TWI264469B - Copper-nickel-alloy and production method for its container - Google Patents

Copper-nickel-alloy and production method for its container Download PDF

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Publication number
TWI264469B
TWI264469B TW090116478A TW90116478A TWI264469B TW I264469 B TWI264469 B TW I264469B TW 090116478 A TW090116478 A TW 090116478A TW 90116478 A TW90116478 A TW 90116478A TW I264469 B TWI264469 B TW I264469B
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TW
Taiwan
Prior art keywords
alloy
copper
nickel
melt
container
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Application number
TW090116478A
Other languages
Chinese (zh)
Inventor
Thomas Helmenkamp
Dirk Rode
Hans-Gunther Wobker
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Km Europa Metal Ag
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Publication date
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Publication of TWI264469B publication Critical patent/TWI264469B/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/059Mould materials or platings
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent

Abstract

For the production of vessels receiving metallic fusion, for example, a melting-pot for melting-and re-melting equipment, a material is necessary, said material has an excellent solderability in addition to an advantageous thermo-mechanical property. In this invention, a copper-alloy is not in a hardened state for this application, which is composed of: 0.2 to 1,55 nickel; 0, 002 to 0.12% at least one element from the group containing phosphor, aluminium, magnesium, lithium, calcium, silicium and boron; and the rest copper including production-related contaminant. In order to suitably increase the strength, the copper-alloy can contain until to 0.3% zirconium.

Description

12644691264469

If- f ,,:ri - — . __ _____ 乂 . .___ J五、發明說明(1 ) 本發明一方面係關於應用銅合金作爲非析出硬化狀態 之材料’以製造容納金屬熔體之容器,例如熔體和非熔體 設備用之坩渦。 本發明另方面針對銅-鎳合金所構成,可容納金屬熔體 的容器之製法。 熔體和非熔體製法在實務上已屬公知。旨在改善鋼, 和以鐵、鎳或鈷爲基礎的超合金之品質。又一應用範圍是 製造非鐵金屬,例如鉬、鈦、鉬或锆。 製造ί甘禍所用材料,通常是銅和銅合金,具有高度熱 傳導性。 無縫焊接或其他裝設的坩堝,通常呈圓管形或正方形 的基本型式。另外可有多角形或四方形基本型式。因此, 個別可有如此應用型式,即適合完成構件之最終型式,例 如彎曲波浪或壓力容器。 容納金屬熔體的容器,例如坩堝,有通常的長度,最 大4公尺,直徑達1.5公尺。 在熔體和非熔體設備內,坩堝原則上被冷卻套筒所包 圍,用來引出製程熱。冷卻套筒本身爲鋼構造,另外亦可 構成把冷卻水導件以細縫或冷卻孔型式整合於銅合金壁上 〇 由美國專利2 1 5 5 40 5號已知一種銅合金,含0 . 25-3% 鎳,0.05-0.6磷,其餘爲銅。此爲導電値預設之合金。 具有導電性67% I ACS和較高的抗拉強度。 1264469 xf, I Q t|If-f,,:ri - — . __ _____ 乂. .___ J V. Description of the Invention (1) One aspect of the present invention relates to the use of a copper alloy as a material in a non-precipitation hardened state to manufacture a container for containing a metal melt, For example, vortexes for melt and non-melt equipment. Another aspect of the invention is directed to a method of making a container of a metal melt which is constructed of a copper-nickel alloy. Melt and non-melt processes are well known in practice. Designed to improve the quality of steel, and superalloys based on iron, nickel or cobalt. Yet another range of applications is in the manufacture of non-ferrous metals such as molybdenum, titanium, molybdenum or zirconium. The materials used to make 355 are usually copper and copper alloys with high thermal conductivity. Seamlessly welded or otherwise mounted 坩埚, usually in the form of a circular tube or square. In addition, there may be a polygonal or square basic pattern. Thus, individual applications may be of a type that is suitable for completing the final version of the component, such as a curved wave or pressure vessel. Containers containing metal melt, such as crucibles, have a typical length of up to 4 meters and a diameter of up to 1.5 meters. In melt and non-melt equipment, the crucible is in principle surrounded by a cooling jacket for introducing process heat. The cooling sleeve itself is of a steel construction, and may also be configured to integrate the cooling water guide into the copper alloy wall in the form of a slit or a cooling hole. A copper alloy is known from US Pat. No. 2 1 5 5 40 5 and contains 0. 25-3% nickel, 0.05-0.6 phosphorus, the balance being copper. This is the alloy of the conductive iridium preset. It has conductivity of 67% I ACS and high tensile strength. 1264469 xf, I Q t|

’㈣修(家)jL本J 五、發明說明(2 ) 又由EP-A1-ο 249 740號已知有析出硬化性銅合金, 由0.2-1.2%鎳和0.04 - 0.25%磷組成。此合金可應用在連 續鑄型之製造材料,以連續鑄造高熔點金屬。基於數小時 的析出硬化處理,此材料可達成硬度ΗΒ 2.5/62.5超過 1 1 5 〇 本發明之目的,在於提供宜作爲坩堝加入熔體和非熔 體設備內所用之材料,除所需熱機械特性外,具有傑出的 焊接性。 另方面提供視需要由多成份組成的金屬熔體用容器之 適當製法。 此目的之解決方式,一方面在於應用一種銅合金,包 含0.2-1.5%鎳,0.002-0.12%選自包含磷、銘、猛、鋰、 15、鎂、砂、硼組群之至少一元素,選用達〇 · 3%銷,其 餘爲包含銅而視製造狀況而定之雜質,作爲材料,以非析 出硬化狀態,來製造容納金屬熔體之容器,例如熔體和非 熔體設備用之坩堝。 本發明所應用合金更好是含0.6-1.3%鎳,〇.〇 u.Q6% 選自包含硼、鎂和磷組群之至少一元素,基餘爲包含銅而 視製造情況而定之雜質。 爲提高強度,合金內宜引進0·01至頂多0.3 %銷。 本發明目的之製法部份的解決方式,列於申請專利範 圍第5至6項。</ br> (4) 修 (家) jL本J. 5. Description of the invention (2) A precipitation hardenable copper alloy is known from EP-A1-o-249,740, which consists of 0.2-1.2% nickel and 0.04 - 0.25% phosphorus. This alloy can be applied to continuous casting of the material to continuously cast high melting point metals. Based on a few hours of precipitation hardening treatment, the material can achieve a hardness of 2.5/62.5 over 1 15 〇. The object of the invention is to provide a material suitable for use in the incorporation of melt and non-melt equipment, in addition to the required thermomechanical In addition to the characteristics, it has outstanding weldability. On the other hand, a suitable method for forming a container for a metal melt composed of a plurality of components as needed is provided. The solution to this object is, on the one hand, the use of a copper alloy comprising 0.2-1.5% nickel, 0.002-0.12% being selected from at least one element comprising phosphorus, Ming, Meng, Li, 15, magnesium, sand, boron groups, The Daxie 3% pin is used, and the rest is an impurity containing copper depending on the manufacturing conditions, and as a material, a non-precipitation hardening state is used to manufacture a container for accommodating the metal melt, such as a melt and a non-melt device. Preferably, the alloy used in the present invention contains 0.6-1.3% nickel, and 6%.〇 u. Q6% is selected from at least one element comprising a group of boron, magnesium and phosphorus, the basis being impurities comprising copper depending on the production. In order to improve the strength, the alloy should be introduced from 0. 01 to the top 0.3% pin. The solution to the method part of the object of the present invention is listed in items 5 to 6 of the patent application.

Claims (1)

1264469 押:〜.// r: % ϊ匕各: — - — - -- --- '_.---. - -w .二- ·ι^六、申請專利範圍 第90 1 1 647 8號「銅-鎳合金及其容器之製造方法」專利 案 (91年9月修正) 六申請專利範圍: 1· 一種銅合金,其處於非硬化狀態,由〇 · 6至1 . 3%之 鎳’ 0 · 01至〇 . 06%之含有磷,鎂及硼之組中之-少 一種元素所組成,其餘成份包含銅在內之視製造情 況而定之雜質作爲可焊接之材料以製造可容納金屬 熔體之容器,例如熔體-和非熔體設備用之坩禍。 2·如申請專利範圍第1項之銅合金,其中鎳含量爲 1 ·0至1 .3%,而磷含量計〇.〇1至0.0 3%。 3·如申請專利範圍第1或2項之銅合金,其中另含達 0.3%之銷。 4. 一種如申請專利範圍第丨至3項中任一項之銅合金 所構成金屬熔體用之容器之製造方法,其特徵爲合 金在加溫成型後以靜態之周圍空氣來冷卻。 5·如申請專利範圍第4項之製造方法,其中加溫成型 後的合金至少1 0%受到冷加工。 6·如申請專利範圍第5項之製造方法,其中在加溫轉 型狀態中所存在之合金之冷加工和隨後的焊接須互 相調整,使焊接縫的強度和導電性相對於基材相對 應之特性値之差(difference)不超過15%者。1264469 押:~.// r: % ϊ匕 :: — — — — -- --- '_.---. - -w . 二 - · ι^6, the scope of application for patents 90 1 1 647 8 Patent No. "Manufacturing Method for Copper-Nickel Alloy and Its Container" (Amended in September 1991) Six patent applications: 1. A copper alloy in a non-hardened state, from 〇·6 to 1.3% nickel ' 0 · 01 to 〇. 06% of phosphorus, magnesium and boron in the group consisting of one less element, the remaining components including copper, depending on the manufacturing conditions, as impurities can be welded to make metal Containers for melts, such as melt-and non-melt equipment, are used. 2. A copper alloy as claimed in item 1 of the patent application, wherein the nickel content is from 1.00 to 1.3%, and the phosphorus content is from 〇1 to 0.03%. 3. If the copper alloy of claim 1 or 2 is applied, the other contains 0.3% of the sales. A method of producing a container for a metal melt composed of a copper alloy according to any one of claims 3 to 3, characterized in that the alloy is cooled by static ambient air after being heated and formed. 5. The manufacturing method of claim 4, wherein at least 10% of the alloy after warm molding is subjected to cold working. 6. The manufacturing method of claim 5, wherein the cold working and subsequent welding of the alloy existing in the heating transition state are mutually adjusted so that the strength and electrical conductivity of the welded joint are relative to the substrate. The difference between no more than 15%.
TW090116478A 2000-07-07 2001-08-02 Copper-nickel-alloy and production method for its container TWI264469B (en)

Applications Claiming Priority (1)

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DE10032627A DE10032627A1 (en) 2000-07-07 2000-07-07 Use of a copper-nickel alloy

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TWI264469B true TWI264469B (en) 2006-10-21

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US (1) US20020005235A1 (en)
EP (1) EP1170074A1 (en)
JP (1) JP2002053921A (en)
KR (1) KR20020003507A (en)
CN (1) CN1261604C (en)
AR (1) AR029563A1 (en)
AU (1) AU5403801A (en)
BR (1) BR0102767A (en)
CA (1) CA2352638A1 (en)
CZ (1) CZ20012424A3 (en)
DE (1) DE10032627A1 (en)
MX (1) MXPA01006886A (en)
PL (1) PL348478A1 (en)
RU (1) RU2001119000A (en)
TR (1) TR200101997A2 (en)
TW (1) TWI264469B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10237052A1 (en) * 2002-08-09 2004-02-19 Km Europa Metal Ag Use of a low-alloy copper alloy and hollow profile component made from it
JP4312641B2 (en) 2004-03-29 2009-08-12 日本碍子株式会社 Copper alloy having both strength and conductivity and method for producing the same
CN1300353C (en) * 2004-05-28 2007-02-14 四川省宇太科技有限公司 Copper alloy with high thermal conductivity
US8956600B2 (en) 2009-08-10 2015-02-17 Taiwan Liposome Co. Ltd. Ophthalmic drug delivery system containing phospholipid and cholesterol
JP2012051766A (en) * 2010-09-02 2012-03-15 Sumco Corp Continuous casting method of silicon ingot
CN109079116A (en) * 2018-07-10 2018-12-25 浙江力博实业股份有限公司 A kind of preparation method of electrode material corson alloy
DE102018122574B4 (en) * 2018-09-14 2020-11-26 Kme Special Products Gmbh Use of a copper alloy
CN109706343A (en) * 2018-12-10 2019-05-03 上海海亮铜业有限公司 A kind of nickel doping C12200 red copper alloy
CN112375939B (en) * 2020-11-16 2021-11-09 福州大学 Cu-Ni-Zr-V-B copper alloy material and preparation method thereof
CN114540660A (en) * 2021-11-11 2022-05-27 佛山中国发明成果转化研究院 High-strength high-conductivity copper alloy and preparation method thereof

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US2155405A (en) * 1938-04-28 1939-04-25 Chase Brass & Copper Co Electrical conductor
DE3760850D1 (en) * 1986-06-20 1989-11-30 Kabelmetal Ag Using a copper alloy
DE3620654A1 (en) * 1986-06-20 1987-12-23 Kabel Metallwerke Ghh COPPER ALLOY
DE3725950A1 (en) * 1987-08-05 1989-02-16 Kabel Metallwerke Ghh USE OF A COPPER ALLOY AS A MATERIAL FOR CONTINUOUS CASTING MOLDS
DE4427939A1 (en) * 1994-08-06 1996-02-08 Kabelmetal Ag Use of a hardenable copper alloy

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RU2001119000A (en) 2003-06-27
CN1261604C (en) 2006-06-28
BR0102767A (en) 2002-02-19
CA2352638A1 (en) 2002-01-07
TR200101997A3 (en) 2002-02-21
JP2002053921A (en) 2002-02-19
AU5403801A (en) 2002-01-10
CZ20012424A3 (en) 2002-07-17
AR029563A1 (en) 2003-07-02
CN1332258A (en) 2002-01-23
PL348478A1 (en) 2002-01-14
KR20020003507A (en) 2002-01-12
MXPA01006886A (en) 2003-08-20
TR200101997A2 (en) 2002-02-21
US20020005235A1 (en) 2002-01-17
DE10032627A1 (en) 2002-01-17
EP1170074A1 (en) 2002-01-09

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