TWI235668B - Non-aerosol type hair cosmetic - Google Patents

Abstract

Hair cosmetics prepared by filling into a non-aerosol type discharging container a composition containing the following components (A) and (B): (A) polypropyleneglycol or polyoxypropylene ether, and (B) polyether-modified silicone or amino-modified silicone. The present hair cosmetics are superior in foamability, rich amount of foams, and stability of foams, having a fine texture, and being creamy and soft. Feeling after drying the hair-applied composition is excellent, and has no problem in safety and environmental issue because it is free from any spraying agent.

Description

1235668 V. INTRODUCTION OF THE INVENTION Field of the Invention The present invention relates to a non-amplified non-foam foam type foam extrusion container for hair granules, 'foam > final salt, 7 4 H /. The hard feeling after getting up. BACKGROUND OF THE INVENTION Hair styling foam, embroidery color, 々, _ +, /, gray disease 疋 foam temple spray-type foamy hair granules are used to age hair 用, 彳 ,, and & The raw material liquid and the propellant are packed in a pressure-resistant closed container. 'Because of its convenience, it has been used in large quantities. However, these types of cosmetic products for hair-type hair use various propellants. Therefore, when designing products, safety, ozone layer destruction, dyeing, and global warming must be considered in response to global environmental protection. It is based on the development of non-use spray sword + non-Kazakh beer, but also non-f-type foamy hair cosmetics. / However, the conventional non-spray type foamy hair cosmetic has the following problems: the foam texture of the foam captured by the container is poor, the feel such as stickiness is also poor, and sufficient styling cannot be obtained. In addition, in general, since it is a type containing a large amount of water, it has poor dryness after being applied to hair. In order to solve their problems, the proposed technology, such as blending polymer compounds, is intended to improve the styling, but in this case, on the dried hair, there may be a stiff feeling derived from polymer compounds, etc. . In addition, in order to improve the tactile feel of the hair after drying, the proposed technology is the blending of dimethyl polyoxygen pits and polyether modified stone ketones, but the problem is that these ㈣ will be expected Foaming affects, especially for non-spraying dosage forms, the foaming situation will be significantly worsened. DISCLOSURE OF THE INVENTION The purpose of the present invention is to provide a kind of granules for non-spray type cinnabar hair-4. This paper size is applicable to China National Standard (CNS) A4 specifications (210X297 Public Love 7 1235668 A7 ___ B7 V. Description of the invention ( 2) The product has excellent foam content and foam texture, and has excellent touch after smearing. The inventors of the present invention have found that if a composition comprising polypropylene glycol or polyoxypropylene ether and a specific silicone is used, Packed in a non-spraying foam extrusion container such as a canister-type bubbler, the extrudate has excellent foaming properties, long-lasting foam, fine foam texture, creamy and soft, and sufficient Hair styling and good hair feel. That is, the present invention provides a cosmetic for hair, which is made by filling a composition into a non-spraying foam extrusion container, wherein the composition contains the following ingredients (A ) And (B): (A) polypropylene glycol or polyoxypropylene ether, and (B) polyacid modified mash or amino modified stone, the same g. The best form for implementing the invention is in the component (A ), Polypropylene glycol is obtained by polymerizing propylene oxide, Its average degree of polymerization is preferably from 7 to 20, more preferably from 8 to 17, particularly preferably from 8 to 15. Polyoxypropylene ethers may have an average degree of polymerization from 2 to 25, more preferably from 5 to 25, and even more preferably from 8 Mono- or dietherates of polyoxypropylene and sugar, methylated sugar, sugar alcohol, glycerol, and polyglycerin up to 25. Here, the sugar may be erythrose, xylose, glucose, mannose, etc., methyl The sugar can be methyl glucose: y: etc., the sugar alcohol can be erythritol, glucosyl alcohol, mannitol, etc., and the polyglycerol can be a polymer having a degree of polymerization of 2 to 3. Polypropylene oxide ether is preferably poly Propylene oxide (9 to 14) diglyceryl ether, polyoxypropylene (2 to 25) sorbitol, polypropylene glycol (2 to 25) methyl glucose component (A) may be a combination of polypropylene glycol and polypropylene oxide, or It is a combination of two or more of any one, and the content thereof is preferably the composition used in the present invention. The paper size is suitable for financial standards (UNS) A4 specification (210X297 public θ 1235668 A7 B7).

V. Description of the invention (from 0.05 to 30% by weight (hereinafter only referred to as%), more preferably from 0.1 to 20%, particularly preferably from 0.3 to 10. 3 Ingredient (B) < Polyether modified The purpose of blending high-quality silicone or amine-modified silicone is to improve the touch during application and after drying. When using polyether to modify silicone, it can give a smooth feel, while using amine-modified silicone together. In the case of ketones, wetting can be imparted. Polyether modified silicone is a general term for polyethylene oxide · methylpolysiloxane copolymers and poly (ethylene oxide · propylene oxide) methylpolysiloxane copolymers. Those with various HLBs are known, and commercially available products such as Silicone KF351A, KF353A, KF6008, KF6016, KF60u, KF6012, and Toray Dow Corning Corporation SH3 of Shin-Etsu Chemical Industry Co., Ltd. 77 1C, its 3773C, its 3 775 C, etc. Poly® | Modified broken ketone is preferably those obtained by Qr 丨 n method ηlb is 4 to 18, particularly preferably 7 to 11. As for the amino modified silicon Ketones, you can use the Amochi Meggan root (eight 1110 (^ 1 ^ 〇11 丨 (: 011 €) oil or emulsion, commercially available products such as Toray. Dokang Hongsha Asia / enjoy a few Meggan root liquid S Μ 8 7 0 4 C, and Toshiba XF-42B1989, etc. The component (B) can be a combination of polyether modified silicone and amine modified silicone, and can also be used in combination of any two or more. The content is preferably used in the present invention. 0.05 to 20% of the composition is more preferably 0.1 to 10%, particularly preferably 05 to 5%. In the composition, it is better to improve the cleaning effect, the solubility of the oil agent, and the foamability. The system contains a surfactant. The surfactant may be an alkyl benzoate, an alkyl or an alkenyl ether sulfate, an alkyl or an alkenyl sulfate, an alkyl hydrocarbon salt, an alkyl salt, saturated or unsaturated Fatty acid salts, end- or alkenyl-end-acid salts, α 飒 fatty acid salts, N-amidate type surfactants, phosphate mono- or diester-type surfactants, anionic surfactants such as sulfosuccinates: Paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) I235668

The amphoteric activity of the amphoteric surfactants, such as amino betaine, amino betaine, sucrose betaine, lignan, or amino betaine amphoteric surfactants, is 丨 · Taken ~ So Di_, Polydiol _, High carbon number fatty amine ',' Di-Yi, polyglycerol fatty acid monoethanolamine or diethanolamine r ^ θ pre-hardened ramie oil, polyethylene glycol sorbitan fatty acid ester: : Ethylene glycol sorbitol fatty acid esters, alkyl gluconate surfactants, non-ionic surfactants such as alkylamine oxides, alkylamidoamines, etc .: Mi ^ Linkai% type fourth ammonium salt, Cationic surfactants such as a fourth ammonium salt, a single long-chain alkyl fourth ammonium salt, and a long-slit base fourth ammonium salt. The pairing ions of the anionic residues of these surfactants can be metal ions such as' ion but ions, mother ions, magnesium ions, and other metal ions, ammonium ions, and have 1 to 3 carbon numbers of 2 Or an alkanolamine of 3 (for example, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). In addition, the counter ion of the cationic residue can be a gaseous ion, a bromide ion, a chemical ion such as anthracene ion, a methyl sulfate ion, and a carbohydrate ion. Among these surfactants, particularly preferred are polyethylene glycol (average 25 to 80) hardened castor oil, imidazoline-type amphoteric surfactants, polyalkylene glycols (average 4 to 30), and radical groups (average Carbon number 丨 2 to 1 8) Ether, single long chain alkyl group (average carbon number 丨 6 to 22) Fourth ammonium salt 3 Two or more kinds of surfactants can be used in combination, and the content is preferably 0.001 to 10% 5 is more preferably 0.5 to 8%, and even more preferably 1 to 5%. In the composition, in order to improve the touch after drying, an oil agent may also be included. The oil can be thirty-six carbon, thirty-carbon alkane, mobile olefin, mobile isoolefin, -7- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 1235668 A7

Cycloolefins and other hydrocarbons: sesame oil, cocoa butter, mink oil, avocado oil, ozov oil glycerol esters: beeswax, winter κZov soil: sericol, oil saponins &gt; ♦, ° rat Etc. 3. Alcohols such as stearyl alcohol, isostearyl alcohol, 2-octyldodecanol propionate, glycerol, etc. Yumen Imada, myristic acid octane I 12: 4 Wei ^ @@ 、 肉 豆Isopropyl acetic acid-_, hexyl laurate, cetyl emulsified base, single hard moon-day paternal propionate, oleine, hydrazone, / from 3, 2-ethylhexyl hexadecyl ester, Isononyl ester, dodecanoic acid isononanoate! p, Shi Ziyi Wu ^ 4 esters: decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, mountain father's rule I, oil fe, coconut oil fatty acid, agaric acid, iso palmitic acid, etc. High carbon number ^ Number of ife fatty Sks, other glyceryl isostearates, polypropylene glycol butyl ether, etc. Etc. (Medium '§ The best category is the best, and 2-Ethylhexyl I 11g day, the isononyl isononate and the isopropyl palmitate are particularly preferred. More than one <oil agent can be used together The content of # is preferably 0 to, particularly preferably 0.5 to 5% of the composition. 10,000; in the admixture, 'horse improves hair styling, improves touch, and may also include a polymer for film formation. Film formation The polymer used may be polyvinylpyrrolidone vinylpyrrolidone / vinyl acetate copolymer, ethylpyrrolidone / ethyl ethyl acetone / propane bismuth ethylene terpolymer, vinylpyrrolidine Ketone / alkyl acrylate (fourth gasification) copolymer, vinylpyrrolidone / §method / (meth) propionic acid copolymer, vinylpyrrolidone / alkyl amine acrylate / vinylhexanone Polyvinylpyrrolidone polymer compounds such as lactone copolymers: Acid vinyl ether polymer compounds such as methyl vinyl St / maleic anhydride alkyl half ester copolymers: vinyl acetate / crotonic acid copolymers, acetic acid Acidic polymers such as vinyl ester / crotonic acid / vinyl neodecanoate copolymer, vinyl acetate / crotonic acid / vinyl propionate copolymer, etc. (Vinyl) acrylic acid ester polymer compound; (meth) acrylic acid / (fluorenyl) propane-8- This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 1235668 A7 B7 V. Description of invention (6) , Greek I @ Said co-hydrate acrylic acid / alkyl acrylate alkyl acrylic acid ammonium copolymer and other sex propylene S parent polymer compounds: ... methyl propyl acryl ethyl, N, N-monomethyl Ammonium · 1 cardioyl carbonyl betaine / butyl methacrylate copolymer acrylic acid acetonitrile / butylamine ethyl methacrylate / octyl acrylate methamine copolymer and other amphoteric propylene acid acid polymer compounds ; Test propionic acid polymer compounds such as methacrylic acid acrylate and propylene copolymers such as Sifan copolymer; cellulose derivatives such as cationic cellulose derivatives: hydroxypropyl chitosan, carboxymethyl chitin, Chitin and chitosan derivatives, such as carboxymethyl chitosan, etc. Two or more kinds of film-forming polymers can be used in combination, and the content thereof is preferably from 0.01 to 10%, particularly preferably from 0.5 to 5%. The composition may also contain ethanol or propylene glycol, the content of which is preferably from 1 to 40%, particularly preferably from 3 to 20%. The preferred form of the composition to be used may be a composition made by combining the better of the additional ingredients listed above in the wounds (A) and (B) which are necessary ingredients. The ingredients ( The compositions of A) and (B) are filled in a non-sprayable foam extrusion container that can be foamed without using propellants such as liquefied petroleum gas, Teflon, and carbonated milk to produce the hair cosmetic of the present invention. The non-spray type foam extrusion container used here is used to mix the composition and air to make it foamy, and it is used to push out the body. For example, it can be used by pressing the body of a soft container with a finger. Squeezable bubbler, bubbler with trigger mechanism, which is used by pressing and covering with a finger, trigger type, etc. The squeeze-type bubbler can be described in Japanese Public Publication No. 62-042785, Japanese Public Publication No. 62-042786, and Japanese Public Publication No. 62-042787. 9- This paper size is applicable to Chinese national standards ( CNS) A4 size (210 X 297 mm) 1235668 A7

The objects' and equivalents thereof, and% &gt; Japanese Patent Application Laid-Open No. 7-3Ί5463, Japanese Patent Application Laid-open No. J type can be those described in Japan and equivalents. For the purpose of improving the texture of the foam at 2 ° 0961 bulletin, etc., in the extruded part of the container, in order to more preferably install the mesh to the 30 'half series of meshes, the present invention The cosmetic for hair is preferably applied to a mesh. Hair conditioner and so on. Horse hair styling agent, head [Exemplary Example] Example 1 W combined table 1 / external composition &quot; I machine bubbler (each equipped with 200 and 250 mesh net clothing I 10,000, that is, tube type The product is produced and subjected to the sensory evaluation shown below. $ Yi Maofan Makeup (evaluation method) Washing; 30 grams of straight hair bundles, rolled up in straight hair &amp; &lt; ^,,, '^ 马 5 Acrylic circle of cm is the same as above. After leaving it for one night, remove the subsequent hair tress from the propanoic acid cylinder. It is necessary to suppose that 5 members of the special group for sleep should change from the tube-type bubbler to the mountain ~ Take it with your hands and observe the state of the foam. After washing your hands, squeeze out the -1 4 liquid from the tube-type bubbler again, and apply it to the pre-prepared tress that is supposed to be sleeping crepe. Evaluation of each item in the table 3 Among the items evaluated, there are 5 evaluation stages such as 1 (poor), 2 (poor), 3 (unable to judge), 4 (slightly better), 5 (better), etc. And calculate its average point. -10-

This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 1235668 A7 B7 V. Description of the invention (8 Table 1 (%) The ratio of the invention, bite 1 2 3 4 5 1 2 Polypropylene oxide ( 9) Diglyceryl ether (SY-DP9, Sakamoto Pharmaceutical Co., Ltd.) 1.5. — 1.0 — — 1.0 Polyoxypropylene (丨 4) dimeter oil ether (SY-DP14, Sakamoto Pharmaceutical Co., Ltd.) — 0.5 — — One —-Polyoxidation Propylene (9) Sorbitol —-1.0 1.0 1.0 — — Polyoxypropylene (15) Sorbitol-1.0 — — — — — Polyoxypropylene glucoside C Glycopolymer PP-25, Japan Oil and Fats Corporation ) —… 1.5 — 1.5 — — Dimethicone (5 (H) () cs) 2.0 — 2.0 — — — Dimethylpolysilane pore fluid (BY22-060, Toray Dow Corning) 2.0 2.0 — 2.0 2.0 — Methylphenyl polysilicon gas (Sichuan () cs) —--—-— 2.0 Dimethyl polysilicon fe · polyalkanediol copolymer (KF-353A, Shin-Etsu Chemical Industry Co., Ltd. ) 3.0-3.0 — 3.0 — — Amino Modified Silicone (KT · 1989, GE Toshiba Silicone Co., Ltd.) — — L5 1.5 A — Amoxigenated Root Emulsion (SM-8704C, Toray Dow Corning Silicone Corporation) ί.〇 1.0 — — — — — Polyethylene oxide (2 ()) Glucitol station monolaurate 3.0 — — — — — — Polyethylene oxide (2 5) hardened vanilla oil — — 1.5 1.5 — — Polyethylene oxide (6 ()) hardened sesame oil-3.0 3.0 — 1.0 3.0 3.0 Poly (ethylene oxide) (9) lauryl ether —--1.5 1.0 —-Propylene glycol 2.0---2.0 —-Dipropylene glycol — -One — 2.0 — — 1.5 Gasified stearyl trimethylammonium 0.5 U.5 0.5 0.5 0.5 0.5 0.5 0.5 Isopropyl succinate-0.2 — 0.2 0.2 0.2 Fragrance trace trace trace trace trace trace trace 95 ° modification Alcohol 15.0 10.0 10.0 10.0 1 (). () 10.0 10.0 Purity Water Residual Residual Residual Residual Foam Smoothness 4.4 4.6 4.6 4.6 4.6 4.6 2.8 4.0 Ease of Foam Disappearance 4.4 4.8 4.6 4.8 4.6 2.2 2.8 Apply to hair Difficulty 4.8 4.6 4.cS 4.6 4.6 2.2 3.0 Assess the smoothness of the hair during application 4.4 4.2 4.4 4.2 4.2 4.4 2.0 3.0 The ease of removal of the imaginary crepe 4.2 4.2 4.2 4.2 4.2 4.2 3.2 3.2 The suppleness of the hair after application 4.4 4.2 4.4 4.2 4.4 2.4 2 .8 Whether the hair feels stiff after smearing 4.4 4.6 4.4 4.6 4.2 2.2 2.8 -11-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1235668 A7 B7 V. Description of Invention (9) Implementation Example 2 The compositions of Examples 1 to 5 of Example 1 were filled in a squeeze-type foamer to obtain a cosmetic for hair. When the hair cosmetics obtained from the container are extruded, each foam bed has a fine texture, is creamy and soft, and has excellent touch, smoothness and wetness after being applied to the hair. It is a good product 3 -12- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1235668 Date of application _ ------ ^ 々ίο, 1, &lt; Case number ------{-&gt; (λ-- ^ cii ϋ Category AL: \ k7L · The above blocks are filled in by the Bureau) Η supplement ^ 4 C4 Chinese Manual Replacement Page (January 1994) — 11 Patent Specification-, t! Name Chinese Non-Spray Mist Hair Cosmetics NON-AEROSOL TYPE HAIR COSMETIC

NOBUTAKA HORINISHI Country Japan Inventor Residence and residence Japan Country. Bunda 2-3 Kamo Co., Ltd. Sumida-ku Tokyo uml

Said Kao Corporation Nationality Applicant s Form i Appeared in Japan Japan 14th, Nihonbashi Kayabacho, Chuo-ku, Tokyo Prefecture Goto Takuya TAKUYA GOTO This paper is applicable to the standard of the paper_Transfer (CNS) A4 size (⑽χ (Tear public director)

Claims (1)

Ι23 _ ^) δ819〇 Patent Application A8, Chinese Patent Application Replacement (January 1994): ¾… '· ;;; D8, "Stones, Application for Boxing Ritual Enclosing 1. A hair cosmetic, which It is made by filling a set of composition into a non-spraying foam extrusion container, wherein the composition contains the following components (A) and (B): (A) 0.05-30% by weight of polypropylene glycol or polyoxypropylene ether And (B) 0.05 to 20% by weight of a polyether modified silicone or an amine modified silicone. 2. The cosmetic for hair according to item 1 of the patent application scope, wherein the composition further comprises a surfactant. 3. The hair cosmetic according to item 1 or 2 of the scope of the patent application, wherein polypropylene glycol or polyoxypropylene ether is selected from polyoxypropylene diglyceryl ether, polyoxypropylene sorbitol, polyoxypropylene methylglucose, and average Polypropylene glycol with a degree of polymerization of 7 to 20. This paper is sized for China National Standard (CNS) A4 (210 X 297 mm)