式,通常需要高於4 0 %以上的比例才可作用,第二類則 為口服性毒殺,需要濃度介於丨〇_ 4 〇%,與果膠結合型態 為懸浮顆粒狀,蟑螂取食本餌劑以後短則一天長到八天 陸續死亡,屬於緩效性殺蟲劑。 陶斯松(C h 1 〇 p y r i f 〇 s )為有機磷劑,由於其低忌避性 (I nsect-repe 1 lent)被廣泛使用之低毒性殺蟲劑,市面 上販售為含有4 0 8%主成分水溶性產品,可與果膠充分混 合加#5後形成乳膠狀,該殺蟲劑為速效型,一般使用劑 量為1-2 %,蟑螂取食後2-3天内大量死亡。 5. 3. 實施例三—低曱氧基氨化果膠(Low methoxy 1 pec t i n-am i da t ed, LMPA) 前述兩個實施例使用的「低曱氧基果膠」(Low Methoxy 1 Pectin, LMP)也可以用「低甲氧基氨化果膠」(Low methoxyl pectin-amidated,LMPA)取代之’其他組成不Page 10 1270347 V. Inventive Note (6) (Blattella germanica) and periplaneta brunnea have little difference in the selectivity of food-type bait components, but tend to prefer a soft and highly water-soluble dosage form. Testing pectin baits is also good for other types of cockroaches. Boric acid (Bo ric Ac id ) is a low water-soluble substance. It has been used as an insecticidal ingredient for many years. Its insecticidal mechanism can be divided into two categories: the first type of contact poisoning method, which usually needs more than 40%. It can be used, the second type is oral poisoning, the concentration needs to be between 丨〇 _ 4 〇%, and the pectin-binding type is suspended granules. After taking the bait, it is as short as eight days. Death is a slow-acting insecticide. Tausson (C h 1 〇pyrif 〇s ) is an organophosphorus agent, which is widely used as a low-toxic insecticide because of its low repellent properties. It is sold in the market as containing 40% of its main components. The water-soluble product can be mixed with pectin and added with #5 to form a latex. The insecticide is a quick-acting type. The dosage is generally 1-2%, and a large amount of death occurs within 2-3 days after feeding. 5. 3. Example 3 - Low methoxy 1 pec ti n-am i da t ed (LMPA) The "low methoxy pectin" used in the above two examples (Low Methoxy) 1 Pectin, LMP) can also be replaced by "Low methoxyl pectin-amidated" (LMPA).

IH1 第11頁 1270347 五、發明說明(7) 變。LMPA的產生可以是將[仰的破氧基(carb〇xyl group) 氨基化形成衍生物「低曱氧基氨化果膠」(Low methoxyl pectin-amidated,LMPA)。LMPA在二價金屬離子存在時 亦可結膠,其膠性與未氨化LMP最大不同點在於LMp熱溶 點較高’可達到1 5 0度C,L Μ P A則較低,通常7 5产c #體、、容 ,:而且在PH值3_ 4以下時LMPA膠體硬度較未氨义化硬 前述描述揭示了本技藝之較IH1 Page 11 1270347 V. Description of invention (7) Change. LMPA can be produced by amination of [carbo-xyl group] to form the derivative "Low methoxyl pectin-amidated" (LMPA). LMPA can also be gelled in the presence of divalent metal ions. The difference between the gelatinity and the unammonized LMP is that the LMp has a higher thermal melting point, which can reach 150 degrees C, and L Μ PA is lower, usually 7 5 Produce c #body, capacity, and the hardness of LMPA colloid is lower than that of non-ammonia at pH below 3_4. The foregoing description reveals the skill of the art.

僅是舉例說明,並非用於限 =,惟,較佳實施例 兮ΐ=均等之技藝手段實施ϋ 2 i之權利範圍於此, 鑰太ί ί利範圍」所涵蓋之權ί者、或是以下述之 離本技藝之精神而為 而實施者,均不脫 V &lt;權利範圍。Illustratively, it is not intended to be limiting, but the preferred embodiment 兮ΐ=equal skill means to implement ϋ 2 i’s rights are here, the key is too ί The implementation of the following is in the spirit of the art, and does not deviate from the scope of the rights.

12703471270347

圖式簡單說明 第13頁 1270347 1270347Brief description of the diagram Page 13 1270347 1270347

死亡率 Death Rate(%) 餵食天數(Days after feeding) 43.3±5.8 H-^ 63.3±5.8 M 1 96.7±5.8 1 U) 100.0±0.0 XX ON XX O XX 00 mu Β»鄹雒湘 水 (Η20) 陶斯松 (Chlorpyrifos) 〇 Ο 5濟 食物誘餌 (Food-based Bait) 1 ft ο 巨. § 96.2% t〇 lOOOppm 1.0% 0.8% 9 Hi 2. ip Wi 县商mi 5 〇 ftii 1 _ ! ο 適量,調配成果膠溶液。 0.5% 〜3% 50-3000 ppm 0·5 〜2% 0.6% 〜10% $ _ G画Φ 〇 ^ 〇 is g A 1 B 〇&quot;Death Rate (%) Days after feeding 43.3±5.8 H-^ 63.3±5.8 M 1 96.7±5.8 1 U) 100.0±0.0 XX ON XX O XX 00 mu Β»鄹雒湘水(Η20) Chlorpyrifos Food Food-based Bait 1 ft ο 巨. § 96.2% t〇lOOOOppm 1.0% 0.8% 9 Hi 2. ip Wi County Mi 5 〇ftii 1 _ ! ο Appropriate amount Result glue solution. 0.5% ~ 3% 50-3000 ppm 0·5 〜2% 0.6% 〜10% $ _ G画Φ 〇 ^ 〇 is g A 1 B 〇&quot;

Claims (1)

270347270347 六'申請專利範圍 1 · 一種蟑螂膠餌,係由下述材料之、、曰人^ 膠體狀之誘餌: 钭之此&amp;物所構成之常態 (^)果膠,係選自於下述族群中的一種或是多種:低曱氧 基化果膠(low methoxyl pectin)、以及 「低甲氧基氨 化果膠」(Low methoxyl pectin-amidated, LMPA); (2) 食物誘僻(food-based bait); (3) 二價金屬離子化合物,選自於下述族群中的一種或是 多種:鎂離子、鈣離子、勰離子、以及鋇離子; (4) 殺蟲劑(Insecticides),選自於下述族群中的一種 或是多種:硼酸、有機磷劑、以及合成菊精;以及 (5 )水。 Μ 1 膠、 部% 相 6 蟑ο 之為 述比 所分 項百 一 量 重 圍之 範膠 利果 專化 請基 申氧 如曱 〜低 之 述 所 中 其 餌 膠 〇 螂% 蟑2 之~ 述5°/0 所ο 項為 一比 第分 圍百 範量 利重 專之 請餌 申誘 如物 •食 3 1 之 述 所 中 其 4. 如申請專利範圍第一項所述之蟑螂膠餌,其中所述之 二價金屬離子化合物之重量百分比為50-300 Op pm ° 5. 如申請專利範圍第一項所述之蟑螂膠I耳,其中戶斤述 石朋酸之重s百分比為20%〜60%。Six 'Application Patent Scope 1 · A type of rubber bait, which is made up of the following materials: 曰人^ Colloidal bait: The normal (^) pectin composed of this &amp; One or more of the population: low methoxyl pectin, and Low methoxyl pectin-amidated (LMPA); (2) food temptation (food) -based bait); (3) a divalent metal ion compound selected from one or more of the following groups: magnesium ions, calcium ions, barium ions, and barium ions; (4) insecticides (Insecticides), One or more selected from the group consisting of boric acid, organophosphorus, and synthetic chrysanthemum; and (5) water. Μ 1 glue, part% phase 6 蟑ο is the ratio of the sub-item of the amount of the weight of the rubber gelatin specialization, please apply the base of the sputum ~ 低 之 低 低 低 低 低 低 低 低 低 低 述 述5°/0 is a ratio of the first division to the first division. Wherein the weight percentage of the divalent metal ion compound is 50-300 Op pm ° 5. The gelatin I ear as described in the first paragraph of the patent application, wherein the weight percentage of the sphagic acid is 20 %~60%. Μ 第14頁 1270347 六、申請專利範圍 6 _如申請專利範圍第一項所述之蟑螂膠餌,其中所述之 有機填劑之重量百分比為0.5%〜g%。 7 _如申請專利範圍第一項所述之蟑螂膠餌,其中所述之 有機磷劑,係選自於下述族群中的一種或是多種:陶斯 松((:111〇1^111^{〇3)、撲滅松(1^11丨4〇1:11丨〇11)、芬殺松 (Fenthion)、馬拉松(Malati〇n)、亞特松 (Pirimiphos-Methyl)、以及亞培松(Temeph〇s)。 8.如申清專利範圍第_項所述之蟑螂膠餌,其中所述之 合成菊精,係選自於下# #被心上九 _ 、下述族群中的一種或是多種·百列 滅争(Bioresmethrin)、耷、士办/ r 、 错使、Λ /TN t 』 賽滅等(Cypermethrin)、第争滅 (Deltamethrin) 、^ ^ ^ ^ ^ ^ / _, 、 自减争(Permethrin)、齡丁滅蟲 (Phenothrin)、列減办/ΓΝ 、 ,一 . 0 . 殊,(Resmethrin)、右亞列争(S- Bioallethrin)、治滅 _ .. w 争(Tetramethrin) 〇Μ Page 14 1270347 VI. Scope of Patent Application 6 _ As claimed in the first paragraph of the patent application, the weight percentage of the organic filler is 0.5% to g%. 7 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 3), puta (1^11丨4〇1:11丨〇11), Fenthion, Malati〇n, Pirimiphos-Methyl, and Tepeph〇 s) 8. The sputum bait according to the scope of the patent application, wherein the synthetic daisy is selected from one or more of the following groups. ·Bioresmethrin, 耷, 士办/r, 错使, Λ /TN t 』Cypermethrin, demise (Deltamethrin), ^ ^ ^ ^ ^ ^ / _, , decrement (Permethrin), Phenothrin, 减 ΓΝ ΓΝ, 一, 0. 士, (Resmethrin), 右亚列列 (S-Bioallethrin), 治灭_.. w dispute (Tetramethrin) 〇 第15頁Page 15
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