TWI241860B - Organic light-emitting device - Google Patents

Organic light-emitting device Download PDF

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Publication number
TWI241860B
TWI241860B TW93107004A TW93107004A TWI241860B TW I241860 B TWI241860 B TW I241860B TW 93107004 A TW93107004 A TW 93107004A TW 93107004 A TW93107004 A TW 93107004A TW I241860 B TWI241860 B TW I241860B
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Taiwan
Prior art keywords
light
cover
substrate
bonding
sealing strip
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TW93107004A
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Chinese (zh)
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TW200533224A (en
Inventor
Jau-Ji Peng
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Lightronik Technology Inc
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Publication of TWI241860B publication Critical patent/TWI241860B/en

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Abstract

An organic light emitting device includes a substrate, a cover disposed above the substrate with a space therebetween, a bonding unit for bonding the substrate and the cover, a light-emitting unit coated on the substrate, and a main moisture-absorbing unit for absorbing moisture. The light-emitting unit is coated on the top of the substrate and includes a plurality of organic light-emitting diodes (OLEDs) arranged in form of an array. The bonding unit includes a main seal strip that is fixed between the substrate and the cover and seals and surrounds the periphery of the light-emitting unit. The cover is fixed at a space above the light-emitting unit. A closed space is commonly defined by the cover, the substrate, and the main seal strip. The main moisture-absorbing unit is fixed on the bottom of the cover and located in the closed space, and surrounds the periphery of the light-emitting unit.

Description

1241860 玖、發明說明: 【發明所屬之技術領域】 本發明是有關於一種有機電激發光裝置,特別是指一 種具防潮結構之有機電激發光裝置Q 【先前技術】 一般有機電激發光裝置的基本結構,大致如圖1所示 ,是在一由玻璃或透明塑膠所製成之基板21頂面被覆設置 一發光單元22 ,此發光單元22是由多數矩陣型態排列之有 機電激發光二極體 221(〇rganic Ught-Emitting Diode,縮略 為0LED)組成,對整體發光裝置而言,每一 〇LED都是— 可被控制明滅之晝素(pixel),由於〇LED的基本結構已為相 關業界所熟知’以下不再詳細揭露與說明。 没計上由於發光單元22中之〇LED若受濕氣侵襲,容 易影響運作機能,因此為了避免發光單元22受濕氣侵襲, 會在基板21頂面膠合一(長)方框狀膠條23,使膠條23封閉 圍繞在發光單元22周圍,並利用一封蓋24接合在膠條23 頂面,使發光單元22被封閉在基板21、封蓋24與膠條23 所圍接出之密閉空間20内。此外,發光裝置更在封蓋24 朝向發光單元22底面先形成一凹穴241,並在凹穴241内 容裝一含有吸濕劑之吸濕層25,藉吸濕層25吸收濕氣以確 保發光單元22不致受潮。 前述習知有機電激發光裝置配置吸濕層25之構造設計 隹;、、;可達到預防發光單元22受潮之效果,但由於該吸濕 層25的σ又置,必須在封蓋24底面開設凹穴241,凹穴 1241860 一般是^砂或_製成,造成封蓋24的平整度、透光率 、 不士加工萷,而且吸濕層25本身也會阻礙光線, 此等因素造成不利於發光單元22由該側發錢示,亦即只 有基板21側適合作為發光面,封蓋24側並不適合。 【發明内容】 口此,本發明之目的,即在提供一種所設置之防潮結 構不會影響封蓋之平整度、透光率及強度之有機電激發: 裝置。 ίο 15 於疋,本發明有機電激發光裝置包含:一基板、—間 ,位於該基板上方之封蓋、—絲接合基板與封蓋之接: 早凡、「被覆在該基板上之發光單元,及一用來吸收水氣 之主吸濕體。該發光單元是被覆在該基板頂面,並包括有 夕數矩陣型態排列之有機電激發光二極體。該接合單元包 括有一固接在該基板盘封蓋門之幸㈣这+ 早7"包 攸/、封盍間之主封接條,該主封接 封閉圍繞在該發光單元周圍。該封蓋是間隔位在該發光單 疋上方,該封蓋並與該基板、該主封接條共同界定出—密 閉空間。該主吸谋辦H m 及濕體疋固定在該封蓋底面,並位於該 空間内且圍繞在該發光單元周圍。 本發明之功效,是藉主吸濕體圍繞設置在發光單元外 圍’而提供甚佳之吸濕效果且不致影響封蓋的 光率及強度。 X、透 【實施方式】 、 〜/入六他孜術q分,付點興功效, 以下配合參考圖式之四種輕彳 裡奴仏貫施例的詳細說明中,將 20 1241860 清楚的明白。 圖2、3所不,本發明有機電激發光裝置 貫施例,包含有一基板3 、士变+ 乐半乂佳 4 販3、一被覆在該基板3上之發光單元 ..多口之接合單凡5、—固接在該接合單元5上之封 盘6,及-用來吸收水氣之主吸濕體71。 封 該基板3可由玻璃或透明塑膠製成。 指料光早疋4包括多數以矩陣型態排列被覆在該基板3 頂面之有機電激發光二 —才體41,該等有機電激發光二極體 ίο 15 1通常是彻驗方式被覆在該基板3上。 5包括有—膠合固接在該基板3頂面之主 =51。在本實施例中該主封接條51是呈⑻方框狀體 f:厚度遠大於該發光單& 4之厚度,並間隔圍繞在發 光早兀4周圍。 該封蓋6是固接在該接合單元5之主封接條Μ頂面, =㈣㈣發光單元4上方。該封蓋6並與該基板3、該 主封接條5 1共同界定出一 — 在閉玉間8。此外,封蓋ό朝發 、之側為平面,且封蓋6的材質可為玻璃、陶磁 :”或塑並具有-凹陷於其底面之環溝61,該環溝 疋位在該密閉空間8内且圍繞在該 該環溝61不以連續為必要。 门㈤ 該主吸濕體71便是固定容置在該封蓋6之環溝61内 ’而圍繞在該發光單开 周圍。该主吸濕體71藉由固狀、 二:大之:及濕材料’而能吸收水氣’以防止密閉空間 大子在水氣導致發光單元4受潮。 20 ίο 15 20 1241860 藉此’本實施例中該主吸濕體71之分佈情形,是圍繞 在該密閉空間8近邊緣處,並位在該發光單元*外圍,因 此可在外部濕氣侵人該㈣空間8時,便立即經由主吸濕 體71加以吸收,而能更有效預防發光單元4受潮。 ‘、 由於該主吸濕、體71是圍繞設置在發光單S 4外圍,也 就是說在封蓋6對應於發光單元4之底面位置,並未開設 任何:影響平整度、透光率及強度之凹穴結構,因此不僅 毛光單70 4可往下由基板3側發光顯示’也可往上從封蓋6 側發光顯示,亦即整體有機電激發光I置藉由此一設 可適用於基板面或蓋板面或雙面發光顯示,確實已:: 知設計之缺點。 " 如圖4、5所示,本發明有機電激發光裝置的第二較佳 貫施例與前述第-實施例不同處在於:該接合單元5更包 括有—接合在該基板3舆該封蓋6間之内接合條Μ。該主 與内接合條52是呈—大—小之(長)方框狀體,且 :條52相對於主封接條51及主吸濕體71是較接近該 二先…。使該封蓋6底面之環溝61,是介於主封接條 與内接合條52間,也就是說該主吸濕體71是介於 f條51與内接合條52間,當'然相對於發光單元4而言, 。亥主吸濕體71同樣是圍繞在該發光單it 4外圍。 藉此,當外界濕氣欲侵入發光單元4 封接條51斑内接人格貝光後通過主 便… 条在濕氣—通過主封接條Η時, 阻;在主:由主吸濕體71加以吸收,加上該内接合條52 在主吸濕體71内圍’可進-步加強阻隔濕氣之效果。 !24186〇 ,圖6所7"" ’本發明有機電激發光裝置的第三較佳實 述第二實施例不同處在於:該接合單元$是之内 上具有多數内外貫通之缺口 521,也就是說設計 對^要/條52並不以封閉阻隔在主吸濕體7丨内圍為絕 10 15 ^如圖―7、8所示,本發明有機電激發光裝置的第四較佳 二了雨一實施例不同處在於:該有機電激發光裝 结^含有一辅助吸濕體72,該封蓋6底面更凹陷有一圍 亥主封接條51外圍之長方框形辅助環溝62,該辅助環 ^便是用來容置該輔助吸濕體72。此外,該接合單元5 ^括有-接合於基板3與封蓋6間之辅助封接條^,該 助封接條53是間隔圍繞在該辅助環溝62外圍。 助21b 7外界濕氣欲侵祕料元4,必㈣後通過輔 與主封接條51,在濕氣通過輔助封接條53盘 主封接條51時,會分別經由輔助吸濕體72與主吸渴體 加以吸收’因此本實施例之設計,具有雙重吸濕作用,更 能顯著提升發光單元4之防潮效果。 又’在此須進一步說明的是,本實施例中是以設置一 組輔助封接條53與辅助吸濕體72為例作說明,實施上辅 助封接條53與辅助吸濕體72設置的組數可視需要增加, ,如可多組設置而依序由內往㈣繞在發光單元*外部, 藉此提供更多重的防潮效果。 歸納上述,本發明有機電激發光裳置中用來提供防潮 之相關結構’如接合單元5各構件、封蓋6之環溝61與辅 20 助%溝62 ’及該等吸濕體71、72,皆位在發光單元4之外 圍位置’不會影響封蓋6的平整度、透光率及強度,因此 不僅發光單元4可往下由基板3側發光顯示,也可往上從 封盍6側發光顯示,故確實能達到發明之目的。 5 10 15 20 1241860 准乂上所述者,僅為本發明之四較佳實施例而已,當 不能以此限定本發明實施之範圍,即大凡依本發明申請專 利範圍及發明說明書内容所作之簡單的等效變化與修倚, 皆應仍屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 圖1是習知有機電激發光裝置之簡略正視剖面圖; ”圖2是本發明有機電激發光裝置的第一較佳實施例之 簡略正視剖面圖; 圖3是圖2沿線羾—皿的剖面圖; "圖4是本發明有機電激發光褒置的第二較佳實施例之 簡略正視剖面圖; 圖5是圖4之V-V剖面圖; ★圖6是-類似圖5之視圖,說明本發明有機電激發光 裝置的第三較佳實施例; 圖7是本發明有機電激發光裝置的第四較佳實施例之 簡略正視剖面圖;及 圖8是圖7沿線Μ -Μ的剖面圖。 10 1241860 【圖式之主要元件代表符號說明】 3…… …基板 5 3…… 輔助封接條 4 · …發光單元 6……… 封蓋 /j 1 β ★ …有機電激發光二極體 1 * 忒 * # # 環溝 5 -接合單元 62…… 輔助環溝 51 — -主封接條 7卜…“ 主吸濕體 52 *… "内接合條 72…… 輔助吸濕體 521 - …缺口 8........ 密閉空間1241860 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to an organic electroluminescence device, in particular to an organic electroluminescence device Q with a moisture-proof structure. [Previous technology] General organic electroluminescence device The basic structure, as shown generally in Figure 1, is a light-emitting unit 22 covered with a top surface of a substrate 21 made of glass or transparent plastic. The light-emitting unit 22 is an organic electroluminescent diode arranged in a matrix pattern. The body 221 (〇rganic Ught-Emitting Diode, abbreviated as 0LED), for the overall light-emitting device, each 〇LED is-can be controlled by day and night (pixel), because the basic structure of 〇LED has been related It is well-known in the industry 'the following will not be disclosed and explained in detail. Excluding that if the LED in the light-emitting unit 22 is affected by moisture, it will easily affect the operation function. Therefore, in order to prevent the light-emitting unit 22 from being affected by moisture, a (long) box-shaped rubber strip 23 is glued on the top surface of the substrate 21, The glue strip 23 is enclosed and surrounded around the light-emitting unit 22, and a cover 24 is used to join the top surface of the glue strip 23, so that the light-emitting unit 22 is closed in the enclosed space surrounded by the substrate 21, the cover 24 and the glue strip 23 Within 20. In addition, the light-emitting device further forms a cavity 241 on the bottom surface of the cover 24 facing the light-emitting unit 22, and installs a moisture-absorbing layer 25 containing a hygroscopic agent in the cavity 241. The moisture-absorbing layer 25 absorbs moisture to ensure light emission. The unit 22 is not affected by moisture. The structure design of the conventional organic electro-excitation light device equipped with a moisture absorption layer 25 can achieve the effect of preventing the light-emitting unit 22 from being wet, but because the σ of the moisture absorption layer 25 is placed again, it must be opened on the bottom surface of the cover 24 The recesses 241 and 1241860 are generally made of sand or _, which causes the flatness, light transmittance, and processing of the cover 24, and the moisture absorption layer 25 itself will block the light. These factors are not good for The light emitting unit 22 is issued from this side, that is, only the substrate 21 side is suitable as the light emitting surface, and the cover 24 side is not suitable. [Summary of the Invention] In view of this, the object of the present invention is to provide an organic electrical excitation device provided with a moisture-proof structure that does not affect the flatness, light transmittance and strength of the cover. ίο 15 Yu Li, the organic electroluminescent device of the present invention includes: a substrate, a cover located above the substrate, and a connection between the silk-bonded substrate and the cover: Zao Fan, "a light-emitting unit coated on the substrate And a main hygroscopic body for absorbing water vapor. The light-emitting unit is covered on the top surface of the substrate and includes an organic electroluminescent diode arranged in a matrix pattern. The bonding unit includes a fixed connection Fortunately, the main board seals the door of the substrate tray. + 7 The main seal of the package and the seal, the main seal is enclosed around the light-emitting unit. The cover is located at the light-emitting unit. Above, the cover and the base plate and the main sealing strip jointly define a closed space. The main suction unit H m and the wet body are fixed on the bottom surface of the cover, and are located in the space and surround the light. Around the unit. The effect of the present invention is that the main absorbent body is provided around the periphery of the light-emitting unit to provide a very good hygroscopic effect without affecting the luminosity and intensity of the cover. X, transparent [Embodiment], ~ / 入Six points of Liutazishu, pay a little bit of effect, In the following detailed description of the four light-duplex slave embodiments with reference to the drawings, 20 1241860 will be clearly understood. As shown in FIGS. 2 and 3, the embodiment of the organic electroluminescence device of the present invention includes a substrate 3 , Shibian + Lebananjia 4 peddle 3, a light-emitting unit covered on the substrate 3: a multi-port joint single Fan 5,-a sealing disc 6 fixed on the joint unit 5, and-for The main moisture absorbing body 71 that absorbs moisture. The sealing substrate 3 can be made of glass or transparent plastic. The finger light prelude 4 includes most of the organic electro-excitation light two-body body arranged in a matrix pattern and covering the top surface of the substrate 3. 41. These organic electro-excitation light-emitting diodes 15 1 are usually coated on the substrate 3 in a thorough manner. 5 Including—the main body glued to the top surface of the substrate 3 = 51. In this embodiment, the main body The sealing strip 51 is in the shape of a rectangular frame f: the thickness is much larger than the thickness of the light-emitting sheet & 4, and is spaced around the light-emitting element 4. The cover 6 is a main seal fixed to the joint unit 5. The top surface of the connection strip M is above the light emitting unit 4. The cover 6 and the substrate 3 and the main sealing strip 51 together define a — In the closed jade room 8. In addition, the cover 6 is flat and the side is flat, and the material of the cover 6 can be glass or ceramic: "or plastic and has a ring groove 61 recessed on its bottom surface, the ring groove It is not necessary for the niche to be continuous in the closed space 8 and surround the annular groove 61. The door ㈤ The main absorbent body 71 is fixedly received in the ring groove 61 of the cover 6 and surrounds the light-emitting single opening. The main absorbent body 71 is capable of absorbing water vapor by solid, two: large, and wet materials' to prevent the enclosed space from being wet by the light emitting unit 4 due to the water vapor. 20 ίο 15 20 1241860 By means of this, the distribution of the main absorbent body 71 in this embodiment is around the near edge of the closed space 8 and is located on the periphery of the light-emitting unit *, so it can be invaded by external moisture. When the air space 8 is absorbed by the main absorbent body 71 immediately, the light-emitting unit 4 can be more effectively prevented from being wet. 'Because the main moisture absorption body 71 is arranged around the periphery of the light emitting sheet S 4, that is, the bottom of the cover 6 corresponding to the light emitting unit 4 is not opened: it affects the flatness, light transmittance and intensity. It has a cavity structure, so not only Mao Guangdan 70 4 can emit light from the substrate 3 side down, but also upward from the cover 6 side, that is, the entire organic electrical excitation light I can be applied through this setting. The display on the substrate surface or cover surface or on both sides has indeed: Know the disadvantages of the design. " As shown in FIGS. 4 and 5, the second preferred embodiment of the organic electro-optical excitation device of the present invention is different from the aforementioned first embodiment in that the bonding unit 5 further includes—bonded to the substrate 3 and the The strips M are joined within 6 of the lids. The main and inner joint strips 52 are in the form of -large-small (long) box-shaped bodies, and the strips 52 are closer to the two first than the main sealing strip 51 and the main absorbent body 71 ... The annular groove 61 on the bottom surface of the cover 6 is interposed between the main sealing strip and the inner joint strip 52, that is, the main absorbent body 71 is between the f strip 51 and the inner joint strip 52. With respect to the light emitting unit 4,. The main absorbent body 71 is also around the periphery of the light emitting unit it 4. With this, when external moisture intrudes into the light-emitting unit 4, the sealing strip 51 of the sealing strip 51 passes through the main body after passing through the main body ... When the moisture—through the main sealing strip Η, blocks; in the main: the main absorbent body 71 to absorb, and the inner jointing strip 52 inside the main absorbent body 71 'can further enhance the effect of blocking moisture. 24186〇, 7 of FIG. 6 " " " " " " " " " " " " " " " " " " " That is to say, the design / requirement / article 52 is not enclosed in the main absorbent body 7 丨 the inner circumference is absolutely 10 15 ^ As shown in FIGS. -7 and 8, the fourth preferred organic electroluminescent device of the present invention The difference between the first embodiment and the second embodiment lies in that: the organic electro-excitation light-emitting junction contains an auxiliary moisture absorbing body 72, and the bottom surface of the cover 6 is further recessed with a long box-shaped auxiliary ring groove surrounding the main sealing strip 51. 62. The auxiliary ring ^ is used to receive the auxiliary absorbent body 72. In addition, the bonding unit 5 ^ includes an auxiliary sealing strip ^ bonded between the substrate 3 and the cover 6, and the auxiliary sealing strip 53 surrounds the periphery of the auxiliary ring groove 62 at intervals. Assist 21b 7 The external moisture wants to invade the secret element 4, and it must pass through the auxiliary sealing strip 51 after the moisture. When the moisture passes through the auxiliary sealing strip 53 and the main sealing strip 51, it will pass through the auxiliary absorbent body 72 respectively. It absorbs with the main thirsty body '. Therefore, the design of this embodiment has a dual moisture absorption effect, and can significantly improve the moisture-proof effect of the light-emitting unit 4. It must be further explained here that in this embodiment, a set of auxiliary sealing strips 53 and auxiliary absorbent bodies 72 are provided as an example, and the implementation of the upper auxiliary sealing strips 53 and auxiliary absorbent bodies 72 is provided. The number of groups can be increased as required. For example, multiple groups can be set up to surround the light-emitting unit * from the inside in order to provide more heavy moisture-proof effects. To sum up, the related structures of the organic electro-excitation light of the present invention for providing moisture resistance are provided, such as each component of the joint unit 5, the ring groove 61 and auxiliary 20 of the cover 6, and the moisture absorbent body 71, 72, all of them are located at the periphery of the light-emitting unit 4 'will not affect the flatness, light transmittance and intensity of the cover 6, so not only the light-emitting unit 4 can be displayed downward from the substrate 3 side, but also upward from the seal 6-sided light-emitting display, so it can indeed achieve the purpose of the invention. 5 10 15 20 1241860 Those mentioned above are only the four preferred embodiments of the present invention. When the scope of implementation of the present invention cannot be limited by this, that is, what is simple according to the scope of patent application and the content of the invention specification The equivalent changes and modifications should still fall within the scope of the invention patent. [Brief description of the drawings] FIG. 1 is a schematic front cross-sectional view of a conventional organic electroluminescent device; “FIG. 2 is a schematic front cross-sectional view of a first preferred embodiment of the organic electroluminescent device of the present invention; 2 is a cross-sectional view along the line; " FIG. 4 is a schematic front sectional view of a second preferred embodiment of the organic electro-excitation light arrangement of the present invention; FIG. 5 is a VV sectional view of FIG. 4; A view similar to FIG. 5 illustrates a third preferred embodiment of the organic electroluminescent device of the present invention; FIG. 7 is a schematic front sectional view of a fourth preferred embodiment of the organic electroluminescent device of the present invention; and FIG. 8 is a diagram 7 A cross-sectional view taken along the line M-M. 10 1241860 [Description of the symbols of the main elements of the drawing] 3 ……… substrate 5 3 …… auxiliary sealing strip 4 ·… lighting unit 6 ………… cover / j 1 β ★ … Organic electro-excitation light-emitting diode 1 * # * # # 环 沟 5 -joining unit 62 ...... Auxiliary ring groove 51 — -Main sealing strip 7… “Main absorbent body 52 *… " Inner bonding strip 72… … Auxiliary absorbent body 521-… gap 8 ... confined space

Claims (1)

1241860 第093107004號案申謗幸种 拾、申請專利範圍 1. 一種有機電激發光裝置,包含: 一基板; 一發光單元’被覆在該基板頂面,並包括有多數矩 陣型態排列之有機電激發光二極體; -接合單元,包括有固接在該基板頂面之 條’该主封接條與内接合條是間隔封閉圍 :在:…元周圍,且該内接合條相對於該 疋較接近該發光單元; :,固接在該接合翠元之主封接條與内接合條 頂=且間隔位在該以單元上方,該封蓋並與該基板 、以封接條共同界定出一密閉空間且該封蓋具有一 ::於其底面之環溝’該環溝是圍繞在該發光單元周圍 並"於該主封接條與該内接合條間;及 2. -可吸收水氣之主吸濕體,固定在該封蓋底面之環 溝内,而圍繞在該發光單元周圍。 ,據申,專利簡第丨項所述之有機電激發光I置,其 ’该接合單元之内接合條上具有多數内外貫通之缺口 〇 “ 2專利範圍第1或2項所述之有機電激發光裳置 σ、、匕3有固定在該封蓋底面之輔助吸濕體,該輔助 L元體=圍繞在该接合單元之主封接條外圍,且該接合 更包括有一接合於基板與封蓋間之輔助封接條,該 助封接條是圍繞在該辅助吸濕體外圍。 12 1241860 4.依據申請專利範圍第3項所述之有機電激發光裝置,其 中,該封蓋底面更凹陷有一圍繞在該主封接條外圍之輔 助環溝,該輔助吸濕體便是容置在該輔助環溝内。1241860 Case No. 093107004 claims the scope of patent application and application scope 1. An organic electroluminescent device, comprising: a substrate; a light-emitting unit 'covered on the top surface of the substrate, and includes an organic electrical device arranged in a majority of matrix types Excitation light diode;-a bonding unit including a strip fixed on the top surface of the substrate; the main sealing strip and the inner bonding strip are spaced and enclosed: around: the element, and the inner bonding strip is opposite to the 疋Closer to the light-emitting unit;: The top of the main sealing strip and the inner bonding strip fixedly connected to the bonding Cuiyuan = and the spacing is above the above-mentioned unit, and the cover is defined together with the substrate and the sealing strip An enclosed space and the cover has a: a ring groove on its bottom surface, the ring groove is surrounding the light emitting unit and " between the main sealing strip and the inner joint strip; and 2.-absorbable The main moisture-absorbing body of water and gas is fixed in a ring groove on the bottom surface of the cover, and surrounds the light-emitting unit. According to the application, the organic electro-excitation light described in item 丨 of the patent summary has the majority of internal and external gaps in the internal bonding strips of the bonding unit. “2 The organic power described in item 1 or 2 of the patent scope The excitation light set σ, and D3 have auxiliary absorbent bodies fixed on the bottom surface of the cover. The auxiliary L element body = surrounds the periphery of the main sealing strip of the bonding unit, and the bonding further includes a bonding to the substrate and The auxiliary sealing strip between the cover and the auxiliary sealing strip surrounds the periphery of the auxiliary absorbent body. 12 1241860 4. The organic electro-optical light-emitting device according to item 3 of the scope of patent application, wherein the bottom surface of the cover Furthermore, there is an auxiliary ring groove surrounding the periphery of the main sealing strip, and the auxiliary absorbent body is accommodated in the auxiliary ring groove. 1313
TW93107004A 2004-03-16 2004-03-16 Organic light-emitting device TWI241860B (en)

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