TWI237671B - Dyeing and finishing of lyocell fabrics - Google Patents

Dyeing and finishing of lyocell fabrics Download PDF

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Publication number
TWI237671B
TWI237671B TW091112873A TW91112873A TWI237671B TW I237671 B TWI237671 B TW I237671B TW 091112873 A TW091112873 A TW 091112873A TW 91112873 A TW91112873 A TW 91112873A TW I237671 B TWI237671 B TW I237671B
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Taiwan
Prior art keywords
fabric
dyeing
acid
cloth
scope
Prior art date
Application number
TW091112873A
Other languages
Chinese (zh)
Inventor
James Martin Taylor
Geoffrey William Collins
Original Assignee
Tencel Ltd
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Publication date
Priority claimed from GB0114605A external-priority patent/GB0114605D0/en
Priority claimed from GB0201067A external-priority patent/GB0201067D0/en
Application filed by Tencel Ltd filed Critical Tencel Ltd
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Publication of TWI237671B publication Critical patent/TWI237671B/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/84Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A process for producing a dyed and finished lyocell fabric having a clean, soft-touch finish by carrying out the steps of dyeing, washing and drying a lyocell fabric using vigorous action such as by jet dyeing or rotary tumbling on the fabric in at least one of the steps so as to produce fibrillation on the surface of the fabric, is characterised in that, before the dyeing step is carried out, the fabric is evenly impregnated with an aqueous solution of an acid or acid donor and is then heat treated in a gaseous atmosphere to activate the action of the acid or acid donor. The dyed and finished fabric has a clean, soft-touch finish substantially free from visible crease marks normally produced on lyocell fabrics which have been subjected to vigorous action in dyeing and/or finishing.

Description

1237671 A7 五、發明説明(,) 方法本發明係有闕對-溶劑拉纺布料進行染色與整理的 料)==構:〜(溶_布 纖維槿:少有一部分含有或是由溶劑拉纺 可由溶劑拉由溶劑拉纺纖維構成,或 維為二,她素底的,比方説,棉、_ ^、聚醋及尼龍)的混合物組成。此外,該布料可 =不含溶劑拉纺纖維的拉纺絲,比方説,前述 〜其他纖軸拉纺絲或是這线_混合絲。 人、^劑拉纺纖維係以一纖維素在一有機溶劑與水的混 δ溶液通經—拉纺頭擠㈣—凝結池中而製成,這樣的 方法稱、、溶劑拉纺〃。這樣的方法在美國專利 US^U46,22!中有述,使用的溶劑係一叔胺ν_氧化 物,尤其是Ν-甲基氧氮雜環己燒Ν-氧化物溶劑。溶劑 拉纺纖維與其他人造纖維素纖維不同的是,其他人造纖 維係將纖維素置入到一可水溶的化學衍生物中,再將逭 化學衍生物的水溶液押出到一液池中,其將該押出物再 生成纖維素纖維。粘液纖維,包括高強度的粘液纖維就 是以這樣方法生產的。 本紙張尺度適用中國國家標準(CNS ) Α4規格(2丨0Χ297公釐) '4、 頁 訂 部 中 央 標 準 局 消 費 社 印 製 大家都知道,溶劑拉纺纖維 烈的染色轉理加王巾 、彳目_,就是在| 業者有著許多的方法。 /、。為了解決逭個問題, 較溫和的加工來進行溶劑就要用蝴 既’以開幅布料進行#打 、、、木色和整理,比戈 染色的布料進行樹脂表面:里:=用;交聯麵 後續的洗滌加工中起毛纖。等纖維以免在 維末端,這些長纖維末〜:二相對地較長的突出纖 形成的(即_的:、::毛;^ 會在該布制表面上^ .^是抑處理的話, 的,因此會有礙效果,通常是平光 纖化過η、、、ί觀。在另—方面,要是經處理在毛 則風剌:域較短的毛纖(_胃的、'二級毛纖化"), 被心曰勵。延些較短的毛纖創造出-種表面,其特徵 淨的%這樣説是因為它幾完全無毛絨效 曰?表面上有著較短的毛纖有著柔软觸感,因此被 存令疋柔軟觸感的表面”。當該較短的毛纖充份虫 後’、然後_料表賴雜觸義更_了,一 觸感的表面被稱作是、'桃皮觸感表面,。 671 671 A7 B7 發明説明(J) 迷,個^在W〇-A-95/30043專利中有 金屬鹽,其韻理使用—酸廳(比方説,— 交聯劑(比方~酸)的水溶液,E合著—理想的 期間形成的初級毛_Nf甲基樹脂),去除在染色加工 理作業中在㈣傳統的交聯處 另—_#w〇^成交賴賴條件下進行加熱。 中兮〜^ 97/30204專利中所述,在該專利 (比布料在染色之前使用一氧化劑的水溶液 預處理P。另二酸_過氧傾)在升條件下進行 、 另個實施例在英國專利PR Δ =溶劑拉纺她—強侧(_,硫酸木)色機’ :欣=處理3〇分鐘到12〇分鐘,然後將料水 =然後财_器中_純傾。這清 ,無法控制以產生—致的結果,而且這二=-種被帶入到全規模的商業運轉。 沒有- 有—種成功地用在商業運轉加工的 的後處理’該布料經㈣式43 纖唯来進仃處理。在—級毛纖化中產生的突出的 I、隹末姑這個後處理中藉著將—纖維素酵=的 ,到該布料而去除。宜人的二級 後 中形成的’比方説,在該染色加工本身^ 經濟部中央標準局員工消費合作社印製 1237671 五、發明説明(斗) 一 =)或在後賴麟及乾燥步驟,使用旋轉式滾筒機在 该布料的表面上產生—柔軟麟的表面。 纖維輯素處财錄在_毛聽巾產生在該布 2表面的長·末端是成功的,但是,·料成本以及 理2工時間來説’都是很昂貴的。此外,纖維素酵素處 在去除麵廣泛地使_水_噴職色加工中產生 宙可,的續痕通常不是很成功。在這些喷射染色機器 布料在繩狀形式裡受到劇烈的液體及機械的動 =會在摺線處產生較顯著的縣,而這些摺線本身 跡韻布料裡就是可見的續痕,有時叫作'繩狀痕 =色㈣料料可見__是_業上價 是普遍_,‘===理練1237671 A7 V. Description of the invention (,) Method The present invention is a material for dyeing and finishing of solvent-drawn fabrics. == Structure: ~ (Solution_cloth fiber hibiscus: A small part contains or is drawn by solvent. It can be composed of solvent-drawn fiber or solvent-drawn fiber. It is composed of a mixture of cotton, cotton, polyester, and polyester. In addition, the cloth can be drawn without solvent-drawn fibers, for example, the aforementioned ~ other fiber-drawn yarns or mixed yarns. The agent-drawing fiber is made by mixing a cellulose-organic solvent and water δ solution through a drawing-spinning head to extrude a coagulation tank. This method is called a solvent-drawn drawing card. Such a method is described in U.S. Patent No. U46,22 !, and the solvent used is a mono-tertiary amine ν-oxide, especially an N-methyloxazepine N-oxide solvent. The difference between solvent drawn fiber and other man-made cellulose fibers is that other man-made fibers put cellulose into a water-soluble chemical derivative, and then extrude the aqueous solution of the amidine chemical derivative into a liquid tank, which will This extrudate regenerates cellulose fibers. Mucus fibers, including high-strength mucus fibers, are produced in this way. This paper size applies the Chinese National Standard (CNS) A4 specification (2 丨 0 × 297 mm) '4. Page printing department Central Standards Bureau printed by the consumer agency Everyone knows that the solvent-drawn fiber is dyed with strong dyeing, plus a kerchief, and a head _, Is in | There are many ways for operators. / ,. In order to solve a problem, the milder processing of the solvent requires the use of a butterfly fabric with # open, cloth, wood color and finishing, Vigo dyed cloth for resin surface: lining: = use; cross-linking The noodles are fluffed during the subsequent washing process. Wait for the fibers to avoid the end of the dimension. These long fibers are formed by two relatively long protruding fibers (that is, _ :::: hair; ^ will be on the cloth surface. Therefore, it will have a detrimental effect, and it is usually flat fiber optics, η ,, and ί. In the other aspect, if treated in the hair, then wind: the shorter hair fibers (_ stomach, 'secondary hair fibers "Inspired by the heart. Some shorter hair fibers create a kind of surface, which has a net characteristic of%. This is because it has almost no fluff effect. It has short hair fibers on the surface. Soft touch, so it ’s stored to make the soft touch surface. ”When the shorter hair fibers are full of insects, and then _ the material table is more complex, the one-touch surface is called "'Peach peel touch surface.' 671 671 A7 B7 Description of the invention (J) Fans, there are metal salts in the WO-A-95 / 30043 patent, its rhyme uses-acid hall (for example,-cross Aqueous solution (such as ~ acid) in aqueous solution, co-authored by E—the primary wool_Nf methyl resin formed during the ideal period), removed in the traditional cross-linking place during the dyeing process —_ # w〇 ^ The heating depends on the conditions. Zhongxi ~ ^ 97/30204 patent, in this patent (preparation of fabrics using an oxidizing agent aqueous solution before dyeing P. Another acid_peroxy Dip) is performed under rising conditions, another example is in the British patent PR Δ = solvent drawing spinning-strong side (_, sulfate wood) color machine ': Xin = processing 30 minutes to 120 minutes, and then feed water = Then the financial device is pure. This is uncontrollable to produce consistent results, and these two =-species are brought into the full-scale commercial operation. No-there are-successfully used in commercial operation processing The post-treatment of the fabric is processed by the type 43 fiber. The outstanding I and 隹 attrition produced in the first-grade wool fibrillation are processed by the cellulose fermentation. The cloth is removed. The pleasant second-level post is formed, for example, in the dyeing process itself ^ printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, printed 1237671 V. Description of the invention (bucket) A =) or later Lai Lin and drying Step, using a rotary drum machine to produce on the surface of the cloth-soft and soft The surface of the fiber is recorded in the _ woolen towel produced on the long and end of the surface of the cloth is successful, but the material cost and processing time are 'very expensive. In addition, cellulose Enzyme removal widely causes _water_spraying color processing to produce scorch, and the repetitive marks are usually not very successful. In these jet dyeing machine cloths, the liquid and mechanical movements in the rope form are severe. Significant counties are generated at the polylines, and these polylines themselves are visible continuation marks in the rhyme cloth, sometimes called 'rope marks = colored materials are visible__YES_Industry price is common _,' == = Practice

的溶本二以生產—經染色的並纖理 的整理,其方“:法,該布料有著乾淨的、觸感柔軟 乾燥的步驟時,在這=;:,、_及 的至乂 一步驟使用劇烈的 --------^_W^II (請先閱讀背面之注意事項再填寫本頁)The solution is produced by dyeing-dyed and fibrous finishing, the method ": method, when the cloth has a clean, soft and dry touch, in this =;: ,, and to the first step Use violently -------- ^ _ W ^ II (Please read the precautions on the back before filling this page)

、1T 冰張尺度適财 ml fnv 210X297公釐)〜7、 1237671 Λ7 五、發明説明(左) 一〜 =’致使在布料的表面上產生毛纖化;其特徵為 ==步驟之前’該布料經以—酸或酸供與體的水溶 該酸或酸=1然再在—氣流環境中經熱處理,以激活 布料古'、/、體的反應。藉此,該經染色的並經整理的 痕,2乾淨的、觸感柔軟的表面、幾完全無可見_ 及整理 在染色及/或洗游及/或乾燥加工期間施加到布 作主要是為了所進行的特別之加工功能而需要 染㈣Γί ’在―噴射染錢中或在—成錢的滾筒式 =杨染色時,或在旋轉滚筒式機器中(比方説, ,洗衣機或滚筒式乾衣機)進行洗滌或乾燥時, =劇烈的動作。這劇烈的動作也會在溶劑拉纺布料 產生毛纖化’要不是本發明的方法所進行的控制,會 :料的表面造成毛髮狀的效果,同時也會有形成前述 可見的縐痕的可能。 本發明的方法_生產出經染色的溶雜纺布料其 劇烈的達式加工步驟,比方説,㈣染色或旋轉滚 =加工《後,有著乾淨的、觸感柔軟的表面,尤其是桃 觸感的表面,完全無可見的續痕,這樣的能力是有著 f大的商業上的重要性。這表示,該布料能夠在現有的 設備上使用正常的加工步驟毋需更多的作業上的注意或 1237671 經濟部中央標準局員工消費合作社印製 Μ Β7 五、發明説明(() 一· 是更多的時關可進行加:^舉侧^使用—噴射染 色機-個染健_期是六财時或不到六個小時。適 合的傳統式水__射染韻包括ThiesE_ft以及 Hisaka Circular CUT-SL等機器。空氣嗔射染色機也可以 使用’這些機器也可以在布料上施加劇烈的動作。適合 的空氣式噴射染色機包括Thies Ai—Thies Luft, 1T ice scale suitable for ml ml fnv 210X297 mm) ~ 7, 1237671 Λ7 V. Description of the invention (left) One ~ = 'Causes fibrillation on the surface of the fabric; its characteristic is = = before the step' the fabric After dissolving the acid or acid with the water of the acid or the acid donor, the acid or the acid is then heat-treated in an air flow environment to activate the reaction of the cloth. With this, the dyed and finished marks, 2 clean, soft-touch surfaces, almost completely invisible _ and finishing is applied to the cloth during dyeing and / or washing and / or drying processes mainly for the purpose of The special processing functions required require dyeing in the 'jet dyeing' or in the 'money-drum type = yang dyeing, or in a rotary drum type machine (for example, a washing machine or a tumble dryer) ) When washing or drying, = vigorous action. This drastic action will also cause hair fibrillation in the solvent-drawn fabric. If it were not controlled by the method of the present invention, the surface of the material will cause a hair-like effect, and there may be the possibility of forming the aforementioned visible crease marks . The method of the present invention _ produces a dyed lyocell fabric which has a drastic Darth processing step, for example, ㈣ dyeing or rotating roll = after processing, it has a clean, soft-touch surface, especially peach touch. On the surface, there are no visible continuation marks, and this ability is of great commercial importance. This means that the fabric can be used in existing equipment with normal processing steps without the need for additional operational attention or 1237671 printed by the Central Consumers Bureau of the Ministry of Economic Affairs' Consumer Cooperatives. Β7 V. Description of the invention (() a. Is more More time can be added: ^ lift side ^ use-jet dyeing machine-a dyeing health _ period is six financial hours or less than six hours. Suitable traditional water _ _ shooting dyeing rhyme including ThiesE_ft and Hisaka Circular CUT -SL and other machines. Air jet dyeing machines can also be used. 'These machines can also exert vigorous action on the fabric. Suitable air jet dyeing machines include Thies Ai—Thies Luft

Roto ^ Hisaka AJ-1 ^ Krantz Aerodye U A Then AFS f 1 器。 用在纖維素布料的餘染料及染料财可用在本發 月的方法巾’包括以直接染料、還原染料、硫化染料及 反應性染料為底的染料。 、々除了能夠應用到整匹平織的或針織的溶劑拉纺布 料’、本發_方法也可用在以_拉纺布料製成的塊料 :成染色及整理。這類成衣可能會有著可見的縐 j ’足是由於麵m的加j:顧(比錢,滚筒染色或 厘式废筒或滚筒乾燥)局部摩擦造成的,但是,如果這 類f农經以本㈣的方法加王則這可見的紐可大大地 遯免。 以酸4酸供與體的溶液之賴以紐後的乾燥及熱 骤可在_劑拉纺布料裁剪成塊料及製作成衣之 ι/τ °然而’它也可以在裁剪成塊料或製作成衣之後 讀到塊料或成衣。 (請先閱讀背面之注意事項再填寫本頁) 、1ΤRoto ^ Hisaka AJ-1 ^ Krantz Aerodye U A Then AFS f 1 device. Residual dyes and dyestuffs used in cellulosic cloths can be used in this month's method. The towels include dyes based on direct dyes, vat dyes, sulfur dyes, and reactive dyes. In addition to being able to be applied to the entire flat knitted or knitted solvent woven fabric ’, this method can also be used for lumps made of woven fabric: dyeing and finishing. This type of clothing may have a visible crepe j 'foot due to the surface m plus j: Gu (compared to money, roller dyeing or centimeter waste barrel or drum drying) caused by local friction, but if this type of agricultural economy The Benjamin method and the king can greatly avoid this new button. After the solution of the donor with acid 4 acid is dried and heated, the fabric can be cut into pieces and made into garments. However, it can also be cut into pieces or made into garments. Then read about blocks or garments. (Please read the notes on the back before filling out this page) 、 1Τ

1237671 A7 五 、發明説明(7) 可見的續痕之避免是本發日麟方贿帶來的主要好 處,但是,我們也發現,在製成品溶劑拉纺布料上乾淨 的由柔軟f刺表面多対以受聰護免於在後續的加 =?,摩擦損害。尤其,以該經染色的: 製成的產印,比万説,成衣或其他塊料,在 洗舰水之後仍能保持其乾淨的、柔軟_的表面Γ _或酸供與_溶液最好是水性溶液。該布料可 :使=傳Γ用來將液體塗怖到布料的技術,比方 說’以減万式將這溶液均勾地浸潰。整匹的布料可以 開幅万式通㈣水歸液的—拍打浴池 的沾遥度麵布料重量的65刺8〇%。 水減 塊料成品’ tb方説成衣可以在—容器中 一滾筒式洗衣機中)浸泡在該水溶液中。 p 頭酸或酸供與體最好為—用在纺織品整理加工中作 =脂:媒的類別之弱酸。適合的酸或酸供與體包括 :酸=説,棒橡酸以及酒石酸以及路易斯酸。氯 二=:、氯化鋅、氟硼酸鋅以及硝酸鋅為合適的 =_。另外’也可使用這些成份的兩種或兩 種义上_合物,事實上,龍表 ,有時在他們的觸媒配方中使用混合物= ΓΐΐΓ本發明的方法中的,子是― 心國巴斯夫公司(BASF)的註冊商標)、_種酸觸 本紙張尺度適用中國國~ ---—— •、竿(〇«)八4規格(210'/297公釐) 麵濟部中央#準局員工^費合作衩印製 上237671 媒J有氯化鎂和氟硼酸鋅的混合物。 之酸7==最Γ的溶液濃度視所使用的特定 免布料受針定’使用高活性·宜钱濃度以避 度。對市」:的酸損害,使用較低活性原料宜較高濃 的濃度,二造商會建議用在樹脂表面處理加工 中。 、口兑來,⑨辆濃度可財本㈣的方法 升t ’有_雜觸職可在水溶射大約每公 升0公克’舉個例説,如果使用檸檬酸,大约每公 求較克。較低活性的酸類或酸供與體可涉入或要 公同遭度,舉個例説,在水溶液中可達大約每公升4〇 這控過2、要_高濃度在所有場合中顧避免,因為 C對布料造成不宜的酸損害。另外,避免 ;、的過_度也可iif雜化學^的使用。 該^浸潰的布料經在—氣流環境中(比方説,在— ;=烤箱中)熱處理。空氣構成該較佳的氣流環境。 曰拓。t熱處理之前在—個綱乾燥步射經乾燥,但 ::燥只是熱處理步驟的最初步驟。該溶劑拉纺布料 =是以關方式經處理,比方説,在―鋪機上通經 口熱烤箱或加熱室。使用在熱處理中的氣流環境的溫 =作取理想賴擇以有效職賴使職定的酸或酸 _、、體的活性。該熱處理作用在激活氣相_以與該溶 服_維交互反應。通常,合適的溫度在·。c到22〇 準(CNS ) A4規格(210X297公釐)1237671 A7 V. Description of the invention (7) The avoidance of visible traces is the main benefit brought by Linfang ’s bribes today. However, we also found that on solvent-drawn fabrics of finished products, the surface is cleaned by soft f I was protected by Satoshi from subsequent damages. In particular, with this dyed: printed product, Biwan said that garments or other pieces can still maintain their clean, soft surface after washing the water. The acid or solution is best. It is an aqueous solution. The cloth can be used to transfer the liquid to the cloth, for example, the solution can be submerged in a subtle manner. The whole piece of cloth can be opened in a wide range of water-liquid return mode-flapping the bath's dip-knitting surface with 65% 80% of the weight of the cloth. The water-reduced block finished product 'tb can be said that the garments can be immersed in the aqueous solution in a container-a drum-type washing machine). p-head acid or acid donor is best-weak acids used in textile finishing processing as = lipid: vehicle type. Suitable acids or acid donors include: acid = say, clavulanic acid as well as tartaric acid and Lewis acid. Chlorine di = :, zinc chloride, zinc fluoborate and zinc nitrate are suitable = _. In addition, two or two synonymous compounds of these ingredients can also be used. In fact, Long Tables sometimes use mixtures in their catalyst formulations = ΓΐΐΓ In the method of the present invention, the child is ― Heartland (Registered trademark of BASF), _ a kind of acid paper size applicable to China ~ ---—— •, pole (〇 «) 8 4 specifications (210 '/ 297 mm) 面 济 部 中心 # 准Bureau staff ^ cooperated to print 237671 media J has a mixture of magnesium chloride and zinc fluoborate. The acid concentration of the acid 7 == maximum Γ depends on the specific solution used. Needless to say, use a high activity and low concentration to avoid it. "For the city": acid damage, the use of lower active raw materials should be higher concentration, the second manufacturer will be recommended for resin surface treatment. According to the word, the concentration of the vehicle can be reduced. The method can be used to dissolve and shoot in water at about 0 grams per liter. For example, if citric acid is used, it is about grams per gram. Lower activity acids or acid donors can be involved or shared. For example, it can reach about 40 per liter in aqueous solution. This is controlled. 2. High concentration should be avoided in all occasions. , Because C caused unfavorable acid damage to the cloth. In addition, avoid the excessive degree of;, can also be used if iif heterogeneous chemical ^. The impregnated cloth is heat-treated in an air-flow environment (for example, in an oven;). Air constitutes this preferred airflow environment. Said extension. Before the heat treatment, drying is performed in a drying step, but :: drying is only the initial step of the heat treatment step. The solvent-drawn fabric = is processed in a closed manner, for example, through a mouth heating oven or heating chamber on the machine. The temperature of the airflow environment used in the heat treatment = the ideal choice depends on the effective role of the acid or acid, the activity of the body. The heat treatment acts on activating the gas phase to interact with the melting dimension. Normally, the proper temperature is at ·. c to 22〇 standard (CNS) A4 specifications (210X297 mm)

12376711237671

經濟部中央標準局員工消費合作社印製 1237671 A7 五、發明説明(/U ) 去除剩餘的苛性鈉。 在經洗滌以去除所有未經上染的染料之後,該經染 色的布料可經給以傳統的整理處理,包括(比方説)藉 著一傳統的浸軋作業來施給一柔軟整理劑。這可在染色 及洗滌加工之後進行,而毋需在中間對該布料進行任何 的乾燥。如果有需要進行一溼式滚筒處理以作成柔軟觸 感的表面,這可以在染色之後在一旋轉滚筒機中進行, 可以與任何柔軟表面處理一起進行或是在其後進行。和 染色步驟一樣,該經處理的溶劑拉纺布料仍保持完全無 可見的縐痕損失,這縐痕若不經柔軟加工會發生在溼式 滚筒作業期間。該經處理的布料可再經最後的乾燥,比 方説,在一滾筒乾燥機中進行。 至此,從某一種意義來看,本發明提供了一種用以 對一平織的溶劑拉纺布料(其已經退漿)染色以及整理 的方法,該方法包括了下列步驟,其順序如下: 1) 藉著使用一水性退漿浴池,去除該布料的漿料; 2) 將一酸或酸供與體的水溶液浸軋到該布料上; 3) 將該布料乾燥以及熱處理,比方説,在120°C到 220°C之間,最好在140°C到200°C之間; 4) 將該布料染色;以及 5) 將該布料進行滾筒乾燥。 茲以下述實施例對本發明作一説明。在所有實施例 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ297公釐) 〜f今、 (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs, 1237671 A7 V. Description of Invention (/ U) Remove the remaining caustic soda. After being washed to remove all undyed dyes, the dyed fabric may be subjected to a conventional finishing process, including, for example, a soft finishing agent by a conventional padding operation. This can be done after dyeing and washing without any drying of the fabric in the middle. If there is a need for a wet roller treatment to make a soft-touch surface, this can be done in a rotary drum machine after dyeing, can be done with any soft surface treatment or afterwards. As with the dyeing step, the treated solvent-drawn fabric remains completely free of visible crepe loss, which would occur during wet drum operations without softening. The treated fabric may be finally dried, for example, in a tumble dryer. So far, in a certain sense, the present invention provides a method for dyeing and finishing a plain knitted solvent-drawn fabric (which has been desizing). The method includes the following steps in the following order: 1) borrow Use an aqueous desizing bath to remove the slurry of the cloth; 2) pad the cloth with an acid or an aqueous solution of an acid donor; 3) dry and heat treat the cloth, for example, at 120 ° C To 220 ° C, preferably 140 ° C to 200 ° C; 4) dye the cloth; and 5) tumble dry the cloth. The invention is illustrated by the following examples. In all embodiments, this paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) ~ f today, (Please read the precautions on the back before filling this page)

、1T 1237671 A7 五、發明説明(I丨1T 1237671 A7 V. Description of the invention (I 丨

Tencel 實施例 1斜紋織法結構織成單 gsm (每平方公尺公克數)的平織布料=重里200 =開:_洗潔精及碳酸鈉水性淨洗:=Tencel Example 1 Twill weave structure woven into a single gsm (grams per square meter) plain weave fabric = Zhongli 200 = open: _ detergent and sodium carbonate aqueous cleaning: =

㈣刪—拉幅機上 該經退漿的布料再叙 M 上以就溫度的空氣進行熱處理5 =: 了二二Thles E_ft嘴射染色機中進行的。除 本紙張尺度㈣ —从' (請先閱讀背面之注意事項再填寫本頁)Deletion-Tentering machine The desizing cloth is re-classified on M to be heat-treated with air at a temperature of 5 =: It was performed in a two-thousand Thles E_ft nozzle dyeing machine. Except this paper size ㈣ —From '(Please read the notes on the back before filling this page)

、1T • I - I —1 - -i ill— 1237671 五 A7 發明説明(必) P=nN〇vyH孤海軍藍染料,從布料重量的百 刀之四(Procicm為Dystar AG的註册商標) 硫酸鈉 60g/l 純鹼 20g/l 該經染色的布料再㈣—柔軟整理心—㈣ (Edumne為Umqema公司的註冊商標)處理, 從布料重量的百分之二,從一, … 德MO 生輕在MG溫度施 佈,然後再在一布料繩轉蘢中加以轉 ^經染色的比對樣本布料有著平光的表面外觀,帶 有務面的«,這是@她毛編^許 的特徵所致,而且因噴射染色機的摩擦動㈣加工的Ϊ 狀布料造成可見_鍾跡而蝴其外觀。 與此呈顯著對_,該贿財發_方法處理的 布料有著料的、乾淨的表面外觀,展現出料染色的, 无份地形成有如桃皮觸感的表面特徵的一柔軟觸感表 面,且幾完全無可見的縐痕。 靠 實施例2 I 重覆㈣例1的步驟’經處理過的以及比對樣本均 | 〶用同樣的布料,但浸潰步驟中使用的檸檬酸以 | c〇NDENSOLFB取代,漠度騎公升2G公克,這是— | 種氯化鎂和氟麵鋅的混合物,銷f作為纺織品的_, 1T • I-I —1--i ill — 1237671 Five A7 invention description (required) P = nNovyH lone navy blue dye, from the weight of the cloth to four hundred (Procicm is a registered trademark of Dystar AG) sodium sulfate 60g / l Soda ash 20g / l The dyed fabric is then ㈣—soft finishing heart ㈣ E (Edumne is a registered trademark of Umqema company) treatment, from 2% of the weight of the fabric, from one,… The temperature is applied, and then the cloth is transferred in a cloth rope. ^ The dyed comparison sample cloth has a flat surface appearance with a work surface «, which is due to the characteristics of @ 她 毛 编 ^ 许, and The 布料 -shaped cloth processed by the friction of the jet dyeing machine causes visible appearance and appearance. This is a significant counterpoint to this. The cloth treated by this bribery method has a material, clean surface appearance, exhibits a material that is dyed, and forms a soft tactile surface with surface characteristics like the touch of peach skin. And almost no visible creases. By Example 2 I Repeat the procedure of Example 1 'The treated and compared samples are all | 〶 Use the same cloth, but the citric acid used in the impregnation step is replaced by | c〇NDENSOLFB, and the degree of inertia is 2G Grams, this is — | a mixture of magnesium chloride and zinc fluoride, selling f as a textile

---------β^— — (請先閲讀背面之注意事項再填寫本頁) 零 —1 = 1 、π -fci - A^767l A7 B7 (CONDENSOLFB為德國巴斯夫公 五、發明説明(e) 表面處理的酸觸媒 司的註册商標)。 著由平光的外觀帶 丨感表面,表面乾 該叙處賴/ ^導賴不纟之丨賴'碰。反之, 淨::里的布料則有著吸引人的桃皮觸 兀全無可見的縐痕。 iMMj 經處理的幅。該布料的—部份保留作為-身 -浸二中=,使一^^ 化鎂六氫化合物及每公升含了公升12公克氯 浸潰的布料再經放到—拉幅機上劑。孩經 度乾燥,再在空氣中以喊:氣中以⑽温 該經處理的布料以及該比::仃45秒的熱處理。 的退漿、染色、柔化以及=布料再個別經下列 二==:清洗,_在: 方’但用量是從布料重量的百以=染液配 、發明説明(外) 該經染色的布料經以_柔軟處理爾,Sand0perm_ (='為aariant公司的註册商標),用 科重虿的百分之-,外丄u 理,妖_2— 水性浴液,在4G°C溫度進行處 行__。細eaianiAir_树驗筒機中造 1 經純㈣_林财軒光_--------- β ^ — — (Please read the notes on the back before filling in this page) Zero -1 = 1 π -fci-A ^ 767l A7 B7 (CONDENSOLFB is the fifth invention of BASF in Germany. Note (e) Registered trademark of Acid Catalyst Division of Surface Treatment). The appearance of the flat light has a sensational surface, and the surface is dry. On the contrary, the net :: fabric has attractive peach peel and no visible creases. iMMj processed width. The-part of the cloth is kept as -body-immersed in two =, so that ^^ magnesium hexahydrogen compound and 12 grams of chlorine per liter impregnated cloth is put on the stenter. The child is dry, and then shouts in the air: the temperature of the treated fabric in the air and the heat treatment of the ratio :: 45 seconds. Desizing, dyeing, softening, and then the fabric is individually subjected to the following two ==: washing, _in: square 'but the amount is from 100% of the weight of the fabric = dye solution, invention description (outside) the dyed fabric After _softening treatment, Sand0perm_ (= 'is a registered trademark of aariant company), using the weight of Kezhong-%, the external health management, demon_2 — water-based bath, perform at 4G ° C temperature __.细 eaianiAir_ Tree inspection machine made 1 warp ㈣_ 林 财 轩 光 _

=:毛纖化特徵的突出的長毛纖。該經依照J =乾淨的外觀,完全無毛髮狀效果,以及完全二=: Prominent long-haired fibers with fibrillation characteristics. The classics follow J = clean appearance, completely hairless effect, and completely two

見的績痕。 兀U μμμλ =劑拉纺布料,以含百分之 的絲’以2X1#紋織法結構織成基本重量^ 的布料。該布料經以開幅方式使用—含有 _碳酸_水溶液,在姚溫度退 圓二 形加熱筒上以hxtc溫度乾燥。’,、、趣在圓揭 汾=退浆並經乾燥的布料再經以In— 二液拍打’溶液濃度每公升18公克,拍淫度百分之八 Condensol Μ為德國巴斯夫公司的註冊商 曰 從重量百分之三十二的氯化鎂的溶液。該_&= 料經以1就溫餘燥,然後再在—拉_上以1贼斤 1237671 A7 B7 五、發明説明(& 度熱處理45秒鐘。 該經處理的布料再經裁剪成有形狀的塊片,這㈣ 片再經缝到-起以製作襯衫。這些襯衫在—開袋式 Tupesa E_e 25触染钱巾制_泳移染色方法 染色’用下賴染料配方’最終上染溫度是_ : PiOcionH-EXL從布料重量的百分之二 硫酸鈉 40g/l 碳酸鈉 15g/l 該等經染色的襯衫經以清水清洗,然後再以一柔軟 劑處理’使用Edimine CSA,從布料重量的百分之二 從一水性浴在桃溫度躲。__再經__’。 該士等經染色及麵的师有著吸引人的桃皮觸感表 面,元全無可見的縐痕,以及長的毛纖。 實施例5 (請先閱讀背面之注意事項再填寫本頁) ,ιτ 經濟部中央標準局員工消費合作社印裝 如實施例4所述的—溶劑拉纺平織布料如 所示的方式退魏及乾燥,然後分朗批,―批叫 對樣本,-批絲依照本發日錢行處理。後者= Condensol M溶液浸潰,然後如實施例4 燥及熱處理。 所不万式乾 該經處理的雜以及輯#林料各 胃-冷_技術使用RemaZGi乙稀?活性染料(^二 本紙張尺度適用中國210X297,JtSee the marks. Wu U μμμλ = agent-drawn fabric, weaving a fabric with a basis weight ^ with a 2X1 # weave structure with a percentage of silk ’. The fabric was used in an open-width manner—containing an aqueous solution of _carbonic acid_, and dried on a Yao-shaped round-shaped heating cylinder at hxtc. ',,, fun in the round Jiefen = desizing and drying the cloth and then beat with In-two-liquid' solution concentration of 18 grams per liter, 8 percent sexuality Condensol Μ is the registrar of BASF, Germany From a solution of thirty-two percent magnesium chloride. The _ & = material is warmed to dryness by 1 and then on the pull-pull with 1 thief 1237671 A7 B7 5. Description of the invention (& degree heat treatment for 45 seconds. The treated fabric is then cut into There are shaped pieces, and this piece is stitched to-to make shirts. These shirts are made in-open-bag Tupesa E_e 25 touch-stained money towel _ swimming dyeing method dyed 'with the next dye formula' and finally dyed The temperature is _: PiOcionH-EXL from the weight of the cloth is 40% sodium disulfate 40g / l sodium carbonate 15g / l These dyed shirts are washed with water and then treated with a softener 'using Edimine CSA, from the cloth Two percent of the weight hides from a water-based bath at peach temperature. __ 再 经 __ '. The dyed and noodles of this scholar have attractive peach skin touch surface, no visible crepe marks, And long hair fibers. Example 5 (Please read the notes on the back before filling out this page), ιτ The printing of solvent-coated plain woven fabrics as described in Example 4 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Way back to Wei and dry, and then batch by batch, ― batch called the sample,-batch Siyi The hair is processed at the same time. The latter is immersed in Condensol M solution, and then dried and heat-treated as in Example 4. Therefore, the processed impurities and series #forest material each stomach-cold_technology use RemaZGi ethylene? Reactive dyes (^ 2 paper sizes apply to China 210X297, Jt

I i .......I- -I 1237671 A7 ______B7 五、發明説明(4) 為Dystar公司的註冊商標)染色。染色浴液為: Remazol 亮黃 GL l〇g/l Remazol 紅 RB 20 g/1 Remazol海軍藍GG 40g/l 矽酸鈉(38Be) 130 g/1 苛性鈉(38 Be) 38.5 g/1 Leonil SRP (沾淫劑) 3.0 g/1 該染液藉浸軋方式以百分之七十鋪賴度施佈, 經濟部中央標準局員工消費合作社印製 在施佈染液之縣染色的布料財聚乙烯薄膜内卷餐八 個小時。 | 同樣以開幅方式在清水洗游及乾燥之後,該二布料 均經看出表面光縣jl|JL幾完全無毛雜目為使用的是 小心的,非摩擦的沾溼加工。 然後’頭二布料再各自裁剪成樣塊,二組樣槐缝製 成二組襯衫,一組以經處理的布料缝製,另一組以比對 樣本布料缝製。該二組襯衫經在Tupesa Eeodye 25開袋十 式洗衣機中使用EdunineCSA (從布料重量的百分之一 水溶液在60 C溫度洗潜並軟化4〇分鐘。 以比對樣本布料縫製的襯衫有著平光的、毛髮狀的 表面,以及可見_痕,而以經處理的布_製的_ 有著乾淨的、均匀的桃皮觸感的表面。 ’1 ------------ C請先閲讀背面之注意事項再填寫本頁) -、_π 本紙張尺度適用中國國家榡準(CNS ) A4規格(210X297公釐) 經濟部中央標準局員工消費合作社印製 1237671 五、發明説明(η £Μίίβ -溶紙纺布料,以㈣ 溶劑拉纺纖維及棉纖維的絲 ^^比的 本重量加_的布料。該布料^ ^織絲構成基 子洗潔精與苛性納的水性溶液中在離 :氧:氯、苛性納以及過氧化物穩定二中在: =:、=就溫度以蒸汽蒸8分鐘,_清: 凊冼再在圚筒乾燥機中乾燥。 水 該布料再經分別剪成一長段用 段用來依照本義的方法_處理長 化鎂六氫化物的水溶液浸軋 拉f 八十,在119°Cia度乾燥,然後再在一 拉機上W not溫賴處理3分鐘。 該比對樣本與_處理的布料經以下樣方法染 色及整理: 染^是在-Thies LUft-R0t0 <t射染色機中進行的,使 用的是與#_ 1中所_關染料配方與步驟,接著 以清水清洗,與實施例1中所述的同樣方式進行柔軟處 义及在 Thies Rototumbler滚筒中乾燥。 該曰比對樣本有著平光的、毛髮狀的表面,就商業上 來看是不宜人的。該經處理的布料有著吸引人的桃皮觸 感表面,完全無可見的總痕,以及有著乾淨的、均 考------ C靖先閲讀背面之注意事冢真—Τ)I i ......... I- -I 1237671 A7 ______B7 V. Description of Invention (4) is a registered trademark of Dystar Company) Dyeing. The dyeing bath is: Remazol Bright Yellow GL 10g / l Remazol Red RB 20 g / 1 Remazol Navy Blue GG 40g / l Sodium Silicate (38Be) 130 g / 1 Caustic Sodium (38 Be) 38.5 g / 1 Leonil SRP (Staining agent) 3.0 g / 1 The dyeing solution was applied at 70% of the degree by padding. The employee cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed the dyed cloth in the county where the dyeing solution was applied. Roll meals in vinyl film for eight hours. In the same way, after washing and drying in clean water, the two fabrics have been found that the surface of Guangxian County jl | JL is almost completely hairless. It is a careful, non-friction wet processing. Then the first two pieces of fabric are cut into pieces, and two sets of samples are sewn into two sets of shirts, one is made with treated fabric, and the other is made with a comparison sample fabric. The two sets of shirts were washed and softened for 40 minutes at 60 ° C using EdunineCSA in a Tupesa Eeodye 25 open-bag ten-type washing machine. The shirts sewn on the sample fabrics had a flat and smooth appearance. , Hair-like surface, and visible _ marks, and the surface made of treated cloth _ has a clean, uniform peach skin touch surface. '1 ------------ CPlease (Please read the notes on the back before filling this page)-, _π This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 1237671 V. Invention Description (η £ Μίίβ-Solvent paper-spun fabric, a fabric with a weight ratio of ^^ to draw the fiber ^^ of the fiber and cotton fiber. The cloth ^ ^ woven silk constitutes a base detergent and an aqueous solution of caustic soda in: Oxygen: Chlorine, Caustic Soda and Peroxide Stabilizer: in: = :, = steam for 8 minutes depending on the temperature, _ clear: 凊 冼 and then dried in a drum dryer. The cloth is then cut into lengths Duan Duan is used in accordance with the original meaning of the method The aqueous solution of the material was drawn and rolled at 80 ° C, dried at 119 ° Cia, and then treated for 3 minutes on a drawing machine. The comparison sample and the treated fabric were dyed and finished by the following method: dyeing ^ It was carried out in -Thies LUft-R0t0 < t-ray dyeing machine, using the formula and steps of dyes as described in #_ 1_, followed by washing with water, in the same manner as described in Example 1. Soft and dry in a Thies Rototumbler roller. The comparison sample has a flat, hair-like surface, which is uncomfortable from a commercial standpoint. The treated fabric has an attractive peach skin touch surface, completely There are no visible total marks, and there is a clean, uniform test ------- C Jingxian read the note on the back of the grave-T)

1237671 五、發明説明(β 外觀。1237671 V. Description of Invention (β Appearance.

經濟部中央標準局員工消費合作社印製 MM&1 ==餘__六氳化物== 6中所獅步難驗 ^::有麵氯化鎂六氫化物:= 及整二Hr—部份經保留用以依照τ述的染色 處而一部份先經在-無鏈條式絲光 溶液==賴百分之十-的苛性鈉的水性 理樣料^對樣本、經酸處理的以及經酸處 哺林㈣關步雜色及整理。染色是 咖ft噴射染色機裡,使用與實施例1中ί ^、问樣染色浴液配方及步驟,接著以清水沖洗,使用 :,油2707 (依布料重量的 :::繼’並且在-一-二 嚴睛機中滾動乾燥。 竹 對足二種雜進行觀齡,比難本布料在其 面上有平光肖初起钱,並且有著許多看得 條的續痕。該經處 冰張尺度適) A4規格 -- (請先閱讀背面之注意事項再填寫本頁} 、11 _ ·_ I -- m —I— II 11 · 1237671 A7 五、發明説明(吖) 且有著吸引人的乾淨的、桃皮觸感的整理。它的顏色比 起比對樣本布料的顏色稍微淡白些。該經整理過並且經 苛性化的布料有著同樣乾淨的、桃皮觸感的整理,完全 無可看見的縐痕,但是相對於該未經苛性化處理的布料 及比對樣本布料,有著更佳的上染效果。 (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs MM & 1 == 余 __ 六六 化 物 == 6 Chinese Institute of Lion Step difficult to test ^ :: surface magnesium chloride hexahydride: = and two Hr-part of the reservation A part of the aqueous solution of caustic soda which was first treated in the dyeing place according to τ-chainless mercerizing solution == ten percent-caustic soda ^ For samples, acid-treated and acid-treated Lin Yaoguan step mottled and finishing. The dyeing is carried out in a jet dyeing machine, using the formula and steps of the sample dyeing bath solution in Example 1, followed by rinsing with water, using :, oil 2707 (according to the weight of the cloth :::: 'and in- Rolling and drying in one-two rigorous eyes machine. Bamboo observes the age of two kinds of miscellaneous materials. Compared with the hard cloth, it has a flat surface on the surface and has many continuation marks. The place is frozen. Appropriate size) A4 specification-(Please read the precautions on the back before filling out this page} 、 11 _ · _ I-m —I— II 11 · 1237671 A7 V. Description of invention (Acridine) and attractive and clean The peach skin touch finishing. Its color is slightly paler than that of the sample cloth. The finished and causticized cloth has the same clean, peach skin touch finishing, which is completely invisible Compared with the un-causticized fabric and the comparison sample fabric, it has a better dyeing effect. (Please read the precautions on the back before filling this page)

、1T 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)、 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210X297 mm)

Claims (1)

、申請專利範圍 _ 17·根據申請專利範圍第 、 徵為,該溶劑拉纺布y,3項中任4的方法,其特 在後續的熱處理步驟之;酸或酸供與體浸漬以及 處理。 後但在染色步驟之前,經苛性化 徵為範圍ΐ1、2或3項中任-項的方法,其特 柔軟處纺布料在最後乾燥之前經以— 除 水性退__自平織_拉纺布料 32;=或酸供與體的水性溶液浸乾到該布料上. )將蔌布料乾燥以及熱處理; , 4) 將該布料染色;以及 5) 將該布料滾動乾燥; 整藉理此生產—經染色的溶劑拉纺布料,其有著桃皮觸感的 20. 根據申請專利範圍第19項的方法 該布料去除之前,對該布料進行燒毛的^在將漿料從 21. 根據申請專利範圍第19項或第2〇項的/、、’ 介於退疑步驟⑴與酸浸軋步# ”万法’其另包括 漂白的步驟。 物〈間的將該布料 22·根據申請專利範圍β項或第%項的方法, ,其另包括在 ^376?! Λ8 六、申請 酸浸軋步驟(2) + a 一 ^〜'— 布稃她❹凝是在染_⑷之餘該 23·根據申請專利範 在染色步驟(4)之後9頁曰或弟2項的方法,其另包括 到該布料上的步驟疋麵燥之前將—柔軟劑浸札 24. 根據帽專魏_19項或 裡,該染色步驟⑷係在^万法,在該方法 25. 根__範圍第19項綠=射機中進行的。 裡,該乾燥及熱處理步驟⑶ 的万法,在該方法 間的溫度進行的。 、一 l4〇°C到200°C之 26·根據申請專利範圍第25項 燥及熱處理步骤⑴係在拉力下進|的孩方法裡,該乾 意 事 填 裝 訂 經濟部中央標準局員工消費合作社印製Scope of patent application _17. According to the scope of patent application, the method is any one of 3 of the solvent woven fabric y, especially in the subsequent heat treatment step; acid or acid donor impregnation and treatment. After but before the dyeing step, the method of causticizing is in the range of any of the items ΐ1, 2 or 3, and the specially soft-spun fabric is subjected to water-removing before the final drying. 32; = or an aqueous solution of an acid donor is dipped into the cloth.) Drying and heat-treating the cloth; and 4) dyeing the cloth; and 5) rolling and drying the cloth; Dyeing solvent drawn fabric with peach skin feel 20. According to the method of the scope of the patent application No. 19 before the cloth is removed, the cloth is scorched ^ in the slurry from 21. According to the scope of the patent application 19 or 20 //, 'Between the dismissal step and the acid leaching step # "万 法' It also includes a step of bleaching. The material is the same as the 22. According to the scope of the patent application β Or the method of item%, which further includes ^ 376 ?! Λ8 6. Applying for the acid padding step (2) + a ^ ~ '— The cloth is condensed in addition to dyeing. 23 · According to The method of applying for a patent on page 9 or 2 after the dyeing step (4), which further includes The step on the cloth will be dipped in softener before the surface is dry. 24. According to the _19 item of the cap, the dyeing step is based on the method, in this method 25. Root__Scope item 19 green = Performed in a jet machine. Here, the drying and heat treatment steps (3) are performed at a temperature between the methods.-1 °° C to 200 ° C 26 · According to the 25th scope of the patent application scope, The heat treatment step is not carried out under the pull of the child's method. It should be printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Μ _ H 衣 1237671 申請曰期 V、Li》 案 號 Qlii 類 別 (以上各搁由本局填註) I罢專利説明書 中 文 溶劑拉纺布料的染色與整理方法 發明 新型 名稱 英 文 姓 名 國 籍 發明 創作 人 住、居所 1詹姆·泰勒 2喬弗雷·柯林斯 1英國籍 2英國籍 1英國段貝DE73 1XH屈蘭斯頓市利納克 里斯大道42號 2英國段貝DE3 5QZ密克利歐弗市邦漢 大道7號 裝 訂 姓 名 (名稱) 經濟部智慧^g工消費合作杜印製 國 三、申請人 住、居所 (事務所) 代表人 姓 名 英商·敦赛爾公司 (英國籍) 英國段貝DE21 1BP斯波頓市贺爾米 街1號 史密斯 線 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) Τ ^ 1· 亏季巳圏 -種用以生產一叙仇 該布料有耗朴1^理_雜纺麵的方法, 拉纺布料染色時=、㈣整理’其方法為在溶劑 上產生毛纖化,師再對]=㈣作,致使在布料的表面 ;其特徵為,在進行染色步c行洗滌和乾燥 酸供與體的水溶液布料經以—酸或 中經熱處理,以 濰及乾燥步驟的至少其:;酸供舆體的反應,前述的洗 行;藉此,該經染色的並經表—面 、觸感柔軟的弟而1衣囬愿理的布科有著乾淨的 續痕。 的染色動作所產生之 2+===:爾法,其特徵為,該劑拉纺 3. 根據申二=㈣染色機中染色。 纺布料是以已成衫1項的万法’其特徵為:該溶劑拉 滚筒產品(例如衣物)的形式,在一旋轉 4. =申請專利範圍第3項的方法,其 徵為,、2或3項中任—項的方法,其特 作,理加, 本紙張尺度適用----- 榡準(0奶)八4規格(21〇\297公聲) 酸 酸 ---------- /ύ\ '申气專利範圍 公升40公克 7·根據申請專利範圍第丨、2或3; 徵為,該酸供與體係氯化鎂。 貞勺万法,其特 8. 根據帽專利範圍第丨、2或31 徵為,該酸係一有機酸。 〃勺万法,其特 9. 根據帽專利範圍第8項的方法 使用的濃度係在水溶液中每、寺㈣,該有機 H).根據申請專利範圍第8項的方法2,至^,克。 係檸檬酸。 其特縣,該有機 Uj__範圍第⑴項的方法 的濃度係在水溶液中每公升4到6八、特试為,該酸 '根據申請專利範圍第"或3項中:―: 徵為,該經浸潰的布料經在 J万法,其特 22代的溫度熱處理。 境中在12Λ到 13·根據中請專利範圍第12項的 溫度係在就到酿之間。其特徵為,該 :申請專利範圍第或3項 15 ^,該用來作熱處理的氣流係空氣。的万法 據申請專利範圍第1、2或3項中任— 徵為,該溶劑拉纺布料係平織 項的方法 16.根據申請專利範圍第1、2或3項中5、」歲布料。 徵為,該溶劑拉纺布料在經以今—項的方法 經—退榮作業。工以或酸供與體 請 先 閱 讀 背 之 注 意 事 項 再 裝 頁 使用 訂 [氣流的 經 濟 部 中 央 標 準 局 員 工 消 t 合 作 社 印 製 其特 其特 其特 [浸潰之前 本紙張纽賴Μ _ H clothing 1237671 Application date V, Li "Case No. Qlii category (the above are filled by the Bureau) I. Patent specification Chinese solvent dyed fabric dyeing and finishing method Invention name English name Nationality Inventor creator 1 、 Residence 1James Taylor 2Jofrey Collins1British nationality 2British nationality1British section DE73 1XH 42 Linacris Avenue, Cranston City 2British section DE3 5QZ Bunkelover City Binding No. 7 Avenue (Name) Ministry of Economy Wisdom ^ g Industrial and Consumer Cooperation Du Printing Country III. Applicant's Residence and Residence (Office) Representative Name British Merchants Dunsell (UK) Duanbei DE21 1BP The paper size of Smith Line, 1 Hermi Street, Sparton, is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Τ ^ 1 · Lost season 种-a kind of fabric used to produce a revenge. The fabric is costly. 1 ^ Management _ method of mixed spun surface, when drawing fabrics dyed =, ㈣ finishing 'The method is to produce wool fibrosis on the solvent, the teacher then on] = ㈣ work, resulting in the surface of the fabric; its characteristics are In the dyeing step c, washing and drying of the aqueous solution of the acid donor is performed by acid or medium heat treatment to at least the drying step: the reaction of the acid donor, the aforementioned washing; , The dyed, surface-surface, soft-touch younger brother and 1 cloth reluctant Bu Ke has clean traces. The 2 + ===: Erfa method produced by the dyeing action is characterized in that the agent is drawn by spinning 3. According to Shen Er = ㈣ dyeing machine. The spinning fabric is a method of one item that has been made into a shirt. It is characterized in that the solvent pulls the drum product (such as clothing) in one rotation. 4. = The method of applying for the third item in the patent scope, which is, 2 Or any of the 3 items—the method, its special work, Riga, This paper is applicable to the standard ----- 榡 榡 (0 milk) 8 4 specifications (21〇 \ 297 sound) sour ------ ---- / ύ \ 'The scope of the patent application for gas is 40 g. 7. According to the scope of the patent application, No. 2 or 3; The acid is supplied to the system with magnesium chloride. According to the characteristics of Cap Patent No. 丨, 2 or 31, the acid is an organic acid. 〃 spoon method, its special 9. The concentration used in the method according to item 8 of the cap patent range is in the aqueous solution, the organic H). According to the method in the patent application range item 8, method 2, to ^, g . Department of citric acid. In its special county, the concentration of the method of item U of the organic Uj__ range is 4 to 6 per liter in the aqueous solution. The special test is that the acid is' according to the " or 3 of the scope of patent application: ―: Levy is The impregnated cloth was heat-treated at J Wanfa, a temperature of 22 generations. The temperature in the environment is from 12Λ to 13. The temperature according to item 12 of the patent application is between the brewing and the brewing. It is characterized by that: the scope of the patent application or item 3 15 ^, the airflow system air used for heat treatment. According to any of the items in the scope of patent application 1, 2, or 3 — the method is that the solvent-drawn fabric is a plain weave item. For this reason, the solvent-drawn fabric is subjected to warfare-retirement operations. Please read the memorandum items on the back of the work or the acid donor, and then install the page. [Printed by the Central Standard Bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs.
TW091112873A 2001-06-15 2002-06-13 Dyeing and finishing of lyocell fabrics TWI237671B (en)

Applications Claiming Priority (2)

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GB0114605A GB0114605D0 (en) 2001-06-15 2001-06-15 Dyeing and finishing of a woven fabric containing lyocell
GB0201067A GB0201067D0 (en) 2002-01-17 2002-01-17 Dyeing and finishing of lyocell fabrics

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ES (1) ES2279866T3 (en)
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GB2399094A (en) * 2003-03-04 2004-09-08 Tencel Ltd Treatment of lyocell containing fibres/fabrics with aqueous carboxylic acid at above atmospheric pressure & elevated temperature, prior to dyeing & tumbling
GB2403956A (en) * 2003-07-17 2005-01-19 Tencel Ltd Treatment of lyocell-containing fibres or fabrics with solution of a multifunctional carboxylic acid and solution of a Lewis acid, followed by heat treatment
CN102634895A (en) * 2011-03-07 2012-08-15 如皋市丁堰纺织有限公司 Cotton pulp solvent method cellulose fiber pure/blended yarn and production process thereof
CN111379040A (en) * 2018-12-28 2020-07-07 上海水星家用纺织品股份有限公司 Dyeing method of lyocell fibers
CN114411425B (en) * 2021-11-24 2023-07-18 鲁丰织染有限公司 Processing technology of efficient environment-friendly stock solution coloring viscose leisure fabric

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GB9304887D0 (en) * 1993-03-10 1993-04-28 Courtaulds Plc Fibre treatment
GB9408742D0 (en) * 1994-05-03 1994-06-22 Courtaulds Fibres Holdings Ltd Fabric treatment
GB9602991D0 (en) * 1996-02-14 1996-04-10 Courtaulds Fibres Holdings Ltd Lyocell fabric treatment to reduce fibrillation tendency
GB2314568A (en) * 1996-06-28 1998-01-07 Courtaulds Fibres Fibre finishing treatment
AU7908198A (en) * 1997-07-07 1999-02-08 Novo Nordisk A/S A method for pre-fibrillation of lyocell

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ES2279866T3 (en) 2007-09-01
CN1272499C (en) 2006-08-30
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AU2002257982A1 (en) 2003-01-02

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