TWI245413B - Method for eliminating inverse narrow width effects in the fabrication of dram device - Google Patents

Method for eliminating inverse narrow width effects in the fabrication of dram device Download PDF

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TWI245413B
TWI245413B TW092115612A TW92115612A TWI245413B TW I245413 B TWI245413 B TW I245413B TW 092115612 A TW092115612 A TW 092115612A TW 92115612 A TW92115612 A TW 92115612A TW I245413 B TWI245413 B TW I245413B
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layer
doped
semiconductor substrate
random access
access memory
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TW092115612A
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Chinese (zh)
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TW200501397A (en
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Ming-Cheng Chang
Tieh-Chiang Wu
Yi-Nan Chen
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Nanya Technology Corp
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Abstract

The present invention provides a method for eliminating inverse narrow width effects in the fabrication of DRAM devices. A semiconductor substrate is provided having thereon a shallow trench. The shallow trench surrounds an active area. A non-doped silicate glass (NSG) layer is deposited to fill the shallow trench, and is then etched back to a depth of the shallow trench, thereby exposing a portion of the semiconductor substrate at an upper portion of the shallow trench. A doped dielectric layer is deposited over the remaining NSG layer to cover the exposed semiconductor substrate. A thermal process is then carried out to diffuse dopants of the doped dielectric layer out to the semiconductor substrate, thereby forming a doped region at the periphery of the active area.

Description

1245413 -— 案號 92115612_年 ^_Θ_修正____^ 五、發明說明(1) 發明所屬之技術領域 本發明係相關於一種半導體製程,尤指一種動態隨 機存取記憶體(Dynamic Random Access Memory,簡稱為 DR AM)元件之製作方法,可以避免電晶體之反轉窄線寬效 應(inverse narrow width effects)。 先前技術1245413-Case No. 92115612_year ^ _Θ_Amendment ____ ^ V. Description of the Invention (1) Field of the Invention The present invention relates to a semiconductor process, especially a dynamic random access memory (Dynamic Random Access Memory). (Referred to as DR AM) components, which can avoid the inverse narrow width effects of transistors. Prior art

隨著各種電子產品朝小型化發展之趨勢,dram元件 的設計也必須符合高積集度、高密度之要求,而溝渠電 容DRAM元件結構即為業界所廣泛採用之高密度dram架構 之一’其係在半導體基材中钱刻出深溝渠並於其内製成 溝渠電容,因而可有效縮小記憶單元之尺寸,妥善利用 晶片空間。 請參閱圖一及圖二,其中圖一為習知溝渠電容dram 單元1之佈局示意圖,圖二為圖一中沿著切線AA,之剖面 側視圖。如圖一所示,溝渠電容DRAM單元1包含有一開關 電晶體(pass transist〇r)2,其設於一主動區域(Acti ve A r e a,A A ) 1 0上,以及一與開關電晶體2電連接之溝渠電 容結構3。主動區域1 0,例如p型矽基底,係被溝渠絕緣 (Shallow Trench Isolation,STI)區域 20所隔離。開關 電晶體2包括有一多晶石夕閘極(Gate Conductor,GC〇12、 一 N型摻雜源極1 0 1、一 N型摻雜汲極1 〇 2。N型摻雜源極With the development of various electronic products toward miniaturization, the design of dram components must also meet the requirements of high accumulation and high density. The trench capacitor DRAM device structure is one of the high-density dram structures widely used in the industry. The deep trench is carved in the semiconductor substrate and a trench capacitor is made in it, so the size of the memory cell can be effectively reduced and the chip space can be properly used. Please refer to FIG. 1 and FIG. 2, wherein FIG. 1 is a schematic diagram of the layout of the conventional trench capacitor dram unit 1, and FIG. 2 is a cross-sectional side view along the tangent line AA in FIG. 1. As shown in FIG. 1, the trench capacitor DRAM cell 1 includes a switching transistor 2, which is disposed on an active area (Acti ve Area, AA) 10, and is electrically connected to the switching transistor 2. Connected trench capacitor structure 3. The active region 10, such as a p-type silicon substrate, is isolated by a trench isolation (STI) region 20. The switching transistor 2 includes a polycrystalline silicon gate (Gate 12), an N-type doped source 110, and an N-type doped drain 102. The N-type doped source

1245413 -— -一_—年曰 修 ^ 五、發明說明(2) ~一~~ 〜 1、〇1以-及N型摻雜汲極102定義出一通道區域103(如斜線區 域所不),其具有一通道長度L以及通道寬度w。開關電晶 體2的N型摻雜源極1 〇 1係藉由一接觸洞1 8與一位元線(圖 未示)電連接,開關電晶體2的N型摻雜汲極i 02則與溝^ 電容結構3之下層儲存電極(圖未示)電連接。如圖二所& 示’在多晶石夕閘極1 2與主動區域1 〇之間尚有一閘極 層1 3。 緣 由於DRAM元件朝微小化發展之需要,使得上述溝泪 電容DRAM單元1之通道長度L以及通道寬度w目前幾乎縮^、 至接近奈米等級之尺寸。如熟習該項技藝者所知,通、首 長度L的縮短會導致短通道效應(sh〇rt channel ^ effect),對此,已有許多研究針對短通道效應提出 方案。然而,針對通道寬度W同時縮小所引起的溝渠絕= 轉角效應(STI corner effect)、或所謂的反轉窄線寬效 應(inverse narrow width effects)以及啟始電壓 ’ (threshold voltage’ Vt)下降造成之次啟始°電壓漏電、、六 (sub-threshold voltage leakage)現象則較少有人 机 墨。這些問題在元件接近奈、米等級時將嚴重影響其 效能,而將成為DRAM元件進一步微小化之瓶頸。 發明内容 種DRAM元件之製 據此,本發明之主要目的在提供一 作方法,已解決上述問題。 1245413 五 事號 92115612 、發明說明(3) 年 月 修正 態隨 一半 成一 底; 形成 雜犧 該淺 底; 介電 底; 型離 一第 為達 機存 導體 襯墊 經該 至少 牲層 溝内 於該 層, 以及 上述目的, 取記憶體元件之方法 基底,具有 層,該襯塾 開口餘刻該 本發明較佳實 包 一第一導電型 一淺溝,同 ,並填滿該 之一預定深 未摻雜犧牲 且該介電層 進行一擴散 子擴散至談半導 一導電型摻雜區 層有 半導 時定 淺溝 度, 層上 覆蓋 製程 體基 開 至少 體基 義出 ;回 藉此暴露 沈積 該淺 ,將 底, 底 主 餘刻 摻 溝中 該介 以於 施例揭 含有下 :於該 口暴露 以於該 動區域 該未摻 出部份 雜第一 暴露出 電層内 該主動 露一種 列步驟 半導體 出該半 半導體 ’沈積 雜犧牲 該半導 導電型 之該半 之該第 區域週 製作動 •提供 基底形 導體基 基底内 一未摻 層,至 體基 離子之 導體基 一導電 邊形成 為了使 貴審查委員食t爭·斤— 2技:内容,請參閱以“ 明之特徵 ,。然而所附圖式僅供參考與 ^ =砰細說明與附 本發明加以限制者。 °兄月用,並非用來對 實施方式 凊參閱圖三至圖八,圖三 實施例製作溝渠電容DRAM元:沾f八為依據本發明較佳 中,相同或類似之元件或區域、、κ法之剖面示意圖,其 a〜用相同之編號。首先, 1245413 _案號92115612_年 月__曰 」^不 五、發明說明(4) 如圖三所示,提供一 P型半導體基底1〇〇,其上已完成有 複數個溝渠電容結構(圖未示)。半導體基底1 〇 〇表^面上具 有一墊氧化(pad oxide)層41以及一墊氮化石夕(pad nitride)層42。接著利用黃光及蝕刻製程,利用塾氧化 層41以及一墊氮化矽層42為蝕刻遮罩,於半導體基底1〇〇 表面上餘刻出複數個溝渠30’同時定義出主動區域 如圖四所示,於半導體基底10 0上沈積一未摻雜矽玻 璃(Non-doped Silicate Glass,NSG)層 52,並填滿溝渠 30。NSG層52的製作可以習知方式完成,例如化學氣相沈 積(chemical vapor deposition,CVD)製程。需注音的 是’ NSG層52亦可採用其它與墊氮化矽層42之間·^且/有刻 選擇比之材質者。 ^ 如圖五所不,接著回蝕刻一預定厚度之NS^ 52,形 成凹陷缺口 54,藉此暴露出在溝渠3〇角落部位6〇之矽基 底主動區域10。 如圖六所不,於半導體基底1〇〇上沈積一摻雜硼之 料層 62,例如硼矽玻璃(boro_siHcate —gUss,BSG),1245413---_-Years Revision ^ V. Description of the invention (2) ~~~~~ 1, 〇1 and-and N-type doped drain 102 define a channel region 103 (as in the slanted region) , Which has a channel length L and a channel width w. The N-type doped source 1 of the switching transistor 2 is electrically connected to a bit line (not shown) through a contact hole 18, and the N-type doped drain i 02 of the switching transistor 2 is connected to The trench ^ capacitor structure 3 is electrically connected to a storage electrode (not shown) below. As shown in Figure 2 & 'there is still a gate layer 13 between the polycrystalline stone gate 12 and the active region 10. Because of the need for miniaturization of DRAM elements, the channel length L and channel width w of the above-mentioned trench capacitor DRAM unit 1 are now almost reduced to a size close to the nanometer level. As those skilled in the art know, the shortening of the length L and the head length L will cause a short channel effect. In this regard, many studies have proposed solutions for the short channel effect. However, for channel ditch caused by simultaneous reduction of channel width W = STI corner effect, or the so-called inverse narrow width effects, and the decrease in threshold voltage 'Vt' Secondly, the phenomenon of ° voltage leakage and sub-threshold voltage leakage is less man-made. These problems will seriously affect the performance when the device is close to the nanometer and meter level, and will become a bottleneck for further miniaturization of DRAM devices. SUMMARY OF THE INVENTION Accordingly, the main object of the present invention is to provide a method for solving the above problems. 1245413 May number 92115612, description of the invention (3) The year-month correction state becomes a bottom with half; the shallow bottom is formed; the dielectric bottom is formed; the first-line storage conductor pad passes through the at least the trench This layer, and the above-mentioned object, a method substrate for taking a memory element, has a layer, and the opening of the liner is engraved with a first conductive type and a shallow trench, preferably the same, and fills one of the predetermined depths. The dielectric layer is sacrificed and the dielectric layer is diffused by a diffuser to a semiconducting-conductive type doped region. The layer has a semiconducting timed shallow groove. The layer is covered with a process body and at least the body is defined. Deposit the shallow layer, and add the bottom and bottom to the trench. In the example, the following is included: exposed at the mouth to the non-doped part in the moving area, first exposed in the electrical layer, the active exposure. A series of steps semiconductor out of the semi-semiconductor deposition of the semi-conducting conductive half of the semi-conducting conductivity type region to provide a base-shaped conductor-based substrate without a doped layer to the bulk of the ion A conductive edge of the body is formed in order to allow your review committee to compete with each other. For the content, please refer to the characteristics of "Ming." However, the drawings are for reference only and ^ = detailed description and the present invention are limited. ° For the month and month, it is not for implementation. Refer to Figure 3 to Figure 8. The embodiment of Figure 3 is used to make trench capacitor DRAM cells: Zf is the same or similar element or area in accordance with the present invention. Schematic diagram of the cross section of the κ method, with a ~ using the same number. First, 1245413 _ case number 92115612_ year month __ "" No. 5. Description of the invention (4) As shown in Figure 3, a P-type semiconductor substrate is provided. At 100, a plurality of trench capacitor structures (not shown) have been completed thereon. The semiconductor substrate 100 has a pad oxide layer 41 and a pad nitride layer 42 on its surface. Then using yellow light and etching processes, using hafnium oxide layer 41 and a silicon nitride layer 42 as an etching mask, a plurality of trenches 30 'are etched on the surface of the semiconductor substrate 100 at the same time, and the active area is defined as shown in Figure 4. As shown, a non-doped silica glass (NSG) layer 52 is deposited on the semiconductor substrate 100 and fills the trenches 30. The NSG layer 52 can be fabricated in a conventional manner, such as a chemical vapor deposition (CVD) process. What needs to be pronounced is that the NSG layer 52 can also be made of other materials that are between the silicon nitride layer 42 and the substrate. ^ As shown in Figure 5, the NS ^ 52 of a predetermined thickness is then etched back to form a recessed notch 54 to expose the silicon-based active region 10 at the corner 30 of the trench 60. As shown in Figure 6, a boron-doped material layer 62, such as borosilicate glass (boro_siHcate-gUss, BSG), is deposited on the semiconductor substrate 100,

且摻雜硼之材料層62與在溝渠3〇角落部位6〇之矽基底兰 動區域1 0相接觸。 材料層62内的爛離子外擴散1溝=部The boron-doped material layer 62 is in contact with the silicon substrate blue region 10 at the corner 30 of the trench. Diffuser ions in the material layer 62 are diffused outward by 1 groove = part

第10頁 1245413 案號92115612 一__^ 月 日—_—修正 i、發明說明(5) 底主動區域1 0,形成P型摻雜區7 0,使得p型摻雜區7 0之 爛濃度大於主動區域1 0之硼濃度。 如圖八所示’接著利用钱刻溶液,例如緩衝氧化姓 刻液(buffered oxide etcher,BOE),去除摻雜删之材 料層62以及NSG層52。接下來的步驟包括STI介電層的填 入' STI介電層化學機械研磨、去除墊氧化層41以及墊氮 化石夕層4 2,以及定義閘極或字元線,最後之結果如圖九 所示,即完成在閘極通道寬度方向上,兩侧鄰近ST I角落 處具有P型掺雜區70之結構。Page 10 1245413 Case No. 92115612 1 __ ^ Month day __ Amendment i. Description of the invention (5) The bottom active region 10, forming a P-type doped region 7 0, makes the p-type doped region 70 0 rotten A boron concentration greater than 10 in the active region. As shown in FIG. 8 ', the doped material layer 62 and the NSG layer 52 are then removed using a money-etching solution, such as a buffered oxide etcher (BOE). The next steps include the filling of the STI dielectric layer. The STI dielectric layer is chemically and mechanically polished, the pad oxide layer 41 and the pad nitride nitride layer 42 are removed, and the gate or word line is defined. The final result is shown in Figure 9 As shown, that is, a structure having a P-type doped region 70 at the corners of both sides adjacent to ST I in the width direction of the gate channel is completed.

相較於先前技術,本發明針對通道寬度W同時縮小所 引起的溝渠絕緣轉角效應(STI corner effect)、或所謂 的反轉窄線寬效應(inverse narrow width effects)以 及啟始電壓(threshold voltage,Vt)下降造成之次啟始 電壓漏電流(sub-threshold voltage leakage)現象,可 利用在閘極通道寬度方向上,兩側鄰近ST I角落處具有p 型摻雜區7 0之電晶體結構解決之。上述優點已顯示本發 明完全符合專利法所規定之產業利用性、新穎性及進步 性等法定要件,爰依專利法提出申請,敬請詳查並賜准 本案專利。 以上所述僅為本發明之較佳實施例,凡依本發明申 請專利範圍所做之均等變化與修飾,皆應屬本發明專利 之涵蓋範圍。Compared with the prior art, the present invention addresses the trench insulation corner effect (STI corner effect), or the so-called inverse narrow width effects and threshold voltage, caused by the simultaneous reduction of the channel width W. The phenomenon of sub-threshold voltage leakage caused by the drop in Vt) can be solved by using a transistor structure with a p-type doped region 70 at the corners of the gate channel width direction on both sides adjacent to ST I. Of it. The above advantages have shown that the present invention fully complies with the statutory requirements of industrial availability, novelty, and progress as stipulated by the Patent Law. The application was made in accordance with the Patent Law. Please check and approve the patent in this case. The above description is only a preferred embodiment of the present invention, and any equivalent changes and modifications made in accordance with the scope of the patent application of the present invention shall fall within the scope of the patent of the present invention.

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1245413 _案號92115612_年月曰 修正__ 圖式簡單說明 、 圖式之簡單說明 圖一為習知溝渠電容DRAM單元之佈局示意圖。 圖二為圖一中沿著切線A A ’之剖面側視圖。 圖三至圖九為依據本發明較佳實施例製作溝渠電容 DRAM元件的方法之剖面示意圖。( 圖式之符號說明1245413 _Case No. 92115612_ Year Month Amendment __ Brief Description of Drawings, Simple Description of Drawings Figure 1 is a schematic diagram of the layout of a conventional trench capacitor DRAM cell. FIG. 2 is a cross-sectional side view taken along line A A ′ in FIG. 1. 3 to 9 are schematic cross-sectional views of a method for fabricating a trench capacitor DRAM device according to a preferred embodiment of the present invention. (Symbol description

1 溝渠電容DRAM單元 2 開關電晶體 3 溝渠電容結構 10 主動區域 12 多晶砍閘極 13 閘極絕緣層 18 接觸洞 20 溝渠絕緣區域 30 溝渠 41 墊氧化層 42 塾氮化^夕層 52 NSG層 54 凹陷缺口 60 溝渠角落部位 62 摻雜删之材料層 70 P型摻雜區 100 P型半導體基底 101 N型摻雜源極 102 N型摻雜没極 103 通道區域1 trench capacitor DRAM unit 2 switching transistor 3 trench capacitor structure 10 active area 12 polycrystalline gate 13 gate insulation layer 18 contact hole 20 trench insulation area 30 trench 41 pad oxide layer 42 nitride layer 52 NSG layer 54 Depression notch 60 Trench corner 62 Doped material layer 70 P-type doped region 100 P-type semiconductor substrate 101 N-type doped source 102 N-type doped electrode 103 Channel region

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Claims (1)

1245413 案號 92115612 年 月 曰 六、申請專利範圍 1 · 一種製作動態隨機存取記憶體元件之方法,包含有 下列步驟: 、 提供一半 於該半導 開口暴露出該 經該開口 形成至少一淺 沈積一未 回钱刻該 度,藉此暴露 於該未摻 介電層,且該 底;以及 導體基底 體基底形 半導體基 蝕刻該半 溝,同時 摻雜犧牲 未換雜犧 出部份該 雜犧牲層 介電層覆 ,具有一 成一襯塾 底; 導體基底 定義出一 層,並填 牲層,至 半導體基 上沈積一 盍該淺溝 進行一擴散製程, 導體基底 子擴散至該半 一導電型摻雜 將該介電 ,以於該 第一導電型; 層,該襯墊層有至少一 ,以於該半導體基底内 主動區域, 滿該淺溝; i 該淺溝内之一預定味 底; 摻雜第一導電蜇離子之 中暴露出之該半導體基 層内之該第一導電漤f 主動區域週邊形成一第 區 二开ί ί ΐ專利範園第1項所述之製作動態隨機存取記憶第:導電型半導體基底具有-第 且該第雜^士 = 摻雜區有—第二摻雜濃度, 且通弟一摻雜濃度大於該第一摻雜濃度。 3·如申請專利範圍第1項所述之製 體70件之方法,其中該第一導電型為p型悲隨機存取記憶1245413 Case No. 92115612 6. Application Patent Scope1. A method for making a dynamic random access memory device includes the following steps: 1. Providing half of the semiconductive opening to expose at least one shallow deposit through the opening; The degree is engraved as soon as no money is returned, thereby being exposed to the un-doped dielectric layer and the bottom; and the conductor substrate body-shaped semiconductor substrate etches the half-trench, and at the same time doping sacrifices does not change the impurity sacrificing part of the impurity sacrificing A layer of dielectric layer has a lining substrate; a conductive substrate defines a layer, and a layer is filled, and a stack of the shallow trench is deposited on the semiconductor substrate for a diffusion process, and the conductive substrate is diffused to the semi-conductive type dopant. Doped with the dielectric to the first conductivity type; layer, the pad layer has at least one, so that the active area in the semiconductor substrate is filled with the shallow trench; i a predetermined taste bottom in the shallow trench; doped The first conductive ions in the semiconductor base layer exposed among the first conductive ions are formed around the active area of the first conductive ions. A second area is opened. Ί Patent Patent Park Item 1 Production of said dynamic random access memory of: a semiconductor substrate having a conductivity type - the first and second doped regions heteroaryl ^ = disabilities have - a second doping concentration, and a brother through doping concentration greater than the first doping concentration. 3. The method of making 70 pieces as described in item 1 of the scope of patent application, wherein the first conductivity type is p-type sad random access memory 第13頁 1245413 ---tS_92H56^_年 月 日 修正 六、申請專利範圍 / 4 ·—如申請專利範圍第1項所述之製作動態隨機存取記憶 體元件之方法,其中該襯墊層包含有一墊氧化層及一墊 氮化矽層。 曰 5·如申請專利範圍第1項所述之製作動態隨機存取記憶 體元件之方法,其中該未摻雜犧牲層係為一未摻雜砍玻 璃(Non-doped Si 1 icate Glass,NSG)層。 乂 6·一如申請專科範圍第1項所述之製作動態隨機存取記憶 體兀件之方法,其中該摻雜第一導電型離子之 係 為一硼矽玻璃(boro-siiicate —glass,BSG)層。曰 7 ·如申請專利範圍第1項所述之製作私能_ 冰 触-从★七土甘士外尸吓义^表作動悲隨機存取記憶 體兀件之方法,其中該方法在形成該第一 之後尚包含有下列步驟: 去除該介電層;以及去除該未摻雜犧牲層。Page 13 1245413 --- tS_92H56 ^ _ year, month, day, amendment 6 、 Scope of patent application / 4 · —The method for making a dynamic random access memory device as described in item 1 of the scope of patent application, wherein the liner layer contains There is a pad of oxide layer and a pad of silicon nitride layer. 5. The method for manufacturing a dynamic random access memory device as described in item 1 of the scope of the patent application, wherein the undoped sacrificial layer is a non-doped Si 1 icate Glass (NSG). Floor.乂 6. The method for making a dynamic random access memory element as described in the first item of the application scope, wherein the first conductive ion-doped system is boro-siiicate-glass (BSG) )Floor. Day 7 · Making private power as described in item 1 of the scope of patent application _ Bing Touch-a method of making random access memory elements from the horrible corpse of the Seven Soil Gan Shi, where the method is forming the The first step further includes the following steps: removing the dielectric layer; and removing the undoped sacrificial layer.
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