1233786 玖、發明說明： 【發明所屬之技術領域】 个货听你一禋樹脂組成物及使用其製 電化製品及成形品，優於抗菌性之同 一、，豕廷 安全性，i此等性質可維持長期間者。/、良於審吴性及 【先前技術】 之間特別注重清潔， 又’在病院等為防止 近年來，消費者，尤其是在女性 對桌子、容器等亦要求有抗菌性者。 p元内感& ’需要具抗菌性之工作a。 …马應：系要，過去有利用合成樹脂混入抗菌劑之 树脂組成物覆盍表面之桌子（太 Α、 丁、日本特開平7— 289359號公 報）或成型此專樹脂組成物之定哭r 之谷态（日本特開2002— 322355 號公報）。 “既有之此專桌子或容器雖具抗菌性，但是，有所含抗 囷劑對人體亚非完全無害之問題。而且亦有抗菌劑會隨時 ，流失而抗菌性降低之問題。再者，混人抗菌劑之桌 容器，其外觀並不美觀。 【發明内容】 本發明之目的為，提供一種樹脂組成物及使用其製成 之体具、家庭電化製品及成形品，優於抗菌性之同時，亦 優於審美性及安全性，且此等性質可維持長期間者。 係至少具，，由抗菌性金屬所成之金屬層及覆蓋其兩 面之合成樹月旨薄膜之疊層體，將其混入於合成樹脂之樹脂 組成物，覆蓋於桌子表面或成型此樹脂組成物成型製造成 1233786 型品。 【實施方式】 第1圖為構成本發明之桌 向剖開，其構成表面邱八二： ）之桌面A由橫方 面設覆蓋# A1。而承二Λ 如圖所示桌面A之表 =又“層A1而復盍層心系合 合後，於紙或木材等所成之基 粒片2此 又，如筮？闰無- 土材A2主布·乾燥所形成。 第2圖所不，於其他基材A2上撒下含粒片 宴 合成樹脂亦可形成。惟含粒片2之分量，係對, 總重量，衡量製品價格與抗菌 卩後^ A1之 重量%為宜。 囷『之關係，以0·5重量%至3 合成樹脂1，只要能覆蓋構成桌面 樹脂則不受限制。此等樹脂例 ==成 平鯈衩备抖日匕一 π 來G烯或聚丙烯等之 水烯垃系树月日、二聚氰胺酚醛 傲0匕、取气略也此 Ν歸树月日、醋酸乙烯 等 心、ABS樹脂、聚醯胺樹脂、聚賴脂等 再者，此等樹脂中，如 [：卜谌A人軺Η 9 a 可』…、S粒片2之相容性，則 之3成樹脂薄膜及粘著劑樹脂之融胃 化點較低之樹脂為佳，如人㈣㈣月曰之融點或軟 對苯二甲酸醋）時，考歲至;=月曰缚膜為聚醋（聚乙二醇 二等樹脂為佳。如使用與構成含粒片2 著劑相同融點·軟化點之樹脂，或較 二：“曰雖換合成樹脂薄膜及粘著劑軟化或溶化而失去 至屬光澤’雖機能仍在卻有 為聚醋（聚乙二醇對苯一甲…士而萬注意。例如樹脂 本—甲酸醋）時：含粒片2可使用聚 1233786 苯二甲酸，薄膜’則同時可確保抗菌性與金屬色 薄臈1 =:片2之放大圖，含粒片2係由合成樹脂 〜之=c、，、，-邊長度約。、 屬層2b产量*中％ ^ ^ _以線或鋸齒狀狀切割使金 膜/卜部。惟如備有覆蓋兩面之合成樹㈣ H吏用其他豐層體代替含粒片2亦可。 -二層金屬層2b，但是，由合成樹 曰乂仔2色或3色之畫盖从—Γ _ 代替#料社 亦可。又，以糸狀或長方狀者 且曰體城以略㈣敎粉狀含 不特別受制限。 大小亦 換之粒片2，例如在合成樹脂薄膜2a蒸鍍可離子交 之全為金屬層213後，將成膜之合成樹脂薄膜相互 體二、J::由枯著劑2c枯合’再將此夾層狀構造 體以縱k向切割成直、線狀或鑛齒狀而製造。 ㈣合ΐ樹脂薄膜2a為聚酿、尼龍、聚乙烯、聚丙烯，等 目’其厚度為約5〜5Mm，衡量機能與製品成本， 則約6〜12 /z m為宜。 *金屬層2b係由具抗g性可離子交換之金屬之銀、銅、 辞ί構成’其中’安全、不變色、不生銹且抗菌性高之銀 為取適當。金屬層之厚度為約20 4 5〇韻，但衡量機能盥 製品成本，則約5〇〜10〇nm為宜。 ” 1233786 酯系粘著劑、丙烯系 酯系粘著劑、或丙烯系 粘著劑2c有聚氨酯系粘著劑、 钻著劑等’以聚氨酯系粘著劑、聚 粘著劑為佳。 冉者，本發明並不受 限於上迷貫施方式，牡如 利範圍所記載之發明技術性範圍内，可有種種變更 例如，於上述實施方式，提示的為傢具 可為辨公桌、椅子、沙發等 >、 仁亦 吸塵機等家電製品亦可 ㈣、洗碗機、洗衣機、 匕又’不以上述樹脂組成物覆蓋基材劑表面，而 月曰組成物㈣射出成型、射出壓縮成型 、厂 成型等製造成型品亦可。第4 二成形，擠壓 之-邱八切…I 為此等成型品（洗臉盒) :广切割放大圖，如圖所示，成型品B ) 、3有含粒片2。至於合成樹脂1之成分，含粒片2曰 =成略粒片2之量比’係與上述覆蓋層μ相 再者’如此成型品例如有：原子筆、自動鉛 洗滞盆、洗臉盆、g链产 、σ葦專文，、， 擗入口—刷子等衛浴用品、切菜板、半 櫃、食品容器等廚房用品、a 刀未板未 内吊環、電話筒等衆人使用者。R τ巴，清潔用具、車 實施例 ”二人，製造本發明有關 u與聚丙烯板（實施例有/ :桌子桌面用表面材（實施例 進一步說明。 ）進行各種試驗，作為本發明之 (1)含粒片之製造 1233786 在厚度9 e m之聚酯薄膜以離子蒸鍍法將純銀蒸鍍上 成膜50 " m之金屬層。其次，以聚酯系粘著劑將上述具 金屬層之聚酯薄膜相互使金屬層向内邊粘合，製造夾層狀 構造體。最後用裁切機將疊層體縱橫鋸齒狀切割而製造含 粒片。 (2) 試驗片之製造 將作為桌面表面材之紙張著色，材其上面撒下在（D 製造之含粒片，在其上以三聚氰胺酚醛樹脂覆蓋使樹脂硬 化，製成試驗片（實施例1)。在此，對三聚氰胺酚醛樹脂 之重1比為1 %，撒下均勻而且成分散狀態。 又，在溶融於200°C之聚丙烯中，對該聚丙烯之重量 比能為1%，將（1)製造之含粒片分散·混入後，放置•冷 卻而製造試驗片（實施例2)。實施例丨及實施例2均呈美 麗銀色光澤。 (3) 抗菌性試驗 對實施例1依JISZ2801 (薄膜密著性）進行抗菌性試 驗，顯示4.8之抗菌活性値之優異抗菌性。試驗菌種採用 汽色葡萄球囷（staphylococcus aureus NBRC 12732 ) 〇 (4) 銀離子溶出試驗 對實施例2，由水質試驗等所用之Icp法，測量銀離 子用出量，測得86ppb之銀離子溶出。在生物學上據云細 囷專微生物遇5〜1 Oppb即會死滅，可知於實施例2具充分 之抗菌性。 如上事實，上述含粒片雖埋没於合成樹脂中，只要在 1233786 其1f7 舌'曰， 金屬之二容Γ:勻:㈣撒下，則含极片内之抗菌性 出’即有抗菌性機能。 本么月有關之樹脂組成物家、 品，係具備由構成疊声體……豕電製品、及成型 人说 乂 尽篮之抗囷性金屬之優昱扣结U^i：从 金屬光澤之審美松，叮产十# t 1支異抗囷性與其 、生，可在而要抗菌性之各種場所利用-且，此抗菌性鱼銮炎地 丁门 厅矛丨用。而 持續長期間。 j文王而 10 1233786 【圖式簡單說明】1233786 发明 Description of the invention: [Technical field to which the invention belongs] You can listen to the resin composition and use it to make electrochemical products and molded products, which are better than antibacterial, and have safety properties. Maintain long-term. /, Good at reviewing the nature of Wu and [previous technology] pay special attention to cleanliness, and also in hospitals, etc. In recent years, consumers, especially women, also require antibacterial properties on tables, containers, etc. The p-element internal sense & ’requires antibacterial work a. … Ma Ying: Yes, in the past, there were tables (Tai A, Ding, Japanese Patent Application Laid-Open No. 7-289359) covering resin surfaces with resin compositions mixed with antibacterial agents using synthetic resins. The state of the valley (Japanese Patent Laid-Open No. 2002-322355). "Although the existing table or container is antibacterial, there is a problem that the anti-tidal agent is completely harmless to the human body, and there is also the problem that the antibacterial agent will be lost at any time and the antibacterial property will be reduced. The table container mixed with antibacterial agent has an unattractive appearance. [Summary of the Invention] The purpose of the present invention is to provide a resin composition and bodyware, household electrochemical products and shaped articles made using the same, which are superior to antibacterial ones. At the same time, it is also superior to aesthetics and safety, and these properties can be maintained for a long period of time. At least, a laminate of a metal layer made of antibacterial metal and a synthetic tree moon film covering both sides, The resin composition mixed with synthetic resin is covered on the surface of the table or the resin composition is molded to form 1233786. [Embodiment] FIG. 1 is a cross-section of a table constituting the present invention, and its composition surface is Qiu Ba Two:） The table top A is set to cover # A1 from the horizontal side. And Cheng Er Λ as shown in the table of the table A = again "Layer A1 and the layer of the heart is combined, the base formed by paper or wood, etc. Tablets 2 again and again, such as 筮闰 None-Main cloth of earth material A2 · Dried. As shown in FIG. 2, a granular resin is sprinkled on other substrate A2. A synthetic resin can also be formed. However, the weight of tablets 2 is the total weight, and it is appropriate to measure the price of the product and the antibacterial weight ^ A1 weight%.囷 "The relationship is from 0.5 to 3% by weight of synthetic resin 1, as long as it can cover the resin constituting the table top. Examples of these resins == Cheng Pingji prepares the sun and the sun for a day, and the hydroenes such as Gene or polypropylene, the moon and the sun, the melamine phenol, and the air is slightly returned. , Vinyl acetate, etc., ABS resin, polyamide resin, polylysin, etc. Among these resins, such as [: bu 谌 Aren 轺 Η 9 a may '..., S tablets 2 compatibility, Then 30% of the resin film and adhesive resin have a lower melting point, such as the melting point or soft terephthalate). Polyvinyl acetate (polyethylene glycol second-grade resin is preferred. If the resin with the same melting point and softening point as the composition of the granule-containing tablet 2 is used, or more than two: "Although the synthetic resin film and adhesive are softened or Dissolve and lose the luster 'Although the function is still there, it is useful for polyvinegar (polyethylene glycol p-phenylene…… pay attention to it. For example, resin resin-formic acid vinegar): Granules 2 can use poly1233786 benzene di Formic acid, film 'can at the same time ensure antibacterial properties and metallic color. 臈 1 =: Enlarged view of sheet 2. Granule-containing sheet 2 is made of synthetic resin ~ = c ,,,,-side length is about. Yield of metal layer 2b * Medium% ^ ^ _Gold film / bubbles are cut by wire or zigzag pattern. However, if there is a synthetic tree covering both sides, it is also possible to replace grain-containing tablets 2 with other layers.-二Layer metal layer 2b, however, the synthetic tree can be used to cover 2 or 3 colors of 乂 仔 from —Γ _ instead of # 料 社. Also, those with 糸 or rectangular shape and the body city are slightly 以The powder contains no special restrictions. The size can also be changed into tablets 2. For example, after the synthetic resin film 2a is vapor-deposited with an ion-exchangeable metal layer 213, the synthetic resin film is formed into a film. J :: by The desiccant 2c is used together, and the sandwich structure is cut into vertical, linear, or dentate shapes in the longitudinal k direction. The resin film 2a is made of polystyrene, nylon, polyethylene, polypropylene, etc. "The thickness is about 5 ~ 5Mm, which is about 6 ~ 12 / zm when measuring the function and product cost. * The metal layer 2b is composed of silver, copper, and ions that are ion-exchangeable with g resistance." Among them, silver is safe, does not change color, does not rust, and has high antibacterial properties. The thickness of the metal layer is about 20 4 5 0 rhyme. In this case, about 50 to 100 nm is suitable. "1233786 Ester-based adhesives, propylene-based ester-based adhesives, or propylene-based adhesives 2c include polyurethane-based adhesives, drilling agents, etc. Adhesives and polyadhesives are preferred. However, the present invention is not limited to the conventional application method, and various modifications can be made within the technical scope of the invention described in the scope of the invention. The way, the reminder is that the furniture can be distinguished from public tables, chairs, sofas, etc., and household appliances such as Renyi vacuum cleaners, dishwashers, washing machines, and daggers. In addition, the composition can also be manufactured by injection molding, injection compression molding, and factory molding. The 4th molding, extrusion-Qiu Baqie ... I these moldings (face wash boxes): wide cut enlarged view, as shown in the figure, moldings 2), 3 have granules 2. As for the composition of the synthetic resin 1, the ratio of the particle-containing tablet 2 = the slightly granular tablet 2 is 'repeated from the above-mentioned coating layer μ'. Examples of such molded products include ball pens, automatic lead wash basins, wash basins, G chain products, σ reed articles, ，, entrances-brushes and other sanitary supplies, cutting boards, half cabinets, food containers and other kitchen supplies, a knife, plate, inner ring, telephone tube and other users. R τ bar, cleaning appliance, car embodiment "two people, to produce the u and polypropylene plates related to the present invention (the examples are /: surface material for desks and desktops (the examples further explain). Various tests were conducted as the invention ( 1) Manufacture of granules 1233786 On a polyester film with a thickness of 9 em, pure silver is vapor-deposited into a metal layer of 50 " m by ion evaporation. Next, the above-mentioned metal layer is coated with a polyester-based adhesive. The polyester films adhere the metal layers to each other inward to produce a sandwich-like structure. Finally, the laminated body is cut longitudinally and zigzag with a cutting machine to produce pellets. (2) The test piece will be used as a desktop surface The paper of the material is colored, and the particle-containing sheet manufactured by D is sprinkled on the sheet, and the resin is covered with melamine phenol resin to harden the resin to form a test piece (Example 1). Here, the weight of the melamine phenol resin The ratio of 1 is 1%, and it is sprinkled uniformly and in a dispersed state. In polypropylene melted at 200 ° C, the weight ratio to polypropylene can be 1%, and the granules produced in (1) are dispersed · After mixing, leave and cool to produce test pieces Example 2). Both Example 丨 and Example 2 exhibited a beautiful silvery luster. (3) Antibacterial test The antibacterial test of Example 1 according to JISZ2801 (film adhesion) showed an excellent antibacterial activity of 4.8. The test bacteria used Staphylococcus aureus NBRC 12732. (4) Silver ion dissolution test For Example 2, the silver ion output was measured by the Icp method used in the water quality test, etc., and 86ppb was measured. Silver ions dissolve. According to the biological data, the microbes will die when they encounter 5 to 1 Oppb. It can be seen that Example 2 has sufficient antibacterial properties. As a matter of fact, although the above pellets are buried in synthetic resin, as long as 1233786 Its 1f7 tongue 'said, the second metal capacity Γ: uniform: spit down, then the antibacterial properties contained in the pole pieces' have antibacterial properties. The resin composition home and product related to this month are equipped with Constitute a supersonic body ... Electric products, and the shapers say that the best metal in the basket is resistant to metal buckle U ^ i: From the aesthetic looseness of metallic luster, Ding ten Can be used in various places where antibacterial properties are required. Use-And, this antibacterial fish cricket is used in Dingmen Hall Spear. And it lasts for a long time. J 文王 而 10 1233786 [Schematic description]
本發明有關之構成 之放大圖。 一種桌子之桌面表面構成 第2圖 第3圖 第4圖 構成'、他種桌子之桌面表面構成之放大圖。 構成含粒片之圖。An enlarged view of the constitution of the present invention. Composition of a table top surface of a table Fig. 2 Fig. 3 Fig. 4 Fig. 4 constitutes an enlarged view of the table surface composition of another table. Picture of tablets containing granules.
本务明有關之成型品之剖面圖及其部分放大 【符號說明】 A 桌面 A1 覆蓋層 A2 基材 B 成型品 1 合成樹脂 2 含粒片 2a 合成樹脂薄膜 2b 金屬層 2c 粘著劑Cross-section view of the molded product related to this matter and a part of it enlarged