TWI230197B - Detergent builder and detergent - Google Patents

Abstract

The present invention provides a detergent builder for detergent and a detergent comprising the detergent builder. The detergent builder has good compatibility with surfactants and excellent detergency, especially, against mud dirt in washing clothes. The detergent comprises an organic amine salt or a quaternary ammonium salt (A) of a carboxyl group-containing polymer, and a nonionic surfactant (B) represented by the following general formula: a general formula RO-(A1O)p-H (wherein R is an aliphatic hydrocarbon group having 8 to 18 carbon atoms, p is an integer of 1 to 30 and A1 is an alkylene group having 2 to 4 carbon atoms.)

Description

1230197 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 -------- R7___ V. Description of the Invention (1) The present invention relates to a detergent builder and detergent. More specifically, it relates to a detergent builder and a detergent which are excellent in the cleaning of sludge. Conventionally, as builders for detergents, alkali metal salts of polyacrylic acid and polyitaconic acid, copolymers of acrylic acid and maleic acid, and the like are known. In addition, detergents used for household clothes are generally mainly mixed with alkylbenzene sulfonic acid, alkyl sulfate, fatty acid ammonium, alkali metal salt of inorganic acid, polyoxyalkylation advanced Surfactants of alcohol and phenol. However, the alkali metal salt of polycarboxylic acid has a problem of being poorly compatible with a surfactant which can improve the detergency. The inventors have made painstaking research to obtain a detergent with excellent compatibility with surfactants and strong detergency for sludge. As a result, they have found that the detergent and detergent used in the detergent of the present invention Those who can achieve the above objectives; finally completed the present invention. '' That is, the present invention refers to: a builder for a detergent composed of an organic amine salt or a quaternary ammonium salt (A) containing a polymer containing a tertiary group; the builder and the nonionic surfactant A cleaning agent composed of a cleaning agent manufactured by adding an epoxy alcohol (bl) to an aliphatic alcohol (ai) and containing a non-ionic surfactant 满足 which satisfies the following conditions ① and ②; further comprising a cationic surfactant ⑹ and / or low molecular weight polyvalent polyacid organic amine salt or quaternary salt ⑼ detergent; where ① and ② refer to: ① weight average molecular weight (Mw) and number average molecular weight (by the ratio of · · Mw / Mn satisfies the following relational expressions (3) or (4); [Num. 7] This paper size applies to China National Standard (CNS) A4 (210 X 297) ----- U-IIH.- --Install -------- order --------- line win (please read it first, read the notes on the back, then fill in this page) 4 1230197

Mw / Mn ^ 0.030Ln (v) + 1.010 (only, ν < 1〇) (3) [Number 8] Mw / Mng-G.G26Ln (v) + 1_139 (only, v—ig) ⑷ (quasi 'v Refers to the average addition mole number per mole of alkylene oxide (^) added to the aliphatic alcohol (al); ② The distribution parameter obtained from the following formula (5) ^ is below two mountains; [ Number 9] c- (v + n0 / n00- l) / [Ln (n00 / n0) + n〇 / n00- 1] ⑺ (However, v is related to (3) or ⑷; refers to Molar number of reacted aliphatic alcohol (al); ^ refers to the molar number of unreacted aliphatic alcohol (al). Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs.

As the carboxyl group-containing polymer used in the present invention, α is used, and in the case of a polymer having an unsaturated carboxylic acid as an essential constituent unit, it is exemplified. The α, / 3-unsaturated carboxylic acids can be exemplified by the following acids, such as: monocarboxylic acids ((m) acrylic acid, etc.), dicarboxylic acids (maleic acid, fumaric acid, itaconic acid, citraconic acid) Acid, etc.), dicarboxylic anhydride (maleic anhydride, itaconic anhydride, citraconic anhydride, etc.); and dicarboxylic acid half esters {with dicarboxylic acids and alkanols, methanol or cellosolves having 2 to 16 carbon atoms Half-esters, such as maleate maleate (monobutyl maleate, male & C monoethyl methanolate, etc.), fumarate semi-vinegar (monobutyl fumarate, monoethyl fumarate) Etc.)} and other acids, and a combination of the above acids. The best of these acids is acrylic acid. 'Another polymerizable monomer can be used as a constituent unit in the aforementioned polymer. Another single system such as the following is not limited to this; (a) Aromatic ethylenically unsaturated monomers ...

This paper size applies to China National Standard (CNS) A4 (21〇 X 297 public love)

1230197 V. Description of the invention (3) Benzoline, α-Basic base, ethyltoluene, and styrene based on acetophenone, etc .; substitution of styrenics such as styrene of dichlorostyrene, etc. (B) aliphatic ethylenically unsaturated monomers with 2 to 20 carbon atoms: ethylene, propylene, butene, isobutylene, pentene, heptene, diisobutylene, octene, twelve Olefins such as alkenes and octadecene; diolefins such as butadiene and isoprene; (c) cycloaliphatic ethylenically unsaturated monomers having 5 to 15 carbon atoms: cyclopentadiene, spinene, Limonene, gadolinium, dicyclopentadiene, ethylidene norbornene, etc .; (d) Alkyl (m) acrylates having 1 to 50 alkyl carbon atoms: methyl (m) acrylic Acid g, ethyl (m) acrylic acid, propyl (m) acrylate, butyl (m) acrylate, 2-ethylhexyl (m) acrylate 'undecyl (m) acrylate, Hexadecyl (m) acrylate, heptadecyl (m) acrylate, eicosyl (m) acrylate, etc .; Esters of ethylenically unsaturated monomers (amounts 44 to 2000) (the aforementioned a, y3-unsaturated carboxylic acids): hydroxyalkyl (methane) acrylates, hydroxypropyl (m) acrylates, etc. Number of atoms 2 ~ 6) (m) acrylate, polyethylene glycol (molecular weight 300) mono (m) acrylate, polypropylene glycol (molecular weight 500) mono (m) acrylate, 10 moles with methanol ethylene oxide (Poly) alkylene oxide groups (molecular weight 44 to 2000; 2 to 4 carbon atoms) Base) (inter) acrylic acid esters; and the aforementioned α, except for the equivalent (inter) acrylic acid esters of the above-mentioned acid esters, a paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) (please (Read the precautions on the back before filling this page)

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Unsaturated acid; (f) Ethyl ethylenically unsaturated monomers containing amidine: (m-) acrylamide, N-methanol-based (m-) acrylamine, etc .; (g) Monomers: Vinyl sulfonic acid, (m) dilute propyl dibasic acid, 2 methylene groups, 3 m (m) propoxypropanesulfonic acid, styrene sulfonic acid, α-methylstyrene sulfonic acid, sulfo Propyl (m-) acrylate, 2-hydroxy-1, 3- (m-acryloxypropanesulfonic acid), 2 ~ (m-) propenylaminoamino-2,2-dimethylethanesulfonic acid, and 2- ( M) Sulfonate-containing monomers such as propenyloxyethanesulfonic acid, etc., and sulfates of polyoxyalkane mono (m) acrylates (this oxyalkane refers to an oxygen group having 2 to 4 carbon atoms) One or two or more alkane mixtures; two or more compounds can be added in a random or block polymerization manner, and the addition mole number is usually 丨 ~ 30). In the aforementioned polymer, the content of an unsaturated fatty acid in terms of constituent units is usually 50 to 100 mol. /. It is more preferably 70 to 100 mole%, and the content of another monomer is usually 0 to 50 mole%, and more preferably 0 to 30 mole%. The polymer can be produced by radical polymerization of the aforementioned monomers. In this case, a radical polymerization initiator can be used. Available as radical polymerization initiators are: 2,2, -azobisisobutyronitrile, 2,2, monoazobis (2,4-dimethylvaleronitrile), 2,2, Mono-azobis (2-methylbutyronitrile), 2,2'-azobis (2,4,4-trimethylpentane), monomethyl-2,2-azobis (2-methyl Propionate), 2,2'-Azobis [2- (hydroxymethyl) propionitrile], 1,1, -Azobis (1-Acetyl- 1-Phenylethane) This paper is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the back ^ / Note? Matters before filling out this page) | Installation -------- Order --------- : Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 7 1230197 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (such as azo compound; dibenzyl peroxide, dicumyl peroxide , Bis-0-butylhexyl) peroxydicarbonate, benzene peroxide, laurel peroxide, laurel, and other organic peroxides; inorganic peroxides such as persulfate, perphoate, hydrogen peroxide, etc. Thing. In addition, a redox initiator composed of a combination of the above compounds and a reducing agent can be used. Reducing agents used in redox initiators are, for example, ascorbic acid (salt), carved white powder, hypolinous acid (salt), sulfurous acid (salt), bisulfite (salt). The polymerization initiators may be used in combination of two or more. The amount of the redox polymerization initiator is generally 0.01 to 20% by mass relative to the total mass of the α, β-unsaturated acid and / or another monomer, and 10 is preferably Li / 0, especially '. 1 to 2% by mass is more preferable. In addition, when the aforementioned monomer is subjected to redox, a bond transfer agent may be used, and as the chain transfer agent, for example, dodecathiol, acetic acid, ethyl alcohol, and triethylene glycol dithiol may be used. The amount of red chain transfer agent is relative to α, the king of unsaturated unsaturated acid and / or another monomer! Generally, it is 0.001 mol% to 10 mol%, and preferably mol% to 3 mol%. In addition, the redox polymerization system can be used in methods such as bulk polymerization, emulsion polymerization, suspension polymerization, and solution polymerization. Among them, solution polymerization is better, and polymerization is 50 ~ 300. 〇, preferably 60-250 ° C. The polymerization temperature used in the polymerization of the coupling liquid is a temperature that can be used below the Buddha's point of the polymerization solvent or above the fulcrum point. The temperature above the stagnation point of the polymerization solvent is preferred.

"Installation -------- Order --------- line (please read the back ^ / notes before filling out this page) 掴 This paper size applies Chinese National Standard (CNS) A4 specification (21 〇297 mm) 1230197 A7 B7 V. Description of the invention (6). Here, the boiling point means the boiling point at normal pressure. According to the gel permeation chromatography (hereinafter abbreviated as Gpc) of the polymer, the Mn in the knife is usually 1,000 to 100,000, and more preferably 3,002,30,000. The weight average molecular weight of GPC is usually ~ 110,000, preferably 3,300 ~ 33,000. The acid value of the polymer is usually, preferably, ~ 1,000. The organic amine used when the organic amine salt of the polymer is used is, for example, an aliphatic amine, an alicyclic amine, a heterocyclic amine, or Alcohol amines, or alkylene oxide adducts of these compounds ^. Examples of aliphatic amines include the following compounds, such as hexylamine, octylamine, methylhexylamine, methyloctylamine, dimethylhexylamine, dimethyloctylamine, dimethyllaurylamine and dimethyldeca Mono-, di-, and tri-trialkylamines having 1 to 18 carbon atoms, such as hexaalkylamine. The cycloaliphatic amine system can be exemplified by the following examples, such as cyclobutylamine, cyclohexylamine, cyclopentamine, cyclooctylamine, N-methylcyclohexylamine-ethylcyclohexylamine, etc. Cycloalkylamines of alkyl groups; and alkyl (carbon number 1 to 6) substituents of these compounds. Heterocyclic amines can be exemplified by heterocyclic amines having 4 to 10 carbon atoms in morpholine and the like, while alcohol amines can be, for example, monoethanolamine, diethanolamine, triethanolamine, and the like having a reverse atom number of 2 to 8 Examples of mono-, di-, and trishydroxylamines of alkyl groups. Examples of the alkylene oxides of the above alkylene oxide adducts include ethylene oxide,% oxypropane, and butylene oxide. Among them, ethylene oxide is preferred. The addition Mohr number of these compounds is usually suitable for each active hydrogen, which is suitable for the paper size _ Home Standard (CNS) A4 size ⑵G x 297) _ 9 1230197 A7 B7 V. Description of the invention (2 Mol. Examples of such alkylene oxide adducts include dihydroxyethylhexylamine, mesitylethylmethylhexylamine, etc. The quaternary ammonium salt of the polymer is based on the quaternary ammonium cation. For example, such as trimethylethylammonium, triethylmethylammonium, trimethylhexyl, trimethyloctyl, tributyloctylammonium, trimethyldecylammonium, trimethyltetradecyl, trimethyldecyl Six carbon atoms and monomethyl dioctyl ammonium and other carbon atoms 丨 ~ 18 alkyl tetraalkylammonium; n, n dimethyl cyclohexyl ammonium and N, N-diethyl cyclohexyl ammonium 4 carbon atoms ~ 12 Cycloalkyl and carbon number 丨 ~ 6 alkyl cycloalkyl dialkylammonium; trihydroxyethylhexyl ammonium, etc. 2 ~ 8 hydroxyalkyl and carbon number 丨 ~ 6 alkyl trihydroxy Burning base, burning money, etc. Among the above compounds, s is a salt derived from an aliphatic or cycloaliphatic amine or an alkylene oxide adduct thereof, preferably a quaternary ammonium salt of these compounds. .and then The preferred one is a salt formed by a quaternary ammonium cation having 2 to 12 carbon atoms, and the particularly preferred one is triethylmethylammonium salt, triethyloctyl salt, trimethyldecanonium salt, and trimethylamine. Hexyl ammonium salt and trimethyloctyl salt. The employees of the Ministry of Intellectual Property Bureau consume organic polymer amine salt of the polymer, which can be synthesized by organic amine neutralization with the polymer. At this time, a solvent can be used in the solution. As a solvent, there can be mentioned, for example: water, alcohols (methanol, ethanol, isopropanol, etc.), amidines (propanone, methyl isobutyl formamide, etc.), and trips (diethyl chloride, tetrahydrofuran, etc.) ), Aliphatic hydrocarbons (hexane, heptane, etc.), aromatic hydrocarbons (toluene, xylene, etc.) and mixtures of the above compounds as examples. Also, when using a non-ionic surfactant w, the polymer After the organic amine is neutralized, the non-ionic surfactant may be mixed, and the polymer and the non-ionic interfacial activity may be mixed together with the organic amine. The degree of neutralization is usually 30 to 100. %, Applicable to Chinese paper standard (CNS) A4 (210 X 297 public love "

I 1230197 A7 B7 V. Description of the invention (8) The best is 60 ~ 1000 /. . The quaternary ammonium salt of the polymer can be manufactured by ordinary methods, such as the number of carbon atoms used to combine secondary amines with alkyl compounds or aryl halides (such as: methyl chloride, bromoethane, and bromobenzene). Hydrazone compound) reaction as a quaternary ammonium compound, and then reacting this with a hydroxide (such as sodium hydroxide, potassium nitrate) to obtain a quaternary ammonium carbonate, the polymer is neutralized with this substance Method, and reacting a primary amine with a dialkyl (carbon number 1 to 6) carbonate (such as dimethyl carbonate, diethyl carbonate) to obtain a quaternary ammonium carbonate, The polymer is anion-exchanged. The neutralization or anion exchange system can be performed in a solution using a solvent used for neutralization with an organic amine. When using a non-ionic surfactant, it can be mixed before or after neutralization or non-ion exchange, as with organic amines. Specifically, the polymer is non-ion-exchanged with a quaternary ammonium carbonate. The method is as follows: for the salt of polyacrylic acid and trimethyloctyl ammonium, by putting monomethyloctylamine 1 mol and dimethyl carbonate equal to or more than mol carbonate and methanol into a pressure-resistant container, Under a pressure of 5 kg / cm2, it is about 120. This was reacted with each other to obtain a methanol solution of trimethyloctylammonium carbonate. Immediately, the methanol solution of trimethyloctylammonium carbonate was added slowly to the aqueous solution of polyacrylic acid at 80 ~ 90 ° C, and the carbon dioxide and methanol generated were distilled off to obtain the trimethyloctylammonium salt of polyacrylic acid. Of an aqueous solution. The degree of neutralization or anion exchange is usually 30 ~ 100%, preferably 60 ~ 100%. The solubility parameter of the polymer's amine salt or quaternary ammonium salt Home Standard (CNS) A4 Specification (210 X 297) (Please read the back ^ Note before filling in this page) Order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 11 1230197

5. Description of the invention (hereinafter referred to as SP value in (9)) is from the viewpoint of solubility in the detergent, usually 8.0 to 12.0 ', preferably 8.5 to n5. When it is in the range of 80 to 120, the cleaning power can be improved, and the solubility in the detergent can be improved. The SP value can be expressed by a general formula; a general formula 5 = (ΔH / V) 1/2 (6). However, in the formula, ㈠ refers to the SP value, refers to the Mohr steamed ㈣㈣), and V refers to the Mohr volume (cm2). Here, the sp value can be determined by the Mohr's evaporation heat (△ &) of the atomic group disclosed in "P0LYMER engineering and FEBRUARY, 1974, Vol.14, No.2, ROBERT F. FEDORS. (Pages 151 ~ 153)". The total (ΔH) and the total (v) of the mole volume (Δ,) are calculated. The cleaning agent of the present invention is a combination of a detergent builder and a nonionic surfactant (B) formed from an organic amine salt or a quaternary ammonium salt (A) of a polymer. The non-ionic surfactant (B) is exemplified by an alkylene oxide addition-molded non-ionic surfactant (b-1) and a polyvalent alcohol-type non-ionic surfactant (b-2). (b-1) is an oxide of a higher alcohol (carbon number 8 to i8) alkylene group (carbon number 2 to 4) (additional mole number of each active hydrogen is 1 to 3) Adducts, alkyl (1 to 12 carbon atoms) phenol ethylene oxide (additional mole number of 1 to 30 per active fluorene) adducts, fatty acids ($ 18 to 18 carbon atoms) ring Oxyethane (additional moles per active hydrogen is 1 ~ 30), adducts, polypropylene glycol (molecular weight 200 ~ 4000), ethylene oxide (additional moles per active hydrogen is 1 ~ 50) Adducts, and polyethylene oxide (Each active paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm)) (Please read the precautions on the back before filling this page)- ------ Order --------- line j Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 12 1230197 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (10) Hydrogen The addition mol number is 1 to 3) the alkyl group (dilute propylene ether with carbon atoms, sorbitan monolaurate ethylene oxide (addition mol number 丨 ~ 3)) adduct, sorbus Sugar Alcohol Monooleate Polyvalent (2 to 8 or more) alcohols (2 to 30 or more) alcohols (2 to 30 or more) of fatty acids (8 to 24 carbons) of ethylene oxide (additional mole number 丨 to 30) Ethylene oxide (additional mole number 1 to 30 per active hydrogen), etc. (b-2) are such as: glycerol monostearate, glycerol monooleate, sorbitan monolaurate Acid, sorbitan monooleate and other polyvalent (2 to 8 or more) alcohols (2 to 30 carbon atoms) fatty acids (8 to 24 carbon atoms) vinegar, lauric acid monoethanolamine, Fatty alcohols such as diethanol ammonium laurate, etc. Among the above compounds, (b- 丨) is preferred, and compounds represented by the following general formula (1) are more preferred, especially the following general formula (2) The compound represented is preferably 〇RO — (A10) p — Η ⑴ [Chemical formula 6] R0-[(C2H40) n · (A20) m]-(C2H40) q- (A20) rH (2) The general formula In (1) or (2), R means an aliphatic nicotyl group having 8 to 18 carbon atoms, preferably an aliphatic hydrocarbon group having 10 to 18 carbon atoms. The number of carbon atoms is within the range of 8 to 18. Good detergency can be obtained. Specifically, the fe-based system If there are: saturated aliphatic hydrocarbon groups such as octyl, 2-ethylhexyl, decyl, lauryl, myristyl, palmyl, stearyl, U-dimethyloctyl; octenyl, decenyl, Unsaturated aliphatic hydrocarbon groups such as dodecenyl, tridecenyl, pentadecyl, oleenyl, linoleyl (alkenyl, double paper standards are applicable to China National Standard (CNS) A4 specifications (21〇χ 297 mm) (Please read the notes on the back before filling out this page)

π equipment -------- order --------- line I 13 1230197 q A7 V. Description of the invention (u-methyl, tri- and polyalkenyl); and ethylcyclohexyl, Cycloaliphatic nicotyl, such as propylcyclohexyl, octyllohexyl, nonylcyclohexyl and the like. The above aliphatic fe groups can be linear or branched. In the general formula (!), A refers to an academy group having 2 to 4 carbon atoms. Specific examples include ethylene, propylene and butyl groups. (A1.) The unit is 2 or more inches' single type, random type, and block type. In addition, p is an integer of 30, preferably 6 to 20. 1> When the range is from 1 to 3, better detergency can be obtained. In the general formula (2), A2 refers to an alkylene group having 3 or 4 carbon atoms, and n refers to an integer of 0 or 1 to 12, and more preferably 1 to 10. In addition, q is an integer of from 16 to 16, preferably 2 to 12. When η is 0 or in the range of 1 to 8, and when it is in the range of 1 to 16, a good detergency can be obtained. In addition, m is an integer of 0 or 1 to 6, and more preferably is 4 to 4. In addition, ^ means an integer of 0 or 1 ~ 15, preferably 丨 ~ 8. When ⑺ is ❻ or an integer in the range of 丨 ~ 6, and r is 0 or an integer in the range of 丨 ~ 15, the flowability of the cleaning force is better. (M + n + q) is an integer of 1 to 30, and preferably 6 to 20. When (m + n + q) is in the range of 1 to 30, a better detergency can be obtained. Moreover, (n + q) / (m + n + q + r) means 0, and it is more preferably 0 7 to 0.9. In the range of 0.5 to 1.0, a better detergency can be obtained. In the compound represented by the general formula (2), it can be produced by adding an alkylene oxide (bl) to an aliphatic alcohol, and the weight obtained by Gpc can be evenly packed. ----- line (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 14 A7

1230197 V. Description of the invention (12) The ratio (Mw / Mn) of the molecular weight (Mw) and the number average molecular weight (Mn) obtained by GPC satisfies the following relationship (3) or (4), and the following general formula ( 5) A compound having a distribution constant c of 2 or less is particularly preferred. [Number 10]

Mw / Mn ^ 0.030Ln (v) +1.010 (However, v < i〇) (3) [Number 11]

Mw / Mn ^ — 0.026Ln (v) + 1.139 (however, vg 10) (4) However, in formulas (3) and (4), v refers to an alcohol (al) added to each mole (The average addition mole number of alkylene oxides (bl)). In addition, Ln (v) refers to the natural logarithm of v. As the aliphatic alcohol (al), an alcohol having an aliphatic hydrocarbon group having 8 to 18 carbon atoms can be used. The aliphatic alcohol (al) is preferably an alcohol having an aliphatic hydrocarbon group having 10 to 18 carbon atoms. Specifically, the alcohol having an aliphatic hydrocarbon group listed in the description of R in the general formula (1) or (2) is taken as an example. The alkylene oxide (bl) may be ethylene oxide, propylene oxide, or butylene oxide, or may be used alone, randomly, or in any combination of the above. [Number 12] c = (v + n〇 / n〇〇-1) / [Ln (n〇〇 / n〇) + n〇 / n〇〇-1] (5) However, in formula (5) , V is the same as formula (3) or (4), n〇〇 means the mole number of the aliphatic alcohol (al) used for the reaction, ... means the mole of the unreacted aliphatic alcohol (al) number. Furthermore, CW1 0 or less is preferable. ^ When it is less than 20, the content of unreacted aliphatic alcohol becomes extremely small, and a better interfacial activity can be obtained. Do not mention the alkylene oxide additional non-ionic surfactant (b__ 丨) is suitable for the paper size of the standard (CNS) A4 specifications (210 X 297 public love) (Please read the precautions on the back before filling in this Page} -Installation ------ 丨 --Order i I ---- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 15 A7

1230197 V. Description of the invention (13) Ordinary alkylene oxide addition reaction manufacturing, which is based on the reaction catalyst D, adding ethylene oxide and propylene oxide in alcohol in a specific additional manner at 70 ~ 20 ° C It can be made by burning, butylene oxide. Its manufacture is such as: adding a base (such as KOH) or an acid (such as BF3) to a higher alcohol with 8 to 18 carbon atoms, and adding ethylene oxide in a random manner in a nitrogen environment And a mixture of propylene oxide, followed by the addition of ethylene oxide in blocks, and then the addition of propylene oxide in blocks. As the aliphatic hydrocarbon alcohol having 8 to 18 carbon atoms, a saturated or unsaturated primary, secondary or tertiary alcohol can be used. Among them, saturated aliphatic primary alcohols are preferred. The number of carbon atoms is preferably in the range of 10 to 18. Aliphatic hydrocarbon alcohols can be used as one or a mixture of two or more. Specifically, the saturated aliphatic primary alcohols are, for example, alcohols synthesized with decanol, lauryl alcohol, stearyl alcohol, Ziegler, s catalyst [such as the trade name ALFOL 1214 (made by CONDEA), etc.] ; Several synthetic alcohols produced by carbonyl synthesis [such as trade names DOBANOL23, 25, 45 (made by Mitsubishi Petrochemical Corporation), tridecyl alcohol (made by Kyowa Fermentation), carbonyl synthesized alcohols 1213, 1215, 1415 (made by chemical industry ), DiAD0L115-L, 115H, 135 (Mitsubishi Chemical Corporation)]. Saturated aliphatic secondary alcohols can be obtained by the oxidation method using U 3 丨 n paraffin as a raw material, and those described in Petrochemicals Vol. 21 No. 5 No. 5 pp. 233 ~ 242 0972). Unsaturated aliphatic alcohols are, for example: oleyl alcohol, alcohols obtained by reduction [such as trade names HICOUO, 60 (made by Gonghe Oil), ANGECOL 5〇A (this paper size applies to Chinese National Standards (CNS) A4 Regulations (210 一 ^ -------- ^ --------- (Please read the back ^ / phonetic? Matters before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 297 mm) 16 1230197 A7 B7 V. Description of the invention (printed by the New Japan Physics and Chemistry Co., Ltd. from the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs)] etc. The manufactured compound satisfies the above formula (3) or ⑷, 1, and the formula (5 ) The method of obtaining the distribution constant 4 or less is 2.0. For example, there are: ① a catalyst used to make the molecular weight distribution ratio-like (such as nitrogen oxides or carbonates of metals such as bell, sodium, unloading or recording, or amines). Test catalysts such as compounds) are also narrow catalysts, and the method of adding epoxy alkyl hydrocarbons to aliphatic alcohols; ② add 1 to 3 moles of epoxy ㈣ to aliphatic alcohols with ordinary catalysts, and then After removing unreacted alcohol by distillation, etc., a method of adding an alkylene oxide with a general catalyst is preferred. The method described in (1) above is preferred. Catalysts capable of forming a narrow molecular weight distribution include, for example, compounds containing calcined magnesium oxide (Japanese Patent Laid-Open No. i_64437), calcined hydrotalcites (Japanese Patent Laying-Open No. 71841), and high acid Catalysts in salts (US Patent No. 4,112,231), perhalic acids (salts), sulfuric acid (salts, nitrates (salts), and divalent or trivalent metal alkoxides. Cationic surfactants (C) are four examples. Examples of cationic surfactants of the type of ammonium salt type or amine salt type. Cationic surfactants of the type quaternary ammonium salt type can be used for tertiary amines and quaternizing agents (gas methane, bromomethane, gas ethane, benzyl chloride, etc. Compounds obtained by the reaction of alkyl halide, methylsulfuric acid, dimethyl carbonate, ethylene oxide, etc., such as: gaseous lauryltrimethylammonium, gaseous didecyldimethylammonium, bromide Octyl dimethyl ammonium, stearyl trimethyl ammonium bromide, lauryl dimethyl benzyl ammonium chloride (vaporized benzyl ammonium chloride), vaporized cetyl pyridinium salt, polyoxyethylene trimethyl ammonium chloride , Stearylamine ethyldiethylammonium methoxysulfate, etc. -------- ^ --------- (Please read the back ^ / notes before filling out this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297) ) 1230197 V. Description of invention printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (15) Amine salt type cationic surfactants can be used with inorganic acids (hydrochloric acid, nitric acid, sulfuric acid, hydrogen bromide, etc.) or organic acids (acetic acid, Formic acid, oxalic acid, lactic acid, gluconic acid, adipic acid, alkanoic acid, etc.) The compounds obtained by neutralizing primary to tertiary amines, such as: for the primary amine salt type, aliphatic higher amines (laurel Amines, stearylamines, cetylamines, hardened tallowamines, rosinamines, and other amines; inorganic salts or organic acid salts; lower amines of higher fatty acids (stearic acid, oleic acid, etc.) salts. Examples of the secondary amine salt type include inorganic acid salts and organic acid salts of an ethylene oxide adduct of an aliphatic amine. The secondary amine salt types are, for example, aliphatic amines (triethylamine, ethyldimethylamine, N, N, N, N-tetramethylethyldiamine, etc.), and alicyclic amines (n- Methylpyrrolidine, N-methyltrimidine, n-methylhexamidine, n-methylmorphine, 1,8-diazabicyclo (5,4,0) — 7--b—dilute Etc.), nitrogen-containing heterocyclic aromatic amines (4-dimethylparaben, N-methylimide, 4,4, dioxamine, etc.) inorganic or organic acid salts; triethanolamine monoamine Inorganic acid salts or organic acid salts of tertiary amines such as stearic acid and stearic acid ethyldiethylmethylethanolamine. As the cationic surfactant (C), one or a mixture of two or more of the above compounds can be used, and one or more compounds selected from the group consisting of the compounds represented by the formulae (6) to (9) are preferred. [Chemical 7] R1 I R2 — N — I R3

X (6) (Please read the precautions on the back before filling this page) -------- Order --------- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 18 1230197 A7 B7 V. Description of the invention (16 [化 8]

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Chemical 9] r R6-COOCH2CH2-N + (CH2CH2〇H) 5i ^ .x-. R5 J (8) [Chemical 10] " RB-OCH2CH2-N + ( CH2CHaOH) 2 VX ~. H5 J (9) However, in the formula ⑹ ~ (9), RiHR3 means a hydrogen atom or an alkyl group, alkenyl group or non-hydroxyalkyl group having 1 to 24 carbon atoms. Alkyl or alkenyl having 1 to 18 carbon atoms. Specific examples of the alkyl group include methyl, ethyl, propyl, hexamethylene, octyl, 2-ethylhexyl, nonyl, isononyl, decyl, isodecyl, undecyl, and isodecyl One base, twelve base, isododecyl, thirteen base, isodyl 13 base, fourteen base, iso 14 base, 15 base, iso 15 base, 16 base, 16 base, 18 base Alkenyl, isooctadecyl, and the like; and alkenyl such as: octenyl, decenyl, dodecenyl, tetradecenyl, hexadecenyl, octadecenyl, and the like. Examples of the / 3-hydroxyalkyl system include 2-hydroxyethyl, 2-hydroxypropyl, and 2-monobutyl. In addition, R4 and R5 are alkyl, hydroxyalkyl, and benzene paper with 1 to 24 carbon atoms. The paper size of China National Standard (CNS) A4 (210 X 297 mm) is applicable. (Please read the notes on the back before filling (This page)-installed -------- order --------- line j 19 1230197

V. Description of the invention (17) Methyl group or formula (AiOh-Zf, A1 series of carbon atoms with 2 to 4 carbon atoms such as ethylene, propylene, butylene), Z-based hydrogen Atom or fluorenyl group, n is an integer of 1 to 50, preferably an integer of 5 to 30}, preferably an alkyl or benzyl group having 1 to 4 carbon atoms. Specifically, such as Methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec monobutyl, etc. R6 is an alkyl group, alkenyl group or / 5 alkyl group having 1 to 36 carbon atoms. 'Preferable is an alkyl or alkenyl group having 8 to 24 carbon atoms. Specifically, in addition to the same groups as R1, R2, and R3, there are icosyl, isoicosyl, and ten dilute' And other bases. Y is a radical of 1 to 36 carbon atoms, a dilute radical, a radical base, and is represented by the formula: R4C〇2CH2 — (also, R4 is the same as above) or represented by the formula: R0CH2 — (Also 'R4 is the same as the above), preferably a alkynyl or alkynyl having 1 to 18 carbon atoms. Specifically, it refers to the same base as R1, R2, and R3. X — Department Counter ion, such as selected from halide ion (F-, Cl , Br—, I-), private ions, carbonate ions or sulfate ions with 1 to 4 carbon atoms in the burned group, and complete acid ions and continuous acid ions with 1 to 24 carbon atoms in the burned or dilute group. One or more types of anions in the group formed. The compound represented by formula (6) can be produced by, for example, the following methods: (1) an alkyl group having 1 to 24 carbon atoms such as laurylamine and stearylamine; , Alkenyl or / 3-hydroxyalkyl primary amine; alkyl, alkenyl or stone-hydroxyalkyl secondary amines with 1 to 24 carbon atoms, such as dilaurylamine, distearylamine, or Tertiary amines with trimethylamine, lauryldimethylamine, dimethylstearylamine, etc., having 1 to 24 carbon atoms, dilute radicals, or -based tertiary amines, applicable to Chinese national standards on this paper scale (CNS) A4 size (210 X 297 mm) (Please read the back ^ / notes before filling in this page)

| -------- Order --------- line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 20 1230197 A7 B7 V. Description of the invention (18) For example, hydrochloric acid, bromic acid or Halogen acids such as iodic acid, or formic acid, formic acid, acetic acid, propionic acid, yatsumatsu 8 and stearic acid, etc., and neutralization methods such as carbon acids with 1 to 24 carbon atoms. Also, ② will be used to have such as trimethylamine, Lauryl dimethylamine, dimethylstearylamine, and other carbon atoms, such as alkyl, alkenyl, or cold-hydroxyalkyl secondary amines such as methane, benzyl gas, dimethyl carbonate It is produced by a method in which an alkylating agent such as an ester, diethyl stone inversion ester, dimethyl sulfuric acid is heated under pressure to react. Also 'can be borrowed ③ will have laurylamine, stearylamine and other alkyl alkene, alkenyl or / 5-hydroxyalkyl primary amines with 1 to 24 carbon atoms; or with dilaurylamine, distearylamine A tertiary amine produced by adding ethylene oxide to a secondary amine such as an alkyl, alkenyl, or cold-hydroxyalkyl group having 1 to 24 carbon atoms in an alkaline environment, such as hydrochloric acid, bromic acid, or It is produced by neutralizing acids such as iodic acid, or carboxylic acids having a carbon number of j to 24, such as formic acid, acetic acid, propionic acid, lauric acid, and stearic acid. The compound represented by the formula (7) is a calcining agent having 1 to 24 carbon atoms, such as methyl chloride, chlorooctane, vaporized stearylamine, vaporized fat, and brominated hydroxyethane. It can be produced by heating and reacting under pressure. The compound represented by the formula (8) is, for example, used to heat and condense a fatty acid having 1 to 36 carbon atoms, such as lauric acid and stearic acid, and triethanolamine to produce a monoester type tertiary amine, which is used in the tertiary amine. It can be produced by a method of neutralizing acids such as hydrochloric acid and acetic acid, and a method in which gaseous methane, dimethyl carbonate, and dimethyl sulfuric acid are heated and reacted under pressure in the aforementioned ester-type tertiary amine. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) | Installation -------- Order ------- --Line | Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 21 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230197 A7 ___ B7 V. Description of the Invention (19) The compounds represented by formula (9) are such compounds that will be used in The amine type tertiary amine obtained by heating and condensing N, N-diethylethylenediamine in fatty acids having 1 to 36 carbon atoms, such as lauric acid and stearic acid, is used in acids such as hydrochloric acid and acetic acid. It can be produced by a method of combining the above-mentioned tertiary amine type tertiary amine with methyl chloride, dimethyl stone invertate, and dimethyl sulfuric acid under heating, and then reacting by heating. When the counter ion X- of the formulae (6) to (9) is used as a hydroxyl ion, a compound of _ ion is prepared by χ, and silver hydroxide is added to the compound to heat it to produce it. Low molecular weight polyvalent dicarboxylic acid, which can be an organic amine salt of a low molecular weight polyvalent carboxylic acid or a quaternary ammonium salt (D). Its molecular weight is usually 700 or less, preferably one with a molecular weight of 5000 or less, 1 molecule. The number of carboxyl groups is usually 2 to 8 aliphatic polyvalent acid and aromatic polyvalent acid. Systems other than end groups may also include hydroxyl and amine groups. Specific examples of the low molecular weight polyvalent carboxylic acid include, for example, oxalic acid, malonic acid, succinic acid, butanetricarboxylic acid, adipic acid, maleic acid, fumaric acid, itaconic acid, aconitic acid, and phthalic acid. , Trimellitic acid, citric acid, malic acid, ethylenediamine tetraacetic acid (EDta), amine triacetate (NTA), aminosuccinic acid, etc. The organic amines used as the organic amine salt of the low molecular weight polyvalent carboxylic acid include the aforementioned aliphatic amines, alicyclic amines, or alkanolamines, or alkylene oxide adducts of fluorene or higher. Among the aforementioned quaternary ammonium salts of low molecular weight polyvalent carboxylic acids, the quaternary ammonium cations can be exemplified by the aforementioned quaternary ammonium cations. The content of (A) in the detergent of the present invention is relative to the total lambda of the detergent, which usually occupies 0 or 1 to 30% by mass, preferably the content is 0 or 2 to 20. This paper is applicable to China. National Standard (CNS) A4 Specification (210 χ 297 Public Love) ------------ Installation -------- Order --------- Line (Please read first Back ^ / Notes, please fill out this page) 22 1230197

%, More preferably 0 or 3 to 15 mass 0/0. In addition, the content of (B) is usually 95% by mass relative to the total mass of the detergent, preferably 20 to 80% by mass, and more preferably 30 to ⑼% by mass ° ⑻. 'The better is relative to the compound represented by _) or ⑺ is the content of 85% by mass or more relative to the content of (B)' and the more preferred is the relative content of the compound represented by the general formula ⑺ The content of (B) 'occupies more than 85% by mass, and the particularly preferred one is the compound represented by the general formula; ^ Relational formula (3) ⑷, and the distribution constant c obtained from the general formula (5) is 2.0 The content of the following compounds is 85% by mass or more based on the content of (B). Moreover, content of (C) is 0 or 0.01-10 mass% with respect to the whole mass of a detergent, Preferably it is 0 or 0.05-5 mass%. The content of (D) is relative to the total mass of the detergent, and usually occupies 0 or 0 · i to 20% by mass, preferably 0 or 1 to 15% by mass 0 / 〇. The content of water is relative to the total mass of the cleaning agent, and usually occupies 2 80 mass% / 0, preferably iq to 60 mass%. In addition, according to needs, another composition other than (a), (B), (C), and water 'may occupy 0 to 50 masses 0 / 〇 relative to the total mass of the detergent. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, another composition is an epoxy resin that may contain anionic surfactants (alkyl (carbon number 1-20)) ¾ sulfate, aliphatic (carbon number 1-20) alcohol Sulfated or carboxymethylated compounds of ethane adducts (additional moles 1 to 30), etc. 0 to 15% by mass, and another builder (basic soda, soda ash, ammonia, triethanolamine, tripolyphosphate) Soda and other alkaline builders ~ 5%, fluorescent agents, bleaching agents, softeners, enzymes, bactericides, perfumes, colorants, etc. 0 ~ 5 quality This paper ruler 2 is in accordance with China National Standard (CNS) A4 (210 X 297 public love) 23 1230197 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ------- B7____ V. Description of the invention (21) Amount%, hydrophilic solvents (methanol, ethanol, isopropanol, Ethylene glycol, propylene glycol) 0 ~ 20 berry. / 〇, defoaming agent (polysiloxane-based defoamer, pLURonic or polyoxyalkylene-based defoamer, mineral oil-based defoamer, etc.). ~ 5% by mass. The detergent of the present invention is specifically targeted at natural fibers, synthetic fiber fibers, and blends of these fibers. Weaving fiber is effective for washing. Natural fiber is such as kapok, hemp, wool, etc .; synthetic fiber is regenerated cellulose fiber such as snail, acetate, etc., polyacetate, polyamine fiber, acrylic, polyurethane elastic fiber Synthetic fibers, etc. The above-mentioned blended and woven fibers are such as: kapok, hemp and another fiber (wool, polyester, polyamide, acrylic, etc.), wool and another fiber (polyester, polyamide, acrylic, etc.) Etc.), polyester fiber and another fiber (spiron, acetate, polyamide, propylene, polyurethane elastic fiber, etc.), and polyamide fiber and another fiber (acetate, acrylic, polyurethane elastic fiber, etc.), etc. The detergent of the present invention is usually used at a concentration in the range of 0.001 lg / L to 5 g / L. Although the bath ratio is not particularly limited, it is usually 1 ·· 4 ~ 1: 4〇, and the preferred one is 1 · 6 ^ 1: 3 0 〇 The washing temperature can be selected at will according to the type of fiber used, usually 5 ~ 80 ° C, preferably 20 ~ 50 ° C. The cleaning agent of the present invention is not only It is used as a detergent for clothing and can also be used in industry Detergents, such as fiber scouring agents, soaping agents, etc. When using the detergent of the present invention, there is no special paper for the cleaning method. Chinese national standard (CNS) A4 specification (210 X 297 mm)

(Please read the Zhuyin on the back? Matters before filling out this page)

| Install -------- order --------- line I 24 1230197

7 Limitation, it can be used in households for hand washing and washing machines. In industrial use, Y is used for batch processing of liquid flow dyeing machines and continuous processing by continuous refining equipment. The towels are particularly suitable for washing detergents used in washing machines such as centrifugal and force-washing type washing machines which have less damage to the strips. Centrifugal washing method refers to a novel washing method used to remove sludge by the hydraulic force of the laundry. Such as Panasonic Electric Industrial Co., Ltd. "centrifugal washing machine να-800p". [Examples] The present invention will be described in detail by the following examples, but the present invention is not limited thereto. In the following, parts and% are parts by mass and mass 0/0. The series of conditions for measuring molecular weight by GPC of a carboxyl group-containing polymer are as follows. < GPC measurement conditions > Model: Waters5 10 (made by Waters, Japan) Column: TSK gel G5000pwXL TSK gel G3000pwXL (both manufactured by Dongsu Co., Ltd.) Column temperature: 40 ° C Detector: RI Solvent: 0.5% acetic acid soda, water / methanol (volume ratio 70/30) Flow rate • 1.0ml / min Sample concentration · 0.25% Injection volume: 200 // 1 Standard: Polyoxyethylene glycol This paper size applies Chinese national standards (CNS) A4 size (210 X 297 mm) (Please read the precautions on the back before filling this page)

-Installation -------- Order --------- line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 25 1230197 A7 B7 V. Invention Description (23) (by Dongsu Co., Ltd.) ： TSK STANDARD POLYETHLENE OXIDE) Data processing device · SC — 8010 (manufactured by Dongsu Co., Ltd.) The series of conditions for measuring the molecular weight based on the GPC of the nonionic surfactant (B) are listed below. < GPC measurement conditions > Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economics and Machines Co., Ltd. HLC-8120 (manufactured by Dongsu Co., Ltd.) TSK gel SuperH4000 TSK gel SuperH3000 TSK gel SuperH2000 (both manufactured by Dongsu Co., Ltd.) 40 ° C RI Tetrahydrocrack 0.6ml / min 0.25% 10 β 1 Polyoxyethylene glycol (manufactured by Tungsu Co., Ltd .: TSK STANDARD POLYETHLENE OXIDE) SC — 8020 (manufactured by Tungsu Co., Ltd.) Activity at non-ionic interface The series of measurement conditions of a gas chromatograph (GC) used in the measurement of the concentration of the unreacted aliphatic alcohol of the agent are as follows. < GC measurement conditions > Column temperature detector Solvent flow rate Sample concentration injection amount Standard data processing device The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling (This page)% ---- Order --------- Line | 26 1230197

Model Detector Column Packing Column Column Temperature Carrier Gas Sample Injection Quantity Quantification: Gas Chromatograph GC-14B (manufactured by Shimadzu Corporation)

: FID • Glass column (inner diameter = about 3mm, length = about 2m): Polyoxysilane GE SE- 30 5%: Heating to 90 ° C to 280 ° C 幵 Temperature speed · 4 ° C / min nitrogen 50 % Acetone solution 1 β 1 Based on the aliphatic alcohol used, an aliphatic alcohol having 2 or 3 carbon atoms is used as an internal standard substance for quantification. Example 1 Into a pressure-resistant reaction container, 420 parts of isopropyl alcohol and 120 parts of water were placed, replaced with nitrogen, and sealed, and the temperature was raised to 100 ° C. With stirring, 77 parts of valeric acid each took 3 hours, 228 parts of acrylic acid, 4 parts of chain transfer agent (triethylene glycol diethanol), 2 parts of sodium hypophosphite 2 hydrate, and gasified ferrous 4 hydrate The homogeneous mixture of 0.7 parts took 2 hours, and 50 parts of 6% aqueous sodium persulfate solution took 3 to 5 hours to drip (simultaneously, dripping started). After the dropping was completed, 3 parts of a 35% hydrogen peroxide aqueous solution was further added, and the mixture was stirred at 100 ° C for 1 hour to obtain a polymer (a) having a polymerization rate of 99.9%. The weight-average molecular weight based on GPC of the product was 10,000, and the weight-average molecular weight based on the number of GPC was 7,800. 195 parts of methanol and 586 parts of dimethyl carbonate were placed in another pressure-resistant container, replaced with nitrogen, sealed, and heated to 120 ° C. Under stirring, the paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ---- Order ------- -Line. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 27 1230197 V. Description of the invention (25) 219 copies of triethylamine, 120t: 2 hours under the instruction, and triethylmethylate invertate ( b) in methanol. After the obtained (707 parts of 60% methanol solution and 400 parts of polymer (a) were mixed and neutralized by 2,000%), isopropyl ^, methanol, and dimethyl carbonate were added under normal pressure and After distilling off at 100 t, 580 parts of water was added to obtain a 牦% aqueous solution of triethylmethylammonium polyacrylate. This was compounded with the non-ionic surfactant (B), triethanolamine citrate, propylene glycol, Alcalase 2.5L, and water 4 described in Table 2 to prepare a detergent at the compounding amounts described in Table 4. Examples 2, 3, 9 to 24 The same procedure as in Example 1 was used except that the non-ionic surfactant (B) was substituted as described in Table 2 using the triethylmethyl ammonium polypropionate salt of Example 1. Detergents were prepared at the compounding amounts described in Tables 4 to 6. Examples 4, 5, 6, 7 Using the polymer (a) obtained in Example 1, the neutralized salt and the degree of neutralization were replaced with those described in Table 1, and the nonionic surfactant (B) was replaced with Except those substituted in Table 2, the rest of the procedure was the same as in Example 1, and a detergent was prepared at the compounding amount described in Table 4. Example 8 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The polymer (a) obtained in Example 1 was neutralized with dimethylhexylamine. This was mixed with the nonionic surfactant (B), triethylmethylamine salt of citric acid, propylene glycol, 2.5L of Alcalase and water, and a detergent was prepared at the compounding amount described in Table 4. Put 370 parts of isopropanol and 170 parts of water in a pressure-resistant reaction container. The paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 28 1230197

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (26) Sealed with nitrogen and heated to 100. (:. With stirring, 264.9 parts of acrylic acid, 401 parts of 2-acrylamido-2 monomethylpropanesulfonic acid, and 80 parts of 4% aqueous sodium persulfate solution were dripped from individual containers for 3 hours ( At the same time, dripping was started.) After the dripping was completed, 3 parts of a 35% hydrogen peroxide aqueous solution was added and stirred at 100 ° C for 1 hour to obtain a copolymer having a polymerization rate of 99 9%. According to the weight of the GPC of the substance The average molecular weight was 8,000 and the number average molecular weight was 5,600. 707 parts of a 60% methanol solution of triethylmethylammonium formate (b) obtained in Example 1 and 174 parts of a copolymer (c) After mixing (100% neutralization), isopropyl alcohol, methanol, and dimethyl carbonate were added under normal pressure to 100%. After distillation, an aqueous solution of triethylmethylammonium polyacrylate was obtained. This was compounded with the nonionic surfactant (B), diethylmethylamine citrate, propylene glycol, Alcalase 2.5L and water 4 described in Table 2 to prepare a detergent at the compounding amounts described in Table XI. Example 26 The same procedure as in Example 25 was used except that the non-ionic surfactant (B) was replaced with the one described in Table 2 except that the polyethyl triethylammonium polyacrylate was used in Example 5. Detergents were prepared at the mixing amount. Example 27 Using the trimethyloctylammonium polyacrylate of Example 6 except that the nonionic surfactant (B) was replaced with the one described in Table 2, the rest was the same as that in Example 25, and the compound described in Table 6 was used. Measure into detergent. Examples 28 ~ 30 The polymerized trimethyldecanoate salt obtained in Example 7 was used. The paper size is in accordance with China National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back before reading) (Fill in this page) ^ 29 --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------—————————————————————————————————————————— 12 12197197 Octyl ammonium salt, propylene glycol, Akalase 2.5L and water were used as detergents at the compounding amounts listed in Table 6. Example 3 1 The reaction of adding stanolamine to stearamide to obtain a cationic surfactant (cl; in formula (6), r4 = c18H37, X- = C1_) ο using the cationic surfactant ( c 1) and the diethylmethylammonium acrylate of Example 1 combined with the nonionic surfactant (B), triethanolamine citrate, propylene glycol, Alcalase 2.5L and water described in Table 2, Detergent was prepared under the conditions described in JC. Example 32 The reaction of adding dimethyl carbonate to dimethylstearylamine to obtain a cationic surfactant (c2; in formula (6), I ^: = (: 18Η37, RLRkRLcH ^, x- = ch3co3- ) 〇 using the cationic surfactant (c2) and polyethyl triethylammonium salt of Example i, and combined with the non-ionic surfactant (B), triethanolamine citrate, propylene glycol, Alcalase 2. 5L and water were used as detergents at the compounding amounts described in Table 7. Example 33 A gasified octane reaction was added to pyridine to obtain a cationic surfactant (c3; in formula y, y = c8hi7, x — = Cl-). Use the cationic surfactant (c3) and the polyethylammonium diacrylate of Example 丨, and cooperate with the non-ionic surfactant described in Table 2. The paper size applies the Chinese National Standard (CNS ) A4 specifications (210 X 297 public shame) " ----- -30------------- ^^ 衣 -------- Order ------ --- line (Please read the note on the back? Matters before filling out this page) 1230197 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (28) Diethanolamine citrate , Propylene glycol, Alcalase 25L, and water were used as detergents at the compounding amounts described in Table 7. Example 34 After adding triethanolamine to caprylic acid, the reaction was followed by dimethyl carbonate reaction to obtain a cationic surfactant (C4; In the formula, R5 = C7hi5, X-—CH3CO3) 0 The cationic surfactant (C4) and the polyethylammonium acrylate of Example 1 were used, and the nonionic surfactant (B), Caining-like acid diethanolamine salt, propylene glycol, Alcalase 2.5L and water were used as detergents at the compounding amounts described in Table 7. Example 35 A gasified methane reaction was added to dilaurylmethylamine to obtain a cationic surfactant. (C5; in formula (6), ri = R2 = Ci8h37, R3 = R4 = CH3, χ— = C1—). Use the cationic surfactant (C5) in combination with the non-ionic surfactant described in Table 2 ( B), citric acid triethanolamine salt, propylene glycol, Alcalase 2.5L and water, the detergents are not used as detergents in the amounts listed in Table 7. Example 36 Diethyl sulfuric acid was added to triethylamine to obtain a cationic surfactant ( c6; in formula (6), x- = C2H5S04 ~) This cationic surfactant (c6) was used in combination with the nonionic surfactant (B), triethanolamine citrate, propylene glycol, Alcalase 2.5L and water described in Table 2 to prepare a detergent at the compounding amounts described in Table 7. . This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 public love). -------- Order --------- Line · (Please read the precautions on the back before (Fill in this page) 31 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230197 A7 --- _B7___ V. Description of the Invention (29) Example 37 The reaction of ethane chloride was added to the pyridine to obtain a cationic surfactant (c7; In formula (2), y = C2h5, χ- ^ d-). This cationic surfactant (c7) was used in combination with the nonionic surfactant (B), triethanolamine salt of citric acid, propylene glycol, Alcalase 2.5L, and water, and cleaned at the compounding amounts described in Table 7. Agent. Example 3 8 After adding N, N-diethylethylenediamine to stearylamine, and then reacting with monomethylsulfuric acid, a cationic surfactant (c8; in formula (9), R5 = CH3, R6 = C17H35, X- = ch3so4-). This cationic surfactant (c8) was used in combination with the non-ionic surfactant (B), triethanolamine citrate, propylene glycol, Alcalase 2.5L, and water described in Table 2, and washed at the compounding amounts described in Table 7. Detergent. Comparative Examples 1 and 2 used the nonionic surfactants described in Table 3, triethanolamine citrate, propylene glycol, Alcalase 2-5L and water, and sodium dodecylbenzenesulfonate or sodium dodecyl ether. Detergents were prepared at the stated blending amounts. Comparative Example 3 The polymer (a) obtained in Example 1 was neutralized with ammonium water. This material was used in combination with the nonionic surfactant, triethanolamine citrate, propylene glycol, AlCalase 2.5L and water described in Table 3 to prepare a detergent at the compounding amounts described in Table 7. Comparative Examples 4 and 5 The polymer 0) obtained in Example 1 was neutralized with sodium hydroxide. Used to install -------- order --------- line (please read the phonetic on the back? Matters before filling out this page)

-32-1230197 A7 B7 V. Description of the invention (30) The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the substance and cooperated with the non-ionic surfactants, triethanolamine citrate, propylene glycol, Alealase 25L and water described in Table 3. Detergents were prepared at the compounding amounts listed in Table 7. Comparative Example 6 The polymer fluorene obtained in Example 1 was neutralized with sodium hydroxide. Using this substance and the nonionic surfactants in Table 3 «, propylene glycol, Aicaiase 2 5L and water, detergents were prepared at the compounding amounts described in Table 7. Comparative Example 7 The polymer (&) obtained in Example 1 was neutralized with sodium hydroxide. Using this product, a nonionic surfactant, propylene glycol, Alcalase 2.5L, and water as shown in Table 3 were blended, and a detergent was prepared at the compounding amount shown in Table 7. Comparative Example 8 Polyvinyl alcohol {trade name: PVA — 105 (made by Claret Co., Ltd.), weight average molecular weight based on GPC: 22,000, and nonionic surfactant described in Table 3, Triethanolamine citrate, propylene glycol, Alcalase 2.5L and water were used as detergents at the compounding amounts listed in Table 7. Comparative Example 9 Sodium polyvinylate {trade name: Cheminat SA — 9 (manufactured by Sanyo Chemical Industry Co., Ltd.), weight average molecular weight based on GPC: 40,000} was used in combination with the nonionic surfactant and citric acid described in Table 3 Triethanolamine salt, propylene glycol, Alcalase 2.5L and water were used as detergents at the compounding amounts described in Table 7. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

I installed -------- order --------- line I 33 1230197 Δ7 Α7 Β7 V. Description of the invention (31) [Table 1] Organic amine or quaternary used in neutralization Ammonium cation neutralization degree (mol%) SP value of polymer (A) Examples 1 to 3, 9 to 25, 31 to 34 Triethylphosphonium ammonium 100 8.7 Example 4 Triethylmethylammonium 85 9.4 Example 5, 26 Triethylmethylammonium 60 10.8 Example 6, 27 Trimethyloctyl ammonium 100 8.6 Example 7, 28 to 30 Trimethyldecanonium 100 8.6 Example 8 Dimethylhexyl ammonium 100 9.4 Comparative Example 3 Forging 100 17.4 Comparative Examples 4 to 7 Nano 100 14.3 Table 2 and Table 3 show the structures of the nonionic surfactants used in the examples and comparative examples. EO refers to oxyethylene and PO refers to oxypropylene. EO / PO means random attachment, EO — PO means block attachment. Mw / Mn (measured value) refers to the measured value according to GPC. Mw / Mn (calculated value) refers to the calculated value calculated from the relational expression (3) or (4). The distribution constant c is a value calculated from the relational expression (5) after measuring the amount of unreacted alcohol by GC. -------------------- Order --------- Line (Please read the back ^ / Notes before filling out this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by employee consumer cooperatives The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 34 1230197 A7 B7 V. Description of the invention (32) [Table 2] Employee Consumer Cooperatives printed and implemented by the Intellectual Property Bureau of the Ministry of Economic Affairs Example Structure of Non-ionic Surfactant (B) Mw / Mn (Actual value) Mw / Mn (Calculated value) C Bu 3 Bu 35 C8H170 (E0) 12H 1.045 1.074 0.89 2 c12h25〇 (e〇) 9h 1.062 1.076 0.92 3 C18H35O (EO) 10H 1.068 1.079 0.87 4 C8H170 (EO) 9- (PO) 3H 1.023 1.074 0.92 5, 32, 36 c12h25o (eo) 9- (po) 3h 1.021 1.074 0.91 6 c18h35o (eo) 9- (po) 3h 1.068 1.074 0.91 7 C8HnO (EO) 4- (PO) 2- (EO) 8H 1.067 1.070 0.82 8,33,37 c13h27o (eo) 4- (po) 2- (eo) 8h 1.059 1.070 0.88 9 c18H35〇 ( E〇) 4- (P〇) 2- (E〇) 8H 1.063 1.070 0.91 10 C13H27O (EO) r (PO) r (EO) 10H 1.052 1.074 0.48 11 c13H27〇 (E〇) 8- (P〇) 2 -(E〇) 3H 1.054 1.072 0.65 12 C10H21O [(EO) 7 / (PO) 2]-(EO) 2H 1.062 0.074 0.68 13 C10H21O [(EO) 8 / (PO) 2]-(EO) 5H 1.058 1.069 0.77 14 c18H35〇 [(E〇) 8 / (P〇) 2]-(E〇) 7H 1.047 1.065 0.78 15 C13H270 [(E0) 4 / (P0) 2]. (E0) 8H 1.045 1.070 0.77 16 C13H27O [( EO) 10 / (PO) 2]-(EO) 3- (PO) 8H 1.052 1.060 0.60 17 C13H270 [(E0) 2 / (P0) 4]-(E0) 15- (P0) 12H 1.045 1.048 0.53 18, 34, 38 C13H27O [(EO) 8 / (PO) 2]-(EO) 10- (PO) 4H 1.045 1.048 0.68 19 C18H35O [(EO) 2 / (PO) 4]-(EO) 10- (PO) 1H 1.063 1.065 0.72 20 ～ 25 C18H35O [(EO) 8 / (PO) 4]-(EO) 10. (PO) 8H 1.048 1.051 0.65 26 C12H250 (E0) 9H 1.221 1.076 3.26 27 C12H250 (E0) 9- (P0 ) 3H 1.089 1.074 3.09 28 c13h27o (eo) 4- (po) 2- (eo) 8h 1.210 1.070 3.02 29 Sorbitol anhydride monolaurate E04 Moore adduct — — 30 Lauryl diethanolamine — — — ------------ Installation -------- Order --------- Line (Please read the precautions on the back before filling this page) Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 35 1230197 V. Description of the invention (33 A7 33) ——- · 1 ------- [Table 3] Comparative Example Nonionic Surfactant ~ 1 to 4 Same as Example 26 ~ 5 to 7 Same as Example 15 ~ 8 Same as Example 29 ~ 9 The same as in Example 30 ~ -------.

Experiments on the cleaning power, foaming power, and stability of the detergent were performed on the pellets prepared in Examples 1 to 38 and Comparative Examples i to 9. The results are described in Tables 4 to 8. The experimental method is described later. f Please read > ± on the back before filling in this page) ·% · Printed by the Consumer Consumption Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [Table 4] Put i if _J 1 2 3 4 5 6 7 8 9 10 Wash $)! Organic salt or quaternary ammonium salt of carboxyl-containing polymer (A) 2 5 10 10 10 10 5 5 5 5 Composition non-ionic surfactant (B) 38 35 30 30 30 30 35 35 35 35 Lemon Acid triethanolamine salt 6 6 6 6 6 6 6 6 6 6 Propylene glycol 5 5 5 5 5 5 5 5 5 5 Total (parts) Alcalase 2.5L * 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Water 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 Evaluation of cleaning power ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ valence foaming power Δ Δ Δ 〇〇〇〇〇〇〇〇〇 The stability of detergent composition 〇〇〇 * Alcalase2.5L: protease (Nove-Nordisk company enzyme)

This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 36 1230197 A7 B7 V. Description of the invention (34) [Table 5] Example printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 11 12 13 14 15 16 17 18 19 20 Detergent composition (parts) Organic salt or quaternary ammonium salt of carboxyl group-containing polymer (A) 5 5 5 5 5 5 5 5 5 5 Nonionic surfactant ( B) 35 35 35 35 35 35 35 35 35 35 35 Triethanolamine citrate 6 6 6 6 6 6 6 6 6 6 Propylene glycol 5 5 5 5 5 5 5 5 5 5 Alcalase2.5L * 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Water 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 Evaluation of cleaning power ◎ ◎ 〇〇 ◎ ◎ ◎ ◎ Foaming power 〇〇〇〇〇〇〇〇〇〇 The stability of the detergent composition 〇〇 〇〇〇〇〇〇〇〇〇〇Alcalase2.5L: protease (Nove-Nordisk company enzyme) [Table 6] Example 21 22 23 24 25 26 27 28 29 30 Detergent composition content (parts) containing Organic or quaternary ammonium salts of carboxyl polymers (A) 1 5 15 5 2 5 10 10 5 5 Ionic surfactant (B) 39 60 25 35 38 35 30 30 35 35 35 Triethanolamine citrate Triethylmethylamine citrate Trimethyloctylamine citrate 6 6 6 6 6 6 6 6 6 6 Propanediol 5 5 5 5 5 5 5 5 5 5 Alcalase2.5L * 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Water 48.6 23.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 Evaluation of cleaning power ◎ ◎ ◎ ◎ ◎ 〇〇〇〇〇 〇〇Δ Δ stability of detergent compositions force 〇〇〇〇〇Δ 〇〇〇〇〇〇〇〇〇〇 * Alcalase2.5L: protease (Nove-Nordisk Inc. enzyme) ------- ----- Installation -------- Order --------- Line (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 37 1230197 Δ7 Α7 Β7 V. Description of the invention (35) [Table 7] Example 31 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the combination of the detergent composition 31 32 33 34 35 36 37 38 Amount (parts) Organic salt or quaternary ammonium salt of carboxyl polymer (A) 5 5 5 5 — — — — Nonionic surfactant (B) 3 4.95 34.8 34 30 39.95 39.8 39 35 Cationic surfactant (C) 0.05 0.2 1 5 0.05 0.2 1 5 Triethanolamine citrate 6 6 6 6 6 6 6 6 Propanediol 5 5 5 5 5 5 5 5 Alcalase2.5L * 0.4 0.4 0.4 0.4 0.4 0.4 .0.4 0.4 Water 48.6 48.6 48.6 48.6 48.6 48.6 48.6 48.6 Evaluation of cleaning power ◎ ◎ ◎ ○ 〇〇〇 foaming power Δ 〇〇 △ 〇〇〇 stability of detergent composition. 〇〇〇〇〇〇〇〇〇Alcalase2.5L: Protease (Nove-Nordisk company's enzyme) [Table 8] Comparative Example 1 2 3 4 5 6 7 8 9 Detergent composition content (parts) ammonium polyacrylate Sodium polyacrylate Polyvinyl alcohol Sodium polysulfonate 5 5 35 5 5 5 5 Nonionic surfactant 10 20 35 35 5 90 35 35 35 Sodium dodecylbenzenesulfonate Sodium dodecyl ether sulfate 30 20 Citric acid Ethanolamine salt 6 6 6 6 6 6 6 Propylene glycol 5 5 5 5 5 5 5 5 Alcalase2.5L * 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Water 48.6 48.6 48.6 48.6 48.6 4.6 48.6 48.6 48.6 Evaluation of cleaning power XX 〇〇Δ 〇 Δ △ Δ Foaming force XX Δ 〇Δ Δ Δ Δ Δ The stability of detergent composition 〇 × XXXXXX * Alcalase2.5L: protease (Nove-Nordisk company-made enzyme) ------------ install -------- order ---- ----- Line (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 38 1230197

V. Description of the invention (36) < Washing power experiment > Washing power is used for the centrifugal washing machine "NP F80〇P" made by Matsushita Electric Industrial Co., Ltd. The cloth is artificially contaminated in a water volume of 50L and a bath ratio of 30 Times, 25g of detergent, 25t water temperature, etc., wash for 10 minutes, and wash with water for 3 minutes twice, and use the following formula to calculate the cleaning power to evaluate. Detergency (° / o) = {(Rw—Rs) / ^ — rs)} X 1〇〇 “Heart refers to the reflectivity of cleaning cloth, Rw refers to the reflectivity of cleaning cloth, RS refers to pollution The reflectance of the cloth was measured using a multi-source spectrophotometer (Suga test mechanism) to determine the reflectance at 540nm. The artificially contaminated cloth used was a wet artificially contaminated cloth with a dirt composition of Table 9 manufactured by the Washing Science Association (reflectivity of 54 ± 11 ° / 40). (Please read the precautions on the back before filling in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 9] Ingredient Name Content Rate (%) Oleic acid 28.3 Oil triolein t 15.6 Fatty cholesterol oleic acid g 12.2 Eighty percent of flowing wax 2.5 minutes 30 carbon six dilute 2.5 Cholesterol 1.6 Protein gelatin 7.0 Inorganic component mud 29.8 Carbon black 0.5 The evaluation benchmark system is that when the cleaning power is more than 40% is ◎, the cleaning power is more than 32% If it is less than 40%, it is 0, if it is more than 200/0 and less than 32%, it is △, and if it is less than 20%, it is represented by X. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). Order --------- line · 39 123Ο197 Α7 Β7 V. Description of the invention (37 < Foaming power test >) 15 L of the ο · ι〇 / 〇 aqueous solution of the refrigerant was used to evaluate the foaming power at 2 5 hours by a high-pressure jet liquid flow foaming tester (Ding U Jii Dyeing Machine Industry Co., Ltd.). In the reference system, the foaming height is less than 20 mm, 0, △ within 20-50 mm, and △ above ⑽㈤⑺ is represented by χ. ≪ Stability of detergent > Stability of detergent It is used to stand at 25t for 24 hours, and the appearance is visually observed. The evaluation is based on the following criteria. The evaluation criterion is that the detergent without separation is 0, and the detergent with separation is X. The present invention The builder used in detergents can exhibit good compatibility with surfactants and "washing for clothing" "It has excellent properties in cleaning sludge and has a low foaming effect. Also, The detergent of the present invention can fully exert a very excellent effect, # for washing with a method of less damage to the washing ▲ Clothes machine ’is especially a detergent for centrifugal washing machines. 0 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 40-

Claims (1)

6. Application Patent Scope No. 88120614 Patent Application Application Patent Scope Amendment Date: November 5, 1993 1. A builder for detergents, the builder comprising (A) a fluorene-based polymer A quaternary ammonium salt, and the (A) quaternary ammonium salt is a tetraalkylammonium having an alkyl group having 1 to 18 carbon atoms. 2. As the detergent builder for item 1 of the scope of the patent application, wherein ii) the solubility parameter of the quaternary ammonium salt is 8.0 ~ 12.0. 3. The detergent builder for item 1 of the scope of patent application, wherein the carboxyl-containing polymer refers to polyacrylic acid. 4. A detergent, which includes the builder described in item 1 of the patent application scope and (B) a non-ionic surfactant. 5. The cleaning agent according to item 4 of the scope of patent application, wherein the (b) nonionic surfactant refers to a compound represented by the following general formula (1); general formula RO— (Α10) ρ ~ Η Η (Formula In the formula, R is an aliphatic hydrocarbon group having 8 to 18 carbon atoms;? Is an integer of 1 to 30; A1 is an alkylene group having 2 to 4 carbon atoms). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. If the detergent is applied for item 5, the detergent (B) nonionic surfactant refers to the compound represented by the following general formula (2); 1] RO- [(C2H40) n · (A20) m] — (C2H40) q — (A20) r—Η (2) (wherein R is an aliphatic hydrocarbon group having 8 to 18 carbon atoms; A2 is Alkylene groups with 3 or 4 carbon atoms; η is an integer of 0 or 1 to 12; m is a paper size of 0 or 1 to 6 applicable to China National Standard (CjNIS) A4 (210 X 297 males; g) 1230197 B8 C8 D8 Seal of the Consumers ’Co-operative Society of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ 6. Integer for applying for profit; q is an integer from 1 to 16; r is an integer from 0 or 1 to 15; (m + n + q) is from 1 to An integer of 30; (n + q) / (m + n + q + r) is 0.5 to io; [(C2H4〇) n · (A20) m] is a random addition or a block force α). 7. The cleaning agent according to item 5 of the scope of patent application, wherein the (B) non-ionic surfactant refers to (al) an aliphatic alcohol added with (bl) alkylene oxide and can satisfy the following ① and Compounds of ②; ① and ② are ① the ratio of weight average molecular weight (Mw) and number average molecular weight (Μη): Mw / Mn is one that satisfies the following relationship (3) or (4); [Number 1] Mw / Mn ^ 0.030Ln (v) + 1.010 (only, ν < 1〇) (3) [number 2] Mw / Mng-〇.〇26Ln (v) + 1.139 (only, v-1〇) (4) (only 'v Refers to (a 1) the average addition mole number of (bl) alkylene oxide per 1 mol of aliphatic alcohols; ② The distribution parameter c obtained from the following formula (5) is below 2.0. [Number 3] c = (v + n〇 / n〇〇- ~ l) / [Ln (n〇〇 / n〇) + n〇 / n〇〇 ~ 1] (5) (but 'v is related to The formula (3) or ⑷ is the same, n00 means the mole number of (al) aliphatic alcohol used for the reaction; it means the mole number of (al) aliphatic alcohol which is not reacted). 8- As for the detergent of item 4 of the patent application scope, the detergent is a cationic surfactant. 9. A detergent 'is produced by adding (bl) an epoxy alkane to an aliphatic alcohol and containing (B) non-ionic interfacial activity that satisfies the following ① and ② Please fill in this page on the back of Mti first) And (C) cationic surfactants; ① the ratio of weight average molecular weight (Mw) and number average molecular weight pottery · Mw / Mn are those satisfying the following relationship (3) or (4); [Number 4] MW /Md_L，+l._ (However, ^ 0) (3) [Number 5] MW / Md〇26Ln (v) + 1.139 (: quasi, V-10) ⑷ (quasi-v system is attached to (al) fat (1) the average addition mole number of alkylene oxide (fe) per 1 mole of family alcohols; ② The distribution parameter obtained from the following formula (5) is 0 or less; [num. 6] Ministry of Economic Affairs wisdom Printed clothing c- (v + n〇 / n〇〇 ~. L) / [Ln (n〇〇 / n〇) + n〇 / n〇〇 ~ 1] 4 (5) (but only 'v is the same as formula (3) or (4), n⑼ is the mole number of (al) aliphatic alcohol used for reaction; nG is the mole number of (al) aliphatic alcohol which is not reacted) . 10. If the detergent of the scope of application for item No. 8 is, the (C) cationic interface> the tongue agent is selected from the group consisting of the compounds represented by the following general formulae (6) to (9) 1 or more compounds; [Chemical 2] R RIN — RRX '本 ⑵㈣ 婚 Scope of Patent Application Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1230197 [化 3] [Chemical formula 4] "R0-CO〇CH2CH2-N + (CH2CH2〇H) qX- l R5 J ⑻ [Chemical formula 5] Γ RB-〇CH2CH2-N + (CH2CH2〇H) 2 V χ ~ l J ⑼ 1 i However, in the formulas (6) to (9), Ri, R2, and R3 refer to a hydrogen atom or an alkyl, alkenyl, or cold monohydroxyalkyl group having a carbon number of I to 24; R4 and R5 refer to a carbon number of I to I 24 alkyl group, hydroxyalkyl group, benzyl group or 10-Z-((A1 is an alkylene group having 2 to 4 carbon atoms; z is a hydrogen atom or a fluorenyl group; η is a An integer of 1 to 50); R6 is an alkyl, alkenyl, or 0-hydroxyalkyl group having 36 carbon atoms; γ is an alkyl group, alkenyl group, or / 3-hydroxy group Base, a base represented by the formula: R4c〇2CH2 (also 'R is the same as above) or a base represented by the formula: r4〇Ch2-(also, R4 is the same as the foregoing); It is selected from the group consisting of a carbonate ion or a sulfate ion having a halide ion, a hydroxyl ion, an alkyl group with a carbon number of ˜4, and an alkyl acid or an alkenyl methionate ion and a sulfonic acid ion with a carbon number of ˜4. More than one country in the group "(210 X 297 Gong) '-44- 1230197 C8. D8. * 6. Anion in the scope of patent application. 11. The cleaning agent according to item 4 of the patent application scope, wherein the cleaning agent contains (D) an organic amine salt or a quaternary ammonium salt of a low molecular weight polyvalent carboxylic acid. Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the national standard (CNS) A4 (210 X 297) 45