TWI238548B - Light emitting diode and method of making the same - Google Patents

Light emitting diode and method of making the same Download PDF

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TWI238548B
TWI238548B TW93111727A TW93111727A TWI238548B TW I238548 B TWI238548 B TW I238548B TW 93111727 A TW93111727 A TW 93111727A TW 93111727 A TW93111727 A TW 93111727A TW I238548 B TWI238548 B TW I238548B
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layer
ohmic contact
light
metal electrode
patent application
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TW93111727A
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TW200417067A (en
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Jin-Ywan Lin
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United Epitaxy Co Ltd
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Abstract

A light emitting diode (LED) having two electrodes at the same side and altitude is disclosed. The LED includes a high reflective metal layer therein to reflect those lights emitted from the active layer toward it, an electrical connecting plug, and an isolation channel. The electrical connecting plug connects the first ohmic contact electrode which is buried in the LED structure to the outer surface of the lower cladding layer. The isolation channel spaced the LED from two parts. The first part has the electrical connecting plug and the second part has a second ohmic contact electrode formed on the lower cladding layer. The active layer in the second part actives after a voltage is applied.

Description

1238548 五、發明說明(1) 【發明所屬之技術領域】 本發明係關於一種發光二極體(Light Emitting D i ode ; LED )晶片結構及其製造方法,特別是一種有關磷 化鋁鎵銦(AlGalnP)發光二極體之結構及其製造方法。 【先前技術】 傳統的磷化鋁鎵銦發光二極體具有一雙異質結構 (Double Heterostructure; DH),其構造如第 5圖所示, 是在一 η型神化鎵(GaAs)基板(Substrate)5 2上,先形成一 緩衝層54,再成長一鋁含量在70%-100 %的η型(A1 XG a u) 〇51〇〇.5?之下包覆層58、一(八1乂〇31-乂)〇51。〇.5?之活性層60、一 鋁含量在70%-100%的p型(AlxGaHUdnuP之上包覆層62, 以及一 P型高能隙的電流分散層(Current Spreading Layer) 64,這一層的材料可以是磷化鎵、磷砷化鎵、磷化 銦鎵或碎化紹鎵等。 藉著改變活性層6 0的組成,便可以改變發光二極體發 光波長,使其產生從6 5 0 n m紅色至5 5 5 n m純綠色的波長。但 此一傳統的發光二極體有一缺點,就是活性層產生的光, 往下入射至砷化鎵基板5 2時,由於砷化鎵基板5 2的能隙較 小,因此入射至砷化鎵基板5 2的光將會被吸收掉,而無法 產生高效率的發光二極體。 為了避免基板5 4的吸光,傳統上有一些文獻揭露出1238548 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a light emitting diode (Light Emitting Diode; LED) wafer structure and a manufacturing method thereof, and particularly to an aluminum gallium indium phosphide ( AlGalnP) structure and manufacturing method of light emitting diode. [Prior technology] The traditional aluminum gallium indium light emitting diode has a double heterostructure (Double Heterostructure; DH), and its structure is shown in FIG. 5, which is an n-type gallium (GaAs) substrate (Substrate). On 2 2, a buffer layer 54 is formed first, and then a cladding layer 58 having an aluminum content of 70% to 100% (A1 XG au) 〇51〇 0.5 is formed. 31-i) 〇51. 0.5? Active layer 60, a p-type (AlxGaHUdnuP cladding layer 62 above 70% -100% aluminum content), and a P-type high-gap current spreading layer 64 (Current Spreading Layer). The material can be gallium phosphide, gallium phosphide arsenide, indium gallium phosphide, or shattered gallium, etc. By changing the composition of the active layer 60, the light emitting diode light emission wavelength can be changed, so that the light emitting diode emits light from 6 50 The wavelength from nm red to 5 5 5 nm pure green. However, this traditional light-emitting diode has a disadvantage, that is, the light generated by the active layer is incident on the gallium arsenide substrate 5 2 because the gallium arsenide substrate 5 2 The energy gap is relatively small, so the light incident on the gallium arsenide substrate 52 will be absorbed, and a high-efficiency light-emitting diode cannot be generated. In order to avoid the light absorption of the substrate 54, some literatures have been exposed conventionally.

第6頁 1238548 五、發明說明(2) LED的技術,然而這些技術都有其缺點以及限制。例如 Sugawara 等人發表於[Appl· Phys Lett. Vol. 6 卜 1 775-1 7 7 7 ( 1 9 9 2 )]便揭示了 一種利用加入一層分散布拉格反射 層 54(Distributed Bragg Reflector; DBR)於砷化鎵基板 上,藉以反射入射向砷化鎵基板的光,並減少砷化鎵基板 吸收,然而由於D B R反射層5 4祇對於較接近垂直入射於砷 化鎵基板的光能有效的反射,因此效果並不大。Page 6 1238548 V. Description of the invention (2) LED technology, however, these technologies have their disadvantages and limitations. For example, Sugawara et al. [Appl. Phys Lett. Vol. 6 Bu 1 775-1 7 7 7 (1 9 9 2)] revealed a method of adding a distributed Bragg reflector 54 (Distributed Bragg Reflector; DBR) in On the gallium arsenide substrate, the light incident on the gallium arsenide substrate is reflected, and the absorption of the gallium arsenide substrate is reduced. However, since the DBR reflective layer 54 can effectively reflect only the light incident on the gallium arsenide substrate perpendicularly, So the effect is not great.

Kish等人發表於[Appl· Phys Lett. Vol. 64,Kish et al. [Appl · Phys Lett. Vol. 64,

No· 21,2839, ( 1 9 94 )之文獻,名稱為「Very high- f| efficiency semi conductor wafer-bonded transparent-substrate (AlxGahDuInuP/GaP」,揭示一種黏接晶圓 (Waier bonding)之透明式基板(Transparent-Substrate; TS) (AlxGaduInuP/GaP發光二極體。這種 丁 S A 1 G a I η P L E D係利用氣相磊晶法(v P E )而形成厚度相當 厚(約50/z m)之P型鱗化鎵(GaP)窗戶(Window)層,然後再以 習知之化學蝕刻法,選擇性地移除N型砷化鎵(GaAs)基 板。接著將此曝露出之N型(AlxGai_x)Q.5InQ 5p下包覆層,黏 接至厚度約為8 - 1 0 m i 1之η型磷化鎵基板上。 0 由於此晶圓黏接(Wafer Bonding)是將二種I I I—V族 化合物半導體直接黏接在一起,因此要在較高溫度下,加 熱加壓一段時間才能完成。就發光亮度而言,以這種方式 所製得之TS A 1 Gal nP LED,比傳統吸收式基板The document No. 21, 2839, (19 94), entitled "Very high-f | efficiency semi conductor wafer-bonded transparent-substrate (AlxGahDuInuP / GaP"), reveals a transparent type of wafer bonding Substrate (Transparent-Substrate; TS) (AlxGaduInuP / GaP light-emitting diode. This type of SA 1 G a I η PLED is formed by vapor phase epitaxy (v PE) to form a relatively thick (about 50 / zm) P-type scaled gallium (GaP) window layer, and then using conventional chemical etching method to selectively remove N-type gallium arsenide (GaAs) substrate. Then exposed N-type (AlxGai_x) Q .5InQ 5p lower cladding layer, adhered to the η-type gallium phosphide substrate with a thickness of about 8-10 mi 1. 0 Because this wafer bonding (Wafer Bonding) is a combination of two III-V compound semiconductors It is directly bonded together, so it can be completed by heating and pressing at a higher temperature for a period of time. In terms of luminous brightness, the TS A 1 Gal nP LED prepared in this way is more efficient than traditional absorption substrates

第7頁 1238548 五、發明說明(3) (Absorbing-Substrate; AS)AlGaInP LED其亮度大兩倍以 上。然而,這種TS A 1 Gal nP LED的缺點就是製造過程太過 繁雜,且通常會在接合界面具有一非歐姆接點的高電阻特 性,因此,無法獲得高生產良率且難以降低製造成本。 另一種傳統技術,例如Η 〇 r n g等人發表於[A p p 1 ·Page 7 1238548 V. Description of the invention (3) (Absorbing-Substrate; AS) AlGaInP LED has more than twice the brightness. However, the disadvantage of this TS A 1 Gal nP LED is that the manufacturing process is too complicated, and usually has a high resistance characteristic of a non-ohmic contact at the bonding interface. Therefore, it is impossible to obtain a high production yield and it is difficult to reduce the manufacturing cost. Another traditional technique, for example, 〇〇 r ng et al. [A p p 1 ·

Phys· Lett· ν〇1·75,Νο·20,3 0 54 ( 1 9 9 9 )文獻,名稱為 「AlGal ηP light-emitting diodes with mirror substrates fabricated by wafer bonding」]。Horng等 人揭示一種利用晶片融合技術以形成鏡面基板(Mirr〇r一 Substrate ; MS)磷化鋁鎵銦/金屬/二氧化矽/矽 LED。其 使用AuBe/Au作為黏著材料藉以接合矽基板與LED蠢晶層。 然而’在20mA操作電流下,這種ms A 1 Gal nP LED之發光強 度僅約為90 mcd,仍然比TS AlGalnP LED之發光強度少至 少百分之四十,所以其發光強度無法令人滿意。 、同時,以上述方法所形成的黏接晶圓丨丨丨—化合物 半導體都無法讓電極在同一側,+適合用於發光二極體 串並聯使用。_因此另一種ρ、Ν兩電極位於同一側者,其構 造如第6圖所示,包括一喔砷化鎵(GaAs)基板 ^ ubStrate)52上成長有一緩衝層54,緩衝層“上則依序 疋一紹含量在 70%- 100%的 、 T λ, ^ ^ X a卜X) Q 5Ι η 〇·5P之活性層6 〇、一鋁含量在7 〇〇 〇% 的P型(AlxGaJuIn。sP之上包覆層62,一 p型高能隙的電流Phys · Let · ν〇1 · 75, No. 20, 3 0 54 (1 9 9), and the name is "AlGal ηP light-emitting diodes with mirror substrates fabricated by wafer bonding"]. Horng et al. Have disclosed a method for forming a mirror substrate (mirror-substrate; MS) aluminum gallium indium phosphide / metal / silicon dioxide / silicon LED using wafer fusion technology. It uses AuBe / Au as an adhesive material to bond the silicon substrate and the LED stupid layer. However, at an operating current of 20 mA, the luminous intensity of this ms A 1 Gal nP LED is only about 90 mcd, which is still at least 40% lower than that of TS AlGalnP LEDs, so its luminous intensity is not satisfactory. At the same time, the bonded wafers formed by the above methods 丨 丨 丨 —compound semiconductors cannot have electrodes on the same side, and + is suitable for series and parallel use of light-emitting diodes. _ Therefore, another ρ and N electrodes are located on the same side, and the structure is shown in FIG. 6, which includes a buffer layer 54 grown on a GaAs substrate ^ ubStrate 52. The sequence is a P-type (AlxGaJuIn) with a content of 70% to 100%, an active layer of T λ, ^ ^ X a) Q 5 1 η 0.5 P, and an aluminum content of 7000%. cladding layer 62 on sP, a p-type high-gap current

1238548 五、發明說明(4) 分散層(Current Spreading Layer)64,這一層的材料可 以是磷化蘇、碟坤化鎵、碗化銦鎵或砰化銘鎵等。p型高 能隙的電流分散層6 4上則有一 P型歐姆接觸電極7 0及一金 屬釘線層7 4。另一 N型歐姆接觸電極7 0及一金屬釘線層則 形成於發光二極體之已被蝕刻成溝渠以裸露下包覆層5 8之 上。本發明所提供的發光二極體可以解決上述的問題。 【發明内容】 综上所述’本發明提供一種發光二極體結構,其結構 包括一具有一發光層的多層蟲晶結構,藉由一黏接層與一 高導熱基板相結合。此二極體之發光層可為同質結構 (Homostructure)、單異質結構(Single heterostructure’ SH)、雙異質結構(Double heterostructure’ DH)或多重量子井結構(Multi quantum we 1 1 s,MQWs ) 〇 發光二極體結構亦包括第一歐姆接點金屬電極層和第 二歐姆接點金屬電極層。第一歐姆接點金屬電極層藉由電 極連接通道與第一金屬釘線電極層連接,第二金屬釘線電 極層在第一歐姆接點金屬電極層上方,利用隔絕溝渠或隔 絕島方式,使得第一金屬釘線電極層與第二金屬釘線電極 層在相對於是位於高導熱性與高反射率之基板同一側。且 由於有電極連接通道,而使得第一金屬釘線電極層與第二 金屬釘線電極層有相同高度水平。1238548 V. Description of the invention (4) Dispersion layer (Current Spreading Layer) 64. The material of this layer can be phosphide, gallium disc, gallium indium, or gallium. A p-type high-gap current dispersing layer 64 has a P-type ohmic contact electrode 70 and a metal pin layer 74. Another N-type ohmic contact electrode 70 and a metal pin line layer are formed on the light-emitting diode which has been etched into a trench to expose the lower cladding layer 58. The light emitting diode provided by the present invention can solve the above problems. [Summary of the Invention] In summary, the present invention provides a light-emitting diode structure, which includes a multi-layered worm crystal structure having a light-emitting layer, and is combined with a highly thermally conductive substrate through an adhesive layer. The light emitting layer of the diode may be a homostructure (Single heterostructure 'SH), a double heterostructure (DH), or a multiple quantum well structure (Multi quantum we 1 1 s, MQWs). The light emitting diode structure also includes a first ohmic contact metal electrode layer and a second ohmic contact metal electrode layer. The first ohmic contact metal electrode layer is connected to the first metal nail line electrode layer through an electrode connection channel, and the second metal nail line electrode layer is above the first ohmic contact metal electrode layer. The first metal nail electrode layer and the second metal nail electrode layer are located on the same side of the substrate with high thermal conductivity and high reflectivity. And because there are electrode connection channels, the first metal nail electrode layer and the second metal nail electrode layer have the same height level.

第9頁 1238548 五、發明說明(5) 此外’本發明更提供上述發光二極體之製造方法。首 先’在一暫時基板上依序形成發光二極體磊晶堆疊層,接 著在系晶堆疊層的最上層上形成第一歐姆接點金屬電極層 與问反射率金屬層。接著,藉由一黏接層,如金屬黏接層 如 In、Au、A 卜 Ag等金屬或 BCB(B-staged bisbenzocyclobutene; BCB)等樹脂,將發光二極體磊晶 層上的高反射率金屬反射層與一高導熱性基板上的非導電 型介電層相結合,再移除發光二極體之暫時基板及蝕刻終 止層。 緊著,進行兩階段钮刻,第一階段形成—電極連接通 道刻寬約1〜3mi Is的通道,蝕刻至第一歐姆接點 電極層,用以與第一歐姆接點金屬電極層相通。第二/ 係隔絕溝渠或隔絕島勉刻,蚀刻寬約〇.2〜lmU,爸^ ▲吾^ 分或全部第-導電型磊曰:層。使第一歐姆接點金屬“極的 電流會經過活化層流到第二歐姆接點金屬電極芦, 來,形成第一金屬釘線電極層,讓第一金屬釘& : 第一歐姆接點金屬電極層相通❶最後再形成第二 ^ 金屬電極層和第二金屬釘線電極層。 胃按μ 本發明之一項優點,為採用隔絕溝渠或隔 讓第一金屬釘線電極層和第二金屬釘線電極層^ 在同一側且相同高度。 j深电極Page 9 1238548 V. Description of the invention (5) In addition, the present invention further provides a method for manufacturing the above-mentioned light emitting diode. First, a light emitting diode epitaxial stacked layer is sequentially formed on a temporary substrate, and then a first ohmic contact metal electrode layer and an inter-reflectivity metal layer are formed on the uppermost layer of the system crystal stacked layer. Next, by using an adhesive layer, such as a metal adhesive layer such as In, Au, Ag or other metals, or a resin such as BCB (B-staged bisbenzocyclobutene; BCB), the high reflectance on the epitaxial layer of the light emitting diode is high. The metal reflective layer is combined with a non-conductive dielectric layer on a highly thermally conductive substrate, and then the temporary substrate and the etch stop layer of the light emitting diode are removed. Tightly, two-step button engraving is performed, and the first stage is formed-the electrode connection channel is etched with a channel having a width of about 1 to 3 mi Is, and is etched to the first ohmic contact electrode layer to communicate with the first ohmic contact metal electrode layer. The second / is an isolated trench or isolated island, and the etching width is about 0.2 ~ lmU, Da ^ ▲ ^ ^ points or all of the first-conductive type Lei: layer. The current of the first ohmic contact metal electrode will flow through the activation layer to the second ohmic contact metal electrode, to form a first metal nail wire electrode layer, and let the first metal nail &: The metal electrode layers communicate with each other, and finally a second metal electrode layer and a second metal nailed wire electrode layer are formed. According to one of the advantages of the present invention, the first metal nailed wire electrode layer and the second metal nailed wire are isolated by using a trench or a barrier. Metal nail electrode layers ^ are on the same side and the same height.

1238548 五、發明說明(6) 本發明之另一項優點,可以利用隔絕溝渠或隔絕島方 式,不會有傳統整個第一蝕刻區表面粗糙,造成傳統直 接釘線封裝時,不易辨識的問題。 本發明之再一項優點,為製程簡單,因此可獲得高良 率與低成本之量產結果。 本發明之再一項優點,為第一歐姆接點金屬電極層 形成後,再藉由通道連接可以得到較佳且穩定的光電特 性,在相同定電流下,有較小的電壓,較好的電流分佈, 以及較佳發光效益。 【實施方式】 本發明揭露一種發光二極體結構及其製造方法。為了 使本發明之敘述更加詳盡與完備,可參照下列描述並配合 第1圖至第4圖之圖示。 首先請先參照第1圖,本發明發光二極體之磊晶結構 包括依序堆疊之N型砷化鎵(G a A s )基板2 4、蝕刻終止層 (Etching Stop Layer) 22、N型磷化鋁鎵銦(A1XG a 卜 X) 〇.5111().5?之下包覆((:13(1(1丨11运)層2 0與磷化鋁鎵銦(六1{314) 〇. 5Ι η 〇· 5P之活性層(Ac t i ve Lay er ) 1 8,P型磷化鋁鎵銦 (A 1 xGa η) 〇 5I n 〇.5P之上包覆層1 6以及P型歐姆接點蠢晶層 (Ohmic Contact EpitaXial Layer)14。接著,在 p型歐姆 接點磊晶層1 4上形成P型歐姆接點金屬電極層3 〇。1238548 V. Description of the invention (6) Another advantage of the present invention is that it can use the method of isolating trenches or isolating islands, without the traditional rough surface of the entire first etched area, which makes it difficult to identify the conventional direct-line package. Still another advantage of the present invention is that the manufacturing process is simple, so that high-yield and low-cost mass production results can be obtained. Another advantage of the present invention is that after the formation of the first ohmic contact metal electrode layer, better and stable photoelectric characteristics can be obtained through the channel connection. Under the same constant current, there is a smaller voltage, which is better. Current distribution, and better luminous efficiency. [Embodiment] The present invention discloses a light emitting diode structure and a manufacturing method thereof. In order to make the description of the present invention more detailed and complete, reference may be made to the following descriptions in conjunction with the diagrams in FIGS. 1 to 4. First, please refer to FIG. 1. The epitaxial structure of the light-emitting diode of the present invention includes an N-type gallium arsenide (G a As s) substrate 2 that is sequentially stacked. 4. Etching Stop Layer 22, N-type Aluminum Gallium Indium Phosphide (A1XG a Bu X) 〇.5111 (). 5? Clad ((: 13 (1 (1 丨 11)) Layer 2 0 and Aluminum Gallium Indium Phosphide (Six 1 {314) 〇 5 5 η 〇 5P active layer (Ac ti ve Lay er) 1 8, P-type aluminum gallium indium phosphide (A 1 xGa η) 〇5I n 〇5P overlying layer 16 and P-type ohms Ohmic Contact EpitaXial Layer 14. Next, a P-type ohmic contact metal electrode layer 30 is formed on the p-type ohmic contact epitaxial layer 14.

1238548 五、發明說明(7) P型歐姆接點蠢晶層1 4之材料可以是石申化銘鎵、碟化 銘鎵銦或磷砷化鎵,祇要其能隙大於活性層1 8,不會吸收 活性層產生的光,但又必須具有高載子濃度,以利於形成 歐姆接點,便可以選擇為P型歐姆接點磊晶層i 4。 上述之活性層18,其鋁含量的範圍是在χ = 0〜〇·45,而 上、下包覆層其鋁含量約控制在χ = 〇·卜丨· 〇,當活性層2〇 的叙含量Χ = 0時,活性層的組成是Ga() 5lnQ 5Ρ,而發光二極 體的波長;I d約是在6 3 5nm。 上述化合物之比例,例如活性層(AlxGaix)()5ln()5PMj| 是¥出一較佳例子,並非用以限制本發明,本發明同樣適 用於其他的比例。此外在本發明中,A丨Ga j np活性層丨8之 結構可以是採用傳統的同質結構(H〇ni〇structure),單異 質結構(Single Heterostructure),雙異質結構(D〇uble Heterostructure; DH)或是多重量子井(Multiple Quantum Well; MQW)。 在本發明中#刻終止層22之材質可以 元素之化合物半導體,祇要其晶格常 7 m 24相匹配以免產生差排,且蝕刻速率 1 =和砷化鎵基板 質所組成之基板2 4,便可以當作蝕刻故=^於由坤化嫁物 終止層2 2。1238548 V. Description of the invention (7) The material of the P-type ohmic contact stupid crystal layer 14 can be Shishenming Ga, Gaoxing Indium, or GaAs, as long as its energy gap is greater than that of active layer 18, it will not absorb The light generated by the active layer, but must have a high carrier concentration to facilitate the formation of ohmic contacts, can be selected as the P-type ohmic contact epitaxial layer i 4. The aluminum content of the above active layer 18 is in the range of χ = 0 to 0.45, and the aluminum content of the upper and lower cladding layers is controlled to be about χ = 〇 · 卜 丨 · 〇. When the content X = 0, the composition of the active layer is Ga () 5lnQ 5P, and the wavelength of the light-emitting diode; I d is about 6 3 5nm. The ratio of the above compounds, such as the active layer (AlxGaix) () 5ln () 5 PMj| is a preferred example, and is not intended to limit the present invention, and the present invention is equally applicable to other ratios. In addition, in the present invention, the structure of the A 丨 Ga j np active layer 丨 8 may be a conventional homostructure (Single Heterostructure), a single heterostructure (Single Heterostructure), or a double heterostructure (Duoble Heterostructure; DH). ) Or Multiple Quantum Well (MQW). In the present invention, the material of the #etched stop layer 22 may be an elemental compound semiconductor, as long as its lattice is often 7 m 24 to avoid differential rows, and the etching rate is 1 = the substrate 24 composed of a gallium arsenide substrate. It can be regarded as an etching process, so it can be used as the etching stopper layer 2 2 by Kunhua.

1238548 五、發明說明(8) 在本發明中蝕刻終止層2 2之較佳材質可為磷化銦鎵 (I n G a P )或坤化銘鎵(a 1 (j a A s )。在本實施例n型鱗化鋁鎵銦 下包覆層2 0的蝕刻速率也遠低於砷化鎵基板2 4。因此,祇 要其厚度較厚,也可以不需要另一層組成不同的磊晶層來 當作钱刻終止層。 接著,提供如第2圖所示之結構,此結構包括黏接層 44、 電層42、一兩導熱性基板40。黏接層44可為金屬 黏接層’如In、Au、Ab Ag等金屬或非金屬黏接層,如 BCB(B-staged bisbenzocyclobutene; BCB)樹脂。高導熱 =基板4 0可以是如矽(s i)晶片、碳化矽(s 士 c )晶片、磷化 鎵(GaP)晶片或Au、Al、Cu金屬等當中的一種,高反射率 金屬層,則可以是Ag、 A卜 Au等當中的一種。 接著將第1圖已形成P型歐姆接點金屬電極層3〇的發光 二極體晶片及第2圖的高導電性與高反射率基板4 〇葬由黏 接層44黏在…黏著好的蟲晶片,接著以腐餘液猎(:黏 51^04:311 20 2:3 11 20或是1〇 4011:3 5 11 20 2)腐#,將不透光的_ 砷化鎵基板24除去。蝕刻終止層22如果採用in(jap41238548 V. Description of the invention (8) In the present invention, a preferred material for the etching stop layer 22 may be indium gallium phosphide (I n G a P) or Kunhuaming gallium (a 1 (ja A s)). The etching rate of the n-type scaled aluminum gallium indium lower cladding layer 20 is also much lower than that of the gallium arsenide substrate 24. Therefore, as long as the thickness is thick, another epitaxial layer with a different composition may not be needed. It is used as a money engraving termination layer. Next, a structure as shown in FIG. 2 is provided, which includes an adhesive layer 44, an electrical layer 42, and a thermally conductive substrate 40. The adhesive layer 44 may be a metal adhesive layer, such as In, Au, Ab Ag and other metal or non-metal adhesive layers, such as BCB (B-staged bisbenzocyclobutene; BCB) resin. High thermal conductivity = substrate 40 can be such as silicon (si) wafers, silicon carbide (s + c) wafers , Gallium phosphide (GaP) wafer or Au, Al, Cu metal, etc., and the high reflectivity metal layer, it can be one of Ag, A, Au, etc. Then the P-type ohmic connection has been formed in Figure 1 The light-emitting diode wafer of the point metal electrode layer 30 and the high-conductivity and high-reflectivity substrate 4 of FIG. 2 are adhered by the adhesive layer 44. Good adhesion Insect wafers, then hunt with humid liquid (: sticky 51 ^ 04: 311 20 2: 3 11 20 or 104011: 3 5 11 20 2) rot # to remove the opaque _ gallium arsenide substrate 24 .Etch stop layer 22 if in (jap4

AlGaAs仍然會吸收活性層18產生的光。因此,也必須以腐 蝕液完全除去,或祇留下與N型歐姆接點金屬電極層'36接 觸的部分。 然後,進行兩階段微影及餘刻技術形成隔離通道及p 型歐姆接點金屬電極層3 〇電極連接通道。 1238548 五、發明說明(9) 首先,以微影及蝕刻技術將N型磷化鋁鎵銦下包覆層 2 0、破化紹鎵銦活化層1 8、P型攝化铭鎵銦上包覆層1 6、 及P型歐姆接點蟲晶層1 4依序由上而下餘刻成一暴露出p型 歐姆接點金屬電極層3 0之電極連接通道3 8 A,寬約1〜 3 m i 1。接著’再利用微影及姓刻技術進行第二次姓刻,由 上而下蝕刻至部分P型磷化鋁鎵銦上包覆層1 6 (圖三)被蝕 刻’以形成隔絕溝渠或隔絕島3 8 B,或P型歐姆接點蠢晶層 1 4之底面為止以形成隔絕溝渠或隔絕島3 8 B (圖四),蝕刻 寬度約0 . 2〜1 m i 1。AlGaAs will still absorb light generated by the active layer 18. Therefore, it must also be completely removed with an etchant, or only the portion in contact with the N-type ohmic contact metal electrode layer '36 must be left. Then, two-stage lithography and post-etching techniques are performed to form isolation channels and p-type ohmic contact metal electrode layer 30 electrode connection channels. 1238548 V. Description of the invention (9) First, lithography and etching technology are used to coat the N-type aluminum gallium indium phosphide indium cladding layer 20, break the gallium indium gallium indium activation layer 18, and P-type gallium indium gallium indium. The cladding layer 16 and the P-type ohmic contact worm crystal layer 14 are sequentially engraved from top to bottom to expose an electrode connection channel 3 8 A of the p-type ohmic contact metal electrode layer 30, with a width of about 1 to 3 mi 1. Then 're-use the lithography and surname engraving technique for the second surname engraving from top to bottom to part of the P-type aluminum gallium indium phosphide upper cladding layer 16 (Figure 3) is etched' to form an isolation trench or isolation The island 3 8 B, or the bottom surface of the P-type ohmic contact dummy layer 14 is formed to form an isolation trench or an island 3 8 B (Figure 4), and the etching width is about 0.2 to 1 mi 1.

接著’形成光阻圖案(未圖示)以定義N型歐姆接點金 屬電極層34於N型磷化鋁鎵銦下包覆層20上。請注意光阻 圖案僅於N型磷化鋁鎵銦下包覆層2 〇上有開口以定義N型歐 姆接點金屬電極層3 4位置。其餘部分都被光阻圖案所覆 蓋’包含以光阻填滿隔絕溝渠或隔絕島3 8 B及電極連接通 道3 8 A。隨後再形成n型歐姆接點金屬電極層3 4。最後,再 去除光阻及形成於光阻上的金屬層以定義一 N型歐姆接點 金屬電極層3 4。 ” 隨後,再如同形成N型歐姆接點金屬電極層3 4的方 法’以光阻圖案定義兩個金屬釘線電極層3 6的位置(包含 裸路N型歐姆接點金屬電極層3 4的開口及裸露第一連通道 38A及電極連接通道38A周圍之部分n型磷化鋁鎵銦下包覆 層2 0。、再^將選自鋁或金之釘線金屬層填滿電極連接通道 38A、裸露之N型磷化鋁鎵銦下包覆層2〇上及裸露之n型歐 姆接點金屬電極層34上。因此如圖示,形成了兩個金屬釘Next, a photoresist pattern (not shown) is formed to define an N-type ohmic contact metal electrode layer 34 on the N-type aluminum gallium indium phosphide indium cladding layer 20. Please note that the photoresist pattern only has openings in the N-type aluminum gallium indium phosphide indium cladding layer 20 to define the position of the N-type ohmic contact metal electrode layer 34. The rest are covered by a photoresist pattern, including filling the isolation trench or island 3 8 B with the photoresist and the electrode connection channel 3 8 A. Subsequently, an n-type ohmic contact metal electrode layer 34 is formed. Finally, the photoresist and the metal layer formed on the photoresist are removed to define an N-type ohmic contact metal electrode layer 34. ”Subsequently, the method of forming the N-type ohmic contact metal electrode layer 34 is again defined by using a photoresist pattern to define the positions of the two metal pin electrode layers 36 (including the bare N-type ohmic contact metal electrode layer 34). The opening and the exposed part of the n-type aluminum gallium indium phosphide indium cladding layer 20 surrounding the first connection channel 38A and the electrode connection channel 38A are filled with the electrode connection channel 38A. On the exposed N-type aluminum gallium indium phosphide indium cladding layer 20 and on the exposed n-type ohmic contact metal electrode layer 34. Therefore, as shown in the figure, two metal nails are formed.

第14頁 1238548 五、發明說明αο) 線,極層36在相對於高導熱基板,都在同—側且在同一水 平南度的發光二極體結構,如第3、 4圖所示。 最彳f,再施以退火,以使N型歐姆接點金屬電極層34 與下包覆層20及P歐姆接觸電極3〇與p型歐姆接觸磊晶層形 成良好之歐姆接觸。 "ί Ϊ之步驟順序並非用以限定本發明,任何熟悉相關 技術者虽可將上述之步驟順序做調整。例&,例如隔絕溝 渠或隔絕島38Β的形成步驟便可以移至兩個金屬釘線電極 層36形成後再進行,而不變更本發明之二極體結構。 依據本發明所得之磷化鋁鎵銦發光二極體所發出之光 波長約為635nm,且在20mA的操作電流下,其光輸出功率 約為4mW,是傳統吸收式基板磷化鋁鎵銦發光二極體之光 輪出功率的2倍以上。 本發明並不限於祇適用於高亮度磷化鋁鎵銦發光二極 體,本發明也可以適用於其他發光二極體材料,如鋁 鎵紅色及紅外線發光二極體。 本發明之發光二極體是採用一黏接層44來接合發光二 極體與一高導熱性與高反射率基板4〇,因此,即便發光二 極體爲晶片表面不平整,也可以利帛丨 心用黏接層44將其緊密地 得合在一起。 ⑴利用隔絕溝渠和隔絕島方式,不會有整個钮刻區 表面粗糙,造成封裝不易辨識的問題。Page 14 1238548 V. Description of the invention αο) line, the polar layer 36 is on the same side and at the same level south with respect to the highly thermally conductive substrate, as shown in Figures 3 and 4. Finally, annealing is performed to make the N-type ohmic contact metal electrode layer 34 and the lower cladding layer 20 and the P-ohmic contact electrode 30 to form a good ohmic contact with the p-type ohmic contact epitaxial layer. The sequence of steps is not intended to limit the present invention, although anyone skilled in the relevant art may adjust the sequence of steps described above. Example & For example, the formation step of the isolation trench or the isolation island 38B can be moved to the formation of the two metal nailed electrode layers 36 and then performed without changing the diode structure of the present invention. The light wavelength emitted by the aluminum gallium indium light emitting diode obtained according to the present invention is about 635 nm, and its light output power is about 4 mW under an operating current of 20 mA, which is a traditional absorption substrate aluminum gallium indium phosphide light emitting device. The output power of the light wheel of the diode is more than 2 times. The present invention is not limited to high-brightness aluminum gallium indium light emitting diodes. The present invention can also be applied to other light emitting diode materials, such as aluminum gallium red and infrared light emitting diodes. The light-emitting diode of the present invention uses an adhesive layer 44 to join the light-emitting diode and a substrate with high thermal conductivity and high reflectivity 40. Therefore, even if the surface of the light-emitting diode is uneven, the light-emitting diode can be used. The core adhesive layer 44 holds them tightly together. ⑴Using the method of isolating the trench and island, there will be no rough surface of the entire button engraved area, which will cause the problem that the package is not easy to identify.

1238548 五、發明說明(11) (2 )在固定電流下可降低電壓及提高電流分佈,以提 昇發光二極體之外部發光效益。 以上所述僅為本發明之較佳實施例而已,並非用以限 定本發明之申請專利範圍,凡其它未脫離本發明所揭示之 精神下所完成之等效改變或修飾,均應包含在下述之申請 專利範圍内。1238548 V. Description of the invention (11) (2) The voltage can be reduced and the current distribution can be increased under a fixed current to improve the external light emitting efficiency of the light emitting diode. The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of patent application of the present invention. Any other equivalent changes or modifications made without departing from the spirit disclosed by the present invention shall be included in the following Within the scope of patent application.

第16頁 1238548 圖式簡單說明 本發明的較佳實施例將於往後之說明文字中輔以下列 圖形做更詳細的闡述: 第1至第4圖係繪示依據本發明一較佳實施例之發光二 極體之製造流程示意圖; 以及 第5和 6圖係繪示傳統之發光二極體結構示意圖 圖號對照說明: ❿ 5 2 :基板 5 4 :緩衝層 56:分散布拉格反射層 5 8 :下包覆層 6 0 ··活性層 62 :上包覆層 6 4 :高能隙電流分散層 7 0 : P歐姆接點金屬電極層 7 2 : N歐姆接點金屬電極層 7 4 :金屬釘線電極層 1 4 : P型歐姆接點磊晶層 1 6 : P型磷化鋁鎵銦上包覆層 1 8 :磷化鋁鎵銦活性層 2 〇 : N型磷化鋁鎵銦下包覆層 2 2 :蝕刻終止層1238548 on page 16 briefly illustrates the preferred embodiment of the present invention. The following figures will be used to explain in more detail in the following explanatory text: Figures 1 to 4 show a preferred embodiment according to the present invention. Schematic diagram of the manufacturing process of the light-emitting diode; and Figures 5 and 6 are schematic diagrams showing the structure of a traditional light-emitting diode. Figure 5 shows a comparison of the drawing numbers: ❿ 5 2: substrate 5 4: buffer layer 56: dispersed Bragg reflector 5 8 : Lower cladding layer 6 0 ·· active layer 62: upper cladding layer 6 4: high energy gap current dispersion layer 70: P ohm contact metal electrode layer 7 2: N ohm contact metal electrode layer 7 4: metal nail Wire electrode layer 1 4: P-type ohmic contact epitaxial layer 16: P-type aluminum gallium indium phosphide upper cladding layer 18: aluminum gallium indium phosphide active layer 2 0: N-type aluminum gallium indium phosphide Coating 2 2: etch stop layer

第17頁 1238548 圖式簡單說明 2 4 : N型砷化鎵基板 3 0 ·· P型歐姆接點金屬電極層 3 2 :高反射率金屬層 3 4 : N型歐姆接點金屬電極層 3 6 :金屬釘線電極層 38A:電極連接通道 3 8 B :隔絕溝渠或隔絕島 4 0 ··局導熱性之基板 42 :非導電型介電層 44 :黏接層Page 17 1238548 Brief description of the drawings 2 4: N-type gallium arsenide substrate 3 0 · P-type ohmic contact metal electrode layer 3 2: High reflectivity metal layer 3 4: N-type ohmic contact metal electrode layer 3 6 : Metal pin electrode layer 38A: Electrode connection channel 3 8 B: Isolated trench or island 4 0 · · Substrate with local thermal conductivity 42: Non-conductive dielectric layer 44: Adhesive layer

第18頁Page 18

Claims (1)

1238548 六、申請專利範圍 1 · 一種發光二極體,至少包含: 覆層依序堆疊; 第一歐姆接點金屬電極層形成於該歐姆接點蠢晶層 發光磊晶多層結構,該發光磊晶多層結構至少包含 歐姆接點磊晶層、一上包覆層、一活性層、以及一下包 上 一高反射率金屬層形成於該第一歐姆接點金屬電極層 與歐姆接點磊晶層上; 一高導熱性基板; 一介電層形成於該高導熱性基板上; + 一黏接層,該黏接層黏合該第一歐姆接點金屬電極層 與該非導電型介電層; 』一第一釘線金屬電極層及一第二歐姆接點金屬電極層 形成於該下包覆層上;及 甘亥Sx光挪日日夕層結構至少具有一電極連接通道及一隔 離溝渠形成於其中,其中該電極連接通道貫穿該發光磊晶 多層結構用以連接該第一歐姆接點金屬電極層與該第一釘 -線金屬電極層,該隔離溝渠將該發光磊晶多層結構隔離並 深及部分該上包覆層,而使該發光磊晶多層結構成為兩部 分,該兩部分分別與該發光二極體之第二歐姆接點金屬電 極層與該第一釘線金屬電極層連接。 2 ·如申請專利範圍第1項所述之發光二極體,其中該發光 磊晶多層結構的活化層係為磷化鋁鎵銦(AlGalnP)之同質1238548 VI. Scope of patent application 1 · A light emitting diode including at least: a cladding layer is sequentially stacked; a first ohmic contact metal electrode layer is formed on the ohmic contact stupid layer light emitting epitaxial multilayer structure, the light emitting epitaxial The multilayer structure includes at least an ohmic contact epitaxial layer, an upper cladding layer, an active layer, and a high reflectivity metal layer formed on the first ohmic contact metal electrode layer and the ohmic contact epitaxial layer. A high thermal conductivity substrate; a dielectric layer formed on the high thermal conductivity substrate; + an adhesive layer which bonds the first ohmic contact metal electrode layer and the non-conductive dielectric layer; A first stud line metal electrode layer and a second ohmic contact metal electrode layer are formed on the lower cladding layer; and the Gan Hai Sx light and sun day and night layer structure has at least an electrode connection channel and an isolation trench formed therein, The electrode connection channel penetrates the light-emitting epitaxial multilayer structure to connect the first ohmic contact metal electrode layer and the first pin-line metal electrode layer, and the isolation trench connects the light-emitting epitaxial multilayer structure. Isolate and deepen the upper cladding layer to make the light-emitting epitaxial multilayer structure into two parts, which are respectively connected to the second ohmic contact metal electrode layer of the light-emitting diode and the first pinned metal electrode. Layer connection. 2. The light-emitting diode according to item 1 in the scope of the patent application, wherein the active layer of the light-emitting epitaxial multilayer structure is homogeneous of aluminum gallium indium phosphide (AlGalnP) 第19頁 1238548 六、申請專利範圍 結構、單異質結構、雙異質結構或量子井結構當中一種。 3 .如申請專利範圍第1項所述之發光二極體,其中該歐姆 接點磊晶層為P型半導體層,該第一歐姆接點金屬電極層 係為P型半導體層;該第二歐姆接點金屬電極層係為N型半 導體層。 Φ 4 .如申請專利範圍第1項所述之發光二極體,該隔離溝渠 更包含貫穿該上包覆層,而使該隔離溝渠底部達該歐姆接 點磊晶層之中。 5 .如申請專利範圍第1項所述之發光二極體,其中該基板 係S自矽(Si )晶片、碳化矽(SiC)晶片、磷化鎵(GaP)晶 片其中一種。 6 .如申請專利範圍第1項所述之發光二極體,其中該基板 係A u、 A 1、 C u金屬其中一種。 7. 如申請專利範圍第1項所述之發光二極體,其中該黏接 層之材質包括 BCB(B-staged bisbenzocyclobutene; BCB) 與樹脂環氧樹脂(E p o x y )其中任一種。 8. 如申請專利範圍第1項所述之發光二極體,其中該黏接 層之材質包括In、 Au、 A1等金屬其中任一種。Page 19 1238548 6. Scope of patent application One of structure, single heterostructure, double heterostructure or quantum well structure. 3. The light-emitting diode according to item 1 of the scope of patent application, wherein the ohmic contact epitaxial layer is a P-type semiconductor layer, and the first ohmic contact metal electrode layer is a P-type semiconductor layer; the second The ohmic contact metal electrode layer is an N-type semiconductor layer. Φ 4. According to the light-emitting diode described in item 1 of the scope of the patent application, the isolation trench further includes a penetration through the upper cladding layer so that the bottom of the isolation trench reaches the ohmic contact epitaxial layer. 5. The light-emitting diode according to item 1 of the scope of patent application, wherein the substrate is one of an S-Si wafer, a silicon carbide (SiC) wafer, and a gallium phosphide (GaP) wafer. 6. The light-emitting diode according to item 1 of the scope of patent application, wherein the substrate is one of Au, A1, and Cu metal. 7. The light-emitting diode according to item 1 of the scope of patent application, wherein the material of the adhesive layer includes any one of BCB (B-staged bisbenzocyclobutene; BCB) and resin epoxy resin (E p o x y). 8. The light-emitting diode according to item 1 of the scope of patent application, wherein the material of the adhesive layer includes any one of metals such as In, Au, A1. 第20頁 12385481238548 p.20 六'申請專利範圍 9 ·如申請專利範圍第1項所述之發光二極體,其甲該介電 層包括氧化鋁(Al2〇3)、二氧化矽(Si02)或氮化矽(SiNx) 1 〇.如申請專利範圍第1項所述之發光二極體,其中該高反 射率金屬層選自Au、 A卜 Ag等金屬其中之一。 11 ·如申請專利範圍第1項所述之發光二極體,更包含第 金屬釘線電極層形成於該第二歐姆接點金屬電極層上。 1 2 · —種發光二極體之製造方法,至少包括: 田提供一發光磊晶多展結構,該發光磊晶多層結構依序 堆疊有一歐姆接點磊晶層、一上包覆層、一活性層、一下 包覆層、蝕刻終止層及一暫時基板; 形成一第一歐姆接點金屬電極層於該歐姆接點蟲晶層 一歐姆接點金屬電極層 形成一高反射率金屬層於該第 及歐姆接點磊晶層上6 'Application for Patent Scope 9 · The light-emitting diode described in item 1 of the patent application scope, wherein the dielectric layer includes aluminum oxide (Al203), silicon dioxide (Si02), or silicon nitride (SiNx) 10. The light-emitting diode according to item 1 of the scope of patent application, wherein the high-reflectivity metal layer is selected from one of metals such as Au, Ag, and the like. 11 · The light-emitting diode according to item 1 of the scope of the patent application, further comprising a second metal pin electrode layer formed on the second ohmic contact metal electrode layer. 1 2 · A method for manufacturing a light-emitting diode, including at least: Tian provides a light-emitting epitaxial multi-spreading structure, the light-emitting epitaxial multilayer structure is sequentially stacked with an ohmic contact epitaxial layer, an upper cladding layer, a An active layer, a lower cladding layer, an etch stop layer, and a temporary substrate; forming a first ohmic contact metal electrode layer on the ohmic contact parasitic layer; an ohmic contact metal electrode layer forming a high reflectivity metal layer on the On the epitaxial layer of the first and ohmic contacts 提供一高導熱性基板; 形成一非導電型介電層層於該高導熱性基板上; θ μ ^黏接層黏合該高導熱性基板導電型介電層層與該高 反射率金屬層及該歐姆接點磊晶層; 去除該暫時基板與該終止蝕刻層;Providing a high thermal conductivity substrate; forming a non-conductive dielectric layer layer on the high thermal conductivity substrate; θ μ ^ adhesive layer bonding the high thermal conductivity substrate conductive type dielectric layer layer and the high reflectivity metal layer and The ohmic contact epitaxial layer; removing the temporary substrate and the stop etch layer; 1238548 六、申請專利範圍 以微影及蝕刻技術’形成一電極連接通道,該電極連 接通道自該發光磊晶多層結構之該下包覆層貫穿至暴露出 P型歐姆接點金屬電極層; 以微影及#刻技術形成隔離通道’該隔離通道貫穿該 發光磊晶多層結構隔絕島,用以使該隔離通道所通過之上 述材料層隔離為第一部分及第二部分,該第一部分包含該 電極連接通道; 形成一第二歐姆接點金屬電極層於位於第二部分之該 — 形成一釘線金屬層以填滿該電極連接通道以連接該第 一歐姆接點金屬電極層並延伸於該第一部分之該下包覆層 上表面以形成第一釘線區,同時也形成於該第二歐姆接點 金属電極層上以形成第二釘線區。 13. 如申請專利範圍第12項之方法,其中上述之第二歐姆 接點金屬電極層係使用光阻圖案定義上述第一釘線區的位 置,再沉積上述之金屬層,再以膠帶去除附著性不佳的金 屬層,最後再去除光阻。 14. 如申請專利範圍第12項之方法,其中上述之第二歐姆 接點金屬電極層形成步驟至少包含使用光阻圖案定義上述 第一釘線區的位置,再沉積上述之第二歐姆接點金屬電極 層,再以膠帶去除該光阻圖案上的金屬層’最後再去除光 阻01238548 6. The scope of the patent application uses lithography and etching techniques to form an electrode connection channel that runs from the lower cladding layer of the light-emitting epitaxial multilayer structure to the P-type ohmic contact metal electrode layer; The lithography and #etching technology form an isolation channel. The isolation channel runs through the light-emitting epitaxial multilayer structure and isolates the island to isolate the material layer passing by the isolation channel into a first part and a second part. The first part includes the electrode. A connection channel; forming a second ohmic contact metal electrode layer on the second part— forming a nail wire metal layer to fill the electrode connection channel to connect the first ohmic contact metal electrode layer and extend to the first A portion of the upper surface of the lower cladding layer forms a first pinned region, and is also formed on the second ohmic contact metal electrode layer to form a second pinned region. 13. The method according to item 12 of the patent application, wherein the second ohmic contact metal electrode layer uses a photoresist pattern to define the position of the first pin line region, and then deposits the metal layer, and then removes the adhesion with tape. The metal layer with poor properties is removed by photoresist. 14. The method according to item 12 of the patent application, wherein the step of forming the second ohmic contact metal electrode layer at least includes using a photoresist pattern to define the position of the first pinned region, and then depositing the second ohmic contact. Metal electrode layer, and then remove the metal layer on the photoresist pattern with tape 第22頁 1238548 六、申請專利範圍 1 5 ·如申請專利範圍第1 2項之方法,其中上述之釘線金屬 層形成步驟至少包含使用光阻圖案定義上述第二釘線區的 位置,再沉積上述之第二歐姆接點金屬電極層,再以膠帶 去除該光阻圖案上的金屬層,最後再去除光阻。 1 6 .如申請專利範圍第1 2項之方法,更包含在上述之第二 釘線區及第二釘線區形成後施以退火步驟,以使該第二歐 姆接點金屬電極層與該下包覆層,及該第一歐姆接點金屬 電極層與該歐姆接點磊晶層形成低阻值之歐姆接觸。 1 7 .如申請專利範圍第1 2項之方法,其中上述之形成隔離 通道:之步驟中更包含蝕刻至停止於該歐姆接點磊晶層。 18.如申請專利範圍第12項之方法,其中上述之形成隔離 通道之步驟可調整至釘線金屬層形成步驟之後再進行。 1 9 .如申請專利範圍第1 2項之方法,其中上述之蝕刻可以 係乾式或濕式蝕刻。Page 22 1238548 VI. Patent Application Range 1 5 · The method of item 12 of the patent application range, wherein the step of forming the nailed metal layer includes at least the use of a photoresist pattern to define the position of the second nailed region, and then depositing For the second ohmic contact metal electrode layer, the metal layer on the photoresist pattern is removed by an adhesive tape, and finally the photoresist is removed. 16. The method according to item 12 of the scope of patent application, further comprising performing an annealing step after the formation of the second pin line region and the second pin line region, so that the second ohmic contact metal electrode layer and the The lower cladding layer and the first ohmic contact metal electrode layer and the ohmic contact epitaxial layer form a low resistance ohmic contact. 17. The method according to item 12 of the scope of patent application, wherein the above-mentioned step of forming an isolation channel: further includes etching to stop at the ohmic contact epitaxial layer. 18. The method according to item 12 of the patent application scope, wherein the above-mentioned step of forming the isolation channel can be adjusted after the step of forming the nail metal layer. 19. The method according to item 12 of the scope of patent application, wherein the above-mentioned etching can be dry or wet etching. 第23頁Page 23
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Publication number Priority date Publication date Assignee Title
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