1231216 ⑴ 玖、發明戴明 【發明所屬之技術範疇】- … 本發明係關於一種浮白少、可得到自然完粧感覺，且可 有效地使形態上之瑕疵諸如毛孔及小皺紋等顯眼瑕疵不 易被發現之優良化粧料。 【先前技術】 以往，為了將皮膚上之毛孔及小皺紋等顯眼瑕疵等形態 上之瑕疵藉由化粧料覆蓋，係將隱蔽力高之顏料，亦即折 光率高且微粒子著色力高之顏料，例如二氧化鈦、紅氧化 鐵、黃氧化鐵、黑氧化鐵及有機色素等添加於化粧料中， 以提高對該形態上瑕疵之覆蓋力，藉此而將肌膚上存在之 毛孔及小皺紋等顯眼瑕疵等形態上之瑕疵隱蔽。然而，此 等含有大量高隱蔽力顏料之化粒料，雖對黑斑或雀斑等 色調上之缺點有效果，但對形態上之瑕疵諸如毛孔或小皺 紋等顯眼瑕疵，則不太有效果，相反地，反而有所謂使毛 孔或小皺紋等更醒目之缺點。再者，藉由上述含有大量高 隱蔽力顏料之化粧料，由於呈現厚化粧感，變得不透明， 也有所謂容易損及肌膚之自然感覺之缺點。 另一方面，覆蓋形態上缺點之其他化粧料，例如為含有 擴散反射型粉體之化粧料（特開昭60-228406號公報）曾被提 出。然而，此種化粧料所使用之擴散反射型粉體，對形態 上瑕疵諸如毛孔或小皺紋等顯眼瑕疵，雖有若干效果，然 而完粧後之感覺蒼白而不自然，常具有所謂呈現粉粉的完 粧缺點。 再者，其他為了覆蓋形態上缺點之化粧料，如含有内包 016927 1231216 (2) 煢明說明續頁 金屬氧化物之樹脂粉體之化粧料（特開平9-208437號公報） ^曾被提出。然而，上述含有_内包金屬氧化物之樹脂粉體之 化粧料中，為了表現紫外線遮蔽能力，常使用平均粒徑小 且高透明性之金屬氧化物，當使用該化粧料時，亦在毛孔 及小皺紋等凹處附著，因而有所謂難以得到充分隱蔽性之 缺點。因此，藉由上述含有内包金屬氧化物之樹脂粉體之 化粧料，無法讓凹處變得明朗，有所謂難以得到將形態上 瑕疵諸如毛孔或小皺紋等顯眼瑕疵隱蔽之效果之缺點。 【本發明欲解決之課題】 本發明之目的，係提供一種沒有浮白，可得到自然之完 粧感覺，且可將形態上之瑕癍：諸如毛孔及小敏紋等顯眼瑕 疵有效地改善之化粧料。 【為解決此課題之手段】 本發明係關於含有平均粒徑為5〜40 //m之球狀複合聚合 體粒子之化粧料，該球狀複合聚合體粒子含有平均粒徑為 0.12〜5.0 /zm之白色無機顏料。 【實施本發明之形態】 本發明之化粧料，含有平均粒徑為5〜40 // m之球狀複合 聚合體粒子，且該球狀複合聚合體粒子含有平均粒徑為 0.12〜5.0 /zm之白色無機顏料。上述球狀複合聚合體粒子中 ，由於含有具有上述平均粒徑之白色無機顏料，若藉由含 有該球狀複合聚合體粒子之化粧料，可將形態上瑕疵諸如 毛孔及小皺紋等顯眼瑕疵有效地改善，而得到充分之隱蔽 性0 016928 發明說明績頁 1231216 (3) 本說明書中，「球狀複合聚合體粒子」意指將聚合體與白 色無機顏料複合化所得到之粒子。… 又，上述術語「球狀複合聚合體粒子」中所使用之「球狀 」包含真球狀者、略球狀者、呈現抑制正反射及/或亂反射 性質之迴轉橢圓體以及球狀物之表面具有凹凸者等。 本發明中，平均粒徑，意指從以乙醇做為測定溶媒，使 用雷射回折式粒度分布測定器測定所得之體積基準平均 粒徑而得之值。 上述白色無機顏料，平均粒徑為0.12〜5.0 //m，而以0.13〜3.0 為較佳，以0.15〜2.0 //m為更佳。上述白色無機顏料之平均 粒徑若在上述範圍内，則由於白色無機顏料呈現之隱蔽性 變高且透明性變低，將該白色無機顏料及聚合體複合化 時，對於形態上之瑕疵諸如毛孔及小皺紋等顯眼瑕疵等， 可得到所謂充分隱蔽效果之優良性質。 又，上述白色無機顏料之折光率，雖無特別限制，然而 以折光率1.5〜2.8為較佳，以折光率2.0〜2.7為更佳。若折光率 為1.5以上，由於透明性變低，對於形態上之瑕疵諸如毛孔 及小皺紋等顯眼瑕疵等可有效地得到充分隱蔽性。再者， 上述折光率者，可使用文獻〔例如，「化學便覽」，日本化 學會編（1993年發行）；「窯業工學手冊」，社團法人曰本陶瓷 協會編（1984年發行）〕等記載之值，對於無文獻值之物質， 可使用藉由液浸法測定之值。上述液浸法，係指測定折光 率之方法，包含在顯微鏡下，觀察浸於已知折光率之液體 之試料與該液體之界線附近之方法〔坪井誠太郎著，「偏 016929 發明說明續頁 1231216 (4) 向顯微鏡」（1955)〕。上述液浸法，係利用「浸於液體之試料 與該液體之界線附近，一破可見到被稱為貝克（Becke)線之 亮線，而在具有與試料相等折光率之液體中，界線與亮線 變不見」之現象之測定方法。 上述白色無機顏料，例如為氧化銘、氧化#5、氧化鎂、 氧化鋅、氧化錘、氧化鈇（金紅石（mtile)型及銳鈇礦（anatase)型 等）等之金屬氧化物，氧化鋅/氧化鈦複合氧化物、氧化鋁/ 氧化鎂複合氧化物及氧化鈣/氧化锆複合金屬氧化物等複 合氧化物，硫酸鋇等硫酸鹽及碳酸鈣等碳酸鹽等；從化粧 料中安定性之觀點言之，以氧化鋁、氧化鋅、氧化錘、氧 化鈦及氧化鋅/氧化鈦複合氧化物為較佳。上述白色無機 顏料，可單獨使用或2種以上組合使用。又，上述白色無 機顏料，可依照需要施以表面處理，例如賦予撥水性之石夕 酮處理，及賦予撥水·撥油性之氟處理等。本發明中，使 用施以上述矽酮處理之白色無機顏料之情況，於一般有機 溶媒中之分散性優良，使用施以上述氟處理之白色無機顏 料之情況，於氟系溶媒中之分散性優良。 在球狀複合聚合體粒子中上述白色無機顏料之含量，從 得到充分隱蔽性，可將形態上瑕疵諸如毛孔及小皺紋等顯 眼瑕疵等有效隱蔽之觀點言之，以5重量％以上為較佳， 又從抑制毛孔及小皺紋等顯眼瑕疵等之觀點言之，以60重 量％以下為較佳。具體而言，於球狀複合聚合體粒子中上 述白色無機顏料之含量，以5〜60重量％為較佳，又以20〜50 重量％為特佳。 -9- 016930 1231216 (5) 發明說明績頁 又，含有白色無機顏料之球狀複合聚合體粒子之密度， 從不會飛散而能充分發揮粒子良好操作性之觀點言之，為 1.0 g/cnr"以上，而以1.1 g/cm。以上為較佳，以1·25 g/cm3以上為更 佳；化粧料中球狀複合聚合體粒子以同重量添加時，在低 密度之情況粒子數變多，粒子之總體積與高密度情況相較 體積變大，從充分表現有效包埋皮膚上凹處之性質之觀點 言之，期望在4.0 g/cm。以下，而以2.5 g/cm。以下為較佳，以3.0 g/cmJ以下為更佳。 上述球狀複合聚合體粒子之平均粒徑，從對於毛孔及皺 紋部位呈現選擇性附著，抑制球狀複合聚合體粒子對於皮 丘部之附著以及化粧後得到自然完粧感覺之觀點言之，為 5 /zm以上；又從抑制粗溫感等而得到良好使用感之觀點 言之，為40 //m以下。具體而言，上述球狀複合聚合體粒子 之平均粒徑，為5〜40 /zm，而以8〜30 /zm為較佳，以10〜20 /zm 為更佳。 又，球狀複合聚合體粒子之隱蔽性，以10〜50為較佳，而 以15〜40為更佳。該隱蔽性若為10以上，則毛孔及小皺紋可 充分隱蔽，為50以下，則毛孔及小皺紋不變白，不會很明 顯。本發明中之隱蔽性，可藉由實施例所示之方法求得。 球狀複合聚合體粒子中所使用之聚合體，只要呈現疏水 性質，聚合體為透明或半透明，且在化粧品中經常使用， 為化粧品原料基準中所記載者即可，並無特別限制，例如 尼龍樹脂、聚酯樹脂、聚甲基丙烯酸曱酯等（甲基）丙烯酸 系樹脂、聚乙烯樹脂、聚苯乙烯樹脂、聚胺基甲酸酯樹脂 -10- 016931 1231216 ⑹ 發明說明續頁 等熱可塑性樹脂；矽酮樹脂、（甲基）丙烯酸月桂酯-二（甲 基）丙晞酸乙二醇酯共聚物、丙烯酸異硬脂酯-以二乙烯苯 共聚物交聯之聚胺基甲酸酯樹脂等交聯聚合體樹脂等。其 中，從所謂物理性及化學性堅固之觀點言之，以交聯聚合 體樹脂為較佳。 將上述聚合體及白色無機顏料複合化之方法，可依照所 使用之聚合體種類適宜地選擇。例如，聚合體之種類為尼 龍樹脂之情況，將石蠟與環狀内醯胺混合，加熱使熔解， 於得到之混合物中添加需要量之白色無機顏料粉末，然後 一面充分混合，一面添加聚合促進劑例如三氯化磷等，進 行鹼聚合，得到粒子，過濾該粒子，將得到之粒子藉由有 機溶劑例如異丙醇或正己烷等洗淨，隨後進行乾燥之方法 等。又，例如，聚合體之種類為矽酮樹脂之情況，將氨或 胺等之水溶液，與白色無機顏料之粉末混合，於得到之混 合物中，將加水分解性碎燒、燒氧石夕燒、及乙醯石夕院等混 合之烷氧矽烷等加水分解，然後，將烷氧矽烷等之加水分 解產物、及燒氧碎燒等之加水分解產物或未加水分解之燒 氧矽烷等進行縮合反應，得到粒子，過濾該粒子，然後將 得到之粒子進行水洗，再進行乾燥之方法等。更且，例如 聚合體之種類為甲基丙晞酸月桂酯-二甲基丙烯酸乙二醇 酯共聚物之情況，將為單體之甲基丙烯酸月桂酯及二甲基 丙烯酸乙二醇酯，與為聚合起始劑之月桂醯基過氧化物混 合，溶解，然後於所得到之混合物中，添加需要量之白色 無機顏料，且使其分散，然後將得到之分散液加至聚乙婦 -11 - 1231216 ⑺ 煢明說明續頁 醇水溶液中且使其分散，一面攪拌一面加熱，以進行聚合 八懸浮聚合），得到粒子，過濾該粒子，將得到之粒子進行水 洗，再進行乾燥之方法等。 又，白色無機顏料在球狀複合聚合體粒子内之分散狀態 ，從隱蔽性等光學特性之觀點言之，以高分散狀態較為理 想。控制上述分散狀態之方法者，如使用均質機、高壓均 質機、超音波分散機、立式球磨機（attritor mill)或球磨機（ball mill)等機械分散之方法，或使用低分子界面活性劑〔例如 ，陰離子性界面活性劑（例如月桂基硫酸鋼、及聚氧伸乙月 桂基醚硫酸鈉等）、陽離子性界面活性劑、或非離子性界 面活性劑等〕、或高分子分散劑〔例如澱粉、聚乙晞醇、致 甲基纖維素及甲基聚矽氧烷等〕等分散之方法等。 上述球狀複合聚合體粒子，可單獨使用或2種以上組合 使用。 化粧料中上述球狀複合聚合體粒子之含量，隨劑型而異 ，並無特別限制，然而期望為0.1〜50重量％，而以1〜20重量 %為較佳。上述球狀複合聚合體粒子之含量，若在上述範 圍内，則所謂「毛孔及小皺紋等顯眼瑕疵難以被發現」之 效果優良’同時使用感亦良好，故較佳。 又，本發明之化粧料中，為了將所謂本發明化粧料具有 之效果「沒有浮白、可得到自然完粧之感覺，且可將形態 上之瑕疵諸如毛孔及小皺紋等顯眼瑕疵等改善」發揮出 來，可依照需要，添加通常化粧料中添加之成分。具體而 言，本發明之化粧料中，在將所謂本發明化粧料具有之效 016933 -12- 奁明說明績頁 1231216 ⑻ 果「沒有浮白而可得到自然之完粧感覺，且可將毛孔及小 〜皺紋等顯眼瑕疵等形態上琅疵改善」發揮出來之量及質之 範圍内，可添加例如凡士林、羊毛脂、地躐（ceresine)、微晶 蠟、高級脂肪酸、高級醇等固體·半固體油份，橄欖油、 希蒙德木（jojoba)油、蓖麻子油、三十緩燒（squalane)、流動石 蠟、酯油、二甘油酯及三甘油酯等流動油份，甲基聚矽氧 燒等碎酮油，全氟聚醚及氟改質硬酮等氟系油劑，水溶性 及/或油溶性聚合物，雲母粉、滑石粉、絹雲母（sericite)、硫 酸鋇等體質顏料，紅氧化鐵、黃氧化鐵、黑氧化鐵及氧化 鈥等無機著色顏料，紅色226號及黃色401號等有機著色顏 料，將有機著色顏料藉由聚合物膠囊化等之膠囊化有色顏 料，有機色素等著色劑，及其他防腐劑、氧化防止劑、增 黏劑、香料、紫外線吸收劑、紫外線遮蔽劑、殺菌劑、制 汗劑及保溼劑等。 本發明之化粧料，雖可以粉末固形劑、高含油性粉末固 形劑、油分散型、水分散型、油中水乳化液及水中油乳化 液等之劑型使用，但從為使皮膚上之形態上瑕疵有效地隱 蔽，而適合做為化裝底層使用之觀點言之，以液狀化粧料 為較佳。 本發明之化粧料，具體而言，雖可做為例如美容化粧料 諸如粉末狀粉底、液狀粉底、半固形粉底、乳化液狀粉底 及染眉毛油等之，以及藥用化粧料諸如防曬乳化液等乳化 液等使用，然而從適合做為化裝底層使用之觀點而言，特 別以液狀粉底、乳化液狀粉底及乳化液為較佳。 -13 - 016934 發明說明續頁 1231216 (9) 本發明之化粧料，除上述球狀複合聚合體粒子，亦可進 一步含有透明性高、光擴散透過性（暈光效果）大之其他球 狀粒子。若為進一步含有上述球狀粒子之化粧料，可更進 一步得到沒有浮白而自然完粧感覺，且呈現可將形態上瑕 疵諸如毛孔及小皺紋等顯眼瑕疵等改善之效果。 此處，上述術語「球狀粒子」中所使用之「球狀」，包含 與上述「球狀複合聚合體粒子」中所使用之「球狀」同樣者。 上述球狀粒子，為從皮丘部至皮溝部均勾地附著者，較 佳之球狀粒子為平均粒徑1〜10 (以2〜9 為較佳）且折 光率為1.3〜1.8 (以1.4〜1.6為較佳）之球狀粒子。球狀粒子之折 光率若為1.8以下，可得到較自然之完粧感覺，球狀粒子之 平均粒徑若為1 以上，則球狀粒子不會被埋入化粧膜 裡，毛孔及小皺紋等與皮丘部之分界部分將充分呈現昏暈 而有難以被看見之效果，即「光暈效果」，若為10 # m以下 ，該效果感覺提高。 本發明中球狀粒子只要具有抑制正反射、亂反射之效果 即可，若具有同樣之效果，亦可為迴轉橢圓體或表面凹凸 之粒子。此等球狀粒子之具體例者，可使用從球狀之矽石 、礬土等金屬氧化物，硫酸鋇等硫酸鹽，碳酸鈣等碳酸鹽 等無機化合物，聚曱基丙埽酸甲酯等熱可塑性樹脂，尼龍 、矽酮樹脂、聚胺基甲酸酯樹脂及交聯聚合物等高分子化 合物等中選出之1種或2種以上之混合物。 化粧料中上述球狀粒子之含量，隨著化粧料之形狀而異 ，並無特別限制，但期望為0.1〜30重量％，而以0.5〜10重量％ -14- 016935 耷明說明續頁 123 1 2 1 6 00) 為較佳。上述球狀粒子之含量，若在上述範圍内，則使毛 孔及小皺紋等形態上之瑕戒難以被看見之效果優良，同時 使用感亦良好，故較佳。 又，依照需要，可添加上述通常化粧料中添加之成分。 【實施例】 (評價方法） 1.隱蔽性 (1) 將球狀複合聚合體粒子L304 g添加於矽酮油（信越化 學（股）製，商品名·· KF-96-lOOOcs) 15 g，將得到之混合物藉由 均勻分散機（Homodisper)(特殊機化工業（股）製，商品名：TK自 動均勻混合機），以800 r/min，預備分散2分鐘，再以6000 r/min 分散5分鐘，得到分散混合物。然後，進行真空脫氣，得到 樣本分散液。 (2) 於具有20 /zm間隔之玻璃製小匣中，注入上述樣本分 散液，該小匣之單面張貼著黑色人工皮革，另一面藉由色 差計（曰本電色工業製，商品名·· SE2000型）設定並測色，以 、a、表色素，分別求取LI#值（顏色明亮度；明度）、al+值 (紅-綠方向之色度）、br值（黃-青方向之色度）。除此之外， 不注入樣本分散液，將張貼著黑色人工皮革之玻璃製小匣 同樣地測色，同樣地分別求取L2+值（顏色明亮度；明度）、a2# 值（紅-綠方向之色度）及b2>值（紅-青方向之色度），並依照 下式求取色差ΔΕ。 △ E 叫(LI、L2*)2+ (al*- a2*)2+ (M*- b2*)Y/2 將上述ΔΕ當做隱蔽性之值。 016936 1231216 r—- (11) 發明說明續頁1231216 发明 发明, invention Deming [Technical category to which the invention belongs]-… The present invention relates to a kind of whiteness, which can get a natural finish feeling, and can effectively make morphological defects such as pores and small wrinkles difficult to notice Discovered an excellent cosmetic. [Previous technology] In the past, in order to cover morphological defects such as pores and small wrinkles on the skin with cosmetics, pigments with high hiding power, that is, pigments with high refractive index and high coloring power of fine particles, For example, titanium dioxide, red iron oxide, yellow iron oxide, black iron oxide, and organic pigments are added to cosmetics to improve the coverage of morphological defects, thereby conspicuous defects such as pores and small wrinkles on the skin. Other morphological defects are hidden. However, these chemical granules containing a large amount of high hiding power pigments are effective for shortcomings such as dark spots and freckles, but are not effective for visible defects such as pores or small wrinkles. On the contrary, there are disadvantages such as making pores or small wrinkles more prominent. Furthermore, the above-mentioned cosmetics containing a large amount of high hiding power pigments have a thick makeup feel and become opaque, which also has the disadvantage of easily damaging the natural feeling of the skin. On the other hand, other cosmetic materials covering the morphological defects, such as those containing a diffuse reflection type powder (Japanese Patent Application Laid-Open No. 60-228406), have been proposed. However, the diffuse reflection powder used in this kind of cosmetic has some effects on morphological defects such as pores or small wrinkles, but it feels pale and unnatural after makeup, and often has a so-called powder appearance The disadvantages of finishing makeup. In addition, other cosmetic materials for covering morphological defects, such as cosmetics containing inner packaging 016927 1231216 (2) 茕 说明 Continued description Cosmetic materials of metal oxide resin powder (Japanese Patent Application Laid-Open No. 9-208437) ^ has been proposed. However, in the above-mentioned cosmetic materials containing resin powder containing metal oxides, in order to exhibit ultraviolet shielding ability, metal oxides with a small average particle size and high transparency are often used. When using this cosmetic material, it is also used in pores and Since small wrinkles and the like are attached, there is a disadvantage that it is difficult to obtain sufficient concealment. Therefore, the above-mentioned cosmetic material containing the resin powder containing metal oxides cannot make the recesses clear, and there is a disadvantage that it is difficult to conceal visible defects such as pores or small wrinkles. [Problems to be Solved by the Present Invention] The object of the present invention is to provide a natural finish without whitening, and can effectively improve morphological flaws such as visible blemishes such as pores and small sensitive lines. Cosmetics. [Means to solve this problem] The present invention relates to a cosmetic containing spherical composite polymer particles having an average particle diameter of 5 to 40 // m, and the spherical composite polymer particles having an average particle diameter of 0.12 to 5.0 / Zm white inorganic pigment. [Form of implementing the present invention] The cosmetic of the present invention contains spherical composite polymer particles having an average particle diameter of 5 to 40 // m, and the spherical composite polymer particles have an average particle diameter of 0.12 to 5.0 / zm White inorganic pigment. Since the spherical composite polymer particles contain a white inorganic pigment having the above-mentioned average particle diameter, if a cosmetic material containing the spherical composite polymer particles is used, morphological defects such as pores and small wrinkles can be effectively noticed. Improvement, and sufficient concealment is obtained. 0 016928 Invention description page 1231216 (3) In this specification, "spherical composite polymer particles" means particles obtained by compounding a polymer with a white inorganic pigment. … In addition, the “spherical shape” used in the term “spherical composite polymer particle” includes a true spheroid, a slightly spheroid, a spheroid and a spheroid that exhibit the properties of suppressing regular reflection and / or random reflection. Those with unevenness on the surface. In the present invention, the average particle diameter means a value obtained from a volume-based average particle diameter obtained by measuring with ethanol as a measurement solvent and using a laser reflex particle size distribution measuring device. The above-mentioned white inorganic pigment has an average particle diameter of 0.12 to 5.0 // m, preferably 0.13 to 3.0, and more preferably 0.15 to 2.0 // m. If the average particle diameter of the white inorganic pigment is within the above range, since the concealment and transparency of the white inorganic pigment are increased, when the white inorganic pigment and the polymer are compounded, morphological defects such as pores And conspicuous flaws such as small wrinkles, etc., can obtain the excellent properties of so-called sufficient concealing effect. In addition, although the refractive index of the white inorganic pigment is not particularly limited, a refractive index of 1.5 to 2.8 is preferable, and a refractive index of 2.0 to 2.7 is more preferable. If the refractive index is 1.5 or more, the transparency becomes low, and concealment of morphological defects such as pores and small wrinkles can be effectively concealed. In addition, those who have the above-mentioned refractive index can use literature [for example, "Handbook of Chemistry", edited by the Chemical Society of Japan (published in 1993); "Handbook of Kiln Industry Engineering", edited by the Japanese corporate ceramics association (issued in 1984), etc.] For the recorded value, the value measured by the liquid immersion method can be used for a substance without a literature value. The above-mentioned liquid immersion method refers to a method for measuring the refractive index, and includes a method of observing a sample immersed in a liquid of known refractive index and the vicinity of the boundary of the liquid under a microscope [by Makoto Tsutsui, "Part 016929 Description of the Invention Continuation Page 1231216" (4) To the microscope "(1955)]. The above-mentioned liquid immersion method uses "the vicinity of the boundary between the sample immersed in the liquid and the liquid, a bright line called the Becke line can be seen, and in a liquid with the same refractive index as the sample, the boundary line and The measurement method of the phenomenon that the bright line disappears. The white inorganic pigments are, for example, metal oxides such as oxide oxide, oxide # 5, magnesium oxide, zinc oxide, hammer oxide, hafnium oxide (such as rutile (mtile) and anatase), and zinc oxide. / Titanium oxide composite oxide, alumina / magnesium oxide composite oxide and calcium oxide / zirconia composite metal oxide and other composite oxides, sulfates such as barium sulfate and carbonates such as calcium carbonate; In terms of viewpoint, alumina, zinc oxide, hammer oxide, titanium oxide, and zinc oxide / titanium oxide composite oxide are preferred. These white inorganic pigments may be used alone or in combination of two or more. Further, the white inorganic pigment may be subjected to a surface treatment as necessary, such as a water-repellent lithone treatment and a water-repellent and oil-repellent fluorine treatment. In the present invention, when the white inorganic pigment subjected to the above-mentioned silicone treatment is used, the dispersibility in a general organic solvent is excellent, and when the white inorganic pigment subjected to the above-mentioned fluorine treatment is used, the dispersibility in the fluorine-based solvent is excellent. . The content of the above-mentioned white inorganic pigment in the spherical composite polymer particles is sufficient to conceal sufficiently and conceal morphological defects such as pores and small wrinkles, and other conspicuous defects. It is preferably 5% by weight or more. From the viewpoint of suppressing prominent blemishes such as pores and small wrinkles, it is preferably 60% by weight or less. Specifically, the content of the white inorganic pigment in the spherical composite polymer particles is preferably 5 to 60% by weight, and particularly preferably 20 to 50% by weight. -9- 016930 1231216 (5) Description sheet of the invention The density of the spherical composite polymer particles containing white inorganic pigment is 1.0 g / cnr & quot from the viewpoint that the particles can fully utilize the good operability of the particles without scattering. Above, and at 1.1 g / cm. The above is better, more preferably 1.25 g / cm3 or more; when the spherical composite polymer particles in the cosmetic are added at the same weight, the number of particles increases in the case of low density, and the total volume of the particles and the case of high density Compared with a larger volume, from the viewpoint of fully expressing the nature of the effective embedding of the recesses on the skin, it is desired to be 4.0 g / cm. Below, and at 2.5 g / cm. The following is more preferable, and 3.0 g / cmJ or less is more preferable. The average particle diameter of the spherical composite polymer particles is from the viewpoint of selectively adhering to pores and wrinkles, and suppressing the adhesion of the spherical composite polymer particles to the skin and mounds, and obtaining a natural finish after makeup. 5 / zm or more; 40 / m or less from the viewpoint of obtaining a good feeling of use by suppressing a rough temperature feeling and the like. Specifically, the average particle diameter of the spherical composite polymer particles is 5 to 40 / zm, more preferably 8 to 30 / zm, and even more preferably 10 to 20 / zm. The concealability of the spherical composite polymer particles is preferably 10 to 50, and more preferably 15 to 40. If the concealment is 10 or more, the pores and small wrinkles can be fully concealed, and if it is 50 or less, the pores and small wrinkles will not become white and will not be noticeable. The concealment in the present invention can be obtained by the method shown in the examples. The polymer used in the spherical composite polymer particles is not particularly limited as long as it exhibits hydrophobic properties, the polymer is transparent or translucent, and is often used in cosmetics, as described in the standards for cosmetic raw materials. (Meth) acrylic resins such as nylon resin, polyester resin, polymethyl methacrylate, polyethylene resin, polystyrene resin, polyurethane resin-10-016931 1231216 Plastic resin; silicone resin, lauryl (meth) acrylate-ethylene glycol di (meth) propionate copolymer, isostearyl acrylate-polyvinylamino acid crosslinked with divinylbenzene copolymer Cross-linked polymer resins such as ester resins. Among them, a crosslinked polymer resin is preferred from the viewpoint of being physically and chemically strong. The method of compounding the polymer and the white inorganic pigment can be appropriately selected according to the kind of polymer used. For example, when the type of the polymer is a nylon resin, paraffin wax and cyclic lactam are mixed, heated to melt, and a required amount of a white inorganic pigment powder is added to the obtained mixture, and then the mixture is fully mixed and a polymerization accelerator is added. For example, phosphorus trichloride and the like are subjected to alkali polymerization to obtain particles, and the particles are filtered, and the obtained particles are washed with an organic solvent such as isopropyl alcohol or n-hexane, and then dried. In addition, for example, when the type of the polymer is a silicone resin, an aqueous solution of ammonia or amine is mixed with a powder of a white inorganic pigment, and in the obtained mixture, hydrodegradable crushing, pyroxite burning, Hydrolyzed products of alkoxysilane and acetazine, etc., are then hydrolyzed, and then the hydrolyzed products of alkoxysilane, etc., and the hydrolyzed products of calcined oxygen, etc., or the unoxidized hydrolyzed silanes are subjected to condensation , To obtain particles, filtering the particles, and then washing the obtained particles with water, and then drying the method. Moreover, for example, in the case where the type of the polymer is a lauryl methacrylate-ethylene glycol dimethacrylate copolymer, the monomers are lauryl methacrylate and ethylene glycol dimethacrylate, It is mixed with lauryl methoxide, which is a polymerization initiator, and dissolved. Then, a required amount of a white inorganic pigment is added to the obtained mixture and dispersed, and the obtained dispersion is added to polyethylene. 11-1231216 ⑺ 茕 Ming describes the method of dispersing and dispersing the continual alcohol in an aqueous solution of alcohol, stirring while heating to carry out polymerization (eight suspension polymerization) to obtain particles, filtering the particles, washing the obtained particles with water, and then drying, etc. . The dispersion state of the white inorganic pigment in the spherical composite polymer particles is preferably a highly dispersed state from the viewpoint of optical properties such as concealment. Methods for controlling the above-mentioned dispersion state include, for example, a mechanical dispersion method using a homogenizer, a high-pressure homogenizer, an ultrasonic disperser, an attritor mill or a ball mill, or a low-molecular surfactant [for example, , Anionic surfactants (such as lauryl sulfate, and sodium polyoxyethylene lauryl ether sulfate, etc.), cationic surfactants, or nonionic surfactants, etc.], or polymeric dispersants [such as starch , Polyethylene glycol, methyl cellulose, methyl polysiloxane, etc.] and other methods of dispersion. The spherical composite polymer particles may be used alone or in combination of two or more. The content of the spherical composite polymer particles in the cosmetic varies depending on the dosage form, and is not particularly limited. However, it is desired to be 0.1 to 50% by weight, and preferably 1 to 20% by weight. As long as the content of the spherical composite polymer particles is within the above range, the so-called "obvious flaws such as pores and small wrinkles are difficult to be found" are excellent in effect, and the use feeling is also good, so it is preferable. In addition, in the cosmetic material of the present invention, in order to make the so-called cosmetic material of the present invention "there is no whiteness, the feeling of natural finish can be obtained, and morphological defects such as pores and small wrinkles can be improved." It can be used to add ingredients added to normal cosmetics as needed. Specifically, in the cosmetic material of the present invention, the effect of the so-called cosmetic material of the present invention is 016933 -12- 奁 说明 明明 绩 表 1231216 ⑻ Fruit "There is no whiteness and a natural finish can be obtained, and pores can be removed. Improvement of morphological defects such as small to wrinkles and other visible defects such as petrolatum, lanolin, ceresine, microcrystalline wax, higher fatty acids, higher alcohol, etc. Semi-solid oil, olive oil, jojoba oil, castor oil, squane, flowing paraffin, ester oil, diglyceride and triglyceride, etc. Crushed ketone oils such as silica gel, fluorine-based oils such as perfluoropolyethers and fluorine-modified hard ketones, water-soluble and / or oil-soluble polymers, mica powder, talc powder, sericite, barium sulfate and other constitutions Pigments, inorganic colored pigments such as red iron oxide, yellow iron oxide, black iron oxide, and oxide, organic colored pigments such as red 226 and yellow 401, encapsulated colored pigments such as organic colored pigments by polymer encapsulation, Organic pigments waiting Agents, and other preservatives, antioxidant agents, tackifiers, perfumes, UV absorbers, UV screening agents, bactericides, moisturizing agents and the like manufactured by sweat. The cosmetic material of the present invention can be used in the form of powder solids, high oil content powder solids, oil-dispersed, water-dispersed, water-in-oil emulsions, oil-in-water emulsions, etc. The flaws are effectively concealed, and in terms of being suitable for use as a makeup base, liquid cosmetics are better. The cosmetic materials of the present invention, in particular, can be used as, for example, cosmetic materials such as powder foundations, liquid foundations, semi-solid foundations, emulsified liquid foundations and eyebrow oils, and medicinal cosmetics such as sunscreen emulsion Emulsions such as liquids are used, but from the viewpoint of being suitable for use as a cosmetic base layer, liquid foundations, emulsified liquid foundations, and emulsions are particularly preferred. -13-016934 Description of the invention continued on 1231216 (9) In addition to the spherical composite polymer particles described above, the cosmetic of the present invention may further contain other spherical particles having high transparency and large light diffusion and transmission (halo effect). . If it is a cosmetic material further containing the above-mentioned spherical particles, it can further obtain a natural finish feeling without blushing, and exhibit the effect of improving visible defects such as pores and small wrinkles. Here, the "spherical shape" used in the term "spherical particle" includes the same as the "spherical shape" used in the "spherical composite polymer particle". The above-mentioned spherical particles are attached from the skin hill portion to the skin groove portion, and the preferred spherical particles have an average particle diameter of 1 to 10 (preferably 2 to 9) and a refractive index of 1.3 to 1.8 (to 1.4 ~ 1.6 is preferred) spherical particles. If the refractive index of the spherical particles is 1.8 or less, a more natural finish can be obtained. If the average particle diameter of the spherical particles is 1 or more, the spherical particles will not be buried in the makeup film, pores and small wrinkles, etc. The boundary part with the Piqiu part will fully show the effect of being dizzy and difficult to see, that is, the "halo effect". If it is 10 # m or less, the effect will be improved. In the present invention, the spherical particles only need to have the effects of suppressing regular reflection and random reflection, and if they have the same effect, they may be particles having a spheroid or a surface with irregularities. Specific examples of these spherical particles include metal oxides such as spherical silica and alumina, sulfates such as barium sulfate, inorganic compounds such as carbonates such as calcium carbonate, polymethylpropionate, and the like. One or two or more selected from thermoplastic resins, polymer compounds such as nylon, silicone resins, polyurethane resins, and crosslinked polymers. The content of the above-mentioned spherical particles in the cosmetic varies depending on the shape of the cosmetic, and is not particularly limited, but is desirably 0.1 to 30% by weight, and 0.5 to 10% by weight -14- 016935 1 2 1 6 00) is preferred. If the content of the spherical particles is within the above range, the effect of making pores and small wrinkles difficult to see is excellent, and the use feeling is also good, so it is preferable. Moreover, you may add the component added to the said normal cosmetics as needed. [Example] (Evaluation method) 1. Hiddenness (1) Spherical composite polymer particles L304 g were added to silicone oil (made by Shin-Etsu Chemical Co., Ltd., KF-96-1000cs) 15 g, The obtained mixture was pre-dispersed at 800 r / min for 2 minutes using a homodisper (Homodisper) (trade name: TK automatic homomixer), and was dispersed at 6000 r / min. 5 minutes to obtain a dispersed mixture. Then, vacuum degassing was performed to obtain a sample dispersion. (2) Inject the above sample dispersion into a glass case with a 20 / zm interval. One side of the case is affixed with black artificial leather, and the other side is measured by a color difference meter (produced by Benden Industries, trade name). ·· SE2000 type) Set and measure the color, and calculate the LI # value (color brightness; lightness), al + value (red-green direction chromaticity), br value (yellow-cyan direction) with, a, and surface pigment. Chroma). In addition, without injecting the sample dispersion liquid, the color of the small box made of black artificial leather was measured in the same manner, and the L2 + value (color brightness; brightness) and a2 # value (red-green direction) were calculated respectively. Chromaticity) and b2 > values (chromaticity in the red-cyan direction), and the color difference ΔΕ is calculated according to the following formula. △ E is called (LI, L2 *) 2+ (al *-a2 *) 2+ (M *-b2 *) Y / 2 The above ΔΕ is taken as the value of concealment. 016936 1231216 r—- (11) Description of the invention continued
/< 、 、 、 V 再者，對於平均粒徑超過17 ym者，使用厚度40 之間 隔，代替厚度20 之間隔 '藉由同樣操作進行測定。 2.平均粒徑之測定方法 於乙醇中適量添加球狀複合聚合體粒子，將得到之混合 物送入超音波分散機，使分散約10分鐘。繼而，將得到之 分散液送入粒度分布測定器（堀場製作所製，商品名：LA-920) ，以分散溶媒：乙醇，循環速度：4，超音波分散：1分鐘之 條件，測定體積平均粒徑。 製造例1 於300 mL容積之燒杯中，加入甲基丙婦酸月桂g旨56 g，二 甲基丙晞酸乙二醇酯19 g及月桂醯基過氧化物1.5 g，得到 溶液。又，將平均粒徑0.25 /zm之氧化鈦（石原產業製，商品 名：CR-50 )，使用甲基氫聚矽氧烷進行撥水處理（為氧化鈦 之2%)。繼而，將得到之溶液與撥水處理用之氧化鈦50 g混 合，繼而使其分散，得到分散液。然後，將上述分散液添加 於1重量％聚乙晞醇（曰本合成化學工業製，商品名：Gohsenol GH-17)水溶液750 g，使用超音波分散機分散（平均粒徑：11.5 )。將得到之分散液加入1000 mL容積之可分離式燒瓶中 ，然後，將該可分離式燒瓶内之氣相以氮置換。繼而，將 上述分散液以150 r/min攪拌，同時維持於75°C 8小時，在氮 氣蒙氣下進行聚合。聚合終了後，將得到之產物過濾，回 收固體，以水洗淨，繼而減壓乾燥，得到含有白色無機顏 料之球狀複合聚合體粒子（平均粒徑：12.9 /zm，白色無機 顏料含有率：40重量％) 120 g。依照上述評價方法，測定上 Γ:6937 -16- 1231216 f、、、…、、— (12) 發明說明續頁 述含有白色無機顏料之球狀複合聚合體粒子之隱蔽性，結 —果其隱蔽性為27.0。 · — 製造例2 除了使用未處理之氧化鈦代替製造例1中使用之撥水 處理用氧化鈦之外，進行與製造例1同樣之操作，得到含 有白色無機顏料之球狀複合聚合體粒子118 g (平均粒徑： 11.0 /zm，白色顏料含有率：40重量％)。依照上述評價方法 ，測定上述含有白色無機顏料之球狀複合聚合體粒子之隱 蔽性，結果其隱蔽性為22.4。 製造例3 於300 mL容積之燒杯中，加入苯乙晞75 g及月桂酿基過氧 化物2.0 g，得到溶液。將得到之溶液與製造例1所使用之 施行撥水處理之氧化鈦25 g混合，繼而使其分散，得到分 散液。然後，將上述分散液添加於1重量％聚乙晞醇（日本 合成化學工業製，商品名·· Gohsenol GH-17)水溶液750 g，繼而 使用超音波分散機分散（平均粒徑：11.5 /zm )。將得到之分 散液加入1000 mL容積之可分離式燒瓶中，然後，將該可分 離式燒瓶内之氣相以氮氣置換。繼而，將上述分散液以150 r/min攪拌，同時維持於75°C 8小時，在氮氣蒙氣下進行聚合 。聚合終了後，將得到之產物過濾，回收固體，以水洗淨 ，繼而減壓乾燥，得到含有白色無機顏料之球狀複合聚合 體粒子（平均粒徑：11.2 /zm，白色無機顏料含有率：25重量 %) 96 g。依照上述評價方法，測定上述含有白色無機顏料 之球狀複合聚合體粒子之隱蔽性，結果其隱蔽性為20.1。 016938 發說明續頁 123 1 2 1 6 03) 比較製造例1 除了將平均粒徑60 nm (0.06 /zm )之紫外線吸收劑級之氧 化鈦（商品名：MT-600B，帝國（Tayca)公司製）以與製造例1同 樣之方式進行撥水處理，添加如此得到之氧化鈦25 g，以 代替製造例1中使用之撥水處理用氧化鈦之外，進行與製 造例1同樣之操作，得到含有白色無機顏料之球狀複合聚 合體粒子（平均粒徑：11.0 #m，白色顏料含有率：25重量％) 120 g。依照上述評價方法，測定上述含有白色無機顏料之球 狀複合聚合體粒子之隱蔽性，結果其隱蔽性為9.1。 比較製造例2 於300 mL容積之燒杯中，加入甲基丙烯酸月桂酯56 g，二 甲基丙烯酸乙二醇酯19 g，及月桂醯基過氧化物1.5 g，得到 溶液。又，將平均粒徑0.45 之氧化鈦（石原產業製，商品 名：CR-50)，使用甲基氫聚矽氧烷進行撥水處理（為氧化鈦 之2%)。然後，將上述分散液添加於1重量％聚乙烯醇（日 本合成化學工業製，商品名：Gohsenol GH-17)水溶液750 g中， 繼而使用超音波分散機充分分散（平均粒徑：3.5 )。將得 到之分散液加至1000 mL容積之可分離式燒瓶中，然後，將 該可分離式燒瓶内之氣相以氮氣置換。繼而，將上述分散 液以250 r/min攪掉，同時於75°C維持8小時，及在氮氣蒙氣 下進行聚合。聚合終了後，將得到之產物過濾，回收固體 ，以水洗淨，繼而減歷：乾燥，得到含有白色無機顏料之球 狀複合聚合體粒子（平均粒徑：3.2 /zm，白色無機顏料含有 率：40重量％) 120 g。依照上述評價方法，測定上述含有白 -18- 016939 奁明說明續頁 1231216 ⑼ 色無機顏料之球狀複合聚合體粒子之隱蔽性，結果該含有 白色無機顏料球狀複合聚合體粒子之隱蔽性為42.4。 實施例1 使用製造例1〜3及比較製造例1及2所得到之含有白色 無機顏料之球狀複合聚合體粒子，依照表1所示之組成， 藉由以下方式，製造液狀粉底，評價使用該液狀粉底時毛 孔之難見度、小皺紋之難見度、及自然完粧之感覺。 (製法） 藉由表1所示之組成，將成分（1)〜(3)任一項與成分（4)〜⑺ 混合，將得到之混合物送入粉碎機，予以粉碎。將得到之 粉碎物添加於成分（10)中，以分散機使其分散，得到液狀 粉底（本發明品1〜3)。又，使用成分（8)或（9)代替成分（1)〜(3) 之任一項成分，並以與本發明品1〜3同樣之製法，得到液 狀粉底（比較品1及2)。 (評價方法） 使用各個液體粉底進行化粧時，對於是否可以改善形態 上之瑕疵諸如毛孔及小皺紋等顯眼瑕疵等之評價，係藉由 20人之專門評審員，以下列評價基準，針對毛孔之難見度 、小敏紋之難見度及自然之完桩感覺予以評價。 〔評價基準〕 毛孔之難見度 ◎ : 16人以上評價為難以看見毛孔。 〇：11〜15人評價為難以看見毛孔。 △ ·· 6〜10人評價為難以看見毛孔。 -19- 016940 發明说明續頁 1231216 (15) X : 5人以下評價為難以看見毛孔。 小皺紋之難見度 ◎ : 16人以上評價為難以看見小皺紋。 〇：11〜15人評價為難以看見小皺紋。 △ : 6〜10人評價為難以看見小敏紋。 X : 5人以下評價為難以看見小皺紋。 自然之完桩感覺 ◎ : 16人以上評價為有自然完粧感覺。 〇：11〜15人評價為有自然完粧感覺。 △ : 6〜10人評價為有自然完粧感覺。 X ·· 5人以下評價為有自然完粧感覺。 各液狀粉底之評價結果如表1所示。 【表1】/ <,,, V For the average particle diameter of more than 17 μm, use a thickness of 40 intervals instead of a thickness of 20 'to measure by the same operation. 2. Method for measuring the average particle size An appropriate amount of spherical composite polymer particles was added to ethanol, and the obtained mixture was fed into an ultrasonic disperser and dispersed for about 10 minutes. Then, the obtained dispersion liquid was sent to a particle size distribution measuring device (trade name: LA-920, manufactured by Horiba, Ltd.), and the volume average particle size was measured under the conditions of dispersing solvent: ethanol, circulation speed: 4, and ultrasonic dispersion: 1 minute. path. Production Example 1 In a beaker having a volume of 300 mL, 56 g of lauric acid glaucumate, 19 g of dimethyl propionate, and 1.5 g of lauryl peroxide were added to obtain a solution. In addition, titanium oxide (manufactured by Ishihara Industries, trade name: CR-50) having an average particle diameter of 0.25 / zm was subjected to water repellency treatment (2% of titanium oxide) using methylhydrogen polysiloxane. Next, the obtained solution was mixed with 50 g of titanium oxide for water repellent treatment, and then dispersed to obtain a dispersion liquid. Then, the above dispersion was added to 750 g of a 1% by weight aqueous solution of polyvinylacetate (manufactured by Ben Synthetic Chemical Industry, trade name: Gohsenol GH-17), and dispersed using an ultrasonic disperser (average particle size: 11.5). The obtained dispersion was added to a separable flask having a volume of 1000 mL, and then the gas phase in the separable flask was replaced with nitrogen. Then, the above dispersion was stirred at 150 r / min while being maintained at 75 ° C for 8 hours, and polymerization was carried out under a nitrogen blanket. After the polymerization was completed, the obtained product was filtered, the solid was recovered, washed with water, and then dried under reduced pressure to obtain spherical composite polymer particles containing a white inorganic pigment (average particle size: 12.9 / zm, white inorganic pigment content rate: 40% by weight) 120 g. According to the above evaluation method, determine the upper Γ: 6937 -16-1231216 f ,,, ... ,, (-) (12) Description of the invention The continuation page describes the concealment of spherical composite polymer particles containing white inorganic pigments, resulting in concealment The sex is 27.0. · —Production Example 2 The same operation as in Production Example 1 was carried out except that untreated titanium oxide was used instead of the titanium dioxide for water repellent treatment used in Production Example 1, and spherical composite polymer particles 118 containing a white inorganic pigment were obtained. g (average particle diameter: 11.0 / zm, white pigment content: 40% by weight). The hiding property of the spherical composite polymer particles containing the white inorganic pigment was measured according to the above-mentioned evaluation method. As a result, the hiding property was 22.4. Manufacturing Example 3 In a beaker having a volume of 300 mL, 75 g of phenethylhydrazone and 2.0 g of lauryl-based peroxide were added to obtain a solution. The obtained solution was mixed with 25 g of titanium oxide subjected to water repellent treatment used in Production Example 1, and then dispersed to obtain a dispersion. Then, the dispersion was added to 750 g of a 1% by weight aqueous solution of polyvinylacetate (manufactured by Nippon Synthetic Chemical Industry, Gohsenol GH-17), and then dispersed using an ultrasonic disperser (average particle size: 11.5 / zm). ). The obtained dispersion was charged into a separable flask having a volume of 1000 mL, and then the gas phase in the separable flask was replaced with nitrogen. Then, the dispersion was stirred at 150 r / min while maintaining the temperature at 75 ° C for 8 hours, and polymerization was performed under a nitrogen blanket. After the polymerization was completed, the obtained product was filtered, the solid was recovered, washed with water, and then dried under reduced pressure to obtain spherical composite polymer particles containing a white inorganic pigment (average particle size: 11.2 / zm, white inorganic pigment content rate: 25% by weight) 96 g. The hiding property of the spherical composite polymer particles containing the white inorganic pigment was measured according to the above evaluation method. As a result, the hiding property was 20.1. 016938 Description of Continuation 123 1 2 1 6 03) Comparative Manufacturing Example 1 Except for titanium dioxide (trade name: MT-600B, manufactured by Tayca) except for an ultraviolet absorber-grade titanium oxide having an average particle diameter of 60 nm (0.06 / zm) ) The water repellent treatment was performed in the same manner as in Production Example 1. 25 g of titanium oxide thus obtained was added in place of the water repellent titanium oxide used in Production Example 1. The same operation as in Production Example 1 was performed to obtain 120 g of spherical composite polymer particles containing a white inorganic pigment (average particle diameter: 11.0 #m, white pigment content rate: 25% by weight). The hiding property of the spherical composite polymer particles containing the white inorganic pigment was measured according to the above evaluation method. As a result, the hiding property was 9.1. Comparative Production Example 2 In a beaker having a volume of 300 mL, 56 g of lauryl methacrylate, 19 g of ethylene glycol dimethacrylate, and 1.5 g of lauryl fluorenyl peroxide were added to obtain a solution. In addition, titanium oxide (manufactured by Ishihara Industries, trade name: CR-50) having an average particle diameter of 0.45 was subjected to water repellency treatment (2% of titanium oxide) using methylhydrogen polysiloxane. Then, the above dispersion was added to 750 g of a 1% by weight aqueous solution of polyvinyl alcohol (manufactured by Nippon Synthetic Chemical Industry, trade name: Gohsenol GH-17), followed by sufficient dispersion using an ultrasonic disperser (average particle size: 3.5). The obtained dispersion was added to a separable flask having a volume of 1000 mL, and then the gas phase in the separable flask was replaced with nitrogen. Then, the above dispersion was stirred off at 250 r / min while maintaining at 75 ° C for 8 hours, and polymerization was carried out under a nitrogen blanket. After the polymerization is completed, the obtained product is filtered, the solid is recovered, washed with water, and then reduced in calendar: dried to obtain spherical composite polymer particles containing a white inorganic pigment (average particle diameter: 3.2 / zm, white inorganic pigment content rate : 40% by weight) 120 g. According to the above evaluation method, the concealment property of the spherical composite polymer particles containing white-18- 016939 奁 说 明明 说明 下 续 121216 ⑼ color inorganic pigment was measured. As a result, the concealability of the spherical composite polymer particles containing white inorganic pigment was 42.4. Example 1 Using white inorganic pigment-containing spherical composite polymer particles obtained in Production Examples 1 to 3 and Comparative Production Examples 1 and 2, according to the composition shown in Table 1, a liquid foundation was produced and evaluated in the following manner. When using this liquid foundation, the pores are hard to see, the small wrinkles are hard to see, and the natural finish is felt. (Manufacturing method) According to the composition shown in Table 1, any one of components (1) to (3) and components (4) to 4 are mixed, and the obtained mixture is sent to a pulverizer and pulverized. The obtained pulverized product was added to component (10) and dispersed by a disperser to obtain a liquid foundation (products 1 to 3 of the present invention). In addition, using the component (8) or (9) in place of any of the components (1) to (3), and using the same production method as the products 1 to 3 of the present invention, a liquid foundation was obtained (Comparative Products 1 and 2) . (Evaluation method) When using each liquid foundation for makeup, the evaluation of whether morphological defects such as pores and small wrinkles can be improved is evaluated by a special reviewer of 20 people based on the following evaluation criteria. The degree of difficulty, the degree of visibility of Xiaomin Wen, and the natural feeling of finishing the pile were evaluated. [Evaluation Criteria] Poorness of pores ◎: 16 or more people evaluated it as difficult to see pores. 〇: 11 to 15 people evaluated that it was difficult to see pores. △ · 6 to 10 people evaluated that it was difficult to see pores. -19- 016940 Description of the Invention Continued 1231216 (15) X: It is difficult to see pores when it is judged by 5 people or less. Visibility of small wrinkles ◎: 16 or more people evaluated it as difficult to see small wrinkles. 〇: 11 to 15 people evaluated that it was difficult to see small wrinkles. (Triangle | delta): 6 to 10 people evaluated that it was difficult to see a small touch. X: Five people or less evaluated that it was difficult to see small wrinkles. Natural finish feeling ◎: More than 16 people evaluated it as natural finish. 〇: 11 to 15 people rated it as having a natural finish. △: 6 to 10 people rated it as having a natural finish. X ·· 5 or less people rated it as having a natural finish. The evaluation results of each liquid foundation are shown in Table 1. 【Table 1】
成分 本發明 品 比車父品 (重量％) 1 2 3 1 2 (1)製造例1之球狀複合聚合體粒子 4.0 — 一 — — (2)製造例2之球狀複合聚合體粒子 — 4.0 — — — (3)製造例3之球狀複合聚合體粒子 一 — 4.0 — 一 (4)氧化欽 6.0 6.0 6.0 6.0 6.0 (5)紅氧化鐵 0.4 0.4 0.4 0.4 0.4 (6)黃氧化鐵 1.5 1.5 1.5 1.5 1.5 (7)黑氧化鐵 0.1 0.1 0.1 0.1 0.1 (8)比較製造例1之球狀複合聚合體 一 — — 4.0 一 粒子 (9)比較製造例2之球狀複合聚合體 — — 一 一 4.0 粒子 (10)二甲基聚矽氧烷η 88.0 88.0 88.0 88.0 88.0 毛孔之難見度 ◎ ◎ 〇 X X 小敏紋之難見度 〇 〇 〇 X X 自然之完粧感覺 ◎ ◎ ◎ ◎ XIngredients The product of the present invention is more than the car parent product (% by weight) 1 2 3 1 2 (1) Spherical composite polymer particles 4.0 in Manufacturing Example 1 — — — (2) Spherical composite polymer particles in Manufacturing Example 2 — 4.0 — — — (3) Spherical composite polymer particles in Production Example 3 — 4.0 — One (4) Oxidation 6.0 6.0 6.0 6.0 6.0 (5) Red iron oxide 0.4 0.4 0.4 0.4 0.4 (6) Yellow iron oxide 1.5 1.5 1.5 1.5 1.5 (7) Black iron oxide 0.1 0.1 0.1 0.1 0.1 (8) Spherical composite polymer 1 of Comparative Production Example 1-4.0 One particle (9) Spherical composite polymer of Comparative Production Example 2-One one 4.0 Particles (10) Dimethicone η 88.0 88.0 88.0 88.0 88.0 Visibility of pores ◎ ◎ XX Visibility of small sensitive lines 〇〇〇XX Natural finish feel ◎ ◎ ◎ X
*1 :信越化學工業（股）製，商品名：KF96A-1000CS -20- 016941 發明說明續頁 1231216 (16) 從表1所示之結果，可知與球狀複合聚合體粒子之隱蔽 性為不到10之比較品1及球狀複合聚一合體粒子之平均粒徑 為不到5 vm之比較品2相較，球狀複合聚合體粒子之隱蔽 性為20.1〜27.0且球狀複合聚合體粒子之平均粒徑為Π.0〜12.9 /zm之本發明品1〜3之任一項，毛孔難以見到之效果及小敏 紋難以見到之效果均優良。再者，本發明品1〜3除毛孔難 以見到之效果及小敏紋難以見到之效果之外，自然之完粧 感覺亦優良。 實施例2 使用製造例1〜3及比較製造例1及2所得到之含有白色 無機顏料之球狀複合聚合體粒子，依照表2所示之組成， 藉由以下方式，製造乳化液狀粉底，評價使用該乳化液狀 粉底時毛孔之難見度、小皺紋之難見度、及自然之完粧感 覺。 (製法） 藉由表2所示之組成，將為油相成分之成分（13)及成分 (14)在室溫混合。於得到之混合物中添加為水相成分之成 分（1)〜(3)之任一項與成分（4)〜(8)，以分散機使其分散。將得 到之產物一面攪拌。一面添加成分（11)及成分（12)，然後使 得到之混合物乳化，以得到乳化液狀粉底（本發明品4〜6)。 又，使用成分（9)或（10)代替成分（1)〜(3)之任一項，並以與本 發明品4〜6之製法同樣的方式，得到乳化液狀粉底（比較品 3 及 4)。 (評價方法） -21 - 016942 發明說明續頁 1231216 (17) 藉由與實施例1同樣之手法及評價基準，針對毛孔之難 見度、小皺紋之難見度及自然之完粒感覺予以評價。各乳 化液狀粉底之評價結果如表2所示。 【表2】* 1: Made by Shin-Etsu Chemical Industry Co., Ltd., trade name: KF96A-1000CS -20- 016941 Description of Invention Continued on page 1231216 (16) From the results shown in Table 1, it can be seen that the concealability with spherical composite polymer particles is not Comparing Comparative Product 1 to 10 and Comparing Product 2 with an average particle size of spherical composite polymer particles less than 5 vm, the concealability of spherical composite polymer particles is 20.1 to 27.0 and spherical composite polymer particles Any one of the products 1 to 3 of the present invention having an average particle diameter of Π.0 to 12.9 / zm is excellent in the effects that are difficult to see in pores and the effects that are hard to see in small sensitive lines. In addition, the products 1 to 3 of the present invention have an effect that is difficult to see on pores and an effect that is difficult to see on small lines, and also have a natural finish feeling. Example 2 Using the spherical composite polymer particles containing white inorganic pigments obtained in Production Examples 1 to 3 and Comparative Production Examples 1 and 2, according to the composition shown in Table 2, an emulsified liquid foundation was produced in the following manner. When this emulsion liquid foundation was used, the visibility of pores, the visibility of small wrinkles, and the natural finish feeling were evaluated. (Manufacturing method) With the composition shown in Table 2, the components (13) and (14), which are oil-phase components, were mixed at room temperature. To the obtained mixture, any one of the components (1) to (3) and the components (4) to (8), which are components of the aqueous phase, were added and dispersed by a disperser. The obtained product was stirred. While adding the component (11) and the component (12), the obtained mixture is emulsified to obtain an emulsified liquid foundation (products 4 to 6 of the present invention). In addition, component (9) or (10) was used in place of any of components (1) to (3), and an emulsion liquid foundation was obtained in the same manner as in the production method of products 4 to 6 of the present invention (Comparative Products 3 and 3). 4). (Evaluation method) -21-016942 Description of the invention continuation page 1231216 (17) By the same method and evaluation criteria as in Example 1, the pores are difficult to see, the small wrinkles are difficult to see, and the feeling of natural finish is evaluated. . Table 2 shows the evaluation results of each emulsion liquid foundation. 【Table 2】
成分 本發明 品 比幸父品 (重量％) 4 5 6 3 4 (1)製造例1之球狀複合聚合體粒子 8.0 — — 一 — (2)製造例2之球狀複合聚合體粒子 — 8.0 — — 一 (3)製造例3之球狀複合聚合體粒子 — — 8.0 — — (4)氧化鈦 6.0 6.0 6.0 6.0 6.0 (5)紅氧化鐵 0.4 0.4 0.4 0.4 0.4 (6)黃氧化鐵 1.5 1.5 1.5 1.5 1.5 (7)黑氧化鐵 0.1 0.1 0.1 0.1 0.1 (8)絹雲母 4.0 4.0 4.0 4.0 4.0 (9)比較製造例1之球狀複合聚合體 — — — 8.0 一 粒子 (10)比較製造例2之球狀複合聚合 — — — — 8.0 體粒子 (11)精製水 42.0 42.0 42.0 42.0 42.0 (12)甘油 7.0 7.0 7.0 7.0 7.0 (13)油劑” 29.0 29.0 29.0 29.0 29.0 (14)紫外線防禦材+2 2.0 2.0 2.0 2.0 2.0 毛孔之難見度 ◎ ◎ 〇 X X 小皺紋之難見度 〇 〇 〇 X X 丨 自然之完粒感覺 ◎ ◎ ◎ ◎ X *1 :矽酮油[信越化學工業（股）製] *2 :對甲氧基桂皮酸2-乙基己酯 從表2所示之結果，可知與球狀複合聚合體粒子之隱蔽 性為不到10之比較品3及球狀複合聚合體粒子之平均粒 徑為不到5 /zm之比較品4相較，球狀複合聚合體粒子之隱 蔽性為20.1〜27.0且球狀複合聚合體粒子之平均粒徑為 11.0〜12.9 之本發明品4〜6之任一項，毛孔難以見到之效 -22- 016943 發明說明讀頁 1231216 03) 果及小皺紋難以見到之效果均優良。再者，本發明品4〜6除 毛孔難以見到之效果及小Μ紋難以見到之效果之外，自然 之完粧感覺亦優良。 實施例3 使用製造例1〜3及比較製造例1及2所得到之含有白色 無機顏料之球狀複合聚合體粒子，依照表3所示之組成， 藉由以下方式製造粉末狀粉底，評價使用該粉末狀粉底時 毛孔之難見度、小皺紋之難見度及自然之完粧感覺。 (製法） 藉由表3所示之組成，將成分（1)〜(3)之任一項與成分（4)〜⑺ 及成分（10)混合，將得到之混合物送入粉碎機，予以粉碎。 將得到之粉碎物，與將成分（11)〜（13)加溫混合均勾化之混 合物’藉由高速捧合機〔三井礦山公司製’商品名：三井 漢氏混合機〕混合，以成為均質。將得到之混合物送入粉 碎機，繼而，將得到之粉碎物通過篩網，使該粉碎物之粒 度一致。將得到之粉碎物放置數日後，於金屬皿等容器中 壓縮成型，得到粉末狀粉底（本發明品7〜9 )。又，使用成分 (8)或（9)代替成分（1)〜(3)任一項成分，與本發明品7〜9之製 法同樣地，得到粉末狀粉底（比較品5及6)。 (評價方法） 藉由與實施例1同樣之手法及評價基準，針對毛孔之難 見度、小皺紋之難見度、及自然之完粧感覺予以評價。各 粉末狀粉底之評價結果如表3所示。 -23- 016944 1231216 (19) 發明嫌明續頁 【表3】 成分 - 本發明 品 比較品 (重量％) 7 8 9 5 6 (1)製造例1之球狀複合聚合體粒子 20.0 — — — 1 — (2)製造例2之球狀複合聚合體粒子 — 20.0 — — — (3)製造例3之球狀複合聚合體粒子 — — 20.0 — — (4)氧化鈥 14.0 10.0 10.0 10.0 10.0 (5)紅氧化鐵 0.8 0.8 0.8 0.8 0.8 (6)黃氧化鐵 2.5 2.5 2.5 2.5 2.5 (7)黑氧化鐵 0.2 0.1 0.1 0.1 0.1 (8)比較製造例1之球狀複合聚合體 一 — — 20.0 — 粒子 (9)比較製造例2之球狀複合聚合體 — — — — 20.0 粒子 (10)體質顏料η 52.4 52.4 52.4 52.4 52.4 (11)油劑 7.0 7.0 7.0 7.0 7.0 (12)紫外線防禦材η 3.0 3.0 3.0 3.0 3.0 (13)防腐劑Μ 0.1 0.1 0.1 0.1 0.1 毛孔之難見度 ◎ ◎ X X 小皺紋之難見度 ◎ 〇 〇 X X 自然之冗粒感覺 ◎ ◎ ◎ ◎ X *1 :滑石粉[淺田製粉（股）製] *2 :矽酮油[信越化學工業（股）製] *3 :對甲氧基桂皮酸2-乙己酯 *4 :對氧安息香酸乙酯 從表3所示之結果，可知與球狀複合聚合體粒子之隱蔽 性為不到10之比較品5及球狀複合聚合體粒子之平均粒 徑為不到5 /z m之比較品6相較，球狀複合聚合體粒子之隱 蔽性為20.1〜27.0且球狀複合聚合體粒子之平均粒徑為 11.0〜12.9 之本發明品7〜9之任一項，毛孔難以見到之效 果及小皺紋難以見到之效果均優良。再者，本發明品7〜9除 毛孔難以見到之效果及小皺紋難以見到之效果之外，自然 -24- 016945 1231216 (20) 發明說明續頁 之完粧感覺亦優良。 實施例4 — " 使用製造例1及3，及比較製造例1及2所得到之含有白 色無機顏料之球狀複合聚合體粒子，及平均粒徑4.0 ， 折光率1.49之球狀PMMA (聚甲基丙烯酸甲酯）樹脂粒子（球 狀粒子）或平均粒徑8.0 //m，折光率1.56之球狀尼龍樹脂粉 體（球狀粒子），依照表4所示之組成，製造乳化液狀粉底， 評價使用該乳化液狀粉底時毛孔之難見度、小皺紋之難見 度及自然之完粧感覺。 (製法） 藉由表4所示之組成，將成分（1)或（2)之任一項、成分（3) 或（4)之任一項與成分（5)〜(9)混合。將得到之混合物送入粉 碎機，予以粉碎。將得到之粉碎物與成分（14)及成分（15)， 以分散機使其分散。將得到之產物攪拌同時添加成分（12) 及成分（13)，使得到之混合物乳化，得到乳化液狀粉底（本 發明品10及11)。又，使用成分（10)或（11)代替成分（1)或（2) 之任一項，與本發明品10及11之製法同樣地進行操作，得 到乳化液狀粉底（比較品7及8)。 (評價方法） 藉由與實施例1同樣之手法及評價基準，針對毛孔之難 見度、小皺紋之難見度、及自然之完粧感覺，予以評價。 各乳化液狀粉底之評價結果如表4所示。 【表4】 成分 本發明品 比較品 (重量％) 10 11 7 8 (1)製造例1之球狀複合聚合體粒子 6.0 — — — -25- 016946 發明邊确續頁 1231216 (21)Ingredients The product of the present invention is better than the parent product (% by weight) 4 5 6 3 4 (1) Spherical composite polymer particles of Production Example 8.0 — — — — (2) Spherical composite polymer particles of Production Example 2 — 8.0 — — (3) Spherical composite polymer particles in Production Example 3 — — 8.0 — — (4) Titanium oxide 6.0 6.0 6.0 6.0 6.0 (5) Red iron oxide 0.4 0.4 0.4 0.4 0.4 (6) Yellow iron oxide 1.5 1.5 1.5 1.5 1.5 (7) Black iron oxide 0.1 0.1 0.1 0.1 0.1 (8) Sericite 4.0 4.0 4.0 4.0 4.0 (9) Spherical composite polymer of Comparative Manufacturing Example 1--8.0 One particle (10) Comparative Manufacturing Example 2 Spherical composite polymerization — — — — 8.0 Volume particles (11) Refined water 42.0 42.0 42.0 42.0 42.0 (12) Glycerin 7.0 7.0 7.0 7.0 7.0 (13) Oil agent ”29.0 29.0 29.0 29.0 29.0 (14) Ultraviolet defense material +2 2.0 2.0 2.0 2.0 2.0 Pore visibility ◎ ◎ XX Small wrinkles visibility 〇〇〇XX 丨 Natural finish feeling ◎ ◎ ◎ ◎ X * 1: Silicone oil [Shin-Etsu Chemical Industry Co., Ltd.] * 2: 2-ethylhexyl p-methoxycinnamic acid From the results shown in Table 2, it was found that the compound was spherically compounded. Concealment of composite particles with a concealability of less than 10 and comparative product 4 with an average particle size of spherical composite polymer particles of less than 5 / zm. Concealability of spherical composite polymer particles is 20.1 ~ 27.0 And the spherical composite polymer particles have an average particle diameter of 11.0 to 12.9, any of the products 4 to 6 of the present invention, the effect is difficult to see pores -22- 016943 Description of the invention reading page 1231216 03) fruit and small wrinkles are difficult to see In addition, the products 4 to 6 of the present invention have an effect that is difficult to see in pores and an effect that are difficult to see in small M lines, and also have a natural finish feeling. Example 3 Use Manufacturing Example 1 to The spherical composite polymer particles containing white inorganic pigments obtained in 3 and Comparative Production Examples 1 and 2 were produced in the following manner according to the composition shown in Table 3 to evaluate the difficulty of pores when using the powdery foundation. Visibility, difficulty of wrinkles, and natural finish. (Manufacturing method) According to the composition shown in Table 3, any one of ingredients (1) to (3) and ingredients (4) to ⑺ and ingredients (10) Mix and feed the obtained mixture into a pulverizer and pulverize. The obtained pulverized material is mixed with a mixture of components (11) to (13) heated and mixed, and then mixed with a high-speed kneader [Mitsui Mining Co., Ltd.'s trade name: Mitsui Han's Mixer] to obtain Homogeneous. The obtained mixture was sent to a pulverizer, and the obtained pulverized material was passed through a screen to make the particle size of the pulverized material uniform. The obtained pulverized material was left for several days, and then compression-molded in a container such as a metal dish to obtain a powdery foundation (products 7 to 9 of the present invention). In addition, using component (8) or (9) instead of any of the components (1) to (3), a powdery foundation was obtained in the same manner as in the method for producing products 7 to 9 of the present invention (Comparative Products 5 and 6). (Evaluation method) By the same method and evaluation criteria as in Example 1, the visibility of pores, the visibility of small wrinkles, and the natural finish feeling were evaluated. The evaluation results of each powdery foundation are shown in Table 3. -23- 016944 1231216 (19) Discovery of the invention continued [Table 3] Ingredient-Comparative product of the present invention (% by weight) 7 8 9 5 6 (1) Spherical composite polymer particles of Production Example 2 2 — — — 1 — (2) Spherical composite polymer particles in Production Example 2 — 20.0 — — — (3) Spherical composite polymer particles in Production Example 3 — 20.0 — — (4) Oxidation — 14.0 10.0 10.0 10.0 10.0 (5 ) Red iron oxide 0.8 0.8 0.8 0.8 0.8 (6) Yellow iron oxide 2.5 2.5 2.5 2.5 2.5 (7) Black iron oxide 0.2 0.1 0.1 0.1 0.1 (8) Spherical composite polymer 1 of Comparative Manufacturing Example 1 — — 20.0 — Particles (9) Spherical composite polymer of Comparative Production Example 2 — — — 20.0 Particles (10) Constitution pigment η 52.4 52.4 52.4 52.4 52.4 (11) Oil agent 7.0 7.0 7.0 7.0 7.0 (12) Ultraviolet shielding material η 3.0 3.0 3.0 3.0 3.0 (13) Preservative M 0.1 0.1 0.1 0.1 0.1 Pore visibility ◎ XX XX Small wrinkle visibility ◎ 〇XX Natural feeling of redundant grain ◎ ◎ ◎ ◎ X * 1: Talc powder [Asada Manufacturing ( [Manufacturing]] * 2: silicone oil [Shin-Etsu Chemical Industry Co., Ltd.] * 3: p-methoxyquinyl 2-Ethylhexyl pivalate * 4: Ethyl p-benzoate According to the results shown in Table 3, it can be seen that the concealability with spherical composite polymer particles is less than 10 and that of Comparative Product 5 and spherical composite polymer particles Compared to Comparative Product 6, which has an average particle size of less than 5 / zm, the concealability of the spherical composite polymer particles is 20.1 to 27.0 and the average composite particle size of the spherical composite polymer particles is 11.0 to 12.9. According to any one of 9, the effect that is hard to see on pores and the effect that is hard to see on small wrinkles are excellent. In addition, the products 7 to 9 of the present invention have effects that are difficult to see on pores and effects that are hard to see on small wrinkles, and naturally -24- 016945 1231216 (20) Description of the invention The finish of the continuation page is also excellent. Example 4-" Spherical composite polymer particles containing white inorganic pigments obtained in Manufacturing Examples 1 and 3 and Comparative Manufacturing Examples 1 and 2 and spherical PMMA (polymer with an average particle diameter of 4.0 and a refractive index of 1.49) Methyl methacrylate) resin particles (spherical particles) or spherical nylon resin powder (spherical particles) with an average particle diameter of 8.0 // m and a refractive index of 1.56, according to the composition shown in Table 4, to produce an emulsion The foundation was evaluated for the visibility of pores, the visibility of small wrinkles, and the natural finish feeling when using this emulsion liquid foundation. (Manufacturing method) According to the composition shown in Table 4, any one of the components (1) or (2) and any one of the components (3) or (4) is mixed with the components (5) to (9). The resulting mixture was sent to a pulverizer and pulverized. The obtained pulverized material, the component (14) and the component (15) were dispersed by a disperser. The obtained product was stirred while components (12) and (13) were added, and the resulting mixture was emulsified to obtain emulsified liquid foundations (products 10 and 11 of the present invention). Moreover, using component (10) or (11) instead of any of component (1) or (2), it carried out similarly to the manufacturing method of this invention product 10 and 11, and obtained emulsion liquid foundation (comparative products 7 and 8). ). (Evaluation method) By the same method and evaluation criteria as in Example 1, the visibility of the pores, the visibility of the small wrinkles, and the natural finish feeling were evaluated. The evaluation results of each emulsion liquid foundation are shown in Table 4. [Table 4] Ingredient The product of the present invention Comparative product (% by weight) 10 11 7 8 (1) Spherical composite polymer particles of Production Example 6.0 6.0 — — — -25- 016946 Confirmation of the invention continued page 1231216 (21)
(2)製造例2之球狀複合聚合體粒子 - 8.0 — — (3)球狀粒子（PMMA樹脂）” 2.0 — 2.0 — (4)球狀粒子（尼龍樹脂Γ - — 2.0 — 2.0 (5)氧化鈥 6.0 6.0 6.0 6.0 (6)紅氧化鐵 0.4 0.4 0.4 0.4 (7)黃氧化鐵 1.5 1.5 1.5 1.5 (8)黑氧化鐵 0.1 0.1 0.1 0.1 (9)絹雲母 4.0 4.0 4.0 4.0 (10)比較製造例1之球狀複合聚合 體粒子 — 6.0 (11)比較製造例2之球狀複合聚合 體粒子 — 6.0 (12)精製水 42.0 42.0 42.0 42.0 (13)甘油 7.0 7.0 7.0 7.0 (14)油劑” 29.0 29.0 29.0 29.0 (15)紫外線防禦材M 2.0 2.0 2.0 2.0 X =毛孔之難見度 ◎ ◎ Δ 小皺紋之難見度 ◎ 〇 X X 自然之完粧感覺 ◎ ◎ ◎ X *1 ··松本油脂製藥（股）製，商品名：松本微球粒M-201 *2 :東麗（股）製，商品名：SP500 *3 :矽酮油[信越化學工業（股）製] *4 :對甲氧基桂皮酸2-乙基己酯 從表4所示之結果，可知與球狀複合聚合體粒子之隱蔽 性為不到10之比較品7及球狀複合聚合體粒子之平均粒 徑為不到5 Am之比較品8相較，球狀複合聚合體粒子之隱 蔽性為20.1〜27.0且球狀複合聚合體粒子之平均粒徑為 11.0〜12.9 /zm之本發明品10及11之任一項，毛孔難以見到之 效果及小皺紋難以見到之效果均優良。再者，本發明品10 及11除毛孔難以見到之效果及小皺紋難以見到之效果之 外，自然之完粧感覺亦優良。 【發明之效果】 016947 26 1231216 (22) 若依照本發明，由於可使具有特定組成之球 —體粒子選擇性地附著於毛孔及小皺纹·"等處，所 謂「形態上之瑕疵諸如毛孔或小皺紋等顯眼瑕 看見」之優良效果。更且，若依照本發明，由 複合聚合體粒子幾乎不會附著於皮丘部，整 均勻，可促進所謂「得到自然完粧感覺」之優 -27- 奋明說明續頁 狀複合聚合 以可促進所 疵等難以被 於上述球狀 體亮度變得 良效果。 016948(2) Spherical composite polymer particles of Production Example 2-8.0 — — (3) Spherical particles (PMMA resin) ”2.0 — 2.0 — (4) Spherical particles (nylon resin Γ-— 2.0 — 2.0 (5) Oxidation — 6.0 6.0 6.0 6.0 (6) Red iron oxide 0.4 0.4 0.4 0.4 (7) Yellow iron oxide 1.5 1.5 1.5 1.5 (8) Black iron oxide 0.1 0.1 0.1 0.1 (9) Sericite 4.0 4.0 4.0 4.0 (10) Comparative manufacturing Spherical composite polymer particles of Example 1 — 6.0 (11) Comparative spherical composite polymer particles of Manufacturing Example 2 — 6.0 (12) Purified water 42.0 42.0 42.0 42.0 (13) Glycerin 7.0 7.0 7.0 7.0 (14) Oil agent ” 29.0 29.0 29.0 29.0 (15) Ultraviolet defense material M 2.0 2.0 2.0 2.0 X = Inaccessibility of pores ◎ △ Δ Inaccessibility of small wrinkles ◎ XX Natural finish makeup feeling ◎ ◎ X * 1 ·· Matsumoto Oil Pharmaceutical (Stock) system, product name: Matsumoto microspheres M-201 * 2: Toray (stock) system, product name: SP500 * 3: Silicone oil [Shin-Etsu Chemical Industry Co., Ltd.] * 4: Paramethyl 2-Ethylhexyl cinnamate From the results shown in Table 4, it was found that the concealability with the spherical composite polymer particles was less than 10 for the comparative product 7 and the sphere Compared with Comparative Product 8 where the average particle size of the composite polymer particles is less than 5 Am, the concealability of the spherical composite polymer particles is 20.1 to 27.0 and the average particle size of the spherical composite polymer particles is 11.0 to 12.9 / zm. Any of the products 10 and 11 of the present invention has excellent effects that are difficult to see on pores and the effect that is difficult to see on small wrinkles. Furthermore, the effects that are difficult to see on pores and small wrinkles of the products 10 and 11 are difficult to see In addition to the effect, the natural finish is also excellent. [Effect of the invention] 016947 26 1231216 (22) According to the present invention, since the sphere-body particles having a specific composition can be selectively attached to pores and small wrinkles · "In other places, the so-called" defects in morphology such as pores or small wrinkles are visible. "Moreover, according to the present invention, the composite polymer particles hardly adhere to the skin hills and are uniform. It can promote the so-called "getting a natural finish feeling". -27- Fen Ming explained that the continuum-like composite polymerization can promote the defects such as the brightness of the spheroids which are difficult to become a good effect. 016948