TWI259527B - Processing system and method for treating a substrate - Google Patents

Processing system and method for treating a substrate Download PDF

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Publication number
TWI259527B
TWI259527B TW94110006A TW94110006A TWI259527B TW I259527 B TWI259527 B TW I259527B TW 94110006 A TW94110006 A TW 94110006A TW 94110006 A TW94110006 A TW 94110006A TW I259527 B TWI259527 B TW I259527B
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Taiwan
Prior art keywords
substrate
processing
gas
amount
chemical
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TW94110006A
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Chinese (zh)
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TW200540982A (en
Inventor
Hongyu Yue
Asao Yamashita
Fumihiko Higuchi
Hiroyuki Takahashi
Akiteru Ko
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Tokyo Electron Ltd
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Priority claimed from US10/704,969 external-priority patent/US7079760B2/en
Priority claimed from US10/705,397 external-priority patent/US7214274B2/en
Priority claimed from US10/705,200 external-priority patent/US6951821B2/en
Priority claimed from US10/705,201 external-priority patent/US7029536B2/en
Priority claimed from US10/812,347 external-priority patent/US20050227494A1/en
Application filed by Tokyo Electron Ltd filed Critical Tokyo Electron Ltd
Publication of TW200540982A publication Critical patent/TW200540982A/en
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Publication of TWI259527B publication Critical patent/TWI259527B/en

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Abstract

A method and system for trimming a feature on a substrate is described. During a chemical treatment of the substrate, the substrate is exposed to a gaseous chemistry, such as HF/NH3, under controlled conditions including surface temperature and gas pressure. An inert gas is also introduced, and the flow rate of the inert gas is selected in order to affect a target trim amount during the trimming of the feature.

Description

1259527 九、發明說明: 相關申請案之交互春照資料 本申請案係相關於審理中的美國專利申請序號10/705, 201, 名稱為『用來處理基板之加工糸統與方法(Processing System and 、 Method For Treating a Substrate)』,申請日為 2003 年 11 月 12 ' 日;審理中的美國專利申請序號10/705,200,名稱為『化學處理 基板之加工系統與方法(Processing System and Method For1259527 IX. INSTRUCTIONS: Interactive Spring Photographs of Related Applications This application is related to the copending U.S. Patent Application Serial No. 10/705,201, entitled "Processing System and Process for Processing Substrates" Method For Treating a Substrate), the application date is November 12, 2003; the US patent application serial number 10/705,200, entitled "Processing System and Method For Chemical Processing Substrate"

Chemically Treating a Substrate)”,申請曰為 2003 年 11 月 12 -日;審理中的美國專利申請序號10/704, 969,名稱為『熱處理基 板之加工系統與方法(Processing System and Method For • Thermally Treating a Substrate)”,申請日為 2003 年 11 月 12 ^日;審理中的美國專利申請序號1〇/705,397,名稱為『使鄰近溫 度控制室絕熱之方法與設備(Method and Apparatus F〇r"Chemical Treating a Substrate"", application 11 November 12, 2003; US Patent Application Serial No. 10/704, 969, entitled "Processing System and Method For • Thermally Treating" a Substrate)", the filing date is November 12, 2003; the US patent application number 1〇/705,397, entitled "Methods and Apparatus for Insulating Adjacent Temperature Control Chambers" (Method and Apparatus F〇r

Thermally Insulating Adjacent Temperature Controlled Chambers)”,申請日為洲的年丨丨月12日;以及審理中的美國專 利申請序號10/ΧΧΧ,ΠΧ,,名稱為『使用局部壓力來調整化學氧化 and Syste, For Adjust"nTa hemical Oxide Removal Process Using Partial Pressure)11 ^ :件編號〇71469—__,其申請日與本案相同。所有的 _那些申請案之整體内容的全部係於此列入參考資料。 【發明所屬之技術領域】 之化方法與系統,尤有關-種基板 【先前技術】 線或板電雜刻製程以沿著細 =除或崎才料。電漿侧製程一“二 ΐ 個轉體基板配置於—加工i室 -將基板女置在m就可以_縣指定的流動速率將 1259527 =種=子化之解離氣體(dlssociatlvegas)混合物導入容室 使-紅泵節加達到—環境製鍾力。 過射雜F)功率之傳送而被感應式或 子用以分解多種環境縫種類之某些種類 ί程係被調整以達到包含期望的反應物與離子 "、田,辰度之適當條件,用以在基板之選定區域中蝕刻各種 之溝:f道、接觸部、閘等)。這種需要蝕刻 % 3 —祕挪1()2)、低k介電材料、多晶賴氮化石夕。 相間,侧這種特徵部—般包含將形成於n 圖案轉移至内部形成有各種特徵部之下層薄膜。此光罩 轉移够絲)+之一圖案 【發明内容】 種化 方法在之—個ί施樣態中,說明—種用來處理基板之加工 之/-終敕旦在:化學氧化物移除製程巾達成—基板上之-特徵部 定-製=方=;:Γί方;, 製程氣體之—數;中:f :包含:設定-第- 該美;te卜夕"二正里,猎由使用5玄製程配方暴露該基板來化學處理 /土才太;?、"特徵部;以及實質上從該·部移除該修整量。 工方法,it另—個實施樣‘態中,說明—觀來處理基板之加 -使用一化學氧化物移除製程來修整一基板上之一特徵 1259527 以下步驟:決定在該特徵部之-倏敕旦盘一 ^ 2與一第二製程氣體之一數立Tj;弟:j程氣體之- ;;藉由使該基板暴露至該數量之該口 達成該哪整 弟一製程氣體、以及該目桿^私軋體、該數量之該 該特徵部,·以及”二來化學處理雜板上之 加4i用s另::實施樣態中’說明-種用來處理基板之Thermally Insulating Adjacent Temperature Controlled Chambers)", the application date is 12th of the year of the continent; and the US patent application number 10/ΧΧΧ, ΠΧ, under the name "Use local pressure to adjust chemical oxidation and Syste, For Adjust"nTa hemical Oxide Removal Process Using Partial Pressure) 11 ^ : Part No. 46971469—__, the filing date is the same as the case. All the contents of the _ those applications are included in the reference materials. Technical field] The method and system are especially related to the kind of substrate [Prior Art] The wire or plate electro-engraving process is to follow the fine = stripping or scraping. The plasma side process is one "two turn substrate configuration" In the processing of the i-room - the substrate can be placed in m, the flow rate of 1259527 = seed = sub-dissociated gas (dlssociatlvegas) can be introduced into the chamber so that the - red pump section is added - the environmental clock force. The transmission of power by the infrasound F) is inductively or sub-decomposed to decompose certain types of environmental seam types. The range is adjusted to achieve the desired conditions for the reactants and ions, and the appropriate conditions for the ions. Used to etch various trenches in selected areas of the substrate: f-channels, contacts, gates, etc.). This requires etching of % 3 — Secret 1 () 2), low-k dielectric material, and polycrystalline silicon nitride. In contrast, the side features generally include a film that is formed by transferring the n pattern to the underside of various features. The reticle transfer is sufficient for the silk) + one of the patterns [invention] The method of cultivating in the form of a method for processing the substrate is processed in the following: chemical oxide removal The process towel is reached - on the substrate - the characteristic part - system = square =;: Γ ί side;, the process gas of the number; the middle: f: contains: set - the first - the beauty; te 卜 夕 &"; The hunting is performed by exposing the substrate using a 5 stencil formulation to chemically treat the soil; the "features; and substantially removing the trimming amount from the portion. Work method, it is another implementation example, the description - the processing of the substrate is added - using a chemical oxide removal process to trim a feature on a substrate 1259527 The following steps: decide on the feature - And the second process gas is one of the second process gases, and the first process gas is obtained by exposing the substrate to the number of the ports, and The target rod ^ private rolling body, the number of the feature portion, and "two to the chemical processing of the miscellaneous board plus 4i with s another:: implementation of the state" description - used to treat the substrate

化石夕特徵部之—修整量,該方法包含以下Ιί成:基板上^一氧 移除製程設定一费藉西古甘 —·為该化學氧化物 設定邢之-數量,収設定、驟包含: 製程調整該製程配方,以鮮Hit為^化學氧化物移除 彳ί部藉程配方暴板=學以= 該數旦:兮二亥5係獨立於该數量之該·而被導入’而 i部該ΐ量之該題3 一起被導入;以及實質上從該特 敕i夕矛、乡正里,其中增加該數量之該氬氣係對應至減少該修 在本發明之又另一個實施樣態中,一種用來處理基板之加工 f統a,用以在一化學氧化物移除製程中達成一基板上之一修整 ^旦該系,包含··一化學處理系統,用以藉由使該基板暴露至一 丈里之二第一製程氣體、一數量之一第二製程氣體、以及一數量 之一鈍氣來改變該基板上之複數個露出表面層;一熱處理系統, 用以熱處理該基板上之該等化學改變表面層;以及一控制器,其 連接至該化學處理系統並具體形成以調整該數量之該鈍氣,以便 達成該修整量。 【實施方式】 在材料加工方法學中,圖案蝕刻包含將光敏材料之一薄層(例 如光阻)塗敷至一基板之一上表面,其接著被圖案化以便提供一光 •1259527 ㈣iculex與相關光學元V而=系充 使用-顯影溶劑移除光敏材料之^昭射H原;^曝光’接著藉由 下)或未受照射區域(當在負光阻的^下)'(田在正先阻的狀況 舉例中之特· 光層中之光罩圖案係在刻一賴中之特徵部時,感 的侧步驟而被轉移至使用-單獨 罩層之露出表面之化學處理以便改變硬性光罩層之表光 =了種硬性光罩層之露出表面之後處理以便釋出改變的=化 理- 2之们Γ U1A顯現出藉由使用譬如光罩層修整來處 1。加工系統1包含-第-處咖。, 含-埶處理于f糸統,而弟二處理系統20可包 二=ί ί、ί弟二處理系統2g可包含—基板清洗系統, ΐΐ;4ίί ΐ。又,如圖1A所示,一傳送系統30可以連接至 Li: 便將基板傳送進出第一處理系統ι〇與第二處 会二m川亚一—多兀件製造系統40交換基板。第一與第二處理 糸j 10、2〇 :乂及傳送系統%可譬如包含在多元件製造系統4〇内 3勺口人ίϊ °舉例而言’多元件製造系統40可允許將基板傳送 刻系統、沈積系統、塗佈系統、®案化系統、度量 二;制5樣的裝置之加玉元件。為了隔離發生在第—與第二系 、充中衣程,可利用一絕緣組件50以連接每個系統。例如,絕緣 1259527 ,件50可包含提供絕熱之一絕熱組件以及提供真空絕緣之一閘閥 組件之至少一個。當然,可以依任何順序來設置處理系統1〇與2〇 . 以及傳送系統30。 /、 ; 或者,在另一個實施例中,圖1B顯現出藉由使用例如光罩層 :之一製程來處理一基板之一加工系統100。加工系統100包^ 了第一處理系統110與一第二處理系統120。舉例而言,第一處理 系統110可包含一化學處理系統,而第二處理系統12〇可包含一 .熱處理系統。或者,第二處理系統120可包含一基板清洗系統, ,如一水洗系統。又,如圖1B所示,一傳送系統130可以連接至 、鲁第一處理系統11〇以便將基板傳送進出第一處理系統110,且可以 連接至弟一處理系統120以便將基板傳送進出第二處理系統 |2〇。此外,傳送系統130可與一個或多個基板晶舟盒(未顯示)交 奐基板。雖然圖1B只顯示兩個加工系統,但其他加工系統可接達 至包,像姓刻系統、沈積系統、塗佈系統、圖案化系統、度量衡 系統等這樣的裝置之傳送系統130。為了隔離發生在第一與第二系 ,中之製程,可利用一絕緣組件15〇以連接每個系統。例如,絕 緣組件15〇可包含提供絕熱之一絕熱組件以及提供真空絕緣之一 閘閥組件之至少一個。此外,舉例而言,傳送系統130可作為絕 緣組件150之一部分。 • 或者,在另一個實施例中,圖1C顯現出藉由使用例如光罩層 b整之一製程來處理一基板之一加工系統6〇〇。加工系統6⑼包含 一第^處理系統610與一第二處理系統62〇,其中第一處理系統 =〇係〕如所示朝一垂直方向堆疊在第二處理系統62〇上面。舉例而 ϋ,第一處理系統610可包含一化學處理系統,而第二處理系統 =〇可包含一熱處理系統。或者,第二處理系統62〇可包含一基板 清洗系統,例如一水洗系統。又,如圖1C所示,一傳送系統63〇 可以連接至第一處理系統610以便將基板傳送進出第一處理系統 610/且可以連接至第二處理系統62〇以便將基板傳送進出第二處 理系統620。此外,傳送系統63〇可與一個或多個基板晶舟盒(未 1259527 顯示巧奐基板。雖然圖lc只顯示兩個加工系統.,但並他加 ί 口系統、沈積系統、塗佈系統、圖案化系統' ί 之傳送系統630。為了隔離發生在第-與 弟一糸、,先中之衣私,可利用一絕緣組件650以連接每個 ^ ’絕緣組件650可包含提供絕熱之一絕熱組件以及提供直 作為絕緣組細之it此外舉例而「傳送系統630可 第一處描綠之加工系統1之第—處理系統10與 ^, : 2f4 送系統30之間通過,而第二鈐详門〇却々4 ^丄14傳 ,二處理系統之間通過。二 elo™^ 刀目^ ^ y —輸销σ部以允許基板經由它通過。 ,現在f考圖2,提供用以執行-基板之化學處理盘敎處理之一 加工糸統200。加工系統2〇〇包含一仆風卢 :…、 熱處理系統“ 可藉由使用-絕数纟且件23G ^處,t 與熱處理容室221 件2:=絕更= 支標-基板242;-直ί f/211絕熱細己置以 以抽空化學處理容室211 連接至化學處理容室211 程氣體導入至化學處理容室用以將一製 如圖2與5所示,敎處理j工間262中。 部270,其被安餘熱處理容室'2=並Fossil eve feature - the amount of dressing, the method includes the following: 基板 成 : 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 基板 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西 西Process adjustment of the process recipe, with fresh Hit for chemical oxide removal 彳 部 借 借 借 配方 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = The problem 3 of the measurement is introduced together; and substantially from the special 敕伊夕矛, 乡正里, wherein the amount of the argon gas system is increased to reduce the repair of another embodiment of the present invention In the state, a processing for processing a substrate is used to achieve a process on a substrate in a chemical oxide removal process, including a chemical processing system for The substrate is exposed to one second of the first process gas, one quantity of the second process gas, and one quantity of the blunt gas to change the plurality of exposed surface layers on the substrate; a heat treatment system for heat treating the substrate The chemically altered surface layer on the substrate; and a control , Which is coupled to the chemical treatment system and in particular to adjust the amount of formation of the noble gas, in order to achieve the trimming amount. [Embodiment] In the material processing methodology, pattern etching comprises applying a thin layer (for example, photoresist) of a photosensitive material to an upper surface of a substrate, which is then patterned to provide a light 1259527 (four) iculex and related The optical element V is used to charge the developing material to remove the photosensitive material. The exposure is followed by the lower or the unexposed area (when under the negative photoresist). In the case of the first resistance example, the reticle pattern in the optical layer is in the engraved feature, and the side step of the sensation is transferred to the chemical treatment of the exposed surface of the use-separate cover layer to change the hard light. The surface of the cover layer = the exposed surface of the hard mask layer is processed to release the change = chemistry - 2 Γ U1A appears to be trimmed by using, for example, a mask layer. The processing system 1 contains - The first-place coffee., contains -埶 processing in the f system, and the second processing system 20 can include two = ί ί, ί 弟 二 processing system 2g can include - substrate cleaning system, ΐΐ; 4 ίί ΐ. Also, as shown As shown in FIG. 1A, a transfer system 30 can be connected to Li: to transfer the substrate in and out. A processing system ι〇 exchanges the substrate with the second meeting, the first and second processes 10j 10, 2: 乂 and the transmission system % can be included in the multi-component manufacturing For example, 'multi-component manufacturing system 40 can allow substrate transfer system, deposition system, coating system, system, system metric 2; In order to isolate the occurrence of the first and second systems, the insulative assembly 50 may be utilized to connect each system. For example, the insulation 1259527, the member 50 may include an insulating component that provides insulation and provides vacuum insulation. At least one of the gate valve assemblies. Of course, the processing systems 1 and 2 can be disposed in any order and the delivery system 30. Alternatively, in another embodiment, FIG. 1B appears to be utilized by using, for example, a mask. Layer: One process to process a substrate processing system 100. The processing system 100 includes a first processing system 110 and a second processing system 120. For example, the first processing system 110 can include a chemical processing system. The second processing system 12A may include a heat treatment system. Alternatively, the second processing system 120 may include a substrate cleaning system, such as a water washing system. Also, as shown in FIG. 1B, a delivery system 130 may be coupled to Ludi. A processing system 11 is configured to transport the substrate into and out of the first processing system 110 and can be coupled to the processing system 120 for transporting the substrate into and out of the second processing system. Further, the delivery system 130 can be coupled to one or more substrates. The boat box (not shown) is transferred to the substrate. Although Figure 1B shows only two processing systems, other processing systems can access the package, such as surname system, deposition system, coating system, patterning system, metrology system, etc. A delivery system 130 of such a device. In order to isolate the processes occurring in the first and second systems, an insulating component 15 can be utilized to connect each system. For example, the insulating component 15A may include at least one of an insulating component that provides insulation and a gate valve component that provides vacuum insulation. Moreover, for example, delivery system 130 can be part of an insulated component 150. • Alternatively, in another embodiment, Figure 1C illustrates the processing of a substrate processing system 6 by using a process such as a mask layer b. The processing system 6 (9) includes a first processing system 610 and a second processing system 62, wherein the first processing system is stacked on the second processing system 62 in a vertical direction as shown. By way of example, the first processing system 610 can include a chemical processing system and the second processing system can include a thermal processing system. Alternatively, the second processing system 62 can include a substrate cleaning system, such as a water wash system. Also, as shown in FIG. 1C, a transport system 63A can be coupled to the first processing system 610 for transporting substrates into and out of the first processing system 610/ and can be coupled to the second processing system 62 to transport substrates into and out of the second processing. System 620. In addition, the transport system 63 can be combined with one or more substrate boat cassettes (the 1259527 does not display a clever substrate. Although Figure lc shows only two processing systems, it adds a system, a deposition system, a coating system, Patterning system ' ί's transport system 630. In order to isolate the first and the other, an insulating component 650 can be used to connect each of the insulating components 650 can include an insulating component that provides thermal insulation. And providing the direct as the insulation group. In addition, the "transport system 630 can be the first processing system 1 of the first green processing system - the processing system 10 and ^, : 2f4 delivery system 30 pass, and the second detailed door 〇 々 丄 4 ^ 丄 14 pass, between the two processing systems. Second eloTM ^ knife ^ ^ y - the output σ part to allow the substrate to pass through it. Now f test 2, provided to perform - substrate The chemical treatment of the coil processing is one of the processing systems 200. The processing system 2〇〇 contains a servant wind: ..., the heat treatment system "can be used by using - the absolute number and the parts 23G ^, t and the heat treatment chamber 221 pieces 2:= absolutely = the standard - the substrate 242; - straight ί f / 211 thermal insulation The gas is introduced into the chemical treatment chamber 211 by the evacuation chemical treatment chamber 211. The gas is introduced into the chemical treatment chamber for processing as shown in Figs. 2 and 5, and is processed in the chamber 262. Refining heat treatment chamber '2=and

10 1259527 it至田巴熱且被配置以支樓一基板242,; 一真空抽氣系統 空熱處理容室221 ;以及一基板升降桿組件290,其 ίΐίϊίΐ1容室22卜升降桿組件290可在-支持平面(實線) /其二%9, 27〇(虛線)或位於其間之一傳送平面之間垂直移動 I扳M2 。熱處理容室221可更包含一上部組件284。 1 ^學處理容室211、熱處理容室221以及絕熱組件23〇 =、:/、同開口部294,-基板可經由此共同開口部294而被運 工期間,共同開口部294可藉由使用一閘閥組件296而 ^封封閉,以便允許在兩個容室犯、221中獨立加工。再者, 輸达開口部298形成於熱處理容室221中,以便允許利用 基板交換,如圖1A所示。舉例而言,一第二絕熱組 M 貝現以使熱處理容室221與一傳送系統(未顯示)絕 ^、、。雖然開口部298係顯示為熱處理容室221之一部分(盥圖1A 才目符),但可使輸送開口部298形成於化學處理容室211中、而非熱 中(如圖1㈣示之相反容室位置),或可使輸送開口 I 8形成於化學處理容室211與熱處理容室221兩者中(如圖1Β 興1C所示)。 女口圖2與3所示,化學處理系統21〇包含一基板支撐部24〇 基板支撐部組件244,以便提供數個熱控制與加工基板242 =操作功能。基板支撐部240與基板支撐部組件244可包含一靜 ,夾持系統(或機械夾持系統)以便電性地(或機械地)將基板2犯 夹至基板支撐部240。再者,基板支撐部24〇可譬如更包含具有一 再循ί裒冷卻劑流之-冷卻系統,其接受來自基板支撐部%◦之熱 f傳送熱至-熱父換器系統(未顯示),或在加熱時,從熱交換器 ίϊ傳送ΐ。此外,—熱傳輸氣體可譬如經由—背面氣體系統^ 破傳运至基板242之背面,用以改善基板242與基板支撐部24〇 ,間的氣體-間隙之熱導。例如,提供至基板Mg之背面之熱 乳體了包,例?氦氣、氬氣、氤、氪之贼,製程氣體,或其他 歹如氧、氮或氫之氣體。當於升高或降低溫度時要求溫度控制基 11 1259527 個區Hr由、、_3種f:統。舉例而言’背面氣體系統可包含例如兩 間ϋ *二ίΐ)系統之—多區間氣體分配系統,其中背面氣體 可以在基板242之中心與邊緣之間獨立改變。在直他實 阻加氣件之加熱/冷卻7^件,賴電熱器〉冷卻 ί 撐部24G中,與在化學處理容室211之容室 支現出用以執行數個上述功能之一溫控基板 L基板支撐部聊包含:—容室接合元件31〇,其連接 接人ΐίΐΐ室211之—下壁面;—絕緣元件312,其連接至容室 ,,以及一溫度控制元件314,其連接至絕緣元件312。 =接溫度控制讀310、314可譬如是由例如紹、不銹鋼、 ,等之-電性與熱傳導材料所製造。絕緣元件312可嬖如是由且 的熱傳導係數之例如石英、氧化鋁、鐵氟隆等之耐熱; 溫度控制元件314可包含例如冷卻通道、加熱通道、電阻加 :、、、元件’或熱電性元件之溫度控制元件。舉例而言,如圖示, 血度控制元件314包含具有一冷卻劑入口 322與一冷卻劑出口 324 ,-冷卻劑通道320。冷卻劑通道32〇可譬如是在溫度控制元件 〃内之螺旋形通過,其允許例如水、Fiu〇rinert(商標名)、 魯GaldenHT 135(商標名)專之冷卻劑之一流動速率,以便提西 控制兀件314之傳導-對流冷卻。或者,溫度控制元件314可包$ 、/熱電性元件陣列,其能依據電流流經各個元件之方向來加熱或 冷部一基板。一種例示的熱電性元件係為商業上可購自Advancd10 1259527 it to Tata hot and configured to support a substrate 242; a vacuum pumping system hollow heat treatment chamber 221; and a substrate lifting rod assembly 290, which can be used in the chamber 22 Support plane (solid line) / its two %9, 27〇 (dashed line) or vertically move between the transfer planes in between one I M2. The heat treatment chamber 221 may further include an upper assembly 284. 1 ^ processing chamber 211, heat treatment chamber 221 and heat insulating member 23 〇 =, : /, with the opening portion 294, - the substrate can be transported through the common opening portion 294, the common opening portion 294 can be used A gate valve assembly 296 is sealed to allow for independent processing in the two chambers, 221. Further, the delivery opening portion 298 is formed in the heat treatment chamber 221 to allow the substrate to be exchanged as shown in Fig. 1A. For example, a second thermal insulation group M is now used to terminate the heat treatment chamber 221 with a delivery system (not shown). Although the opening portion 298 is shown as a portion of the heat treatment chamber 221 (not shown in FIG. 1A), the delivery opening portion 298 may be formed in the chemical processing chamber 211 instead of in the heat (as shown in FIG. 1 (d)). Position), or the delivery opening I 8 may be formed in both the chemical processing chamber 211 and the heat treatment chamber 221 (as shown in Fig. 1C1C). As shown in Figures 2 and 3, the chemical processing system 21A includes a substrate support portion 24, a substrate support portion assembly 244, to provide a plurality of thermal control and processing substrates 242 = operational functions. The substrate support portion 240 and the substrate support assembly 244 can include a static, clamping system (or mechanical clamping system) to electrically (or mechanically) clamp the substrate 2 to the substrate support portion 240. Furthermore, the substrate support portion 24 may further comprise a cooling system having a recirculating coolant flow that receives heat from the substrate support portion to transfer heat to the hot parent converter system (not shown). Or when heating, transfer the crucible from the heat exchanger. In addition, the heat transfer gas can be transported to the back surface of the substrate 242 via a back-side gas system, for example, to improve the gas-gap thermal conduction between the substrate 242 and the substrate support portion 24b. For example, a hot emulsion provided to the back side of the substrate Mg is packaged, for example? Helium, argon, helium, thieves, process gases, or other gases such as oxygen, nitrogen or hydrogen. When the temperature is raised or lowered, the temperature control base is required. 11 1259527 Areas Hr are, and _3 types are f:. For example, a backside gas system can include, for example, two inter-system gas distribution systems in which the backside gas can be independently varied between the center and the edge of the substrate 242. In the heating/cooling of the gas-curing member, the heating device is cooled, and the chamber 24 of the chemical processing chamber 211 is used to perform a plurality of the above functions. The control substrate L substrate support portion includes: a chamber engagement member 31〇 connected to the lower wall of the chamber 211; an insulating member 312 connected to the chamber, and a temperature control member 314 connected To the insulating member 312. The temperature control reads 310, 314 can be fabricated, for example, from electrically and thermally conductive materials such as Sho, stainless steel, and the like. The insulating member 312 can be heat resistant, such as quartz, alumina, Teflon, etc.; the temperature control element 314 can include, for example, a cooling channel, a heating channel, a resistor plus, a component, or a thermoelectric component. Temperature control element. For example, as illustrated, blood control element 314 includes a coolant inlet 322 and a coolant outlet 324, a coolant passage 320. The coolant passage 32 can be spirally passed through, for example, within the temperature control element, which allows for a flow rate of one of the coolants such as water, Fiu〇rinert (trade name), and Lu Galden HT 135 (trade name), in order to Conduction-convection cooling of the west control element 314. Alternatively, temperature control component 314 can include an array of /, thermoelectric elements that can heat or cool a substrate depending on the direction of current flow through the various components. An exemplary thermoelectric element is commercially available from Advancd.

Thermoelectric 的一個元件,型號 ST—127-i· 4-8· 5M(具有 72 f 之最大熱能傳遞功率之4〇麵X 40誦X 3· 4 mm熱電ί生裝置)。 ^外,基板支撐部300可更包含一靜電夾(esc)328,其包含 一陶瓷層330、埋入其中之一夾持電極332及藉由使用一電連接部 336而1接。至夾持電極332之一高電壓(HV)DC電壓源334。既3& 可譬如是單極或雙極。這種靜電夾之設計與實行係為熟習靜電夾 12 1259527One component of Thermoelectric, model ST-127-i· 4-8· 5M (4 〇 X 40诵X 3· 4 mm thermoelectric device with a maximum thermal energy transfer of 72 f). In addition, the substrate support portion 300 may further include an electrostatic chuck (esc) 328 including a ceramic layer 330, one of the clamping electrodes 332 embedded therein, and connected by using an electrical connection portion 336. To a high voltage (HV) DC voltage source 334 of the clamping electrode 332. Both 3& can be unipolar or bipolar. The design and implementation of this electrostatic clamp is familiar with electrostatic clamps 12 1259527

持系統之本項技藝者所熟知的。 一此外,基板支撐部300可更包含一背面氣體供應系統340,用 以經由至少一條氣體供應線342以及複數個孔與通道之至少一個 將一熱傳輸氣體(例如包含氦氣、氬氣、氙、氪之鈍氣,製程氣體, 或其他包含氧、氮或氫之氣體)提供給基板242之背面。背面氣體 供應,統340可譬如是例如兩個區間(中心—邊緣)系統之一多區間 供應系統’其中背面壓力可從中心至邊緣呈放射狀改變。 絕緣元件312可更包含一絕熱間隙350,以便提供溫度控制元 件314兵下層接合元件310之間的額外絕熱。絕熱間隙350可藉 由使用一抽排氣系統(未顯示)或作為真空抽氣系統25〇之一部分 或連接至一氣體供應部(未顯示)之一真空線而被抽空,以便改 變其熱傳導係數。氣體供應部可譬如是被利用以將熱傳輸氣體連 接至基板242之背面之背面氣體供應部34〇。 、接合元件310可更包含一升降銷組件36〇,其能舉起與降低三 三個以上的升降銷362,以便垂直移動基板242來回基板支 邛30^之一上表面與加工系統中之一傳送平面。 每個元件310—、312與314更包含扣接裝置(例如螺栓與螺紋 —$彳更f 一個兀件扣接於另一個元件,並將基板支撐部300固 =至化學處理容室2Π。再者,每個元件310、312與314幫助上This technique is well known to those skilled in the art. In addition, the substrate supporting portion 300 may further include a back surface gas supply system 340 for transferring a heat transfer gas (for example, helium, argon, or neon via at least one gas supply line 342 and at least one of the plurality of holes and the channel). The blunt gas, process gas, or other gas containing oxygen, nitrogen or hydrogen is supplied to the back side of the substrate 242. The backside gas supply 340 can be, for example, a multi-zone supply system of one of two zone (center-edge) systems where the backside pressure can vary radially from the center to the edge. The insulating member 312 can further include an insulating gap 350 to provide additional thermal insulation between the temperature control element 314. The adiabatic gap 350 can be evacuated by using an exhaust system (not shown) or as part of the vacuum pumping system 25 or connected to a vacuum line of a gas supply (not shown) to change its heat transfer coefficient. . The gas supply portion can be utilized, for example, to connect the heat transfer gas to the back surface gas supply portion 34 of the back surface of the substrate 242. The engaging element 310 can further include a lift pin assembly 36〇 that can lift and lower three or more lift pins 362 to vertically move the substrate 242 back and forth to one of the upper surface of the substrate support 30 and the processing system. Transfer plane. Each of the elements 310-, 312, and 314 further includes a fastening device (e.g., a bolt and a thread - a member is fastened to the other member, and the substrate support portion 300 is fixed to the chemical processing chamber 2). Each element 310, 312 and 314 helps

個元件,且在f要維持加玉系統之真空完整性的 地方=關如合成橡膠〇型環之真空密封部。 埶^控pf Ϊ支^卩2仙之溫度可藉由使用例如熱電偶(例如K型 加…、裔7G件笔流或電壓敎帝驻罢 便影響基板支撐部二之、生荨之商至少一項,以 旦夂。U之皿度及/或基板242之溫度中的改變。 再茶考02與3,化學處理系統210包含-氣體分配系統260。 13 1259527 於一實施例中,如圖8所示,一氣體分配系統400包含一蓮蓬頭 氣體注入系統,其具有一氣體分配組件402以及連接至氣體分配 組件402並具體形成以形成一氣體分配充氣腔406之一氣體分配 板404。雖然未顯示,但氣體分配充氣腔406可包含一個或多個氣 體分配隔板。氣體分配板404更包含一個或多個氣體分配孔408 以將一製程氣體從氣體分配充氣腔406分配至化學處理容室211 内之製程空間。此外,一個或多個氣體供應線410、410’等可經由 譬如氣體分配組件而連接至氣體分配充氣腔406,以便供應包含一 . 種或多種氣體之一製程氣體。製程氣體可譬如包含NH3、HF、H2、 〇2、CO、C〇2、Ar、He 等。 在另一個實施例中,如圖9A與9B(圖9A之展開圖)所示,用 以分配包含至少兩種氣體之製程氣體之一氣體分配系統420包 含:一氣體分配組件422,其具有一個或多個元件424、426與428; 一第一氣體分配板430,連接至氣體分配組件422並具體形成以連 接一第一氣體與化學處理容室211之製程空間;以及一第二氣體 分配板432,其連接至第一氣體分配板430並具體形成以連接一第 二氣體與化學處理容室211之製程空間。第一氣體分配板430在 連接至氣體分配組件422時形成一第一氣體分配充氣腔440。此 外,第二氣體分配板432在連接至第一氣體分配板430時形成一 φ第二氣體分配充氣腔442。雖然未顯示,但氣體分配充氣腔440、 442可包含一個或多個氣體分配隔板。第二氣體分配板432更包 含:一第一陣列之一個或多個孔444,其連接至形成於第一氣體分 配板430内之一陣列之一個或多個通道446並與其共同產生;以 及一第二陣列之一個或多個孔448。與一個或多個通道446之陣列 相關,的第一陣列之一個或多個孔444係被具體形成以將第一氣 體從第一氣體分配充氣腔440分配至化學處理容室211之製程空 =。,二陣列之一個或多個孔448係被具體形成以將第二氣體從 第二氣體分配充氣腔442分配至化學處理容室211之製程空間。 ‘私氣體可譬如包含丽3、HF、H2、〇2、CO、C〇2、Ar、He等。因為Components, and where f is to maintain the vacuum integrity of the jade system = off the vacuum seal of the synthetic rubber ring.埶^ control pf Ϊ 卩 卩 仙 仙 仙 temperature can be used by using, for example, a thermocouple (such as K-type plus ..., 7G pieces of flow or voltage 敎 驻 罢 罢 影响 影响 影响 影响 影响 影响 影响 影响 影响 影响 影响 影响 影响A change in the temperature of the U and/or the temperature of the substrate 242. The tea treatments 02 and 3, the chemical processing system 210 includes a gas distribution system 260. 13 1259527 In one embodiment, As shown in Fig. 8, a gas distribution system 400 includes a showerhead gas injection system having a gas distribution assembly 402 and a gas distribution plate 404 coupled to the gas distribution assembly 402 and specifically formed to form a gas distribution plenum 406. The gas distribution plenum 406 can include one or more gas distribution baffles. The gas distribution plate 404 further includes one or more gas distribution holes 408 for distributing a process gas from the gas distribution plenum 406 to the chemical processing chamber. Process space within 211. Additionally, one or more gas supply lines 410, 410', etc., may be coupled to gas distribution plenum 406 via a gas distribution assembly, for example, to supply one or more gases The process gas may, for example, comprise NH3, HF, H2, 〇2, CO, C〇2, Ar, He, etc. In another embodiment, as shown in Figures 9A and 9B (expanded view of Figure 9A), A gas distribution system 420 for dispensing a process gas comprising at least two gases comprises: a gas distribution assembly 422 having one or more components 424, 426 and 428; a first gas distribution plate 430 coupled to the gas distribution The assembly 422 is specifically formed to connect a process space of the first gas and the chemical processing chamber 211; and a second gas distribution plate 432 is coupled to the first gas distribution plate 430 and specifically formed to connect a second gas and chemistry The process space of the chamber 211 is processed. The first gas distribution plate 430 forms a first gas distribution plenum 440 when connected to the gas distribution assembly 422. Further, the second gas distribution plate 432 is coupled to the first gas distribution plate 430. A φ second gas distribution plenum 442 is formed. Although not shown, the gas distribution plenums 440, 442 may include one or more gas distribution baffles. The second gas distribution plate 432 further includes: a first array A plurality of apertures 444 coupled to and co-produced with one or more channels 446 formed in an array within the first gas distribution plate 430; and one or more apertures 448 of a second array. One or more One or more apertures 444 of the first array associated with the array of channels 446 are specifically formed to distribute the first gas from the first gas distribution plenum 440 to the process chamber 211. One or more apertures 448 are specifically formed to distribute the second gas from the second gas distribution plenum 442 to the process space of the chemical processing chamber 211. ‘Private gases may include, for example, MN3, HF, H2, 〇2, CO, C〇2, Ar, He, and the like. because

14 1259527 ίί種Ζΐϊί 一氣體ί第二氣體係被獨立導入至製程空 曰 示了在衣程空間以外就不會互相影變。 之一所7^ H體可經由形成於氣齡配組件422内 ΐ了 =:供應通道,而連接至第—氣體分配充氣腔44〇。此 之-第二驶^、’ί 一氣體可經由形成於氣體分配組件422内 ㈤供應通運452而連接至第二氣體分配充氣腔442。 、,化處理系統210更包含維持於—高溫之一 7辟I二Γ至211 °舉例而言’―壁面加熱元件2防可以連接 ^Ϊ;;?ί]ίη 266 織合譬如^含例如鎢、錄絡合金、 砌4 阻式加熱器70件,譬如燈絲。商羋上可 ^ «Ιι 二Akrotha卜其為由Bethel,(^之“制公司所製造 名稱。Kanthal家族包含鐵氧體合 α14 1259527 ίί Ζΐϊί a gas ί second gas system is independently introduced into the process space 示 shows that it will not change from each other outside the clothing space. One of the bodies can be connected to the first gas distribution plenum 44 经由 via the =: supply passage formed in the gas ageing component 422. The second gas, a gas, can be coupled to the second gas distribution plenum 442 via a supply 452 formed in the gas distribution assembly 422. The processing system 210 further comprises: maintaining at - one of the high temperature, 7 I I to 211 °, for example, 'the wall heating element 2 can be connected to the Ϊ;; ίίίίίί 266 织 ^ 70 parts of recording alloy and brick 4 resistance heater, such as filament. Shangyu Shangke ^ «Ιι 二Akrotha is made by Bethel, (the name of the "manufactured by the company". The Kanthal family contains ferrite

Nikrothal > NiCrFe) 〇 ,二散發為熱,因此,壁面財㈣單元268 1^°^ 二f電源供應部。舉例而言,壁面加熱元件施^包含 可採用-冷卻元:二jit;在化;處理容室211中亦 熱電偶(例如K型孰電偶、Pt ^ ^可可藉由使用例如 龄顏。二偶^感測$4)之溫度感測裝置而受到被 ί之^ 器可利用溫度測量作為對壁面溫度控制單元 巧饋,以便控制化學處理容室211之溫度。 溫产3 處理系統21 G可更包含可被維持於任何選定 fit接舉綱言,,分配加熱元件 元件267=^= ^統溫度控制單元269,且氣體分配加赦 含例如鶬加熱元件可譬如包 ° …業上可取传的製造電阻加熱元件之材料的例子包含 1259527 K=haL、、馳r〇thal 與 Akr〇thal,其為由 Bethel,CT 之 Kanthal 金之:標名稱。—家族包含鐵氧體 二f ) 〇_家族包含奥氏體合金(NiCr、 1 rFe)。t電流流經此燈絲時,功率被散發為熱 :二先溫度Ϊ制單元湖可譬如包含—可控·電源供4體i i 2S H为配加熱元件267可包含具有大約1卿W(或大約5 =之功率密度)之一雙區間糊橡膠加熱器(大約丄厚)。氣 =配祕260之温度可藉由使_如熱電( 偶Nikrothal > NiCrFe) 〇, two scatters as heat, therefore, wall face (four) unit 268 1 ^ ° ^ two f power supply. For example, the wall heating element includes an -cooling element: two jit; in the processing; the processing chamber 211 is also a thermocouple (for example, a K-type galvanic couple, Pt ^ ^ cocoa by using, for example, an aging face. The temperature sensing device of the $4 sense sensor is subjected to the temperature measurement by the temperature control unit to control the temperature of the chemical processing chamber 211. The warm-production 3 processing system 21 G may further comprise a heating element element 267 that can be maintained in any selected fit, and the gas distribution enthalpy, for example, a heating element, such as Examples of materials which are commercially available for the manufacture of resistive heating elements include 1259527 K=haL, Chi Rththal and Akr〇thal, which are named by Kanthal Gold of Bethel, CT: - The family contains ferrites. The second f) 〇_ family contains austenitic alloys (NiCr, 1 rFe). When the current flows through the filament, the power is dissipated as heat: the second temperature is controlled by the unit lake, for example, the controllable power supply for the body ii 2S H is the heating element 267 can contain about 1 qing W (or approximately 5 = power density) One of the double-interval paste rubber heaters (approx. thickness). Gas = the temperature of the secret 260 can be made by making _ such as thermoelectricity

Pt感測II等)之溫度感測裝置而受到監視。再者,—控以、= 量作騎氣體分配系統溫度控 : 制=分配系統咖之溫度。圖δ,之氣體分配系^ 元:度控制系統。或者或此外,在任何—個實施例中可採用冷卻 請仍餐考圖2與3 ’真空抽氣系統25〇可一直 七,254用以抑制容室壓力。真空泵252可譬如包含I: 4二f大約5刪公升(且大於)之抽真空速*之—渦輪分子直介泵 =MP)。舉例而言,TMp可以是一触〇 STp—删真空泵,或β 真空泵。曹對健加工(一般小於約5() mT〇= €))疋有用的。對高壓(亦即,大於大約⑽虹 (亦I沒有氣心言’可使用—機械加壓泵與乾燥低真空里農。 右一圖3,化學處理系統210可更包含一控制器218,苴且 11'記憶體、以及—數位1/(3埠,其能夠產生足以'傳' 統210以及監視從例如溫度與壓力感 可:ί ίΐ:ΐίί 之輸出的控制電壓。此外,控制器218The temperature sensing device of Pt sensing II, etc. is monitored. In addition, the control and the amount of gas are used to control the temperature of the gas distribution system: system = temperature of the distribution system. Figure δ, the gas distribution system ^ degree: degree control system. Alternatively or additionally, cooling may be employed in any of the embodiments. Still, the vacuum pumping system 25 and the vacuum evacuation system 25 can be used to suppress the chamber pressure. The vacuum pump 252 can comprise, for example, I: 4 2 f, about 5 liters (and greater than) the vacuum rate* - turbomolecular direct pump = MP). For example, the TMp can be a touch-sensitive STp-de-vacuum pump, or a beta vacuum pump. Cao is useful for machining (generally less than about 5 () mT〇 = €)). For high pressure (i.e., greater than about (10) rainbow (also I can't use it - mechanical pressurization pump and dry low vacuum cultivator. Right Fig. 3, chemical treatment system 210 can further include a controller 218, 苴And the 11' memory, and the digit 1/(3埠, which is capable of generating a control voltage sufficient to 'pass' the system 210 and monitor the output from, for example, temperature and pressure: ίίΐ: ΐίί. In addition, the controller 218

ΛΙ件244、氣體分配系統260、真雜氣系統 度控帝 =2Γβ、壁面溫f”單元268以及氣體分配系統溫 5情體中之,可與它們交換資訊。舉例而言’可利用儲存於 if t式以依據一製程配方啟動這些輸入至化學處理系 、、、 之刖u兀件。控制器218之一例係為一 DELL PRECISION 16 1259527 WORKSTA—T⑽⑽《,其可從德克_'丨之奥斯丁之_公 在「個例子中,圖4顯現出—化學處理系 二 ίΓΛ手Λ3、至少一扣環214與至少一鼓鏈2Π之」密^ 光予視窗215以及至少一壓力感測裝置216。、風 稽邱其 _ ’熱處理祕220更包含—溫控基板支 室221 支r?部i7G包含猎由制—鱗274喃熱處理容 =:銹鋼或鎳所製造’而熱障274可以由 : 或石央之絕歸料所製造。基板支撐部27()更包含埋人 二6 接它的一基板支撐部溫度控制單元278、。加埶元 ^ 例如鎢、鎳鉻合金、_合金、氮化紹等電 夕牛,譬如燈絲。靠上可取得的製造電阻加埶元件 =料的例子包含Kan_、Nikn)thal與Akrothal,A為由 et=l £kKanthal公司所製造的金屬合金之註j ^ „ Nikrothal ^ ^ ^ 3體5 *⑽Cr、hCrFe)。當電流流經此燈絲時,功率被散發為 :、,因此,基板支撐部溫度控制單元278可譬如包含—可控 ,源供應部。或者’溫控基板支撐部27Q可譬如是商業上$從具 ,大約400至大約45(TC之最大操作溫度之Watl〇w公司(131()八The element 244, the gas distribution system 260, the true miscellaneous system degree control 2 = β, the wall temperature f" unit 268, and the gas distribution system temperature 5 can exchange information with them. For example, 'can be stored in The if t type starts the input to the chemical processing system according to a process recipe, and the controller 218 is a DELL PRECISION 16 1259527 WORKSTA-T(10)(10) ", which can be obtained from Dirk _'丨Austin's _ public in "in the case, Figure 4 shows - chemical processing system 2, at least one buckle 214 and at least one drum chain 2" dense light to the window 215 and at least one pressure sensing Device 216. , Feng Ji Qiu Qi _ 'The heat treatment secret 220 more includes - temperature control substrate support room 221 r? part i7G contains hunting system - scale 274 heat treatment capacity =: stainless steel or nickel made 'and thermal barrier 274 can be: Or it is made by Shiyang. The substrate supporting portion 27 () further includes a substrate supporting portion temperature control unit 278 which is buried therein. Adding a ^ element ^ such as tungsten, nickel-chromium alloy, _ alloy, nitriding, etc., such as filament. Examples of the manufactured resistance-twisting elements that are available on the top include Kan_, Nikn)thal and Akrothal, and A is a metal alloy made by et=l £kKanthal. j ^ „ Nikrothal ^ ^ ^ 3 body 5 * (10) Cr, hCrFe). When a current flows through the filament, the power is dissipated as: ,, therefore, the substrate support temperature control unit 278 can include, for example, a controllable source supply portion, or the 'temperature-controlled substrate support portion 27Q can be It is commercially available from $40 to approximately 45 (TC's maximum operating temperature of Watl〇w (131() eight)

Kn^land Dr.,Batavia’ IL,60510)取得的-鑄造加熱器,或 ^ 3鼠化銘材料之-薄膜加熱器,其商業上亦可從Wati〇w公司取 仔’且具有像大約3〇(Tc-樣高的操作溫度與高達大約23 w/cm2 之功率讀:或者’可將—冷卻元件併入基板支撐部27〇中。 基板支撐部270之溫度可藉蛾關如熱電偶㈤如熱電 感i貝!f置而受到監視。再者,一控制器可利用溫度&量 卩溫度控制單元’之回饋,崎㈣基板支樓 、此外,基板溫度可藉由使用例如光纖溫度計之—溫度感測裝 置或-頻帶邊緣溫度測量系統騎到監視,其中,光纖溫度計商 1259527 業上可從 Advanced Energies 公司(1625 Sharp point drive,FortKn^land Dr., Batavia' IL, 60510) obtained - casting heater, or ^ 3 mouse material material - film heater, which can also be taken from Wati〇w company and has a like 〇 (Tc-like high operating temperature with power up to about 23 w/cm2 read: or 'can be-cooled element incorporated into the substrate support 27〇. The temperature of the substrate support 270 can be used as a thermocouple (5) For example, the thermal inductance i is monitored and monitored. In addition, a controller can utilize the feedback of the temperature & temperature control unit, the substrate, and, in addition, the substrate temperature can be obtained by using, for example, a fiber optic thermometer. - Temperature sensing device or - Band edge temperature measurement system rides to the surveillance, where the fiber thermometer supplier 1259527 is available from Advanced Energies (1625 Sharp point drive, Fort)

Collms,CO, 80525),型號OR2000F取得,其具有從大約5〇至 J約20,:C之測量範圍以及大約正負15t之精度,而頻帶邊緣 ^度測置系統係如在審理中的美國專利申請案號丨〇/168544中所 ’其申清曰為2002年7月2曰,其内容係全部於此併入作 為芩考文獻。 再ί考圖5 ’熱處理糸統220更包含維持於一選定溫度之一、、w 度=熱處理容請。舉例而言,一熱壁面加熱二;^連: 至…、土面’皿度控制單元281,且熱壁面加熱元件283可且體形成 ΞΪίί處理容室22卜加熱元件可譬如包含例如鎢、鎳鉻合金、 鋁鐵合金、氮化鋁等之電阻式加熱器元件,譬如燈絲。商業上可 造電阻加熱元件之材料關子包含Kantha卜斷0伽1 父^IU為由Bethe1,CT^Kanthal公司所製造的金屬 w°H,才示名稱。Kanthal家族包含鐵氧體合金(FeCrA1),而 上:0 :二族包含奥氏體合金(Nicr、NicrFe)。當電流流經此燈 j ’功率被散發秘,因此,酸面溫度控制單元281可學如 制DC電源供應部。舉例而言,熱壁面加熱元件28°3可 6^53lf)iir^Watl〇WM〇31〇KingSlandDr.’Batavia,IL, 筒夾加熱器°或者’或此外,在熱 =各至221中可採用冷卻元件。熱處理容室221之溫度 押制單#者於一控制益可利用溫度測量作為對熱壁面溫度 &制早兀281之回饋,以便控制熱處理容室221之溫产。 上與5 ’熱處理系統220更包含一上“件284。 件284可譬如包含-氣體注入系統,用以將一吹 2衣ff體導人至熱處理容室22卜或者,熱處理容室 # ^ 7卩組件分離之—氣體注人系統。舉_言,-吹除 /3=清洗氣體可經由其繼而被導人至熱處理容室 ”了更包含具有至少-鉸鏈、—把手與—扣環之 1259527 ίΐΐ件閂鎖在-封閉位置。於-替代實施例中, η 2弋可包“列如—陣列之鎢函素燈管之一輻射加埶哭, ,if t倚靠在基板升降桿組件290之葉片5〇〇(參見圖ϋ面 容外於此情況下’基板支撐部270可能被排除在熱處理 一 統220可更包含可維持於一選定溫度之 組件284。舉例而t,-上部組件加熱元件28 ίίΓ單元286,且上部組件加熱元件285可具 f紹鐵合金、祕!時之電阻式加熱器元件,譬如燈絲 ik可ϋ的ί造電阻加㉟元件之材料的例子包含Kanthal、α、 =roi厘n ai ’其為由此制,ct之Ka她al公司所製 ief t ΐΐΐ㈣標名稱° Kanthal家族包含鐵氧體合金 (FeCrAl),而斷麵1家族包含奥氏體合金(船、齡 3,功率被散發為熱,因此上部組件溫度控制 ^ f Z = 31可控制DC電源供應部。舉例而言,上部組 =加熱兀件285可包含具有大約· w(或大約5龍2 度)之-雙區間石烟橡膠加熱器(大約i醜厚)。上部组件28^ 溫度可藉由使關如熱電偶(例如κ型熱電 iif ϊ,受到監視。再者,—控織 ^口^牛溫度控制早疋286之回饋,以便控制上部組件284之溫 度。上部組件284可附帶或另外包含一冷卻元件。 _ If H2與5,熱處理系統220更包含一基板升降桿組件 fΓ90係具體形成以將—基板242,降低至基板 ΪΪ Γ 表面’並將—基板242, ’從基板支樓部270之- 1 = :,起至—支持平面’或於其間之—傳送平面。於傳送平面, 基板242可與被利用以運送基板進出化學與熱處理容室2ii、221 統作交換。於支持平面,基板242,,可被冷卻而另一個 基板如在傳送糸統與化學與熱處理容室21卜221之間作交換。如 19 1259527 三個以土u板升降桿組件290包含一葉片500,其具有三個或 、垂片510、用以將基板升降桿組件290耦合至熱處理容 #吉@^—凸緣520以及用以允許葉片500在熱處理容室221内 242,,之^一驅動系統530。這些垂片510係具體形成以將基板 據部在Γ舉起錄,並核於降他置時職在基板支 毖i曰(^見圖5)内之接受孔穴540内之凹部。驅動系統530可 二l種氧動驅動系統’其被設計以符合各種不同的規格,包 、汽紅衝程速度、位置精度、非旋轉精度等,其 "’、為无、^氣動驅動系統設計之本項技藝者所熟知的。 280 圖2與5,熱處理系統220更包含^真空抽氣系統 …軋系統280可譬如包含—真空泵與例如—關或蝴蝶 : ⑽閥。真空泵可譬如包含具有每秒高達大約5000公升(且 之抽真空速率之一渦輪分子真空泵(TMP)。TMP對低壓加工 -般广於約50 raTorr)是有用的。對高壓加工(亦即,大於大約 U mTcfr)而言,可使用一機械加壓泵與乾燥低真空泵。 茶考圖5 ’熱處理系統22Q可更包含一控制器275,1且有 =處理H、記㈣、以及—數位1/()埠能生足以傳遞並啟 =入至熱處理系統22〇以及監視從熱處理系統⑽之輸出的控 制電壓。此外,控制器275可連接至基板支撐部溫度控制單元工 =、上,組件溫度控制單元娜、上部組件284、熱壁面溫度控 ^兀—1、真空抽氣系統280以及基板升降桿組件29q並可與它 們父換資訊。舉例而言,可利用儲存於記憶體中之一程式以依、 一製程配方啟動這些輸入至熱處理系統220之前述元件。控制界 275 之一例係為一 DELL PRECISI〇N w〇RKSTATI〇N 61〇TM,二= 薩斯州之奥斯丁之Dell公司取得。 在-替代實施例中,控制器218與275可以是相同的控制器。 在一個例子中,圖6顯現出一熱處理系統22〇,,其更包^呈 m22i3與至少一欽鍵224之一密封蓋222、一光學檢視窗、 225以及至少一壓力感測裝置226。此外,熱處理系統22〇,更包含 20 1259527 一基板偵測系統227,以便確認一基板是否位於支持平 摘測糸統可譬如包含一 Keyence數位雷射感測器。 圖12、13與14分別說明絕熱組件230之侧視圖、俯 • 及側剖面圖。一種類似的組件亦可被使用作為絕熱組件5〇 - 或650。絕熱組件230可包含:一界面板231,其連接至嬖如化與 處理容室211(如圖12所示),並具體形成以形成在敎^子 221(參見圖14)與化學處理容室211之間的一構造接觸 緣板232,其連接至界面板231並具體形成以減少在熱處理 -221與化學處理容室211之間的熱接觸。再者,於圖12中,界 板231包含一個或多個構造接觸元件233,其具有一接合表面\ •具體形成以與熱處理容室221上之一接合表面連接。界面^ 231 可以是由例如鋁、不銹鋼等之金屬所製造,以便形成兩個容室 211、221之間的一剛性接觸。絕緣板232可以是由例如鐵氟隆、 氧化鋁、石英等之具有低熱傳導係數之材料所製造。一種絕熱组 件係更詳細說明於審理中的美國申請案1〇/7〇5,397,申請曰^ 2003年11月12日,名稱為”使鄰近溫度控制室絕熱之方法與設備 (Method and Apparatus For Thermally Insulating Adjacent Temperature Controlled Chambers)”,且其全部係列人參考資料。 - 如圖2與14所示,閘閥組件296係被利用以垂直移動一、閘閥 % 297,以便開啟與關閉共同開口部294。閘閥組件296可更包含一 _閘閥配接板239,其提供與界面板231之一真空密封部並提供與閘 閥297之一密封部。 、 兩個谷室211、221可以藉由使用一個或多個對準裝置235並 終結^如在圖6中之一個或多個對準接受器235,中而彼此連接, 以及藉由使用經由第一容室(例如化學處理容室211)上之一凸緣 =7延伸之一個或多個扣接裝置236(亦即,螺栓)並終結在第二容 至(例如熱處理容室221)中之如在圖6中之一個或多個接受裝置 236’(亦即,螺紋孔)之内而彼此連接。如圖14所示,一真空密封 部可藉由使用譬如合成橡膠〇型環密封部238而形成於絕緣板 21 1259527 Z真Hit1、閉闕配接板239以及化學處理容室211之間, 熱處22^1=由〇型環密封部238而形成於界面板231與 之多學處理容室211與熱處理容室221之這些元件Collms, CO, 80525), model OR2000F, with a measurement range from about 5 〇 to J about 20, :C, and an accuracy of about plus or minus 15 t, while the band edge measurement system is as in the US patent under trial. The application number 丨〇/168544's “Shen Qing 曰 is July 2, 2002, the contents of which are hereby incorporated by reference. Further, the heat treatment system 220 further includes one of the selected temperatures, and the w degree = heat treatment. For example, a hot wall surface is heated by two to: a soil surface control unit 281, and the hot wall surface heating element 283 can be formed into a processing chamber 22, for example, containing tungsten, nickel, for example A resistive heater element such as a chrome alloy, an aluminum-iron alloy, or an aluminum nitride, such as a filament. The material of the commercially available resistive heating element contains Kantha Bux 0 ga 1 and the parent IU is the metal w°H manufactured by Bethe1, CT^Kanthal Company. The Kanthal family contains ferrite alloys (FeCrA1), while the upper:0:bis family contains austenitic alloys (Nicr, NicrFe). When the current flows through the lamp j ' power is dissipated, the acid surface temperature control unit 281 can be learned as a DC power supply. For example, the hot wall heating element 28°3 can be 6^53lf)iir^Watl〇WM〇31〇KingSlandDr.'Batavia,IL, collet heater° or 'or in addition, in heat=each to 221 can be used Cooling element. The temperature of the heat treatment chamber 221 is controlled by the temperature measurement as a feedback to the hot wall temperature & 281 to control the temperature production of the heat treatment chamber 221 . The upper portion and the 5' heat treatment system 220 further comprise an upper member 284. The member 284 can include, for example, a gas injection system for guiding a blown body to the heat treatment chamber 22 or heat treatment chamber #^7卩Component separation - gas injection system. _ _, - blowing / 3 = cleaning gas can be led to the heat treatment chamber through it" and more including at least - hinge, - handle and - buckle 1259527 The ΐΐ member is latched in the - closed position. In an alternative embodiment, η 2 弋 can be packaged as "one of the array of tungsten elements of the array, and the radiation of the tungsten lamp tube, if t, leans against the blade 5 of the substrate lifting rod assembly 290 (see Figure ϋ 容 容In this case, the substrate support portion 270 may be excluded from the heat treatment unit 220 and may further include an assembly 284 that may be maintained at a selected temperature. For example, t, the upper assembly heating element 28 ίίΓ unit 286, and the upper assembly heating element 285 An example of a material that can be made of a ferroelectric heater, such as a filament ik, a resistor, and a 35-component material, includes Kanthal, α, =roi nn ai 'which is made by this, ct Kay her company's ief t ΐΐΐ (four) standard name ° Kanthal family contains ferrite alloy (FeCrAl), while section 1 family contains austenitic alloy (ship, age 3, power is dissipated as heat, so the upper component temperature The control ^ f Z = 31 can control the DC power supply. For example, the upper group = heating element 285 can comprise a double interval stone smoke rubber heater having about w (or about 5 dragons 2 degrees) (about i Ugly thick. Upper part 28^ temperature can be turned off A thermocouple (e.g., a κ-type thermoelectric iif ϊ, is monitored. Further, the woven control is controlled by the temperature control of the upper 286 to control the temperature of the upper assembly 284. The upper assembly 284 may or additionally include a cooling element. _ If H2 and 5, the heat treatment system 220 further includes a substrate lifting rod assembly f Γ 90 is specifically formed to lower the substrate 242 to the substrate ' surface ' and the substrate 242, 'from the substrate branch portion 270 - 1 = :, from - to the support plane 'or the transfer plane between them. On the transfer plane, the substrate 242 can be used interchangeably with the substrate to be used to transport the substrate into and out of the chemical and thermal processing chambers 2ii, 221. On the support plane, the substrate 242, , can be cooled while another substrate is exchanged between the transport system and the chemical and heat treatment chamber 21 221 . For example, 19 1259527 three soil plate lifting rod assemblies 290 comprise a blade 500 having three or a tab 510 for coupling the substrate lifter assembly 290 to the heat treatment volume φ@@- flange 520 and for allowing the blade 500 to be within the heat treatment chamber 221, a drive system 530. 510 series specific shape In order to record the substrate, the recess is in the receiving cavity 540 in the substrate support (see Figure 5). The drive system 530 can be driven by two kinds of oxygen. The system 'is designed to meet a variety of different specifications, including package, steam red stroke speed, positional accuracy, non-rotational accuracy, etc., which is well known to those skilled in the art of designing a pneumatic drive system. 2 and 5, the heat treatment system 220 further includes a vacuum pumping system. The rolling system 280 can include, for example, a vacuum pump and a valve such as a butterfly or a butterfly (10). Vacuum pumps can be useful, for example, to have a turbomolecular vacuum pump (TMP) of up to about 5000 liters per second (and one of the evacuation rates. TMP is typically about 50 raTorr for low pressure processing). For high pressure machining (i.e., greater than about U mTcfr), a mechanical pressurizing pump and a dry low vacuum pump can be used. Tea Test Figure 5 'The heat treatment system 22Q may further comprise a controller 275, 1 and have = treatment H, record (four), and - digit 1 / () 埠 can be sufficient to transfer and enter into the heat treatment system 22 〇 and monitor the heat treatment The control voltage of the output of system (10). In addition, the controller 275 can be coupled to the substrate support temperature control unit =, upper, component temperature control unit Na, upper assembly 284, hot wall temperature control 1-3, vacuum pumping system 280, and substrate lifter assembly 29q. Can exchange information with their parents. For example, one of the programs stored in the memory can be used to initiate these inputs to the aforementioned components of the thermal processing system 220 in accordance with a process recipe. One of the control circles 275 is a DELL PRECISI〇N w〇RKSTATI〇N 61〇TM, two = obtained by Dell Company of Austin, Sas. In an alternate embodiment, controllers 218 and 275 can be the same controller. In one example, FIG. 6 shows a heat treatment system 22 that further includes a sealing cover 222, an optical inspection window, 225, and at least one pressure sensing device 226 in the form of one of m22i3 and at least one of the keys 224. In addition, the heat treatment system 22〇 further includes a 20 1259527 substrate detecting system 227 to confirm whether a substrate is in a supporting singulation system, for example, including a Keyence digital laser sensor. Figures 12, 13 and 14 illustrate side, side and side cross-sectional views, respectively, of the thermal insulation assembly 230. A similar assembly can also be used as the thermal insulation component 5〇- or 650. The heat insulating assembly 230 can include: an interface plate 231 coupled to the processing and processing chamber 211 (shown in FIG. 12) and specifically formed to be formed in the 221 (see FIG. 14) and the chemical processing chamber. A structural contact edge plate 232 between 211 is coupled to the interface plate 231 and is specifically formed to reduce thermal contact between the heat treatment -221 and the chemical processing chamber 211. Further, in Fig. 12, the interface 231 includes one or more structural contact elements 233 having an engagement surface that is specifically formed to interface with one of the bonding surfaces of the heat treatment chamber 221. The interface ^ 231 may be made of a metal such as aluminum, stainless steel or the like to form a rigid contact between the two chambers 211, 221. The insulating plate 232 may be made of a material having a low heat transfer coefficient such as Teflon, alumina, quartz, or the like. An insulating component is described in more detail in the U.S. Application Serial No. 1/7,5,397, filed on November 12, 2003, entitled "Method and Apparatus For Thermally Insulating Temperature Control Room" (Method and Apparatus For Thermally Insulating Adjacent Temperature Controlled Chambers)", and its full range of people's references. - As shown in Figures 2 and 14, the gate valve assembly 296 is utilized to vertically move a gate valve % 297 to open and close the common opening portion 294. The gate valve assembly 296 can further include a gate valve adapter plate 239 that provides a vacuum seal with one of the interface plates 231 and provides a seal with one of the gate valves 297. The two valleys 211, 221 can be connected to each other by using one or more alignment devices 235 and terminating one or more alignment receptors 235 in FIG. 6, and by using One or more fastening devices 236 (ie, bolts) extending over one of the chambers (eg, chemical processing chamber 211) and ending in a second volume (eg, heat treatment chamber 221) They are connected to one another as in one or more receiving devices 236' (i.e., threaded holes) in FIG. As shown in FIG. 14, a vacuum sealing portion can be formed between the insulating plate 21 1259527 Z, the true Hit 1, the closed mating plate 239, and the chemical processing chamber 211 by using, for example, a synthetic rubber ring-shaped ring seal portion 238. 22^1= these elements formed on the interface plate 231 and the multi-processing chamber 211 and the heat treatment chamber 221 by the 〇-ring seal portion 238

Kapton (商標ί) 有一保護阻絕物。保護阻絕物可包含 等之陶瓷嘖+载鼠隆、表面陽極氧化、例如氧化鋁,氧化釔 寺c、電漿電解氧化等之至少-種。 圖_所說明,,法壯從步驟_開始之一流程 板支撑勒之騎銷而接受基 : ί、t基板支撐部。然後,藉由使用例如一靜電 輸氣體提供至基將基板固定至基板支撐部’且將-熱傳 理用於設定一個或多個化學加工參數以供基板之化學處 塵力、二二,理化學加卫參數包含—化學處理加工 度、—化學處理氣體分喊統溫度以及-化學處理 ;f=率之至少-項。舉例而言,可產生下述的-個或多個 夕一 4^^」用連接至一壁面溫度控制單元與一第一溫度感測裝置 南丨田、=拉态以Γ疋供化學處理容室用之一化學處理容室溫度;2) 接ϋ體分配系統溫度控制單元與—第二溫度感測裝置 ^控^ ϋ以奴供化學處理容室用之—化學處理氣體分配系統 / 皿又,利用連接至至少一溫度控制元件與一第三溫度感測裝置 控制H以設定-化學處理基板支撐部溫度;4)利用連接至基 ,樓部中之-溫度控制元件、—背面氣體供應系統與一爽持系 f至少-個,以及-第四溫度感測裝置之—控制器以設定一化 予处理基板溫度;5)利用連接至一真空抽氣系統與一氣體分配系 統之至少-個,以及-壓力制裝置之—控繼以設定化學處理 22 1259527 1内之-加讀力;及/或喃鱗接域齡配祕内之 2個質流控·之-㈣H來設定—個❹個餘氣體 流率。 係ί於步驟820所提出之條件之下被化學處 理持貝-弟-㈣間。舉例而言,第—段之Kapton (trademark ί) has a protective barrier. The protective barrier may comprise at least one of ceramic crucible + squirrel, surface anodized, such as alumina, cerium oxide c, plasma electrolytic oxidation, and the like. As shown in Fig. _, the method is based on one of the steps of the process board to support the riding of the pin and accept the base: ί, t substrate support. Then, the substrate is fixed to the substrate support portion by using, for example, an electrostatic gas supply, and the heat transfer is used to set one or more chemical processing parameters for the chemical dust of the substrate. The chemical protection parameters include - chemical processing degree, - chemical processing gas temperature and chemical treatment; f = rate at least - term. For example, the following one or more of the following may be generated by connecting to a wall surface temperature control unit and a first temperature sensing device, Nantian, = pull state, for chemical processing capacity. One of the chambers is used to chemically treat the chamber temperature; 2) the temperature distribution unit of the joint distribution system and the second temperature sensing device are controlled by the slave to the chemical processing chamber - the chemical processing gas distribution system / the dish Controlling H by setting to at least one temperature control element and a third temperature sensing device to set-chemically treat the temperature of the substrate support portion; 4) utilizing a temperature control element connected to the base, the floor, the back gas supply system At least one with a refreshing system f, and - a fourth temperature sensing device - the controller sets the substrate temperature to be processed; 5) utilizes at least one connected to a vacuum pumping system and a gas distribution system And - the pressure system - control is set to the chemical treatment 22 1259527 1 - plus reading force; and / or the squall is connected to the domain of the two kinds of quality control - (four) H to set - a The remaining gas flow rate. The system is chemically treated under the conditions set forth in step 820 to hold the Bell-Di-(4). For example, paragraph -

至大約480秒。 #岡」1疋八、」丄U 於步驟840,基板係從化學處理容室被傳送至熱處理容室。在 該期=,移除基板夾,並終止熱傳輸氣體流動至基板之背面。基 板係藉由彳巧誠在基板支料内之升降雜件而從紐支撐部 被垂直升㊉至傳达平面。傳送系統接受來自升降銷之基板,並將 基板配置在熱處理系、_。於射,基板升降桿組件接受來自傳 送系統之基板,並使基板下降至基板支撐部。 於步驟850,設定複數個熱加工參數以供基板之熱處理用。舉 例而a,一個或多個熱加工參數包含一熱處理壁面溫度、一熱處 理上部組件溫度、一熱處理基板溫度、一熱處理基板支撐部溫度、 一熱處理基板溫度以及一熱處理加工壓力之至少一項。舉例而 言,可產生下述的一個或多個現象·· 1)利用連接至熱處理容室中 之一熱壁面溫度控制單元與一第一溫度感測裝置之一控制器以設 定一熱處理壁面溫度;2)利用連接至上部組件中之一上部^件溫 度控制單元與一第二溫度感測裝置之一控制器以設定一熱處理= 組件溫度,3)利用連接至熱基板支撐部中之一基板支樓部溫度 控制單元與一第三溫度感測裝置之一控制器以設定一熱處理基板 支撐部溫度;4)利用連接至熱基板支撐部中之一基板支撐部溫度 ,制單元與一第四溫度感測裝置以及連接至基板之一控制器以言 ^ 定一熱處理基板溫度;及/或5)利用連接至一真空抽氣系統二一氣 體分配系統與一壓力感測裝置之一控制器以設定在熱處理容室内 之—熱處理加工壓力。 於步驟860 ’基板係在於步驟850所提出之條件之下被熱處理 持續一第二段時間。舉例而言,第二段時間之範圍可從大約1〇至 23 1259527 大約480秒。 於一例中’如圖2所示,加工系統2〇〇可以是一化學氧化 f除系統’用以修整二氧化物硬性光罩。加工系統測包含 處理系統210’用以化學處理-1板上之例如氧化物表面層之露出 表面層’藉以露出表面上之製程化學之吸附影響表面層之化 ^。此外,加工系統200包含熱處理系統22〇,用以熱處理基板, 藉以提升基板溫度以便釋出(或蒸鍍)基板上之化學改變的露出 面層。 。 ^ 在化學處理系統210中,將製程空間2β2予以排空(參見圖 2) ’而導人包含HF與勵之-製程氣體。或者,製程氣體可更包 含一運載氣體(carrier gas)。運載氣體可譬如包含例如氬、 氦等之一鈍氣。 加工壓力之範圍可從大約1至大約1〇〇 mT〇rr,而譬如一般範 圍可從大約2至大約25 mTorr。每個種類之製程氣體流動速率之 範圍可從大約1至大約200 seem,而譬如可從大約10至大約1〇〇 seem。雖然真空抽氣系統250係顯示於圖2與3中以從該側接達 化學處理容室211,但可達到均勻(三維)壓力場。表丨顯示在基板 表面上之壓力變化之百分比’其為加工壓力以及氣體分配系統260 與基板242之上表面之間的間距之一函數。 表1 (%) h(間距) 摩力 50 mm 62 75 100 200 20 mTorr 9 7 4 3 [6 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 0.75 0.42 ΝΑ 3.1 1· 6 1.2 ΝΑ ΝΑ 5. 9 2.8 ΝΑ ΝΑ ΝΑ ΝΑ 3.5 3.1 1.7 0.33 此外,化學處理容室211可被加熱至範圍從大約l〇°c至大約 200°C之溫度,而譬如溫度之範圍可從大約35。(:至大約55。(:。此 24 1259527 外’氣體分配系統可被加熱至範圍從1〇。匸至2⑽。c之溫度,而譬 如溫度之範圍可從大約4〇。(:至大約6(rC。基板可被維持於範圍從 $==_之—溫度,而譬如基板溫度之範圍可從大約 在熱處理系統220中,熱處理容室221可被加熱至範圍從大 約20C至大約20(TC之溫度,而譬如溫度之範圍可從大約75。〇至 ioo°c。此外,上部組件可被加熱至範圍從大約2(rc至大約 2〇oc之溫度,而譬如溫度之範圍可從大約75。〇至大約1〇〇艽。美 _ ,可被加熱至超過範圍從大約l〇(TC至大約20(rc之大約1〇〇。^ /m度。舉例而言,溫度之範圍可從大約1〇〇艺至大約1邡。^。 1化物=====處理無處料魅下舰《 ··對熱氧 凝列旦.母6〇秒超過大約10 nm之一露出氧化物表面層之 乳化物之化學處理每通秒超過大約25服之露出 Ϊ”;以及對臭氧Τ題之化學處理每⑽秒超 橫越過小於1刻量。這些處理亦可產生 :£β撕:、====: 至化與九里^:衣“體以外,第一製程氣體册係‘導入 導入至製程空間以作為氣體之一混合物兩個衣“體係被混合並 # _又,如上所述,例如惰性氣體之一化學鈍氣可以盘楚一制 ,體HF-起,與第二製程氣體勵於二程 與第二製程氣體以外,或直任何么二立^弟7, 如包含氬氣。 任17、、且口而被>入。惰性氣體可譬 、、六中’氯氣係被導入至第二製程氣體腿3,且隨著气气夕 j速率的增加,觀察到的修整量 巧鼠乳之 圖16顯現出一修餐詈甘炎& # 正里)疋減少的。 25 1259527 28 seem,NIL之流動速率大約為 基板支撐部溫度大約為2(TC,CCmJ壓力大約為15 fflTorr, °C,暴露至HF/Nfib化學劑之期門容室之壁面溫度大約為40 板之間的間距大約為56 B 、、、、為60移、,在氣體分配板與基 大約40 sccm。例如,可使用圖亞從大約〇改變至 (oirve fits)以定義修整量與 貝科之一曲線擬合 整量與鈍氣之流動速率之間的一合以定義修 >巧速率之間的一種關係,量與鈍氣之 定量之-第二製程氣體而言,suf·;製程氣體之既 之間的關係。舉例而言,氣體數旦又正里舁鈍氣之一數量 流動速率、-氣體濃度、包含-質量流率、-摩爾 在另一例中,圖17顯示使用表2中所提供 不製程之圖。圖17顯現出氬氣之流動速率发為一個例 石夕之修整量)之函數。例如,圖17中之實驗資料之里(一乳化 3被使用以定義修整量與純氣之流動速率之間的4或多:合 於圖P中,顯示出數個加工範圍。在一第—_ f吉;(修整量)從大約2 nm改變至大約6围在1乾f中二製 二:製程結果(修整量)從大約6 nm改變至大約1弟-加工乾圍 第三加工範圍中,製程結果(修整量)從大約17. 3 nm =一 23 nm。在替代實施例中,可以有—些 =大約 以是不同的。 工乾圍,且極限可 26 1259527 表2It takes about 480 seconds. #冈"1疋8,"丄U In step 840, the substrate is transferred from the chemical processing chamber to the heat treatment chamber. In this period =, the substrate holder is removed and the heat transfer gas is stopped to flow to the back side of the substrate. The substrate is vertically raised from the support portion to the conveying plane by the clever miscellaneous pieces in the substrate support. The transport system accepts the substrate from the lift pins and places the substrate in a heat treatment system, _. In the shot, the substrate lifter assembly accepts the substrate from the transfer system and lowers the substrate to the substrate support. In step 850, a plurality of thermal processing parameters are set for heat treatment of the substrate. For example, a, the one or more thermal processing parameters include at least one of a heat treatment wall temperature, a heat treatment upper component temperature, a heat treatment substrate temperature, a heat treatment substrate support temperature, a heat treatment substrate temperature, and a heat treatment process pressure. For example, one or more of the following phenomena may be generated: 1) using a thermal wall temperature control unit connected to one of the heat treatment chambers and a controller of a first temperature sensing device to set a heat treatment wall temperature 2) using a controller connected to one of the upper component temperature control unit and a second temperature sensing device to set a heat treatment = component temperature, 3) using a substrate connected to the thermal substrate support portion a temperature control unit of the branch building and a controller of a third temperature sensing device to set a heat treatment substrate support temperature; 4) using a substrate support portion temperature connected to the thermal substrate support portion, the unit and a fourth a temperature sensing device and a controller coupled to the substrate to determine a heat treated substrate temperature; and/or 5) utilizing a controller coupled to a vacuum pumping system and a pressure sensing device The heat treatment processing pressure is set in the heat treatment chamber. The substrate is heat treated for a second period of time in the step 860' under the conditions set forth in step 850. For example, the second period of time can range from approximately 1 〇 to 23 1259527 approximately 480 seconds. In one example, as shown in Figure 2, the processing system 2 can be a chemical oxidation f-removal system for trimming the dioxide hard mask. The processing system includes a treatment system 210' for chemically treating the exposed surface layer of the surface layer of the oxide, for example, on the -1 surface to expose the surface chemical chemistry of the surface to affect the surface layer. In addition, processing system 200 includes a thermal processing system 22 for heat treating the substrate to thereby raise the substrate temperature to release (or vapor) the chemically altered exposed surface layer on the substrate. . ^ In the chemical processing system 210, the process space 2β2 is evacuated (see Figure 2) and the HF and Excise-Process gases are included. Alternatively, the process gas may further comprise a carrier gas. The carrier gas may, for example, comprise an inert gas such as argon, helium or the like. The processing pressure can range from about 1 to about 1 〇〇 mT rr, and for example, the general range can range from about 2 to about 25 mTorr. Each type of process gas flow rate can range from about 1 to about 200 seem, and can range from about 10 to about 1 seem. Although the vacuum pumping system 250 is shown in Figures 2 and 3 to access the chemical processing chamber 211 from this side, a uniform (three-dimensional) pressure field can be achieved. The gauge shows the percentage change in pressure on the surface of the substrate as a function of the processing pressure and the spacing between the gas distribution system 260 and the upper surface of the substrate 242. Table 1 (%) h (pitch) Moment 50 mm 62 75 100 200 20 mTorr 9 7 4 3 [6 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 0.75 0.42 ΝΑ 3.1 1· 6 1.2 ΝΑ ΝΑ 5. 9 2.8 ΝΑ ΝΑ ΝΑ ΝΑ 3.5 3.1 1.7 0.33 Further, the chemical processing chamber 211 can be heated to a temperature ranging from about 10 ° C to about 200 ° C, and for example, the temperature can range from about 35. (: to approximately 55. (:. This 24 1259527 external 'gas distribution system can be heated to a temperature ranging from 1 〇. 匸 to 2 (10). c, and such as temperature can range from about 4 〇. (: to about 6) (rC. The substrate can be maintained at a temperature ranging from $==_, and the substrate temperature can range from approximately to the heat treatment system 220, and the heat treatment chamber 221 can be heated to a range from about 20C to about 20 (TC The temperature, for example, the temperature can range from about 75 〇 to ioo ° C. In addition, the upper component can be heated to a temperature ranging from about 2 (rc to about 2 〇 oc, and for example, the temperature can range from about 75 〇 to about 1 〇〇艽. _, can be heated beyond the range from about l〇 (TC to about 20 (rc of about 1 〇〇 ^ / m degrees. For example, the temperature can range from about 1〇〇艺至约1邡.^.1化=====Processing nowhere to be under the enchantment of the ship. ················································· The chemical treatment of the emulsion exceeds about 25 exposures per pass;" and the chemical treatment of the ozone problem every (10) seconds It is less than 1 moment. These treatments can also produce: £β tear:, ====: to the chemical and Jiuli ^: outside the body, the first process gas system is imported into the process space as one of the gases The two garments of the mixture "the system is mixed and #_ again, as described above, for example, one of the inert gases can be made of a chemically inert gas, the body is HF-, and the second process gas is excited by the second process and the second process gas. Other than, or any of the two 立立^弟7, if it contains argon. Any 17, and the mouth is > into. The inert gas can be 譬, and the six middle 'chlorine gas system is introduced into the second process gas leg 3, And as the gas-gas rate increases, the observed amount of trimming mouse milk Figure 16 shows a reduction in the amount of meal 詈 炎 & 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 The substrate support temperature is about 2 (TC, CCmJ pressure is about 15 fflTorr, °C, and the wall surface temperature of the door chamber exposed to the HF/Nfib chemical agent is about 40 B between the plates, about 56 B, , for 60 shifts, in the gas distribution plate with a base of about 40 sccm. For example, you can use Tua from about 〇 Change to (oirve fits) to define a relationship between the amount of trimming and the flow rate of one curve of Beca and the flow rate of the blunt gas to define a relationship between the amount of repair and the rate of blunt gas. In the case of the second process gas, the relationship between the process gas and the process gas. For example, the gas flow rate of a few deniers and a blunt gas, the gas flow rate, the inclusion-mass flow rate, - Moore In another example, Figure 17 shows the use of the non-process diagrams provided in Table 2. Figure 17 shows the flow rate of argon as a function of the trimming amount of the case. For example, in the experimental data in Figure 17 (an emulsification 3 is used to define 4 or more between the trimming amount and the flow rate of pure gas: in Figure P, it shows several processing ranges. In a _ f 吉; (trimming amount) changed from about 2 nm to about 6 in 1 dry f in two systems: process results (dressing amount) changed from about 6 nm to about 1 in the third processing range The process result (trimming amount) is from about 17.3 nm = a 23 nm. In an alternative embodiment, there may be some = approximately different. Work circumference, and the limit may be 26 1259527 Table 2

修整(nm) Ar(sccm) 配方 2 219 A 3 156 A 4 107 A 5 73.8 A 6 53.2 A 7 100 B 8 74.5 B 9 56.6 B 10 44.3 B 11 36.1 B 12 30.6 B 13 26.8 B 14 24 B 15 21.8 B 16 19.9 B 17 18.2 B 18 16.5 B 19 14 9 B 20 13.3 B 21 11.9 B 22 10.6 B 23 9.5 B 在每個加工範圍中,可使用一方程式以計算在製程結果(修整 量)與製程參數(氣體流量)之間的關係。製程配方可包含下述至少 一者··一額定配方成分,一靜態配方成分,以及一處方模型成分。 27 1259527 或者,可使用一些不同成分及/或不同型式之成分。 如說明之實施例所示,使用於第一加工範圍中之製程配方可 包含一額定配方成分、一靜態配方A成分以及一處方模型A成分; 使用於第二加工範圍中之製程配方可包含一額定配方成分、一靜 態配方B成分以及一處方模型B1成分;以及使用於第三加工範圍 、中之製程配方可包含一額定配方成分、一靜態配方B成分以及一 處方模型B2成分。舉例而言,額定配方成分跨越修整資料之整個 範圍,亦即,2 nm至23 nm之一修整量,如圖17所示。此外,舉 - 例而言,可將額定配方成分分割成兩個以上的靜態配方成分,亦 _ 即,靜態配方A成分與靜態配方B成分,如圖17所示。可為修整 _ 量之一範圍(亦即,成分A跨越2 nm至6 nm之一修整量,而成分 ^ B跨越6 nm至23 nm之一修整量,請參見圖17)設計每個靜態配 方成分(例如,成分A與B)。再者,每個靜態配方成分可包含一不 同數量之第一反應物,一不同數量之第二反應物,以及一不同的 製程壓力(例如,第一反應物之數量,第二反應物之數量與製程壓 力對靜態配方A成分之全部範圍(span)而言是固定的,而第一反 應物之數量,第二反應物之數量與製程壓力對靜態配成分之 全部範圍(span)而言是固定的)。此外,舉例而言,每個靜態配方 . 成分(亦即,成分A與B)可以一個或多個處方模型成分表示。舉例 •而言」如圖17所示,靜態配方A成分係以一個處方模型成分表示 (換言之,處方模型A成分),而靜態配方B成分係以兩個處方模 型成分表示(換言之,處方模型B1成分與處方模型β2成分)。兩 個以上的處方模型成分之使用可例如允許使用不同的模型擬合 =列如’使用一多項式、一乘冪定律、一指數定律等之至少一項之 ^料擬合)’以便獲得最佳資料擬合供—靜態配方成分之不同區域 用0 ,例而言,圖18顯現出一控麵型9〇〇,其顯示出氬氣之流 —j(sccm)與修整量(nm)之間的一種關係。控制模型9〇〇係顯 不出”有供一第一加工範圍用之一第一製程配方91〇,與供一第二 28 1259527 加工fe圍用之一第二製程配方92〇。第一製程配方91〇係對應至大 約14 seem之HF之一流動速率,大約7 sccm之NH3之一流動速率, 以及大約14mTo汀之一壓力。第二製程配方920係對應至大約5〇 seem之HF之一流動速率,大約25 sccq12NH3之一流動速率,以 . 及大約10 mTorr之一壓力。 ' ^使用圖18中之實驗資料之多重曲線擬合以分別定義在每個 加工範圍之修整量與鈍氣之流動速率之間的兩種關係。或者,可 使用圖18中之實驗資料之插補法與外推法以定義修整量與鈍氣之 流動速率之間的一種關係。一個或多個多重曲線擬合可包含一多 f式擬合(polyn〇minal fit)。舉例而言,第一製程配方91〇之一 ❿第二曲線擬合係顯示為一種六次多項式,而第二製程配方卿之 - 一第二曲線擬合係顯示為一種六次多項式。 此外,可改變多項式曲線擬合之次數或階數(〇rder),以便最 佳化精度與每個製程配方之強固度(r〇bustness)。舉例而言,可 ,,多項式擬合之次數,以便使一物理上正確的模型之修整量(或 氬氣流動速率)之範圍最大化。舉例而言,於高修整量(亦即,大 於圖18中之23酬)下使用帛二製程配方,對於氬氣之流動速率為 零之情形可能導致兩個根之發生;參見圖19。此外,舉例而古, \ 配方之曲線擬合之走向可能是錯誤方向。圖20顯示修整i對 鲁氬氣之流動速率的改變之敏感度。例如,對使用於修整量小於約 -10^的第一製程配方910與第二製程配方920之一部分而言',修 整置對氬氣之流動速率之改變或誤差是較不敏感的。然而,第二 製程配方920在用於超過大約10 nm之修整量時顯現出對氬氣之 流動速率之改變之高度敏感的修整量(亦即,在氬氣之流動速率中 大約2 seem之改變可導致大約1挪之修整量之改變)。因此,在 質量流率之控制上的小誤差可顯示成修整量之大誤差。在本笋明 之一實施例令,一單獨的質流控制器係用於每個製程配方,^便 使每個加工範圍之質量流率的解析度最大化。再者,如圖罚示, 當修整量超過大約23· 5 nm時,曲線擬合朝錯誤方向向上翻轉。 29 1259527 藉由使_ 18之#料,圖21顯截顯示為—種二次多 弟-製程配方910之第-曲線擬合,以及顯示為—種五多 製程配方920之第二曲線擬合。參見第二製程配方了第 整量對圖21之各個曲線擬合中之氬氣之 j 交的函數之修整量之走向不再朝錯誤方向。 、羊之改 久相23Α,氬氣之_速率之·懷差(卿,資料盘 ^個曲線擬合之關差異)係被齡為健量(nm)之函數。圖^ ^現出對應於氬氣之流動速率之誤差之健量之誤 葬 ^用圖23A與各個曲線擬合以將流動速率誤差換算成/敫= ^。與第-配方相關的修整量之誤差係小於約〇. 2nm二 衣程配方相關的修整量之誤差係小於約〇. 5 nm。 ”弟一 現在參考® 24’取圖22之:雜之舰關喊錢氣之 速率(seem)之函數之修整量(咖)。圖24顯現出顯示種:二夕 =反向第:製程配方之第一曲線擬合,以種二: 多項式之反向第二製程配方之第二曲線擬合。圖25 tS二係小於約〇.1,而關於第二製程配方 之1>正里之決差係小於約〇· 4 nm 〇 因此,依據本發明之另一個實施例,可將包含資 擬合之至少一製程配方予以最佳化,以便使修整量之誤 π 化。當採用多項式曲線擬合時,最佳化可包含多項式次數之最佳 化。 土 習本項技藝 與優點之情 所有這種修 雖然上述只詳細說明本發明之某些實施例,但熟 者將輕易明白到在沒有實質上背離本發明之嶄新教導 況下’多數修改係可能在本實施例之範圍中 。因此, 改係意圖被包含在本發明之範_之内。 【圖式簡單說明】 ~ 於附圖中: 30 1259527 處理 一熱之供—化學處理系統與 一』狀供—化料理系統與 面圖 圖4顯示依據本發明之另一個實施例之一化學處理系統之立 丨圖$顯示依據本發明之—實施例之一熱處理系統之概要剖面 圖6顯示依據本發明之另一個實施例之一熱處理系統之立 .圖7顯示依據本發明之-實施例之—基板支撐部之概要剖 圖8顯示依據本發明之_實施例之氣體分配系統之概要 圖, 要刹=顯示依據本發明之另—個實施例之—氣體分配系統之概 圖9B顯現出依據本發明之一實施例之圖臥 系統之一展開圖; 礼 圖^ΟΑ與10B顯現出依據本發明之一實施例之圖9 體分配糸統之立體圖; π 丁之亂 圖U顯示依據本發明之一實施例之一基板升降桿組件; 示依據本發明之_實施例之—絕熱組件之側視圖; 圖頒,依據本發明之一實施例之一絕熱組件之俯視圖· 圖14顯示依據本發明之一實施例之一絕熱組件之剖面侧視 體圖 圖 圖; 體 圖 面 體分配 31 1259527 圖Trimming (nm) Ar(sccm) Formulation 2 219 A 3 156 A 4 107 A 5 73.8 A 6 53.2 A 7 100 B 8 74.5 B 9 56.6 B 10 44.3 B 11 36.1 B 12 30.6 B 13 26.8 B 14 24 B 15 21.8 B 16 19.9 B 17 18.2 B 18 16.5 B 19 14 9 B 20 13.3 B 21 11.9 B 22 10.6 B 23 9.5 B In each machining range, a program can be used to calculate the process results (dressing amount) and process parameters ( The relationship between gas flow). The process recipe can include at least one of the following: a nominal formulation component, a static formulation component, and a prescription model component. 27 1259527 Alternatively, some different ingredients and/or different types of ingredients may be used. As shown in the illustrated embodiment, the process recipe used in the first processing range may include a nominal formulation component, a static formulation A component, and a prescription model A component; the process recipe used in the second processing range may include a The rated formulation component, a static formulation B component, and a prescription model B1 component; and the process recipe used in the third processing range, may include a nominal formulation component, a static formulation B component, and a prescription model B2 component. For example, the nominal formulation component spans the entire range of trim data, that is, one trim from 2 nm to 23 nm, as shown in Figure 17. In addition, for example, the nominal formulation component can be divided into two or more static formulation components, that is, the static formulation A component and the static formulation B component, as shown in FIG. It can be a range of trimming _ quantity (ie, component A spanning one of 2 nm to 6 nm, and component ^ B spanning one of 6 nm to 23 nm, see Figure 17) to design each static formula Ingredients (for example, ingredients A and B). Furthermore, each static formulation component can comprise a different amount of the first reactant, a different amount of the second reactant, and a different process pressure (eg, the amount of the first reactant, the amount of the second reactant) The process pressure is fixed for the full range of the static formulation A component, and the amount of the first reactant, the amount of the second reactant, and the process pressure are all for the entire range of the static component. stable). Further, for example, each static formulation. component (ie, components A and B) can be represented by one or more prescription model components. For example, as shown in Fig. 17, the static formula A component is represented by a prescription model component (in other words, the prescription model A component), and the static formula B component is represented by two prescription model components (in other words, the prescription model B1) Composition and prescription model β2 component). The use of more than two prescription model components may, for example, allow for the use of different model fits = columns such as 'using a polynomial, a power law, an exponential law, etc." to obtain the best The data is fitted to different regions of the static formulation component with 0. For example, Figure 18 shows a control surface type 9〇〇, which shows the flow of argon gas between j(sccm) and trimming amount (nm). a relationship. The control model 9 shows that there is a first process recipe for a first processing range of 91〇, and a second process recipe for a second 28 1259527. Formulation 91 corresponds to a flow rate of HF of about 14 seem, a flow rate of NH3 of about 7 sccm, and a pressure of about 14 mTo. The second process recipe 920 corresponds to one of HF of about 5 〇seem. The flow rate, a flow rate of about 25 sccq12NH3, and a pressure of about 10 mTorr. ' ^ Use the multiple curve fit of the experimental data in Figure 18 to define the trim and buff gas in each processing range. The relationship between the flow rates. Alternatively, the interpolation and extrapolation methods of the experimental data in Figure 18 can be used to define a relationship between the amount of trimming and the flow rate of the blunt gas. One or more multiple curves The combination may include a polyf〇minal fit. For example, one of the first process recipes 91〇 is a sixth-order polynomial, and the second process recipe is - a second curve fitting system display A sixth-order polynomial. In addition, the number or order (多项rder) of the polynomial curve fit can be changed to optimize the accuracy and r强bustness of each process recipe. For example, can, polynomial The number of fits to maximize the range of trimming (or argon flow rate) of a physically correct model. For example, use at high trim (ie, greater than 23 in Figure 18) In the second process recipe, the flow rate of argon is zero, which may lead to the occurrence of two roots; see Figure 19. In addition, for example, the curve fit of the formula may be the wrong direction. Figure 20 shows the trimming i sensitivity to changes in the flow rate of argon gas, for example, for a portion of the first process recipe 910 and the second process recipe 920 used for a trim amount less than about -10^, trimming the argon gas The change or error in flow rate is less sensitive. However, the second process recipe 920 exhibits a highly sensitive trimming amount to a change in the flow rate of argon when used for a trim amount in excess of about 10 nm (i.e., in A change of about 2 seem in the flow rate of gas can result in a change in the amount of trimming of about 1). Therefore, a small error in the control of the mass flow rate can be shown as a large error in the amount of trimming. Therefore, a separate mass flow controller is used for each process recipe, so that the resolution of the mass flow rate of each processing range is maximized. Moreover, as shown in the figure, when the trimming amount exceeds about 23.5 At nm, the curve fits up in the wrong direction. 29 1259527 By making the _ 18 material, Figure 21 is shown as the first-curve fit of the second multiple-process recipe 910, and the display is - A second curve fit of the five multi-process recipe 920. Referring to the second process recipe, the amount of trimming of the argon gas in the curve fitting of Fig. 21 is no longer in the wrong direction. The change of the sheep, the long-term phase 23 Α, the argon rate _ rate of the difference (Qing, data disk ^ curve fitting difference) is the function of age is a function of health (nm). Fig. ^ ^ The error of the health of the error corresponding to the flow rate of argon is shown to be fitted with the respective curves in Fig. 23A to convert the flow rate error into /敫 = ^. The error in the amount of trimming associated with the first formulation is less than about 〇. The error of the trimming amount associated with the 2nm coating process is less than about 〇. 5 nm. "Brother 1 now refers to ® 24' to take Figure 22: the amount of trimming of the function of the money of the miscellaneous ship (seem). Figure 24 shows the display species: Erxi = reverse: process recipe The first curve is fitted to the second curve of the inverse second process recipe of the polynomial. Figure 25 tS is less than about 〇1, and the second process recipe is 1> The difference is less than about 〇·4 nm. Therefore, according to another embodiment of the present invention, at least one process recipe containing the fit can be optimized to make the trimming amount π. When using a polynomial curve In the meantime, the optimization may include the optimization of the number of polynomials. The skills and advantages of the present invention are all the same. Although only some embodiments of the present invention are described in detail above, those skilled in the art will readily understand that there is no In the course of the novel teachings of the present invention, the majority of the modifications may be within the scope of the present embodiment. Therefore, the modifications are intended to be included in the scope of the present invention. [Simplified Schematic] ~ In the drawings : 30 1259527 Treatment of a heat supply - Chemistry FIG. 4 shows a schematic view of a chemical processing system according to another embodiment of the present invention. FIG. 1 shows a schematic cross section of a heat treatment system according to an embodiment of the present invention. 6 shows a heat treatment system according to another embodiment of the present invention. FIG. 7 shows a schematic sectional view of a substrate support portion according to an embodiment of the present invention. FIG. 8 shows a gas distribution system according to an embodiment of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 9B showing a gas distribution system according to another embodiment of the present invention shows an unfolded view of a lying system according to an embodiment of the present invention; FIG. 9 is a perspective view showing a body distribution system according to an embodiment of the present invention; FIG. 5 shows a substrate lifting rod assembly according to an embodiment of the present invention; Side view of an insulating component according to one embodiment of the present invention. FIG. 14 is a cross-sectional side view of a heat insulating component according to an embodiment of the present invention. FIG sided FIG fluid distribution 311,259,527

以及 _ j 3示用以處理一基板之流程圖; 化學氧化物移除製程之例示資料; ㈣移除製程用之—控制模型; 圖19 17中所描、、、曰之關係之分解圖;目20 i tm8中所描緣之關係之敏感度; 圖幻動逮率的改變之敏感度; 圖23A鱼你&η _係之敏感度; 圖24顯現‘Γ鱗氧會之關係最佳化之方法; 多除i程用之另一個控制模型; f 25顯示一種使圖21中所插繪 【主要元件符號說明】 9 1〜加工系統 之關係最佳化之方法And _j 3 shows a flow chart for processing a substrate; an exemplary material for a chemical oxide removal process; (4) a process for removing the process-control model; and an exploded view of the relationship between the structures described in FIG. The sensitivity of the relationship between the traces in Figure 20 i tm8; the sensitivity of the change in the phantom capture rate; Figure 23A The sensitivity of the fish you & η _ system; Figure 24 shows that the relationship between the squama and oxygen is best Method of merging; another control model for multiple divisions; f 25 shows a method for optimizing the relationship between the processing of the main component symbols in Fig. 21

1〇〜第一處理系統 20〜第二處理系統 3〇〜傳送系統 40〜多元件製造系統 5 0〜絕緣組件/絕熱組件 100〜加工系統 110〜第一處理系統 120〜第二處理系統 130〜傳送系統 15 0〜絕緣組件/絕熱組件 200〜加工系統 210〜化學處理系統 210’〜化學處理系統 211〜化學處理容室 1259527 212〜密封蓋 213〜把手 214〜扣環 215〜光學檢視窗 216〜壓力感測裝置 217〜鼓键 218〜控制器 220〜熱處理系統 220’〜熱處理系統 221〜熱處理容室 222〜密封蓋 223〜把手 224〜鉸鏈 225〜光學檢視窗 226〜壓力感測裝置 227〜基板"(貞測糸統 230〜絕熱組件 231〜界面板 232〜絕緣板 233〜構造接觸元件 234〜接合表面 235〜對準裝置 235’〜對準接受器 236〜扣接裝置 236’〜接受裝置 237〜凸緣 238〜0型環密封部 239〜閘閥配接板 240〜基板支撐部 1259527 242〜基板 242’〜基板 242’ ’〜基板 244〜基板支撐部組件 250〜真空抽氣系統 252〜真空泵 254〜閘閥 260〜氣體分配糸統 262〜製程空間 266〜壁面加熱元件 267〜氣體分配加熱元件 268〜壁面溫度控制單元 269〜氣體分配系統溫度控制單元 270〜基板支撐部 272〜固定基座 274〜熱障 275〜控制器 276〜加熱元件 278〜基板支撐部溫度控制單元 280〜真空抽氣系統 281〜熱壁面溫度控制單元 283〜熱壁面加熱元件 284〜上部組件 285〜上部組件加熱元件 286〜上部組件溫度控制單元 290〜升降桿組件 294〜共同開口部 296〜閘閥組件 297〜閘閥 34 1259527 298〜開口部 300〜基板支撐部 310〜接合元件 312〜絕緣元件 , 314〜溫度控制元件 , 320〜冷卻劑通道 322〜冷卻劑入口 324〜冷卻劑出口 328〜靜電夾(ESC) 330〜陶瓷層 鲁 332〜夾持電極 334〜高電壓(HV)DC電壓源 336〜電連接部 340〜背面氣體供應部 342〜氣體供應線 344〜溫度感測裝置 350〜絕熱間隙 360〜升降銷組件 、 362〜升降銷 ^ 400〜氣體分配系統 * 觀〜氣體分配組件 404〜氣體分配板 406〜氣體分配充氣腔 408〜氣體分配孔 410〜氣體供應線 410’〜氣體供應線 420〜氣體分配系統 422〜氣體分配組件 424〜元件 35 1259527 426〜元件 428〜元件 430〜第一氣體分配板 432〜第二氣體分配板 440〜第一氣體分配充氣腔 442〜第二氣體分配充氣腔 444〜孔 446〜通道 448〜孔 450〜第一氣體供應通道 452〜第二氣體供應通道 500〜葉片 510〜垂片 520〜凸緣 530〜驅動系統 540〜接受孔穴 600〜加工系統 610〜第一處理系統 620〜第二處理系統 630〜傳送系統 650〜絕緣組件/絕熱組件 800〜流程圖 810-860〜步驟 900〜控制模型 910〜第一製程配方 920〜第二製程配方 361〇1 to 1st processing system 20 to 2nd processing system 3〇~transfer system 40~multi-component manufacturing system 50~insulation component/insulation component 100~processing system 110~first processing system 120~second processing system 130~ Transfer system 15 0~insulation unit/insulation unit 200~processing system 210~chemical processing system 210'~chemical processing system 211~chemical processing chamber 1259527 212~sealing cover 213~handle 214~ buckle 215~ optical inspection window 216~ Pressure sensing device 217 ~ drum button 218 ~ controller 220 ~ heat treatment system 220 ' ~ heat treatment system 221 ~ heat treatment chamber 222 ~ sealing cover 223 ~ handle 224 ~ hinge 225 ~ optical inspection window 226 ~ pressure sensing device 227 ~ substrate " (Measurement system 230 ~ insulation component 231 ~ interface plate 232 ~ insulation plate 233 ~ structure contact element 234 ~ engagement surface 235 ~ alignment device 235' ~ alignment receiver 236 ~ fastening device 236' ~ receiving device 237~Flange 238~0 ring seal portion 239~gate valve adapter plate 240~substrate support portion 1259527 242~substrate 242'~substrate 242''~substrate 244~substrate support Component 250 to vacuum pumping system 252 to vacuum pump 254 to gate valve 260 to gas distribution system 262 to process space 266 to wall heating element 267 to gas distribution heating element 268 to wall temperature control unit 269 to gas distribution system temperature control unit 270~ Substrate support portion 272 to fixed base 274 to thermal barrier 275 to controller 276 to heating element 278 to substrate support portion temperature control unit 280 to vacuum pumping system 281 to hot wall surface temperature control unit 283 to hot wall surface heating element 284 to upper portion Component 285 to upper component heating element 286 to upper component temperature control unit 290 to lifting lever assembly 294 to common opening portion 296 to gate valve assembly 297 to gate valve 34 1259527 298 to opening portion 300 to substrate supporting portion 310 to bonding member 312 to insulating member 314~temperature control element, 320~ coolant passage 322~ coolant inlet 324~ coolant outlet 328~ electrostatic clamp (ESC) 330~ ceramic layer 332~ clamping electrode 334~ high voltage (HV) DC voltage source 336 〜 Electrical connection portion 340 〜 back gas supply portion 342 〜 gas supply line 344 〜 temperature sensing device 350 ~ thermal insulation Gap 360~lift pin assembly, 362~lift pin ^400~gas distribution system* view~gas distribution assembly 404~gas distribution plate 406~gas distribution plenum 408~gas distribution hole 410~gas supply line 410'~gas supply line 420~gas distribution system 422~gas distribution component 424~element 35 1259527 426~element 428~element 430~first gas distribution plate 432~second gas distribution plate 440~first gas distribution plenum 442~second gas distribution charge Cavity 444 ~ hole 446 ~ channel 448 ~ hole 450 ~ first gas supply channel 452 ~ second gas supply channel 500 ~ blade 510 ~ tab 520 ~ flange 530 ~ drive system 540 ~ accept hole 600 ~ processing system 610 ~ A processing system 620 to a second processing system 630 to a transmission system 650 to an insulating component/insulation component 800 to a flowchart 810-860 to a step 900 to a control model 910 to a first process recipe 920 to a second process recipe 36

Claims (1)

I259527 十、申請專利範圍: 1·〆種用來處理基板之加工方法,用以在一 中達^-基板上之-特徵部之—修整量’該方g 程 製程配方設定步驟’為該化學氧化物移二::上. 方’該製程配方設定步驟包含:設定第 二衣^酉己 設定第二製程氣體之數量; 妹㈣之數i ’以及 鈍氣數量設定步驟,域化學躲物 方,以便藉由設定-鈍氣之數量來達成娜碰謂程配 化學處理特徵部步驟,藉由使用該劁 b 學處理該基板上之該特徵部;以及^ —方恭蕗該基板來化 修整量實質上移除步驟,實質上從該特徵部移除該修整量。 板之溫度來熱處理該基板。 予< ⑷細提南該基 衣枉赌之數置之步驟包含設定通之數量。 該鈍5氣數如量^專牛^圍第1項之用來處理基板之加工方法,其中 花数里q步驟包含:設定氬氣之數量。 該化項之用來處理基板之力江方法,其中 特徵#驟包含··獨立於該第二製程氣體以外導入該 1259527 第一製程氣體 7·如申請專利範圍第1項之用來處理基板之加 該製程配方設定步驟更包含:設定_墨力。 去,其中 ’其中 8. 如申請專利細第丨項之用來處理基板之加 該製程配方設定步驟更包含:設定該基板之一溫度。π决 9. 如申請專利範圍第1項之用來處理基板之加工方、土 該製程配方設定步驟更包含:設定一期間用以化學處理方讀去基^中 如申請專利範圍第i項之用來處理基板之加 中該製程配方設定步驟更包含:^ 方法,其 以化學處理該基板。 子處理衣知之―温度用 申請專利範圍第1項之用來處理基板之加U 中该化學處理特徵部步驟包含:化學處理-氧化法,其 除製程來修方5方化學氧化物移 而建立,· 马弟衣知氣體之數量與第二製程氣體之數量 選擇步驟,選擇-目標修整 純氣之目標數量選擇步 藉由使用該關係來達成該^修之—目標數量,用以 化學處理特徵部^正里, 製程氣體、該數量之^ ^由使該基板暴露於該數量之該第一 來化學處理板上程㈣、以及該目標數量之該鈍氣 伐上之5亥特徵部;以及 1259527 整量 目標修整量實質移除步驟,實質上從該特徵部移除該目標修 13· 利範_12項之用來處理基板之加-方法,立 中清洗該基板。 予處理後在一水溶液 量間的關係 中為=數3 ΐί利範圍第12項之用來處理基板之加卫方法,1 ^馮μ數里之该弟一製程氣體與該數量之該第-制 的該關係’包含_HF之-數量與NHH—體而建立 中在該特彳ίίΐί利範圍第12項之縣處理基板之加工方法,並 該特徵部之-修整的該關係’包含 中該ϋϊΓΐ專利範圍第12項之用來處理基板之加工方法,且 該第-iiij破部步驟包含:獨立於該第二製程氣體以外導入 中:係⑵立項之用來處理基板之加1方法, 中該1 關9係^SSSin4:1取加工方法, 其 其 39 1259527 20. 如申请專利範圍第a項之 中該關係更進—步為該化學處理之-射;;建^之加工方法,其 21. ^中請專利範_ 12項之用 中該化學處闕彳_驟包含:化學處理===法,其 請專利範圍第12項之用來處_板之加 包含以下步驟 工方法,更 最,化该關係之步驟,以便使一修整量 該修整量中之該誤差係藉由使用該關係而2盥二中 係之間的—減換算成該修整量之該誤麵決厂里貝枓與_ 23·如申請專利範圍帛12項之用來處理 中該關係決定步驟包含·蔣兮菸敫曰次 土扳之力方法,其 之雜晉之-轉Γ 修整1讀進行曲線擬合成該鈍氣 3將該鈍氣之該數量進行曲線擬合成該修整 24.如申請專利範圍第23項之 中該曲線擬合步驟包含:以多項式擬合。板加方法,其 更 包含:下專利範圍第24項之用來處理基板之加工方法, 該修!,以便使—修整量之誤差最小化,其中 門的係精由使用_係而由該修整量資料與該關 係之間的差/、換异成該修整量之該誤差所決定。 中利範圍第25項之用來處理基板之加工方法,其 中忒取仏化忒關係之步驟包含:調整該等多項式之次數。 1259527 中圍第23項之用來處理基板之加工方法,其 之^個驟包含··將該修整量資料與該純氣之該數量内 之兩個或兩個以上的加工範圍作曲線擬合。 流控制$卩步驟包含·為每個加工翻使用—單獨的質I259527 X. Patent application scope: 1. The processing method for processing the substrate, which is used to adjust the amount of the 'component' in the middle of the substrate. The oxide shifts two:: upper. The 'process recipe setting step includes: setting the second garment to set the number of the second process gas; the sister (four) number i 'and the blunt gas quantity setting step, the domain chemical hiding side In order to achieve the step of the chemical processing feature by setting the amount of blunt gas, the feature on the substrate is processed by using the ;b; and the substrate is trimmed The amount is substantially removed and the trim amount is substantially removed from the feature. The temperature of the plate is used to heat the substrate. To < (4) The steps to set the number of the gambling gambling in the South include the number of settings. The blunt 5 gas number is as follows. The processing method of the substrate is used to process the substrate, wherein the number of steps includes: setting the amount of argon gas. The Lijiang method for processing a substrate, wherein the feature #subject comprises: introducing the 1259527 first process gas independently of the second process gas. 7. The substrate is processed according to the first item of the patent application. Adding the process recipe setting step further includes: setting _ ink force. Going, wherein 'the 8. The processing recipe setting step of applying the patent detail item further includes: setting a temperature of the substrate. π决9. As claimed in the scope of claim 1, the processing unit for processing the substrate, the process recipe setting step further comprises: setting a period for chemical processing to read the base ^ as in the patent application scope i The process recipe setting step for processing the substrate further comprises: a method of chemically treating the substrate. The sub-treatment garment is known as the temperature treatment of the substrate for processing the addition of U. The chemical treatment characteristic step comprises: a chemical treatment-oxidation method, which is formed by removing the chemical oxide shift from the process. , · Ma Diyi knows the quantity of gas and the number of second process gas selection steps, selects the target number of targets to trim the pure gas, selects the step to achieve the target number by using the relationship to chemically process the feature ^正, process gas, the amount of ^ ^ by exposing the substrate to the first amount of the chemical processing on-board (four), and the target number of the 5 Hai feature on the blunt gas; and 1259527 The target target trimming amount substantial removal step substantially removes the target-processing method for processing the substrate from the feature portion, and cleans the substrate in a vertical manner. In the relationship between the amount of the aqueous solution after the treatment, the relationship between the amount of the aqueous solution is = 3 ΐ ί 范围 第 第 第 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来 用来The relationship of the system 'contains _HF-number and NHH-body to establish a processing method for processing the substrate in the special item of the 12th item of the special ,ίίΐί range, and the relationship of the characteristic-trimming' The method for processing a substrate according to Item 12 of the patent scope, and the step of the -iiij breaking portion comprises: introducing the substrate independently of the second process gas: (2) the method for processing the substrate, The processing method of the 1st 9 series ^SSSin4:1, which is 39 1259527 20. If the relationship is further in the item a of the patent application, the processing method is the processing method of the chemical processing; 21. ^In the case of patents _12, the chemistry department _ _ contains: chemical treatment === method, which is used in the scope of the patent scope of the 12th _ board plus the following steps, More, the steps of the relationship are made so that the trimming amount is adjusted. The error is calculated by using the relationship between the two-line system and the subtraction into the trimming amount. The error is determined by the factory and the _23. The relationship determining step includes the method of the force of the Jiang 兮 敫曰 敫曰 敫曰 , , , , , , , Γ 修 修 修 修 修 修 修 修 修 修 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线 曲线24. The curve fitting step of claim 23, wherein the curve fitting step comprises: fitting with a polynomial. The board adding method further comprises: a processing method for processing a substrate according to item 24 of the patent scope, wherein the error of the trimming amount is minimized, wherein the trimming of the door is performed by using the system The difference between the quantity data and the relationship is determined by the error of the variation. The processing method for processing a substrate according to item 25 of the Zhongli scope, wherein the step of extracting the bismuth telluride relationship comprises: adjusting the number of times of the polynomial. 1259527 The method for processing a substrate according to item 23 of the middle section, wherein the method comprises: fitting the trimming amount data to two or more processing ranges within the quantity of the pure gas . Flow control $卩 step contains · for each processing turn - separate quality 學氧化物移除製程設定—製程配方,其h定該製程 驟包含:設定册之一數量,以及設定NH3之一數量; 為氧化物移除製程調整該製程配方,以便藉由設定氨 乳之一數1來達成該修整量; 少4製*配方恭露該基板之方式以化學處理該基板上 Μ特徵和其中魏量之該HF係獨立於該數量之該腿而被導 入,而該數量之該氬氣與該數量之該ΝΗ3一起被導入;以及 從該特徵部實質上移除該修整量, 其中增加該數量之該氬氣係對應於減少該修整量。 w制種用來處理基板之加工系、统,用以在一化學氧化物移 除衣程中達成一基板上之一修整量,該系統包含: 。友化學處理系統,用以藉由使該基板暴露於一數量之第一製 ^氣體、-數量之第二製程氣體、以及—數量之—鈍氣來改變^ |扳上之複數個露出表面層; 熱處理糸統,用以熱處理該基板上之該等受到化學改變之 表面層;以及 控制器,其連接至該化學處理系統並用以調整該鈍氣之該 41 1259527 數量,以便達成該修整量 十一、圖式:The oxide removal process setting - the process recipe, wherein the process includes: setting the quantity of one of the settings, and setting the quantity of NH3; adjusting the process recipe for the oxide removal process to set the ammonia solution a number of 1 to achieve the trimming amount; a lesser 4 formula * method of deducting the substrate to chemically process the substrate on the top surface feature and wherein the amount of the HF is introduced independently of the number of the leg, and the number The argon gas is introduced with the amount of the crucible 3; and the trim amount is substantially removed from the feature, wherein increasing the amount of the argon gas system corresponds to reducing the trim amount. The seed processing system for processing a substrate for achieving a trimming amount on a substrate in a chemical oxide removal process, the system comprising: a chemical processing system for modifying a plurality of exposed surface layers by exposing the substrate to a quantity of the first gas, the second amount of the process gas, and the amount of blunt gas a heat treatment system for heat treating the chemically altered surface layer on the substrate; and a controller coupled to the chemical processing system for adjusting the amount of the insufficiency of the 41 1259527 to achieve the trim amount First, the schema:
TW94110006A 2003-11-12 2005-03-30 Processing system and method for treating a substrate TWI259527B (en)

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US10/704,969 US7079760B2 (en) 2003-03-17 2003-11-12 Processing system and method for thermally treating a substrate
US10/705,397 US7214274B2 (en) 2003-03-17 2003-11-12 Method and apparatus for thermally insulating adjacent temperature controlled processing chambers
US10/705,200 US6951821B2 (en) 2003-03-17 2003-11-12 Processing system and method for chemically treating a substrate
US10/705,201 US7029536B2 (en) 2003-03-17 2003-11-12 Processing system and method for treating a substrate
US10/812,347 US20050227494A1 (en) 2004-03-30 2004-03-30 Processing system and method for treating a substrate

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