TWI238201B - Architectural aluminum alloy material and process for manufacturing the same - Google Patents

Architectural aluminum alloy material and process for manufacturing the same Download PDF

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Publication number
TWI238201B
TWI238201B TW090119385A TW90119385A TWI238201B TW I238201 B TWI238201 B TW I238201B TW 090119385 A TW090119385 A TW 090119385A TW 90119385 A TW90119385 A TW 90119385A TW I238201 B TWI238201 B TW I238201B
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Taiwan
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treatment
baking
temperature
aluminum alloy
alloy material
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TW090119385A
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Chinese (zh)
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Kiyohiro Kawai
Yoshiro Togami
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Furukawa Electric Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Finishing Walls (AREA)

Abstract

There is provided an architectural Al alloy material which undergoes minor loss of proof stress even after a baking finish treatment at a high temperature of 260 to 280 DEG C. and which can be subjected to acute-angle bending, as well as, a process for manufacturing the same. This architectural Al alloy material, which is a hot rolled JIS A3003 material, contains a fiber structure and a recrystallized grain structure having an area ratio of 20% or less after a baking finish treatment at 300 DEG C. or lower, and undergoes a proof stress loss of 10% or less after the baking finish treatment. The Al alloy material is manufactured only by hot rolling which is carried out under control such that the temperature at the end of rolling be in the range of 290 to 340 DEG C.

Description

經濟部智^財產局肖工消費合作社印^ 1238201 A 7 _B7 ----------_ 五、發明説明(彳) ~ ^ ' [發明所屬之技術領域] 本發明係關於一種建築用銘合金材料及宜製造方法, 更進一步詳細地說,係關於一種在2 60至2 8 〇t:的高溫區域 下進行烘漆處理爲則提用以作爲建築用材料而被實際使用 的銘合金材料,且即使在於烘漆處理的前後,其耐力下降 小’且也可以充分保持其延伸性的緣故,屬於折曲性佳的 建築用鋁合金材料及其製造方法。 [先行技術] 輕量的錕合金材料係被使用在高層大樓的外牆材料及 內部裝潢材料或懸牆材等。 此時,例如第1圖所示,將鋁合金板材1折曲加工成 9CT 。最近,如第2圖所示,將板材折曲加工成超過90。以 上之銳角者有增加的趨勢。接著,在於這種折曲加工,追 求將折曲部2作成尖銳用以提高創意性。其一範例,係如第 3圖所示’顯示其在鋁合金材料1導入缺口 3後予以折曲的方 法。 接著’在於進行上述折曲加工之前,利用一定的溫度 將例如氟樹脂塗料、壓克力樹脂塗料、氨基甲酸樹脂塗料 般的塗料進行烘漆處理於鋁合金材料上,進而執行提高創 意性與耐腐蝕性的措施。 這種狀態下被實際使用的建築用鋁合金材料,被要求 具備下列功能。 首先,從建築用材料的角度來看,即使在施工後也要 (請先閱讀背面之注意事項再填寫本頁)Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Xiao Gong Consumer Cooperative, 1238201 A 7 _B7 ----------_ V. Description of the Invention (彳) ~ ^ '[Technical Field to which the Invention belongs] The present invention relates to a building The Ming alloy material and the suitable manufacturing method are further detailed. The invention relates to a Ming alloy which is subjected to baking treatment in a high temperature region of 2 60 to 280 to: and is actually used as a building material. Material, and even before and after the baking treatment, its resistance decreases little, and its elongation can be fully maintained. It belongs to a flexible aluminum alloy material for construction and its manufacturing method. [Advanced technology] Light-weight samarium alloy materials are used for exterior wall materials, interior decoration materials, and curtain wall materials in high-rise buildings. At this time, for example, as shown in FIG. 1, the aluminum alloy sheet 1 is bent to 9CT. Recently, as shown in FIG. 2, the sheet material is bent to more than 90 degrees. The above acute angles have an increasing trend. Next, in this bending process, it is required to sharpen the bent portion 2 to improve creativity. As an example, as shown in Fig. 3 ', a method is shown in which the aluminum alloy material 1 is bent after the notch 3 is introduced. Then 'before performing the above-mentioned bending process, a coating such as a fluororesin coating, an acrylic resin coating, or a urethane resin coating is baked on an aluminum alloy material at a certain temperature, so as to improve creativity and resistance. Corrosive measures. The aluminum alloy materials used in construction in this state are required to have the following functions. First, from the perspective of building materials, even after construction (please read the precautions on the back before filling this page)

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*1T 本纸張尺度適用中國國家標準(CNS ) A4規格(210X 291公釐) 4 1238201 B7 經濟部智丛財產局員工消費合作社印裝 五、發明説明(2) 具有適當的強度特性方可。具體而言,例如大樓用的外牆 材料的場合’即使在施工後也被要求要有95N/n]m2的耐力。 同時,要具有適切的延伸特性,可以圓滑地折曲加工 ’而且折曲加工部需形成尖銳形狀。 從前’建築用鋁合金材料是強調強度特性爲重點,使 用JIS所規定的A3004-H24材料(在ASTM B209所規定之3004- H24)、A3004-H32 材料(在 ASTM B209 所規定之 3004-H32)等 〇 在於製造這些材料時,首先,溶解所定規格之鋁合金 材料後,製造出該鑄塊(ingot)。然後,在於所規定的溫度所 規定的時間內對此鑄塊施行加熱之均勻熱處理後,以所規 定的加工率進行熱軋加工。 在於此熱軋加工的過程中,鑄塊的鑄造組織(凝固組織) 會朝向軋製方向被推壓延伸後轉換成纖維組織。 之後’執行冷軋用以處理結晶粒子直徑之細微化與厚 度調整’接著,利用退火處理來去除加工應變後,再次施 予冷軋後,執行爲了去除當時加工應變的熱處理,用以提 供作爲實際使用。 此外,在於上述一連串的製造工程中,在於熱軋加工 、冷軋加工的結束時點,於軋製材料內會積儲軋製應變。 接著’之後將軋製材料加熱到再結晶化溫度以上的溫度時 ,會將加工應變能量當作起點形成組織爲再結晶粒子成長 〇 上述3 0 0 4 - Η 2 4材料等的材料中之任何一種皆屬於冷軋 (請先閲讀背面之注意事項再填寫本頁 to 裝 、11 本纸張尺度適用中國國家標準(CNS ) Α4規格(210Χ 297公f ) -5 - 1238201 A7 _ B7 經濟部智慧W產局員工消費合作社印製 五、發明説明(3) 用的材料’其再結晶粒子細微,且仍然殘存有纖維組織, 可以折曲加工尖銳的90。。 當折曲加工9(Τ以上的銳角後在折曲部發生裂痕時,需 溶接該部份予以修補。 [發明所欲解決之課題] 本發明的目的,係提供一種針對當作建築材料使用, 而且以烘漆處理爲前提所使用的鋁合金材料,即使在烘漆 後其耐力的下降非常小,同時延伸特性也適當的緣故,因 此即使尖銳的折曲加工或銳角折曲加工也不會發生裂痕之 建築用鋁合金材料及其製造方法。 爲了達成上述目的,本發明提供一種符合π s所規定之 A3003(ASTM B209 3003)的熱軋材料,且在溫度3〇〇t;以下 的烘漆處理後的組織係由纖維組織與面積比例2 〇 %以下的再 結晶粒子組織所組成後,在於前述烘漆處理的前後的耐力 的下降率控制在10%以下爲其特徵之建築用鋁合金材料。 同時,本發明又提供一種對於]IS所規定之a3〇〇3(astm B209 3003)的鑄塊進行均勻熱處理後,接著,只要執行軋 製結束時的溫度在2 9 0至3 4 0 °C之熱軋加工即可以供應作爲 實際使用爲特徵之建築用鋁合金材料的製造方法。 [用以解決課題之手段] 本發明之鋁合金材料,係針對強度特性佳的A 3003材料 僅給予進行後述條件的熱軋加工後立即供應作爲實際使用 本纸張尺度適用中國國家#準(CNS ) Α4規格(210X 297公I ) (讀先閱讀背面之注意事項再填寫本頁)* 1T This paper size is in accordance with Chinese National Standard (CNS) A4 (210X 291 mm) 4 1238201 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (2) Only with proper strength characteristics. Specifically, for example, in the case of an exterior wall material for a building ', it is required to have a resistance of 95 N / n] m2 even after construction. At the same time, in order to have a suitable extension characteristic, it can be smoothly bent and processed, and the bent portion needs to be formed into a sharp shape. In the past, the aluminum alloy materials for construction emphasized the strength characteristics, and used A3004-H24 material (3004-H24 specified in ASTM B209) and A3004-H32 material (3004-H32 specified in ASTM B209). Waiting ○ is that when manufacturing these materials, first, an aluminum alloy material of a predetermined specification is dissolved, and then the ingot is manufactured. Then, the ingot is subjected to a uniform heat treatment by heating for a predetermined time at a predetermined temperature, and then hot-rolled at a predetermined processing rate. During the hot rolling process, the cast structure (solidified structure) of the ingot is pushed and stretched in the direction of rolling and transformed into a fibrous structure. After that, “cold rolling is performed to deal with the miniaturization and thickness adjustment of the crystal particle diameter.” Then, the annealing process is used to remove the processing strain, and then the cold rolling is applied again, and then a heat treatment is performed to remove the processing strain at that time. use. In addition, in the above-mentioned series of manufacturing processes, rolling strain is accumulated in the rolling material at the end point of hot rolling processing and cold rolling processing. Next, when the rolled material is heated to a temperature higher than the recrystallization temperature, the processing strain energy is used as a starting point to form a structure to grow the recrystallized particles. Any of the above materials such as 3 0 0 4-Η 2 4 materials One type is cold rolling (please read the precautions on the back before filling in this page), 11 paper sizes are applicable to China National Standard (CNS) A4 specifications (210 × 297 male f) -5-1238201 A7 _ B7 Ministry of Economy Wisdom Printed by the W Production Bureau employee consumer cooperative V. Description of the invention (3) The material used is' fine recrystallized particles, and still has fibrous structure, which can be bent and sharpened 90. When bent to process 9 (T or more When a crack occurs in a bent portion after an acute angle, the portion needs to be welded and repaired. [Problems to be Solved by the Invention] The object of the present invention is to provide a method for use as a building material and on the premise of baking paint treatment. The aluminum alloy material has a very small decrease in endurance even after baking. At the same time, the elongation characteristics are suitable, so even if it is sharply bent or sharply bent, it will not crack. In order to achieve the above object, the present invention provides a hot-rolled material that conforms to A3003 (ASTM B209 3003) specified by π s, and the temperature is 300 t; the following baking paint treatment The subsequent structure is composed of a fibrous structure and a recrystallized particle structure having an area ratio of 20% or less, and the reduction rate of the endurance before and after the aforementioned baking treatment is controlled to 10% or less, which is a characteristic aluminum alloy material for construction. At the same time, the present invention provides a homogeneous heat treatment of the a3003 (astm B209 3003) ingot specified in [IS], and then, as long as the temperature at the end of the rolling is between 290 and 3 40 ° C. The hot rolling process can provide a manufacturing method of aluminum alloy materials for construction, which is characterized by practical use. [Means to Solve the Problem] The aluminum alloy material of the present invention is only given to the A 3003 material with good strength characteristics, which will be described later. The conditions of the hot-rolled processing are immediately supplied as actual use. This paper size applies to China National Standards (CNS) Α4 specifications (210X 297 male I) (Read the precautions on the back before filling Page)

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*1T -6 - 1238201 經濟部智few/i^;員工消费合作社印製 --_______B7五、發明説明(4) 一 〜 ' —一' 的材料。換言之,不像傳統的鋁合金材料的情形一般,在 於經過熱軋後,進一步經過冷軋-中間退火-冷軋-熱處理的 工程予以製造。 具體的說,被製造成如下所述。 首先,溶解所規定組成之A3003材料後,製造成禱塊。 接著,對此鑄塊進行均勻熱處理後再給予熱軋加工處理。 均句熱處理’係在於500至63CTC的溫度區域下經過1至 1 5小時左右者較爲理想。如果處理溫度低於5〇(rc的話,例 如以鋁錳爲主體的金屬間化合物的生成量會減少導致由鑄 造組織(凝固組織)成長的再結晶粒子會變成粗大化的緣故, 容易發生材料的折曲加工性的降低或外觀不良,同時,當 處理溫度高於630°C時,鑄塊發生變形或膨脹後,導致在於 經過後段工程(熱軋)的過程中發生組織缺陷的現象。最佳的 處理溫度範圍是在600至630°C。 同時,當處理時間不到1個小時的情形下,形成鑄塊整 體無法達到均勻熱化,導致難獲得均勻材質之熱軋加工。 此外,即使處理時間超過1 5個小時的長時間會使均勻熱效 果達到飽和狀態,只會造成熱能源的浪費不利於成本。最 佳的處理時間範圍是在2至6個小時。 針對這樣被均句熱化的鑄塊,接著,立即被施以熱軋 後使該鑄造組織變成纖維組織的同時,也成長成細微的2次 組織(sub grain)。 本發明的A 3003材料,係在於結束上述熱軋之後,即便 當作建築用材料供應實際使用。因此,當被供應實際使用 本纸張尺度適用中國國家標準(CMS ) A4規格(2iOX 297^f *) ' -7- (請先閱讀背面之注意事項再填寫本頁)* 1T -6-1238201 Ministry of Economic Affairs wisdom / i ^; printed by employee consumer cooperatives --_______ B7 V. Description of the invention (4) I ~ '-I' materials. In other words, unlike the case of traditional aluminum alloy materials, it is manufactured after cold rolling, intermediate annealing, cold rolling, and heat treatment after hot rolling. Specifically, it is manufactured as follows. First, after dissolving the A3003 material of the prescribed composition, it is made into a prayer block. Next, this ingot is subjected to a uniform heat treatment and then subjected to a hot rolling process. The homojunction heat treatment 'is preferably performed in the temperature range of 500 to 63CTC for about 1 to 15 hours. If the processing temperature is lower than 50 ° C, for example, the production amount of intermetallic compounds mainly composed of aluminum and manganese will decrease, and the recrystallized particles grown from the cast structure (solidified structure) will become coarser. Reduced bending workability or poor appearance. At the same time, when the processing temperature is higher than 630 ° C, the ingot is deformed or expanded, which results in the occurrence of structural defects during the post-process (hot rolling). The processing temperature range is 600 to 630 ° C. At the same time, when the processing time is less than 1 hour, the entire ingot cannot be uniformly heated, which makes it difficult to obtain a hot rolling process with a uniform material. In addition, even when processing A long time of more than 15 hours will saturate the uniform thermal effect, which will only cause the waste of thermal energy and is not conducive to cost. The best processing time is in the range of 2 to 6 hours. Then, immediately after being hot-rolled, the cast ingot was transformed into a fibrous structure, and it also grew into a fine secondary grain. The A 3003 material is after the above hot rolling, even if it is supplied as a construction material for actual use. Therefore, when it is supplied for actual use, the paper standard applies to the Chinese National Standard (CMS) A4 specification (2iOX 297 ^ f *) '-7- (Please read the notes on the back before filling this page)

、1T 麵 1238201 Α7 _ Β7 經濟部智¾財產局員工消費合作社印災 五、發明説明(5) 的時點,此一熱軋材料之A 3003材料的組織,係以利用軋製 加工所形成的纖維組織爲主體,且在該處規定量之細微的 二次組織形成分散的狀態。 由於此一 A 3003材料,係形成如上述的組織的緣故,因 此可以發揮以下的效果。 例如進行銳角折曲加工時,當組織爲只有纖維組織的 情形下,會在折曲部份沿著纖維組織的粒子界面發生裂痕 等。但是,因爲在此材料中細微的二次組織也同時共存的 緣故,因此上述的裂痕的發生會被抑制。 換句話說,形成可以銳角折曲加工。 同時,使用此一 A 3 0 0 3材料時,即使溫度在3 〇 〇。(:以下 ’具體而言,即使在於溫度260至28CTC的高溫區域烘漆處 理’在於烘漆處理的則後’形成A 3 0 0 3材料的耐力下降率到 途1 0 %以下。接著,即使在烘漆處理後,該耐力的絕對値可 以確保在95N/mm2以上,可以滿足作爲大樓的外牆材料的必 要條件。同時,延伸率也在2 7 %以上,可以獲得良好的折曲 加工。 上述特性中之烘漆處理前後的耐力下降率可以在1 〇 %以 下的特性’係由於前述細微的二次組織與纖維組織同時共 7子所得到的效果。當然’此二次組織,在高溫區域的烘漆 處理時’會成長爲再結晶粒子使粒子直徑變大,而且其析 出量也會增加。 但是,使用本發明的A 3003材料時,即使在高溫區域的 烘漆處理後,此一再結晶粒子組織的存在量爲組織整體所 本紙張尺度適用中國國家標準(CNS ) A4規格(210X29^^7 ~一~ ---- (請先閲讀背面之注意事項再填寫本頁}1T surface 1238201 Α7 _ Β7 Ministry of Economic Affairs, Intellectual Property Bureau, Employee Consumption Cooperative, Printing Disaster V. At the time of the invention description (5), the organization of this hot rolled material A 3003 is based on the fiber formed by rolling processing The structure is the main body, and a predetermined amount of fine secondary structure is dispersed. Since this A 3003 material is formed as described above, the following effects can be exhibited. For example, in the case of acute-angle bending processing, when the structure is only a fibrous structure, cracks may occur along the particle interface of the fibrous structure at the bent portion. However, because the fine secondary structure also coexists in this material, the occurrence of the aforementioned cracks can be suppressed. In other words, the formation can be bent at an acute angle. At the same time, when using this A 3 0 0 3 material, even the temperature is 300. (: The following 'specifically, even in the high-temperature area baking paint treatment at a temperature of 260 to 28 CTC', and after the baking paint treatment, the formation of the endurance reduction rate of the A 3 0 0 3 material reaches 10% or less. Then, even if After the baking treatment, the absolute strength of the endurance can be ensured above 95N / mm2, which can meet the necessary conditions for the exterior wall material of the building. At the same time, the elongation is also above 27%, which can obtain good bending processing. Among the above characteristics, the rate of decrease in endurance before and after lacquer treatment can be 10% or less. 'This is the effect obtained by the aforementioned fine secondary structure and fibrous structure for a total of 7 children. Of course,' this secondary structure is at high temperature. During the baking process in the area, it will grow into recrystallized particles, which will increase the particle diameter and increase the amount of precipitation. However, when the A 3003 material of the present invention is used, even after the baking process in the high temperature area, this is repeated. The amount of crystalline particle structure is the size of the whole paper. The paper size applies the Chinese National Standard (CNS) A4 specification (210X29 ^^ 7 ~ a ~ ---- (Please read the precautions on the back before filling in this }

裝 、1Τ 0. -8- 1238201 A7 B7 五、發明説明(6) 占有面積比率的20%以下,所剩則被控制爲纖維組織’此一 緣故在於烘漆處理前後的耐力下降率變得在於10%以下。 (請先閱讀背面之注意寧項再填寫本頁) 此種特性是在上述熱軋加工中,利用將軋製結束時的 材料溫度管理在290至3 00 °C即可實現。 若該軋製結束時的溫度高於340°C時,雖然延伸率會達 到35 %左右,但是其組織幾乎會形成爲再結晶粒子組織。此 一緣故,折曲加工時的折曲部份會產生皺紋的現象。 同時,當軋製結束時的溫度小於290°C時,前述細微的 二次組織的生成量會變少,同時延伸率也會低於27 %,造成 在於銳角折曲加工時發生裂痕。 爲了將軋製結束時的溫度管理在290至340 °C,在於本 發明中,將軋製開始時的溫度設定在350至450°C。 當此溫度低於3 5 0 °C時,軋製結束時的溫度便無法確保 在29 0 °C以上。形成強度高而延伸率變小的緣故,在折曲加 工時會發生裂痕等。 經濟部皙.^財/1局員工消骨合作社印製 此外’如果高於45(TC時,形成軋製結束時的溫度不易 在於340 °C以下,在於軋製結束時的組織上,變成以粗大的 再結晶粒子組織爲主體,在折曲加工時的折曲部會發生皴 紋。接著,耐力會變得小於95N/mm2。 [發明之實施形態] 以貫施例1至1 6、比較例1至9作說明。 (1)鋁合金材料 本纸張尺度適用中國國家標準(CNS )八4規格(21〇χ2ϋ:^· -9- 1238201 _ B7 五、發明説明(7) 溶解以下的鋁合金材料後,製造成鑄塊(厚度爲500mm) 〇 (請先閱讀背面之注意事項再填寫本頁) A3003材料成份爲:Si0.58質量%、 Fe0.68質量%、 (:11〇.18質量%、]\4111.48質量%、%2〇.02質量%、211〇.09質量% ,所剩爲鋁與無法避免的不純物質。 (2) 板材料的製造 利用具備下列條件的方法製造如表1所示之板厚的板材 料。 本發明方法(A):在溫度600°C的均勻熱爐中對鑄塊熱處 理6個小時後,將軋製開始時的溫度設定爲5 5 0 °C,且將軋 製結束時的溫度在表1所示的溫度之溫度管理下進行熱軋加 工。並以此當作板材料使用。 傳統方法(B)··在溫度600°C的均勻熱爐中對鑄塊熱處理 6個小時後,進行軋製開始時的溫度爲5 5 0 °C,且軋製結束 時的溫度爲3 1 0°C °C的熱軋,接著,進行80°C的冷軋。 然後,在溫度3 60 °C下進行3小時的中間退火處理後, 進一步地進行8 0 °C的冷軋後,以2 3 0 °C進行3小時的熱處理 。之後,作爲板材料使用。 (3) 特性的測定 烘漆處理前後的耐力下降率(%): 測定烘漆處理前的各種板材料的耐力(Γ。)與延伸率 本A沒尺度適用中國國家標準(CMS ) A4現格(210X 19*7公釐) -10- 1238201 A7 B7 經濟部智^封產局資工消贫合作社印緊 五、發明説明(8) 接著,塗上氟元素樹脂塗料到各板材料,並進行如表1 所不的溫度之供漆處理後’測定此時的耐力(F )與延伸 率。 計算1 0 0 X ( Γ。- Γ ) / ( Γ。),作爲烘漆處理前後的耐 力下降率(%)。其結果顯示於表1。 再結晶粒子組織的面積比率: 利用巴克法(Barker)法觀察結晶組織。 具體而言,於刨光加工各板材料的表面後,電解硏磨 該加工面,並且利用HBF4液體對硏磨面進行腐蝕處理後, 使用偏光的影像處理累計每一個再結晶粒子組織的面積。 接著,求出可視範圍(5 m m X 5 m m )內的上述累計値的比例( 百分率)。其結果顯示於表1。 同時,關於實施例9與比較例8的板材料,其組織的顯 微鏡相片(倍率X50)分別顯示於第4圖與第5圖。 (4)折曲試驗 針對各烘漆處理後的各板材料進行折曲加工後,以目 視觀查折曲部分的皺紋(烘漆的剝落)與裂痕的有無。 關於皺紋,分成如第6圖所示之與軋製方向4垂直的方 向(板材料的長方行方向)與第7圖所示之與軋製方向4(板材 料·的寬度方向)平行的方向之2種方式進行,求出觀查皺紋 時之折曲角度。 同時,關於裂痕方面,如第7圖所示,分別對於與軋製 方向平行的方向(板材料的寬度方向)折曲加工成90°和折曲 (請先閱讀背面之注意事項再填寫本頁Equipment, 1T 0. -8- 1238201 A7 B7 V. Description of the invention (6) Occupied area ratio is less than 20%, and the rest is controlled to fibrous structure. 'The reason is that the rate of endurance reduction before and after the baking paint treatment becomes 10% or less. (Please read the note on the back before filling in this page.) This characteristic can be achieved by controlling the material temperature at the end of rolling to 290 to 300 ° C in the hot rolling process described above. If the temperature at the end of the rolling is higher than 340 ° C, the elongation will reach about 35%, but the structure will almost become a recrystallized particle structure. For this reason, wrinkles may occur in the bent portion during the bending process. At the same time, when the temperature at the end of rolling is less than 290 ° C, the amount of the aforementioned fine secondary structure will be reduced, and the elongation will be less than 27%, which will cause cracks during sharp bending. In order to control the temperature at the end of rolling to 290 to 340 ° C, in the present invention, the temperature at the start of rolling is set to 350 to 450 ° C. When this temperature is lower than 350 ° C, the temperature at the end of rolling cannot be guaranteed above 29 0 ° C. Due to its high strength and low elongation, cracks and the like occur during bending. Printed by the Ministry of Economic Affairs ^ Finance / 1 Bureau staff boneless cooperative. In addition, if it is higher than 45 (TC, the temperature at the end of rolling is not easy to be below 340 ° C, and the structure at the end of rolling becomes The coarse recrystallized particle structure is the main body, and ridges will occur in the bent portion during the bending process. Then, the endurance will be less than 95 N / mm2. [Embodiments of the invention] In the examples 1 to 16, comparison Examples 1 to 9 are explained. (1) Aluminum alloy material The paper size is in accordance with Chinese National Standard (CNS) 8-4 specification (21〇χ2ϋ: ^ · -9-1238201 _ B7 V. Description of the invention (7) Dissolve the following After the aluminum alloy material, it is manufactured into an ingot (thickness of 500mm) 〇 (Please read the precautions on the back before filling in this page) A3003 material composition is: Si0.58 mass%, Fe0.68 mass%, (: 11. 18% by mass,] \ 4111.48% by mass,% 20.02% by mass, 211.09% by mass, and the remainder is aluminum and unavoidable impurities. (2) Manufacture of plate materials Manufactured by a method with the following conditions The plate thickness is shown in Table 1. Method (A) of the present invention: uniform heat at a temperature of 600 ° C After the ingot was heat-treated for 6 hours, the temperature at the start of rolling was set to 550 ° C, and the temperature at the end of rolling was hot-rolled under the temperature management of the temperature shown in Table 1. This is used as a sheet material. Conventional method (B) ... After the ingot is heat-treated in a uniform heating furnace at a temperature of 600 ° C for 6 hours, the temperature at the start of rolling is 5 50 ° C, and the rolling At the end of the production process, hot rolling was performed at a temperature of 3 1 0 ° C ° C, followed by cold rolling at 80 ° C. Then, an intermediate annealing treatment was performed at a temperature of 3 60 ° C for 3 hours, and then further 8 0 After cold rolling at ° C, heat treatment was performed at 230 ° C for 3 hours. After that, it was used as a board material. (3) Measurement of characteristics The endurance (Γ.) And elongation of various board materials are not applicable to the Chinese National Standard (CMS) A4 standard (210X 19 * 7 mm) -10- 1238201 A7 B7 Poor cooperatives printed five. Description of invention (8) Next, apply fluorine resin coating to each board material, and proceed as shown in Table 1. After the paint is supplied at different temperatures, the endurance (F) and elongation at this time are measured. Calculate 100 X (Γ.-Γ) / (Γ.) As the rate of decrease in endurance (%) before and after the baking paint treatment. The results are shown in Table 1. Area ratio of recrystallized particle structure: The crystalline structure was observed by the Barker method. Specifically, after the surface of each plate material was planed, the processed surface was electrolytically honed, and After the honing surface was etched with HBF4 liquid, the area of each recrystallized particle structure was accumulated using polarized image processing. Next, the ratio (percentage) of the cumulative chirp in the visible range (5 m m × 5 m m) is obtained. The results are shown in Table 1. Meanwhile, with respect to the plate materials of Example 9 and Comparative Example 8, microscopic photographs (magnification X50) of their structures are shown in Fig. 4 and Fig. 5, respectively. (4) Bending test After bending processing of each plate material after each baking paint treatment, visually inspect the presence of wrinkles (peeling of baking paint) and cracks in the bent portion. The wrinkles are divided into a direction perpendicular to the rolling direction 4 (the longitudinal direction of the sheet material) as shown in FIG. 6 and a direction parallel to the rolling direction 4 (the sheet material and the width direction) as shown in FIG. 7. The direction is performed in two ways to find the bending angle when viewing wrinkles. At the same time, as for the cracks, as shown in Fig. 7, the direction parallel to the rolling direction (the width direction of the plate material) is bent into 90 ° and bent (please read the precautions on the back before filling this page).

裝 參 本紙張尺度適/ίΐ巾_家標準(CNS) A4規格(2⑷以财潑) -11 - 1238201 A7 _ B7 五、發明説明(9) 加工成180°進行處理後,觀查有無裂痕的發生。 沒有裂痕時標記〇,若發生微小的裂痕但實際使用上 不會造成問題的情形時標記△,發生明顯裂痕時標記X。 (請先閱讀背面之注意事項再填寫本頁) 經濟部皙慧財產局員工涓費合作社印製 格 規 |釐 2 1238201 Λ 7 Β7 五、發明説明(士 經濟部智慧时1局肖工消f合作社印製 折曲I式驗 破裂 折曲 180°C <3 <1 <1 <〇〇〇〇〇〇〇〇〇〇< 〇 X U U Ο 0 U X X X 折曲 90°C 〇〇〇〇〇〇〇〇〇〇()〇〇〇〇〇 Χ〇〇〇〇〇X X <] 皺紋 與軋製方向 呈平行的方 向 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 COOOCOOOCOOOOOCOOOOOOOCOOOCOOOOD r—* · r.—I r· < f丨丨 ‘ ι Ί t—< f < r—«· τ·_— «" 11 < »1 < τ1 f < r_—« * —< 〇〇〇〇〇〇〇〇〇 CO "'χ}- τ~*( '―™* r~~t f丨一< f—ί I— i \ < ψ — t < »—-< 1 1 f — it? 藏糊 s _ i_l«z « 1 i>> · ί,〆 « ί tijz ·λ..ι 产 «11' vUx t_i 1/» vij/· \JJ〆 i_Ll〆 ί \A^ \ \ ffl; ffl: ffl: ffl:苗:苗二坦二坦二坦::ffl: ffl:坦二坦二坦二垣二坦二 *τΗ·> 'τΗν ^γΗ、*τΗ·ν 'τΗ'ν *τΗν *τΗ·ν '^γΜ、^rfi、 UJ^OOOOOOOO 辟〇〇〇〇 — 寸寸一寸寸 '"、 r—Η Γ—^ r—^ r—H »—< r—^ »—< *—♦ 烘漆處理 耐力 下降 率(%) ^C〇r^_〇CC〇CO^〇MD<>J 〇OC7NaNr^ CD v—( t—* ί~' 1.2 31.5 26.4 5.7 1.1 2.1 10.7 28.9 65.8 S g SI £ W tt rf ^ OOOOOOOOOOOOO^o^O 〇sss§§§§§ 特性(烘漆後) 延伸率 (%) ^oiooqo'O^fOcor^ r^c^i^r^ooo^^cKcKcKoo^r^cNC'i 〇lCN〇l(NCNoi<N<N〇J〇]corocomcnm Ο-ί \〇 r—( t—t t—i CO 一· oS od 寸·寸’寸· uS oi cn c^i cn cn cn ^ ^ r<i 耐力 (N/min2) \〇i~*〇〇v〇unc〇CN 寸 CN — O 寸 寸寸0^0〇〇30^0<10<10^。】<:^一 — 〇〇《 y—^ < ___·Η >—«4 f lit — * i—4 ψ "1 ” _一 _ — 产 1 > f——4 f __一 ψ 1 ^ 烘漆溫度 ro 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 ΟΟΌ^〇ν〇00〇ν〇ν〇^〇〇〇ν〇〇ν〇〇 一 〇·】〇〇 οι cn 〇3 cn 〇】N m 〇〇 <N N cq ooooooooo V〇 寸寸 V〇〇〇O〇〇V〇 寸 οί τ<~ι cn 〇〇 '~~> 〇J .> 〇) m 扳材料的製造 特性(烘漆前) 延伸率 (%) 26.5 26.5 26.5 26.5 28.5 28.6 28.8 28.5 28.6 28.8 28.6 30.4 30.4 31.0 31.2 31.0 19.8 28.6 31.0 33.3 34.1 34.1 8.8 8.8 8.8 耐力 (N/mm2) v〇 r- 寸 m ^ 寸 c*。寸寸寸 υη 寸 un 寸寸寸 ~- ι— ο ο 〇 T—H 1—« r—H r·— r—H t < r—H ,n* r -< ι * π i t < f—< ,•丨— v 1 · f1,1,1 < g 3 s £ s S g g « s’? ® I, vr*', l/·) 〇 〇 W, Ο O vy) 〇 〇 〇 iy^ uo Ο 〇 〇 —·」vrS 一· 一· Ή 〆二〆 ur:· cS ’ ι/S vc5 cr; pppppoopp m cn rn c^\ m c^\ cn cn 钆製結束 時的溫度 (°C ) 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 C7> ^ ^ 1 CO i "*^· ,'^}· r^4 〇3 cn cn co m cn rn cn rn m cn cn cn m ooooooooo ί—i CO ί—1 H »—♦ cn cn cn m 〇〇 cn m 製造方 法的種 類 <<<<<<<<<<<<<<<< <<<<P3PQPQPQCQ 台金的 種類 co r。 cn cn m cn cn m m cn ro <r*t c^j co c^> 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 oooooooooooooooo ro c^i cn ro γ*^ι cn c^i m m cn m m ^ rn cm <<<<<<<<<<<<<<<< A3003 A3003 A3003 A3003 A3003 A3003 A3004 A3004 A3004 丨 實施例1 實施例2 實施例3 實施例4 實施例5 實施例6 實施例7 實施例8 實施例9 實施例10 實施例U 實施例Γ2 實施例Π 實施例Μ 實施例15 實施例16 -' cn *·〇 o r- go 〇-\ 匡匡匡s匡匡s匡s (請先閱讀背面之注意事項再填寫本頁) •裝--- 訂 豢 本紙張尺度適用中國國家標準(CNS ) A4規格(210><297公釐) -13- 1238201 A7 B7 五、發明説明(d [發明之效果] 從表1可淸楚了解下列結果。 (請先閲讀背面之注意事項再填寫本頁) (1) 比較實施例9與^比較例6明顯地看出,即使材料相同 ,軋製結束的溫度相同且板厚一樣,在於熱軋之後,隨之 經過冷軋或中間退火等製造的比較例6的情形下,即使烘漆 溫度同樣爲260°C,烘漆後的耐力與實施例9相比,未達到 9 5 N / m m2。接著,即使在折曲試驗,也比實施例9容易起皺 紋。此乃由於比較例6的組織在於熱軋後的一連串的工程後, 進一步地在於烘漆處理時形成再結晶的粒子組織的緣故。 由此可知,即使烘漆處理只要使用防止再結晶粒子組 織的成長的條件之熱軋就可以明確本發明的製造方法之有 效性。 (2) 第4圖所示的實施例9之烘漆處理後的組織係纖維組 織與細微的二次組織(sub grain)混合存在。接著,烘漆處理 後的耐力與延伸率分別爲122N/mm2與29.5%的高數値,且耐 力下降率爲1.6%非常低。 哇齊.郎智&財/-1局肖工4^合作社印製 此一緣故,可以獲得良好的折曲試驗的結果。此外, 在於第5圖所示的比較例8中的烘漆處理後的組織中不認定 纖維組織的存在,而認定是屬於粗大的再結晶粒子組織。 接著,烘漆處理後的耐力雖然爲160N/mm2的高數値,但是 其延伸率爲1 5.2 %很小,同時耐力下降率爲2 8 · 9 %非常的大 。其結果,折曲試驗的皺紋、裂痕會變得更爲惡化。 從此一觀點,具備共同存在之纖維組織與細微的二次 組織的組織之本發明的建築用鋁合金材料的有效性非常明 本·或張尺度適用中國國家標準(CNS ) A4規格(210.X 297公釐) -14 - 1238201 ____ B7_ 五、發明説明(^ 顯。 (請先閱讀背面之注意事項再填寫本頁) 由以上說明可以淸楚了解,將軋製結束時的溫度管理 在290至340°C之A3003材料的熱軋材料,即使在於烘漆處理 後其再結晶粒子組織也不會成長形成維持以纖維組織爲主 體的狀態,且耐力下降率在1 0%以下,同時,耐力的絕對値 會確保在9 5 N / m m2以上,延伸率會確保在2 7 %以上。因此, 本發明的鋁合金材料,係即使進行烘漆處理後,其折曲加 工性仍佳,而且針對作爲不會引發耐力下降的建築用材料 一環而言其工業上的價値非常大。 此外,上述的說明,係針對烘漆處理時的溫度在260至 2 8 0 °C的情形下進行,但是本發明的建築用鋁合金材料,也 可以適用於烘漆處理的溫度在260°C以下,且即使在280至 300°C的範圍下也可以有效使用。 [圖面之簡單說明] 第1圖係顯示將板材料折曲加工成90°的槪略圖形。 第2圖係顯示將板材料折曲加工成銳角的槪略圖形。 第3圖係顯示將作成缺口之板材折曲加工成9 〇 °的槪略 圖形。 第4圖係實施例9的板材料組織的顯微鏡相片。 第5圖係比較例8的板材料組織的顯微鏡相片。 第6圖係顯示將板材料朝向與軋製方向呈垂直的方向折 曲的槪略圖形。 第7圖係IrJ樣地顯不將板材料朝向與乳製方向呈平行1的 —*^ ___________________________________________ 本紙張^度適用中國國家標準(CNS ) Λ4規格(210X 297公釐) " ' --- -15- 1238201 A7 B7 五、發明説明(^ 方向折曲的槪略圖形。 元件對照表 1 銘合金材料 3 缺口。 (請先閱讀背面之注意事項再填寫本頁 裝---The paper size of this paper is suitable. Ϊ́ 家 standard (CNS) A4 size (2). -11-1238201 A7 _ B7 V. Description of the invention (9) After processing to 180 ° for processing, check for cracks. occur. Mark 0 when there are no cracks, mark △ if there is a slight crack but it will not cause a problem in practical use, and mark X when a significant crack occurs. (Please read the precautions on the back before filling out this page) Employees of Xihui Property Bureau of the Ministry of Economic Affairs print the rules for the cooperatives | 厘 2 1238201 Λ 7 Β7 V. Description of the invention Cooperative prints Bending I-type bursting test 180 ° C < 3 < 1 < 1 < 〇〇〇〇〇〇〇〇〇〇〇〇〇 < 〇XUU 〇 0 UXXX Bend 90 ° C 〇〇〇 〇〇〇〇〇〇〇〇〇〇 〇〇〇〇〇〇〇〇〇〇〇〇XX <] Wrinkles and rolling direction is parallel to the direction r— * · r.—I r · < f 丨 丨 'ι Ί t— < f < r— «· τ · _—« " 11 < »1 < τ1 f < r_—« * — & 〇〇〇〇〇〇〇〇〇〇〇〇 CO " 'χ}-τ ~ * (' ― ™ * r ~~ tf 丨 一 < f—ί I— i \ < ψ — t < »—- < 1 1 f — it? Tibetan paste s _ i_l« z «1 i > > · ί, 〆« ί tijz · λ..ι production «11 'vUx t_i 1 /» vij / · \ JJ 〆i_Ll〆ί \ A ^ \ \ ffl; ffl: ffl: ffl: Miao: Miao Ertan Tantan Tantan :: ffl: ffl: Tan Tantan Tan Tan Eryuan Er Tan Er * τΗ · > 'τΗν ^ γΗ, * τΗ · ν' τΗ'ν * τΗν * τΗν '^ γΜ, ^ rfi, UJ ^ OOOOOOOO 〇〇〇〇〇— inch inch inch inch' ", r—Η Γ— ^ r— ^ r—H »— < r— ^» — < * — ♦ Baking paint processing endurance reduction rate (%) ^ C〇r ^ _〇CC〇CO ^ 〇 MD < > J 〇OC7NaNr ^ CD v— (t— * ί ~ '1.2 31.5 26.4 5.7 1.1 2.1 10.7 28.9 65.8 S g SI £ W tt rf ^ OOOOOOOOOOOOO ^ o ^ O 〇sss§§§§§ After painting) Elongation (%) ^ oiooqo'O ^ fOcor ^ r ^ c ^ i ^ r ^ ooo ^^ cKcKcKoo ^ r ^ cNC'i 〇lCN〇l (NCNoi < N < N〇J〇) corocomcnm Ο- ί \ 〇r— (t—tt—i CO 1 · oS od inch · inch 'inch · uS oi cn c ^ i cn cn cn ^ r < i endurance (N / min2) \ 〇i ~ * 〇〇v 〇unc〇CN inch CN — O inch inch inch 0 ^ 0〇0030 ^ 0 < 10 < 10 ^. ] ≪: ^ 一 — 〇〇 《y— ^ < ___ · Η > — «4 f lit — * i—4 ψ " 1” _ 一 _ — Product 1 > f——4 f __ 1 ψ 1 ^ Baking paint temperature ro 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 ○ ○ ○ 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 0]] 〇οι cn 〇3 cn 〇] N m 〇〇 < NN cq ooooooooo V〇inch inch V〇〇〇〇〇〇V〇 inch ο τ < ~ ιcn 〇〇 '~~ > 〇J. ≫ 〇) m Manufacturing characteristics of the material (before baking) Elongation (%) 26.5 26.5 26.5 26.5 28.5 28.6 28.8 28.5 28.6 28.8 28.6 30.4 30.4 31.0 31.2 31.0 19.8 28.6 31.0 33.3 34.1 34.1 8.8 8.8 8.8 Endurance (N / mm2) v〇r -Inch m ^ inch c *. Inch inch inch υη inch un inch inch ~~ ι— ο ο 〇T—H 1— «r—H r · — r—H t < r—H, n * r-< ι * π it < f— <, • 丨 — v 1 · f1,1,1 < g 3 s £ s S gg «s '? ® I, vr *', l / ·) 〇〇W, 〇 O vy) 〇〇〇iy ^ uo 〇 〇〇 ———— "vrS 1 · 1 · Ή 〆 二 〆ur: · cS 'ι / S vc5 cr; pppppoopp m cn rn c ^ \ mc ^ \ c n cn Temperature (° C) at the end of the temptation 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 C7 > ^ ^ 1 CO i " * ^ ·, '^} · r ^ 4 〇3 cn cn co m cn rn cn rn m cn cn cn m ooooooooo ί—i CO ί—1 H »— ♦ cn cn cn m 〇〇cn m Types of manufacturing methods < < < < < < < < < < < < < < < < < < < < P3PQPQPQCQ The type of Taiwan gold co r. cn cn m cn cn mm cn ro < r * tc ^ j co c ^ > 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇oooooooooooooooooo ro c ^ i cn ro γ * ^ ι cn c ^ imm cn mm ^ rn cm < < < < < < < < < < < < < < < < A3003 A3003 A3003 A3003 A3003 A3003 A3004 A3004 A3004 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Example U Example Γ 2 Example Π Example M Example 15 Example 16-'cn * · 〇o r- go 〇- \ Kuang Kuang Kuang s Kuang Kuang s Kuangs (Please read the precautions on the back before filling in this page) • Packing --- The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 > < 297 mm) -13- 1238201 A7 B7 V. Description of the invention (d [Effect of the invention] The following results can be understood from Table 1. (Please read the precautions on the back before filling this page) ( 1) It is clear from Comparative Example 9 and Comparative Example 6 that even if the materials are the same, the temperature at the end of rolling is the same and the plate thickness is the same. After hot rolling, cold rolling or intermediate annealing is followed. In the case of Comparative Example 6, even if the baking temperature is 260 ° C, the endurance after baking is less than 9 5 N / m m2 compared with Example 9. Then, even in the bending test, it is better than the implementation. It is easy to wrinkle in Example 9. This is because the structure of Comparative Example 6 is a series of processes after hot rolling, and further, it forms a recrystallized particle structure during baking paint treatment. It can be seen that even if baking paint treatment is used, The effectiveness of the production method of the present invention can be clarified by hot rolling under conditions that prevent the growth of the recrystallized particle structure. (2) The fibrous structure of the microstructure-based fibrous structure after the lacquer treatment of Example 9 shown in FIG. Sub grains are mixed. Next, the endurance and elongation after baking treatment are 122N / mm2 and 29.5%, respectively, and the decrease rate of endurance is 1.6% is very low. Wow. Lang Zhi & Cai / -1 Bureau Xiaogong 4 ^ Cooperative printed this, it is possible to obtain good results of the bending test. In addition, fibers are not recognized in the structure after the baking treatment in Comparative Example 8 shown in Fig. 5 The existence of an organization that is considered to be gross Tissue recrystallized particles. Next, endurance after baking treatment, although a high number of 160N / mm2 in Zhi, but an elongation of 5.2% is very small, and decreased endurance was 28 · 9% is very large. As a result, wrinkles and cracks in the bending test are further deteriorated. From this point of view, the effectiveness of the construction aluminum alloy material of the present invention having a coexisting fibrous structure and a fine secondary structure is very clear. Or the scale is applicable to the Chinese National Standard (CNS) A4 specification (210.X 297 mm) -14-1238201 ____ B7_ 5. Description of the invention (^ significant. (Please read the notes on the back before filling out this page) From the above description, you can understand clearly that the temperature at the end of rolling is managed at 290 to The hot-rolled material of A3003 material at 340 ° C will not grow and maintain the state of fibrous structure even after baking treatment, and maintain the fiber structure as the main body, and the endurance reduction rate is below 10%. Absolutely no less than 9 5 N / m m2, and elongation will be no less than 27%. Therefore, the aluminum alloy material of the present invention has good bending workability even after baking treatment, and is As a construction material that does not cause a decrease in endurance, its industrial price is very high. In addition, the above description is based on the temperature of baking paint treatment at 260 to 280 ° C. However, the aluminum alloy material for construction of the present invention can also be used for baking paint treatment at a temperature of 260 ° C or lower, and can be effectively used even in the range of 280 to 300 ° C. [Simplified description of the drawing] Section 1 Figure 2 shows a rough figure of the board material being bent to 90 °. Figure 2 shows a rough figure of the board material being bent to be sharp. Figure 3 is showing a notch plate being bent to 9 Figure 4 shows a schematic diagram of a plate material structure in Example 9. Figure 4 is a microscope picture of a plate material structure in Comparative Example 8. Figure 6 shows a plate material in a rolling direction and a rolling direction. It is a rough figure bent in the vertical direction. Figure 7 shows that the IrJ plot display does not point the plate material in parallel with the dairy direction. 1 ** ___________________________________________ This paper applies the Chinese National Standard (CNS) Λ4 specification ( 210X 297 mm) " '--- -15- 1238201 A7 B7 V. Description of the invention (Simplified figure bent in ^ direction. Component comparison table 1 Inscription alloy material 3 notch. (Please read the precautions on the back first) Fill this page Install ---

、1T 經濟部智悉財/i-局g(工消费合作狂印製 本纸張尺度適用中國國家標準(CNS ) Λ4規格(210Χ297公釐) -16-、 1T Ministry of Economic Affairs Zhisicai / i- Bureau g (printed by industry and consumer cooperation) This paper size is applicable to China National Standard (CNS) Λ4 specification (210 × 297 mm) -16-

Claims (1)

12382011238201 六、申請專利範圍 ίϋΐΐ替換本 第901 1 9385號專利申請案__|3^^1^ 中文申請專利範圍修正本 民國93年7月27日修正 1. 一種建築用鋁合金材料,其特徵爲: 係由下列條件組成: 屬於符合JIS規定的組成之Α 3 003 (相當於ASTM Β209 規定之3003)的鑄塊之熱軋材料; 厚度爲6.0mm以下; 在於溫度3 0 0 °C以下進行的烘漆處理後的組織,係由: 纖維組織、及面積比率在20%以下的再結晶組織所組成, 且’在於前述烘漆處理前之耐力爲l〇4N/mm2以上,而前 述烘漆處理後之耐力爲95N/mm2以上。 2 ·如申請專利範圍第1項之建築用鋁合金材料,其中在 於前述烘漆處理後之延伸率在27%以上。 3.如申請專利範圍第1項或第2項之建築用鋁合金材料, 其中前述烘漆處理時的溫度係在260至28CTC。 4·一種建築用鋁合金材料的製造方法,其特徵爲: 經濟部智慧財產局員工消費合作社印製 係由下列條件所形成: 對屬於符合]IS規定之A3003 (相當於ASTM B 209規定 之3003)的鑄塊實施均熱處理後,接著, 只要軋製結束時的溫度管理在2 90至34CTC,而厚度成 爲6·Omni以下地將鑄塊進行熱軋加工,即可將其提供實際使 用, 在於溫度300°C以下進行的烘漆處理後的組織,係由: 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公董) 1238201 A8 B8 C8 D8 經濟部智慧財產局員工消費合作社印製 六、申請專利範圍 纖維組織、及面積比率在20%以下的再結晶組織所組成, 且,在於前述烘漆處理前之耐力爲104N/mm2以上,而 前述烘漆處理後之耐力爲95N/mm2以上。 本紙張尺度適用中國國家榡準(CNS ) A4規格(210 X 297公釐) -2-Sixth, the scope of the patent application is replaced by the patent application No. 901 1 9385. __ | 3 ^^ 1 ^ The scope of the Chinese patent application is amended on July 27, 1993. 1. An aluminum alloy material for construction, which is characterized by: : It is composed of the following conditions: Hot rolled material of ingots of A 3 003 (equivalent to 3003 of ASTM B209) in accordance with the composition specified by JIS; the thickness is 6.0mm or less; the temperature is below 30 ° C The structure after the baking paint treatment is composed of: a fibrous structure and a recrystallized structure having an area ratio of less than 20%, and 'the endurance before the baking paint treatment is more than 104N / mm2, and the baking paint treatment The endurance is 95N / mm2 or more. 2 · If the aluminum alloy material for construction in item 1 of the scope of patent application, the elongation after the above baking treatment is above 27%. 3. For the aluminum alloy materials used in construction as claimed in item 1 or 2 of the patent scope, wherein the temperature during the aforementioned baking treatment is 260 to 28CTC. 4. A manufacturing method of aluminum alloy material for construction, characterized by: The printing of the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is formed by the following conditions: For A3003 that is in compliance with] IS (equivalent to 3003 of ASTM B 209) The ingot is subjected to soaking treatment, and then, as long as the temperature management at the end of rolling is 2 90 to 34 CTC and the thickness is 6 · Omni or less, the ingot can be hot-rolled to provide practical use. The organization after baking paint treatment at a temperature below 300 ° C is based on: This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 public directors) 1238201 A8 B8 C8 D8 System 6. The scope of patent application is composed of fibrous structure and recrystallized structure with an area ratio of less than 20%, and the endurance before the baking treatment is above 104N / mm2, and the endurance after the baking treatment is 95N / mm2 or more. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -2-
TW090119385A 2000-08-09 2001-08-08 Architectural aluminum alloy material and process for manufacturing the same TWI238201B (en)

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